versalis technologies and capabilities: not only a market ... · versalis technologies and...
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Versalis technologies and capabilities: not only a market opportunity Soccol Stefano –Vice President
IP, Licensing and Business Development
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1953-1954 eni acquires ANIC and inaugurates in Ravenna (Italy) one of the
largest centers of Italian petrochemical for the production of synthetic rubbers and nitrogen fertilizers derived from natural gas
Historical backgound
March 2012 Polimeri Europa becomes Versalis
2002 Polimeri Europa absorbs polymer and
chemical strategic assets of Enichem
1981-1985 eni founds Enichem (at the beginning called Enichimica) aimed to manage
ANIC and others acquired companies. Enichem will become the main Italian industrial player operating in the field of chemistry in several segments (basic
chemicals, intermediates, polymers, fertilizers, synthetic fibers and fine chemicals)
1936 Born ANIC (National Company
Hydrogenation Fuels)
1995 Establishment of Polimeri Europa, joint venture 50% -50% Enichem
and Union Carbide, aimed to serve polyethylene market
Efficiency
Market-oriented and focus on diversified
products Green chemistry
R&D enhancement
Licensing
Internationalization
March 2012
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versalis european nameplate capacity chain (kty)
DCPD hp (8)
C4 mix (620 )
Propylene (760)
Xylenes + EB (255)
LDPE/ EVA (662)
LLDPE/ HDPE (722)
Cumene (300)
Ethylbenz. (550)
GPPS/SAN (195)
HIPS/ABS (245)
EPS (135)
Xylenes (180)
Cy-one & KA oil (270)
α-MS (7)
Phenol (310) & Acetone (192)
EPR/EPDM (115)
Latexes HS/LS (62) ; CBX (38)
HCBR Nd (86)
SIS/SEBS/SBS (110)
NBR (38) e-SBR (205)
Raffinates (330 )
propylene
s-SBR (40)
Ethylene (1900)
Reformate (950)
Butadiene (290 )
Benzene (580)
to market
to market to market to market
LCBR (90)
Py-gas (1300)
Steam Crackings fed by VN, GPL, others
to market
H2
Styrene (610)
EB
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versalis proprietary technology(kty)
Most of the units we operate are based on internally developed process and proprietary Technologies and catalysts
We are continuously investing in process optimization, technology improvements and development of new technologies and new catalysts
The improvements in our technology portfolio are shared with our licensees that can also access to dedicated joint research programs to solve specific needs
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Some examples of new process developed by Versalis in recent years
Flexibility in operation and optimization of portfolio ABS grades
Lower investment cost
Lower environmental impact
Continuous mass technology
Innovative process for production of cyclohexanone oxime. Mild operating conditions
Reduction of by products, substantially lower investment and environmental impact
Can be retrofitted on existing plants
Cyclohexanone Oxime process-Ammoximation Technology
Neodimium based high-cis polybutadiene rubber. Developed to match with the new demanding requirements of the tire sector
HCBR
Utilized with success by many petrochemical operators in caprolactam, phenol
PO processes
Proprietary TS-1 catalyst
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Some examples of new process developed by Versalis in recent years
Among the first 7 producers only Versalis and another player have proprietary continuos mass technology
STYRENIC
Overall investment saving up to 35% in caprolactam compared to conventional route INTERMEDIATES
Among the first 11 elastomer producers only Versalis and other two can offer a portfolio of 7 rubber families out of the 9 actually commercialized
ELASTOMERS
In 1992 our catalyst won the Donald Breck Award for advancing the knowledge of the structures and properties of titanium MFI zeolites and for demonstrating both the potential and applications of these novel catalysts for partial oxidation reactions
CATALYSTS
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Licensing: Versalis proprietary process technololgies
* Licensing through Lummus technology (CB&I company) ** Close to commercialization
Phenol & Derivatives
DMC & Derivatives
Polyethylene Styrenics Elastomers
Proprietary catalyst
technologies
Cumene PBE-1 Zeolite catalyst based*
Phenol & Acetone*
DMC & Derivatives via CO & MEOH*
DPC*
LDPE
EVA
Ethylbenzene PBE-1/2 Zeolite catalyst based
catalyst based
Styrene Monomer
GPPS
HIPS
EPS suspension/ continuous mass
ABS continuous mass
SAN
e-SBR
s-SBR
high cis BR
low cis BR
NBR
SBS
SIS
EPR/EP(D)M
Latices
Titanium Silicalite
Silicalite
PBE-1 Zeolite
PBE-2 Zeolite
Acetone to IPA
Acetone to Cumene via IPA**
high selectivity Cyclohexanone & KA-oil
Ammoxymation with TS1 Cyclohexanone and H2O2
Versalis licencing is designed to meet the customer's specific needs and support them with engineering services (up to BEDP/FEED),
technical assistance and staff training
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21%
14%
12% 11%
10%
10%
7%
4%
3% 2% 2% 2%
Bulding up in the time successful cooperations worldwide
Installed capacity based on versalis technologies in the last 10 years by area
Versalis started the licensing activities in September 1992: LPDE tubular technology sold to QAPCO - Qatar Petrochemical Company
Elastomers
Polystyrene
Polyethylene
Iran
India
Malaysia
Brazil
France
Russia
China
Taiwan
Korea
Egypt
39%
61%
Ethylbenzene & Styrene Monomer
Phenol & Derivates
39%
25%
6%
29%
Iran China Malaysia
Downstream Intermediates
By Product
By Area
18%
67%
15%
Italy
UK
Taiwan
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Licensing options: extended and flexible range of services
Licensing PDP,BEDP, FEED
Feasibility assessment
Assistance to commissioning and startup
Proprietary equipment design and supply
Training of the operators
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Licensing options: extended and flexible range of services
Licensing
PDP,BEDP, FEED
Feasibility assessment
Assistance to commissioning and startup
Proprietary equipment design and supply
Training of the operators
Design and construction
Engineering
Procurement
Construction
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Licensing options: extended and flexible range of services
Licensing
PDP,BEDP, FEED
Feasibility assessment
Assistance to commissioning and startup
Proprietary equipment design and supply
Training of the operators
Design and construction
Engineering
Procurement
Construction
After sales
Optimization
Troubleshooting
Process evaluation
New products development
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Licensing options: extended and flexible range of services
Licensing
PDP,BEDP, FEED
Feasibility assessment
Assistance to commissioning and startup
Proprietary equipment design and supply
Training of the operators
Design and construction
Engineering
Procurement
Construction
After sales
Optimization
Troubleshooting
Process evaluation
New products development
Revamp projects
Extend life
Debottlenecking
Equipment replacement
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Licensing options: extended and flexible range of services
Design and construction
Engineering
Procurement
Construction
After sales
Optimization
Troubleshooting
Process evaluation
New products development
Revamp projects
Extend life
Debottlenecking
Equipment replacement
Licensing PDP,BEDP, FEED
Feasibility assessment
Assistance to commissioning and startup
Proprietary equipment design and supply
Training of the operators
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Flexible package of services
Versalis can offer a very flexible package of services associated with the license:
Extended engineering services including PDP, BASIC and FEED all developed with internal engineering resources
Possibility to offer a complete EPC LSTK in partnership with approved and experienced EPC contractors
On site and theoretical training for the operators in Versalis industrial facilities
Assistance to plant commissioning a start up
Support for plant optimization and improvements along the entire lifetime of the plant
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In technology licensing Versalis offers the combined advantages of being in the same time:
Leading position, with a deep knowledge and Understanding of the global marked requirements and developments
Direct and day by day experience in plant operation, maintenance and optimization
Engineering Team involved in all Versalis new investments and in all the licensing Projects
Flexible and professional offer of services (PDP, BEDP, FEED)
Capability to perform internally the complete mechanical design of key and proprietary equipment
Capability to work with different standards
Capability to work in cooperation with other licensors
Capability to work in cooperation with EPC contractors
A producer An experienced
engineering contractor
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Versalis an integrated producer
Versalis is present and integrated in the production chain from the
production of chemical intermediates to monomers and
polymers.
This knowledge is offered to our licensors helping to professionally
support the upstream and downstream integration of one unit in the chain as well as in
minimizing the interfaces from one unit and the other
All the technologies present in the licensing portfolio have the backup of industrial reference units of worldscale capacity
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Licensing: an important vehicle to develop mutual beneficial cooperations
The possibility to offer multiple technologies covering in many cases the complete range of market applications and our capability to share our technological and market expertise has contributed to develop successful business relations with important petrochemical players
This is becoming an significant contribution to our turnaround and globalization that we are interested to further exploit
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Versalis globally-oriented strategies
Opportunity under development
North America
South America
JV Hydrocarbon resins complex
(75 kty)
Integrated with C5 separation unit
JV Elastomers complex: 200 KTY
South Korea
JV Elastomers complex: 270 KTY
Malaysia
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Our current licensing offer includes
Straight licensing with flexible engineering package
Integration with other technology licenses
Supply of proprietary equipment
Commercial agreements for specific products manufacturing and long term basis buy back
Equity participation in the venture