tecno-sil 619 silicone sealant - fsi limited 619/tecno... · tecno-sil 619® silicone sealant...

Product name Tecno-Sil 619 Silicone Sealant

Product Code FSM310TECN

Section 1: Identification of the substance/mixture and of the company / undertaking

1.1 Product identifier

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

Company Name FSi Limited,Westminster Industrial Estate,Tamworth Road,Measham,DE12 7DS.U.K.

Tel (0) 44 1530 515130

Fax (0) 44 1530 273564

Email [email protected]

1.4. Emergency telephone number

Identified uses: Used for making joints, sealing and gluing.Uses advised against: None known.

Emergency Number (0) 44 1530 515130

2.1. Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008

Section 2: Classification of the substance or mixture

Not classified

The product has not been classified as hazardous according to the legislation in force.

TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET MATERIAL SAFETY DATA

Product name Tecno-Sil 619® Silicone Sealant

Product Code FSM310TECN

Revision Date 08/08/2018

Revision number 02

UIC

SAFETY DATA SHEET

FSi Limited,Westminster Industrial Estate,

Tamworth Road, Measham,DE12 7DS, UK.

Tel: +44 (0) 1530 515130 Fax: +44 (0) 1530 273564 Email: [email protected] Website: www.fsiltd.com

2.2. Label elements

Supplemental label information EUH210: Safety data sheet available on request.

Hazard summary

Physical Hazards: No specific recommendations.

Health Hazards Inhalation: No specific symptoms noted.

Eye contact: No specific symptoms noted.

Skin Contact: No specific symptoms noted.

Ingestion: No specific symptoms noted.

Other Health Effects: No other information noted.

Environmental Hazards: Not regarded as dangerous for the environment.

2.3. Other hazards

Chemical Name Concentration CAS-No. EC No. REACH Registration No. Notes

Methanol <3% 67-56-1 01-2119433307-44-XXXX #

Substance(s) formed under the conditions of use:

3.2. Chemical characterisation: Mixtures

Section 3 Composition/information on ingredients

General information: Mixture of polydimethylsiloxanes, silica and curing agents.

Chemical name Concentration CAS-No. EC No. Reach Registration No.

M-Factor: Notes

Trimethoxyvinylsilane 1 - <5% 2768-02-7 220-449-8 01-2119513215-52-XXXX

No data available.

Methanol 0,1 - <1% 67-56-1 200-659-6 01-2119433307-44-XXXX

No data available.

#

* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.# This substance has workplace exposure limit(s).

Classification

Chemical name Classification Notes

Trimethoxyvinylsilane Flam. Liq. 3 H226; Acute Tox. 4 H332; No data available.

Methanol Flam. Liq. 2 H225; Acute Tox. 3 H331; Acute Tox. 3 H311; Acute Tox. 3 H301; STOT SE 1 H370;

No data available.

CLP: Regulation No. 1272/2008.The full text for all H-statements is displayed in section 16.

No data available

TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET




5.1. Extinguishing media suitable extinguishing agents

Section 4: First aid measures

4.1. Description of first aid measures

General information Get medical attention if symptoms occur. Contaminated clothing to be placed in closed container until disposal or decontamination.

After inhalation Move into fresh air and keep at rest.

After skin contact Remove contaminated clothing and shoes. Wash with soap and water.

After eye contact In the event of contact with the eyes, rinse thoroughly with clean water. Continue to rinse for at least 15 minutes.

After swallowing Do not induce vomiting. Rinse mouth thoroughly.

4.2. Most important symptoms and effects, both acute and delayed

4.3. Indication of any immediate medical attention and special treatment needed

Section 5: Fire-Fighting measures

5.2. Special hazards arising from the substance or mixture

None known.

Hazards: No specific recommendations.Treatment: No specific recommendations.

Extinguish with foam, carbon dioxide or dry powder.

Unsuitable extinguishing media: Do not use water as an extinguisher.

For further information, refer to section 10: “Stability and Reactivity”.

5.3. Advice for fire-fighters

Advice for firefightersSpecial fire fighting

procedures:

Water spray should be used to cool containers.

Special protective equipment for

fire-fighters:

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

General Fire Hazards: No specific recommendations.

TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET




Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.3. Methods and materials for containment and cleaning up

6.4. Reference to other sections

6.1.1 For non-emergency personnel:

Use personal protective equipment. Do not breathe vapor. See Section 8 of the SDS for Personal Pro-tective Equipment. Ventilate the area.

6.1.2 For emergency responders:

No data available.

Collect spillage. Do not discharge into drains, water courses or onto the ground.

Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Container must be kept tightly closed. Absorb with sand or other inert absorbent. To clean the floor and all objects contaminated by this material, use an appropriate solvent.(cf. : § 9) Flush area with plenty of water. Incinerate in suitable combustion chamber.

Caution: Contaminated surfaces may be slippery. For waste disposal, see Section 13 of the SDS.

TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET




Section 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

7.3. Specific end use(s)

Specific end use(s) No data available.

Section 8: Exposure controls/personal protection

Adequate ventilation should be provided so that exposure limits are not exceeded.

Avoid discharge into drains, water courses or onto the ground. Store in tightly closed original container. Store in a cool, dry place with adequate ventilation. Keep away from incompatible materials, open flames, and high temperatures. Avoid contact with oxidizing agents. Vulcanizes at room temperature on contact with moisture in the air. For further information, refer to section 10: "Stability and Reactivity". Suitable containers: Steel drums coated with epoxy-resin.

8.1. Control parameters

Occupational Exposure Limits

Chemical name Type Exposure Limit Values Source

Methanol TWA 200 ppm 266 mg/m3 UK. EH40 Workplace Exposure Limits (WELs) (2007)

STEL 250 ppm 333 mg/m3 UK. EH40 Workplace Exposure Limits (WELs) (2007)

TWA 200 ppm 260 mg/m3 EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU, 2017/164/EU (12 2009)

Additional exposure limits under the conditions of use

Chemical name Type Exposure Limit Values Source

Methanol TWA 200 ppm 266 mg/m3 UK. EH40 Workplace Exposure Limits (WELs) (2007)

STEL 250 ppm 333 mg/m3 UK. EH40 Workplace Exposure Limits (WELs) (2007)

TWA 200 ppm 260 mg/m3 EU. Indicative Exposure Limit Values in Directives 91/322/EEC, 2000/39/EC, 2006/15/EC, 2009/161/EU, 2017/164/EU (12 2009)

TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET




8.2. Exposure controls

Exposure controlsAppropriate Engineering

Controls:

Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of vapors. Use engineering controls to reduce air contamination to permissible exposure level.

Individual protection measures, such as personal protective equipment

General information: Provide sufficient ventilation during operations which cause vapor formation.

Eye/face protection: Safety Glasses.

Skin protectionHand Protection:

Material: Rubber gloves are recommended.

Other: It is a good industrial hygiene practice to minimize skin contact. Wear appropriate clothing to prevent any possibility of skin contact.

Respiratory Protection: If ventilation is insufficient, suitable respiratory protection must be provided.

Hygiene measures: Provide eyewash station and safety shower.

Environmental Controls: No data available.

Additional information: The lists that were valid during the creation were used as basis.

TECNO-SIL 619®

SAFETY DATA SHEET

SILICONE SEALANT




Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance

Physical state: Paste

Form: No data available.

Colour: Tan

Odor: Alcohol

Odor Threshold No data available.

pH: Not applicable

Melting Point: No data available.

Boiling Point: No data available.

Flash Point: 100,5 °C (Closed cup according to method ISO 3679)

Evaporation Rate: No data available.

Flammability (solid, gas: No data available.

Flammability Limit - Upper (%) No data available.

Flammability Limit - Lower (%) No data available.

Vapor Pressure: No data available.

Vapor Density (air=1) No data available.

Density: Approximate 1,49 kg/dm3 (20 °C)

Solubility(ies)

Solubility in water: Insoluble in water

Solubility (Other): Acetone: SolubleAliphatic hydrocarbons: SolubleAromatic hydrocarbons: SolubleChlorinated solvents: Soluble

Partition coefficient (n-octanol/water):

No data available.

Autoignition Temperature: No data available.

Decomposition Temperature: No data available.

Viscosity: No data available.

Explosive Properties: No data available.

Oxidizing Properties: According to the data on the components Not considered as oxidizing. (evaluation by structure-activity relationship)

9.2. Other information

Other information No data available.

TECNO-SIL 619®

SAFETY DATA SHEET

SILICONE SEALANT




Section 11: Toxicological information

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity Vulcanizes at room temperature on contact with moisture in the air.

10.2. Chemical stability

Chemical Stability: Stable at room temperature provided it is not in contact with air.

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

Conditions to avoid No other information noted.

No data available.

10.5. Incompatible materials

Incompatible materials Strong oxidizing agents. Water.

10.6. Hazardous decomposition products

Haz. decomp. products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. Amorphous silica.

Inhalation: No data available.Ingestion: No data available.Skin Contact: No data available.Eye contact: No data available.

TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET




11.1. Information on toxicological effects

Acute toxicity:

Oral:Product:

ATEmix (): 8 224,55 mg/kg

Dermal:Product:

ATEmix 24 666,21 mg/kg

Inhalation:Product:

ATEmix (4 h): 9,77 mg/l Vapor

Repeated dose toxicity:Product:

No data available.

Specified substance(s):Trimethoxyvinylsilane

NOAEL (Rat(Female, Male), Oral): < 62,5 mg/kg Method: OECD 422 LOAEL (Rat(Female, Male), Oral): 62,5 mg/kgNOAEL (Rat(Female, Male), Inhalation - vapor): 0,0605 mg/l

Methanol LOAEL (Rat(Female, Male), Inhalation - vapor): 1,3 mg/l

Skin Corrosion/Irritation:

Product: Composition/information on ingredients


Occluded (Dermal) (Rabbit, 24 h) : Not irritating

Methanol Rabbit : Not irritating

Serious Eye Damage/Eye Irritation:

Product: No data available.


OECD 405 (Rabbit, 24 h) : Not irritating

Methanol Rabbit : Not irritating

Respiratory or Skin Sensitization:



OECD 406 (Guinea Pig) : Not a skin sensitizer.

Methanol According to a standardised method. (Guinea Pig) : Not a skin sensitizer.

Germ Cell Mutagenicity:

In vitro:Product:

Composition/information on ingredients


Bacteria (OECD 471): No mutagenic effects.Chromosomal aberration (OECD 473): Clastogenic effect.In vitro gene mutations test on mammalian cells: (OECD 476): No mutagenic effects.

Methanol Bacteria (OECD 471): No mutagenic effects.In vitro gene mutations test on mammalian cells: (OECD 476): No mutagenic effects.

In vivo:Product:

No data available.


(OECD 474)No mutagenic effects.

Methanol (Expert judgement.)No mutagenic effects.

TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET




11.1. Information on toxicological effects

Carcinogenicity:


Reproductive toxicity:


Reproductive toxicity (Fertility):



Rat Female (Ingestion): NOAEL (parent): 250 mg/kg NOAEL (F1):None. NOAEL (F2): None. Method: OECD 422

Developmental toxicity (Teratogenicity):



Rat (Inhalation - vapor): NOAEL (terato): 0,6 mg/l NOAEL (mater): 0,15 mg/l Method: According to a standardised method.

Specific Target Organ Toxicity - Single Exposure:



Not classified

Methanol Central nervous system. - Causes damage to organs.

Specific Target Organ Toxicity - Repeated Exposure:



Not classified

Aspiration Hazard:


TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET




Section 12: Ecological information

12.1. Toxicity

Aquatic toxicity

Fish:Product:



LC 50 (Oncorhynchus mykiss, 96 h): 191 mg/l

Methanol LC 50 (Bluegill Sunfish, 96 h): 15 400 mg/l

Aquatic Invertebrates:Product:



EC 50 (Water flea (Daphnia magna), 48 h): 168,7 mg/l

Methanol EC 50 (Water flea (Daphnia magna), 48 h): 18 260 mg/l

Chronic Toxicity:

Fish:Product:


Specified substance(s):Methanol

NOEC (Fish, 28 d): 446,7 mg/l

Aquatic Invertebrates:Product:



NOEC (Aquatic invertebrates, 21 d): 208 mg/l

Toxicity to Aquatic Plants:Product:



EC 50 (Algae (Pseudokirchneriella subcapitata), 7 d): 210 mg/lEC10 (Algae (Pseudokirchneriella subcapitata), 7 d): 25 mg/l

Methanol EC 50 (Algae (Pseudokirchneriella subcapitata), 96 h): 22 000 mg/l

12.2. Persistence and degradability

Biodegradation:Product:



51 % (28 d, OECD 301 F) The product is not readily biodegradable.

Methanol 95 % (20 d) Readily biodegradable

BOD/COD Ratio:Product:

No data available.

TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET




Section 14: Transport information

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB assessment:

No data available.

12.6. Other adverse effects

Other adverse effects No data available.

Mobility in soil: No data available.

Section 13: Disposal considerations

13.1. Waste treatment methods

General information: The user’s attention is drawn to the possible existence of local regulations regarding disposal.

Disposal methods

Disposal instructions: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Incinerate.

Contaminated Packaging: Contaminated packages should be as empty as possible. Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Recycle following cleaning or dispose of at an authorised site.

12.3. Bioaccumulative potential



(Expert judgement.) The product is not considered to have a bioaccumulative potential.

Transport in bulk according to Annex II of

Marpol and the IBC Code

Not applicable.

14.7 Transport in bulk according to Annex II of Marpol and the IBC Code

This material is not subject to transport regulations.

Other information: No special precautions.

TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET




Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.2. Chemical Safety Assessment

Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended:

None

Chemical safety assessment:

No Chemical Safety Assessment has been carried out.

Inventory Status:

Australia AICS: On or in compliance with the inventory.

Canada DSL Inventory List: Not in compliance with the inventory.

EINECS, ELINCS or NLP: On or in compliance with the inventory.

Japan (ENCS) List: On or in compliance with the inventory.

China Inv. Existing Chemical Substances:

On or in compliance with the inventory.

Korea Existing Chemicals Inv. (KECI):


Canada NDSL Inventory: Not in compliance with the inventory.

Philippines PICCS: On or in compliance with the inventory.

US TSCA Inventory: On or in compliance with the inventory.

New Zealand Inventory of Chemicals:


National Regulations

TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET




Section 16: Other information

Other information

Revision Information: Not relevant.

References

PBT PBT: persistent, bioaccumulative and toxic substance.vPvB vPvB: very persistent and very bioaccumulative substance.

Key abbreviations or acronyms used: No data available.Key literature references and sources for data: No data available.

Wording of the H-statements in section 2 and 3

H225 Highly flammable liquid and vapor.H226 Flammable liquid and vapor.H301 Toxic if swallowed.H311 Toxic in contact with skin.H331 Toxic if inhaled.H332 Harmful if inhaled.H370 Causes damage to organs.

Training information: No data available.

Issue Date: 21.06.2018

SDS No.:

Disclaimer:

The information given is based on data available for the material, the components of the material, and similar materials. The information is believed to be correct. It is given in good faith. This information should be used to make an independent determination of the methods to safeguard workers and the environment.

TECNO-SIL 619®

SILICONE SEALANT

SAFETY DATA SHEET




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