turco 5351 msds

MATERIAL SAFETY DATA SHEET

DATE OF ISSUE: 24.02.09 REVISION OF: 28.04.06 IDH NO: 377680Page 1 of 5 PRODUCT NAME: TURCO 5351

SECTION 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Product Name: TURCO 5351

Proper Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (CONTAINS 54% w/wDICHLOROMETHANE AND 17% w/w PHENOL)

Product Code(s): 377809 (20 litres), 377813 (200 litres), 382778 (4x5 litres)

Use: Industrial grade paint stripper.

Supplier: HENKEL AUSTRALIA PTY. LIMITED ABN 82 001 302 996ADHESIVE TECHNOLOGIES135-141 Canterbury Road, Kilsyth, Victoria,3137 Tel: (03) 9724 644424 HOUR EMERGENCY CONTACT NUMBER Tel: 1800 032 379

SECTION 2. HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE:Hazardous according to the criteria of ASCC. This material has been classified as Toxic (T), Corrosive(C) and Harmful (Xn).

Risk phrase(s):R20 Harmful by inhalation.R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.R34 Causes burns.R41 Risk of serious damage to eyes.R42/43 May cause sensitisation by inhalation and skin contact.R45(2) May cause cancer (Category 2, Carcinogen)R46(2) May cause heritable genetic damage (Category 2 mutagen).R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure throughinhalation, in contact with skin and if swallowed.R60(2) May impair fertility (Toxic to Reproduction, Category 2).R61(2) May cause harm to the unborn child (Toxic to Reproduction, Category 2).R68 Possible risk of irreversible effects (Mutagenic Category 3).

Safety phrase(s):S23 Do not breathe vapour.S24/25 Avoid contact with skin and eyes.S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S27 Take off immediately all contaminated clothing.S28 After contact with skin, wash immediately with plenty of soap and water, then methylated spirit ifavailable. Seek medical advice.S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.S45 In case of accident or if you feel unwell, seek medical advice immediately (show the labelwhenever possible.)

DANGEROUS GOODS INFORMATION:Classified as Dangerous Goods according to the criteria of the Australian Code for the Transport ofDangerous Goods by Road and Rail (ADG Code).

Class: 6.1 -ToxicSubsidiary Risk: 8 - Corrosive

SUSDP POISON SCHEDULE: 6



SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

INGREDIENTS:

CHEMICAL ENTITY CAS NO. PROPORTIONDichloromethane [75-09-2] 54% w/wPhenol [108-95-2] 17% w/wSodium dichromate,anh. [10588-01-9]



safe for human contact. Note: Residues are not water soluble. Wash down waters may still containresidues which require treatment through local effluent treatment plant. Do not contaminatewatercourse. Dispose of residues in chemical waste disposal area in accordance with relevant Stateand Federal requirements.

SECTION 7. HANDLING AND STORAGE

Safe Handling: Observe recommendations made under SECTION 8. EXPOSURECONTROLS/PERSONAL PROTECTION. Always handle with impervious gloves and chemical splashgoggles. Use in a well ventilated area. This product contains dichloromethane which is a highlyvolatile solvent. Precautions should be taken to minimise vapour concentrations in the workenvironment. Workers should not work alone when dichloromethane is used in open tanks for paintstripping.2

Storage: Store indoors in a cool, dry, well ventilated area. Keep containers sealed when not in use.Containers may explode if heated beyond 60?C. Protect from physical damage. Keep away fromincompatible materials. Store according to relevant State Dangerous Goods Storage Requirements.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

National exposure standards: TWA : 1 ppm (4 mg/m3) as phenol 50 ppm (174 mg/m3) as dichloromethane

Engineering controls: A local mechanical exhaust system is required where vapour or mistis being generated.

Personal protective equipment: Use good industrial hygiene. Avoid contact with skin and eyes.Wear suitable protective clothing, safety footwear, silver shield/4H gloves and chemical splashgoggles or full face shield. Use in a well ventilated area. If inhalation risk exists, wear an organicvapour respirator or air supplied mask complying with the requirements of AS 1715 and AS 1716.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical data:Appearance: Viscous yellow two phase liquid.Specific gravity 1.17-1.18 @ 20COdour: PhenolicSolubility: Partially soluble in waterBoiling point: 40C approximately

SECTION 10. STABILITY AND REACTIVITY

Chemical stability: Stable under normal conditions of temperature and pressure.Conditions to avoid: Avoid strong heat sources and open flames.Incompatible materials: Keep away from alkalies, powdered metals and strong oxidising agents.Hazardous decomposition products: When heated to decomposition, it will emit toxic fumes ofphosgene and acrid smoke.Hazardous reactions: Will not polymerise.

SECTION 11. TOXICOLOGICAL INFORMATION

HEALTH EFFECTS:

Acute:Ingestion: Toxic if swallowed. This product can cause serious burns to the mouth, throat

and digestive tract. Systemic effects by ingestion may include nausea,vomiting, stomach pain, blood disorders, convulsions, a change in cardiac rate,coma and damage to the liver, kidneys and pancreas.



Skin: Toxic and corrosive to skin. Absorption of this product through the skin maycause serious effects to the central nervous system, liver, kidneys and spleen.May cause sensitisation by skin contact.

Eyes: Liquid contact with the eyes can cause severe burns which may result inpermanent injury or even blindness.

Inhalation: Inhalation of vapour or mist may cause respiratory irritation and burns to themucous membranes. Exposure to high concentrations of vapour may causeirregular heartbeat, headache, lung congestion and narcosis. May causerespiratory sensitisation.

Chronic: This material can cause corrosive damage to skin tissue. Long term inhalationexposure may lead to blood disorders, kidney and liver damage, chest pain andharmful effects on the central nervous system. Dichloromethane is regarded asa Category 3 Carcinogen. This product contains less than one percent sodiumdichromate, which is classified as a Category 2 Carcinogen, Category 2Mutagen and is Toxic to reproduction (Category 2)

Toxicity information: Acute Oral LD50 (rat) : 2136 mg/kg as dichloromethane4Inhal TCLo (human) : 500 ppm as dichloromethane4Acute Oral LDLo (human) : 140 mg/kg as phenol4

SECTION 12. ECOLOGICAL INFORMATION

Do not contaminate waterways and soil. This product will cause harmful effects to aquatic life.Dichloromethane is not readily biodegradable.

Fish toxicity: 96 h LC50 (P.promelas) : 310 mg/l as dichloromethane5 96 h LC50 (Oncorhynchus mykiss) : 5.4 mg/l as phenol6

Daphnia toxicity: 48 h EC50 (Daphnia magna) : 1682 mg/l as dichloromethane5 48h EC50 (Daphnia magna) : 10 mg/l as phenol6

SECTION 13. DISPOSAL CONSIDERATIONS

Dispose of residues in chemical waste disposal area in accordance with relevant State and Federalrequirements. Empty containers should be left open to allow residual solvents to evaporate and thentriple rinsed with fresh water prior to disposal to drum reconditioner or approved landfill site.

SECTION 14. TRANSPORT INFORMATION

UN Number: 2927 Proper Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (CONTAINS 54% w/w

DICHLOROMETHANE AND 17% w/w PHENOL)Class: 6.1, ToxicSubsidiary Risk: 8, CorrosivePacking Group: IIHazchem code: 2XEEmergency Information: Dangerous Goods-Initial Emergency Response Guide (SAA/SNZ HB 76),

Guide 36 or EPG 6J4.

SECTION 15. REGULATORY INFORMATION

SUSDP POISON SCHEDULE: 6



SECTION 16. OTHER INFORMATION

Abbreviations/acronyms:ASCC - Australian Safety and Compensation CouncilSUSDP - Standard for the Uniform Scheduling of Drugs and PoisonsTWA - Time-weighted average

References:1. NIOSH, International Chemical Safety Cards, Phenol, October 20012. NICNAS Alert No.3. Caution required for Methylene Chloride in Paint Stripping, Existing Chemicals, July 20043. Quick Selection Guide to Chemical Protective Clothing, Fifth Edition, 2007: Forsberg and

Mansdorf, Wiley-Interscience3.4. Sax and Lewis, Dangerous Properties of Industrial Materials, 7th Edition (1989).5. Ecological data: Merck MSDS for Dichloromethane, Aug. 20016. Ecological data: Merck MSDS for Phenol, Jan. 2003

DISCLAIMER:

The percentage weight (% w/w) of ingredients is not to be taken as a specification guaranteed byHenkel Australia Pty. Limited, but only as an approximate guide to the content of hazardousingredients in the material. The information contained herein does not constitute a guarantee byHenkel Australia Pty. Limited concerning the properties of the material.

The information contained in this Material Safety Data Sheet is offered in good faith and has beendeveloped from what is believed to be accurate and reliable sources. The information is offeredwithout warranty, representation, inducement or licence and Henkel Australia Pty. Limited assumesno legal responsibility for reliance upon same. Henkel Australia Pty. Limited disclaims any liability forloss, injury or damage incurred in connection with the use of the material or its associated MaterialSafety Data Sheet.

This information is not to be construed as a representation that the material is suitable for anyparticular purpose or use except those conditions and warranties implied by either Commonwealth orState statutes. Customers are encouraged to make their own enquiries as to the material'scharacteristics and, where appropriate, to conduct their own tests in the specific context of thematerial's intended use.

turco 5351 msds

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