teaching geochemistry workshop rock samples and geochemical analysis maria de lourdes rosa &...
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![Page 1: Teaching Geochemistry Workshop Rock Samples and Geochemical Analysis Maria de Lourdes Rosa & Débora Correia Rios Federal University of Bahia Federal University](https://reader036.vdocuments.mx/reader036/viewer/2022062522/5706384c1a28abb8238f679e/html5/thumbnails/1.jpg)
Teaching Geochemistry WorkshopTeaching Geochemistry Workshop
Rock Samples and Rock Samples and Geochemical Geochemical
AnalysisAnalysisMaria de Lourdes Rosa & Débora Correia RiosMaria de Lourdes Rosa & Débora Correia Rios Federal University of BahiaFederal University of Bahia Earth Sciences InstituteEarth Sciences Institute BrazilBrazil
Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Geochemistry at the Geochemistry at the Federal University of Bahia - Federal University of Bahia -
BrazilBrazil
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Geochemistry at the Geochemistry at the Federal University of Bahia (UFBA) - Federal University of Bahia (UFBA) -
BrazilBrazil Brief DescriptionBrief Description
• 2 Disciplines of Geochemistry2 Disciplines of GeochemistryChemistry for Geologists (first year)Chemistry for Geologists (first year)Geochemistry (fourth year)Geochemistry (fourth year)
For who?For who?• Undergraduate students of GeologyUndergraduate students of Geology
Background:Background:• Introductory GeologyIntroductory Geology
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Chemistry for Geologists Chemistry for Geologists CourseCourse
Syllabus - Lectures (60%)Syllabus - Lectures (60%) Lab Activities (40%)Lab Activities (40%) 48 students/semester48 students/semester 2 Teachers2 Teachers 75 hours/semester75 hours/semester
• 30 h Lectures30 h Lectures• 45 h Laboratory Activities45 h Laboratory Activities
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Laboratory ActivitiesLaboratory Activities 15 Laboratory Activities: 1 per week15 Laboratory Activities: 1 per week The laboratory practices are for students to The laboratory practices are for students to
recognize what is involved in modern recognize what is involved in modern geochemistry analyses of these geological geochemistry analyses of these geological materials:materials:
Rocks and mineralsRocks and minerals WaterWater Soil and sedimentsSoil and sediments
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Goals for Lab ActivitiesGoals for Lab Activities Types of materials subject to geochemical analysis.Types of materials subject to geochemical analysis. Procedures and care in sampling.Procedures and care in sampling. Tools for sample preparation.Tools for sample preparation. Avoiding contamination and common errors.Avoiding contamination and common errors. Analytical Instruments at UFBA:Analytical Instruments at UFBA:
• ICP-AESICP-AES• AASAAS• XRFXRF• MicroprobeMicroprobe
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-01AC-01
Lab Activity 01: What do geochemical analysis mean?Lab Activity 01: What do geochemical analysis mean?• Research about geochemical analysisResearch about geochemical analysis..
WebsitesWebsites Earth Sciences Institute LibraryEarth Sciences Institute Library
• At this point, we will discuss different kind geologic samples At this point, we will discuss different kind geologic samples and ways of reporting geochemistry data.and ways of reporting geochemistry data. TablesTables Qualitative versus quantitative analysesQualitative versus quantitative analyses Major, minor and trace constituentsMajor, minor and trace constituents Chemical formChemical form
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-01AC-01
Lab Activity 01: What do geochemical analysis Lab Activity 01: What do geochemical analysis mean?mean?• Students will discuss the analyses as Students will discuss the analyses as
measurements which provide quantitative measurements which provide quantitative information about the chemical composition of a information about the chemical composition of a sample and the importance of the results.sample and the importance of the results.
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-02AC-02
Lab Activity 02: SamplingLab Activity 02: Sampling• Sample CollectionSample Collection
Sample scheme: What to collect?Sample scheme: What to collect? Geochemical investigation: How to proceed?Geochemical investigation: How to proceed? How many and how much: number and size of How many and how much: number and size of
samples that I needsamples that I need Which tools should be used?Which tools should be used? Identification: Sample protocolsIdentification: Sample protocols
• Field ActivityField Activity NeighborhoodNeighborhood Granite outcropsGranite outcrops
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-02AC-02
Lab Activity 02: SamplingLab Activity 02: Sampling• Students must understand the importance of Students must understand the importance of
sampling and of a well planned field study and sampling and of a well planned field study and the importance of these steps in the the importance of these steps in the geochemical analysis.geochemical analysis.
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-03AC-03
Lab Activity 03: Classic Sample PreparationLab Activity 03: Classic Sample Preparation• Granulometric ReductionGranulometric Reduction• Polished slicePolished slice• Rock powder Rock powder • Mineral ConcentrationMineral Concentration• Effects of these choices on the resultsEffects of these choices on the results
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Sample Preparation LaboratorySample Preparation Laboratory• 1 Hydraulic rock breaker1 Hydraulic rock breaker• 3 Stell crushers3 Stell crushers• And also other tools…And also other tools…
HammersHammers SievesSieves PaperPaper Storage containers…Storage containers…
Rock Sample Rock Sample Preparation: AC-03Preparation: AC-03
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-03AC-03
Reciprocating rock crusher Sample Preparation LaboratorySample Preparation Laboratory
• During these steps, During these steps, students will:students will: Perform a typical procedure Perform a typical procedure
for preparing solid rock for preparing solid rock samples for analyses.samples for analyses.
Discuss the media used to Discuss the media used to fabricate the equipments and fabricate the equipments and risks of sample risks of sample contamination.contamination.
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-03AC-03
Sample Preparation LaboratorySample Preparation Laboratory• During these steps, students will see:During these steps, students will see:
Representative fractions of sample to analyzeRepresentative fractions of sample to analyze Sample storageSample storage Possible sources of systematic errorsPossible sources of systematic errors
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Shatter Box
Mineral Concentration LaboratoryMineral Concentration Laboratory• 2 Swing mills2 Swing mills
Tungsten carbide potTungsten carbide pot Agate potAgate pot
• 1 Ball mill1 Ball mill Hardened steel ballsHardened steel balls
• 1 Mineral Separator Table1 Mineral Separator Table• 2 Frantz 2 Frantz
Isodynamic magnetic separatorIsodynamic magnetic separator• Heavy LiquidsHeavy Liquids
BromophormBromophorm
Rock Sample Preparation: Rock Sample Preparation: AC-03AC-03
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-03AC-03
Mineral Concentration LaboratoryMineral Concentration Laboratory• Other skills and goals for this activity are to concentrate mineral Other skills and goals for this activity are to concentrate mineral
grains. Students will be taught that some geochemical procedures grains. Students will be taught that some geochemical procedures require a pure mineral sample and that a single mineral can be require a pure mineral sample and that a single mineral can be physically separated from the rock.physically separated from the rock.
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-03AC-03
Lab Activity 03: Classic Sample PreparationLab Activity 03: Classic Sample Preparation• At the end of this step, students will At the end of this step, students will
be able to prepare their samples:be able to prepare their samples: Thin sectionsThin sections PowderPowder Mineral concentrationMineral concentration
• Now, they have samples ready for Now, they have samples ready for XRF (powder - solid disc) and XRF (powder - solid disc) and Electron Microprobe analysis (thin Electron Microprobe analysis (thin section).section).
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-04AC-04
Lab Activity 04: Sample decomposition-solutionLab Activity 04: Sample decomposition-solution
• The Lab environmentThe Lab environment Safety in the geochemistry Safety in the geochemistry
lab lab Equipments Equipments Glasses Glasses Reagent purity and blanks Reagent purity and blanks
• Here, following the physical preparation Here, following the physical preparation procedures, students will perform one or more procedures, students will perform one or more stages of chemical processing. stages of chemical processing.
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-04AC-04
Lab Activity 04: Sample decomposition-solutionLab Activity 04: Sample decomposition-solutionAcid digestion (open and closed systems)Acid digestion (open and closed systems)Alkaline fusionsAlkaline fusions
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Rock Sample Preparation: Rock Sample Preparation: AC-04AC-04
Lab Activity 04: Sample Decomposition-Lab Activity 04: Sample Decomposition-SolutionSolution• By the end of this activity, rock samples were By the end of this activity, rock samples were
converted into solution by a variety of procedures.converted into solution by a variety of procedures.• Therefore, we will emphasize the procedures Therefore, we will emphasize the procedures
producing solutions suitable for analysis by ICP-AES producing solutions suitable for analysis by ICP-AES and AAS.and AAS.
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Geochemical Analyses: Geochemical Analyses: AC-05AC-05
Lab Activity 05: Running SamplesLab Activity 05: Running Samples• ICP-AES – AAS – XFR – MicroprobeICP-AES – AAS – XFR – Microprobe
ICP-AES AAS
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Geochemical Analyses: Geochemical Analyses: AC-05AC-05
Lab Activity 05: Running SamplesLab Activity 05: Running Samples• From the analytical viewpoint, students will perform From the analytical viewpoint, students will perform
the analyses using the instrumental methods the analyses using the instrumental methods available at the Federal University of Bahia.available at the Federal University of Bahia.
• Additionally they will be able to evaluate the Additionally they will be able to evaluate the differences in methods and results by comparisondifferences in methods and results by comparisonTime to get an analysisTime to get an analysisPrecision and accuracyPrecision and accuracyCostsCosts
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Student EvaluationStudent Evaluation Students work in groups of four (3 groups Students work in groups of four (3 groups
per class)per class)• For each activity a preliminary reportFor each activity a preliminary report• A seminar bA seminar by the end of the term including:y the end of the term including:
A final write-up: first time they are expected to A final write-up: first time they are expected to write up their own datawrite up their own data
An oral presentationAn oral presentation Seminars allow comparison between the groups. Seminars allow comparison between the groups.
Each one uses a distinct analytical method.Each one uses a distinct analytical method.
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
DifficultiesDifficulties Restricted fundsRestricted funds Time for assessment this discipline is Time for assessment this discipline is
insufficient insufficient Absence of Technical SupportAbsence of Technical Support
• Labs off-routineLabs off-routine Students missing classesStudents missing classes References:References:
• ScarcityScarcity• Native language: EnglishNative language: English
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
SolutionsSolutions
Limit field activities to nearby the UniversityLimit field activities to nearby the University Buy some books ourselvesBuy some books ourselves Limiting the course reference to the ones Limiting the course reference to the ones
availableavailable Resuming and translating some texts and making Resuming and translating some texts and making
them available to studentsthem available to students Emphasizing operating methodsEmphasizing operating methods Looking for working labs in other institutesLooking for working labs in other institutes
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
Nice News…Nice News…
The GeoChronos Net: The GeoChronos Net: • A Brazilian national Earth Sciences Project creating the A Brazilian national Earth Sciences Project creating the
Geochronological, Geodynamic and Environmental Net. Geochronological, Geodynamic and Environmental Net.
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
The GeoChronos NetThe GeoChronos Net
SHRIMP
LA-ICP-MS
• University of São Paulo
• Federal University of Pará• University of Brasilia• Federal University of RS
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Laboratório de Petrologia Aplicada à Pesquisa Mineral – CPGG – IGEO – UFBA
AcknAcknwledgmentswledgments
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