Florida Community College at Jacksonville Syllabus:

CHM 2046C: General Chemistry II 4 cr. Section: 284690 Fall Term 2008

SITE: D-211/D204 

DAY/TIME: Lecture: Tuesday and Thursday 1:00-4:00 p.m. D-211 Lab: Thursday 2:00-4:00 p.m. D-204 Pretesting: Tuesday and Thursday 12:30-1:00 p.m.; 4:00-4:30 p.m.

FCCJ Course Description: This course, a continuation of General Chemistry and Qualitative Analysis I, stresses chemical equilibrium, chemical kinetics, electrochemistry, oxidation-reduction and selected families of metals and non-metals. Laboratory work includes studies of ionic equilibrium in aqueous solutions and semi-micro qualitative analysis. Six contact hours: three lecture hours, three laboratory hours. A.A., A.S., A.A.S.

Prerequisites: grade of C or better in CHM 2045C. (3 class hours, 3 lab hours, 4 credit hours)

Required Textbooks:Lecture Text, Laboratory Text, Supplies, and Materials:

John C. Kotz, Paul M. Treichel and Gabriela C. WeaverChemistry and Chemical Reactivity (with General ChemistryNOW CD-ROM) 6th Edition  © 2006* *(some may have 7th Edition sold in Bookstore)1322 Pages  Case Bound 8 1/2 x 10Thompson Learning: Brooks Cole PublishersISBN: 053499766XBook is an Old Edition only the 7th Edition is in Bookstore (Grading outline will be developed week by week for the 7th edition.)

CHM 2046C covers Chapter 11, 13-20, 23 in Eight Modules

Table of Contents

CHM 2046C General Chemistry and Qualitative Analysis II 11. Carbon--More Than Just Another Element. Interchapter: THE CHEMISTRY OF LIFE: BIOCHEMISTRY 13. Intermolecular Forces, Liquids, and Solids. Interchapter: THE CHEMISTRY OF MODERN MATERIALS 14. Solutions and Their Behavior. 15. Principles of Reactivity:Chemical Kinetics. 16. Principles of Reactivity:Chemical Equilibria. 17. Principles of Reactivity:The Chemistry of Acids and Bases. 18. Principles of Reactivity:Other Aspects of Aqueous Equilibria. 19. Principles of Reactivity: Entropy and Free Energy. 20. Principles of Reactivity:Electron Transfer Reactions. Interchapter: THE CHEMISTRY OF THE ENVIRONMENT 21. The Chemistry of the Main Group Elements. (not covered) 22. The Chemistry of the Transition Elements (not covered) 23. Nuclear Chemistry. (optional-if time permits)

Laboratory Text: Weekly Printouts from Student CD and/or also Posted on Web Site

Required: Scientific Calculator (non-alphanumeric)

Optional Texts/Online Activity:If you purchased the book new, then you have access to ChemistryNOW web site. If you purchased it used, then if the access code was not registered by the previous owner, then you should register your access. To purchase from Brooks-Cole:

General ChemistryNOW™ 2-Semester Instant Access Code for Kotz/Treichel/Weaver's Chemistry and Chemical Reactivity, 6th Edition

ISBN-10: 0-534-40022-1© 2006 (price $46.47-New price) not available in bookstore

Student Solutions Manual (New: $46.49) not available in Book store ISBN-10:  0534998526 The Student Solutions Manual, written by Alton Banks, North Carolina State University contains detailed solutions to selected end-of-chapter Study Questions found in the text. Solutions match the problem-solving strategies used in the text. Sample chapters are available for review at the text's website at http://chemistry.brookscole.com.

Study Guide $42.99 (Bookstore $59.75)ISBN-10:  0534998518 |  ISBN-13:  9780534998516 The perfect way to prepare for exams, this Study Guide for CHEMISTRY AND CHEMICAL REACTIVITY makes studying efficient and easy. It includes an overview, key terms and definitions for each chapter as well as study tips and worked out examples. Sample tests give you the practice you need to succeed on exams.

Required only if ACS 2nd Semester General Chemistry Exam is used:Preparing for Your ACS Examinations

InGeneral ChemistryThe Official Guide;

Eubanks, Lucy T, & Eubanks, Dwaine I,

American Chemical SocietyDivision of Chemical Education;

1998ACS General Chemistry Exams - Official Study Guide ($12.00)

Topics Covered Atomic Structure (CHM 2045C) Molecular Structure and Bonding (CHM 2045C) Stoichiometry (CHM 2045C) States of Matter / Solutions (CHM 2045C) Energetics (CHM 2045C) Dynamics (CHM 2046C) Equilibrium (CHEM 1212) Electrochemistry / Redox (CHM 2046C) (CHM 2045C) Descriptive Chemistry / Periodicity (CHM 2046C) (CHM 2045C) Laboratory Chemistry  (CHM 2045C) (CHM 2046C)

Features

Description of important ideas included in each topic Questions that emphasize the concepts most frequently studied Analysis of how to think through each study question Worked-out solution for each study question Insight into how wrong responses are constructed Practice questions for you to try on your own

Answers for all questions

Goggles or Visorgogs

 Instructor: John T. Taylor About Me ResumeOffice: D-270Office Phone: 904-766-6763Internet: (904) 410-1924 Cell Phone: 904-614-0531 or leave messages at instructor’s home at designated times or extreme emergencies on weekends. (Jacksonville 904-992-2052 most weekends)

Link to site: http://www.fccj.us/OfficeF08.htm for current office hours The instructor is available for additional office hours by appointment. Appointments must be made at least two days in advance, except for extreme emergencies. Office hours are subject to change

email: johtaylo@fccj.edu  

E-Mail assignments to both addresses belowSubjects of emails must describe briefly the assignments being submitted and begin with the # 46: i.e. 46: First Email or 46: your subject

Email Requirement:Each student should send the instructor an email during the first week from both your FCCJ email account and/or an outside email account for your primary contact, and the other as a backup contact. Be certain you put in subject box:

46: first email Tell me about yourself. Why are you taking this course? When did you complete CHM 2045C, where, with which instructor, and your grade. What is your highest math course completed? Where do you live? What are your telephone numbers? What is your external email address which can serve as a backup to FCCJ assigned email. Always begin the subject of each email with 46: Subject-less emails will be deleted or subjects without the number code may be deleted. Attachments will only be opened if the number code is in the subject line. This prevents viruses and spam.

ATTENDANCE:

Students are expected to attend class and will be responsible for all material presented. The student must sign the attendance roster to earn credit for attendance. Each on campus class attended will be worth one point. The student will fill out a data card similar to your instructor one the last page of this syllabus worth one point of the two points for the first day’s attendance. One student will serve as attendance monitor and record the day’s attendance for end of term point assignment. Student will sign lab role twice, once in the beginning of lab and then when they leave noting time out.

Online First Week Activities: The descriptions may be found at:http://www.hccfl.edu/faculty/john_taylor/cgs1555/spring04/syllabus/activity.htm

Free Time Chart: Find me 10 hours per week of the 168 weekly total: List themDescription: http://www.hccfl.edu/faculty/john_taylor/cgs1555/spring04/syllabus/freetime.htmActivity: http://college.hmco.com/masterstudent/series/becoming_a_master_student/11e/students/by_chapter/02.html

Free Time First Lab Exercise: Chemistry takes a lot of time to study. Each student should identify at least 10 hours or more per week of free time that she/he will commit towards his/her study of chemistry. The following are suggested strategies for scheduling your study times. Make an hour by hour seven day matrix 8 columns (hour and each day of the week) by 24 lines (representing each hour). See Master Student Web Site above. A blank matrix has been attached to this syllabus for you to complete.

 Starting with wake-up and end with sleeping:1. Schedule fixed blocks of time first. These include work, class time, eating, and sleeping.2. Include time for travel and errands3. Schedule time for fun.4. Set realistic goals.5. Allow flexibility in your schedule.6. Study at least two hours for every hour in class plus an extra two for computer assignments in the open lab and an extra two with a cooperative group member for homework comparison and checking.7. Avoid scheduling marathon study sessions. 8. Set clear starting and stopping times.9. Plan for the Unplanned! 

Study Groups/Phone Network/Lab Partner: On the first day of class each student will complete a Data Card, Interview a peer, and introduce (if time permits) that peer to the class. From these exercises and the learning styles inventory, study groups, a phone network, and lab partners need to be established. Study areas, as well as the classroom, should be used for study groups plus lunch and learn sessions. Some portions of the office times may meet in the library computer learning lab. Each week volunteers will be appreciated to assist in the group operation of the class. The first personal assistant volunteer will prepare a matrix with each student’s free study time so that study groups may begin to be formed the second week of school. The phone network will be established so that in case of emergencies by the instructor each student will be responsible to call two other students in the network to alert the student of the emergency so that information may be distributed prior to the next scheduled class. Emergencies will usually also include a group email on the morning/afternoon of the class meeting.  

Required Assessments Week One: TBA

E-Instruction (option) or Clickers:

During a scheduled class (75-90 minutes), after going through the lecture on the assigned chapters via many modalities of teaching including Internet web sites, the instructor will utilize either the last 10 minutes or the first 10 minutes of class to go through the Power Point for the assigned chapter as a review.

However, multiple choice questions will be inserted into the online power points which will require all students to answer via the instructor’s e-Instruction system (keypads). Each correct response will be worth one point, while an incorrect response will count zero points. e-Instruction system will be worth no more than 50 points (out of 100 possible) for the term (5% total if used Fall Term 2008). For each exam when e-Instruction is not used, the multiple choice section of the modules will be increased at five to ten questions per chapter.

Students are expected to get 50% correct on each day’s e-Instruction questions. During the term, the instructor may pretest a section of the multiple choice for the course using the e-Instruction system where the responses will count 1 point each of the 10 to 15 points assigned to multiple choice for that Module.

CHM 2046C Practice/Take Home/or Pre-Final Exam: During the last week of school, (Dec 4-Dec 11) students will complete the on-line practice final exam during the

last scheduled lab section (Dec 9) (No other lab activities are scheduled during final exam week). The Prefinal must be completed before attempting the Final. The course home page will have a link posted December 4 for the prefinal. The prefinal may be one of the previous finals designated as the practice final (usually the latest term available) or a new mock ACS exam may be developed for Fall Term 2008. The exam will be closed book and taken with your lab partner in the library computer center. It will be interactive allowing you to change answers after initial scoring. If it is from ExamView, then you are allowed three submissions. Each cooperative group will submit one practice final section for each module completed during the course. Both students will receive the same grade for the practice final. The practice final will count as the first 5% completion towards the final grade. A student may chose to work without a partner. One student will be requested to type the prefinal into the HTML exam template to allow multiple attempts to achieve the answer, otherwise ExamView will be utilized which does not have multiple tries available.

ACS General Chemistry Exam-Second-Term or Instructor Made Final Exam from TestbankThe final exam is not optional. It will be the 75 (best 50 will be scored) questions of the standard American Chemical Society General Chemistry-Second Term Exam. The Final counts as two to three modular test scores or 10% of the total grade. The multiple choice sections of the module exams are mini-tests of the final as well as online multiple choice homework. If you score more than 50 correct answers, the instructor will award bonus 1 point per correct answer (not adjusted to 2.0 factor for the first 50 correct questions). If the Final exam is not ACS, then it will be 100 questions worth one point each. Questions selected from Kotz 6e testbank.

ACS General Chemistry-Second Term Breakdown____(10) Solutions ____(10) Kinetics____(10) Equilibrium____(10) Thermodynamics____(10) Electrochemistry____(05) Nuclear____(05) Polymers____(05) Descriptive____(05) Organic____(05) Solids____(75) Total

Final Exam Challenge: If a student scores a higher % on the final exam (all 75 questions-adjusted ACS norm score) then the grade earned

through the total points assigned, then the Final Exam score will constitute the final grade average for the lecture. The instructor will not drop the lowest exam score during the course, but may allow post-testing the last two weeks to raise a poor score earned earlier in the course. A special post test day is Saturday December 6 at 10:30 a.m.-3:30 p.m. in D-207. However, the student scoring the highest final exam grade as long as its better than 70%, will receive a final grade of an “A”  

Chemistry and the World Wide Web:  CHM 2046C Home Page: http://www.fccj.us/chm2046.html Grading Outline/Sample Quizzes: http://www.fccj.us/chm2046/46grdF08.htm Online Grade Calculator: http://www.fccj.us/chm2046/46grdcal.html Email/Phone Contacts: http://www.fccj.us/chm2046/46email.html (not posted Spring 08 term)Kotz 5th ed.Text Power Points: http://www.fccj.us/chm2046/46pptmenu.html

Daily Pretest Quizzes (optional): Pretest quizzes may be administered before (12:30-1:00), sometimes during, and/or after (4:00-4:30) every class which is not a scheduled exam day. These pretest quizzes may not be made up outside of class time, unless directed by the instructor to complete the pretest in the test center during an assigned period of time.

Scored pretest quizzes are NOT recorded in the instructor’s grade book or on Blackboard, but must be attached to the Modular Exam Grading Outline the day of the exam to receive the pretest grade. This pretest packet is submitted as a separate packet. Students must write the scores on both the cover sheet of the pretest packet and on the front page of each exam.

The student will skip the section of the modular exam that is pre-tested. The Pretest scores sometimes may be recorded on the attendance sheet, but only for your instructor’s sense of current levels of class achievement. If you loose the graded pretests, you will have to do the section over on the exam.

The instructor only records Module Exam totals and the Final Exam in his grade book and on Blackboard. Multiple choice and vocabulary sections of modules are usually only tested on exam day and are usually never pre-tested or post-tested.

Do Not Staple the Modular Exams together as they are graded separately, listed on Blackboard separately, and returned separately after the exam day. Please staple carefully as directed. Mixing the modular papers on Exam day may result in a lower grade.

1. Pretests are exams. They are not open book. They are not open notes. They are not collaboration with your neighbor.

2. The pretests may NOT be used during the exam!3. You must do the pretests in class. You may NOT take

the pretests home. Samples of each section (pretest) of each exam may be found on the grading outline on the web site. On the sample tests are suggestions for paper and pencil homework in the textbook. The grading outline may be found at:Kotz 6th Edition: http://www.fccj.us/chm2046/46grdF08.htmMcMurray 5th edition: http://www.fccj.us/chm2046/46grdF08McM.htm

Pre-testing is a privilege not a right!Our classroom D-211 may not have a scheduled class in the room before our class on Tuesday and Thursday. Pretesting will begin at 12:30 to 1:00 p.m. each class day and must be completed before class begins at 1:00. Students who are late to class (after 1:00), will not be allowed to pretest until after class. Students should plan to stay late if they can not arrive early. Many times the pretest will not be administered till the last 5 minutes of class so that student may complete the item after class has concluded. Pretest will be graded for all students who stay after 4:00 p.m. Pretesting may also be done 4:00-4:30 p.m.

 Post-Testing:

The instructor may post test sections of the modular exams that a majority of the students on designated days. Multiple choice and vocabulary sections may not be post-tested. The designated last day for post testing is Saturday December 6 at a time to be announced.(Either 10:30-3:30 or 1:00-5:30 depending if dr. Darby has her Winter Festival on that day. The post test is a free attempt. Scoring lower on the post test than on the modular exam section will not penalize the student. The post test will be ignored and the exam section score will count. Improving on the post test will replace that section’s score on the modular exam and the improvement will raise the score of the modular test. A student scores 5 out of 10, post test and scores 10 out of 10, the student’s grade is improved by the net five points. . The student will resubmit his/her exam with the graded post test stapled on top for an adjustment in the modular exam score. If the student does not have her/his exam, then post testing will NOT be possible. Post testing is allowed only on items that the instructor has a third or fouth different post test available. If post tests are not available, then they may not be post tested.

MAKE-UP POLICY: Make-up exams are usually not given. In the event of an unavoidable absence on exam day (jury duty, hospitalization, incarceration, and death in the immediate family), you will be allowed make-up tests only upon the instructor’s approval.. You must contact the instructor, no later than, the week of the exam in order to discuss what arrangements might be made. This may be done with a quick email. A message must be left on the instructor's e-mail (johtaylo@fccj.edu ) or his office phone 766-6763 if the instructor cannot be reached. If a makeup is allowed, it must be completed prior to return of the exam papers completed by the students attending the scheduled exam. Missed exams will otherwise count as 0 points. Papers are returned usually after one or two weekends after the exam.

Students who take the test on the assigned day are guaranteed to receive their graded exam on or before the next exam day, otherwise the student will be assigned a 100% grade for the un-graded paper. Students not taking the exam on the assigned exam day may not receive their grade until days or weeks after the class papers are returned.

 A-16 Tentative Exam Schedule North Campus:Bonding Concepts Pretest: Lecture Tuesday August 26Exam #1 (Modules 4II & 16) Thursday September 4Exam #2 (Modules 7II & 8II) Tuesday September 23Exam #3 (Modules 9 &10) Tuesday October 21Exam #4 (Modules 11&12) Thursday November 6Exam#5 (Module 13, 14, 15) Thursday December 4On-Line Prefinal will be available December 4-December 11 until 1:00 p.m.)Final Exam: Thursday December 11: 1:00-4:00 p.m.  

Major Learning Outcomes (Goals):

This course is designed as the second semester of a two semester sequence of College Chemistry. CHM 2046C has been modified and streamlined to accomplish the following major learning outcomes in 45-60 total hours of class and instruction. Students entering the class should have had CHM2045C with a passing grade.

. Learning Objectives for General Chemistry IIStudents who have completed General Chemistry I (CHM 2045C) are expected to demonstrate knowledge of the following content-based learning objectives. The learning objectives are arranged by major content area.

Module 4 Part II: Objectives (Chapters 9 & 10): (Review from CHM 2045C) Terms: valence electrons, chemical bond formation, bonding in ionic compounds, covalent bonding, bond

properties, charge distribution, in covalent compounds, molecular shapes, molecular polarity, orbitals and bonding theories, valence bond theory, and molecular orbital theory.

1. Predict molecular geometry of a molecule.2. Predict and explain the polarity of a molecule.3. Explain the geometry of a molecule using one of the bonding theories.4. Predict the hybrid orbital type for an atom in a covalent molecular

Module 16 formerly Module 4_III Organic Chemistry (Chapter 11)Students must know or be able to do the following:

Define organic chemistry. Know the four types of hydrocarbons including their general formula, hybridization, bond angle, name

ending, and some examples of each. Define structural isomers and stereoisomers and provide examples of each. Describe the difference between saturated and unsaturated hydrocarbons and give examples. Define functional group. Provide general structure, functional group, name ending and some examples of several families of

organic compounds including alcohols, aldehydes, ketones., carboxylic acids, esters, amines, and amides.

Polymer Chemistry or BioChemistry (Chapter 11.5)Students must know or be able to do the following: Define polymer, plastic, thermoplastic, and thermoset. Describe the two reaction types used to synthesize polymers and give some specific examples of

each. Know the synthesis of polyethylene and its derivatives, polyamides, and polyesters. Know the “Big Six” plastics including recycling number, abbreviation, name, structure of the

monomer, thermoplastic or thermoset, and addition or condensation. Compare the structural differences, physical properties, and uses of LDPE and HDPE

M-7 Part II Liquids and Solids (Chapter 13) Students must know or be able to do the following: Describe the difference between intermolecular and intramolecular forces. Describe and apply the various intermolecular forces including ion/dipole, dipole/dipole, hydrogen

bonding, dipole/induced dipole, and induced dipole/induced dipole. Know the properties of liquids in relation to their intermolecular forces. Define and apply the terms critical temperature, critical pressure, surface tension, capillary action,

cohesive force, adhesive force, and viscosity. Be familiar with the characteristics of the two types of solids – amorphous and crystalline. Be familiar with the characteristics of the four types of crystalline solids – ionic, metallic, molecular,

and network. Define and apply the terms space lattice and unit cell. Be familiar with the characteristics of the three types of cubic unit cell – simple, body-centered, and

face-centered. Calculate the radius of an atom or ion based on type of cubic unit cell. Be familiar with the characteristics of a simple and face-centered cubic unit cell of an ionic compound

in terms of lattice points occupied by anions and holes occupied by cations. Define vaporization or boiling point and melting point. Be familiar with the change in enthalpy of fusion, crystallization, vaporization, and condensation. Use a phase diagram. Define triple point.

Module 8-Part II Solutions and Their Behavior (Chapter 14)Students must know or be able to do the following: Know and be able to carry out calculations using molarity, molality, mole fraction, weight percent,

parts per million, and parts per billion. Define solubility, saturated solution, unsaturated solution, supersaturated solution, miscible, and

immiscible. Determine the solubility of a salt based on the change in enthalpy of solution. Know and apply the affects of pressure and temperature on the solubility of a gas in a liquid. Know and apply the affect of temperature on the solubility of a solid in a liquid. Define and give examples of colligative properties. Define and perform calculations using Raoult’s Law. Calculate freezing point depression and boiling point elevation when a solute is added to a solvent

when the solute is an electrolyte and a nonelectrolyte. Calculate molar masses of compounds based on colligative properties. Define ion pairing and describe its affect on colligative properties. Define osmosis, reverse osmosis, and osmotic pressure. Calculate osmotic pressure. Define and give examples of the various types of solutions including isotonic, hypotonic, and

hypertonic. Define crenation and homolysis. Define and give examples of colloidal dispersions. Define and give examples of an emulsion, emulsifying agent, and surfactant. Describe how soap is made and how it works. Define hydrophobic and hydrophilic.

Describe what is meant by the term “hard water”.

Module 9 Principles of Reactivity: Chemical Kinetics (Chapter 15)Students must know or be able to do the following: Define kinetics. Calculate the average and instantaneous rate of a chemical reaction. Know the factors that affect the rate of a chemical reaction and how they affect the rate including

concentration, temperature, state of subdivision, and addition of a catalyst. Write rate equations for chemical reactions based on experimental data. Determine the order of a chemical reaction. Determine the rate constant based on experimental data. Know and apply first order rate equations including calculation of half-lives. Know and apply zero order and second order rate equations. Define and apply the collision theory. Use the Arrhenius equation to find activation energy. Define reaction mechanism, intermediate, and free radical. Write rate equations for mechanistic steps. Define rate-determining step.

Module 10: Principles of Reactivity: Chemical Equilibria (Chapter 16)Students must know or be able to do the following: Define equilibrium. Write equilibrium constant expressions for chemical reactions applying rules. Calculate equilibrium constants using equilibrium constants of other related reactions and from

equilibrium concentrations. Interpret equilibrium constants in terms of whether the reaction is reactant or product favored. Assess reaction quotient to determine how a reaction will proceed. Calculate equilibrium concentrations based on initial concentrations and the equilibrium constant. Define and apply LeChatelier’s Principle. Know how reactions at equilibrium are affected by stresses such as temperature, concentration, and

pressure.

Module 11 Principles of Reactivity: The Chemistry of Acids and Bases (Chapter 17)Students must know or be able to do the following: Describe the properties of acids and bases. Define acids and bases in terms of the Arrhenius or Classical definition, the Bronsted-Lowry

definition, and the Lewis definition. Predict the products of a neutralization reaction. Provide the self-ionization reaction for water. Memorize a list of acids and bases including their name, formula, number of protons they can donate

or accept, and strength. Define monoprotic, diprotic, and triprotic acids and bases. Write ionization reactions for acids and bases. Define and give examples of species which are amphiprotic and amphoteric. Define and apply the terms conjugate acid and conjugate base. Determine the equilibrium position of an acid-base reaction. Determine acid and base strength based on Ka and Kb. Describe the leveling effect. Write equilibrium expressions for the ionization of weak acids and bases. Define, apply, and perform calculations using the pH and pOH equations. Correlate acidity, basicity, pH, pOH, hydronium ion concentration, and hydroxide concentration. Perform calculations using the equilibrium expression for the ionization of water. Know two ways to determine pH. Calculate pH from Ka or Kb using initial concentrations and the equilibrium expression. Calculate % ionization of a weak acid or base. Be familiar with the common acid and basic ions that form acidic and basic salts. Determine equilibrium concentrations for all ionization products of diprotic and triprotic acids. Describe how acid strength is affected by the inductive effect and bond strength. Describe molecules as Lewis acids or bases.

Module 11: Principles of Reactivity: Other Aspects to Aqueous Equilibria (Chapter 18.1-18.4)

Students must know or be able to do the following:

Define and apply the concept of buffer solutions. Define pKa and use it in calculations. Know and apply the Henderson-Hasselbach Equation to buffer systems. Calculate the pH of a buffer solution before and after a strong acid or base is added. Perform calculations to determine how you would prepare a buffer solution at a given pH. Perform calculations that apply the common ion effect to acid and base ionization reactions. Predict the acidity/basicity of a solution at the equivalence point of a titration based on the strength of

the acid and base reacted. Calculate the pH at all of the various points during a titration - prior to the equivalence point, at the

equivalence point, and after the equivalence point for all of the following combinations - strong acid/strong base, strong acid/weak base, and strong base/weak acid.

Generate titration curves for all of the following combinations of reactants: strong acid/strong base, strong acid/weak base, and strong base/weak acid.

Predict the shape of a titration curve for the titration of a diprotic or triprotic acid. Define acid-base indicator and determine which is the best choice for predicting the equivalence point

of a particular acid/base combination.

Module 12: Principles of Reactivity: Precipitation Reactions (Chapter 18.4-18.7)Students must know or be able to do the following: Define Ksp. Write the Ksp expression for a slightly soluble salt. Determine Ksp from experimental measurements. Determine salt solubility from Ksp. Predict whether precipitation will occur based on calculation of reaction quotient. Calculate solubility before and after a common ion is added to the solution. Predict the Knet of a reaction via simultaneous equilibria. Provide equations and discussion to explain how the solubility of a salt is increased by addition of a

weak acid and decreased by the addition of strong acid. Be familiar with the solubility of complex ions.

Module 13: Principles of Reactivity: Entropy and Free Energy (Chapter 19)Students must know or be able to do the following: Define thermodynamics. Know the three laws of thermodynamics. Know the two fundamental laws of nature. Define all of the following – change in enthalpy, entropy, and free energy – and give the meaning of a

positive and negative value for each. Provide examples where entropy is increasing and decreasing. Calculate the entropy of a system using the equation: S = q/T. Calculate the entropy of the Universe using the equation: Suniverse = Ssystem + Ssurroundings

Calculate the entropy, enthalpy, and free energy changes of a system by finding the difference in the summation of the product formation (S, H, or G) minus the summation of the reactant formation (S, H, or G).

Utilize the equation G = H – TS Determine if a reaction is enthalpy of entropy-driven. Describe how a reactant-favored reaction can be made product-favored by coupling it to a very

product-favored reaction. Determine the minimum temperature needed to make a reaction spontaneous. Use the equation, G = R T ln K, to find G or K.

Module 14: Principles of Reactivity: Electron Transfer Reactions (Chapter 20)Students must know or be able to do the following: Define redox reaction, oxidation, reduction, oxidizing agent, and reducing agent. Provide some examples of redox reactions. Balance redox reactions in neutral, acidic, and basic solution. Draw and describe how an electrochemical cell works. Calculate G using cell potential: Go = - n F Eo

Calculate cell potential using standard reduction potentials. Describe how the standard reduction potentials are generated. Describe the standard hydrogen electrode and provide its purpose. Describe how a positive/negative reduction potential indicates a better oxidizing/reducing agents. Use the Nernst equation to calculate cell potential under non-standard conditions. Calculate the equilibrium constant for a reaction using cell potential via

Ln K = nEo / 0.0257 Define and give examples of primary batteries, secondary batteries, and fuel cells Define corrosion and be familiar with what causes it. Provide at least two ways to prevent corrosion. Define electrolysis and Faraday’s Law Apply Faraday’s Law in an electrolysis calculation.

Module 15: Nuclear Chemistry (Chapter23)Students must know or be able to do the following: Define radioactivity and give a brief description of its discovery. Know the three forms of radiation including symbol, charge, mass, speed, and penetrating power. Predict products in an alpha emission, beta emission, positron emission, and electron capture. Briefly describe “Band of Stability”. Define binding energy and use Einstein’s equation to predict its value. Define half-life and apply first order kinetics to radioactive decays. Define Carbon-14 dating and Artificial Transmutation. Predict products in artificial transmutation reactions. Define nuclear fission and nuclear fusion. Describe the parts of a nuclear power reactor. Define breeder reactor. Describe nuclear bombs. Describe several units of radiation. Describe the major sources of radiation exposure. Provide some examples of the applications of radioactivity including food irradiation, radioactive

tracers, and medical imaging.

LaboratoryStudents must know or be able to do the following: Carry out an experiment involving intermolecular forces. Carry out an experiment involving solubility. Carry out an experiment involving colligative properties. Carry out a kinetics experiment Carry out an equilibrium experiment. Carry out an experiment using a pH meter. Carry out an experiment involving acid-base titration curves. Carry out an experiment involving a buffer solution. Carry out a qualitative analysis experiment. Carry out a redox experiment. Carry out an organic synthesis. Carry out a lab involving polymers.

Quiz monitors, attendance monitor, personal assistants, test preparers, camera persons/editors, study guide word processor assistant, Chemistry WebMasters, as well as study groups are forms of cooperative learning environments where the student needs to learn how to function in teams. Each student MUST take charge of his/her commitment to learning in order to achieve success in not only this course but also in college.

Power Points from the 5th edition of the textbook may be downloaded by the student for their study. Go to:http://www.brookscole.com/cgi-wadsworth/course_products_wp.pl?fid=M20bI&discipline_number=12&product_isbn_issn=003033604X

Power Points for the 6th edition may be viewed on Blackboard:

Grading Scale:

Overall Percentages Grade100 – 90 % A* 89 – 80 % B* 79 – 65 % C*

64 – 50 % D*< 50 % F

*Lab is an essential part of this class. If you acquire less than 60% in lab, you will automatically receive a letter grade of ‘F’ in this course. If you make less than 70% in lab you may not earn a final grade above ‘D’

Grade Review:  See Grading Sheet (distributed separately) for a point by point summary of the course. It also serves as a Course outline, indicating sections of the text being covered on each exam.

Grading Outline: http://www.fccj.us/chm2046/46grdF08.htm  Grade Calculator: http://www.fccj.us/chm2046/46grdcal.html  Point Grade Summary: ______ (010) Explorations/Safety Lab wk 1 [Email (2); Dis Wheel: (2) LrnSty:(4) Time:(2) Card (2)_______(040) Attendance [Lecture 29+ lectures x 1 point each + 1 pt for lab]_______(050) e-Learning (if no e-Instruction Modular Exams will be 650 points)_______(600) Modular Exams_______(150) Final Exam [20 Practice + 50 of 70 x 2 pts ACS Exam]_______(150) Lab Assignments [15x10]

_______(1000) Grand Total Tentative (point)   

% Weighting of the Components of the Course:Exams 60-65%Attendance 5%e-Instruction 0- 5%Final Exam 15%Lab Assignments 15%----------------- ------------Total 100%

ON-Line Grade Calculator: http://www.fccj.us/chm2046/46grdcal.html 

Instructor’s Right to Change or Modify Grading Procedures:  This instructor reserves the right to make changes in this syllabus whenever he feels it is appropriate to do so. The instructor reserves the right to modify or change the grading progress as the course proceeds. Any additional course assignments will substitute for deleted items. Some may also be modified if not deleted. The instructor will not add major examinations as a modification and maintain the above general category point distributions. Tests will constitute ~60-65% of the grade excluding the final’s 15%, 15% for the laboratory component, 0-5% of the grade for Interactive Classroom Presentation System, and 5% for attendance.

Students absent on exam days will do a makeup exam outside of class time when they return on the next Tuesday or Thursday following the absence or by special arrangements in the Assessment Center. This exam must be completed before the next scheduled exam or the day the instructor returns the exam missed. The instructor guarantees the student two days to make up the exam, but thereafter it depends on the day the tests are returned.

Student who takes the test on the assigned test day are guaranteed to receive their graded exam on or before the next exam day after completion of the new exam, otherwise the student will be assigned a 100% grade for the un-graded paper.

Lab Reports/Write-ups, and/or Lab Notebook are due prior to the next scheduled lab. Lab reports submitted after that date may be subject to a one to two point (10-20%) penalty depending on whether the instructor has graded that weeks lab. Lab Data submitted without calculation will receive a minimum of 5 points (50%). Labs not submitted receive a grade of zero. Students absent from lab receive a zero. Students attending and submitting all lab reports receive up to 10 extra points as a student is allowed only one absence from lab.

 

Other Pertinent Information (Supplemental Notes):

Students with Disabilities: Qualified students with documented disabilities are eligible for physical and academic accommodations under the American Disabilities Act and Section 504 of the Rehabilitation Act of 1973. Students requesting accommodations should contact Student Development Services at 264-7220 (voice) or 264-3371 (TTY) and this professor during the first week of class.

Withdrawal Policy: Students will be allowed to withdraw from this class any time during the semester through

Monday, November 3 for an A-16 schedule and will receive a grade of “W”. Students failing to attend class for the first two consecutive weeks are subject to withdrawal by the instructor according to FCCJ policy. These ‘no shows’ must be reported to Admissions and Records by the end of two weeks Tuesday September 9

Academic Misconduct: Academic misconduct or dishonesty such as cheating and plagiarism is not permitted. Suspected cases may be reported to the Dean of Liberal Arts and may result in failure of an assignment, failure for the course or exclusion from the class. Also, the instructor reserves the right to reassign work to students if the instructor senses the work submitted is not the work of the student. (No questions asked-The instructor may tell the student to resubmit the work to earn the daily pretest grade or examination grade or may be assigned a zero if second request is made).

Classroom Etiquette: Students are expected to conduct themselves as adults in the classroom showing respect to

their classmates. Only persons registered for this class are permitted in the laboratory. As a courtesy to the instructor and your fellow classmates, cellular telephones and pagers should be cut off before entering the classroom or laboratory. Likewise, the instructor sometimes forgets to shut his down at the beginning of class, so hopefully someone sitting close to the front may remind the instructor with a hand gesture for him to check his phone,

Children in the Classroom Policy: It is the goal of FCCJ to provide a safe and effective learning environment for all students. Any action, which interferes with this goal, will not be permitted. Children must not be left unattended at any time on campus. If an emergency arises which requires a student to bring an underage child (defined as any child under the age of sixteen who is not a FCCJ student enrolled in a credit class) to campus, the child must be under the direct supervision of an adult at all times. Parents and guardians of children considered disruptive or unsupervised will be asked to remove the children from the campus immediately.

Bringing children to the classroom is not permissible under most circumstances. However, if an emergency arises which necessitates bringing a child to class, the student must receive the prior consent of the faculty member involved. Children who are ill may not be brought to class regardless of the circumstances. Due to the nature of the equipment, the subject matter involved, and the level of supervision necessary, underage children will not be allowed in college laboratories or in the Learning Center at any time and/or under any circumstances.

Children enrolled in non-credit classes must be under the direct supervision of an adult at all times. Likewise, children attending campus events must be supervised at all times. Any child under the age of 16 must be under the direct supervision of his/her parent, legal guardian, or other responsible adult when in the college library unless the child is part of a call AND the supervising teacher or paraprofessional is present

Studying: In order to do well in this course, it is essential to study and work problems. The following is a list of study suggestions 1) Read the text chapters before the material is covered in class.2) Take good notes and review them daily.3) Work all assigned homework problems. Do not get behind!!!!!!4) Work the practice exams that will be made available without looking at the answer key.5) Work problems in ACS study guide.6) Use the interactive CD-Rom for studying/or the CD-Rom Printouts.

‘Muddy Water’ Issues: Each day, students may use 3x5 file cards (as provided by the instructor the first week) to list the day’s muddiest water

issue or send the instructor an email immediately after class. What was confusing? What don’t you understand? What problems at the end of the chapter overwhelm you? As you leave the classroom, you will submit a card with your name and the issue or issues. If you are absolutely on target, no problem then no card submitted a card indicates to the instructor you are on course on time and understand the learning concepts. At the end of each on-line group/individual quiz/homework may be a place to journal your discovery statements, the muddy water issues, and check list of vocabulary words that you do not understand.

The Learning Center (D-330) (904) 766-6718

The Learning Center has chemistry tutoring. Please call for times and appointments. The Center is open Mon-Thur 8:00 a.m.-10:00 p.m. Friday and Saturday 8:00 a.m.-3:00 p.m.

The Learning Center also needs tutors. Please contact if interested.

  Additional Chemistry Web Sites:Chemdex is a large chemistry directory created by Dr. Mark Winter at the Department of Chemistry, University of Sheffield, England with links to over 7000 Internet sites: http://www.chemdex.org

Links for chemists and Virtual Library chemistry may be found at:http://www.liv.ac.uk/chemistry/links

Chemistry Web Guide: http://science.searchbeat.com/chemistry.htm

The NIST Chemistry WebBook (database of physical data and spectra): http://webbook.nist.gov

General Chemistry Texts: http://academic.cengage.com/cengage/catalog.do?courseid=CH04&disciplinenumber=12&codeid=2C0A&codeFlag=true

Other General Chemistry Text Books with Practice Multiple ChoiceHill: General Chemistry 4th http://wps.prenhall.com/esm_hillpetrucci_genchem_4Tro: Chemistry-A Molecular Approach: http://wps.prenhall.com/esm_tro_chemistry_1/Averill: Chemistry Principles, Patterns and Applications http://wps.aw.com/bc_averill_principles_1/47/12214/3126955.cw/index.html

Brown 9th: Chemistry-The Central Science http://wps.prenhall.com/esm_brown_chemistry_9/ Brown 8th: Chemistry-The Central Science http://wps.prenhall.com/esm_brown_chemistry_8e/

Other Introductory Chemistry Texts with Practice Quizzes:Tro: Fundamentals of Chemistry 4th http://wps.prenhall.com/esm_burns_chemistry_4/ Corwin: Introductory Chemistry 4th: http://wps.prenhall.com/esm_corwin_chemistry_4/

Liberal Arts Texts with Practice Multiple Choice:World of Chemistry 4th http://www.brookscole.com/cgi-wadsworth/course_products_wp.pl?fid=M20b&flag=student&product_isbn_issn=9780495012139&disciplinenumber=12 Chemistry in Focus: A Molecular View of Our World: http://www.brookscole.com/cgi-wadsworth/course_products_wp.pl?fid=M20b&flag=student&product_isbn_issn=9780495017691&disciplinenumber=12

Objectives/Links/TutorialsMcMurray5th: http://wps.prenhall.com/esm_mcmurry_chemistry_5/ Adventures in Chemistry (Demonstrations): http://college.cengage.com/chemistry/liberal/millard/chemistry/1e/student_home.html

Ebbing: http://www.hmco.com/college/chemistry/index.html

 Alternate Text being used by some students:Chemistry, 5/E (text used by Dr. Lorenzo and Dr. Gant for 2045C)John E McMurry ISBN-10: 0131993232Robert C Fay ISBN-13: 9780131993235

Publisher: Prentice HallPublished: 04/13/2007Suggested retail price: $181.33 (In Book Store-New and used)

Grading Outline for Students using McMurray 5th edition:McMurray 5th edition: http://www.fccj.us/chm2046/46grdF08McM.htmExam#17.   Covalent Bonds and Molecular Structure 23.   Organic ChemistryExam#210.   Liquids, Solids, and Phase Changes 11.   Solutions and Their Properties  Exam#312.   Chemical Kinetics 13.   Chemical Equilibrium  Exam#414.   Aqueous Equilibria: Acids and Bases. 15.   Applications of Aqueous Equilibria  Exam#516.   Thermodynamics: Entropy, Free Energy, and Equilibrium 17.   Electrochemistry 22.   Nuclear Chemistry 

Instructor Requested Information: During the first week of class, the student will fill out a 4x6 file card. The instructor has provided a sample below with his personal data and his block scheduled time. The completion of this card is worth (2 points) toward the student's final grade

Data Card (4x6 file card): Front Side (Personal Data) --------------------------------------------------------------------------------------

Name: John Taylor CHM 2046COffice: D-270

Address: 4417 Port Arthur Road Jacksonville, FL 32224

Telephone: 904-766-6763 (office) Cell: 904 614-0531 Home: 904-992-2052E-MAIL : johtaylo@fccj.edu or jtaylor@hccfl.edu   Employment: FCCJ since 8/21/06

Full time chemistry faculty 

Major: Instructional Technologies Minor: Chemical EducationLong Term Goal: Educational Software Developer 

Prerequisite: MAC 1105 equivalent Algebra completed: yes Chemistry Background: CHM 2045C: yes A Physics Background: High School Physics completed: no 

Software/Computer Literacy: WP, Word, Excel, HTML, Javascript 

Home Computer: yes Internet ISP: yes or have access

Why are you taking this course? Required for chemistry major

--------------------------------------------------------------------------------------Data Card (4x6 file card): Back Side (Scheduled Time Blocks)

Class/Work Schedule Summary:Number Section Room Time DaysCHM 1020 283919 A-171 3:00-4:15 p.m. MW CHM 1025C 286714 D-207 9:00-12:00 p.m.RLab D-204 9:00-12:00 p.m.TESC 1000 270079 D-207 12:00-1:15 p.m.MWCHM 2046C 284690 D-207 1:00-4:00 p.m. R Lab D-204 1:00-4:00 p.m. T CHM 2211C 286138 D-207 7:00-10:00 p.m. MLab D-204 7:00-10:00 p.m. W

Class/Office Matrix Schedule (Where is Your Instructor?):My Schedule Matrix: I have 10 hours of office hours, Office/Pretest means I am in the course’s classroom, while Office means my office D-270. You must find 10 hours in you weekly matrix for studying chemistry. Please make your own!

 Time Monday Tuesday Wednesday Thursday Friday7:30 At Home At Home8:00 At Home On the Road At Home On the Road Community8:45 Course On the Road Course On the Road Service

9:00 Preptime CHM 1025C Preptime CHM 1025C Projects

9:30 PreptimeLecture 9-10

D-TBA Preptime Lecture 9-12

Off Campus or

10:00 Preptime Lab 10-12 Preptime D207 Corporate10:30 On the Road D-204 On the Road Lecture Computer11:00 On the Road Lab On the Road D207 Training

11:30Pretest/Office

A0171 LabPretest/Office

A0171 LectureOff Campus

or

12:00 ESC 1000Office/Pretest

D204/D270 ESC 1000Office/Pretest

D207/D270 Special

12:30A0171

Earth ScienceOffice/Pretest

D211A-171

Earth ScienceOffice/Pretest

D211 Help1:00 Sect# 283919 CHM 2046C Sect# 283919 CHM 2046C Pre-testing

1:15 Pretest/Office A-171

LectureD-211

Pretest/Office A0171

LectureD-211/204 Sessions

1:30 Office: D-270 Sect# 284690 Office: D-270 Sect# 284690 as2:00 Office D-270 CHM 2046C Office D-270 CHM 2046C announced

2:30Office/Pretest

A-171 CHM 2046COffice/Pretest

A-171 Lab D 204 via3:00 CHM 1020 Lecture CHM 1020 CHM 2046C email

 3:30 Lecture A-171 D-211 Lecture A-171 Lab On Campus

 4:00 Sect#283919Office/Pretest

D-211 Sect#283919Office/Pretest

D-211/204

4:15Office/Pretest

A-171 Office D-270

Office/Pretest A-171

Office D-270

4:30 On the Road On the Road 5:30 On the Road On the Road6:00 2211 Pretesting 2211 Pretesting

6:30 Pretesting D-203A CHM 2046CPretesting

D203A CHM 2046C

7:00 CHM 2211CIndependent

Study CHM 2211CIndependent

Study7:15 Sect#286138 See Above Lecture See Above7:30 D-207 Sect#2861388:00 CHM 2210C Lab/Lecture8:30 Lecture Lab Room9:00 D-207 D-204   9:30 Lecture Lab

10:00 Office D-270 Office D-27010:15 On the Road On the Road10:30 On the Road On the Road

Student’s Class/Work Matrix Schedule:

Where can you find 10 hours per week minimum to study?Name: ___________________________ CHM 2046C Fall Term 2008

 Time Monday Tuesday Wednesday Thursday Friday Saturday Sunday7:30

8:008:459:009:30

10:0010:3011:0011:3012:0012:301:001:302:002:102:303:00

 3:30 4:004:305:005:306:006:307:157:308:008:309:00  9:30

10:0010:1510:30

Submit this form the second class period