schmedt gmbh & co. kg safety data sheet...for permanent contact: nbr (nitrile rubber) or fkm...

according to Regulation (EC) No 1907/2006

Safety Data SheetSchmedt GmbH & Co. KG

Ascocolor-Marmorierfarben

Revision date: 18.03.2019 Product code: FU838 of 12

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Color for marbling

1.3. Details of the supplier of the safety data sheet

Schmedt GmbH & Co. KGCompany name:

Street: Dwengerkamp 1

Place: D-21035 Hamburg

Telephone: Telefax:040-734 744 11 040-734 744 31

[email protected]:

Daniel HerterContact person:

www.schmedt24.deInternet:

purchasing departmentResponsible Department:

0341-39295837 (24h)1.4. Emergency telephone

number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008

Hazard categories:

Flammable liquid: Flam. Liq. 2

Acute toxicity: Acute Tox. 4



Aspiration hazard: Asp. Tox. 1

Skin corrosion/irritation: Skin Irrit. 2

Serious eye damage/eye irritation: Eye Irrit. 2

Respiratory or skin sensitisation: Skin Sens. 1

Specific target organ toxicity - single exposure: STOT SE 3

Hazardous to the aquatic environment: Aquatic Chronic 2

Hazard Statements:

Highly flammable liquid and vapour.

Harmful if swallowed.

Harmful in contact with skin.

Harmful if inhaled.

May be fatal if swallowed and enters airways.

Causes skin irritation.

Causes serious eye irritation.

May cause an allergic skin reaction.

May cause drowsiness or dizziness.

Toxic to aquatic life with long lasting effects.

2.2. Label elements

Regulation (EC) No. 1272/2008

Hazard components for labellingturpentine, oil

Hydrocarbons, C6-C7, isoalkanes, cycloalkanes, <5% n-hexane

Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane

Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics

Print date: 29.03.2019GB - ENRevision No: 1.00

mailto:[email protected]

http://www.schmedt24.de





Signal word: Danger

Pictograms:

H225 Highly flammable liquid and vapour.

H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled.

H315 Causes skin irritation.

H319 Causes serious eye irritation.

H317 May cause an allergic skin reaction.

H336 May cause drowsiness or dizziness.

H304 May be fatal if swallowed and enters airways.

H411 Toxic to aquatic life with long lasting effects.

Hazard statements

P102 Keep out of reach of children.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P280 Wear protective gloves and eye/face protection.

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P403+P235 Store in a well-ventilated place. Keep cool.

P273 Avoid release to the environment.

P501 Dispose of contents/container to according to the legal regulations of disposal.

Precautionary statements

Labelling of packages where the contents do not exceed 125 ml

DangerSignal word:

Pictograms:

H317-H304

Hazard statements

No information available.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures






Hazardous components

QuantityChemical nameCAS No

EC No Index No REACH No

GHS Classification

65 - < 70 %8006-64-2 turpentine, oil

232-350-7 650-002-00-6

Flam. Liq. 3, Acute Tox. 4, Acute Tox. 4, Acute Tox. 4, Asp. Tox. 1, Eye Irrit. 2, Skin Irrit. 2, Skin

Sens. 1, Aquatic Chronic 2; H226 H332 H312 H302 H304 H319 H315 H317 H411

<= 20 %Hydrocarbons, C6-C7, isoalkanes, cycloalkanes, <5% n-hexane

926-605-8

Flam. Liq. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H225 H336 H304 H411

<= 15 %Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane

921-024-6 01-2119475514-35

Flam. Liq. 2, Skin Irrit. 2, STOT SE 3, Asp. Tox. 1, Aquatic Chronic 2; H225 H315 H336 H304

H411

<= 12 %64742-49-0 Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics

927-510-4 01-2119475515-33


H411 EUH066

<= 8 %64742-49-0 Hydrocarbons, C6, isoalkanes, <5% n-hexane

931-254-9


H411

Full text of H and EUH statements: see section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

In case of discomfort consult a doctor. Remove affected person from the danger area and lay down. Remove

contaminated, saturated clothing immediately.

General information

Provide fresh air. If breathing is irregular or stopped, administer artificial respiration.If unconscious place in

recovery position and seek medical advice.

After inhalation

Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse.

After contact with skin

Rinse immediately carefully and thoroughly with eye-bath or water. In case of eye irritation consult an

ophthalmologist. In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15

minutes holding eyelids apart and consult an ophthalmologist.

After contact with eyes

Observe risk of aspiration if vomiting occurs. Rinse mouth immediately and drink plenty of water. Induce

vomiting when the affected person is not unconscious. Medical treatment necessary. Do NOT induce

vomiting.

After ingestion

4.2. Most important symptoms and effects, both acute and delayed

Harmful, Irritant effect, Headache, Dizziness, Drowsiness, Unconsciousness, drowsiness/fatigue, Disturbance

of the central nervous system., dry skin.

May be fatal if swallowed and enters airways.

May cause an allergic skin reaction.






Aspiration may cause pulmonary oedema and pneumonitis.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically. If breathing is irregular or stopped, administer artificial respiration.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Carbon dioxide (CO2), Foam, Extinguishing powder. Fight larger fires with water spray or alcohol resistant

foam.

Suitable extinguishing media

High power water jet.

Unsuitable extinguishing media

5.2. Special hazards arising from the substance or mixture

Not readily flammable. Vapours can form explosive mixtures with air. Do not breathe gas/fumes/vapour/spray.

Heating causes rise in pressure with risk of bursting.

In case of fire, can be released: Hydrocarbons, Carbon monoxide, Carbon dioxide (CO2).

Wear a self-contained breathing apparatus and chemical protective clothing. Full protection suit.

Do not inhale explosion and combustion gases.

5.3. Advice for firefighters

Use water spray jet to protect personnel and to cool endangered containers. Collect contaminated fire

extinguishing water separately. Do not allow entering drains or surface water. Cool endangered containers

with water spray - risk of bursting.

Additional information

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Provide adequate ventilation. Remove all sources of ignition. Refrain from smoking! Wear breathing

apparatus if exposed to vapours/dusts/aerosols. Do not breathe gas/fumes/vapour/spray. Avoid contact with

skin, eyes and clothes. Use personal protection equipment.

Do not allow uncontrolled discharge of product into the environment. Danger of explosion If large quantities

are released, inform the competent authorities. Take up mechanically. Due to danger of explosion, prevent

leakage of vapours into cellars, flues and ditches.

6.2. Environmental precautions

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat

the recovered material as prescribed in the section on waste disposal.

6.3. Methods and material for containment and cleaning up

Safe handling: see section 7

Personal protection equipment: see section 8

Disposal: see section 13

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe

gas/fumes/vapour/spray. Ensure good room ventilation also on the floor level (vapors are heavier than air).

Do not breathe gas/vapour/aerosol. Avoid contact with eyes and skin. Handle and open container with care.

Advice on safe handling

Only use the material in places where open light, fire and other flammable sources can be kept away. Take

precautionary measures against static discharges. Vapours can form explosive mixtures with air. Use

explosion-proof machinery, apparatus, ventilation facilities, tools etc.

Advice on protection against fire and explosion






7.2. Conditions for safe storage, including any incompatibilities

Keep container tightly closed. Keep locked up. Keep in a cool place. Keep away from heat, hot surfaces,

sparks, open flames and other ignition sources. No smoking.

Suitable container/equipment material: Refined steel, Teflon.

Unsuitable container/equipment material: Butyl caoutchouc (butyl rubber), polystyrene.

Requirements for storage rooms and vessels

Do not store together with: Oxidising agent. Pyrophoric or self-heating substances. Strong acid, Alkali (lye).

Hints on joint storage

Protect from direct sunlight. Heating causes rise in pressure with risk of bursting.

Further information on storage conditions

7.3. Specific end use(s)

Color for marbling

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

Categoryfibres/mlmg/m³ppmSubstanceCAS No Origin

TWA (8 h)100Turpentine8006-64-2 566 WEL

STEL (15 min)150 850 WEL






DNEL/DMEL values

CAS No Substance

DNEL type Exposure route Effect Value


Worker DNEL, long-term inhalation systemic 5306 mg/m³

Worker DNEL, long-term dermal systemic 13964 mg/kg

bw/day

Consumer DNEL, long-term inhalation systemic 1131 mg/m³

Consumer DNEL, long-term dermal systemic 1377 mg/kg

bw/day

Consumer DNEL, long-term oral systemic 1301 mg/kg

bw/day


Consumer DNEL, long-term oral systemic 699 mg/kg bw/day

Consumer DNEL, long-term dermal systemic 699 mg/kg bw/day

Worker DNEL, long-term dermal systemic 773 mg/kg bw/day



64742-49-0 Hydrocarbons, C6, isoalkanes, <5% n-hexane

Worker DNEL, long-term dermal systemic 13964 mg/kg

bw/day


Consumer DNEL, long-term oral systemic 1301 mg/kg

bw/day

Consumer DNEL, long-term dermal systemic 1377 mg/kg

bw/day


8.2. Exposure controls

Ensure good ventilation / exhaustion at the workplace. Do not breathe gas/fumes/vapour/spray.

Appropriate engineering controls

Remove contaminated, saturated clothing.Wash hands before breaks and after work. When using do not eat

or drink. Keep away from food, drink and animal feedingstuffs.

Protective and hygiene measures

Suitable eye protection: goggles.

Eye/face protection

Chemical resistant protective gloves (EN 374)

For permanent contact: NBR (Nitrile rubber) or FKM (fluoro rubber), Thickness of the glove material: =>

0,11mm, Breakthrough time => 480 min

At first signs of signs of wear, the protective gloves should be replaced.

When handling with chemical substances, protective gloves must be worn with the CE-label including the four

control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the

specific working place concentration and quantity of hazardous substances. For special purposes, it is

recommended to check the resistance to chemicals of the protective gloves mentioned above together with

the supplier of these gloves.

Hand protection

Wear suitable protective clothing. Solvent resistant protective clothing.

Skin protection






In case of short-term use or low-exposure, use respiratory filter device. In case of intensive or prolonged

exposure, use respiratory protection.

Combination filter type: A

Respiratory protection

colourless

liquidPhysical state:

Colour:

9.1. Information on basic physical and chemical properties

SECTION 9: Physical and chemical properties

characteristicOdour:

pH-Value: not determined

Changes in the physical state

<-20 °CMelting point:

not determinedInitial boiling point and boiling range:

< 0 °CFlash point:

Flammability

not applicableSolid:

not applicableGas:

~0.6 vol. %Lower explosion limits:

~8.3 vol. %Upper explosion limits:

not determinedIgnition temperature:

Auto-ignition temperature

not applicableSolid:

not applicableGas:

not determinedDecomposition temperature:

Not oxidising.

Oxidizing properties

>5 hPa hPaVapour pressure:

(at 20 °C)

Density (at 20 °C): ca 0.82 g/cm³

Water solubility:

(at 20 °C)

poorly soluble

Solubility in other solvents

not determined

not determinedPartition coefficient:

Viscosity / kinematic:

(at 20 °C)

> 0.3 mm²/s

Vapour density: not determined

9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity

Explosive.

10.2. Chemical stability

The product is stable under storage at normal ambient temperatures.

10.3. Possibility of hazardous reactions






Vapours may form explosive mixtures with air.

Risk of explosion by shock, friction, fire or other sources of ignition. Remove all sources of ignition. Ignition

hazard. Keep away from heat.

10.4. Conditions to avoid

Protect against: Contact with air/oxygen. Strong acid, Alkali (lye).

10.5. Incompatible materials

In case of fire, can be released: Hydrocarbons, Carbon monoxide, Carbon dioxide (CO2).

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity

Harmful if swallowed, in contact with skin or if inhaled.

ATEmix calculated

ATE (oral) 769.2 mg/kg; ATE (dermal) 1692.3 mg/kg; ATE (inhalation vapour) 16.92 mg/l; ATE (inhalation

aerosol) 2.308 mg/l

Chemical nameCAS No

SourceSpeciesDoseExposure route Method

8006-64-2 turpentine, oil

ATE 500

mg/kg

oral

ATE 1100

mg/kg

dermal

inhalation vapour ATE 11 mg/l

inhalation aerosol ATE 1.5 mg/l


RatLD50 17500

mg/kg

ECHA-Databaseoral

RabbitLD50 3500

mg/kg

ECHA-Databasedermal


RatLD50 5760

mg/kg

ECHA Dossieroral

RabbitLD50 >2000

mg/kg

ECHA Dossierdermal

inhalation (4 h) vapour LC50 25,2 mg/l Rat ECHA Dossier

64742-49-0 Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics

RatLD50 5840

mg/kg

ECHA-Databaseoral

RatLD50 2800

mg/kg

ECHA-Databasedermal

inhalation (4 h) vapour LC50 23,3 mg/l Rat ECHA-Database

64742-49-0 Hydrocarbons, C6, isoalkanes, <5% n-hexane

RatLD50 17250

mg/kg

ECHA-Databaseoral

RabbitLD50 3450

mg/kg

ECHA-Databasedermal






Causes skin irritation.

Causes serious eye irritation.

Irritation and corrosivity

Sensitising effects

May cause an allergic skin reaction. (turpentine, oil)

Carcinogenic/mutagenic/toxic effects for reproduction

Based on available data, the classification criteria are not met.

STOT-single exposure

May cause drowsiness or dizziness. (Hydrocarbons, C6-C7, isoalkanes, cycloalkanes, <5% n-hexane)

Based on available data, the classification criteria are not met.

STOT-repeated exposure

Aspiration hazard

May be fatal if swallowed and enters airways. (turpentine, oil; Hydrocarbons, C6-C7, isoalkanes, cycloalkanes,

<5% n-hexane; Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane; Hydrocarbons, C7,

n-alkanes, isoalkanes, cyclics; Hydrocarbons, C6, isoalkanes, <5% n-hexane)

The mixture is classified as not hazardous according to Directive 1999/45/EC.

Additional information on tests

SECTION 12: Ecological information

12.1. Toxicity

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

CAS No Chemical name

[h] | [d]Aquatic toxicity Dose SourceSpecies Method


Acute fish toxicity 96 h ECHA DossierLC50 11,4

mg/l

Acute crustacea

toxicity

48 h ECHA DossierEC50 3 mg/l

Crustacea toxicity NOEC 0,17

mg/l

21 d ECHA Dossier

Hydrocarbons, C7, n-alkanes, isoalkanes, cyclics64742-49-0

Acute fish toxicity 96 h ECHA DossierLC50 11,4

mg/l

Acute crustacea

toxicity

48 h ECHA DossierEC50 3 mg/l

Crustacea toxicity NOEC 0,17

mg/l

21 d ECHA Dossier

12.2. Persistence and degradability

The product has not been tested.

CAS No Chemical name

SourceValueMethod d

Evaluation


OECD 301 F 98% 28

12.3. Bioaccumulative potential







Partition coefficient n-octanol/water

Log PowChemical nameCAS No

2,2-6Hydrocarbons, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane


12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment



12.6. Other adverse effects

Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.

Further information

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal

Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of waste

according to applicable legislation.

Waste disposal number of waste from residues/unused products

140603 WASTE ORGANIC SOLVENTS, REFRIGERANTS AND PROPELLANTS (EXCEPT 07 AND 08);

waste organic solvents, refrigerants and foam/aerosol propellants; other solvents and solvent

mixtures; hazardous waste

Non-contaminated packages may be recycled. Handle contaminated packages in the same way as the

substance itself.

Contaminated packaging

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: UN 3295

HYDROCARBONS, LIQUID, N.O.S.14.2. UN proper shipping name:

314.3. Transport hazard class(es):

14.4. Packing group: II

Hazard label: 3

Classification code: F1

Special Provisions: 640D

Limited quantity: 1 L

Excepted quantity: E2

Transport category: 2

33Hazard No:

Tunnel restriction code: D/E

Inland waterways transport (ADN)


14.2. UN proper shipping name: HYDROCARBONS, LIQUID, N.O.S.

14.3. Transport hazard class(es): 3


Hazard label: 3

F1Classification code:

640DSpecial Provisions:








Marine transport (IMDG)



14.3. Transport hazard class(es): 3


Hazard label: 3

-Special Provisions:



EmS: F-E, S-D

Air transport (ICAO-TI/IATA-DGR)



314.3. Transport hazard class(es):

II14.4. Packing group:

Hazard label: 3

Special Provisions: A3 A324

Limited quantity Passenger: 1 L

Y341Passenger LQ:


353IATA-packing instructions - Passenger:

5 LIATA-max. quantity - Passenger:

364IATA-packing instructions - Cargo:

60 LIATA-max. quantity - Cargo:

14.6. Special precautions for user


14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulatory information

13 %2010/75/EU (VOC):

20 %2004/42/EC (VOC):

Information according to 2012/18/EU

(SEVESO III):

E2 Hazardous to the Aquatic Environment

P5cAdditional information:

National regulatory information

Observe restrictions to employment for juvenils according to the 'juvenile

work protection guideline' (94/33/EC). Observe employment restrictions

under the Maternity Protection Directive (92/85/EEC) for expectant or

nursing mothers.

Employment restrictions:

2 - clearly water contaminatingWater contaminating class (D):

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information


Schmedt GmbH & Co. KG · Dwengerkamp 1 · D-21035 Hamburg · www.schmedt.de Telefon: 040/ 734 744-0 · Telefax: 040/ 734 744-30 · E-Mail: [email protected]

schmedt gmbh & co. kg safety data sheet...for permanent contact: nbr (nitrile rubber) or fkm...

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