vinyl ester resins epovia optimum - gazechim ester_epovia.pdf · epovia® rf-1001, based on...

VINYL ESTER RESINS EPOVIA® OPTIMUM

“It may surprise you to know that CRAY

VALLEY is the largest resin and gelcoat

producer in the world as well as the

premier composite materials distributor.

Our range of high specifi cation products

are delivered to customers across fi ve

continents. (Europe, North America, South

America, Africa and Asia-Pacifi c)

This global presence is formed by the

combined force of COOK COMPOSITES

& POLYMERS (CCP) in North America

and CRAY VALLEY in all the other

parts of the world. Together, with the

backing and support of the chemicals

division of our parent company TOTAL,

we specialise in the development and

production of an impressive range of

solutions for the composite industry:

polyester and vinyl ester resins, gelcoats,

bonding pastes, low profi le additives,

VOC-free cleaning agents.

It is on this sound basis that CRAY

VALLEY is able to supply the complete

Polycor® range – the world’s number

one selling gel coat – to all of our

customers, wherever they are.

Using cutting edge techniques

and state of the art equipment, our

production facilities consistently

produce Norsodyne® polyester resins,

Enydyne® DCPD resins, Epovia® vinyl

esters, Polycor® gel coats, Gravicol®

bonding pastes, Norsolook® additives

and Thermaclean® cleaning agents to

rigorously accurate standards for superior

performance. In fact, the undeniable

quality of our products is recognised

worldwide, conforming as they do to

industry standards.

A long term strategy of investment in Plant

& Technology – Research & Development

– and of course highly skilled Technicians

& Operators has paid huge dividends

to all of our stakeholders and fi rmly

fi xes CRAY VALLEY’s position as a

market leader in the supply of composite

solutions.

It is reassuring to know that all CRAY

VALLEY products are formulated without

the use of cadmium and lead containing

pigments. This policy gives peace of

mind to all our customers who face ever

increasing legislation regarding the

handling and use of hazardous materials.

Our pigments are high quality organic

replacements already extensively used to

excellent effect in the automotive industry.

All CRAY VALLEY products are

manufactured and supplied in

accordance with ISO 9001 quality

control requirements.”

• A WORLD LEADER

CONTENTSAT A GLANCE

• A WORLD LEADER

• HISTORY BACKGROUND 2

• GENERAL DESCRIPTION 3

• ADVANTAGE OF CORROSION RESISTANT FRP 3

• EPOVIA® OPTIMUM 4

• EPOVIA® OPTIMUM RANGE 5

• REACTIVITY CURVES: EPOVIA® KRF-1001 6



• GENERAL FABRICATION TIPS 9

• COMPARISON OF CORROSION RESISTANT MATERIAL 10

• APPLICATION OF EPOVIA® OPTIMUM RESINS 11

• CHEMICAL CORROSION GUIDE 12

• SPECIAL PRECAUTIONS 29

March 1979 Started to produce vinyl ester resin, EPOVIA® RF-1001, based on technical tie-up with Nippon Shokubai Kagaku Kogyo (NSKK)

July 1986 Started to produce Novolac vinyl ester, EPOVIA® RF-1051, by the technology of NSKK

December 1988 Developed fi re retardant vinyl ester resin, EPOVIA® RF-2000 SE

December 1992 Developed HET acid based resin, especially for chromic acid resistant applications

January 2000 Developed Low Styrene Content vinyl ester resin, EPOVIA® RF-3000

August 2003 Developed rubber modifi ed vinyl ester resin, EPOVIA® RF-3200

June 2008 Developed brand-new vinyl esters: EPOVIA® OPTIMUM range (KRF 1001, KRF 1051 & KRF-2000)

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GENERAL DESCRIPTION

Commonly structures use glass-lining, rubber coating, metallic material such as stainless steel and PTFE for the corrosion resistance of equipment and plant projects. The EPOVIA® corrosion resistant resins can offer considerably higher resistance to attack, from various kinds of corrosive chemicals, than many other plastic or metallic materials. They are being used widely in fabricating industrial equipment and structures such as absorption towers, process vessels, storage tanks, pipes, hood, scrubbers, ducts and exhaust stacks. Its use is increasing at an accelerating rate over a broad rand of industrial applications.

ADVANTAGE OF CORROSION RESISTANT FRP Corrosion-resistant EPOVIA® products are generally used as FRP reinforced material with glass fi bres or synthetic fi bres for special purposes. In most applications, higher corrosion resistance can be obtained when the surface exposed to the chemical solutions has 80 to 90% resin content.

Corrosion EPOVIA® is equipped with outstanding resistanceresistance to corrosion attack from many different chemicals.

Light weight Corrosion resistant FRP is about one fi fth the weight of steel. EPOVIA® based structure can be designed to offer higher strength than steel on an equal weight basis. This property is called structural effi ciency or strength to weight ratio. By the selection of the reinforcing materials, a wide range of strength properties is available in FRP structures.

Heat resistance Thermosetting resins have higher degree of resistance to thermal aging than thermoplastic resin such as PVC and PE. And thermosetting resins are much stronger at low temperature environment as well.

Thermal Thermal conductivity values for the corrosion resistant FRP isconductivity in the order of magnitude of 200 times lower than that of carbon steel and therefore it results in superior insulation.

Chemical FRP structures have high resistance to chemical attack,stability resulting in long term structural integrity during its service.

Clear casting properties The clear nature of EPOVIA® resins allows for improved internal inspection.

Lamination EPOVIA® resins can be applied in many types of ways, for example via hand lay-up, spray-up, RTM, fi lament winding, pultrusion, etc…

A corrosion barrier is also suggested for the exterior layer where spillage of aggressive chemicals may occur.

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EPOVIA® vinyl ester resins

EPOVIA® vinyl esters possess outstanding corrosion resistance against many kinds of chemicals including both acids and alkalis, at room and elevated temperature. It has high impact resistance and offers signifi cant cost-saving advantages through construction, installation, and continuing use such as absorption towers, process vessels, storage tanks, pipes, hood scrubbers, ducts, and exhaust stacks.

EPOVIA® OPTIMUM

EPOVIA® OPTIMUM has been developed as an innovative product to meet market needs for the highest performance. When compared to traditional vinyl esters it offers a high level of cure control and low reaction foam. This results in a far lighter colour in liquid state, castings and laminates as well as the ability to produce a high quality air free laminate. All of this is achieved whilst maintaining the balance of mechanical properties and the high level of corrosion resistance associated with EPOVIA®, which has 30 years of successful case histories. These enhanced properties of EPOVIA® OPTIMUM refl ects the market requirements for innovative technology whilst balanced with traditional Vinyl ester properties.

Main benefi ts of EPOVIA® OPTIMUM

• Lighter colour than conventional vinyl ester • Easy-to-fabricate (easy control for gel time and exothermic temperature) • Enhanced storage stability • Customer-friendly for thin or thick laminates • Less foaming • Same corrosion resistance as the same grade of EPOVIA®

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KRF-1001 Bisphenol A epoxy vinyl ester. Designed for high corrosion resistance to a range of acids, alkalis and solvents. High elongation with balanced mechanical properties. Widely used for contact molding, closed molding, pultrusion and fi lament winding. 3.7 15 58% 148 3.6 4.0% 101°C

KRF-1051 Novolac epoxy vinyl ester. Exceptional chemical resistance and excellent heat resistance due to its high cross-linked backbone. 4.7 25 70% 134 3.4 3.0% 150°C

KRF-2000 Fire retardant epoxy vinyl ester. Offers the same chemical resistance as KRF-1001. Widely used to handle fl ammable liquids and mixture of hot gases in FRP ducts, scrubbers and stacks. 3.5 15 65% 143 3.5 3.6% 117°C

FLEXURAL FLEXURAL EPOVIA® OPTIMUM TYPE VISCOSITY GEL TIME SOLID STRENGTH MODULUS ELONGATION HDT dPa.s minutes CONTENT MPa GPa AT BREAK

EPOVIA® OPTIMUM Range

• Special vinyl esters, such as low styrene content, rubber modifi ed or primer are also available upon request.• Brookfi eld viscosity measured at 50 rpm at 23°C. Gel time: 1.5% K12 / LPT + 0.5% NL23 at 23°C. Mechanical properties are measured on pure resin, after post-curing. (2 hours at 80°C and 1 hour at 120°C)• Many other technical information are available upon request (cut in gel, exotherm properties, glass impregnation properties, interlaminar adhesion,…)

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% of NLC10

NL23 (%) Gel time (min.)KRF-1001

0,20 450,45 170,60 121,00 7

NLC10 (%) Gel time(min.)

0,00 360,05 400,10 500,20 76

% Cobalt Gel time(min.)

0,10 1280,20 650,30 480,40 -0,50 38

% NLC10 Gel time(min.)

0,00 50,20 120,40 210,80 68

Fig.1:1.5% K12 / LPT (23°C)

Fig. 2:1,5% K12 / LPT + 0,1% Co (6%) + 0.04% DMA (25°C)

Fig. 3:1,5% K12 / LPT + 0,02% DMA (15°C)15°C is the lowest temperature to make FRP parts.

Fig. 4:1,5% K12 / LPT + 0.3% Co (6%) + 0,06% DMA (35°C)35°C is the highest temperature to make FRP parts.

Reactivity is under infl uence of temperature, metals, salts, amine content and peroxide. The curing is exothermic and should be run under control to avoid delamination in thick laminate and stress due to warpage. Cumene hydroperoxide is often used to reduce foaming and better control gel time and exotherm. Other reactivity curves are available upon request. LPT stands for Butanox LPT. K12 stands for Luperox K12.

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NL23 (%) Gel time(min.)

0,20 540,45 300,60 201,00 10

NLC10 (%) Gel time(min)

0,00 440,05 500,10 53


0,10 1900,20 1200,30 860,40 720,50 70


0,00 70,20 110,40 180,80 28

Fig.1:1.5% K12 / LPT (23°C)

Fig. 2:1,5% K12 / LPT + 0,1% Co (6%) + 0.04% DMA (25°C)


Fig. 4:1,5% K12 / LPT + 0.3% Co (6%) + 0,06% DMA (35°C)35°C is the highest temperature to make FRP parts.

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NL23 (%) Gel time(min.)

0,20 320,45 130,60 101,00 7

NLC10 (%) Gel time(min.)

0,00 200,05 260,10 36


0,10 960,20 490,30 380,40 320,50 29


0,00 40,20 100,40 160,60 28

Fig.1:1.5% K12 / LPT (23°C)

Fig. 2:1,5% K12 / LPT + 0,1% Co (6%) + 0.04% DMA (25°C)


Fig. 4:1,5% K12 / LPT + 0.3% Co (6%) + 0,06% DMA (35°C) 35°C is the highest temperature to make FRP parts.

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STANDARD REQUIREMENTS FOR PROCESS Corrosion The layer is mainly comprised of minimum 0.25-0.50 mm thickness resistant barrier of resin by using C-glass surface mat or synthetic veil. Support Minimum 3-5mm of layer has to be reinforced with chopped Barrier strand mat or gun roving, i.e. discontinuous strands. Structural The reinforced layer must meet tensile and fl exural strength suitablelaminates for anti-corrosion structure. When applying layers of mat, woven roving and yarn cloth, each layer has to be overlapped by at least 25 mm when laminated. When woven roving or yarn cloth is applied, chopped strand mat has to be used within alternate layers of roving or yarn cloth. Thickness A minimum corrosion barrier and support barrier is required in allof laminates structures, typically 3.2 mm for ducts and 4.8 mm for pipes or tanks. Appearance Final laminated products should not have defects such as insuffi cient impregnation of mat, air bubbles and pinholes, also be free from contamination of foreign particles or substances. Dosage Vinyl ester will not completely cure if the dosage of promoter & hardenerof Promoter/ is too low or if it is not dispersed adequately. When vinyl ester is not cured Hardener well, post-cure will not be effective. The key to obtaining good resistance to the chemicals is to have a well-cured laminate. Please refer to the standard cure conditions mentioned in the individual product data sheet. Post-cure Post-cure should be carried out to reach the optimum corrosion resistance of laminates. Recommendation: 1 hour per mm thickness (between 4 and 10 hours) at 80°C Wax solution To cure the air-contacting surface of laminates, paraffi n wax solution should be used. Recommendation: 3 parts of 5% paraffi n wax solution per 100 parts of resin in the fi nal ply.

STANDARD OF LAMINATIONTypical structural lay-up of Chemical resistant FRP Products is illustrated below

Topcoat or Corrosion Resistant barrier with surfacing mat/veil (0.25 – 1mm)

Support barrier with chopped strand mat (3~5mm)

Structural Laminate built to required strength

Gelcoat, if necessary for UV resistanceof chemical vessel, or primer if lining

C H E M I C A L S

O U T E R L AY E R O R S U B S T R AT E

Specifi c gravity 1.43-1.47 1.36-1.40 7.91 8.00 8.80 2.84 1.45 1.64 0.91

Tensile strength (kg/mm2) 12 12 46.4 59.6 59.6 8.5 5.0-6.0 1.9-3.5 2.5-3.8

Young modulus (kg/mm2x102) 9.0 9.0 211 197 183 70 2.4-4.2 0.7-4.2 1.1-1.4

Coef. of thermal expansion(cm/cm.°Cx10-5 ) 2.1 2.3 1.2 1.6 1.1 2.4 7.0 12-13 11.0

Thermal conductivity(kcal/mhr.°C) 0.22 0.22 41.5 14.0 9.7 199.5 0.13 0.10 0.08

Structural effi ciency(specifi c strength) 6.1-12.9 6.1-12.9 2.9 3.1 4.0 1.0 1.7-2.9 1.2-2.1 2.8-4.2

Chloroacetic acid O O X X O X O X X 99% max 60°max

Oxalic acid O O X X X X O O O 60°max

H2SO4 dil. O O X O O X O O O 5% max 60°max

H2SO4 conc. O O O O O X O O O 75% max 75% max 85% min 85% min 25°C 60°max 25°C 50%/80°Cmax

HCI dil. O O X X O X O O O 60°max

HCI conc. O O X O O X O X O 60°max 36%/20°Cmax

H3PO4 conc. O O X O O X O O O 60°max 95% max

HF O O X X X X O X O 20% max 20% max 25°max

H2SiF6 O O X X X X O X O 35% max 35% max 60°max

NaOH dil. O O O O O X O O O 50% max 50% max 20% max 77% max 60°max 50% max 38%/80°Cmax

KOH dil. O O X X O X O O O 50% max 50% max 60°max

Ammonia Water O O X O O X X O O 50% max

NaOCI ClO2 , CI2 O O X X O X O X X

NH4Cl O O X X O X O O O 50% max 50% max 60%/25°Cmax

Acid chloride salts O O X X O X O X X 70%/40°Cmax 70%/40°Cmax 25%/25°C

EPOVIA EPOVIA Carbon Stainless Hastelloy Neoprene Poly- RF-1051 RF-1001 steel steel C Aluminum PVC rubber propylene Mat laminate Mat laminate (SS41) (SUS32)

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INDUSTRY APPLICABLE PARTS

Pulp & Paper Bleaching tank, washer tank, general bleaching facilities, scrubber, absorbing tower, waste water tank, gas pipe, storage chest, hoods, covers

Textile Raw material tank, neutralizing tank, washing tank, absorbing tower, bleaching tank, mangle bath, rinsing tank, waste liquid pipe, ducts, hoods, fans, covers and linings

Chemicals Chemical plant: raw material tank, pipe, fl ange, duct, pump, valve, strainer, fi lter press, reacting tank, …

Food & Drug Storage tank, transportation tank, pure water tank, processing equipment, container and lining

Metals Pickling tank, waste treatment tank

Mining Electrolyzing tank, galvanizing tank, absorbing tower, scrubber, washing tank, waste liquid pipe, various pipes, fans, ducts, equipment and fl oor lining

Pollution Treatment Desulphurization facilities, lining and fi lter press for waste water treatment plant

Transportation Transportation container, tanker vehicles

Power plant Desulphurization facilities, waste water pipe

Hot springs Hot water pipe, water tanks, tile joints

Oil Oil transportation pipe, storage tank, sea water pipes

Note: Since many variables that affect the performance of laminates are beyond of CRAY VALLEY’s control, no warranty concerning any use of EPOVIA® resin can be made. However, service conditions shown in this document are believed acceptable within the properties of EPOVIA® when laminates are properly designed, fabricated and installed.

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Acetaldehyde CR 20 35 40 35

Acetaldehyde CR 100 NR NR NR

Acetic Acid CR 25 100 100 100



Acetic Acid, Glacial CR 100 NR 30 NR

Acetic Anhydride CR 100 NR 35 NR

Acetone CR 2 50 70 50

Acetone CR 10 TC 60 TC

Acetone CR 100 NR NR NR

Acetonitrile CR 20 40 40 40

Acetonitrile CR 100 NR TC NR

Acetyl Acetone CR 20 40 50 40

Acetyl Acetone CR 100 NR TC NR

Acrolein (Acrylaldehyde) CR 20 40 40 40

Acrolein (Acrylaldehyde) CR 100 NR TC NR

Acrylamide CR 50 35 40 35

Acrylic Acid CR 25 40 40 40

Acrylic Acid CR 100 NR 40 NR

Acrylic Latex CR All 80 80 80

Acrylonitrile CR 20 40 40 40

Acrylonitrile CR 100 NR NR NR

Acrylonitrile Latex Dispersion CR 2 25 25 25

Activated Carbon Beds, Water Treatment CR 100 80 90 80

Adipic Acid A.S CR 100 80 80 80

Alcohol, Amyl and Butyl CR 100 50 65 50

Alcohol, Ethyl CR 95 25 40 25

Alcohol, Isodecyl CR 100 50 80 50

Alcohol, Propyl CR 100 50 50 50

Alkyl Aryl Sulfonate Salts CR All 60 60 60

Alkyl (C8-C10) Dimethyl Amine CR 100 80 100 80

Alkyl (C8-C18) Chloride CR All 80 100 95

Alkyl Aryl Ammonium Salt CR All 80 80 80

Alkyl Aryl Sulfonic Acid CR All 60 60 60

Alkyl Benzene Ammonium Salt CR All 80 80 80

Alkyl Benzene Sulfonic Acid CR All 60 60 60

Alkyl Phenol Polyglycol Ether Sulfates and Salts CR All 60 60 60

Alkyl Sulfonate CR All 60 60 60

Alkyl Sulfonic Acid CR All 60 60 60

Allyl Alcohol CR 100 NR 25 NR

Allyl Chloride CR 100 25 25 25

Alpha-Methylstyrene CR 100 TC 50 TC

Alpha-Oleum Sulfates CR 100 50 50 50

Alum CR All 100 120 100

Alumina Hydrate CR All 80 80 80

Aluminum Chloride CR Sat’d 100 120 100

Aluminum Chlorohydrate CR All 95 100 95

Aluminum Chlorohydroxide CR 50 95 95 95

Aluminum Fluoride DSV All 25 30 25

Aluminum Hydroxide DSV 100 75 95 75

Aluminum Nitrate CR Sat’d 85 90 85

Aluminum Potassium Sulfate CR Sat’d 100 120 100

Aluminum Sulfate CR Sat’d 100 120 100

Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)

Maximum Service Temperature (°C) for EPOVIA® OPTIMUM Resins

Please see the last page for ‘NOTES’

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KRF-1001 KRF-1051 KRF-2000 (%)

Amine Salts CR All 50 65 50

Amino Acids CR All 40 45 40

Ammonia Gas (Dry) CR 100 30 40 30

Ammonia Vapors (Wet) CR 40 vol% 80 80 80

Ammonia, Liquifi ed Gas CR 100 NR NR NR

Ammonium Acetate CR All 25 40 25

Ammonium Bicarbonate CR 0-50 70 70 70

Ammonium Bicarbonate CR Sat’d 60 70 60

Ammonium Bifl uoride CR All 65 65 65

Ammonium Bisulfi te Black Liquor CR All 80 80 80

Ammonium Bisulfi te Cooking Liquor CR 100 65 65 65

Ammonium Bromate CR All 70 80 70

Ammonium Bromide CR All 70 80 70

Ammonium Carbonate CR All 60 70 50

Ammonium Chloride CR All 100 100 100

Ammonium Citrate CR All 65 65 65

Ammonium Fluoride CR All 65 65 65

Ammonium Hydroxide DSV 5 60 80 60



Ammonium Lauryl Sulfate CR All 50 50 50

Ammonium Ligno Sulfonate CR All 80 80 80

Ammonium Molybdate CR All 65 45 45

Ammonium Nitrate CR All 100 120 100

Ammonium Oxalate CR All 65 45 45

Ammonium Pentaborate CR All 50 40 40

Ammonium Perchlorate CR 0-15 75

Ammonium Persulfate CR All 80 80 80

Ammonium Phosphate, dibasic CR All 95 100 95

Ammonium Phosphate, monobasic CR All 100 100 100

Ammonium Polysulfi de CR All 50 65 50

Ammonium Sulfate CR All 100 120 100

Ammonium Sulfi de (Bisulfi de) CR All 50 50 50

Ammonium Sulfi te CR Sat’d 65 65 65

Ammonium Thiocyanate CR 20 100 100 100

Ammonium Thiocyanate CR Sat’d 50 50 50

Ammonium Thioglycolate CR All 40 40 40

Ammonium Thiosulfate CR All 50 50 50

Amyl Acetate CR All 20 50 NR

Amyl Alcohol CR 100 50 65 50

Amyl Alcohol, Vapor CR 100 50 100 50

Amyl Chloride CR 100 50 50 50

Aniline CR 20 40 40 40

Aniline CR 100 NR NR NR

Aniline Hydrochloride CR All 80 80 80

Aniline Sulfate CR All 100 100 100

Animal Fat CR 100 80

Anionic Surfactant CR All 40 50 40

Aqueous Ammonia DSV 5 60 80 60

Aqueous Ammonia DSV 20 60 70 60

Arsenic Acid CR All 80 80 80

Barium Acetate CR All 80 80 80

Barium Bromide CR All 95 95 95



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Barium Carbonate CR All 100 120 100

Barium Chloride CR All 100 100 100

Barium Cyanide CR All 65 65 65

Barium Hydroxide CR All 65 65 65

Barium Sulfate CR All 80 80 80

Barium Sulfi de CR All 80 80 80

Barley Solution CR > 0.5 75 NR NR

Beer CR > 0.5 50 NR NR

Beet Sugar Liquor CR > 0.5 80 NR NR

Benzaldehyde CR 100 NR NR NR

Benzalkonium Chloride CR Diluted 40

Benzene CR 100 NR 40 NR

Benzene Sulfonic Acid CR 50 65 65 65

Benzene, Vapor CR 100 25 40 NR

Benzoic Acid CR All 100 100 100

Benzyl Alcohol CR 20 40 50 40

Benzyl Alcohol CR 100 NR 40 NR

Benzyl Chloride CR 100 NR 25 NR

Benzyltrimethylammonium Chloride CR 60 40 40 40

Bicarbonate CR 50 60 70 60

Black Liquor (Pulp & Kraft Mill) DSV Thick 90 100 105

Black Liquor (Pulp & Kraft Mill) DSV Thin 80 80 80

Black Liquor Recovery, Furnace Gases CR 100 165 205 165

Borax CR All 100 100 100

Boric Acid CR All 100 100 100

Boron Trichloride Scrubbing CR > 0.5 65 65 65

Brake Fluids CR 100 50 50 50

Brine, Salt CR All 100 100 100

Brominated Phosphate Ester CR > 0.5 50

Bromine, Dry and Wet Gas CR All 30 40 30

Bromine, Liquid CR 100 NR NR NR

Brown Stock CR 100 90 80 90

Bunker C Fuel Oil (Heavy fraction) CR 100 100 105 100

Butadiene (Gas) CR 100 45 45 45

Butane CR 100 60 60 60

Butanol CR 100 50 65 50

2,2-Butoxy Ethoxy Ethanol CR 100 40 40 40

Butyl Acetate CR 100 NR 30 NR

Butyl Acrylate CR 100 NR 25 NR

Butyl Alcohol CR All 50 65 50

Butyl Alcohol / Benzene CR 93/4 NR 50 NR

Butyl Amine CR 100 NR NR NR

Butyl Benzoate CR 70 NR 40 NR

Butyl Benzyl Phthalate CR 100 80 100 80

Butyl Carbitol, Diethylene Glycol Butyl Ether CR 100 40 40 40

Butyl Chloride CR 0.1 - 100 NR 25 NR

Butyl Hypochlorite CR 98 NR NR NR

Butyl Stearate (5% in Mineral Spirits) CR All NR 40 NR

Butylene Glycol CR 100 70 80 70

Butylene Oxide CR 100 NR NR NR

Butyraldehyde CR 100 NR 35 NR

Butyric Acid CR 50 100 100 100

Butyric Acid CR 100 30 45 30

Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)



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Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)

Cadmium Chloride CR All 100 100 100

Calcium Bisulfi te CR All 100 100 100

Calcium Bromide CR All 100 100 100

Calcium Carbonate (slurry) CR All 80 80 80

Calcium Chlorate CR All 100 120 100

Calcium Chloride CR All 100 120 100

Calcium Hydroxide DSV 25 90 100 90

Calcium Hydroxide DSV 100 90 90 90

Calcium Hypochlorite DSV+BPO 20 80 100 80

Calcium Hypochlorite DSV+BPO+PC All 70 80 70

Calcium Nitrate CR All 100 100 100

Calcium Sulfate CR All 100 120 100

Calcium Sulfi te CR All 100 100 100

Cane Sugar Liquor & Sweetwater CR All 80 80 80

Capric Acid (Decanoic Acid) CR All 80 80 80

Caproic Acid (Hexanoic Acid) CR 100 25 50 25

Caprolactam CR 100 NR TC NR

Caprolactam CR 0-50 40 40 40

Caprolactone CR 100 NR TC NR

Caprylic Acid (Octanoic Acid) CR 100 80 100 80

Caramel CR All 50

Carbon Dioxide Gas CR All 160 205 165

Carbon Disulfi de CR 100 NR TC NR

Carbon Disulfi de, Dry fumes CR, NCC Fumes 40 60 40

Carbon Monoxide Gas CR - 160 205 165

Carbon Tetrachloride CR 100 65 80 45

Carbon Tetrachloride, Vapor CR All 70 90 60

CARBOWAX Polyethylene Glycol CR 100 65 80 65

Carboxyethyl Cellulose CR 10 65 65 65

Carboxymethyl Cellulose CR All 65 65 65

Cashew Nut Oil CR 100 65 65 65

Castor Oil (Ricinus Oil) CR 100 70 70 70

Cationic/Anionic Polymer Emulsions in Petroleum Distillates/Water CR 0 - 50 40 50

Cetyl Alcohol (Hexadecanol) CR 100 65 80 65

Chlordimeform (Galecron Insecticide) CR 100 25 50 25

Chloric Acid CR All 25 25 25

Chlorinated Brine, pH < 2.5 DSV+BPO Sat’d Cl2 80 95 80

Chlorinated Brine, pH > 9 (Hypochlorite) DSV+BPO Sat’d Cl2 80 65 80

Chlorinated Pulp CR All 80 95 90

Chlorinated Wax CR All 80 80 80

Chlorination Washer (Hoods & Vent Systems) CR Vapors, All 80 95 80

Chlorine Dioxide DSV All 60 65 50

Chlorine Dioxide Scrubber DSV+BPO 75 75

Chlorine Dioxide, No Chlorine (Bleaching Solution) CR All 80 95 90

Chlorine Dioxide,Solution Storage CR 100 20 20 20

Chlorine Dry Gas DVC 100 100 120 100

Chlorine Water, pH < 2.5 CR Sat’d Cl2 80 95 80

Chlorine Water, pH > 9 DSV+BPO Sat’d Cl2 80 65 80

Chlorine Water, pH 2.5-9 CR Sat’d Cl2 TC TC TC

Chlorine, Wet Gas DSV 100 100 120 100

Chlorine-Hydrogen Chloride, with Aqueous Condensate DSV+DVC+ECR 8-10% HCl 80 100 80



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Chloroacetic Acid CR 0-25 50 50 50



Chloroacetic Acid CR 86 - 100 NR NR NR

Chlorobenzene CR 100 NR 40 NR

Chloroform CR 100 NR. NR. NR.

Chloroform, Dry fumes CR, NCC Fumes 80 80

Chloropentane (1 to 5 Cl) CR 100 40 55 40

Chloropicrin (Nitrochloroform) CR 100 NR TC NR

Chloropropionic acid CR 100

Chloropyridine (Tetra) CR 100 25 50 25

Chlorosulfonic Acid CR 10 NR NR NR

Chlorotoluene CR 100 25 40 25

Choline Chloride CR All 50 65 50

Chrome Reduction Process CR 25 90 90

Chromic Acid CR 10 65 65 60

Chromic Acid CR 20 40 50 40

Chromic Acid CR 30 NR NR NR

Chromic/Sulphuric Acid CR 10 TC TC TC

Chromium Plate, Electroplating with a Salt Solution CR 100 55 55 55

Chromium Sulfate, Water soluble forms CR All 100 100 100

Citric Acid CR All 100 100 100

Cobalt Chloride CR All 100 100 100

Cobalt Citrate CR All 80 80

Cobalt Nitrate CR All 100 100 100

Coconut Oil CR All 80 95 80

Cod-liver Oil CR All 40 40 40

Copper Chloride CR All 100 100 100

Copper Cyanide CR All 100 100 100

Copper Nitrate CR All 100 100 100

Copper Sulfate CR All 100 120 100

Corn Oil CR 100 80 100 80

Corn Starch CR Slurry 90 100 90

Corn Sugar/Syrup (Glucose) CR All 90 100 90

Cottonseed Oil CR 100 90 100 90

Crude Oil, Sweet, Sour CR 100 100 120 100

Cumene CR 100 25 50 25

Cyanuric Acid CR All 25 50 25

Cyanuric Chloride CR All 50 50 50

Cyclohexane CR 100 50 65 50

Cyclohexanol CR 100 35

Cyclohexylamine CR 100 30

Cyclopentane CR 100 40 50 40

Decanoic Acid CR All 80 80 80

Decanol CR 100 50 80 50

Detergents, Organic CR 100 70 95 70

De-waxed Paraffi n Distillate CR 100 80 80 80

Di-2-Ethylhexyl Phosphoric Acid in Kerosene CR 20 80 80 80

Diacetone Alcohol CR 10 40 50 40

Diacetone Alcohol CR 100 NR NR NR

Diallyl Phthalate CR All 80 100

Diammonium Phosphate CR All 100 100 100

Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)



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Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)

Dibromonitrilo-Proprionamide CR 100 NR 40 NR

Dibromophenol CR 100 NR 40 NR

Dibromopropane CR 100 NR 40 NR

Dibromopropanol CR 100 40

Dibutyl Carbitol (Diethylene glycol dibutyl ether) CR 100 25 40 25

Dibutyl Ether CR 100 25 65

Dibutyl Phthalate CR 100 80 100 80

Dibutyl Sebacate CR 100 50 65

Dichlorobenzene (o-, m-, p-) CR 100 NR 50 NR

Dichloroethane CR 100 NR 25 NR

Dichloroethylene CR 100 NR NR NR

Dichloromethane (Methylene Chloride) CR 100 NR TC NR

Dichloropropane CR 100 NR 40 NR

Dichloropropene CR 100 NR 25 NR

Dichloropropionic Acid CR 100 NR 40 NR

Dichlorotoluene CR 100 25 50 25

Diesel Engine Oil CR 100 80 100 72

Diesel Fuel CR 100 80 90 70

Diethanolamine CR 100 50 65 50

Diethyl Benzene CR 100 40 65 30

Diethyl Carbonate CR 100 NR 40 NR

Diethyl Ether CR 100 NR NR NR

Diethyl Formamide CR 20 40 40 40

Diethyl Formamide CR 100 NR NR NR

Diethyl Hydroxylamine CR 100 NR TC NR

Diethyl Ketone CR 20 40 50 40

Diethyl Ketone CR 100 NR NR NR

Diethyl Sulfate CR 100 40 50 40

Diethylamine CR 20 40 40 40

Diethylamine CR 100 NR NR NR

Diethylaminoethanol CR 100 50 50 50

Diethylbenzene CR 100 40 65 40

Diethylene Glycol CR All 80 100 80

Diethylene Glycol Dimethylether CR 20 40 40 40

Diethylene Glycol Dimethylether CR 100 NR NR NR

Diethylene Glycol n-Butyl Ether CR 100 40 40 40

Diethylenetriaminepentaacetic Acid CR All 40 50 50

Diethylenetriaminepentaacetic Acid,sodium salt CR 40 40 50 50

Diglycolamine (Aminoethoxyethanol) CR 20 40 50 40

Diglycolamine (Aminoethoxyethanol) CR 50 40 40 40

Diglycolamine (Aminoethoxyethanol) CR 100 NR TC NR

Diisobutyl Ketone CR 100 NR 50 NR

Diisobutyl Phthalate CR 100 65 65 65

Diisobutylene CR 100 30 40 30

Diisonoyl Phthalate CR 100 65 100 65

Diisopropanolamine CR 100 50 65 50

Dimethyl Acetamide CR 20 40 40 40

Dimethyl Acetamide CR 100 NR NR NR

Dimethyl Acetamide, Dry fumes CR Fumes 80 80

Dimethyl Amine CR 20 40 40 40

Dimethyl Amine CR 40 NR NR NR

Dimethyl Aniline CR 100 NR 40 NR

Dimethyl Formamide CR 20 40 40 40



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Dimethyl Formamide CR 100 NR NR NR

Dimethyl Formamide, Dry fumes CR, NCC Fumes 80 80

Dimethyl Morpholine CR 100 NR 40 NR

Dimethyl Phthalate CR 100 65 80 65

Dimethyl Sulfate CR 20 40 50 40

Dimethyl Sulfate CR 100 NR NR NR

Dimethyl Sulfi de CR 100 NR 25 NR

Dimethyl Sulfoxide CR 20 40 40 40

Dimethyl Sulfoxide CR 100 NR NR NR

Dimethyl Sulfoxide (DMSO) in Water CR 20 20

2,2-Dimethyl Thiazolidine CR 1 65 80 65

Dimethylammonium Hydrochloride CR 70 40 50 40

Dimethylcarbonate CR 100 NR NR NR

Dioctyl Phthalate CR 100 65 100 65

Diphenyl Oxide (Diphenyl Ether) CR 100 25 50 25

Dipotassium Phosphate CR All 100 100 100

Dipropylene Glycol CR All 80 100 80

Dipropylene Glycol Monomethyl Ether CR 20 40 65 50

Dipropylene Glycol Monomethyl Ether CR 100 NR 20 NR

Divinyl Benzene CR 100 30 47 30

Dodecanol (Lauryl Alcohol) CR 100 65 80 65

Dodecene CR 100 65 80 65

Dodecyl Benzene Sulfonic Acid CR All 80 100 80

Dodecyldimethylamine CR 100 80 100 80

Dodecylmercaptan CR 100 80 100 80

Epichlorohydrin CR 100 TC 25 NR

Epoxidized Castor Oil CR All 40 40 40

Epoxidized Soybean Oil CR 100 65 65 65

Esters, Fatty Acid CR 100 80 80 80

Ethanol (Ethyl Alcohol) CR 10 50 65 50

Ethanol (Ethyl Alcohol) CR 50 40 60 30

Ethanol (Ethyl Alcohol) CR 100 NR NR NR

Ethanol (Ethyl Alcohol) CR 51-95 25 40 25

Ethanol, Dry fumes CR, NCC Fumes 65 80 65

Ethanolamine CR 20 40 50 40

Ethanolamine CR 100 25 40 25

Ethephon CR 100 40

Ethoxy Acetic Acid CR 10 40

Ethoxy Acetic Acid CR 100 NR TC NR

Ethoxylated Alcohol, C12-C14 CR 100 25 50 25

Ethoxylated Nonyl Phenol CR 100 NR 40 NR

Ethyl Acetate CR 100 NR 25 NR

Ethyl Acetate, Dry fumes CR, NCC Fumes 80 60

Ethyl Acrylate CR 100 NR 25 NR

Ethyl Alcohol (see Ethanol)

Ethyl Amine CR 20 40 40 40

Ethyl Amine CR 40 NR 25 NR

Ethyl Amine CR 70 NR TC NR

Ethyl Bromide CR 100 NR NR NR

Ethyl Chloride CR 100 NR 25 NR

Ethyl Ether CR 100 NR NR NR

2-Ethyl hexanol CR 100 65 80 65

Ethyl Sulfate CR 100 40 40 40

Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)



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Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)

Ethyl-3-Ethoxy Propionate CR 100 NR 25 NR

Ethylbenzene CR 100 25 50 25

Ethylene Chloride CR 100 NR 25 NR

Ethylene Chlorohydrin CR 20 40 65 50

Ethylene Chlorohydrin CR 100 40 40 40

Ethylene Diamine CR 20 40 40 40

Ethylene Diamine CR 100 NR TC NR

Ethylene Dibromide CR 100 NR NR NR

Ethylene Dichloride CR 100 NR 25 NR

Ethylene Glycol CR 100 100 100 100

Ethylene Glycol Monobutyl Ether CR 20 40 65 40

Ethylene Glycol Monobutyl Ether CR 100 40 40 40

Ethylene Oxide CR 100 NR NR NR

Ethylene Tetrachloride CR 100 30 50 30

Ethylenediaminetetraacetic Acid (EDTA) CR All 80 80 80

Ethylenesulfonic Acid, Sodium Salt CR All 70 70 70

Eucalyptus Oil CR 100 60 60 60

Fatty Acid/Sterol/Triglyceride CR All 100 120 100

Fatty Acid/Sulfuric Acid CR 5 100 100 100

Fatty Acids CR All 100 120 100

Ferric Acetate CR All 80 80 80

Ferric Chloride CR All 100 100 90

Ferric Chloride/Ferrous Chloride CR 5/20 95 100 95

Ferric Sulfate CR All 100 100 90

Ferrous Chloride CR All 90 100 90

Ferrous Nitrate CR All 100 100 90

Ferrous Sulfate CR All 100 100 90

Flue Gas, Dry DSV All 160 200 160

Flue Gas, Wet DSV All 80 100 80

Fluoroboric Acid DSV 10 85 100 85

Fluoroboric Acid DSV 25 40 60 40

Fluorine in Flue Gas, Wet DSV 2 80 100 80

Fluorosilicic Acid DSV 10 80 80 70

Fluorosilicic Acid DSV 35 35 35 30

Fluorosilicic Acid, Fumes DSV All 80 80 80

Fly Ash Slurry CR 80 80 80

Formaldehyde CR All 65 65 50

Formamide CR 20 40 65 50

Formamide CR 100 20 20 20

Formic Acid CR 10 80 80 70



Fuel Oil CR 100 80 100 80

Furfural CR 100 NR NR NR

Furfural in Organic Solvent CR 0-20 NR 40 NR

Furfural in Water CR 5 40 50 35

Furfuryl Alcohol CR 20 40 65 40

Furfuryl Alcohol CR 100 NR 25 NR

Gallic Acid CR All 80 80 80

Gasoline CR 100 50 40 40

Gasoline (5% Methanol) CR 100 45 50 45

Gasoline (Up to 10% Alcohol) CR 100 40 50 40

Gasoline (10-100% Alcohol) CR 100 NR 40 NR



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Gasoline, Aviation CR 100 50 65 50

Gasoline, Leaded CR 100 50 65 50

Gasoline, No Lead, No Methanol CR 100 50 65 50

Glucose CR All 80 100 80

Glutamic Acid CR 50 50 50 50

Glutaraldehyde CR 50 50 50 50

Glutaric Acid CR All 50 50 50

Glycerine CR 100 100 100 100

Glycine and Derivatives CR All 40 40 40

Glycol CR 100 100 100 100

Glycolic Acid (Hydroxyacetic Acid) CR 10 80 80 80



Glyconic Acid CR 50 80 80 80

Glyoxal CR 40 40 40 40

Glyphosate CR All 40

Green liquor (Pulp Mill) DSV All 80 80 80

Gypsum Slurry CR All 100 100 100

Hard Chrome Plating Baths (no H2SO4) CR 100 60

Heptane CR 100 100 100 100

Heptane, Dry fumes CR, NCC Fumes 80 80 80

Hexachloroethane CR 100 TC 50 TC

Hexadecanol CR 100 65 80 65

Hexamethylenetetramine CR 40 40 50 40

Hexane CR 100 70 70 60

Hexanoic Acid CR 100 25 50 25

Hydrazine CR 20 TC TC TC

Hydrazine CR 100 NR TC NR

Hydriodic Acid CR 40 65 65 65

Hydriodic Acid CR 50 40

Hydrobromic Acid CR 25 80 80 80



Hydrochloric Acid DVC+ECR+CC 1-20 100 100 100






Hydrochloric Acid DVC+ECR+CC 37 40 50 40

Hydrochloric Acid and trace organics DVC+ECR+CC 0-33 60

Hydrochloric Acid, Fumes DVC+ECR+CC 100 90 130 90

Hydrocyanic Acid CR All 80 100 70

Hydrofl uoric Acid DSV, NG 10 60 65 60



Hydrogen Bromide, Dry Gas CR 100 80 100 80

Hydrogen Bromide, Wet Gas CR 100 80 80 80

Hydrogen Chloride, Dry Gas DVC+ECR+CC 100 100 170 80

Hydrogen Chloride, Wet Gas DVC+ECR+CC 100 100 110 80

Hydrogen Fluoride, Dry Gas DSV+BPO 100 80 80 80

Hydrogen Fluoride, Wet Gas DSV+BPO 100 40 40 40

Hydrogen Peroxide DSV+BPO 30 60 65 60

Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)



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Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)

Hydrogen Peroxide DSV+BPO 35 30 40 30

Hydrogen Peroxide DSV+BPO 50 NR NR NR

Hydrogen Sulfi de CR 5 100 150 100

Hydrogen Sulfi de, Aqueous CR All 100 100 100

Hydrogen Sulfi de, Dry Gas CR All 100 110 100

Hydroxyacetic Acid (see Glycolic Acid)

Hypochlorous Acid CR 10 80 80 75



Hypophosphorous Acid CR 0-50 50 50 50

Iodine, Crystals CR 100 65 65 65

Iodine, Vapor CR 100 65 80 65

Isoamyl Alcohol CR 20 65 80 65

Isoamyl Alcohol CR 100 50 65 50

Isobutyl Alcohol CR 20 65 80 65

Isobutyl Alcohol CR 100 50 65 50

Isodecanol (Isodecyl Alcohol) CR 100 50 80 50

Isononyl Alcohol CR 100 65 65 65

Isooctyl Adipate CR 100 50 65 50

Isooctyl Alcohol CR 100 65 65 65

Isopropanol Amine CR 100 50 50 50

Isopropyl Alcohol CR All 40 50 30

Isopropyl Amine CR 30 40 40 40

Isopropyl Amine CR 100 NR TC NR

Isopropyl Myristate CR 100 100 110 90

Isopropyl Palmitate CR 100 100 110 100

Itaconic Acid CR 40 60 60 60

Jet Fuel, General CR 100 50 60 50

Kerosene CR 100 80 80 80

Lactic Acid CR All 100 100 100

Latex, Emulsion in Water CR All 50 50 50

Lauroyl Chloride CR 100 40 50 40

Lauryl Alcohol CR 100 65 80 65

Lauryl Chloride CR 100 100 100 100

Lauryl Mercaptan CR 100 80 100 80

Lead Acetate CR All 100 110 100

Levulinic Acid CR All 100 110 100

Lignin Sulfonate CR All 80 80 80

Limestone Slurry CR All 80 80 80

Linseed Oil CR 100 100 110 100

Liquid Petroleum Gas (LPG) CR 100 60 60 60

Liquid Sugar CR All 85 100 80

Lithium Bromide CR All 100 120 100

Lithium Carbonate DSV All 80 80 80

Lithium Chloride CR All 100 100 100

Lithium Hydroxide DSV All 80 40 80

Lithium Hypochlorite DSV+BPO+PC All 80 40 80

Magnesium Bisulfi te CR All 100 100 100

Magnesium Carbonate CR All 100 100 70

Magnesium Chloride CR All 100 120 90

Magnesium Fluosilicate DSV All 80 80 70

Magnesium Hydroxide DSV All 100 100 100

Magnesium Nitrate CR All 100 100 100



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Magnesium Oxide / Lime CR 0.1-10 100 100 100

Magnesium Phosphate CR All 100 100 100

Magnesium Sulfate CR All 100 120 90

Magnesium Sulfate / Phosphoric Acid CR 1-40 / 0-36 100 100 100

Maleic Acid CR All 100 100 100

Manganese Chloride (Manganous Chloride) CR All 100 100 100

Manganese Nitrate (Manganous) CR All 100 100 100

Melamine Formaldehyde Resin CR All 40 50 40

Mercaptoacetic Acid CR All NR 40 NR

Mercaptoethanol CR 10 80

Mercuric Chloride CR All 100 100 100

Mercurous Chloride CR All 100 100 100

Mercury CR All 100 120 100

Methacrylic Acid CR 40 40 50 40

Methacrylic Acid CR 100 NR 40 NR

Methane Sulfonic Acid CR All NR 40 NR

Methanol (Methyl Alcohol) CR 5 50 50 50

Methanol (Methyl Alcohol) CR 20 NR 40 NR

Methanol (Methyl Alcohol) CR 40 - 100 NR NR NR

Methanol, Dry fumes CR, NCC Fumes 80 60

Methoxy-2-Propanol CR 100 NR 20 NR

Methyl Acetate CR 20 40 40 40

Methyl Acetate CR 100 NR TC NR

Methyl Alcohol (see Methanol)

Methyl Bromide CR 10 25 25 25

Methyl Bromide CR 100 NR NR NR

Methyl Butyl Ketone CR 100 25 50 25

Methyl Chloride, Dry fumes CR, NCC Fumes 80 80

Methyl Chloride, Gas CR All 40 65 40

Methyl Ethyl Ketone CR 20 40 40 40

Methyl Ethyl Ketone CR 100 NR NR NR

Methyl Formate CR 5 40 50 45

Methyl Isobutyl Ketone CR 100 25 50 25

Methyl Mercaptan (Gas) CR All 40 65 40

Methyl Methacrylate CR All NR 25 NR

Methyl t-Butyl Ether CR 100 NR 25 NR

Methylamine CR 20 40 40 40

Methylamine CR 40 TC TC TC

Methylamine CR 100 NR NR NR

Methyldiethanolamine CR 20 50 80 50

Methyldiethanolamine CR 100 50 65 50

Methylene Chloride CR 100 NR NR NR

Methylene Chloride, Dry fumes CR, NCC Fumes 80 80

Methylstyrene (alpha) CR 100 25 50 25

Mineral Oils, Aliphatic CR 100 100 120 100

Mineral Spirit CR 100 100 120 100

Molasses CR 100 80

Monochlorobenzene CR 100 NR 40 NR

Monomethylhydrazine CR 100 NR NR NR

Morpholine CR 20 40 50 45

Morpholine CR 100 NR NR NR

Motor Oil CR 100 100 120 100

Myristic Acid CR 100 100 120 100

Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)



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Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)

Naphtha, Aliphatic CR 100 80 100 80

Naphtha, Aromatic CR 100 40 50 40

Naphtha, Heavy Aromatic CR 100 50

Naphthalene CR 100 100 100 100

N-Chloro-o-Tolyl (Insecticide Emulsion) CR 10 50 50 50

Neopentyl Glycol CR 100 80 80 80

Neutralizer & Desmut CR All 65 65 65

Nickel Chloride CR All 100 100 90

Nickel Nitrate CR All 100 100 90

Nickel Sulfamate CR All 80 80 80

Nickel Sulfate CR All 100 100 90

Nitric Acid DSV 5 65 80 60




Nitric Acid DSV 40 NR 25 25

Nitric Acid DSV 70 NR TC NR

Nitric Acid, Dry fumes DSV, NCC Fumes 70 80 70

Nitrobenzene CR 100 NR 40 NR

Nitrophenol CR 100 NR 40 NR

N-methyl-2-pyrrolidone CR All NR NR NR

o-Benzoyl Benzoic Acid CR All 100 100 100

Octanoic Acid CR 100 80 100 80

Oil, Sour and Sweet Crude CR 100 100 120 100

Oleic Acid CR All 90 90 90

Oleum (Fuming Sulfuric) CR 100 NR TC NR

Olive Oils CR 100 100 100

Oxalic Acid CR All 50 50 50

Ozone Gas CR 2 NR TC NR

Ozone in solution CR 2 mg/L 40 40 40

Palmitic Acid CR 100 100 100 100

Paraffi n wax CR All 80 95 80

Peanut Oil CR All 80 95 80

Pentabromodiphenyl Oxide CR 100 25 50 25

Pentachlorophenol CR All 50 50 50

Peracetic Acid DSV+BPO 20 40 40 40

Peracetic Acid DSV+BPO 35 NR TC NR

Perchloric Acid CR 10 65 65 40

Perchloric Acid CR 30 40 40

Perchloroethylene CR 100 25 50 25

Phenol CR 5 25 50 25

Phenol CR 10 NR 30 NR

Phenol CR 15 NR NR NR

Phenol Formaldehyde Resin CR All 40 50 40

Phosphoric Acid CR All 100 100 100

Phosphoric Acid, Vapor CR All 100 120 100

Phosphorous Acid CR 70 80 80 80

Phosphorus Oxychloride CR 100 NR TC NR

Phthalate esters CR All 50 60 50

Phthalic Acid CR All 100 100 100

Phthalic anhydride CR All 100 105 100

Picric Acid CR 10 NR 40 NR

Pine Oil CR 100 90 90 90



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Plating Solutions, Chrome DSV 60 60

Plating Solutions, Copper DSV 40 50

Plating Solutions, Gold DSV 80 90

Plating Solutions, Lead DSV 80 90

Plating Solutions, Nickel DSV 90 100

Plating Solutions, Zinc DSV 60 70

Polyacrylamide CR All 80 80 80

Polyacrylic Acid CR All 80 80 80

Polyethyleneimine CR All 80 80 80

Polyvinyl Acetate Adhesives CR All 50 50 50

Polyvinyl Alcohol CR All 80 80 80

Polyvinyl Chloride Latex with 35 parts Dioctylphthalate CR All 50 50 50

Potassium CR 10 60 65 60

Potassium Aluminum Sulfate CR All 100 120 100

Potassium Bicarbonate CR 10 60 65 60

Potassium Bicarbonate CR 50 80 80 70

Potassium Bromide CR All 100 100 100

Potassium Carbonate DSV 0-50 60 65 60

Potassium Chloride CR All 100 100 100

Potassium Cyanide CR All 60 60

Potassium Dichromate CR All 100 100 100

Potassium Ferricyanide CR All 100 100 100

Potassium Fluoride CR All 80 80 80

Potassium Gold Cyanide CR 12 100 100 100

Potassium Hydroxide DSV 0-45 60 65 60

Potassium Iodide CR All 65 65 65

Potassium Nitrate CR All 100 100 100

Potassium Oxalate CR All 65 65 65

Potassium Permanganate CR All 100 100 100

Potassium Persultate CR All 100 100 100

Potassium Pyrophosphate CR 60 55 65 55

Potassium Silicofl uoride DSV All 40 40 40

Potassium Sulfate CR All 100 100 100

Propane CR 100 60 60 60

Propanol (n-) CR 100 50 50 50

Propanol (n-), Dry fumes CR, NCC Fumes 80 80 80

Propionic Acid CR 0-50 80 80 80

Propionic Acid CR 100 NR 40 NR

Propionyl Chloride CR 100 NR TC NR

Propyl Acetate CR 100 NR 25 NR

Propyl Alcohol CR 100 50 50 50

Propyl Bromide CR 100 NR 25 NR

Propyl Chloride CR 100 NR 25 NR

Propylene Glycol CR All 100 100 100

Propylene Glycol Monomethyl Ether Acetate CR 20 40 50 40

Propylene Glycol Monomethyl Ether Acetate CR 100 NR 20 NR

Propylene Oxide CR 100 NR NR NR

Propylene Oxide, Dry fumes CR, NCC Fumes 80 80

Pyridine CR 20 40 40 40

Pyridine CR 100 NR NR NR

Quaternary Amine Salts CR All 80 80 80

Quinoline CR 20 40 40 40

Quinoline CR 100 NR NR NR

Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)



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Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)

Rayon Spin Bath CR Fumes 60

Rayon Spinning CR Fumes 60 60 60

Red Liquor CR All 80 80 80

Salicylic Acid CR All 80 90 70

Salt Brine CR Sat’d 100 120 100

Saturated Aqueous Chlorine CR All 80 100 80

Sea Water CR 100 100 100 100

Selenious Acid CR All 100 100 100

Silicone (grease-oil) CR 100 80 90 80

Silver Nitrate CR All 100 100 90

Sodium Acetate CR All 100 100 100

Sodium Alkyd Aryl Sulfonates CR All 80 80 80

Sodium Aluminate DSV All 70 50 70

Sodium Benzoate CR All 80 80 80

Sodium Bicarbonate DSV All 70 80 50

Sodium Bifl uoride DSV All 50 50 50

Sodium Bisulfate CR All 100 100 90

Sodium Bisulfi de (Hydrosulfi de) CR All 80 80 80

Sodium Bisulfi te CR All 100 100 100

Sodium Borate CR All 100 100 100

Sodium Bromate CR All 100 100 100

Sodium Bromide CR All 100 100 100

Sodium Carbonate DSV 0-35 65 65 55

Sodium Carbonate/Sodium Bicarbonate DSV 20/15 80 65 80

Sodium Chlorate CR 100 100 110 90

Sodium Chloride CR All 100 100 100

Sodium Chlorite CR 10 60 65 50

Sodium Chlorite CR 50 40 40 40

Sodium Chromate CR 50 100 100 100

Sodium Cyanide CR All 100 100 100

Sodium Dichromate CR All 100 100 100

Sodium Diphosphate CR All 100 100 100

Sodium Dodecylbenzene Sulfonate CR All 70 70 70

Sodium Ferrocyanide CR All 100 100 100

Sodium Fluoride CR All 80 80 80

Sodium Fluoroborate DSV All 90 90 90

Sodium Fluorosilicate DSV All 50 50 50

Sodium Glycolate CR All 80 100 80

Sodium Hexametaphosphate CR All 80 80 80

Sodium Hydrosulfi de CR All 80 80 80

Sodium Hydroxide DSV 0-50 80 90 80

Sodium Hypochlorite DSV 5 65 65 65

Sodium Hypochlorite DSV 21 80 80 80

Sodium Hypochlorite, pH>11(Active chlorine) DSV+BPO 24 TC TC TC

Sodium Lauryl Sulfate CR All 70 70 70

Sodium Metabisulfi te CR All 100 100 100

Sodium Methyldithiocarbamate CR All 80 80 80

Sodium Monophosphate CR All 100 100 100

Sodium Myristyl Sulfate CR All 70 70 70

Sodium Nitrate CR All 100 100 90

Sodium Nitrite CR All 100 100 100

Sodium Oxalate CR All 100 100 100

Sodium Perchlorate CR 60 40 40 40



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Sodium Persulfate CR All 100 100 100

Sodium Phosphate CR All 100 100 90

Sodium Phosphate, mono-,di-, tribasic CR > 0.5 100 100 100

Sodium Polyacrylate CR All 80 80 80

Sodium Sarcosinate CR 40 50 50 50

Sodium Silicate CR All 100 100 100

Sodium Sulfate CR All 100 100 100

Sodium Sulfi de CR All 100 100 100

Sodium Sulfi te CR All 100 100 100

Sodium Tartrate CR All 100 100 100

Sodium Tetraborate CR All 80 80 80

Sodium Thiocyanate CR All 80 80 80

Sodium Thiosulfate CR All 80 80 80

Sodium Tripolyphosphate CR All 100 100 100

Sodium Xylene Sulfonate CR All 70 70 70

Sorbitol Solutions CR All 70 80 70

Soy Sauce CR All 70 70

Soya Oil CR All 100 100 100

Spearmint Oil CR 100 40

Stannic Chloride CR All 100 100 100

Stannous Chloride CR All 100 100 100

Steam, Dry, No Condensation CR 100 100 105 100

Steam, Wet, Condensation CR 100 80 80 80

Stearic Acid CR All 100 100 100

Styrene CR 100 NR 50 NR

Styrene Acrylic Emulsion CR All 50 50 50

Styrene-Butadiene Latex CR All 60 60 60

Succinic Acid CR All 80 80 80

Succinonitrile, Aqueous CR All 25 40 25

Sugar Cane, Liquor & Sweetwater CR All 80 80 80

Sugar/Sucrose CR All 100 100 100

Sulfamic Acid CR 0-10 100 100 100



Sulfanilic Acid CR All 100 100 100

Sulfonated Detergents CR All 70 80 70

Sulfur Chloride CR 100 NR NR NR

Sulfur Chloride CR Fumes 80 90 80

Sulfur Dioxide, Dry or Wet CR Fumes 100 100 80

Sulfur Trioxide Gas CR Fumes 100 100 90

Sulfur Trioxide, Dry CR Fumes 100 100 100

Sulfuric Acid DSV+ECR+CC 25 100 100 100




Sulfuric Acid DSV+ECR+CC > 80 NR TC NR

Sulfuric Acid, Gas DSV+ECR+CC Fumes 100 170 100

Sulfurous Acid CR 10 50 50 50

Superphosphoric Acid, 76% P2O5 CR 100 100 100 100

Surfactant, Anionic CR All 40 50 40

Tall Oil CR 100 90 100 90

Tallow/Sulfuric Acid CR 99/1 80

Tannic Acid CR All 100 100 100

Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)



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Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)

Tartaric Acid CR All 100 100 100

t-Butyl Methyl Ether (MTBE) CR 20 40 50 40

t-Butyl Methyl Ether (MTBE) CR 100 NR 25 NR

Tetra n-Butylphosphonium Hydroxide DSV 40 40 40

Tetrabutyltin CR 100 50 50 50

Tetrachloroethane CR 100 40 55 40

Tetrachloroethylene (Perchloroethylene) CR 100 25 50 25

Tetrachloropyridine CR 100 25 50 25

Tetrahydrofuran CR 0-5 40 50 40

Tetrahydrofuran CR 10-100 NR TC NR

Tetrahydrofuran, Dry fumes CR, NCC Fumes 80 80

Tetramethyl Ammonium Hydroxide DSV 0-10 50 50

Tetrapotassium Pyrophospate CR 5 80 90 80

Tetrapotassium Pyrophospate CR 60 50 65 50

Tetrasodium Ethylenediaminetetraacetic Acid CR All 80 65 80

Thionyl Chloride CR 100 NR TC NR

Thiourea CR 0 - 50 65 65 65

Titanium Dioxide CR All 80 80 80

Titanium Dioxide/Sulfuric Acid CR 0 - 30/30 100 100 100

Titanium Tetrachloride CR All 65 80 65

Tobias Acid CR All 100 100 100

Toluene CR 100 25 49 20

Toluene, Dry fumes CR, NCC Fumes 60

Toluene Sulfonic Acid CR All 80 100 95

Toluidine (o-, p-, m-) CR 100 NR 20 NR

Tomato Sauce CR All 90

Transformer Oils (Ester types) CR 100 50 65

Transformer Oils (Silicone and Mineral) CR 100 100 150 110

Tribasic Sodium CR All 100 100 90

Tributyl Phosphate CR 100 50 60 50

Trichloroethane CR 100 TC 40 TC

Trichloroethylene CR 100 NR NR NR

Tricresyl Phosphate CR 100 70 70 70

Triethanol Amine CR 100 50 50 30

Triethylamine CR All 40 50 40

Trimethyl Ammonium Chloride CR 70 40 50 40

Trimethyl Benzene CR 100 25 50 25

Trimethylamine CR 20 40 50 40

Trimethylamine CR 100 25 40 25

Trimethylamine, Dry fumes CR, NCC Fumes 80 80

Trimethylene Chlorobromide CR 100 NR NR NR

Trioctylphosphate CR 100 60 60 50

Trisodium Phosphate CR Sat’d 100 120 100

Turpentine CR 100 65 100 65

Uranium Extraction Solutions Isodecanol / Alamine 336 / Kerosene CR 2,5/5,5/92 80 80 80

Urea CR 0 - 50 70 70 70

Urea / Ammonium Nitrate / Water CR 35/44/21 65 65 65

Urea Formaldehyde Resin CR All 40 50 40

Vegetable oil CR All 90 100 90

Vinegar CR All 100 100 100

Vinyl Acetate CR 20 40 40 40

Vinyl Acetate CR 100 NR NR NR



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Vinyl Chloride CR 100 NR NR NR

Vinyl Chloride, Dry fumes CR, NCC All 80 80

Vinyltoluene CR 100 25 50 25

Water Vapor, Wet CR Sat’d 80 80 80

Water, Deionized / Demineralized / Distilled CR 100 80 80 80

Water, Sea, Desalination CR All 80 80 80

Water, Steam Condensate CR 100 80 80 80

Water, Tap, Hard CR 100 100 100 100

Water, Tap, Soft CR 100 80 80 80

Whey (Milk plasma) CR All 65

White Liquor (Pulp Mill) DSV All 80 40 80

Xylene CR 100 25 50 25

Xylene, Dry fumes CR, NCC Fumes 80 80

Zinc Chloride CR Sat’d 100 120 100

Zinc Nitrate CR Sat’d 100 120 100

Zinc Phosphate (Slurry) CR All 80 80 80

Zinc Sulfate CR All 110 120 90

Chemicals

Notes Concentration

KRF-1001 KRF-1051 KRF-2000 (%)



Notes:

BPO: Amine/BPO cure recommendable

CC: Color change may occur during exposures to chemicals

CR: Classical Recommendation (Surface veil in anticorrosion barrier)

DSV: Double synthetic veil in the anticorrosion barrier (5 mm)

DVC: Double C glass veil in the anticorrosion barrier (5 mm)

ECR: ECR glass recommended in the anticorrosion barrier

NG: no glass on surface, no thixotropic resin

NR: Not Recommended

TC: Temporary Contact (less than 72 hours at 40°C. Check and clean after exposure)

Not only check the corrosion resistance for the chemical in contact with the FRP equipment,

but also check the corrosion resistance for the solvent that is used to dilute this chemical

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SCHEMICAL FEATURES 1) Products are best to used within 3 months of the manufacturing date. Avoid long-term storage of hardener and promoter. Pre-accelerated resin and thixotropic or pigmented resin must especially be treated with special care due to the possibilities of changes in chemical characters. (Products that have expired should be used only after contacting with Cray Valley sales team or the R&D centre.)

2) In the case of using unpromoted resin, mix promoter in advance and apply hardener agent just prior to work.

3) Treat all chemical substances carefully to prevent the danger of fi re. Special care should be taken with hardeners such as peroxides; these products can be especially dangerous when they are combined or dissolved with promoter, so they should be kept apart and stored separately.

4) Products must be used with working environment temperature of 15-35°C

5) Cray Valley EPOVIA® is a specially formulated product using an optimized level of styrene when manufactured. Any post added styrene monomer should not exceed 5%. Please note that before adding additional Styrene monomer in EPOVIA®, contact the Cray Valley sales team or the R&D centre for guidance.

6) The amount of the hardener used should follow the requirements of individual product datasheet. When the hardener is used under 0.7% of resin, then under curing is very likely to occur.

7) During the curing process, exothermic heat will occur and has the potential to lead to fi re. Therefore, all the working area should be managed in a proper way.

8) Products should be used only for industrial purposes. In the case of changing the application or end usage of the product, please contact Cray Valley sales team or the R&D centre.

9) If problems are experienced when using the resin or the products, stop using it immediately and please contact Cray Valley sales team or the R&D centre.

STORAGE GUIDANCE 1) Avoid direct sunlight or heat sources and store products at the temperature of 25°C or less

2) Products must be kept covered with lid to prevent deterioration from evaporating styrene or contamination.

3) Since the product is a fl ammable liquid, the product should only be used or stored in an area free from heat or ignition sources. Ensure adequate and appropriate fi re prevention systems are in place.

4) If fi re occurs, use dry chemical powder, CO2, water spray or foam. 5) The hardener, promoter and the EPOVIA® should be stored separately due to the potential danger of fi re.

6) When disposing of resin please follow the appropriate administrative regulations on waste materials.

CAUTION 1) Please refer to product MSDS for full safety requirements

2) Products are for industrial use only

3) Keep all products out of reach of children. 4) The working place must be open and well ventilated. Operators must wear masks and gloves for their safety.

5) Prevent contact with eyes and wash hands immediately after using resin, hardener or promoter. If contact occurs wash the eyes with water or boron dissolved water fi rst, then consult a doctor immediately.

6) When resin comes in contact with skin or clothing please wash off immediately.

29

LA DEFENSE 6 • 16/32 RUE HENRI REGNAULT • F-92902 PARIS LA DEFENSE CEDEX • FRANCE

TELEPHONE: +33 (0)1 47 96 98 64 - FAX +33 (0)1 47 96 99 98

www.crayvalley.com

For further technical or product information, please email:

[email protected]

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