undergraduate thesis tectono-magmatic analysis of the

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UNIVERSITY OF LOS ANDES FACULTY OF SCIENCES DEPARTMENT OF GEOSCIENCES Undergraduate thesis TECTONO-MAGMATIC ANALYSIS OF THE JUANAMBÚ CANYON, SOUTHWESTERN COLOMBIAN ANDES. SOFIA MARGARITA DELGADO BALAGUERA MAY, 2018

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Page 1: Undergraduate thesis TECTONO-MAGMATIC ANALYSIS OF THE

UNIVERSITY OF LOS ANDES

FACULTY OF SCIENCES

DEPARTMENT OF GEOSCIENCES

Undergraduate thesis

TECTONO-MAGMATIC ANALYSIS OF THE JUANAMBÚ CANYON, SOUTHWESTERN

COLOMBIAN ANDES.

SOFIA MARGARITA DELGADO BALAGUERA

MAY, 2018

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UNIVERSITY OF LOS ANDES

FACULTY OF SCIENCES

DEPARTMENT OF GEOSCIENCES

Undergraduate Thesis

Tesis de Pregrado

TECTONO-MAGMATIC ANALYSIS OF THE JUANAMBÚ CANYON, SOUTHWESTERN

COLOMBIAN ANDES.

Tesis que presenta SOFIA MARGARITA DELGADO BALAGUERA para optar al grado de Geocientífico por la

Universidad de los Andes

Fdo. Sofia Margarita Delgado Balaguera

V°B° del Director V°B° del Codirector

Yamirka Rojas-Agramonte Andrés Ignacio Rodríguez

Bogotá, 21 de Mayo de 2018

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AGRADECIMIENTOS

A mi familia que siempre está conmigo, a todas las personas que me acompañaron durante mi

estadía en la universidad y a las que permitieron el desarrollo de este proyecto de grado. Agradezco

a mis directores de tesis Yamirka Rojas-Agramonte y Andrés Ignacio Rodríguez por acompañar el

desarrollo intelectual de este estudio y por confiar en mis capacidades. Especialmente agradezco

el seguimiento y la contribución de los conocimientos de Nicolás Pérez-Consuegra y de Marco

Antonio Rodríguez Ruíz, sin los que no hubiera sido posible realizar este trabajo y por enseñarme

la importancia del método geocientífico e involucrarme con el planteamiento de preguntas de

investigación y la resolución de las mismas.

Gracias al extenso apoyo de José María Jaramillo y a GMas Lab: Laboratorio de Soluciones

Geocientíficas, por instruirme en la preparación de muestras y permitirme realizar los análisis

químicos correspondientes al proyecto. A Ivette Cucunubo, por aguantarme tantos días en el

laboratorio de la universidad y ayudarme con la elaboración de láminas delgadas.

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Abstract

This contribution integrates petrological and field relation constrains from the geological record of the

Juanambú River Canyon and provides another important record of the Late Cretaceous to Miocene tectono-

magmatic evolution of the southwestern margin of the Colombian Andes. Furthermore, the first 1:25.000

geological cartographic chart is presented within this project and it could be enhanced and used as a basis

for the territorial planning, the evaluation of natural resources and the recognition of geological risks. Two

intrusive bodies were recognized in the study area: First, a Late Oligocene to Early Miocene phaneritic-

tonalitic rock body mainly composed by plagioclase with complex zonation, variable quantities of mafic

minerals and lesser amounts of quartz. Second, a Middle to Late Miocene porphyritic intermediate to acid

rock intruding the tonalitic bodies and mainly constituted by plagioclase and quartz, and in lesser amounts

hydrated amphibole and biotite filling interstitial spaces. Granitoids are characterized by high contents of

silica 𝑆𝑖𝑂2(66 − 70 𝑤𝑡. %), with a metaluminous to slightly peraluminous composition (𝐴𝑆𝐼 = 0.96 −

1.03). The analyzed samples exhibit a calc-alkaline character and show an intermediate to acid composition,

ranging from granodiorites to granites. Tectonic classification diagrams also suggest a volcanic arc affinity

related to a subduction tectonic setting. Eastward migration of the magmatic arc has been suggested for

northern and central segments of the Colombian Andes, nevertheless, in the southern Juanambú Canyon

region the longitudinal displacement of magmatism is not recognized. The observed spatial framework in the

canyon could be related to a late migration of the magmatism over a stationed axis for southern parts of the

Colombian Andes or to a subduction edge with convex center and concave extremes geometrical

configuration which induced a less prominent slab dip to the southern segment represented by this region.

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Resumen

Esta contribución integra relaciones de campo y un análisis petrológico partiendo del registro geológico del Cañón

del Río Juanambú, el cual provee otro importante ejemplo de la evolución tectono-magmática desde el Cretácico

Tardío al Mioceno temprano a lo largo del margen sur occidental de los Andes colombianos. Además, el proyecto

presenta el primer mapa geológico a escala 1:25000 de la zona el cual puede ser mejorado y usado como base para

el planeamiento territorial, la evaluación de recursos naturales y el reconocimiento de riesgos geológicos. Dos

cuerpos de roca se diferenciaron en la zona de estudio: Primero, un cuerpo fanerítico – tonalítico de edad Oligoceno

Tardío a Mioceno temprano, principalmente compuesto por plagioclasa con zonación compleja, cantidades variables

de minerales máficos y cuarzo en menores cantidades. Segundo, un cuerpo porfirítico de intermedio a ácido con

edades de Mioceno Medio a Tardío cuya composición principal se basa en plagioclasa, cuarzo y en menor cantidad

cristales de anfíbol y biotita rellenando espacios intersticiales en la roca. Los granitoides se caracterizan por un alto

contenido de óxido de sílice 𝑆𝑖𝑂2(66 − 70 𝑤𝑡. %) con una composición metaluminosa a ligeramente peraluminosa

(𝐴𝑆𝐼 = 0.96 − 1.03). Las muestras analizadas exhiben un carácter calco-alcalino y muestran una composición

intermedia a ácida, variando desde granodiorita a granito. Los diagramas de clasificación tectónica también sugieren

afinidad de arco volcánico asociado a un ambiente de subducción para estas rocas. Hacia los segmentos central y

más al norte del área trabajada se ha sugerido una migración hacia el este del arco magmático, sin embargo, hacia

el segmento sur en el Cañón del Juanambú no se reconoce un desplazamiento longitudinal del magmatismo. Se

sugiere por tanto que el escenario magmático observado en el cañón puede estar relacionado con una migración

tardía del arco magmático a través de un eje estacionario, o a un eje de subducción con configuración convexa hacia

el centro y cóncava hacia los extremos que induce un buzamiento menos prominente de la placa hacia los bordes.

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INDEX

1. Introduction ........................................................................................................................................................... 1

2. Geological Setting .................................................................................................................................................. 4

2.1. Paleogene Magmatism in Western Colombia ..................................................................................................... 7

2.2. Miocene Magmatism in Western Colombia ....................................................................................................... 7

3. Methods and Analytical techniques ........................................................................................................................ 8

3.1. Petrography and Whole rock analyses ............................................................................................................... 8

4. Results ................................................................................................................................................................... 9

4.1. Field Relations ................................................................................................................................................. 9

4.2. Petrography................................................................................................................................................... 15

4.2.1. Porphyritic Intermediate to Acid Composition ........................................................................................... 15

4.2.2. Phaneritic Tonalite Composition ................................................................................................................ 19

4.3. Whole Rock Geochemistry .............................................................................................................................. 20

4.3.1. Major Elements ....................................................................................................................................... 20

5. Discussion ............................................................................................................................................................ 24

5.1. Magma origin ................................................................................................................................................ 24

5.2. Magmatic Evolution ....................................................................................................................................... 25

6. Conclusions .......................................................................................................................................................... 27

7. References cited ................................................................................................................................................... 30

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1. INTRODUCTION

Geological mapping is the fundamental for territorial planning, the recognition of threats related to geological

events and the modeling of economic resources. Understanding origin, distribution and dynamics of

convergent plate margins is fundamental to decode the continental orogenesis and coupling of subduction

(Jordan et al., 1983). The Paleogene-Neogene Andean geometrical configuration, coupled with its

magmatism and tectonics, are controlled predominantly by variables such as the age of the subducting plate,

the subduction angle, plates convergence rate and thermal variations in the crust (Pilger, 1984). Geological

data suggest that different segments of the western edge of the Andean Cordillera have experienced

decoupled tectonic evolution, associated with changes in these variables (Ramos, 2010; Romeauf et al., 1995)

(Fig. 2). Some subduction zones of the northern active margin in the Andean Cordillera show contrasting

models of convergence dominated by oblique, orthogonal and flat-slab subduction segments (Echeverri et

al., 2015; Taboada et al., 2000; Ramos, 2010; Villagómez and Spikings, 2013; Gutscher et al., 1999). In

Colombia, the temporal and spatial distribution of magmatism together with the sedimentary record has

been controlled by orogenic processes related to the formation of the Northern Andes (Echeverri et al.,

2015). However, the mechanisms, distribution and factors that have controlled the magmatic and orogenic

development of the Andean mountain system during the Cenozoic remain enigmatic.

The Colombian Andes register a continuous magmatic arc activity from Paleozoic to recent times, and it is

recorded in meta-igneous, volcanic and plutonic rocks exposed along the Western and Central cordilleras.

(Aspden et al., 1987; Villagómez et al., 2011). The magmatic and orogenic history of the Andes towards

southwestern Colombia during the Cenozoic has been linked to different theories (Fig. 2), from de occurrence

of a continuous orthogonal subduction of shallow angle during the Miocene (Echeverri et al., 2015) to the

collision/subduction of the submarine cordillera of Carnegie with South America (Villagómez and Spikings,

2013; Gutscher et al., 1999) and changes in the plates directions and rates of convergence (Taboada et al.,

2000; Somoza and Ghidella, 2012). In southwestern Colombia, at the Nariño department (Fig. 3), previous

works in the area identify at least two pulses of magmatism during the Cenozoic, one of them exposed as a

tonalitic intrusion during the Oligocene and other exposed by porphyritic igneous rocks of tonalitic to granitic

composition during the Miocene (Murcia and Cepeda, 1991; Leal-Mejia, 2011). Therefore, the igneous record

arising in this area suggests a continuous magmatism at least from the Late Oligocene to the Miocene related

to the subduction of the younger Nazca Plate beneath the South American plate, after the Farallon plate split

(Aspden et al., 1987; Echeverri et al., 2015).

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Subduction of shallow angle during the Miocene is proposed by Echeverri et al., (2015) as an orogenic model

for southwestern Colombia to sustain a fore-arc strong subsidence, changes in the intra-arc environment

with increasing deformation and eastern migration of the magmatic arc. On the other hand, Gutscher et al.,

(1999) inferred a continuation of the Carnegie Ridge beneath the southwestern Colombian margin according

to relative plate motions and active subsidence consistent with migration of the ridge during the Miocene.

By contrast, other authors suggested that a Neogene reorientation of convergence direction resulted in an

orthogonal subduction regime due to the break-up of the Farallon plate into the Nazca and Cocos plates that

triggers Cenozoic plutonism associated with the Nazca plate subduction (Taboada et al, 2000; Aspden et al.,

1987; Meschede and Barckhausen; 2000).

Magmatism studies in the northern and central segments of the Colombian Andes have been developed by

different authors (Aspden et al., 1987; Echeverri et al., 2015; Villagómez et al., 2011), whereas in southern

parts the lack of geological studies is evident. The Juanambú River Canyon was selected as the study area due

to its unexplored topography and the lack of geological works. The Juanambú Canyon is a morphological

depression located in southwestern Colombia, at the Nariño department (Fig.1 and 3). The river flows from

east to west until it reaches the Patía River, from which it is a tributary. Also, it actively migrating across its

flood plain and the channel extends longitudinally on the order of 80 km (Guerrero, 2014). The incised

topography of the Juanambú river allows the exposure of Cretaceous bedrocks together with the

sedimentary and magmatic record, and the recent extensive volcanic activity which has contributed to the

modeling of relief in the area (Murcia and Cepeda, 1991; Royo, 1942).

This contribution provides new cartographic, petrographic and geochemical constrains from magmatic units

exposed along of the Juanambú Canyon area. The main goals of this project are the following: To identify the

geological units which give the shape to this poorly constrained morphological depression. To recognize

timing, spatial distribution and if there is a tectonic and geochemical differentiation of the Cenozoic igneous

units. To quantify the depths and temperatures of the plutons to understand better the exhumation

mechanisms and to address the Late Paleogene to Miocene geologic and tectonic history of Southwestern

Colombia as essential part of the Northern Andes submitting it to a critical review of previously works in the

Juanambú River Canyon. Based on these results, the study aims to find a model that best suits the geological

features of the region and discuss around the dominant convergence model in this segment of Southwestern

Colombia.

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Figure 1. Google Earth Photo of the study area, Juanambú Canyon and nearly municipalities.

Figure 2. Proposed models of convergence in the Southwestern Colombian, Andean Cordillera. A) Proposed

shallow subduction for the Southwestern Colombian margin (Echeverri et al., 2015). B) Inferred positions of

Carnegie Ridge prolongation (Gutscher et al, 1999).

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2. GEOLOGICAL SETTING

Colombian Andes are made up of three main mountain ranges: The Eastern, Central and Western Cordilleras

with approximate N-S orientation and separated by the inter Andean geomorphologic depressions of the

Magdalena and Cauca-Patía Valleys (Aspden et al., 1987; Jaramillo et al., 2017; Villagómez et al., 2011). The

Central Cordillera includes autochthonous and para-autochthonous terranes constituted by Paleozoic

metamorphic basement rocks of continental and oceanic affinity intruded by numerous Mesozoic magmatic

arc products (Jaramillo et al., 2017; Villagómez et al., 2011; Villagómez and Spikings, 2013). The basement of

the Western Cordillera represents the geological record of the allochthonous oceanic terrane accreted during

the Upper Cretaceous composed by mafic, ultramafic and marine sediments intruded by several Cenozoic

magmatic pulses (Aspden et al., 1987; Villagómez et al., 2011). The Romeral fault system is interpreted as an

extinct subduction zone that separates bedrock of the Central and Western Cordilleras and it is constituted

by the Cauca-Almaguer, Silvia-Pijao and San Jerónimo faults (Murcia and Cepeda, 1991; Aspden et al., 1987;

Rodríguez and Arango, 2013; Chicangana, 2005).

The Colombian Massif is crossed by the Romeral fault system, which separates the bedrocks of the Central

and Western Cordilleras and represents the tectonic limit of the oceanic terranes accreted to the continental

margin. Towards the east of the Romeral fault is exposed a group of graphite schists, slates and quartzites

called the Metamorphic rocks of Buesaco, which has been interpreted as a remnant of the Arquia Complex

by Ruíz-Jiménez et al., 2012. These para-autochthonous complex is defined as a tectonic mélange associated

with collision/subduction processes during the Mesozoic (Rodríguez and Arango 2013; Ruíz -Jiménez et al.,

2012; Villagómez et al., 2011). In addition, the Diabásico Group emerges towards west of the Romeral fault,

constituted by units of basalts, diabases and marine sediments related to a phenomenon of accretion,

subduction and obduction of terranes in the Mesozoic (Murcia and Cepeda, 1991). The Metamorphic rocks

of Buesaco as well as the Diabásico Group are intruded by plutons and Cenozoic subvolcanic rocks and are

unconformably covered by Pliocene to Holocene deposits of volcano-clastic and sedimentary components

(Murcia and Cepeda, 1991) (Fig. 4).

Along the southwestern western margin of Colombia, different authors have reported an eastward migration

of the Paleogene-Neogene magmatic arc (Echeverri et al., 2015; Villagómez et al., 2011). Nonetheless, this

longitudinal Miocene migration remain poorly constrained at the Nariño department segment. Therefore,

the Juanambú canyon area is an important target in order to evaluate previous geological models for the

magmatic evolution of the Colombian Massif.

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Figure 3. Distribution of the Cenozoic Magmatism and Arquía Complex along the Colombian Western and Central

Cordilleras. The red box locates the study area. CC: Central Cordillera. WC: Western Cordillera. EC: Eastern Cordillera. CP:

Cauca-Patía Depression. MV: Magdalena Valley.

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Figure 4. Cartographic chart of Juanambú Canyon developed based on field relations on a 1:25.000 scale.

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2.1 Paleogene Magmatism in Western Colombia

The Paleogene magmatism in Colombia has been described as a continental arc product related to the

subduction of the Farallon plate and subsequent subduction of the younger and buoyant Nazca plate during

the Paleogene-Neogene boundary (Aspden et al., 1987; Taboada et al., 2000; Echeverri et al., 2015; Bayona

et al., 2012). Magmatic activity during the Paleogene in the Colombian Andes has been mainly assigned to

the Central Cordillera. However, evidence of plutonism has been found to a lesser extend towards the

Western Cordillera and the Cauca-Patía basin (Fig. 3). A variety of intrusive rocks crop out in the Western

Cordillera with variation from diorite to tonalite in compositions. They intrude volcano-sedimentary

sequences with Mesozoic-Cenozoic ages, whereas towards the Central mountain range the batholiths and

stocks have fluctuations in composition from granodiorites to tonalites and intruded metamorphic basement

rocks (Aspden et al., 1987; Bayona et al., 2012; Bustamante et al., 2017; Leal-Mejia., 2011). Along the

Juanambú river canyon, intrusive rocks of tonalitic composition intruding Cretaceous rocks of oceanic affinity

are exposed (Fig. 4).

2.2 Miocene Magmatism in Western Colombia

Plutonic bodies in Colombia during the Miocene are exposed along the Western Cordillera, the Cauca-Patía

depression and the Central Cordillera (Fig. 3) and are associated with the subduction of the Nazca Plate

against the South American Plate. Intrusives rocks ranging from diorites to granodiorites are located at the

Central and Western Cordilleras and are intruding the metamorphic basement and rock bodies of oceanic

affinity. In the inter-Andean valley, hypabyssal bodies of diorite and quartz-diorite composition are exposed,

cutting rocks with oceanic affinity (Aspden et al., 1987; Leal-Mejia, 2011). Along the Juanambú river canyon

sub-volcanic and intrusive rocks intrude both the Metamorphic rocks of Buesaco and the Cretaceous rocks

of the Diabásico Group (Fig. 4). Particularly, this magmatism is ascribed to the occidental oceanic

metallogenetic province of Colombia (Salinas et al., 1999) and it is extensively associated with the formation

of important ore deposits along the western margin of the country which are subject of exploration and

mining.

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3. METHODOLOGY AND ANALYTICAL TECHNIQUES

Field work was executed during 12 days in the Juanambú River Canyon. This study presents the first

approximation to the geological cartography of the region in 1:25000 scale (Fig. 4) taking into account field

observations and the “Mapa geológico de la Plancha 410-La Unión” in 1:100.000 scale (Murcia and Cepeda,

1991). Digitalization of the map was carried out in ArcGIS® for desktop. Several samples were taken during

the field trip; however, ten samples were carefully chosen to perform petrological analyses. Despite of having

the aim to develop EPMA analysis and determine the P-T conditions for two of the selected samples, the

results were not obtained for the final deadline of this project. Table 1 shows the analysis carried out for each

of the samples selected during the study.

3.1 Petrography and Whole rock geochemistry

Seven samples from de Juanambú Canyon intrusive and porphyritic bodies were selected for petrographic

description and four were selected for whole-rock geochemistry. For each petrographic analysis, counting of

300 points in 10X optical microscope magnification was executed at Los Andes University (Colombia) to

determine the modal abundance of minerals. Powdered whole-rock samples were obtained by grinding the

rock in an Agatha mill, major elements were determined by the glass beads method using the proportion of

1 g of powder sample diluted in 7 g of lithium borate (𝐿𝑖2𝐵4𝑂7) with a Bruker S4 Explorer X-ray spectrometer

by X-ray fluorescence (XRF) at the “GMas Lab: Laboratorio de Soluciones Geocientíficas” in Bogotá, Colombia.

The results were obtained as weight percentages of oxides or elements, with an uncertainty of ± 0,02%.

Sample ID N W Petrography XRF

Juanam-3 1,443031 -77,173781 X

Juanam-4 1,448889 -77,182781 X X

Juanam-6 1,442414 -77,173250 X

Juanam-7 1,433050 -77,147439 X X

Juanam-8 1,433050 -77,147439 X X

Juanam-10 1,445150 -77,145269 X

Juanam-12 1,442550 -77,138911 X

Juanam18-24 1,448730 -77,183420 X

Juanam18-30 1,442530 -77138920 X

Juanam18-33 1,455490 -77,148250 X

Table 1. Analyses carried out for each sample and their respective location.

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1. RESULTS

4.1 Field Relations

Field word was carried out in the Colombian Massif along the Juanambú River Canyon from N1° 25’ to N1°29’

in the Nariño department (Fig. 3 and 4). Wandering along the Canyon allow to reconstruct a geological history

of the units which compose this depression. Basement, volcanic and plutonic units exposed in the region are

mostly deformed showing the tectonic control related to the high-strain zone and the prominent strike-slip

component of the Romeral Fault System. A schematic and generalize reconstruction of field relations and

evidence photos are presented within the study area (Fig. 4.1 to 4.6).

The history is presented starting from the oldest geological unit to the youngest one identified: The geological

units include from the east green and black schists, quartzites and rocks with gneiss texture. This unit is

named the Buesaco Metamorphic rocks (Murcia and Cepeda, 1990) (Fig. 4.1). Towards the west of the unit,

increasing of the deformation and the presence of secondary folds in the schists were observed suggesting

an approach to a fault zone (Fig. 4.1). Some authors attribute a Cambrian-Ordovician age to these rocks

(Murcia and Cepeda, 1991). However, Rodríguez and Arango (2013) presents this unit as part of the Arquía

Complex which is geologically associated to metamorphic rocks with both sedimentary and igneous basic

protoliths and is limited to the east by the Silvia-Pijao Fault and to the west by the Cauca-Almaguer Fault

(Ruíz-Jiménez et al., 2012).

The Metamorphic rocks of Buesaco are found in fault contact with sheared and metamorphized diabases and

basalts of the cretaceous Diabásico Group (Fig. 4.2). Additionally, in some areas this unit presents

interbedded with grey claystones. The Cretaceous rocks in the Juanambú Canyon were interpreted as part of

the allochthonous Calima terrane, product of the Caribbean Large Igneous Province juxtaposed to South

America during late Cretaceous times (Restrepo and Toussaint, 1996; Kerr et al., 1997).

The para-autochthonous Arquía Terrane and the cretaceous Diabásico Group allochthonous terrane are

intruded by plutonic holocrystalline, phaneritic and fine to medium-grained stocks of tonalitic composition,

some outcrops present several groups of joints and are highly altered and weathered. The plutonic rocks

exhibit mafic enclaves supporting they are intruding the Diabásico Group (Fig. 4.3). Furthermore, towards

the regions of El Tambo and La Llanada, near the study area, similar intrusive rocks dated by the whole rock

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K/Ar method yielded an age of 26.3 ± 1.8 Ma (De Souza et al., 1984) and by zircon U/Pb an age of 23.4 ± 0.5

Ma (Leal-Mejía, 2011), confirming the Late Oligocene-Early Miocene intrusion of these stocks.

The Buesaco Metamorphic rocks, the Diabásico Group and the tonalitic igneous bodies are intruded at the

same time by hypabyssal, holocrystalline and porphyritic stocks ranging from diorite to granodiorite

compositions. Hypabyssal rocks present several groups of joints and in some cases, are highly altered. Also,

in these porphyritic bodies, mafic enclaves are observed and particularly an enclave exhibit a contact

between the tonalitic intrusive unit and the black schist (Fig. 4.4), which shows that the intrusion of the

hypabyssal rocks occurs after the emplacement of the Cretaceous rocks and after the intrusion of the plutonic

tonalitic stocks. In addition, some radiometric dates of similar bodies near this area were reported by K/Ar

method yielded ages of 13 ± 3 Ma (Álvarez and Linares, 1979) and 9.9 ± 0.8 Ma (Leal-Mejía, 2011).

The magmatic record during the Late to Middle Miocene is the previous episode from the Late Neogene to

Quaternary extensive volcanic activity associated to different eruptive sources as the Galeras, Doña Juana,

Morasurco, Ánimas and Bordoncillo volcanoes (Pardo et al., 2018; Murcia and Cepeda, 1991). The

metamorphic basement and the igneous plutonic rocks are unconformably covered by deposits related to

volcanic activity and sedimentation processes (Fig. 4.5 and 4.6). In the region, diluted and concentrated

pyroclastic density current deposits interbedded with debris avalanches and lahars were differentiated

considering previous descriptions of Murcia and Cepeda (1991) and tuff occurrences as El Gigante Tuff

Formation near the Animas Volcano mentioned by Pardo et al., (2018). Lastly, alluvial deposits of interbedded

polymictic conglomerate with claystones and epiclastic deposits associated to erosion and re-working of

some of the volcanoclastic units were found (Murcia and Cepeda, 1991).

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Figure 5.1 Field reconstruction of the Juanambú Canyon geological sequence. Cretaceous Stage.

Figure 5.2 Field reconstruction of the Juanambú Canyon geological sequence. Cretaceous terranes accretion.

*(Jaramillo et al., 2017).

Thrust Fault*

7 km

7 km

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Figure 5.3 Field reconstruction of the Juanambú Canyon geological sequence. Early Magmatic Stage.

Figure 5.4 Field reconstruction of the Juanambú Canyon geological sequence. Late Magmatic Stage.

7 km

7 km

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Figure 5.5 Field reconstruction of the Juanambú Canyon geological sequence. Deposition, erosion and uplift (?).

7 km

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Figure 5.6 Field reconstruction of the Juanambú Canyon geological sequence. River Incision Stage.

Terrace Deposits

7 km

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4.2 Petrography

4.2.1 Porphyritic Intermediate to Acid Rocks

Description is based on several samples, showing variations in modal compositions from diorite to

granodiorite (Table 2). These inequigranular rocks intrude the Metamorphic rocks of Buesaco and the

Diabásico group and are in contact with intrusive rocks of tonalitic composition. The crystals size varies from

few millimeters to 1 centimeter and the main composition consists on plagioclase, hornblende and variable

presence of biotite, pyroxenes and quartz embedded in an aphanitic and holocrystalline matrix that

predominates over phenocrysts in most samples, in order of 40% to 60% (Table 2). The main components of

the matrix are plagioclase and in few quantities quartz. In numerous specimens a slight alignment of biotite

and amphibole (Fig. 7-E) is observed indicating the possible structural control of regional faults.

Sample ID Classification Pl Qtz Kfs Amp Bt Px Matrix

Juanam-3 Diorite 29 -- 2 10 7 1 51

Juanam-4 Granodiorite 19 12 3 16 -- -- 50

Juanam-6 Quartz-diorite 24 6 1 12 2 1 54

Juanam-7 Quartz-diorite 28 7 -- 12 12 -- 41

Juanam-8 Quartz-diorite 33 5 -- 11 8 -- 43

Juanam-10 Diorite 22 -- 2 15 -- 3 58

Table 2. Modal composition (volume %) of porphyritic samples analyzed under petrographic microscopy.

Plagioclase

Crystals vary from idiomorphic to sub-idiomorphic and in several samples, present a prismatic habit.

Inclusions of amphibole, pyroxene and biotite are common, polysynthetic twinning is observed and some

periclinal twins can be distinguish. The zoning of the plagioclases is normal and, in some cases, appear

convolute or oscillatory (Fig. 6-B and 7-C). Possible hydrothermal alteration is exhibit as sericite (Fig. 7-F),

oxides and in lesser amounts as potassic feldspar, filling interstitial spaces and veins (Fig. 7-B).

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Amphibole

Idiomorphic to sub-idiomorphic phenocrystals of green amphibole disseminated in the matrix, as inclusions

in plagioclases (Fig. 7-A) and in some cases altered to biotite. Crystals habit is generally tabular or prismatic.

Hornblende crystals show partially pyroxene core replacement (Fig. 6-C). Grains present highly pleochroism,

simple twinning is observed, and zonation is not very common.

Quartz

Two samples are depleted in quartz, it appears as euhedral (Fig. 6-D) to anhedral crystals of low modal

percentage integrated in the matrix. Monocrystalline sub-idiomorphic to xenomorphic phenocrysts with

rounded faces and right-angle extinction are observed and, in some sections, polycrystalline quartz

aggregates (Fig. 6-E) with inter-granular suture contacts and wavy extinction are presented as product of a

possible deformational event.

Biotite

Idiomorphic to sub-idiomorphic primary phenocrysts disseminated in the matrix with tabular elongated

habit, high birefringence colors and medium pleochroism. Secondary biotite (Fig. 6-A) is observed in some

samples as anhedral smaller grain crystals surrounding plagioclase, replacing amphibole borders or following

a slight alignment along the matrix, and is accompanied by sericite, calcite and potassic feldspar.

Pyroxene

Xenomorphic crystals of small size disseminated in the matrix (Fig. 6-F), as inclusions within plagioclase or

replacing amphibole cores (Fig. 7-D), crystals present parallel extinction, lower pleochroism and in some

cases a prismatic habit with cleavage lines perpendicular to elongated axis.

Opaque minerals

In thin section is possible to differentiate magnetite and hematite crystals disseminated in the sample and as

exsolution in biotite.

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Figure 6. A) Primary and secondary biotite (Juanam-7). B) Convolute and normal zonation in plagioclases (Juanam-7). C) Plagioclase-

amphibole-biotite intergrowth and pyroxene trapped in an amphibole core as a clot texture (Juanam-7). D) Quartz phenocryst and minerals

of the porphyritic composition (Juanam-7). E) Plagioclase altered to sericite and polycrystalline quartz aggregates (Juanam-6). F) Euhedral

amphiboles and pyroxenes suspended in the matrix (Juanam-10). Pl: Plagioclase. Amp: Amphibole. Qz: Quartz. Px: Pyroxene. Bt1: 1ry

Biotite. Bt2: Secondary Biotite. Ser: Sericite. Cal: Calcite.

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Figure 7. A) Amphibole inclusion on plagioclase (Juanam-3). B) Hydrothermal alteration to potassic feldspar and biotite

(Juanam-3). C) Convolute zonation in plagioclase and mafic minerals aligned (Juanam-6). D) Pyroxene trapped in amphibole

core with sericite alteration (Juanam-6). E) Aligned amphibole and biotite surrounding plagioclase (Juanam-8). F) Seritization

and polysynthetic twin in plagioclase, opaque mineral (Juanam-10). Pl: Plagioclase. Amp: Amphibole. Qz: Quartz. Px: Pyroxene. Bt1:

1ry Biotite. Bt2: Secondary Biotite. Ser: Sericite. Cal: Calcite.

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4.2.2 Phaneritic Tonalite Composition

Description is based on sample Juanam-12, the rock was classified as a tonalite following the QAPF

Streckeisen diagram for plutonic rocks. These equigranular rocks intrude Cretaceous rocks of oceanic affinity

belonging to the Diabásico group and basement rocks and are in contact with porphyritic rocks of

intermediate to felsic character. The crystals size varies from few millimeters to 1 centimeter and its main

composition consists on plagioclase and quartz (Fig. 8-B). The rock is holocrystalline and shows a phaneritic

and fine to medium-grained textures. This sample is mainly rich in mafic accessory minerals as biotite and

hornblende and hydrothermal alteration is mainly presented as sericite and secondary biotite. An enclave

mainly composed of amphibole with partially sericitization is observed in this sample (Fig. 8-D).

Sample ID Classification Plagioclase K-Feldspar Quartz Amphibole Biotite

Juanam-12 Tonalite 44,2 3,1 35,3 8,9 8,5

Table 3. Modal composition (volume %) of tonalitic sample analyzed under petrographic microscopy.

Plagioclase

Crystals are idiomorphic to sub-idiomorphic and the habit is short prismatic. The zoning of the plagioclases is

normal and, in some cases, appears convolute. The twinning is in the albite law and polysynthetic twins are

presented too. Phenocrysts are surrounded by fine grained amphiboles and biotite (Fig. 8-A). Inclusions of

mafic minerals are observed, and, in some cases, inclusions show alignment.

Amphibole

Xenomorphic to sub-idiomorphic crystals of green amphibole as inclusions or surrounding plagioclases and

in some cases altered to biotite. Crystals habit is generally tabular or prismatic. Zoning and twinning cannot

be distinguished in this samples because of the grain size. In some cases, amphibole may be altered to

secondary biotite. Mafic enclave is mainly composed of sub-idiomorphic, prismatic, olive-green and high

pleochroic amphiboles.

Quartz

Sample shows xenomorphic crystals and the modal abundance remains lower than plagioclase.

Polycrystalline quartz is observed with inter-granular suture contacts and wavy extinction.

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Biotite

Xenomorphic to sub-idiomorphic primary phenocrysts surrounding and as inclusions (Fig. 8-C) in plagioclase

is presented with tabular elongated habit, fine grain-size and medium pleochroism. In some cases, secondary

biotite is replacing amphibole or following inclusions alignment.

Opaque minerals

In thin section is possible to differentiate magnetite and hematite crystals disseminated in the sample and as

exsolution in biotite.

Figure 8. A) Plagioclase zonation and surrounded by amphibole and biotite (Juanam-12). B) Mainly minerals of the tonalitic composition

facies (Juanam-12). C) Aligned inclusions of amphibole and biotite in plagioclase (Juanam-12). D) Mafic enclave showing sericitization

(Juanam-12). Pl: Plagioclase. Amp: Amphibole. Qz: Quartz. Px: Pyroxene. Bt1: 1ry Biotite. Bt2: Secondary Biotite. Ser: Sericite. Cal: Calcite.

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4.3 Whole rock geochemistry

4.3.1 Major Elements

Both the porphyritic and the phaneritic rocks show similar major element geochemistry, samples evidence a

sub-alkaline acid composition and are characterized by high contents of 𝑆𝑖𝑂2 showing variations from 66 −

70 𝑤𝑡. % (calculated at 100% anhydrous basis). The phaneritic sample presents the highest percentage of

silica oxide. With respect to representative chemical values of acid rocks, samples show in general high

contents of 𝑇𝑖𝑂2 (0.247 − 0.399 𝑤𝑡. %), 𝐹𝑒𝑂 (2.28 − 3.73 𝑤𝑡. %), 𝑀𝑔𝑂 (1.35 − 1.92 𝑤𝑡. %) and

𝐶𝑎𝑂 (3.47 − 4.89 𝑤𝑡. %). Rocks present relatively low contents of 𝑀𝑛𝑂 (0.031 − 0.068 𝑤𝑡. %), and

standard contents of 𝐴𝑙2𝑂3 (15,27 − 16,89 𝑤𝑡. %), 𝐾2𝑂 (1.31 − 2.26 𝑤𝑡. %) and 𝑁𝑎2𝑂 (2.73 −

4.66 𝑤𝑡. %) (Table 4). All samples of the porphyritic rocks plot in the total alkalis classification diagram for

plutonic rocks as quartz-diorites/granodiorites and sample of the intrusive phaneritic rock classify as granite

(Fig. 9-A).

Discrimination diagram based on 𝐾2𝑂 and 𝑆𝑖𝑂2 contents plot all the samples in the calc-alkaline field (Fig.

9-B) and this nature is confirmed by the AFM diagram (Fig. 9-D). In the Alumina Saturation Index diagram,

the rocks exhibit values of Alkalinity Index from 𝐴/𝑁𝐾 = 1.6 − 2.3 and Alumina Index from 𝐴/𝐶𝑁𝐾 =

0.96 − 1.03, plotting in metaluminous field except one that reaches the peraluminous space. Sample from

phaneritic acid rock body indicates a peraluminous magma, however, samples from both bodies remain very

close to the metaluminous/peraluminous boundary (Fig. 9-C).

The 𝑅1 vs 𝑅2 show two samples of the porphyritic acid rocks and the phaneritic tonalite rock body plotting

into the Pre-Collision field, conversely, one sample of the hypabyssal rocks falls in the Mantle Fractionates

field and two more of the same nature plot in the Mantle Fractionates – Pre-Collision limit (Fig. 9-E). Leal-

Mejía (2011) defined some intrusive rocks with similar mineral assemblages and geochemical features from

Arboleda and La Llanada municipalities, near the study area, as diorites and quartz-diorites of medium-K calc-

alkaline character and metaluminous affinity related to Pre-plate Collision and Post-Collision uplift tectonic

settings.

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Figure 9. Diagrams of geochemical classification and discrimination of the samples collected from de Juanambú Canyon igneous

rocks. A) Chemical classification and nomenclature of plutonic rocks based on total alkalis versus silica (TAS) diagram (Cox et al.,

1979). B) K2O versus silica diagram for subdivision of subalkalic rocks (Peccerillo & Taylor, 1976). C) Alumina saturation index

diagram for plutonic rocks (Shand 1943). D) AFM plot (Irvine and Baragar, 1971) for the intrusive rocks of the Juanambú Canyon. E)

R1 vs. R2 geotectonic plot (Batchelor and Bowden, 1985) for the intrusive rocks of the Juanambú Canyon.

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Figure 10. Discrimination trace diagrams of samples collected in this study. F) Sr-Y plotted against Y diagram (Defant & Drummond, 1990).

G) Rb plotted against SiO2 diagram (Pearce, Harris, & Tindle, 1984). VAG: Volcanic Arc Granites. syn-COL G: Syn-Collision granites.

Sample Juanam-4 Juanam-7 Juanam-10 Juanam18-24 Juanam18-30 Juanam18-33

𝑆𝑖𝑂2 68,908 65,676 68,744 67,927 69,025 66,947

𝑇𝑖𝑂2 0,342 0,327 0,342 0,399 0,247 0,285

𝐴𝑙2𝑂3 15,273 16,575 15,665 15,639 15,907 16,899

𝐹𝑒𝑂 3,209 3,731 3,151 3,704 2,276 2,868

𝑀𝑛𝑂 0,055 0,068 0,051 0,057 0,034 0,031

𝑀𝑔𝑂 1,487 1,92 1,349 1,746 1,79 1,696

𝐶𝑎𝑂 4,078 3,984 4,105 4,515 3,467 4,893

𝑁𝑎2𝑂 3,971 4,438 3,672 2,731 4,601 4,113

𝐾2𝑂 1,795 1,977 2,111 2,263 1,729 1,307

𝑃2𝑂5 0,149 0,18 0,159 0,167 0,092 0,134

Total 96,058 95,145 96,198 95,444 96,892 96,305

Ba 2095,9 3660,1 1852,6 2076,2 2517,5 2684,5

Cr 23,7 46,7 21,3 39,4 48,7 35

Cu 68 52 60,3 105,9 95,6 118,2

Ni 21,8 40,5 23 22,1 47,4 38,2

Pb 0 51,1 0 0 0 41,2

Rb 508,3 615,3 135,4 1183,2 1076,1 0

Sr 809,4 2350,3 500,8 565,1 1720,8 1924,4

Zn 85,6 95,9 209,6 237,8 108,9 66,2

Zr 157,9 157,6 159,1 160,4 160,4 157,9

Y 0 27,2 33,7 21,7 0 0

Table 4. Major and some trace elements compositions of the Juanambú Canyon samples rock (wt. %).

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Discrimination diagram based on 𝑆𝑟 and 𝑌 contents plot two of the samples in the normal arc magmas field

and one of them plotted outside the classification realms (Fig. 10-F), nevertheless, three of the samples lack

of 𝑌 contents and did not achieve in this plot. On the other hand, the 𝑅𝑏 against 𝑆𝑖𝑂2 diagram yielded two

of the samples in the syn-Collision granite field and one on the Volcanic Arc - Collision granites boundary.

Three of the samples did not achieve in this plot due to both the lack of 𝑅𝑏 and the high contents of this

element which yielded outside the diagram.

5. Discussion

5.1 Magma Origin

Petrographic features observed in several samples as the presence of secondary or late-stage

hydrated minerals such as biotite and hornblende amphibole filling interstitial spaces and the variety

of zonation-types presented by the plagioclases are commonly found in the products associated to

the formation of Cordilleran-type batholiths (Castro et al., 2010). A temperature of more than 1000°C

is necessary to reach an equilibrium between hydrated phases, thus, the presence of water-rich

components suggest an input of water supplied which allows to satisfy the undersaturated content

of the granodiorite and tonalitic magmas composition (Castro et al., 2010). In addition, there is a

geological consensus about the calc-alkaline character of granitoids associated to destructive plate

margins and the origin of Cordilleran batholiths (Sheth, Torres-Alvarado & Verma, 2010; Frost et al.,

2001). Intrusive pulses found in the Juanambú Canyon are the result of magmatic assimilation

processes with volcanic arc affinity in a subduction-related tectonic setting indicated in the Pre-

Collision field diagram. On the other hand, the continent-oceanic collision regime and the contents

of rubidium in the rocks allow to determine and indicate the temporal relations of the magmatic

pulses with the major deformation event. The collisional granitoid rpaleegime indicates at least a syn-

or a post-collision magmatism related to the Farallon and succeeding Nazca Plate subductions.

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5.2 Magmatic Evolution

Information of the geological constitution of the Juanambú Canyon was presented in this project as the first

detailed cartography in 1:25.000 scale supported by previous maps and field relations determined in the

morphological depression. The geological constraints allow to recognize the canyon as an important target

to develop studies and go deeper into the tectono-magmatic evolution and the dominant styles of subduction

in the northwestern margin of South America. The black schists can be identified as the oldest geological unit

in the area and are interpreted as part of the Late Cretaceous para-autochthonous Arquía Complex (Ruíz-

Jiménez et al., 2012; Rodríguez & Arango, 2013). Towards the west, meta-igneous and meta-sedimentary

rocks of oceanic character are exposed, which according to the literature and previous studies in the Western

Cordillera, belong to the Cretaceous allochthonous Diabásico Group (Murcia & Cepeda, 1991; McCourt et al.,

1984; Marriner & Millward., 1984). Schists show an increasing deformation to the west and previous reports

account for a fault contact between the Diabásico group and the Buesaco Metamorphic rocks (Murcia &

Cepeda, 1991; McCourt et al., 1984; Aspden et al., 1987).

Two subduction zone-related intrusive bodies were identified in the area: First, a tonalitic body which intrude

both components of the basement. Furthermore, the influence of the strike slip component of the Romeral

Fault System in the region could worked as a road to transfer silicic melts to low crustal levels. Previous

studies around the area established Late Oligocene – Early Miocene ages for similar rocks (De Souza et al.,

1984; Leal-Mejía, 2011). Therefore, this pulse is related to a magmatic peak from the subduction of the

Farallon plate and its coeval rupture during the same period (Echeverri et al., 2015). Second, a more dioritic-

granodioritic pulse rises cutting the cretaceous basement and the ancient tonalitic pulse. This intrusive

trapped highly deformed xenolith, as well as enclaves founded in the tonalitic pulse. Particularly, an enclave

which exhibited a contact between the tonalitic intrusive unit and the black schists shows that the intrusion

of the hypabyssal rocks occurs after the emplacement of the Cretaceous basement rocks and after the

intrusion of the plutonic tonalitic stocks. On the other hand, Middle to Late Miocene ages have been

attributed to similar bodies near this area (Álvarez and Linares, 1979; Leal-Mejía, 2011). Thus, the second

magmatic pulse could be part of the magmatic peak emplaced along the Cauca-Patía Valley and the Central

Cordillera due to the youngest Nazca Plate subduction after the Farallon plate break-up (Echeverri et al.,

2015).

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An exhumation event in the study area was recognized based on the unconformity presented between the

Late-Miocene intrusive rocks and the Quaternary deposits along the Juanambú Canyon. The depth of the

intrusive bodies could be used as a proxy to determine if an exhumation pulse was developed after the Late

Oligocene – Early Miocene intrusion. The P-T emplacement conditions of the rocks were not calculated but

the research question related to an exhumation event remains open and mineral analyses must be

developed.

By means of the spatial distribution, Echeverri et al., (2015) proposed an almost 40 km eastward migration

of the Miocene magmatism in southwestern Colombia. The migration was conceived after the weakening of

the dominant oblique-type subduction beneath southwestern Colombian margin in most of the Oligocene,

which was triggered by the rupture of the Farallon plate and results in the beginning of an orthogonal

subduction type and the subsequent shallowing of the subduction angle during the Miocene, which allow the

eastward displacement of the magmatism. Nevertheless, this work reveals that at least in the Juanambú

Canyon area the eastward migration of the magmatism is poorly constraint, on the basis of spatial

observations where the ancient pulse is intruded by the youngest one. Therefore, the shallowing subduction

model proposed by Echeverri et al., (2015) for southwestern segment of the Colombian margin should be

reevaluated at least in the Juanambú Canyon and other southern segments where a magmatic arc migration

is not presented or is delayed.

On the other hand, the inferred continuation of the Carnegie Ridge proposed by Gutscher et al., (1999) and

the time of influence are widely discussed. The collision and the exhumation rates clouted by the Carnegie

ridge range from 1 to 15 Ma (Shumway, 1954; Villagómez et al., 2011) and in the southwestern margin of

Colombia this model is coupled with relative plate motions and active subsidence consistent with migration

of the ridge during the Miocene (Gutscher et al., 1999). Nevertheless, the geochemical signature of the

magmatic response which has been associated to this aseismic ridge subduction (Bourdon et al., 2003) is not

consistent with those determined for the Juanambú Canyon rocks (Normal Volcanic Arc). Hence more

geochemical studies must be done in order to determine if this southwestern segment of Colombia was

influenced by the collision of the Carnegie Ridge.

However, Echeverri et al. (2015) report in the geological map that at southern parts of its studied segment

and moreover from this work there are some poorly identified Oligocene and Miocene magmatic pulses.

These bodies do not show a longitudinal migration as well. Consequently, another scenario should be

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evaluated where the eastward migration is not orthogonal but is over a stationed axis and the Juanambú

intrusive rocks and southern ones where emplaced on this axis. This idea could explain the absence of

migration at the south of Colombia. Another idea which could explain the stationary magmatism during the

Miocene is likely to be a geodynamical model proposed by Schellart (2017), where the mantle or the plate

subduction in a range of at least 200 Ma induces a shallowing in the subduction angle taking in consideration

a convex center in the subducted slab and a concave configuration away from it (Fig. 11). The further

geometrical configuration of the slab allows a pronounced shallowing to the center and a less pronounced

slab dip to the end of the edge as in the case of the study segment. In the Juanambú segment the subduction

of the Nazca Plate started at Late Oligocene – Early Miocene times suggesting an earlier phase of the

proposed model. Migration in northern parts of the segment could be earlier than at southern parts of the

Colombian margin. Nevertheless, both ideas stablished above must be better sustained by means of more

field, petrological, geophysical and geodynamical constraints.

6. Conclusions

The geological cartographic chart presented in this project is the first developed in 1:25.000 scale at the

Juanambú River Canyon and it could be enhanced and used as a fundamental basis for the territorial planning,

the evaluation of natural resources and the recognition of geological threats. The identified units at this

segment are another important record of the Late-Cretaceous to Miocene evolution of the Northern Andes.

The intrusive bodies found in the canyon are volcanic arc products associated with a subduction tectonic

setting. Two pulses were identified: First, a tonalitic pulse of Late Oligocene to Early Miocene age associated

to a magmatic peak coeval with the Farallon Plate split. Second, a diorite to granodiorite pulse which intrudes

the previous one during Middle to Late Miocene and is related to another magmatic peak product of the

Nazca orthogonal subduction. In northern segments of the Colombian Andes has been identify a 40-km

eastward migration of the Paleogene-Neogene arc magmatism, whereas in the study region these magmatic

peaks are superimposed. Consequently, in southern segments of the Colombian Andes the Miocene

evolution of the subduction zone must be revaluated. The unconformity observed between the Late-Miocene

intrusive rocks and the Quaternary deposits allow to recognize at least an exhumation event in the study

area which coincides with the Miocene exhumation of the southern Colombian Andes segment. Depths and

temperatures of the plutons were not calculated due to the lack of time to develop the EPMA analyses. The

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geological features of the Juanambú Canyon allow to determine that the subduction model which best suits

the Late-Paleogene to Neogene tectonic history of southwestern Colombian Andes is the one proposed by

Echeverri et al., (2015), moreover, in southern segments the model must be revaluated to justify the

distribution of the intrusive bodies and the superimposed magmatic peaks.

Figure 11. Geometrical configuration edge evolution for the South American margin since Jurassic Times

proposed by Schellart (2017).

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7. References

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Mesozoic and Cenozoic plutonic history of Western Colombia. Journal of the Geological Society, 144(6), 893-905.

Batchelor, R. A., & Bowden, P. (1985). Petrogenetic interpretation of granitoid rock series using multicationic

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Bayona, G., Cardona, A., Jaramillo, C., Mora, A., Montes, C., Valencia, V. & Ibañez-Mejia, M. (2012). Early

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convergence. Earth and Planetary Science Letters, 331, 97-111.

Bourdon, E., Eissen, J. P., Gutscher, M. A., Monzier, M., Hall, M. L., & Cotten, J. (2003). Magmatic response to early

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Bustamante, C., Cardona, A., Archanjo, C. J., Bayona, G., Lara, M., & Valencia, V. (2017). Geochemistry and isotopic

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Castro, A., Gerya, T., García-Casco, A., Fernández, C., Díaz-Alvarado, J., Moreno-Ventas, I., & Löw, I. (2010). Melting

relations of MORB–sediment mélanges in underplated mantle wedge plumes; implications for the origin of

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Chicangana, G. (2005). The Romeral fault system: a shear and deformed extinct subduction zone between oceanic

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Cox, K. G., Bell, J. D., and Pankhurst, J. 1979. The interpretation of igneous rocks. William Clowes, London,

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De Souza, H. A., Espinosa, A., & Delaloye, M. (1984). K-Ar ages of basic rocks in the Patia Valley, Southwest

Colombia. Tectonophysics, 107(1-2), 135-145.

Defant, M. J., & Drummond, M. S. (1990). Derivation of some modern arc magmas by melting of young subducted

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Echeverri, S., Cardona, A., Pardo, A., Monsalve, G., Valencia, V. A., Borrero, C., Rosero, S., & López, S. (2015).

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Miocene orogeny in the Northern Andes. Terra Nova, 27(5), 356363.

Frost, B. R., Barnes, C. G., Collins, W. J., Arculus, R. J., Ellis, D. J., & Frost, C. D. (2001). A geochemical classification

for granitic rocks. Journal of petrology, 42(11), 2033-2048.

Guerrero, V. (2014). Caracterización Geográfica del Cañón del Río Juanambú. Tesis de Grado. Facultad de Ciencias

Humanas. Departamento de Geografía. Universidad de Nariño, Colombia.

Gutscher, M. A., Malavieille, J., Lallemand, S., & Collot, J. Y. (1999). Tectonic segmentation of the North Andean

margin: impact of the Carnegie Ridge collision. Earth and Planetary Science Letters, 168(3-4), 255-270.

Irvine, T. N., & Baragar, W. (1971). A guide to the chemical classification of the common volcanic rocks. Canadian

journal of earth sciences, 8(5), 523-548.

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