united states environmental protection agency '/o · mc0069 se mc0078 se matrix spike...

\\o'/

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYENVIRONMENTAL SCIENCE CENTER

701 MAPES ROADFORT MEADE, MD 20755-5350

S°MS DOC/O2065645

DATE : September 4, 2002

SUBJECT: Region III Data QA_Review

FROM : Fredrick ForemaiRegion III ESAT l PO (3ES20;

TO : Romuald RomanRegional Project Manager (3HS22)

r-

Attached is the inorganic"data validation report for the ValmontTCE site (Case #: 30647, SDG#: MC002, MC0035, MC0069, MC0078,MC0109, MC0128, MC0143M MC0153) completed by the Region IIIEnvironmental Services Assistance Team (ESAT) contractor under thedirection of Region III ESD.

If you have any questions regarding this review, please call me at(410) 305-2629.

Attachments

cc: Neil Teamerson (Tetratech NUS)

TO File: 0007 TDF#: 0746

OFFICE OF ANALYTICAL SERVICES AND QUALITY ASSURANCE

Internet Address (URL) • http://www.epa.govRecycled/Recyclable ••Printed with Vegetable Oil Based Inks on Recycled Paper (Minimum 30% Postconsumer)

Lockheed Martin Environmental ServicesUS EPA Environmental Science Center701 Mapes Road Ft. Meade, MD 20755-5350Telephone 410-305-3037 Facsimile 410-305-3597

L O C K H E E D HI A R

DATE: August 29,2002

SUBJECT: Inorganic Data Validation (IM2 Level)Case: 30647SDGs: MC0002,MC0035,MC0069,MC0078,MC0109,MC0128,

MC0143.MC0153Site: Valmont TGE

FROM:

TO:

OVERVIEW

Kenneth W. CurryInorganic Data Reviewer

Fredrick ForemanESAT Region 3 Project Officer

Mahboobeh Mecanic *Senior Oversight Chemist

Case 30647, Sample Delivery Groups (SDGs) MC0002, MC0035, MC0069, MC0078, MC0109,MC0128, MC0143 and MC0153, from the Valmont TCE site consisted of one hundred thirty-one (131) soil samples and four (4) associated aqueous blanks analyzed for total metals andcyanide (CN~) in addition one (1) aqueous blank was analyzed for total metals only. All sampleswere analyzed by CompuChem (LEBRTY). The sample set included two (2) rinsate blanks, three(3) field blanks and eight (8) field duplicate pairs. Samples were analyzed in accordance withContract Laboratory Program (CLP) Statement of Work (SOW) ILM04.1 through RoutineAnalytical Services (RAS) program.

SUMMARY

All samples were successfully analyzed for all Target Analyte List (TAL) parameters with theexception of those listed under "Major Problem". Areas of concern with respect to data usabilityare listed below.

One (1) field blank was collected 6/24/02 while the remaining field and rinsate blanks werecollected 6/28/02. The samples were collected 6/24/02,6/26/02,6/27/02 and 6/28/02. Due tothe sampling dates of the blanks, the highest detected concentration of an analyte in the rinsateand field blanks were utilized by the reviewer to assess these data for blank contamination.

Data in this case have been impacted by outliers present in laboratory, field and rinsate blanks,sample cooler chest temperature as well as matrix spike, laboratory duplicate, ICP serial dilution,continuing calibration verification, laboratory control sample and Contract Required DetectionLimit (CRDL) standard analyses. Details of these outliers are discussed under "Major and MinorProblems"; specific samples affected are outlined in "Table 1A" and qualified analytical resultsfor all samples are summarized on Data Summary Forms (DSFs).

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MAJOR PROBLEM

Matrix spike recoveries were extremely low (<30%) for antimony (Sb) in SDG MC0002 and formanganese (Mn) in SDG MC0143. Reported results for these analytes in these SDGs may bebiased extremely low. The "L" qualifier for Mn in SDG MC0143 has been superseded by "J"on the DSFs. Quantitation limits for Sb in SDG MC0002 were rejected and qualified "R".

MINOR PROBLEMS

Continuing Calibration (CCB), Preparation (PB), Field (FB) and/or Rinsate (RB) Blanks hadreported results greater than the Instrument Detection Limits (DDLs) for analytes listed below.Reported results in affected samples which are less than or equal to five times (<5X) blankconcentrations may be biased high and have been qualified "B" on DSFs.

SDG Blank Affected AnalvtesMC0002 CCB selenium (Se)

FB nickel (Ni), sodium (Na)RB calcium (Ca), cyanide (CN")

MC0035 CCB aluminum (Al), barium (Ba), Ca, iron (Fe), magnesium (Mg)PB zinc (Zn), CN'

MC0069 CCB Sb, beryllium (Be)FB Ni, NaRB Ca, Mg,

MC0078 CCB Sb, BeFB . Ni,NaRB Ca, Mg,

MC0109 FB Ni,NaRB Ca, Mg,

MC0128 CCB BeFB • Ni, NaRB Ca,CN'

MC0143 CCB Sb, BeFB Ni,NaRB Ca, Mg,

MC0153 CCB Be, thallium (Tl)FB copper (Cu), Ni, NaRB Ca, Mg,

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Continuing calibration and/or preparation blanks had negative values greater than the absolutevalue of the EDLs for analytes listed below. Reported results less than two times (<2X) theabsolute value of the blank and quantitation limits for these analytes in affected samples may bebiased low and have been qualified "L" and "UL", respectively, on the DSFs unless supersededby "B".

Analyte(s)MC0035 chromium (Cr)MC0069 CaMC0078 Ca,NaMC0109 SbMC0153 Se,Na

CRDL standard recoveries were low (<90%) for analytes listed below. Low recoveries mayindicate negative biases for results detected near detection limits due to an unstable baseline.Reported result which are <2XCRDL and quantitation limits for these analytes in affectedsamples may be biased low and have been qualified "L" and "UL", respectively, on the DSFs.

SPG Analvte(s)MC0035 lead (Pb)MC0069 Se,zinc(Zn)MC0078 ZnMC0128 SeMC0153 Se,Zn

CRDL standard recoveries were high (>110%) for analytes listed below. High recoveries mayindicate positive biases for results detected near detection limits due to an unstable baseline.Reported results which are <2XCRDL for these analytes in affected samples may be biased highand have been qualified "K" on the DSFs unless superseded by "B".

SPG Analyte(s)MC0002 arsenic (As), Se, ZnMC0069 SeMC0078 Se

Matrix spike recoveries were low (<75%) for analytes listed below. Reported results andquantitation limits for these analytes in these SDGs may be biased low and have been qualified"L" and "UL", respectively, on the DSFs unless superseded by "B".

1 Analvte(s)MC0002 SeMC0069 Sb, Mn, mercury (Hg), TlMC0078 Sb, Mn, TlMC0109 SbMC0128 SbMC0143 Sb, SeMC0153 Sb, Tl

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Matrix spike recoveries were high (>125%) for Pb and Mn in SDG MC0002 as well as for Pb inSDG MCO 109. Reported results for this analyte in these SDGs may be biased high and havebeen qualified "K" on the DSFs.

Relative Percent Differences (RPDs) for laboratory duplicate analyses were outside control limits(35% RPD, ±2CRDL) for As in SDG MC0069 and for Mn in SDG MC0143. Reported resultsfor these analytes in these SDGs are estimated and have been qualified "J" on the DSFs.

Percent Differences (%Ds) for ICP serial dilution analyses were outside control limits (>10%)for analytes listed below. Reported results for these analytes are estimated and have beenqualified "J" on the DSFs unless superseded by "B".

SDG AnalvtesMC0002 Mg, ZnMC0109 MgMC0128 ZnMC0143 ZnMC0153 Ca, Cr, potassium (K)

Recoveries of Na in the Laboratory Control Sample (LCS) analyses in SDGs MC0002, MC0109,MC0128 and MC0143 were outside the upper control limit. Reported results for this analyte inthis SDG may be biased high. The "K" qualifier for this outlier has been superseded by "B" onthe DSFs.

The sample coolers had interior temperatures of 7.1 °C and /or 8.0 °C for samples analyzed inSDGs MC0002, MC0035, MC0143 and MC0153 when received by the laboratory. Reportedresults and quantitation limits for CM" in affected samples may be biased low and have beenqualified "L" and "UL", respectively, on the DSFs unless superseded by "B". Due tothermostability of metals, no other data were qualified based on the sample cooler cheststemperature.

Matrix spike recoveries were low (<75%) while CRDL standard recoveries were high (>110%)for Hg in SDG MC0128 and for Se in SDG MCO143, producing opposing bias effects for resultsdetected near detection limits due to an unstable baseline. Reported results which are <2XCRDLfor these analyte? in affected samples in these SDGs are estimated and have been qualified "J" onthe DSFs.

A continuing calibration verification standard recovery was high for Al in SDG MCO 153.Reported results for this analyte in affected samples in this SDG may be biased high and havebeen qualified "K" on the DSFs.

NOTES

The laboratory duplicate results for Mn and Zn in SDG MC0002 as well as for Cr and Fe in SDGMCO 143 were outside the contractual control limit of 20% RPD, ±CRDL. However, the resultsfor these analytes were within the control limit of 35% RPD, ±2XCRDL utilized for datavalidation of soil samples in Region 3. No data were qualified based on these outliers.

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The matrix spike recovery for Mn in SDG MC0002 was not considered outside the QC limits bythie laboratory since the result would round down to the upper limit. Laboratory Form Is do notindicate a matrix spike outlier for this analyte in this SDG. The reviewer considered this result asbeing outside the upper QC limit and qualified results accordingly.

Field blank, sample MC0185, was not analyzed for CN". This sample was listed on the Chain ofCustody (COC) record for CN' analysis.

Reported results for the field duplicate pairs were within 35% RPD, ±2XCRDL for all analytesexcept for those listed below.

Duplicate Pair Analyte(s)MC0017/MC0018 Al,Mn,ZnMC0075/MC0076 MnMC0100/MC0101 - Fe,PbMC0109/MC0110 As, Cr, Fe, Pb, MnMC0166/MC0181 Cr,Fe,PbMC0167/MC0182 Al

Data for Case 30647, SDGs MC0002, MC0035, MC0069, MC0078, MC0109, MC0128,MC0143 and MC0153, were reviewed in accordance with National Functional Guidelines forEvaluating Inorganic Analyses with Modification for use within Region in.

ATTACHMENTS

INFORMATION REGARDING REPORT CONTENT

Table 1A is a summary of qualifiers applied to the laboratory- generated results during datavalidation.

TABLE 1A SUMMARY OF QUALIFIERS ON DATA SUMMARY FORMS AFTERDATA VALIDATION

TABLE IB CODES USED IN COMMENTS COLUMN OF TABLE 1AAPPENDIX A GLOSSARY OF DATA QUALIFIER CODESAPPENDIX B ~ DATA SUMMARY FORMSAPPENDIX C CHAIN OF CUSTODY (COC) RECORDSAPPENDIX D LABORATORY CASE NARRATIVES

DCN:30647IM2.wpd

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TABLE 1ASUMMARY OF QUALIFIERS ON DATA SUMMARY

FORM AFTER DATA VALIDATIONCASE: 30647SDG#: MC0002

ANALYTE

Sb

As

Ca

Se

SAMPLESAFFECTED

All Samples

MC0012, MC0014,MC0015.MC0017,MC0018,MC0021,MC0022, MC0024,MC0025, MC0033

All Samples ExceptMC0015,MC0021,MC0025, MC0028

MC0022, MC0023,MC0024, MC0027,MC0029, MC0030,MC0031.MC0032,MC0033

MC0027, MC0029,MC0030,MC0031,MC0032, MC0033

MC0012, MC0014,MC0015,MC0017,MC0018,MC0021,MC0022, MC0023,MC0024, MC0025

NON-POSITIVE DETECTEDVALUES VALUES

K

B

Pb

Mg

Mn

Ni

All Samples

All Samples

All Samples

MC0002, MC0012,

K

J

K

B

B

BIAS

Extr./Low

High

High

High

High

High

Mixed

High

COMMENTS*

MSE(28.6%)

CRH(110.8%)

RB(851|ig/L)

MSH(161.6%)

MSH(125.3%)

FB(4.8'|ig/L)

MSL(66.4%)CRH(112.5%)

CCB(3.3CRH(112.5%)MSL(66.4%)

* See explanation of Comments on Table IB.

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CASE: 30647SDG#: MC0002

TABLE1ASUMMARY OF QUALIFIERS ON DATA SUMMARY

FORM AFTER DATA VALIDATION

ANALYTE

Se

Na

Zn

SAMPLESAFFECTED

MC0002, MC0004,MC0020

MC0028

All Samples

All Samples ExceptMC0024, MC0033

MC0024, MC0033

MC0002, MC0004,MC0015,MC0017,MC0020, MC0022,MC0023, MC0024,MC0027, MC0028,MC0030.MC0031,MC0032, MC0033

MC0012, MC0014,MC0018,MC0021,MC0025, MC0029

NON-POSITIVE DETECTEDVALUES VALUES

B

L

B

B

BIAS

High

Low

High

High

UL Low

COMMENTS

CCB(3.3MSL(66.4%)

MSL(66.4%)

FB(1190»ig/L)LCH(374.4%)

CRH(110.8%)

RB(1.4ng/L)CHT(7.1 °C)

CHT(7.1


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SAMPLESANALYTE AFFECTED

Al

Ba

Ca

Cr

Fe

Pb

Mg

Zn

MC0035

MC0035

MC0141,MC0142,MC0184.MC0185

MC0035

All Samples

MC0035

MC0184

All Samples

MC0035

MC0141.MC0142,MC0184, MC0185

All Samples

MC0141,MC0142

MC0035

MC0184

NON-POSITIVE DETECTED

B

B

B

B

L

B

B

B

B

B

B

VALUES

UL

UL

UL

UL

BIAS

High

High

High

High

Low

High

High

Low

High

High

High

High

Low

Low

COMMENTS*

CCB(81.2ng/L)

CCB(0.7 jig/L)

CCB(0.5 \Lg/L)

CCB(106.4 jig/L)

PBN(-0.521 ng/L)

CCB(26.5 jig/L)

CCB(10.1 ng/L)

CRL(88.8%)

CCB(154.4^ig/L)

CCB(97.6 pg/L)

PB (2.907 |ig/L)

PB (0.792 \igfL)

CHT(7.1 °C)

CHT(8.0 °C)


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CASE: 30647SDG#: MC0069



ANALYTE

Sb

As

Be

Ca

SAMPLESAFFECTED

MC0069, MC0070,MC0071,MC0072,MC0073, MC0074,MC0075, MC0076,MC0077, MC0079

MC0080, MC0082,MC0083, MC0085,MC0086

MC0081.MC0084,MC0087, MC0088,MC0089

All Samples

MC0069, MC0070,MC0073

MC0074, MC0076,MC0077, MC0079,MC0081.MC0082,MC0084, MC0085,MC0086

MC0087, MC0088,MC0089

All Samples ExceptMC0072, MC0074,MC0077.MC0081,MC0088

MC0077

NON-POSITIVE DETECTEDVALUES VALUES BIAS

B

B

J

B

B

B

B

B

High

UL

High

Low

COMMENTS*

CCB( 2.9 ng/L)MSL(51.8%)

CCB( 2.0 ng/L)MSL(51.8%)

MSL(51.8%)

DUP(91.4%)

High CCB(0.5 jig/L)

High CCB(0.3 jig/L)

High CCB(0.4 |ig/L)\

High RB(851ng/L)

High RB (851 jig/L)CBN(-48.0 jig/L)


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NON-

ANALYTE

Ca

Mg

Mn

Hg

Ni

SAMPLESAFFECTED

MC0088

MC0083, MC0086

All Samples

All Samples

All Samples Except

POSITIVE DETECTEDVALUES VALUES

B

B

L

UL

, B

BIAS

High

High

Low

Low

High

Se

Na

Tl

Zn

ON'

MC0069, MC0072,MC0082

All Samples Except KMC0075, MC0087,MC0088, MC0089

MC0087, MC0088,MC0089

All Samples Except BMC0077

All Samples

MC0070 L

MC0086 L

MC0069, MC0070, BMC0071.MC0072,MC0073, MC0074,MC0076, MC0079,MC0081.MC0082,MC0084, MC0085,MC0086, MC0088

UL

UL

High

Low

High

Low

Low

Low

High

COMMENTS

CBN(-31.0ng/L)

RB (112 ng/L)

MSL(74.2%)

MSL(61.8%)

FB (4.8

CRH(113.5%)

CRL(77.4%)

FB(1190iig/L)

MSL(71.4%)

CRL(87.2%)

CRL(88.0%)

RB(1.4ng/L)

< _


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ANALYTE

Sb

Be

Ca

SAMPLESAFFECTED

MC0078, MC0090,MC0091

MC0093, MC0094,MC0095, MC0096,MC0097, MC0098,MC0100,MC0101

MC0103,MC0104,MC0105,MC0106,MC0107

MC0092, MC0099,MC0102,MC0108

MC0078, MC0090,MC0091

MC0092, MC0093,MC0094, MC0095,MC0096, MC0097,MC0098, MC0099,MCOIOO.MCOIOI

MC0102,MC0103,MC0104.MC0105,MC0106,MC0107,MC0108

All Samples ExceptMC0092, MC0095,MC0104,MC0105,MC0106

MC0092, MC0095,MC0104,MC0105,MC0106


B

B

B

B

B

B

B

B

High

High

UL

High

Low

High

High

High

High

High

COMMENTS*

CCB( 2.5 jig/L)MSL(50.6%)

CCB( 2.3MSL(50.6%)

CCB(2.7MSL(50.6%)

MSL(50.6%)

CCB(1.1 iig/L)

CCB(0.7 jig/L)

CCB(0.5

RB(851jig/L)

RB(851 jig/L)PBN(-11.841mg/Kg)


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CASE: 30647SDG#: MC0078



ANALYTE

Mg

Mn

Ni

Se

Na

Tl

Zn

SAMPLESAFFECTED

MC0092, MC0104,MC0108

All Samples

All Samples ExceptMC0091,MC0096

MC0093,MC0095,MC0097,MC0100,MC0102,MC0105,MC0107

MC0094,MC0096,MC0098,MC0101,MC0103,MC0106,

All Samples ExceptMC0102, MC0103,MC0104.MC0105,MC0106,'MC0107

MC0102.MC0103,MC0104,MC0105,MC0106,MC0107

All Samples

MC0092, MC0095,MC0104, MC0107,MC0108

All Samples ExceptMC0090,MC0100,MC0108


B

L

B

K

B

B

B

High

UL

COMMENTS*

RB(112ng/L)

Low MSL(67.4%)

High FB (4.8 jig/L)

High CRH(112.4%)

High FB(1190ng/L)

High FB(1190[ig/L)CBN(-228.8 jig/L)

Low MSL(74.7%)

Low CRL(87.3%, 87.2%)

High RB(1.4jig/L)


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NON-

ANALYTE

Sb

Ca

Pb

Mg

Ni

Na

CN-

SAMPLESAFFECTED

All Samples

All Samples

All Samples


MC0109,MC0110

All Samples ExceptMC0114,MC0118,MC0121,MC0124,MC0125,MC0127


All Samples Except


UL

B

K

J

B

B

B

B

BIAS

Low

High

High

High

High

High

High

COMMENTS*

MSL(3LO%)PBN(-0.473 mg/Kg)

MSH(176.4%)

ISD(24.1%)

RB(112ng/L)ISD(24.1%)

FB (4.8

FB(1190ng/L)LCH(331.4%)

RB(1.4|Ag/L)MC0118


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CASE: 30647SDG#: MC0128



NON-

ANALYTE

Sb

Be

SAMPLESAFFECTED

All Samples

MC0128

MC0129,MC0130,


UL

B

B

BIAS

Low

High

High

COMMENTS*

MSL(47.2%)

CCB(0.3 pg/L)

CCB(0.2 ng/L)

Ca

Hg

Ni

Se

Na

.Zn

MC0133.MC0136,MC0139


All Samples

All Samples ExceptMC0128,MC0134,MC0135,MC0138

MC0128, MC0129,MC0130,MC0132

All Samples ExceptMC0133

All Samples

All Samples ExceptMC0128.MC0135,MC0136

B

B

B

J

B

UL

High RB (851

Mixed MSL(70.9%)CRH(135.0%)

High FB (4.8

Low CRL(89.2%)

High FB(1190fig/L)LCH(336.9%)

ISD(19.6%)

High , RB(1.4ng/L)


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SAMPLESANALYTE AFFECTED


Ni

Se

All Samples ExceptMC0143, MC0146,MC0147.MC0155,MC0158, MC0159


MC0163

MC0156.MC0158,MC0159

B

UL

High

Mixed

Low

COMMENTS*

Sb

Be

Ca

Mg

Mn


MC0163

MC0152


MC0163

All Samples

^

L

B

B

B

B

J

UL Low

High

High

High

MSL(49.5%)

CCB(2.6 |ig/L)MSL(49.5%)

CCB(0.2 ^g/L)

RB(851 jig/L)

RB(112iig/L)

DUP(101.8%)MSE(-15.5%)

FB (4.8 jig/L)

Mixed MSL(74.0%)CRH(113.0%)

MSL(74.0%)CRH(118.5%)

MSL(74.0%)


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ANALYTE

Na

Zn

SAMPLESAFFECTED


All Samples

All Samples ExceptMC0150,MC0151,MC0154

MC0150.MC0151,MC0154


B

J

B

High

UL

High

Low

COMMENTS*

FB(1190tig/L)LCH(352.6%)

ISD(13.8%)

RB(1.4ng/L)CHT(8.0 °C)

CHT(8.0


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ANALYTE

Al

Sb

Be

Ca

SAMPLESAFFECTED

MC0170,MC0172,MC0174,MC0176,MC0178,MC0180,MC0182

MC0171,MC0173,MC0175,MC0177,MC0179,MC0181,

All Samples

MC0153

MC0164,MC0165,MC0166.MC0167,MC0168.MC0169

MC0170,MC0172,MC0174,MC0176,MC0178,MC0180,MC0182

MC0171,MC0173,MC0175,MC0177,MC0179,MC0181,

All Samples ExceptMC0164.MC0165,MC0169, MC0174,MC0175.MC0178

MC0164,MC0165,MC0169,MC0174,MC0175,MC0178


K High

L

B

B

B

B

COMMENTS*

CVH(110.4%)

UL Low MSL(35.2%)

High CCB(0.4 iig/L)

High CCB(0.5 jig/L)

High CCB(0.6 jig/L)

High RB(851ng/L)ISD(23.0%)

ISD(23.0%)

See explanation of Comments on Table IB.

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CASE: 30647SDG#: MC0153



ANALYTE

Cr

Cu

Mg

Ni

K

Se

Na

SAMPLESAFFECTED

All Samples

MC0181

MC0177


All Samples

All Samples ExceptMC0153.MC0180

MC0153

MC0180

MC0153,MC0164,MC0165.MC0166,MC0167,MC0169

MC0170.MC0171,MC0172.MC0173,MC0174,MC0175,MC0176,MC0177,MC0178.MC0179,MC0180,MC0181,MC0182


J

B

B

B High

L

B

B

UL

UL

Low

Low

Low

High

High

COMMENTS*

ISD(12.6%)

FB (2.9 jig/L)

RB(112ng/L)

FB (4.8 |ig/L)

ISD(10.7%)

CRL(78.5%)PBN(-0.562 mg/Kg)

CRL(88.4%)PBN(-0.562 mg/Kg)

CRL(78.5%)

FB(1190ng/L)

CBN(-492.8 jig/L)

See explanation of Comments on Table IB.

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ANALYTE

Tl

Zn

ON'

SAMPLESAFFECTED

All Samples ExceptMC0177.MC0180

MC0177,MC0180

MC0166.MC0171


MC0153


UL • Low

B High

L Low

B High

UL Low

COMMENTS*

MSL(72.6%)

CCB(7.6MSL(72.6%)

CRL(84.2%, 82.8%)

CHT(8.0

CHT(8.0

See explanation of Comments on Tabie IB.

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TABLE IBCODES USED IN COMMENTS COLUMN

MSB = Matrix spike recoveries were extremely low (<30%) [% recoveries are inparenthesis]. Reported results may be biased extremely low. Quantitation limitsare unusable.

CRH = CRDL standard recoveries were high (>110%) [% recoveries are in parenthesis].Reported results which are <2XCRDL may be biased high.

RB = Rinsate blanks had results > IDL (results are in parenthesis). Reported resultswhich are less than five times (<5X) blank concentrations may be biased high.

MSH = Matrix spike recoveries were high (>125%) [% recoveries are in parenthesis].Reported results may be biased high.

ISD = Percent differences (%Ds) for ICP serial dilution analyses exceeded control limits(10%) [% Ds are in parenthesis]. Reported results are estimated.

FB = Field blanks had results > DDLs (results are in parenthesis). Reported results whichare less than five times (<5X) the blank concentration may be biased high.

MSL = Matrix spike recoveries were low (<75%) [% recoveries are in parenthesis].Reported results and quantitation limits may be biased low.

CCB = Continuing calibration blanks had results > IDLs (results are in parenthesis).Reported results which are less than five times (<5X) the blank concentration maybe biased high. !

LCH = Laboratory Control Sample (LCS) recoveries were high (>120%) [% recoveries arein parenthesis]. Reported results may be biased high.

CHT = The sample cooler temperature was outside the required temperature range (4 °C ±2°C) [sample cooler temperature is in parenthesis]. Reported results andquantitation limits may be biased low.

PEN = Preparation blanks had negative results with absolute values greater than the IDLs(results are in parenthesis). Reported results less than two times (<2X) the absolutevalue of the blank and quantitation limits may be biased low.

CRL = CRDL standard recoveries were low (<90%) [% recoveries are in parenthesis].Reported results which are <2XCRDL and quantitation limits may be biased low.

PB = Preparation blanks had results > IDLs (results are in parenthesis). Reported resultswhich are less than five times (<5X) the blank concentration may be biased high.

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TABLE IBCODES USED IN COMMENTS COLUMN

DUP = The Relative Percent Difference (RPD) for the laboratory duplicate analysis wasoutside control limits (35%, ±2XCRDL) [RPD is in parenthesis]. Reported resultsare estimated.

CBN = Calibration blanks had negative results with absolute values greater than the IDLs(results are in parenthesis). Reported results less than two times (<2X) the absolutevalue of the blank may be biased low.

CVH = Continuing calibration verification standard recoveries were high (>110%) [%recoveries are in parenthesis]. Reported results may be biased high.

APPENDIX A

Glossary of Qualifier Codes

GLOSSARY OF DATA QUALIFIER CODES (INORGANIC)

CODES RELATED TO IDENTIFICATION(confidence concerning presence or absence of analytes):

U = Not detected. The associated number indicates approximate sample concentrationnecessary to be detected.

(NO CODE) = Confirmed identification.

B = Not detected substantially above the level reported in laboratory or field blanks.

R = Unusable result. Analyte may or may not be present in the sample. Supporting datanecessary to confirm result.

CODES RELATED TO OUANTITATION(can be used for both positive results and sample quantitation limits):

J = Analyte Present. Reported value may not be accurate or precise.

K = Analyte present. Reported value may be biased high. Actual value is expected to belower.

L = Analyte present. Reported value may be biased low.Actual value is expected to be higher.

[ ] = Analyte present. As values approach the IDL the quantitation may not be accurate.

UJ = Not detected, quantitation limit may be inaccurate or imprecise.

UL = Not detected, quantitation limit is probably higher.

OTHER CODES

Q = Ne analytical result.

APPENDIX B

Data Summary Forms

DATA SUMMARY FORM: INORGANIC Page _1 of _28

Case #: 30647

Site:

Lab.:

SDG: MC0002

VALMONT TCE

LIBRTY

Number of Soil Samples: 20

Number of Water Samples: 0

Sample Number':

Sampling Location :

Rek) QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%Sdids:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40

12

2

40

1

1

1000

2

10

5

20

0.6

1000

3

0.1

8

1000

1

2

1000

2

10

4

0.5

MC0002

SB-AOO-O406

Soil

mg/Kg

06/24/2002

09:25

86.9

1.0

Result

12300

4.1

[24.9]

[0.29]

[0.16]

[147]

14.4

[0.79]

14.4

20200

12.6

[217]

21.3

[0.067]

(2-4][684]

1.1

[51.1]

24.2

9.6[0.053]

Flag

R

B

K

J

K

B

B

B

JB

MC0004

SB-DOO-0206

Soil

mg/Kg

06/24/2002

09:55

84.1

1.0

Result

13600

4.2

[35.5]

[0.38]

[0.16]

[171]

17.9

13.3

21.3

21800

18.3

[476]

160

[0.088]

[8.4]

[918]

[1.13

[74.9]

26.9

22.2[0.058]

Flag

R

B

K

J

K

B

B

J

B

MC0012

SB-J100-0205

Soil

mg/Kg

06/24/2002

11:25

91.9

1.0

Result

7020

3.7

[17.2]

[0.20]

[0.094]

[141]

8.4

[1.5]

10.9

12200

7.2

[295]

44.0

[0.059]

[3.1]

[515]

[0.71]

[55.7]

14.4

14.5

Flap

R

K

B

K

J

K

B

B

B

J

UL

MC0014

SB-J200-0204

Soil

mg/Kg

06/24/2002

11:50

89.9

1.0Result

9750

3.9[23.8]

[0.32]

[0.12]

[300]

13.3

[3.7]

16.8

17000

10.0

[791]

151[0.070]

[5.6]

[712]

1.1

[69.1]

19.0

20.6

Flag

RK

B

KJK

B

B

JUL

MC0015

SS-J250-0002

Sofl

mg/Kg

06/24/2002

12:15

88.9

1.0

Result

9630

3.9P5.2]

[0.33]

[0.23]

4150

20,1

[3-3]

20.6

16500

23.7

[867]

120[0.055]

[6.5]

[686]

[1.0]

[226]

18.3

112(0.0601

Flag

RK

KJK

B

B

JB

CRDL = Contract Required Quantitation Limit

To calculate sample quantitation limits: (CRDL * Dilution Factor) / (%Solids/100)

SEE NARRATIVE FOR CODE DEFINITIONS

Revised 09/99

DATA SUMMARY FORM: INORGANIC Page_2 <rf_28_

Case ft 30647

Site:

Lab.:

SOG: MC0002

VALMONTTCE

LIBRTY

Sample Number :

Sampling Location :

FteWQC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%SoHds:

Dilution Factor:

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

. .CHROMIUMCOBALT

/COPPER.

IRON

•LEAD ; -

MAGNESIUM

.MANGANESE

MERCURY

NICKELPOTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE • . .

CRDL

40

12

2

401

'. . 1 ,

1000

2

10

5

20

0.6

1000

3

0.1

8

1000

'• --.t2

1000

2

10

4

0.5

MC0017

SB-J250-0709

Field Dup. of

MC0018

Sofl

mg/Kg

06/24/2002

12:25

80.4

1.0

Result

8580

[2.1]

119.4]

(0.46]

[0.17]

[392]

,. 20.2

[2.3]

27.3

27500

18.9

[359]

58.3

[0.067]

[6.0]

[863]

... [1.1]

[86.9]

20.5

29.9- fO.049]

Flap,

R

K

B

K

J

K

B

B

JB:

MCOQ1B

SB-DUP-01

Field Dup. of

MC0017.

Soil

mg/Kg

06/24/2002

12:30

84.9

1.0

Result

13800

[2.0]

H8.6]

[0.37]

[0.26J

[228]

20.8

[1.3]

27.7

31700

16.2

[389]

38.6

[0.093]

[5.7]

[846]

1.5

[57.81

27.4

19.9

Flap

R

K

B

K

J

K

B

B

J

UL

MC0020

SB-GOO-0206

Soil

mg/Kg

06/24/2002

10:45

87.4

1.0

Result

11900

8.0

61.4

[0.48]

[0.18]

[171]

18.2

[4.0]

26.6

23800

12.9

[574]

108

[0.075]

17.8]

[783]

(1.11

[89.4]

23.9

28.8

{0.0511 .

Ftafl

R

B

-

K

J

k

B

B

JB

MC0021

SS-J300-0002

Sodmg/Kg

06/24/2002

13:05

93.3

1.0Result

4950

3.2:puoj[0.25]

; [0.10]

1210

9.2

[3.0]

10.4

10600

8.8

[1020]

• 188

[0.052]

[7.9]

[626]

1.2

[109]

19.6

32.1

Flap

R

K

K

J

K

B

B

J

UL

MC0022

SB-J300-0203

Soil

mg/Kg

06/24/2002

13:10

86.3

1.0

Result

13200

4.4

[21.5]

[0.28]

= [0-17]

1161]

18.6

[0.96]

18.8

20000

14.7

[233]

20.1

[0.094]

[2.7]

[745]

1.2

[61.1].

27.7

12.3

[0.0921

Flag

R

K

B

K

J

K

B

B

B

J

BCRDL = Contract Required Quanfflafon Limit

To calculate sample quantitatton limits: (CRDL * Dilution Factor) / (%SoDds/100)SEE NARRATIVE FOR CODE DEFINITIONS

Revised 09/99

DATA SUMMARY FORM: INORGANIC Page _3 of 28

Case tt 30647

Site:

Lab.:

SDG: MC0002

VALMONTTCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%SoKds:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE.

CRDL

40

12

2

401

1

1000

2

10

.5

20

0.6

1000

3

0.1

8

1000

1

2

1000

2

10

4

0.5

MC0023

SS-J400-0002

Sonmg/Kg

06/24/2002

13:25

83.9

1.0Result

13700

10.0

[27.2]

[0.32]

[0.12]

[223]

15.8

[2.4]

21.6

17900

22.0

[275]

42.0

0.14

[3.8]

[798]

[0.81]

. [57.1]

26.8

11.6(0.069]

Flat,

R

B

KJk

6

B

B

JB

MC0024

SB-J400-0205

Soil

mg/Kg

06/24/2002

13:30

87.8

1.0

Result

7130

3.7

[14.6]

[0.14]

[192]

8.7[2.8]

9.99250

12.2

[206]

48.5

[0.083]

[2.0]

[588]

[0.47]

(51.7]

13.4

6.6[0.057]

Flap

RK

B

KJK

B

B

B

JB

MC0025

SS-J450-0002

Soil

mg/Kg

06/247002

13:45

92.8

1.0

Result

7300

4.2

[37.0]

[0.36]

[0.14]

[1040]

10.8

[6.1]

14.6

17800

11.1

1620

351

[0.068]

13.2

[636]

10.72]

1129]

12.4

45.3

Flafl

R

K

K

J

K

B

B

J

UL

MC0027

SS-I500-0002

Son

mg/Kg

06/24/2002

14:10

85.8

1.0Result

14100

5.8[26.6]

[0.33]

[0.14]

[254]

18.4

[1.1]

17.1

21300

14.3

[291]

24.2

[0.099]

[3.4]

(722]

[1.1]

(49.8]

28.6

12.9

(0.0421

Flafl

R

B

KJK

B

J

B

J

B

MC0028

SS-H525-0002

Soil

mg/Kg

06/24/2002

14:30

90.8

1.0Result

9860

15.6

[34.1]

[0.42]

[0.31]

[1060]

12£[4.1]

19.0

21200

24.0

[940]

3450.18

(8-0][874]

3.3

[159]

18.2

34.4

[0.0621

Flag

R

KJK

L

B

JB

CRDL = Contract Required Quantitatkxi Limit



Revised 09/99

DATA SUMMARY FORM: INORGANIC Page_4 of_28_

Case ft 30647Site:Lab.:

SDG:MC0002

VALMONTTCELIBRTY

Sample Number :

Sampling Location :RetdQC:

Matrix:Units:

Date Sampled :Time Sampled :%Sdids:Dilution Factor :ANALYTEALUMINUM

ANTIMONYARSENIC

BARIUMBERYLLIUMCADMIUMCALCIUMCHROMIUMCOBALT

'. COPPERIRON

•LEADMAGNESIUM

MANGANESEMERCURY

NICKELPOTASSIUM

SELENIUM , ;SILVER

SODIUMTHALLIUM

VANADIUMZINCCYANIDE

CRDL40

122

4011

1000

210

. 5200.6

10003

0.18

100012

10002

104

0.5

MC0029

SB-H525-0205

Soilmg/Kg06/24/2002

14:4084.7

1.0Result15100

5.0

[24.0][0.25]

[0.16][211]19.3

[0.98]

19.623300

12.8[263]20.4

[0.081]

[2-9][747]

[0.98]

[61.9]

29.9

14.3

Flap

R

B

K

JK

a

J

B

JUL

MC0030SS-G500-0002

Field Dup. ofMC0031Solmg/Kg

06/24/2002

15:1585.11.0

Result12800

4.6[31.0]10.25]

[0.15][176]14.8[1.7]

16.117800

12.1

[458]

51.4

[0.089]

[4.2]

[720]

[0.98]

[87 -2]

24.6

14.3

[0.0741

Flaf)

R

B

K

J

K

B

J

B

JB

MC0031SS-DUP-01

Field Dup. ofMC0030Soilmg/Kg

06/24/200215:2087.4

1.0Result14000

4.7

[31.3][0.27]

[0.10][200]16.3{2.0]

16.918400

11.6[556]49.9[0.11]

[5.2][796][0.68]

[96.8]

26.017.1

[0.079]

Flag

R

B

KJK

B

J

B

JB

MC0032SB-G500-0206

Soil

mg/Kg06/24/200215:2585.41.0

Result13800

4.7

[32.7110.27]

[0.12][156]16.2

t.1.3]17.4

1980013.9[335]

32.3[0.060]

[3-8][781]

[0.88]

.[68.1]

27.613.2

[0.047]

Flag

R

B

KJK

B

J

B

JB

MC0033SB-G500-0911

Soilmg/Kg

06/24/200215:3083.7

1.0Result

8290

3.8

neJzj[0.30]

[158]11.5

[0.62]

18.217200

17.0[157]

15.2[0.091]

[1-9][663]

1.6

157.5]

18.67.2

[0.060]

Flag

RK

B

KJ

K

B

J

B

J

BCRDL = Contract Required Quantitation Limit

. To calculate sample quantitation limits: (CRDL • Dilution Factor) / (%Sdids/100)

SEE NARRATIVE FOR CODE DEFINITIONSRevised 09/99

DATA SUMMARY FORM: INORGANIC Page_5 of_28

Case #: 30647

Site:

Lab.:

SDG: MC0035

VALMONTTCE

LIBRTY


Number of Water Samples: S

Sample Number :

Sampling Location :

RefcJQC:

Matrix:

Units:

Date Sampled :

Time Sampled :

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

•ARSENIC

BARIUM

BERYLLIUM

•CADMIUM

CALCIUM

•CHROMIUM

COBALT

.COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

^NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

•CYANIDE

CRDL

20060

10200

55 „

5000

10SO25

1003

5000

15

0.240

5000

510

5000

105020

10

MC0035

FB-01

Fiek) Blank

Water

ug/L

06/24/2002

12:45

1.0Result

[30.9]

-. [1-1]

[376]

[1.6]

[38.8]

[71.7]

[536]

[2.4]

FlaflB

B

B

UL

B

UL

B

B

UL

MC0141

RB-01

Rinsate Blank

Water

ug/L

06/28/2002

12:00

1.0Result

[74.2]

[1.5]

[851]

[0.96]

[2.8]

[72.8]

[112]

[1.0]

[1160]

[2.8]

[1.4]

Flap

B

L

ULB

-

BB

MC0142

FB-02

Field Blank

Water

ug/L

06/28/2002

13:00

1.0Result

[74.2]

[1.8]

[832]

[0.65]

[2.9]

[93.3]

[109]

[1.2]

[4.8]

[1190]

[2.1]

[0.92]

Flap

B

L

ULB

BB

MC0184

RB-02

Rinsate Balnk

Water

ug/L /

06/28/2002

16:00

1.0Result

[0.32]

(1.0J

[15.9]

[62.0]

[2.1]

[1.8]

Flag

B

L

BULB

B

UL

MC0185

FB-03

Field Blank

Water

ug/L

06/28/2002

12:15

1.0Result

[0.57]

11.0]

[64.0]

-

[2.7]

Flag

B

L

ULB

BQ


To calculate sample quantitation limits: (CRDL * Dilution Factor)

'Action Level Exists SEE NARRATIVE FOR CODE DEFINITIONSRevised 09/99

DATA SUMMARY FORM: INORGANIC Page_6 ot_28_

Case ft 30647

Site:

Lab.:

SOG: MC0069

VALMONTTCE

LIBRTY-


Number of Water Samples: 0

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled:

Time Sampled :

%So«ds:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

.BARIUM

BERYLLIUM

CADMIUM

CALCIUM

.CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

: SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40

12

2

40

1

1

1000'

2

10

5

20

0:6

1000

3

0.1

8

1000

.1'

2

1000

2

10

4

0.5

MC0069

SS-B3SO

Soil

mg/Kg

06/26/2002

10:30

91.2

1.0

Result

9570

[0.54J

4.6

[33.4J

[0.33]

[482]

11.7

[4.0]

12.8

15800

13.4

[886]

286

[6.9]

[480]

[0.64]

[54.8]

18.0

26.4

(0.0.99}.

Flap

B

J

B '

B

L

UL

K

B

UL

B

MC0070

SB-B350-0206

Soil

mg/Kg

06/26/2002

10:35

92.2

1.0

Result

4750

[0.45]

2.2

[14.1]

[0.21]

[35.2]

7.5

[0.70]

[4.0]

8110

10.2

[131]

19.8

[1.8]

[444]

[0.54]

[62.0]

[9.2]

6.4

[0.0531

Flafl

B

J

B

B

L

UL

B

K

B

UL

L

B

MC0071

SB-B 350-0607

Soil

mg/Kg

06/26/2002

10:40

88.7

1.0

Result

8530

[0.52]

3.8

[19.6J

[0.38]

[50.6]

10.3

[0.98]

7.3

15000

12.9

[160]

21.6

[2-3]

[583]

[0.76]

[63.2]

16.8

11.7

[0.0351

Flag

B

J

B

L

UL

B

K

B

UL

B

MC0072

SS-B325

Soil

mg/Kg

06/26/2002

10:50

87.0

1.0

Result

9700

[0.53]

5.0

55.0

[0.55]- -:

1320

12.9

[6.7]

23.2

21900

20.7

1700

717

9.9

[471]

1.3

[83.2]

19.7

53.2

[0.25]

nafl

B

J

L

UL

K

B

UL

B

MC0073

SB-B325-0206

SoU

mg/Kg

06/26/2002

10:55

91.8

1.0

Result

6180

[0.55]

3.0

[17.6]

[0.21]

(81.8]

7.0

[5.2]

7.5

10000

7.8

[784]

191

[5.1][368]

[0.48]

[159]

11.9

14.7

[0.0661

Flag

B

J

B

B

L

UL

B

K

B

UL

B


To calculate sample quantttation limits: (CRDL * Dilution Factor) / (%Sol'ds/ 100)


Revised 09/99

DATA SUMMARY FORM: INORGANIC Page _7__ of _28_

Case* 30647Site:

Lab.:

SDG: MC0069

VALMONTTCE

LIBRTY

Sample Number:

Sampling Location :

FtetdQC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%Sdkls:

Dilution Factor :

ANALYTEALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM .

.CHROMIUM

COBALT

COPPER

IRON

•tEAD

MAGNESIUM

MANGANESE

MERCURY

NICKELPOTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

'VANADIUMZINCCYANIDE

CRDL

40

12

2

401

1

1000

2

10

5

20

0.6

1000

3

0.1

a1000

12

1000

2

104

O.S

MC0074

SS-B100

Soil

mg/Kg

06/26/2002

11:15

82.0

1.0

Result

7670

>[0.63]

3.0[32.6]

[0.20]

2690

12.3

[2-0]

8.8

11800

24.6

[728]

135

[4.4]

[431]

[0.84]

[72.1]

17.0

43.2[0.25]

Flag

BJ

B •

LULe

K

B

UL

B

MC0075

SB-B100-0206

Field Dup. of

MC0076

Soilmg/Kg

06/26/2002

11:20

87.7

1.0

Result

13000

10-41]4.5

[35.0]

[0.35]

[24.5]

16.6

[1.2]

10.4

21400

12.9

[299]

27.2

[3.2]

[615]

166.9]

26.6

12.2

Flap

BJ

B

LUL

B

BUL

MC0076

SB-DUP-03

Field Dup. of

MC0075

Soilmg/Kg

06/26/2002

11:2388.21.0

Result

11200[0.66]

4.1

[29.6][0.30]

[182]16.7[1.7]

9.4

18600

10.9[493]

51.6

[4.4][548]

[0.65]

[142]

22.513.9

[0.036]

Flag

BJ

B

B

LUL

B

K

BUL

B

MC0077

SB-B100-0608

Soilmg/Kg

06/26/2002

11:2582.51.0

Result

19100, 10.93]

5.8[34.2][0.24]

[18.6]

23.2

[1.0]11.4

27000

11.7[269]

10.t

[2.9][451][0.82]

37.0

10.3

Flag

BJ

B

B

-

LULB

K

UL

MC0079

SB-D300-0206

Soilmg/Kg

06/26/2002

11:5586.21.0

Result

11800

[0.55]

3.5124.9]

10.27]

[30.6]

23.9[1.6]

8,327300

10.8[429]59.7

[3.3][390][0.90]

[65.3]

33.512.5

[0.0481

Flag

BJ

B

B

LULB

K

BUL

BCRDL = Contract Required Quantitatton Limit

To calculate sample quantitatton limits: (CRDL * Dilution Factor) / (%Solids/100)


Revised 09/99


Case #: 30647

Site:

Lab.:

SDG: MC0069

VALMONTTCE

LIBRTY-

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%So»ds:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

. CHROMIUM

COBALT

; COPPER

IRON

>LEAD;

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

. VANADIUM

ZINC

CYANIDE

CRDL

4012

2401

11000

2

105

200.6

1000

30.1

81000

12

1000

2

104

0.5

MC0080

SB-D300-1012

•

Soil

mg/Kg

06/26/2002

12:00

64.2

1.0Result

6050

[0.48]

[1.9]

[30.2]

[0.66]

[146]

14.5

[1.3]

23.9

18800

15.2

[148]

44.8

[2.1]

[693]

[0.72]

[92.0]

19.9

9.9

Flaq

BJ

B

L

ULB

K

B

UL

MC0081

SS-E300-0002

Soil

mg/Kg

06/26/2002

12:20

89.2

1.0Result

7800

2.7[17.7]

[0.18]

[1080]

10.2

[2.2]

7.512700

8.2[718]

96.0

[4.3]

[462]

[0.92]

[90.7]

15.8

14.9

(0.040]

Flafl

ULJ

B

LULB

K

BUL

B

MC0082

SB-E300-0206

Soil

mg/Kg

06/26/2002

12:25

82.7

1.0Result

18100

. [0:69],

4.9

46.4

[0.26]

[312]

20.6

[2.8]

13.1

22400

13.4

1560

49.9

[7.9]

[604]

1.4

[84.5]

33.3

23.9

[0.070]

Flafl

BJ

B

B

LUL

K

B

UL

B

MC0083

SB-E300-1012

Soil

mg/Kg

06/26/2002

12:30

92.5

1.0Result

4290

10-38}

[1.3]

[23.21

[0.30]

[39.9]

7.718.7

12.8

18000

8.6[79.3]

306

n. n[424]

[0.76]

[37.9]

11.9

12.5

Flag

BJ

B

B

LULB

K

BUL

MC0084

SS-0225-0002

Soil

mg/Kg

06/26/2002

13:10

85.2

1.0Result

7240

12.0]

I17.3J

[0.11]

[488]

8.2[1.0]

[4.5]

10200

6.8[355]

47.6

[2.2]

[309]

[0-67]

[72.2]

15.3

10.5

[0.081]

Flag

ULJ

B

B

LUL

B

K

BUL

BCRDL = Contract Required Quantitatton Limit

To calculate sample quantitation limits: (CRDL • Dilution Factor) / (%Sofids/ 100)


Revised 09/99


Case ft 30647

Site:

Lab.:

SDG:MC0069

VALMONTTCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix: .

Units:

Date Sampled :

Time Sampled :

%SolkJs:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM.

COBALT

COPPER

IRONTEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINCCYANIDE

CRDL

40

12

2

401

1

1000

2

10

5 "„20

0.6-

1000

3

0.1

a1000

12

1000

2

10

4

0.5-

MC0085

SB-D225-0206

Soil

mg/Kg

06/26/2002

13:15

86.8

1.0

Result

9630

[0.57]

3.0

[27.0J

[0.18]

[539]

14.0

[2.0]

7.8

17900

9.8

[459]

52.6

[3.4]-

[417]

[0.98]

186.6]

21.1

11.7

W.095]

Flag

B

J

B •

B

L

UL

B

k

B

UL

8

MC0086

SB-D225-1012

Soil

mg/Kg

06/26/2002

13:20

92.0

1.0

Result

3540

[0.61]

[1.9]

111.0]10.13]

[123]

4.9

[2.5]

8.2

10700

5.6

[71.6]

20.2

[0.77]

[360]

[0.55] ;

[59.4]

[9-3]

4.7

[0.0461

Flat)

B

J

B

B

B

L

UL

B

K,

B

UL

L

B

MC0087

SS-F400-0002

Soil

mg/Kg

06/26/2002

13:40

89.1

1.0

Result

8140

2.8

[21.8]

[0.19]

[150]

12.8

[1.4]

7.2

15100

7.8

[482]

62.5

[3.4]

[378]

[95.8]

18.5

12.9

Flap

UL

J

B

B

L

UL

B

UL

B

UL

MC0088

SB-F400-0206

Soil

mg/Kg

06/26/2002

13:45

85.8

1.0

Result

11000

3.2

129.4J

[0.30]

[8.6]

15.7

[1.1]

11.5

18400

11.0

[262]

22.3

[2-8]

[403]

[40.3]

25.3

10.2

[0.067]

Flaq

UL

J

B

,

B

L

UL

B

UL

B

UL

B

MC0089

SB-F400-0608

Soil

mg/Kg

06/26/2002

13:50

86.7

1.0

Result

9320

2.8

123.8]

10.21]

[49.2]

14.4

[0.96]

10.9

16600

9:7

[187]

13,4

[2.2]

[320]

[233]

22.2

9.6

Flag

UL

J

B

B

-

L

UL

B

UL

B

UL


To calculate sample quantitation limits: (CRDL * Dilution Factor) / (%SolWs/100)


Revised 09/99


Case #-. 30647Site:

Lab.:

SDG : MC0078

VALMONT TCE

LIBRTY

Number of Soil Samples : 20

Number of Water Samples : 0

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%Solids :

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

' MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINCCYANIDE

CRDL

40122

4011

1000

2

105

200.6

1000

30.1

81000

12

1000

2104

0.5

MC0078

SS-D300-0002

Soil

mg/Kg

06/26/2002

11:50

89.0

1.0Result

6960

[0.73]

2.4

H9.9]

[0.33]

[183]

8.4

[1.6]

[5.0]

10400

9.5[499]

109

[3.6]

[322]

[77.9]

14.5

13.2

[0.079]

Flag

B

B •

B

L

B

BUL

B

MC0090

SS-E400-0002

Soil

mg/Kg

06/26/2002

14:20

90.2

1.0Result

7400

[0.55]

2.8[23.4]

[0.27]

[228]

10.4

12.3]

5.610400

11.2

[470]

104

[3.9]

[314]

[75.7]

16.0

16.6

Flafl

B

B

B

L

B

BUL

MC0091

SB-E400-0206

Soil

mg/Kg

06/26/2002

14:25

89.0

1.0Result

7920

[0.54J

3.3[21.7]

[0.37]

[27.8]

10.3

[3.7]

7.614600

7.5[784]

134

[5-4][421]

171-3]

16.6

16.9

[0.076]

Flafl

B""•

B

B

L

BUL

B

MC0092

SB-E400-1011

Soil

mg/Kg

06/26/2002

14:30

92.3

1.0Result

4210

2.2[11.0]

[0.24]

[9.4]

5.3[6.9]

6.78580

5.6[82.2]

95.8

[1.3]

[342]

[70.1]

[8.1]

[4.1][0.076]

Flafl

UL

B

B

B

L

B

BUL

L

B

MC0093

SS-D400-0002

Soil

mg/Kg

06/26/2002

14:45

84.1

1.0Result

8540

[0.48]

3.2

120.5]

[0.20]

[333]

9.6[0.88]

[3.6]

14300

8.8[346]

76.7

[2.3]

[247]

[0.84]

[106]

24.9

16.0

[0.10]

Flaq

B

B

B

L

B

K

BUL

B


To calculate sample quantftation limits: (CRDL * Dilution Factor) / (%Solids/100)


Revised 09/99


Case ft 30647

Site:

Lab.:

SDG: MC0078

VALMONTTCE

LIBRTY '

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%Sofids:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

lEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40

12

2

40

1

1

1000

2

10

5

20

0.6

1000

3

0.1

8

1000

1

2

1000

2

10

4

0.5

MC0094

SB-D400-0206

Soil

mg/Kg

06/26/2002

14:50

85.9

1.0 ..

Result

20200

[0.51]

5.7

[21.7J

[0.34]

[31.1]

22.5

[1.0]

11.7

24700

9.2

[305]

23.2

[0.092]

[3.1][419]

[0.94]

[59.0]

34.7

11.6[0.060]

Flag

B

B

B

L

B

K

B

UL

B

MC0095

SB-D400-0810

Soil

mg/Kg

06/26/2002

14:55

86.3

1.0

Result

13900

[0.55]

4.4

[15.6]

[0.26]

[10.8]

13.3

[1.2]

11.5

17800

10.6

[215]

31.2

[0.077]

[3.0]

[340]

[0.71]

[37.7]

22.3

8.0, [0.098]

Flafl

B

B

B

L

B

K

B

UL

L

B

MC0096

SS-C400-0002

Soil

mg/Kg

06/26/2002

15:15

92.0

1.0

Result

7450

[0.44]

2.9

[23.0J

10.26]

[7141

9.0

[2.1]

5.9

12400

13.0

[772]

63.6

[5.9]

[328]

[0.72]

[125]

14.1

26.6

[0.12]

Flag

B

B

B

L

,

K

B

UL

B

MC0097

SB-C400-0206

Soil

mg/Kg

06/26/2002

15:20

89.3

1.0

Result

10200

[0.38]

3.3

122.6]

[0.30]

[111]

10.2

[1.9]

7.9

13300

9.9

[457]

55.2

[3.5]

[444]

[0.52]

[102]

18.5

11.7

[0.111

Flaq

B

B

B

L

B

K

B

UL'

B

MC0098

SB-C400-0607

SoO

mg/Kg

06/26/2002

15:25

86.1

1.0

Result

24300

[0.74]

6.4

[25.41

[0.38]

[60.9]

26.8

[1.2]12.0

27100

11.6.

[291]

22.9

13.3]

[483]

[0.93]

[40.2]

40.8

12.9

[0.101

Rag

B

B

B

L

B

K

B

UL

B

CRDL = Contract Required Quantitatton LimH

To calculate sample quantitalion limits: (CRDL * Dilution Factor) / (%Solids/ 100)


Revised 09/99


Case #-.30647

Site:

Lab.:

SDG: MC0078

VALMONTTCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled:

Time Sampled :

%SoKds:

Dilution Factor:

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40

12

2

401

1

1000, „ p

10

5200.6

1000

. 3

0.1

81000

12

1000

2

104

0.5

MC0099

SS-8450-0002

Sofl

mg/Kg

06/26/2002

15:35

89.7

1.0Result

6020

4.0

I17.2J

[0.21]

[175]

7.2[7.5]

[4.2]

10200

13.3

[584]

346

[5.0]

[398]

[82.9]

[9.8]

12.4

[0.057]

Flafl

UL

B '

B

L

8

B

UL

B

MC0100

SB-B450-0204

Field Dup. of

MC0101

Soil

mg/Kg

06/26/2002

15:40

93.3

1.0Result

5450

[0.47]

3.6

[18.4]

[0.23]

[202]

6.7

[1.9]

[3.9]

8440

9.5

[537]

61.9

[4.0]

[552]

[0.68]

[46.2]

[8.5]

11.4

Flafl

B

B

B

L

B

K

B

UL

MC0101

SS-OUP-03

Field Dup. of

MC0100

Soil

mg/Kg

06/26/2002

15:15

90.3

1.0

Result

7590

[0.45]

2.5

[19.4]

[0.21]

[94.5]

10.1

[1.0]

6.4

13700

6.6

[378]

44.5

[2.8]

[307]

[0.94]

[98.0]

16.7

11.4

ro.0641

Flslfl

B

B

B

L

B

K

B

UL

B

MC0102

SS-D450-0002

Sofl

mg/Kg

06/27/2002

07:45

87.1

1.0

Result

4680

[2.0]

[21.2]

[0.15]

[267]

5.2

[0.94]

(3.5]

7410

13.0

[190]

68.8

[1.8]

[171]

[0.56]

[96.3]

11.9

11.4

[0.11]

Flafl

UL

B

B

L

B

K

BUL

B

MC0103

SB-D450-0206

Soil

mg/Kg

06/27/2002

07:50

88.0

1.0Result

8920

10.49]

4.0f25.2J

[0.22]

[79.8]

13.9

[2.6]

6.715900

8.2[787]

77.5

(5.0]

[331]

(0.62]

[62,9].

18.4

16.2

[0.15]

Flag

B

B

B

L

B

K

BUL

BCRDL - Contract Required Quantrtatton Limit

To calculate sample quantitation limits: (CRDL ' Dilution Factor) / (%Sdids/ 100)


Revised 09/99

DATA SUMMARY FORM: INORGANIC Page_l3 of 28

Case* 30647

Site:

Lab.:

SDG: MC0078

VALMONT TCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%Solids:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40122

401

11000

2105

200.6

1000

30.1

81000

12

1000

2104

0.5

MC0104

SS-D450-0911

Sofl

mg/Kg

06/27/2002

07:55

88.3

1.0Result

6850

[0.47]

2.2[10.0]

10.16]

[20.5]

6.7[1.0]

[5.2]

7890

6.7[95.8]

31.4

[1.1]

[311]

[45.0]

[10.9]

[4.1]

[0.0651-

Flao,

B

B

B

BL

8

BUL

LB

MC0105

SS-E450-0002

Soil

mg/Kg

06/2712002

08:15

83.1

1.0Result

9720

[0.62]

3.3

[20.0]

[0.20]

[22.1]

14.6

[1.0]

8.018000

8.9[372]

42.7

I3.0]

[402]

[0.75]

[50.6]

21.9

11.0

[0.053]

Flafl

B

B

B

L

B

K

BUL

B

MC0106

SB-E450-0206

Soil

mg/Kg

06/27/2002

08:20

90.0

1.0Result

10500

[0.50]

3.4

[21.6]

[0.28]

[8.0]

17.1

[0.78]

13.6

22600

11.6

[169]

18.5

11.9]

[477]

1.3

[52.5]

25.8

9.6[0.0571

Flap,

B

B

B

L

B

K.

BUL

B

MC0107

SB-E450-0709

Soil

mg/Kg

06/27/2002

08:25

91.2

1.0Result

7540

fO-SSJ

3.6[17.6]

[0.22]

[64.0]

40.9

[3.5]

7.916200

10.2

[232]

88.8

[2.8]

[475]

[0.80]

[60.6]

15.2

7.9(0.048)

Flaq

B

B

B

1

B

K

BUL

L

B

MC0108

SS-I350-0002

Soil

mg/Kg

06/27/2002

08:40

85.7

1.0Result

7220

2.9

115.5]

[0.22]

[33.2]

10.5

10.53]

8.8

13800

11.4

[117]

14.3

[1.4]

[409]

[149]

16.2

7.8

Flag

UL

B

B

BL

B

BUL

L




Revised 09/99

DATA SUMMARY FORM: INORGANIC Page_i4 of_28

Case #-.30647

Site:

Lab.:

SDG : MC0109

VALMONT TCE

LIBRTY



Sample Number :Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%So«ds :

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUMBERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKELPOTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINCCYANIDE

CRDL

40

12

2

401

1

1000

2

10

5

20

0.6

1000

3

0.1

8

1000

1

2

1000

2

10

4

0.5

MC0109

SB-1350-0206

Field Dup. of

MC0110

Soil

mg/Kg

06/27/2002

08:45

87.2

1.0

Result

9770

8.7

[16.9J[0.54]

[0.34]

[37.1]

19.4

[2.9]

16.9

44800

21.5

[109]

139

[0.052]

[2.5]

[595]

1.3

[69.3]

31.0

9.6

[0.043)

Flag

UL

B

K

B

B

B

B

MC0110SB-DUP-04

Field Dup. of

MC0109

Soilmg/Kg

06/27/2002

08:45

86.8

1.0

Result

7820

3.4

[13.3]

[0.24]

[0.17]

[42.6]

9.8

[0.62]

12.0

21400

10.6

[99.5]

30.6

[1.3]

[572]

[0.54]

[62.3]

17.3

6.4

[0.053]

Flap

UL

B

K

B

B

B

B

MC0111

SS-F450-0002

Soil

mg/Kg

06/27/2002

09:10

88.0

1.0

Result

5660

[2.1]

-122.1]

[0.12]

10.10]

(388)

6.7

[1.9]

7.0

9370

7.9

[290]

130

[2.0]

[432]

[85.0]

14.2

11.7

[0.0401

Flag

UL

B

K

J

B

B

B

MC0112

SB-F450-0206

Soil

mg/Kg •

06/27/2002

09:15

87.0

1.0

Result

9510

3^

[21.7]

[0.23]

[0.13]

[45.5]

11.4

[1.6]

14.9

15500

10.3

[432]

62.3

[3.9]

[642]

[54.3]

20.5

14.1

[0.098]

Flaq

UL

B

K

J

B

B

B

MC0113SB-F450-1012

Soil

mg/Kg

06/27/2002

09:2088.8

1.0

Result

10800

4.8115.5]

[050][0.14]

[24.9]

11.4

[1.2]

18.5

17400

10.6

[142]

21.9

[0.086]

[1.7]

[664]

20.8

8.1

[0.10]

Flao.

UL

B

K

J

B

B

CRDL = Contract Required Quantitatton Limit

. To calculate sample quantitation limits: (CRDL * Dilution Factor) / (%Solids/100)


Revised 09/99

DATA SUMMARY FORM: INORGANIC Page_i5 of_28_

Case #: 30647Site:Lab.:

SOG: MC0109

VALMONT TCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

KSolids:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY .

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40122

401

1

1000

210

520

0.61000

30.1

81000

12

1000

2104

0.6

MCQ114

SS-G450-0002

Soil

mg/Kg

06/27/2002

09:40

84.7

1.0Result

15100

5.7

[36.0]

[0.25]

[0.18]

[69.0]

16.8

[3.0]

18.3

20400

10.8

1400

66.3

[7.5][665]

[0.90]

[76.1]

29.2

28.5[0.040]

Flag

UL

B

KJ

B

B

MC0115

SB-G450-0206

Soil

mg/Kg

06/27/2002

09:45

85.9

1.0

Result

15600

5.6

[34.9]

[0.32]

[0.19]

[54.7]

19.0

[1.5]

18.6

21100

12.5

[480]

28.6

[4.6]

[768]

[0.58]

[60.7]

31.6

17.2[0.0671

Flaq

UL

B

KJ

B

B

B

MC0116

SB-G450-1012

Soil

mg/Kg

06/27/2002

09:50

84.1

1.0Result

9650

8.1[17.4]

[0.59]

[0.21]

[33.5]

11.8

[1.3]

32.6

29500

13.4

[152]

45.6

- [2.9][754]

[0.71]

[84.1]

22.4

17.7

[0.072]

Flag

UL

B

KJ

B

B

B

MC0117

SS-H450-0002

Soil

mg/Kg

06/27/2002

10:15

88.5

1.0Result

12000

4.4

[22,4]

[0.30]

[0.20]

[563]

16.9

[0.72]

17.7

19400

13.6

[211]

29.4

[2.8]

[757]

[72.4]

25.7

11.7

[0.066]

Flag

UL

B

KJ

B

B!

B

MC0118

SS-G400-0002

Soil

mg/Kg

06/27/2002

10:40

89.1

1.0Result .

11000

4.2124.2]

[0.23]

[0.15]

[52.8]

12.4

[2.8]

16.5

15200

9.0[1030]

73.8

[6.9]

[658]

159.1]

20.7

21.1

Flag

UL

B

KJ

B




Revised 09/99

DATA SUMMARY FORM: INORGANIC Page_16 .of_28

Case #: 30647

Site:

Lab.:

SDG: MC0109

VALMONT TCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%S<Xids :

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40122

401

1

1000

210

520

0.6

1000

30.1

81000

1

21000

2104

0.5

MC0119

SB-G400-0206

Soil

mg/Kg

06/27/2002

10:45

86.2

1.0Result

14600

4.4

(28.1)

[0.25]

[0.21]

[26.4]

18.0

[1.0]

16.3

19300

13.4

[261]

21.1

13.6]

[752]

[50.2]

27.8

12.5[0.056]

Flap

UL

B

K

J

B

B

B

MC0120

SB-G400-1012

Soil

mg/Kg

06/27/2002

10:50

87.7

1.0Result

7910

5.2

114.8][0.16]

[23.8]

8.611.8

18.3

11600

12.6

[150]

169

[2.0]

[583]

[0.51]

[47.1]

17.5

8.4[0.094]

Flap

UL

B

KJ

B

B

B

MC0121

SS-E500-0002

Soil

mg/Kg

06/27/2002

11:05

83.8

1.0Result

13400

5.1(29.2]

[0.19]

[0.17]

[158]

16.0

[2.2]

16.8

21500

9.2[1000]

100[0.062]

[6.0]

[653]

[124]

28.9

24.6

fO.060]

Flap

UL

B

KJ

B

B

MC0122

SB-E500-0206

Soil

mg/Kg

06/27/2002

11:10

82.4

1.0Result

13700

4.6129.0]

[0.28]

10.21]

[48.2]

19.0

[1.1]

17.9

24700

12.9

[387]

38.8

0.12

[3.8]

(727]

(0.77]

[45.4]

29.6

14.0

[0.201

Flap

UL

B

KJ

B

B

B

MC0123

SB-E500-0911

Soil

mg/Kg

06/27/2002

11:15

88.6

1.0Result

13800

4.4

(19-31[0.21]

10.24]

(40.6]

19.3

(1.4]

17.3

21200

11.4

[209]

16.9

[2.6]

(637]

[0.80]

(48.5]

26.1

10.8

[0.0561

Flag

UL

B

KJ

B

B


To calculate sample quantitation limits: (CRDL * Dilution Factor) / (%Solids/ 100)SEE NARRATIVE FOR CODE DEFINITIONS

Revised 09/99


Case #-.30647

Site:

Lab.:

SDG : MC0109

VALMONT TCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%Sofids:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40122

401

1

1000

2105

200.6

1000

30.1

81000

12

1000

2104

0.5

MC0124

SS-E100-0002

Soil

mg/Kg

06/27/2002

12:30

89.7

1.0Result

12200

4.5[27.5J

[0.22]

[0.16]

[457]

15.1

[2.6]

16.6

18000

10.5

[945]

114

I6.6]

[645]

[59.0]

23.0

24.2

fO.16]

Flat)

UL

B

K

J

B

B

MC0125

SB-E100-0206

Soil

mg/Kg

06/27/2002

12:35

86.5

1.0Result

10500

4.0[27.1]

[0.19]

[0.19]

[766]

19.6

[2.2]

13.2

16900

10.7

[704]

96.9

[5.6]

[623]

[0.77]

[71.0]

22.2

19.9

(0.063)

Flag

UL

B

KJ

B

B

MC0126

SB-E100-0709

Soil

mg/Kg

06/27/2002

12:40

95.0

1.0Result

3030

[1.4]

[8.0]

[0.097]

[375]

6.1[1.1]

5.06250

5.9[289] .

30.6

[2.3]

[364]

[43.6]

[5.6]

7.0[0.049]

Flap

UL

B

KJ

B •

B

B

MC0127

SS-H 100-0002

Field Dup. of

MC0128

Soil

mg/Kg

06/27/2002

13:15

91.6

1.0Result

7950

4.7

[18.8]

[0.23]

[0.16]

[80.6]

10.3

[3.3]

15.7

14900

7.7

[965]

110

[6.2]

[514]

[62.9]

15.8

19.7

(0.0671

Flag

UL

B

KJ

B

B

MC0131

SB-F 150-0206

Soil

mg/Kg

06/27/2002

13:50

87.1

1.0Result

9510

2.5{19.9]

(0.20)

(0.19]

[202]

14.2

[0.75]

15.0

15500

11.2

[222]

18.6

[2.8]

[655]

[0.63]

20.9

12.3

(0.038]

Flag

UL

B

KJ

B




Revised 09/99

DATA SUMMARY FORM: INORGANIC PageJB of_28

Case ft: 30647

Site:

Lab.:

SDG: MC0128

VALMONTTCE

LIBRTY



Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%Solids :

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40

122

4011

1000

210

5200.6

1000

30.1

81000

1

2

1000

2

10 .

40.5

MC0128

SS-DUP-04

Field Dup. of

MC0127

Soil

.mg/Kg

06/27/2002

13:15

92.3

1.0..

Result

7450

3.8.

[18.4]

[0.21]

[0.11]

[141]

8.2[3.0]

15.1

12200

7.0[904]

102[0.068]

[5.9]

[493]

[37.7]

14.1

18.5

Ftefl

UL

B

B

J

UL

B

J

MC0129

SB-H100-0206

Soil

mg/Kg

06/27/2002

13:20

92.3

1.0Result

5100

3.1[15.5]

[0.20]

[0.17]

[589]

10.6

[4.1]

11.6

13800

7.4

[632]

219[0.050]

[4.7]

[440]

[40.0]

11.7

15.2[0.073]

Flacj

UL

B

B

J

B

UL

B

JB

MC0130

SS-F 150-0002

Soil

mg/Kg

06/27/2002

13:45

83.1

1.0Result

13900

6.0(25.6]

[0.16]

[0.34]

[87.2]

15.6

[1.2]

15.6

27000

10.7

[612]

50.8

[0.081]

[4.8]

[607]

[1.1]

[65.6]

27.3

20.7

[0.070]

Flaq

UL

B

B

J

B

L

B

JB

MC0132

SB-F1 50-0810

Soil

mg/Kg

06/27/2002

13:55

85.2

1.0Result

13400

4.5125.8]

[0.29]

[0.22]

2190

19.4

11.8]

20.2

22800

12.3

[419]

71.6

0.14

[4.4]

[804]

[0.90]

[42.5]

27.3

19.7

[0.11]

Flag

UU

J

B

L

B

JB

MC0133

SS-G200-0002

Soil

mg/Kg

06/27/2002

14:20

86.6

1.0Result

8860

2.4

118.0]

10.15]

10.19]

[93.8]

11.1

[1.6]

13.8

14500

7.0[609]

33.0

[0.077]

14.6][507]

17.2

15.9

[0.18]

Flag

UL

B

B

JB

JB

CRDL = Contract Required Quantilation Limit



Revised 09/99


Case * 30647

Site:

Lab.:

SOG: MC0128

VALMONT TCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%So)ids :

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40

12

2

401

1

1000

2

10

5

20

0.6

1000

3

0.1

8

1000

1

2

1000

2

10

4

0.5

MC0134

SB-G200-0206

Soil

mg/Kg

06/27/2002

14:25

85.8

1.0

Result

11200

4.3

[28.8]

[0.35]

[0.29]

[274]

16.8

[2.1]

20.0

21100

11.2

[616]

57.4

[0.094]

[6.2]

[679]

[0.71]

. [40.3]

24.0

21.3. [0.092]

Flap

UL

B

J

B

JB

MC0135

SB-G200-0608

Soil

mg/Kg

06/27/2002

14:30

88.3

1.0

Result

12300

6.6

[26.4]

- [0.24]

[0.30]

[97.3]

17.2

[2.5]

21.2

22200

10.0

1210

59.6

[0.097]

[7.4]

[647]

[0.74]

[56.0]

'25.1

25.1

Flag

UL

B

J

B

J

MC0136

SS-H300-0002

Soil

mg/Kg

06/27/2002

14:50

89.4

1.0

Result

11300

3.9

[21.2]

[0.21]

[0.21]

[235]

13.4

[1.3]

16.6

16000

10.5

[340]

42.7

[0.067]

[3.6]

[605]

[0.66]

[40.2]

21.9

14.1

Flag

UL

B

B

J

B

B

J

MC0137

SB-H300-0206

Soil

mg/Kg

06/27/2002

14:55

88.1

1.0

Result

10800

5.0

[20.8]

[0.31]

[0.26]

[175]

j 19.4

[0.84]

18.5

18900

13.6

[239]

3145

[0.078]

[3.3]

[647]

[0.73]

[48.2]

22.4

17.0

[0.0581

Flag

UL

B

J

B

B

J

B

MC0138

SS-17

Soil

mg/Kg

06/27/2002

08:15

98.3

1.0

Result .

4670

2.9

121.11

10.22]

[0.41]

962

12.5

[7.0]

17.6

12600

19.6

1040

284

[0.059]

9.2

[546]

[0.62]

•[221]

11.0

48.0

[0.12]

Flag

UL

J

B

J

B


• To calculate sample quantitation limits: (CRDL * Dilution Factor) / (%Solids/100)


Revised 09/99

DATA SUMMARY FORM: INORGANIC Page _20 of _28_

Case fc 30647Site:

Lab.:

SDG : MC0128

VALMONTTCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%Solids :

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON .

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER •

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40

12

2

40

1

1

1000

2

10

5

20

0.6

1000

3

0.1

8

1000

1

2

1000

2

10

4

0.5

MC0139

SB-1 7-0206

Soil

mg/Kg

06/27/2002

09:35

79.2

1.0

Result

9560

3.0

[29.8}

[0.21]

[0.20]

[213]

10.0

[4.4]

11.7

11600

13.0

[676]

167

[0.087]

15.1][4941

[0.70]

[86.4]

18.0

24.6[0.096]

Flap

UL

B '

B

J

B

B

JB

Result Flao, Result Rafl Result

/

Flaq Result Flag




Revised 09/99


Case #: 30647Site:

Lab.:

SDG: MC0143

VALMONTTCE

LIBRTY

Number of Soil Samples : 20


Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%SolkJs :

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40

12

2

401

1

1000

2

10

5

20

0.6

1000

3

0.1

8

1000

1 ,

2

1000

2

10

4

0.5

MCQ143

SS-F535

Soil

mg/Kg

06/28/2002

08:15

73.5

1.0

Result

8420

[0.91J

6.4

63.0

[0.40]

[0.94]

[1070]

13.8

[5.0]

33.7

17900

111

[1030]

461

[0.058]

13.3

[626]

[1.0]

[0.14]

[324]

25.0

147

[0.42]

Flafl

L

B

J

J

B

J

B

MC0144

SB-F535-0206

Soil

mg/Kg

06/28/2002

08:20

84.4

1.0

Result

9440

[0.52]

3.1

[15.9]

[0.16]

[409]

12.9

[0.74]

13.7

17000

8.6

[320]

40.6 '

[2.7]

[494]

[1.0]

[54.4]

21.7

13.1

[0.10]

Flafl

L

B

J

B

J

B

J

B

MC0145

SB-F535-0810

Soil

mg/Kg

06/28/2002 •

08:25

88.5

1.0

Result

9590

2.9

[15.6]

[0.18]

[233]

13.2

[0.53]

12.6

17300

10.3

[172]

15.9

[1.8]

[606]

[0.78]

[55.5]

19.3

8.1

[0.061]

Flafl

UL

B

J

B

J

B

J

B

MC0146

SS-D535

Soil

mg/Kg

06/28/2002

08:40

89.6

1.0

Result

6040

[0.69]

3.8

47.7

[0.36]

[0.40]

1470

9.3

[5.1]

20.0

14400

39.4

[1010]

305

10.3

[571]

[1.0]

[173] '

16.6

68.7

[0.14]

Flap

L

J

J

B!

J

B

MC0147

SB-D535-0206

Soil

mg/Kg

06/28/2002

08:45

87.1

1.0

Result

24200

7.3

[28.71

[0.301

[0.19]

[327]

26.6

[1.3]

25.6

30900

13.1

[465)

48.8

[0.078]

[5.4]

[709]

[0.77]

[58.3]

44.4

18.8

[0.065]

Flag

UL

*

B

J

J

B

J

B




Revised 09/99


Case fc 30647

Site:

Lab.:

SDG : MC0143

VALMONT TCE

LIBRTY-

Sample Number :

Sampling Location :

ReWQC:

Matrix:

Units:

Date Sampled :

Time Sampled : '

%Solids:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40

12

2

401

1

1000

2

10

5

20

0.6

1000

3

0.1

8.

10001

2

1000

2

10

4

0.5

MC0148

SB-D535-0810

Soil

mg/Kg

06/28/2002

08:50

85.0 •

1.0

Result

16500

[0.56]

5.6

[19.5J

[0.20]

[0.14]

[267]

20.0

[0.68]

17.5

21400

11.1

[241]

20.4

[0.049]

[2.9]

[597]

[0.84]

[50.2]

31.5

11.4

[0.042]

Flacj

L

B

J

B

J

B

J

B

MC0149

SS-B540

Soil

mg/Kg

06/28/2002

09:10

87.3

1.0

Result

2380

[0.57]

[0.93]

[10.3]

[0.063]

[1100]

2.8

[0.45]

[4.3]

4130

8.5

[170]

47.1

[1.3]

[200]

[0.66]

[58.6]

[6.7]

12.0(0.058]

Flacj

L

J

B

J

B

J

B

MC0150

SB-B540-0206

Soil

mg/Kg

06/26/2002

09:15

94.9

1.0

Result

5790

[0.58J

2.3

[15.5]

[0.18]

[207]

7.5

[0.61]

7.0

11300

11.3

[196]

21.2

[2.0]

[522]

[0.67]

[38.8]

11.7

9.0

Flag

L

B

J

B

J

B

J

UL

MC0151

SB-B540-0608

Soil

mg/Kg

06/28/2002

09:20

89.0

1.0

Result

6820

2,4

117.3]

[0.16]

[204]

8.5

[1.3]

8.8

10600

10.6

[302]

41.7

[2.9]

[592]

[0.62]

[40.2]

12.7

8.8

Flag

UL

B

J

B

J

B1

J

UL

MC0152

SS-A540

Soil

mg/Kg

06/28/2002

09:30

87.5

1.0

Result

9630

4.2

125.7]

[0.22]

[0.12]

[490]

11.0

[3.6]

13.3

16600

15.8

[696]

216

[4.7]

[561]

1.6

[80.6]

21.1

26.7

[0.071]

Flag

UL

B

B

J

B

J

B

J

B


To calculate sample quantitation limits: (CRDL' Dilution Factor) / (%Solids/100)


Revised 09/99

DATA SUMMARY FORM: INORGANIC Page_23 ot_28

Case #: 30647Site:

Lab.:

SDG: MC0143

VALMONTTCE

LIBRTY

Sample Number ;

Sampling Location :

FeW QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%Solids :

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINCCYANIDE

CRDL

40.

12

2

401

1

1000

2

10

5

20

0.6

1000

3

0.1

8

1000

1

2

1000

2

10

4

0.5

MC0154

SB-A540-0607

Soil

mg/Kg

06/28/2002

09:45

90.2

1.0Result

4610

[1.7]

[16.5]

[0.18]

[201]

5.9[1.6]

6.99090

9.1[166]

36.0

[1.4]

[680]

[0.47]

[39.7]

[9.8]

7.4

Flaq

UL

B

J

B

J

B

JUL

MC0155

SS-A200

Soilmg/Kg

06/28/2002

10:05

83.2

1.0Result

8430

2.951.7

[0.42]

[0.19]

1870

9.7[3.0]

11.6

13300

24.1

1350

496

[6.5]

[508]

[0.86]

[119]

17.9

44.2

(0.20]

Flafl

UL

J

J

B

JB

MC0156

SB-A200-0206

Soil

mg/Kg

06/28/2002

10:10

85.0

1.0Result

13800

4.6

[25.3]

[0.40]

[0.10]

[285]

17.8

[0.82]

16.2

21000

13.0

[304]

25.0

[0.068]

[3.6]

[606]

[46.8]

27.1

12.0

[0.0431

Flaq

UL

B

J

B

UL

B

JB

MC0157

SB-A200-0608

Soil

mg/Kg

06/28/2002

10:15

87.4

1.0Result

9510

3.6

[23.8]

[0.39]

[176]

10.5

[4.0]

14.1

20000

17.1

[159]

135

[1.8]

[532]

[0.74]

19.4

12.5

[0.063]

Flag

UL

B

J

B

J

JB

MC0158

SS-A400

Soil

mg/Kg

06/28/2002

10:40

85.2

1.0Result

5240

[0.69]

3.1

[33.0]

[0.29]

. 10.22]

2070

7.5[3.7]

13.5

12200

24.8

[725]

213

[6.8]

[528]

[162]

[11.2]

62.1

[0.12]

Flag

L

J

UL

B

J


To calculate sample quantitation limits: (CRDL * Dilution Factor) / (%Solids/ 100)


Revised 09/99


Case #: 30647

Site:

Lab.:

SDG : MC0143

VALMONT TCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

VSolids:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40122

401

11000

2105

200.6

1000

30.1

8

1000

1 '

2.1000

2104

0.5

MC0159

SB-A400-0206

Soil

mg/Kg

06/28/2002

10:45

90.8

1.0Result

6760

3.5I21.7J

[0.18]

[651]

7.7[2.3]

10.8

10400

9.7[908]

63.3

[5.4]

[563]

[66.1]

11.3

16.2[0.044]

Flap

UL

B

J

UL

B

JB

MC0160

SB-A400-0608

Soil

mg/Kg

06/28/2002

10:50

94.3

1.0Result

3850

[0.47]

2.5

[14.6]

[0.24]

[199]

4.4[5.3]

5.26740

13.2

[207]

75.8

[1.8]

[604]

[0.45]

[46.3]

[7.4]

7.0[0.043]

Flap

L

B

J

B

J

B

JB

MC0161

SS-D200-0002

Soil

mg/Kg

06/28/2002

11:10

85.6

1.0Result

9230

[0.63]

3.0[24.31

[0.13]

[719]

11.3

[1.1]

13.6

15800

10.3

[722]

77.5

[3.2]

[486]

[0.71]

[76.9]

21.8

16.1

[0.037]

Flat)

L

B

J

B

J

B

JB

MC0162

SB-D200-0206

Soil

mg/Kg

06/28/2002

11:15

89.0

1.0Result

7430

2.6

[24.01

[0.28]

[520]

10.8

[1.1]

13.3

16100

10.9

[355]

40.0

[3.2]

[5951

[0.95]

[60.2]

18.6

10.9

[0.054]

Flap

UL

B

J

B

J

B

J

B

MC0163

SB-D200-1012

Soil

mg/Kg

06/28/2002

11:20

87.3

1.0

Result

4130

(0.59]

10.77]

(13.7]

[0.31]

[188]

5.7[6.1J

8.716000

10.8

[76.11

24.5

[1.4]

(453J

[0.89]

161.2]

[10.0]

11.8

[0.046]

Flag

B

B

B

J

B

J

B

J

B


. To calculate sample quantitation limits: (CRDL * Dilution Factor) / (%SolkJs/ 100)


Revised 09/99


Case* 30647

Site:

Lab.:

SDG : MC0153

VALMONTTCE

LIBRTY'

Number of Soil Samples: 20Number of Water Samples : 0

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units :

Date Sampled :

Time Sampled :

%Solids:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINCCYANIDE

CRDL

40122

4011

10002

10

5200.6

10003

0.18

100012

10002

104

0.5

MC0.153

SB-A540-0206

Soilmg/Kg

06/28/2002

09:40

86.8

1.0 .Result

11300

3.8(24.2]

[0.18]

[253]- 12.1

[2.0]6.2

14300

8.1[982]

92.0

[5.4][479]

[67.6]

19.8

23.9

Flafl

UL

B '

BJ

BJ

UL

BUL

UL

MC0164SS-I200-0002

Soil

mg/Kg

06/28/2002

11:3590.4

1.0Result

8810

4.3[28.9]

[0.31]

2440

11.4[3.5]

9.916900

8.61150233

- [7-9][394]

[68.0]

15.923.4

[0.053]

Flafl

UL

B

JJ

JUL

BUL

B

MC0165

SB-1 200-0206

Soil

mg/Kg

06/28/2002

11:4085.4

1.0Result

10400

3.4

[27.8]

[0.29]

160016.5[1.5]

14.520800

12.0[389]

57.0

[4.4][488]

[61.1]

23.118.4

[0.048]

Flafl

UL

B

J

J

BJ

UL

BUL

B

MC0166

SS-C350-0002

Field Dup. of

MC0181

Soil

mg/Kg

06/28/2002

12:1590.0

1.0Result

5060

[1.9]

114.81

[0.13]

[192]6.2[1.2]

[3.8]8440

5.5

[361]

47.9

[2.2]

[244]

[90.3]

12.3

7.8

[0.0471

Flafl

UL

B

BJ

BJ

UL

BUL

LB

MC0167

SB-C350-0206

Field Dup. of

MC0182

Soil

mg/Kg

06/28/2002

12:2088.7

1.0Result ,

11800

3.6

[34.5]

10.26]

(410)14.4

[1.3]7.3

1560012.4[422]39.4

[3.5][388]

[54.1]

22.3

10.6[0.099]

Flag

UL

B

BJ

BJ

UL

BUL




Revised 09/99

DATA SUMMARY FORM: INORGANIC Paoe 26 of 2fl_

Case #: 30647Site:

Lab.:

SDG : MC0153VALMONT TCELIBRTY

Sample Number :Sampling Location :

Field QC:

Matrix:Units:Date Sampled :Time Sampled :%Solids :Dilution Factor :

ANALYTEALUMINUMANTIMONY

ARSENICBARIUMBERYLLIUM

CADMIUMCALCIUMCHROMIUMCOBALT

COPPERIRON

•LEADMAGNESIUMMANGANESEMERCURY

NICKELPOTASSIUMSELENIUMSILVERSODIUMTHALLIUMVANADIUM

ZINCCYANIDE

CRDL

40122

4011

10002

105

200.6

1000

30.1

81000

12

10002

104

0.5

MC0168SB-C350-0911

Soilmg/Kg

06/28/200212:3084.9

1.0Result

17600

5.8120.0][0.32],

1512)18.2

[1.2]16.8

2340012.0[345]

38.7[0.074]

13.1][370]

30.712.4

[0.085]

Flaq

UL

B

BJ

BJ

UL

UL

B

MC0169SS-D350-0002

Soilmg/Kg06/28/2002

12:5091.3

1.0Result

7730[0.42]

3.2124.7][0.24]

164010.1[7.1]7.1

133009.8

[530]

146

[3.5][403]

[85.5]

16.0

11.610.17]

Flafl

L

B

JJ

BJ

UL

BUL

B

MC0170

SB-D350-0206

Soilmg/Kg

06/28/2002

13:0087.4

1.0Result

11100[0.39]

3.6[26.1][0.25]

[778]13.7

[1.8]

8.017700

8.2[646]62.1

[4.0][364]

>

196.0]

22.613.1

[0.14]

FlagKL

B

BJ

BJ

UL

BUL

B

MC0171SB-D350-1012

Soilmg/Kg06/28/2002

13:1087.61.0

Result7150

2.4

[13.4][0.19]

[585]

9.1[0.52]

8.212600

7.5[186]

19.9

[1.71[247]

[133J

15.3

5.8[0.047]

FlacjKUL

B

BJ

BJ

UL

BUL

LB

MC0172SS-E350-0002

SoUmg/Kg

06/28/200213:4089.7

1.0

Result5340

2.6115.01[0.18]

[807]9.9[2.4][4.9]

118006.6

[383]

105

[2.7][285]

[80.8]

12.012.0

[0.080]

FlaflK

UL

B

BJ

BJ

UL

BUL

BCRDL = Contract Required Quantitation LimitTo calculate sample quantitation limits: (CRDL * Dilution Factor) / (%Solids/100)


Revised 09/99


Case ft 30647

Site:

Lab.:

SDG: MC0153

VALMONTTCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%Solids:

Dilution Factor :

ANALYTE 'ALUMINUM

ANTIMONY

ARSENIC

BARIUMBERYLLIUM

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKELPOTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40

12

2

40

1

1

1000

2

10

5

20

0.6

1000

3

0.1

8

1000

1

2

1000

2

10

4

0.5

MC0173SB-E350-0206

Soilmg/Kg

06/28/2002

13:45

86.6

1.0

Result

12900

4.0

134.3)

10.23]

[468]

16.0

[2.0]

10.0

19400

9.8[869]

53.4

[5-0]

[443]

[66.3]

26.6

18.9[0.081]

Flafl

K

UL

B '

BJ

BJ

UL

B

UL

B

MC0174

SB-E350-0709

Soil

mg/Kg

06/28/2002

13:50

85.5

1.0Result

9960

3.2[30.3]

[0.32]

3390

20.5

[2.0]

11.9

22700

11.5

[592]

85.6

[0.047]

[4.1]

[504]

[87.8]

22.8

15.5[0.046]

FlapK )UL

B

J

J

BJ

UL

BUL

B

MC0175SS-F350-0002

Soil

mg/Kg

06/28/2002

14:10

89.9

1.0Result

7590

3.2[23.2]

[0.21]

1340

9.5[3.2]

6.712700

7.9[721]

124

14-2][404]

R6.2]

15.4

13.7

[0.036]

Flafl

KUL

B

JJ

BJ

UL

BUL

B

MC0176

SB-F350-0206

Soil

mg/Kg

06/28/2002

14:15

86.0

1.0Result

9020

3.4[26.0][0.27]

[754]

13.9

[1.7]

9.517600

9.4

[515]

62.4

[3.9]

[382]

[86.4]

21.6

13.7

[0.0561

FlaflK

U.

B

B

J

B

J

UL

B

UL

B

MC0177

SB-F350-1012

Soilmg/Kg

06/28/2002

14:20

86.5

1.0

Result

6870

[0.42]

4.3

(22.6]

[0.35]

[280]

12.2

[9.5]

16.3

21000

13.1

[112]

242

[3.2]

[468]

[65.5]

[0.76]

18.0

9.8

10.052]

Flat)

K

.

B

B

J

B

B

J

UL

B

B

B


To calculate sample quantitation limits: (CRDL • Dilution Factor) / (%Solids/100)


Revised 09/99


Case ft 30647

Site:

Lab.:

SDG: MC0153

VALMONTTCE

LIBRTY

Sample Number :

Sampling Location :

Field QC:

Matrix:

Units:

Date Sampled :

Time Sampled :

%Solids:

Dilution Factor :

ANALYTE

ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

CADMIUM

CALCIUM

, CHROMIUM

COBALT

COPPER

IRON

•LEAD

MAGNESIUM

MANGANESE

MERCURY

NICKEL

POTASSIUM

SELENIUM

SILVER

SODIUM

THALLIUM

VANADIUM

ZINC

CYANIDE

CRDL

40122

4011

1000

210

520

0.61000

30.1

81000

12

1000

2104

0.5

MC0178

SS-G350-0002

Soil

mg/Kg

06/28/2002

14:45

92.7

1.0Result

9910

3.8

.[25.7][0.27]

1170

12.5

J3.3]

9.216400

12.5

[664]

88.6

[4.5]

[436]

[117]

20.2

50.1

[0.0901

Flag

K

UL

B '

J

J

eJUL

BUL

B

MC0179

SB-G350-0206

Soil

mg/Kg

06/28/2002

14:55

85.0

1.0Result

10600

3.7

[27.7]

[0.31]

[626]

14.5

[1.2]

10.7

18300

10.5

[405]

32.4

[3.4]

[541]

'

[141]

22.4

13.4

[0.0761

Flap

K

UL

B

BJ

BJ

UL

BUL

B

MC0180

SB-G3SO-0911

Soil

mg/Kg

06^28/2002

15:00

85.9

1.0Result

9290

[O.SO]

8.392.3

[0.54]

[166]

15.4

42.4

20.0

33800

93.5

[128]

1180

[0.061]

[2.3]

(365]

1.4

[50.5]

[1.8]

18.4

39.3

[0.099]

Flag

K

L

B

B

J

BJL

BB

B

MC0181

SS-DUP-05

Field Oup. of

MC0166

Soil

mg/Kg

06/28/2002

12:00

85.8

1.0Result

6650

[1.8]

[14.7]

{0.17]

[162]

11.8

[1.1]

[2.9]

14000

8.4[306]

53.4

[0.063]

12.1][217]

[84.5]

14.8

12.5

[0.10]

Flat}

K

UL

B

BJ

B

BJ

UL

BUL

B

MC0182

SB-DUP-05

Field Dup. of

MC0167

Soil

mg/Kg

06/28/2002

12:05

82.9

1.0Result

18000

5.2

[20.0]

[0.27]

{511]

16.8

[1.3]

15.0

21600

12.1

[287]

41.7

[0.079]

[3.0]

[376]

[59.2]

29.8

11.6

[0.11]

FlaflK

UL

B

B

J

BJUL

BUL




Revised 09/99

APPENDIX C

Chain of Custody (COC) Records

AEPA USEPA Contract Laboratory ProgramInorganic Traffic Report & Chain of Custody Record

Date Shipped: 6/25/02

Carrier Name: FedEx

Airbill: 828684709982

Shipped to: Liberty Analytical501 Madison AvenueGary NC 2751 3(919)379-4080

Chain of Custody RecordRelinquished By (Date / Time)

13i_ycL4; 6/15/02. \T.oe>

2

3

4

Sampler < — -^ » i< .,-Signature: LJLpsA v^— -«^^Received By \ T (Date / Time)

^WlMUwiij! frlb'0£W

\J

Case No: 3ut>4/DAS No: 1SDS"°: MOnrm LFor Lab Use Only -vj-Lab Contract No: (tf& AQOCRSh

Unit Price: ^~]°\ &1

Transfer To:

Lab Contract No:

Unit Price:

INORGANICSAMPLE No.

M(JUU02^

>tO I ' .'** - v -~fv -M60G05

MC0012

MC0014 '

MC0015 '

MC0017

MC0018

MC0020 '

MC0021 '

MATRIX/SAMPLER

Subsurface Soil(>12"XDaniel HartiganSubsurface Soil

Daniel HartiganSubsurface Soil


Daniel HartiganSurface Soil




Daniel 'HartiganSurface Soil

CONG/TYPE

L/G

L/G

L/G

L/G

L/G

L/G

L/G

L/G

ANALYSIS/ TAG No./TURNAROUND PRESERVATIVE

FM/CN (21) 3-107 (Not pre

TM/CN(21)

TM/CN(21)

TM/CN(21) H& ,

TM/CN(21) bl£\<>1

TM/CN(21)

TM/CN(21)

served) (1)

f3-120(1)

3-148(1)

3-156(1)

3-160(1)

3-168(1)

3-172(1)

iTM/CN (21) 3-187 (Not preserved),

3-1 88 (Not preserved) (2)

TM/CN (21) ^3-192(1)

STATIONLOCATION

SB-AOO-0406

SB-DOO-0602-

SB-J1 00-0205

SB-J200-0204

SS-J250-0002

SB-J250-0709

SB-DtiP-01

SB-GOO-0206

SS-J300-0002

SAMPLE COLLECTDATE/TIME

3:

S:

S:

S:

S:

S:

S:

S:

S:

6/24/02

6/24/02

6/24/02

6/24/02

6/24/02

6/24/02 .

6/24/02

6/24/02

6/24/02

9:25

0C&fJjx0§^

11:25

11:50

12:15

12:25

12:30

10:45

13:05

ORGANIC FOR LAB USE ONLYSAMPLE No. Sample Condition On Receipt

-Z^nb^ttoO*"^Pc- /v\ 0.0004 ncn* t£«uo^

C0012 , G~O~6O

C0014 , /

. y>VlC0015 "A*1^ I

CO0 17

C0018

C0020

C0021

Daniel Hartigan ORIGINALShipment for CaseComplete^N

Analysis Key:

TM/CN = CLP TAL Total

Sample(s) to be used for laboratory QC:

MC0020

Additional Sampler Signature(s): Cooler TemperatureUpon ReceiptjpC/

MConcentration: L = Low, M = Low/Medium, H = High Type/Designate:Composite = C, Grab = G

Chain of Custody Seal Number:

Custody Seal lntact?V

Metals and Cyanide '

Shipment Iced V

/

TFTNumber: 3-424838327-062502-0001 0 |\PC1P ATftl*elifflinary results. Requests for oreliminary results will increase analytical costs. H*i4- -ft H-n« % J> rt \ i- 'V fc \,*'<rCbfitract Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-922 F2V5.0.66 Page 1 of 3

V>EPA USEPA Con tract Laboratory ProgramInorganic Traffic Report & Chain of Custody Record


Carrier Name: FedEx

Airbill: 828684709982



1 r^>__^\-L-^ sfeloT- \r-e>6

2

3

4

Sampler — 1\ . \ i v -_Signature: y \H_s^~Retseived By

( xjpOWJL

I

\ (Date / Time)

tU|k iattfVityU

"

Case No: 30647

DAS No: 1

SDGNo: VACQOOSl L-

For Lab Use Only LOLab Contract No: 1 0^ VÔÔC^&;

j. _y\ p_ --) ^ *JUnit Price: ^> HiO /

Transfer To:

Lab Contract No:

Unit Price:

INORGANICSAMPLE No.

MC0022 f

MC0023 '

MC0024 '

MC0025 '

MC0027 /

MC0028 /

MC0029 '

MC0030

MC0031 '

MATRIX/SAMPLER

Subsurface Soil(>12")/Daniel HartiganSurface Soil

Daniel HartiganSurface Soil

Daniel HartiganSurface Soil(0--1211)/Daniel HartiganSurface Soil(0"-12"XDaniel HartiganSurface Soil


Daniel HartiganSurface Soil(0"-12"XDaniel HartiganSurface Soil

Daniel Hartigan

CONC/TYPE

L/G

L/G

L/G

L/G

L/G

L/G

L/G

L/G

ANALYSIS/ TAG No./TURNAROUND PRESERVATIVE

TM/CN (21)

TM/CN(21)

TM/CN(21)

TM/CN-(21)

TM/CN(21) ^ Jb

TM/CN(21) o6/«ôt

TM/CN(21)

N TM/CN(21)

TM/CN(21)

' 3-196 (1)

3-200(1)

3-204(1)

3-208(1)

3-214(1)

3-218(1)

3-222(1)

3-226(1)

3-230(1)

ORIGINAL

STATIONLOCATION

SB-J300-0203

SS-J400-0002

SB-J400-0205

SS-J450-0002

SS-I500-0002

SS-H525-0002

SB-H525-0205

SS-G500-0002

SS-DUP-01


S: 6/24/02

S: 6/24/02

S: 6/24/02

S: 6/24/02

S: 6/24/02

S: 6/24/02

S: 6/24/02

S: 6/24/02

S: 6/24/02

13:10

13:25

13:30

13:45

14:10

14:30

14:40

15:15

15:20

ORGANIC FOR LAB USE ONLYSAMPLE No. Sam pie Condition On Receipt

UUU22 /jj

C0023

C0024

C0025

C0027

C0028

C0029

C0030

C0031

ood

Shipment for CaseComplete?N

Analysis Key:



MC0020

Additional Sampler Signature(s): Cooler TemperUpon Receipt:n.

Concentration: L = Low, M = Low/Medium, H = High Type/Designate:Composite = C, Grab = G

Metals and Cyanide

ature

*S


v/ \/Custody Seal lntact?> 1 Shipment Iced Y

I

FR Number: 3-424838327-062502-0001 | A o $ > p 4 y:f> p y f\1 results. Requests for preliminary results will increase analytical costs. i^r^fiwf' ^ 8%%>^"*>. n W % 'K & ^Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-922 F2V5.0.66 Page 2 of 3

SEPA USEPA Contract Laboratory ProgramInorganic Traffic Report & Chain of Custody Record


Carrier Name: FedEx

Airbill: 828684709982



1£LAY\ -X 6/l5/oL '00

2

3

4

Sampler —rs. vvl \ •Signature' •!••* -SM ^ \

/R§Ce|ved By [) (Date / Time)

/teftM\(lulli9 tofa'Crts~ I W>

Case No: 30647

DAS No: 1SDGNo: MCjoo^MCjooesL.For Lab Use Only ' COLab Contract No: VO^ xfoOCfeS £",

Unit Price: ^~lHt5~?

Transfer To:

Lab Contract No:

Unit Price:

INORGANICSAMPLE No.

MC0032 /

MC0033 ^

MC0035 y

MATRIX/ CONC/SAMPLER TYPE

Subsurface Soil L/G(>12")/Daniel HartiganSubsurface Soil L/G

Daniel HartiganField QC/ L/G

ANALYSIS/ TAG No./ STATION SAMPLE COLLECTTURNAROUND PRESERVATIVE LOCATION DATE/TIME

TM/CN (21)

^^Lv*f^^TTM/CN (21) ^(^

TM/CN (21) 3-243

{3-234 (1) bb-G500-0206 S: b/24/02 15:25

3-238(1) SB-G500-0911 S: 6/24/02 15:30

(HNO3), 3-244 FB-01 S: 6/24/02 12:45

ORGANIC FOR LAB USE ONLYSAMPLE No. Sample Condition On Receipt

C0032 C\s* " I

00033 SO^P^C0035

SoouOQV^=>~v

Daniel Hartigan (NaOH) (2)

ORIGINAL

Shipment for CaseCOmplete?N

Analysis Key:



MC0020

Additional Sampler Signature(s): Cooler Temperature Upon Receipt- /rt^

l»(Concentration: L = Low, M = Low/Medium, H = High Type/Designate:Composite = C, Grab = G

'Chain of Custody Seal Number:

Custody Seal IntactW I Shipment Iced V

Metals and Cyanide '

FR Number: 3-424838327-062502-0(101rfeiiffiinary results. Requests for preliminary results will increase analytical5: Contract Laboratory Analytical Services Support, 2000 Edmund Halley Dr.,

costs. Erodr . Saff T*iJr H -jtr"?Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-922

TORY COPYF2V5.0.66 Page 3 of 3

c^fcPA USEPA Contract Laboratory ProgramInorganic Traffic Report & Chain of Custody Record

Region: 3 Date shipped:.Project Code: Carrier Name:Account Code: A|rb|1|.

CERCLISIO: Shipped to:Spill ID:

Site Name/State: Valmont TCE 6724/02/PAProject Leader: Neil TeamersonAction: Combined RI/FSSampling Co: Tetra Tech NUS, Inc.

e/28/02 Chain of CustodyFHF* ,ft7BRfl47101S1 Relinquished By

Liberty Analytical 1 //£/^~ &

Gary NC 2751 3 2

3

4

Case No: 30647 Q

DAS No: |X

Record *""'••' / <S&—Signature: *-TS/ ^*T

(Date /Time) Received By (Date /Time)

'2&"02. /<&§

INORGANIC MATRIX/ CONG/ ANALYSIS/ TAO No./ STATION SAMPLE COLLECT ORGANIC QCSAMPLE No. SAMPLER TYPE TURNAROUND PRESERVATIVE LOCATION DATE/TIME SAMPLE No. Type

MCOOP9 Surface Soil L/G TM/CN(21) 3-388(1) SS-B350 S: 6/26/02 10:30 C0069

Eric HlnkleMC0070 Subsurface Soil L/G TM/CN(21) 3-392(1) SB-B350-0206 S: 6/26/02 10:35 C0070

Eric HinkleMC0071 Subsurface Soil L/G TM/CN(21) 3-396 (Not preserved) (1) SB-B350-0607 S: 6/26/02 10:40 C0071

Eric HlnkleMC0072 Surface Soil L/G TM/CN(21) 3-400(1) SS-B325 S: 6/26/02 10:50 C0072

Eric HinkleMC0073 Subsurface Soil L/G TM/CN(21) 3^»03 (Not preserved), SB-B325-0206 S: 6/26/02 10:55 C0073

(>1 2")/ 3-523 (Not preserved) (2)Eric Hinkie

MC0074 Surface Soil L/G TM/CN(21) 3-408(1) SS-B100 S: 6/26/02 11:15 C0074

Eric HinkleMC0075 Subsurface Soil L/G TM/CN(21) 3-412(1) SB-B1 00-0206 S: 6/26/02 11:20 C0075

Eric HinkleMC0076 Subsurface Soil L/G TM/CN(21) 3-416(1) SB-DUP-03 S: 6/26/02 11:23 C0076 Field Duplicate of C0075

Eric HinkleMC0077 Subsurface Soil L/G TM/CN(21) 3-420(1) SB-B100-0608 S: 6/26/02 11:25 C0077

Eric HinkleMC0078 Surface Soil L/G TM/CN(21) 3-423 (Not preserved), SS-D300-0002 S: 6/26/02 11:50 C0078 , - ,

(0"-12")/ 3-51 5 (Not preserved) (2) ,'' .Eric Hinkle

Shipment for Case Sample(s) to be used for laboratory QC:Complete? N

MC0073,MC0078,MC0131

Analysis Key: Concentration: L « Low, M = Low/Medium, H =• High

Additional Sampler Signature(s):

Type/Designate: Composite » C, Grab = G

TM/CN = CLP TAL Total Metals and Cyanide


f —

Shipment lead?

TR Number 3-424838327-062802-0001PR provides preliminary results. Requests for preliminary results will increase analytical costs. -„,„.„-„ .. ..S^ Copy to: Contr»ct Laboratory Analytical Services Support, 2000 Edmund Haltey Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-9222 F2V5.0.66 Page 1 Of 8

t n'> '!••• L^^v /? «.

?5ii **V SUM i^^jW ****&

Region:

Project Code:

Account Code:

CERCLIS ID:

Spill ID:

Site Nama/State

Project Leader:

Action:

Sampling Co:

INORGANICSAMPLE No.

. MC0079

MC0080

MC0081

MC0082

MC0083

MC0084

MC0085

MC0086

MC0087

MC0088

USEPA Contract Laboratory Program case NO:Inorganic Traffic Report & Chain of Custody Record DAS NO.-

3

i

: Valmorrt TCE 6724/02/PA

Neil TeamersonCombined RI/FS

Tetra Tech NUS, Inc.

MATRIX/ CONG/ ANALYSIS/SAMPLER TYPE TURNAROUND

Subsurface Soil L/G TM/CN (21)(>iryEric HinkleSubsurface Soil L/G TM/CN (21)

Eric HinkleSurface Soil L/G TM/CN (21)

Eric HinkleSubsurface Soil L/G TM/CN (21)


Eric HlnkieSurface Soil L/G TM/CN (21)


Eric HinkleSubsurface Soil L/G TM/CN (21) ,

Eric HinkleSurface Soil L/G TM/CN (21)(0"-12")/Eric HinkleSubsurface Soil L/G TM/CN (21)

Data shipped: 6/28/02 Chain of Custody Record

Abwn. ft9ftRM7imsi Relinquished By (OatefTlm*

Shipped to: Liberty Analytical 1 ^^^^- £~20&2*/l501 Madison Avenue , . _ . . , — , fGary NC 2751 3 2

3

4

30647 O

Sampler ^^"^sfsZ/Signature: ^^//^£ —

) Received By (Date / Time)

TAG No./ STATION SAMPLE COLLECT ORGANIC QCPRESERVATIVE LOCATION DATE/TIME SAMPLE No. Type

3-428(1) SB-D300-0206 S: 6/26/02 11:55 C0079 - "

3-432(1) SB-D300-1012 S: 6/26/02 12:00 C0080

3-436(1) SS-E300-0002 S: 6/26/02 ' 12:20 C0081

3-440(1) SB-E300-0206 S: 6/26/02 12:25 C0082

3-444(1) SB-E300-1012 S: 6/26/02 12:30 C0083

3-448(1) SS-D225-0002 S: 6/26/02 13:10 C0084

3-452(1) SB-D225-0206 S: 6/26/02 13:15 C0085

3-456(1) SB-D225-1012 S: 6/26/02 13:20 C0086

3-460(1) SS-F400-0002 S: 6/26/02 l5'V.<? C0087 , )

y\ , 'T-3-464(1) SB-F400-0206 S: 6/26/02 13:45 C0088 ./ '

Eric Hinkle

Shipment tor CaseComplete? N

Analysis Key:

TM/CN = CLP TAL Tol


MC0073. MC0078, MC0131


Concentration: L =» Low, M = Low/Medium. H = High Type/Designate: Composite = C, Grab = G

Chain of Custody Seal Number

Shipment Iced? ,

tal Metals and Cyanide

TR Number: 3-424838327-062802-0001PR provides preliminary results. Requests for preliminary results will increase analytical costs.Send Copy to: Contract Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-9222 F2V5.0.66 Page 2 of 8

4'itPA USEPA Contract Laboratory ProgramInorganic Traffic Report & Chain of Custody Record

Region: 3Project Code:

Account Code:

CERCLIS ID:

Spill ID:

Site Name/State: Valmont TCE 6724/02/PA

Project Leader: Neil TeamersonAction: Combined RI/FS

Sampling Co: Tetra Tech NUS, Inc.

INORGANIC MATRIX/ CONG/ ANALYSIS/SAMPLE No. SAMPLER TYPE TURNAROUND

MC0089 Subsurface Soil L/G TM/CN (21)

Eric HlnkleMC0090 Surface Soil L/G TM/CN (21)

Eric HlnkleMC0091 Subsurface Soil L/G TM/CN (21)


Eric HinkleMC0093 Surface Soil L/G TM/CN (21)


Eric HlnkfeMC0095 Subsurface Soil L/G TM/CN (21)


Eric HinkleMC0097 Subsurface Soil L/G TM/CN (21)



Carrier Name: FedEx

Airbill: 828684710151

Shipped to: Liberty Analytical501 Madison AvenueGary NC 2751 3-(919)379-4080

TAO No./ STATIONPRESERVATIVE LOCATION

Case No: 30647 ^

DAS No: |*X

Chain of Custody Record

Relinquished By

Sampler ^^">^^<>r>Sl8nahire: ^_X^^

(Date /Time) Received By (Date /Time)

^t£>f2£-- 6-&'*2- /<£t>2

3

4


3-468(1) SB-F400-0608 S: 6/26/02

3-472(1) SS-E400-0002 S: 6/26/02

3-476(1) SB-E400-0206 S: 6/26/02

3-480(1) SB-E400-1011 S: 6/26/02

3-484(1) SS-D400-0002 S: 6/26/02

3-488(1) SB-D400-0206 S: 6/26/02

3-492(1) SB-D400-0810 S: 6/26/02

3-496(1) SS-C400-0002 S: 6/26/02

3-500(1) SB-C400-0206 S: 6/26/02

3-504(1) SB-C400-0607 S: 6/26/02

13:50

14:20

14:25

14:30

14:45

14:50

14:55

15:15

15:20

15:25

ORGANIC QCSAMPLE No. Type

C0089

C0090

C0091

C0092

C0093

C0094

C0095

C0096

C0097

C0098

Eric Hinkle


Analysis Key:

TM/CN = CLP TALTol

Samples) to be used for laboratory QC:

MC0073.MC0078.MC0131

Additional Sampler Slgnature(s):

Concentration: L = Low, M = Low/Medium, H = High Type/Deslgnslte: composite = C, Grab = G


Shipment Iced?

al Metals and Cyanide

TR Number: 3-424838327-062802-0001PR provides preliminary results. Requests for preliminary results will increase analytical costs.Send Copy to: Contract Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-9222 F2V5.0.66 Page 3 of 8

4>t".PA USEPA Contract Laboratory ProgramInorganic Traffic Report & Chain of Custody Record

Region: 3

Project Code:

Account Code:

CERCLIS ID:Spill ID:





MC0099 Surface Soil L/G TM/CN (21)











Carrier Name: FedEx

Airbill: 828684710151


TAG No./ STATIONPRESERVATIVE LOCATION

Case No: 30647DAS No: R

Chain of Custody Record ffmpler s^s/sZ/Signature: ^^ ^y ^£ ~ '

Relinquished By (Date / Time) Received By (Date / Time)

1 <£^&£- 6-28-cz /A»o2

3

4

SAMPLE COLLECT ORGANICDATE/TIME SAMPLE No.

QCType

3-508(1) SS-B450-0002 S: 6/26/02 15:35 C0099

3-512(1) SB-B450-0204 S: 6/26/02 15:40 C0100

3-519 (Not preserved) (1 ) SS-DUP-03 S: 6/26/02 15:15 C0101 Field Duplicate of C01 00

3-528 (Not preserved) (1) SS-D450-0002 S: 6/27/02 7:45 C0102

3-532 (Not preserved) (1) SB-D450-0206 S: 6/27/02 7:50 C0103

3-536 (Not preserved) (1 ) SS-D450-091 1 S: 6/27/02 7:55 C0104

3-540 (Not preserved) (1) SS-E450-0002 S: 6/27/02 8:15 C0105

3-544 (Not preserved) (1) SB-E450-0206 S: 6/27/02 8:20 C0106


3-552 (Not preserved) (1 ) SS-1350-0002 S: 6/27/02 8:40 C0108

Eric Hinkle


Analysis Key:

TM/CN « CLP TAL Tol

Samp)e(s) to be used for laboratory QC:

MC0073, MC0078, MC0131


Concentration: L = Low, M = Low/Medium, H = High Type/Designate: Composite = C, Grab « G


Shipment Iced?

:al Metals and Cyanide

TR Number. 3-424838327-062802-0001PR provides preliminary results. Requests for preliminary results will Increase analytical costs.Sand Copy to: Contract Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-9222 F2V6.0.66 Page 4 of 8

-a-EPARegion:

Project Code:

Account Code:


Site Name/StateProject Leader:

Action:

Sampling Co:

INORGANICSAMPLE No.

MC0109

MC0110

MC0111

MC0112

MC0113

MC0114

MC0115

MC0116

MC0117

MC0118

USEPA Contract Laboratory ProgramInorganic Traffic Report & Chain of Custody

3

: Valmont TCE 6724/02/PA



MATRIX/ CONC/SAMPLER TYPE

Subsurface Soil L/G

Eric HinkleSubsurface Soil L/G

Eric HinkleSurface Soil L/G(0--12")/Eric HinkleSubsurface Soil L/G


Eric HinkleSurface Soil L/G





ANALYSIS/TURNAROUND

TM/CN (21)

TM/CN (21)

TM/CN (21)

TM/CN (21)

TM/CN (21)

TM/CN (21)

TM/CN (21)

TM/CN (21)

TM/CN (21)

TM/CN (21)

RecordDate Shipped: 6/28/02

Carrier Name: FedEx

Airbill: 828684710151


TAO No./PRESERVATIVE

3-556 (Not preserved) (1)









-3-592 (Not preserved) (1)

STATIONLOCATION

SB-1350-0206

SB-DUP-04

Case No

DAS No:


Relinquished By

: 30647

SamplerSignature: ^

(Date / Time) Received By

R^^^-

(Date /Time)

^ ^/P^fc- &*2& *92- /<£%. >

2

3

4 '

SAMPLE COLLECT ORGANICDATE/TIME SAMPLE No.

S: 6/27/02

S: 6/27/02

SS-F450-0002 S: 6/27/02

SB-F450-0206 S: 6/27/02

SB-F450-1012 S: 6/27/02

SS-G450-0002 S: 6/27/02

SB-G450-0206 S: 6/27/02

SB-G450-1012 S: 6/27/02

SS-H450-0002 S: 6/27/02

SS-G400-0002 S: 6/27/02

8:45

8:45

9:10

9:15

9:20

9:40

9:45

9:50

10:15

10:40

C0109

QCType

'

C01 1 0 Field Duplicate of C01 09

com

C0112

com

C0114

C0115

C0116

com

C0118

—

-

-

-

-

-

-

-

Eric Hinkle


Analysis Key:

TM/CN - CLP TAL Tol


MC0073.MC0078.MC0131


Concentration: L = Low, M = Low/Medium, H = High TypeCeslgnate: Composite = C, Grab = G


Shipment Iced?

•al Metals and Cyanide

TR Number. 3-424838327-062802-0001PR provides preliminary results. Requests for preliminary results will increase analytical costs.Send Copy to: Contract Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-9222 F2V5.0.66 Page 5 of 8

JtHpA USEPA Contract Laboratory Program case NO:"**' JT-* • 9«»»^ 1 &. k ^^

Inorganic Traffic Report & Chain of Custody Record DAS NO:Region: 3

Project Code:

Account Code:

CERCLIS ID:




INORGANICSAMPLE No.

MC0119

MC0120

MC0121

MC0122

MC0123

MC0124

MC0125

MC0126

MC0127

MC0128


Subsurface Soil L/G TM/CN (21)(>iryEric HinkleSubsurface Soil L/G TM/CN (21)









Date shipped: 6/28/02 Chain ofCustody RecordCurrier Name: FftdEx .. _AlrMii. ft9flfiftA7iniRi Relinquished By (Date /Tim

Shipped to: Liberty Analytical 1 / ^^~ £*Z& -02. fa

Gary NC 2751 3 2

3

4

30647 ^

iSr. x^e) Received By (Date / Time)

*ce>

TAG No./ STATION SAMPLE COLLECT ORGANIC QCPRESERVATIVE LOCATION DATE/TIME SAMPLE No. Type

3-596 (Not preserved) (1) SB-G400-0206 S: 6/27/02 10:45 C0119

3-600 (Not preserved) (1) SB-G400-1012 S: 6/27/02 10:50 C0120 * -


3-608 (Not preserved) (1) SB-E500-0206 S: 6/27/02 11:10 C0122 -

3-61 2 (Not preserved) (1) SB-E500-0911 S: 6/27/02 11:15 C0123


3-620 (Not preserved) (1) SB-E1 00-0206 S: 6/27/02 12:35 C0125


3-628 (Not preserved) (1) SS-H100-0002 S: 6/27/02 13:15 C0127

3-632 (Not preserved) (1) SS-DUP-04 S: 6/27/02 13:15 C0128 V Field Duplicate of C01 27

Eric Hinkle •- - r

Shipment for CaseComplete? N

Analysis Key:

TM/CN = CLP TAL Tol


MC0073, MC0078, MC0131


Concentration: L = Low, M = Low/Medium, H = High Type/Designate: composite = C, Grab * G


Shipment Iced?


TR Number. 3-424838327-062802-0001PR provides preliminary results. Requests forprellminary results wilMncrease analytical costs. „„,....«.. ,,«,..,».,.,,Send Copy to: Contract Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-9222 F2V6.0.66 Page 6 of 8

ivfcPA USEPA Contract Laboratory ProgramInorganic Traffic Report & Chain of Custody Record

Region:

Project Code:

Account Code:CERCLIS ID:Spill ID:

Site Name/StateProject Leader-

Action:Sampling Co:

INORGANICSAMPLE No.

MC0129

MC0130

MC0131

MC0132

MC0133

MC0134

MC0135

MC0136

MC0137

MC0138

3


Nell TeamereonCombined RI/FS


MATRIX/ CONG/ ANALYSB/SAMPLER TYPE TURNAROUND

Subsurface Soil L/G TM/CN (21)






Eric HinkleSubsurface Soil L/G • TM/CN (21)



Eric HinkleSurface. Soil L/G TM/CN (21)


Carrier Name: FedExAirbill: 828684710151

Shipped to: Liberty Analytical501 Madison AvenueCaryNC27513(919)379-4080

TAO No./ STATIONPRESERVATIVE LOCATION

Case No:DAS No:


Relinquished By (Date / Tim*

1 <£/?'%r 6~2#'#2 /2

3

4

30647 V"\

Sampler .> i /Signature: j^/s^llC ~~

i) Received By (Date / Time)

v*>

SAMPLE COLLECT ORGANIC QCDATE/TIME SAMPLE No. Type

3-636 (Not preserved) (1) SB-H100-0206 8:6/27/02 13:20 C0129 /

3-640 (Not preserved) (1) SS-F1 50-0002 S: 6/27/02 13:45 C0130

3-647 (Not preserved), SB-F1 50-0206 S: 6/27/02 13:50 C01313-648 (Not preserved) (2)

3-652 (Not preserved) (1) SB-F150-0810 S: 6/27/02 13:55 C0132

3-656 (Not preserved) (1) SS-G200-0002 S: 6/27/02 14:20 C0133

3-660 (Not preserved) (1) SB-G200-0206 S: 6/27/02 14:25 C0134

3-664 (Not preserved) (1) SB-G200-0608 5:6/27/02 14:30 C0135

3-668 (Not preserved) (1) SS-H300-0002 S: 6/27/02 14:50 C0136

3-672 (Not preserved) (1) SB-H300-0206 S: 6/27/02 14:55 C0137

3-676 (Not preserved) (1 ) SS-1 7 S: 6/27/02 8:15 C0138

Eric Hinkle

Shipment for Cat*Complete? N

Analysis Key:

TM/CN - CLP TAL To


MC0073, MC0078, MC0131


Concentration: L = Low, M = Low/Medium, H = High TypeCeslgnate: Composite » C, Grab = G

Chain of Custody Seal Number;

Shipment Iced?


TR Number: 3-424838327-062802-0001PR provides preliminary results. Requests for preliminary results will increase analytical costs. -.„«-,..«,Send Copy to: Contract Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-9222 F2V6.0.66 Page 7 of 8

*>fcPA USEPA Contract Laboratory Program case NO: sow? QInorganic Traffic Report & Chain of Custody Record DAS NO: IX

Region: 3Project Code:Account Code:

CERCLISID:Spill ID:

SHe Name/State: Valmont TCE 6724/02/PAProject Leader: Neil TeamereonAction: Combined RI/FS



Carrier Name: FedEx

Airbill: 828684710151



Relinquished By (Date / Time)

1 /?'&~ £'26 -42 /<&2

3

4

Sampler ^" f J/Signature: I//, ^— —

Received By (Date / Time)

* |

INORGANIC MATRIX/ CONC/ ANALYSIS/ TAG No./ STATION SAMPLE COLLECT ORGANIC QCSAMPLE No. SAMPLER TYPE TURNAROUND PRESERVATIVE LOCATION DATE/TIME SAMPLE No. Type

MC01 39 Subsurface Soil L/G

Eric HfnkleMC0141 Field QC/ L/G

Eric Hinkle

MC0142 Field QC/ L/GEric Hinkle

TM/CN(21) 3-680 (Not preserved) (1) SB-17-0206 S: 6/27/02 9:35 C0139

TM/CN(21) 3-687 (HN03), 3-688 RB-01 S: 6/28/02 12:00 C0141 Rlnsate(NaOH) (2)

TM/CN(21) 3-693 (HNO3), 3-694 FB-02 S: 6/28/02 13:00 C0142(NaOH) (2)


Analysis Key:

TM/CN - CLP TAL To)


MC0073, MC0078, MC0131


Concentration: L * Low, M * Low/Medium, H =• High TypeCeslgnate: Composite = C, Grab =* G

Chain of Custody Seal Number

Shipment Iced?


TR Number 3-424838327-062802-0001PR provides preliminary results. Requests for preliminary results will increase analytical costs.Send Copy to: Contract Laboratory Anarytteal Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/284-9222 F2VS.0.66 Page 8 of 8

^VCrA USEPA Contract Laboratory ProgramInorganic Traffic Report & Chain of Custody Record

Region:

Project Code:

Account Code:


Site Name/State

Project Leader:

Action:Sampling Co:

INORGANICSAMPLE No.

MC0143

MC0144

MC0145

MC0146

MC0147

MC0148

MC0149

MC0150

MC0151

MC0152

3


Nell TeamersonCombined RI/FS



Surface Soil L/G TM/CN(21)(0"-12"VNeb DedicSubsurface Soil L/G TM/CN(21)

Neb DedicSubsurface Soil L/G TM/CN(21)

Neb DedicSurface Soli L/G TM/CN(21)



Neb DedicSurface Soil L/G TM/CN(21)


Neb DedicSubsurface Soil UG TM/CN(21)




Shipped to: Liberty Analytical501 Madison AvenueGary NC 2751 3(919) 379-4080

TAG HoJ STATIONPRESERVATIVE LOCATION

Case No:

DAS No:


Relinquished By (Date / Time

1 /fa faJ^T 7-l~<>*-/t

2

3

4

30647 Q

££« /#/ feA^

) Received By (Date /Time)

•

SAMPLE COLLECT ORGANIC QCDATE/TIME SAMPLE No. Type

3-699 (Not preserved) (1) SS-F535 S: 6/28/02 8:15 C0143

3-703(1) SB-F535-0206 S: 6/28/02 8:20 C0144

3-707 (Not preserved) (1) SB-F535-0810 S: 6/28/02 8:25 C0145

3-711 (1) SS-D535 S: 6/28/02 8:40 C0146

3-715(1) SB-D535-0206 S: 6/28/02 8:45 C0147

3-71 9 (Not preserved) (1) SB-D535-0810 S: 6/28/02 8:50 C0148

3-723(1) SS-B540 S: 6/28/02 9:10 C0149

3-727 (Not preserved) (1) SB-B540-0206 S: 6/28/02 9:15 C0150

3-731 (Not preserved) (1) SB-B540-0608 S: 6/28/02 9:20 C0151

3-738 (Not preserved), SS-A540 S: 6/28/02 9:30 C0152

Neb Dedic3-739 (Not preserved) (2)

Shipment for CaseComplete? Y

Analysis Key:

TM/CN = CLPTALTot


MC0152. MC0153

Additional Sampler Signatures):

Concentration: L = Low, M = Low/Medium, H = High Type/Designate: Q^


poslte = C, Grab = G


Shipment lead?

TR Number: 3-424838327-070102-0002PR provides preliminary results. Requests for preliminary results will Increase analytical costs.Send Copy to: Contract Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-9222 F2V5.0.66 Page 1 of,'

</EPA USEPA Contract Laboratory ProgramInorganic Traffic Report & Chain of Custody Record

Region: 3

Project Code:

Account Code:





MC0153 Subsurface Soil L/G TM/CN (21)

Neb DedicMC0154 Subsurface Soil L/G TM/CN (21)

Neb DedicMC0155 Surface Soil L/G TM/CN (21)



Neb DedicMC0158 Surface Soil L/G TM/CN (21)



Neb DedicMC0161 Surface Soil . L/G TM/CN (21)

Neb DedicMC0162 Subsurface Soil UG TM/CN (21)



Shipped to: Liberty Analytical501 Madison AvenueGary NC 27513(919) 379-4080

TAG NoJ STATIONPRESERVATIVE LOCATION

Case No:

DAS No:


Relinquished By (Date / Tlrm

1

2

3

4

SAMPLE COL LJECT

30647 ^

Signature:

») Received By (Date / Time)

ORGANIC QCDATE/TIME SAMPLE No. Type

3-746 (Not preserved), SB-A540-0206 S: 6/28/02 9:40 C0153 ^ ^ f ' •-«3-747 (Not preserved) (2) . ''"/' '•

3-751 (Not preserved) (1) SB-A540-0607 S: 6/28/02 9:45 C0154

3-755 (Not preserved) (1) SS-A200 S: 6/28/02 10:05 C0155

3-759(1) SB-A200-0206 S: 6/28/02 10:10 C0156


3-767 (Not preserved) (1 ) SS-A400 S: 6/28/02 10:40 C0158



3-779(1) SS-D200-0002 S: 6/28/02 11:10 C0161

'"

3-783 (Not preserved) (1) SB-D200-0206 S: 6/28/02 11:15 C0162

Neb Dedic


Analysis Key:

TM/CN = CLP TAL Td


MC0152, MC0153


Concentration: L = Low, M = Low/Medium, H = High Type/Designate: Composite = C, Grab = G


Shipment Iced? .__


TR Number: 3^124838327-070102-0002PR provides preliminary results. Requests for preliminary results will Increase analytical costs. * *•rao<

Send Copy to: Contract Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3430 Phone 703/264-9340 Fax 703/264-9222 page 2 or;

^yEPA USEPA Contract Laboratory ProgramInorganic Traffic Report & Chain of Custody

Region:

Project Code:

Account Code:

Spill ID:

Site Name/State

Project Leader:

Action:

Sampling Co:

INORGANICSAMPLE No.

MC0163

MC0164

MC0165

MC0166

MC0167

MC0168

MC0169

MC0170

MC0171

MC0172

' 3


Nell TeamersonCombined RI/FS

Tetra Tech NUS. Inc.


Subsurface Soil L/G TM/CN(21)









Neb DedicSurface .Soil L/G . TM/CN(21)


Carrier Name: FedEx

Airbill: 828684645727

Shipped to: Liberty Analytical501 Madison AVEGary NC 27513(919) 379-4080

TAONoJPRESERVATIVE











Case No: 30647 ^

Record DASNO: |>

Chain of Custody Record l""1^

Relinquished By (Date /Time) Received By (Date /Time)

1

2

3

4

STATION SAMPLE COLLECT ORGANIC QCLOCATION DATE/TIME SAMPLE No. Type

SB-D200-1012 S: 6/28/02 11:20 C0163

SS-I200-0002 S: 6/28/02 11:35 C0164

SB-I200-0206 S: 6/28/02 11:40 C0165

SS-C350-0002 S: 6/28/02 12:15 C0166 -

SB-C350-0206 S: 6/28/02 12:20 C0167 - -

SB-C350-0911 S: 6/28/02 12:30 C0168

SS-D350-0002 S: 6/28/02 12:50 C0169

SB-D350-0206 S: 6/28/02 13:00 C0170

SB-D350-1012 S: 6728/02 13:10 C0171

SS-E350-0002 S: 6/28/02 13:40 C0172

Neb Dedic


Analysis Key:

TM/CN = CLPTALTol


MC0152, MC0153


Concentration: L = Low, M = Low/Medium, M = High Type/Deslgnata composite = C, Grab = G


Shipment Iced? ..


TR Number: 3-424838327-070102-0002PR provides preliminary result*. Requests for preliminary results will Increase analytical costs.Send Copy to: Contract Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 PflOfie 703/264-9348 Fax 703/264-9222 F2V5.0.6gPafle3of!

V>EPA USEPA Contract Laboratory Program case NO:Inorganic Traffic Report & Chain of Custody Record DAS NO:

Region:

Project Code:

Account Code:

Spill ID:Site Name/State

Project Leader:

Action:Sampling Co:

INORGANICSAMPLE No.

MC0173

MC0174

MC0175

MC0176

MC0177

MC0178

MC0179

MC0180

MC0181

MC0182

3

I




MATRIX/ CONC/ ANALYSIS/SAMPLER TYPE TURNAROUND

Subsurface Soil UG TM/CN(21)


Neb DedicSurface Soil UG TM/CN(21)



Neb DedicSurface Soil UG TM/CN(21)



Neb DedicSurface Soil UG . TM/CN(21)




Shipped to: Liberty Analytical501 Madison AverGary NC 27513(919)379-4080

TAG No/PRESERVATIVE






3^47 (Not preserved) (1)






Relinquished By (Date / Tim

1

2

3

4

30647 ^

SamplerSignature:

a) Received By (Date /Time)

STATION SAMPLE COLLECT ORGANIC QCLOCATION DATEmME SAMPLE No. Type

SB-E350-0206 S: 6/28/02 13:45 C0173

SB-E350-0709 S: 6/28/02 . 13:50 C0174

SS-F350-0002 S: 6/28/02 14:10 C0175

SB-F350-0206 S: 6/28/02 14:15 C0176

SB-F350-1012 S: 6/28/02 14:20 C0177

SS-G350-0002 S: 6/28/02 14:45 C0178 -" -

-r

SB-G350-0206 S: 6/28/02 14:55 C0179

SB-G350-0911 S: 6/28/02 15:00 C0180

SS-DUP-05 S: 6/28/02 12:00 C0181 Field DuplicateOf. Aico/^6 \

SB-DUP-05 S: 6/28/02 12:05 C0182 Field Duplicatejf^ ^ f^ j^ «« V j* "* *

Neb Dedic


Analysis Key: .

TM/CN = CLPTALTol

Samplers) to be used for laboratory QC:

MC0152, MC0153

Concentration: L = Lc


Additional Sampler Signature ):

w, M = Low/Medium, H = High Type/Designate: ^mposlte = C, Grab = G


Shipment Iced? ., .

TR Number: 3-424838327-070102-0002 m^PR provides preliminary results. Requests for preliminary results will Increase analytical costs. a «.«»»send Copy to- Contract Laboratory Analytical Services Support, 2000 Edmund Haffey Dr., Reston, VA. 20191-3436 Phone 7031264-9348 Fax 7031264-9222

oEPARegion:

Project Code:

Account Code:

CERCLIS ID:

Spill ID:

Site Name/State:

Project Leader:Action:

Sampling Co:

INORGANICSAMPLE No.

MC0184

MC0185

USEPA Contract Laboratory ProgramInorganic Traffic Report & Chain of Custody Record

3

ValmontTCE6?24/02/PA




Carrier Name: FedEx

Airbill: 828684645727

Shipped to: Liberty Analytical501 Madison AvenueGary NC 2751 3(919) 379-4080

Case No: 30647 [

DAS No: |>


Relinquished By (Date /Time)

1

2

3

4

SamplerSignature:

Received By (Date / Time)

MATRIX/ CONG/ ANALYSIS/ TAG No./ STATION SAMPLE COLLECT ORGANIC QCSAMPLER TYPE TURNAROUND PRESERVATIVE LOCATION DATE/TIME SAMPLE No. Type

Field QC/ L/G TM/CN (21) 3-871 (HNO3), 3-872 RB-02 / S: 6/28/02Neb Dedlc (NaOH) (2)

Field QC/ L/G TM/CN (21) 3-877 (HNO3), 3-878 FB-03 S: 6/28/02Neb Dedic (NaOH) (2)

16:00 C0184 Rinsate

12:15 C0185 P|r


Analysis Key:

TM/CN = CLP TALTol

Sample(8) to be used for laboratory QC:

MC0152, MC0153

Additional Sampler Slgnaturefs):

Concentration: L - Low, M = Low/Medium, H = High Type/Designate: Composite = C, Grab = G


Shipment Iced? .,.,

a! Metals and Cyanide

TR Number: 3-424838327-070102-0002 DEPR provides preliminary results. Requests for preliminary results will Increase analytical costs. Rt Sto

Send Copy to: Contract Laboratory Analytical Services Support, 2000 Edmund Halley Dr., Reston, VA. 20191-3436 Phone 703/264-9348 Fax 703/264-9222 F2V5.0.66 Page5of.'

JudySnyder , To: [email protected]:

07/22/02 01:59 PM Subject: inorganic portion of 30647, Valmont TCE: need Regional copies ofsome COC's and memo to file

Dear Neil: We need the Regional copies of the COC/TR's 3-424838327-062502-001 pages onethrough three. We need the field QC information and duplicate pairs.

Memo to file needed for the following errors/discrepancies:1. Sampler did not sign/relinquish COC pages 2 and 3 of 3-424838327-070102-002. You need to state inthe memo who relinquished the samples and the date and time of relinquishment.2. Sample MC0005 was listed on COC page one of 3-424838327-062502-01 but was not shipped, per labdocumentation. -The lab did receive sample MC0004, tag 3-115 sampled 6-24-02 @ 9:55 from stationlocation SB-DOO-0206 which is not listed on the COC. Sampler will please delete MC0005 and addMC0004 by memo to file.3. Tag 3-878 was crossed off on the lab copy of the COC for sample MC0185 but the cyanide analysiswhich would have been done on this aliquot was not crossed off. Also the cross through was no dated.The lab analyzed the total metals aliquot only. Sampler will please indicate who cancelled the cyanidealiquot and on what date and confirm that the cyanide analysis and tag 3-878 were indeed cancelled, ifthat was the intent.4. Tags listed on the COC for sample MC0078 are 3-423 and 3-515. Tag number 3-423 is incorrect. Theactual tag number is 3-424.5. Tags listed on COC for MC0073 are 3-402 and 3-523. Tag #3-4-3 is incorrect on the COC. The actualtag number for MC0073 is 3-404.6. Neither the tag nor the COC list a sample collection time for MC0087.

For the very large number of samples collected on the inorganic portion of this case alone, thedocumentation errors were minimal. Good job.

Judy SnyderESAT Auditor, Region 3Lockheed Martin Environmental Services701 Mapes RoadFt. Meade, MD 20755-5350Phone 410-305-3015Fax 410-305-3095

TETRA TECH NUS, INC.600 Clark Avenue, Suite 3 • King of Prussia, PA 19406-1433(610) 491-9688 • FAX (610) 491-9645 • www.tetratech.com

PHIL-16425

July 29', 2002

Project Number 4192

Ms. Judy SnyderESAT Auditor, Region 3Lockheed MartinEPA Environmental Science Center701 Mapes RoadFort Meade, Maryland 20755-5350

Subject: Memo to FileCase Number 30647Valmont TCE,J-iazleton, Pennsylvania

Dear Ms. Snyder:

This is a memo to correct documentation errors for the Valmont TCE sampling event.

• Sampler Neb Dedic should have signed and relinquished pages 2 through 5 forCOC 3-424838327-070102-002 on 07/01/02 at 20:00.

• The inorganic soil sample MC0005 listed on Traffic Report (TR) # 3-424838327-062502-01 for TM/CNanalysis is incorrectly listed. A correction should be made to list sample MC0004 collected on 6/24/02 at09:55 instead of sample MC0005 collected on 6/24/02 at 10:00.

• Sampler Neb Dedic crossed off the tag # 3-878 for sample MC0185, the cyanide analysis should also havebeen crossed off and the changes should have been initialed and dated by the sampler.

• Tags listed on the COC for sample MC0078 are 3-423 and 3-515. Tag number 3-423 is incorrect. The actualtag number is 3-424.

• Tags listed on the COC for sample MC0073 are 3-403 and 3-523. Tag # 3-403 is incorrect on the COC. Theactual tag number for MC0073 is 3-404.

/• The collection time for sample MC0087 was 13:40 on 6/26/02, this information was mistakenly omitted from

the COC and the lag.

We apologize for the inconvenience. Please do not hesitate to call if you have any questions.

Respectfully,

Daniel Hartigan

DH/vh

Romuald Roman (EPA Region 3)Neil Teamerson (TtNUS)File No. 3.2

Melissa Stevens

.Melissa Stevens <[email protected]>Holly Rogers <[email protected]>Tuesday, July 16, 2002 4:02 PM30647-071602.pdf30647

From:To:Sent:Attach:Subject:Hi Holly,

I forgot to send you an e-mail about this. Sample MC0185 is listed as TM/CN, -but we only received TM. If youtake a look at the traffic report the sampler marked the CN tag number out, but did not nnark the CN off from theanalysis colume. Please see attachment.

Melissa StevensEPA Coordinator(919)379-4081CompuChem a division of Liberty [email protected]

•"> ! PX<~ *-»*

07/16/02

TETRA TECH NUS, INC.600 Clark Avenue, Suke 3 • King of Prussia, PA 19406-1433 /• /(610) 491-9688- FAX (610) 491-9645. www.tetratech.com '' / Jin

• />/*nPHIL-16367 ; ///V^7'-

\ / A 5 " r% '\ T-'I <r~* i f°*t «..*,'. . • ' " * • • •'!''•'Project Number 4192 V AlJ DATUM 8 CCr Y -

July 2, 2002

Ms. Betty Ann JefferyUnited States Environmental Protection Agency, Region 3Office of Analytical Services and Quality AssuranceThe Environmental Science Center701 Mapes RoadFort Meade, Maryland 20755-5350

Subject: Case Number 30647Valmont TCEMemo to File

Dear Ms. Jeffery: '

In response to sample listing issue regarding the-case # 30647:

The inorganic soil sample MC0005 listed on Traffic Report (TR) # 3-4248327-062502-0001 forTM/CN analysis is incorrectly listed. A correction should be made and list sample MC0004collected on 6/24/02 at 09:55 instead the sample MC0005 collected on 6/24/02 at 10:00.

We apologize for the erroneous sample listing on the Chain of Custody documents and causingthe discrepancy. Thank you for your cooperation and please contact us if you need additionalinformation in solving this issue.

Respectfully,

Neb DedicEarth Scientist

ND/vh

Roman Romuald (EPA Region 3)Dan Slizys (EPA Region 3)Holly Rogers (CLASS)

Melissa Stevens

From: Rogers, Holly <[email protected]>To: Alice Evans (E-mail) <[email protected]>; Melissa Stevens-(E-mail)

<[email protected]>Cc: Betty Ann Jeffery (E-mail) <[email protected]>; Dan Slizys tE-mail)

<[email protected]>; John Kwedar (E-mail) <[email protected]>; Khin-ChoThaung (E-mail) <[email protected]>

Sent: Friday, June 28, 2002 9:23 AMSubject: Region 03 | Case 30647 | Lab LIBRTY | Issue TR/COC discrepancy - sample level | FINALAlice,

Following is the resolution from Region 3 regarding the TR discrepancy issuefor Case 30647. Per the Region, the lab should note the issue in theCase/SDG narrative and proceed with the analysis of the samples. Thesampler has been instructed to write a memo to file to clear up thediscrepancy.

Please let me know if you have any other questions or problems.

Thanks,Holly

Holly RogersDynCorp Systems and Solutions LLCCLP Coordinator for Regions 3 & [email protected] <mailto:[email protected]>

Original MessageFrom: [email protected] [mailto:[email protected]]Sent: FndayTJune 28, 2002 7:29 AMTo: Rogers, Holly; [email protected]; [email protected];[email protected]:"R"eTNEW ISSUE | Case 30647 | Lab LIBRTY | Issue TR/COC discrepancysample level

Holly,

The Region III CST Brokerage is waiting for the field personnel to respondto this issue. The field personnel are the only ones that can resolve thisissue. They will have to write a memo to file for TR/COC discrepancy.The lab should proceed with the analysis of samples and document this issuein the case narrative.

Dan Slizys

From: "Rogers, Holly"<[email protected]>

To: Betty Jeffery/ESC/R3/USEPA/US@EPA, Dan Slizys/ESC/R3/USEPA/US@EPA,John Kwedar/ESC/R37USEPA/US@EPA, Khin-Cho " ' "

Thauhg/ESC/R3/USEPA/US@EPA 077_ - - - - . _ . . . L _ / /

06/23/02

cc:Subject: NEW ISSUE | Case 30647 | Lab LIBRTY | Issue TR/COC discrepancysample level06/27/02 03:50PM

The lab is still waiting on a resolution to this issue. Please advise thelab how to proceed.

Thanks,Holly


Original MessageFrom: [email protected] [mailto:[email protected]]Sent: Thursday, June 27, 2002 1:09 PMTo: Rogers, Holly; [email protected]; [email protected];[email protected]: Betty Ann Jeffery (E-mail); John Kwedar (E-mail); Khin-Cho Thaung(E-mail)Subject: Re: NEW ISSUE | Case.30647 | Lab LIBRTY | Issue TR/COC discrepancysample level

Everyone,

The field personnel will have to investigate and resolve this sampleidentity issue on TR/COC. They are requested to provide feedback assoon as possible so analysis of samples would not be impeded.

Dan SlizysA-

From: "Rogers, Holly"<[email protected]>To: Betty Jeffery/ESC/R3/USEPA/US@EPA, Dan Slizys/ESC/R3/USEPA/US@EPA,John Kwedar/ESC/R3/USEPA/US@EPA, Khin-Cho :

"Thaung/ESC/R3/USEPA/US@EPAcc:Subject: NEW ISSUE | Case 30647 | Lab LIBRTY | Issue TR/COC discrepancy -sample level06/27/02 11:48 AM


Thanks,Holly

278

06/28/02


Original MessageFrom: Rogers, HollySent: Wednesday, June 26, 2002 2:23 PMTo: Betty Ann Jeffery (E-mail); Dan Slizys (E-mail); John Kwedar (E-mail);Khin-Cho Thaung (E-mail)Subject: NEW ISSUE | Case 30647 | Lab LIBRTY | Issue TR/COC discrepancy -sample levelImportance: High

Following is an email from LIBRTY regarding samples received on 6/26 forCase 30647.

s

Soil sample MC0005 was listed on the TR for TM/CN analysis but was notreceived by the lab. However, the lab did receive soil sample MC0004, whichwas not listed on the TR. The sample collection date and,time listed forsample MC0005 is 6/24 09:55. The sample collection date and time listed onthe tag for sample MC0004 is 6/24 10:00.

Please advise the lab how to proceed.

Thanks,Holly


Original MessageFrom: Alice Evans [mailto:[email protected]]Sent: Wednesday, June 26, 2002 1:53 PMTo: Rogers, HollySubject: Case 30647Importance: High

Holly,

Liberty received 20'soils and 1 water for Total Metals and Cyanides on06/26/02.

1. Received sample MC0004 which is not listed on the Traffic Report. Thesample Date is 06/24/02, the time collected is 09:55 (label on thebottle). Soil - 8 oz jar. Tag no. 3-115.

279

t)6/28/02

2. Sample MC0005 is listed on the Traffic Report but we did not receivedthe sample (date collected: 06/24/02, Time 10:00) Soil.

Thanks,Alice

Alice EvansCompuChem/Liberty501 Madison AveCary,NC 27513919-379-4080

280

06/28/02

of2

Alice Evans <

From: Rogers, Holly <[email protected]>To: Alice Evans (E-mail) <[email protected]>; Melissa Stevens {E-mail)

<[email protected]>Cc: Betty Ann Jeffery (E-mail) <[email protected]>; Dan Slizys (E-mail)

<[email protected]>; John Kwedar (E-mail) <[email protected]>; Khin-ChoThaung (E-mail) <[email protected]>

Sent: Wednesday, July 03, 2002 10:19 AMSubject: Region 03 | Case 30647 | Lab LIBRTY | Issue TR/COC discrepancy - sample level | FINALAlice, , u

Following is the resolution from Region 3 regarding the TR discrepancy forCase 30647. Per the Region, the lab should document the issue in theCase/SDG narrative and proceed with the analysis of the samples.

I f - y o u have any other questions or problems, please let me know.

Thanks,Holly

Holly Rogers - :

DynCorp Systems and Solutions LLCCLP Coordinator for Regions 3 & [email protected] <mailtci:[email protected]>

Original MessageFrom: [email protected][mailto:[email protected]]Sent: Wednesday, July 03, 2002 10:12 AMTo: Rogers, HollyCc: Dan Slizys (E-mail) ; John Kwedar (E-mail); Khin-Cho Thaung (E-mail)Subject: Re: NEW ISSUE I Case 30647 | Lab LIBRTY I Issue TR/COC discrepancysample level

Holly, the lab must document the TR/COC discrepancy in the case narrativeand continue with the analysis.. Thanks

From: "Rogers, Holly"<[email protected]>

To: Betty Jeffery/ESC/R3/USEPA/US@EPA, Dan Slizys/ESC/R3/USEPA/US6EPA,John Kwedar/ESC/R3/USEPA/US@EPA, Khin-Cho

Thaunq/ESC/R3/USEPA/US@EPAcc:Subject: NEW ISSUE | Case 30647 | Lab LIBRTY | Issue TR/COC discrepancy -sample level07/03/02 09:23 AM


Thanks,Holly


Original MessageFrom: Rogers, HollySent: Monday, July 01, 2002 1:08 PM OO1

381

07/11/02

of 2

To: Betty Ann Jeffery (E-mail); Dan Slizys (E-mail); John Kwedar (E-mail);Khin-Cho Thaung (E-mail)Subject: NEW ISSUE I Case 30647 | Lab LIBRTY | Issue TR/COC discrepancy -sample levelImportance: High

This is Jessica Brown, Holly is out for the day.

Per LIBRTY, the sample collection time was not listed on the TR/COC,received 6/29/02, for sample MC0087, Case 30647. Please advise on how thelab should proceed.

Thanks,Jessica

11:07AM 7/01/02Jessica Brown, SMO, spoke with" Alice Evans, LIBRTY, concerning Case 30647.The sample collection time was not listed on the TR/COC for sample MC0087.

Holly RogersDynCorp Systems and Solutions LLCCLP Coordinator for Regions 3 & 9703-264-9526holly, [email protected] <iuailto:holly. roqers@dyncorp. com>

382

07/11/02

Region III Sample Scheduling Request Form

RASCASENo:CT1363 / 3O (s>^=^

Date:

DAS No:

Data Validation Level: M-3 *f "$. r^J - 3_

Site Name: Valmont Rlitmlil'Jl ParltSitc- / CL-fc:

Address: Deer Run Road

Latitude:

Program: SUPERFUND

Longitude:

NSF No:

EPA Lab Reply:

Cost:

City: West Hazleton

CERCL1S No: PAD982363970

Account No:-OOTONFAX03*M€e04-

Preparer: Russell Sloboda

Phone: 610-491-9688

FAX: 610-491-9645

E-mail: [email protected]

EPA CO: Al PInero

Lab Assignment Date:

Organic Lab: (__€. \ V

Inorganic Lab: l — l t

SAMPLES

100

10

5

/OO

iO

Operable Unit:

RPM/PO:Romuald Roman

Phone: 215-814-3212

FAX: 215-814-3002

E-mail: Romuald [email protected]

Contract Type: RAC 3

State: PA

Anal +Val Data TAT:42 days

Activity: RI/FS

Spill ID:

Site Leader: Neil Teamerson

Phone: 610-491-9688

FAX: 610-491-9645

E-mail: [email protected]

Prime: Tetra Tech NUS

Analytical TAT: 21

vvT <—3^TVMETHOD

OLM04.2

OLM04.2

OLM04.2

l l f \ 0* - \

ILHOV.I

days

Sub:

Ship Date From: 06724/02

Ship Date To: 07/05/02

Carrier:

PARAMETER

TCL / 9 £fo $

VOCs /9s-&7VOCs/SVOCs/Pest/PCBs / "jS&ff

~~ TA I— •-•-xE.' 'sl ^ f C«-/'J>A-1» A-<4_ //3^>9

'A( fOi^tc^lS / Cc/3ru<^-£- ' f 5 ™ f)

\

MATRIX

Soil

AQ

AQ

^0. /

^J l" *")/\ \i<_

NOTE: Data validation levels M3 & IM2 require justification. QC field samples must be included as part of total number of samples.

1. Special Instructions: Send results to: Neil Teamerson, Tetra Tech NUS 600 Clarke Ave., Ste. 3, King of Prussia, PA 194062. Objectives / Project Plan ID / Permit ID: validated data used later for risk assessment: (Not Drinking Water)3. Program / Project / Permit Reporting Limits According to method used.4. DQO (QC Requirements) According to method used.

Teamerson, Neil" To: Lisa Penix/ESC/R3/USEPA/US@EPA<TeamersonN@TTNus. cc:Com> Subject: FW: Valmont Soil Samples

08/20/02 11:14 AMVALIDATOR'S COPY

> Original Message> From: Teamerson, Neil> Sent: Friday, August 16, 2002 1:21 PM> To: '[email protected]'> Subject: Valmont Soil Samples>> MC0031 (SS-DUP-01) is the dup of MC0030 (SS-G500-0002)>> MC0018 (SB-DUP-01) is the dup of MC0017 (SB-J250-0709)>> Neil Teamerson> Tetra Tech NUS, Inc. (TtNUS)> 600 Clark Avenue, Suite 3> King of Prussia, PA 19406-1433> (610) 491-9688> .(610) 491-9645 (facsimile)> [email protected]

APPENDIX D

Laboratory Case Narrative

Lab Name: COMPUCHEM

Lab Code: LIBRTY

U. S, EPA - CLPCOVER PAGE - INORGANIC ANALYSES DATA PACKAGE

Contract: 68W00082

SAS No.: •Case No.: 30647

SOW No. : ILM04.1

SDG No.: MC0002

EPA Sample No.

MC0002MC0004MC0012MC0014MC0015MC0017MC0018MC0020MC0020DMC0020SMC0021MC0022MC0023MC0024MC0025MC0027MC0028MC0029MC0030MC0031MC0032

Here ICP interelement corrections applied?

Were ICP background corrections applied?If yes-were raw data generated beforeapplication of background corrections?

Lab Sample ID.

MC0002-43MC0002-44MC0002-45MC0002-46MC0002-47MC0002-48MC0002-49MC0002-50WG18450-2.WG18450-1MC0002-51MC0002-52MC0002-53MC0002-54MC0002-55MC0002-56MC0002-57MC0002-58MC0002-59MC0002-60MC0002^61

Yes/No YES

Yes/No YES

Yes/No NO

Comments: THE FOLLOWING ANALYTES HAVE BEEN FLAGGED WITH AN "E" TO INDICATE SERIALDILUTION RESULTS WHICH ARE NOT WITHIN CONTROL LIMITS:

I certify that this data package is in compliance with the terms and conditions of thecontract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hardcopy data package and in the computer-readable datasubmitted on diskette has been authorized by the Laboratory Manager or the Manager's designee, asverified by the following signature.

Signature ;•

Date:

Name:

Title:

iCOVER PAGE - IN ILM04.1

U. S. EPA - CLPCOVER PAGE - INORGANIC ANALYSES DATA PACKAGE

Lab Name: COMPUCHEM \ Contract: 68W00082

Lab Code: LIBRTY Case No.: 30647 SAS No.: SDG No.: MC0002

SOW No. : ILM04.1

EPA Sample No. Lab Sample ID.

MC0033 MC0002-62

Were ICP interelement corrections applied? Yes/No YES

Were ICP background corrections applied? Yes/No YESIf yes-were raw data generated beforeapplication of background corrections? Yes/No NO

Comments: THE FOLLOWING ANALYTES HAVE BEEN FLAGGED WITH AN "E" TO INDICATE SERIALDILUTION RESULTS WHICH ARE NOT WITHIN CONTROL LIMITS:MACTTTT.CiTTTM

I certify that this data package is in compliance with the terms and conditions of thecontract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hardcopy data package and in the computer-readable datasubmitted on diskette has been authorized by the Laboratory Manager or the Manager' s designee, asverified by the following signature.

Signatures —T *- ^ •/ • L yV-X . Name:

f] f] QDate: (Ju (x/ ' C/-U (L. Title:

71

COVER PAGE - IN ILM04.1

CompuChema Division of Liberty Analytical Corp.•501 Madison Avenue Cary.NC 27513

SDG NARRATIVECASE # 30647 SDG # MC0002

CONTRACT # 68W00082

The indicated Sample Delivery Group (SDG) consisting of twenty (20) soil samples was received into thelaboratory information management system (LIMS) on June 26, 2002; intact and in good condition \vithChains of Custody (COC) Records in order, unless otherwise noted in any attachments or QualityAssurance Notices. Sample ID's reported in this data package are noted by the receiving department on theCOC if they differ from those listed by the samplers on the COC.

The samples were analyzed, in accordance with EPA - CLP Statement of Work (SOW) document ILM04.1for CLP TAL total metals and cyanide.

The correlation coefficients for the mercury and cyanide analytical runs are confirmed to be > 0.9950.

The cooler temperature bottle was present with samples received on June 26, 2002; and sampletemperature was 7.1 degrees Celsius.

LIBRTY did not receive sample MC0005 (with collection date and time 06/24/02 - 10:00) as listed on theTraffic Report but received sample MC0004 (with collection date and time 06/24/02 - 9:55). "

The Laboratory Control Sample (LCS) for sodium analyzed outside the control limits established for thatanalyte. Sodium is present in the LGS below the CRDL. Thus, the control limits are only advisory limits.

EQUATIONS FOR SOLID SAMPLE CALCULATIONS:

Client sample MC0020 is used for illustration.

Any sample result that is < the instrument detection limit (IDL) will be entered at the IDL for thatanalyte.

ICP Equation:Equation for obtaining metals sample results in mg/Kg as presented on FORM I data sheets from ICPinstrument acquired results in ug/L (ppb).

C x D x VConcentration (% solids) (mg/Kg)

W x SWhere

C = concentration (ug/L)D = dilution factorV = final volume in liters after sample preparationW = weight in grams of wet sampleS = % solids/100

Example: aluminum result ug/L to mg/Kg.52195.07 ug/L (C) x 1 (D) x 0.2 L(V)

= 11943.95 mg/Kg reported as 11900 mg/Kgl .Og(W) x 0.874 (S)

Mercury Equation:

Equation for obtaining mercury sample results in mg/Kg as presented on FORM I data sheets frominstrument acquired results in ug/L (ppb).

A x D x F

B x EWhere

A = ug/L HgB = wet weight of sampleD = dilution factor to bring sample into analysis rangeE = % solids/100F = final volume in liters (0.1 L)

Example: mercury result ug/L to mg/Kg0.1307 ug/L (A) x 1(D) x 0.1 (F)

= 0.0748 mg/Kg reported as 0.075 mg/Kg0.2 g(B) x 0.874 (E) :

Cyanide Equation:

Equation for obtaining cyanide sample results in mg/Kg as presented on FORM I data sheets frominstrument acquired results in ug/L (ppb).

A x D x F

B x EWhere

A = ug/LCNB = wet weight of sampjeD = dilution factor to bring sample into analysis rangeE = %solids/100F = final volume in liters (0 05 L)

Example: cyanide result ug/L to mg/Kg0.887464 ug/L (A) x 1 (D) x 0.05 L (F)

= 0.0508 mg/Kg reported as 0.051 mg/Kgl.OOg(B) x 0.874 (E)

SAMPLE IDs:f

The following customer IDs are associated with this SDG:

MC0002 MC0004 MC0012 MC0014 MC0015 MC0017

MC0018 MC0020 MC0021 MC0022 MC0023 MC0024

MC0025 MC0027 MC0028 MC0029 MC0030 MC0031

MC0032 MC0033

7

INSTRUMENTAL QUALITY CONTROL:

All calibration verification solutions (ICV & CCV), blanks (ICB, & CCB), and interference check samples(ICSA & ICSAB) associated with this data were confirmed to be within EPA CLP allowable limits.

SAMPLE PREPARATION QUALITY CONTROL:

The sample preparation procedure verifications (LCSS & PBS) were found to be within acceptable rangesand all field samples were prepared and analyzed within the contract specified holding times.

MATRIX RELATED QUALITY CONTROL:

The sample matrix spike, CCN = WG18450-1 (MC0020S) was found to be outside CLP control limits forantimony, lead, and selenium. The reported concentrations for these analytes are flagged with an "N" onall associated Form 1 and on Form 5a.

An "N" indicates a matrix-related interference in the sample preparation procedure &/or analysis for theflagged analyte. This is normally the consequence of a relatively high anionic content in the sample or (forsome sediments) an inconsistent sample matrix relative to that analyte.

CLP control limits for matrix spike recoveries are set at 75% to 125% of the analyte quantity added unlessoriginal sample concentrations exceed the true values of these "spikes" by a factor of four or more. In thiscase, affected analytes are not flagged even if recoveries are outside percentage recovery control limits.

Post-digestion spikes are mandatory for analytes demonstrating unsatisfactory matrix spike recoveriesduring ICP analysis (excluding silver). The results of such spikes are presented on Form 5b.

Unsatisfactory recovery of post-digestion spikes of this type do not have bearing upon the aforementioned"N" flags, but may indicate interference during analysis &/or a solution matrix which is hostile to theanalyte in question.-

Satisfactory recovery of an analyte in a post-digestion spike of this type implies interference by therequired preparation procedure or in the sample matrix itself. Lack of uniformity for an analyte insediments will also result in satisfactory recovery of post-digestion spikes after failure in the related matrixspike.

The sample matrix duplicate, CCN = WG 18450-2 (MC0020D) was outside CLP control limits formanganese and zinc. The reported concentrations for these analytes are flagged with a "*" on allassociated Form 1 and on Form 6.

A "*" indicates a non-homogeneous sample matrix in regard to the flagged analyte. This is normally theconsequence of a relatively coarse texture or of a mixed-matrix in sediment samples.

CLP control limits for duplicate determinations are +/- 20% Relative Percent Difference (RPD) forconcentrations greater than or equal to five times the CRDL in both the original and duplicate samples, and+/- the CRDL for concentrations less than five times the CRDL. The RPD is not calculated if both theoriginal and duplicate values fall below the IDL.

A five-fold serial dilution of sample, CCN = MC0002-50 (MC0020L) was performed in accordance withCLP requirements for ICP analysis.

The adjusted sample concentrations were outside CLP control limits for magnesium and zinc, which areflagged with an "E" on all associated Form 1, the Cover Page and Form 9.

8

An "E" indicates that a chemical or physical interference effect was encountered during the analysis of theflagged analyte. As a result of this interference, all values for the analyte in the same matrix must beconsidered to be estimated quantities.

CLP control limits for serial dilution are defined as a deviation less than or equal to 10% in the dilution-adjusted concentrations from the original values for all analyte concentrations with values greater thanfifty (50) times their respective Instrument Detection Limit (IDL) in the original sample.

The laboratory manager or his designee, as verified by the following signature has authorized release of thedata contained in this hard copy data package.

Thomas R. ColeData Reviewer IIJuly 9, 2002

CompuChema Division of Liberty Analytical Corp.501 Madison Avenue Cary.NC 27513

DATA REPORTING QUALIFIERS FOR INORGANICS

On Form I, under the column labeled "C" for concentration qualifier and "Q" for qualifier, each result is flagged with the specific datareporting qualifiers listed below, as appropriate. Up to five qualifiers may be reported on Form I for each analyte.

The C (concentration) qualifiers used are:

U: This flag indicates the analyte was analyzed for but not detected. This reported value was obtained from a reading thatwas less than the Instrument Detection Limit (1DL). The 1DL will be adjusted to reflect any dilution and, for soils, the

percent moisture.

B: This flag indicates the analyte was analyzed for and the reported value was obtained from a reading that was less than theContract Required Detection Limit (CRDL) but .greater than or equal to the Instrument Detection Limit (IDL).

The Q qualifiers used are:

E: This flag indicates an estimated value. This flag is used:

1. When the serial dilution (a five fold dilution for CLP and a five fold dilution for SW-846 method 601 OB) results arenot within 10%. The analyte concentration must be sufficiently high (minimally a factor of SOX above the IDL inthe original sample).

2. When the analytical spike recovery associated with the sample is below 40% after two successive dilutions byGraphite Furnace Atomic Absorption (GFAA).

M: This flag applies to GFAA analyses for concentrations greater than the Contract RequiredDetection Limit (CRDL). This flag is only used for GFAA if the analytical sample or analyticalspike duplicate injection reading is not within 20% of the Relative Standard Deviation (RSD).

N: This flag indicates the sample spike recovery is outside of control limits:

*: This flag is used for duplicate analysis when the sample and the sample duplicate results are notwithin control limits.

S: This flag applies to GFAA analyses to indicate the reported value was determined by theMethod Of Standard Addition (MSA).

\V: This flag applies to GFAA analyses when the post-digestion spike (analytical spike) is out of control limits (85% -115%),while sample absorbance is less than 50% of "spike" absorbance ["spike" is defined as (absorbance or concentration ofspike sample) minus (absorbance or concentration of the sample)].

+; This flag applies to GFAA analyses when the correlation coefficient for the MSA is less than 0.995 after two MSAanalyses.

NOTE: Entering "S", "W", or"+" is mutually exclusive. No combination of these qualifiers can appear in the same field for ananalyte.

The extensions: D, S, SD, L. A, added to the end of the client ID represent as follows:D: matrix duplicateS: matrix spikeSD: matrix spike duplicateL: serial dilution ,A: post digestion spike

Method Codes:P: ICP PLASMACV: MERCURY COLD VAPOR AACA MIDI-DISTILLATION SPECTROPHOTOMETRIC >] nF: FURNACE AA -L *J


Lab Name: COMPUCHEM Contract: 68W00082

Lab Code: LIBRTY Case No. : 30647 SAS No. : SDG No. : MC0035

SOW No.: ILM04.1


MC0035 MC0035-1MC0141 MC0035-2MC0142 MC0035-3MC0184 MC0035-4MC0185 MC0035-5

Were ICP interelement corrections applied? Yes/No YES

Were ICP background corrections applied? : Yes/No

If yes-were raw data generated beforeapplication of background corrections? Yes/No NO

Comments:

I certify that this data package is in compliance with the terms and conditions of thecontract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hardcopy data package and in thecomputer-readable data submitted on diskette has been authorized by the Laboratory Manager orthe Manager's designee, as verified by'the following signature.

Signature: (Lj&vK jiia^S? (j^e££J~ Name: . feWVeS. W

Date: // _ 7 / / (f Id 2 _ Title: "Se VN \C> r


CompuChema Division of Liberty Analytical Corp.'501 Madison Avenue Gary, NC 27513


CONTRACT # 68W00082

The indicated Sample Delivery Group (SDG) consisting of five (5) water samples was received into thelaboratory information management system (LIMS) on June 26,29, and July 2, 2002 intact and in goodcondition with Chain of Custody (COC) Records in order, unless otherwise noted in any attachments orQuality Assurance Notices. The temperature of the samples received on June 26, 2002 was 7.1°C. Thetemperature of the samples received on June 29,2002 was 3°C. The temperature of the samples received onJuly 2, 2002 was 8°C. Cooler temperature indicator bottles were present with all shipments.

Sample MC0185 is listed on the Traffic Report as TM/CN. It appears that the Sampler crossed out the tagnumber for the Cyanide fraction. The Laboratory only received a TM fraction for this sample, and onlyreported results for TAL metals.

All samples in this SDG are identified on the Traffic Report as Field QC. No matrix related QC sampleswere analyzed.

The samples were analyzed, in accordance with EPA CLP Statement of Work (SOW) document ILM04.1for the complete Inorganic Target Analyte List (TAL).

The correlation coefficient for the mercury and cyanide analytical runs are confirmed to be > 0.9950.

EQUATIONS FOR LIQUID SAMPLE CALCULATIONS:

Equation for obtaining metals sample results in ug/L as presented on FORM I data sheets from ICPinstrument acquired results in |ig/L (ppb).

C x F

1

Where

C = concentration (ug/L)

F = final volume in liters after sample preparation

I = initial volume in liters

Example: Aluminum result in ug/L

30.92848 ug/L (C) x 0.05 L (F)-- = 30.92848 ug/L reported as 30.9 ug/L0.05 L (I)

Equation for obtaining cyanide sample results in ug/L as presented on FORM I data sheets from instrumentacquired results in ug/L (ppb).

C x F x D

I

Where

C = concentration (ug/L) CN

F = final volume

D = dilution factor to bring sample into analysis range

I = initial volume in liters

Example: cyanide result in ug/L

0.390252 ug/L (C) x 1 (D) x 0.05 L (F)= 0.390252 ug/L reported as 0.60 ug/L *

0.05 L (F)

Equation for obtaining mercury sample results in ug/L as presented on FORM I data sheets frominstrument acquired results in ug/L (ppb).

C x D x F

I

Where

C = concentration (ug/L) Hg


F = final volume in liters (0.1 L)

1 = initial volume in liters

Example: Mercury result in ug/L

0.0882 ug/L (C) x 1 (D) x 0.1 (F)= 0.0882 ug/L reported as 0.10 ug/L *

* This result reported down to the IDL.

SAMPLE IDs:The following customer IDs are associated with this SDG:MC0035 MC0141 MC0142 MC0184 MC0185


All calibration verification solutions (ICV & CCV), blanks (IGB, & CCB), and interference check samples(1CSA & ICSAB) associated with this data were confirmed to be within EPA CLP allowable limits.

•\


The sample preparation procedure verifications (LCSW & PBW) were found to be within acceptableranges and all field samples were prepared and analyzed within the contract specified holding times.


mes E. Medlinenior Chemist

July 16,2002

of 1

Melissa Stevens

From: Melissa Stevens <[email protected]>To: Holly Rogers <[email protected]>Sent: Tuesday, July 16, 2002 4:02 PMAttach: 30647-071602.pdfSubject: 30647Hi Holly,

I forgot to send you an e-mail about this. Sample MC0185 is listed as TM/CN, but we, only received TM. If youtake a look at the traffic report the sampler marked the CN tag number out, but did not mark the CN off from theanalysis colume. Please see attachment.

Melissa Stevens•EPA Coordinator(919)379-4081CompuChem a division of Liberty [email protected]

807/16/02


Lab Name: COMPUCHEM

Lab Code: LIBRTY Case No.: 30647

SOW No.: ILM04.1

Contract: 68W00082

SAS No.: SDG No.: MC0069

EPA Sample No.

MC0069MC0070MC0071MC0072MC0073MC0073DMC0073SMC0074MC0075MC0076MC0077MC0079MC0080MC0081MC0082MC0083MC0084MC0085MC0086MC0087MC0088

Were ICP interelement corrections applied?

Were ICP background corrections applied?

If yes-were raw data generated beforeapplication of background corrections?

Lab Sample ID.

MC0069-1MC0069-2MC0069-3MC0069-4MC0069-5WG18532-2WG18532-1MC0069-6MC0069-7MC0069-8MC0069-9MC0069-10MC0069-11MC0069-12MC0069-13MC0069-14MC0069-15MC0069-16MC0069-17MC0069-18MC0069-19

Yes/No

Yes/No

Yes/No NO

Comments:

I certify that this data package is in compliance with the terms and conditions of thecontract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hardcopy data package and in thecomputer-readable data submitted on diskette has been authorized by the Laboratory Manager orthe Manager's designee, as verified by the following signature.

Signature:. K-

Date: iJijt / b,

Name:

Title: \) \AJ-t l\ 4 )

•COVER PAGE - IN ILM04.1

U. S. EPA - CLP

COVER PAGE - INORGANIC ANALYSES DATA PACKAGE



SOW No.: ILM04.1


MC0089 . MC0069-20

Here ICP interelement corrections applied? Yes/No YES

Were ICP background corrections applied? Yes/No YESIf yes-were raw data generated beforeapplication of background corrections? Yes/No NO

Comments:

I certify that this data package is in compliance with the terms and conditions of thecontract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hardcopy data package and in thecomputer-readable data submitted on diskette has been authorized by the Laboratory Manager orthe Manager's-designee, as verified by the following signature.

Signature.:_ jksMo L Kr • ( JJj2— Name: I /Vl U/LS ./H

Date: JltiL, ' *> . /7*OQ<s*- Title:


CompuChema Division of Liberty Analytical Corp.501 Madison Avenue Gary, NC 27513


CONTRACT # 68W00082

The indicated Sample Delivery Group (SDG) consisting of twenty (20) soil samples was received into thelaboratory information management system (LIMS) on June 29, 2002; intact and in good condition with

• Chains of Custody (COC) Records in order, unless otherwise noted in any attachments or QualityAssurance Notices. Sample ID's reported in this data package are noted by the receiving department on theCOC if they differ from those listed by the samplers on the COC.



The cooler temperature bottle was present with samples received on June 29, 2002; and sampletemperature was 3.0 degrees Celsius.

The collection time is missing from the Traffic Report for sample MCOOS7. Per Region 3, the sample wasanalyzed.




ICP Equation:

Equation for obtaining metals sample results in mg/Kg as presented on FORM I data sheets from ICPinstrument acquired results in ug/L (ppb).


W x SWhere

C = concentration (ug/L) ,D = dilution factorV = final volume in liters after sample preparationW = weight in grams of wet sampleS = %solids/100

Example: aluminum result ug/L to mg/Kg.28361.53 ug/L (C) x 1 (D) x 0.2 L (V)

=6178.98 mg/Kg reported as 61 SO mg/Kg1.0 g(W) x 0.918 (S)

Mercury Equation:


A x D x F

B x EWhere

A = ug/L HgB = wet weight of sampleD = dilution factor to bring sample into analysis range •E = % solids/100

. F = final volume in liters (0.1 L)Example: mercury result ug/L to mg/Kg0.10 ug/L* (A) x 1(D) x 0.1 (F)

= 0.05447 mg/Kg reported as 0.054 mg/Kg*0.2 g(B) x 0.918 (E)

* The result is reported down to the instrument detection limit.

Cyanide Equation:


A x D x F

B x EWhere

A = ug/LCN 'B = wet weight of sampleD = dilution factor to bring sample into analysis range

• E = % solids/100F = final volume in liters (0 05 L)


= 0.06558 mg/Kg reported as 0.066 mg/Kgl.OOg(B) x 0.918 (E)

SAMPLE IDs:


MC0069 MC0070 MC0071 MC0072 MC0073 MC0074

MC0075 MC0076 MC0077 MC0079 MC0080 MC0081

MC0082 MC0083 MC0084 MC0085 MC0086 MC0087

MC0088 MC0089


All calibration verification solutions (ICV & CCV), blanks (ICB, & CCB), and interference check samples(ICSA & ICSAB) associated With this data were confirmed to be within EPA CLP allowable limits.




The sample matrix spike, CCN = WG18532-1 (MC0073S) was found to be outside CLP control limits forantimony, manganese, mercury, and thallium. The reported concentrations for these analytes are flaggedwith an "N" on all associated Form 1 and on Form 5a.




Unsatisfactory recovery of post-digestion spikes of this type do not have bearing upon the aforementioned"N" flags, but may indicate interference during analysis &/or a solution matrix which is hostile to theanalyte in question.


The sample matrix duplicate, CCN = WG 18532-2 (MC0073D) was outside CLP control limits for arsenic.The reported concentration for this analyte is flagged with a "*" on all associated Form 1 and on Form 6.

A "*" indicates a non-homogeneous sample matrix in regard to the flagged analyte. This is normally theconsequence of a relatively coarse texture or of a mixed-matrix in sediment samples.

was inside CLP control limits for the requested analytes.



The adjusted sample concentrations were inside CLP control limits for the requested analytes.

7


The laboratory manager or his.designee, as verified by the following signature has authorized release of thedata contained in this hard copy data package.


8


DATA .REPORTING QUALIFIERS FOR INORGANICS



U: This flag indicates the analyte was analyzed for but not detected. This reported value was obtained from a reading thatwas less than the Instrument Detection Limit (IDL). The IDL will be adjusted to reflect any dilution and. for soils, the

percent moisture.

B: This flag indicates the analyte was analyzed for and the reported value was obtained from a reading that was less than theContract Required Detection Limit (CRDL) but greater than or equal to the Instrument Detection Limit (IDL).



1. When the serial dilution (a five fold dilution for CLP and a five fold dilution for SW-S46 method 601 OB) results arenot within 10%. The analyte concentration must be sufficiently high (minimally a factor of SOX above the IDL inthe original sample).




*: This flag is used for duplicate analysis when the sample and the sample duplicate results are not ,within control limits.


\V: This flag applies to GFAA analyses when the post-digestion spike (analytical spike) is out of control limits (85% - 115%),while sample absorbance is less than 50% of "spike" absorbance ["spike" is defined as (absorbance or concentration ofspike sample) minus (absorbance or concentration of the sample)]. "

+: This flag applies to GFAA analyses when the correlation coefficient for the MSA is less than 0.995 after two MSAanalyses.


The extensions: D, S, SD, L. A, added to the end of the client ID represent as follows:D: matrix duplicateS: matrix spikeSD: matrix spike duplicateL: serial dilutionA: post digestion spike

Method Codes:P: ICP PLASMACV. MERCURY COLD VAPOR AACA: MIDI-DISTILLATION SPECTROPHOTOMETRIC (

F. FURNACE AA


Lab Name:

Lab Code:

COMPUCHEM

LIBRTY Case No.: 30647

SOW No.: JLM04.1

Con tract: 68W00082


EPA Sample No.

MC0078MC0078DMC0078SMC0090MC0091MC0092MC0093MC0094MC0095MC0096MC0097MC0098MC0099MC0100MC0101MC0102MC0103MC0104MC0105MC0106MC0107



Lab Sample ID.

MC0078-14WG18530-2WG18530-1MC0078-15MC0078-16MC0078-17MC0078-18MC0078-19MC0078-20MC0078-21MC0078-22MC0078-23MC0078-24MC0078-25MC0078-26MC0078-27MC0078-28MC0078-29MC0078-30MC0078-31MC0078-32

Yes/No

Yes/No YES

Yes/No NO

Comments:

I certify that this data package is in compliance with the terms and conditions of thecontract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hardcopy data package and in thecomputer-readable data submitted on diskette has been authorized by the Laboratory -Manager orthe Manager's designee, as verified by the following signature.

Signature:

Date:

Name:

Title:


U.S. EPA-CLPCOVER PAGE - INORGANIC ANALYSES DATA PACKAGE

•Lab Name: COMPUCHEM Contract: 68W00082

Lab Code: LIBRTY Case No.: 30647 SAS No.: SDG No. : MC0078

SOW No.: ILM04.1


MC0108 MC0078-33

Were ICP interelement corrections applied? Yes/No

Were ICP background corrections applied? \ Yes/NoIf yes-were raw data generated beforeapplication of background corrections? Yes/No NO

Comments:

I certify that this data package is in compliance with the terras and conditions of thecontract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hardcopy data package and in thecomputer-readable data submitted on diskette has been authorized by the Laboratory Manager orthe Manager's designee, as verified by the following signature.

Yl g -JSignature : ( M&yY &l ^g-J^ Name :

>

Date: // 7 / / g'/dZ- _ Title:




CONTRACT # 68W00082

The indicated Sample Delivery Group (SDG) consisting of twenty (20) soil samples was received into thelaboratory information management system (LIMS) on June 29,2002 intact and in good condition withChain of Custody (COC) Records in order, unless otherwise noted in any attachments or Quality AssuranceNotices. The temperature of the samples upon receipt was 3°C, as determined from the cooler temperatureindicator bottle.

The samples were analyzed, in accordance with EPA CLP Statement of Work (SOW) document ILM04.1,for the complete Inorganic Target Analyte List (TAL).


EQUATIONS FOR SOLED SAMPLE CALCULATIONS:

Equation for obtaining metals sample results in mg/kg as presented on FORM I data sheets from ICPinstrument acquired results in ug/L (ppb).

C x V

W x S

Where


V = final volume in liters after sample preparation

W = weight in grams of wet sample

S = % solids/100

Example: aluminum result ug/1 to mg/kg.

30976.51 ug/L(C) x 0.2 L(V)

l.Og(W) x 0.890 (S)= 6961.013 mg/kg reported as 6960 mg/kg

Equation for obtaining cyanide sample results in mg/kg as presented on FORM I data sheets frominstrument acquired results in ug/LXppb).

C x D x V

W x S

Where

C = concentration of cyanide (ug/L)

W = wet weight of sample


S = % solids/100

V = final volume in liters

Example: cyanide result ug/L to mg/kg

1.399607 ug/L (C) x 1 (D) x 0.05 L (V)

l.Og(W) x 0.890 (S)= 0.07863 mg/kg reported as 0.079 mg/kg

' Equation for obtaining mercury sample results in mg/kg as presented on FORM 1 data sheets frominstrument acquired results in ug/L (ppb). .

C x D x V

W x S

Where




S = %solids/100


Example: mercury result ug/L to mg/kg

0.0165 ug/L(C) x 1 (D) x 0.1 L (V)= 0.0093 mg/kg reported as 0.056 mg/kg *

0.2 g (W) x 0.890 (S)

* This result reported down to the IDL. f

SAMPLE IDs:The following customer IDs are associated with this SDG:MC0078 MC0090 MC0091 MC0092 MC0093 MC0094 MC0095 MC0096 MC0097MC0098 MC0099 MC0100 MC0101 MC0102 MC0103 MC0104 MC0105 MC0106MC0107 MC0108






The sample matrix spike, CCN = WG18530-1 (MC0078S) was found to be outside CLP control limits forAntimony, Manganese and Thallium.


The sample matrix duplicate, CCN = WG18530-2 (MC0078D) was found to be inside CLP control limitsfor the requested analytes.


A five-fold serial dilution of sample, CCN = SDIMC0078-1 (MC0078L) was performed in accordancewith CLP requirements for 1CP analysis.

The adjusted sample concentrations were inside CLP control limits for the requested analytes.

CLP .control limits for serial dilution are defined as a deviation less than or equal to 10% in the dilutionadjusted concentrations from the original values for all analyte concentrations greater than fifty (50) timestheir respective Instrument Detection Limit (IDL) in the original sample.


James E. MedlinSenior ChemistJuly 16,2002

8


Lab Name: COMPUCHEM


SOW No. : ILM04.1

EPA Sample No.

MC0109MC0110MC0111MC0112MC0113MC0114MC0115MC0116MC0117MCOH8MC0119MC0120MC0121MC0122MC0123MC0124MC0125MC0126MC0127MC0131MC0131D



Contract: 68W00082

SAS No.:

Lab Sj""ple ID.

MC0109-1MC0109-2MC0109-3MC0109-4MC0109-5MC0109-6MC0109-7MC0109-8MC0109-9MC0109-10MC0109-11MC0109-12MC0109-13MC0109-14MC0109-15MC0109-16MC0109-17MC0109-18MC0109-19MC0109-20WG18531-2

SDG No. : MC0109

Yes/No YES

Yes/No YES

Yes/No NO

Comments: THE FOLLOWING ANALYTES HAVE BEEN FLAGGED WITH AN "E" TO INDICATE SERIALnTT.ITTTON RESULTS WHICH ARE NOT WTTHIN CONTROL LIMITS:MAGNESIUM . _


Signatur

Date:

Name:

Title:

COVER PAGE - IN

IN&it.

1L 3

ILM04.1




SOW No. : ILM04.1


MC0131S WG18531-1

Were ICP interelement corrections 'applied? Yes/No YES

Were ICP background corrections applied? ' Yes/No YESIf yes-were raw data generated beforeapplication of background corrections? Yes/No NO

Comments: THE FOLLOWING ANALYTES HAVE BEEN FLAGGED WITH AN "E" TO INDICATE SERIALDTT.1TTTON RESULTS WHICH ARE NOT WTTHTN CONTROL T.TMTTS; ._


&• -Signatur^^/A^-ViMA**- **• - \_0\$_ Name:

Date: I / < A - / V , 1.5, d-Cfl&t Title: Uwf-" J\^£AJUJ^-^\. \{ ~f.Q I y




CONTRACT # 68W00082

The indicated Sample Delivery Group (SDG) consisting of twenty (20) soil samples was received into thelaboratory information management system (LIMS) on June 29,2002; intact and in good condition withChains of Custody (COC) Records in order, unless otherwise noted in any attachments or QualityAssurance Notices. Sample ID's reported in this data package are noted by the receiving department on theCOC if they differ from those listed by the samplers on the COC.



The cooler temperature bottle was present with samples received on June 29,2002; and sampletemperature was 3.0 degrees Celsius.

The Laboratory Control Sample (LCS) for sodium analyzed outside the control limits established for thatanalyte. Sodium is present in the LCS below the CRDL. Thus, the control limits are only advisory limits.




ICP Equation:

Equation for obtaining metals sample results in ing/Kg as presented on FORM I data sheets from ICPinstrument acquired results in ug/L (ppb).


. W x SWhere

C = concentration (ug/L)D = dilution factorV = final volume in liters after sample preparationW = weight in grams of wet sampleS = %solids/100

Example: aluminum result ug/L to mg/Kg.41422.58 ug/L (C) x 1 (D) x 0.2 L(V)

=9511.5 mg/Kg reported as 9510 mg/Kgl.Og(W) x 0.«71(S)

Mercury Equation:


A x D x F

B x EWhere

A = ug/L HgB = wet weight of sampleD = dilution factor to bring sample into analysis rangeE = %solids/100F = final volume in liters (0.1 L)

Example: mercury result ug/L to mg/Kg0.10 ug/L* (A) x 1(D) x 0.1 (F)

= 0.0574 mg/Kg reported as 0.057 mg/Kg*0.2 g(B) x 0.871(E)


Cyanide Equation:


A x D x F

B x EWhere

A = ug/L CNB = wet weight of sampleD = dilution factor to bring sample into analysis rangeE = % solids/100 ''F = final volume in liters (0 05 L)


= 0.03768 mg/Kg reported as 0.038 mg/Kgl.OOg(B) x 0.871(E)

SAMPLE IDs:


MC0109 MC0110 MC0111 MC0112 MC0113 MC0114

MC0115 MC0116 MC0117 MC0113 MC0119 MC0120

MC0121 MC0122 MC0123 MC0124 MC0125 MC0126V

MC0127 MC0131

7






The sample matrix spike, CCN = WG18531-1 (MC0131S) was found to be outside CLP control limits forantimony and lead. The reported concentrations for these analytes are flagged with an "N" on allassociated Form 1 and on Form 5a.






The sample matrix duplicate, CCN = WG 18531-2 (MC0131D) was inside CLP control limits for therequested analytes.


A five-fold serial dilution of sample, CCN = MCO109-20 (MC0131L) was performed in accordance withCLP requirements for ICP analysis.

The adjusted sample concentrations were outside CLP control limits for magnesium, which is flagged withan "E" on all associated Form 1, the Cover Page and Form 9.


8



omas R. ColeData Reviewer IIJuly 15, 2002





U: This flag indicates the analyte was analyzed for but not detected. This reported value was obtained from a reading thatwas less than the Instrument Detection Limit (IDL). The IDL will be adjusted <o reflect any dilution and, for spils, the

percent moisture.





2. When the analytical spike recovery associated with the sample is belo\\ 40% after two successive dilutions byGraphite Furnace Atomic Absorption (GFAA).



*: This flag is used for duplicate analysis when the sample and the sample duplicate results are not .within control limits.


\V: This flag applies to GFAA analyses when the post-digestion spike (analytical spike) is out of control limits (85% - 115%),while sample absorbance is less than 50% of "spike" absorbance ["spike" is defined as (absorbance or concentration ofspike sample) minus (absorbance or concentration of the sample)].




Method Codes:P: ICP PLASMACV: MERCURY COLD VAPOR AACA: MIDI-DISTILLATION SPECTROPHOTOMETR1CF: FURNACE AA 10


Lab Name: COMPUCHEM


SOW No. : ILM04.1

Contract: 68W00082

SAS No.: SDG No. MC0128

EPA Sample No.

MC0128MC0128DMC0128SMC0129MC0130MC0132MC0133MC0134MC0135MC0136MC0137MC0138MC0139

Lab ID .

MC0128-1WG18589-2WG18589-1MC0128-2MC0128-3MC0128-4MC0128-5MC0128-6MC0128-7MC0128-8MC0128-9MC0128-10MC0128-11



Yes/No YES

'• Yes/No YES

Yes/No NO

Comments: THE FOLLOWING ANALYTES HAVE BEEN FLAGGED WITH AN "E" TO INDICATE SERIAL' nTT.TTTTQN TJF.SULTS WHTCH ARE NOT WITHIN CONTROL T.TMTTS:

ZiNC : =


Signature :r

Date:

I Name:

Title:

COVER PAGE - IN

/ AoTlAAS K - L

JAt/i, K £k>

ILM04.1



CONTRACT # 68W00082

The indicated Sample Delivery Group (SDG) consisting of eleven (11) soil samples was received into thelaboratory information management system (LIMS) on June 29,2002; intact and in good condition withChains of Custody (COC) Records in order, unless otherwise noted in any attachments or QualityAssurance Notices. Sample ID's reported in this data package are noted by the receiving department on theCOC if they differ from those listed by the samplers on the COC.



The cooler temperature bottle was present with samplesTeceived on June 29, 2002; and sampletemperature was 3.0 degrees Celsius.

The sampler did not designate as sample for MS/MSD. LIBRTY selected sample MC0128 for QC.

The Laboratory Control Sample (LCS) for sodium analyzed outside the control limits established for thatanalyte. Sodium is present in the LCS below the CRDL. Thus, the control limits are only advisory limits.



Any sample result that is < the instrument detection limit (IDL) will be entered at the IDL for thatanalyte.ICP Equation:Equation for obtaining metals sample results in mg/Kg as presented on FORM I data sheets from ICPinstrument acquired results in ug/L (ppb).


W x SWhere


Example: aluminum result ug/L to mg/Kg.34365,69 ug/L (C) x 1 (D) x 0.2 L (V)

= 7446.5 mg/Kg reported as 7450 mg/Kgl.Og(W) x 0.923(8)

Mercury Equation:

Equation for obtaining mercury sample results in mg/Kg as presented on fORM I data sheets frominstrument acquired results in ug/L (ppb).

A x D x F

B x EWhere

A = ug/L HgB = wet. weight of sampleD = dilution factor to bring sample into analysis rangeE = % sol ids/100F = final volume in liters (0.1 L)

Example: mercury result ug/L to mg/Kg0.1253 ug/L (A) x 1 (D) x 0.1 (F)

= 0.06788 mg/Kg reported as 0.068 mg/Kg0.2 g(B) x 0.923 (E)

Cyanide Equation:


A x D x F

B x EWhere

A = ug/L CNB = wet weight of sampleD = dilution factor to bring sample into analysis rangeE = % solids/100F = final volume in liters (0 05 L)

Example: cyanide result ug/L to mg/Kg0.60 ug/L* (A) x 1 (D) x 0.05 L (F)

= 0.0325027 mg/Kg reported as 0.033 mg/Kg*l.OOg(B) x 0.923 (E)


SAMPLE IDs:


MCOI28 MC0129 MC0130 MC0132 MC0133 MC0134

MC0135 MC0136 MC0137 MC0138 MC0139


All calibration verification solutions (ICY & CCV), blanks (1CB, & GCB), and interference check samples(ICSA & ICSAB) associated with this data were-confirmed to be within EPA CLP allowable limits.




The sample matrix spike, CCN = WG18589-1 (MC0128S) was found to be outside CLP control limits forantimony and mercury. The reported concentrations for these analytes are flagged with an "N" on allassociated Form 1 and on Form 5a.


CLP control limits for matrix spike recoveries are set at 75% to 125% of the analyte quantity added unlessoriginal sample concentrations exceed the true.values of these "spikes" by a factor of four or more. In thiscase, affected analytes are not flagged even if recoveries are outside percentage recovery control limits.



jSatisfactory recovery of an analyte in a post-digestion spike of this type implies interference by therequired preparation procedure or in the sample matrix itself. Lack of uniformity for an analyte insediments will also result in satisfactory recovery of post-digestion spikes after failure in the related matrixspike.

The sample matrix duplicate, CCN = WG 18589-2 (MC0128D) was inside CLP control limits for therequested analytes.


A five-fold serial dilution of sample, CCN = MCO128-1 (MC0128L) was performed in accordance withCLP requirements for ICP analysis.

VThe adjusted sample concentrations were outside CLP control limits for zinc, which is flagged with an "E"on all associated Form 1, the Cover Page and Form 9.



7



8


DATA.REPORTING QUALIFIERS FOR INORGANICS


The C (concentration) qualifiers used are;

U: This flag indicates the analyte was analyzed for but not detected. This reported value was obtained from a reading thatwas less than the Instrument Detection Limit (IDL). The IDL will be adjusted to reflect any dilution and, for soils, the

percent moisture.

B: This flag indicates the analyte was analyzed for and the reported value was obtained from a reading that was less than the "Contract Required Detection Limit <CRDL) but .greater than or equal to the Instrument Detection Limit (IDL).



" 1. When the serial dilution (a five fold dilution for CLP and a five fold dilution for SXV-846 method 6010B) results arenot within 10%. The analyte concentration must be sufficiently high (minimally a factor of SOX above the IDL inthe original sample).

2. When the analytical spike recovery associated with the sample is below 40% after ruo successive dilutions byGraphite Furnace Atomic Absorption (GFAA).

M: This flag applies to GFAA analyses for concentrations greater than .the Contract RequiredDetection Limit (CRDL). This flag is only used forGFAA if the analytical sample or analyticalspike duplicate injection reading is not within 20% of the Relative Standard Deviation (RSD).


*: This flag is used for duplicate analysis when the sample and the sample duplicate results are not:within control limits.


W: This flag applies to GFAA analyses when the post-digestion spike (analytical spike) is out of control limits (85% -115%),while sample absorbance is less than 50% of "spike" absorbance ("spike" is defined as (absorbance or concentration ofspike sample) minus (absorbance or concentration of the sample)].

+; This flag applies to GFAA analyses when the correlation coefficient for the MSA is less than 0.995 after two MSAanalyses.



Method Codes:P. ICP PLASMACV: MERCURY COLD VAPOR AA .,CA: MIDI-DISTILLATION SPECTROPHOTOMETRICF: FURNACE AA


Lab Name: COMPUCHEM

Lab Code: LIBRTY

SOW No.: ILM04.1

Case No.: 30647

Contract: 68W00082


EPA Sample No.

MC0143MC0144MC0145MC0146MC0147MC0148MC0149MC0150MC0151MC01S2MC0152DMC0152SMC0154MC0155MC0156MC0157MC0158MC0159MC0160MC0161MC0162


Were ICP background corrections applied?If.yes-were raw data generated beforeapplication of background corrections?

Lab Sample ID.

MC0143-1MC0143-2MC0143-3MC0143-4MC0143-5MC0143-6MC0143-7MC0143-8MC0143-9MC0143-10WG18575-2WG18575-1MC0143-11MC0143-12MC0143-13MC0143-14MC0143-15MC0143-16MC0143-17MC0143-18MC0143-19

Yes/No YES

Yes/No YES

Yes/No NO

Comments: THE FOLLOWING ANALYTES HAVE BEEN FLAGGED WITH AN "E" TO INDICATE SERIALDILUTION RESULTS WHICH ARE NOT WITHIN CONTROL LIMITS : ZINC.

I certify that this data package is in compliance with the terms and conditions of thecontract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hardcopy data package and in thecomputer-readable data submitted on diskette has been authorized by the Laboratory Manager orthe Manager's designee, as verified by the following signature.

Signature:

Date:

Name:

Title:



Lab Name: COMPUCHEM Contract: 68WO0082

Lab Code: LIBRTY Case No. : 30647 SAS No. : SDG No. : MC0143

SOW No.: ILM04.1


MC0163 MC0143-20

Were ICP interelement corrections applied? Yes/No

Were ICP background corrections applied? •• Yes/NoIf yes-were raw data generated beforeapplication of background corrections? Yes/No NO

Comments: THE FOLLOWING ANALYTES HAVE BEEN FLAGGED WITH AN "E" TO INDICATE SERIALDILUTION RESULTS WHICH ARE NOT WITHIN CONTROL LIMITS : ZINC.

I certify that this data package is in compliance with the terms and conditions of thecontract, both technically and for completeness , for other than the conditions detailedabove. Release of the data contained in this hardcopy data package and in thecomputer-readable data submitted on diskette has been authorized by the Laboratory Manager orthe Manager's designee, as verified by the following signature.

Signature: /^L^^^ Name: J^VY\-eS YY\&d\ln

Date:C

7/7*7 /<9<3 _ Title: S^n JQC




CONTRACT # 68W00082

The indicated Sample Delivery Group (SDG) consisting of twenty (20) soil samples was received into thelaboratory information management system (LIMS) on July 2, 2002 intact and in good condition withChain of Custody (COC) Records in order, unless otherwise noted in any attachments or Quality AssuranceNotices. The temperature of the samples upon receipt was 8°C, as determined from the cooler temperatureindicator bottle. '

The samples were analyzed, in accordance with EPA CLP Statement of Work (SOW) document ILM04.1,for the complete Inorganic Target Analyte List (TAL).


EQUATIONS FOR SOLDD SAMPLE CALCULATIONS:

Equation for obtaining metals sample results in mg/kg as presented on FORM I data sheets from ICPinstrument acquired results in ug/L (ppb).

C x V

W x S

Where


V = final volume in liters after sample preparation

W = weight in grams of wet sample

S = %solids/100

Example: aluminum result ug/1 to mg/kg.

42130.18 ug/L (C) x 0.2 L(V)= 9629.755 mg/kg reported as 9630 mg/kg

l.Og(W) x 0.875 (S)

Equation for obtaining cyanide sample results in mg/kg as presented on FORM I data sheets frominstrument acquired results in ug/L (ppb).

C x D x VV

W x S

Where '

C = concentration of cyanide (ug/L)



S = %solids/100


Example: cyanide result ug/L to mg/kg

1.246421 ug/L (C) x 1 (D) x 0.05 L (V)= o.071224 mg/kg reported as 0.071 mg/kg

l .Og(W) x 0.875(8)

Equation for obtaining mercury sample results in mg/kg as presented on FORM I data sheets frominstrument acquired results in Ug/L (ppb).

C x D x V

W x S .

Where




S = % solids/100


Example: mercury result ug/L to mg/kg

0.0892 ug/L(C) x 1 (D) x 0.1 L (V)= 0.0510 mg/kg reported as 0.057 mg/kg *

0.2 g (W) x 0.822 (S)

7This result reported down to<he IDL.

SAMPLE IDs:The following customer IDs are associated with this SDG:MC0143 MC0144 MC0145 MC0146 MC0147 MC0148 MC0149 MC0150 MC0151MC01S2 MC0154 MC01S5 MC01S6 MC0157 MCOI58 MC0159 MC0160 MC0161MC0162 MC0163




The sample preparation procedure verifications (LCSS & PBS) were found to be within acceptable rangesand all field samples were prepared and analyzed within the contract specified holding times. The Sodiumresult for the LCSS is above the control'limit. The True Value for Sodium is below the CRDL and thecontrol limits are stated to be advisory only.


The sample matrix spike, CCN = WG18575-1 (MC0152S) was found to be outside CLP control limits forAntimony, Manganese and Selenium.


The sample matrix duplicate, CCN = WG 18575-2 (MC0152D) was found to be outside CLP control limitsfor Chromium, Iron and Manganese.


A five-fold serial dilution of sample, CCN = SDIMC0143-10 (MC0152L) was performed in accordancewith CLP requirements for ICP analysis.

The adjusted sample concentration was outside CLP, control limits for Zinc, which is flagged with an "E"on all associated Form I and Form IX.

CLP control limits for serial dilution are defined as a deviation less than or equal to 10% in the dilutionadjusted concentrations from the original values for all analyte concentrations greater than fifty (50) timestheir respective Instrument Detection Limit (IDL) in the original sample.

An "E" flag indicates that a chemical or physical interference effect was encountered during the analysis ofthat analyte. As a result of the interference, all values for that analyte in the same matrix must beconsidered estimated values.


ames E. MedlinSenior ChemistJuly 17,2002

Lab Name: COMPUCHEM

Lab Code: LIBRTY

U. S. EPA - CLP

COVER PAGE - INORGANIC ANALYSES DATA PACKAGE

Contract: 68W00082

SAS No.:Case No.: 30647

SOW No. : ILM04. 1

SD6 No. MC0153

EPA Sample No.

MC0153MC0153DMC0153SMC0164MC0165MC0166MC0167MC0168MC0169MC0170MC0171MC0172MC0173MC0174MC0175MC0176MC0177MC0178MC0179MC0180MC0181



Lab Sample ID.

MC0153-15WG18576-2WG1857€-1MC0153-16MC0153-17MC0153-18MC0153-19MC0153-20MC0153-21MC0153-22MC0153-23MC0153-24MC0153-25MC0153-26MC0153-27MC0153-28MC0153-29MC0153-30MC0153-31MC0153-32MC0153-33

Yes/No YES

Yes/No YES

Yes/No NO


rHTtnMTTTM, PDTRSSTTJM '

I certify that this data package is in compliance with the .terms and conditions of thecontract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hardcopy data package and in the computer-readable datasubmitted on diskette has been authorized by the Laboratory Manager or the Manager's designee, asverified by the following signature.

Signature: _

Date:

Name:

Title:

COVER PAGE - IN

-UJ^ \-tJT, JL

ILM04.J


Lab Name: COMPUCHEM Contract: 68WOOO82

Lab Code: LIBRTY Case Ho. : 30647 SAS No. : SDG No. : MC0153

SOW No. : ILM04.1


MC0182 MC0153-34

Here ICP interelement corrections applied? Yes/No YES

Were ICP background corrections applied? • Yes/No YESIf yes-were raw data generated beforeapplication of background corrections? Yes/No NO


I certify that this data package is in compliance with the terms and conditions of thecontract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hardcopy data package and in the computer-readable datasubmitted on diskette has been authorized by the Laboratory Manager or the Manager' s designee, asverified by the following signature.

K - (j>*JL Name: / /WWA£ A - Cfif JjSignature: ^/fK^jjU- K - (J^UL Name: / nfrfW4£ A- - (-fit &

i

Date: . LUULu I / O . 2 0^/^~ Title:



SDG NARRATIVE

CASE # 30647 SDG # MC0153CONTRACT # 68W00082

The indicated Sample Delivery Group (SDG) consisting of twenty (20) soil samples was received into thelaboratory information management system (LIMS) on July 2, 2002; intact and in good condition withChains of Custody (COC) Records in order, unless otherwise noted in any attachments or QualityAssurance Notices. Sample ID's reported in this data package are noted by the receiving department on theCOC if they differ from those listed by the samplers on the COC.



The cooler temperature bottle was present with samples received on July 2,2002; and sample temperaturewas 8.0 degrees Celsius.




ICP Equation:

Equation for obtaining metals sample results in mg/Kg as presented on FORM I data sheets from ICPinstrument acquired results in ug/L (ppb).


W x SWhere


Example: aluminum result ug/L to mg/Kg.48942.08 ug/L (C) x 1 (D) x 0.2 L (V)

= ll276.98 mg/Kg reported as 11300 mg/Kgl .Og(W) x 0.868(5)

Mercury Equation:


A x D .x F

B x EWhere

A = ug/L HgB = wet weight of sampleD = dilution factor to bring sample into analysis rangeE = % solids/100F = final volume in liters (0.1 L)

Example: mercury result ug/L to mg/Kg0.10 ug/L* (A) x 1 (D) x 0.1 (F)

= 0.05760 mg/Kg reported as 0.058 mg/Kg*0.2 g (B) x , 0.868 (E)


Cyanide Equation:


A x D x F

B x EWhere

A = ug/L CNB = wet weight of sampleD = dilution factor to bring sample into analysis rangeE = % solids/100F = final volume in liters (0 05 L)

Example: cyanide result ug/L to mg/Kg0.60 ug/L* (A) x 1 (D) x 0.05 L (F)

= 0.03456 mg/Kg reported as 0.035 mg/Kg*l.OOg(B) x 0.868 (E)


SAMPLE IDs.


MC0153 MC0164 MC0165 MC0166 MC0167 MC0168

MC0169 MC0170 MC0171 MC0172 MC0173 MC0174

MC0175 MC0176 MC0177 MC0178 MC0179 MC0180

MC0181 MC0182

7






The sample matrix spike, CCN = WG18576-1 (MC0153S) was found to be outside CLP control limits forantimony and thallium. The reported concentrations for these analytes are flagged with an "N" on allassociated Form 1 and on Form 5a.






The sample matrix duplicate, CCN = WG18576-2 (MC0153D) was inside CLP control limits for therequested analytes.



The adjusted sample concentrations were outside CLP control limits for calcium, chromium, andpotassium, which are flagged with an "E" on all associated Form 1, the Cover Page and Form 9.


8



Thomas R. ColeData Reviewer IIJuly 16,2002




The C (concentration) qualifiers used are;

I): This flag indicates the analyte was analyzed for but not detected. This reported value was obtained from a reading thatwas less than the Instrument Detection Limit (IDL). The IDL will be adjusted to reflect any dilution and, for soils, the

percent moisture.






M: This flag applies to GFAA analyses for concentrations greater than the Contract RequiredDetection Limit (CRDL). This flag is only used for GFAA if the analytical sample or analyticalspike duplicate injection reading is not within 20% of the Relative Standard Oeviation-(RSD).


*: This flag is used for duplicate analysis when the sample and the sample duplicate results are not .within control limits.


\V: This flag applies to GFAA analyses when the post-digestion spike (analytical spike) is out of control limits (85% -115%),while sample absorbance is less than 50% of "spike" absorbance ["spike" is defined as (absorbance or concentration ofspike sample) minus (absorbance or concentration of the sample)].


NOTE: Entering "S", "W", or "+" is mutually exclusive. No combination of these qualifiers can appear in the same field for ananalyte.

\


Method Codes:P: ICP PLASMACV: MERCURY COLD VAPOR AA 1 f)CA: MIDI-DISTILLATION SPECTROPHOTOMETRIC •*-f: FURNACE AA

united states environmental protection agency '/o · mc0069 se mc0078 se matrix spike...

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