sds - pilot ii - marine_protective - english (us) - canada

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Pilot II MM00000635 Coatings: Solvent-borne. 1-800-424-9300 Jotun Paints, Inc. 9203 Highway 23 Belle Chasse, LA 70037 Telephone: (800) 229-3538 or (504) 394-3538 [email protected] Material Safety Data Sheet Trade name Material uses Manufacturer Code In case of emergency Product and company identification Pilot II : : : : : 1 . Emergency overview Hazards identification Potential acute health effects No known significant effects or critical hazards. May cause eye irritation. No known significant effects or critical hazards. May cause skin irritation. Eyes Skin Inhalation Ingestion Physical state Liquid. See toxicological information (section 11) WARNING! FLAMMABLE LIQUID AND VAPOR. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD - CONTAINS MATERIAL WHICH CAN CAUSE CANCER. Flammable liquid. Keep away from heat, sparks and flame. Avoid exposure - obtain special instructions before use. Do not breathe vapor or mist. Avoid contact with skin and clothing. Contains material that may cause target organ damage, based on animal data. Contains material which can cause cancer. Risk of cancer depends on duration and level of exposure. Use only with adequate ventilation. Keep container tightly closed and sealed until ready for use. : : : : : : CARCINOGENIC EFFECTS: Classified 1 (Proven for humans.) by IARC [ethanol]. Classified A3 (Proven for animals.) by ACGIH [ethanol]. Classified 3 (Possible for humans.) by European Union [2-butanone oxime]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical conditions aggravated by over- exposure Pre-existing disorders involving any target organs mentioned in this MSDS as being at risk may be aggravated by over-exposure to this product. Potential chronic health effects : : Odor : Characteristic. 2 . Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard Communication Standard). Composition/information on ingredients Naphtha (petroleum), hydrodesulfurized heavy 64742-82-1 25 - 50 titanium dioxide 13463-67-7 10 - 25 ethanol 64-17-5 0.1 - 1 Name CAS number % 3 . Continued on next page

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Page 1: SDS - Pilot II - Marine_Protective - English (Us) - Canada

Pilot II

MM00000635

Coatings: Solvent-borne.

1-800-424-9300

Jotun Paints, Inc.9203 Highway 23Belle Chasse, LA 70037Telephone: (800) 229-3538 or(504) [email protected]

Material Safety Data Sheet

Trade nameMaterial usesManufacturer

CodeIn case of emergency

Product and company identification

Pilot II

::

:::

1 .

Emergency overview

Hazards identification

Potential acute health effects

No known significant effects or critical hazards.

May cause eye irritation.

No known significant effects or critical hazards.

May cause skin irritation.EyesSkinInhalationIngestion

Physical state Liquid.

See toxicological information (section 11)

WARNING!FLAMMABLE LIQUID AND VAPOR. CONTAINS MATERIAL THAT MAY CAUSETARGET ORGAN DAMAGE, BASED ON ANIMAL DATA. CANCER HAZARD -CONTAINS MATERIAL WHICH CAN CAUSE CANCER.Flammable liquid. Keep away from heat, sparks and flame. Avoid exposure - obtainspecial instructions before use. Do not breathe vapor or mist. Avoid contact with skinand clothing. Contains material that may cause target organ damage, based on animaldata. Contains material which can cause cancer. Risk of cancer depends on durationand level of exposure. Use only with adequate ventilation. Keep container tightly closedand sealed until ready for use.

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CARCINOGENIC EFFECTS: Classified 1 (Proven for humans.) by IARC [ethanol].Classified A3 (Proven for animals.) by ACGIH [ethanol]. Classified 3 (Possible forhumans.) by European Union [2-butanone oxime].MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available.

Medical conditionsaggravated by over-exposure

Pre-existing disorders involving any target organs mentioned in this MSDS as being atrisk may be aggravated by over-exposure to this product.

Potential chronic healtheffects

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:

Odor : Characteristic.

2 .

Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard CommunicationStandard).

Composition/information on ingredients

Naphtha (petroleum), hydrodesulfurized heavy 64742-82-1 25 - 50titanium dioxide 13463-67-7 10 - 25ethanol 64-17-5 0.1 - 1

Name CAS number %

3 .

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Wash out mouth with water. Do not induce vomiting unless directed to do so bymedical personnel. Never give anything by mouth to an unconscious person. Getmedical attention immediately.

Check for and remove any contact lenses. Immediately flush eyes with plenty ofwater for at least 15 minutes, occasionally lifting the upper and lower eyelids. Getmedical attention immediately.In case of contact, immediately flush skin with plenty of water for at least 15 minuteswhile removing contaminated clothing and shoes. Wash clothing before reuse.Clean shoes thoroughly before reuse. Get medical attention immediately.Move exposed person to fresh air. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attentionimmediately.

Section 4. First aid measuresEye contact

Skin contact

Inhalation

Ingestion

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Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If itis suspected that fumes are still present, the rescuer should wear an appropriatemask or self-contained breathing apparatus. It may be dangerous to the personproviding aid to give mouth-to-mouth resuscitation. Wash contaminated clothingthoroughly with water before removing it, or wear gloves.

Flammable.Decomposition products may include the following materials:carbon dioxidecarbon monoxidemetal oxide/oxides

Use dry chemical, CO2, water spray (fog) or foam.

Fire-fighting measuresFlammability of the productProducts of combustion

Extinguishing media

Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool. Fire water contaminated with this materialmust be contained and prevented from being discharged to any waterway, sewer ordrain.Flammable liquid. In a fire or if heated, a pressure increase will occur and the containermay burst, with the risk of a subsequent explosion. Runoff to sewer may create fire orexplosion hazard.

Special protectiveequipment for fire-fighters

Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.

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Special exposure hazards :Do not use water jet.

Suitable :Not suitable :

No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate.Put on appropriate personal protective equipment (see section 8).

Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows. Contain andcollect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculiteor diatomaceous earth and place in container for disposal according to localregulations (see section 13). Use spark-proof tools and explosion-proof equipment.Dispose of via a licensed waste disposal contractor. Contaminated absorbentmaterial may pose the same hazard as the spilled product. Note: see section 1 for

Environmental precautions

Section 6. Accidental release measures

: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air). Water polluting material. May be harmfulto the environment if released in large quantities.

Personal precautions :

Methods for cleaning up :

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Section 6. Accidental release measuresemergency contact information and section 13 for waste disposal.

Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food anddrink. Eliminate all ignition sources. Separate from oxidizing materials. Keepcontainer tightly closed and sealed until ready for use. Containers that have beenopened must be carefully resealed and kept upright to prevent leakage. Do not storein unlabeled containers. Use appropriate containment to avoid environmentalcontamination.

Put on appropriate personal protective equipment (see section 8). Eating, drinkingand smoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking andsmoking. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathingvapor or mist. Avoid release to the environment. Use only with adequate ventilation.Wear appropriate respirator when ventilation is inadequate. Do not enter storageareas and confined spaces unless adequately ventilated. Keep in the originalcontainer or an approved alternative made from a compatible material, kept tightlyclosed when not in use. Store and use away from heat, sparks, open flame or anyother ignition source. Use explosion-proof electrical (ventilating, lighting and materialhandling) equipment. Use non-sparking tools. Take precautionary measuresagainst electrostatic discharges. To avoid fire or explosion, dissipate static electricityduring transfer by grounding and bonding containers and equipment beforetransferring material. Empty containers retain product residue and can behazardous. Do not reuse container.

Section 7. Handling and storageHandling

Storage

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Exposure controls/personal protectionProduct name Exposure limits

Personal protection

Naphtha (petroleum), hydrodesulfurized heavy ACGIH TLV (United States, 1/2005). Notes: Substances for whichthe TLV is higher than the OSHA Permissible Exposure Limit (PEL)and/or the NIOSH Recommended Exposure Limit (REL). See CFR58(124) :36338-33351, June 30, 1993, for revised OSHA PEL. TWA: 525 mg/m³ 8 hour(s). Form: All forms TWA: 100 ppm 8 hour(s). Form: All forms

titanium dioxide CA British Columbia Provincial (Canada, 10/2009). TWA: 3 mg/m³ 8 hour(s). Form: Respirable dust TWA: 10 mg/m³ 8 hour(s). Form: Total dustCA Alberta Provincial (Canada, 4/2009). Skin sensitizer. 8 hrs OEL: 10 mg/m³ 8 hour(s).CA Quebec Provincial (Canada, 6/2008). TWAEV: 10 mg/m³ 8 hour(s). Form: Total dust.CA Ontario Provincial (Canada, 8/2008). TWAEV: 10 mg/m³ 8 hour(s). Form: total dust

ethanol CA Alberta Provincial (Canada, 4/2009). 8 hrs OEL: 1880 mg/m³ 8 hour(s). 8 hrs OEL: 1000 ppm 8 hour(s).CA Ontario Provincial (Canada, 8/2008). TWAEV: 1900 mg/m³ 8 hour(s). TWAEV: 1000 ppm 8 hour(s).CA Quebec Provincial (Canada, 6/2008). TWAEV: 1880 mg/m³ 8 hour(s). TWAEV: 1000 ppm 8 hour(s).CA British Columbia Provincial (Canada, 10/2009). STEL: 1000 ppm 15 minute(s).

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Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.

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Exposure controls/personal protection8 .

Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.

Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts.Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.

Eyes

Skin

Respiratory

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Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.

Hands :

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.

Liquid.

1.13 g/cm3

Insoluble in the following materials: cold water and hot water.

Characteristic.Various colors.

Physical and chemical propertiesPhysical state

Relative density

Solubility

OdorColor

37,3 % (w/w) [ISO11890-1]

VOC

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Flash point : Closed cup: 36°C (96,8°F)

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9.43 pounds/gallon3.51 pounds/gallon (US)

The product is stable.

Under normal conditions of storage and use, hazardous polymerization will notoccur.

Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.

Section 10. Stability and reactivityStability and reactivityHazardous decompositionproductsHazardous polymerization

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Section 11. Toxicological information

Specific effects

Exposure to component solvent vapor concentrations in excess of the statedoccupational exposure limit may result in adverse health effects such as mucousmembrane and respiratory system irritation and adverse effects on the kidneys, liverand central nervous system. Solvents may cause some of the above effects byabsorption through the skin. Symptoms and signs include headache, dizziness,fatigue, muscular weakness, drowsiness and, in extreme cases, loss ofconsciousness. Repeated or prolonged contact with the preparation may causeremoval of natural fat from the skin, resulting in non-allergic contact dermatitis andabsorption through the skin. If splashed in the eyes, the liquid may cause irritationand reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastro-intestinal irritation and chemical pneumonia.

Contains 2-butanone oxime, hexanoic acid, 2-ethyl-, cobalt salt. May produce anallergic reaction.

CARCINOGENIC EFFECTS: Classified 1 (Proven for humans.) by IARC [ethanol].Classified A3 (Proven for animals.) by ACGIH [ethanol]. Classified 3 (Possible forhumans.) by European Union [2-butanone oxime].Contains material which may cause damage to the following organs: lungs, upperrespiratory tract, skin.

Chronic effects on humans

Other toxic effects onhumans

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Section 11. Toxicological informationCarcinogenic effects Contains material which can cause cancer. Risk of cancer depends on duration and

level of exposure.Mutagenic effects No known significant effects or critical hazards.Reproduction toxicity No known significant effects or critical hazards.Chronic effects Contains material that may cause target organ damage, based on animal data.

Contains material which may cause damage to the following organs: lungs, upperrespiratory tract, skin.

Target organs

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Products of degradation: carbon oxides (CO, CO2) and water. Some metallic oxides.

Ecological information

Products of degradation

Ecotoxicity data

Naphtha (petroleum),hydrodesulfurized heavy

Fish (LC50)Daphnia (EC50)Algae (IC50)

96 hour(s)48 hour(s)72 hour(s)

<10 mg/l<10 mg/l<10 mg/l

titanium dioxide Daphnia magna (EC50) 48 hour(s) >1000 mg/lethanol Daphnia magna (EC50)

Daphnia magna (EC50)Daphnia magna (EC50)Daphnia magna (LC50)Pimephales promelas (LC50)Oncorhynchus mykiss (LC50)

48 hour(s)48 hour(s)48 hour(s)96 hour(s)96 hour(s)96 hour(s)

2 mg/l9.3 mg/l>100 mg/l>100 mg/l>100 mg/l13000 mg/l

Product/ingredient name Species Period Result

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Environmental precautions : Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment. Water polluting material. May be harmful to the environment if released inlarge quantities.

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The generation of waste should be avoided or minimized wherever possible. Emptycontainers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Dispose of surplus and non-recyclable products viaa licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protectionand waste disposal legislation and any regional local authority requirements. Avoiddispersal of spilled material and runoff and contact with soil, waterways, drains andsewers.

Waste disposal

Disposal considerations

Disposal should be in accordance with applicable regional, national and local laws and regulations. Localregulations may be more stringent than regional or national requirements.

The information presented below only applies to the material as supplied. The identification based oncharacteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is theresponsibility of the waste generator to determine the toxicity and physical properties of the material generated todetermine the proper waste identification and disposal methods in compliance with applicable regulations.

Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees.

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Section 14. Transport information

3 - DOT Classification

TDG Classification 3

Paint. III

1263 Paint. III

Regulatoryinformation

UN number Proper shippingname

Class PG* Label Additionalinformation

1263

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Section 14. Transport information

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ADR/RID Class Paint. 3 III

IMDG Class Paint.. Marinepollutant (Naphtha(petroleum),hydrodesulfurizedheavy)

3 III

Paint.1263IATA-DGR Class

3 III

1263

1263

Tunnel restrictioncode: (D/E)Hazard identificationnumber: 30Special provisions:640E

Emergency schedules(EmS): F-E, S-EMarine pollutant: Yes.

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PG* : Packing group

Regulatory information

CEPA Toxic substances: None of the components are listed.Canadian ARET: None of the components are listed.Canadian NPRI: None of the components are listed.Alberta Designated Substances: None of the components are listed.Ontario Designated Substances: None of the components are listed.Quebec Designated Substances: None of the components are listed.

WHMIS (Canada) Class B-2: Flammable liquidClass D-2A: Material causing other toxic effects (Very toxic).

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R10- Flammable.R67- Vapors may cause drowsiness and dizziness.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.

Risk phrases

EU regulations

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Hazard symbol or symbols :

Dangerous for theenvironment

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This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations andthe MSDS contains all the information required by the Controlled Products Regulations.

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Regulatory information15 .S23- Do not breathe vapor / spray.S38- In case of insufficient ventilation, wear suitable respiratory equipment.S61- Avoid release to the environment. Refer to special instructions/safety data sheet.

Safety phrases :

Other information

Notice to readerTo the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.

Date of issueVersion

14.06.2010.1.01:

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Indicates information that has changed from previously issued version.