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Author(s)

Citation Bulletin of the Institute for Chemical Research, KyotoUniversity (1980), 57(5-6)

Issue Date 1980-01-31

URL http://hdl.handle.net/2433/76853

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Type Others

Textversion publisher

Kyoto University

ISSN 0023-6071

BULLETIN OF THE INSTITUTE

FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

Vol. 57, Nos. 5-6

Published bi-monthly by

THE INSTITUTE FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

KYOTO, JAPAN

November, 1979

(Bull. Inst. Chem. Res., Kyoto Univ.)

INSTITUTE FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

I3irector

Megumi Tasxrxo

lVlembers of Council

Yoshichika BANDO Eiichi FuJITA Hiroshi INAGAKIYuzo INouYE Ryqzo KITAMARu Naokazu KolzuMI

Michio KURATA Shinzaburo Oxa Masaya Oxa--oTatsuo Ool Tsunenobu SHIGEMATsu Toshio TAKADAMitsuru TAKANAMI. Hidekuni TAKEKosHI Tohru TAKENAKAYOS111ri1�.S�. TAKEZAKI Megumi TA$HIRO N$LSU UYEDATatsuo YAMAMoTo T稾uj i YANABu

Publication Committee

Naokazu KolzuMI Tadashi KoKuBo Michio KuRATAHIT'Oril禊祟AZAKI M禊�.ya, OKANO SIIO TAKAHASHI

Business Staff

K�.tSUtOSIll MIURA KUri1111kO SASAKI YOriCZO TANAKA

History of Publications

Term I Vol. I Title I Published

Jan.,1929‐Dec.,1947卜16鱗 響 …藩 ・一 …te for・-1一 蜘

・…1,1933 -ioCTヒ 繍 嶽 搬 鴇 構 翻he Fo「schung -

March 1949_ 化 研 講 演 集 . .

Dec.,ff1949f」17-19(The Reports of the lnstitute for Chemical lndeterminatelyResearch)

March 1950_ 化 学 研 突 所 報 告 .

・・p…195220-30≦Bulletin of the lnstearch) 血te fo「Chem'ca'Re-()ua「te「'y

The Commemoration Volume for the SilverDec,,1951 - Jubilee -

(化 学 研 究所 創 立 二 十 五 周 年 記念 号)

Jan.,19530nwards 31No.1‐ぞ鶴 燕 婁 務nst'tute fo「Chcm'ca'Resea「ch Bi-m・n・hly

Nov.,196644N o.・ 講 講 藷 鱒 罵 ㎡t比 一

Nov.,19・654N o.・ 鶴 鎌 灘 灘 罪 舳 ㎡t地 一

CONTENTS

Masakazu Matsui, Jun'ichi Toei, Shigeo Umetani, and Tsunenobu Shigematsu: 4-Acy1-5-Pyrazolones as an Analytical Reagent (II). Applicability of

Halogen Substituted 4-Acyl-5-Pyrazolones to the Solvent Extraction of Metals ...................................................................................................337

Hidekazu Doe, Masakazu Matsui, and Tsunenobu Shigematsu : Nonaqueous Liquid-Liquid Extraction: Solvent Extraction Studies of Zinc Chloride

and Perchlorate Complexed in Glycols ......................................................343 Tetsu Kumagai, Masakazu Matsui, Toru Aoki, Atsuko Yamashita, and Tsune-

nobu Shigematsu: Forced-Flow Chromatography of Alkali Earth Ions De- tected by Photometric Method..................................................................349

Tadashi Kokubo, Masayuki Arioka, and Megumi Tashiro: Preparation of Li2O.2SiO2 Ceramics with Oriented Microstructures by Unidirectional

Solidification of Their Melts.....................................................................355 Taitiro Fujinaga, Satoshi Okazaki, and Hiroyuki Hirai : Flow Coulometry with

Ring-Disk Electrode.................................................................................376 Shigeo Tanimoto, Norio Yoshida, Toyonari Sugimoto, and Masaya Okano :

Preparation of 3-Aryl-2H-1,2,4-benzothiadiazine 1,1-Dioxides by the Reaction of o-Aminobenzenesulfonamide with Aromatic Carboxylic Acid

Derivatives .............................................................................................381

Review

Eiichi Fujita, Kaoru Fuji, Yoshimitsu Nagao, and Manabu Node: The Chemistry on Diterpenoids in 1978. Part-II.............................................385

Abstracts......................................................................................................411

BULLETIN OF THE INSTITUTE

FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

Vol. 57

Published bi-monthly by

THE INSTITUTE FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

KYOTO, JAPAN

197 9

(Bull. Inst. Chem. Res., Kyoto Univ.)

Contents of Volume 57,1979

Lyle B. Borst: Rotation in Molecular Crystals................................................1 Toshiyasu Higo, Seishi Matsuki, Yoshihisa Iwashita, Akira Okihana, Noboru

Fujiwara, and Takuji Yanabu: Efficiency Calculation and Measurement of Large NE213 Neutron Counter .........................................................13

Nobuhiro Maeda, Naoto Kobayashi, Toshio Kusakabe, and Masakatsu Sakisaka : Production of Multiply Ionized Atoms by Ion-Atom ColIisions .....................23

Takeshi Mukoyama and Laszlo Sarkadi : Electronic Relativistic Effects in K- Shell Ionization by Charged-Particle Impact ..........................................33

Toshiro Takabatake and Hiromasa Mazaki: Superconducting and Magnetic Properties of Dilute Tc-(Fe) Alloys .........................................................45

Takekazu Ishida and Hiromasa Mazaki: Complex Susceptibility Measurement of Superconducting Transition of Electrodeposited Technetium .....................55

Seishi Matsuki, Yasuko Inoue, Seishi Noguchi, and Sukeaki Yamashita: Mini- computer On-line System for Measuring Projector of Bubble Chamber Film......67

Yoshihisa Watanabe and Takeshi Mukoyama: Excitation of Nuclear Isomers by

y Rays from 6OCo..............................................................................72 Shigeru Kakigi, Kiyoji Fujinaga, Takao Ohsawa, and Seiji Tanaka: Three-

Particle Relativistic Kinematics ............................................................83 Kiyoji Fukunaga and Shigeru Kakigi: Computer Program for Three Body

Break up Reaction..............................................................................92 Kazuo Shin, Mitsuo Yoshida, Yoshitomo Uwamino, Tomonori Hyodo, and

Takashi Nakamura: Experimental Research on Penetration of Neutrons and Photons Produced in Graphite Target Bombarded by 52-MeV Protons......102

Morihisa Yamagishi, Takanori Niki, Atsunobu Hiraoka, and Haruto Uchino: Effect of an Antrogen on the Radiosensitivity and Recovery after Irradiation

of Mouse Hemopoietic Cells ...............................................................112 Melvin S. Freedman : New Experimental Approaches to the Detection of Solar

Neutrinos .......................................................................................117 Shiro Hine, Teruya Shinjo, and Toshio Takada: The Stability of Evaporated

Fe Films Sandwiched with Various Materials; A Mossbauer Study ...............130 Denes Berenyi: The Ke,/Kp Ratio for X-ray Transitions in Higher Energy

Collision Processes ...........................................................................139

Junko Miyajima, Takehiro Nisidai, and Hidekuni Takekoshi: Fast Neutron Fields Produced by Kyoto University Cyclotron ....................................147

Kunihiro Osaki, Kanji Kajiwara, Nobuo Bessho, and Michio Kurata: Time- Dependent Flow Fields in a Coaxial Cylinder Rheometer. The Flow of a

BKZ Fluid at the Start of Rotation ......................................................169 Hiroo Iwata and Yoshito Ikada: Intramolecular Crosslinking in Gelation.........184 Suong-Hyu Hyon and Ryozo Kitamaru: Structure and Properties of Lightly

Crosslinked Polyvinylidene Fluoride Crystallized from the Deformed Molten State .................................................................................193

11

Akiyoshi Kawaguchi : Structural Changes of Polyethylene Single Crystal due to Electron Irradiation .....................................................................206

Yasushi Kubota, Sho Takahashi, and Tatsuo Ooi : An Integral Method to Analyze Sedimentation Equilibrium......................................................220

Hisashi Odani, Kazuo Taira, Norio Nemoto, and Michio Kurata: Transport and Equilibrium Phenomena of Gases in Styrene-Butadiene Block Copoly-

mers .............................................................................................226 Shigeo Tanimoto, Shingo Iwata, Tamotsu Imanishi, Toyonari Sugimoto, and

Masaya Okano : Interchange Reactions of Diphenyl Acetals and Alkyl Dialkylaminomethyl Ethers with Thiols ................................................235

Yasumasa Sakakibara, Koichi Aiba, Mutsuji Sakai, and Norito Uchino: A Study on the Oligomerization of Olefins by Nickel Complexes. VI. A Kinetic Study of Propylene Dimerization Catalyzed by Bis(acetylacetonato)

nickel (II) -Triethyldialuminium Trichloride-Triphenylphosphine ...............240 Yasuhiro Kariya, Tatsuo Yamamoto, Yoshihiro Sameshima, Tetsuo Yoshida,

Akira Kimura, and Tatsurokuro Tochikura: Fermentative Phosphory- lation of Glucosamine by Yeast ............................................................245

Yasushi Kubota, Sho Takahashi, and Tatsuo Ooi: Subunit-Monomer Equili- brium of Maleylated Tropomyosin ......................................................254

Heung Lark Lee, and Taitiro Fujinaga: Polarographic Behavior of Metal Acetylacetonates in Acetylacetone as New Non-aqueous Electrochemical

Medium .......................................................................................285 Tetsuya Hanai, Koji Asami, and Naokazu Koizumi: Dielectric Theory of

Concentrated Suspensions of Shell-Spheres in Particular Reference to the Analysis of Biological Cell Suspensions ...................................................297

Toshihiko Shigematsu, Shiro Hine, and Toshio Takada: Mossbauer Studies on

Supersaturated FeSb Solid Solutions ...................................................306 Toshihiko Shigematsu, Teruya Shinjo, Yoshichika Bando, and Toshio Takada:

Formation of Metastable Phases in Vapor-Deposited FeSb Films ..................310 Ryozo Kitamaru, Fumitaka Horii, Kazuo Ogawa, Takashi Yasuda, and

Tsumuko Okuno : The Mechanism of Dyeing and Phase Structure of Nylon 6 Fiber by Broad-Line 111 NMR Spectroanalysis ..............................318

Jiro Nakanishi, Junzo Umemura, and Tohru Takenaka : Vibrational Spectra and Normal Vibrations of Tetracyanothiophene Anion Radicals ..................329

Masakazu Matsui, Jun'ichi Toei, Shigeo Umetani, and Tsunenobu Shigematsu: ° 4-Acyl-5-Pyrazolones as an Analytical Reagent (II). Applicability of

Halogen Substituted 4-Acyl-5-Pyrazolones to the Solvent Extraction of Metals .......................................................................................337

Hidekazu Doe, Masakazu Matsui, and Tsunenobu Shigematsu: Nonaqueous Liquid-Liquid Extraction : Solvent Extraction Studies of Zinc Chloride and

Perchlorate Complexed in Glycols.........................................................343

•

Tetsu Kumagai, Masakazu Matsui, Toru Aoki, Atsuko Yamashita, and Tsune-

nobu Shigematsu: Forced-Flow Chromatography of Alkali Earth Ions

Detected by Photometric Method .........................................................349

Tadashi Kokubo, Masayuki Arioka, and Megumi Tashiro: Preparation of

ui

Li2O.2SiO2 Ceramics with Oriented Microstructures by Unidirectional

Solidification of Their Melts ...............................................................355 Taitiro Fujinaga, Satoshi Okazaki, and Hiroyuki Hirai : Flow Coulometry with

Ring-Disk Electrode ........................................................................376 Shigeo Tanimoto, Norio Yoshida, Toyonari Sugimoto, and Masaya Okano:

Preparation of 3-Ary1-2H-1,2,4-benzothiadiazine 1,1-Dioxides by the Reaction of o-Aminobenzenesulfonamide with Aromatic Carboxylic Acid

Derivatives ....................................................................................381

Note

Chihiro Kikuchi: Story of Ruby Maser ......................................................157

Communication

Kazuko Fukumura, Takayuki Kobayashi, and Yasuyuki Nakayama : A Study on Electron Irradiation Effects in Hydrated Cobalt Ferricyanide Using

Mossbauer Spectroscopy.....................................................................164

Reviews

Eiichi Fujita, Kaoru Fuji, Yoshimitsu Nagao, and Manabu Node: The Chemistry on Diterpenoids in 1978. Part-I ..........................................260

Eiichi Fujita, Kaoru Fuji, Yoshimitsu Nagao, and Manabu Node: The Chemistry on Diterpenoids in 1978. Part-II ..........................................385

iv

Author Index to Volume 57, 1979

Aiba, Koichi..........................................................................................240 Aoki, Toru ..........................................................................................349 Arioka, Masayuki .................................................................................355 Asami, Koji ..........................................................................................297 Bando, Yoshichika .................................................................................310 Berenyi, Denes.......................................................................................139 Bessho, Nobuo.......................................................................................169 Borst, Lyle B. .......................................................................................1 Doe, Hidekazu.......................................................................................343 Freedman, Melvin S ..............................................................................117 Fuji, Kaoru ....................................................................................260, 385 Fujinaga, Kiyoji ....................................................................................83 Fujinaga, Taitiro..............................................................................285, 376 Fujita, Eiichi .................................................................................260, 385

Fujiwara, Noboru .................................................................................13 Fukumura, Kazuko.................................................................................164 Fukunaga, Kiyoji....................................................................................92 Hanai, Tetsuya ....................................................................................297 Higo, Toshiyasu ....................................................................................13 Hine, Shiro ....................................................................................130, 306

Hirai, Hiroyuki ....................................................................................376 Hiraoka, Atsunobu .................................................................................112 Horii, Fumitaka ....................................................................................318

Hyodo, Tomonori .................................................................................102 Hyon, Suong-Hyu .................................................................................193 Ikada, Yoshito.......................................................................................184 Imanishi, Tamotsu .................................................................................235 Inoue, Yasuko .......................................................................................67 Ishida, Takekazu....................................................................................55 Iwashita, Yoshihisa.................................................................................13 Iwata, Hiroo .......................................................................................184 Iwata, Shingo .......................................................................................235 Kajiwara, Kanji ....................................................................................169 Kakigi, Shigeru .................................................................................83, 92 Kariya, Yasuhiro .................................................................................245 Kawaguchi, Akiyoshi ..............................................................................206 Kikuchi, Chihiro....................................................................................157 Kimura, Akira.......................................................................................245 Kitamaru, Ryozo..............................................................................193, 318 Kobayashi, Naoto .................................................................................23

V

Kobayashi, Takayuki ..............................................................................164 Koizumi, Naokazu .................................................................................297 Kokubo, Tadashi....................................................................................355 Kubota, Yasushi ..............................................................................220, 254

Kumagai, Tetsu ....................................................................................349 Kurata, Michio ..............................................................................169, 226

Kusakabe, Toshio .................................................................................23 Lee, Heung Lark....................................................................................285 Maeda, Nobuhiro .................................................................................23 Matsui, Masakazu .....................................................................337, 343, 349 Matsuki, Seishi....................................................................................13, 67 Mazaki, Hiromasa ..............................................................................45, 55

Miyajima, Junko....................................................................................147 Mukoyama, Takeshi ...........................................................................33, 72 Nagao, Yoshimitsu ...........................................................................260, 385 Nakamura, Takashi.................................................................................102 Nakanishi, Jiro.......................................................................................329 Nakayama, Yasuyuki ..............................................................................164 Nemoto, Norio.......................................................................................226 Niki, Takanori.......................................................................................112 Nishidai, Takehiro .................................................................................147 Node, Manabu.................................................................................260, 385 Noguchi, Seishi ....................................................................................67

Odani, Hisashi.......................................................................................226 Ogawa, Kazuo.......................................................................................318 Ohsawa, Takao ....................................................................................83 Okano, Masaya ..............................................................................235, 381 Okazaki, Satoshi ....................................................................................376 Okihana, Akira ....................................................................................13 Okuno, Tsumuko....................................................................................318 Ooi, Tatsuo ....................................................................................220, 254 Osaki, Kunihiro ....................................................................................169 Sakai, Mutsuji .......................................................................................240 Sakakibara, Yasumasa ...........................................................................240 Sakisaka, Masakatsu ..............................................................................23 Sameshima, Yoshihiro..............................................................................245 Sarkadi, Laszlo ....................................................................................33 Shigematsu, Toshihiko .....................................................................306, 310 Shigematsu, Tsunenobu...............................................................337, 343, 349 Shin, Kazuo..........................................................................................102 Shinjo, Teruya.................................................................................130, 310 Sugimoto, Toyonari ........................................................................235, 381 Taira, Kazuo .......................................................................................226 Takabatake, Toshiro ..............................................................................45 Takada, Toshio ........................................................................130, 306, 310

vi

Takahashi, Sho ..............................................................................220, 254 Takekoshi, Hidekuni ..............................................................................147 Takenaka, Tohru....................................................................................329 Tanaka, Seiji .......................................................................................83 Tanimoto, Shigeo ...........................................................................235, 381 Tashiro, Megumi....................................................................................355 Tochikura, Tatsurokuro...........................................................................245

Toei, Jun'ichi .......................................................................................337 Uchino, Haruto ....................................................................................112 Uchino, Norito.......................................................................................240 Umemura, Junzo....................................................................................329 Umetani, Shigeo ....................................................................................337 Uwamino, Yoshitomo..............................................................................102 Watanabe, Yoshihisa ..............................................................................72 Yamagishi, Morihisa ..............................................................................112 Yamamoto, Tatsuo.................................................................................245 Yamashita, Atsuko .................................................................................349 Yamashita, Sukeaki.................................................................................67 Yanabu, Takuji ....................................................................................13 Yasuda, Takashi '.........................................................................................318 Yoshida, Mitsuo ....................................................................................102 Yoshida, Norio.......................................................................................381 Yoshida, Tetsuo ....................................................................................245

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