teflon can we do better? sachin amrute, kateryna christian, husain danish, karina demair, patrick...
TRANSCRIPT
TeflonCan we do better?
Sachin Amrute, Kateryna Christian, Husain Danish, Karina DeMair, Patrick Gorman, Christopher HollydayJoshua Israel, Allen Lin, Vrajesh Modi, Justin Petrillo, Steven Schwartz
T2 Advisors: Dr. Gloria Anderle and Dr. Michael AvaltroniAssistant: Jeremy Tang
1938: Dupont Research Labs1938: Dupont Research Labs
• Dr. Roy Plunkett accidentally discovers Teflon.
• A.K.A. PTFE - Polytetrafluoroethylene
Uses of Teflon
Benefits of TeflonBenefits of Teflon
• Non-stick, hydrophobic (water-repellant) surface
• Efficiently, commercially manufactured
• Chemically inert• Extremely versatile; can be used
in numerous applications
Problems with TeflonProblems with Teflon
• Only forms physical bonds
• Wears away over time
• Is a Carcinogen
Our Alternative: ODPAOur Alternative: ODPA
• Chemically bonded• Stays on indefinitely• Environmentally friendly (non-
carcinogenic)
•Self-assembled monolayer (SAM)
Octadecylphosphonic Octadecylphosphonic AcidAcid
Hydrophobic End
Bonding End• ODPA is an
excellent substitute for Teflon
• Has all of benefits and none of the drawbacks.
Our GoalOur Goal
•Develop a viable Teflon substitute (ODPA)
•Improve efficiency of application of ODPA to an oxide surface
Physical vs. Chemical Bonding
• Physical bond:– Electrostatic attraction to surface– Can be removed
• Chemical bond: – Actual covalent bond to surface– Cannot be removed
Bonding of ODPA to Oxide Surface
OH
Glass
OH
Glass
P
HO OH
O
P
HO OH
O
R R
n n
O OO O
Glass
PO
PO
R R
n n
120 °C
18 hours
PHO
HOO
Rn
OO
O
OHO
What is Contact Angle?What is Contact Angle?Highly
Hydrophilic:
Highly Hydrophobic:
Our goalOur goal
Measuring Contact Angle
Large contact angle we observedContact Angle Goniometer
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“The GoldGold Standard”
• T-BAG (Tethering by Aggregation and Growth)– Substrate immersed in ODPA
solution– Evaporate for 24 hrs
• Oven for dehydration– 48 hrs at 120 degrees C
• What’s the problem? It takes too long
Alternate Coating Methods
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Spray
PipetMayer Rod
Drain
Acid Pre-TreatmentAcid Pre-Treatment• Hypothesized that it might
corrode the surface• Increases number of ODPA
bonding sites
www.elmhurst.edu
Dehydration MethodsDehydration Methods
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Microwave Infrared Ultraviolet
Heat GunIron
Contact Angle vs. Dehydrating Methods: Drain (15 min)
0.0
20.0
40.0
60.0
80.0
100.0
120.0
IR – 10 min IR – 20 min UV – 20 min Heat gun – 10min
Heat gun – 20min
Iron – 5 min
Dehydrating Method
Co
nta
ct A
ng
leOur Results Say…
Average Contact Angle: Mayer Rod
0.0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
Oven IR (IR)2x Heatgun
Dehydration Method
Co
nta
ct A
ng
le
Untreated
Acid
Ethanol
Inconsistency of Coating Before and After Soaking
0.00
2.00
4.00
6.00
8.00
10.00
12.00
14.00
(IR – 10 min)2x (IR – 10 min)2x Ethanol, (IR – 10 min)2x
Dehydration Method
Sta
nd
ard
De
via
tio
n
Before
After
Discussion/Conclusions
• Application method– Drain, Drop, Mayer Rod
• Chemical bonding method – Iron• Pre-treatments inconsistent• Multiple repetitions good• Sample size and consistency
• Continue work with ODPA to coat glass, plastics, and metals (e.g. Ti replacements)
• Try fluoronating the phosphonic acid
• Used VMD (Visual Molecular Dynamics) to simulate SAMs
What’s in Store for the Future?
Our results offered potential promise as an industrially plausible replacement for
Teflon, with low toxicity and high hydrophobicity.
The Bottom Line…The Bottom Line…
Works Cited• www.fibraplex.com • profile.myspace.com • www.discountedwheelwarehouse.
com • www.runnertime.com • www.labconco.com • www.senorcafe.com • shop.pcgenerations.com • www.sofia.usra.edu • www.natequipment.com • www.burningmonk.com • www.thesavvytraveller.com • www.smecc.org • www.enlightenedgifts.org • www.laboratory-supply.com • profile.myspace.com• capecodtravel.com • www.zeolite.ca • www.nationalgeographic.com • www.elizabethan-era.org.uk • www.easyseo.com • www.csiministorage.com • profile.myspace.com • www.wallpaperbase.com
• www.nottinghillhousing.org.uk • www.env.gov.bc.ca • www.wirelessedge.co.uk
We’d like to thank…
NJGSS
Dr. David Miyamoto
Dr. Paul Quinn
Dr. Michael Avaltroni
Dr. Gloria Anderle
Mr. and Mrs. John Overdeck
Jeremy
TangAnd who can forget..