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  • Green AmmoniaNovember 2017Ian Wilkinson

    siemens.comRestricted © Siemens AG 2017

  • Restricted © Siemens AG 2017November 2017Seite 2 CT

    The Role of "Green" Ammonia in Decarbonising Energy Systems

    • Why I think ammonia has a role to play – thetechnical argument;

    • How ammonia can play a role – the economicargument;

    • Practical demonstration: ammonia synthesis andenergy storage system demonstrator.

  • Restricted © Siemens AG 2017November 2017Seite 3 CT

    The scale of the task to decarbonise is considerable...

    Graphs are the work ofDr. Grant Wilson at theUniversity of Sheffield,reproduced with permission.

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    0 GWh

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    Data are from National Grid, Elexon and BEIS. Charts are licensed under an Attribution-NoDerivatives 4.0 International licenseCharts can be downloaded from http://bit.ly/energycharts

    by Dr Grant Wilson [email protected]

    2014 2015 2016 2017

    Great Britain’s Energy Vectors – in GWh per day

    Electricity demand = INDO + embedded generation

  • Restricted © Siemens AG 2017November 2017Seite 4 CT

    The scale of the task to decarbonise is considerable...

    Graphs are the work ofDr. Grant Wilson at theUniversity of Sheffield,reproduced with permission.

    Feb

    Mar Ap

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    ay Jun

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    0 GWh

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    hpe

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    Data are from National Grid, Elexon and BEIS. Charts are licensed under an Attribution-NoDerivatives 4.0 International licenseCharts can be downloaded from http://bit.ly/energycharts

    by Dr Grant Wilson [email protected]

    2014 2015 2016 2017

    Great Britain’s Energy Vectors – in GWh per day

    Transport fuel = DERV (Diesel)

  • Restricted © Siemens AG 2017November 2017Seite 5 CT

    The scale of the task to decarbonise is considerable...

    Graphs are the work ofDr. Grant Wilson at theUniversity of Sheffield,reproduced with permission.

    Feb

    Mar Ap

    rM

    ay Jun

    Jul

    Aug

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    1500 GWh

    2000 GWh

    2500 GWh

    3000 GWh

    3500 GWh

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    4500 GWh

    GW

    hpe

    rday

    30 GWh

    Data are from National Grid, Elexon and BEIS. Charts are licensed under an Attribution-NoDerivatives 4.0 International licenseCharts can be downloaded from http://bit.ly/energycharts

    by Dr Grant Wilson [email protected]

    2014 2015 2016 2017

    Great Britain’s Energy Vectors – in GWh per day

    Transport fuel = Motor Spirit (Petrol)

  • Restricted © Siemens AG 2017November 2017Seite 6 CT

    The scale of the task to decarbonise is considerable...

    Graphs are the work ofDr. Grant Wilson at theUniversity of Sheffield,reproduced with permission.

    Feb

    Mar Ap

    rM

    ay Jun

    Jul

    Aug

    Sep

    Oct

    Nov

    Dec Jan

    Feb

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    ay Jun

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    0 GWh

    500 GWh

    1000 GWh

    1500 GWh

    2000 GWh

    2500 GWh

    3000 GWh

    3500 GWh

    4000 GWh

    4500 GWh

    GW

    hpe

    rday

    30 GWh

    Data are from National Grid, Elexon and BEIS. Charts are licensed under an Attribution-NoDerivatives 4.0 International licenseCharts can be downloaded from http://bit.ly/energycharts

    by Dr Grant Wilson [email protected]

    2014 2015 2016 2017

    Great Britain’s Energy Vectors – in GWh per day

    Electricity from Non PS Hydro + Wind + Solar

  • Restricted © Siemens AG 2017November 2017Seite 7 CT

    Addressing energy storage needs will require a range of technologies

    1) Electro-Thermal Energy Storage 2) Compressed Air Energy Storage

    Storage time

    Chemicals: Methane / Hydrogen /Ammonia

    Flywheel storage(< 1MW Flywheel, up to 100 MW Turbines)

    Supercapacitor

    Flow-Batteries Pumped

    Hydro

    Thermo-mechanicalstorage

    Min

    utes

    Seco

    nds

    Hou

    rsW

    eeks

    1 kW Power100 kW 1 MW 10 MW 100 MW 1,000 MW

    Li-Ion

    NaS, Lead Acid

    NaNiCl

    AquionBatteries

    Day

    s

    Technology

    MechanicalElectrical

    Electrochemical

    ChemicalThermal

    Maturity

    ETES1)

    CAES2)

    ACAES3)

    3) Adiabatic Compressed Air Energy Storage

    Commercial

    DemonstrationEarly commercial

    Concept phase

  • Restricted © Siemens AG 2017November 2017Seite 8 CT

    Several potential markets exist for Green Ammonia:it is a carbon-free flexible asset

    Generation

    AgileAmmoniaSynthesis

    Solar Power

    Wind Power

    Electrolysis

    HydrogenStorage Transport Fuel for

    Fuel Cell Vehicles

    AmmoniaStorage

    Gas TurbinePower Generation

    Grid

    N2

    Air SeparationUnit

    Synthesis Use

    AmmoniaShipment

    AmmoniaCracking

    Feedstock (Fertiliseror other Industry)

    Reducingproduct value

    DSR / Gridbalancing services

  • Restricted © Siemens AG 2017November 2017Seite 9 CT

    Electrolyser CAPEX costs - An EU study

    Source:“Development of Water Electrolysisin the European Union“, E4techSàrl with Element Energy Ltd forthe Fuel Cells and Hydrogen JointUndertaking February 2014

    With acknowledgements toThomas Wasser, Siemens AG.

  • Restricted © Siemens AG 2017November 2017Seite 10 CT

    Low Bids for Solar PV

    Source:https://cleantechnica.com/2016/09/20/lowest-ever-solar-price-bid-2-42%C2%A2kwh-dropped-abu-dhabi-jinkosolar-marubeni-score/ With acknowledgements to

    Thomas Wasser, Siemens AG.

  • Restricted © Siemens AG 2017November 2017Seite 11 CT

    Green Ammonia production cost estimate – 200 MW plant

    BEIS“Low” LCOE2018-2030estimates

    BEIS“Central” LCOE2018-2030estimates

    Commodity price

    Electricity price

    Variables held constant:

    Control plant

    Electricity price has been calculated using90 GBP/MWh and a 50% ammonia-to-electricityconversion efficiency

    Source: “"Islanded power-to-ammonia production process: Key variables and their sensitivity”; R. Banares-Alcantara, R. Nayak-Luke, I. Wilkinson;Submitted to Computers & Chemical Engineering October 2017 with manuscript number CACE-D-17-00766.

    https://www.google.co.uk/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&uact=8&ved=0CAcQjRxqFQoTCJaN1pb56cgCFUg5GgodbGwMbw&url=https://en.wikipedia.org/wiki/File:University_of_Oxford.svg&bvm=bv.106379543,d.ZWU&psig=AFQjCNH3OXETPTxhBCLys6ox5uK4Mh4N_w&ust=1446285951581076

  • Restricted © Siemens AG 2017November 2017Seite 12 CT

    Green Ammonia production cost estimate – 200 MW plant

    BEIS“Low” LCOE2018-2030estimates

    BEIS“Central” LCOE2018-2030estimates

    Commodity price

    Electricity price

    Variables held constant:

    Control plant

    Electricity price has been calculated using90 GBP/MWh and a 50% ammonia-to-electricityconversion efficiency

    Source: “"Islanded power-to-ammonia production process: Key variables and their sensitivity”; R. Banares-Alcantara, R. Nayak-Luke, I. Wilkinson;Submitted to Computers & Chemical Engineering October 2017 with manuscript number CACE-D-17-00766.

    FCEV Hydrogen price at €10/kg

    FCEV Hydrogen price at €5/kg

    https://www.google.co.uk/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&uact=8&ved=0CAcQjRxqFQoTCJaN1pb56cgCFUg5GgodbGwMbw&url=https://en.wikipedia.org/wiki/File:University_of_Oxford.svg&bvm=bv.106379543,d.ZWU&psig=AFQjCNH3OXETPTxhBCLys6ox5uK4Mh4N_w&ust=1446285951581076

  • Restricted © Siemens AG 2017November 2017Seite 13 CT

    Several potential markets exist for Green Ammonia:it is a carbon-free flexible asset

    Generation

    AgileAmmoniaSynthesis

    Solar Power

    Wind Power

    Electrolysis

    HydrogenStorage Transport Fuel for

    Fuel Cell Vehicles

    AmmoniaStorage

    Gas TurbinePower Generation

    Grid

    N2

    Air SeparationUnit

    Synthesis Use

    AmmoniaShipment

    AmmoniaCracking

    Feedstock (Fertiliseror other Industry)

    Reducingproduct value

    DSR / Gridbalancing services

  • Restricted © Siemens AG 2017November 2017Seite 14 CT

    The Green Ammonia Demonstrator will show the complete cycle of renewablepower, storage as ammonia, and conversion back to electricity

    https://www.google.co.uk/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&uact=8&ved=0CAcQjRxqFQoTCJaN1pb56cgCFUg5GgodbGwMbw&url=https://en.wikipedia.org/wiki/File:University_of_Oxford.svg&bvm=bv.106379543,d.ZWU&psig=AFQjCNH3OXETPTxhBCLys6ox5uK4Mh4N_w&ust=1446285951581076https://www.google.co.uk/url?sa=i&rct=j&q=&esrc=s&frm=1&source=images&cd=&cad=rja&uact=8&ved=0CAcQjRxqFQoTCN7zraj56cgCFcrnGgodghsNiA&url=https://magicandthesupernaturalcardiff.wordpress.com/&bvm=bv.106379543,d.ZWU&psig=AFQjCNEhRv3TqCNTdmW05honm6JHRU-N0A&ust=1446285986304887

  • Restricted © Siemens AG 2017November 2017Seite 15 CT

    The main components of the Green Ammonia energy storage systemdemonstrator are: wind turbine, N2 generator, H2 electrolyser, ammoniareactor, and an internal combustion engine

    NH3 H-BReactor

    (Bespoke)

  • Restricted © Siemens AG 2017November 2017Seite 16 CT

    Test site, Combustion and Synthesis Containers

  • Restricted © Siemens AG 2017November 2017Seite 17 CT

    The demonstrator will be used to explore 4 development areas – and providea platform for future development work

    Ammonia combustion studiesHaber-Bosch synthesis catalyst

    Energy managementsystem

    Control system

  • Restricted © Siemens AG 2017November 2017Seite 18 CT

    Thank you for your attention!

    Dr. Ian WilkinsonCT REE

    [email protected]

    siemens.com

  • Restricted © Siemens AG 2017November 2017Seite 19 CT

    For further information, see

    http://www.siemens.co.uk/green-ammonia