south central ucmr4 results semi vols metal haa combined€¦ · 16/04/2019 · 2118 profenofos...
TRANSCRIPT
LABORATORY REPORT
This report may not be reproduced, except in full, without written approval from EEA.
If you have any questions concerning this report, please do not hesitate to call us at (800) 332-4345 or (574) 233-4777.
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=::: e u ro fi n s I Eaton Analytical
Revision date: 03/14/2019
STATE CERTIFICATION LIST
State Certification State Certification Alabama 40700 Missouri 880 Alaska IN00035 Montana CERT0026 Arizona AZ0432 Nebraska NE-OS-05-04
Arkansas IN00035 Nevada IN00035 California 2920 New Hampshire* 2124 Colorado IN00035 New Jersey* IN598
Colorado Radiochemistry IN00035 New Mexico IN00035 Connecticut PH-0132 New York* 11398 Delaware IN035 North Carolina 18700 Florida* E87775 North Dakota R-035 Georgia 929 Ohio 87775 Hawaii IN035 Oklahoma D9508 Idaho IN00035 Oregon (Primary AB)* 4074
Illinois* 200001 Pennsylvania* 68-00466 Illinois Microbiology 17767 Puerto Rico IN00035
Illinois Radiochemistry IN00035 Rhode Island LAO00343 Indiana Chemistry C-71-01 South Carolina 95005
Indiana Microbiology M-76-07 South Dakota IN00035 Iowa 098 Tennessee TN02973
Kansas* E-10233 Texas* T104704187-18-12 Kentucky 90056 Texas/TCEQ TX207
Louisiana* LA014 Utah* IN00035 Maine IN00035 Vermont VT-8775
Maryland 209 Virginia* 460275 Massachusetts M-IN035 Washington C837
Michigan 9926 West Virginia 9927 C Minnesota* 018-999-338 Wisconsin 999766900 Mississippi IN035 Wyoming IN035
EPA IN00035 *NELAP/TNI Recognized Accreditation Bodies
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~:: eu rofi ns I Eaton Analytical
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449073
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00002
0787002
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261003 19030347-01-2 200.8 04/15/19 08:22 Client 04/16/19 10:00
4261004 19030347-01-3,4,5 525.3 04/15/19 08:22 Client 04/16/19 10:00
4261005 19030347-01-6,7,8 530 04/15/19 08:22 Client 04/16/19 10:00
4261006 19030347-01-9,10,11 541 04/15/19 08:22 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449073
Authorized Signature Title Date
05/10/2019
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=:~ eurofins I Eaton Analytical
§
Analytical Services Manager
Client Name: Report #: 449073Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL62907870787002
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
1053 Germanium 200.8 0.300 < 0.300 ug/L 04/22/19 13:30 04/23/19 13:22 4261003
1032 Manganese 200.8 0.400 < 0.400 ug/L 04/22/19 13:30 04/23/19 13:22 4261003
2115 alpha-Hexachlorocyclohexane 525.3 0.0100 < 0.0100 ug/L 04/27/19 06:03 04/29/19 15:30 4261004
2057 Chlorpyrifos 525.3 0.0300 < 0.0300 ug/L 04/27/19 06:03 04/29/19 15:30 4261004
2116 Dimethipin 525.3 0.200 < 0.200 ug/L 04/27/19 06:03 04/29/19 15:30 4261004
7570 Ethoprop 525.3 0.0300 < 0.0300 ug/L 04/27/19 06:03 04/29/19 15:30 4261004
2117 Oxyfluorfen 525.3 0.0500 < 0.0500 ug/L 04/27/19 06:03 04/29/19 15:30 4261004
2118 Profenofos 525.3 0.300 < 0.300 ug/L 04/27/19 06:03 04/29/19 15:30 4261004
2119 Tebuconazole 525.3 0.200 < 0.200 ug/L 04/27/19 06:03 04/29/19 15:30 4261004
2114 Permethrin, cis & trans 525.3 0.0400 < 0.0400 ug/L 04/27/19 06:03 04/29/19 15:30 4261004
2120 Tribufos 525.3 0.0700 < 0.0700 ug/L 04/27/19 06:03 04/29/19 15:30 4261004
2433 Butylated hydroxyanisole 530 0.0300 < 0.0300 ug/L 04/26/19 08:13 04/27/19 03:01 4261005
2434 o-Toluidine 530 0.00700 < 0.00700 ug/L 04/26/19 08:13 04/27/19 03:01 4261005
3435 Quinoline 530 0.0200 < 0.0200 ug/L 04/26/19 08:13 04/27/19 03:01 4261005
2084 1-Butanol 541 2.00 < 2.00 ug/L 05/07/19 07:00 05/09/19 23:32 4261006
2431 2-Methoxyethanol 541 0.400 < 0.400 ug/L 05/07/19 07:00 05/09/19 23:32 4261006
2432 2-Propen-1-ol 541 0.500 < 0.500 ug/L 05/07/19 07:00 05/09/19 23:32 4261006
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
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Lab Definitions
Continuing Calibration Check Standard (CCC) / Continuing Calibration Verification (CCV) / Initial Calibration Verification Standard (ICV) / Initial Performance Check (IPC) - is a standard containing one or more of the target analytes that is prepared from the same standards used to calibrate the instrument. This standard is used to verify the calibration curve at the beginning of each analytical sequence, and may also be analyzed throughout and at the end of the sequence. The concentration of continuing standards may be varied, when prescribed by the reference method, so that the range of the calibration curve is verified on a regular basis. CCL, CCM, and CCH are the CCC standards at low, mid, and high concentration levels, respectively.
Internal Standards (IS) - are pure compounds with properties similar to the analytes of interest, which are added to field samples or extracts, calibration standards, and quality control standards at a known concentration. They are used to measure the relative responses of the analytes of interest and surrogates in the sample, calibration standard or quality control standard.
Laboratory Duplicate (LD) - is a field sample aliquot taken from the same sample container in the laboratory and analyzed separately using identical procedures. Analysis of laboratory duplicates provides a measure of the precision of the laboratory procedures.
Laboratory Fortified Blank (LFB) / Laboratory Control Sample (LCS) - is an aliquot of reagent water to which known concentrations of the analytes of interest are added. The LFB is analyzed exactly the same as the field samples. LFBs are used to determine whether the method is in control. FBL, FBM, and FBH are the LFB samples at low, mid, and high concentration levels, respectively.
Laboratory Method Blank (LMB) / Laboratory Reagent Blank (LRB) - is a sample of reagent water included in the sample batch analyzed in the same way as the associated field samples. The LMB is used to determine if method analytes or other background contamination have been introduced during the preparation or analytical procedure. The LMB is analyzed exactly the same as the field samples.
Laboratory Trip Blank (LTB) / Field Reagent Blank (FRB) - is a sample of laboratory reagent water placed in a sample container in the laboratory and treated as a field sample, including storage, preservation, and all analytical procedures. The FRB/LTB container follows the collection bottles to and from the collection site, but the FRB/LTB is not opened at any time during the trip. The FRB/LTB is primarily a travel blank used to verify that the samples were not contaminated during shipment.
Matrix Spike Duplicate Sample (MSD) / Laboratory Fortified Sample Matrix Duplicate (LFSMD) - is a sample aliquot taken from the same field sample source as the Matrix Spike Sample to which known quantities of the analytes of interest are added in the laboratory. The MSD is analyzed exactly the same as the field samples. Analysis of the MSD provides a measure of the precision of the laboratory procedures in a specific matrix. SDL, SDM, and SDH / LFSMDL, LFSMDM, and LFSMDH are the MSD or LFSMD at low, mid, and high concentration levels, respectively.
Matrix Spike Sample (MS) / Laboratory Fortified Sample Matrix (LFSM) - is a sample aliquot taken from field sample source to which known quantities of the analytes of interest are added in the laboratory. The MS is analyzed exactly the same as the field samples. The purpose is to demonstrate recovery of the analytes from a sample matrix to determine if the specific matrix contributes bias to the analytical results. MSL, MSM, and MSH / LFSML, LFSMM, and LFSMH are the MS or LFSM at low, mid, and high concentration levels, respectively.
Quality Control Standard (QCS) / Second Source Calibration Verification (SSCV) - is a solution containing known concentrations of the analytes of interest prepared from a source different from the source of the calibration standards. The solution is obtained from a second manufacturer or lot if the lot can be demonstrated by the manufacturer as prepared independently from other lots. The QCS sample is analyzed using the same procedures as field samples. The QCS is used as a check on the calibration standards used in the method on a routine basis.
Reporting Limit Check (RLC) / Initial Calibration Check Standard (ICCS) - is a procedural standard that is analyzed each day to evaluate instrument performance at or below the minimum reporting limit (MRL).
Surrogate Standard (SS) / Surrogate Analyte (SUR) - is a pure compound with properties similar to the analytes of interest, which is highly unlikely to be found in any field sample, that is added to the field samples, calibration standards, blanks and quality control standards before sample preparation. The SS is used to evaluate the efficiency of the sample preparation process.
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-:~ eurofins Eaton Analytical
jwww Euronosus com/Eaton
! Shaded area for EEA use onlv
!CLIENT NAME: !SAMPLER (Print name)
110 S. Hill Street South Bend, IN 46617 T: 1.800.332.4345 F: 1.574.233.8207
UCMR 4 CHAIN OF CUSTODY RECORD
OrdertCJ5lJ02.0 Batch# 4M O •7·3
Pago __ of __ _
*PWS ID# STATE of sample origin !Check If this is a resample D
Example: IN1234567
!PO#: !If samples are not shipped the same day as collection then the temperature I
Chock If requires upload to EPA database D wo must have info for fields Indicated with • for
upload Bill To: the samples were held at must be recorded here("C):
*Sampling Event
LAB Number COLLECTION
DATE I TIME I l>M
ust 1 Addflionals SEA 1 SEA2 Preservative II) a:
Sampling Evant# ___ SEA3 SEA4: SEH 1 SEH2 SEH3 Checks w z
SEH4 < (Me~bebw) .... *FACILITY ID: (per EPA *Sampling z
*SAMPLE POINT ID: (per EPA Temperature Upon 0 Requirement)-5 Point Type Test Name UCMR4-
pH Residual u Requirement)-20 characters max Lab Receipt •c accop- Chlorino u..
PM I characters max Code 0 tablo?; PIA ..
, l47Jol nh2i (X)4 .
L/ft~/1t,I o<?i~I x I
no<;; ~ I
200.8 Metals 1
525.3 I J
530 I J
\c ()'7'. n \ \V \ ,I,,- 541 I J
6
- ,. _ •• _ w '"'nrl u ,1~~ nnt ~innP.d at 1~1a11ef:A u'f.':'I uluu ...... _ - ,.;;. .
: _ _ ~.: __ -1 ........ u "'" r'l,ont 10
Hellr 1qq1sr ep uy uy '-""'-' " ..
11
!RELINQUISHED BY:(Signature) DATE TIME
AMl PM
!RECEIVED BY:(Signature) DATE TIME I LAB COMMENTS
1AM' PM 1-X A\\ ,nfo -to.~ ft'loM bo\-\-\-t\ ~ e,l,tV\fs coc,, !RELINQUISHED BY:(Signature) DATE TIME RECEIVED BY:(Signature) DATE TIME
AM I PM I I I AM I PM jCONDITIONS UPON RECEl?r/4d: W~ Blue Check if received on day of coi:Coo'~:· 11
L.t::"'
--.... NO ICEPRF~l=t-JT 11\1 ~!11\ADI t::'C'
D !RELINQUISHED BY:(Signature) DATE TIME ~ DATE TIME Samples received within 48 hours of collection must be received at a temperature of s 10'C.
Samples received past 48 hours of collection are only valid if received at,; 6' C. verified and IJ(/// ei OU documented that the samples were refrigerated between collection and shipment. Temperature requirements apply to AM I PM I I AM PM all methods EXCEPT 200.8 and 300.0.
KEY A See Metal Samples Preservation Log P = Present A= Absent
UCMR4 accepGI1f"ce criteria for Receiving Checks: *Sampling Point Type Code: 200.8 pH < 2 541 pH < 3 SR = source water taken from plant intake; untreated water entering the water treatment plant 525.3 pH s 4 544 pH 6.5-7.5 EP = entry point to the distribution system 530 pH about 7 (6-8) TOC pH < 2 DS = distribution system sample
I Must be absent of residual chlorine(free): 525.3. 530. 541. 544. 545. 546. and 552.3.
Note in Comments section any samples which do not meet acceptance criteria. 06-LO·F0912 Issue: 5.0 Effective Date: 2018.01-18
Sample analysis will be provided according to the standard EEA/Water Services Terms, which are available upon request. Any other terms proposed by Customer are deemed material alterations and are rejected unless expressly agree to in writing by EEA.
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Subcontracted Chain of Custody .-------------+-'--H.-+-------, ~----~---------~
---- II I I II I 111111111111111 Hillsborough County 'orida
:nvironmental Laboratory Customer: South Central CWS
Public Utilities
Sample ID: Customer: PWS#
19030347-01-10 South Central CWS 6290787
Address: 9460 E Columbus Dr
Collector: (En~ironmental Specialist I) Title:
1903034 7-01-11 South Central CWS 6290787
Address: 9460 E Columbus Or - ·-,--.. , _ ........ Collector (Environmental Specialist I) Title:
1903034 7-01-2 South Central CWS 6290787
Address: 9460 E Columbus Dr ........ , ....... , ---···· Collector: (Environmental Specialist I) Tille:
19030347-01-3 South Central CWS 6290787
Address: 9460 E Columbus Dr -·-,--··· ---···· Collector: (Environmental Specialist I) Tille:
19030347-01-4 Soulh Central CWS 6290787
Address: 9460 E Columbus Dr ....... , ........ , ---···· Collector: (Environmental Specialist I) Title:
1903034 7-01 -5 South Central CWS 6290787
Address: 9460 E Columbus Dr ---,--··· ............ Collector: (Environmental Specialist I) Title:
19030347-01-6 South Central CWS 6290787
Address: 9460 E Columbus Dr
Collector: (En~ironmental Specialist I) Tille:
19030347-01-7 South Central CWS 6290787
Address: 9460 E Columbus Dr
Collector: (En~ironmenlal Specialist I) Title:
1903034 7-01-8 South Central CWS 6290787
Address: 9460 E Columbus Dr
Collector. (En~ironmental Specialist I) Tille:
R ,rnnrt r.PnPr:atArl · 0'111!'il?01!'.l 14 ·!'i1
9456 E Columbus Dr Tampa, FL 33619
Certification Number: E44104
Phone No. (81 3) 272-5977 x 43635
Work Order: 19030347
Scheduled Sample SC • UCMR4 SV Set Name:
Subcontracted Vendor: Eurofins Eaton Analytical ...._-------LLC
Project: SC - UCMR4-SV
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile#
Sample Information Site: Collection Dale/Time:
CHWTP- Start: 4/1512019 8:22:00 AM 001 End: 4/1512019 8:22:00 AM
Environmental Specialist I
CHWTP- Start: 4/15/2019 8:22:00 AM 001 End: 4/1512019 8:22:00 AM
Environmental Specialist I
CHWTP- Start: 4/15/2019 8:22:00 AM 001
End: 4/15/2019 8·22:00 AM
Environmental Specialist I
CHWTP- Start: 4/1512019 8:22:00 AM 001 End: 4/1512019 8:22:00 AM
Environmental Specialist I
CHWTP- Start: 411512019 8:22:00 AM 001 End: 4115/2019 8:22:00 AM
Environmental Specialist I
CHWTP- Start: 411512019 8:22:00 AM 001 End: 4/1512019 8:22:00 AM
Environmental Specialist I
CHWTP- Start: 4115/2019 8:22:00 AM 001 End: 411512019 8:22:00 AM
Environmental Specialist I
CHWTP- Start: 4115/2019 8:22:00 AM 001 End: 4115/2019 8:22:00 AM
Environmental Specialist I
CHWTP- Start: 4/1512019 8:22:00 AM 001 End: 4/15/2019 8:22:00 AM
Environmental Specialist I
Sample Type: Container Type:
Drinking Waler Glass 125 ml Amber
{Grab)
Drinking Water Glass 125 ml Amber
(Grab)
Drinking Water Plastic 250 ml
(Grab)
Drinking Water Glass 1 L Amber
{Grab)
Drinking Water Glass 1 L Amber
(Grab)
Drinking Water Glass 1 L Amber
(Grab)
Drinking Water Glass 1 L Amber
(Grab)
Drinking Waler Glass 1 L Amber
(Grab)
Drinking Water Glass 1 L Amber
(Grab)
Preservative:
Sulfite + Bisulfale
Sulfite + Bisulfate
None
AA+ EDTA+ Kdihydrogen citrate
AA+ EDTA + Kdihydrogen citrate
AA+EDTA+Kdihydrogen citrate
Analysis Method:
200.8 • UCMR Metals Subcontracted
525.3 - UCMR List Subcontracted
Trizma + AA + EDTA + 530 - UCMR Semivolatiles Subcontracted dUrea
Trizma +AA+ EDTA + dUrea
Trizma +AA+ EDTA + dUrea
Analyles:
P:anA 1 nf 1
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Subcontracted Chain of Custody ~--------------~ r-----=--------- ---- -
Sample ID:
19030347-01-9
Address:
Collector:
Hillsborough County rlnrirfa Public Utilities
Customer: PWS#
South Central CWS 6290787
9460 E Columbus Dr -·-,--··· ---···· (Environmental Specialist I) Title:
1903034 7-02-1 0 South Central CWS 6290787
Address: 5402 Lithia Pinecrest Rd
Collector: (En~ironmental Specialist I) Title:
1903034 7-02-11 South Central CWS 6290787
Address: 5402 Lithia Pinecrest Rd -·-,--· ·· ____ ,, ,
Collector: (Environmental Specialist I} ntle:
1903034 7-02-2 South Central CWS 6290787
Address: 5402 Lithia Pinecrest Rd -·-,--··, ----.. Collector: (Environmental Specialist I) Title:
1903034 7-02-3 South Central CWS 6290787
Address: 5402 Lithia Pinecrest Rd - ·-1--··· ............
Collector: (Environmental Specialist t) TIiie
1903034 7-02-4 South Central CWS 6290787
Address: 5402 Lithia Pinecrest Rd ........ , ........ , ... ......... Collector: (Environmental Specialist t) Title·
1903034 7-02-5 South Central CWS 6290787
Address: 5402 Lithia Pinecrest Rd ---,---··· ----·· Collector· (Environmental Specialist I) Title:
1903034 7-02-6 South Central CWS 6290787
Address: 5402 Lithia Pinecrest Rd ........ , ....... , ... ......... Collector· (Environmental Specialist I) TIiie:
19030347-02-7 South Central CWS 6290787
Address: 5402 Lithia Pinecrest Rd .... .... , ....... , ............. Collector. (Environmental Specialist I) TIiie·
RPnnrt r,pnPr:>IP.rl ' n4/1/i/?n1q 14·/i'.'1
Environmental Laboratory
9456 E Columbus Dr Tampa, FL 33619
Certification Number : E441O4
P hone No. (813) 27 2-5977 x 43635
1111111111111111111111 Work Order: 19030347
Scheduled Sample SC • UCMR4 SV Set Name:
Subcontracted Vendor: Eurofins Eaton Analytical
~------- LLC
Customer: South Central CWS
Project: SC - UCMR4-SV
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile#
Sample Information Site: Collection Date/Time:
CHWTP-001
Start: 4/15/2019 8:22:00 AM
End: 4/15/2019 8:22:00 AM
Environmental Specialist I
LIWTP-002 Start: 4/1512019 12:13:00 PM
End: 4/1512019 12:13:00 PM
Environmental Specialist I
LIWTP-002 Start: 4/1512019 12:13:00 PM
End: 4/1512019 12:13:00 PM
Environmental Specialist I
LIWTP-002 Start: 4/15/2019 12:13:00 PM
End: 4/15/2019 12:13:00 PM
Environmental Specialist I
LIWTP-002 Start: 4/1512019 12:13:00 PM
End: 4/15/2019 12:13:00 PM
Environmental Specialist I
LIWTP-002 Start: 4/15/2019 12:13:00 PM
End: 4/15/2019 12:13:00 PM
Environmental Specialist I
LIWTP-002 Start: 4/15/2019 12:13:00 PM
End: 4/1512019 12:13:00 PM
Environmental Specialist I
LIWTP-002 Start: 4/1512019 12:13:00 PM
End: 4/ 15/2019 12:13:00 PM
Environmental Specialist I
LIWTP-002 Start: 4/1512019 12: 13:00 PM
End: 4/ 15/2019 12:13:00 PM
Environmental Specialist I
Sample Type:
Drinking Water
(Grab)
Drinking Water
(Grab)
Drinking Waler
(Grab)
Drinking Water
(Grab)
Drinking Water
(Grab)
Drinking Water
(Grab)
Drinking Water
(Grab)
Drinking Water
(Grab)
Drinking Water
(Grab)
Container Type:
Glass 125 ml Amber
Glass 125 ml Amber
Glass 125 ml Amber
Plastic 250 ml
Glass 1 l Amber
Glass 1 l Amber
Glass 1 l Amber
Glass 1 l Amber
Glass 1 l Amber
Preservative:
Sulfite + Bisulfate
Sulfite + B1sulfate
Sulfite + B1sulfate
None
AA + EDTA + Kdihydrogen citrate
AA+ EDTA + Kdihydrogen citrate
AA+ EDTA + Kdihydrogen citrate
Analysis Method:
541 - UCMR Alcohols Subcontracted
200.8 - UCMR Metals Subcontracted
525.3 - UCMR List Subcontracted
Trizma + AA + EDTA + 530 - UCMR Semivolatiles Subcontracted dUrea
Trizma +AA + EDTA + dUrea
Analytes:
P:anP? n f ~
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2
Subcontracted Chain of Custody ~--------------~ ,----------~----------~
....--:---...
Hillsborough County , Public Util ities
Env ironmental Labora tory
9456 E C o lu m bus D r Tampa, FL 33619
Certificatio n Num ber: E441 04
P hone N o . (813) 272-5977 x 436 35
II I I II I 1111 11111111 111 Work Order: 19030347
Scheduled Sample SC • UCMR4 SV Set Name:
Subcontracted Vendor: Eurofins Eaton A na lytica l
'--------- LLC
Customer: South Central CW S
Project: SC • UCMR4-SV
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile#
Sample Information Sample ID: Customer: PWS# Site: Collection Date/Time:
19030347-02-8 South Central CWS 6290787 LIWTP-002 Start: 411512019 12:13:00 PM
Address: 5402 Lithia Pinecrest Rd End: 4/1512019 12:13:00 PM
Collector: {En~ironmental Specialist I) Tille: Environmental Specialist I
1903034 7-02-9 South Central CWS 6290787 LIWTP-002 Stan: 4115/2019 12:13:00 PM
Address: 5402 Lithia Pinecrest Rd End: 4/1512019 12:13:00 PM -·-,--.. , ----·· Collector: {Environmental Specialist I) Tille: Environmental Specialist I
Rel1nqu1shed By. IS~ Accepted By: /'
Rehnqu1she-d By Accepted By
Relinquished By· Dale/Time Accepted By
RP.nnrt r:;pnpr::,lprl· n <111 !'./?()1 fl 1 d ·!'.1
Sample Type: Container Type:
Drinking Water Glass 1 L Amber
(Grab)
Drinking Water Glass 125 ml Amber
(Grab)
Date/Time
Date/Time·
Preservative:
Trizma +AA+ EDTA + dUrea
Sulfite + Bisulfate
o~oo
Analysis Method: Analytes:
541 - UCMR Alcohols Subcontracted
Notes
P::,np 1 nf 1
1
Jessie Brasch
Subject: FW: Incoming April 2019 UCMR4 sampling
From: Stanley, John [mailto:[email protected]] Sent: Tuesday, April 16, 2019 8:44 AM To: Jessie Brasch Cc: Watson, Edward Subject: Incoming April 2019 UCMR4 sampling
EXTERNAL EMAIL*
Hello Jessie, We sampled our April 2019 UCMR4 yesterday and they should arrive in South Bend today (UPS Tracking Numbers: J4634795594, J4634795601, J4634795610) Here is the information cross reference:
HCPUD Sample ID EPA Sample point ID Facility ID SP Type Sample Point Name
19030346‐01 SC1 00004 DS SC1 1309 Windjammer Place
19030346‐02 SC2 00004 DS SC2 415 Smithfield Lane
19030346‐03 SC3 00004 DS SC3 1107 S. Lenna Ave
19030346‐04 SC4 00004 DS SC4 113 Holly Lane
19030346‐05 SC5 00004 DS SC5 6912 Ohio Ave
19030346‐06 SC6 00004 DS SC6 807 4th Ave SW
19030346‐07 SC7 00004 DS SC7 10130 Harney Rd.
19030346‐08 SC8 00004 DS SC8 336 Brandywine
19030346‐09 SC9 00004 DS SC9 6110 Nundy Ave
19030346‐10 SC10 00004 DS SC10 11843 Whisper Creek Dr
19030346‐11 SC11 00004 DS SC11 12121 Colonial Estates
19030346‐12 SC12 00004 DS SC12 1534 Del Webb Ave
19030347‐01 0787002 00002 EP Central WTP POE
19030347‐02 0787001 00001 EP Lithia WTP POE
Let me know if you need any other information. Regards,
John K. Stanley Chief Environmental Scientist Public Utilities: Environmental Services Division ‐ Environmental Laboratory
Page 10 of 22
Eurofins Eaton AnalyticalRun Log
Run ID: 258160 Method: 200.8
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4269180 DS 04/23/2019 12:07RW
QCS 4269182 DS 04/23/2019 12:15RW
DFBL 4268504 DS 04/23/2019 12:23RW
LDB 4268501 DS 04/23/2019 12:28RW
CCM 4269183 DS 04/23/2019 13:14RW
FS 4261003 19030347-01-2 DS 04/23/2019 13:22DW
CCH 4269185 DS 04/23/2019 14:12RW
0.00
Page 1 of 2 EEA Run ID 258160 / EEA Report # 449073
Page 11 of 22
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70
.3
04
/23
/20
19
10
:45
04
/23
/20
19
12
:07
Fals
e
IS-I
ndiu
m200.8
N/A
CC
L1
.00
90
N/A
1.0
42
69
18
0--
---
---
-6
0 -
12
51
01
1.0
0
4/2
3/2
01
9 1
0:4
50
4/2
3/2
01
9 1
2:0
7F
als
e
Manganese
200.8
0.4
00
CC
L0
.36
49
99
ug
/L1
.04
26
91
80
---
---
---
50
- 1
50
12
20
.3
04
/23
/20
19
10
:45
04
/23
/20
19
12
:07
Fals
e
IS-S
candiu
m200.8
N/A
CC
L1
.01
83
N/A
1.0
42
69
18
0--
---
---
-6
0 -
12
51
02
1.0
0
4/2
3/2
01
9 1
0:4
50
4/2
3/2
01
9 1
2:0
7F
als
e
IS-Y
ttri
um
200.8
N/A
CC
L1
.00
82
N/A
1.0
42
69
18
0--
---
---
-6
0 -
12
51
01
1.0
0
4/2
3/2
01
9 1
0:4
50
4/2
3/2
01
9 1
2:0
7T
rue
Germ
aniu
m200.8
0.3
00
QC
S4
8.6
36
ug
/L1
.04
26
91
82
---
---
---
90
- 1
10
97
50
.0
04
/23
/20
19
10
:45
04
/23
/20
19
12
:15
Tru
e
IS-I
ndiu
m200.8
N/A
QC
S0
.99
80
N/A
1.0
42
69
18
2--
---
---
-6
0 -
12
51
00
1.0
0
4/2
3/2
01
9 1
0:4
50
4/2
3/2
01
9 1
2:1
5T
rue
Manganese
200.8
0.4
00
QC
S5
0.2
50
99
9ug
/L1
.04
26
91
82
---
---
---
90
- 1
10
10
15
0.0
0
4/2
3/2
01
9 1
0:4
50
4/2
3/2
01
9 1
2:1
5T
rue
IS-S
candiu
m200.8
N/A
QC
S1
.01
47
N/A
1.0
42
69
18
2--
---
---
-6
0 -
12
51
01
1.0
0
4/2
3/2
01
9 1
0:4
50
4/2
3/2
01
9 1
2:1
5T
rue
IS-Y
ttri
um
200.8
N/A
QC
S1
.00
41
N/A
1.0
42
69
18
2--
---
---
-6
0 -
12
51
00
1.0
0
4/2
3/2
01
9 1
0:4
50
4/2
3/2
01
9 1
2:1
5F
als
e
Germ
aniu
m200.8
0.3
00
DF
BL
0.2
88
99
9ug
/L1
.04
26
85
04
---
---
---
50
- 1
50
96
0.3
0
4/2
2/2
01
9 1
3:3
00
4/2
3/2
01
9 1
2:2
3F
als
e
IS-I
ndiu
m200.8
N/A
DF
BL
1.0
01
4N
/A1
.04
26
85
04
---
---
---
60
- 1
25
10
01
.0
04
/22
/20
19
13
:30
04
/23
/20
19
12
:23
Fals
e
Manganese
200.8
0.4
00
DF
BL
0.3
23
ug
/L1
.04
26
85
04
---
---
---
50
- 1
50
10
80
.3
04
/22
/20
19
13
:30
04
/23
/20
19
12
:23
Fals
e
IS-S
candiu
m200.8
N/A
DF
BL
1.0
12
4N
/A1
.04
26
85
04
---
---
---
60
- 1
25
10
11
.0
04
/22
/20
19
13
:30
04
/23
/20
19
12
:23
Fals
e
IS-Y
ttri
um
200.8
N/A
DF
BL
1.0
01
0N
/A1
.04
26
85
04
---
---
---
60
- 1
25
10
01
.0
04
/22
/20
19
13
:30
04
/23
/20
19
12
:23
Tru
e
Germ
aniu
m200.8
0.3
00
LD
B-0
.02
10
01
ug
/L1
.04
26
85
01
---
---
---
---
---
<
04
/22
/20
19
13
:30
04
/23
/20
19
12
:28
Tru
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ndiu
m200.8
N/A
LD
B1
.00
31
N/A
1.0
42
68
50
1--
---
---
-6
0 -
12
51
00
1.0
0
4/2
2/2
01
9 1
3:3
00
4/2
3/2
01
9 1
2:2
8T
rue
Manganese
200.8
0.4
00
LD
B0
.03
3ug
/L1
.04
26
85
01
---
---
---
---
---
<
04
/22
/20
19
13
:30
04
/23
/20
19
12
:28
Tru
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IS-S
candiu
m200.8
N/A
LD
B1
.02
47
N/A
1.0
42
68
50
1--
---
---
-6
0 -
12
51
02
1.0
0
4/2
2/2
01
9 1
3:3
00
4/2
3/2
01
9 1
2:2
8T
rue
IS-Y
ttri
um
200.8
N/A
LD
B1
.00
22
N/A
1.0
42
68
50
1--
---
---
-6
0 -
12
51
00
1.0
0
4/2
2/2
01
9 1
3:3
00
4/2
3/2
01
9 1
2:2
8F
als
e
Germ
aniu
m200.8
0.3
00
CC
M4
8.6
71
99
9ug
/L1
.04
26
91
83
---
---
---
85
- 1
15
97
50
.0
04
/23
/20
19
10
:45
04
/23
/20
19
13
:14
Fals
e
IS-I
ndiu
m200.8
N/A
CC
M0
.93
94
N/A
1.0
42
69
18
3--
---
---
-6
0 -
12
59
41
.0
04
/23
/20
19
10
:45
04
/23
/20
19
13
:14
Fals
e
Manganese
200.8
0.4
00
CC
M4
9.0
88
99
9ug
/L1
.04
26
91
83
---
---
---
85
- 1
15
98
50
.0
04
/23
/20
19
10
:45
04
/23
/20
19
13
:14
Fals
e
IS-S
candiu
m200.8
N/A
CC
M0
.93
82
N/A
1.0
42
69
18
3--
---
---
-6
0 -
12
59
41
.0
04
/23
/20
19
10
:45
04
/23
/20
19
13
:14
Fals
e
IS-Y
ttri
um
200.8
N/A
CC
M0
.92
68
N/A
1.0
42
69
18
3--
---
---
-6
0 -
12
59
31
.0
04
/23
/20
19
10
:45
04
/23
/20
19
13
:14
Tru
e
Germ
aniu
m200.8
0.3
00
FS
0.3
00
ug
/L1
.04
26
10
03
19
03
03
47
-01
-2--
---
---
---
-
<0
4/2
2/2
01
9 1
3:3
00
4/2
3/2
01
9 1
3:2
2T
rue
IS-I
ndiu
m200.8
N/A
FS
0.9
04
9N
/A1
.04
26
10
03
19
03
03
47
-01
-2--
---
-6
0 -
12
59
01
.0
04
/22
/20
19
13
:30
04
/23
/20
19
13
:22
Tru
e
Manganese
200.8
0.4
00
FS
0.4
00
ug
/L1
.04
26
10
03
19
03
03
47
-01
-2--
---
---
---
-
<0
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2/2
01
9 1
3:3
00
4/2
3/2
01
9 1
3:2
2T
rue
IS-S
candiu
m200.8
N/A
FS
0.8
95
1N
/A1
.04
26
10
03
19
03
03
47
-01
-2--
---
-6
0 -
12
59
01
.0
04
/22
/20
19
13
:30
04
/23
/20
19
13
:22
Tru
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IS-Y
ttri
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200.8
N/A
FS
0.8
98
2N
/A1
.04
26
10
03
19
03
03
47
-01
-2--
---
-6
0 -
12
59
01
.0
04
/22
/20
19
13
:30
04
/23
/20
19
13
:22
Fals
e
Germ
aniu
m200.8
0.3
00
CC
H1
93
.00
29
99
ug
/L1
.04
26
91
85
---
---
---
85
- 1
15
97
20
0
04
/23
/20
19
10
:45
04
/23
/20
19
14
:12
Fals
e
IS-I
ndiu
m200.8
N/A
CC
H0
.89
43
N/A
1.0
42
69
18
5--
---
---
-6
0 -
12
58
91
.0
04
/23
/20
19
10
:45
04
/23
/20
19
14
:12
Fals
e
Manganese
200.8
0.4
00
CC
H1
95
.85
3ug
/L1
.04
26
91
85
---
---
---
85
- 1
15
98
20
0
04
/23
/20
19
10
:45
04
/23
/20
19
14
:12
Fals
e
IS-S
candiu
m200.8
N/A
CC
H0
.86
77
N/A
1.0
42
69
18
5--
---
---
-6
0 -
12
58
71
.0
04
/23
/20
19
10
:45
04
/23
/20
19
14
:12
Fals
e
IS-Y
ttri
um
200.8
N/A
CC
H0
.87
15
N/A
1.0
42
69
18
5--
---
---
-6
0 -
12
58
71
.0
04
/23
/20
19
10
:45
04
/23
/20
19
14
:12
Page 2
of
2E
EA
Run I
D 2
58160 /
EE
A R
eport
# 4
49073
Page 12 of 22
D D D
.___.ODD□□ DDDDDDDD DODD□ DODD□ DOD
Eurofins Eaton AnalyticalRun Log
Run ID: 258642 Method: 525.3
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4274113 DN 5253-DN-032119.mth04/29/2019 11:13RW
LRB 4274109 DN 5253-DN-032119.mth04/29/2019 12:27RW
FBL 4274111 DN 5253-DN-032119.mth04/29/2019 13:40RW
FS 4261004 19030347-01-3,4,5 DN 5253-DN-032119.mth04/29/2019 15:30DW
CCM 4274115 DN 5253-DN-032119.mth04/29/2019 22:13RW
QCS 4274182 DN 5253-DN-032119.mth04/29/2019 23:27RW
0.00
Page 1 of 4 EEA Run ID 258642 / EEA Report # 449073
Page 13 of 22
=::: e u rofi n s I Eaton Analytical
QC
Su
mm
ary
Re
po
rt
EE
AID
#R
PD
Un
its
Ta
rge
tA
mo
un
tC
lie
nt
IDM
eth
od
An
aly
teS
am
ple
Typ
eD
ilF
ac
tor
RP
DL
imit
Re
co
ve
ryL
imit
s%
R
eco
ve
ryR
es
ult
Fla
gM
RL
Ex
tra
cte
dA
na
lyze
d
Fals
e
IS-A
cenaphth
ene
-d10
525.3
N/A
CC
L1
42
64
9ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
81
20
75
6
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
IS-C
hry
sene-d
12
525.3
N/A
CC
L2
40
00
8ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
82
02
73
0
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
IS-P
henanth
rene-d
10
525.3
N/A
CC
L2
29
66
5ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
71
95
70
4
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
CC
L1
.11
30
ug
/L1
.04
27
411
3--
---
---
-7
0 -
13
011
11
.0
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
CC
L1
.10
30
ug
/L1
.04
27
411
3--
---
---
-7
0 -
13
011
01
.0
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
SS
-Tri
phenyl
phosp
hate
525.3
N/A
CC
L1
.00
10
ug
/L1
.04
27
411
3--
---
---
-7
0 -
13
01
00
1.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 1
1:1
3F
als
e
Chlo
rpyr
ifos
525.3
0.0
300
CC
L0
.03
3ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
00
.03
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 1
1:1
3F
als
e
Dim
eth
ipin
525.3
0.2
00
CC
L0
.17
1ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
08
60
.2
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
Eth
opro
p525.3
0.0
300
CC
L0
.03
1ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
01
03
0.0
3
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
alp
ha-H
exa
chlo
rocy
clohexa
ne
525.3
0.0
100
CC
L0
.01
2ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
01
20
0.0
1
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
Oxy
fluorf
en
525.3
0.0
500
CC
L0
.07
1ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
01
42
0.0
5
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
cis-
Perm
eth
rin
525.3
0.0
109
CC
L0
.01
2ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
01
22
0.0
09
84
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 1
1:1
3F
als
e
trans-
Perm
eth
rin
525.3
0.0
290
CC
L0
.03
5ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
70
.03
00
4
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
Pro
fenofo
s525.3
0.3
00
CC
L0
.30
5ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
01
02
0.3
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 1
1:1
3F
als
e
Tebuco
nazo
le525.3
0.2
00
CC
L0
.22
7ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
40
.2
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
Tri
bufo
s525.3
0.0
700
CC
L0
.05
8ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
08
30
.07
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 1
1:1
3T
rue
IS-A
cenaphth
ene
-d10
525.3
N/A
LR
B1
42
86
9ug
/L0
.99
42
74
10
9--
---
---
-5
0 -
15
011
81
20
75
6
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
IS-C
hry
sene-d
12
525.3
N/A
LR
B2
31
70
0ug
/L0
.99
42
74
10
9--
---
---
-5
0 -
15
011
42
02
73
0
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
IS-P
henanth
rene-d
10
525.3
N/A
LR
B2
22
62
2ug
/L0
.99
42
74
10
9--
---
---
-5
0 -
15
011
41
95
70
4
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
LR
B0
.81
00
ug
/L0
.99
42
74
10
9--
---
---
-7
0 -
13
08
21
.0
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
LR
B0
.95
30
ug
/L0
.99
42
74
10
9--
---
---
-7
0 -
13
09
61
.0
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
SS
-Tri
phenyl
phosp
hate
525.3
N/A
LR
B0
.89
20
ug
/L0
.99
42
74
10
9--
---
---
-7
0 -
13
09
01
.0
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
Chlo
rpyr
ifos
525.3
0.0
300
LR
B0
.0ug
/L0
.99
42
74
10
9--
---
---
---
---
-
<0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
2:2
7T
rue
Dim
eth
ipin
525.3
0.2
00
LR
B0
.01
6ug
/L0
.99
42
74
10
9--
---
---
---
---
-
<0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
2:2
7T
rue
Eth
opro
p525.3
0.0
300
LR
B0
.0ug
/L0
.99
42
74
10
9--
---
---
---
---
-
<0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
2:2
7T
rue
alp
ha-H
exa
chlo
rocy
clohexa
ne
525.3
0.0
100
LR
B0
.0ug
/L0
.99
42
74
10
9--
---
---
---
---
-
<0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
2:2
7T
rue
Oxy
fluorf
en
525.3
0.0
500
LR
B0
.0ug
/L0
.99
42
74
10
9--
---
---
---
---
-
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01
9 0
6:0
30
4/2
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01
9 1
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7T
rue
cis-
Perm
eth
rin
525.3
0.0
109
LR
B0
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.99
42
74
10
9--
---
---
---
---
-
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9 0
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7T
rue
trans-
Perm
eth
rin
525.3
0.0
290
LR
B0
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42
74
10
9--
---
---
---
---
-
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4/2
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9 0
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7T
rue
Pro
fenofo
s525.3
0.3
00
LR
B0
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42
74
10
9--
---
---
---
---
-
<0
4/2
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01
9 0
6:0
30
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01
9 1
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7T
rue
Tebuco
nazo
le525.3
0.2
00
LR
B0
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.99
42
74
10
9--
---
---
---
---
-
<0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
2:2
7T
rue
Tri
bufo
s525.3
0.0
700
LR
B0
.0ug
/L0
.99
42
74
10
9--
---
---
---
---
-
<0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
2:2
7F
als
e
IS-A
cenaphth
ene
-d10
525.3
N/A
FB
L1
30
20
3ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
01
08
12
07
56
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
IS-C
hry
sene-d
12
525.3
N/A
FB
L2
06
26
8ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
01
02
20
27
30
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
IS-P
henanth
rene-d
10
525.3
N/A
FB
L1
99
92
6ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
01
02
19
57
04
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
FB
L0
.82
30
ug
/L1
.04
27
411
1--
---
---
-7
0 -
13
08
21
.0
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
FB
L0
.94
90
ug
/L1
.04
27
411
1--
---
---
-7
0 -
13
09
51
.0
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
SS
-Tri
phenyl
phosp
hate
525.3
N/A
FB
L0
.92
30
ug
/L1
.04
27
411
1--
---
---
-7
0 -
13
09
21
.0
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
Chlo
rpyr
ifos
525.3
0.0
300
FB
L0
.03
4ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
011
30
.03
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
Dim
eth
ipin
525.3
0.2
00
FB
L0
.13
9ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
07
00
.2
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Page 2
of
4E
EA
Run I
D 2
58642 /
EE
A R
eport
# 4
49073
Page 14 of 22
D D D D
.___.ODD□□ DDDDDDDD DODD□ DODD□ DDDDDDDD
Sa
mp
leTyp
eE
EA
ID #
An
aly
zed
Ex
tra
cte
dR
PD
Un
its
Ta
rge
tA
mo
un
tC
lie
nt
IDM
RL
Me
tho
dA
na
lyte
Dil
Fa
cto
rR
PD
Lim
itR
ec
ove
ryL
imit
s%
R
eco
ve
ryR
es
ult
Fla
g
QC
Su
mm
ary
Rep
ort
(co
nt.
)
Fals
e
Eth
opro
p525.3
0.0
300
FB
L0
.03
4ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
011
30
.03
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
alp
ha-H
exa
chlo
rocy
clohexa
ne
525.3
0.0
100
FB
L0
.011
ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
011
00
.01
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
Oxy
fluorf
en
525.3
0.0
500
FB
L0
.07
2ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
01
44
0.0
5
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
cis-
Perm
eth
rin
525.3
0.0
109
FB
L0
.00
9ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
09
10
.00
98
4
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
trans-
Perm
eth
rin
525.3
0.0
290
FB
L0
.03
1ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
01
03
0.0
30
04
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
Pro
fenofo
s525.3
0.3
00
FB
L0
.29
6ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
09
90
.3
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
Tebuco
nazo
le525.3
0.2
00
FB
L0
.23
6ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
011
80
.2
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
Tri
bufo
s525.3
0.0
700
FB
L0
.06
1ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
08
70
.07
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0T
rue
IS-A
cenaphth
ene
-d10
525.3
N/A
FS
13
48
08
ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
,4,5
---
---
50
- 1
50
112
12
07
56
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
5:3
0T
rue
IS-C
hry
sene-d
12
525.3
N/A
FS
21
73
61
ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
,4,5
---
---
50
- 1
50
10
72
02
73
0
04
/27
/20
19
06
:03
04
/29
/20
19
15
:30
Tru
e
IS-P
henanth
rene-d
10
525.3
N/A
FS
21
51
62
ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
,4,5
---
---
50
- 1
50
110
19
57
04
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
5:3
0T
rue
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
FS
0.7
97
0ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
,4,5
---
---
70
- 1
30
81
1.0
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
5:3
0T
rue
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
FS
0.9
24
0ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
,4,5
---
---
70
- 1
30
94
1.0
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
5:3
0T
rue
SS
-Tri
phenyl
phosp
hate
525.3
N/A
FS
0.9
33
0ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
,4,5
---
---
70
- 1
30
95
1.0
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
5:3
0T
rue
Chlo
rpyr
ifos
525.3
0.0
300
FS
0.0
30
0ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
15
:30
Tru
e
Dim
eth
ipin
525.3
0.2
00
FS
0.2
00
ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
15
:30
Tru
e
Eth
opro
p525.3
0.0
300
FS
0.0
30
0ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
15
:30
Tru
e
alp
ha-H
exa
chlo
rocy
clohexa
ne
525.3
0.0
100
FS
0.0
10
0ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
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---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
15
:30
Tru
e
Oxy
fluorf
en
525.3
0.0
500
FS
0.0
50
0ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
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---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
15
:30
Tru
e
cis-
Perm
eth
rin
525.3
0.0
109
FS
0.0
10
9ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
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---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
15
:30
Tru
e
trans-
Perm
eth
rin
525.3
0.0
290
FS
0.0
29
0ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
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---
---
---
---
<
04
/27
/20
19
06
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04
/29
/20
19
15
:30
Tru
e
Perm
eth
rin, ci
s &
tra
ns
525.3
0.0
400
FS
0.0
40
0ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
15
:30
Tru
e
Pro
fenofo
s525.3
0.3
00
FS
0.3
00
ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
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---
---
---
---
<
04
/27
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19
06
:03
04
/29
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19
15
:30
Tru
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Tebuco
nazo
le525.3
0.2
00
FS
0.2
00
ug
/L0
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42
61
00
41
90
30
34
7-0
1-3
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---
---
---
---
<
04
/27
/20
19
06
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04
/29
/20
19
15
:30
Tru
e
Tri
bufo
s525.3
0.0
700
FS
0.0
70
0ug
/L0
.98
42
61
00
41
90
30
34
7-0
1-3
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---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
15
:30
Fals
e
IS-A
cenaphth
ene
-d10
525.3
N/A
CC
M1
23
69
9ug
/L1
.04
27
411
5--
---
---
-5
0 -
15
01
02
12
07
56
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
IS-C
hry
sene-d
12
525.3
N/A
CC
M1
94
45
0ug
/L1
.04
27
411
5--
---
---
-5
0 -
15
09
62
02
73
0
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
IS-P
henanth
rene-d
10
525.3
N/A
CC
M1
88
63
0ug
/L1
.04
27
411
5--
---
---
-5
0 -
15
09
61
95
70
4
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
CC
M1
.05
50
ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
01
06
1.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
CC
M1
.03
20
ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
01
03
1.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
SS
-Tri
phenyl
phosp
hate
525.3
N/A
CC
M1
.05
50
ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
01
06
1.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
Chlo
rpyr
ifos
525.3
0.0
300
CC
M0
.32
2ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
01
07
0.3
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
Dim
eth
ipin
525.3
0.2
00
CC
M1
.86
7ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
32
.0
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
Eth
opro
p525.3
0.0
300
CC
M0
.28
9ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
60
.3
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
alp
ha-H
exa
chlo
rocy
clohexa
ne
525.3
0.0
100
CC
M0
.09
3ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
30
.1
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
Oxy
fluorf
en
525.3
0.0
500
CC
M0
.56
2ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
011
20
.5
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
cis-
Perm
eth
rin
525.3
0.0
109
CC
M0
.09
5ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
70
.09
84
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
trans-
Perm
eth
rin
525.3
0.0
290
CC
M0
.29
3ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
80
.30
04
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
Pro
fenofo
s525.3
0.3
00
CC
M2
.67
7ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
08
93
.0
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
Tebuco
nazo
le525.3
0.2
00
CC
M1
.94
5ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
72
.0
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
Tri
bufo
s525.3
0.0
700
CC
M0
.65
ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
30
.7
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Page 3
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4E
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Run I
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# 4
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Page 15 of 22
D D D
DD DDDDDDDD DODD□ DODD□ DDDDDDDD DODD
Sa
mp
leTyp
eE
EA
ID #
An
aly
zed
Ex
tra
cte
dR
PD
Un
its
Ta
rge
tA
mo
un
tC
lie
nt
IDM
RL
Me
tho
dA
na
lyte
Dil
Fa
cto
rR
PD
Lim
itR
ec
ove
ryL
imit
s%
R
eco
ve
ryR
es
ult
Fla
g
QC
Su
mm
ary
Rep
ort
(co
nt.
)
Tru
e
IS-A
cenaphth
ene
-d10
525.3
N/A
QC
S1
21
70
7ug
/L1
.04
27
41
82
---
---
---
50
- 1
50
10
11
20
75
6
04
/27
/20
19
06
:10
04
/29
/20
19
23
:27
Tru
e
IS-C
hry
sene-d
12
525.3
N/A
QC
S1
85
64
5ug
/L1
.04
27
41
82
---
---
---
50
- 1
50
92
20
27
30
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
IS-P
henanth
rene-d
10
525.3
N/A
QC
S1
85
42
9ug
/L1
.04
27
41
82
---
---
---
50
- 1
50
95
19
57
04
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
QC
S1
.09
20
ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
10
91
.0
04
/27
/20
19
06
:10
04
/29
/20
19
23
:27
Tru
e
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
QC
S1
.07
20
ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
10
71
.0
04
/27
/20
19
06
:10
04
/29
/20
19
23
:27
Tru
e
SS
-Tri
phenyl
phosp
hate
525.3
N/A
QC
S1
.11
60
ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
112
1.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
Chlo
rpyr
ifos
525.3
0.0
300
QC
S0
.33
9ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
113
0.3
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
Dim
eth
ipin
525.3
0.2
00
QC
S1
.811
ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
91
2.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
Eth
opro
p525.3
0.0
300
QC
S0
.30
7ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
10
20
.3
04
/27
/20
19
06
:10
04
/29
/20
19
23
:27
Tru
e
alp
ha-H
exa
chlo
rocy
clohexa
ne
525.3
0.0
100
QC
S0
.08
6ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
86
0.1
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
Oxy
fluorf
en
525.3
0.0
500
QC
S0
.57
1ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
114
0.5
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
cis-
Perm
eth
rin
525.3
0.0
109
QC
S0
.16
4ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
98
0.1
68
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
trans-
Perm
eth
rin
525.3
0.0
290
QC
S0
.23
7ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
10
20
.23
2
04
/27
/20
19
06
:10
04
/29
/20
19
23
:27
Tru
e
Pro
fenofo
s525.3
0.3
00
QC
S2
.76
4ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
92
3.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
Tebuco
nazo
le525.3
0.2
00
QC
S2
.011
ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
10
12
.0
04
/27
/20
19
06
:10
04
/29
/20
19
23
:27
Tru
e
Tri
bufo
s525.3
0.0
700
QC
S0
.79
2ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
113
0.7
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7
Page 4
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4E
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Run I
D 2
58642 /
EE
A R
eport
# 4
49073
Page 16 of 22
D
._....___. __ DDDDDDDD DD
Eurofins Eaton AnalyticalRun Log
Run ID: 258385 Method: 530
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4272750 FV M 530 UCMR4 0228201904/26/2019 22:04RW
LRB 4272748 FV M 530 UCMR4 0228201904/26/2019 22:57RW
FBL 4272749 FV M 530 UCMR4 0228201904/26/2019 23:55RW
FS 4261005 19030347-01-6,7,8 FV M 530 UCMR4 0228201904/27/2019 03:01DW
CCM 4272751 FV M 530 UCMR4 0228201904/27/2019 06:32RW
0.00
Page 1 of 2 EEA Run ID 258385 / EEA Report # 449073
Page 17 of 22
=::: e u rofi n s I Eaton Analytical
QC
Su
mm
ary
Re
po
rt
EE
AID
#R
PD
Un
its
Ta
rge
tA
mo
un
tC
lie
nt
IDM
eth
od
An
aly
teS
am
ple
Typ
eD
ilF
ac
tor
RP
DL
imit
Re
co
ve
ryL
imit
s%
R
eco
ve
ryR
es
ult
Fla
gM
RL
Ex
tra
cte
dA
na
lyze
d
Tru
e
IS-A
cenaphth
ene
-d10
530
N/A
CC
L3
66
93
4ug
/L1
.04
27
27
50
---
---
---
50
- 1
50
79
46
40
60
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
2:0
4T
rue
IS-P
henanth
rene-d
10
530
N/A
CC
L5
91
74
4ug
/L1
.04
27
27
50
---
---
---
50
- 1
50
85
69
51
49
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
2:0
4T
rue
SS
-Quin
olin
e-d
7530
N/A
CC
L0
.52
22
ug
/L1
.04
27
27
50
---
---
---
70
- 1
30
10
40
.5
04
/26
/20
19
08
:13
04
/26
/20
19
22
:04
Tru
e
SS
-o-T
olu
idin
e-d
9530
N/A
CC
L0
.51
67
ug
/L1
.04
27
27
50
---
---
---
50
- 1
30
10
30
.5
04
/26
/20
19
08
:13
04
/26
/20
19
22
:04
Tru
e
Buty
late
d h
ydro
xyanis
ole
530
0.0
300
CC
L0
.03
48
ug
/L1
.04
27
27
50
---
---
---
50
- 1
50
116
0.0
29
99
9
04
/26
/20
19
08
:13
04
/26
/20
19
22
:04
Tru
e
Quin
olin
e530
0.0
200
CC
L0
.02
34
ug
/L1
.04
27
27
50
---
---
---
50
- 1
50
117
0.0
19
99
9
04
/26
/20
19
08
:13
04
/26
/20
19
22
:04
Tru
e
o-T
olu
idin
e530
0.0
0700
CC
L0
.00
94
ug
/L1
.04
27
27
50
---
---
---
50
- 1
50
13
40
.00
7
04
/26
/20
19
08
:13
04
/26
/20
19
22
:04
Fals
e
IS-A
cenaphth
ene
-d10
530
N/A
LR
B3
74
14
8ug
/L1
.01
42
72
74
8--
---
---
-5
0 -
15
08
14
64
06
0
04
/26
/20
19
08
:13
04
/26
/20
19
22
:57
Fals
e
IS-P
henanth
rene-d
10
530
N/A
LR
B6
12
86
7ug
/L1
.01
42
72
74
8--
---
---
-5
0 -
15
08
86
95
14
9
04
/26
/20
19
08
:13
04
/26
/20
19
22
:57
Fals
e
SS
-Quin
olin
e-d
7530
N/A
LR
B0
.42
27
ug
/L1
.01
42
72
74
8--
---
---
-7
0 -
13
08
40
.5
04
/26
/20
19
08
:13
04
/26
/20
19
22
:57
Fals
e
SS
-o-T
olu
idin
e-d
9530
N/A
LR
B0
.40
75
ug
/L1
.01
42
72
74
8--
---
---
-5
0 -
13
08
10
.5
04
/26
/20
19
08
:13
04
/26
/20
19
22
:57
Fals
e
Buty
late
d h
ydro
xyanis
ole
530
0.0
300
LR
B0
.0ug
/L1
.01
42
72
74
8--
---
---
---
---
-
<0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
2:5
7F
als
e
Quin
olin
e530
0.0
200
LR
B0
.00
62
ug
/L1
.01
42
72
74
8--
---
---
---
---
-
<0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
2:5
7F
als
e
o-T
olu
idin
e530
0.0
0700
LR
B0
.00
03
ug
/L1
.01
42
72
74
8--
---
---
---
---
-
<0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
2:5
7T
rue
IS-A
cenaphth
ene
-d10
530
N/A
FB
L3
48
03
2ug
/L1
.04
27
27
49
---
---
---
50
- 1
50
75
46
40
60
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5T
rue
IS-P
henanth
rene-d
10
530
N/A
FB
L5
67
42
6ug
/L1
.04
27
27
49
---
---
---
50
- 1
50
82
69
51
49
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5T
rue
SS
-Quin
olin
e-d
7530
N/A
FB
L0
.42
82
ug
/L1
.04
27
27
49
---
---
---
70
- 1
30
86
0.5
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5T
rue
SS
-o-T
olu
idin
e-d
9530
N/A
FB
L0
.39
41
ug
/L1
.04
27
27
49
---
---
---
50
- 1
30
79
0.5
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5T
rue
Buty
late
d h
ydro
xyanis
ole
530
0.0
300
FB
L0
.02
74
ug
/L1
.04
27
27
49
---
---
---
50
- 1
50
91
0.0
29
99
9
04
/26
/20
19
08
:13
04
/26
/20
19
23
:55
Tru
e
Quin
olin
e530
0.0
200
FB
L0
.02
02
ug
/L1
.04
27
27
49
---
---
---
50
- 1
50
10
10
.01
99
99
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5T
rue
o-T
olu
idin
e530
0.0
0700
FB
L0
.00
78
ug
/L1
.04
27
27
49
---
---
---
50
- 1
50
111
0.0
07
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5F
als
e
IS-A
cenaphth
ene
-d10
530
N/A
FS
30
47
60
ug
/L0
.98
42
61
00
51
90
30
34
7-0
1-6
,7,8
---
---
50
- 1
50
66
46
40
60
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
3:0
1F
als
e
IS-P
henanth
rene-d
10
530
N/A
FS
48
71
34
ug
/L0
.98
42
61
00
51
90
30
34
7-0
1-6
,7,8
---
---
50
- 1
50
70
69
51
49
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
3:0
1F
als
e
SS
-Quin
olin
e-d
7530
N/A
FS
0.4
22
9ug
/L0
.98
42
61
00
51
90
30
34
7-0
1-6
,7,8
---
---
70
- 1
30
86
0.5
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
3:0
1F
als
e
SS
-o-T
olu
idin
e-d
9530
N/A
FS
0.3
88
3ug
/L0
.98
42
61
00
51
90
30
34
7-0
1-6
,7,8
---
---
50
- 1
30
79
0.5
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
3:0
1F
als
e
Buty
late
d h
ydro
xyanis
ole
530
0.0
300
FS
0.0
30
0ug
/L0
.98
42
61
00
51
90
30
34
7-0
1-6
,7,8
---
---
---
---
<
04
/26
/20
19
08
:13
04
/27
/20
19
03
:01
Fals
e
Quin
olin
e530
0.0
200
FS
0.0
20
0ug
/L0
.98
42
61
00
51
90
30
34
7-0
1-6
,7,8
---
---
---
---
<
04
/26
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:13
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:01
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:13
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/20
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/27
/20
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:32
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.17
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- 1
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/20
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:13
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/27
/20
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:32
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70
- 1
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111
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7
04
/26
/20
19
08
:13
04
/27
/20
19
06
:32
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D D D
-------------□□□DD DDDDDDDD DODD□ DODD□ DD
Eurofins Eaton AnalyticalRun Log
Run ID: 258986 Method: 541
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4282885 FN M 541 UCMR4 0317201905/09/2019 16:20OS
LRB 4282838 FN M 541 UCMR4 0317201905/09/2019 17:36RW
FBL 4282840 FN M 541 UCMR4 0317201905/09/2019 18:51RW
FS 4261006 19030347-01-9,10,11 FN M 541 UCMR4 0317201905/09/2019 23:32DW
CCM 4282887 FN M 541 UCMR4 0317201905/10/2019 03:01OS
0.00
Page 1 of 2 EEA Run ID 258986 / EEA Report # 449073
Page 19 of 22
=::: e u rofi n s I Eaton Analytical
QC
Su
mm
ary
Re
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:04
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:20
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85
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50
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.5
05
/07
/20
19
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05
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62
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50
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86
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/20
19
17
:36
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-1-B
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541
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.68
00
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.04
28
28
38
---
---
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70
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87
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05
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/20
19
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/20
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50
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70
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90
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1
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Page 20 of 22
D D
-------------□□□DD DDDDDDDD DODD□
Sa
mp
le T
yp
e K
ey
Typ
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Ab
br.
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am
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CC
HC
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alib
ratio
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igh
CC
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alib
ratio
n L
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CC
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alib
ratio
n M
id
DF
BL
DF
B L
ow
FS
Fie
ld S
am
ple
FB
LF
ort
ifie
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lank L
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BLabora
tory
Dig
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lank
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BLabora
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ontr
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am
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1.0
0
Page 21 of 22
END OF REPORT
Page 22 of 22
LABORATORY REPORT
This report may not be reproduced, except in full, without written approval from EEA.
If you have any questions concerning this report, please do not hesitate to call us at (800) 332-4345 or (574) 233-4777.
Page 1 of 22
=::: e u ro fi n s I Eaton Analytical
Revision date: 03/14/2019
STATE CERTIFICATION LIST
State Certification State Certification Alabama 40700 Missouri 880 Alaska IN00035 Montana CERT0026 Arizona AZ0432 Nebraska NE-OS-05-04
Arkansas IN00035 Nevada IN00035 California 2920 New Hampshire* 2124 Colorado IN00035 New Jersey* IN598
Colorado Radiochemistry IN00035 New Mexico IN00035 Connecticut PH-0132 New York* 11398 Delaware IN035 North Carolina 18700 Florida* E87775 North Dakota R-035 Georgia 929 Ohio 87775 Hawaii IN035 Oklahoma D9508 Idaho IN00035 Oregon (Primary AB)* 4074
Illinois* 200001 Pennsylvania* 68-00466 Illinois Microbiology 17767 Puerto Rico IN00035
Illinois Radiochemistry IN00035 Rhode Island LAO00343 Indiana Chemistry C-71-01 South Carolina 95005
Indiana Microbiology M-76-07 South Dakota IN00035 Iowa 098 Tennessee TN02973
Kansas* E-10233 Texas* T104704187-18-12 Kentucky 90056 Texas/TCEQ TX207
Louisiana* LA014 Utah* IN00035 Maine IN00035 Vermont VT-8775
Maryland 209 Virginia* 460275 Massachusetts M-IN035 Washington C837
Michigan 9926 West Virginia 9927 C Minnesota* 018-999-338 Wisconsin 999766900 Mississippi IN035 Wyoming IN035
EPA IN00035 *NELAP/TNI Recognized Accreditation Bodies
Page 2 of 22
~:: eu rofi ns I Eaton Analytical
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449080
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00001
0787001
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261025 19030347-02-2 200.8 04/15/19 12:13 Client 04/16/19 10:00
4261026 19030347-02-3,4,5 525.3 04/15/19 12:13 Client 04/16/19 10:00
4261027 19030347-02-6,7,8 530 04/15/19 12:13 Client 04/16/19 10:00
4261028 19030347-02-9,10,11 541 04/15/19 12:13 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449080
Authorized Signature Title Date
05/10/2019
Page 1 of 2
Page 3 of 22
=:~ eurofins I Eaton Analytical
§
Analytical Services Manager
Client Name: Report #: 449080Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL62907870787001
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
1053 Germanium 200.8 0.300 < 0.300 ug/L 04/22/19 13:30 04/23/19 13:47 4261025
1032 Manganese 200.8 0.400 1.24 ug/L 04/22/19 13:30 04/23/19 13:47 4261025
2115 alpha-Hexachlorocyclohexane 525.3 0.0100 < 0.0100 ug/L 04/27/19 06:03 04/29/19 20:23 4261026
2057 Chlorpyrifos 525.3 0.0300 < 0.0300 ug/L 04/27/19 06:03 04/29/19 20:23 4261026
2116 Dimethipin 525.3 0.200 < 0.200 ug/L 04/27/19 06:03 04/29/19 20:23 4261026
7570 Ethoprop 525.3 0.0300 < 0.0300 ug/L 04/27/19 06:03 04/29/19 20:23 4261026
2117 Oxyfluorfen 525.3 0.0500 < 0.0500 ug/L 04/27/19 06:03 04/29/19 20:23 4261026
2118 Profenofos 525.3 0.300 < 0.300 ug/L 04/27/19 06:03 04/29/19 20:23 4261026
2119 Tebuconazole 525.3 0.200 < 0.200 ug/L 04/27/19 06:03 04/29/19 20:23 4261026
2114 Permethrin, cis & trans 525.3 0.0400 < 0.0400 ug/L 04/27/19 06:03 04/29/19 20:23 4261026
2120 Tribufos 525.3 0.0700 < 0.0700 ug/L 04/27/19 06:03 04/29/19 20:23 4261026
2433 Butylated hydroxyanisole 530 0.0300 < 0.0300 ug/L 04/26/19 08:13 04/27/19 06:06 4261027
2434 o-Toluidine 530 0.00700 < 0.00700 ug/L 04/26/19 08:13 04/27/19 06:06 4261027
3435 Quinoline 530 0.0200 < 0.0200 ug/L 04/26/19 08:13 04/27/19 06:06 4261027
2084 1-Butanol 541 2.00 < 2.00 ug/L 05/07/19 07:00 05/10/19 01:53 4261028
2431 2-Methoxyethanol 541 0.400 < 0.400 ug/L 05/07/19 07:00 05/10/19 01:53 4261028
2432 2-Propen-1-ol 541 0.500 < 0.500 ug/L 05/07/19 07:00 05/10/19 01:53 4261028
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 4 of 22
Lab Definitions
Continuing Calibration Check Standard (CCC) / Continuing Calibration Verification (CCV) / Initial Calibration Verification Standard (ICV) / Initial Performance Check (IPC) - is a standard containing one or more of the target analytes that is prepared from the same standards used to calibrate the instrument. This standard is used to verify the calibration curve at the beginning of each analytical sequence, and may also be analyzed throughout and at the end of the sequence. The concentration of continuing standards may be varied, when prescribed by the reference method, so that the range of the calibration curve is verified on a regular basis. CCL, CCM, and CCH are the CCC standards at low, mid, and high concentration levels, respectively.
Internal Standards (IS) - are pure compounds with properties similar to the analytes of interest, which are added to field samples or extracts, calibration standards, and quality control standards at a known concentration. They are used to measure the relative responses of the analytes of interest and surrogates in the sample, calibration standard or quality control standard.
Laboratory Duplicate (LD) - is a field sample aliquot taken from the same sample container in the laboratory and analyzed separately using identical procedures. Analysis of laboratory duplicates provides a measure of the precision of the laboratory procedures.
Laboratory Fortified Blank (LFB) / Laboratory Control Sample (LCS) - is an aliquot of reagent water to which known concentrations of the analytes of interest are added. The LFB is analyzed exactly the same as the field samples. LFBs are used to determine whether the method is in control. FBL, FBM, and FBH are the LFB samples at low, mid, and high concentration levels, respectively.
Laboratory Method Blank (LMB) / Laboratory Reagent Blank (LRB) - is a sample of reagent water included in the sample batch analyzed in the same way as the associated field samples. The LMB is used to determine if method analytes or other background contamination have been introduced during the preparation or analytical procedure. The LMB is analyzed exactly the same as the field samples.
Laboratory Trip Blank (LTB) / Field Reagent Blank (FRB) - is a sample of laboratory reagent water placed in a sample container in the laboratory and treated as a field sample, including storage, preservation, and all analytical procedures. The FRB/LTB container follows the collection bottles to and from the collection site, but the FRB/LTB is not opened at any time during the trip. The FRB/LTB is primarily a travel blank used to verify that the samples were not contaminated during shipment.
Matrix Spike Duplicate Sample (MSD) / Laboratory Fortified Sample Matrix Duplicate (LFSMD) - is a sample aliquot taken from the same field sample source as the Matrix Spike Sample to which known quantities of the analytes of interest are added in the laboratory. The MSD is analyzed exactly the same as the field samples. Analysis of the MSD provides a measure of the precision of the laboratory procedures in a specific matrix. SDL, SDM, and SDH / LFSMDL, LFSMDM, and LFSMDH are the MSD or LFSMD at low, mid, and high concentration levels, respectively.
Matrix Spike Sample (MS) / Laboratory Fortified Sample Matrix (LFSM) - is a sample aliquot taken from field sample source to which known quantities of the analytes of interest are added in the laboratory. The MS is analyzed exactly the same as the field samples. The purpose is to demonstrate recovery of the analytes from a sample matrix to determine if the specific matrix contributes bias to the analytical results. MSL, MSM, and MSH / LFSML, LFSMM, and LFSMH are the MS or LFSM at low, mid, and high concentration levels, respectively.
Quality Control Standard (QCS) / Second Source Calibration Verification (SSCV) - is a solution containing known concentrations of the analytes of interest prepared from a source different from the source of the calibration standards. The solution is obtained from a second manufacturer or lot if the lot can be demonstrated by the manufacturer as prepared independently from other lots. The QCS sample is analyzed using the same procedures as field samples. The QCS is used as a check on the calibration standards used in the method on a routine basis.
Reporting Limit Check (RLC) / Initial Calibration Check Standard (ICCS) - is a procedural standard that is analyzed each day to evaluate instrument performance at or below the minimum reporting limit (MRL).
Surrogate Standard (SS) / Surrogate Analyte (SUR) - is a pure compound with properties similar to the analytes of interest, which is highly unlikely to be found in any field sample, that is added to the field samples, calibration standards, blanks and quality control standards before sample preparation. The SS is used to evaluate the efficiency of the sample preparation process.
Page 1 of 1
Page 5 of 22
Page 6 of 22
• eurofins Order d~f:X~b -: .. 110 S. Hi ll Street South Bend, IN 46617
Eaton Analytical T: 1.800.332.4345
Batch# 44-qo&) F: 1.574.233.8207
www EurofinsUS,com/Eaton UCMR 4 CHAIN OF CUSTODY RECORD Pago_of __
Shaded area for EEA use onlv CLIENT NAME: SAMPLER (Print name) - *PWS ID # STATE of sample origin Check if this is a resample D
Check if requlros upload to EPA database D Example: IN1234567 we must havo Info for fiolds indicated with• for
PO#: If samples are not shipped the same day as collection then the temperature upload
Bill To: the samples were held at must be recorded here("C):
*Sampling Event
List 1 AddtionaJs SEA 1 SEA2 Preservative 1/) er:
Sampling Evont # ___ SEAJ SEM: SEH1 SEH2 SEHJ Checks w z
SEH4 (Me~below) ~
*FACILITY ID: (per EPA *Sampl ing z COLLECTION *SAMPLE POINT ID: (per EPA Temperature Upon 0
LAB Number Requirement)-5 Point Type Test Name UCMR4- pH Residual 0
Requirement)-20 characters max Lab Receipt •c accop- Chlorine ~ DATE TIME AM PM characters max Code 1ablo? i IP/A\ .. 1 47 ( n \ h7~ i 4l1•d1,· 1'7. '. l~ i-.... 1Cl0~h~41 ~07 - '2- 200.8 Metals n.o " NA 1
2 \ n ·71n _i). l1o2...r-;2,L/ 1 ~rrJ - ·; L\ ~,_ 525.3 1.u ✓ A 3
3 \ nz,, I I 1 O~o3LJ 'l - n 7 - (Q 1 9 530 3.4 ✓ A 3
I 072-J (C, o.'~0'2,4, -o? - q IO 11 () ~ ✓ A 4 \1/ ,~ V \V 541 3
5
6
7
8 11 ln-:1- ,.J r-1 l'\r \A -:le nrit ~inned at I 1u11-.... ..... - -
..-1 h"" hH r.liont 9 ,, - - : - ,_ -nc; 11 IYl I,._; "· "" ..., J -J - - -
10
11
RELINQUISHED BY:(Signature) DATE TIME RECEIVED BY:(Signature) DATE TIME LAB COMMENTS k?ott-\.t \ \ 01 tV\'\-, LOG * )\\ \ it'\tD -\-Cl~ fro'M
AM I PM AMI PM RELINQUISHED BY:(Signature) DATE TIME RECEIVED BY:(Signature) DATE TIME
AM I PM AM I PM CONDITIONS UPON RECEIP~: WetPBlue Check if received on day of collection: D RELINQUISHED BY:(Signature) DATE TIME
r l?E:TORY BY DATE TIME Samples received within 48 hoJrs of collection must be received at a temperature of s 1 o•c.
-1 /1lf / /' coo Samples received past 48 hours of collection are only valid if received at s 6°C, verified and documented that the samples were refrigerated between collection and shipment. Temperature requirements apply to
AM PM AM I PM all methods EXCEPT 200.8 and 300.0. KEY UCMR4 acceptance criteria for Receiving Checks: *Sampling Point Type Code:
A See Metal Samples Preservation 200.8 pH < 2 541 pH < 3 SR = source water taken from plant intake; untrealed water entering the water treatment plant Log 525.3 pH s 4 544 pH 6.5-7.5 EP = entry point to the distribution system P = Present 530 pH about 7 (6-8) TOC pH< 2 OS = distribution system sample A= Absent Musi be absent of residual chlorine(free): 525.3, 530. 541 . 544, 545. 546. and 552.3.
Note in Comments section any samples ..tllch do nol meet acceptance criteria. 06-LO-F0912 Issue: 5.0 Effective Date: 2018-01-18
Sample analysis will be provided according to the standard EENWater Services Terms . ..tiich are available upon request. Any other terms proposed by Customer are deemed material alterations and are rejected unless expressly agree to in writing by EEA.
Page 7 of 22
...------------ S_u_b_c_on_t_ra_c_te_,d Chain of Custod;vrt;½ I II I 111111111111111~ Ill Hillsborough
County r:1orida Public Utilities
Sample ID: Customer: PWS#
19030347--01-10 South Central CWS 6290787
Address: 9460 E Columbus Or .... ,-,--··· ... ---··
Collector: (Environmental Specialist I) Title:
1903034 7--01-11 South Central CWS 6290787
Address: 9460 E Columbus Or -·-,--.. , ... --·· Collector: (Environmental Specialist I) Title:
19030347--01-2 South Central CWS 6290787
Address: 9460 E Columbus Or
Collector. -·-,--··· ___ .. ., (Environmental Specialist I) Title·
19030347--01-3 South Central CWS 6290787
Address· 9460 E Columbus Or
Collector (En;ironmental Specialist I) Title.
19030347--01-4 South Central CWS 6290787
Address. 9460 E Columbus Or
Collector (En;lronmental Specialist I) Trt!e:
19030347--01-5 South Central CWS 6290787
Address: 9460 E Columbus Or -·-,--.. , ............ Collector (Environmental Specialist I) Title.
19030347--01-6 South Central CWS 6290787
Address 9460 E Columbus Dr -·-,--··· ---·· Collector (Environmental Specialist I) Trt!e:
19030347--01-7 South Central CWS 6290787
Address· 9460 E Columbus Dt -·-,--.. , .. - -·· Collector (Environmental Specialist I) Trt!e
19030347-01-8 South Central CWS 6290787
Address 9460 E Columbus Dr -·-,--··· ----·· Collector (Environmental Specialist I) Trtle
RPnnr1 r. .. n .. ,,.1 .. ri · n4/ 1 'i/?n1Q 14·!','>,
Environmental L a bo ra tory
9456 E Columbus Dr Tampa, FL 33619
Certification Number: E44104
P hone N o . (813) 272-5977 x 43635
Work Order: 19030347
Scheduled Sample SC - UCMR4 SV Set Name:
Subcontracted Vendor: E u rofins E aton Analytical ~-------LLC
Sample Information
Customer: South Central CWS
Project: SC • UCMR4-SV
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile#
Site: Collect~ i;wemme: Sample Type: Container Type: Preservative: Analysis Method: Analytes:
CHWTP- ~ tart: 4/15/2019 8:22:00 AM Drinking Water Glass 125 ml Amber Sulfite + Bisulfate 001 End: 4/15/2019 8:22:00 AM (Grab)
Environmental Specialist I
CHWTP- Siert: 4/15/2019 8:22:00 AM Drinking Water Glass 125 ml Amber Sulfite + Bisulfate 001 End: 4/15/2019 8:22:00 AM (Grab)
Environmental Specialist I
CHWTP- Start: 4/15/2019 8:22:00 AM Drinking Water Plastic 250 ml None 200 8 • UCMR Metals Subcontracted 001 End: 4/15/2019 8:22:00 AM (Grab)
Environmental Specialist I
CHWTP· Start: 4/15/2019 8:22:00 AM Drinking Water Glass 1 l Amber M+EDTA+K- 525.3 • UCMR Lisi Subcontracted 001 End: 4/15/201 9 8:22:00 AM (Grab) dihydrogen citrate
Environmental Specialist I
CHWTP- Start: 4/15/2019 8:22:00 AM Drinking Water Glass 1 l Amber M+EDTA+K-001 End: 4/15/2019 8:22:00 AM (Grab) dihydrogen citrate
Environmental Specialist I
CHWTP- Sten: 4/1512019 8:22:00 AM Drinking Water Glass 1 L Amber M+ EDTA+K-001
End: 4/15/2019 8:22:00 AM (Grab) dihydrogen citrate
Environmental Specialist I
CHWTP- Start: 4/15/2019 8:22:00 AM Drinking Water Glass 1 l Amber Trizina +AA+ EDTA + 530 • UCMR Semlvolatiles Subcontracted 001 End: 4/15/2019 8:22:00 AM <<eoPY dUrea
Environmental Specialist I
CHWTP- Start: 4/15/2019 8:22:00 AM Drinking Water Glass 1 l Amber Trtzma + AA + EDTA • 001 End: 4/15/2019 8:22:00 AM (Grab) dUrea
Environmental Specialist i
CHWTP- Stan: 4/15/2019 8:22:00 AM Drinking Water Glass 1 L Amber Trizina +AA + EDTA + 001 End: 4/15/2019 8 22·00 AM (Grab) dUrea
Environmental Specialist I
P""" 1 nf,
Page 8 of 22
Subcontracted Chain of Custody ...-----------------, ,----------=-----------~ --- II I I II I 11 1111111 111111 Hillsborough County r-•orida
Environmental Laboratory Customer: South Central CWS
Public Utilities
Sample ID: Customer: PWS#
19030347-01-9 South Central CWS 6290787
Address: 9460 E Columbus Or -·-,--, .... ---·· Collector: (Environmental Specialist I) TiUe:
19030347-02-10 South Central CWS 6290787
Address: 5402 I.Jthia Pinecrest Rd -·-,--··· ----·· Collector: (Environmental Specialist I) Tille:
1903034 7-02-11 South Central CWS 6290787
Address. 5402 Lithia Pinecrest Rd -·-,--··· ----·· Collector (Environmental Specialist I) TiUe
1903034 7-02-2 South Central CWS 6290787
Address: 5402 I.Jthia Pinecrest Rd - ·-, ........ , .. .......... Collector (Environmental Specialist I) TiUe.
1903034 7-02-3 South Central CWS 6290787
Address· 5402 Lithia Pinecrest Rd -·-,--··· ---·· Collector (Environmental Specialist I) TIiie
19030347-02-4 South Central CWS 6290787
Address 5402 I.Jthia P1necn,sl Rd
Collector (En;lronmental Specialist I) TIUe:
1903034 7-02-5 South Central CWS 6290787
Address: 5402 Lithia Pinecrest Rd -·-,---.. , ----·· Collector (Environmental Specialist I) TIiie:
19030347-02-6 South Central CWS 6290787
Address· 5402 Lithia Pinecrest Rd -·-,--.. , ... ---·· Collector (Environmental Specialist I) rllle.
19030347•02•7 South Central CWS 6290787
Address 5402 Lithia Pinecrest Rd -·-,---··· ----·· Collector (Environmental Specialist I ) TIiie
R<>nnrt r,<>n<>r::l!Prl · 04/1!'i/?01Q 14·!'>~
9456 E Columbus Dr Tampa, FL 33619
Certification Number: E44104
Phone No. (813) 272-5977 x 43635
Work Order: 19030347
Scheduled Sample SC • UCMR4 SV Set Name:
Subcontracted Vendor. Eurofins Eaton Analytical L--- -----LLC
Project: SC • UCMR4-SV
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (81 3) 272-5977 x 43635
Profile#
Sample Information Site: Collection Date/Time:
CHWTP· Stan: 4/15/2019 8:22:00 AM
OOl _ rfl'~ 4/15/2019 8:22:00 AM
Environme~ criilist I
LIWTP--002 Stan: 4/15/2019 12·13·00 PM
End: 4/15/2019 12 13:00 PM
Environmental Specialist I
LIWTP-002 Stan: 4/1 5/2019 12 13:00 PM
End: 4/15/2019 12:13:00 PM
Environmental Specialist I
LIWTP-002 Stan: 4/15/2019 12:13:00 PM
End: 4/15/2019 12:13:00 PM
Environmental Specialist I
Sample Type:
Drinking Water
(Grab)
Drinking Waler
(Grab)
Drinking Water
(Grab)
Drinking Water
(Grab)
LIWTP.002 Stan: 4/15/2019 12:13:00 PM Drinking Water
End· 4/15/2019 12:13·00 PM (Grab)
Environmental Specialis1 I
LIWTP--002 Sten: 4115/2019 12 13.00 PM Drinking Water
End· 4/15/2019 12 13·00 PM (Grab)
Environmental Specialist I
LIWTP--002 Stan. 4/15/2019 12 13:00 PM Dnnklng Water
End: 4/15/2019 12:13·00 PM (Grab)
Environmental Specialist I
LIWTP-002 Stan: 4/15/2019 12:13:00 PM Dnnkong Water
End: 4/15/2019 12 13·00 PM (Grab) Environmental Specialist I
LIWTP-002 Stan: 4115/2019 12 13:00 PM Drinking Water
End 4/15/2019 12 13·00 PM (Grab)
Environmental Specialist I
Container Type:
Glass 125 ml Amber
Glass 125 mL Amber
Glass 125 ml Amber
Plastic 250 ml
c at') t A1ber
Glass 1 L Amber
Glass 1 l Amber
Glass 1 l Amber
Glass 1 L Amber
Preservative:
Sulfite + Bisulfate
Sulfite + B1sullate
Sulfite + B1sulfale
None
AA+ EDTA + K· dihydrogen citrate
AA + EDTA+ Kdihydrogen citrate
AA+ EDTA+ K· dihydrogen citrate
Analysis Method:
541 • UCMR Alcohols Subcontracted
200.8 • UCMR Metals Subcontracted
525.3 • UCMR List Subcontracted
Trizma +AA+ EDTA + 530 • UCMR Semivolatiles Subcontracted dUrea
Trizma + AA + EDTA • dUrea
Analytes:
P::1n<>? nl ~
Page 9 of 22
Subcontracted Chain of Custody ~-------- ------~ ~---_.::;_ ____ ______ _
Sample ID:
1903034 7-02-8
Address:
Collector.
19030347-02-9
Address:
Collector-
Reli"lqu lShed By:
Rennqui,hed By:
Relinquished By
Hillsborough County t-'lorida Public Utilities
Environmental Laboratory
9456 E Columbus Dr Tampa, FL 33619
Certification Number: E44104
Phone No. (813) 272-5977 x 43635
II I I II I 111111111111111 Work Order: 19030347
Scheduled Sample SC • UCMR4 SV Set Name:
Subcontracted Vendor: Eurofios Eaton Analytical L--------LLC
Customer: South Central CWS
Project: SC - UCMR4-SV
Contact: Stanley, John (Chief Environmental Scientist)
Phone. (813) 272-5977 x 43635
Profile#
Sample Information Customer: PWS# Site: Collection Date/Time: Sample Type: Container Type: Preservative: Analysis Method: Analytes:
South Central CWS 6290787 LIWTP-002 Start: 4/1512019 12:13:00 PM Drinking Water Glass 1 L Amber Trizma + AA+ EDTA + 5402 Lithia Pinecrest Rd End: 4/1512019 12:13:00 PM (Grab) dUrea _, ... , ....... , ..... .,._ .. (Environmental Specialist I) nue: Environmental Specialist I
South Central CWS 6290787 LIWTP-002 Start: 4/1 5/20t~? 1' Drinking Water Glass 125 ml Amber Sulfite + Bisulfate 541 • UCMR Alcohols Subcontracied 5402 Lithia Pinecrest Rd End: 4/15/201 2: 3:00 PM (Grab) (En~ironmental Specialist I) nue· Environmental Specialist I
I I I I H/ II Oe/.etrmr IS"-0 Accepted By~ Date/Time: 11 Notes
D:oO rV Y'--.: -~.ioh.. ' Accepted By Date/Time
D1te/Time AccepladBy: Date!T•me
Ro> nnr1 no>nPr::OtPrl ' 0<1/1t:;/?01Q 1d· t:;:>, P::.nP, nf,
1
Jessie Brasch
Subject: FW: Incoming April 2019 UCMR4 sampling
From: Stanley, John [mailto:[email protected]] Sent: Tuesday, April 16, 2019 8:44 AM To: Jessie Brasch Cc: Watson, Edward Subject: Incoming April 2019 UCMR4 sampling
EXTERNAL EMAIL*
Hello Jessie, We sampled our April 2019 UCMR4 yesterday and they should arrive in South Bend today (UPS Tracking Numbers: J4634795594, J4634795601, J4634795610) Here is the information cross reference:
HCPUD Sample ID EPA Sample point ID Facility ID SP Type Sample Point Name
19030346‐01 SC1 00004 DS SC1 1309 Windjammer Place
19030346‐02 SC2 00004 DS SC2 415 Smithfield Lane
19030346‐03 SC3 00004 DS SC3 1107 S. Lenna Ave
19030346‐04 SC4 00004 DS SC4 113 Holly Lane
19030346‐05 SC5 00004 DS SC5 6912 Ohio Ave
19030346‐06 SC6 00004 DS SC6 807 4th Ave SW
19030346‐07 SC7 00004 DS SC7 10130 Harney Rd.
19030346‐08 SC8 00004 DS SC8 336 Brandywine
19030346‐09 SC9 00004 DS SC9 6110 Nundy Ave
19030346‐10 SC10 00004 DS SC10 11843 Whisper Creek Dr
19030346‐11 SC11 00004 DS SC11 12121 Colonial Estates
19030346‐12 SC12 00004 DS SC12 1534 Del Webb Ave
19030347‐01 0787002 00002 EP Central WTP POE
19030347‐02 0787001 00001 EP Lithia WTP POE
Let me know if you need any other information. Regards,
John K. Stanley Chief Environmental Scientist Public Utilities: Environmental Services Division ‐ Environmental Laboratory
Page 10 of 22
Eurofins Eaton AnalyticalRun Log
Run ID: 258160 Method: 200.8
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4269180 DS 04/23/2019 12:07RW
QCS 4269182 DS 04/23/2019 12:15RW
DFBL 4268504 DS 04/23/2019 12:23RW
LDB 4268501 DS 04/23/2019 12:28RW
CCM 4269183 DS 04/23/2019 13:14RW
FS 4261025 19030347-02-2 DS 04/23/2019 13:47DW
CCH 4269185 DS 04/23/2019 14:12RW
0.00
Page 1 of 2 EEA Run ID 258160 / EEA Report # 449080
Page 11 of 22
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Manganese
200.8
0.4
00
LD
B0
.03
3ug
/L1
.04
26
85
01
---
---
---
---
---
<
04
/22
/20
19
13
:30
04
/23
/20
19
12
:28
Tru
e
IS-S
candiu
m200.8
N/A
LD
B1
.02
47
N/A
1.0
42
68
50
1--
---
---
-6
0 -
12
51
02
1.0
0
4/2
2/2
01
9 1
3:3
00
4/2
3/2
01
9 1
2:2
8T
rue
IS-Y
ttri
um
200.8
N/A
LD
B1
.00
22
N/A
1.0
42
68
50
1--
---
---
-6
0 -
12
51
00
1.0
0
4/2
2/2
01
9 1
3:3
00
4/2
3/2
01
9 1
2:2
8F
als
e
Germ
aniu
m200.8
0.3
00
CC
M4
8.6
71
99
9ug
/L1
.04
26
91
83
---
---
---
85
- 1
15
97
50
.0
04
/23
/20
19
10
:45
04
/23
/20
19
13
:14
Fals
e
IS-I
ndiu
m200.8
N/A
CC
M0
.93
94
N/A
1.0
42
69
18
3--
---
---
-6
0 -
12
59
41
.0
04
/23
/20
19
10
:45
04
/23
/20
19
13
:14
Fals
e
Manganese
200.8
0.4
00
CC
M4
9.0
88
99
9ug
/L1
.04
26
91
83
---
---
---
85
- 1
15
98
50
.0
04
/23
/20
19
10
:45
04
/23
/20
19
13
:14
Fals
e
IS-S
candiu
m200.8
N/A
CC
M0
.93
82
N/A
1.0
42
69
18
3--
---
---
-6
0 -
12
59
41
.0
04
/23
/20
19
10
:45
04
/23
/20
19
13
:14
Fals
e
IS-Y
ttri
um
200.8
N/A
CC
M0
.92
68
N/A
1.0
42
69
18
3--
---
---
-6
0 -
12
59
31
.0
04
/23
/20
19
10
:45
04
/23
/20
19
13
:14
Tru
e
Germ
aniu
m200.8
0.3
00
FS
0.3
00
ug
/L1
.04
26
10
25
19
03
03
47
-02
-2--
---
---
---
-
<0
4/2
2/2
01
9 1
3:3
00
4/2
3/2
01
9 1
3:4
7T
rue
IS-I
ndiu
m200.8
N/A
FS
0.8
68
9N
/A1
.04
26
10
25
19
03
03
47
-02
-2--
---
-6
0 -
12
58
71
.0
04
/22
/20
19
13
:30
04
/23
/20
19
13
:47
Tru
e
Manganese
200.8
0.4
00
FS
1.2
4ug
/L1
.04
26
10
25
19
03
03
47
-02
-2--
---
---
---
-
0
4/2
2/2
01
9 1
3:3
00
4/2
3/2
01
9 1
3:4
7T
rue
IS-S
candiu
m200.8
N/A
FS
0.8
38
2N
/A1
.04
26
10
25
19
03
03
47
-02
-2--
---
-6
0 -
12
58
41
.0
04
/22
/20
19
13
:30
04
/23
/20
19
13
:47
Tru
e
IS-Y
ttri
um
200.8
N/A
FS
0.8
50
7N
/A1
.04
26
10
25
19
03
03
47
-02
-2--
---
-6
0 -
12
58
51
.0
04
/22
/20
19
13
:30
04
/23
/20
19
13
:47
Fals
e
Germ
aniu
m200.8
0.3
00
CC
H1
93
.00
29
99
ug
/L1
.04
26
91
85
---
---
---
85
- 1
15
97
20
0
04
/23
/20
19
10
:45
04
/23
/20
19
14
:12
Fals
e
IS-I
ndiu
m200.8
N/A
CC
H0
.89
43
N/A
1.0
42
69
18
5--
---
---
-6
0 -
12
58
91
.0
04
/23
/20
19
10
:45
04
/23
/20
19
14
:12
Fals
e
Manganese
200.8
0.4
00
CC
H1
95
.85
3ug
/L1
.04
26
91
85
---
---
---
85
- 1
15
98
20
0
04
/23
/20
19
10
:45
04
/23
/20
19
14
:12
Fals
e
IS-S
candiu
m200.8
N/A
CC
H0
.86
77
N/A
1.0
42
69
18
5--
---
---
-6
0 -
12
58
71
.0
04
/23
/20
19
10
:45
04
/23
/20
19
14
:12
Fals
e
IS-Y
ttri
um
200.8
N/A
CC
H0
.87
15
N/A
1.0
42
69
18
5--
---
---
-6
0 -
12
58
71
.0
04
/23
/20
19
10
:45
04
/23
/20
19
14
:12
Page 2
of
2E
EA
Run I
D 2
58160 /
EE
A R
eport
# 4
49080
Page 12 of 22
D D D
.___.ODD□□ DDDDDDDD DODD□ DODD□ DOD
Eurofins Eaton AnalyticalRun Log
Run ID: 258642 Method: 525.3
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4274113 DN 5253-DN-032119.mth04/29/2019 11:13RW
LRB 4274109 DN 5253-DN-032119.mth04/29/2019 12:27RW
FBL 4274111 DN 5253-DN-032119.mth04/29/2019 13:40RW
FS 4261026 19030347-02-3,4,5 DN 5253-DN-032119.mth04/29/2019 20:23DW
CCM 4274115 DN 5253-DN-032119.mth04/29/2019 22:13RW
QCS 4274182 DN 5253-DN-032119.mth04/29/2019 23:27RW
0.00
Page 1 of 4 EEA Run ID 258642 / EEA Report # 449080
Page 13 of 22
=::: e u rofi n s I Eaton Analytical
QC
Su
mm
ary
Re
po
rt
EE
AID
#R
PD
Un
its
Ta
rge
tA
mo
un
tC
lie
nt
IDM
eth
od
An
aly
teS
am
ple
Typ
eD
ilF
ac
tor
RP
DL
imit
Re
co
ve
ryL
imit
s%
R
eco
ve
ryR
es
ult
Fla
gM
RL
Ex
tra
cte
dA
na
lyze
d
Fals
e
IS-A
cenaphth
ene
-d10
525.3
N/A
CC
L1
42
64
9ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
81
20
75
6
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
IS-C
hry
sene-d
12
525.3
N/A
CC
L2
40
00
8ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
82
02
73
0
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
IS-P
henanth
rene-d
10
525.3
N/A
CC
L2
29
66
5ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
71
95
70
4
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
CC
L1
.11
30
ug
/L1
.04
27
411
3--
---
---
-7
0 -
13
011
11
.0
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
CC
L1
.10
30
ug
/L1
.04
27
411
3--
---
---
-7
0 -
13
011
01
.0
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
SS
-Tri
phenyl
phosp
hate
525.3
N/A
CC
L1
.00
10
ug
/L1
.04
27
411
3--
---
---
-7
0 -
13
01
00
1.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 1
1:1
3F
als
e
Chlo
rpyr
ifos
525.3
0.0
300
CC
L0
.03
3ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
00
.03
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 1
1:1
3F
als
e
Dim
eth
ipin
525.3
0.2
00
CC
L0
.17
1ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
08
60
.2
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
Eth
opro
p525.3
0.0
300
CC
L0
.03
1ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
01
03
0.0
3
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
alp
ha-H
exa
chlo
rocy
clohexa
ne
525.3
0.0
100
CC
L0
.01
2ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
01
20
0.0
1
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
Oxy
fluorf
en
525.3
0.0
500
CC
L0
.07
1ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
01
42
0.0
5
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
cis-
Perm
eth
rin
525.3
0.0
109
CC
L0
.01
2ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
01
22
0.0
09
84
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 1
1:1
3F
als
e
trans-
Perm
eth
rin
525.3
0.0
290
CC
L0
.03
5ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
70
.03
00
4
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
Pro
fenofo
s525.3
0.3
00
CC
L0
.30
5ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
01
02
0.3
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 1
1:1
3F
als
e
Tebuco
nazo
le525.3
0.2
00
CC
L0
.22
7ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
011
40
.2
04
/27
/20
19
06
:10
04
/29
/20
19
11
:13
Fals
e
Tri
bufo
s525.3
0.0
700
CC
L0
.05
8ug
/L1
.04
27
411
3--
---
---
-5
0 -
15
08
30
.07
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 1
1:1
3T
rue
IS-A
cenaphth
ene
-d10
525.3
N/A
LR
B1
42
86
9ug
/L0
.99
42
74
10
9--
---
---
-5
0 -
15
011
81
20
75
6
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
IS-C
hry
sene-d
12
525.3
N/A
LR
B2
31
70
0ug
/L0
.99
42
74
10
9--
---
---
-5
0 -
15
011
42
02
73
0
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
IS-P
henanth
rene-d
10
525.3
N/A
LR
B2
22
62
2ug
/L0
.99
42
74
10
9--
---
---
-5
0 -
15
011
41
95
70
4
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
LR
B0
.81
00
ug
/L0
.99
42
74
10
9--
---
---
-7
0 -
13
08
21
.0
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
LR
B0
.95
30
ug
/L0
.99
42
74
10
9--
---
---
-7
0 -
13
09
61
.0
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
SS
-Tri
phenyl
phosp
hate
525.3
N/A
LR
B0
.89
20
ug
/L0
.99
42
74
10
9--
---
---
-7
0 -
13
09
01
.0
04
/27
/20
19
06
:03
04
/29
/20
19
12
:27
Tru
e
Chlo
rpyr
ifos
525.3
0.0
300
LR
B0
.0ug
/L0
.99
42
74
10
9--
---
---
---
---
-
<0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
2:2
7T
rue
Dim
eth
ipin
525.3
0.2
00
LR
B0
.01
6ug
/L0
.99
42
74
10
9--
---
---
---
---
-
<0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
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7T
rue
Eth
opro
p525.3
0.0
300
LR
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42
74
10
9--
---
---
---
---
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<0
4/2
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9 0
6:0
30
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rue
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rocy
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ne
525.3
0.0
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LR
B0
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42
74
10
9--
---
---
---
---
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01
9 0
6:0
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9/2
01
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7T
rue
Oxy
fluorf
en
525.3
0.0
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/L0
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42
74
10
9--
---
---
---
---
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9 0
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rue
cis-
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rin
525.3
0.0
109
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42
74
10
9--
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9 0
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rue
trans-
Perm
eth
rin
525.3
0.0
290
LR
B0
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42
74
10
9--
---
---
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-
<0
4/2
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01
9 0
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01
9 1
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rue
Pro
fenofo
s525.3
0.3
00
LR
B0
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/L0
.99
42
74
10
9--
---
---
---
---
-
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4/2
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01
9 0
6:0
30
4/2
9/2
01
9 1
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7T
rue
Tebuco
nazo
le525.3
0.2
00
LR
B0
.0ug
/L0
.99
42
74
10
9--
---
---
---
---
-
<0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
2:2
7T
rue
Tri
bufo
s525.3
0.0
700
LR
B0
.0ug
/L0
.99
42
74
10
9--
---
---
---
---
-
<0
4/2
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01
9 0
6:0
30
4/2
9/2
01
9 1
2:2
7F
als
e
IS-A
cenaphth
ene
-d10
525.3
N/A
FB
L1
30
20
3ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
01
08
12
07
56
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
IS-C
hry
sene-d
12
525.3
N/A
FB
L2
06
26
8ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
01
02
20
27
30
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
IS-P
henanth
rene-d
10
525.3
N/A
FB
L1
99
92
6ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
01
02
19
57
04
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
FB
L0
.82
30
ug
/L1
.04
27
411
1--
---
---
-7
0 -
13
08
21
.0
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
FB
L0
.94
90
ug
/L1
.04
27
411
1--
---
---
-7
0 -
13
09
51
.0
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
SS
-Tri
phenyl
phosp
hate
525.3
N/A
FB
L0
.92
30
ug
/L1
.04
27
411
1--
---
---
-7
0 -
13
09
21
.0
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
Chlo
rpyr
ifos
525.3
0.0
300
FB
L0
.03
4ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
011
30
.03
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
Dim
eth
ipin
525.3
0.2
00
FB
L0
.13
9ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
07
00
.2
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Page 2
of
4E
EA
Run I
D 2
58642 /
EE
A R
eport
# 4
49080
Page 14 of 22
D D D D
.___.ODD□□ DDDDDDDD DODD□ DODD□ DDDDDDDD
Sa
mp
leTyp
eE
EA
ID #
An
aly
zed
Ex
tra
cte
dR
PD
Un
its
Ta
rge
tA
mo
un
tC
lie
nt
IDM
RL
Me
tho
dA
na
lyte
Dil
Fa
cto
rR
PD
Lim
itR
ec
ove
ryL
imit
s%
R
eco
ve
ryR
es
ult
Fla
g
QC
Su
mm
ary
Rep
ort
(co
nt.
)
Fals
e
Eth
opro
p525.3
0.0
300
FB
L0
.03
4ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
011
30
.03
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
alp
ha-H
exa
chlo
rocy
clohexa
ne
525.3
0.0
100
FB
L0
.011
ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
011
00
.01
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
Oxy
fluorf
en
525.3
0.0
500
FB
L0
.07
2ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
01
44
0.0
5
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
cis-
Perm
eth
rin
525.3
0.0
109
FB
L0
.00
9ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
09
10
.00
98
4
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
trans-
Perm
eth
rin
525.3
0.0
290
FB
L0
.03
1ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
01
03
0.0
30
04
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0F
als
e
Pro
fenofo
s525.3
0.3
00
FB
L0
.29
6ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
09
90
.3
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
Tebuco
nazo
le525.3
0.2
00
FB
L0
.23
6ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
011
80
.2
04
/27
/20
19
06
:03
04
/29
/20
19
13
:40
Fals
e
Tri
bufo
s525.3
0.0
700
FB
L0
.06
1ug
/L1
.04
27
411
1--
---
---
-5
0 -
15
08
70
.07
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 1
3:4
0T
rue
IS-A
cenaphth
ene
-d10
525.3
N/A
FS
12
53
40
ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
50
- 1
50
10
41
20
75
6
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
IS-C
hry
sene-d
12
525.3
N/A
FS
20
38
01
ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
50
- 1
50
10
12
02
73
0
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
IS-P
henanth
rene-d
10
525.3
N/A
FS
19
97
61
ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
50
- 1
50
10
21
95
70
4
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
FS
0.7
41
0ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
70
- 1
30
76
1.0
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 2
0:2
3T
rue
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
FS
0.8
92
0ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
70
- 1
30
92
1.0
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 2
0:2
3T
rue
SS
-Tri
phenyl
phosp
hate
525.3
N/A
FS
0.8
58
0ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
70
- 1
30
88
1.0
0
4/2
7/2
01
9 0
6:0
30
4/2
9/2
01
9 2
0:2
3T
rue
Chlo
rpyr
ifos
525.3
0.0
300
FS
0.0
30
0ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
Dim
eth
ipin
525.3
0.2
00
FS
0.2
00
ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
Eth
opro
p525.3
0.0
300
FS
0.0
30
0ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
alp
ha-H
exa
chlo
rocy
clohexa
ne
525.3
0.0
100
FS
0.0
10
0ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
Oxy
fluorf
en
525.3
0.0
500
FS
0.0
50
0ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
cis-
Perm
eth
rin
525.3
0.0
109
FS
0.0
10
9ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
trans-
Perm
eth
rin
525.3
0.0
290
FS
0.0
29
0ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
Perm
eth
rin, ci
s &
tra
ns
525.3
0.0
400
FS
0.0
40
0ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
Pro
fenofo
s525.3
0.3
00
FS
0.3
00
ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
Tebuco
nazo
le525.3
0.2
00
FS
0.2
00
ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Tru
e
Tri
bufo
s525.3
0.0
700
FS
0.0
70
0ug
/L0
.97
42
61
02
61
90
30
34
7-0
2-3
,4,5
---
---
---
---
<
04
/27
/20
19
06
:03
04
/29
/20
19
20
:23
Fals
e
IS-A
cenaphth
ene
-d10
525.3
N/A
CC
M1
23
69
9ug
/L1
.04
27
411
5--
---
---
-5
0 -
15
01
02
12
07
56
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
IS-C
hry
sene-d
12
525.3
N/A
CC
M1
94
45
0ug
/L1
.04
27
411
5--
---
---
-5
0 -
15
09
62
02
73
0
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
IS-P
henanth
rene-d
10
525.3
N/A
CC
M1
88
63
0ug
/L1
.04
27
411
5--
---
---
-5
0 -
15
09
61
95
70
4
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
CC
M1
.05
50
ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
01
06
1.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
CC
M1
.03
20
ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
01
03
1.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
SS
-Tri
phenyl
phosp
hate
525.3
N/A
CC
M1
.05
50
ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
01
06
1.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
Chlo
rpyr
ifos
525.3
0.0
300
CC
M0
.32
2ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
01
07
0.3
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
Dim
eth
ipin
525.3
0.2
00
CC
M1
.86
7ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
32
.0
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
Eth
opro
p525.3
0.0
300
CC
M0
.28
9ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
60
.3
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
alp
ha-H
exa
chlo
rocy
clohexa
ne
525.3
0.0
100
CC
M0
.09
3ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
30
.1
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
Oxy
fluorf
en
525.3
0.0
500
CC
M0
.56
2ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
011
20
.5
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
cis-
Perm
eth
rin
525.3
0.0
109
CC
M0
.09
5ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
70
.09
84
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
trans-
Perm
eth
rin
525.3
0.0
290
CC
M0
.29
3ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
80
.30
04
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
2:1
3F
als
e
Pro
fenofo
s525.3
0.3
00
CC
M2
.67
7ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
08
93
.0
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
Tebuco
nazo
le525.3
0.2
00
CC
M1
.94
5ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
72
.0
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Fals
e
Tri
bufo
s525.3
0.0
700
CC
M0
.65
ug
/L1
.04
27
411
5--
---
---
-7
0 -
13
09
30
.7
04
/27
/20
19
06
:10
04
/29
/20
19
22
:13
Page 3
of
4E
EA
Run I
D 2
58642 /
EE
A R
eport
# 4
49080
Page 15 of 22
D D D
DD DDDDDDDD DODD□ DODD□ DDDDDDDD DODD
Sa
mp
leTyp
eE
EA
ID #
An
aly
zed
Ex
tra
cte
dR
PD
Un
its
Ta
rge
tA
mo
un
tC
lie
nt
IDM
RL
Me
tho
dA
na
lyte
Dil
Fa
cto
rR
PD
Lim
itR
ec
ove
ryL
imit
s%
R
eco
ve
ryR
es
ult
Fla
g
QC
Su
mm
ary
Rep
ort
(co
nt.
)
Tru
e
IS-A
cenaphth
ene
-d10
525.3
N/A
QC
S1
21
70
7ug
/L1
.04
27
41
82
---
---
---
50
- 1
50
10
11
20
75
6
04
/27
/20
19
06
:10
04
/29
/20
19
23
:27
Tru
e
IS-C
hry
sene-d
12
525.3
N/A
QC
S1
85
64
5ug
/L1
.04
27
41
82
---
---
---
50
- 1
50
92
20
27
30
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
IS-P
henanth
rene-d
10
525.3
N/A
QC
S1
85
42
9ug
/L1
.04
27
41
82
---
---
---
50
- 1
50
95
19
57
04
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
SS
-Benzo
(a)p
yrene-d
12
525.3
N/A
QC
S1
.09
20
ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
10
91
.0
04
/27
/20
19
06
:10
04
/29
/20
19
23
:27
Tru
e
SS
-1,3
-Dim
eth
yl-2
-nitro
benze
ne
525.3
N/A
QC
S1
.07
20
ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
10
71
.0
04
/27
/20
19
06
:10
04
/29
/20
19
23
:27
Tru
e
SS
-Tri
phenyl
phosp
hate
525.3
N/A
QC
S1
.11
60
ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
112
1.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
Chlo
rpyr
ifos
525.3
0.0
300
QC
S0
.33
9ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
113
0.3
0
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01
9 0
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00
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01
9 2
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Dim
eth
ipin
525.3
0.2
00
QC
S1
.811
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/L1
.04
27
41
82
---
---
---
70
- 1
30
91
2.0
0
4/2
7/2
01
9 0
6:1
00
4/2
9/2
01
9 2
3:2
7T
rue
Eth
opro
p525.3
0.0
300
QC
S0
.30
7ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
10
20
.3
04
/27
/20
19
06
:10
04
/29
/20
19
23
:27
Tru
e
alp
ha-H
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chlo
rocy
clohexa
ne
525.3
0.0
100
QC
S0
.08
6ug
/L1
.04
27
41
82
---
---
---
70
- 1
30
86
0.1
0
4/2
7/2
01
9 0
6:1
00
4/2
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Oxy
fluorf
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525.3
0.0
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QC
S0
.57
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.04
27
41
82
---
---
---
70
- 1
30
114
0.5
0
4/2
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00
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rue
cis-
Perm
eth
rin
525.3
0.0
109
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S0
.16
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/L1
.04
27
41
82
---
---
---
70
- 1
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98
0.1
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70
- 1
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2
04
/27
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06
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04
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19
23
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Tru
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Pro
fenofo
s525.3
0.3
00
QC
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.76
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.04
27
41
82
---
---
---
70
- 1
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92
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.04
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70
- 1
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04
/27
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19
06
:10
04
/29
/20
19
23
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Tru
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Tri
bufo
s525.3
0.0
700
QC
S0
.79
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.04
27
41
82
---
---
---
70
- 1
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113
0.7
0
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01
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00
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01
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3:2
7
Page 4
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Run I
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58642 /
EE
A R
eport
# 4
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Page 16 of 22
D
._....___. __ DDDDDDDD DD
Eurofins Eaton AnalyticalRun Log
Run ID: 258385 Method: 530
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4272750 FV M 530 UCMR4 0228201904/26/2019 22:04RW
LRB 4272748 FV M 530 UCMR4 0228201904/26/2019 22:57RW
FBL 4272749 FV M 530 UCMR4 0228201904/26/2019 23:55RW
FS 4261027 19030347-02-6,7,8 FV M 530 UCMR4 0228201904/27/2019 06:06DW
CCM 4272751 FV M 530 UCMR4 0228201904/27/2019 06:32RW
0.00
Page 1 of 2 EEA Run ID 258385 / EEA Report # 449080
Page 17 of 22
=::: e u rofi n s I Eaton Analytical
QC
Su
mm
ary
Re
po
rt
EE
AID
#R
PD
Un
its
Ta
rge
tA
mo
un
tC
lie
nt
IDM
eth
od
An
aly
teS
am
ple
Typ
eD
ilF
ac
tor
RP
DL
imit
Re
co
ve
ryL
imit
s%
R
eco
ve
ryR
es
ult
Fla
gM
RL
Ex
tra
cte
dA
na
lyze
d
Tru
e
IS-A
cenaphth
ene
-d10
530
N/A
CC
L3
66
93
4ug
/L1
.04
27
27
50
---
---
---
50
- 1
50
79
46
40
60
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
2:0
4T
rue
IS-P
henanth
rene-d
10
530
N/A
CC
L5
91
74
4ug
/L1
.04
27
27
50
---
---
---
50
- 1
50
85
69
51
49
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
2:0
4T
rue
SS
-Quin
olin
e-d
7530
N/A
CC
L0
.52
22
ug
/L1
.04
27
27
50
---
---
---
70
- 1
30
10
40
.5
04
/26
/20
19
08
:13
04
/26
/20
19
22
:04
Tru
e
SS
-o-T
olu
idin
e-d
9530
N/A
CC
L0
.51
67
ug
/L1
.04
27
27
50
---
---
---
50
- 1
30
10
30
.5
04
/26
/20
19
08
:13
04
/26
/20
19
22
:04
Tru
e
Buty
late
d h
ydro
xyanis
ole
530
0.0
300
CC
L0
.03
48
ug
/L1
.04
27
27
50
---
---
---
50
- 1
50
116
0.0
29
99
9
04
/26
/20
19
08
:13
04
/26
/20
19
22
:04
Tru
e
Quin
olin
e530
0.0
200
CC
L0
.02
34
ug
/L1
.04
27
27
50
---
---
---
50
- 1
50
117
0.0
19
99
9
04
/26
/20
19
08
:13
04
/26
/20
19
22
:04
Tru
e
o-T
olu
idin
e530
0.0
0700
CC
L0
.00
94
ug
/L1
.04
27
27
50
---
---
---
50
- 1
50
13
40
.00
7
04
/26
/20
19
08
:13
04
/26
/20
19
22
:04
Fals
e
IS-A
cenaphth
ene
-d10
530
N/A
LR
B3
74
14
8ug
/L1
.01
42
72
74
8--
---
---
-5
0 -
15
08
14
64
06
0
04
/26
/20
19
08
:13
04
/26
/20
19
22
:57
Fals
e
IS-P
henanth
rene-d
10
530
N/A
LR
B6
12
86
7ug
/L1
.01
42
72
74
8--
---
---
-5
0 -
15
08
86
95
14
9
04
/26
/20
19
08
:13
04
/26
/20
19
22
:57
Fals
e
SS
-Quin
olin
e-d
7530
N/A
LR
B0
.42
27
ug
/L1
.01
42
72
74
8--
---
---
-7
0 -
13
08
40
.5
04
/26
/20
19
08
:13
04
/26
/20
19
22
:57
Fals
e
SS
-o-T
olu
idin
e-d
9530
N/A
LR
B0
.40
75
ug
/L1
.01
42
72
74
8--
---
---
-5
0 -
13
08
10
.5
04
/26
/20
19
08
:13
04
/26
/20
19
22
:57
Fals
e
Buty
late
d h
ydro
xyanis
ole
530
0.0
300
LR
B0
.0ug
/L1
.01
42
72
74
8--
---
---
---
---
-
<0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
2:5
7F
als
e
Quin
olin
e530
0.0
200
LR
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.00
62
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/L1
.01
42
72
74
8--
---
---
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---
-
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6/2
01
9 0
8:1
30
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01
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2:5
7F
als
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o-T
olu
idin
e530
0.0
0700
LR
B0
.00
03
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/L1
.01
42
72
74
8--
---
---
---
---
-
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4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
2:5
7T
rue
IS-A
cenaphth
ene
-d10
530
N/A
FB
L3
48
03
2ug
/L1
.04
27
27
49
---
---
---
50
- 1
50
75
46
40
60
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5T
rue
IS-P
henanth
rene-d
10
530
N/A
FB
L5
67
42
6ug
/L1
.04
27
27
49
---
---
---
50
- 1
50
82
69
51
49
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5T
rue
SS
-Quin
olin
e-d
7530
N/A
FB
L0
.42
82
ug
/L1
.04
27
27
49
---
---
---
70
- 1
30
86
0.5
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5T
rue
SS
-o-T
olu
idin
e-d
9530
N/A
FB
L0
.39
41
ug
/L1
.04
27
27
49
---
---
---
50
- 1
30
79
0.5
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5T
rue
Buty
late
d h
ydro
xyanis
ole
530
0.0
300
FB
L0
.02
74
ug
/L1
.04
27
27
49
---
---
---
50
- 1
50
91
0.0
29
99
9
04
/26
/20
19
08
:13
04
/26
/20
19
23
:55
Tru
e
Quin
olin
e530
0.0
200
FB
L0
.02
02
ug
/L1
.04
27
27
49
---
---
---
50
- 1
50
10
10
.01
99
99
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5T
rue
o-T
olu
idin
e530
0.0
0700
FB
L0
.00
78
ug
/L1
.04
27
27
49
---
---
---
50
- 1
50
111
0.0
07
0
4/2
6/2
01
9 0
8:1
30
4/2
6/2
01
9 2
3:5
5F
als
e
IS-A
cenaphth
ene
-d10
530
N/A
FS
311
69
6ug
/L0
.98
42
61
02
71
90
30
34
7-0
2-6
,7,8
---
---
50
- 1
50
67
46
40
60
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
6:0
6F
als
e
IS-P
henanth
rene-d
10
530
N/A
FS
53
78
67
ug
/L0
.98
42
61
02
71
90
30
34
7-0
2-6
,7,8
---
---
50
- 1
50
77
69
51
49
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
6:0
6F
als
e
SS
-Quin
olin
e-d
7530
N/A
FS
0.3
87
9ug
/L0
.98
42
61
02
71
90
30
34
7-0
2-6
,7,8
---
---
70
- 1
30
79
0.5
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
6:0
6F
als
e
SS
-o-T
olu
idin
e-d
9530
N/A
FS
0.4
04
0ug
/L0
.98
42
61
02
71
90
30
34
7-0
2-6
,7,8
---
---
50
- 1
30
82
0.5
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
6:0
6F
als
e
Buty
late
d h
ydro
xyanis
ole
530
0.0
300
FS
0.0
30
0ug
/L0
.98
42
61
02
71
90
30
34
7-0
2-6
,7,8
---
---
---
---
<
04
/26
/20
19
08
:13
04
/27
/20
19
06
:06
Fals
e
Quin
olin
e530
0.0
200
FS
0.0
20
0ug
/L0
.98
42
61
02
71
90
30
34
7-0
2-6
,7,8
---
---
---
---
<
04
/26
/20
19
08
:13
04
/27
/20
19
06
:06
Fals
e
o-T
olu
idin
e530
0.0
0700
FS
0.0
07
00
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/L0
.98
42
61
02
71
90
30
34
7-0
2-6
,7,8
---
---
---
---
<
04
/26
/20
19
08
:13
04
/27
/20
19
06
:06
Tru
e
IS-A
cenaphth
ene
-d10
530
N/A
CC
M2
93
70
8ug
/L1
.04
27
27
51
---
---
---
50
- 1
50
63
46
40
60
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
6:3
2T
rue
IS-P
henanth
rene-d
10
530
N/A
CC
M4
89
92
4ug
/L1
.04
27
27
51
---
---
---
50
- 1
50
70
69
51
49
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
6:3
2T
rue
SS
-Quin
olin
e-d
7530
N/A
CC
M0
.49
04
ug
/L1
.04
27
27
51
---
---
---
70
- 1
30
98
0.5
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
6:3
2T
rue
SS
-o-T
olu
idin
e-d
9530
N/A
CC
M0
.48
68
ug
/L1
.04
27
27
51
---
---
---
50
- 1
30
97
0.5
0
4/2
6/2
01
9 0
8:1
30
4/2
7/2
01
9 0
6:3
2T
rue
Buty
late
d h
ydro
xyanis
ole
530
0.0
300
CC
M0
.22
52
ug
/L1
.04
27
27
51
---
---
---
70
- 1
30
75
0.2
99
99
9
04
/26
/20
19
08
:13
04
/27
/20
19
06
:32
Tru
e
Quin
olin
e530
0.0
200
CC
M0
.17
ug
/L1
.04
27
27
51
---
---
---
70
- 1
30
85
0.1
99
99
9
04
/26
/20
19
08
:13
04
/27
/20
19
06
:32
Tru
e
o-T
olu
idin
e530
0.0
0700
CC
M0
.07
76
ug
/L1
.04
27
27
51
---
---
---
70
- 1
30
111
0.0
7
04
/26
/20
19
08
:13
04
/27
/20
19
06
:32
Page 2
of
2E
EA
Run I
D 2
58385 /
EE
A R
eport
# 4
49080
Page 18 of 22
D D D
-------------□□□DD DDDDDDDD DODD□ DODD□ DD
Eurofins Eaton AnalyticalRun Log
Run ID: 258986 Method: 541
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4282885 FN M 541 UCMR4 0317201905/09/2019 16:20OS
LRB 4282838 FN M 541 UCMR4 0317201905/09/2019 17:36RW
FBL 4282840 FN M 541 UCMR4 0317201905/09/2019 18:51RW
FS 4261028 19030347-02-9,10,11 FN M 541 UCMR4 0317201905/10/2019 01:53DW
CCM 4282887 FN M 541 UCMR4 0317201905/10/2019 03:01OS
0.00
Page 1 of 2 EEA Run ID 258986 / EEA Report # 449080
Page 19 of 22
=::: e u rofi n s I Eaton Analytical
QC
Su
mm
ary
Re
po
rt
EE
AID
#R
PD
Un
its
Ta
rge
tA
mo
un
tC
lie
nt
IDM
eth
od
An
aly
teS
am
ple
Typ
eD
ilF
ac
tor
RP
DL
imit
Re
co
ve
ryL
imit
s%
R
eco
ve
ryR
es
ult
Fla
gM
RL
Ex
tra
cte
dA
na
lyze
d
Tru
e
IS-C
hlo
robenze
ne-d
5541
N/A
CC
L5
88
66
ug
/L1
.04
28
28
85
---
---
---
50
- 1
50
76
76
97
8
05
/07
/20
19
08
:04
05
/09
/20
19
16
:20
Tru
e
SS
-1-B
uta
nol-
d10
541
N/A
CC
L1
0.2
70
0ug
/L1
.04
28
28
85
---
---
---
70
- 1
30
10
31
0.0
0
5/0
7/2
01
9 0
8:0
40
5/0
9/2
01
9 1
6:2
0T
rue
1-B
uta
nol
541
2.0
0C
CL
2.0
61
ug
/L1
.04
28
28
85
---
---
---
50
- 1
50
10
32
.0
05
/07
/20
19
08
:04
05
/09
/20
19
16
:20
Tru
e
2-M
eth
oxy
eth
anol
541
0.4
00
CC
L0
.44
4ug
/L1
.04
28
28
85
---
---
---
50
- 1
50
111
0.4
0
5/0
7/2
01
9 0
8:0
40
5/0
9/2
01
9 1
6:2
0T
rue
2-P
ropen-1
-ol
541
0.5
00
CC
L0
.49
9ug
/L1
.04
28
28
85
---
---
---
50
- 1
50
10
00
.5
05
/07
/20
19
08
:04
05
/09
/20
19
16
:20
Fals
e
IS-C
hlo
robenze
ne-d
5541
N/A
LR
B6
62
28
ug
/L1
.04
28
28
38
---
---
---
50
- 1
50
86
76
97
8
05
/07
/20
19
07
:00
05
/09
/20
19
17
:36
Fals
e
SS
-1-B
uta
nol-
d10
541
N/A
LR
B8
.68
00
ug
/L1
.04
28
28
38
---
---
---
70
- 1
30
87
10
.0
05
/07
/20
19
07
:00
05
/09
/20
19
17
:36
Fals
e
1-B
uta
nol
541
2.0
0L
RB
0.0
ug
/L1
.04
28
28
38
---
---
---
---
---
<
05
/07
/20
19
07
:00
05
/09
/20
19
17
:36
Fals
e
2-M
eth
oxy
eth
anol
541
0.4
00
LR
B0
.0ug
/L1
.04
28
28
38
---
---
---
---
---
<
05
/07
/20
19
07
:00
05
/09
/20
19
17
:36
Fals
e
2-P
ropen-1
-ol
541
0.5
00
LR
B0
.05
3ug
/L1
.04
28
28
38
---
---
---
---
---
<
05
/07
/20
19
07
:00
05
/09
/20
19
17
:36
Tru
e
IS-C
hlo
robenze
ne-d
5541
N/A
FB
L6
52
43
ug
/L1
.04
28
28
40
---
---
---
50
- 1
50
85
76
97
8
05
/07
/20
19
07
:00
05
/09
/20
19
18
:51
Tru
e
SS
-1-B
uta
nol-
d10
541
N/A
FB
L8
.77
00
ug
/L1
.04
28
28
40
---
---
---
70
- 1
30
88
10
.0
05
/07
/20
19
07
:00
05
/09
/20
19
18
:51
Tru
e
1-B
uta
nol
541
2.0
0F
BL
1.6
92
ug
/L1
.04
28
28
40
---
---
---
50
- 1
50
85
2.0
0
5/0
7/2
01
9 0
7:0
00
5/0
9/2
01
9 1
8:5
1T
rue
2-M
eth
oxy
eth
anol
541
0.4
00
FB
L0
.35
7ug
/L1
.04
28
28
40
---
---
---
50
- 1
50
89
0.4
0
5/0
7/2
01
9 0
7:0
00
5/0
9/2
01
9 1
8:5
1T
rue
2-P
ropen-1
-ol
541
0.5
00
FB
L0
.47
6ug
/L1
.04
28
28
40
---
---
---
50
- 1
50
95
0.5
0
5/0
7/2
01
9 0
7:0
00
5/0
9/2
01
9 1
8:5
1F
als
e
IS-C
hlo
robenze
ne-d
5541
N/A
FS
69
10
0ug
/L1
.04
26
10
28
19
03
03
47
-02
-9,1
0,1
1--
---
-5
0 -
15
09
07
69
78
0
5/0
7/2
01
9 0
7:0
00
5/1
0/2
01
9 0
1:5
3F
als
e
SS
-1-B
uta
nol-
d10
541
N/A
FS
8.9
10
0ug
/L1
.04
26
10
28
19
03
03
47
-02
-9,1
0,1
1--
---
-7
0 -
13
08
91
0.0
0
5/0
7/2
01
9 0
7:0
00
5/1
0/2
01
9 0
1:5
3F
als
e
1-B
uta
nol
541
2.0
0F
S2
.00
ug
/L1
.04
26
10
28
19
03
03
47
-02
-9,1
0,1
1--
---
---
---
-
<0
5/0
7/2
01
9 0
7:0
00
5/1
0/2
01
9 0
1:5
3F
als
e
2-M
eth
oxy
eth
anol
541
0.4
00
FS
0.4
00
ug
/L1
.04
26
10
28
19
03
03
47
-02
-9,1
0,1
1--
---
---
---
-
<0
5/0
7/2
01
9 0
7:0
00
5/1
0/2
01
9 0
1:5
3F
als
e
2-P
ropen-1
-ol
541
0.5
00
FS
0.5
00
ug
/L1
.04
26
10
28
19
03
03
47
-02
-9,1
0,1
1--
---
---
---
-
<0
5/0
7/2
01
9 0
7:0
00
5/1
0/2
01
9 0
1:5
3T
rue
IS-C
hlo
robenze
ne-d
5541
N/A
CC
M6
93
56
ug
/L1
.04
28
28
87
---
---
---
50
- 1
50
90
76
97
8
05
/07
/20
19
08
:04
05
/10
/20
19
03
:01
Tru
e
SS
-1-B
uta
nol-
d10
541
N/A
CC
M9
.02
00
ug
/L1
.04
28
28
87
---
---
---
70
- 1
30
90
10
.0
05
/07
/20
19
08
:04
05
/10
/20
19
03
:01
Tru
e
1-B
uta
nol
541
2.0
0C
CM
18
.00
3ug
/L1
.04
28
28
87
---
---
---
70
- 1
30
90
20
.0
05
/07
/20
19
08
:04
05
/10
/20
19
03
:01
Tru
e
2-M
eth
oxy
eth
anol
541
0.4
00
CC
M3
.77
4ug
/L1
.04
28
28
87
---
---
---
70
- 1
30
94
4.0
0
5/0
7/2
01
9 0
8:0
40
5/1
0/2
01
9 0
3:0
1T
rue
2-P
ropen-1
-ol
541
0.5
00
CC
M4
.44
8ug
/L1
.04
28
28
87
---
---
---
70
- 1
30
89
5.0
0
5/0
7/2
01
9 0
8:0
40
5/1
0/2
01
9 0
3:0
1
Page 2
of
2E
EA
Run I
D 2
58986 /
EE
A R
eport
# 4
49080
Page 20 of 22
D D
-------------□□□DD DDDDDDDD DODD□
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tory
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tory
Reagent
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nk
QC
SQ
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y C
ontr
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am
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1.0
0
Page 21 of 22
END OF REPORT
Page 22 of 22
LABORATORY REPORT
This report may not be reproduced, except in full, without written approval from EEA.
If you have any questions concerning this report, please do not hesitate to call us at (800) 332-4345 or (574) 233-4777.
Page 1 of 43
=::: e u ro fi n s I Eaton Analytical
Revision date: 03/14/2019
STATE CERTIFICATION LIST
State Certification State Certification Alabama 40700 Missouri 880 Alaska IN00035 Montana CERT0026 Arizona AZ0432 Nebraska NE-OS-05-04
Arkansas IN00035 Nevada IN00035 California 2920 New Hampshire* 2124 Colorado IN00035 New Jersey* IN598
Colorado Radiochemistry IN00035 New Mexico IN00035 Connecticut PH-0132 New York* 11398 Delaware IN035 North Carolina 18700 Florida* E87775 North Dakota R-035 Georgia 929 Ohio 87775 Hawaii IN035 Oklahoma D9508 Idaho IN00035 Oregon (Primary AB)* 4074
Illinois* 200001 Pennsylvania* 68-00466 Illinois Microbiology 17767 Puerto Rico IN00035
Illinois Radiochemistry IN00035 Rhode Island LAO00343 Indiana Chemistry C-71-01 South Carolina 95005
Indiana Microbiology M-76-07 South Dakota IN00035 Iowa 098 Tennessee TN02973
Kansas* E-10233 Texas* T104704187-18-12 Kentucky 90056 Texas/TCEQ TX207
Louisiana* LA014 Utah* IN00035 Maine IN00035 Vermont VT-8775
Maryland 209 Virginia* 460275 Massachusetts M-IN035 Washington C837
Michigan 9926 West Virginia 9927 C Minnesota* 018-999-338 Wisconsin 999766900 Mississippi IN035 Wyoming IN035
EPA IN00035 *NELAP/TNI Recognized Accreditation Bodies
Page 2 of 43
~:: eu rofi ns I Eaton Analytical
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC1
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261125 19030346-01-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 3 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC1
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.74 ug/L 04/24/19 07:08 04/26/19 02:53 4261125
9535 Bromodichloroacetic acid 552.3 0.500 1.30 ug/L 04/24/19 07:08 04/26/19 02:53 4261125
9339 Chlorodibromoacetic acid 552.3 0.300 0.749 ug/L 04/24/19 07:08 04/26/19 02:53 4261125
2454 Dibromoacetic acid 552.3 0.300 1.83 ug/L 04/24/19 07:08 04/26/19 02:53 4261125
2451 Dichloroacetic acid 552.3 0.200 1.01 ug/L 04/24/19 07:08 04/26/19 02:53 4261125
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 04/24/19 07:08 04/26/19 02:53 4261125
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 02:53 4261125
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 02:53 4261125
2452 Trichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/24/19 07:08 04/26/19 02:53 4261125
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 4 of 43
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC2
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261126 19030346-02-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 5 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC2
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.81 ug/L 04/24/19 07:08 04/26/19 03:30 4261126
9535 Bromodichloroacetic acid 552.3 0.500 0.735 ug/L 04/24/19 07:08 04/26/19 03:30 4261126
9339 Chlorodibromoacetic acid 552.3 0.300 < 0.300 ug/L 04/24/19 07:08 04/26/19 03:30 4261126
2454 Dibromoacetic acid 552.3 0.300 0.620 ug/L 04/24/19 07:08 04/26/19 03:30 4261126
2451 Dichloroacetic acid 552.3 0.200 2.89 ug/L 04/24/19 07:08 04/26/19 03:30 4261126
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 04/24/19 07:08 04/26/19 03:30 4261126
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 03:30 4261126
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 03:30 4261126
2452 Trichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/24/19 07:08 04/26/19 03:30 4261126
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 6 of 43
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC3
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261127 19030346-03-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 7 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC3
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.84 ug/L 04/24/19 07:08 04/26/19 04:06 4261127
9535 Bromodichloroacetic acid 552.3 0.500 1.25 ug/L 04/24/19 07:08 04/26/19 04:06 4261127
9339 Chlorodibromoacetic acid 552.3 0.300 0.768 ug/L 04/24/19 07:08 04/26/19 04:06 4261127
2454 Dibromoacetic acid 552.3 0.300 1.87 ug/L 04/24/19 07:08 04/26/19 04:06 4261127
2451 Dichloroacetic acid 552.3 0.200 1.04 ug/L 04/24/19 07:08 04/26/19 04:06 4261127
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 04/24/19 07:08 04/26/19 04:06 4261127
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 04:06 4261127
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 04:06 4261127
2452 Trichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/24/19 07:08 04/26/19 04:06 4261127
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 8 of 43
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC4
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261128 19030346-04-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 9 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC4
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.56 ug/L 04/24/19 07:08 04/26/19 04:42 4261128
9535 Bromodichloroacetic acid 552.3 0.500 0.756 ug/L 04/24/19 07:08 04/26/19 04:42 4261128
9339 Chlorodibromoacetic acid 552.3 0.300 0.349 ug/L 04/24/19 07:08 04/26/19 04:42 4261128
2454 Dibromoacetic acid 552.3 0.300 0.584 ug/L 04/24/19 07:08 04/26/19 04:42 4261128
2451 Dichloroacetic acid 552.3 0.200 2.78 ug/L 04/24/19 07:08 04/26/19 04:42 4261128
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 04/24/19 07:08 04/26/19 04:42 4261128
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 04:42 4261128
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 04:42 4261128
2452 Trichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/24/19 07:08 04/26/19 04:42 4261128
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 10 of 43
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC5
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261129 19030346-05-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 11 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC5
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.72 ug/L 04/24/19 07:08 04/26/19 06:32 4261129
9535 Bromodichloroacetic acid 552.3 0.500 0.981 ug/L 04/24/19 07:08 04/26/19 06:32 4261129
9339 Chlorodibromoacetic acid 552.3 0.300 0.554 ug/L 04/24/19 07:08 04/26/19 06:32 4261129
2454 Dibromoacetic acid 552.3 0.300 1.13 ug/L 04/24/19 07:08 04/26/19 06:32 4261129
2451 Dichloroacetic acid 552.3 0.200 1.96 ug/L 04/24/19 07:08 04/26/19 06:32 4261129
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 04/24/19 07:08 04/26/19 06:32 4261129
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 06:32 4261129
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 06:32 4261129
2452 Trichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/24/19 07:08 04/26/19 06:32 4261129
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 12 of 43
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC6
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261130 19030346-06-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 13 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC6
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.87 ug/L 04/24/19 07:08 04/26/19 07:08 4261130
9535 Bromodichloroacetic acid 552.3 0.500 0.770 ug/L 04/24/19 07:08 04/26/19 07:08 4261130
9339 Chlorodibromoacetic acid 552.3 0.300 0.335 ug/L 04/24/19 07:08 04/26/19 07:08 4261130
2454 Dibromoacetic acid 552.3 0.300 0.713 ug/L 04/24/19 07:08 04/26/19 07:08 4261130
2451 Dichloroacetic acid 552.3 0.200 2.58 ug/L 04/24/19 07:08 04/26/19 07:08 4261130
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 04/24/19 07:08 04/26/19 07:08 4261130
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 07:08 4261130
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 07:08 4261130
2452 Trichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/24/19 07:08 04/26/19 07:08 4261130
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 14 of 43
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC7
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261131 19030346-07-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 15 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC7
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.91 ug/L 04/24/19 07:08 04/26/19 07:45 4261131
9535 Bromodichloroacetic acid 552.3 0.500 1.33 ug/L 04/24/19 07:08 04/26/19 07:45 4261131
9339 Chlorodibromoacetic acid 552.3 0.300 0.729 ug/L 04/24/19 07:08 04/26/19 07:45 4261131
2454 Dibromoacetic acid 552.3 0.300 2.18 ug/L 04/24/19 07:08 04/26/19 07:45 4261131
2451 Dichloroacetic acid 552.3 0.200 1.17 ug/L 04/24/19 07:08 04/26/19 07:45 4261131
2453 Monobromoacetic acid 552.3 0.300 0.331 ug/L 04/24/19 07:08 04/26/19 07:45 4261131
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 07:45 4261131
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/24/19 07:08 04/26/19 07:45 4261131
2452 Trichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/24/19 07:08 04/26/19 07:45 4261131
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 16 of 43
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC8
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261132 19030346-08-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 17 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC8
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.11 ug/L 04/25/19 08:10 04/26/19 20:48 4261132
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/25/19 08:10 04/26/19 20:48 4261132
9339 Chlorodibromoacetic acid 552.3 0.300 0.359 ug/L 04/25/19 08:10 04/26/19 20:48 4261132
2454 Dibromoacetic acid 552.3 0.300 0.486 ug/L 04/25/19 08:10 04/26/19 20:48 4261132
2451 Dichloroacetic acid 552.3 0.200 1.86 ug/L 04/25/19 08:10 04/26/19 20:48 4261132
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 04/25/19 08:10 04/26/19 20:48 4261132
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/25/19 08:10 04/26/19 20:48 4261132
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/25/19 08:10 04/26/19 20:48 4261132
2452 Trichloroacetic acid 552.3 0.500 0.583 ug/L 04/25/19 08:10 04/26/19 20:48 4261132
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 18 of 43
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC9
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261133 19030346-09-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 19 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC9
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.22 ug/L 04/25/19 08:10 04/26/19 22:36 4261133
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/25/19 08:10 04/26/19 22:36 4261133
9339 Chlorodibromoacetic acid 552.3 0.300 0.359 ug/L 04/25/19 08:10 04/26/19 22:36 4261133
2454 Dibromoacetic acid 552.3 0.300 0.712 ug/L 04/25/19 08:10 04/26/19 22:36 4261133
2451 Dichloroacetic acid 552.3 0.200 1.38 ug/L 04/25/19 08:10 04/26/19 22:36 4261133
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 04/25/19 08:10 04/26/19 22:36 4261133
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/25/19 08:10 04/26/19 22:36 4261133
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/25/19 08:10 04/26/19 22:36 4261133
2452 Trichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/25/19 08:10 04/26/19 22:36 4261133
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 20 of 43
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC10
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261134 19030346-10-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 21 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC10
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.31 ug/L 04/25/19 08:10 04/26/19 23:12 4261134
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/25/19 08:10 04/26/19 23:12 4261134
9339 Chlorodibromoacetic acid 552.3 0.300 0.367 ug/L 04/25/19 08:10 04/26/19 23:12 4261134
2454 Dibromoacetic acid 552.3 0.300 0.563 ug/L 04/25/19 08:10 04/26/19 23:12 4261134
2451 Dichloroacetic acid 552.3 0.200 2.09 ug/L 04/25/19 08:10 04/26/19 23:12 4261134
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 04/25/19 08:10 04/26/19 23:12 4261134
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/25/19 08:10 04/26/19 23:12 4261134
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/25/19 08:10 04/26/19 23:12 4261134
2452 Trichloroacetic acid 552.3 0.500 0.543 ug/L 04/25/19 08:10 04/26/19 23:12 4261134
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 22 of 43
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC11
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261135 19030346-11-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 23 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC11
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.32 ug/L 04/25/19 08:10 04/26/19 23:48 4261135
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/25/19 08:10 04/26/19 23:48 4261135
9339 Chlorodibromoacetic acid 552.3 0.300 0.365 ug/L 04/25/19 08:10 04/26/19 23:48 4261135
2454 Dibromoacetic acid 552.3 0.300 0.562 ug/L 04/25/19 08:10 04/26/19 23:48 4261135
2451 Dichloroacetic acid 552.3 0.200 2.16 ug/L 04/25/19 08:10 04/26/19 23:48 4261135
2453 Monobromoacetic acid 552.3 0.300 < 0.300 ug/L 04/25/19 08:10 04/26/19 23:48 4261135
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/25/19 08:10 04/26/19 23:48 4261135
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/25/19 08:10 04/26/19 23:48 4261135
2452 Trichloroacetic acid 552.3 0.500 0.563 ug/L 04/25/19 08:10 04/26/19 23:48 4261135
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 24 of 43
Laboratory Report
Client:
Attn:
Report:
Priority:
Status:
PWS ID:
Hillsborough County Board of County Commissioners
Ed Watson
332 N. Falkenburd Rd.
449090
FL6290787
Standard Written
Final
Tampa, FL 33619
Sample Event Code:
PWS Facility ID:
Sampling Point ID:
00004
SC12
SE2
Lab ID Code: IN00035
110 South Hill StreetSouth Bend, IN 46617Tel: (574) 233-4777Fax: (574) 233-82071 800 332 4345
EEA ID #
Client ID Method CollectedDate / Time
CollectedBy:
ReceivedDate / Time
4261136 19030346-12-1 552.3 04/15/19 22:00 Client 04/16/19 10:00
Sample Information
Report Summary
Detailed quantitative results are presented on the following pages. The results presented relate only to the samples provided for analysis.
We appreciate the opportunity to provide you with this analysis. If you have any questions concerning this report, please do not hesitate to call Jessie Brasch at (574) 233-4777.
Note: This report may not be reproduced, except in full, without written approval from EEA.
Client Name:
Report #:
Hillsborough County Board of County Commissioners
449090
Authorized Signature Title Date
05/02/2019
Page 1 of 2
Page 25 of 43
=:~ eurofins I Eaton Analytical
Ana lytical Services Manager
Client Name: Report #: 449090Hillsborough County Board of County Commissioners
Sampling Point ID: PWS ID: FL6290787SC12
UCMR Result Summary
AnalyteID #
Analyte Method MRL† Result Units PreparationDate
AnalyzedDate
EEAID #
2455 Bromochloroacetic acid 552.3 0.300 1.51 ug/L 04/25/19 08:10 04/27/19 00:24 4261136
9535 Bromodichloroacetic acid 552.3 0.500 < 0.500 ug/L 04/25/19 08:10 04/27/19 00:24 4261136
9339 Chlorodibromoacetic acid 552.3 0.300 0.352 ug/L 04/25/19 08:10 04/27/19 00:24 4261136
2454 Dibromoacetic acid 552.3 0.300 0.650 ug/L 04/25/19 08:10 04/27/19 00:24 4261136
2451 Dichloroacetic acid 552.3 0.200 1.90 ug/L 04/25/19 08:10 04/27/19 00:24 4261136
2453 Monobromoacetic acid 552.3 0.300 0.429 ug/L 04/25/19 08:10 04/27/19 00:24 4261136
2450 Monochloroacetic acid 552.3 2.00 < 2.00 ug/L 04/25/19 08:10 04/27/19 00:24 4261136
9639 Tribromoacetic acid 552.3 2.00 < 2.00 ug/L 04/25/19 08:10 04/27/19 00:24 4261136
2452 Trichloroacetic acid 552.3 0.500 0.515 ug/L 04/25/19 08:10 04/27/19 00:24 4261136
† EEA has demonstrated it can achieve these report limits in reagent water, but can not document them in all sample matrices.
Page 2 of 2
Page 26 of 43
Lab Definitions
Continuing Calibration Check Standard (CCC) / Continuing Calibration Verification (CCV) / Initial Calibration Verification Standard (ICV) / Initial Performance Check (IPC) - is a standard containing one or more of the target analytes that is prepared from the same standards used to calibrate the instrument. This standard is used to verify the calibration curve at the beginning of each analytical sequence, and may also be analyzed throughout and at the end of the sequence. The concentration of continuing standards may be varied, when prescribed by the reference method, so that the range of the calibration curve is verified on a regular basis. CCL, CCM, and CCH are the CCC standards at low, mid, and high concentration levels, respectively.
Internal Standards (IS) - are pure compounds with properties similar to the analytes of interest, which are added to field samples or extracts, calibration standards, and quality control standards at a known concentration. They are used to measure the relative responses of the analytes of interest and surrogates in the sample, calibration standard or quality control standard.
Laboratory Duplicate (LD) - is a field sample aliquot taken from the same sample container in the laboratory and analyzed separately using identical procedures. Analysis of laboratory duplicates provides a measure of the precision of the laboratory procedures.
Laboratory Fortified Blank (LFB) / Laboratory Control Sample (LCS) - is an aliquot of reagent water to which known concentrations of the analytes of interest are added. The LFB is analyzed exactly the same as the field samples. LFBs are used to determine whether the method is in control. FBL, FBM, and FBH are the LFB samples at low, mid, and high concentration levels, respectively.
Laboratory Method Blank (LMB) / Laboratory Reagent Blank (LRB) - is a sample of reagent water included in the sample batch analyzed in the same way as the associated field samples. The LMB is used to determine if method analytes or other background contamination have been introduced during the preparation or analytical procedure. The LMB is analyzed exactly the same as the field samples.
Laboratory Trip Blank (LTB) / Field Reagent Blank (FRB) - is a sample of laboratory reagent water placed in a sample container in the laboratory and treated as a field sample, including storage, preservation, and all analytical procedures. The FRB/LTB container follows the collection bottles to and from the collection site, but the FRB/LTB is not opened at any time during the trip. The FRB/LTB is primarily a travel blank used to verify that the samples were not contaminated during shipment.
Matrix Spike Duplicate Sample (MSD) / Laboratory Fortified Sample Matrix Duplicate (LFSMD) - is a sample aliquot taken from the same field sample source as the Matrix Spike Sample to which known quantities of the analytes of interest are added in the laboratory. The MSD is analyzed exactly the same as the field samples. Analysis of the MSD provides a measure of the precision of the laboratory procedures in a specific matrix. SDL, SDM, and SDH / LFSMDL, LFSMDM, and LFSMDH are the MSD or LFSMD at low, mid, and high concentration levels, respectively.
Matrix Spike Sample (MS) / Laboratory Fortified Sample Matrix (LFSM) - is a sample aliquot taken from field sample source to which known quantities of the analytes of interest are added in the laboratory. The MS is analyzed exactly the same as the field samples. The purpose is to demonstrate recovery of the analytes from a sample matrix to determine if the specific matrix contributes bias to the analytical results. MSL, MSM, and MSH / LFSML, LFSMM, and LFSMH are the MS or LFSM at low, mid, and high concentration levels, respectively.
Quality Control Standard (QCS) / Second Source Calibration Verification (SSCV) - is a solution containing known concentrations of the analytes of interest prepared from a source different from the source of the calibration standards. The solution is obtained from a second manufacturer or lot if the lot can be demonstrated by the manufacturer as prepared independently from other lots. The QCS sample is analyzed using the same procedures as field samples. The QCS is used as a check on the calibration standards used in the method on a routine basis.
Reporting Limit Check (RLC) / Initial Calibration Check Standard (ICCS) - is a procedural standard that is analyzed each day to evaluate instrument performance at or below the minimum reporting limit (MRL).
Surrogate Standard (SS) / Surrogate Analyte (SUR) - is a pure compound with properties similar to the analytes of interest, which is highly unlikely to be found in any field sample, that is added to the field samples, calibration standards, blanks and quality control standards before sample preparation. The SS is used to evaluate the efficiency of the sample preparation process.
Page 1 of 1
Page 27 of 43
Page 28 of 43
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7 /~ I t-1 ,.; 111 i •. /0 )( rc; o3o3lf o - o, - \ n.u 8 l~7- tf/ ,~I 11 l '-'~ X. [ 9030'.2,L) l_o - 0'6 - \ () . "2--9 ,~.3 :t/1.~M 1q '. 2,1,.. )( / q O ?JO.~L l,Q -Ql)- \ 0 .2-10 f ?j-/ L{{ /<;, ,ci I lt3S- X. 10 O';o 2.,L H o - 10 - , () ,L(
I ,v L~~ ~ ,c:; 11'1 10· .. iw )(_ 110~0~'1 l.P - 11-\ ~ {) .l) -s ,V I 11 '\
RELINQUISHED BY:(Signatu~ DATE TIME RECEIVED BY:(Signature) DATE TIME
~• c\('"~~ ~ 'i:l:,-1;\({,\ ts L\t11Y)\:\ LO(._ t.
~A;_ \ Vla~ OC was not igned at AM PM AMI PM RELINQUISHED BY:(Signature) DATE TIME RECEIVED BY:(Signature) DATE TIME
"Relinquished bv" bv Client
,~\ 0,
AM PM AM I PM CONDITIONS UPON RECEIPT: Iced: Wet / Blue Check if received on day of collection: D RELINQUISHED BY:(Signature) DATE TIME RECEIVED FOR LABORATORY BY: DATE TIME Samples received within 48 hours of collection must be received at a temperature of s 1o•c.
Samples received past 48 hours of collection are only valid if received at s 6°C, verified and documented that the samples were refrigerated between collection and shipment. Temperature requirements apply to
AM PM AMI PM all methods EXCEPT 200.8 and 300.0. KEY UCMR4 acceptance criteria for Receiving Checks: *Sampling Point Type Code:
" See Metal Sa m p les Preservation 200.8 p H < 2 541 pH < 3 SR = source water taken from plant intake; u ntreated water entering the water treatm e nt p lant Log 525.3 pH !i 4 544 pH 6 .5-7.5 EP = e ntry poin t to the distributio n syste m P = Present 530 pH about 7 (6-8) TOC p H < 2 DS = d istribution system sample A = A bsent Must be absent of residual chlorine(free): 525.3, 530,541.544, 545. 546, and 552.3.
Note in Comments section any samples which do not meet acceptance criteria. 06-LO-F0912 Issue: 5.0 Effective Dalo: 2018-01-18
Sample analysis will be provided according to the standard EENWater Services Tenns. which are available upon request. Any other terms proposed by Customer are deemed material alterations and are rejected unless expressly agree to in writing by EEA.
Page 29 of 43
• !\ eurofins 110 S. Hill Street Order# 3S-C,/ 0 L '-{ -: .. South Bend, IN 46617
T: 1.800.332.4345
Eaton Analytical F: 1.574.233.8207 Batch#
www Eurofinsus com/Eaton UCMR 4 CHAIN OF CUSTODY RECORD Page_of __
Shaded area for EEA use onlv CLIENT NAME: SAMPLER (Print name) *PWS ID# STATE of sample origin Check if this is a resample D
Check if roquires upload to EPA database D Example. IN1234567 we must have info for fields indicated with• for
PO#: If samples are not shipped the same day as collection then the temperature upload
Bill To: the samples were held at must be recorded here{°C):
- *Sampling Event
Preservative Cl)
Last 1 Addltionals SEH 1 SEH2 a: Sampling Evont # _ __
SEH3 SEH4 Checks w z
(see at0f\3bolow) ~ *FACILITY ID: (pe r EPA •sampling z
COLLECTION *SAMPLE POINT ID: (per EPA Temperature Upon pH Rosldual 0
LAB Number Requirement)-5 Point Type Test Name UCMR4- u Requirement)-20 characters max Lab Receipt ·c accep• Chlorine u.
0 DATE TIME AM PM characters max Code table?, IP/Al ..
11421111 \?-Jln .J.I. t.J/i<::, IA \\'. ~ )(_ IOi O ~03LJ /,n - 1-Z..- \ 552.3 HAAs () 0 NA A- 1
2
3
4
5
6
7
8 . . - - -I -+ 9 I\ , ~. led COv was nul , JI y_, I:-,, u l.A\.
10 " i: olinnuished bV t: y l.,llel IL I
11
RELINQUISHED BY:{Signature) DATE TIME RECEIVED BY:{Signature) DATE TIME LAB COMMENTS frwY\A VJD+H< ~ G\ i ¼ h CO c *A'\ -, (\+a t-Cl.~V\ AM PM AMI PM
RELINQUISHED BY:(Signature) DATE TIME RECEIVED BY:(Signature) DATE TIME
AM PM AMI PM CONDITIONS UPON RECEIPT: Iced: Wet/ Blue Check if received on day of collection: D RELINQUISHED BY:(Signature) DATE TIME RECEIVED FOR LABORATORY BY: DATE TIME Samples received within 48 hours of collection must be received at a temperature of s 1 o•c.
Samples received past 48 hours of colleclion are only valid if received at s 5•c, verified and documented that the samples were refrigerated between collection and shipment. Temperature requirements apply to
AM PM AM I PM all methods EXCEPT 200.8 and 300.0. KEY UCMR4 acceptance criteria for Receiving Checks: *Sampling Point Type Code:
~ See Metal Samples P reservation 200.8 pH < 2 541 pH< 3 SR = source water taken from plant intake; untreated water entering the water treatment plant Log 525.3 pH s 4 544 pH 6.5-7.5 EP = entry point to the distribution system P = Present 530 pH about 7 (6-8) TOG pH< 2 OS = distribution system sample A = Absent Must be absent of residual chlorine(free): 525.3, 530, 541, 544, 545, 546, and 552.3.
Note in Comments section any samples which do not meet acceptance criteria. 06-LO-F0912 Issue: 5.0 Effective Oate: 2018-01-18
Sample analysis will be provided according to the standard EEAfWater Services Terms, which are available upon request. Any other terms proposed by Customer are deemed material alterations and are rejected unless expressly agree to in writing by EEA.
Page 30 of 43
Subcontracted Chain of Custody ~----- ---------~ ~------=--------- -----
Sample ID:
19030346-01-1
Address:
Collector:
19030346-02-1
Address:
Collector:
19030346-03-1
Address:
Collector:
19030346-04-1
Address·
Collector:
19030346-05-1
Address:
Collector.
19030346-06-1
Address:
Collector.
19030346-07-1
Address:
Collector
19030346-08-1
Address:
Collector.
19030346-09-1
Address:
Collector
Hillsborough County 1 ,r u Public Utilities
Customer: PWS#
South Central CWS 6290787
1309 WindJammer Pl -·-,--.. , ____ ,, .
(Environmental Specialist I) Title:
South Central CWS 6290787
415 Smithfield Ln -·-,--.. , ----·· (Environmental Specialist I) Title:
South Central CWS 6290787
1107 N Lenna Ave - ·-,--.. , ____ ,, ,
(Environmental Specialist I) TIiie:
South Central CWS 6290787
113 Holly Tree Ln -·-,--.. , .,._._.., .. (Environmental Specialist I) Title:
South Central CWS 6290787
6912 Ohio Ave
(En~ironmental Specialist I) Title:
South Central CWS 6290787
807 4th Av SW -·-,--··· -----·· (Environmental Specialist I) Title:
South Central CWS 6290787
10130 Harney Rd
(En~ironmental Specialist I) Title.
South Central CWS 6290787
336 Brandywine Dr -·-,--··· ----· · (Environmental Specialist I) Title:
South Central CWS 6290787
6110 Nundy Ave -·-,--··· ........... . (Environmental Specialist I) Title:
RP.nnrt r,.,npr:,fprl· n d / 1t:;/?n1Q 1d·dQ
Environmental Laboratory
9456 E Columbus Dr Tampa, FL 33619
Certification Number: E44104
Phone No. (813) 272-5977 x 43635
Site: Collection DatefTime:
SC-024 Start: 4/1512019 1:26:00 PM
End: 4115/2019 1:26:00 PM
Environmental Specialist I
SC-037 Start: 411512019 10:18:00 AM
End: 4115/2019 10:18:00 AM
Environmental Specialist I
SC-045 Start: 4115/2019 2:44:00 PM
End: 4/15/2019 2:44:00 PM
Environmental Specialist I
SC-062 Start: 4/15/2019 12:48:00 PM
End: 4/ 15/2019 12:48:00 PM
Environmental Specialist I
SC-085 Start: 4/15/2019 9:06:00 AM
End: 4/1512019 9:06:00 AM
Environmental Specialist I
SC-090 Start: 4/15/2019 10:00:00 AM
End: 4/15/2019 10:00:00 AM
Environmental Specialist I
SC-093 Start: 4/15/2019 2:10:00 PM
End: 4115/2019 2:10:00 PM
Environmental Specialist I
SC-099 Start: 4/ 15/2019 1:14:00 PM
End: 4/15/2019 1:14:00 PM
Environmental Specialist I
SC-113 Start: 4/1512019 9:22:00 AM
End: 4/15/2019 9:22:00 AM
Environmental Specialist I
II I I II I 111111111111111 WorkOrder: 19030346
Scheduled Sample SC - UCMR4 HAA9 Set Name:
Subcontracted Vendor: Eurofins Eaton Analytical '---------LLC
Customer: South Central CWS
Project: SC - UCMR4-HAA
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile#
Sample Information Sample Type: Container Type: Preservative: Analysis Method: Analytes:
Drinking Water Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
(Grab)
Drinking Water Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
(Grab)
Drinking Water Glass 250 ml Amber NH4CL 552.3 - HAA9 Subcontracted
(Grab)
Drinking Water Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
(Grab)
Drinking Water Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
(Grab)
Drinking Waler Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
(Grab)
Drinking Water Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
(Grab)
Drinking Waler Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
(Grab)
Drinking Water Glass 250 ml Amber NH4CL 552.3 - HAA9 Subcontracted
(Grab)
P :>nP. 1 n f?
Page 31 of 43
Subcontracted Chain of Custody ,--------------------, .---------=--------------
Sample ID:
19030346-10-1
Address:
Collector:
19030346-11 -1
Address:
Collector:
19030346-12-1
Address:
Collector·
Hillsborough County 1 ... .-ida Public Utilities
Customer: PWS#
South Central CWS 6290787
11643 Whisper Creek Dr ..... -, ....... , .,. ___ , ,
(Environmental Specialist I) Title:
South Central CWS 6290787
12121 Colonial Estates Ln ....... , ... .... , ...... ...... (Environmental Specialist I) Title:
South Central CWS 6290787
1534 Del Webb Blvd ---, --.. , ............ (Environmental Specialist I) Tille:
E nvironmental Laboratory
9456 E Columbus Dr Tampa, FL 33619
Certification Number: E441O4
Phone N o . (813) 272-5977 x 43635
Site: Collection Date/Time:
SC-117 Stan: 4/15/2019 11 :35:00 AM
End: 4/1512019 11 :35:00 AM
Environmental Specialist I
SC-167 Stan: 4115/2019 10:36:00 AM
End: 411512019 10·36:00 AM
Environmental Specialist I
SC-154 Stan: 4/15/2019 11:50:00 AM
End: 411512019 11:50:00 AM
Environmental Specialist I
II I I II I 111111111111111 Work Order: 19030346
Scheduled Sample SC - UCMR4 HAA9 Set Name:
Subcontracted Vendor: Eurofins Eaton Analytical
'--------LLC
Customer: South Central CWS
Project: SC - UCMR4-HAA
Contact: Stanley, John (Chief Environmental Scientist)
Phone: (813) 272-5977 x 43635
Profile#
Sample Information Sample Type: Container Type: Preservative: Analysis Method: Analytes:
Drinking Waler Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
(Grab)
Drinking Waler Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
(Grab)
Drinking Waler Glass 250 ml Amber NH4Cl 552.3 - HAA9 Subcontracted
(Grab)
ReUnquosheo By. / / rw II n Dot~lk-;rr~ AcceptedB~ Date/Time 11 Notes.
IS~ 4 /1t1 I I Cj Ji.)' .<P Relinqutshed By / Date/ nme Accepted By Datcrnmc
Relinquished By· Date/Time Accepted By· Date/Tune
RP.nnrt ('.;p npr:atPrl· nLl/1!'il?n1Q 14·,rn P,.nP? n f ?
1
Jessie Brasch
Subject: FW: Incoming April 2019 UCMR4 sampling
From: Stanley, John [mailto:[email protected]] Sent: Tuesday, April 16, 2019 8:44 AM To: Jessie Brasch Cc: Watson, Edward Subject: Incoming April 2019 UCMR4 sampling
EXTERNAL EMAIL*
Hello Jessie, We sampled our April 2019 UCMR4 yesterday and they should arrive in South Bend today (UPS Tracking Numbers: J4634795594, J4634795601, J4634795610) Here is the information cross reference:
HCPUD Sample ID EPA Sample point ID Facility ID SP Type Sample Point Name
19030346‐01 SC1 00004 DS SC1 1309 Windjammer Place
19030346‐02 SC2 00004 DS SC2 415 Smithfield Lane
19030346‐03 SC3 00004 DS SC3 1107 S. Lenna Ave
19030346‐04 SC4 00004 DS SC4 113 Holly Lane
19030346‐05 SC5 00004 DS SC5 6912 Ohio Ave
19030346‐06 SC6 00004 DS SC6 807 4th Ave SW
19030346‐07 SC7 00004 DS SC7 10130 Harney Rd.
19030346‐08 SC8 00004 DS SC8 336 Brandywine
19030346‐09 SC9 00004 DS SC9 6110 Nundy Ave
19030346‐10 SC10 00004 DS SC10 11843 Whisper Creek Dr
19030346‐11 SC11 00004 DS SC11 12121 Colonial Estates
19030346‐12 SC12 00004 DS SC12 1534 Del Webb Ave
19030347‐01 0787002 00002 EP Central WTP POE
19030347‐02 0787001 00001 EP Lithia WTP POE
Let me know if you need any other information. Regards,
John K. Stanley Chief Environmental Scientist Public Utilities: Environmental Services Division ‐ Environmental Laboratory
Page 32 of 43
Eurofins Eaton AnalyticalRun Log
Run ID: 258332 Method: 552.3
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4270361 BF m 552.3 042419BF04/25/2019 15:56RW
LRB 4270356 BF m 552.3 042419BF04/25/2019 17:10RW
CCM 4270364 BF m 552.3 042419BF04/25/2019 23:51RW
FS 4261125 19030346-01-1 BF m 552.3 042419BF04/26/2019 02:53DW
FS 4261126 19030346-02-1 BF m 552.3 042419BF04/26/2019 03:30DW
FS 4261127 19030346-03-1 BF m 552.3 042419BF04/26/2019 04:06DW
FS 4261128 19030346-04-1 BF m 552.3 042419BF04/26/2019 04:42DW
FS 4261129 19030346-05-1 BF m 552.3 042419BF04/26/2019 06:32DW
FS 4261130 19030346-06-1 BF m 552.3 042419BF04/26/2019 07:08DW
FS 4261131 19030346-07-1 BF m 552.3 042419BF04/26/2019 07:45DW
CCH 4270366 BF m 552.3 042419BF04/26/2019 08:21RW
0.00
Page 1 of 5 EEA Run ID 258332 / EEA Report # 449090
Page 33 of 43
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<
04
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Page 2
of
5E
EA
Run I
D 2
58332 /
EE
A R
eport
# 4
49090
Page 34 of 43
D D D D
.___.ODD□□ DDDDDDDD DODD□ DODD□ DDDDDDD
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90
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34
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---
---
---
---
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04
/24
/20
19
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:08
04
/26
/20
19
04
:42
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.04
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---
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---
<
04
/24
/20
19
07
:08
04
/26
/20
19
04
:42
Fals
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0.5
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.04
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112
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---
---
---
<
04
/24
/20
19
07
:08
04
/26
/20
19
04
:42
Fals
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552.3
N/A
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112
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.04
26
112
81
90
30
34
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---
---
50
- 1
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10
51
07
4
04
/24
/20
19
07
:08
04
/26
/20
19
04
:42
Fals
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l H
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34
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4-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
04
:42
Page 3
of
5E
EA
Run I
D 2
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EE
A R
eport
# 4
49090
Page 35 of 43
D D D
._....___. __ DDDDDDDD DODD□ DODD□ DDDDDDDD DODD
Sa
mp
leTyp
eE
EA
ID #
An
aly
zed
Ex
tra
cte
dR
PD
Un
its
Ta
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tA
mo
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tC
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IDM
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Me
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Lim
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QC
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ary
Rep
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)
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nic
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d552.3
N/A
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4.6
43
8ug
/L1
.04
26
112
91
90
30
34
6-0
5-1
---
---
70
- 1
30
93
5.0
0
4/2
4/2
01
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80
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rue
Bro
moch
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tic
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d552.3
0.3
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FS
1.7
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.04
26
112
91
90
30
34
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5-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
06
:32
Tru
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Bro
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aci
d552.3
0.5
00
FS
0.9
81
ug
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.04
26
112
91
90
30
34
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---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
06
:32
Tru
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Chlo
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aci
d552.3
0.3
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0.5
54
ug
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.04
26
112
91
90
30
34
6-0
5-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
06
:32
Tru
e
Dib
rom
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tic
aci
d552.3
0.3
00
FS
1.1
3ug
/L1
.04
26
112
91
90
30
34
6-0
5-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
06
:32
Tru
e
Dic
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roace
tic
aci
d552.3
0.2
00
FS
1.9
6ug
/L1
.04
26
112
91
90
30
34
6-0
5-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
06
:32
Tru
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Monobro
moace
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aci
d552.3
0.3
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FS
0.3
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ug
/L1
.04
26
112
91
90
30
34
6-0
5-1
---
---
---
---
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04
/24
/20
19
07
:08
04
/26
/20
19
06
:32
Tru
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Monoch
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aci
d552.3
2.0
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.00
ug
/L1
.04
26
112
91
90
30
34
6-0
5-1
---
---
---
---
<
04
/24
/20
19
07
:08
04
/26
/20
19
06
:32
Tru
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Tri
bro
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aci
d552.3
2.0
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.00
ug
/L1
.04
26
112
91
90
30
34
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5-1
---
---
---
---
<
04
/24
/20
19
07
:08
04
/26
/20
19
06
:32
Tru
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aci
d552.3
0.5
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FS
0.5
00
ug
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.04
26
112
91
90
30
34
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5-1
---
---
---
---
<
04
/24
/20
19
07
:08
04
/26
/20
19
06
:32
Tru
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IS-1
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chlo
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ropane
552.3
N/A
FS
112
0ug
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.04
26
112
91
90
30
34
6-0
5-1
---
---
50
- 1
50
10
41
07
4
04
/24
/20
19
07
:08
04
/26
/20
19
06
:32
Tru
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l H
AA
5552.3
2.0
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S3
.09
ug
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.04
26
112
91
90
30
34
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---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
06
:32
Fals
e
SS
-2-B
rom
opro
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nic
aci
d552.3
N/A
FS
4.5
34
9ug
/L1
.04
26
113
01
90
30
34
6-0
6-1
---
---
70
- 1
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d552.3
0.3
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1.8
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.04
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113
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04
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:08
04
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:08
Fals
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0.5
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0.7
70
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.04
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113
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30
34
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6-1
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---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:08
Fals
e
Chlo
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tic
aci
d552.3
0.3
00
FS
0.3
35
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/L1
.04
26
113
01
90
30
34
6-0
6-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:08
Fals
e
Dib
rom
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aci
d552.3
0.3
00
FS
0.7
13
ug
/L1
.04
26
113
01
90
30
34
6-0
6-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:08
Fals
e
Dic
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roace
tic
aci
d552.3
0.2
00
FS
2.5
8ug
/L1
.04
26
113
01
90
30
34
6-0
6-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:08
Fals
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Monobro
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tic
aci
d552.3
0.3
00
FS
0.3
00
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/L1
.04
26
113
01
90
30
34
6-0
6-1
---
---
---
---
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04
/24
/20
19
07
:08
04
/26
/20
19
07
:08
Fals
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Monoch
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aci
d552.3
2.0
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.04
26
113
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30
34
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6-1
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---
---
---
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04
/24
/20
19
07
:08
04
/26
/20
19
07
:08
Fals
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d552.3
2.0
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.00
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.04
26
113
01
90
30
34
6-0
6-1
---
---
---
---
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04
/24
/20
19
07
:08
04
/26
/20
19
07
:08
Fals
e
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d552.3
0.5
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0.5
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.04
26
113
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90
30
34
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---
---
---
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04
/24
/20
19
07
:08
04
/26
/20
19
07
:08
Fals
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chlo
rop
ropane
552.3
N/A
FS
112
2ug
/L1
.04
26
113
01
90
30
34
6-0
6-1
---
---
50
- 1
50
10
41
07
4
04
/24
/20
19
07
:08
04
/26
/20
19
07
:08
Fals
e
Tota
l H
AA
5552.3
2.0
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S3
.29
3ug
/L1
.04
26
113
01
90
30
34
6-0
6-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:08
Tru
e
SS
-2-B
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opro
pio
nic
aci
d552.3
N/A
FS
4.5
22
2ug
/L1
.04
26
113
11
90
30
34
6-0
7-1
---
---
70
- 1
30
90
5.0
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01
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80
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01
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rue
Bro
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aci
d552.3
0.3
00
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1.9
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.04
26
113
11
90
30
34
6-0
7-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:45
Tru
e
Bro
modic
hlo
roace
tic
aci
d552.3
0.5
00
FS
1.3
3ug
/L1
.04
26
113
11
90
30
34
6-0
7-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:45
Tru
e
Chlo
rodib
rom
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tic
aci
d552.3
0.3
00
FS
0.7
29
ug
/L1
.04
26
113
11
90
30
34
6-0
7-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:45
Tru
e
Dib
rom
oace
tic
aci
d552.3
0.3
00
FS
2.1
8ug
/L1
.04
26
113
11
90
30
34
6-0
7-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:45
Tru
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Dic
hlo
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tic
aci
d552.3
0.2
00
FS
1.1
7ug
/L1
.04
26
113
11
90
30
34
6-0
7-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:45
Tru
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Monobro
moace
tic
aci
d552.3
0.3
00
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0.3
31
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/L1
.04
26
113
11
90
30
34
6-0
7-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:45
Tru
e
Monoch
loro
ace
tic
aci
d552.3
2.0
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S2
.00
ug
/L1
.04
26
113
11
90
30
34
6-0
7-1
---
---
---
---
<
04
/24
/20
19
07
:08
04
/26
/20
19
07
:45
Tru
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Tri
bro
moace
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aci
d552.3
2.0
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.00
ug
/L1
.04
26
113
11
90
30
34
6-0
7-1
---
---
---
---
<
04
/24
/20
19
07
:08
04
/26
/20
19
07
:45
Tru
e
Tri
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aci
d552.3
0.5
00
FS
0.5
00
ug
/L1
.04
26
113
11
90
30
34
6-0
7-1
---
---
---
---
<
04
/24
/20
19
07
:08
04
/26
/20
19
07
:45
Tru
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chlo
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ropane
552.3
N/A
FS
110
3ug
/L1
.04
26
113
11
90
30
34
6-0
7-1
---
---
50
- 1
50
10
31
07
4
04
/24
/20
19
07
:08
04
/26
/20
19
07
:45
Tru
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Tota
l H
AA
5552.3
2.0
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.68
1ug
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.04
26
113
11
90
30
34
6-0
7-1
---
---
---
---
04
/24
/20
19
07
:08
04
/26
/20
19
07
:45
Fals
e
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rom
opro
pio
nic
aci
d552.3
N/A
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H5
.01
29
ug
/L1
.04
27
03
66
---
---
---
70
- 1
30
10
05
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04
/24
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19
07
:08
04
/26
/20
19
08
:21
Fals
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Bro
moch
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ace
tic
aci
d552.3
0.3
00
CC
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5.7
71
2ug
/L1
.04
27
03
66
---
---
---
70
- 1
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10
51
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01
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tic
aci
d552.3
0.5
00
CC
H2
8.2
26
1ug
/L1
.04
27
03
66
---
---
---
70
- 1
30
113
25
.0
04
/24
/20
19
07
:08
04
/26
/20
19
08
:21
Fals
e
Chlo
rodib
rom
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tic
aci
d552.3
0.3
00
CC
H1
7.5
36
6ug
/L1
.04
27
03
66
---
---
---
70
- 1
30
117
15
.0
04
/24
/20
19
07
:08
04
/26
/20
19
08
:21
Fals
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Dib
rom
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tic
aci
d552.3
0.3
00
CC
H1
5.5
07
2ug
/L1
.04
27
03
66
---
---
---
70
- 1
30
10
31
5.0
0
4/2
4/2
01
9 0
7:0
80
4/2
6/2
01
9 0
8:2
1
Page 4
of
5E
EA
Run I
D 2
58332 /
EE
A R
eport
# 4
49090
Page 36 of 43
D D D
._....___. __ DDDDDDDD DODD□ DODD□ DDDDDDDD DODD
Sa
mp
leTyp
eE
EA
ID #
An
aly
zed
Ex
tra
cte
dR
PD
Un
its
Ta
rge
tA
mo
un
tC
lie
nt
IDM
RL
Me
tho
dA
na
lyte
Dil
Fa
cto
rR
PD
Lim
itR
ec
ove
ryL
imit
s%
R
eco
ve
ryR
es
ult
Fla
g
QC
Su
mm
ary
Rep
ort
(co
nt.
)
Fals
e
Dic
hlo
roace
tic
aci
d552.3
0.2
00
CC
H9
.68
85
ug
/L1
.04
27
03
66
---
---
---
70
- 1
30
97
10
.0
04
/24
/20
19
07
:08
04
/26
/20
19
08
:21
Fals
e
Monobro
moace
tic
aci
d552.3
0.3
00
CC
H1
4.2
94
ug
/L1
.04
27
03
66
---
---
---
70
- 1
30
95
15
.0
04
/24
/20
19
07
:08
04
/26
/20
19
08
:21
Fals
e
Monoch
loro
ace
tic
aci
d552.3
2.0
0C
CH
28
.97
73
ug
/L1
.04
27
03
66
---
---
---
70
- 1
30
97
30
.0
04
/24
/20
19
07
:08
04
/26
/20
19
08
:21
Fals
e
Tri
bro
moace
tic
aci
d552.3
2.0
0C
CH
30
.28
85
ug
/L1
.04
27
03
66
---
---
---
70
- 1
30
10
13
0.0
0
4/2
4/2
01
9 0
7:0
80
4/2
6/2
01
9 0
8:2
1F
als
e
Tri
chlo
roace
tic
aci
d552.3
0.5
00
CC
H2
6.2
55
6ug
/L1
.04
27
03
66
---
---
---
70
- 1
30
10
52
5.0
0
4/2
4/2
01
9 0
7:0
80
4/2
6/2
01
9 0
8:2
1F
als
e
IS-1
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-Tri
chlo
rop
ropane
552.3
N/A
CC
H1
04
9ug
/L1
.04
27
03
66
---
---
---
50
- 1
50
98
10
74
0
4/2
4/2
01
9 0
7:0
80
4/2
6/2
01
9 0
8:2
1
Page 5
of
5E
EA
Run I
D 2
58332 /
EE
A R
eport
# 4
49090
Page 37 of 43DD DOD
Eurofins Eaton AnalyticalRun Log
Run ID: 258413 Method: 552.3
Sample SiteSample IdType Instrument ID Calibration FileAnalysis DateMatrix
CCL 4271709 BP m 552.3 042619BP04/26/2019 09:24RW
QCS 4271724 BP m 552.3 042619BP04/26/2019 10:36RW
LRB 4271707 BP m 552.3 042619BP04/26/2019 11:12RW
CCM 4271711 BP m 552.3 042619BP04/26/2019 17:48RW
FS 4261132 19030346-08-1 BP m 552.3 042619BP04/26/2019 20:48DW
FS 4261133 19030346-09-1 BP m 552.3 042619BP04/26/2019 22:36DW
FS 4261134 19030346-10-1 BP m 552.3 042619BP04/26/2019 23:12DW
FS 4261135 19030346-11-1 BP m 552.3 042619BP04/26/2019 23:48DW
FS 4261136 19030346-12-1 BP m 552.3 042619BP04/27/2019 00:24DW
CCH 4271713 BP m 552.3 042619BP04/27/2019 01:01RW
0.00
Page 1 of 4 EEA Run ID 258413 / EEA Report # 449090
Page 38 of 43
=::: e u rofi n s I Eaton Analytical
QC
Su
mm
ary
Re
po
rt
EE
AID
#R
PD
Un
its
Ta
rge
tA
mo
un
tC
lie
nt
IDM
eth
od
An
aly
teS
am
ple
Typ
eD
ilF
ac
tor
RP
DL
imit
Re
co
ve
ryL
imit
s%
R
eco
ve
ryR
es
ult
Fla
gM
RL
Ex
tra
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na
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Fals
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rom
opro
pio
nic
aci
d552.3
N/A
CC
L4
.85
63
ug
/L1
.04
27
17
09
---
---
---
70
- 1
30
97
5.0
0
4/2
5/2
01
9 0
8:1
00
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6/2
01
9 0
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Bro
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loro
ace
tic
aci
d552.3
0.3
00
CC
L0
.34
91
ug
/L1
.04
27
17
09
---
---
---
50
- 1
50
116
0.3
0
4/2
5/2
01
9 0
8:1
00
4/2
6/2
01
9 0
9:2
4F
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Bro
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hlo
roace
tic
aci
d552.3
0.5
00
CC
L0
.45
55
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/L1
.04
27
17
09
---
---
---
50
- 1
50
91
0.5
0
4/2
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01
9 0
8:1
00
4/2
6/2
01
9 0
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4F
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Chlo
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rom
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tic
aci
d552.3
0.3
00
CC
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.37
02
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.04
27
17
09
---
---
---
50
- 1
50
12
30
.3
04
/25
/20
19
08
:10
04
/26
/20
19
09
:24
Fals
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Dib
rom
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aci
d552.3
0.3
00
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18
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27
17
09
---
---
---
50
- 1
50
114
0.3
0
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00
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6/2
01
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Dic
hlo
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d552.3
0.2
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74
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.04
27
17
09
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50
- 1
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99
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Monobro
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aci
d552.3
0.3
00
CC
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.35
94
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.04
27
17
09
---
---
---
50
- 1
50
12
00
.3
04
/25
/20
19
08
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04
/26
/20
19
09
:24
Fals
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Monoch
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tic
aci
d552.3
2.0
0C
CL
1.6
91
6ug
/L1
.04
27
17
09
---
---
---
50
- 1
50
85
2.0
0
4/2
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8:1
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4/2
6/2
01
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Tri
bro
moace
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d552.3
2.0
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CL
1.7
59
1ug
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.04
27
17
09
---
---
---
50
- 1
50
88
2.0
0
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01
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8:1
00
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01
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d552.3
0.5
00
CC
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.58
28
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.04
27
17
09
---
---
---
50
- 1
50
117
0.5
0
4/2
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01
9 0
8:1
00
4/2
6/2
01
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chlo
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552.3
N/A
CC
L1
27
5ug
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.04
27
17
09
---
---
---
50
- 1
50
10
11
25
7
04
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19
08
:10
04
/26
/20
19
09
:24
Tru
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nic
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d552.3
N/A
QC
S5
.07
91
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.04
27
17
24
---
---
---
70
- 1
30
10
25
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04
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19
08
:10
04
/26
/20
19
10
:36
Tru
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Bro
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loro
ace
tic
aci
d552.3
0.3
00
QC
S5
.88
9ug
/L1
.04
27
17
24
---
---
---
70
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98
6.0
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Bro
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tic
aci
d552.3
0.5
00
QC
S7
.10
13
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.04
27
17
24
---
---
---
70
- 1
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71
10
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04
/25
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19
08
:10
04
/26
/20
19
10
:36
Tru
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Chlo
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tic
aci
d552.3
0.3
00
QC
S4
.67
85
ug
/L1
.04
27
17
24
---
---
---
70
- 1
30
78
6.0
0
4/2
5/2
01
9 0
8:1
00
4/2
6/2
01
9 1
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rue
Dib
rom
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tic
aci
d552.3
0.3
00
QC
S5
.90
99
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.04
27
17
24
---
---
---
70
- 1
30
98
6.0
0
4/2
5/2
01
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8:1
00
4/2
6/2
01
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rue
Dic
hlo
roace
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aci
d552.3
0.2
00
QC
S4
.16
61
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.04
27
17
24
---
---
---
70
- 1
30
10
44
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04
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19
08
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04
/26
/20
19
10
:36
Tru
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Monobro
moace
tic
aci
d552.3
0.3
00
QC
S5
.63
11ug
/L1
.04
27
17
24
---
---
---
70
- 1
30
94
6.0
0
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01
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8:1
00
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01
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Monoch
loro
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tic
aci
d552.3
2.0
0Q
CS
38
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79
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27
17
24
---
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---
70
- 1
30
97
40
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19
08
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04
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19
10
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Tru
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bro
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aci
d552.3
2.0
0Q
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18
.05
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.04
27
17
24
---
---
---
70
- 1
30
90
20
.0
04
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/20
19
08
:10
04
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/20
19
10
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Tru
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tic
aci
d552.3
0.5
00
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.76
83
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/L1
.04
27
17
24
---
---
---
70
- 1
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98
10
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04
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19
08
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04
/26
/20
19
10
:36
Tru
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chlo
rop
ropane
552.3
N/A
QC
S1
28
6ug
/L1
.04
27
17
24
---
---
---
50
- 1
50
10
21
25
7
04
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/20
19
08
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04
/26
/20
19
10
:36
Fals
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rom
opro
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nic
aci
d552.3
N/A
LR
B5
.14
30
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/L1
.04
27
17
07
---
---
---
70
- 1
30
10
35
.0
04
/25
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19
08
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04
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19
11
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Fals
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moch
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tic
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d552.3
0.3
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27
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27
17
07
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---
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04
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17
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27
17
07
---
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04
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d552.3
0.5
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.04
27
17
07
---
---
---
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04
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08
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04
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19
11
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Fals
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552.3
N/A
LR
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27
7ug
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.04
27
17
07
---
---
---
50
- 1
50
10
21
25
7
04
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19
08
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04
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19
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N/A
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.82
87
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.04
27
17
11--
---
---
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13
09
75
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04
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19
08
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04
/26
/20
19
17
:48
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tic
aci
d552.3
0.3
00
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.87
16
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.04
27
17
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---
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86
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04
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19
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04
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19
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d552.3
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.05
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/20
19
08
:10
04
/26
/20
19
17
:48
Page 2
of
4E
EA
Run I
D 2
58413 /
EE
A R
eport
# 4
49090
Page 39 of 43
D D D D
.___.ODD□□ DDDDDDDD DODD□ DODD□ DDDDDDD
Sa
mp
leTyp
eE
EA
ID #
An
aly
zed
Ex
tra
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dR
PD
Un
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Ta
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mo
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Me
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Fa
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rR
PD
Lim
itR
ec
ove
ryL
imit
s%
R
eco
ve
ryR
es
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Fla
g
QC
Su
mm
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Rep
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(co
nt.
)
Tru
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Monoch
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tic
aci
d552.3
2.0
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CM
20
.57
34
ug
/L1
.04
27
17
11--
---
---
-7
0 -
13
01
03
20
.0
04
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19
08
:10
04
/26
/20
19
17
:48
Tru
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Tri
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tic
aci
d552.3
2.0
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CM
19
.39
61
ug
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.04
27
17
11--
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72
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0
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d552.3
0.5
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14
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27
17
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71
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01
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rue
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552.3
N/A
CC
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30
7ug
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.04
27
17
11--
---
---
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15
01
04
12
57
0
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d552.3
N/A
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4.8
41
4ug
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.04
26
113
21
90
30
34
6-0
8-1
---
---
70
- 1
30
97
5.0
0
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Bro
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d552.3
0.3
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1.1
1ug
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.04
26
113
21
90
30
34
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8-1
---
---
---
---
04
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19
08
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04
/26
/20
19
20
:48
Fals
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Bro
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roace
tic
aci
d552.3
0.5
00
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0.5
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.04
26
113
21
90
30
34
6-0
8-1
---
---
---
---
<
04
/25
/20
19
08
:10
04
/26
/20
19
20
:48
Fals
e
Chlo
rodib
rom
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tic
aci
d552.3
0.3
00
FS
0.3
59
ug
/L1
.04
26
113
21
90
30
34
6-0
8-1
---
---
---
---
04
/25
/20
19
08
:10
04
/26
/20
19
20
:48
Fals
e
Dib
rom
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aci
d552.3
0.3
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0.4
86
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/L1
.04
26
113
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30
34
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8-1
---
---
---
---
04
/25
/20
19
08
:10
04
/26
/20
19
20
:48
Fals
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d552.3
0.2
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1.8
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.04
26
113
21
90
30
34
6-0
8-1
---
---
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Page 3
of
4E
EA
Run I
D 2
58413 /
EE
A R
eport
# 4
49090
Page 40 of 43
D D D
._....___. __ DDDDDDDD DODD□ DODD□ DDDDDDDD DOD
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.49
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/L1
.04
26
113
61
90
30
34
6-1
2-1
---
---
---
---
04
/25
/20
19
08
:10
04
/27
/20
19
00
:24
Tru
e
SS
-2-B
rom
opro
pio
nic
aci
d552.3
N/A
CC
H5
.11
99
ug
/L1
.04
27
17
13
---
---
---
70
- 1
30
10
25
.0
04
/25
/20
19
08
:10
04
/27
/20
19
01
:01
Tru
e
Bro
moch
loro
ace
tic
aci
d552.3
0.3
00
CC
H1
5.3
76
ug
/L1
.04
27
17
13
---
---
---
70
- 1
30
10
31
5.0
0
4/2
5/2
01
9 0
8:1
00
4/2
7/2
01
9 0
1:0
1T
rue
Bro
modic
hlo
roace
tic
aci
d552.3
0.5
00
CC
H2
3.3
52
4ug
/L1
.04
27
17
13
---
---
---
70
- 1
30
93
25
.0
04
/25
/20
19
08
:10
04
/27
/20
19
01
:01
Tru
e
Chlo
rodib
rom
oace
tic
aci
d552.3
0.3
00
CC
H1
3.8
60
3ug
/L1
.04
27
17
13
---
---
---
70
- 1
30
92
15
.0
04
/25
/20
19
08
:10
04
/27
/20
19
01
:01
Tru
e
Dib
rom
oace
tic
aci
d552.3
0.3
00
CC
H1
5.6
30
6ug
/L1
.04
27
17
13
---
---
---
70
- 1
30
10
41
5.0
0
4/2
5/2
01
9 0
8:1
00
4/2
7/2
01
9 0
1:0
1T
rue
Dic
hlo
roace
tic
aci
d552.3
0.2
00
CC
H1
0.1
88
2ug
/L1
.04
27
17
13
---
---
---
70
- 1
30
10
21
0.0
0
4/2
5/2
01
9 0
8:1
00
4/2
7/2
01
9 0
1:0
1T
rue
Monobro
moace
tic
aci
d552.3
0.3
00
CC
H1
6.3
03
4ug
/L1
.04
27
17
13
---
---
---
70
- 1
30
10
91
5.0
0
4/2
5/2
01
9 0
8:1
00
4/2
7/2
01
9 0
1:0
1T
rue
Monoch
loro
ace
tic
aci
d552.3
2.0
0C
CH
31
.76
12
ug
/L1
.04
27
17
13
---
---
---
70
- 1
30
10
63
0.0
0
4/2
5/2
01
9 0
8:1
00
4/2
7/2
01
9 0
1:0
1T
rue
Tri
bro
moace
tic
aci
d552.3
2.0
0C
CH
28
.35
21
ug
/L1
.04
27
17
13
---
---
---
70
- 1
30
95
30
.0
04
/25
/20
19
08
:10
04
/27
/20
19
01
:01
Tru
e
Tri
chlo
roace
tic
aci
d552.3
0.5
00
CC
H2
5.4
58
9ug
/L1
.04
27
17
13
---
---
---
70
- 1
30
10
22
5.0
0
4/2
5/2
01
9 0
8:1
00
4/2
7/2
01
9 0
1:0
1T
rue
IS-1
,2,3
-Tri
chlo
rop
ropane
552.3
N/A
CC
H1
28
7ug
/L1
.04
27
17
13
---
---
---
50
- 1
50
10
21
25
7
04
/25
/20
19
08
:10
04
/27
/20
19
01
:01
Page 4
of
4E
EA
Run I
D 2
58413 /
EE
A R
eport
# 4
49090
Page 41 of 43
D D D
._....___. __ DDDDDDDD DODD□ DODD□ DDDDDD
Sa
mp
le T
yp
e K
ey
Typ
e (
Ab
br.
)S
am
ple
Typ
eTyp
e (
Ab
br.
)S
am
ple
Typ
e
CC
HC
ontin
uin
g C
alib
ratio
n H
igh
CC
LC
ontin
uin
g C
alib
ratio
n L
ow
CC
MC
ontin
uin
g C
alib
ratio
n M
id
FS
Fie
ld S
am
ple
LR
BLabora
tory
Reagent
Bla
nk
QC
SQ
ualit
y C
ontr
ol S
am
ple
1.0
0
Page 42 of 43
END OF REPORT
Page 43 of 43