spherical microgranules give good bubble form

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INNOVATION AND NEW PRODUCTS Spherical microgranules give good bubble form Holland Colours in Netherlands has made available a blowing agent derived from azodicarbonamide. Holocell helps achieve good cell distribution when released early during the injection or extrusion process. The additive is suitable for use in mono- or co-extrusion PVC applications. It is also being offered in dust-free spherical microgranule forms for accurate dosing and there are grades for different decomposition temperature ranges. Modern Plastics International, Sep 2002, 32 (9), 34 Green polyvinyl chloride binding agent Bayer Chemical has announced the development of a new solvent-free binding agent for polyester and polyamide fibres and materials covered with a polyvinyl chloride layer. In addition the product increases the life of such materials and has low viscosity and volatility. Chimie Hebdo, 30 Sep 2002, (186), 16 Expancel plans expansion of microsphere production Expancel plans to expand its plant at Sundsvall, Sweden, for the production of microspheres. These have a diameter of 30 micrometres, but when warmed they release gas and the plastic shell softens, causing the microspheres to swell to a diameter of 120 micrometres. A decision will be made at about the end of 2002 whether to invest several SKR 100 M in the plant. The project will involve expanding an industrial facility in the Stockvik area and then moving in equipment to match growth in the market. Expancel is interested in mixing the microspheres with PP, PVC, or another thermoplastic and spray moulding. This should produce plastics with a foam structure which has the advantage over normal foam of having a more homogeneous structure and therefore being stronger, as well as waterproof. Kemivarlden, Aug 2002, (8), 6 Polyol for automotive seating US-based Renosol Corp has used polyols from Dow Chemical Co for its new automotive seating products. The polyols, which are marketed under the name Voranol and Voractive, reportedly lower the amine emissions that are said to lead to windshield fogging and discoloration of PVC parts, as well as degradation of PC components in automobile interiors. The company plans to supply the new technology for moulded PU seating and interior trim products for the automotive industry, including armrest, headrest, console cushions, seat cushions and back. High Performance Plastics, Sep 2002, 9 Fluid colours add an extra touch to PVC ColorMatrix Europe has made available highly-loaded liquid titanium dioxide colours. Only 65% liquid titanium dioxide is needed to achieve equivalent UV protection compared with 100% of its rival dry product. The liquid’s lower abrasion allows mixer blade and barrel as well as screw life to be lengthened over dry formulations. Modern Plastics International, Sep 2002, 32 (9), 29 Strandex deal with HMG Paints HMG Paints has agreed that users of the processing technology from Strandex for polymers filled with wood fibre will be able to apply coloured and metallic surface finishes using its priming system. The Strandex profiles can simulate soft and hard woods as well as traditional PVC and aluminium products. Plastics and Rubber Weekly, 13 Sep 2002, 20 Stabilisers target wood/PVC blend for profiles Chemson Polymer-Additive in Arnoldstein, Austria, offers stabilisers for PVC/wood extrusion. The stabilisers, Naftosafe PHX 395C and 922B, have been produced from calcium/zinc or organic materials. Addition levels have been set at 8 phr. No coupling agent is needed by the vinyl part of the melt for processing compounds of up to 70% wood flour or fibre. The products also do not require equipment tweaking. Modern Plastics International, Sep 2002, 32 (9), 32 Materials family gives PVC added impact strength Rohm & Haas Plastics Additives in France is marketing paraloid acrylic impact modifiers for PVC. K342 offers impact efficiency and low fusion promotion during extruded or injection moulding while KM369 is formulated for window profiles. K435, which is suitable at low addition levels, can be used as a processing aid for PVC foam-core pipe and foamed profiles. Modern Plastics International, Sep 2002, 32 (9), 32 Organic PVC stabiliser fits in well with fittings Crompton Vinyl Additives in Lampertheim, Germany, has made available an organic-based heat stabiliser for injection moulded PVC pipe fittings. The OBS stabiliser, which is suitable for complex flow paths and wall-thickness ratios, also provides initial colour and long-term heat stability. Addition levels have been set at 3.5 to 5 phr. Modern Plastics International, Sep 2002, 32 (9), 32 New process for CPVC A thermal initiation aqueous phase suspension process for CPVC production has been developed Qingdao Haijing Chemical (Group) Co Ltd, by utilising SG-7 or SG-5 type polyvinyl chloride resin and liquid chloride as raw materials. This offers lower cost and reduced pollution. Rigid CPVC pipes produced perform well with good properties and meet heat and corrosion requirements. CPVC resins produced from SG-5 type polyvinyl chloride display much better impact resistance than those of SG-7 type polyvinyl chloride while their mechanical properties and dynamic stability are satisfied. Qingdao Haijing Chemical currently has capacities of 110,000 tonnes/y of caustic soda, 80,000 tonnes/y of 6 NOVEMBER 2002 FOCUS ON POLYVINYL CHLORIDE

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INNOVATIONAND NEW

PRODUCTS

Spherical microgranules give goodbubble form

Holland Colours in Netherlands hasmade available a blowing agentderived from azodicarbonamide.Holocell helps achieve good celldistribution when released earlyduring the injection or extrusionprocess. The additive is suitable foruse in mono- or co-extrusion PVCapplications. It is also being offered indust-free spherical microgranuleforms for accurate dosing and thereare grades for different decompositiontemperature ranges.

Modern Plastics International, Sep 2002, 32 (9), 34

Green polyvinyl chloride binding agent

Bayer Chemical has announced thedevelopment of a new solvent-freebinding agent for polyester andpolyamide fibres and materialscovered with a polyvinyl chloridelayer. In addition the productincreases the life of such materialsand has low viscosity and volatility.

Chimie Hebdo, 30 Sep 2002, (186), 16

Expancel plans expansion ofmicrosphere production

Expancel plans to expand its plant atSundsvall, Sweden, for the productionof microspheres. These have adiameter of 30 micrometres, but whenwarmed they release gas and theplastic shell softens, causing themicrospheres to swell to a diameter of120 micrometres. A decision will bemade at about the end of 2002whether to invest several SKR 100 Min the plant. The project will involveexpanding an industrial facility in theStockvik area and then moving inequipment to match growth in themarket. Expancel is interested inmixing the microspheres with PP,PVC, or another thermoplastic andspray moulding. This should produceplastics with a foam structure whichhas the advantage over normal foamof having a more homogeneous

structure and therefore beingstronger, as well as waterproof.

Kemivarlden, Aug 2002, (8), 6

Polyol for automotive seating

US-based Renosol Corp has usedpolyols from Dow Chemical Co for itsnew automotive seating products. Thepolyols, which are marketed under thename Voranol and Voractive,reportedly lower the amine emissionsthat are said to lead to windshieldfogging and discoloration of PVCparts, as well as degradation of PCcomponents in automobile interiors.The company plans to supply the newtechnology for moulded PU seatingand interior trim products for theautomotive industry, includingarmrest, headrest, console cushions,seat cushions and back.

High Performance Plastics, Sep 2002, 9

Fluid colours add an extra touch toPVC

ColorMatrix Europe has madeavailable highly-loaded liquid titaniumdioxide colours. Only 65% liquidtitanium dioxide is needed to achieveequivalent UV protection comparedwith 100% of its rival dry product. Theliquid’s lower abrasion allows mixerblade and barrel as well as screw lifeto be lengthened over dryformulations.

Modern Plastics International, Sep 2002, 32 (9), 29

Strandex deal with HMG Paints

HMG Paints has agreed that users ofthe processing technology fromStrandex for polymers filled with woodfibre will be able to apply colouredand metallic surface finishes using itspriming system. The Strandex profilescan simulate soft and hard woods aswell as traditional PVC and aluminiumproducts.

Plastics and Rubber Weekly, 13 Sep 2002, 20

Stabilisers target wood/PVC blend forprofiles

Chemson Polymer-Additive inArnoldstein, Austria, offers stabilisersfor PVC/wood extrusion. Thestabilisers, Naftosafe PHX 395C and922B, have been produced from

calcium/zinc or organic materials.Addition levels have been set at 8 phr.No coupling agent is needed by thevinyl part of the melt for processingcompounds of up to 70% wood flouror fibre. The products also do notrequire equipment tweaking.

Modern Plastics International, Sep 2002, 32 (9), 32

Materials family gives PVC addedimpact strength

Rohm & Haas Plastics Additives inFrance is marketing paraloid acrylicimpact modifiers for PVC. K342 offersimpact efficiency and low fusionpromotion during extruded or injectionmoulding while KM369 is formulatedfor window profiles. K435, which issuitable at low addition levels, can beused as a processing aid for PVCfoam-core pipe and foamed profiles.

Modern Plastics International, Sep 2002, 32 (9), 32

Organic PVC stabiliser fits in well withfittings

Crompton Vinyl Additives inLampertheim, Germany, has madeavailable an organic-based heatstabiliser for injection moulded PVCpipe fittings. The OBS stabiliser,which is suitable for complex flowpaths and wall-thickness ratios, alsoprovides initial colour and long-termheat stability. Addition levels havebeen set at 3.5 to 5 phr.

Modern Plastics International, Sep 2002, 32 (9), 32

New process for CPVC

A thermal initiation aqueous phasesuspension process for CPVCproduction has been developedQingdao Haijing Chemical (Group) CoLtd, by utilising SG-7 or SG-5 typepolyvinyl chloride resin and liquidchloride as raw materials. This offerslower cost and reduced pollution.Rigid CPVC pipes produced performwell with good properties and meetheat and corrosion requirements.CPVC resins produced from SG-5type polyvinyl chloride display muchbetter impact resistance than those ofSG-7 type polyvinyl chloride whiletheir mechanical properties anddynamic stability are satisfied.Qingdao Haijing Chemical currentlyhas capacities of 110,000 tonnes/y ofcaustic soda, 80,000 tonnes/y of

6 NOVEMBER 2002

F O C U S O N P O L Y V I N Y L C H L O R I D E