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  • 8/18/2019 scambio termico

    1/6

    ARNOLD G. FREDRICKSON and

    R.

    BYRON BIRD

    Department of Chemical Engineering, University of Wisconsin, Madison, Wis.

    Non-Newtonian Flow in Annuli

    Extrusion of molten plastics and

    Row

    of drilling muds in annular

    space are typical problems to

    which

    th is

    study can be applied

    T o A K E deductions from flow data

    concerning t he range of applicab ilit y of

    various empirical non-Newtonian flow

    models, it is necessary to have good ex-

    perimental flow data and accurate solu-

    tions to t he equations of motion in various

    geometrical arrangements. Experimen-

    tal data for a few fluids and analytical

    solutions are available for axial flow in

    tubes and for tangential flow in cylindri-

    cal annuli

    (3, 7, 77,

    72). Thi s discussion

    is concerned with the analytical solution

    of the equation of motion for the steady-

    state axial flow of an incompressible,

    non-Newtonian fluid in a long cylindrical

    annulus. This problem is of importance

    in connection with heat transfer to and

    from fluids flowing in annular spaces,

    flow of molten plastics in extrusion ap-

    paratus, and flow of drilling muds in

    annular spaces.

    Th e equations describing the flow of a

    compressible, isothermal fluid are equa-

    tions of continuity and motion (2,

    4

    :

    dr/dt + (V.YV) = 0

    (1

    1

    -VP

    V.7) + Yg ( 2 )

    Assumption of isothermal flow implies

    not only th at there is no impressed tem-

    peratur e field (6) but that the viscous dis-

    sipation term 7:Vu) n the energy bal-

    ance equation is negligible (7, 2).

    In

    the developments which follow, the

    flow between two coaxial cylinders (Fig-

    ure 1) is considered. Th e following as-

    sumptions are made:

    The fluid is incompressible

    y

    = con-

    stant).

    T he flow is in steady-state-Le., time-

    independent.

    Th e flow is laminar.

    Th e cylinders are sufficiently long that

    end effects may be neglected.

    For the specific system under con-

    sideration Equations 1 and

    2

    may be

    written in cylindrical coordinates and

    combined a nd simplified to

    :

    r[bulbt + ( U . V ) V l =

    in whichpo and p L are the static pressures

    a t z

    =

    0 and z = L, respectively, and gs

    is the component of gravitational ac-

    celeration g in the direction of flow. P

    designates the sum of forces per unit

    volume on the right side of Equation 1.

    This first-order differential equation,

    valid over the entire annular region for

    an y kind of fluid, may be integrated to

    give :

    4)

    in which

    X

    is the constant of integration.

    The radial distance r = XR represents

    that position at which r,, = 0. Equation

    4

    is

    taken as the starting point for the

    derivations for the Bingham plastic and

    the power law models.

    Solution f o r Bingham Plast ic Model

    Van Olphen

    (70)

    has presented an

    approximate solution; Mori and Oto-

    take

    (9)

    have given the complete solution,

    but their analytical and graphical re-

    sults are in erro r; Laird's solution 5)

    is

    correct. Howe ver, Laird's expression

    for the volume throughput is more

    complicated than that given here, and

    he has not presented his results in terms

    of

    a

    dimensionless correlation for general

    use.

    For this model the local shear stress,

    T, ,

    s related to the local shear rate,

    dv,/dr, according to the formula :

    wherein + is used when momentum is

    being transported in the +r direction

    and - when transport is in the -rdi-

    rection. Th e meaning of TO and pa is

    given in Figure 2 , where the Bingham

    model is compared with the Newtonian

    model.

    The introduction

    of

    the following di-

    mensionless variables is useful :

    T = 2r,,/PR

    To = 2ro/PR

    = dimensionless shear stress

    = dimensionless limiting

    =

    dimensionless velocity

    shear stress

    9

    =

    ( 2 ~ 0 / P R ~ ) p ~

    = dimensionless radial distance

    p = r / R

    Th e equations describing the system are

    X+ and 1- epresent the bounds on the

    plug flow region. Clearly they a re those

    values of

    p

    for which TI = TO

    Figure 1 . Shear stress distribution for

    axial annular flow corresponding to

    Equation 4 and characteristic velocity

    distributions for power law fluids

    Equations 22 and 23) and Bingham

    plastic fluid Equations 1 1 , 12, and 13)

    Actually it is convenient to express all the

    final results not in terms of X but rather

    in terms of either A+ or

    X ;

    et

    us

    choose

    k+

    to

    be

    consistent with Mori and

    Ototake (9). From Equation

    9

    it follows

    that:

    Xa

    =

    X+(X+ To)

    = A+ To)

    (10)

    Hence

    X

    is just the geomet ric mean of

    A+ and X .

    Figure 2. Shear stress vs. shear late

    for several types of fluids

    N.

    Newtonian, with slope

    p

    B.

    P.

    D.

    In annular flow rpSs negative

    for r / R

    < X and

    positive for

    r / R

    >

    A

    see Figure

    1 )

    Bingham plastic, slope po and i ntercepts

    1 r p

    Pseudoplastic, n <

    1

    in Equation 21

    Dilatant, with n >

    1

    in Equation

    21

    VOL.

    50,

    NO. 3

    MARCH

    1958 347

  • 8/18/2019 scambio termico

    2/6

    Table 1

    Values

    for

    Bingham

    Flow

    TO

    0.1 0 . 2 0 . 3 0.4 0 .5 0 . 6 0.7 0.8 0 .9

    .01

    0

    0.01

    0.03

    0.05

    0.07

    0.1

    0.2

    0.3

    0.4

    0.5

    0.6

    0.7

    0.8

    0.9

    1.0

    0

    0.01

    0.03

    0.05

    0.07

    0.1

    0.2

    0.3

    0.4

    Q.5

    0.6

    0.7

    0.8

    0.9

    1.0

    0

    0.01

    0.03

    0.05

    0.07

    0.1

    0.2

    0.3

    0.4

    0.5

    0.6

    0.7

    0.8

    0.9

    1.0

    0

    0.01

    0.03

    0.05

    0.07

    0.1

    0.2

    0.3

    0.4

    0.5

    0.6

    0.7

    0.8

    0.9

    1.0

    0.0000

    0.3295

    0.3776

    0.4080

    0.4326

    0.4637

    0.5461

    0.6147

    0.6770

    0.7355

    0.7915

    0.8455

    0.8981

    0.9495

    1.0000

    0.1000

    0.3709

    0.4195

    0.4507

    0.4757

    0.5075

    0.5916

    0.6614

    0.7246

    0.7838

    0.8404

    0.8960

    0.9481

    1.0000

    0.3000

    0.4727

    0.5194

    0.5501

    0.5751

    0.6070

    0.6922

    0.7630

    0.8272

    0.8873

    0.9447

    1.0000

    0.4000

    0.5335

    0.5775

    0.6072

    0.6316

    0.6629

    0.7474

    0.8181

    0.8823

    0.9425

    1.0000

    0.5000

    0.6006

    0.6410

    0.6691

    0.6925

    0.7229

    0.8059

    0.8760

    0.9399

    1.0000

    0.6000

    0.6734

    0.7095

    0.7356

    0.7577

    0.7868

    0.8676

    0.9367

    1.0000

    0.7000

    0.7512

    0.7826

    0.8064

    0.8269

    0.8544

    0.9323

    1.0000

    0.2000

    0.4185

    0.4667

    0.4980

    0.5232

    0.5552

    0.6402

    0.7108

    0.7746

    0.8344

    0.8915

    0.9465

    1.0000

    0.8000

    0.8334

    0.8600

    0.8811

    0.8999

    0.9256

    1.0000

    0.9000

    0.9195

    0.9411

    0.9595

    0.9764

    1.0000

    0.005000

    0.003306

    0.001807

    0.0008701

    0.0002977

    0

    90

    0.1250

    0.08914

    0.07486

    0.06523

    0.05749

    0.04787

    0.02502

    0.01069

    0.002639

    0

    0.5000

    0.3252

    0.2902

    0.2675

    0.2497

    0.2273

    0.1671

    0.1271

    0.09204

    0.06330

    0.04044

    0.02214

    0.009983

    0.002480

    0

    0.4050

    0.2687

    0.2375

    0.2175

    0.2016

    0.1817

    0.1315

    0.09393

    0.06413

    0.04066

    0.02272

    0.01007

    0.002541

    0

    0.3200

    0.2165

    0.1896

    0.1721

    0.1582

    0.1409

    0.09743

    0.06559

    0.04123

    0.02292

    0.0101 1

    0.002535

    0

    0.2450

    0.1689

    0.1463

    0.1315

    0.1196

    0.1049

    0.06821

    0.04226

    0.02330

    0.01024

    0.002555

    0

    0.1800

    0.1263

    0.1080

    0.09577

    0.08596

    0.07374

    0.04405

    0.02394

    0.01041

    0.002572

    0

    0.08000

    0.05776

    0.04734

    0.04018

    0.03441

    0.02731

    0.01122

    0.002686

    0

    0.04500

    0.03269

    0.02579

    0.02088

    0.01701

    0.01232

    0.002840

    0

    0.02000

    0.01437

    0.01042

    0.007669

    0.00533 1

    0.003122

    0

    Q B

    0.4752 0.3541

    0.3638 0.2700

    0.3192 0.2324

    0.2876 0.2057

    0.2611 0 1833

    0.2268 0.1545

    0.1372 0 . O m 2

    0.07353 0.03486

    0.03085 0.008273

    0.007177

    0

    0

    __

    0.06990 0.01875

    0.05133 0.01252

    0.03784 0.006939

    0.02820 0.003382

    0.02053 0.001178

    0.01174 0

    0

    0.8667

    0.6745

    0.6123

    0.5685

    0.5315

    0.4825

    0.3480

    0.2401

    0.1541

    0.08893

    0.04349

    0.01597

    0.003030

    0

    0.7339

    0.5677

    0.5109

    0.4709

    0.4371

    0.3928

    0.2726

    0.1788

    0.1067

    0.05473

    0.02 151

    0.004579

    0

    0.6028

    0.4636

    0.4126

    0.3767

    0.3464

    0.3069

    0.2015

    0.1224

    0.06460

    0.02648

    0.005929

    0

    1.0000

    0.7829

    0.7153

    0.6679

    0 6276

    0.5743

    0 4258

    0.3041

    0.2043

    0.1260

    0.0686

    0.03066

    0.009608

    0.001298

    0

    ...

    ...

    e . .

    I

    ...

    ...

    ...

    ...

    ...

    ...

    ...

    ...

    ...

    ...

    0.2432

    0.1845

    0.1546

    0.1331

    0.1153

    0.09267

    0.03882

    0.009272

    0

    0.1467

    0.1103

    0.08859

    0,07284

    0.05995

    0.04398

    0.01034

    0

    QBITO

    0.7082

    0,5400

    0.4648

    0.4104

    0.3666

    0.3090

    0.1642

    0.06972

    0.01655

    0

    2.009

    1.545

    1.388

    1.256

    1.155

    1.023

    0.6717

    0.4080

    0.2153

    0.08827

    0.01976

    0

    1.188

    0,9095

    0.7980

    0.7190

    0.6528

    0.5670

    0.3430

    0.1839

    0.07712

    0,01794

    0

    8.667

    6.745

    3.670

    2.839

    2.555

    2.354

    2.186

    1.964

    1.363

    0.8940

    0.5335

    0.2736

    0.1076

    0.02190

    0

    0.4053

    0.3075

    0.2577

    0.2218

    0.1922

    0.1544

    0.06470

    0.01545

    0

    0.08738 0.02083

    0.06416 0.01391

    0.04730 0.007710

    0.03525 0.003758

    0.02566 0.001309

    0.01469 0

    0

    0.2096

    0.1576

    0.1266

    0.1040

    0.08564

    0.06283

    0.01477

    0

    6.123

    5.685

    5.315

    4.825

    3.480

    2.401

    1.541

    0.8893

    0.4349

    0.1597

    0.0303

    0

    ...

    Table II. Values of X

    for Power Law

    Model

    K

    8

    0

    0 . 5 =

    1

    2

    3

    4

    5

    6

    7

    8

    9

    10

    m

    a Obtain

    0.01

    0.1

    0.5050

    0.5500

    0.4000

    0.5000

    0.3295

    0.4637

    0.2318

    0.4192

    0.1817 0.3932

    0.1640

    0.3787

    0.1503

    0.3712

    0.1413 0.3606

    0.1350

    0.3550

    0.1304

    0.3506

    0.1268

    0.3470

    0.1237 0.3442

    0.1000

    0.3162

    ed by interpolation and chec

    0 . 2

    0.6000

    0.5710

    0.5461

    0.5189

    0.5030

    0.4927

    0.4856

    0.4804

    0.4764

    0.4733

    0.4707

    0.4687

    0.4472

    :ked

    b y num

    0.3

    0.6500

    0.6300

    0.6147

    0.5970

    0.5866

    0.5797

    0.5749

    0.5713

    0.5686

    0.5664

    0.5646

    0.5632

    0.5477

    erica1 integral

    0 . 4

    0.7000

    0.6875

    0.6770

    0.6655

    0.6587

    0.6541

    0.6509

    0.6486

    0.6467

    0.6453

    0.6441

    0.6325

    ion.

    b Obi

    0.6429

    0 .5 0.6

    0.7500 0.8000

    0.7420

    0.7960

    0.7355

    0.7915

    0.7280 0.7872

    0.7239

    0.7847

    0.7211 0.7830

    0.7191

    0.7818

    0.7175

    0.7809

    0.7164

    0.7801

    0.7154

    0.7794

    0.7147

    0.

    7tBb

    0.7141b

    0.7784b

    0.7071 0.7746

    ;ained from a plot of X

    u s .

    0.7

    0.8500

    0.8470

    0.8455

    0.8433

    0.8420

    0.8411

    0.8405

    0.8401

    0.8397b

    0. 3945

    0.8390b

    0,8389'

    0.8367

    l/ s by interp

    0 .8

    0.9000

    0.8990

    0.8981

    0.8972

    0.8967

    0.8962

    0.8960

    0.8958*

    0.8957*

    0 895S5

    0.8959

    0.8953b

    0.8944

    Nolation.

    0.9

    0.9500

    0.9497

    0.9495

    0.9493

    0.9492

    0.9491b

    0.9491*

    0. 9490b

    0.9490b

    0.948gb

    0.948gb

    0. 948g5

    0.9487

    348

    INDUSTRIAL AND ENGINEERING CHEMISTRY

  • 8/18/2019 scambio termico

    3/6

    NON-NEWTONIAN

    FLOW

    Table 1 1 1

    Values of s

    +

    2)Qp/ l

    ) +

    = T(s,

    K )

    and

    v,,,/v,,

    for Power Law Model

    0.01 0 . 1 0.2 0.3 0.4 0 . 5 0.6 0.7 0.8 0.9

    0.5050 0.5500 0.6000 0.6500 0.7000 0.7500 0.8000 0.8500 0.9000 0.9500

    0.5312

    0.5606 0.6062

    0.6539

    0.7024 0.7516

    0.8009

    0.8504 0.9002 0.9500

    0.5397

    0.5641

    0.6082

    0.6552

    0.7032 0.7521 0.8011

    0.8506 0.9003

    0.9501

    0.5566 0.5710 0.6122 0.6577 0.7048 0.7531 0.8018 0.8509 0.9004 0.9501

    0.6051

    0.5908 0.6237 0.6649 0.7094 0.7560 0.8034

    0.8517

    0.9008

    0.95OZb

    0.6929

    0.6270 0.6445 0.6781

    0.7179 0.7611 0.8064

    0.8533 0.9015b 0.9504b

    0.7468

    0.6547 0.6612

    0.6882

    0.7246 0.7651

    0. SO81

    0.8546 0. 9022b 0. 9506b

    0.7819 0.6755 0.6736 0.6966

    0.7297 0.7685 0.8107 0.8551 0.9027b O.950Sb

    0.8064

    0.6924 0.6838 0.7030

    0.7342 0.7711 O.812Sb

    0.856Sb

    0.9032b 0.951ob

    0.8246

    0.7046 0.6919 0.7084

    0.7372 0.7732 0.8144b

    0.8577b

    0.9036b O.951lb

    0.8388

    0.7150 0.6987

    0.7128 0.7401 0.7751 0.8160b

    0.8585b

    0.9041b 0.9513b

    0.8502

    0.7235 0.7042 0.7164

    0.7418 0.7760 0.816Sb

    0.8594b 0.9045h 0.9515b

    0.8595

    0.7306 0.7089

    0.7195 0.7446

    0 .

    7770b 0.8176*

    0.8602b 0.9050b

    0.9517b

    0.8673

    0.7367 0.7130

    0.7222b

    0.7462b 0.777Sb 0.8184b 0.8611b 0.9054b 0.951Qb

    K

    S

    f

    2)/ '/(1 - ) ' =

    y(S,

    K )

    S

    0

    1/4a

    1/3

    1 2

    1

    2

    3

    4

    5

    6

    7

    8

    9

    10

    0 2.000 2.000

    2.000

    2.000

    2.000 2.000

    1/4a 1.869

    1.803 1.815 1.810

    1.806 1.803

    1/3 1.835 1.787 1,769 1.762

    1.757 1.754

    1/2 1.778 1.714 1.693

    1.682 1.676

    1.672

    1 1.662

    1.567 1.538

    1.523

    1.514 1.508

    2 1.540 1.419 1.380

    1.361 1.350

    1.344

    3 1.442 1.342 1.297 1.278 1.267 1.261

    4 1.365 1.280 1.246 1.227 1.217 1.212

    5 1.310 1.240 1.210 1.194 1.186 1.180

    6 1.270

    1.210 1.183

    1.168

    1.152 1.146

    7 1.239 1.187 1.162 1.146

    1. 129' 1. 127c

    8 1.215 1.168 1.145 1.130 1.114c 1.113c

    9 1.192 1.154 1.132

    1.117 1.102c

    1.101

    10 1.176

    1.140 1.120 1.106c 1.093c

    1.092c

    m 1.000

    1.000 1.000 1.000

    1.000 1.000

    * Obtained by parabolic interpolation using values for

    8

    = 0 , 1, 2.

    Obtained by graphical interpolation

    of

    T s,

    K ) / T (O ,

    ) , using the fact that lim T(s ,

    K )

    K + 1

    =

    1.

    2 000

    1.802

    1.752

    1.670

    1.505

    1.340

    1.257

    1.208

    1. 177c

    1. 145c

    1. 126c

    1.1120

    1.1000

    1.091c

    1.000

    2.000

    1.802

    1.752

    1.669

    1.504

    1.3370

    1. 254c

    1.205

    1.

    174c

    1. 144c

    1.126O

    1.111c

    1.lOOC

    1.091c

    1.000

    2 000

    1.800

    1.751

    1.668

    1.502

    1. 336c

    1.

    252c

    1. 203c

    1. 17lC

    1. 143'

    1.125'

    1.111c

    11OOG

    1.0910

    1.000

    2.000

    1.800

    1.750

    1.667

    1.501.

    1,334=

    1.2518

    1.201s

    1.

    16QC

    1. 143c

    1. 125c

    1.111'

    1 low

    1

    0910

    1,000

    Obtained by graphical interpolation of '=using th e fact th at

    vmax /z ~Bv-

    1

    a s s + m

    + 2 I

    Combination of Equations 7 and

    8

    and

    integration over p gives th e following ex-

    pressions for the velocity distribution :

    1

    L = -T T o p ) - 3 p 2 2 )

    +

    X 2 h P ;

    K

    5

    P 5

    h

    11)

    Go

    =

    (h) ++ ; A-

    5 P 5

    X

    (12)

    1

    ++ =

    To(1

    ) + 2 1 021 +

    Xalnp;

    A+

    5

    p

    5

    1 13)

    where use has been made of the boundary

    conditions that 4 = 0 at p = K and

    p =

    1.

    The determining equation for

    A,

    is just t he statement that the velocity

    4- A- ) be the same as q5+

    A,)

    :

    To

    - ) ~I- 2To(l A + ) = 0

    (14)

    From this equation X+ has been deter-

    mined as a function

    of K

    and TO nd is

    plotted in Figure

    3.

    The volume rate of

    flow

    for the Bing-

    ham plastic is obtained by integrating

    the velocity distribut ion in Equations

    11,

    12, and 13 over the annular region and

    simplifying the result with the help of

    Equation 1 4

    1

    Q = 2rR2 v,pdp

    Q/ rR4P/8pO)s plotted in Figure 4 s a

    function of

    K

    and

    TO.

    This graph

    enables one to compu te easily the volume

    rate of flow for a given pressure drop

    when the dimensions of R and K and po

    and

    TO

    re known.

    A

    plot of

    C l B / T o

    (Figure 5 is useful for calculating the

    This expression holds for

    TO> 1

    K ) ;

    there is no flow if

    TO5 (1

    ) . The

    dimensionless volume rate of flow OB =

    Figure

    3.

    X ,

    and , for Bing-

    ham plastic flow

    in an annulus

    10

    0.8

    06

    2

    0 4

    a2

    00

    VOL.

    50,

    NO. 3 MARCH 1958

    349

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    4/6

    YO

    4

    Figure

    4.

    for Bingham plastic

    10

    flow through an annulus

    09 09

    08 08

    07

    07

    06

    Figure 6.

    X

    for power law flow

    b 06

    through an annulus

    -

    0 5

    50s

    -

    I-0

    P O

    04

    03

    03

    0 2

    0 2

    01

    01

    00

    00

    00

    1

    02 a3 04 05

    06

    07 08 09 i o

    K

    pressure drop when the volume rate of Bingham Flow in Circular Tubes Solut ion

    for

    the Power l a w Mode l

    flow is known. Th e use of Figures 4 and

    5

    is discussed in Exam ples

    1

    and

    2.

    The For this model the local shear stress

    TR4P 4 1 depends on the local shear rate as follows:

    numerical results for the Bingham

    flow

    (21

    1

    For high rates of

    flow

    when the plug

    flow region is small compared with the

    dimensions of the annulus, Equation 1 5

    in which m and n are the rheological con-

    stants, obtainable by viscometric tech-

    ma y be simplified by using the Newtonian

    niques

    (7,

    I I ,

    12).

    Neivtonian fluids are

    a special case

    of

    Equation 21 with

    rn

    =

    p

    expression for

    X

    (see Equation

    18)

    and

    making the further assumption that

    A,

    + X- F

    2X.

    Then:

    Equations

    21

    and

    4

    may be combined

    and integrated to give the velocity dis-

    ( K = 0

    X-

    =

    0, X+

    = To)

    Q = __ [ I

    -

    T~+ W ] ( 1 7 )

    calculations are presented in Table I. PO

    3

    Newtonian Flow in Circular

    Annulus

    ( T , = O , P ~ = ~ , X + ~ = X _ ~ = ( ~

    21n (1;;;)

    Q

    = __ [(l - i*

    (1

      18)

    R4P

    8 P

    In 1 / K ) a n d n = 1.

    Newtonian Flow in

    a

    tribution:

    (15a) Very Thin

    lit

    ~1~ R ( P R / 2 m ) s ) d p ; ti

    5

    p

    5 X (22)

    5 P 5 1 (23)

    (1

    4) M

    ( 1 +

    3) To

    Q e[ n

    (1/.)

    This expression differs slightly from that

    (To

    =

    0,

    /

    =

    p ,

    K w

    1)

    given by Laird 5, Equation 30).

    Eauation 15 are: Q = 1 1 9 )

    l1P

    Five important limiting cases

    of

    ?rR4P v, = R ( P R ) / 2 m ) e

    UP

    Newtonian Flow in Circular Tubes

    in which s = l / n ; in the integrations,

    and p =

    1

    have been used. Clcarly both

    Equations 22 and 23 must give the same

    value of velocity at p =

    X :

    To

    =

    0

    =

    0,

    Po

    =

    P )

    Bingham in a V e r y

    Thin

    the boundary conditions

    u, = 0

    at

    p =

    K

    Iar

    Slit ( K

    = 1

    r R 4 P

    GPO

    I -

    ) 3

    [ I -

    16)

    r R 4 P

    Q = -

    8~

    LA p) dp =

    L1

    P - ? ) d p (24)

    This is the determining equation for A,

    which is a function of K and s.

    Finally the volume rate of flow is ob-

    tained by substituting Equations 22 and

    23 into the first line of Equa tion 15. The

    order of integration may then be inter-

    changed and one integration performed

    to give:

    Q = T ~ 3 ~ ~ / 2 m ) h I ~2 6 + l p - a d

    P

    (25)

    L1

    which can easily be integrated once

    X

    has

    been determined from Equation 24.

    The integrals appearing in the general

    results in Equations 24 and 25 may

    b

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    WON-NEWTONIAN FLOW

    0

    0 1

    0 2 0 3 0 4

    05 06 0 1 0 8 0 9

    I O

    K

    easily be integrated when

    s

    is a positive

    integer (pseudoplastic materials), by ex-

    pandin g the integrands in a binomial ex-

    pansion and interchanging the order of

    summation and integration. Equation

    24, which determines

    X,

    then becomes:

    k A s g hac+ A s f 1 = 0

    s

    = 1,2,3. . .(26)

    i = O

    i # T

    + l

    in which

    (;) (-1)ifl

    1

    1

    +

    (-1)8 K 8 - - 2 i t 1

    ,I =

    s - 2 i + 1

    A = 2 2 (:) (-')' [seven] (29)

    i = O s 2i + 1

    Equations 26 to 29 are polynomial

    equations which can be solved to get

    X

    as

    a

    function of

    s

    and

    K ,

    although this

    method breaks down for high values of

    s

    and K . Values of X so computed were

    used to prepare Table

    I1

    and Figure

    6.

    The limiting values of h are h =

    (1

    + ) /

    2 a t

    s

    = 0 and X = t

    s

    = co.

    The latter may be shown by expanding

    the int egrand of the left side of Equatio n

    24 in a Taylor series about p = K and

    the right side about p = 1, and taking

    the first term in both expansions.

    The expression for the throughput rate

    given in Equation 25 may be expanded

    in a similar fashion to get:

    Figure 7.

    vmnx/vav for

    power law

    flow through

    an annulus

    4

    IO

    0 9

    o n

    -

    0 7

    b

    Figure 8.

    T(s, K )

    for

    power law

    flow through

    an annulus

    K

    Power Law Flow in

    a

    Very

    Thin

    Annular Slit

    =

    R3(PR/2rn)8 n p ( s , K ) (30)

    Applications

    in which

    1

    (31)

    - l )a+ lKI- -2 i+8

    s - 1

    ( -1) In (1 / ~) [sodd]

    (32)

    [seven] (33)

    i = o 2i

    - s + l

    T(s, K ) , defined by 'T (s, E ) = (s + 2 )

    QP/ l- ) ' + ~ ,

    is tabulated in Table

    111

    as a

    function of s and

    X .

    One can

    easily compute the throughput for any

    pressure drop once the dimensions of

    R

    and

    K

    and m and

    s

    are known. Table 111

    may also be used to deduce the rheo-

    logical constants from annular flow data

    (Examples 3 and

    4).

    The various limiting cases of Equation

    30 may be tabulated :

    Newtonian Flow

    in

    a Circular Tube

    (s

    =

    1, m = p, K = 0)-Equation 16

    Power-Law Flow

    in a

    Circular Tu be

    S

    1, K =

    0 )

    Example

    1.

    Calculation of Pressure

    Drop for Annular Flow

    of

    a Bingham

    Plastic Material.

    A

    mud having a den-

    sity of 1.69 grams per cc.

    flows

    at 5 feet

    per second average velocity through an

    annulus made from 0.5-inch sta ndard pipe

    (outside diameter = 0.840 inch =

    0.0700

    foot) and 2-inch standard pipe (inside

    diameter = 2.067 inches

    =

    0.1726 foot).

    The Bingham plastic constants for this solu-

    tion are 7 = 0.554 pound/ per square foot

    and po

    =

    0.000582 pound, second per

    square foot. Compute the pressure drop

    per unit length required.

    SOLUTION.From the dimensions of the

    annulus, K

    =

    0.840/2.067

    =

    0.406 and

    R = 0.1726/2 = 0.0863 foot. The

    volume throughput is given by:

    Q = nR2(1 ')U,,.

    ~ ( 0 . 0 8 6 3 ) ~l 0.406)2]

    = 0.09775 cubic foot per second.

    The quantity &/To = 4fi0Q/nR3~os then:

    O B I T O=

    4(0.000582) (0.09775)/

    ~ ( 0 . 0 8 6 3 ) ~0.554) = 0.204

    From Figure 5, TO= 0.295. Thus , the

    pressure drop per u nit length:

    P = 270/ToR = 2(0.554)/(0.295) (0.0863)

    = 43.5 poundf per square foot per foot

    = 0.30 pound/ per square inch per foot

    Newtonian Flow

    in a

    Circular

    An

    Example 2. Deduction

    of

    Bingham

    Plastic Rheological Constants from An-

    nulus (s

    = = kh * o)-Equation nu la r Flow Data,

    A

    Bingham plastic

    18

    material flows through the annulus de-

    Newtonian Flow in

    a

    Verv Thin An- scribed in Example 1. The following

    data are obtained; For v,, = 5 feet p&

    second, P = 16.8 pound, square foot per

    foot; for 0, 10 feet per second, P = 28.3

    nula r Slit

    (s

    = 1,

    m = p , K =

    1)-Equation 19

    VOL. 50, NO. 3 MARCH 1958 351

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    pound, per square foot per foot. Calcu-

    late T Oand P O or the substance.

    SOLUTION.By using Equation 15

    we

    can calculate the ratio of 0,

    ( 5

    feet per

    second) to C ~ 10 feet per second)

    :

    Q B ( ~

    t./sec.)

    Q ~ ( 1 0t./sec.)

    Q ( 5 ft./sec.) P(10 ft. /sec.)

    Q(l0 ft./sec.) P(5 ft./sec.)

    Similarly, from Equation 6, we find:

    Ta(5 ft./sec.) P(10 ft./sec.)

    To(1O ft. /sec.) ~ ( 5t. /sec.)

    -

    ’$ = 1.685

    I n order to calculate th e value of

    TO

    t

    either flow rate, a trial-and-error method

    is

    used. This can be done by assuming a

    value of

    TO

    t one velocity from which one

    can get

    To

    at the other velocity. Values

    of fie corresponding to these two TO alues

    may be found from Fi ure 4. T h e ratio

    of

    ne (5

    feet per second7 to Q B (IO feet per

    second) is then computed; the procedure

    is repeated until this ratio is as near to 0.843

    as is desired. Such a trial- and-error pro-

    cedure takes the form

    :

    To

    To(l0 Q B 5 Ft./Sec.)/

    (5 Ft./Sec.) Ft./Sec.)

    Re(10 Ft./Sec.)

    0.100 0.060 0.868

    0 . 2 0 0

    0.119

    0.730

    0.138 0.082

    0.837

    Hence, Equation 6 gives TO =

    ToPR. 2

    =

    (0.138)(16.8)(0.0863)/2

    =

    0.10 poundf

    per square foot. Th en from Equation 15

    Q

    = 0.09775 =

    ~ ( 0 . 0 8 6 3 ) ~16.8) (0.1 33)/8~0

    whence it is found tha t

    po

    = 0.0005 pound?

    second per square foot.

    Example 3. Calculation of Pressure

    Drop for

    Power-Law Flow through

    an Annulus.

    A

    0.67% aqueous solution

    of carboxy methyl cellulose flows at 5 feet

    per second average velocity through the

    annulus described in Example

    1.

    The

    power law constants for this solution 8) are

    s = 1.398 and rn = 0.00635 pound/

    (second)O.7’6 per sq uare foot. Compute

    the pressure drop per un it length required.

    SOLUTION. s in Example

    1,

    K = 0.406

    and R = 0.0863 foot. The volume

    throughput is

    Q = .rrR’(I - K~)U,\..

    ~(0.0863)’ l - (0.406)’] (5)

    = 0.09775 cubic foot per second

    For the values of K and s given above, we

    find by interpolation from Table I11 that

    th e dimensionless function T s,

    K )

    is 0.7155.

    Hence the dimensionless throughput is:

    fi p =

    (1 - ) ’ + ’ ( S

    +

    2 ) - ’ T S ,

    K )

    (1 0.406)’.’9*+2 1.398 + 2)-’

    (0.7155)

    = 0.0359

    From Equation 30

    0.09775 = ~ ( 0 . 0 8 6 3 ) ~0.0863 P /

    (2) (0.00635))’,[email protected])

    whence

    P =

    25.5 pound, per cubic

    foot

    or

    0.177 pound, per square inch per foot.

    Deduction

    of

    Power Law

    Constants from Flow through an

    An-

    nulus. A polymer solution known to be

    of

    the power-law type flows through the

    annulus described in Example

    1.

    The

    following dat a are obtained : at Q =

    0.09775 cubic foot per second,

    P

    = 326

    Example

    4.

    pound, per square foot per foot and at

    Q

    =

    0.19550 cubic foot per second, P = 460

    pound, per square foot per foot. It is de-

    sired to calculate the power-law constants

    of this fluid.

    SOLUTION. rom Equation 30 we have

    0.09775 =

    ?iR3

    (326R/2m)s Q p ( s , 0.406)

    0.19550 = .rrR3((460R/2m)’Qp(~,.406)

    Division of these two expressions gives the n:

    (112) = (326/460)s

    when s = 2.0 (or n = 0.50). Interpolating

    from Table 111, we f i nd T(2.0 , 0.406)

    =

    0.7205, whence Q p = 0.0224. Hence

    Equation 30 gives (for Q = 0.09775 cubic

    foot per second).

    0.09775 = ~10.0 863) ’ (326) (0.0863)/

    (2m)]*.O 0.0224)

    from which = 0.30 pound, (second)0,50

    per square foot.

    Acknowledgment

    The authors are greatly indebted to

    the computing staff of the University of

    Wisconsin Naval Research Laboratory,

    under the direction

    of

    Elaine Gessert,

    for assistance with the computational

    work. Th ey wish to thank J. 0 Hirsch-

    felder for making these arrangements

    possible.

    Nomenclature

    9

    2

    L

    m,

    P

    Po

    PL

    P

    0

    r

    R

    S

    t

    T

    TO

    V

    VZ

    2

    Y

    K

    x

    = external body force per unit

    = dummy index used in sum-

    = length

    of

    annu lar region

    = parameters in power law

    model (Equation 21)

    =

    static pressure

    = static pressure at entrance

    = static pressure at exit to

    mass

    mations

    to annulus

    (z

    =

    0)

    annulus ( z

    = L )

    =

    Po P d / L

    +

    Ygz

    = volume rate of flow through

    annulus

    = radial coordinate, measured

    from common axis of cyl-

    inders forming annulus

    = radius of outer cylinder of

    annulus

    =

    reciprocal of

    = time

    = dimensionless shear-stress for

    Bingham flow (Equation 6)

    = dimensionless limiting shear-

    stress

    for

    Bingham flow

    (Equation

    6)

    = velocity vector

    = z-component of velocity vec-

    tor

    =

    axial coordinate, measured

    from entrance of annulus

    = mass density of fluid

    = ratio of radius of inner cyl-

    inder to that of outer cvl-

    P = Xewt onian viscosity

    = “plastic viscositv”

    of

    the

    ABingliarn plastic (Equ a-

    tion 5)

    = expansion coefficients in ex-

    pression for volume rate of

    flow of a power-law fluid

    through an annulus (de-

    fined in Equations 31, 32,

    and 33)

    = 3.1416

    = r,’R = dimensionless radial.

    coordinate

    = she ar stress tensor

    = limiting shear stress of Bing-

    ham fluid

    =

    rt-component of shear stress

    tensor

    = function defined just after

    Equation 33

    = dimensionless velociry for

    Bingham plastic (Equation

    6)

    40

    =

    dimensionless maximum ve-

    locity for Bingham plastic

    (Equation 12)

    +-, ++ = dimensionless velocity for

    Bingham plastic outside

    plug flow region (defined

    in Equations 11 and

    13)

    OB: Q p = dimensionless

    flow

    rates for

    Bingham and power-law

    models, respectively

    A = “del” or “nabla” operator

    literature Cited

    (1) Bird,

    R.

    B.,

    SPE

    Journal 11, 35-40

    (1955).

    (2) Bird, R. B., “Theory of Diffusion,”

    Chau. in “Advances in Chemical

    Engineering,” vol. 1, pp. 155-239,

    Academic Press,

    New

    York, 1956.

    (3) Christiansen,

    E.

    B., Ryan, N. W.,

    Stevens, Lt’.

    E. ,

    A.I.Ch.E. Journal

    1, 544-9 (1955).

    (4) Hirschfelder, J .

    O.,

    Curtiss, C. F.,

    Bird,

    R.

    B., “Molecular Theory

    of

    Gases and Liquids,” Chap. 11,

    Wiley, New York, 1954.

    (5) Laird,

    h’. M., ~ N D .

    ENG.CHEM. 49,

    138-41 (1957).

    Lyche, B. k. ird, R. B., Chem. Eng.

    Metzner, A . B., “Yon-Newtonian

    Technology

    :

    Fluid Mechanics,

    Mixing, and Heat Transfer,” in

    “Advances in Chemical Engineer-

    ing,” vol. I pp. 77-153, Academic

    Press, New York, 1956.

    Metzner, A. B., Reed, J. C., A.I .Ch.E.

    Journal

    1

    434-41 (1955).

    Mori,

    Y.,

    Ototake, N . , Chem. Eng.

    J u p u n ) 17, 224-9 (1953).

    Olphen, H. van, J . Znst.

    Petroleum

    36 ,

    223-34 (1950).

    Philippoff,

    W.,

    Viskositat der

    Kolloide,” Steinkopff, 1942; Ed-

    wards Brothers, Ann Arbor, Mich.,

    Sci.

    6, 35-41 (1956).

    1944.

    (12 ) Reiner, M., “Deformation and Flow,”

    H.

    K. Lewis and Co., London,

    1949.

    RECEIVEDor review February 13, 1957

    h C E P T E D Jun e 10, 1957

    ind er Division of Industri al and Engineering

    = value of dimensionless rad ial Chemistry, Symposium

    on

    Fluid

    Me-

    coordinate for which chanics in Chemical Engineering, Purdue

    University, Lafayette, Ind., December

    1956. Presented in part , Society of Rheol-

    hear stress is zero

    ogy, Pittsburgh, Pa., November 1956.

    x = limits of plug

    flow

    region in

    Bin gha m flow Work supported by fellowship from Na-

    AS, ASZ = coefficients defined in Equ a- tional Science Foundation and grant from

    tions 27, 28, a n d

    29

    Wisconsin Alumni Research Foundation.

    352 INDUSTRIAL AN D ENGINEERING CHEMISTRY