Thiophanate Methyl Label

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<ul><li><p>For the prevention and control of turf diseases. Not for homeowner use.ACTIVE INGREDIENT:Thiophanate-methyl (dimethyl 4,4-o-phenylenebis[3-thioallophanate] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19.4%OTHER INGREDIENTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80.6%</p><p>TOTAL . . . . . . . . . . . . . . . . . . . .100%*This product contains 2.0 lbs thiophanate methyl per gallon.</p><p>KEEP OUT OF REACH OF CHILDRENWA R N I N G</p><p>EPA Reg. No. 1001-78EPA Est. No. 70815-GA-1CLEARY CHEMICALS LLC178 Ridge Rd., Suite ADayton, NJ 08810-1501732-329-8399800-524-1662</p><p>Notification: 09.07.2010Version: 09.02.2011Replaces: 09.15.09</p><p>For emergency information, call (732) 329-8399 or your poison control center. For medical or transportation emergencies only call 24 hours a day CHEMTREC (800)424-9300. Have the product container or label with you when calling a poison control center or doctor, or going for treatment.</p><p>IF ON SKIN OR CLOTHING</p><p>IF SWALLOWED</p><p>IF IN EYES</p><p>IF INHALED</p><p> Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for further treatment advice.</p><p> Call poison control center or doctor for treatment advice. Do not induce vomiting unless told to do so by the poison control center or doctor. Have person sip a glass of water if able to swallow. Do not give anything by mouth to an unconscious person.</p><p> Hold eye open and rinse slowly and gently with water for 15-20 minutes.</p><p> Call a poison control center or doctor for further treatment advice.</p><p> Move person to fresh air. </p><p>preferably mouth-to-mouth, if possible. Call poison control center or doctor for treatment advice.</p><p>FIRST AID</p><p>file: 56743_book_art created by: customerfolder: 56743_cleary_3336plus alt: 09-20-11 ekcolors: black, 355 size: 5 (w) x 6 (h)</p><p>dp proofed______</p><p>56743_book_art_56743_book_art 9/20/11 2:15 PM Page 1</p><p>Christina Zimmerman2011-2013</p><p>Christina ZimmermanText Box9174.36</p></li><li><p>PRECAUTIONARY STATEMENTSHAZARDS TO HUMANS AND DOMESTIC ANIMALS. WARNING Causes skin irritation. Harmful if swallowed. Harmful if absorbed through skin. Causes moderate eye irritation. Do not get on skin or clothing. Avoid contact with eyes.</p><p>PERSONAL PROTECTION EQUIPMENT (PPE):Some materials that are chemical-resistant to this product are made of any waterproof materials. If you want more options, follow the instructions for Category C on an EPA chemical resistance selection chart.Handlers mixing, loading and applying the product as a dip must wear: Coveralls over long-sleeved shirt and long pants Chemical-resistant gloves Chemical-resistant footwear plus socks Chemical-resistant apron For overhead exposure wear Chemical-resistant headgear When cleaning equipment, wear a Chemical-resistant apronAll other mixers, loaders and applicators must wear: Coveralls over short sleeved shirt and short pants Chemical-resistant footwear plus socks Chemical-resistant gloves (such as or made out of any waterproof material, selection category C) Chemical-resistant apron for mixers, loaders and other handlers exposed to concentrate, and for </p><p>cleaning equipment. For overhead exposure wear Chemical-resistant headgear</p><p>USER SAFETY REQUIREMENTSFollow manufacturers instructions for cleaning/maintaining PPE. If no such instructions for wash-ables exist, use detergent and hot water. Keep and wash PPE separately from other laundry.Discard clothing and other absorbent materials that have been drenched or heavily contaminated with this products concentrate. Do not reuse them.</p><p>USER SAFETY RECOMMENDATIONSUsers Should: Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. Remove clothing/PPE immediately if pesticide gets inside. Then wash thoroughly and put on clean </p><p>clothing. Remove PPE immediately after handling this product. Wash the outside of gloves before remov-</p><p>ing. As soon as possible, wash thoroughly and change into clean clothing.</p><p>ENVIRONMENTAL HAZARDSDo not apply directly to water, or areas where surface water is present or to intertidal areas below the mean </p><p>Do not contaminate water when disposing of equipment wash water.</p><p>IT IS A VIOLATION OF FEDERAL LAW TO USE THIS PRODUCT IN A MANNER INCONSISTENT WITH ITS LABELING. Do not apply this product in a way that will contact workers or other persons, either directly </p><p>to your State or Tribe, consult the agency responsible for pesticide regulation.</p><p>DIRECTIONS FOR USE</p><p>56743_book_art_56743_book_art 9/16/11 10:39 AM Page 2</p></li><li><p>AGRICULTURAL USE REQUIREMENTSUse this product only in accordance with its labeling, and with the Worker Protection Standard, 40 CFR part 170. This Standard contains requirements for the protection of agricultural workers on farms, forests, nurseries, greenhouses and handlers of agricultural insecticides. It contains requirements for training, de-</p><p>pertaining to the statements on this label about personal protective equipment (PPE), and restricted-entry interval. The requirements on this box only apply to uses of this product that are covered by the Worker Protection Standard.Do not enter or allow worker entry into treated areas during the restricted entry interval (REI) of 12 hours. PPE required for early entry to treated areas that is permitted under the Worker Protection Standard and that involves contact with anything that has been treated, such as plants, soil, or water, is: Coveralls over long-sleeved shirt and long pants Chemical-resistant gloves made of any waterproof material Chemical-resistant footwear plus socks Chemical-resistant headgear for over head exposures.Exemption: if the product is applied by drenching, the Worker Protection Standard, under certain circum-stances, allows workers to enter treated areas if there will be no contact with anything that has been treated. </p><p>NON-AGRICULTURAL USE REQUIREMENTSThe requirements in this box only apply to uses of this product that are NOT within the scope of the Worker Protection Standard for agricultural pesticides (40 CFR part 170). The WPS applies when this product is used to produce agricultural plants on farms, forests, nurseries, or greenhouses.Turf and Landscape Uses: Do not enter or allow others to enter until sprays have dried.</p><p>STORAGE AND DISPOSALDo not contaminate water, food, or feed by storage or disposal.Pesticide Storage: Store in a cool, dry place.Pesticide Disposal: Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be used according to the label instructions, contact your state Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the </p><p> Do not reuse this container to hold materials other than pesti-cides or dilute pesticides (rinsate). After emptying and cleaning, it may be allowable to temporarily hold rinsate or other pesticide-related materials in the container. Contact your state regulatory agency to determine allow-</p><p>Residue Removal: Triple rinse or pressure rinse container (or equivalent) promptly after emptying. Triple rinse as follows: Empty the remaining contents into application equipment or a mix tank and drain for 10 </p><p>Pour rinsate into application equipment or a mix tank or store rinsate for later use or disposal. Drain for 10 Pressure rinse as follows: </p><p>Empty the remaining contents into application equipment or mix tank and continue to drain for 10 seconds </p><p>rinsate for later use or disposal. Insert pressure rinsing nozzle in the side of the container, and rinse at about 40 PSI for at least 30 seconds. Drain for 10 seconds after the </p><p>GENERAL INFORMATIONFailure to follow directions and precautions on this label may result in crop injury, poor disease con-trol, and/or illegal residues.3336 PLUS is a broad spectrum fungicide exhibiting preventative, curative and systemic properties. It is </p><p>56743_book_art_56743_book_art 9/16/11 10:39 AM Page 3</p></li><li><p>useful on a wide variety of turf disease problems. Apply 3336 PLUS with ground or overhead equipment, </p><p>Use the higher rates under conditions of severe disease pressure. Also, see local State Extension Service recommendations for application schedules.This product is not for homeowner use, and can only be used by </p><p>Chemigation instructions follow Directions For Use. Read and follow these instructions carefully for this method of application.Resistance Management: To avoid the development of tolerant strains of fungi, 3336 PLUS should be used </p><p>containing thiabendazole in combination or rotation with 3336 PLUS. These utilize similar chemistry and mode of action and can contribute to development of disease tolerance. If after using 3336 PLUS as recom-</p><p>Chemical representative, your State Agricultural Experiment Station, or your State Cooperative Extension </p><p>disease control strategy. As long as recommended precautions are followed, 3336 PLUS can remain useful for disease control.Mixing Instructions: SHAKE WELL BEFORE USING. Some settling may occur during prolonged periods of </p><p>pH 6-7 prior to the addition of 3336 PLUS is recommended. Add required amount of 3336 PLUS to partially -</p><p>low), agitate again and then add remaining required amount of water. Continuous agitation is recommended to keep the material in proper suspension. For best results, use spray mixture the same day it is prepared.Tank Mixing Instructions: 3336 PLUS may be compatible with most commonly used pesticides. If tank </p><p>-</p><p>products is implied. Do not tank mix with copper-containing materials or with highly alkaline pesticides, such as Bordeaux mixture or lime sulfur. Consult the intended tank mix partner product label for appropriate appli-cation rates and use instructions. Follow the label directions for the most restrictive of label precautions and limitations. Read and observe the most restrictive precautionary statements and other information appearing on product labels used in mixtures. 3336 PLUS may be applied in conjunction with chemically neutral liquid fertilizers. Application in conjunction with highly alkaline fertilizers, such as aqueous ammonia, may cause a degradation of the pesticide, resulting in reduced performance and should be avoided.</p><p>CHEMIGATION REQUIREMENTSGENERIC REQUIREMENTS1. Apply this product only through the following types of systems: sprinkler including center pivot, lateral move, </p><p>not apply this product through any other type of irrigation system.2. -</p><p>tion of treated water. 3. If you have questions about calibration, you should contact State Extension Service specialists, equipment manufacturers or other experts.</p><p>4. Do not connect an irrigation system (including greenhouse systems) used for pesticide application to a public water system unless the pesticide label-prescribed safety devices for public water systems are in place.</p><p>5. A person knowledgeable of the chemigation system and responsible for its operation, or under the supervi-sion of the responsible person, shall shut the system down and make necessary adjustments should the need arise.</p><p>SPECIFIC REQUIREMENTS1. Public water system means a system for the provision to the public of piped water for human consumption </p><p>if such system has at least 15 service connections or regularly serves an average of at least 25 individuals daily at least 60 days out of the year.</p><p>2. Chemigation systems connected to public water systems must contain a functional, reduced-pressure </p><p>56743_book_art_56743_book_art 9/16/11 10:39 AM Page 4</p></li><li><p>point of pesticide introduction. As an option to the RPZ, the water from the public water system should be discharged into a reservoir tank prior to pesticide introduction. There shall be a complete physical break </p><p>3. The pesticide injection pipeline must contain a functional, automatic, quick-closing check valve to prevent </p><p>4. The pesticide injection pipeline must contain a functional, normally closed, solenoid-operated valve lo-</p><p>being drawn from the supply tank when the irrigation system is either automatically or manually shut down.5. </p><p>pump when the water pump motor stops, or in cases where there is no water pump, when the water pres-</p><p>6. Systems must use a metering pump, such as a positive displacement injection pump (e.g. diaphragm </p><p>7. Do not apply when wind speed favors drift beyond the area intended for treatment NON SPECIFIC REQUIREMENTS1. Remove scale, pesticide residue, and other foreign matter from the chemical tank and entire injector sys-</p><p>tem. Flush with clean water.2. Prepare a suspension of product in the mix tank or stock bucket. Fill the tank with 1/2 or 3/4 of the desired </p><p>amount of water. Start agitation and add the required amount of product to the solution along with the remaining volume of water.</p><p>3. Maintain a gentle agitation in the mix tank during application to assure a uniform suspension. Follow mix-ing instructions and tank mixing instructions previously indicated.</p><p>4. Start system and then uniformly inject the suspension of 3336 PLUS into the irrigation line so as to deliver </p><p>5. Greater accuracy in calibration and distribution will be achieved by injecting a larger volume of a more dilute suspension per unit time.</p><p>6. The suspension of 3336 PLUS should be injected with a positive displacement pump into the main line ahead of a right angle turn to insure adequate mixing.</p><p>SPRINKLER (OVERHEAD) CHEMIGATIONfol-</p><p>lowing additional requirements:1. The system must contain a functional check valve, vacuum relief valve, and low pressure drain appropri-</p><p>2. The irrigation line or water pump must include a functional pressure switch which will stop the water pump </p><p>Set sprinkler system to deliver 1/10 to 1/4 inches of water per acre. Volumes of water higher than this may </p><p>--</p><p>and drained in a center pivot system, block the nozzle set nearest the well pivot injection unit to prevent </p><p>FLOOD (BASIN) CHEMIGATION1. </p><p>2. Systems utilizing a pressurized water and pesticide injection system must meet the following require-</p><p>items 1 and 2 of the sprinkler irrigation requirements.DRIP (TRICKLE) CHEMIGATION</p><p>c requirements sections above.</p><p>56743_book_art_56743_book_art 9/16/11 10:39 AM Page 5</p></li><li><p>TURF APPLICATIONS</p><p>and aprons) of cool and warm season grasses such as Bentgrass, Bluegrass, Bermudagrass, Fescue, Rye-grass, St. Augustinegrass, Zoysiagrass, or their mixtures. 3336 PLUS is not phytotoxic to any of the above mentioned grasses when used in accordance with the label. 3336 PLUS is to be used for the prevention and control of the diseases mentioned below. It has both preventative and curative activity. Do not graze animals on treated turf. Do not feed clippings to livestock or poultry. Not for use on turf being grown for sale or other commercial use as sod.Application Instructions: Apply material with properly calibrated hand held, mechanical or motorized spray equipment or by chemigation through appropriate sprinkler irrigation systems. Spray uniformly o...</p></li></ul>