tuyen chon bai tap luyen thi dai hoc hoa hoc

7/26/2019 Tuyen Chon Bai Tap Luyen Thi Dai Hoc Hoa Hoc

1/74

Thanh Tng_ sv HKHTN-HQGHN_ luyn thi i hc ho hc_ nm !""-!". Mithc mc v bi xin lin h st 098.555.6536hoc e-mail [email protected]

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Chu-n / b1i t2 lu-4n thi /i hc n7m hc 0:0.#g; &? Thanh Tng =Akhoa hoB 'HKHT#:'H%H#


2/74


#huy:n ; !"< #=u to nguy:n t> v? @Ang h thBng tuCn ho?n

!D 1i t2 tF lu2n

Bi1: Vit c!" h#nh e c$a %&'e( %)*" ( +,B ( %*a ( 1&/ ( 'e%0( 'e+0 ( *"%0( B-. 2c 3nh v3 t4 c$a ch5n6 ton6 b7n6h th8n6 t"9n hon ." t4nh ch!t ho2 hc c t;n6 c$a 'e( *"( *a( /( B%( v vit


3/74


6"Fn t c$a mQt n6"Fn t8 cA tTn6 s8 h?t c= b7n l ]%( ton6 A s8 h?t man6 in nhi" h=n s8 h?t RhUn6man6 in la %% . 2c 3nh s8 hi" n6"Fn t ( s8 Rh8i v tn n6"Fn t8 . Vit c!" h#nh e c$a n6"Fn t vc2c ion t?o thnh tX .Vit c2c tH c$a M ton6 b7n6 JKKJ v cho bit M l n6"Fn t8 no ton6 c2c n6"Fn t8 sa" SF: ,P%P*,P

%,Mn( ,P%&'e( ,P%\*oBi 1,: [J Rh8i B %+^KTn6 s8 h?t < v n (e ton6 hai n6"Fn t Rim lo?i D( B l 1P%. Kon6 A tTn6 s8 h?t man6 in nhi" h=n s8 h?t

RhUn6 man6 in l P%. /8 h?t man6 in c$a n6"Fn t B nhi" h=n n6"Fn t D l 1%. 2c 3nh % Rim lo?i D(B Bit 11a ( 1%M6 ( %*a ( +n ( %&'eBi 1&: J`< ch!t t?o bWi hai n6"Fn t8 D( B cA Rh8i l;`n6 c M a@bton6 A @ chim &(&&\k v Rh8i l;`n6. Kon6h?t nhSn n6"Fn t M cA n L < 0 P( ton6 h?t nhSn n6"Fn t @ cA n ( L


4/74


*S" P:MQt n6"Fn t c$a n6"Fn t8 cA tTn6 s8 h?t tH tn6 O9n tX t2i san6


5/74


D. Ds. B. /. *. .p G. d.*S" 1]: 6"Fn t c$a n6"Fn t8 cA c!" h#nh electon l< n6oi cCn6 l ns%nc Q


6/74


%. [*-%]^ *ho OIF c2c ch!t: NJ( *a[N +^%( /N+( aJ/NP( a%/N+( %/NP. /8 ch!t ton6 OIF t?o thnhRt t$a Rhi n6 vi O"n6 O3ch Ba*l%l

D. P B. & *. + G. %+. [J B-%]^ *ho OIF c2c ch!t: Dl[/N P^%.1%J%N( *%J,NJ( *1%J%%N11[saccaoz=^( *J+*NNJ( *a[NJ^%*J+*NNJP. /8 ch!t in li l

D. + B. P *. , G. %P. [J B-%]^ KQn 1ml O"n6 O3ch cA a h|n h`< 6Ym a %*N+1(,M v J*N+1M. hZ tX tX tXn6 6it cho nht %ml O"n6 O3ch J*l 1M vo 1ml O"n6 O3ch ( sinh a V lit Rh4 [Rtc^. i2 t3 c$a V l

D. +(+& B. 1(1% *. P(P] G. %(%P1+. [J D-%)^ *A nm O"n6 O3ch Hn6 in6 bit ton6 nm 8n6 n6him: [J P^%/NP( 'e*l%( *[N+^+%*N+( Dl[N+^+. *ho O"n6 O3ch Ba[NJ^%n O; vo nm O"n6 O3ch tn. /a" Rhi n6 Rt th5c( s8 8n6n6him cA Rt t$a l

D. + B. , *. % G. P1P. [J B-%)^ KQn 1ml O"n6 O3ch h|n h`< 6Ym J%/NP(,M v J*l (1M vi 1ml O"n6 O3ch h|n h`n6 R nha" ton6 nhAm D t2c OEn6 ht vi J%N th" ;`c&.\% l4t Rh4 J%[Rtc^ v O"n6 O3ch f.

a- 2c 3nh tn c$a hai Rim lo?i tn.b- K4nh thg t4ch O"n6 Oich J*l %M c9n OCn6 g t"n6 h}a ht O"n6 O3ch fBi %%: *ho \(% 6am m"8i cacbonat c$a hai Rim lo?i R ti< nha" ton6 nhAm D h}a tan ht ton6 O"n6 O3chJ%/NP loIn6 th" ;`c Rh4 B. *ho ton bQ Rh4 B h!< thE vo P, ml O"n6 O3ch Ba[NJ^% (%M th" ;`c 1,(\&6am Rt t$a. K#m cUn6 th>c c$a hai m"8i cacbonat ban 9".Bi %+: *ho \(,, 6am h`< Rim 6Ym hai Rim lo?i t2c OEn6 vi O"n6 O3ch J%/NPloIn6( O; th" ;`c %(%P l4t Rh4J%( Yn6 thi c}n 1(, 6am Rim lo?i RhUn6 tan. J}a tan l;`m6 Rim lo?i c}n l?i nF ton6 O"n6 O3ch J%/NPc( O; th# th" ;`c 11%ml /N%. *2c Rh4 o W Rtc. 2c 3nh tn c$a hai Rim lo?i ton6 h`< Rim.Bi %P: J}a Kan hon ton +(& 6am h|n h`< 6am m"8i cacbonat c$a hai Rim lo?i R ti< nha" ton6


10/74


D. ,k. B. +,k. *. %k. G. Pk.Bi %. MQt h|n h`< 6Ym 1+ 6am Rm v ,(& 6am st t2c OEn6 vi O"n6 O3ch axit s"n"ic loIn6 O;. Khg t4ch Rh4hiOo [Rtc^ ;`c 6i7i


11/74


D. &)k. B. )&k. *. PPk G. ,&k.Bi 1\. *ho %(] 6am h|n h`< bQt Rim lo?i b?c v Yn6 t2c OEn6 vi O"n6 O3ch JN +c( O; th# th" ;`c (])&l4t Rh4 N%O"F nh!t [W Rtc^. Khnh a mQt m"8iO"F nh!t v (1\)% l4t [Rtc^ h|n h`< Rh4 N( %cA tq Rh8i h=i so J%l 1P(%,. K4nh a D. (P,) 6am. B. (,)P 6am. *. ,()P 6am. G. (),P 6am.Bi %: *ho h|n h`< D 6Ym *" v M6 vo O"n6 O3ch J*l O; th" ;`c ,(& l4t Rh4 [Rc^ RhUn6 m" v mQt ch!tn RhUn6 tan B. GCn6 O"n6 O3ch J%/NPc( nAn6 g ho tan ch!t n B th" ;`c %(%P l4t Rh4 /N%[Rc^. h8il;`n6 h|n h`< D ban 9" l:D. &(P 6am. B. 1%(P 6am. *. &( 6am. G. ]( 6am.Bi %1: *ho a 6am h|n h`< M6 v Dl vo %, ml O"n6 O3ch ch>a % axit : J*l 1M v J %/NP(,M ;`c O"n6O3ch B v P(+&] l4t J%[Rtc^ th# ton6 O"n6 O3ch B s:

D. G; axit B. Khi" axit *. G"n6 O3ch m"8i G. K!t c7 " saiBi %%: *ho %(& 6am h|n h`< 6Ym 'e( Dl( *" t2c OEn6 vi O"n6 O3ch JN +loIn6 O; th" ;`c (])& l4t NO"F nh!t W Rtc. h8i l;`n6 m"8i N+-sinh a l :D. )(, 6am B. \(PP 6am *. \(% 6am G. P(,P 6amBi %+: *ho %(1& 6am M6 t2c OEn6 vi O"n6 O3ch JN + [O;^. /a" Rhi n6 x7F a hon ton th" ;`c(])& l4t Rh4 N [W Rtc^ v O"n6 O3ch . h8i l;`n6 m"8i Rhan th" ;`c Rhi lm baF h=iO"n6 O3ch lD. ](]] 6am. B. 1+()% 6am. *. &(,% 6am. G. 1+(+% 6am.Bi %P: *ho m 6am h|n h`< 6Ym Dl( *" vo O"n6 O3ch J*l [O;^( sa" Rhi Rt th5c n6 sinha +(+& l4t Rh4 [W Rtc^. " cho m 6am h|n h`< tn vo mQt l;`n6 O; axit nitic [c( n6"Qi^( sa" Rhi Rtth5c n6 sinh a &(\% l4t Rh4 N%[s7n


12/74


Bi +: J}a tan hon ton 1% 6am h|n h`< 'e( *" [tq l mol 1:1^ bjn6 axit JN +( th" ;`c V l4t [W Rtc^ h|nh`< Rh4 [6Ym N v N%^ v O"n6 O3ch f [chq ch>a hai m"8i v axit O;^. Kq Rh8i c$a 8i vi J% bjn61). i2 t3 c$a V l:D. %(%P. B. P(P]. *. ,(&. G. +(+&.Bi +1: *ho m 6am h|n h`< M6( Dl vo %, ml O"n6 O3ch ch>a h|n h`< axit J*l 1M v axit J %/NP

(,M( th" ;`c ,(+% l4t J% [W Rtc^ v O"n6 O3ch f [coi thg t4ch O"n6 O3ch RhUn6 Ti^. G"n6 O3ch f cA


13/74


B Kd dJBi 1. hi cho O}n6 in mQt chi" L%D {"a O"n6 O3ch *"*l%ton6 1


14/74


D. 1](. B. \,(&. *. ,P(. G. &\(,.Bi 1P: in


15/74


Bi %\: in n6 xon6 l!F l2 Rm a RhZi O"n6O3ch( a nh( lm RhU th# th!F Rh8i l;`n6 l2 Rm tn6 thm %(+,k so vi Rh8i l;`n6 l2 Rm t;c n6.h8i l;`n6 l2 Rm t;c n6 l:

D. ]6am B. &6am *. %6am G. P6amBi +. h5n6 mQt inh st cA Rh8i l;`n6 ] 6am vo ,ml O"n6 O3ch *"/NP%M. /a" mQt thi 6ian l!F inh sta cSn l?i th!F nn6 ](] 6am. Yn6 Q mol~l c$a *"/NPton6 O"n6 O3ch sa" n6 l:

D. (%\M B. 1(+&M *. 1(]M G. %(+MBi P: 6Sm l2 Rm ton6 O"n6 O3ch ch>a (1 mol *"/NP. dh7n >n6 xon6 th!F Rh8i l;`n6 l2 Rm:D. tn6 (1 6am. B. tn6 (1 6am. *. 6i7m (1 6am. G. RhUn6 thaF Ti.Bi ,: Jo tan hon ton %] 6am bQt 'e vo O"n6 O3ch D6N+O; th# Rh8i l;`n6 ch!t n th" ;`c lD. 1] 6am. B. 1&% 6am. *. %1& 6am. G. 1,P 6am.Bi &: h5n6 1 thanh nhUm nn6 , 6am vo Pml O"n6 O3ch *"/NP(,M. /a" mQt thi 6ian l!F thanh nhUma cSn nn6 ,1(+] 6am. JZi Rh8i l;`n6 *" tho2t a l bao nhi"D. (&P6am. B. 1(%]6am. *. 1()%6am. G. %(,&6am.Bi \: 6Sm mQt l2 'e ton6 O"n6 O3ch *"/NP. /a" mQt thi 6ian n6 l!F l2 'e a a nh lm RhU( emcSn th!F Rh8i l;`n6 tn6 thm 1(& 6am. h8i l;`n6 *" b2m tn l2 'e l bao nhi" 6amD. 1%(] 6am. B. ](% 6am. *. &(P 6am. G. )(& 6am.Bi ]: 6Sm mQt l2 Rm ton6 1 ml O"n6 O3ch D6N +(1M. hi n6 Rt th5c( Rh8i l;`n6 l2 Rm tn6thmD. (&, 6am. B. 1(,1 6am. *. (\,, 6am. G. 1(+ 6am.Bi ): *ho m 6am h|n h`< bQt n v 'e vo l;`n6 O; O"n6 O3ch *"/N P. /a" Rhi n6 Rt th5c( lc bZ


16/74


Bi 11: *ho h|n h`< bQt Dl( 'e vi O"n6 O3ch ch>a *"[N+^%v D6N+. /a" Rhi c2c n6 x7F ahon ton( th" ;`c h|n h`< n 6Ym ba Rim lo?i l:D. 'e( *"( D6. B. Dl( *"( D6. *. Dl( 'e( *". G. Dl( 'e( D6.Bi 1%: Jo tan hon ton 'e+NP ton6 O"n6 O3ch J%/NPloIn6 [O;^ ;`c O"n6 O3ch 1. *ho l;`n6 O; bQt 'evo O"n6 O3ch 1 [ton6 i" Rin RhUn6 cA RhUn6 Rh4^ n Rhi n6 x7F a hon ton( th" ;`c O"n6 O3ch

%ch>a ch!t tan lD. 'e%[/NP^+v J%/NP. B. 'e/NP. *. 'e%[/NP^+. G. 'e/NPv J%/NP.Bi 1+: *ho h|n h`< bQt 6Ym %(\ 6am Dl v ,(& 6am 'e vo ,, ml O"n6 O3ch D6N+1M. /a" Rhic2c n6 x7F a hon ton( th" ;`c m 6am ch!t n. i2 t3 c$a m l [bit th> tH ton6 OIF thin ho2: 'e+0~'e%0>n6 t;c D60~D6^D. ,)(P. B. &P(]. *. +%(P. G. ,P(.Bi 1P: *ho &(\% 6am 'e vo P ml O"n6 O3ch JN+1M( n Rhi n6 x7F a hon ton( th" ;`c Rh4 N[s7n a a mol db[N+^%th# Rh8il;`n6 thanh Rim lo?i tn6 \(1k. im lo?i @ l:

D. M6 B.'e *.n G.i



17/74


Bi %+: *ho a 6am bQt 'e n6 vi h|n h`< 6Ym 1P(& 6am J*l v %,(& 6am *"/NP( sa" Rhi n6 x7Fa hon ton th" ;`c h|n h`< Rim lo?i cA Rh8i l;`n6 (\a 6am v x l4t Rh4 [K*^. i2 t3 c$a a v l:

D. ++.&\ v %%.P B. +.+&\ v P.P] *. +.+&\ v %(%P G. ++.&\ v P(P]Bi %P: *ho +(] 6am 'e vo 1, ml O"n6 O3ch D6N+ 1M( lc Rq cho n Rhi n6 x7F a hon ton th";`c m 6am ch!t n. i2 t3 c$a m l:

D. 11.]] B. 1&(% *. 1](% G. 1\()&Bi %,: *ho 1)(% 6am *" vo 1 l4t O"n6 O3ch h|n h`< 6Ym J%/NP(1M v N+(%M th" ;`c V l4t Rh4 NO"F nh!t [K*^. i2 t3 c$a V l:

D. 1.1% B. %.%P *. P.P] G. +.+&Bi %&: h5n6 mQt thanh 6ac c$a m"8i *l+.

D. n*l+ B. a*l+ *. 'e*l+ G. e*l+.Bi %): *ho (+ mol bUt *" v (& mol 'e[N+^%vo O"n6 O3ch ch>a () mol J%/NP[loIn6^. /a" Rhi c2c n6 x7F a hon ton( th" ;`c V l4t Rh4 N [s7n


18/74


Bi \: *ho l"Yn6 Rh4 *N [O;^ i {"a )(1 6am h|n h`< 6Ym *"N v Dl %N+n"n6 nAn6 n Rhi n6 honton( th" ;`c ](+ 6am ch!t n. h8i l;`n6 *"N cA ton6 h|n h`< ban 9" l

D. (] 6am. B. ](+ 6am. *. %( 6am. G. P( 6am.Bi ]. *ho O}n6 Rh4 *N O; i {"a h|n h`< [^ ch>a +1() 6am 6Ym Dl %N+( nN( 'eN v *aN th# th" ;`c %](\6am h|n h`< ch!t n [f^. *ho ton bQ h|n h`< ch!t n [f^ t2c OEn6 vi O"n6 O3ch J*l O; th" ;`c V l4t J

[Rc^. i2 t3 V lD. ,(& l4t. B. P(P] l4t. *. &(\% l4t. G. %(%P l4t.Bi ): h &(P 6am *"N bjn6 J%W nhit Q cao th" ;`c ch!t n D v h|n h`< Rh4 B. Gn ton bQ l;`n6 Rh4B {"a b#nh Hn6 J%/NPm c( th!F Rh8i l;`n6 b#nh tn6 () 6am. Khnh Hn6 (P mol h|n h`< 6Ym 'eN v 'e %N+n"n6 nAn6( ;`c ch!t n fnn6 P(\]P 6am v (P& mol *N%. /8 mol tXn6 ch!t ton6 h|n h`< l.

D. (1, mol 'eN v (%, mol 'e%N+ B. (1 mol 'eN v (+mol 'e%N+*. (% mol 'eN v (% mol 'e%N+. G. (% mol 'eN v (+ mol 'e%N+.Bi 1,: *ho mQt l"Yn6 Rh4 *N i {"a %) 6am mQt oxit st. /a" Rhi n6 x7F a hon ton n6;i ta th";`c mQt ch!t n cA Rh8i l;`n6 %1 6am. 2c 3nh cUn6 th>c oxit st.D. hUn6 x2c 3nh ;`c B. 'e%N+ *. 'eN G. 'e+NPBi 1&: GCn6 *N O; g Rh hon t}an m 6am bQt st oxit. Gn t}an bQ l;`n6 Rh4 sinh a i tht chm {"a 1 l4tO"n6 O3ch Ba[NJ^%(1M th# vXa $ v th" ;`c )(],6am Rt t$a. Mt Rh2c h}a tan t}an bQ m 6am bQt st oxittn bjn6 OO J*l O; Yi cU c?n th# th" ;`c 1&(%,6am m"8i Rhan. m cA 6i2 t3 l bao nhi" 6am V cUn6 th>coxit ['exNF^.D( ]6am 'e%N+ B. 1,(16am( 'eN *. 1&6am 'eN G. 11(&6am 'e+NPBi 1\: GCn6 *N O; g Rh h}an t}an m 6am bQt st oxit['exNF^ On t}an bQ l;`n6 Rh4 sinh a i tht chm{"a 1 l4t O"n6 O3ch Ba[NJ^%(1M th# n6 vXa $ th" ;`c )(],6am Rt t$a. /8 mol Rh4 *N %th" ;`c lbao nhi"D. (,mol B. (1, mol *. (%,mol G. (, v (\, molBi 1]: GCn6 *N O; g Rh h}an t}an m 6am bQt st oxit ['exNF^( On t}an bQ l;`n6 Rh4 sinh a i tht chm{"a 1 l4t O"n6 O3ch Ba[NJ^%(1M th# vXa $ v th" ;`c )(],6am Rt t$a. Mt Rh2c h}a tan t}an bQ m 6am bQtst oxit bjn6 O"n6 O3ch J*l O; Yi cU c?n th# th" ;`c 1&(%, 6am m"8i Rhan. m cA 64a t3 l



19/74


D. ] 6am B. 1,(16am *. 1&6am G. 11(&6amBi 1): J|n h`< 6Ym 'e v oxit st cA Rh8i l;`n6 %(&6am. *ho Rh4 *N O; i {"a n"n6 nAn6( h4 sinh ah!< thE vo O"n6 O3ch n;c vUi ton6 O; th# ;`c 16am Rt t$a. KTn6 Rh8i l;`n6 'e cA ton6 lD. 1 6am B. (,&6am *. % 6am G. 1(1%6amBi %: Gn 1 l"Yn6 *N O; {"a 8n6 Hn6 m 6am h|n h`< 6Ym 'e %N+v *"N n"n6 nAn6 th" ;`c ch!t n

f Rh4 a RhZi 8n6 ;`c On vo b#nh Hn6 O"n6 O3ch *a[NJ^ %O;( th" ;`c P 6am Rt t$a. J}a tan ch!t n fton6 O"n6 O3ch J*l O; th!F cA P(P] l4t Rh4 J%baF a [Rtc^. 4a t3 m lD. %P B. 1& *. +% G. 1%Bi %1: "n6 nAn6 \(%6am 'e%N+vi Rh4 *N. /a" mQt thi 6ian th" ;`c m 6am ch!t n . h4 sinh a sa"n6 ;`c h!< thE ht bWi OOBa[NJ^%;`c ,()16 Rt t$a( ti< tEc cho Ba[NJ^%O; vo O"n6 O3ch tn th!FcA +()P 6am Rt t$a na. K#m mD. (+%6am B. &P6am *. +(%6am G. &(P6amBi %%: *ho Rh4 *N {"a 8n6 s> ch>a 1,(%6am h|n h`< ch!t n *"N v 'e+NP n"n6 nAn6 ( th" ;`c Rh4 v1+(& 6am ch!t n f. Gn tX tX Rh4 vo O"n6 O3ch *a[NJ^%O; th!F cA Rt t$a. rc l!F Rt t$a v n"n6 nRh8i l;`n6 RhUn6 Ti ;`c m 6am ch!t n. m cA 64a t3 lD. 16am B. 1&6am *. 1%6am G. 1]6am

Bi %+: *ho l"Yn6 Rh4 J% [O;^ {"a h|n h`< c2c oxit *"N( 'e%N+( nN( M6N n"n6 W nhit Q cao. /a" n6h|n h`< n c}n l?i l:D. *"( 'e( n( M6N. B. *"( 'e( nN( M6N. *. *"( 'e( n( M6. G. *"( 'eN( nN( M6NBi %P: dh7n >n6 ho2 hc x7F a ton6 t;n6 h`< no O;i SF RhUn6 th"Qc lo?i n6 nhit nhUmD. Dl t2c OEn6 vi 'e+NPn"n6 nAn6. B. Dl t2c OEn6 vi *"N n"n6 nAn6.*. Dl t2c OEn6 vi 'e%N+ n"n6 nAn6. G. Dl t2c OEn6 vi axit J%/NPc( nAn6Bi %,: *ho Rh4 *N [O;^ i vo 8n6 s> n"n6 nAn6 Hn6 h|n h`< 6Ym Dl%N+( M6N( 'e+NP( *"Nth" ;`c ch!t n f. *ho f vo O"n6 O3ch aNJ [O;^( Rh"!F R( th!F c}n l?i


20/74


D. 1,. B. 1. *. %. G. +.Bi +1: *ho l"Yn6 Rh4 *N [O;^ i {"a )(1 6am h|n h`< 6Ym *"N v Dl %N+ n"n6 nAn6 n Rhi n6 honton( th" ;`c ](+ 6am ch!t n. h8i l;`n6 *"N cA ton6 h|n h`< ban 9" lD. (] 6am. B. ](+ 6am. *. %( 6am. G. P( 6am.Bi +%: "n6 nAn6 m 6am h|n h`< 6Ym Dl v 'e+NPton6 i" Rin RhUn6 cA RhUn6 Rh4. /a" Rhi n6 x7F

a hon ton( th" ;`c h|n h`< n . *ho t2c OEn6 vi O"n6 O3ch aNJ [O;^ th" ;`c O"n6 O3ch f( ch!t n v +(+& l4t Rh4 J%[W Rtc^. /Ec Rh4 *N%[O;^ vo O"n6 O3ch f( th" ;`c +) 6am Rt t$a. i2 t3 c$a m lD. P,(&. B. P](+. *. +&(\. G. ,\(.Bi ++: h hon ton m 6am oxit MxNFc9n vXa $ 1\()% l4t Rh4 *N [Rtc^( th" ;`c a 6am Rim lo?i M. J}atan ht a 6am M bjn6 O"n6 O3ch J %/NPc nAn6 [O;^( th" ;`c %(1& l4t Rh4 /N%[s7n


21/74


.?i X. *ho m 6am Rim lo?i a vo % 6am. O"n6 O3ch Dl%[/NP^+ 1(\1k. /a" Rhi n6 xon6 th" ;`c (\]6am Rt t$a. m cA 6i2 t3 lD. (&) 6am. B. 1(&1 6am.*. c7 D v B " 5n6. G. 2< 2n Rh2c.?i "!. *ho (,P 6am Dl vo P ml O"n6 O3ch aNJ 1M( sa" n6 hon ton th" ;`c O"n6 O3ch . *ho

tX tX O"n6 O3ch J*l (,M vo O"n6 O3ch th" ;`c Rt t$a. g th" ;`c l;`n6 Rt t$a ln nh!t c9n thg t4chO"n6 O3ch J*l (,M lD. 11 ml. B. ) ml. *. \ ml. G. ] ml..?i "". J|n h`< D 6Ym a v DlP*+h}a tan vo n;c chq th" ;`c O"n6 O3ch B v +(+& l4t Rh4 *. h8i l;`n6a t8i thig" c9n OCn6 l:D. (1,6 B. %(\&6 *. (&)6 G. P(%6.?i ". J|n h`< D 6Ym a( Dl ( *" cho 1% 6am D vo n;c O; th" %(%P l4t Rh4 [Rtc^ ( c}n n" cho vo O"n6O3ch aNJ O; th" +()% l4t Rh4 [ Rtc^ . k Dl ton6 h|n h`< ban 9" D. ,)(&k B. %%(,k *. &\(, k G. )&(%,k.?i "R. *ho m 6am h|n h`< 6Ym a%N v Dl ho tan ht vo J%N O; th" ;`c % ml O"n6 O3ch D chq ch>a1 ch!t tan O"F nh!t cA nYn6 Q (%M. i2 t3 c$a m l :

D. %(+% B. +(,& *. +(,% G. ,(+&.?i "S. J}a tan ht m 6am n/NPvo n;c ;`c O"n6 O3ch . *ho 11ml O"n6 O3ch NJ %M vo ( th";`c a 6am Rt t$a. Mt Rh2c( n" cho 1P ml O"n6 O3ch NJ %M vo th# cun6 th" ;`c a 6am Rt t$a. i2t3 c$a m lD. %(1%,. B. 1%(+\,. *. %%(,P. G. 1\(\1..?i " J|n h`< 6Ym c2c Rim lo?i Dl 'e Ba. *hia thnh +


22/74


.?i "WJo tan hon ton m 6am h|n h`< 6Ym a v Dl [34567 89 N: ;< * =9 3> ?@ A5? ?< 1 1 ^ vo mQtl;`n6 n;c O; th" ;`c O"n6 O3ch f %(\6 ch!t n v ]()&l4t Rh4 K W Rtc. i2 t3 c$a m l:D. 1\6 B. 11(&6 *. 1P(+6 G. 1&(16.?i ". *ho +](\\, 6am h|n h`< bQt Dl v Dl*l+vo l;`n6 vXa $ O"n6 O3ch aNJ th" ;`c O"n6 O3ch D [Rtt$a vXa tan ht^ v &(\% l4t J%[Rtc^. Khm %,ml O"n6 O3ch J*l vo O"n6 O3ch D th" ;`c %1(]P 6am Rt t$a.

Yn6 Q M c$a O"n6 O3ch J*l l :D. 1(1%M hoc %(P]M B. %(%PM hoc %(P]M*. 1(1%M hoc +(]PM G. %(%PM hoc +(]PM.?i . *ho %+(P, 6am h|n h`< 6Ym Ba v vo 1%, ml O"n6 O3ch Dl*l+1M th" ;`c V l4t Rh4 J%[Rtc^O"n6 O3ch D v +() 6am Rt t$a. V cA 6i2 t3 l :D. 1(] l4t B. +()% l4t *. ,(P l4t G.&(\% l4t

./0 T)* ' H02$ D$T *HYN ZNG

.?i ". KQn 1+(, 6 bQt Dl vi +P(]6 bQt 'e+NPYi tin hnh n6 nhit nhUm. i7 s l5c A chq x7F a n6 Rh 'e+NPthnh 'e. Jo tan hon ton h|n h`< ch!t n sa" n6 bjn6 O"n6 O3ch J %/NPloIn6 O; th#

th" ;`c 1P(11% ?3J%[W 83=^. K4nh hi" s"!t n6 nhit nhUm.D. \k B. \,k *. ]k G.&k.?i . hi oxi hAa 11(% l4t J+[W Rtc^ g i" ch JN+vi hi" s"!t c$a c7 {"2 t#nh l ]k th# th" ;`cRh8i l;`n6 O"n6 O3ch JN+&(+k lD. + 6am. B. , 6am. *. %, 6am. G. P 6am..?i R. Ga nhSn t?o [dV*^ ;`c i" ch tX Rh4 thin nhin theo s= Y: *JP *%J% *J%L*J*l *J%*J*ln." hi" s"!t c$a ton bQ {"2 t#nh i" ch l %k( m"8n i" ch ;`c 1 t!n dV* th# thg t4ch Rh4 thin nhin[ch>a ]k metan^ W i" Rin ti" ch"n c9n OCn6 lD. P+\, m+. B. PP, m+. *. PP] m+. G. &]\, m+

.?i S. "n6 ](1 6am Dl vi %+(% 6am 'e+NPW nhit Q cao [ 6i7 s chq cA n6 Rh oxit st thnh st^ th"

;`c h|n h`< . *ho h|n h`< vo O"n6 O3ch J%/NPloIn6 O;( "n nAn6 th" ;`c ](&P l4t J%[Rtc^. JIFcho bit hi" s"!t c$a n6 nhit nhUm D. \,k B. ]k *. ],k G. )k.?i . h8i l;`n6 este metFlmetacFlat th" ;`c l bao nhi" Rhi "n nAn6 %1,6 axit metacFlic vi 16ancol metFlic( 6i7 thit hi" s"!t n6 este ho2 ?t &k.D. 1%,6 B. 1\,6 *. 1,6 G. %6.?i U. in


23/74


.?i "! "n nAn6 h|n h`< 6Ym (%, mol *%J+*NNJ v (1, mol *+J&[NJ^% cA mt c$a J%/NPc lm x5ct2c( sa" mQt thi 6ian th" ;`c 1)(,, 6am mQt este O"F nh!t. Ji" s"!t c$a n6 este ho2 lD. %,k. B. \k. *. ]k. G. ],k..?i "" h8i l;`n6 6l"coz= c9n g i" ch (1 l4t ;`" tFlic n6"Fn ch!t [Rh8i l;`n6 in6 G L (] 6~ml^ vihi" s"!t ]k l

D. 1] 6am. B. 1),(&, 6am. *. 1]&(,, 6am. G. % 6am..?i " J}a tan hon ton 1& 6am ;`" etFlic vo n;c ;`c %, ml O"n6 O3ch ;`"( cho bit Rh8i l;`n6 in6c$a ;`" etFlic n6"Fn ch!t l (] 6~ml. G"n6 O3ch cA Q ;`" l:

D. ,(1% &(P *. 1% G. ]

.?i "R MQt lo?i 6?o ch>a \,k tinh bQt. r!F \](%] R6 6?o nF i n!" ;`" etFlic P( hi" s"!t


24/74


thi th" ;`c 1)(\6 Rt t$a. Bit tq Rh8i h=i c$a 8i vi hiOo bjn6 1](, v D( B cCn6 OF Yn6 n6.1^ 2c 3nh OF Yn6 n6 c$a % hiOocacbon a. DnRan b. DnRen c. Den O. DnRaOien%^ K m cUn6 th>c a])ml O"n6 O3ch Ba[NJ^%1M th Rh8i l;`n6 b nh 1 tn6 1P(P6 v W b nh % th" ;`c 1++()&6 Rt t$a tn6.2c 3nh OF Yn6 n6 c$a D v B. a. DnRin b. DnRen c. DnReOien O. DnRan*S" P. 8t ch2F hon ton mQt hiOocacbon vi mQt l;`n6 vXa $ oxi. Gn h|n h`< s7n c


25/74


a^ 2c 3nh OF Yn6 n6 c$a + hiOocacbon a. *nJ%n % b. *nJ%n 0 % b. *nJ%n & O. *nJ%nb^ 2c 3nh cUn6 th>c c ( thnh c


26/74


*S" 1]. *ho (&\% lit [Rtc^ h|n h`< Rh4 D 6Ym hai hiOocacbon m?ch hW. *hia D thnh % c c a ton6 J%/NPc O;( b nh hai ch>a +(, lit *a[NJ^%(1M th" ;`c +6 Rt t$a( Rh4O"F nh!t baF a cA thg t4ch (%%P lit o W %\(+o* v 1(1 atm. 2c 3nh cUn6 th>c


27/74


a. *%J% b. *%J] c. *+J]hoc *%J% O. *+J]hoc *%J%hoc *JP*S" %\. *ho h|n h`< Rh4 6Ym hiOocacbon D v oxi l!F O;( ton6 A cA 1k D theo thg t4ch vo mQt Rh4 nhinR( t?o 2< s"!t 1 atm W o*. Bt tia la in g D ch2F hon ton Yi cho n;c n6;n6 tE W o* th 2< s"!t W ton6b nh 6i7m cn (] atm. Bit l;`n6 oxi O; RhUn6 {"2 ,k l;`n6 oxi ban 9". JF tm cUn6 th>c c tTn6 {"2t *nJ%n 0 % %Rth" ;`c s7n n6 vi R nhZ nh!t. *Un6 th>c c


28/74


B [Rtc^. 8t ch2F hon ton h|n h`< tn Yi cho ton bQ s7n a +(+& lit J%v %(%P lit *%JP[Rtc^ v mQt 4t bQt niRen. 8t nAn6b nh mQt thi 6ian( /a" A lm l?nh v o*( 2< s"!t ton6 b nh l5c A l


29/74


thnh c c c a mQtn6"Fn t bom ton6


30/74


b^ 2c 3nh hai hiOocacbon cho( bit ch5n6 [ x< theo th> tH tn6 O9n c c c!" t?oc$a *]J]l:a. *&JP[*J+^% b. *&J,*JL*J% c. *&J,*J%L*J+ O. *S" b 5n6*S",,. MQt h|n h`< hai anRan R cn ton6 OF Yn6 n6 cA tq Rh8i h=i vi J%l %P(].a^ *Un6 th>c c


31/74


a. *%J&v *%J% b. *+J]v *+JP c. *%J&v *+JP O. *PJ1v *%J%*S",]. J|n h`< Rh4 D 6Ym hai hiOocacbon cA cCn6 s8 n6"Fn t cacbon [Rtc^.a^ K m tq Rh8i h=i c$a h|n h`< D 8i vi ito( bit jn6 ,&cm+h|n h`< A nn6 1(+&%,6. a. 1() b. % c. 1(& O. Rt {"7 Rh2cb^ 8t ch2F Vcm+h|n h`< D cho c2c s7n a \,k tinh bQt.r!F \](%] R6 6?o nF i n!" ;`" etFlic ( hi" s"!t


32/74


*S" &: *ho m 6am mQt ancolno( =n ch>c {"a b#nh Hn6 O; n"n6 nAn6./a" Rhi n6 hon ton.

Rh8i l;`n6 ch!t n ton6 b#nh 6i7m .+%6.J|n h`< h=i th" ;`c cA tq Rh8i8i vi l 1,.,

*S" \: *ho 1(,%6 h|n h`< hai ancol=n ch>c l Yn6 n6R ti< nha" t2c OEn6 vi a vXa $( sa" n6th" ;`c %(1]6 ch!t n. *Un6 th>c c c!" t?oc$a D l:

*S" ): 8t ch2F hon ton m 6am h|n h`< 6Ym hai ancolD v B th"Qc cCn6 OIF Yn6 n6th" ;`c &(\% l4t

v \(&,6 . Mt Rh2c Rhi cho m 6am h|n h`< t2c OEn6 vi a O; th" ;`c %(] l4t . Bit tq Rh8ih=i c$a m|i ch!t so vi hio " nhZ h=n P( c2c thg t4ch Rh4 o W Rtc. D v B cA cUn6 th>c c vi c W th" ;`c h|n h`< 6Ym c2c ete cAs8 mol bjn6 nha" v cA Rh8i l;`n6 l 111(%6. /8 mol c$a m|i ete ton6 h|n h`< l 6i2 t3 no O;i SF

*S" 11: 8t ch2F hon ton (+ mol h|n h`< 6Ym % ;`" lin ti< ton6 OIF Yn6 n6*S" %P: Nxi hAaht(% mol ;`" =n ch>c D( B lin ti< ton6 OIF Yn6 n6bjn6 *"N "n nAn6 ;`c h|n h`< 6Ym % anhit.

*ho t2c OEn6 vi l;`n6 O; O"n6 Oich ;`c ,P6 b?c. D( B l % ;`" no

;`c v (, mol . *Un6 th>c a *(J(N^ th# cA . r!F hai ;`" =n ch>c (

f em "n nAn6 vi c W nhit Q th4ch h`< th# th" ;`c D.*Un6 th>c [m?ch hW^ D( ( f [bit D lete^ l

*S" 1P: @;`" D t2c OEn6 vi O; cho mQt thg t4ch bjn6 vi thg t4ch h=i ;`" D I OCn6. Mt Rh2c 8t

ch2F ht mQt thg t4ch h=i ;`" D th" ;`c ch;a n ba thg t4ch Rh4 [c2c thg t4ch o W cCn6 i" Rin^.@;`" D cA tn 6i

*S" 1,: MQt h|n h`< 6Ym % ;`" no =n ch>c D( B Yn6 n6R tic


33/74


*S" 1\: MQt ;`" no a ch>c m?ch hW ( cA n n6"Fn tcacbonv m nhAm . *ho \(& 6am n6

vi O;( th" ;`c (1 mol Rh4 . Big" th>c lin h 6ia n v m l

*S" 1]: *ho h|n h`< 6Ym ancol etFlicv ancolf th"Qc OF Yn6 n6c$a ancol etFlic( cho .\& 6am t2cOEn6 ht vi a th!F tho2t a (1&] l4t Rh4 [Rc^( cho bit tq l s8 mol c$aancol etFlicvancolf l %:1( cUn6

th>c c hai ;`" l

*S" %+: J|n h`< 6Ym 1 ancol v % s7n c R ti< nha" ton6 OIF Yn6 n6 t2c OEn6 ht vi P(& 6am a;`c 1%(%, 6am ch!t n. 2c 3nh *KdK c$a % ancol

*S" %): "n nAn6 h|n h`< hai anRanol lin ti< ton6 OIF Yn6 n6 vi J %/NPc W 1P*( th" ;`c %1(&6am J%N v 1+)(% 6am h|n h`< ba ete cA s8 mol bjn6 nha".2c 3nh *KdK c$a hai anRanol*S" + : "n nAn6 h|n h`< 6Ym hai ;`" [ancol^ =n ch>c( m?ch hW( R ti< nha" ton6 OIF Yn6 n6 viJ%/NPc W 1Po*. /a" Rhi c2c n6 Rt th5c( th" ;`c & 6am h|n h`< 6Ym ba ete v1(] 6am n;c. 2c3nh cUn6 th>c


34/74


*S" +%: hi "n nAn6 mQt ancol =n ch>c no D vi J%/NP c W i" Rin nhit Q th4ch h`< th" ;`c s7nc c$a D.*S" ++: *ho 1%()6 h|n h`< + ancol no( =n ch>c( m?ch hW tham 6ia n6 t2ch n;c W i" Rin th4ch h`c. Bit jn6 t2c OEn6 ;`c vi D6N+~J+cho D6. *ho bit cUn6 th>c c!" t?o 5n6 c$a fD. *J*JN B. *%J,*JN *. *J%L*J-*JN G. t {"7 Rh2c*S" +& : GCn6 nhn6 hAa ch!t no g a * ( J ( N t2c OEn6 vXa $ vi +ml O"n6 O3ch D6N%M ton6 J+th" ;`c P+(% 6am D6 . Bit tq Rh8i h=i c$a so vi oxi bjn6 %(1%, . 2c 3nh cUn6 th>c c!" t?oc$a D. *J+*J%*JN B. *J%L*J-*J%-*JN *. *J*-*J%*JN G. *J*-

*JN*S" P : MQt h`< ch!t h" c= f ch>a c2c n6"Fn t8 * ( J ( N chq ch>a mQt lo?i nhAm ch>c . Rhi cho (1 molf t2c OEn6 vi O"n6 O3ch D6N+ ton6 J+O; th" ;`c P(+% 6am D6 . f cA c!" t?o m?ch thn6 v ch>a+\(%1k oxi v Rh8i l;`n6 . *Un6 th>c c!" t?o 5n6 c$a f l: D. J*JN B. *J+*JN *NL*J-*JLN G. NL*J-[*J%^%*JLN*S" P1 : *ho (1 mol anOehit t2c OEn6 hon ton vi J%th# c9n &(\% l4t J%[Rtc^ v th" ;`c s7n a + n6"Fn t8 * ( J ( N ton6 A oxi chim ,,(\1k theo Rh8i l;`n6 . hi th" c c!" t?o c$a ( f ( D. *J+*l ( J*JN ( *J+NJ B. *%J,*l ( *J+*JN ( *%J,NJ *. *%JP*l% ( [*JN^% ( *%JP[NJ^% G. {"7 Rh2c*S" P, : l h`< ch!t h" c= m?ch hW =n ch>c ch>a * ( J ( N . 8t ch2F hon ton 1 mol c9n P mol oxi vth" ;`c *N%v h=i J%N cA thg t4ch bjn6 nha" [o W cCn6 i" Rin nhit Q v 2< s"!t^ . 2c 3nh cUn6 th>cc!" t?o cA thg cA c$a D. *J+-*J%-*JN hoc [*J+^%*N B. *J%L*J-*J%-NJ *. *J%L*J-N-*J+ G. c7 D ( B ( **S" P& : 8t ch2F %() 6 mQt anOehit th" ;`c &(& 6 *N%v %(\ 6 J%N. VF cA cUn6 th>c c!" t?o th" 6nl:D. *J+*JN B. *%J,*JN *. J*JN G[*JN^%*S" P\ : 8t ch2F hon ton (& 6 J*JN v 1(\P 6 * %J,*JN Yi cho s7n


38/74


D. 1()] B. &(]% *. 11(1& G. %(P]*S" P] : *ho 1P(&6 h|n h`< % anehit no =n ch>c Yn6 n6 lin ti< nha" t2c OEn6 ht vi J%t?o a 1,(%6h|n h`< % ancol. *Un6 th>c c$a % anehit lD. J*JN( *J+*JN B. *J+*JN( *%J,*JN *. *%J,*JN( *+J\*JN G. *+J\*JN*PJ)*JN

*S" P) : *A thg OCn6 n;c Bom g c c!" t?o c$a.Bi %. MQt este t?o bWi axit =n ch>c v ancol =n ch>c cA tq Rh8i h=i so vi *N %bjn6 %. hi "n nAn6 estenF vi O"n6 O3ch aNJ t?o a l;`n6 m"8i cA Rh8i l;`n6 ln h=n l;`n6 este I n6 . 2c 3nh *K*Kc$a este.Bi +. MQt este =n ch>c cA c c!" t?o c$a .Bi P. hi 8t ch2F hon ton P(P 6am ch!t h" c= =n ch>c th" ;`c s7n c th" ;`c +(,% 6am *N %v 1(1,% 6am J%N. *ho 1 6am t2cOEn6 vi O"n6 O3ch aNJ [vXa $^( cU c?n O"n6 O3ch sa" n6 th" ;`c 1P 6am m"8i Rhan f. *ho f t2cOEn6 vi axit vU c= loIn6 th" ;`c RhUn6 c c!" t?o c$a Bi &. Kh$F c no bjn6 O"n6 O3ch aNJ th" ;`c m"8i Rhan cA Rh8i l;`n6 c vi % ml O"n6 O3ch aNJ 1(,M [l!F O;^. *U c?n O"n6 O3ch sa"n6 th" ;`c ch!t n cA Rh8i l;`n6 1\(P6 v mQt ancol f. hiat hAa f th" ;`c %(%P l4t anRen.[Ji" s"!t t2ch n;c ?t 1k^. 2c 3nh *K*K c$a Bi ). hi cho (1, mol este =n ch>c t2c OEn6 vi O"n6 O3ch aNJ [O;^( sa" Rhi n6 Rt th5c th#l;`n6 aNJ n6 l 1% 6am v tTn6 Rh8i l;`n6 s7n c. *ho h=i i {"a 8n6

Hn6 *"N( t;`c h`< ch!t K cA Rh7 nn6 tham 6ia n6 t2n6 b?c. 8t ch2F hon ton %(] 6am c bit O~N%L +(1%, . 2c 3nh *K*K c$a ton6 m|i t;n6 h`< sa":a. % 6am t2c OEn6 vi + ml OO aNJ 1M . *U c?n OO sa" n6 th" ;`c %+(% 6am bI

n.



39/74


b. .1, mol t2c OEn6 vXa $ vi OO aNJ . *U c?n OO sa" n6 th" %1 6am m"8i Rhan[ m?ch RhUn6 nh2nh ^

b.1i toBn QBc /Rnh CTCT cSa =t tGong hUn hV.

Bi 1. Jai este l Yn6 c. "n 1+(& 6am vi OO aNJ th" ;`c s7n c (RhUn6 no v h|n h`< hai ancol no =n ch>c R ti< nha" . 8t hon

ton %\(% 6am c9n OCn6 ht ++(& lit N %th" ;`c %)(1% lit *N%v J%N [ W cCn6 Rtc ^. 2c 3nh *KdK c$a Dv B Bi ,. J|n h`< 6Ym % este =n ch>c D( B. *ho 1)() 6am h|n h`< n6 vi aNJ vXa $ th# th" ;`c%(, 6am mQt m"8i v h|n h`< hai ancol Yn6 n6 R tia *( J( N^ " =n ch>c. *ho h|n h`< n6 vXa $

vi 1ml OO aNJ ,M th" ;`c P+(] 6am h|n h`< hai m"8i c$a hai axit no =n ch>c v mQt ancol no =nch>c f . *ho ton bQ f t2c OEn6 ht vi vi ati th" ;`c +(+& lit J %[Rtc^. 2c 3nh *K*K c$a D( B bitMBL MD 0 %]Bi %. *ho 1+(P 6am h|n h`< M 6Ym hai ch!t h" c= =n ch>c ( f [ chq ch>a * (J (N ^ t2c OEn6 vXa $ vi P6am aNJ th" ;`c m"8i c$a mQt axit h" c= =n ch>c v )(% 6am mQt ancol. r;`n6 ancol th" ;`c cho t2cOEn6 vi a O; th!F tho2t a %(%P lit Rh4 J%[Rtc^. 2c 3nh *K*K c$a ( fBi +. J|n h`< 6Ym % ch!t h" c= =n ch>c. *ho (1 mol hh t2c OEn6 vXa $ (1 mol aNJ( cU c?n O"n6O3ch sa" n6 th" ;`c \(+& 6am h|n h`< m"8i v ancol f. Nxi hAa hon ton ancol f bjn6 *"N th" ;`canehit. *ho ton bQ l;`n6 anehit A t2c OEn6 vi D6N +~ J+th" ;`c %,()% 6am D6. 2c 3nh cUn6 th>cc$a % ch!t ton6 h|n h`< .

.?i t[\ adit cac@odylic

Bi 1: i" RhUn6 5n6 Rhi nAi v mQt axit cacboxFlic >n6 vi *KdK *nJ%n-%N% l ton6 *K*K:D. *A thg m?ch hW( % lin Rt Ui B. *hq cA mQt nhAm *NNJ*. *A thg ch>a mQt v}n6 G. *hq ch>a mUt lin Rt Ui



40/74


Bi 1.1: *ho 1P(] 6am h|n h`< % axit h" c= =n ch>c t2c OEn6 vi mQt l;`n6 vXa $ a%*N+ sinh a %(%P l4tRh4 *N% W Rtc. h8i l;`n6 m"8i th" ;`c l:D. 1\(& B. 1)(% *. %1(% G. %)(1Bi 1.%: K"n6 ho ,(P] 6am h|n h`< 6Ym axit axetic( c. g 8t ch2F (1 mol c9n &(\% l4t N% W Rtc. cA tn 6i l:D. Dxit axetic B. axit


41/74


D. % B. , *. ] G. &Bi ): [K/* D %1^ *ho 1&(P 6am h|n h`< 6Ym % axit cacboxFlic l Yn6 n6 R ti< nha" n6hon ton vi % ml O"n6 O3ch aNJ 1M v NJ 1M( th" ;`c O"n6 O3ch f. *U c?n O"n6 O3ch f( th" ;`c+1(1 6am h|n h`< ch!t n Rhan. *Un6 th>c c$a % axit ton6 l:D. *%JPN%v *+JPN% B. *%JPN%v *+J&N%

*. *+JPN%v *PJ&N% G. *+J&N%v *PJ]N%.Bi 1: [K/* D %1^ Dxit cacboxFlic cA cUn6 th>c =n 6i7n nh!t l *+J,N%. hi cho 1 ml O"n6 O3chaxit nYn6 Q (1M n6 ht vi O"n6 O3ch aJ*N+[O;^( th" ;`c V ml Rh4 *N%[Rtc^. i2 t3 c$a V lD. PP]. B. %%P. *. 11%. G. ++&Bi 1.1: *ho 11(]P 6am mQt axit h" c= =n ch>c t2c OEn6 vXa $ vi O"n6 O3ch aNJ( cU c?n O"6 O3ch sa"n6 th" ;`c 1,(+& 6am m"8i Rhan. VF tn c$a Dxit A l:D. Dxit axetic B. Dxit c t2c OEn6 vi % ml O"n6 O3ch aNJ 1M ;`c O"n6 O3ch mi. *U c?nO"n6 O3ch mi ;`c 1+(P 6am ch!t n Rhan. *Un6 th>c c$a axit l:D. axit n6 ht vi O"n6 O3ch D6N +ton6 J+l!F O;( th" ;`c %1(& 6am D6 Rim lo?i.- dh9n %: *9n 5n6 1 ml O"n6 O3ch NJ %M g t"n6 ho. K#m % axit.

Bi 1%.%: J|n h`< D 6Ym 1 axit v % anOehit( c7 + " no( =n ch>c. r!F m 6am D t2c OEn6 ht vi O"n6 O3chD6N+~J+ ;`c ,P6 D6. GCn6 %m 6am D t2c OEn6 vi l;`n6 O; O"n6 O3ch a%*N+ th" ;`c (&1& l4t *N%.Mt Rh2c


42/74


Bi 1%.+: J|n h`< 6Ym hai axit h" c= no( =n ch>c( m?ch hW. K"n6 ho ](+ 6am bjn6 O"n6 O3ch aNJYi cU c?n O"n6 O3ch sa" n6 th" ;`c 11(& 6am m"8i Rhan. Mt Rh2c( n" cho ](+ 6am t2c OEn6 vil;`n6 O; O"n6 O3ch D6N+ ton6 J+ th# th" ;`c %1(& 6am b?c. *Un6 th>c c$a % axit l:D. J*NNJ *%J,*NNJ B. J*NNJ *J+*NNJ*. *%J,*NNJ *+J\*NNJ G. *J+*NNJ *%J,*NNJ

Bi 1+: *ho h|n h`< 6Ym (1 mol J*NNJ v (% mol J*JN t2c OEn6 ht vi D6N+~J+O; th# Rh8i l;`n6D6 th" ;`c l : D. 1] 6 B. 1(] 6 *. &P(] 6 G. &(P] 6Bi 1P: *ho ,(\& 6am axit h" c= =n ch>c t2c OEn6 ht vi 2 vUi th" ;`c \(%] 6am m"8i. *ho bit tn axittnD. Dxit axetic B. Dxit omic *. Dxit n6 sa" A cho % axit nF n6 vi %, ml O"n6

O3ch aNJ (%&M ;`c O"n6 O3ch D. g t"n6 ho l;`n6 aNJ O; ton6 O"n6 O3ch D c9n

OCn6 5n6 1 ml O"n6 O3ch J*l (%,M. cU c?n O"n6 O3ch D( em 8t ch2F ch!t n cU c?n t?o;`c +(,% 6am *N%v () 6am J%N. *KdK c$a % anOehit D v B l:D. J*JN v *%J,*JN B. J*JN v *%J+*JN*. J*JN v *J+*JN G. *J+*JN v *%J,*JNBi 1]: *h!t l JN-@-*NNJ t2c OEn6 vi *"N( "n nAn6 t?o a anOehit. 1+(, 6am t2c OEn6 vi a%*N+t?o a 1&(] 6am m"8i v *N%. K#m c!" t?o c$a .D. *J+-*J[NJ^-*NNJ B. *J+-*J[NJ^-*J-*NNJ*. JN-*J%-*J%-*NNJ G. hUn6 x2c 3nhBi 1): *ho (P mol mQt h|n h`< 6Ym *J%L*J-*NNJ *J+*NNJ v *J%L*J-*JN n6 vXa $vi O"n6 O3ch &(P 6am Bom. Mt Rh2c( g t"n6 ho (P mol c9n OCn6 vXa $ P ml O"n6 O3ch aNJ(\,M( h8i l;`n6 *J%L*J-*NNJ ton6 l:

D. 1(PP B. %(]] *. (\% G. (,&Bi %: J|n h`< 6Ym axit h" c= f no( =n ch>c v axit h" c= hai ch>c [f nhi" h=n mQt n6"Fn tcacbon^. *hia thnh %


43/74


a~% 0 b L (%, mol

(%, w a 0 b w (,. GHa vo n6 8t ch2F t4nh s8 n6"Fn t cacbon t"n6 b#nh.

1(P wE

w %(]

l!F *% v *+

#huy:n ; !U< .?i t[\ amin4 aminoadit

#eu "< *ho OIF ch"Fgn hAa: lFxin

+aN J

+ J*l

f

lFxin

+J*l

+aNJ

K.f v K l9n l;`t l:D. " l *lJ+*J%*NNa B. *lJ+*J%*NNJ v *lJ+*J%*NNa

*. *lJ+*J%*NNa v J%*J%*NNa G. *lJ+*J%*NNJ v J%*J%*NNa#eu < *ho bit s8 amin bc c$a *PJ11:

D. 1 B. % *. + G.P#eu R< *\J) cA bao nhi" Yn6 1 mol amin tn c9n OCn6 l;`n6 UxF l:

D. [&n0+^~P B. [%n0+^~% *. [&n0+^~% G. [%n0+^~P.

#eu W< hi cho etFlamin vo O"n6 O3ch 'e*l+(hin t;`n6 no x7F a cA:

D. Rh4 baF a B. Rt t$a m" Z nS"

*. Rh4 mCi Rhai baF a G.hUn6 hin t;`n6 6#.



44/74


#eu X< /< x< no sa" SF l 5n6 D. *&J,J% *%J,J% B. *J+J% J+ *%J,J% *. *%J,J% *J+J% *&J,J% G. *&J,J%*J+J% J+

#eu "!< *Un6 th>c ch"n6 c$a amin no =n ch>c( m?ch hW l:D. *nJ%n01 B. *nJ%n01J% *. *nJ%n0+ G. *xJF

#eu ""< *h!t tham 6ia n6 tCn6 n6;n6 lD. *%J,NJ. B. *J%L *J*NNJ. *. J%*J%*NNJ. G. *J+*NNJ.#eu "< g nhn bit + ch!t h" c= J%*J%*NNJ( JNN**J[J%^*NNJ( J%*J[J%^*NNJ( ta

chq c9n th vi mQt ton6 c2c ch!t no sa" SF:D. aNJ B. J*l *. CF t4m G. *J+NJ~J*l

#eu "R< *ho c2c ch!t: etFl axetat( anilin( ancol [;`"^ etFlic( axit acFlic( n6 minh t4nh l;n6 t4nh c$a J%-*J%-*NNJ [^ ( ta cho t2c OEn6 viD. J*l( aNJ. B. a%*N+( J*l. *. JN+( *J+*NNJ. G. aNJ( J+.

#eu "W< Mot amino axit coC coSn6 thCc c c9n 1ml O"n6 O3ch J*l 1M. Dmin A l: D. *J, *. *+J) B. *%J\ G. *+J\

#eu R< *ho \(& 6 hh hai amin =n ch>c( bSc mUt R ti< nha"( t2c OEn6 vXa $ vi %ml OO J*l1M.

*K*K c$a hai amin tn l D. *J+J%( *J+J*J+( B. *J+J%( *%J,J%



45/74


*. *%J,J%(*+J\J% G. 2< 2n Rh2c#eu S< *ho (1 mol [-amino axit O?n6 J%@*NNJ^ n6 ht vi J*l t?o 11(1, 6am m"8i.

l:D. lFxin B. Dlanin *. dhenFlalanin G. Valin

#eu < *ho -amino axit m?ch thn6 cA cUn6 th>c J%@[*NNJ^%n6 ht vi (1 mol aNJ

t?o )(,, 6am m"8i. l: D. Dxit %-aminoa mQt nhAm J%v mQt nhAm *NNJ l"Un l s8 l.* . Kh$F


46/74


#eu RV< *Un6 th>c no sa" SF 5n6 vi tn 6i: Dxit %-amino c c$a % amin lD. *J+J%( *%J,J% B. *+J\J%( *PJ)J%*. *%J,J%( *+J\J% G. *PJ)J%( *,J11J%

#eu S!< *ho )(+ 6am anRFl amin t2c OEn6 vi OO 'e*l+O; th" ;`c 1(\ 6am Rt t$a. anRFl amin lD. *J+J% B. *%J,J% *. *+J\J% G. *PJ)J%

#eu S"< *ho l;`n6 O; anilin n6 vi OO ch>a (, mol J%/NPloIn6( l;`n6 m"8i th" ;`c bjn6:D. %](P 6am B. ](] 6am *. 1)(1 6am G. 1P(% 6am

#eu S< l mQt -aminoaxit m?ch thn6 chq ch>a mQt nhAm J%v mQt nhAm -*NNJ. *ho 1(+6am t2c OEn6 vi OO J*l O; th" ;`c 1+(), 6am m"8i clo"a c$a . *K*K th" 6n c$a l:

D. *J+*J[J%^*NNJ B. J%*J%*NNJ*. J%*J%*J%*NNJ G. *J+*J%*J[J%^*NNJ

#eu SR< *ho \(, 6am axit aminoaxetic [J%-*J%-*NNJ^ n6 ht vi O"n6 O3ch aNJ. /a"n6( Rh8i l;`n6 m"8i th" ;`c l [*ho J L 1( * L 1%( N L 1&( a L %+^

D. 11(, 6am. B. )(] 6am. *. \(, 6am. G. )(\ 6am.#eu SS< 8t ch2F ht amol 1 aminoaxit bjn6 Nxi vXa $ Yi n6;n6 tE h=i n;c ;`c %(,a mol h|n

h`< *N%v %. *Un6 th>c


47/74


#huy:n ; !V< @?i ton #6tc fng vi ff i;m

.?i "J!< thE hon ton %(&]] lit Rh4 *N%[W Rtc^ vo %(, lit OO Ba[NJ^% nYn6 a mol~l th" ;`c 1,(\&6 Rtt$a.i2 t3 c$a a l bao nhi" a.(+% b.(& c.(P O.(P]

.?i J!< thE hon ton P(P] lit Rh4 /N %[W Rtc^ vo OO ch>a 1&6 aNJ th" ;`c OO .h8i l;`n6 m"8i tan th";`c ton6 OO l bao nhi"a.%(]6 b.1]()6 c.%+(6 O.%,(%6.

.?i R/Ec Vlit *N%W Rtc vo 1,ml OO Ba[NJ^%1M(sa" n6 th" ;`c 1)(\6 Rt t$a.i2 t3 c$a V l bao nhi"a.%(%P lit P(P]lit. b.%(%Plit +(+&lit c.+(+&lit %(%Plit O.%%(Plit +(+&lit.

.?i S/Ec %(%Plit *N%W Rtc vo \,ml OO aNJ (%M../8 mol c$a a%*N+v aJ*N+l bao nhi"a.(, v (, b.(& v (& c.(, v (& O.(\ v (,

.?i J!< thE hon ton x lit Rh4 *N%W Rtc vo % lit OO *a[NJ^%(1M th# ;`c 16 Rt t$a.K4nh 6i2 t3 c$a xa.(%%Plit v (&\%lit b.(%%P lit v (++& lit c.(P% lit v (\&% lit. O.(%P lit v (\&% lit

.?i UGn 1 lit h|n h`< Rh4 6Ym %v *N%o W Rtc sEc vo % lit OO *a[NJ^ %(%M th" ;`c 16 Rt t$a.K4nh


48/74


hit c t4nh n6"Fn t Rh8i c$a M theo a v b 2< s8: ML:F

:E

1%(1%

1&&(++

=

B


49/74


*hCn 00< mjt sB ; thi tham hAo

T^OkNG TH*T #H$%&NNG$%N H$&

' TH0 TH 0 H3# 1N THZ H50N89 H3# !!X - !"!

9pN< Hq5 - KHL0 54 .TM 7:6 ?


50/74


#eu Xc c$a cA O?n6 l:5 *&J\N%[N*N*J+^%NJn. *&J\N%[N*N*J+^+n hoc *&J\N%[N*N*J+^%NJn# *&J\N%[N*N*J+^[NJ^%n

, *&J\N%[N*N*J+^+n#eu "!


51/74


#eu c D( B bjn6 J%th" ;`c h|n h`< f. " chof t2c OEn6 ht vi a O; th" ;`c 1(&] l4t J% [Rtc^. " cho \(1 6am h|n h`< t2c OEn6 vi O"n6 O3chD6N+~J+O; th" ;`c P+(% 6am D6. *K*K c$a % anhit l :5 *J+-*JN *J%L*J-*JN . *J+-*JN *J%L*J-*J%-*JN# J*JN *J+-*J%-*JN , J*JN *J%L*J-*JN

#eu R


52/74


#eu RUa 1 lin Rt Ui hai ch>c ,o hai ch>c#eu S


53/74


5 O"n6 O3ch aNJ( O"n6 O3ch bom . O"n6 O3ch J*l( O"n6 O3ch mnNP# O"n6 O3ch bom( {" t4m , {" t4m( O"n6 O3ch bom#eu !c c l :5 *l-*J%-*NN-*J%-*J+ . *J+-*NN-*J%-*J%*l# *J+- *J*l- *NN -*J+ , *J+-*NN-*J*l-*J+#eu V


54/74


#eu U!


55/74


#eu "!< J}a tan hon ton &( 6am h|n h`< hai Rim lo?i ton6 O"n6 O3ch J*l O; th!F t?o a P(P] l4t Rh4 J%[Rtc^. *U c?n O"n6 O3ch sa" n6 th" ;`c m 6am m"8i Rhan. i2 t3 c$a m l

5%(&. .%(%. # 1+(+. , 1+(1.#eu ""n6 minh c *JN.# dh7n >n6 vi , n6 minh cA , nhAm NJ ton6 n6 minh c th# th" ;`c anehit.. dh;=n6 c bc 1 l cho an Ren cQn6 n;c.# "n nAn6 ancol metFlic vi J%/NPc W 1\* th" ;`c ete., Dncol a ch>c h}a tan *"[NJ^%t?o thnh O"n6 O3ch m" xanh.

#eu !< J|n h`< cA % este =n ch>c l Yn6


56/74


#D6N+~ J+ *J+J% *%J,NJ NJ a%*N+. ,a%N a*l 'e*J+NJ *%J,*l.#eu


57/74


#eu RRn6t?m thi l

5%. .+. #P. ,,.*HN ^0&NG "! ceuxKh4 sinh chq ;`c lm mQt ton6 hai Tho ch;Yng tGnh chun>#eu S"< *A mQt lo?i n6 t;c hiOo ton6 OIF in hAa^ bjn6O"n6 O3ch J*l O;( th" ;`c %(%P l4t Rh4 J%[Rtc^. g h}a tan %(P 6am th# c9n OCn6 ch;a n %,ml O"n6O3ch J*l 1M. im loai l

5Ba. .n. #*a. ,M6.#eu S< 8t mQt l;`n6 Dl ton6 &(\% l4t N%. *h!t n th" ;`c sa" n6 cho h}a tan hon ton vo O"n6O3ch J*l th!F tho2t a &(\% l4t J%[ c2c thg t4ch Rh4 o W Rtc^. h8i l;`n6 Dl I OCn6 l

51&(% 6am. .,(P 6am. #](1 6am. ,1(] 6am.



58/74


#eu SU


59/74


#eu W


60/74


#eu W


61/74


#eu


62/74


#eu Ra 1 m"8iO"F nh!t. i2 t3 c$a m l:5 +(1\ . %(,& # 1()% , +(%

#eu S!c c!" t?o c$a % axit l:

5 JNN*-[*J%^+-*NNJ. . JNN*-*J%-*NNJ.# JNN*-*J%-*J%-*NNJ. , JNN*-[*J%^P-*NNJ.

#eu Sc c!" t?o c$a D1l:5 J*NN*J%*J+. . *J+*N*J%NJ.# *J+*J%*NNJ. , JN*J%*J%*JN.

#eu SR


63/74


#eu SUn6( O"n6 O3ch 6l"coz=( O"n6 O3ch 6lixeol(O"n6 O3ch metanal( etanol. JAa ch!t A l:

5 *"[NJ^%. . MnNP # JN+c , J*l#eu


64/74


5 P . % # + , 1#eu X


65/74


dh9n 1 cho t2c OEn6 vi O"n6 O3ch aNJ O; th" ;`c 1(] l4t J %[Rtc^ v c}n l?i ,(P6 ch!t n RhUn6tan.

dh9n % cA Rh8i l;`n6 %)(\)6am( cho t2c OEn6 vi O"n6 O3ch JN +loIn6 O; th" ;`c ](&P l4t N [Rtc( ls7n a (+ mol D6N +~J+th";`c %1(&6 D6. l:

5 %-metFlb"t-+-inal . B"t-1-inal #b"t-%-inal , B"t - +- inal#eu ""a Ba%0( NJ-( /%-. KQn vi f cA thg x7F a baonhi" n6 hAa hc

5 \ . , # ] , eu "


66/74


#eu "c Yn6 n6 lin tic c$a % ancol l:5 *PJ)NJ v *,J11NJ . *J+NJ v *%J,NJ# *%J,NJ v *+J\NJ , *+J\NJ v *PJ)NJ

#eu Ra 0 J*N+-: (& mol*N+%-: (, mol th" ;`c m 6am Rt t$a. i2 t3 c$a m l:

5 1,(\& 6am . 1+()\ 6am # 1)(\ 6am , %1(&\ 6am#eu X


67/74


#eu RSc cA s8 nhAm NJ bjn6 s8 n6"Fn t cacbon. Kon6 ( J chim x!< xq 1kv Rh8i l;`n6. "n nAn6 vi ch!t x5c t2c W nhit Q th4ch h`< g lo?i n;c th# th" ;`c mQt ch!t h" c= fcA MfL M 1]. t l"n no sa" SF h`< l nh!t:

5 Kq Rh8i h=i c$a f so vi l (] . l 6lixeol# f l anehit acFlic , f l etanal

#eu Ra m"8i s"nat v V l4t N [Rtc^ l s7n


68/74


#eu SS< G"n6 O3ch ch>a c2c ion : Ba%0( a0( J*N+-( *l-ton6 A s8 mol *l-l (%P. *ho O"n6 O3ch t2cOEn6 vi O"n6 O3ch aNJ O; th" ;`c )(],6 Rt t$a. *ho O"n6 O3ch t2c OEn6 vi O"n6 O3ch Ba[NJ^ %O;th" ;`c 1,(\&6 Rt t$a. " "n sUi O"n6 O3ch n c?n th# th" ;`c m 6am ch!t n Rhan. i2 t3 c$a m l :

5 1,(]1 . 1](%) # +1(&% , +&(,]#eu Sc^. JAa h=i hon ton m6am M th" ;`c thg t4ch h=i bjn6 thg t4ch c$a \ 6am nit= o cCn6 i" Rin nhit Q( 2< s"!t. " cho m 6am M t2cOEn6 vi a O; th" ;`c P(P] l4t J%[Rtc^. hi 8t ch2F hon ton m 6am M th" ;`c %](&6 *N%. *Un6 th>c n6 nh R4nh

5N . *N%. # /N%. , *N

#eu


69/74


#eu V< *ho tX tX n O; O"n6 O3ch J+l9n l;`t vo c2c O"n6 O3ch sa": *"*l%( Dl*l+( 'e[N+^+( i/NPD6N+( M6/NP. /a" Rhi c2c n6 x7F a hon ton( s8 Rt t$a th" ;`c l:

5 % . P # , , +#eu Wc c$a axit

5 *J+*NNJ . *%J+*NNJ # *+J,*NNJ , *%J,*NNJ----------- JK ----------

KHL0 TH*T #H$%&NH Q$p# G05 H/ N~0

THI TH I HC ! CA" #NG MN HA HC$H%I A

NN HC 2010 ! 2011 LN II

0 *HN #H$NG #H6 TT #Y TH D0NH S! ceu4 t| ceu "}n ceu S!x

#eu "cc!" t?o c$a thZa mIn l:

5 , . & # + , P#eu


70/74


#eu Xa F mol *"/N Pv z mol J%/NP loIn6( sa" n6hon ton th" ;`c Rh4 J%( m 6am *" v O"n6 O3ch chq ch>a mQt ch!t tan O"F nh!t. M8i {"an h 6ia F v z l

5 F L \z. . F L ,z. # F L z. , F L +z.#eu "


71/74


#eu c c c!" t?o c$a v 6i2 t3 c$a m l

5 J*NN*J%*J+v ](]] 6am. . *J+*NN*J+v&(&& 6am.# *%J,*NNJ v ](]] 6am. , *%J,*NNJ v &(&& 6am.

#eu R!c( m?ch hW ;`c +(,]P l4t *N % [Rtc^ v %(+P 6am J%N. " cho1, 6am t2c OEn6 vi % ml O"n6 O3ch aNJ 1M( cU c?n O"n6 O3ch sa" n6 th" ;`c 1P(+ 6am ch!t nRhan. VF cUn6 th>c c$a ancol t?o nn este tn cA thg l

5 *J%L*J-NJ . *J+NJ # *J+*J%NJ , *J%L*J-*J%NJ#eu R"c( m?ch hW. 8thon ton h|n h`< + ch!t tn [cA s8 mol bjn6 nha" th" ;`c tq l mol 6ia *N%v J%N l 11:1%. *Un6 th>c


72/74


#eu RS


73/74


#eu SUc


74/74


5 1%(] 6am . %,(& 6am # %%(P 6am , 1)(% 6am#eu V

tuyen chon bai tap luyen thi dai hoc hoa hoc

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