stereochemistry of biaryls and ansa compounds
DESCRIPTION
ansa compoudsTRANSCRIPT
April 12, 2023 1By Mohd Anzar Sakharkar
April 12, 2023 2By Mohd Anzar Sakharkar
STEREOCHEMISTRY OF BIARYLS
April 12, 2023 3By Mohd Anzar Sakharkar
April 12, 2023 4By Mohd Anzar Sakharkar
R
R R
R COOHCOOH
April 12, 2023 5By Mohd Anzar Sakharkar
P-3 b b
a a
b a
a b
b b
a a
90o 180o 270o 360o
Interplanar angle
b a
a b
April 12, 2023 6By Mohd Anzar Sakharkar
April 12, 2023 7By Mohd Anzar Sakharkar
NO2
HOOC
NO2
COOH
R
NO2
O2N
COOH
COOH
Al(CH3)3
H
H
HS
Al3(CH3)
H
H
F
April 12, 2023 8By Mohd Anzar Sakharkar
X X
H2C CH2
(CH2)n
April 12, 2023 9By Mohd Anzar Sakharkar
X X
H2C CH2
(CH2)n
April 12, 2023 10By Mohd Anzar Sakharkar
R-S NOMENCLATURE:
April 12, 2023 11By Mohd Anzar Sakharkar
O O
H2C CH2
(CH2)n
Pilot Atom 2
H3C CHIRAL PLANE
2
2
O O
H2C CH2
(CH2)n
CHIRAL PLANE
Pilot Atom
CH3
R S
O
O
H2CCH2
(CH2)n
Pilot Atom
H3C
CHIRAL PLANE
S
1 1
1
3 3
3
April 12, 2023 12By Mohd Anzar Sakharkar
April 12, 2023 13By Mohd Anzar Sakharkar
April 12, 2023 14By Mohd Anzar Sakharkar
April 12, 2023 15By Mohd Anzar Sakharkar