separation science and technology education: … science and technology education: chemical...
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Separation Science and Technology Education: Chemical Engineering Perspective
Yoshiaki Kawajiri
Assistant Professor School of Chemical & Biomolecular Engineering
Georgia Institute of Technology
August 12, 2014 Separation Science and Technology as a Convergence Platform for SusChEM
San Francisco, CA
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Outline
1. Separations in Chemical Engineering: Multi-scale perspective
2. Challenges in Undergraduate Education 3. Graduate Education
2
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1. Separations in Chemical Engineering: Multi-scale Perspective
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Separations in Chemical Engineering
4
Separation process system (plant level)
Integration with other operations Control
Unit operation (process level)
Mass balance Heat balance
Separation science (molecular level)
Equilibrium Kinetics
Grams
tons
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Separation science
5
Equilibria Mass transfer
Materials
Seader and Henley, 2006
Grams
tons
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Separation processes Unit design: Determine unit size (capital cost) and utility requirements
Seader and Henley, 2006
Grams
tons
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Separation process system synthesis
7
Example 1: Separation process sequence
Distillation column sequence to separate multiple components Membrane cascade to increase recovery
Reyneke et al. US 7311813 B2
Grams
tons
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Separation process system synthesis (continued)
8
Example 2: Ethylene hydration to produce ethanol
• 2 reactors • 7 separation units (3 absorbers, 3 distillation columns, 1 flash)
Seader and Henley, 2006
Grams
tons
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2. Undergraduate education
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Enrollment in Chemical & Biomolecular Engineering at Georgia Tech
Popularity for energy and sustainability: Class size increasing
0
100
200
300
400
500
600
700
800
900
1000
2005 2006 2007 2008 2009 2010 2011 2012 2013
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Curriculum at Georgia Tech: Courses related directly to separations
11
Chemical Process Principles
Thermodynamics I
Thermodynamics II Transport Phenomena I
Transport Phenomena II Separation processes
Unit Operations Lab
Process design (lecture and project)
Freshman
Sophomore
Junior
Senior
Mass and heat balance calculations
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Topics in undergraduate separation course
12
Equilibrium • Vapor-liquid • Liquid-liquid
Seader and Henley, 2006
Unit design and operation • Single stage vs. multi-stage • Co-current vs. counter-current • Continuous vs. batch
Kinetics • Mass transfer • Diffusion
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From physical properties to separation process design Example: distillation column
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Vapor-liquid equilibrium
Stage calculations
Mass balance and unit design
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Separation techniques covered in undergraduate course
14 www.wikipedia.com
Distillation
Membrane (liquid and gas)
Absorption
Adsorption and ion exchange Crystallization
Extraction
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Computer-aided engineering in separations
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Process flowsheet Physical property database
Students use Aspen Plus® from sophomore until senior in multiple courses
Covers most traditional chemicals (commodity chemicals)
http://www.aspentech.com/
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Capstone senior process design project
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Process flow diagram (from raw material to final product) Process economics: cost and profitability
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Industry involvement in capstone design course
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Past sponsors include:
Sponsors are involved in this course through:
• Project problem development • Guest lectures • Evaluation of oral presentations • Recruiting
We are currently looking for sponsor for 2015!
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Introducing energy and sustainability in process design project
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Algal biofuel processes Sponsors
http://www.solidworks.com/
Life-cycle assessment for production of cosmetic esters
Sponsor
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Separations for biological and biochemical products
19 www.novasep.com
• Product information • Property database • Public information of process flow
Lack of
Same separation techniques as in traditional chemicals: Chromatography (adsorption), membrane, centrifugation, etc.
www.pharmaceuticaltechnology.com
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3. Graduate education
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Graduate courses related separations
• Chemical Process Safety • Chemical Engineering Thermodynamics • Transport Phenomena • Mass Transfer • Kinetics and Reactor Design • Mathematical Modeling of Chemical Processes • Chemical Engineering Elective
21
Chemical Engineering Core Courses (mandatory for 1st year graduate students)
No “Separation” course! Courses related closely to separations are in red
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Separation faculty in Chemical Engineering at Georgia Tech
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Charles Eckert: Supercritical separations
Christopher Jones: Carbon capture
adsorption materials
William Koros Membranes
Krista Walton Metal organic framework,
adsoption
Yoshiaki Kawajiri Chromatography,
adsorption
Ronald Rousseau Crystallization
Sankar Nair Nanoporous materials
for adsorption and membrane
Amyn Teja Thermodynamics
Ryan Lively Membrane
hollow fiber adsorbent
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Graduate research programs in US
23
Grams
tons
Current focus in most research programs in the US, heavily on materials
Smaller number of research programs in US
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Process-level research example: Multi-column chromatography
24 Sreedhar, Hobbs, Kawajiri, Separation and Purification Technology, in press Sreedhar, Suzuki, Hobbs, Kawajiri, Journal of Separation Science, in press
Nd Sm
Collaborators: David Hobbs (Savannah River National Laboratory) Tatsuya Suzuki (Nagaoka University of Technology, Japan)
𝜀𝑏𝜕𝐶𝑖𝜕𝜕 + 1 − 𝜀𝑏
𝜕𝑞𝑖𝜕𝜕 + 𝑢
𝜕𝐶𝑖𝜕𝜕 = 0
1 − 𝜀𝑏𝜕𝑞𝑖𝜕𝜕 = 𝑘𝑎,𝑖(𝐶𝑖 − 𝐶𝑖
𝑒𝑒)
𝑞𝑖 = 𝑘𝐷,𝑖𝐶𝑖𝑒𝑒
Mathematical model
Simulated moving bed chromatography
Chromatogram of lanthanides
Tertiary pyridine resin
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Industrial collaboration for process engineering
Multi-column continuous reactive chromatographic
separation
Agrawal, Oh, Sreedhar, Donaldson, Frank, Shultz, Bommarius, Kawajiri, Journal of chromatography A (in press). Oh, Agrawal, Sreedhar, Donaldson, Shultz, Frank, Bommarius, Kawajiri, Chemical Engineering Journal (in press).
Production of DowanolTM PMA
Reaction in a chromatographic column
Acetic acid
Chromatographic column
DOWANOLTM PM
Water DOWANOLTM PMA
Reaction +
Separation
DOWANOLTM PM 1-Methoxy 2-Propanol
Acetic Acid DOWANOLTM PMA 1-Methoxy 2-Propanol
AmberlystTM 15
University Partnership Program
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Graduate research programs in US
26
Grams
tons
Current focus in most research programs in the US, heavily on materials
Smaller number of research programs in US
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Air
Coal
PC Boiler Particulate Removal
Ash
Fan Sulfur
Removal CO2 Capture
Process
Flue gas
CO2 Comp.
CO2 to Storage
Steam Cycle
LP Steam
Graduate research project example CO2 capture from flue gas in coal-fired power plant
Post-combustion CO2 capture
Target by NETL: CO2 recovery ≥ 90% Increase in cost of electricity ≤ 35%
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Collaborative research: CO2 capture by hollow fiber adsorbent material
28
CO2 adsorption
CO2 desorption
Christopher Jones William Koros Ryan Lively Matthew Realff Yoshiaki Kawajiri
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Development of separation process
29
Rapid temperature swing adsorption process
80°C
34°C 80°C
4 min
Rezaei, Swernath, Kalyanaraman, Lively, Kawajiri, Realff: Chemical Engineering Science 2014, 113, 62-76 Kalyanaraman, Fan, Lively, Koros, Jones, Realff, Kawajiri, Chemical Engineering Journal, in press
Mathematical models to design process and operation
Model validation with experiments
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From molecular level to plant level
30
Grams
tons
Development of separation material
Jones Koros Lively
Process integration, technoeconomic
evaluation Realff Target by NETL: CO2 recovery ≥ 90% Increase in cost of electricity ≤ 35%
Separation process modeling and
design Kawajiri
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31
Summary
1. Separations in chemical engineering covers multiple scales
2. Challenges in undergraduate education includes: • Enrollment keeps incrasing • Integration with sustainability and energy topics • Computer aided design • Biological and biochemical processes
3. Challenges in graduate education includes • Few process-level and plant-level research projects • Collaborations with industry • Multi-scale collaborative research
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Acknowledgments
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• The Dow Chemical Company: University Partnership Program Megan Donaldson, Timothy Frank, Alfred Schultz
• Ronald Rousseau and Matthew Realff, Georgia Tech
• My research group members
• Research sponsor for CO2 capture project