shirinskaya anna gilles horowitz, yvan bonnassieux€¦ · gilles horowitz, yvan bonnassieux...
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Ph.D. Candidate Shirinskaya Anna
Professors: Gilles Horowitz, Yvan Bonnassieux
Organic Large Area Electronics (OLAE) Group, LPICM (CNRS UMR7647) Ecole polytechnique, Palaiseau, France
This project receives funding from the European Community's Seventh Framework Program under Grant Agreement n° 6078961
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Bioelectronics Biosensors
Electronic devices
Biological systems
Portable devices
Implantable devices
Real time monitoring and diagnostic
Actuation and therapy
Convergence of biologyand electronics
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OECT-Conductive polymer based transistor consists of three electrodes
(source, drain and gate) and two conducting layers: electrolyte and
conducting polymer
• Campana,A.;Cramer,T.;Simon,D.T.;Berggren,M.; Biscarin i, F. Adv. Mater. (Deerfield Beach, Fla.) 2014, 26, 3874.• Strakosas, X., Bongo, M. and Owens, R. M. (2015), The organic electrochemical transistor for biological applications. J. Appl.
Polym. Sci., 132, 41735.
Ion Sensors: react on change of ions
consentration and composition
Enzimatic Sensors: react on change of
local pH, on oxidation of species or transfer
of electrons to the gate of the device (e.g.
penicillin, glucose, ascorbic acid )
Immunosensors/Nucleotide
Sensors: detect presence of cells and
biomolecules
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OECT-Conductive polymer based transistor consists of three electrodes
(source, drain and gate) and two conducting layers: electrolyte and
conducting polymer
• Campana,A.;Cramer,T.;Simon,D.T.;Berggren,M.; Biscarin i, F. Adv. Mater. (Deerfield Beach, Fla.) 2014, 26, 3874.
Wide variety of fabrication methods
(also by low-cost printing techniques)
High curent modulation
High sensitivity
High stability in aquarious solutions
Biocompatability
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Immerced electrode structure Planar structure
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Structure: OECT consists ofthree electrodes (source, drainand gate), conductive dopedpolymer layer and electrolyte.
Operation mode: Normally-ontransistor. Voltage appliedbetween source and gatemodulate the current on thedrain
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Conductive polymer:PEDOT :PSS p-type semiconductor
Ionic conductor: Electrolyte
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Voltage applied between gate and source electrodes reduces amount of holes by polymer
reduction.
Result in OECT: current is decreasing with gate voltage increasing.
Stavrinidou, E., Leleux, P., Rajaona, H., Khodagholy, D., Rivnay, J., Lindau, M., Sanaur, S. and Malliaras, G. G. (2013), Direct Measurement of Ion Mobility in a Conducting Polymer. Adv. Mater., 25: 4488–4493.
Then positive electrolyte ions penetrate inside conductive layer to maintain electro neutrality.
Before voltage application
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PEDOT+ reduction, positive ions injection
Negative ions reaction at the electrode
Ions of electrolyte, electrons and holes distribution
PEDOT+ + e→ PEDOT0
𝑐𝑝𝑒𝑑𝑜𝑡 + =𝑐𝑖𝑛𝑖𝑡𝑖𝑎𝑙 _𝑝𝑒𝑑𝑜𝑡 +
1 + exp(𝑧𝐹𝑅𝑇
𝑉0 − 𝑉 )
X- → X0 + e
PSS - +Na+ → PSS - :Na+
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Poisson-Boltzmann equation
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*COMSOL Multiphysics® simulation software was used to obtain following results
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Vgs
Modelled 1D structure
consists of two point
electrodes at both sides
of line-layer of partially
dedoped PEDOT:PSS
with Na ions
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Model of moving front
under applied potential
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PEDOT+; PEDOT0 ; Na+ d=50 nm
Vds
L=200 nm
VgsModelled 2D structure
consists of three planar
electrodes: Drain and
grounded Source at the
bottom and Gate at the
top of partially dedoped
PEDOT:PSS with Na
ions.
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Potential distribution inside
PEDOT:PSS layer under applied Gate-
Source potential with Drain-Source
potential: Vds=-0.5V
𝑉𝑔𝑠 = 0.1 V
𝑉𝑔𝑠 = 0.6 V
𝑉𝑔𝑠 = 0.3 V
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𝑉𝑔𝑠 = 0.1 V
𝑉𝑔𝑠 = 0.6 V
𝑉𝑔𝑠 = 0.3 V
Reduction of PEDOT+ in PEDOT:PSS
layer under applied Gate-Source
potential with Drain-Source potential:
Vds=-0.5V
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Penetration of Na+ into PEDOT:PSS
layer under applied Gate-Source
potential with Drain-Source potential:
Vds=-0.5V
𝑉𝑔𝑠 = 0.1 V
𝑉𝑔𝑠 = 0.6 V
𝑉𝑔𝑠 = 0.3 V
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Moving front experiment was numericallymodelled
Color chandge of PEDOT:PSS layer could beexplaned by introduction of Nernst equationof redox reaction
Further investigations would be dedicated to 3D model of full OECT transistor with different real geometries to build up a full model of this type of biosensor
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