tctc qhqh qcqc w thth. (a) - piston at room temp and atmospheric pressure p v a heat engine example

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T c Q h Q c W T h

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Tc

Qh

Qc

W

Th

(a) - piston atroom temp and

atmosphericpressure P

Va

Heat Engine Example

(a-b) - gasheated to keep

volumeconstant as

cart rolls ontopiston

P

Va

b

Heat Engine Example

(b-c) - gasheated toincrease

volume and liftthe cart

P

Va

b c

Heat Engine Example

(c-d) - gascooled to keep

volumeconstant atcart rolls off

pistonP

Va

b c

d

Heat Engine Example

(d-a) - gascooled to

reduce volumeback to initial

level

P

Va

b c

d

Heat Engine Example

Work done?

W, QH, QC, Efficiency, Power

1st Law

Energy is conserved

QWE int

2nd Law

Impossible to convert heat completely to work

i.e. no perfect heat engines

DO DREAMS MATTER?Scott Adams: "Losers have goals, winners have systems." "Success caused passion more than passion caused success."

vs.

Nathan Pacheco: Give dreams you attention - they aren't going to burn brighter in the future.

Carnot’s big ideaA reversible engine works as well backwards as forwards . . .

So no engine operating between two thermal reservoirs can have more efficiency than a reversible engine between the same reservoirs, and all reversible engines will have the same efficiency.

Carnot cycle1. Isothermal expansion2. Adiabatic expansion3. Isothermal compression4. Adiabatic compression

Carnot Efficiency

Carnot engine Most efficient engine possible:

h

c

h

c

T

T

Q

Q

1e

1Q

We

inHeat

Workefficiency

h

Perpetual motion

machines These machines violate either

– Conservation of Energy– 2nd Law of Thermodynamics

What is wrong with this picture?

My first million $

Generator

Battery

Recycling heat from exhaust

Otto Cycle

COP Refrigerators and Heat Pumps

Why gasoline?

“Gasoline stinks. It pollutes the atmosphere with carbon dioxide, and it is blamed for global warming and for nitrous oxides that cause smog. It finances totalitarian dictatorships and terrorists and drives us to war.”

– Richard Muller, Physics for Future Presidents

What about Batteries?

For the same weight : Gasoline has 100 times the usable

energy of the best rechargeable batteries