the sun’s total and spectral irradiance for solar energy applications and solar radiation models
TRANSCRIPT
Solar Energy 76 (2004) 423–453
www.elsevier.com/locate/solener
The sun’s total and spectral irradiance for solarenergy applications and solar radiation models
Christian A. Gueymard 1
Solar Consulting Services, 2959 Ragis Rd, Edgewater, FL 32132, USA
Received 29 May 2003; received in revised form 29 August 2003; accepted 29 August 2003
Communicated by: Associate Editor David Renne
Abstract
Using the most recent composite time series of total solar irradiance spaceborne measurements, a solar constant
value of 1366.1 Wm�2 is confirmed, and simple quadratic expressions are proposed to predict its daily value from the
Zurich sunspot number, the MgII index, or the 10.7 cm radio flux index. Whenever these three indices are available on a
daily basis (since 1978), it is possible to predict the sun’s irradiance within 0.1% on average, as accurately as current
measurements.
Based on this value of the solar constant, an improved approximation of the extraterrestrial solar spectrum from 0 to
1000 lm is proposed. It is obtained by dividing the spectrum into nine bands and selecting representative (and recent)
spectra, as well as appropriate scaling coefficients for each band. Comparisons with frequently used spectra are dis-
cussed, confirming previous findings of the literature.
This synthetic and composite spectrum is proposed at 0.5-nm intervals in the UV (280–400 nm), 1-nm intervals
between 0–280 and 400–1705 nm, 5-nm intervals between 1705 and 4000 nm, and progressively larger intervals beyond 4
lm, for a total of 2460 wavelengths.
� 2003 Published by Elsevier Ltd.
Keywords: Radiation; Spectral distribution; Solar constant and extraterrestrial radiation; Solar spectrum
1. Introduction
The magnitude and variations of the solar energetic
output directly or indirectly affects many atmospheric
and biological processes on Earth. For all applications
where spectral solar radiation needs to be evaluated
from the top of the atmosphere down to ground level,
precise knowledge of the extraterrestrial spectrum (ETS)
is of primarily importance.
Terrestrial spectra can be calculated through the use
of radiative transfer models (RTMs), which describe
atmospheric extinction processes on a spectral basis. A
E-mail address: [email protected] (C.A.
Gueymard).1 ISES member.
0038-092X/$ - see front matter � 2003 Published by Elsevier Ltd.
doi:10.1016/j.solener.2003.08.039
description of these atmospheric processes is beyond the
scope of this contribution, except for one important
aspect: their spectral resolution. All RTMs are devel-
oped around a specific spectral resolution and accord-
ingly calculate each process’ extinction at more or less
regular spectral intervals or ‘‘step size’’. These intervals
can vary from very narrow and essentially monochro-
matic at one extreme––in the case of ‘‘line-by-line’’
atmospheric codes such as FASCOD or LBLRTM
(Clough et al., 1981, 1992)––to very coarse at the other
extreme, in the case of engineering-type models such as
SPCTRAL2 (Bird, 1984; Bird and Riordan, 1986). An
intermediate case is worth mentioning here for the sake
of subsequent discussions. SMARTS is a ‘‘medium-res-
olution’’ (0.5–5 nm) spectral radiative model, versatile
enough to cover a variety of solar energy applications
(Gueymard, 2001, 2003; Gueymard et al., 2002). Three
resolutions and spectral intervals are now used in
Nomenclature
Ek spectral irradiance (Wm�2 nm�1)
RZ daily Zurich sunspot number
SC solar constant (Wm�2)
TSI total solar irradiance (Wm�2)
MG daily MgII index
RF daily 10.7 cm radio flux index
k wavelength (nm)
424 C.A. Gueymard / Solar Energy 76 (2004) 423–453
SMARTS: 0.5 nm in the UV (280–400 nm), 1 nm in the
visible and part of the near infrared (400–1702 nm) and
5 nm beyond, up to 4000 nm. These same intervals will
also be used here in the development of the proposed
ETS, so that it can accommodate the SMARTS model
among others.
During the five decades that followed the seminal
publication of the ‘‘Johnson curve’’ (Johnson, 1954),
considerable progress has been made in the determina-
tion of the ETS, but most of this progress dates back
only 30 years. In a 1965 review paper on then current
developments in ETS determination (Thekaekara, 1965),
its author pointed out ‘‘that the results from different
sources have wide discrepancies, that no new experi-
mental data have been taken in recent years, and that
the conventional technique of extrapolation to zero air
mass leaves large uncertainties’’. These problems were
addressed in later years through the development of
better instrumentation that could be deployed at
increasingly higher altitudes, thus eliminating much, if
not all, atmospheric interference and the associated er-
rors introduced by the extrapolation to zero air mass.
These platforms include high-altitude observatories
(e.g., Burlov-Vasiljev et al., 1995, 1998; Kurucz et al.,
1984; Lockwood et al., 1992; Neckel and Labs, 1981,
1984), research aircraft (e.g., Thekaekara, 1973; The-
kaekara and Drummond, 1971), stratospheric balloons
(e.g., Anderson and Hall, 1989), parachute launched
from a rocket (Mentall et al., 1981), rockets (e.g., Mount
and Rottman, 1981), and finally spacecraft (e.g., Brue-
ckner et al., 1996; Cebula et al., 1996; Floyd et al., 1999;
Thuillier et al., 1998a; VanHoosier et al., 1988; Woods
et al., 1996). In recent years, the new developments in
measuring the solar constant and ETS were driven in
great part by the realization that, to some extent, their
variation could explain various features of the Earth’s
climate and its short-term or long-term fluctuations. The
magnitude of this ‘‘solar forcing’’ is still discussed in the
current debate about the global climate change. For a
more thorough background information and historical
perspective, see, e.g., Hoyt and Schatten (1997).
Most of the experimental results mentioned above
concentrated on a few parts of the solar spectrum.
Spectral measurements are performed with instruments
whose spectral range is usually very limited. As a result,
a complete ETS must be obtained as a combination of
various spectra sensed by different instruments, in dif-
ferent spectral bands, with different resolution and cal-
ibration methods, on different platforms, and at different
moments in time. All these issues introduce noticeable
uncertainties in the resulting ETS. To address this, new
instruments with extended spectral range and refined
calibration techniques are being developed and sent in
orbit for long-term observations. One such instrument,
SOLSPEC (Thuillier et al., 1998b, 2003a), covers the
range 200–3000 nm and has been flown on various space
platforms since 1983. A more recent instrument is the
solar irradiance monitor (SIM). Even though its spectral
range (300–2000 nm) appears reduced, it offers the im-
mense advantage of an exceptionally low uncertainty,
�0.1% (Rottman et al., 2004). SIM is part of the Solar
Radiation and Climate Experiment (SORCE), now in
orbit, and has started producing data in mid-2003
(http://lasp.colorado.edu/sorce/data_access.html), dur-
ing the reviewing process of this paper. These new
datasets will help assess the accuracy of the ETS dis-
cussed here, and will certainly provide the basis for
updated spectra. The SORCE mission also includes two
spectral instruments that are monitoring the sun’s out-
put in the 1–34 and 115–320 nm bands (Woods et al.,
2000). Therefore, most of the spectrum below 2000 nm
will be monitored with great accuracy from a single
platform, and hopefully for a long time.
Different ETS distributions have been used in the
past for solar radiation modeling, astrophysical re-
search, or other applications (e.g., Arvesen et al., 1969;
Burlov-Vasiljev et al., 1995; Colina et al., 1996; Johnson,
1954; Lockwood et al., 1992; Neckel and Labs, 1984;
Nicolet, 1989; Simon, 1981; Smith and Gottlieb, 1974;
Thekaekara, 1973), but most were only partial spectra.
An important milestone was the adoption by the World
Meteorological Organization (WMO) of the World
Radiometric Center (WRC) spectrum (Wehrli, 1985),
more generally known as the ‘‘Wehrli spectrum’’. It was
developed as a composite of four existing datasets,
concatenated to cover most of the spectrum (200 nm–10
lm), and smoothed, scaled and forced in such a way that
the resulting total irradiance equals the WMO-recom-
mended value for the solar constant, 1367 Wm�2.
More recently, the American Society for Testing and
Materials (ASTM) standardized an updated four-band
spectrum, using more recent sources for some of its
C.A. Gueymard / Solar Energy 76 (2004) 423–453 425
parts, along with a wider spectral range (120 nm–1000
lm), and different resolution and spectral intervals
(ASTM, 2000). Some scaling and adjustments were also
necessary so that the integrated irradiance could be
obtained as 1366.1 Wm�2, the ASTM-recommended
value for the solar constant.
A revised ETS is proposed here for the following
reasons.
ii(i) Some problems have been discovered in the still
widely used Wehrli spectrum. These include anom-
alous dips around 940, 1270, and 2300 nm (Gao
and Green, 1995; Green and Gao, 1993), and inac-
curacies or biases due to the brute smoothing/scal-
ing process used to concatenate datasets obtained
with vastly different methods (personal communica-
tions with Claus Fr€ohlich, 1992, Eric P. Shettle,
1993, and Bo-Cai Gao, 1994).
i(ii) Even though the ASTM spectrum represents an
improvement over Wehrli’s, it also shows slight
problems, which will be discussed later (Section
4). Furthermore, its resolution is limited to 1 nm
below 630 nm, and 2 nm below 2500 nm, which is
not sufficient for many applications––considering
the important spectral structure at shorter wave-
lengths, particularly below 600 nm.
(iii) New datasets have been published recently. They
are based on modern instrumentation undergoing
sophisticated and frequent calibration and data
quality control. These recent data are therefore of
potentially better quality and accuracy than some
of the older data used in the Wehrli and ASTM
spectra.
Even though this contribution’s emphasis is about
spectral irradiance, it is by essence tied to the determi-
nation of the broadband solar irradiance often referred
to as the ‘‘solar constant’’, which will be discussed in
Section 2. The importance of this discussion stems from
the obvious constraint that the spectral integration of
any ETS should coincide with the solar constant. Be-
cause of the slight variations of solar output during an
11-year sunspot cycle, the ETS will be defined here for
the same average solar activity conditions as the solar
constant.
To respect the different spectral bands and resolu-
tions described above, the derivation of the proposed
ETS will be made band-by-band in Section 3. The
resulting spectrum is compared to existing ‘‘reference’’
spectra in Section 4.
2. Solar constant and total solar irradiance
The determination of the ‘‘solar constant’’ and its
possible variations was of considerable interest at the
turn of the 20th century and became the main driving
force that motivated pioneers such as Langley and Ab-
bott in those early days of solar radiation research (Hoyt
and Schatten, 1997). After a few decades of constant
monitoring by sensors on board various satellites, it is
now recognized that this ‘‘solar constant’’ is misnamed
because the solar energetic output does vary over time,
albeit by a small amount. Nowadays, this varying solar
output should be referred to as total solar irradiance
(TSI), whereas the term ‘‘solar constant’’ should be used
only to describe the long-term average TSI. For more
details on the history of TSI measurement from satel-
lites, experimental challenges, and scientific advances in
understanding the TSI variability, the reader is referred
to recent reviews (Fr€ohlich, 2004; Hoyt and Schatten,
1997; Willson, 1994).
It is now established that TSI is directly affected by
solar activity, which follows the well-documented
Schwabe (11-year) cycle. In particular, when the sun’s
activity increases at the onset of a new cycle, different
phenomena occur and have opposite effects. The ‘‘sun-
spot blocking’’ effect tends to lower TSI, whereas facu-
lae, plages and flares tend to increase it. Therefore, from
one day to the next, TSI can vary in one way or the
other depending on the relative strength and location
(on the sun’s disc) of these phenomena, which are also
influenced by the 27-day sun’s rotation cycle.
Various spaceborne radiometers have been monitor-
ing TSI since 1978. Because of calibration and degra-
dation problems, overlapping datasets were originally
not in perfect quantitative agreement, even though they
did agree qualitatively on the shape and magnitude of
the TSI variations during successive solar cycles. Con-
siderable effort was devoted to correcting each individ-
ual dataset and developing a unique composite time
series from the best available data (Fr€ohlich, 2004;
Fr€ohlich and Lean, 1998). The most recent version of
this composite dataset was ‘‘d25-05-0301’’ as of this
writing. It has been obtained from WRC in Davos,
Switzerland (http://www.pmodwrc.ch/) and used in what
follows.
Fig. 1 shows the measured TSI time series, consisting
of mean daily values, as well as a 27-day running mean
to dampen short-term effects. For the duration of this
dataset (November 1978 to January 2003, or 24.2 years),
the absolute minimum and maximum daily TSI were
1363 and 1368 Wm�2, respectively. Using the 27-day
smoothing filter, these numbers become 1365.0 and
1367.2 Wm�2, respectively, yielding a mean value
[(min+max)/2] of 1366.1 Wm�2 and a half-amplitude of
1.1 Wm�2 (i.e., ±0.08% of the mean). This value of the
mean TSI confirms the solar constant value, SC, whichhas been recently standardized (ASTM, 2000). It is also
only 0.9 Wm�2 less than the value of 1367 Wm�2 rec-
ommended by the World Meteorological Organization
(WMO) in 1981, and which has been widely used thus
1363
1364
1365
1366
1367
1368
0
100
200
300
1978 1983 1988 1993 1998 2003
Dai
ly T
SI (
Wm
-2)
Daily S
unspot Num
berYear
Total Solar Irradiance and Sunspot NumbersDaily values, 1978–2003
Fig. 1. Daily TSI for the period 11/1978–1/2003 (top panel) and
daily sunspot number for the same period (bottom panel). The
thicker lines indicate the smoothed 27-day running mean.
1362
1363
1364
1365
1366
1367
1368
1369
0 50 100 150 200 250 300
Daily TSI vs Daily Sunspot Numbers, 1978-2002
Dai
ly T
SI (
Wm
-2)
Daily Sunspot Number
Fig. 2. Daily TSI vs sunspot number for the period 11/1978–1/
2003.
426 C.A. Gueymard / Solar Energy 76 (2004) 423–453
far. Because of the inherent absolute uncertainty of at
least 0.1% or 1.4 Wm�2 in TSI measurements, it can be
argued that the difference between the two SC values just
mentioned is not significant, so that the WMO value can
still be considered valid. Nevertheless, the latest deter-
mination of SC (1366.1 Wm�2) will be used here in all
what follows.
Fig. 1 also shows the variability in the daily Zurich
sunspot number, RZ, as obtained from solar observato-
ries around the world since 1749 and distributed by the
Sunspot Index Data Center (SIDC), which is the world
data center for the Sunspot Index (http://sidc.oma.be).
During the same period (1978–2003) as above, RZ varied
between 0 and 302, with a similar wave pattern as TSI.
Even though a correlation exists between the two phe-
nomena, and can be expressed as
TSI ¼ 1365:5þ 0:012461RZ � 4:6078� 10�5R2Z ð1aÞ
or
TSI=SC ¼ 0:99956þ 9:1216� 10�6RZ � 3:37296
� 10�8R2Z ð1bÞ
it is not as strong as could be expected, with a correla-
tion coefficient of only 0.491 (Fig. 2). [The important
scatter produced by Eq. (1) was previously noticed
(Solanki and Fligge, 1999), and led to slightly different
coefficients, because of the shorter and older dataset
used by these authors.] The pronounced curvature can
be explained by the dynamic balance between the facu-
lae (brightening) effect and the sunspot blocking (dark-
ening) effect, which is not directly or only a function of
the number of sunspots.
A slightly better correlation is obtained when con-
sidering the MgII index, MG, as the independent vari-
able. This index has been specifically developed to
monitor changes in the UV irradiance (Heath and
Schlesinger, 1986), and has been calculated by NOAA’s
Space Environment Center (http://sec.noaa.gov/Data/
solar.html) from spectral measurements around 280 nm
using spaceborne sensors since 1978. A quadratic rela-
tionship is again obtained
TSI ¼ 1164:6þ 1426:4MG � 2521:3M2G ð2aÞ
or
TSI=SC ¼ 0:8525þ 1:04414MG � 1:84562M2G ð2bÞ
with a correlation coefficient of 0.592 (Fig. 3).
It has been also argued (Fligge and Solanki, 1998a,b)
that the 10.7 cm radio flux index, RF, would be a good––
if not the best––proxy for faculae brightening. Even
though this might be true on a longer time scale (which
was the main focus of the above-mentioned studies), its
correlation with the daily TSI is not as good as that
obtained with Eq. (2). Nevertheless, a combination of
RZ;MG and RF explains more variance in TSI than any
1362
1363
1364
1365
1366
1367
1368
1369
1362 1363 1364 1365 1366 1367 1368 1369
Daily TSI Correlation Model
Pre
dict
ed T
SI (
Wm
-2)
Measured TSI (Wm-2)
Fig. 4. Predicted TSI using Eq. (3) vs measured TSI (daily
values) for the period 11/1978–1/2003. The horizontal line
indicates the solar constant value defined here (1366.1 Wm�2),
and the dashed lines represent the limits for an uncertainty of
±0.1% around the perfect 1:1 line.
C.A. Gueymard / Solar Energy 76 (2004) 423–453 427
of them independently. This effect can be simply mod-
eled as
TSI ¼ 1327:87� 0:0038269RZ þ 143:1027MG
� 2:87203� 10�5R2F ð3aÞ
or
TSI=SC ¼ 0:97202� 2:80133� 10�6RZ
þ 0:104753MG � 2:10236� 10�8R2F ð3bÞ
with a correlation coefficient of 0.744. The ‘‘adjusted’’
Ottawa RF index used here has been obtained from the
Dominion Radio Astrophysical Observatory (http://
www.drao-ofr.hia-iha.nrc-cnrc.gc.ca/). Nearly all of the
predicted TSI values with Eq. (3) are within ±0.1% of
the measured TSI, as shown with the scatterplot in
Fig. 4.
Because measurements of the MgII index are rela-
tively recent, Eq. (3) cannot be used to reconstitute TSI
before its own measurements started in space. To esti-
mate the daily TSI between 1947 and 1978, a 2-variable
fit with lesser accuracy (R ¼ 0:576) may be used:
TSI ¼ 1364:0� 2:4008� 10�3RZ þ 0:026452RF
� 6:5502� 10�5R2F ð4aÞ
or
TSI=SC ¼ 0:99846� 1:7574� 10�6RZ þ 1:9363
� 10�5RF � 4:7948� 10�8R2F ð4bÞ
1362
1363
1364
1365
1366
1367
1368
1369
0.26 0.265 0.27 0.275 0.28 0.285 0.29 0.295
Daily TSI vs NOAA's MgII index, 1978-2002
Dai
ly T
SI (
Wm
-2)
MgII index
Fig. 3. Daily TSI vs MgII index for the period 11/1978–1/2003.
Future predictions and longer-term historical reconsti-
tutions––with possibly more accurate estimates than Eq.
(1) [which can be used for periods from 1749 to pres-
ent]––would require substantially more sophisticated
models of the solar cycle (e.g., Fligge and Solanki, 2000;
Fligge et al., 1998; Foukal and Lean, 1990; Fr€ohlich,2002; Fr€ohlich and Lean, 1998; Lean, 2000; Lean et al.,
1997; Solanki and Fligge, 1998; Tobiska et al., 2000;
Unruh et al., 1999).
3. Spectral irradiance
All wavelengths are not affected by solar activity
equally. Theoretical studies as well as a variety of
experimental measurements have revealed that most of
the sun’s output variation––at least in relative terms––
occurs in the far and extreme UV (below 200 nm), as
documented elsewhere (Floyd et al., 1998; Lean, 1991,
1997; Rottman, 1999; Rottman et al., 2004; Woods and
Rottman, 2002). The variability there considerably in-
creases with decreasing wavelength, to the point where
the ratio of maximum to minimum irradiance reaches an
estimated factor of 100 at 0.5 nm (Woods and Rottman,
2002). Short-term variations are of the same order of
magnitude as long-term variations (Brueckner et al.,
1996; Chandra et al., 1995; Lean, 1991; Rottman, 1988),
with 27-day amplitudes normally lower than 11-year
amplitudes (Woods and Rottman, 2002). Because for
428 C.A. Gueymard / Solar Energy 76 (2004) 423–453
UV to near infrared (NIR) wavelengths (300–4000
nm)––of most interest here––the solar variability has
normally only a very small amplitude of about �0.1%
and possibly less (i.e., an order of magnitude below the
precision of current spectral measurements), this vari-
ability will not be taken into consideration in what fol-
lows. In other words, a single spectrum, corresponding
to average activity conditions will be developed and
proposed. The spectral irradiance Ek, is therefore related
to the solar constant through
SC ¼Z 1
0
Ek dk ð5Þ
It must be acknowledged, however, that the ETS vari-
ability can be very important at a few specific wave-
lengths in the visible and NIR corresponding to some
solar absorption lines, such as the Ca K line around
393.5 nm, and the He line at 1083 nm. The solar cycle
modulation for the latter reaches 200% (Livingston,
1992), but it is unlikely that such spikes can explain the
±2–3 Wm�2 maximum daily variability in SC, so that
there might be either other strong localized effects or
small, smooth and spectrally broad variations falling
under the detection limit of current instrumentation.
Two essentially different sources of spectral data are
available and need be considered to assemble an ETS
because they complement each other. The first source is
from ground observatory telescopes pointing to the sun
center (Burlov-Vasiljev et al., 1995, 1998; Kurucz et al.,
1984; Neckel and Labs, 1981, 1984). These measure-
ments are made with either high-performance spec-
trometers or with a Fourier transform spectrometer
(FTS) at extremely high resolution (e.g., 0.0005 nm).
Such a high resolution is an asset to this method, but it
also has two drawbacks: (i) the raw disk-center radiance
measurements have to be converted into disk-average
irradiance, and this requires more or less empirical
spectral corrections to take the sun’s spatial inhomo-
geneity into consideration (the limb-darkening effect in
particular); (ii) because of strong absorption bands by
ozone, water vapor, carbon dioxide and other gases, no
reliable data can be directly obtained below �300 nm or
in strong NIR absorption bands, even when the obser-
vatory is at relatively high altitude––unless precise and
thorough atmospheric corrections are expressly made,
see, e.g. Burlov-Vasiljev et al. (1998). (The effect of this
atmospheric interference on spectral accuracy will be
discussed further in Section 4.)
The second source of data is from spectrometers
deployed on space platforms. They normally sense the
complete solar disk, thus integrating all possible sources
of inhomogeneity (limb-darkening, sunspots, flares, and
faculae) without the need for any correction. Another
asset is that they directly observe the ‘‘air mass zero’’
spectrum for long periods of time, without any atmo-
spheric interference or resulting spectral limitations. On
the other hand, they also have some drawbacks: (i) their
half-angle field-of-view is normally larger than that of
the sun disk to allow small variations in the satellite
orbit or pointing; their resolution is thus limited to
about 0.1–1 nm, due to the inverse relationship between
resolution and field-of-view (Jacquinot, 1954); (ii)
instrumentation tends to degrade noticeably because of
harsh conditions in space; (iii) monitoring this degra-
dation is difficult, and most of the time must be esti-
mated a posteriori; (iv) maintaining proper calibration
over long periods of time is an issue in unmanned
spacecraft, therefore better results are usually achieved
during short missions on a space shuttle.
Because of the strong interest in solar UV monitoring
associated with concerns in climate change and strato-
spheric ozone depletion, long continuous records of
daily extraterrestrial UV irradiance now exist. As more
instruments are sent to space, there are also more
occurrences ofmultiple overlaps in datasets (Cebula et al.,
1996; Lean et al., 1997; Thuillier et al., 1998a; Woods
et al., 1996), which permit intercomparisons and better
quality control. Two of these instruments in particular,
SUSIM and SOLSPEC, have also been deployed during
the three shuttle missions known as ATLAS-1 (1992),
ATLAS-2 (1993) and ATLAS-3 (1994). [More details
about these missions can be found elsewhere (Kaye and
Miller, 1996).] These relatively short missions increased
the accuracy of the measurements by (i) permitting
careful manipulation by the crew, (ii) avoiding long-term
degradation in space, and (iii) allowing for post-flight
calibration. All these efforts helped decrease the mea-
surement uncertainty, which has been studied in detail
(Thuillier et al., 1998a; Woods et al., 1996).
3.1. Selected sources of data
An exhaustive survey of the existing sources of data
is beyond the scope of this contribution, but the inter-
ested reader can find detailed reviews elsewhere (e.g.,
Nicolet, 1989; Smith and Gottlieb, 1974; Thuillier et al.,
1998b, 2003a, 2004). In what follows, 23 spectra have
been selected, in great part as a result of this review of
literature, and will constitute the pool of data from
which a synthetic spectrum will be assembled. They are
first rapidly presented in alphabetical order in the three
following sections.
3.1.1. Partial spectra
This category corresponds to a variety of experi-
mental spectra that, by essence, do not cover the whole
solar spectrum for reasons explained in Section 1.
However, they have generally been used in various
combinations to assemble complete spectra.
The Arvesen spectrum has been obtained in 1967
from a series of flights with an instrumented aircraft at
C.A. Gueymard / Solar Energy 76 (2004) 423–453 429
about 12 km altitude (Arvesen et al., 1969). This spec-
trum extends from 300 to 2495 nm and has been used in
the subsequent construction of composite spectra (Co-
lina et al., 1996; Nicolet, 1989; Smith and Gottlieb, 1974;
Wehrli, 1985). Even though these measurements were
done at high altitude, it seems that telluric absorption
features, and possibly instrument-related problems, are
still present in this spectrum between 1.2 and 2.5 lm at
least (Gao and Green, 1995; Thuillier et al., 2004).
The ATLAS-3 spectrum (VanHoosier, 1996) has
been measured by the SUSIM instrument on November
13, 1994. Of the three ATLAS missions mentioned
above, ATLAS-3 is considered to have generated the
best dataset, partly because of grating drive and read-
out improvements performed on SUSIM before
launch (Personal communication with Linton Floyd,
NRL, 2003). The original dataset covers the range
150–408 nm at 0.05-nm intervals, with a 0.15-nm reso-
lution.
The Burlov-Vasiljev spectrum (Burlov-Vasiljev
et al., 1995, 1998) has been recently measured from a
high-altitude observatory. Only the radiance of the disk
center was observed, but a number of sophisticated
corrections were introduced to remove terrestrial
absorption features. This spectrum extends from 310 to
1070 nm at 1-nm intervals with some overlap. For
later use in this study (Section 3.4), a separation at
650 nm between the two original spectra has been
considered, and the disk center’s radiance has been
converted into disk-center irradiance, and then into
disk-average irradiance using recent spectral ratios
(Neckel, 1997).
The Colina spectrum (Colina et al., 1996) is a com-
posite using both experimental data (120–960 nm) and
modeled data in the IR (960–2500 nm). It has been
developed as a reference model for astrophysical appli-
cations.
The Harrison spectrum (Harrison et al., 2003) has
been obtained with a rotating shadowband spectrora-
diometer (RSS) using careful zero air mass extrapolation
and corrections, from 360 to 1050 nm. However, it has
not been corrected for terrestrial absorption features.
The Kitt Peak ‘‘solar flux atlas’’ (Kurucz et al., 1984)
is a high-resolution spectrum from 296 to 1300 nm,
which has been largely used by astrophysicists even
though it has not been corrected for terrestrial absorp-
tion features.
The Lockwood spectrum (Lockwood et al., 1992) has
been obtained with an original methodology: rather
than using a telescope to point to the sun’s center, a
small image of it was obtained with a 30-lm pinhole. Its
irradiance between 329 and 850 nm was then absolutely
calibrated by comparison with the spectrum of a similar
star, Vega. However it reportedly contains strong ter-
restrial absorption features beyond 600 nm (Thuillier
et al., 1998b).
The Neckel & Labs spectrum (Neckel and Labs,
1984), hereafter NL84, has been one of the most cited
spectra for about two decades. It has been derived from
measurements of the disk-center radiance in the range
330–1250 nm. Specific corrections were considered to
remove terrestrial absorption features. It has been used
in various composite spectra (ASTM, 2000; Colina
et al., 1996; Nicolet, 1989; Wehrli, 1985). However, the
results of some comparative studies (Burlov-Vasiljev
et al., 1995; Harrison et al., 2003; Thuillier et al., 1998b,
2004) suggested that NL84 was most probably too low
below �450 nm and too high above 850 nm. When
incorporating the spectral corrections proposed subse-
quently (Neckel, 2003), a corrected spectrum has been
obtained here and will be referred to as NL03 in what
follows.
The SOLSPEC spectrum, version 13c from 200 to
2400 nm, has been proposed recently (Thuillier et al.,
2003a) as an improvement over previous versions
(Thuillier et al., 1997, 1998a,b). As mentioned in the
Introduction, it is––as of this writing––the only opera-
tional spaceborne instrument with a spectral range
extending to the infrared, which is an important
advantage.
This SOLSPEC spectrum has been used in part to
assemble the composite Thuillier ‘‘reference’’ spectra
(Thuillier et al., 2004), hereafter T03. Two spectra,
which both extend from 0 to 2400 nm, have been defined
to represent an active sun and a quiet sun, respectively.
An elaborate methodology has been used in their deri-
vation, involving multiple spectral adjustment factors.
The spectrum corresponding to an active sun, based on
the ATLAS-1 data, is used here.
From the multitude of spectra recorded by satellite-
based instruments in the UV over many years, only three
have been retained here for practical reasons. The spe-
cific UARS-SOLSTICE spectrum selected here has been
obtained with the SOLSTICE instrument onboard the
UARS satellite on November 11, 1994, i.e., in parallel
with the ATLAS-3 mission. Results from the latest ver-
sion (17) of the retrieval algorithm, which has been used
here, provide spectral data at 0.05 nm intervals in the
range 119–420.5 nm. The SOLSTICE instrument and
original calibration technique are described elsewhere
(Rottman et al., 1993, 2004; Woods et al., 1993).
The specific UARS-SUSIM spectrum retained here
originates from the same satellite, but with another
spectrometer, SUSIM. It has similar optical character-
istics and spectral range as SOLSTICE, but uses a more
conventional calibration technique. More details on this
experimentation and its results can be found elsewhere
(Brueckner et al., 1993, 1996; Floyd et al., 1998; Rottman
et al., 2004; Woods et al., 1996). The representative spec-
trum selected here has been measured on April 15, 1993
(i.e., in parallel with the ATLAS-2 mission), and has
been produced with the improved version-20 algorithm.
430 C.A. Gueymard / Solar Energy 76 (2004) 423–453
This spectrum covers the range 115–410 nm at 0.05-nm
intervals.
Finally, the composite Woods ‘‘reference’’ spectrum
for the UV during Solar Cycle 22 (Woods and Rottman,
2002) is used because it covers an extended spectral
range of 0–420 nm at 1-nm intervals. The latest version
(Personal communication with Tom Woods, 2003) has
been modified in October 2002 to include new extreme
UV data.
3.1.2. MODTRAN spectra
The MODTRAN RTM (Anderson et al., 1993; Berk
et al., 1999) has become a de facto standard in a variety
of atmospheric applications. An interesting characteris-
tic in the framework of this study is that it offers different
ETS options. Besides the Wehrli spectrum that will be
further discussed in the next section, five spectra are
available to perform irradiance calculations. They are all
derived from the modeled Kurucz spectrum (Kurucz,
1995), all cover the range 50–50,000 cm�1 (200 nm–200
lm) at 1 cm�1 intervals, and therefore constitute essen-
tially complete spectra at an apparent high resolution.
(In fact, linear interpolation has been used extensively to
fill in some of the spectra within different bands, so that
the true resolution is frequently different from the step
size.) They will be referred to here with the file names
used in MODTRAN: cebchkur, chkur, newkur, oldkur,
and thkur. Whereas oldkur refers to an older version of
the Kurucz spectrum, the four other spectra are based
on a more recent version (Kurucz, 1995), with various
alternatives in the UV and visible. More precisely, chkur
refers to the use of the Chance spectrum (Chance and
Spurr, 1997) below 800 nm, cebchkur is a variant of
chkur that additionally uses the Cebula UV spectrum
(Cebula et al., 1996) obtained during the ATLAS-1
mission, and thkur uses the Thuillier spectra (Thuillier
et al., 1997, 1998b), also from the ATLAS-1 mission, but
for wavelengths up to 877 nm. All these options also
incorporate other spectra over limited spectral ranges
(e.g., Anderson and Hall, 1989), but the details of their
assemblage have not been published. Despite this, it is
argued that, because of the prominent importance of
MODTRAN in atmospheric studies and related appli-
cations, it is worthwhile to consider and intercompare
these optional spectra.
3.1.3. Complete composite spectra
In the era posterior to the Johnson curve (Johnson,
1954), only four complete ETS have been in wide cir-
culation, and they are reviewed here. For reasons ex-
plained above, any ETS is necessarily assembled by
combining a number of basic spectra from different
sources, instruments, etc.
The ASTM spectrum is the latest in this series, and
has been elevated to standard status (ASTM, 2000). It is
assembled from four parts. From 119 to 380 nm, the
ATLAS-2 validation spectrum combining measurements
from SUSIM and SOLSTICE onboard UARS (Woods
et al., 1996) has been used and scaled by 0.968443. NL84
was used between 380 and 825 nm without scaling.
Modeled Kurucz data were used in the 825–4000 nm
range and scaled by 1.00085. The synthetic Smith and
Gottlieb spectrum (see below; Smith and Gottlieb, 1974)
was used between 4 and 1000 lm and scaled by 0.99437.
Finally, all data points were scaled by 0.99745 to force
the integrated irradiance to equal the solar constant
value of 1366.1 Wm�2. No mention is made of the
irradiance at wavelengths below 119 nm, but it would
amount to less than 0.1 Wm�2 and therefore would not
change the scaling necessary to match the integrated
irradiance and the solar constant.
The Smith and Gottlieb spectrum (Smith and Gott-
lieb, 1974) has been assembled from a variety of sources,
using curve fitting to smooth the differences in data. The
resulting ETS is of too low resolution to be used here
(except where noted), but has been used in the ASTM
spectrum as mentioned above, and, to even a larger
extent, in the Wehrli spectrum discussed below.
The Thekaekara/NASA spectrum (Thekaekara,
1973; Thekaekara and Drummond, 1971; Thekaekara
et al., 1971) was the first serious revision to the Johnson
curve and resulted in the adoption of a noticeably re-
duced solar constant (1353 Wm�2, compared to 1396
Wm�2 for Johnson). It has been in wide use until the
release of the Wehrli spectrum (discussed below). Most
of the Thekaekara spectrum (between 300 and 15,000
nm) relied on aircraft-based measurements. Later it be-
came apparent that terrestrial absorption features were
still present in the spectrum, as well as impacts from
calibration and other experimental problems (Fr€ohlich,1983; Thuillier et al., 1998b, 2004).
These problems were addressed in great part in the
Wehrli spectrum (Wehrli, 1985), which replaced an
earlier 1981 version by Fr€ohlich and Wehrli. Whereas
the latter only had limited circulation (Bird, 1984; Iqbal,
1983; Riordan, 1987), the 1985 Wehrli spectrum has
been in wide use since its release. It was assembled from
four different parts: 199–310 nm (Brasseur and Simon,
1981), 310–330 nm (Arvesen et al., 1969), 330–869 nm
(Neckel and Labs, 1984), and 870–10075 nm (Smith and
Gottlieb, 1974). Uniform scaling was used to force the
total irradiance within 199–10075 nm to the WMO-
recommended solar constant value of 1367 Wm�2. (This
obviously assumed that the irradiance below 199 nm and
above 10075 nm can be neglected.) As mentioned above,
however, a few problems were discovered later, both in
the visible and NIR.
3.2. General corrections
Because all spectra recorded in space use vacuum
wavelengths, whereas the intended applications of this
C.A. Gueymard / Solar Energy 76 (2004) 423–453 431
contribution are exclusively terrestrial, these vacuum
wavelengths have been first converted to air wave-
lengths. A 5-coefficient dispersion formula for the index
of refraction (Peck and Reeder, 1972) has been used for
this conversion. (This formula was devised by its authors
as an updated and improved version of the classic Edl�enformula still used by most astronomers; although these
two formulae assume standard air composition, pressure
and temperature, it is unlikely that non-standard
atmospheric conditions would introduce any significant
change to the medium-resolution spectrum proposed
here.) Note, however, that the spectrum below 280 nm
has not been converted to air wavelengths because it is
completely absorbed in the upper layers of the earth’s
atmosphere.
In order to compare spectra of extremely differ-
ent resolution wavelength-by-wavelength, appropriate
smoothing was performed whenever possible. It consists
in applying a filter with a triangular shape, and with a
bandwidth (full width at half maximum) equal to the
desired target resolution, e.g., 0.5 nm in the interval 280–
400 nm.
3.3. Total irradiance in selected spectral bands
With due consideration for the spectral limits of the
spectra reviewed in Section 3.1.1 in particular, the whole
solar spectrum has been divided into nine unequal bands
for easier manipulation and discussion. These are
• Band 1: 0–200 nm
• Band 2: 200–280 nm
• Band 3: 280–400 nm
• Band 4: 400–700 nm
• Band 5: 700–1000 nm
• Band 6: 1.0–1.705 lm• Band 7: 1.705–2.390 lm• Band 8: 2.390–4.0 lm• Band 9: 4.0 lm–1.
For each of the above bands, the total irradiance
was calculated for all the spectra just reviewed, pro-
vided that they were defined over the whole band.
These results appear in Table 1, showing some inter-
esting features when comparing individual band irra-
diances to the band average: (i) the standard deviation
of all results is near 1% in Bands 4–6; (ii) the most
recent complete spectrum, ASTM, has a Band-2 irra-
diance lower by 2–5% compared to recent spaceborne
measurements; (iii) the Wehrli spectrum is possibly too
high in Band 6 and too low in Bands 7 and 8, com-
pared to the mean values; (iv) NL84 is possibly too
high in Band 5; (v) T03 is possibly too high in Bands 6
and 7. Moreover, the total irradiance, i.e., the solar
constant, of the complete spectra integrates to between
1353 and 1376.3 Wm�2 ()0.23% and +0.75% compared
to 1366.1 Wm�2, respectively––a margin substantially
larger than the currently accepted uncertainty of about
±0.1%).
These findings suggest that a synthetic spectrum can
be constructed band-by-band through proper selection
of a high-quality base spectrum for that band, followed
by proper individual band scaling, defined in such a way
that two conditions are simultaneously met: (i) each
band irradiance must be reasonably close to the average
value listed in Table 1, and (ii) the total spectrum must
integrate to 1366.1 Wm�2. The scaling factors thus de-
rived are described in more detail in what follows.
3.4. Synthetic spectral irradiance for each band
• Band 1 (below 200 nm) and Band 2 (200–280 nm)
Together, these extreme UV regions account for
only a very small part of TSI (<1%). They are both
completely absorbed by the upper atmosphere and thus
cannot play any role in terrestrial applications such as
solar energy utilization. For completeness and proper
calculation of the solar constant, however, a represen-
tative spectrum is needed. The spectral region 0–280
nm (at 1 nm intervals) from the Woods spectrum re-
viewed above is selected here. Because average solar
activity conditions must be met, an average spectrum
has been derived from the reported minimum and
maximum activity conditions. After conversion from
photons s�1 cm�2 to Wm�2 nm�1, this average-activity
spectrum yields a total irradiance of 0.11 Wm�2 below
200 nm, and 7.00 Wm�2 for the 200–280 nm spectral
range.
• Band 3 (280–400 nm)
A primary dataset, consisting of the ATLAS-3
spectrum, has been selected because of its highly re-
garded status. A secondary dataset has been assembled
as the arithmetic mean of four different spectra: UARS-
SOLSTICE, UARS-SUSIM, Kitt Peak (for wavelengths
above 327 nm only, to avoid interference with ozone
absorption), and the Harrison spectrum above 362 nm.
The resulting synthetic spectrum (at 0.5-nm intervals) is
obtained as a weighted average, with weights of 0.6 and
0.4 applied to the primary and secondary spectrum,
respectively. The resulting spectrum is plotted in Fig. 5.
The UV irradiance in this band integrates to 103.76
Wm�2 or 7.6% of SC.• Band 4 (400–700 nm)
T03 is selected here as the base spectrum. Because the
corresponding band irradiance appears slightly too high,
some scaling is required. To lessen the difference of its
spectral irradiance with that of the ASTM, Burlov-
Vasiljev, Harrison, NL03, and SOLSPEC spectra, a
progressively decreasing correction with wavelength, k,is applied: 1.09217–0.000172k, resulting in a +2.3%
correction at 400 nm and a )2.8% correction at 700 nm.
A few individual data points are also corrected (by no
Table 1
Integrated irradiance of various spectra calculated for nine bands of the solar spectrum
Spectral range (nm) Total
0–200 200–280 280–400 400–700 700–1000 1000–1705 1705–2390 2390–4000 4000–1Band
1 2 3 4 5 6 7 8 9
Partial spectra
1. Arvesen – 7.28 111.64 546.68 311.94 289.71 77.89 – – –
2. ATLAS-3/
SUSIM
– 6.83 104.16 – – – – – – –
3. Burlov-
Vasiljev/Neckel
– – – 535.54 310.14 – – – – –
4. Colina – – 103.57 532.04 308.46 282.09 77.87 – – –
5. Harrison – – – 542.41 [284.8] – – – – –
6. Kitt Peak – – – 529.51 [289.2] – – – – –
7. Lockwood – – – 532.34 – – – – – –
8. Neckel &
Labs 1984
– – – 531.43 314.23 – – – – –
9. Neckel &
Labs 2002
– – – 539.84 313.57 – – – – –
10. SOLSPEC-
Thuillier
– 6.73 104.99 529.20 307.53 285.62 81.12 – – –
11. Thuillier
reference
0.11 6.85 103.51 535.35 311.65 289.62 82.24 –- –
12. UARS-
SOLSTICE
– 7.07 104.18 – – – – – – –
13. UARS-
SUSIM
– 6.78 102.39 – – – – – – –
14. Woods &
Rottman
0.11 7.11 103.66 – – – – – – –
MODTRAN spectra
15. Cebchkur 0.10a 6.92 103.55 531.08 306.67 283.67 78.33 40.01 11.90 1362.2
16. Chkur 0.10a 7.25 100.96 530.96 306.67 283.67 78.33 40.01 11.90 1359.9
17. Newkur 0.10a 7.58 105.04 532.82 308.64 283.67 78.33 40.01 11.90 1368.1
18. Oldkur 0.10a 6.90 104.51 530.84 311.70 288.41 78.65 40.09 11.90 1373.1
19. Thkur 0.10a 6.82 106.09 536.81 312.60 283.67 78.33 40.01 11.90 1376.3
Complete spectra
20. ASTM 0.10 6.62 99.87 530.11 311.17 287.92 78.57 40.04 11.74 1366.1
21. Smith &
Gottlieb
0.08 7.48 96.61 527.20 310.82 288a 70a 45a 13a 1358.0
22. Thekaekara/
NASA
0.11 7.53 110.42 516.23 305.57 282.30 74.20 43.89 12.75 1353.0
23.Wehrli/WRC 0.01 7.04 101.64 532.10 310.10 290.60 76.75 38.50 10.25 1367.0
AVERAGE
(Wm�2)
0.09 7.05 103.93 532.76 310.09 285.91 78.38 40.32 11.78 1370.3
St. Dev.
(Wm�2)
0.04 0.30 3.50 6.30 2.59 3.14 1.98 1.54 0.69 –
St. Dev./mean
(%)
45.4 4.2 3.4 1.2 0.8 1.1 2.5 3.8 5.9 –
24. This work 0.11 7.00 103.76 534.64 308.58 283.68 78.10 39.27 11.00 1366.1
[ ] Spectrum strongly affected by terrestrial absorption features in this band; these underestimated values are not considered in the
average.a Estimated value.
432 C.A. Gueymard / Solar Energy 76 (2004) 423–453
more than ±4%) when deviations to Burlov-Vasiljev and
NL03 appear too large. The resulting spectrum (at 1-nm
intervals) is plotted in Fig. 6. The visible irradiance in
this band integrates to 534.64 Wm�2 or 39.1% of SC.
0
0.2
0.4
0.6
0.8
1
1.2
1.4
1.6
1.8
280 290 300 310 320 330 340 350 360 370 380 390 400
Synthetic Spectrum
Irra
dian
ce (
Wm
-2 n
m-1
)
Wavelength (nm)
Fig. 5. Proposed synthetic spectrum for Band 3, 280–400 nm.
0.7
0.8
0.9
1
1.1
1.2
1.3
1.4
1.5
700 720 740 760 780 800 820 840 860 880 900 920 940 960 980 1000
Synthetic Spectrum
Irra
dian
ce (
Wm
-2 nm
-1)
Wavelength (nm)
Fig. 7. Proposed synthetic spectrum for Band 5, 700–1000 nm.
C.A. Gueymard / Solar Energy 76 (2004) 423–453 433
• Band 5 (700–1000 nm)
As in Band 4, the selected base spectrum is T03, but
it is scaled by 0.9904 to match the band irradiance of
the newkur spectrum, 308.58 Wm�2, or 22.6% of SC.A few data points are also corrected, as for Band 4.
The resulting spectrum (at 1-nm intervals) is shown in
Fig. 7.
1.3
1.4
1.5
1.6
1.7
1.8
1.9
2
2.1
2.2
2.3
400 420 440 460 480 500 520 540 560 580 600 620 640 660 680 700
Synthetic Spectrum
Irra
dian
ce (
Wm
-2 nm
-1)
Wavelength (nm)
Fig. 6. Proposed synthetic spectrum for Band 4, 400–700 nm.
• Band 6 (1.0–1.705 lm)
T03 is selected here too as the base spectrum, but a
progressive correction is applied to obtain a better
match with newkur: 1.0467–0.052389 k, for k here in lm.
The resulting spectrum (at 1-nm intervals) integrates to
283.68 Wm�2 (20.8% of SC) and is shown in Fig. 8.
• Band 7 (1.705–2.390 lm)
An initial base spectrum (at 5-nm intervals) is ob-
tained here as a weighted average of T03 (weight: 0.6),
newkur (weight: 0.3) and Colina (weight: 0.1). To better
match the newkur and Colina spectra, the base spectrum
is scaled by 0.9686 and results in a band irradiance of
78.10 Wm�2, or 5.7% of SC.• Band 8 (2.39–4.0 lm)
The selected base spectrum (at 5-nm intervals) is here
newkur. It is scaled by 0.9814 to match the average band
irradiance of ASTM and Wehrli, which results in a band
irradiance of 39.27 Wm�2, or 2.9% of SC.• Band 9 (4 lm–1)
ASTM is selected for the initial base spectrum. It is
scaled by 0.932 for 4 < k < 5 mm and by 0.942 for
5 < k < 1000 lm to better match the average of ASTM
and Wehrli, and to take into consideration recent find-
ings (Thuillier et al., 2004) that ASTM appears slightly
too high around 4.5 lm. The corrected irradiance totals
11.00 Wm�2 in this band, or 0.8% of SC. The spectrum
beyond 1000 lm is not known precisely, but can be
approximated by Planck’s law, and its irradiance is
negligible.
With the individual band corrections described
above, the total irradiance obtained for the whole
0.15
0.25
0.35
0.45
0.55
0.65
0.75
1000 1100 1200 1300 1400 1500 1600 1700
Synthetic Spectrum
Irra
dian
ce (
Wm
-2 nm
-1)
Wavelength (nm)
Fig. 8. Proposed synthetic spectrum for Band 6, 1.0–1.705 lm.
0
10
20
30
Irradiance Comparisonswith Synthetic Spectrum
Per
cent
Diff
eren
ce
434 C.A. Gueymard / Solar Energy 76 (2004) 423–453
spectrum is exactly 1366.1 Wm�2 (Table 1), so that no
further spectrum-wide scaling is necessary, contrarily to
the ASTM and Wehrli spectra.
As mentioned earlier in this section, the reference
spectrum just described is representative of periods of
moderate solar activity. As a first approximation, the
actual spectral irradiance for any day, E�k, can be ob-
tained from the reference irradiance in Appendix A, Ek,
through
E�k ¼ EkðTSI=SCÞ ð6Þ
where the ratio (TSI/SC) can be estimated from Eqs.
(1b), (2b), (3b) or (4b), depending on the available input
data. There are indications, also mentioned above, that
a more precise correction would involve an intricate UV-
weighted spectral dependence, but it is still too uncertain
to be formulated explicitly. An additional correction is
well known, however: E�k needs to be corrected for the
actual sun–earth distance, a deterministic astronomical
quantity.
-30
-20
-10
280 300 320 340 360 380 400
ASTM
Wehrli
Wavelength (nm)
Fig. 9. Percent difference between the ASTM and Wehrli irra-
diance, and the proposed synthetic spectrum in Band 3.
4. Comparison with existing spectra
Even though the integrated band irradiances dis-
played in Table 1 show relatively limited scatter, there
are important differences in the case of small spectral
ranges or, even more so, single wavelengths. These dif-
ferences may be caused by calibration problems, inter-
ferences with atmospheric absorbers, or wavelength
accuracy around Fraunhofer lines and other solar
absorption features. The latter experimental error may
induce important spikes in the relative difference be-
tween two spectra, particularly below 1000 nm because
of the abundance of this kind of sharp structure in the
solar spectrum (Figs. 5–8). It is therefore nearly impos-
sible to establish the wavelength-by-wavelength uncer-
tainty of the proposed synthetic spectrum, or of any
other that preceded it. Nevertheless, important infor-
mation can be gained by comparing different spectra on
the same basis. Such intercomparisons have been fre-
quently used in the literature (e.g., Burlov-Vasiljev et al.,
1995, 1998; Thekaekara et al., 1971; Thuillier et al.,
1998b, 2004). However, these earlier contributions
elected to show only smoothed differences between
spectra, using a relatively large averaging interval (e.g., 5
nm), whereas differences will be displayed here at the
maximum resolution of the proposed spectrum to
demonstrate the very frequent wavelength-shift prob-
lem.
Fig. 9 shows the relative difference between two
earlier composite spectra, ASTM and Wehrli, and the
proposed synthetic spectrum for Band 3. As was noted
before, the ASTM UV spectrum is consistently lower
than those of Wehrli or this work. Important differences
also exist between Wehrli and this work. Because the
present synthetic spectrum is mostly based on the AT-
LAS-3 data in this band, and because the latter dataset
is considered to have an excellent wavelength accuracy,
it is argued that most of these differences and spikes are
-30
-20
-10
0
10
20
30
280 300 320 340 360 380 400
Irradiance Comparisonswith Synthetic Spectrum
chkur
Thuillier 03
Per
cent
Diff
eren
ceWavelength (nm)
Fig. 11. Percent difference between the chkur and T03 irradi-
ance, and the proposed synthetic spectrum in Band 3.
C.A. Gueymard / Solar Energy 76 (2004) 423–453 435
due to inadequacies in the three original spectra that
have been assembled by Wehrli in Band 3. The lower
ASTM irradiance seems to be due to the low overall
scaling factor (0.96596) affecting the UARS/ATLAS-2
spectrum used below 380 nm, to its wavelength accu-
racy, and to the relatively low NL84 irradiance below
450 nm, already noticed above.
Similarly, Figs. 10 and 11 show the relative difference
between the newkur, cebchkur, chkur or T03 spectra,
and the proposed synthetic spectrum in the UV. The
cebchkur spectrum, obtained from spaceborne mea-
surements in this band, is consistent with the proposed
spectrum, even though a persistent wavelength shift is
noticeable. In comparison, newkur appears less consis-
tent, particularly around 385 nm. The chkur spectrum
also seems to have some inconsistencies below 330 nm.
The T03 spectrum, on average, is remarkably consistent
with the proposed spectrum, but a wavelength shift is
obvious here too. Although the ATLAS-3 data used
here are believed to have better wavelength alignment
than the ATLAS-1 data––basis for the ‘‘high activity’’
Thuillier spectrum––there is no way of knowing which
one is really closer to the truth.
Fig. 12 compares the spectral irradiance from Arve-
sen and Thekaekara to that of the proposed spectrum
for the visible, Band 4. The Arvesen spectrum seems to
become progressively too high above 560 nm, whereas
Thekaekara’s reveals a significant drop between 520 and
610 nm, at which point its resolution becomes too coarse
for meaningful comparisons.
-30
-20
-10
0
10
20
30
280 300 320 340 360 380 400
Irradiance Comparisonswith Synthetic Spectrum
newkur
cebchkur
Per
cent
Diff
eren
ce
Wavelength (nm)
Fig. 10. Percent difference between the newkur and cebchkur
irradiance, and the proposed synthetic spectrum in Band 3.
Similarly, but for a spectral range extending to 900
nm, Fig. 13 compares the Smith & Gottlieb and SOL-
SPEC spectra to the proposed synthetic spectrum. The
former is based on NL84 in this band and appears rel-
atively low below 550 nm. As could be expected, the
-20
-15
-10
-5
0
5
10
15
20
400 420 440 460 480 500 520 540 560 580 600 620 640 660 680 700
Irradiance Comparisonswith Synthetic Spectrum
Arvesen
Thekaekara
Per
cent
Diff
eren
ce
Wavelength (nm)
Fig. 12. Percent difference between the Arvesen and Thekae-
kara irradiance, and the proposed synthetic spectrum in Band 4.
-12
-10
-8
-6
-4
-2
0
2
4
6
8
10
12
400 500 600 700 800 900
Irradiance Comparisonswith Synthetic Spectrum
newkurthkur
Per
cent
Diff
eren
ceWavelength (nm)
Fig. 14. Percent difference between the newkur and thkur
irradiance, and the proposed synthetic spectrum in Bands 4–5.
-12
-10
-8
-6
-4
-2
0
2
4
6
8
10
12
400 500 600 700 800 900
Irradiance Comparisonswith Synthetic Spectrum
Smith & Gottlieb
SOLSPEC-Thuillier
Per
cent
Diff
eren
ce
Wavelength (nm)
Fig. 13. Percent difference between the Smith & Gottlieb and
SOLSPEC irradiance, and the proposed synthetic spectrum in
Bands 4 and 5.
-12
-10
-8
-6
-4
-2
0
2
4
6
8
10
12
400 500 600 700 800 900
Irradiance Comparisonswith Synthetic Spectrum
Neckel & Labs 1984Neckel & Labs 2003
Per
cent
Diff
eren
ce
Wavelength (nm)
Fig. 15. Percent difference between two versions of the Neckel
& Labs irradiance, and the proposed synthetic spectrum in
Bands 4–5.
436 C.A. Gueymard / Solar Energy 76 (2004) 423–453
SOLSPEC and proposed spectra are mutually consistent
because they rely on very closely related datasets.
An irradiance intercomparison in Bands 4 and 5 is
proposed in Figs. 14 and 15, showcasing the newkur,
thkur, NL84 and NL03 spectra. Whereas newkur ap-
pears too low between 400 and 500 nm, thkur appears
too high in the 820–870 nm range, demonstrating that
the SOLSPEC data underwent significant changes be-
tween version 8 as used in thkur (Personal communi-
cation with G�erard Thuillier, 1998) and version 13c as
used in the more recent SOLSPEC spectrum (Thuillier
et al., 2003a). As illustrated in Fig. 15, the comparison
between the two versions of the Neckel & Labs spectrum
shows that the newer version effectively corrected the
tendency of the older version to underestimate below
about 510 nm. However, both versions are possibly too
high in the 560–700 nm range.
Figs. 16 and 17 cover Bands 4, 5 and
6 (in part). They show two similar comparisons of
spectra measured from the ground, but with [Colina
and Burlov-Vasiljev] or without [Harrison and Kitt
Peak] atmospheric correction. The two latter spectra
exhibit characteristic sudden drops exactly where the
atmospheric gaseous absorptance increases sharply, as
calculated with the SMARTS code (Gueymard, 2001)
for a US Standard Atmosphere and a site at 2-km
altitude. These perturbations are not present in the
Colina spectrum (based in this spectral range on NL84,
and thus showing the same trends as noted just above,
which are absent in Harrison’s spectrum) or in the
Burlov-Vasiljev radiance spectrum coupled with Nec-
kel’s disk-center to disk-average function.
-80
-70
-60
-50
-40
-30
-20
-10
0
10
20
0
0.2
0.4
0.6
0.8
1
400 500 600 700 800 900 1000 1100 1200 1300
Irradiance Comparisons with Reference Spectrum
ColinaHarrison
Per
cent
Diff
eren
ce
Gaseous A
bsorptanceWavelength (nm)
Gaseous Absorptance at 2-km altitude
Fig. 16. Percent difference between the Colina and Harrison
irradiance, and the proposed synthetic spectrum in Bands 4–6
(top panel), and gaseous absorptance of the earth’s atmosphere
as predicted by the SMARTS code for an elevated site (bottom
panel).
-80
-70
-60
-50
-40
-30
-20
-10
0
10
20
0
0.2
0.4
0.6
0.8
1
400 500 600 700 800 900 1000 1100 1200 1300
Irradiance Comparisons with Synthetic Spectrum
Burlov-Vasiljev/Neckel
Kitt Peak atlas
Per
cent
Diff
eren
ce
Gaseous A
bsorptance
Wavelength (nm)
Gaseous Absorptance at 2-km altitude
Fig. 17. Percent difference between the Burlov-Vasiljev/Neckel
and Kitt Peak irradiance, and the proposed synthetic spectrum
in Bands 4–6 (top panel), and gaseous absorptance of the
earth’s atmosphere as predicted by the SMARTS code for an
elevated site (bottom panel).
-20
-15
-10
-5
0
5
10
1700 1800 1900 2000 2100 2200 2300 2400
Irradiance Comparisonswith Synthetic Spectrum
ASTM
Wehrli
Per
cent
Diff
eren
ceWavelength (nm)
Fig. 18. Percent difference between the ASTM and Wehrli
irradiance, and the proposed synthetic spectrum in Band 7.
-4
-2
0
2
4
1700 1800 1900 2000 2100 2200 2300 2400
Irradiance Comparisonswith Synthetic Spectrum
Colina
newkur
Per
cent
Diff
eren
ce
Wavelength (nm)
Fig. 19. Percent difference between the Colina and newkur
irradiance, and the proposed synthetic spectrum in Band 7.
C.A. Gueymard / Solar Energy 76 (2004) 423–453 437
Finally, Figs. 18 and 19 provide a comparison of
spectra (ASTM, Wehrli, Colina and newkur) to the
synthetic spectrum for Band 7. ASTM is here consistent
with the proposed spectrum, whereas Wehrli’s spectrum
438 C.A. Gueymard / Solar Energy 76 (2004) 423–453
displays a wide valley between 2050 and 2400 nm, thus
confirming previous findings (Gao and Green, 1995). In
this spectral region, Wehrli based his spectrum on Smith
& Gottlieb, and hence on older spectra (Arvesen et al.,
1969; Pierce, 1954) in which atmospheric interferences
were likely. In turn, Colina based his spectrum on Ku-
rucz’s modeled results, explaining the similitude with
newkur, even though the latter appears about 0.5%
higher than the former––apparently because two differ-
ent versions of the Kurucz model were used.
5. Conclusion
The solar constant of 1366.1 Wm�2 obtained here
from 24 years of irradiance measurements in space is
identical to the value now standardized by ASTM. Day-
to-day variations in solar activity (sunspots, faculae,
etc.) are responsible for detectable structure in the TSI
time series. For the solar conditions that prevailed
during this 24-year period at least, the daily TSI can be
simply predicted with relatively good accuracy from
three important solar indices, the Zurich sunspot num-
ber, the MgII index, and the 10.7 cm radio flux. Eqs. (1),
(4), and (3) can be used for simple estimates of the daily
TSI for the periods 1749–1947, 1947–1978 and 1978–
present, respectively.
Twenty-three existing measured or modeled spectra
were analyzed within nine spectral bands, covering the
whole solar spectrum. From this analysis, a synthetic/
composite spectrum has been assembled. For each
band, a single spectrum (or a weighted average of
different spectra) was selected as the base case. A
scaling factor (close to 1) was applied––if necessary––so
that the total irradiance in that band could better
match other representative spectra, and moreover, so
that the total integrated irradiance becomes exactly
equal to the solar constant value mentioned above.
This result is achieved without a spectrum-wide ren-
ormalization, contrarily to previous 4-band composite
spectra (ASTM and Wehrli). Because of current limi-
tations in instrumentation and calibration techniques
[which are such that the accuracy in spectral mea-
surements (1–3% at best) is an order of magnitude
larger than that in TSI (�0.1%)], scaling of measured
spectra appears necessary to constrain a complete
spectrum to the solar constant value. The methodology
used here, however, limits such scaling to 1.7% on
average over the 2460 wavelengths considered.
An intercomparison study has been conducted to
gain more insight into the strengths and weaknesses
of each original or composite spectrum. Four types of
problems have been identified in these spectra: (i)
localized inaccuracy around a specific wavelength, the
cause of which is unknown; (ii) large-band underesti-
mations or overestimations (e.g., NL84 below 510 nm or
in the 560–700 nm region; newkur possibly too low
around 385 nm and between 400 and 500 nm; Wehrli too
low between 2050 and 2400 nm), confirming previous
studies; (iii) sharp underestimation structure corre-
sponding to atmospheric absorption interference in
uncorrected spectra, particularly in the near infrared
(e.g., Harrison, Kitt Peak, Lockwood); and (iv) rapid
wavelength-to-wavelength fluctuations of a few percents
close to solar Fraunhofer lines or other solar absorption
features, particularly in the UV and visible, caused by
slight spectral shift between spectra, themselves resulting
from differences in wavelength accuracy of �0.1 nm or
less.
The selection of the ATLAS-3 spectrum in the 280–
400 nm band should limit the uncertainty in the pro-
posed spectrum because this dataset is considered
to have one of the best wavelength accuracies ever
achieved in space. Nevertheless, radically new instru-
mentation with absolute accuracies comparable to the
radiometers measuring TSI (�0.1%)––such as the Solar
Irradiance Monitor which has been recently launched
as part of the SORCE mission––will be necessary to
assess the accuracy of existing spectra or of this newly-
proposed synthetic spectrum, and to improve these
spectra in both resolution and accuracy. Furthermore,
new spaceborne instruments will be necessary to mon-
itor the solar spectrum in the infrared beyond 2.5 lmor so.
The new spectrum (tabulated in Appendix A and
available from http://rredc.nrel.gov/solar/spectra/am0/
special.html) has a resolution roughly equal to the step
size, i.e., 1 nm for 0–280 and 400–1705 nm, 0.5 nm be-
tween 280 and 400nm, 5 nm between 1705 and 4000 nm,
and increasing intervals beyond 4 lm.
It is felt that the 0.5- and 1-nm constant intervals
used here over the most important part of the spec-
trum (0–1705 nm) constitutes a good compromise be-
tween resolution and ease of use in solar radiation
models.
Acknowledgements
The author is particularly thankful to all the indi-
viduals who contributed largely to this work by pro-
viding basic data or valuable discussions: Gail P.
Anderson, Linton E. Floyd, Bo-Cai Gao, Dianne K.
Prinz, Gary J. Rottman, Eric P. Shettle, G�erard Thuil-
lier, Michael E. VanHoosier, and Tom Woods. Permis-
sion to use unpublished data from the VIRGO
Experiment on the cooperative ESA/NASA Mission
SOHO, and TSI data from PMOD/WRC is acknowl-
edged.
Appendix
Extraterrestrial spectruma
k Ek k Ek k Ek k Ek k Ek k Ek
0.5 2.278E)06 345 9.981E)01 700 1.413E+00 1110 5.823E)01 1520 2.852E)01 2830 3.200E)021.5 1.219E)04 345.5 1.018E+00 701 1.410E+00 1111 5.778E)01 1521 2.813E)01 2835 3.182E)022.5 1.513E)05 346 8.640E)01 702 1.402E+00 1112 5.739E)01 1522 2.812E)01 2840 3.148E)023.5 2.519E)05 346.5 9.766E)01 703 1.408E+00 1113 5.725E)01 1523 2.838E)01 2845 3.133E)024.5 3.708E)05 347 1.044E+00 704 1.422E+00 1114 5.775E)01 1524 2.815E)01 2850 3.111E)025.5 4.610E)05 347.5 8.414E)01 705 1.424E+00 1115 5.728E)01 1525 2.823E)01 2855 3.093E)026.5 4.367E)05 348 9.597E)01 706 1.410E+00 1116 5.732E)01 1526 2.843E)01 2860 3.074E)027.5 3.115E)05 348.5 9.591E)01 707 1.407E+00 1117 5.757E)01 1527 2.843E)01 2865 3.047E)028.5 2.828E)05 349 8.876E)01 708 1.410E+00 1118 5.703E)01 1528 2.836E)01 2870 2.994E)029.5 1.652E)05 349.5 8.760E)01 709 1.396E+00 1119 5.625E)01 1529 2.755E)01 2875 2.977E)0210.5 6.771E)06 350 1.081E+00 710 1.403E+00 1120 5.626E)01 1530 2.735E)01 2880 2.988E)0211.5 3.362E)06 350.5 1.138E+00 711 1.396E+00 1121 5.663E)01 1531 2.812E)01 2885 2.973E)0212.5 1.756E)06 351 1.014E+00 712 1.385E+00 1122 5.685E)01 1532 2.800E)01 2890 2.953E)0213.5 1.958E)06 351.5 9.808E)01 713 1.377E+00 1123 5.676E)01 1533 2.773E)01 2895 2.938E)0214.5 2.140E)05 352 1.053E+00 714 1.382E+00 1124 5.636E)01 1534 2.748E)01 2900 2.918E)0215.5 1.636E)05 352.5 8.210E)01 715 1.356E+00 1125 5.481E)01 1535 2.780E)01 2905 2.899E)0216.5 3.398E)05 353 1.032E+00 716 1.363E+00 1126 5.535E)01 1536 2.792E)01 2910 2.883E)0217.5 5.008E)04 353.5 1.102E+00 717 1.382E+00 1127 5.580E)01 1537 2.767E)01 2915 2.862E)0218.5 2.875E)04 354 1.143E+00 718 1.360E+00 1128 5.558E)01 1538 2.738E)01 2920 2.843E)0219.5 2.038E)04 354.5 1.158E+00 719 1.335E+00 1129 5.497E)01 1539 2.719E)01 2925 2.813E)0220.5 1.958E)04 355 1.152E+00 720 1.361E+00 1130 5.508E)01 1540 2.694E)01 2930 2.803E)0221.5 9.410E)05 355.5 1.038E+00 721 1.346E+00 1131 5.536E)01 1541 2.725E)01 2935 2.790E)0222.5 1.025E)04 356 1.084E+00 722 1.345E+00 1132 5.538E)01 1542 2.732E)01 2940 2.770E)0223.5 2.287E)05 356.5 9.246E)01 723 1.357E+00 1133 5.447E)01 1543 2.748E)01 2945 2.747E)0224.5 4.762E)05 357 7.635E)01 724 1.346E+00 1134 5.501E)01 1544 2.754E)01 2950 2.733E)0225.5 1.173E)04 357.5 9.338E)01 725 1.337E+00 1135 5.503E)01 1545 2.758E)01 2955 2.719E)0226.5 4.025E)05 358 7.391E)01 726 1.339E+00 1136 5.510E)01 1546 2.740E)01 2960 2.704E)0227.5 8.475E)05 358.5 6.309E)01 727 1.348E+00 1137 5.454E)01 1547 2.681E)01 2965 2.689E)0228.5 8.556E)05 359 8.815E)01 728 1.324E+00 1138 5.383E)01 1548 2.679E)01 2970 2.671E)0229.5 4.375E)05 359.5 1.122E+00 729 1.297E+00 1139 5.402E)01 1549 2.691E)01 2975 2.655E)0230.5 6.252E)04 360 1.188E+00 730 1.329E+00 1140 5.359E)01 1550 2.678E)01 2980 2.635E)0231.5 1.190E)04 360.5 9.484E)01 731 1.319E+00 1141 5.367E)01 1551 2.704E)01 2985 2.620E)0232.5 1.593E)04 361 8.627E)01 732 1.322E+00 1142 5.388E)01 1552 2.708E)01 2990 2.601E)0233.5 1.566E)04 361.5 9.897E)01 733 1.318E+00 1143 5.401E)01 1553 2.660E)01 2995 2.581E)02
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
439
Appendix (continued)
k Ek k Ek k Ek k Ek k Ek k Ek
34.5 6.937E)05 362 8.526E)01 734 1.332E+00 1144 5.351E)01 1554 2.645E)01 3000 2.560E)0235.5 5.933E)05 362.5 1.176E+00 735 1.313E+00 1145 5.395E)01 1555 2.644E)01 3005 2.555E)0236.5 8.039E)05 363 1.053E+00 736 1.307E+00 1146 5.433E)01 1556 2.646E)01 3010 2.539E)0237.5 1.383E)05 363.5 9.672E)01 737 1.317E+00 1147 5.418E)01 1557 2.674E)01 3015 2.522E)0238.5 5.931E)06 364 1.180E+00 738 1.295E+00 1148 5.383E)01 1558 2.660E)01 3020 2.505E)0239.5 5.832E)06 364.5 1.007E+00 739 1.273E+00 1149 5.373E)01 1559 2.645E)01 3025 2.489E)0240.5 9.781E)06 365 1.024E+00 740 1.292E+00 1150 5.358E)01 1560 2.664E)01 3030 2.469E)0241.5 1.810E)05 365.5 1.283E+00 741 1.271E+00 1151 5.354E)01 1561 2.681E)01 3035 2.432E)0242.5 4.798E)06 366 1.356E+00 742 1.265E+00 1152 5.311E)01 1562 2.661E)01 3040 2.393E)0243.5 1.101E)05 366.5 1.271E+00 743 1.295E+00 1153 5.341E)01 1563 2.633E)01 3045 2.415E)0244.5 4.389E)06 367 1.236E+00 744 1.287E+00 1154 5.351E)01 1564 2.648E)01 3050 2.414E)0245.5 4.824E)06 367.5 1.281E+00 745 1.284E+00 1155 5.321E)01 1565 2.641E)01 3055 2.397E)0246.5 1.738E)05 368 1.119E+00 746 1.290E+00 1156 5.304E)01 1566 2.612E)01 3060 2.383E)0247.5 6.925E)06 368.5 1.127E+00 747 1.292E+00 1157 5.305E)01 1567 2.612E)01 3065 2.362E)0248.5 1.155E)05 369 1.215E+00 748 1.289E+00 1158 5.291E)01 1568 2.590E)01 3070 2.351E)0249.5 3.965E)05 369.5 1.293E+00 749 1.274E+00 1159 5.169E)01 1569 2.595E)01 3075 2.343E)0250.5 1.680E)05 370 1.376E+00 750 1.273E+00 1160 5.182E)01 1570 2.620E)01 3080 2.324E)0251.5 5.743E)06 370.5 1.066E+00 751 1.260E+00 1161 5.084E)01 1571 2.641E)01 3085 2.306E)0252.5 9.808E)06 371 1.137E+00 752 1.265E+00 1162 5.220E)01 1572 2.623E)01 3090 2.296E)0253.5 7.458E)06 371.5 1.421E+00 753 1.271E+00 1163 5.216E)01 1573 2.610E)01 3095 2.282E)0254.5 4.843E)06 372 9.422E)01 754 1.274E+00 1164 5.147E)01 1574 2.523E)01 3100 2.266E)0255.5 2.165E)05 372.5 1.128E+00 755 1.267E+00 1165 5.175E)01 1575 2.498E)01 3105 2.258E)0256.5 6.578E)06 373 1.145E+00 756 1.266E+00 1166 5.134E)01 1576 2.475E)01 3110 2.240E)0257.5 6.528E)06 373.5 7.436E)01 757 1.268E+00 1167 5.169E)01 1577 2.417E)01 3115 2.201E)0258.5 3.689E)05 374 1.079E+00 758 1.253E+00 1168 5.177E)01 1578 2.546E)01 3120 2.208E)0259.5 7.776E)06 374.5 8.919E)01 759 1.249E+00 1169 5.065E)01 1579 2.587E)01 3125 2.201E)0260.5 3.112E)05 375 8.660E)01 760 1.249E+00 1170 5.160E)01 1580 2.600E)01 3130 2.188E)0261.5 9.737E)06 375.5 1.292E+00 761 1.245E+00 1171 5.175E)01 1581 2.560E)01 3135 2.177E)0262.5 4.209E)05 376 1.070E+00 762 1.223E+00 1172 5.161E)01 1582 2.502E)01 3140 2.163E)0263.5 1.060E)05 376.5 1.108E+00 763 1.246E+00 1173 5.156E)01 1583 2.521E)01 3145 2.150E)0264.5 2.442E)06 377 1.171E+00 764 1.239E+00 1174 5.132E)01 1584 2.535E)01 3150 2.125E)0265.5 1.916E)06 377.5 1.368E+00 765 1.226E+00 1175 4.988E)01 1585 2.555E)01 3155 2.119E)0266.5 1.709E)06 378 1.482E+00 766 1.176E+00 1176 5.072E)01 1586 2.533E)01 3160 2.112E)0267.5 1.750E)06 378.5 1.400E+00 767 1.216E+00 1177 5.071E)01 1587 2.490E)01 3165 2.095E)0268.5 6.027E)06 379 1.155E+00 768 1.221E+00 1178 5.012E)01 1588 2.395E)01 3170 2.079E)02
440
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
69.5 4.452E)06 379.5 1.055E+00 769 1.209E+00 1179 5.085E)01 1589 2.318E)01 3175 2.075E)0270.5 1.172E)05 380 1.096E+00 770 1.209E+00 1180 5.097E)01 1590 2.379E)01 3180 2.058E)0271.5 5.120E)06 380.5 1.325E+00 771 1.201E+00 1181 5.061E)01 1591 2.433E)01 3185 2.049E)0272.5 3.833E)06 381 1.325E+00 772 1.198E+00 1182 5.000E)01 1592 2.521E)01 3190 2.039E)0273.5 4.995E)06 381.5 1.048E+00 773 1.205E+00 1183 4.855E)01 1593 2.543E)01 3195 2.027E)0274.5 6.155E)06 382 9.288E)01 774 1.198E+00 1184 4.998E)01 1594 2.551E)01 3200 2.008E)0275.5 9.412E)06 382.5 7.899E)01 775 1.188E+00 1185 5.043E)01 1595 2.508E)01 3205 2.001E)0276.5 2.379E)05 383 7.300E)01 776 1.202E+00 1186 5.032E)01 1596 2.439E)01 3210 1.991E)0277.5 2.156E)05 383.5 7.020E)01 777 1.186E+00 1187 5.031E)01 1597 2.515E)01 3215 1.975E)0278.5 3.043E)05 384 7.734E)01 778 1.179E+00 1188 4.847E)01 1598 2.528E)01 3220 1.967E)0279.5 1.429E)05 384.5 1.136E+00 779 1.180E+00 1189 4.839E)01 1599 2.499E)01 3225 1.954E)0280.5 1.468E)05 385 1.125E+00 780 1.173E+00 1190 4.980E)01 1600 2.477E)01 3230 1.943E)0281.5 1.668E)05 385.5 1.046E+00 781 1.174E+00 1191 5.011E)01 1601 2.449E)01 3235 1.929E)0282.5 2.465E)05 386 8.946E)01 782 1.181E+00 1192 4.986E)01 1602 2.466E)01 3240 1.916E)0283.5 4.209E)05 386.5 1.173E+00 783 1.160E+00 1193 4.981E)01 1603 2.475E)01 3245 1.904E)0284.5 3.061E)05 387 9.740E)01 784 1.165E+00 1194 4.972E)01 1604 2.457E)01 3250 1.900E)0285.5 3.409E)05 387.5 1.093E+00 785 1.158E+00 1195 4.911E)01 1605 2.454E)01 3255 1.886E)0286.5 3.613E)05 388 1.008E+00 786 1.172E+00 1196 4.916E)01 1606 2.427E)01 3260 1.874E)0287.5 4.301E)05 388.5 9.949E)01 787 1.167E+00 1197 4.795E)01 1607 2.448E)01 3265 1.863E)0288.5 4.915E)05 389 1.073E+00 788 1.161E+00 1198 4.742E)01 1608 2.459E)01 3270 1.854E)0289.5 5.978E)05 389.5 1.298E+00 789 1.167E+00 1199 4.691E)01 1609 2.385E)01 3275 1.841E)0290.5 7.044E)05 390 1.301E+00 790 1.165E+00 1200 4.886E)01 1610 2.336E)01 3280 1.827E)0291.5 5.389E)05 390.5 1.196E+00 791 1.149E+00 1201 4.907E)01 1611 2.380E)01 3285 1.816E)0292.5 1.922E)05 391 1.406E+00 792 1.138E+00 1202 4.880E)01 1612 2.400E)01 3290 1.800E)0293.5 1.685E)05 391.5 1.433E+00 793 1.123E+00 1203 4.676E)01 1613 2.415E)01 3295 1.763E)0294.5 1.201E)05 392 1.206E+00 794 1.110E+00 1204 4.788E)01 1614 2.409E)01 3300 1.760E)0295.5 6.964E)06 392.5 1.078E+00 795 1.136E+00 1205 4.845E)01 1615 2.352E)01 3305 1.774E)0296.5 7.241E)06 393 5.989E)01 796 1.140E+00 1206 4.851E)01 1616 2.317E)01 3310 1.768E)0297.5 1.296E)04 393.5 4.347E)01 797 1.139E+00 1207 4.842E)01 1617 2.371E)01 3315 1.751E)0298.5 1.474E)05 394 8.837E)01 798 1.138E+00 1208 4.595E)01 1618 2.402E)01 3320 1.721E)0299.5 2.274E)05 394.5 1.122E+00 799 1.139E+00 1209 4.687E)01 1619 2.372E)01 3325 1.732E)02100.5 9.215E)06 395 1.368E+00 800 1.129E+00 1210 4.713E)01 1620 2.306E)01 3330 1.729E)02101.5 1.065E)05 395.5 1.389E+00 801 1.132E+00 1211 4.730E)01 1621 2.337E)01 3335 1.718E)02102.5 9.719E)05 396 1.203E+00 802 1.127E+00 1212 4.787E)01 1622 2.374E)01 3340 1.706E)02103.5 1.004E)04 396.5 7.019E)01 803 1.122E+00 1213 4.781E)01 1623 2.407E)01 3345 1.700E)02104.5 1.470E)05 397 5.261E)01 804 1.120E+00 1214 4.782E)01 1624 2.387E)01 3350 1.688E)02105.5 1.244E)05 397.5 1.069E+00 805 1.106E+00 1215 4.780E)01 1625 2.377E)01 3355 1.679E)02
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
441
Appendix (continued)
k Ek k Ek k Ek k Ek k Ek k Ek
106.5 1.184E)05 398 1.497E+00 806 1.121E+00 1216 4.772E)01 1626 2.386E)01 3360 1.672E)02107.5 1.257E)05 398.5 1.546E+00 807 1.112E+00 1217 4.759E)01 1627 2.400E)01 3365 1.658E)02108.5 2.109E)05 399 1.670E+00 808 1.110E+00 1218 4.741E)01 1628 2.401E)01 3370 1.644E)02109.5 1.419E)05 399.5 1.663E+00 809 1.101E+00 1219 4.721E)01 1629 2.373E)01 3375 1.640E)02110.5 1.513E)05 400 1.727E+00 810 1.104E+00 1220 4.735E)01 1630 2.363E)01 3380 1.631E)02111.5 1.388E)05 401 1.769E+00 811 1.115E+00 1221 4.716E)01 1631 2.366E)01 3385 1.623E)02112.5 1.512E)05 402 1.861E+00 812 1.116E+00 1222 4.698E)01 1632 2.353E)01 3390 1.617E)02113.5 1.181E)05 403 1.763E+00 813 1.118E+00 1223 4.683E)01 1633 2.315E)01 3395 1.596E)02114.5 7.990E)06 404 1.733E+00 814 1.111E+00 1224 4.696E)01 1634 2.326E)01 3400 1.575E)02115.5 1.313E)05 405 1.730E+00 815 1.105E+00 1225 4.681E)01 1635 2.340E)01 3405 1.582E)02116.5 1.484E)05 406 1.697E+00 816 1.103E+00 1226 4.660E)01 1636 2.290E)01 3410 1.575E)02117.5 6.311E)05 407 1.665E+00 817 1.099E+00 1227 4.567E)01 1637 2.251E)01 3415 1.561E)02118.5 1.671E)05 408 1.729E+00 818 1.077E+00 1228 4.642E)01 1638 2.197E)01 3420 1.559E)02119.5 5.556E)05 409 1.847E+00 819 1.071E+00 1229 4.651E)01 1639 2.207E)01 3425 1.550E)02120.5 1.687E)04 410 1.610E+00 820 1.064E+00 1230 4.626E)01 1640 2.212E)01 3430 1.541E)02121.5 8.119E)03 411 1.740E+00 821 1.063E+00 1231 4.611E)01 1641 2.200E)01 3435 1.537E)02122.5 5.962E)05 412 1.863E+00 822 1.065E+00 1232 4.589E)01 1642 2.224E)01 3440 1.529E)02123.5 4.230E)05 413 1.816E+00 823 1.076E+00 1233 4.598E)01 1643 2.235E)01 3445 1.520E)02124.5 3.217E)05 414 1.834E+00 824 1.073E+00 1234 4.574E)01 1644 2.217E)01 3450 1.512E)02125.5 3.050E)05 415 1.834E+00 825 1.070E+00 1235 4.569E)01 1645 2.234E)01 3455 1.503E)02126.5 4.499E)05 416 1.861E+00 826 1.078E+00 1236 4.583E)01 1646 2.255E)01 3460 1.496E)02127.5 2.361E)05 417 1.813E+00 827 1.076E+00 1237 4.577E)01 1647 2.256E)01 3465 1.487E)02128.5 1.932E)05 418 1.777E+00 828 1.070E+00 1238 4.567E)01 1648 2.239E)01 3470 1.476E)02129.5 2.273E)05 419 1.797E+00 829 1.063E+00 1239 4.510E)01 1649 2.230E)01 3475 1.468E)02130.5 1.817E)04 420 1.787E+00 830 1.060E+00 1240 4.519E)01 1650 2.236E)01 3480 1.462E)02131.5 2.964E)05 421 1.866E+00 831 1.054E+00 1241 4.538E)01 1651 2.232E)01 3485 1.454E)02132.5 2.270E)05 422 1.771E+00 832 1.057E+00 1242 4.492E)01 1652 2.242E)01 3490 1.446E)02133.5 2.163E)04 423 1.727E+00 833 1.024E+00 1243 4.453E)01 1653 2.243E)01 3495 1.437E)02134.5 2.023E)05 424 1.825E+00 834 1.029E+00 1244 4.497E)01 1654 2.237E)01 3500 1.431E)02135.5 4.616E)05 425 1.818E+00 835 1.045E+00 1245 4.509E)01 1655 2.241E)01 3505 1.424E)02136.5 2.997E)05 426 1.765E+00 836 1.050E+00 1246 4.481E)01 1656 2.251E)01 3510 1.416E)02137.5 3.188E)05 427 1.730E+00 837 1.045E+00 1247 4.475E)01 1657 2.246E)01 3515 1.407E)02138.5 3.158E)05 428 1.684E+00 838 1.029E+00 1248 4.493E)01 1658 2.237E)01 3520 1.399E)02139.5 9.267E)05 429 1.590E+00 839 1.026E+00 1249 4.488E)01 1659 2.230E)01 3525 1.392E)02
442
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
140.5 7.694E)05 430 1.389E+00 840 1.043E+00 1250 4.473E)01 1660 2.248E)01 3530 1.385E)02141.5 4.532E)05 431 1.377E+00 841 1.037E+00 1251 4.441E)01 1661 2.247E)01 3535 1.374E)02142.5 4.897E)05 432 1.773E+00 842 1.028E+00 1252 4.410E)01 1662 2.229E)01 3540 1.367E)02143.5 5.708E)05 433 1.780E+00 843 1.016E+00 1253 4.432E)01 1663 2.218E)01 3545 1.364E)02144.5 5.554E)05 434 1.652E+00 844 1.009E+00 1254 4.433E)01 1664 2.213E)01 3550 1.356E)02145.5 5.972E)05 435 1.725E+00 845 1.033E+00 1255 4.421E)01 1665 2.194E)01 3555 1.344E)02146.5 7.424E)05 436 1.938E+00 846 1.027E+00 1256 4.404E)01 1666 2.187E)01 3560 1.336E)02147.5 9.217E)05 437 1.906E+00 847 1.004E+00 1257 4.402E)01 1667 2.174E)01 3565 1.333E)02148.5 9.396E)05 438 1.732E+00 848 1.003E+00 1258 4.398E)01 1668 2.152E)01 3570 1.324E)02149.5 8.473E)05 439 1.795E+00 849 9.749E)01 1259 4.408E)01 1669 2.183E)01 3575 1.318E)02150.5 9.444E)05 440 1.848E+00 850 9.330E)01 1260 4.410E)01 1670 2.190E)01 3580 1.309E)02151.5 1.021E)04 441 1.910E+00 851 9.939E)01 1261 4.385E)01 1671 2.149E)01 3585 1.303E)02152.5 1.286E)04 442 2.046E+00 852 9.844E)01 1262 4.375E)01 1672 2.105E)01 3590 1.298E)02153.5 1.429E)04 443 1.995E+00 853 9.427E)01 1263 4.391E)01 1673 2.144E)01 3595 1.290E)02154.5 2.543E)04 444 2.034E+00 854 8.179E)01 1264 4.349E)01 1674 2.142E)01 3600 1.283E)02155.5 2.101E)04 445 1.991E+00 855 8.930E)01 1265 4.357E)01 1675 2.100E)01 3605 1.279E)02156.5 2.113E)04 446 1.894E+00 856 9.783E)01 1266 4.365E)01 1676 2.104E)01 3610 1.272E)02157.5 1.910E)04 447 2.042E+00 857 9.964E)01 1267 4.322E)01 1677 2.120E)01 3615 1.266E)02158.5 1.837E)04 448 2.077E+00 858 9.905E)01 1268 4.292E)01 1678 2.103E)01 3620 1.260E)02159.5 1.836E)04 449 2.077E+00 859 9.894E)01 1269 4.337E)01 1679 2.063E)01 3625 1.252E)02160.5 2.064E)04 450 2.131E+00 860 9.896E)01 1270 4.352E)01 1680 1.990E)01 3630 1.245E)02161.5 2.419E)04 451 2.208E+00 861 9.847E)01 1271 4.341E)01 1681 1.971E)01 3635 1.239E)02162.5 2.778E)04 452 2.125E+00 862 9.994E)01 1272 4.330E)01 1682 2.024E)01 3640 1.231E)02163.5 3.047E)04 453 1.996E+00 863 1.023E+00 1273 4.310E)01 1683 2.069E)01 3645 1.222E)02164.5 3.391E)04 454 2.079E+00 864 9.716E)01 1274 4.293E)01 1684 2.092E)01 3650 1.214E)02165.5 5.295E)04 455 2.091E+00 865 9.627E)01 1275 4.310E)01 1685 2.093E)01 3655 1.204E)02166.5 3.695E)04 456 2.138E+00 866 8.656E)01 1276 4.309E)01 1686 2.089E)01 3660 1.201E)02167.5 4.362E)04 457 2.172E+00 867 9.032E)01 1277 4.298E)01 1687 2.089E)01 3665 1.198E)02168.5 4.852E)04 458 2.100E+00 868 9.827E)01 1278 4.279E)01 1688 2.086E)01 3670 1.190E)02169.5 6.357E)04 459 2.086E+00 869 9.621E)01 1279 4.245E)01 1689 2.065E)01 3675 1.182E)02170.5 7.352E)04 460 2.092E+00 870 9.894E)01 1280 4.191E)01 1690 2.088E)01 3680 1.167E)02171.5 7.377E)04 461 2.138E+00 871 9.760E)01 1281 3.958E)01 1691 2.100E)01 3685 1.166E)02172.5 7.963E)04 462 2.150E+00 872 9.723E)01 1282 3.749E)01 1692 2.102E)01 3690 1.166E)02173.5 7.993E)04 463 2.136E+00 873 9.703E)01 1283 4.051E)01 1693 2.098E)01 3695 1.149E)02174.5 9.816E)04 464 2.095E+00 874 9.587E)01 1284 4.164E)01 1694 2.093E)01 3700 1.133E)02175.5 1.209E)03 465 2.063E+00 875 9.395E)01 1285 4.182E)01 1695 2.088E)01 3705 1.136E)02176.5 1.310E)03 466 2.079E+00 876 9.496E)01 1286 4.199E)01 1696 2.081E)01 3710 1.132E)02
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
443
Appendix (continued)
k Ek k Ek k Ek k Ek k Ek k Ek
177.5 1.580E)03 467 2.043E+00 877 9.588E)01 1287 4.208E)01 1697 2.078E)01 3715 1.130E)02178.5 1.762E)03 468 2.066E+00 878 9.702E)01 1288 4.192E)01 1698 2.076E)01 3720 1.129E)02179.5 1.723E)03 469 2.076E+00 879 9.550E)01 1289 4.192E)01 1699 2.060E)01 3725 1.125E)02180.5 2.061E)03 470 2.010E+00 880 9.344E)01 1290 4.139E)01 1700 2.043E)01 3730 1.119E)02181.5 2.481E)03 471 2.006E+00 881 9.231E)01 1291 4.172E)01 1701 2.039E)01 3735 1.101E)02182.5 2.312E)03 472 2.114E+00 882 9.436E)01 1292 4.190E)01 1702 2.026E)01 3740 1.075E)02183.5 2.471E)03 473 2.087E+00 883 9.448E)01 1293 4.166E)01 1703 2.022E)01 3745 1.073E)02184.5 2.114E)03 474 2.094E+00 884 9.410E)01 1294 4.157E)01 1704 2.043E)01 3750 1.083E)02185.5 2.417E)03 475 2.116E+00 885 9.480E)01 1295 4.174E)01 1705 2.028E)01 3755 1.081E)02186.5 2.769E)03 476 2.058E+00 886 9.126E)01 1296 4.175E)01 1710 1.981E)01 3760 1.080E)02187.5 3.211E)03 477 2.067E+00 887 9.158E)01 1297 4.138E)01 1715 1.993E)01 3765 1.078E)02188.5 3.402E)03 478 2.121E+00 888 9.357E)01 1298 4.133E)01 1720 1.959E)01 3770 1.073E)02189.5 3.834E)03 479 2.103E+00 889 9.360E)01 1299 4.154E)01 1725 1.933E)01 3775 1.063E)02190.5 3.969E)03 480 2.102E+00 890 9.387E)01 1300 4.138E)01 1730 1.911E)01 3780 1.059E)02191.5 4.360E)03 481 2.135E+00 891 9.316E)01 1301 4.113E)01 1735 1.814E)01 3785 1.056E)02192.5 4.664E)03 482 2.140E+00 892 9.167E)01 1302 4.094E)01 1740 1.848E)01 3790 1.048E)02193.5 3.532E)03 483 2.108E+00 893 9.112E)01 1303 4.063E)01 1745 1.857E)01 3795 1.043E)02194.5 5.901E)03 484 2.062E+00 894 9.134E)01 1304 4.076E)01 1750 1.843E)01 3800 1.039E)02195.5 5.754E)03 485 1.962E+00 895 9.098E)01 1305 4.098E)01 1755 1.842E)01 3805 1.035E)02196.5 6.512E)03 486 1.712E+00 896 9.232E)01 1306 4.096E)01 1760 1.816E)01 3810 1.029E)02197.5 6.603E)03 487 1.791E+00 897 9.093E)01 1307 4.073E)01 1765 1.797E)01 3815 1.024E)02198.5 6.658E)03 488 1.965E+00 898 9.131E)01 1308 4.068E)01 1770 1.783E)01 3820 1.021E)02199.5 7.231E)03 489 1.973E+00 899 9.104E)01 1309 4.065E)01 1775 1.758E)01 3825 1.019E)02200.5 7.933E)03 490 2.072E+00 900 8.896E)01 1310 4.039E)01 1780 1.735E)01 3830 1.013E)02201.5 8.826E)03 491 2.033E+00 901 8.590E)01 1311 4.037E)01 1785 1.726E)01 3835 1.005E)02202.5 8.766E)03 492 1.919E+00 902 8.678E)01 1312 3.928E)01 1790 1.721E)01 3840 1.002E)02203.5 1.010E)02 493 1.981E+00 903 9.008E)01 1313 3.962E)01 1795 1.701E)01 3845 9.991E)03204.5 1.119E)02 494 2.000E+00 904 9.098E)01 1314 3.996E)01 1800 1.682E)01 3850 9.942E)03205.5 1.159E)02 495 2.016E+00 905 9.072E)01 1315 3.878E)01 1805 1.668E)01 3855 9.883E)03206.5 1.190E)02 496 2.028E+00 906 8.862E)01 1316 3.971E)01 1810 1.654E)01 3860 9.806E)03207.5 1.388E)02 497 2.059E+00 907 8.934E)01 1317 3.989E)01 1815 1.583E)01 3865 9.739E)03208.5 1.565E)02 498 1.962E+00 908 8.777E)01 1318 3.972E)01 1820 1.555E)01 3870 9.701E)03209.5 2.250E)02 499 1.988E+00 909 8.598E)01 1319 4.000E)01 1825 1.599E)01 3875 9.682E)03210.5 3.016E)02 500 1.932E+00 910 8.768E)01 1320 3.980E)01 1830 1.592E)01 3880 9.631E)03
444
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
211.5 3.682E)02 501 1.899E+00 911 8.722E)01 1321 3.957E)01 1835 1.576E)01 3885 9.544E)03212.5 3.344E)02 502 1.878E+00 912 8.734E)01 1322 3.965E)01 1840 1.555E)01 3890 9.526E)03213.5 3.190E)02 503 1.961E+00 913 8.926E)01 1323 3.961E)01 1845 1.530E)01 3895 9.475E)03214.5 4.486E)02 504 1.933E+00 914 8.820E)01 1324 3.964E)01 1850 1.533E)01 3900 9.424E)03215.5 3.663E)02 505 1.983E+00 915 8.747E)01 1325 3.946E)01 1855 1.520E)01 3905 9.398E)03216.5 3.437E)02 506 2.048E+00 916 8.785E)01 1326 3.923E)01 1860 1.500E)01 3910 9.358E)03217.5 3.394E)02 507 1.948E+00 917 8.661E)01 1327 3.919E)01 1865 1.479E)01 3915 9.313E)03218.5 4.915E)02 508 1.881E+00 918 8.703E)01 1328 3.883E)01 1870 1.455E)01 3920 9.262E)03219.5 5.061E)02 509 1.929E+00 919 8.733E)01 1329 3.836E)01 1875 1.348E)01 3925 9.226E)03220.5 5.191E)02 510 1.915E+00 920 8.626E)01 1330 3.893E)01 1880 1.424E)01 3930 9.174E)03221.5 3.602E)02 511 1.962E+00 921 8.410E)01 1331 3.883E)01 1885 1.431E)01 3935 9.121E)03222.5 5.262E)02 512 1.981E+00 922 8.378E)01 1332 3.840E)01 1890 1.409E)01 3940 9.093E)03223.5 6.923E)02 513 1.874E+00 923 8.148E)01 1333 3.901E)01 1895 1.378E)01 3945 9.030E)03224.5 6.178E)02 514 1.859E+00 924 8.406E)01 1334 3.905E)01 1900 1.388E)01 3950 8.952E)03225.5 5.441E)02 515 1.840E+00 925 8.404E)01 1335 3.880E)01 1905 1.381E)01 3955 8.896E)03226.5 3.993E)02 516 1.836E+00 926 8.297E)01 1336 3.886E)01 1910 1.366E)01 3960 8.871E)03227.5 3.837E)02 517 1.630E+00 927 8.561E)01 1337 3.870E)01 1915 1.357E)01 3965 8.854E)03228.5 5.683E)02 518 1.714E+00 928 8.575E)01 1338 3.847E)01 1920 1.341E)01 3970 8.813E)03229.5 4.896E)02 519 1.798E+00 929 8.461E)01 1339 3.789E)01 1925 1.334E)01 3975 8.764E)03230.5 5.909E)02 520 1.864E+00 930 8.505E)01 1340 3.830E)01 1930 1.303E)01 3980 8.716E)03231.5 4.909E)02 521 1.882E+00 931 8.505E)01 1341 3.837E)01 1935 1.302E)01 3985 8.643E)03232.5 5.513E)02 522 1.885E+00 932 8.460E)01 1342 3.834E)01 1940 1.272E)01 3990 8.589E)03233.5 4.566E)02 523 1.852E+00 933 8.492E)01 1343 3.830E)01 1945 1.203E)01 3995 8.533E)03234.5 3.652E)02 524 1.921E+00 934 8.471E)01 1344 3.840E)01 1950 1.246E)01 4000 8.300E)03235.5 5.941E)02 525 1.948E+00 935 8.371E)01 1345 3.820E)01 1955 1.267E)01 4020 7.975E)03236.5 4.667E)02 526 1.862E+00 936 8.330E)01 1346 3.803E)01 1960 1.251E)01 4040 7.815E)03237.5 5.654E)02 527 1.758E+00 937 8.389E)01 1347 3.811E)01 1965 1.230E)01 4060 7.658E)03238.5 3.827E)02 528 1.862E+00 938 8.382E)01 1348 3.809E)01 1970 1.225E)01 4080 7.506E)03239.5 4.642E)02 529 1.965E+00 939 8.322E)01 1349 3.780E)01 1975 1.204E)01 4100 7.357E)03240.5 4.219E)02 530 1.938E+00 940 8.224E)01 1350 3.751E)01 1980 1.191E)01 4120 7.213E)03241.5 5.072E)02 531 1.968E+00 941 7.925E)01 1351 3.777E)01 1985 1.183E)01 4140 7.071E)03242.5 7.710E)02 532 1.901E+00 942 8.090E)01 1352 3.791E)01 1990 1.182E)01 4160 6.933E)03243.5 6.826E)02 533 1.845E+00 943 8.189E)01 1353 3.775E)01 1995 1.162E)01 4180 6.798E)03244.5 6.614E)02 534 1.898E+00 944 8.079E)01 1354 3.753E)01 2000 1.159E)01 4200 6.667E)03245.5 5.095E)02 535 1.937E+00 945 8.160E)01 1355 3.716E)01 2005 1.147E)01 4220 6.538E)03246.5 5.134E)02 536 1.953E+00 946 8.189E)01 1356 3.699E)01 2010 1.144E)01 4240 6.413E)03247.5 5.980E)02 537 1.874E+00 947 8.207E)01 1357 3.704E)01 2015 1.134E)01 4260 6.290E)03
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
445
Appendix (continued)
k Ek k Ek k Ek k Ek k Ek k Ek
248.5 4.587E)02 538 1.906E+00 948 8.214E)01 1358 3.732E)01 2020 1.114E)01 4280 6.171E)03249.5 5.894E)02 539 1.890E+00 949 8.207E)01 1359 3.696E)01 2025 1.108E)01 4300 6.054E)03250.5 6.228E)02 540 1.813E+00 950 8.149E)01 1360 3.699E)01 2030 1.091E)01 4320 5.941E)03251.5 4.689E)02 541 1.831E+00 951 8.105E)01 1361 3.728E)01 2035 1.081E)01 4340 5.829E)03252.5 4.114E)02 542 1.891E+00 952 8.112E)01 1362 3.688E)01 2040 1.076E)01 4360 5.721E)03253.5 5.376E)02 543 1.866E+00 953 8.038E)01 1363 3.670E)01 2045 1.077E)01 4380 5.614E)03254.5 5.853E)02 544 1.903E+00 954 7.792E)01 1364 3.685E)01 2050 1.064E)01 4400 5.511E)03255.5 8.455E)02 545 1.896E+00 955 7.660E)01 1365 3.694E)01 2055 1.053E)01 4420 5.409E)03256.5 1.020E)01 546 1.909E+00 956 7.984E)01 1366 3.671E)01 2060 1.037E)01 4440 5.311E)03257.5 1.274E)01 547 1.904E+00 957 7.922E)01 1367 3.659E)01 2065 1.029E)01 4460 5.214E)03258.5 1.355E)01 548 1.879E+00 958 8.008E)01 1368 3.645E)01 2070 1.023E)01 4480 5.119E)03259.5 1.116E)01 549 1.883E+00 959 8.016E)01 1369 3.621E)01 2075 1.022E)01 4500 5.026E)03260.5 9.016E)02 550 1.905E+00 960 7.903E)01 1370 3.619E)01 2080 1.006E)01 4520 4.936E)03261.5 8.884E)02 551 1.881E+00 961 7.941E)01 1371 3.626E)01 2085 9.972E)02 4540 4.847E)03262.5 1.119E)01 552 1.894E+00 962 7.873E)01 1372 3.656E)01 2090 9.874E)02 4560 4.761E)03263.5 1.631E)01 553 1.861E+00 963 7.834E)01 1373 3.654E)01 2095 9.729E)02 4580 4.677E)03264.5 2.743E)01 554 1.906E+00 964 7.831E)01 1374 3.622E)01 2100 9.745E)02 4600 4.594E)03265.5 2.761E)01 555 1.911E+00 965 7.800E)01 1375 3.593E)01 2105 9.684E)02 4620 4.513E)03266.5 2.617E)01 556 1.887E+00 966 7.737E)01 1376 3.577E)01 2110 9.573E)02 4640 4.434E)03267.5 2.701E)01 557 1.830E+00 967 7.804E)01 1377 3.607E)01 2115 9.489E)02 4660 4.356E)03268.5 2.623E)01 558 1.819E+00 968 7.793E)01 1378 3.612E)01 2120 9.370E)02 4680 4.281E)03269.5 2.421E)01 559 1.788E+00 969 7.788E)01 1379 3.619E)01 2125 9.285E)02 4700 4.207E)03270.5 2.975E)01 560 1.812E+00 970 7.780E)01 1380 3.604E)01 2130 9.277E)02 4720 4.134E)03271.5 2.451E)01 561 1.838E+00 971 7.756E)01 1381 3.592E)01 2135 9.165E)02 4740 4.064E)03272.5 1.956E)01 562 1.828E+00 972 7.774E)01 1382 3.562E)01 2140 9.141E)02 4760 3.994E)03273.5 2.249E)01 563 1.882E+00 973 7.692E)01 1383 3.577E)01 2145 9.059E)02 4780 3.926E)03274.5 1.265E)01 564 1.834E+00 974 7.598E)01 1384 3.583E)01 2150 9.007E)02 4800 3.859E)03275.5 1.850E)01 565 1.821E+00 975 7.690E)01 1385 3.564E)01 2155 8.921E)02 4820 3.794E)03276.5 2.680E)01 566 1.797E+00 976 7.647E)01 1386 3.565E)01 2160 8.778E)02 4840 3.731E)03277.5 2.625E)01 567 1.835E+00 977 7.630E)01 1387 3.558E)01 2165 8.270E)02 4860 3.668E)03278.5 1.709E)01 568 1.829E+00 978 7.619E)01 1388 3.570E)01 2170 8.508E)02 4880 3.607E)03279.5 7.821E)02 569 1.807E+00 979 7.555E)01 1389 3.550E)01 2175 8.562E)02 4900 3.547E)03280 7.846E)02 570 1.803E+00 980 7.594E)01 1390 3.529E)01 2180 8.491E)02 4920 3.488E)03280.5 1.023E)01 571 1.786E+00 981 7.635E)01 1391 3.553E)01 2185 8.458E)02 4940 3.431E)03
446
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
281 1.716E)01 572 1.843E+00 982 7.609E)01 1392 3.541E)01 2190 8.358E)02 4960 3.375E)03281.5 2.410E)01 573 1.865E+00 983 7.554E)01 1393 3.528E)01 2195 8.337E)02 4980 3.320E)03282 2.916E)01 574 1.862E+00 984 7.544E)01 1394 3.511E)01 2200 8.258E)02 5000 3.266E)03282.5 3.142E)01 575 1.832E+00 985 7.550E)01 1395 3.505E)01 2205 8.068E)02 5050 3.197E)03283 3.429E)01 576 1.815E+00 986 7.494E)01 1396 3.518E)01 2210 8.048E)02 5100 3.078E)03283.5 3.223E)01 577 1.833E+00 987 7.479E)01 1397 3.521E)01 2215 8.019E)02 5150 2.964E)03284 3.211E)01 578 1.800E+00 988 7.489E)01 1398 3.516E)01 2220 7.969E)02 5200 2.854E)03284.5 2.514E)01 579 1.798E+00 989 7.371E)01 1399 3.478E)01 2225 7.868E)02 5250 2.751E)03285 1.185E)01 580 1.818E+00 990 7.402E)01 1400 3.429E)01 2230 7.827E)02 5300 2.652E)03285.5 1.377E)01 581 1.817E+00 991 7.415E)01 1401 3.455E)01 2235 7.761E)02 5350 2.558E)03286 3.006E)01 582 1.842E+00 992 7.438E)01 1402 3.473E)01 2240 7.656E)02 5400 2.467E)03286.5 3.581E)01 583 1.839E+00 993 7.418E)01 1403 3.447E)01 2245 7.616E)02 5450 2.380E)03287 3.778E)01 584 1.850E+00 994 7.418E)01 1404 3.449E)01 2250 7.541E)02 5500 2.298E)03287.5 3.782E)01 585 1.802E+00 995 7.385E)01 1405 3.455E)01 2255 7.456E)02 5550 2.218E)03288 2.504E)01 586 1.765E+00 996 7.379E)01 1406 3.447E)01 2260 7.414E)02 5600 2.143E)03288.5 3.588E)01 587 1.810E+00 997 7.376E)01 1407 3.446E)01 2265 7.347E)02 5650 2.071E)03289 4.201E)01 588 1.793E+00 998 7.351E)01 1408 3.446E)01 2270 7.318E)02 5700 2.001E)03289.5 4.911E)01 589 1.646E+00 999 7.317E)01 1409 3.452E)01 2275 7.264E)02 5750 1.935E)03290 6.177E)01 590 1.716E+00 1000 7.307E)01 1410 3.435E)01 2280 7.142E)02 5800 1.871E)03290.5 6.459E)01 591 1.782E+00 1001 7.352E)01 1411 3.364E)01 2285 7.103E)02 5850 1.810E)03291 6.097E)01 592 1.780E+00 1002 7.320E)01 1412 3.365E)01 2290 7.064E)02 5900 1.751E)03291.5 6.020E)01 593 1.784E+00 1003 7.233E)01 1413 3.384E)01 2295 6.909E)02 5950 1.695E)03292 5.728E)01 594 1.781E+00 1004 7.100E)01 1414 3.398E)01 2300 6.918E)02 6000 1.641E)03292.5 4.965E)01 595 1.752E+00 1005 6.779E)01 1415 3.409E)01 2305 6.897E)02 6050 1.589E)03293 5.672E)01 596 1.779E+00 1006 7.078E)01 1416 3.387E)01 2310 6.843E)02 6100 1.539E)03293.5 5.760E)01 597 1.767E+00 1007 7.208E)01 1417 3.408E)01 2315 6.760E)02 6150 1.491E)03294 5.039E)01 598 1.751E+00 1008 7.203E)01 1418 3.393E)01 2320 6.671E)02 6200 1.445E)03294.5 5.434E)01 599 1.746E+00 1009 7.199E)01 1419 3.368E)01 2325 6.534E)02 6250 1.401E)03295 5.160E)01 600 1.737E+00 1010 7.188E)01 1420 3.368E)01 2330 6.561E)02 6300 1.358E)03295.5 5.821E)01 601 1.715E+00 1011 7.167E)01 1421 3.336E)01 2335 6.509E)02 6350 1.318E)03296 6.210E)01 602 1.702E+00 1012 7.141E)01 1422 3.311E)01 2340 6.487E)02 6400 1.278E)03296.5 4.926E)01 603 1.727E+00 1013 7.141E)01 1423 3.318E)01 2345 6.461E)02 6450 1.241E)03297 4.241E)01 604 1.754E+00 1014 7.091E)01 1424 3.320E)01 2350 6.351E)02 6500 1.204E)03297.5 5.976E)01 605 1.743E+00 1015 7.050E)01 1425 3.301E)01 2355 6.220E)02 6550 1.168E)03298 5.577E)01 606 1.732E+00 1016 7.023E)01 1426 3.280E)01 2360 6.246E)02 6600 1.134E)03298.5 3.788E)01 607 1.745E+00 1017 7.045E)01 1427 3.293E)01 2365 6.230E)02 6650 1.102E)03299 5.767E)01 608 1.722E+00 1018 6.999E)01 1428 3.303E)01 2370 6.157E)02 6700 1.070E)03
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
447
Appendix (continued)
k Ek k Ek k Ek k Ek k Ek k Ek
299.5 5.214E)01 609 1.722E+00 1019 6.914E)01 1429 3.247E)01 2375 6.089E)02 6750 1.040E)03300 4.166E)01 610 1.706E+00 1020 6.972E)01 1430 3.287E)01 2380 6.055E)02 6800 1.011E)03300.5 4.391E)01 611 1.713E+00 1021 6.951E)01 1431 3.291E)01 2385 5.856E)02 6850 9.825E)04301 4.939E)01 612 1.706E+00 1022 6.920E)01 1432 3.341E)01 2390 5.906E)02 6900 9.552E)04301.5 5.295E)01 613 1.683E+00 1023 7.000E)01 1433 3.308E)01 2395 5.884E)02 6950 9.290E)04302 3.743E)01 614 1.657E+00 1024 6.976E)01 1434 3.301E)01 2400 5.847E)02 7000 9.036E)04302.5 5.437E)01 615 1.690E+00 1025 6.971E)01 1435 3.310E)01 2405 5.813E)02 7050 8.790E)04303 6.767E)01 616 1.632E+00 1026 6.957E)01 1436 3.303E)01 2410 5.769E)02 7100 8.553E)04303.5 6.886E)01 617 1.627E+00 1027 6.939E)01 1437 3.307E)01 2415 5.596E)02 7150 8.324E)04304 5.771E)01 618 1.688E+00 1028 6.930E)01 1438 3.304E)01 2420 5.622E)02 7200 8.102E)04304.5 6.481E)01 619 1.670E+00 1029 6.853E)01 1439 3.272E)01 2425 5.602E)02 7250 7.888E)04305 6.729E)01 620 1.681E+00 1030 6.876E)01 1440 3.142E)01 2430 5.580E)02 7300 7.681E)04305.5 6.124E)01 621 1.686E+00 1031 6.859E)01 1441 3.225E)01 2435 5.515E)02 7350 7.481E)04306 5.422E)01 622 1.670E+00 1032 6.831E)01 1442 3.184E)01 2440 5.501E)02 7400 7.287E)04306.5 5.857E)01 623 1.648E+00 1033 6.730E)01 1443 3.218E)01 2445 5.429E)02 7450 7.100E)04307 6.442E)01 624 1.617E+00 1034 6.728E)01 1444 3.206E)01 2450 5.337E)02 7500 6.918E)04307.5 6.515E)01 625 1.613E+00 1035 6.749E)01 1445 3.248E)01 2455 5.297E)02 7550 6.743E)04308 6.563E)01 626 1.638E+00 1036 6.791E)01 1446 3.222E)01 2460 5.311E)02 7600 6.572E)04308.5 6.802E)01 627 1.665E+00 1037 6.678E)01 1447 3.223E)01 2465 5.299E)02 7650 6.407E)04309 5.619E)01 628 1.663E+00 1038 6.710E)01 1448 3.242E)01 2470 5.217E)02 7700 6.248E)04309.5 5.133E)01 629 1.663E+00 1039 6.710E)01 1449 3.231E)01 2475 5.207E)02 7750 6.094E)04310 4.648E)01 630 1.628E+00 1040 6.684E)01 1450 3.188E)01 2480 5.100E)02 7800 5.944E)04310.5 7.144E)01 631 1.629E+00 1041 6.716E)01 1451 3.154E)01 2485 5.065E)02 7850 5.799E)04311 8.236E)01 632 1.604E+00 1042 6.670E)01 1452 3.186E)01 2490 5.079E)02 7900 5.658E)04311.5 7.643E)01 633 1.638E+00 1043 6.652E)01 1453 3.180E)01 2495 5.050E)02 7950 5.522E)04312 6.417E)01 634 1.611E+00 1044 6.679E)01 1454 3.145E)01 2500 5.034E)02 8000 5.389E)04312.5 6.965E)01 635 1.631E+00 1045 6.592E)01 1455 3.141E)01 2505 4.997E)02 8050 5.261E)04313 7.110E)01 636 1.603E+00 1046 6.523E)01 1456 3.151E)01 2510 4.919E)02 8100 5.137E)04313.5 7.252E)01 637 1.625E+00 1047 6.586E)01 1457 3.171E)01 2515 4.894E)02 8150 5.015E)04314 7.931E)01 638 1.633E+00 1048 6.627E)01 1458 3.197E)01 2520 4.881E)02 8200 4.898E)04314.5 5.927E)01 639 1.611E+00 1049 6.608E)01 1459 3.184E)01 2525 4.856E)02 8250 4.784E)04315 7.536E)01 640 1.591E+00 1050 6.583E)01 1460 3.165E)01 2530 4.826E)02 8300 4.673E)04315.5 6.800E)01 641 1.587E+00 1051 6.580E)01 1461 3.154E)01 2535 4.779E)02 8350 4.566E)04316 5.180E)01 642 1.576E+00 1052 6.559E)01 1462 3.127E)01 2540 4.700E)02 8400 4.462E)04
448
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
316.5 6.628E)01 643 1.597E+00 1053 6.514E)01 1463 3.114E)01 2545 4.685E)02 8450 4.361E)04317 8.224E)01 644 1.588E+00 1054 6.536E)01 1464 3.134E)01 2550 4.657E)02 8500 4.263E)04317.5 8.798E)01 645 1.593E+00 1055 6.549E)01 1465 3.113E)01 2555 4.619E)02 8550 4.166E)04318 6.342E)01 646 1.569E+00 1056 6.536E)01 1466 3.135E)01 2560 4.587E)02 8600 4.073E)04318.5 6.820E)01 647 1.577E+00 1057 6.524E)01 1467 3.129E)01 2565 4.556E)02 8650 3.983E)04319 7.530E)01 648 1.591E+00 1058 6.372E)01 1468 3.116E)01 2570 4.535E)02 8700 3.895E)04319.5 6.829E)01 649 1.560E+00 1059 6.389E)01 1469 3.135E)01 2575 4.527E)02 8750 3.809E)04320 8.363E)01 650 1.529E+00 1060 6.384E)01 1470 3.083E)01 2580 4.473E)02 8800 3.727E)04320.5 9.076E)01 651 1.586E+00 1061 6.382E)01 1471 3.080E)01 2585 4.365E)02 8850 3.646E)04321 7.151E)01 652 1.568E+00 1062 6.426E)01 1472 3.067E)01 2590 4.405E)02 8900 3.567E)04321.5 6.749E)01 653 1.566E+00 1063 6.370E)01 1473 3.033E)01 2595 4.376E)02 8950 3.491E)04322 8.146E)01 654 1.543E+00 1064 6.442E)01 1474 3.028E)01 2600 4.354E)02 9000 3.417E)04322.5 7.013E)01 655 1.509E+00 1065 6.419E)01 1475 3.036E)01 2605 4.334E)02 9050 3.344E)04323 6.399E)01 656 1.321E+00 1066 6.274E)01 1476 3.049E)01 2610 4.297E)02 9100 3.273E)04323.5 6.829E)01 657 1.356E+00 1067 6.361E)01 1477 3.034E)01 2615 4.257E)02 9150 3.205E)04324 7.812E)01 658 1.509E+00 1068 6.240E)01 1478 3.035E)01 2620 4.179E)02 9200 3.138E)04324.5 8.264E)01 659 1.513E+00 1069 6.036E)01 1479 3.075E)01 2625 3.984E)02 9250 3.073E)04325 7.840E)01 660 1.517E+00 1070 6.262E)01 1480 3.055E)01 2630 4.101E)02 9300 3.010E)04325.5 9.411E)01 661 1.527E+00 1071 6.297E)01 1481 3.044E)01 2635 4.141E)02 9350 2.948E)04326 1.052E+00 662 1.537E+00 1072 6.272E)01 1482 3.038E)01 2640 4.059E)02 9400 2.887E)04326.5 9.968E)01 663 1.504E+00 1073 6.168E)01 1483 3.012E)01 2645 4.071E)02 9450 2.829E)04327 1.009E+00 664 1.512E+00 1074 6.265E)01 1484 3.054E)01 2650 4.055E)02 9500 2.771E)04327.5 9.959E)01 665 1.506E+00 1075 6.132E)01 1485 3.060E)01 2655 4.003E)02 9550 2.716E)04328 9.529E)01 666 1.504E+00 1076 6.271E)01 1486 3.021E)01 2660 3.996E)02 9600 2.661E)04328.5 9.132E)01 667 1.499E+00 1077 6.270E)01 1487 2.896E)01 2665 3.917E)02 9650 2.608E)04329 1.024E+00 668 1.496E+00 1078 6.177E)01 1488 2.793E)01 2670 3.943E)02 9700 2.557E)04329.5 1.139E+00 669 1.517E+00 1079 6.143E)01 1489 3.008E)01 2675 3.907E)02 9750 2.507E)04330 1.162E+00 670 1.509E+00 1080 6.229E)01 1490 3.026E)01 2680 3.899E)02 9800 2.457E)04330.5 9.725E)01 671 1.507E+00 1081 6.057E)01 1491 3.013E)01 2685 3.883E)02 9850 2.410E)04331 1.005E+00 672 1.493E+00 1082 6.003E)01 1492 3.011E)01 2690 3.854E)02 9900 2.363E)04331.5 9.815E)01 673 1.514E+00 1083 5.994E)01 1493 3.028E)01 2695 3.823E)02 9950 2.317E)04332 1.006E+00 674 1.507E+00 1084 6.140E)01 1494 3.032E)01 2700 3.806E)02 10000 2.272E)04332.5 9.721E)01 675 1.492E+00 1085 6.176E)01 1495 2.980E)01 2705 3.776E)02 11000 1.540E)04333 9.790E)01 676 1.501E+00 1086 6.100E)01 1496 2.938E)01 2710 3.745E)02 12000 1.085E)04333.5 9.164E)01 677 1.485E+00 1087 5.893E)01 1497 2.974E)01 2715 3.726E)02 13000 7.856E)05334 9.417E)01 678 1.488E+00 1088 6.024E)01 1498 2.975E)01 2720 3.700E)02 14000 5.831E)05334.5 1.040E+00 679 1.463E+00 1089 6.015E)01 1499 2.976E)01 2725 3.669E)02 15000 4.418E)05
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
449
Appendix (continued)
k Ek k Ek k Ek k Ek k Ek k Ek
335 9.537E)01 680 1.474E+00 1090 6.095E)01 1500 2.993E)01 2730 3.650E)02 16000 3.401E)05335.5 1.072E+00 681 1.464E+00 1091 6.065E)01 1501 2.975E)01 2735 3.629E)02 17000 2.666E)05336 7.396E)01 682 1.462E+00 1092 6.009E)01 1502 2.825E)01 2740 3.597E)02 18000 2.120E)05336.5 9.049E)01 683 1.459E+00 1093 5.811E)01 1503 2.783E)01 2745 3.584E)02 19000 1.705E)05337 7.526E)01 684 1.452E+00 1094 5.568E)01 1504 2.745E)01 2750 3.554E)02 20000 1.385E)05337.5 9.392E)01 685 1.463E+00 1095 5.835E)01 1505 2.742E)01 2755 3.502E)02 25000 5.699E)06338 8.864E)01 686 1.456E+00 1096 5.830E)01 1506 2.871E)01 2760 3.460E)02 30000 2.760E)06338.5 9.904E)01 687 1.474E+00 1097 5.839E)01 1507 2.916E)01 2765 3.465E)02 35000 1.488E)06339 9.808E)01 688 1.457E+00 1098 5.759E)01 1508 2.869E)01 2770 3.456E)02 40000 8.770E)07339.5 9.380E)01 689 1.454E+00 1099 5.892E)01 1509 2.910E)01 2775 3.425E)02 50000 3.608E)07340 1.133E+00 690 1.444E+00 1100 5.927E)01 1510 2.938E)01 2780 3.409E)02 60000 1.743E)07340.5 1.016E+00 691 1.433E+00 1101 5.848E)01 1511 2.926E)01 2785 3.387E)02 80000 5.539E)08341 9.640E)01 692 1.420E+00 1102 5.772E)01 1512 2.872E)01 2790 3.376E)02 100000 2.280E)08341.5 8.880E)01 693 1.422E+00 1103 5.885E)01 1513 2.865E)01 2795 3.353E)02 120000 1.102E)08342 1.060E+00 694 1.426E+00 1104 5.865E)01 1514 2.868E)01 2800 3.325E)02 150000 4.531E)09342.5 9.903E)01 695 1.426E+00 1105 5.863E)01 1515 2.882E)01 2805 3.302E)02 200000 1.441E)09343 1.084E+00 696 1.438E+00 1106 5.845E)01 1516 2.857E)01 2810 3.287E)02 250000 5.916E)10343.5 1.017E+00 697 1.432E+00 1107 5.824E)01 1517 2.871E)01 2815 3.263E)02 300000 2.779E)10344 7.664E)01 698 1.412E+00 1108 5.827E)01 1518 2.874E)01 2820 3.242E)02 400000 9.514E)11344.5 7.515E)01 699 1.431E+00 1109 5.821E)01 1519 2.867E)01 2825 3.218E)02 1000000 3.184E)12
k: Wavelength (nm); Ek: Irradiance (Wm�2 nm�1).a Also available as a text file from http://rredc.nrel.gov/solar/spectra/am0/special.html.
450
C.A.Gueymard
/SolarEnerg
y76(2004)423–453
C.A. Gueymard / Solar Energy 76 (2004) 423–453 451
References
Anderson, G.P. et al., 1993. MODTRAN2: suitability for
remote sensing. In: Kohnle, A., Miller, W.B. (Eds.), Proc.
Atmospheric Propagation and Remote Sensing II, vol. 1968.
SPIE, Orlando, pp. 514–525.
Anderson, G.P., Hall, L.A., 1989. Solar irradiance between
2000 and 3100 Angstroms with spectral band pass of 1.0
Angstrom. J. Geophys. Res. 94, 6435–6441.
Arvesen, J.C., Griffin, R.N., Pearson, B.D., 1969. Determina-
tion of extraterrestrial solar spectral irradiance from a
research aircraft. Appl. Opt. 8, 2215–2232.
ASTM, 2000. Standard solar constant and zero air mass solar
spectral irradiance tables. Standard E490-00. American
Society for Testing and Materials, West Conshohocken, PA.
Berk, A. et al., 1999. MODTRAN4 radiative transfer modeling
for atmospheric correction. In: Proc. Optical Spectroscopic
Techniques and Instrumentation for Atmospheric and
Space Research III, SPIE vol. 3756.
Bird, R.E., 1984. A simple, solar spectral model for direct-
normal and diffuse horizontal irradiance. Solar Energy 32,
461–471.
Bird, R.E., Riordan, C., 1986. Simple solar spectral model for
direct and diffuse irradiance on horizontal and tilted planes
at the Earth’s surface for cloudless atmospheres. J. Clim.
Appl. Meteor. 25, 87–97.
Brasseur, G., Simon, P.C., 1981. Stratospheric chemical and
thermal response to long-term variability in solar UV
irradiance. J. Geophys. Res. 86C, 7343–7362.
Brueckner, G.E., Edlow, K.L., Floyd, L.E., Lean, J.L.,
VanHoosier, M.E., 1993. The Solar Ultraviolet Spectral
Irradiance Monitor (SUSIM) experiment on board the
Upper Atmosphere Research Satellite (UARS). J. Geophys.
Res. 98D, 10695–10711.
Brueckner, G.E., Floyd, L.E., Lund, P.A., Prinz, D.K.,
VanHoosier, M.E., 1996. Solar ultraviolet spectral-irradi-
ance observations from the SUSIM-UARS experiment.
Metrologia 32, 661–665.
Burlov-Vasiljev, K.A., Gurtovenko, E.A., Matvejev, Y.B.,
1995. New absolute measurements of the solar spectrum
310–685 nm. Solar Phys. 157, 51.
Burlov-Vasiljev, K.A., Matvejev, Y.B., Vasiljeva, I.E., 1998.
New measurements of the solar disk-center spectral intensity
in the near IR from 645 nm to 1070 nm. Solar Phys. 177, 25–
40.
Cebula, R.P., Thuillier, G.O., VanHoosier, M.E., Hilsenrath,
E., Herse, M., Brueckner, G.E., Simon, P.C., 1996. Obser-
vations of the solar irradiance in the 200–350 nm interval
during the ATLAS-1 mission: a comparison among three
sets of measurements––SSBUV, SOLSPEC, and SUSIM.
Geophys. Res. Lett. 23, 2289–2292.
Chance, K., Spurr, R.J.D., 1997. Ring effect studies: Rayleigh
scattering, including molecular parameters for rotational
Raman scattering, and the Fraunhofer spectrum. Appl. Opt.
36, 5224–5230.
Chandra, S., Lean, J.L., White, O.R., Prinz, D.K., Rottman,
G.J., Brueckner, G.E., 1995. Solar UV irradiance variability
during the declining phase of the solar cycle 22. Geophys.
Res. Lett. 22, 2481–2484.
Clough, S.A., Iacono, M.J., Moncet, J.L., 1992. Line-by-line
calculation of atmospheric fluxes and cooling rates: appli-
cation to water vapor. J. Geophys. Res. 97, 15761–
15785.
Clough, S.A., Kneizys, F.X., Rothman, L.S., Gallery, W.O.,
1981. Atmospheric spectral transmittance and radiance:
FASCOD1B. Proceedings, SPIE vol. 277, 152 pp.
Colina, L., Bohlin, R.C., Castelli, F., 1996. The 0.12–2.5 lmabsolute flux distribution of the sun for comparison with
solar analog stars. Astron. J. 112, 307–315.
Fligge, M., Solanki, S.K., 1998a. Long-term behavior of
emission from solar faculae: steps towards a robust index.
Astron. Astrophys. 332, 1082–1086.
Fligge, M., Solanki, S.K., 1998b. Search for a robust index of
long-term facular variations. ASP Conf. Ser. 140, 317–321.
Fligge, M., Solanki, S.K., 2000. The solar spectral irradiance
since 1700. Geophys. Res. Lett. 27, 2157–2160.
Fligge, M., Solanki, S.K., Unruh, Y.C., Fr€ohlich, C., Wehrli,
C., 1998. A model of solar total and spectral irradiance
variations. Astron. Astrophys. 335, 709–718.
Floyd, L.E., Prinz, D.K., Crane, P.C., Herring, L.C., Brueck-
ner, G.E., 1999. SUSIM UARS measurements of solar UV
irradiance. Adv. Space Res. 24, 225–228.
Floyd, L.E., Reiser, P.A., Crane, P.C., Herring, L.C., Prinz,
D.K., Brueckner, G.E., 1998. Solar cycle 22 UV spectral
irradiance variability: current measurements by SUSIM
UARS. Solar Phys. 177, 79–87.
Foukal, P., Lean, J., 1990. An empirical model of total solar
irradiance variation between 1874 and 1988. Science 247,
556–558.
Fr€ohlich, C., 1983. Data on total and spectral irradiance:
comments. Appl. Opt. 22, 3928.
Fr€ohlich, C., 2002. Total solar irradiance variations since 1978.
Adv. Space Res. 29, 1409–1416.
Fr€ohlich, C., 2004. Solar irradiance variability. In: Pap, J.M.
et al. (Eds.), Solar Variability and its Effects on Climate.
Geophysical Monograph 141, American Geophysical
Union.
Fr€ohlich, C., Lean, J., 1998. The sun’s total irradiance: cycles,
trends and related climate change uncertainties since 1976.
Geophys. Res. Lett. 25, 4377–4380.
Gao, B.C., Green, R.O., 1995. Presence of terrestrial atmo-
spheric gas absorption bands in standard extraterrestrial
solar irradiance curves in the near-infrared spectral region.
Appl. Opt. 34, 6263–6268.
Green, R.O., Gao, B.C., 1993. A proposed update to the solar
irradiance spectrum used in LOWTRAN and MODTRAN.
In: Green, R.O. (Ed.), Proc. AVIRIS Workshop, Summa-
ries of the Fourth Annual JPL Airborne Geoscience
Workshop, NASA/JPL Publ. 93–26, vol. 1.
Gueymard, C., 2001. Parameterized transmittance model for
direct beam and circumsolar spectral irradiance. Solar
Energy 71, 325–346.
Gueymard, C., Myers, D., Emery, K., 2002. Proposed reference
irradiance spectra for solar energy systems testing. Solar
Energy 73, 443–467.
Gueymard, C.A., 2003. Interdisciplinary applications of a
versatile spectral solar irradiance model: a review. In: Proc.
Int’l Expert. Conf. on Measurement and Modeling of Solar
Radiation, Edinburgh, Scotland.
Harrison, L., Kiedron, P., Berndt, J., Schlemmer, J., 2003. The
solar spectrum 360 to 1050 nm from rotating shadowband
spectroradiometer (RSS) measurements at the Southern
452 C.A. Gueymard / Solar Energy 76 (2004) 423–453
Great Plains Site. J. Geophys. Res. 1080, 4424, doi:10.1029/
2001JD001311.
Heath, D.F., Schlesinger, B.M., 1986. The Mg 280-nm doublet
as a monitor of changes in solar ultraviolet irradiance. J.
Geophys. Res. 91D, 8672–8682.
Hoyt, D.V., Schatten, K.H., 1997. The Role of the Sun in
Climate Change. Oxford Univ. Press, New York.
Iqbal, M., 1983. An Introduction to Solar Radiation. Academic
Press, Toronto.
Jacquinot, P., 1954. The luminosity of spectrometers with
prisms, gratings or Fabry–Perot etalons. J. Opt. Soc. Am.
44, 761–765.
Johnson, F.S., 1954. The solar constant. J. Meteorol. 11, 431–
439.
Kaye, J.A., Miller, T.L., 1996. The ATLAS series of shuttle
missions. Geophys. Res. Lett. 23, 2285–2288.
Kurucz, R.L., 1995. The solar irradiance by computation. In:
Anderson, G.P. et al. (Eds.), Proc. 17th Annual Conf.
Transmission Models. Phillips Lab., Hanscom AFB, PL-
TR-95-2060, pp. 333–334.
Kurucz, R.L., Furenlid, I., Brault, J., Testerman, L., 1984.
Solar flux atlas from 296 to 1300 nm. National Solar
Observatory Atlas No. 1, NOAO, Sunspot, NM.
Lean, J., 1991. Variations in the sun’s radiative output. Rev.
Geophys. 29, 505–535.
Lean, J., 1997. The sun’s variable radiation and its relevance for
Earth. Ann. Rev. Astron. Astrophys. 35, 33–67.
Lean, J., 2000. Evolution of the sun’s spectral irradiance since
the Maunder minimum. Geophys. Res. Lett. 27, 2425–
2428.
Lean, J.L., Rottman, G.J., Kyle, H.L., Woods, T.N., Hickey,
J.R., Puga, L.C., 1997. Detection and parameterization of
variations in solar mid- and near-ultraviolet (200–400 nm).
J. Geophys. Res. 102D, 29,939–29,956.
Livingston, W., 1992. Observations of solar spectral irradiance
variations at visible wavelengths. In: Donnelly, R.F. (Ed.),
Proc. Workshop on the Solar Electromagnetic Radiation
Study for Solar Cycle 22. NOAA-ERL, Boulder, CO, pp.
11–19.
Lockwood, G.W., T€ug, H., White, N.M., 1992. A new solar
irradiance calibration from 3295 �A to 8500 �A derived from
absolute spectrophotometry of Vega. Astrophys. J. 390,
668–678.
Mentall, J.E., Frederick, J.E., Herman, J.R., 1981. The solar
irradiance from 200 to 330 nm. J. Geophys. Res. 86C, 9881–
9884.
Mount, G.H., Rottman, G.J., 1981. The solar spectral irradi-
ance 1200–3184 �A near solar maximum: July 15, 1980. J.
Geophys. Res. 86A, 9193–9198.
Neckel, H., 1997. On the wavelength dependency (and its
variations) of the ratio disk-averaged to disk-center inten-
sity, F =I0 (0.385 to 10 lm). Solar Phys. 171, 257–268.
Neckel, H., 2003. On the sun’s absolute disk-center and mean
disk intensities, its limb darkening, and its �limb tempera-
ture’ (330 to 1099 nm). Solar Phys. 212, 239–250.
Neckel, H., Labs, D., 1981. Improved data of solar spectral
irradiance from 0.33 to 1.25 l. Solar Phys. 74, 231–249.Neckel, H., Labs, D., 1984. The solar radiation between 3300
and 12500 �A. Solar Phys. 90, 205–258.
Nicolet, M., 1989. Solar spectral irradiances with their diversity
between 120 and 900 nm. Planet. Space Sci. 37, 1249–1289.
Peck, E.R., Reeder, K., 1972. Dispersion of air. J. Opt. Soc.
Am. 62, 958–962.
Pierce, A.K., 1954. Relative solar energy distribution in the
spectral region 10,000–25,000 �A. Astrophys. J. 119, 312–
327.
Riordan, C., 1987. Extraterrestrial spectral solar irradiance
data for modeling spectral solar irradiance at the Earth’s
surface. Rept. SERI TR-215-2921, Solar Energy Research
Institute, Golden, CO.
Rottman, G., 1999. Solar ultraviolet irradiance and its temporal
variation. J. Atmos. Solar-Terr. Phys. 61, 37–44.
Rottman, G., Floyd, L., Viereck, R., 2004. Measurement of the
solar ultraviolet irradiance. In: Pap, J.M. et al. (Eds.), Solar
Variability and its Effects on Climate. Geophysical Mono-
graph 141, American Geophysical Union.
Rottman, G.J., 1988. Observations of solar UV and EUV
variability. Adv. Space Res. 8, 753–766.
Rottman, G.J., Woods, T.N., Sparn, T.P., 1993. Solar Stellar
Irradiance Comparison Experiment I: 1. Instrument Design
and Operation. J. Geophys. Res. 98, 10667–10677.
Simon, P.C., 1981. Solar irradiance between 120 and 400 nm
and its variations. Solar Phys. 74, 273–291.
Smith, E.V.P., Gottlieb, D.M., 1974. Solar flux and its
variations. Space Sci. Rev. 16, 771–802.
Solanki, S.K., Fligge, M., 1998. Solar irradiance since 1874
revisited. Geophys. Res. Lett. 25, 341–344.
Solanki, S.K., Fligge, M., 1999. A reconstruction of total solar
irradiance since 1700. Geophys. Res. Lett. 26, 2465–2468.
Thekaekara, M.P., 1965. The solar constant and spectral
distribution of solar radiant flux. Solar Energy 9, 7–20.
Thekaekara, M.P., 1973. Solar energy outside the earth’s
atmosphere. Solar Energy 14, 109–127.
Thekaekara, M.P., Drummond, A.J., 1971. Standard values for
the solar constant and its spectral components. Nature 229,
6–9.
Thekaekara, M.P., Drummond, A.J., Murcray, D.G., Gast,
P.R., Laue, E.G., Willson, R.C., 1971. Solar electromag-
netic radiation. NASA SP-8005, National Aeronautics and
Space Administration.
Thuillier, G., Hers�e, M., Simon, P.C., Labs, D., Mandel, H.,
Gillotay, D., 1997. Observation of the UV solar spectral
irradiance between 200 and 350 nm during the ATLAS 1
mission by the SOLSPEC spectrometer. Solar Phys. 171,
283–302.
Thuillier, G., Hers�e, M., Simon, P.C., Labs, D., Mandel, H.,
Gillotay, D., 1998a. Observation of the solar spectral
irradiance from 200 nm to 870 nm during the ATLAS 1
and ATLAS 2 missions by the SOLSPEC spectrometer.
Metrologia 35, 689–695.
Thuillier, G., Hers�e, M., Simon, P.C., Labs, D., Mandel, H.,
Gillotay, D., Foujols, T., 1998b. The visible solar spectral
irradiance from 350 to 850 nm as measured by the
SOLSPEC spectrometer during the ATLAS 1 mission.
Solar Phys. 177, 41–61.
Thuillier, G., Hers�e, M., Labs, D., Foujols, T., Peetermans, W.,
Gillotay, D., Simon, P.C., Mandel, H., 2003a. The solar
spectral irradiance from 200 to 2400 nm as measured by the
SOLSPEC spectrometer from the ATLAS and EURECA
missions. Solar Phys. 214, 1–22.
Thuillier, G., Woods, T.N., Floyd, L., Hilsenrath, E., Cebula,
R., Hers�e, M., Labs, D., 2004. Sun reference spectra from
C.A. Gueymard / Solar Energy 76 (2004) 423–453 453
solar cycle 22 measurements. In: Pap, J.M. et al. (Eds.),
Solar Variability and its Effects on Climate. Geophysical
Monograph 141, American Geophysical Union.
Tobiska, W.K., Woods, T., Eparvier, F., Viereck, R., Floyd, L.,
Bouwer, D., Rottman, G., White, O.R., 2000. The
SOLAR2000 empirical solar irradiance model and forecast
tool. J. Atmos. Solar-Terr. Phys. 62, 1233–1250.
Unruh, Y.C., Solanki, S.K., Fligge, M., 1999. The spectral
dependence of facular contrast and solar irradiance varia-
tions. Astron. Astrophys. 345, 635.
VanHoosier, M.E., 1996. Solar ultraviolet spectral irradiance
with increased wavelength and irradiance accuracy. SPIE
Proceedings vol. 2831, pp. 57–64.
VanHoosier, M.E., Bartoe, J.D.F., Brueckner, G.E., Prinz,
D.K., 1988. Absolute solar spectral irradiance 120 nm–400
nm. Results from the Solar Ultraviolet Spectral Irradiance
Monitor––SUSIM––experiment on board Spacelab 2. As-
tro. Lett. Comm. 27, 163–168.
Wehrli, C., 1985. Extraterrestrial solar spectrum. Pub. No. 615,
World Radiation Center, Davos, Switzerland.
Willson, R.C., 1994. Solar irradiance. In: Gurney, R.J. et al.
(Eds.), Atlas of Satellite Observations Related to Climate
Change. Cambridge Univ. Press, pp. 5–18.
Woods, T., Rottman, G., Harder, J., Lawrence, G., McClin-
tock, B., Kopp, K., Pankratz, C., 2000. Overview of the
SORCE mission. SPIE Proceedings vol. 4135, 192 pp.
Woods, T.N. et al., 1996. Validation of the UARS solar
ultraviolet irradiances: comparison with the ATLAS 1 and 2
measurements. J. Geophys. Res. 101D, 9541–9569.
Woods, T.N., Rottman, G.J., 2002. Solar ultraviolet variability
over time periods of aeronomic interest. In: Mendillo, M.
et al. (Eds.), Comparative Aeronomy in the Solar System.
American Geophysical Union Monograph.
Woods, T.N., Rottman, G.J., Ucker, G., 1993. Solar Stellar
Irradiance Comparison Experiment: instrument calibration.
J. Geophys. Res. 98, 10679–10694.