safety data sheets - douglas county, wi
TRANSCRIPT
Safety Data Sheet Index
Binder: HHS 4th Floor - HHS 4th Floor
096-000 106-97-8 Norazza, Inc. 05/05/2015 3
CARPET STAIN REMOVER Spartan Chemical Company, Inc. 01/22/2015 8
Clorox Commercial Solutions Green Works 99%Naturally Derived General Purpose Cleaner -Ready-to-Use Solution - 1:48 from Concentrate
Clorox Professional ProductsCompany
05/23/2015 14
Comet Deodorizing Cleanser with Chlorinol Procter & Gamble Professional 06/12/2015 23
Disinfecting Multi-Surface Cleaner Seventh Generation Inc 05/28/2015 30
Expo White Board Cleaner Newell Rubbermaid 08/05/2015 36
Fabuloso Pro APC Cleaner Lavender Colgate-Palmolive Company 44
Febreze Air Effects - Sun Baked Procter & Gamble 02/24/2015 53
Goo Gone Spray Gel Goo Gone 08/14/2014 60
Lemon SHine Furnature Polish Nyco Products Company 08/16/2005 66
MURPHY OIL SOAP WOOD CLEANERSPRAY RTU
Colgate-Palmolive Company 05/22/2015 68
Office Max Compressed Gas Duster 75-37-6 Falcon Safety Products, Inc 04/28/2015 75
PLEDGE FURNITURE CLEANER & POLISHWITH NATURAL ORANGE OIL
S.C. Johnson and Son, Limited 05/21/2014 83
PURELL Hand Sanitizing Wipes GOJO Industries, Inc. 03/30/2015 91
Sani-Cloth HB Germicidal Disposable Wipe Professional DisposablesInternational, Inc. NP Nice Pak
105
SHINE M UP AEROSOLSAMPLE, CAN CL CERTIFIED LABS - DIVISION OFNCH CORPORATION
11/18/2009 111
Static Free Hand Guard CHEMTRONICS 05/18/2015 115
ULTRA MARK ICELAND DAWN Mohawk Finishing ProductsDivision of RPM Wood FinishesGroup, Inc.
07/04/2015 126
Product Name CAS Number Manufacturer Version Date Page
Page 2 of 132Page 2 of 132Page 2 of 132Page 2 of 132
Page 1 of 4 SDS for: 2914011
Printed: 5/5/2015
SAFETY DATA SHEET This document is not intended for general distribution.
It can be used as the basis for a general distribution document if appropriate changes are made to the identification
section.
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: 096-000 Product Code: 2914011 Chemical Name: Endust for Electronics Screen & Electronics Cleaner 8oz Details of the supplier of the safety data sheet:
This Safety Data Sheet has been updated in accordance with the Global Harmonized System (GHS) Manufacturer/Supplier:
Norazza, Inc. 3938 Broadway St Buffalo NY 14227 US Supplier Phone Number: Contact Phone 716-706-1160
Emergency telephone number: 800-255-3924 International +01-813-248-0585
Product Use: Anti-static cleaner for electronic equipment
2. HAZARDS IDENTIFICATION
CLASSIFICATION
Flammable aerosol 2
Gas under pressure Liquefied gas
SIGNAL WORD: Warning
Page 3 of 132Page 3 of 132Page 3 of 132Page 3 of 132
Page 2 of 4 SDS for: 2914011
Printed: 5/5/2015
Hazard Statements
Flammable aerosol
Contains gas under pressure; may explode if heated
Precautionary Statements
Keep away from heat/sparks/open flames/hot surfaces – No smoking
Do not spray on an open flame or other ignition source
Pressurized container – Do not pierce or burn, even after use
Protect from sunlight. Store in a well ventilated place
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No. Percent
WATER 7732-18-5 97.00
BUTANE 106-97-8 1.90
4. FIRST AID MEASURES
INHALATION: Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped
. Get medical attention.
EYE CONTACT: Wash immediately with large volumes of fresh water for at least 15 minutes . Get medical attention.
SKIN CONTACT: Wipe off with a towel. Wash with soap and water. Get medical attention if irritation persists.
INGESTION: Not a likely route of exposure.
Most important symptoms/effects, acute and delayed: Repeated exposure may cause skin dryness or cracking.
May cause drowsiness or dizziness.
Indication of immediate medical attention and special treatment needed: None known.
5. FIRE FIGHTING MEASURES
Suitable and unsuitable extinguising media: Foam, Alcohol foam, CO2, Dry chemical, Water fog . Water spray
may be ineffective.
Specific hazards arising from the chemical: Closed containers may explode from internal pressure build-up when
exposed to extreme heat and discharge contents. Liquid content of container will support combustion.
Overexposure to decomposition products may cause a health hazard. Symptoms may not be readily apparent.
Obtain medical attention. Hazardous decomposition products include carbon dioxide, carbon monoxide, and other
toxic fumes
Special equipment and precautions for fire-fighters: Water may be used to cool containers to prevent pressure
build-up and explosion when exposed to extreme heat. Wear goggles and use self-contained breathing apparatus . If
water is used, fog nozzles are preferred.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment, and emergency procedures: Avoid breathing vapors. Ventilate
area. Remove all sources of ignition.
Page 4 of 132Page 4 of 132Page 4 of 132Page 4 of 132
Page 3 of 4 SDS for: 2914011
Printed: 5/5/2015
Methods and materials for containment and cleaning up: Clean up with absorbent material and place in closed
containers for disposal.
7. HANDLING AND STORAGE
Precautions for safe handling: Do not puncture or incinerate (burn) cans. Do not stick pins, nails, or any other
sharp objects into opening on top of can. Do not spray in eyes. Do not take internally. See product label for
additional information.
Conditions for safe storage, including any incompatibilities: Store and use in cool, dry, well-ventilated areas .
Do not store above 120 F.
8. EXPOSURE CONTROL/PERSONAL PROTECTION
Chemical Name / CAS No. OSHA Exposure Limits ACGIH Exposure Limits Other Exposure Limits
WATER
7732-18-5
Not established Not established
BUTANE
106-97-8
Not established TWA: 1000 ppm
Appropriate engineering controls: Ventilation should be sufficient to prevent inhalation of any vapors . General
dilution and/or local exhaust ventilation in volume to keep PEL/TLV of most hazardous ingredient below acceptable
limit and well below stated limit.
Individual protection measures:
Respiratory protection: None under normal use. Avoid breathing vapors. In restricted areas , use approved
chemical/mechanical filters designed to remove a combination or particles and vapor. In confined areas, use an
approved air line respirator or hood. Self-contained breathing apparatus is required for vapor concentrations above
PEL/TLV limits.
Protective gloves: None under normal use. Use solvent-resistant for prolonged or repeated contact.
Eye protection: None under normal use. However, use of safety glasses with splash guards or full face shield
should be used if indicated.
Other protective clothing or equipment: None under normal use. However, use of solvent- resistant aprons or other
clothing is recommended. Eye washes and safety showers in the workplace are recommended.
SHOWERS IN THE WORKPLACE ARE RECOMMENDED.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Aerosol product
Vapor Pressure: Not determined
Vapor Density: Heavier than air
Density: 0.985259828
Freezing point: Not determined
Boiling point: N/A
Evaporation rate: Slower than ether
Explosive Limits: Not determined
Auto ignition temperature: Not determined
Viscosity: Not determined
Page 5 of 132Page 5 of 132Page 5 of 132Page 5 of 132
Page 4 of 4 SDS for: 2914011
Printed: 5/5/2015
Odor: Pleasant
Odor threshold: Not determined
pH: Not determined
Melting point: Not determined
Solubility: Not determined Flash
point: Not determined
Flammability: Level 1 Aerosol
Partition coefficient (n- Not determined
octanol/water):
Decomposition temperature: Not determined
10. STABILITY AND REACTIVITY
Reactivity: Not reactive under normal conditions of use.
Chemical stability: Stable under normal storage and handling conditions.
Possibility of hazardous reactions: None known.
Incompatible materials:
No data
Hazardous decomposition products:
No data
11. TOXICOLOGICAL INFORMATION
Long-term toxicological studies have not been conducted for this product.
12. ECOLOGICAL INFORMATION
Long-term ecological studies have not been conducted for this product.
13. DISPOSAL CONSIDERATIONS
Page 6 of 132Page 6 of 132Page 6 of 132Page 6 of 132
Page 5 of 4 SDS for: 2914011
Printed: 5/5/2015
Dispose of in accordance with local, state, and federal regulations. Before attempting clean up, refer to other sections
this document for hazard cautionary information.
14. TRANSPORT INFORMATION
By land: DOT Proper Shipping Name: None required per 49 CFR 173 .306(i) for products that conform to the Limited
Quantity provisions. Commodity shipping description: Cleaning Compound, NOI
By water: DOT & IMDG Proper Shipping Name: UN1950, Aerosols, 2 .1, LTD QTY
By air: DOT & IATA Proper Shipping Name: UN1950, Aerosols, flammable, 2 .1, LTD QTY (packing instruction Y203
applies)
15. REGULATORY INFORMATION
All ingredients are either listed on the TSCA inventory or are exempt .
16. OTHER INFORMATION
Date revised: 2015-05-05
Date Printed: 2015-05-05
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE. HOWEVER, NO
WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE
OBTAINED FROM THE USE THEREOF. BECAUSE THE INFORMATION CONTAINED HEREIN MAY BE APPLIED
UNDER CONDITIONS BEYOND OUR CONTROL, WE ASSUME NO RESPONSIBILITY FOR ITS USE.
Revision 0
Page 7 of 132Page 7 of 132Page 7 of 132Page 7 of 132
Revision Date: 22-Jan-2015
Safety Data SheetSpartan Chemical Company, Inc.
1. PRODUCT AND COMPANY IDENTIFICATION
Product Identifier Product Name: CARPET STAIN REMOVERProduct Number: 6374Recommended Use: Cleaning agentUses Advised Against: For Industrial and Institutional Use Only
Manufacturer/Supplier: Spartan Chemical Company, Inc.1110 Spartan DriveMaumee, Ohio 43537 USA800-537-8990 (Business hours)www.spartanchemical.com
24 Hour Emergency Phone Numbers:Medical Emergency/Information: 888-314-6171Transportation/Spill/Leak: CHEMTREC 800-424-9300
2. HAZARDS IDENTIFICATION
GHS ClassificationSerious Eye Damage/Eye Irritation: Category 2A
GHS Label Elements Signal Word: Danger
Hazard Statements: Causes serious eye irritationExtremely flammable aerosol.Contains gas under pressure; may explode if heated
Precautionary Statements: Prevention: Wash hands and any exposed skin thoroughly after handling.
Wear eye / face protectionKeep away from heat/sparks/open flames/hot surfaces. — No smokingDo not spray on an open flame or other ignition sourcePressurized container: Do not pierce or burn, even after useIntentional misuse by deliberately concentrating and inhaling contents may be harmful orfatal.
Response:-Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.-Specific Treatment: See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information.
Storage: Protect from sunlight. Do not expose to temperatures exceeding 122°F (50°C) Store in awell-ventilated place
Disposal: Not Applicable
_____________________________________________________________________________________________
Flammable Aerosols Category 1Gases Under Pressure
Page 1 / 6
Liquefied gas
Symbols:
Page 8 of 132Page 8 of 132Page 8 of 132Page 8 of 132
_____________________________________________________________________________________________6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015
Hazards Not Otherwise Classified: Not Applicable
Other Information: • May cause skin irritation.• May be harmful if swallowed.• Inhalation of vapors or mist may cause respiratory irritation.• Keep out of reach of children.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%water 7732-18-5 60-100
2-butoxyethanol 111-76-2 5-10isopropanol 67-63-0 1-5
propane 74-98-6 1-5N-butane 106-97-8 1-5
Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
-Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present andeasy to do. Continue rinsing. If eye irritation persists: Get medical attention.
-Skin Contact: Wash with soap and water. If skin irritation occurs: Get medical attention.-Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
poison control center or physician if you feel unwell.-Ingestion: Rinse mouth. Do NOT induce vomiting. Never give anything by mouth to an unconscious
person. Get medical attention if you feel unwell.Note to Physicians: Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media: Water spray (fog), FoamSpecific Hazards Arising from theChemical:
Extremely flammable aerosol. Exposure to high temperature may cause containers to burst.Bursting aerosol containers may be propelled from fire at high speed.
Hazardous Combustion Products: May include Carbon monoxide Carbon dioxide and other toxic gases or vapors.
Protective Equipment andPrecautions for Firefighters:
Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and fullprotective gear. Water may be used to cool closed containers to prevent pressure build-upand possible auto ignition or explosion when exposed to extreme heat.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.Environmental Precautions: Do not rinse spill onto the ground, into storm sewers or bodies of water.Methods for Clean-Up: Prevent further leakage or spillage if safe to do so. Contain and collect spillage with
non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite)and place in container for disposal according to local / national regulations (see Section 13).
_____________________________________________________________________________________________
7. HANDLING AND STORAGE
Page 2 / 6
Advice on Safe Handling: Handle in accordance with good industrial hygiene and safety practice. Intentional misuseby deliberately concentrating and inhaling contents may be harmful or fatal. Keep awayfrom heat/sparks/open flames/hot surfaces. — No smoking. Wash thoroughly afterhandling.
Page 9 of 132Page 9 of 132Page 9 of 132Page 9 of 132
_____________________________________________________________________________________________6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015
Storage Conditions: NFPA 30B Level 1 Aerosol. Do not store in direct sunlight or above 122 F° / 50 C°.Exposure to high temperature may cause containers to burst. Keep out of the reach ofchildren.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits: .Chemical Name ACGIH TLV OSHA PEL NIOSH2-butoxyethanol
111-76-2TWA: 20 ppm TWA: 50 ppm
TWA: 240 mg/m3
(vacated) TWA: 25 ppm(vacated) TWA: 120 mg/m3
(vacated) S*S*
IDLH: 700 ppmTWA: 5 ppm
TWA: 24 mg/m3
isopropanol 67-63-0
STEL: 400 ppmTWA: 200 ppm
TWA: 400 ppmTWA: 980 mg/m3
(vacated) TWA: 400 ppm(vacated) TWA: 980 mg/m3
(vacated) STEL: 500 ppm(vacated) STEL: 1225 mg/m3
IDLH: 2000 ppmTWA: 400 ppm
TWA: 980 mg/m3
STEL: 500 ppmSTEL: 1225 mg/m3
propane 74-98-6
TWA: 1000 ppm TWA: 1000 ppmTWA: 1800 mg/m3
(vacated) TWA: 1000 ppm(vacated) TWA: 1800 mg/m3
IDLH: 2100 ppmTWA: 1000 ppm
TWA: 1800 mg/m3
N-butane 106-97-8
TWA: 1000 ppm (vacated) TWA: 800 ppm(vacated) TWA: 1900 mg/m3
TWA: 800 ppmTWA: 1900 mg/m3
Engineering Controls: Provide good general ventilation.If work practices generate dust, fumes, gas, vapors or mists which expose workers tochemicals above the occupational exposure limits, local exhaust ventilation or otherengineering controls should be considered.
Personal Protective Equipment Eye/Face Protection:
_____________________________________________________________________________________________
Wear splash goggles.Skin and Body Protection: Not required with expected use.Respiratory Protection:
Page 3 / 6
Not required with expected use.If occupational exposure limits are exceeded or respiratory irritation occurs, use of aNIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section3 should be considered.
General Hygiene Considerations: Wash hands and any exposed skin thoroughly after handling.See 29 CFR 1910.132-138 for further guidance.
Page 10 of 132Page 10 of 132Page 10 of 132Page 10 of 132
_____________________________________________________________________________________________6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015
10. STABILITY AND REACTIVITY
Reactivity: This material is considered to be non-reactive under normal conditions of use.Chemical Stability: Stable under normal conditions.Possibility of Hazardous Reactions: Not expected to occur with normal handling and storage.Conditions to Avoid: Extremes of temperature and direct sunlight.Incompatible Materials: Strong oxidizing agents. Strong acids.Hazardous DecompositionProducts:
May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors.
11. TOXICOLOGICAL INFORMATION
Likely Routes of Exposure: Eyes, Skin, Ingestion, Inhalation.Symptoms of Exposure:-Eye Contact: Pain, redness, swelling of the conjunctiva and blurred vision.-Skin Contact: Drying of the skin.-Inhalation: Nasal discomfort and coughing.-Ingestion: Pain, nausea, vomiting and diarrhea.Immediate, Delayed, Chronic EffectsProduct Information: Data not available or insufficient for classification.
Target Organ Effects: -Eyes. Respiratory System. -Skin. Blood. Central nervous system. hematopoietic system.kidney. Liver,
Numerical Measures of ToxicityThe following acute toxicity estimates (ATE) are calculated based on the GHS document..ATEmix (oral): 4331 mg/kgATEmix (dermal): 11323 mg/kgATEmix (inhalation-gas): 10511385ATEmix (inhalation-dust/mist): 23.1 mg/lATEmix (inhalation-vapor): 22.9 mg/l
Component Acute Toxicity InformationChemical Name Oral LD50 Dermal LD50 Inhalation LC50
water 7732-18-5
> 90 mL/kg ( Rat ) Not Available Not Available
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance/Physical State: AerosolColor: WhiteOdor: solventpH: 10.0-11.0Melting Point / Freezing Point: No information available.Boiling Point / Boiling Range: 100 °C / 212 °F (Product without propellant)Flash Point: < -18 °C / < 0 °F (Propellant-estimated)Evaporation Rate: <1 (Butyl acetate = 1)Flammability (solid, gas) No information available.Upper Flammability Limit: No information available.Lower Flammability Limit: No information available.Vapor Pressure: No information available.Vapor Density: No information available.Specific Gravity: 0.96 (Product without propellant)Solubility(ies): No information available.
_____________________________________________________________________________________________
Partition Coefficient: No information available.Autoignition Temperature: No information available.
Page 4 / 6
Decomposition Temperature: No information available.Viscosity: No information available.
Page 11 of 132Page 11 of 132Page 11 of 132Page 11 of 132
_____________________________________________________________________________________________6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015
2-butoxyethanol 111-76-2
= 470 mg/kg ( Rat ) = 2270 mg/kg ( Rat ) = 220 mg/kg (Rabbit )
= 2.21 mg/L ( Rat ) 4 h = 450 ppm( Rat ) 4 h
isopropanol 67-63-0
= 4396 mg/kg ( Rat ) = 12800 mg/kg ( Rat ) = 12870mg/kg ( Rabbit )
= 72.6 mg/L ( Rat ) 4 h
propane 74-98-6
Not Available Not Available = 658 mg/L ( Rat ) 4 h
N-butane 106-97-8
Not Available Not Available = 658 mg/L ( Rat ) 4 h
Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA.
12. ECOLOGICAL INFORMATION
EcotoxicityChemical Name Algae/Aquatic Plants Fish Toxicity to
MicroorganismsCrustacea
2-butoxyethanol 111-76-2
Not Available 1490: 96 h Lepomismacrochirus mg/L LC50
static 2950: 96 h Lepomismacrochirus mg/L LC50
Not Available 1698 - 1940: 24 h Daphniamagna mg/L EC50 1000: 48
h Daphnia magna mg/LEC50
isopropanol 67-63-0
1000: 96 h Desmodesmussubspicatus mg/L EC50
1000: 72 h Desmodesmussubspicatus mg/L EC50
9640: 96 h Pimephalespromelas mg/L LC50
flow-through 11130: 96 hPimephales promelas mg/LLC50 static 1400000: 96 hLepomis macrochirus µg/L
LC50
Not Available 13299: 48 h Daphnia magnamg/L EC50
Persistence and Degradability: No information available.Bioaccumulation: No information available.
Other Adverse Effects: No information available.
13. DISPOSAL CONSIDERATIONS
Disposal of Wastes: Dispose of in accordance with federal, state and local regulations.Contaminated Packaging: Pressurized container: Do not pierce or burn, even after use. Dispose of in accordance with
federal, state and local regulations.
14. TRANSPORT INFORMATION
DOT: UN/ID No: UN1950Proper Shipping Name: AerosolsHazard Class: 2.1Special Provisions: This product meets the exception requirements of section 49 CFR 173.306 as a limited
quantity and may be shipped as a limited quantity.
15. REGULATORY INFORMATION
TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory)All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances.
SARA 313This product contains the following listed substances:2-butoxyethanol
_____________________________________________________________________________________________
CAS No 111-76-2 applies to R-(OCH2CH2)n-OR', where n = 1, 2, or 3, R=Alkyl C7 or less, or R = Phenyl or Alkyl substitutedphenyl, R' = H or Alkyl C7 or less, or OR' consisting of Carboxylic acid ester, Sulfate, Phosphate, Nitrate, or Sulfonate, ChemicalCategory N230
SARA 311/312 Hazard Categories
Page 5 / 6
Acute Health Hazard: Yes
Page 12 of 132Page 12 of 132Page 12 of 132Page 12 of 132
_____________________________________________________________________________________________6374 - CARPET STAIN REMOVER Revision Date: 22-Jan-2015
Chronic Health Hazard: NoFire Hazard: NoSudden release of pressure hazard: YesReactive Hazard: No
California Proposition 65This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65formaldehyde - 50-00-0 Carcinogen
WARNING: This product contains a chemical known to the State of California to cause cancer.
16. OTHER INFORMATION
Revision Date: 22-Jan-2015Reasons for Revision: No information available.
Disclaimer:The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and beliefat the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Theinformation relates only to the specific material designated and may not be valid for such material used in combinationwith any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
NFPA Health Hazards: 2
_____________________________________________________________________________________________
Flammability: 1 Instability: 0 Special: N/AHMIS
Page 6 / 6
Health Hazards: 2 Flammability: 2 Physical Hazards: 2
Page 13 of 132Page 13 of 132Page 13 of 132Page 13 of 132
SAFETY DATA SHEET
Issuing Date May 23, 2015
Revision Date New
Revision Number 0
Page 1 / 9
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox Commercial Solutions® Green Works® 99% Naturally Derived General
Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended use Ready-to-use general purpose cleaner dilution from the Clorox® EZ Dilute™ system Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address Clorox Professional Products Company 1221 Broadway Oakland, CA 94612 Phone: 1-510-271-7000
Emergency telephone number Emergency Phone Numbers For Medical Emergencies call: 1-800-446-1014
For Transportation Emergencies, call Chemtrec: 1-800-424-9300
Page 14 of 132Page 14 of 132Page 14 of 132Page 14 of 132
Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate
Revision Date New
Page 2 / 9
2. HAZARDS IDENTIFICATION Classification This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). GHS Label elements, including precautionary statements
Emergency Overview
This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Appearance Clear,
colorless-to-very-light green
Physical State Thin liquid
Odor Lemon
Precautionary Statements - Prevention None Precautionary Statements - Response None Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 0.3% of the mixture consists of ingredient(s) of unknown toxicity Other information May cause slight eye irritation. Interactions with Other Chemicals No information available.
3. COMPOSITION/INFORMATION ON INGREDIENTS
This product contains no substances that at their given concentrations are considered to be hazardous to health.
Page 15 of 132Page 15 of 132Page 15 of 132Page 15 of 132
Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate
Revision Date New
Page 3 / 9
4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Hold eye open and rinse slowly and gently with water for 15–20 minutes. If present, remove
contact lenses after the first 5 minutes of rinsing, then continue rinsing eye. Call a poison control center or doctor for further treatment advice.
Skin Contact Rinse skin with plenty of water. If irritation persists, call a doctor. Inhalation Move to fresh air. If breathing problems develop, call a doctor. Ingestion Drink a glassful of water. Call a doctor or poison control center. Most important symptoms and effects, both acute and delayed Most Important Symptoms and Effects
May cause slight eye irritation.
Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Hazardous Combustion Products Oxides of carbon. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Protective equipment and precautions for firefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protectivegear.
Page 16 of 132Page 16 of 132Page 16 of 132Page 16 of 132
Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate
Revision Date New
Page 4 / 9
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary
treatment facility in advance to assure ability to process washed-down material.
7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
eyes, skin, and clothing. Do not eat, drink, or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Keep containers tightly closed. Incompatible Products None known.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters Exposure Guidelines This product does not contain any ingredients with occupational exposure limits that are at
concentrations below their cut-off values/concentrations and that contribute to the hazard classification of the product.
Appropriate engineering controls Engineering Measures Showers
Eyewash stations Ventilation systems
Individual protection measures, such as personal protective equipment Eye/Face Protection No special protective equipment required. Skin and Body Protection No special protective equipment required. Respiratory Protection No protective equipment is needed under normal use conditions. If irritation is experienced,
ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
Page 17 of 132Page 17 of 132Page 17 of 132Page 17 of 132
Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate
Revision Date New
Page 5 / 9
9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Thin liquid Appearance Clear
Odor Lemon Color Colorless-to-very- light green
Odor Threshold No information available Property Values
Remarks/ Method pH 6 - 9
None known Melting/freezing point No data available
None known Boiling point / boiling range No data available
None known Flash Point No data available
None known Evaporation rate No data available
None known Flammability (solid, gas) No data available
None known Flammability Limits in Air
Upper flammability limit No data available
None known Lower flammability limit No data available
None known Vapor pressure No data available
None known Vapor density No data available
None known Specific Gravity ~1.0
None known Water Solubility Complete
None known Solubility in other solvents No data available
None known Partition coefficient: n-octanol/water No data available
None known Autoignition temperature No data available
None known Decomposition temperature No data available
None known Kinematic viscosity No data available
None known Dynamic viscosity No data available
None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content (%) No data available Particle Size No data available Particle Size Distribution No data available
10. STABILITY AND REACTIVITY Reactivity No data available.
Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None known. Conditions to avoid None known. Incompatible materials None known. Hazardous Decomposition Products None known.
Page 18 of 132Page 18 of 132Page 18 of 132Page 18 of 132
Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate
Revision Date New
Page 6 / 9
11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation Exposure to vapor or mist may cause slight respiratory tract irritation Eye Contact May cause slight irritation. Skin Contact May cause slight irritation. Ingestion Ingestion of liquid may cause slight irritation to mucous membranes and gastrointestinal tract. Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Ethanol 64-17-5
- - 125 mg/L (Rat, 4 h)
Information on toxicological effects Symptoms May cause slight redness and tearing of eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen.
Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage.
Chemical Name ACGIH IARC NTP OSHA
Ethanol 64-17-5
A3 Group 1 Known X
ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program) Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present
Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity Contains a known or suspected carcinogen. Ethanol has been shown to be carcinogenic in
long-term studies only when consumed as alcoholic beverage. Contains a known or suspected reproductive toxin. Ethanol has been shown to be a reproductive toxin only when consumed as an alcoholic beverage. May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Repeated abuse can have long-term health effects.
Target Organ Effects Eyes, blood, central nervous system (CNS), liver, reproductive system, respiratory system.
Page 19 of 132Page 19 of 132Page 19 of 132Page 19 of 132
Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate
Revision Date New
Page 7 / 9
Aspiration Hazard Not an aspiration hazard. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS documentNo information available.
12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to MicroorganismsDaphnia Magna (Water
Flea)
Ethanol 64-17-5
LC50: 12.0 - 16.0 mL/L (96 h static) Oncorhynchus mykissLC50: 13400 - 15100 mg/L
(96 h flow-through) Pimephales promelas
LC50: > 100 mg/L (96 h static) Pimephales promelas
EC50 = 34634 mg/L 30 min EC50 = 35470 mg/L 5 min
LC50: 9268 - 14221 mg/L (48h ) Daphnia magna
EC50: 10800 mg/L (24 h ) Daphnia magna
EC50: 2 mg/L (48 h Static) Daphnia magna
Persistence and DegradabilityNo information available. Bioaccumulation
Chemical Name Log Pow Ethanol 64-17-5
-0.32
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations.
14. TRANSPORT INFORMATION
DOT Not regulated. TDG Not regulated. ICAO Not regulated. IATA Not regulated IMDG/IMO Not regulated
Page 20 of 132Page 20 of 132Page 20 of 132Page 20 of 132
Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate
Revision Date New
Page 8 / 9
15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt
from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. US State Regulations California Proposition 65 This product contains the following Proposition 65 chemical. Ethyl alcohol is only a considered a Proposition 65 developmental and cancer hazard when it is ingested as an alcoholic beverage.
Chemical Name California Proposition 65 Ethanol 64-17-5
Developmental Cancer
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Ethanol 64-17-5
X
International Regulations Canada WHMIS Hazard Class Not controlled.
Page 21 of 132Page 21 of 132Page 21 of 132Page 21 of 132
Clorox Commercial Solutions® Green Works® 99% Naturally Derived General Purpose Cleaner - Ready-to-Use Solution - 1:48 from Concentrate
Revision Date New
Page 9 / 9
16. OTHER INFORMATION NFPA
Health Hazard 0
Flammability 0
Instability 0
Physical and Chemical Hazards -
HMIS
Health Hazard 0
Flammability 0
Physical Hazard 0
Personal Protection -
Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501
Preparation/Revision Date May 23, 2015 Revision Note Reference
New INT0049
General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
Page 22 of 132Page 22 of 132Page 22 of 132Page 22 of 132
1. IDENTIFICATION
Product Name Comet� Deodorizing Cleanser with Chlorinol�
Product Code(s) 3-10
Product ID: 97086927_PROF_NG
Product Type: Finished Product - Professional Use Only
Recommended Use Hard Surface Cleaner
Restrictions on Use Do not mix with other cleaning products or chemicals as irritating fumes may be formed.
Manufacturer Procter & Gamble Professional2 P&G PlazaCincinnati, Ohio 45202
Procter & Gamble Inc.P.O. Box 355, Station AToronto, ON M5W 1C5
1-800-332-7787
E-mail Address [email protected]
Emergency Telephone Transportation (24 HR)CHEMTREC - 1-800-424-9300(U.S./ Canada) or 1-703-527-3887Mexico toll free in country: 800-681-9531
2. HAZARD IDENTIFICATION
This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.
Hazard Category Eye Damage / Irritation Category 2B
Page 1 / 7
Hazard pictograms None
Issuing Date: 12-Jun-2015
Precautionary Statements -Prevention
Wash hands thoroughly after handlingDo not mix with other cleaning products or chemicals as irritating fumes may be formed
Signal Word WARNING
Revision Date: 12-Jun-2015
Precautionary Statements -Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsingIf eye irritation persists: Get medical advice/attentionIF SWALLOWED:Drink 1 or 2 glasses of water
SAFETY DATA SHEET
Version 1
Hazard Statements Causes eye irritation
Page 23 of 132Page 23 of 132Page 23 of 132Page 23 of 132
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation
4. FIRST AID MEASURES
First aid measures for different exposure routes
Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists.
Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists.
Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately ifsymptoms occur.
Inhalation Move to fresh air. If symptoms persist, call a physician.
Most important symptoms/effects,acute and delayed
None under normal use conditions.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray.
Unsuitable Extinguishing Media None.
Special hazard None known.
Special protective equipment forfire-fighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent) and full protective gear.
Specific hazards arising from thechemical
None.
Page 2 / 7
Revision Date: 12-Jun-2015
Precautionary Statements -Disposal
Dispose of contents/container in accordance with local regulation
Precautionary Statements -Storage
None
97086927_PROF_NG - Comet� Deodorizing Cleanser withChlorinol�
Hazards not otherwise classified(HNOC)
None
Chemical Name Synonyms Trade Secret CAS-No Weight %Limestone - No 1317-65-3 40 - 100
Sodium carbonate - No 497-19-8 5 - 10Symclosene - No 87-90-1 1 - 5
Benzenesulfonic acid,mono-C10-16-alkyl derivs., sodium
salts
- No 68081-81-2 1 - 5
Page 24 of 132Page 24 of 132Page 24 of 132Page 24 of 132
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing.
Advice for emergency responders Use personal protective equipment as required.
Methods and materials for containment and cleaning up
Methods for containment Prevent dust cloud. Prevent further leakage or spillage if safe to do so.
Methods for cleaning up Sweep up and shovel into suitable containers for disposal. Dispose of in accordance withlocal regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use.Never return spills in original containers for re-use. Keep out of the reach of children.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible products Do not mix with other cleaning products or chemicals as irritating fumes may be formed.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines .
Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PELLimestone 1317-65-3 TWA: 15 mg/m3 total dust
TWA: 5 mg/m3 respirablefraction
(vacated) TWA: 15 mg/m3
total dust(vacated) TWA: 5 mg/m3
respirable fraction
Mexico: TWA 10 mg/m3
Mexico: STEL 20 mg/m3
Chemical Name CAS-No Alberta Quebec Ontario TWAEV British ColumbiaLimestone 1317-65-3 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3
TWA: 3 mg/m3
STEL: 20 mg/m3
No relevant exposure guidelines for other ingredients
Exposure controls
Engineering Measures Distribution, Workplace and Household Settings:Ensure adequate ventilation
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Where reasonably practicable this should be achieved by the use of local exhaustventilation and good general extraction
Personal Protective Equipment
Page 3 / 7
Revision Date: 12-Jun-201597086927_PROF_NG - Comet� Deodorizing Cleanser withChlorinol�
Page 25 of 132Page 25 of 132Page 25 of 132Page 25 of 132
Eye Protection Distribution, Workplace and Household Settings:No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Use appropriate eye protection
Hand Protection Distribution, Workplace and Household Settings:No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Protective gloves
Skin and Body Protection Distribution, Workplace and Household Settings:No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Wear suitable protective clothing
Respiratory Protection Distribution, Workplace and Household Settings:No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):In case of insufficient ventilation wear suitable respiratory equipment
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State @20°C solidAppearance whiteOdor PineOdor threshold No information available
Oxidizing properties These substances will accelerate burning when involved in a fire.VOC Content (%) Products comply with US state and federal regulations for VOC content in consumer
products.
10. STABILITY AND REACTIVITY
Reactivity None under normal use conditions.
Page 4 / 7
No information available
Lower Flammability Limit No information available
Values
Vapor pressure No information available
Boiling point/boiling range
Vapor density
Revision Date: 12-Jun-2015
No information available
No information available
Relative density No information available
Note
Water solubility
Flash point
15%Solubility in other solvents
No information available
No information availablePartition coefficient: n-octanol/waterNo information available
pH value
Autoignition temperature
Evaporation rate
No information available .Decomposition temperature
No information available
No information available .Viscosity of Product No information available
11.5
Flammability (solid, gas)
Property
No information available
(as 1% solution)
Flammability Limits in Air
Melting/freezing point
Upper flammability limit
97086927_PROF_NG - Comet� Deodorizing Cleanser withChlorinol�
No information available
Page 26 of 132Page 26 of 132Page 26 of 132Page 26 of 132
Stability Stable under normal conditions.
Hazardous polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.
Conditions to Avoid None under normal processing.
Materials to avoid Do not mix with other cleaning products or chemicals as irritating fumes may be formed.
Hazardous Decomposition Products None under normal use.
11. TOXICOLOGICAL INFORMATION
Product Information Information on likely routes of exposure
Inhalation No known effect.Skin contact No known effect.Ingestion No known effect.Eye contact Irritating to eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Acute toxicity No known effect.Skin corrosion/irritation No known effect.Serious eye damage/eye irritation Irritating to eyes.Skin sensitization No known effect.Respiratory sensitization No known effect.Germ cell mutagenicity No known effect.Neurological Effects No known effect.Reproductive toxicity No known effect.Developmental toxicity No known effect.Teratogenicity No known effect.STOT - single exposure No known effect.STOT - repeated exposure No known effect.Target Organ Effects No known effect.Aspiration hazard No known effect.Carcinogenicity No known effect.
Component Information
Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 InhalationSodium carbonate 497-19-8 2800 mg/kg bw > 2000 mg/kg bw (US EPA
16 CFR 1500.40)-
12. ECOLOGICAL INFORMATION
Ecotoxicity
The product is not expected to be hazardous to the environment.
Persistence and degradability No information available.
Bioaccumulative potential No information available.
Mobility No information available.
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Page 5 / 7
97086927_PROF_NG - Comet� Deodorizing Cleanser withChlorinol�
Revision Date: 12-Jun-2015
Page 27 of 132Page 27 of 132Page 27 of 132Page 27 of 132
Waste treatment
Waste from Residues / UnusedProducts
Disposal should be in accordance with applicable regional, national and local laws andregulations.
Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws andregulations.
California Hazardous Waste Codes(non-household setting)
331
14. TRANSPORT INFORMATION
DOT Not regulated
IMDG Not regulated
IATA Not regulated
15. REGULATORY INFORMATIONU.S. Federal Regulations
SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substance under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):
Chemical Name CAS-No HazardousSubstances RQs
Extremely HazardousSubstances RQs
CERCLA/SARA 302TPQ
Piperidine 110-89-4 - 1000 lb 1000 lb
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air ActAmendments of 1990.
Clean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42)
California Proposition 65This product is not subject to warning labeling under California Proposition 65.
U.S. State Regulations (RTK)
Chemical Name CAS-No New JerseyLimestone 1317-65-3 X
Symclosene 87-90-1 X
Chemical Name CAS-No PennsylvaniaLimestone 1317-65-3 X
Symclosene 87-90-1 X
Page 6 / 7
97086927_PROF_NG - Comet� Deodorizing Cleanser withChlorinol�
Revision Date: 12-Jun-2015
Page 28 of 132Page 28 of 132Page 28 of 132Page 28 of 132
International Inventories
United StatesAll intentionally-added components of this product(s) are listed on the US TSCA Inventory.
CanadaThis product is in compliance with CEPA for import by P&G.
LegendTSCA - United States Toxic Substances Control Act Section 8(b) InventoryCEPA - Canadian Environmental Protection Act
16. OTHER INFORMATION
HMIS Ratings Health hazard 2Flammability 0Physical hazard 0
Health hazard 2Flammability 0Instability 0
Issuing Date: 12-Jun-2015Revision Date: 12-Jun-2015DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of itspublication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any other materials or in any process, unlessspecified in the text
End of SDS
Page 7 / 7
97086927_PROF_NG - Comet� Deodorizing Cleanser withChlorinol�
Revision Date: 12-Jun-2015
Page 29 of 132Page 29 of 132Page 29 of 132Page 29 of 132
28 May 2015
aqua (water) diluent 7732-18-5 Not applicable
thymol (a component of thyme oil) antimicrobial active 8007-46-3 0.05% 980 mg/kgOther ingredients: . 99.95% .
Ingredient Function CAS Number Concentration1 LD502
Active ingredient . .
Eyes Minimal eye irritant category IV
Regardless of hazard classification, Seventh Generation discloses all intentionally added ingredients and, if applicable incidental ingredients ≥1% on the consumer product label.
Section 3: Composition, Information on Ingredients
Precautionary Statements
Emergency Overview No symptoms or effects under normal use. May cause slight irritation of eyes, skin or respiratory tract.
This product is not considered hazardous under the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).This product is not considered hazardous under the WHMIS 2015.
Classification
U.S.
Canada
Section 2: Hazards Identification
APERSONAL PROTECTION
Not determined
Hazardous Materials Identification System (HMIS) Rating
0
0
0PHYSICAL HAZARDS
FLAMMABILITY
Skin Slight dermal irritant category IV. Non-sensitizer.Ingestion May cause transient gastrointestinal irritation.
HEALTHLegend: 4-Severe, 3-Serious, 2-Moderate, 1-Slight, 0-Minimal
Inhalation May cause slight irritation.Hazards not otherwise identified None known
Percent ingredients with unknown acute toxicity 0% of the product consists of ingredients of unknown acute oral toxicity. Refer to Section 3.
SAFETY DATA SHEET
National Fire Protection Association (NFPA) Rating
Botanical Disinfecting Multi-Surface CleanerHard Surface Disinfecting and Cleaning
Seventh Generation, Inc.60 Lake Street, Burlington, VT 05401, USA
This Safety Data Sheet (SDS) is intended to provide product information for workplaces, emergency personnel and other situations where there is potential for longer exposure or exposure to larger quantities of product. For consumer use, applicable precautionary information is provided on the product label. This SDS is designed to cover both U.S. and Canadian requirements. Differences between U.S. and Canadian requirements are noted where applicable.
Issue date
Emergency Telephone Number U.S. Canada1-800-211-42791-800-255-3924 (ChemTel)
Monday -Friday 8 am - 5 pm ET (except holidays)Outside these hours
Address
Restrictions on Use Follow directions on the product label
Section 1: Identification of Product and Company
Product NameSynonymsProduct Use
Manufacturer Name
Disinfecting Multi-Surface Cleaner
FM000054-00.2
Page 1 of 6
Page 30 of 132Page 30 of 132Page 30 of 132Page 30 of 132
SAFETY DATA SHEET
Safe HandlingHousehold Setting Use as directed on product label.Industrial Setting Wear appropriate personal protective equipment (refer to section 8).
Section 7: Handling and Storage
Section 6: Accidental Release Measures
Personal Precautions
Protective Equipment and Precautions for FirefightersFire fighters should wear full protective clothing and self contained breathing apparatus as for surrounding fire.
Suitable Extinguishing Media As appropriate for surrounding fire. Use water, dry chemical, carbon dioxide or foam.
Unsuitable Extinguishing Media Not available.
Most important symptoms and effects Acute exposure may result in eye irritation.
Specific Hazards arising from the chemical mixture Not available.Hazardous Combustion Products Not available.
Section 4: First Aid Measures
*Lemongrass Citrus Scent: cymbopogon nardus (citronella) oil, cymbopogon schoenanthus (lemongrass) oil. Citral is a component of these essential oils. 1 Where ranges are shown, the exact concentration has been withheld as a trade secret. 2 LD50 Acute oral toxicity (rat) – This is a value provided by the raw material supplier or scientific literature. It is not a value generated by Seventh Generation by testing using rats. Seventh Generation uses alternative, non-animal based methods and scientific literature to determine the safety classification of our products and their ingredients.
sodium citrate water softener 6132-04-3 6730 mg/kg
essential oils* fragrance mixture >5000 mg/kgoriganum vulgare (oregano) oil fragrance 8007-11-2 1850 mg/kg
copper sulfate pentahydrate (bluestone) water mineralizer 7758-99-8 300 mg/kg
citric acid water softener 77-92-9 3000 mg/kg
sodium lauryl sulfate cleaning agent 151-21-3 ≤1% 1288 mg/kg
Eye ContactHold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Call a doctor or poison control center for treatment advice.
Section 5: Fire Fighting Measures
Skin Contact Rinse thoroughly with water if skin contact occurs. Call a physician if irritation develops or persists.
IngestionHave person sip a glass of water if able to swallow. Do not induce vomiting unless told to by a doctor or poison control center. Do not give anything to an unconscious person.
Inhalation Remove to fresh air. If breathing is affected, call a physician.Notes to Physician Treat symptomatically.
Industrial Setting Wear appropriate personal protective equipment (refer to Section 8).Environmental Precautions Avoid entry into lakes, streams, ponds or public waterways.Methods for Containment and Cleaning Up
Household SettingSmall spills and leaks may be cleaned up and disposed of in normal household trash or diluted and disposed of via sewer.
Industrial Setting
Before attempting clean up, refer to hazard data given. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labeled containers. Prevent extremely large spills from entering sewers or waterways. Dispose in accordance with all applicable local, state, and federal regulations.
Page 2 of 6
Page 31 of 132Page 31 of 132Page 31 of 132Page 31 of 132
SAFETY DATA SHEET
Possibility of Hazardous Reactions None known.
Household SettingIn general, cleaning products should not be mixed with other household chemicals, unless specifically provided for in the use directions.
Section 10: Stability and Reactivity
Industrial Setting None known.Hazardous Decomposition Products None known.
Conditions to Avoid None known.Incompatible Materials
VOC (weight %) Not available.
Partition Coefficient: n-octanol/water Not available.Viscosity Not available.
Vapor Density (Air = 1) Not available.Solubility in Water Soluble
Specific Gravity (H2O = 1) 1.00-1.02Relative Density Not available.
Lower Explosive Limit (LEL) Not applicable.Vapor Pressure (mmHg) Not available.
Evaporation Rate As per water.Upper Explosive Limit (UEL) Not applicable.
Flash Point Not available. Aqueous Solution.
Freezing Point As per water.Initial Boiling Point and Boiling Range As per water.
pH 4.0 - 5.0Melting Point As per water.
Odor Scented. Characteristic of the ingredientsOdor Threshold Not available.
Color Colorless (water-white)Clarity Clear
Physical State Liquid.
Section 9: Physical and Chemical Properties
Eye Protection Goggles or other protective eye wear may be worn for protection. Skin Protection Gloves may be worn for protection. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
Safe Storage
KEEP OUT OF REACH OF CHILDREN AND PETS.Nonrefillable container. Store airtight at room temperature in original container and keep container closed when not in use.Avoid freezing.
Storage Incompatibilities None known.
Industrial Setting Respiratory Protection None required under normal conditions. General ventilation required.
Exposure Limits None known.Engineering Controls Not applicable.Personal Protective Equipment (PPE)
Household Setting No special precautions necessary as long as product is used as directed.
Section 8: Exposure Controls, Personal Protection
Reactivity None known.Chemical Stability Stable.
Page 3 of 6
Page 32 of 132Page 32 of 132Page 32 of 132Page 32 of 132
SAFETY DATA SHEET
Washington Hazardous Waste Code WT02
Industrial Setting
When disposed as waste in its original form, this product is not considered hazardous waste under Federal regulations, however regulations may vary by state or province and may designate it as hazardous waste. Check with your local waste and waste water authorities. We are aware of the following state waste classifications:
California Hazardous Waste Code 232 Connecticut Hazardous Waste Code CT04 Michigan Liquid Waste Code 029L Vermont Hazardous Waste Code VT06
Product WasteAny disposal must be in compliance with applicable local, state, provincial and federal laws and regulations.
Household Setting Product residues in the bottle may be discarded in trash, or diluted with water and disposed via sewer.
Compatible with septic systems.
Section 13: Disposal Considerations
Environmental Fate No adverse effects expected.
Bioaccumulative Potential Not applicable.Mobility in Soil Not available.
Ecotoxicity Not available.Persistence and Degradability Meets requirements for ready biodegration based on OECD 301B.
Section 12: Ecological Information
Target Organ Effects Not expected to have chronic health effects.
Not expected to have chronic health effects.Reproductive EffectsTeratogenicity Not expected to have chronic health effects.Mutagenicity Not expected to have chronic health effects.
NTP No Ingredients ListedIARC No Ingredients ListedOSHA No Ingredients Listed
Carcinogenicity Not expected to have chronic health effects.
Not expected to have chronic health effects.
SensitizationDoes not indicate a potential for allergic contact sensitization, based on Human Repeat Insult Patch Test (HRIPT).
Skin Contact Non to slight dermal irritant category IV, based on ingredients and in-vitro data.Component Information Refer to section 3 for ingredient LD50 (acute oral).
Effects of Acute Exposure
Section 11: Toxicological Information
Oral Toxicity LD50 >5000 mg/kg, calculated based on ingredients.Dermal Toxicity LD50 >5000 mg/kg, calculated based on ingredients.Inhalation Toxicity >20 mg/L/4h, based on ingredients.
Eye Contact
Potential Route(s) of Exposure Eyes. Skin. Ingestion.
Minimal eye irritant category IV, based on ingredients and in-vitro data.
Effects of Chronic Exposure
Page 4 of 6
Page 33 of 132Page 33 of 132Page 33 of 132Page 33 of 132
SAFETY DATA SHEET
Offer empty container for recycling. If recycling is not available, discard in trash.
Prepared by Seventh Generation Inc.Issuing Date 28 May 2015
Section 16: Other Information
Health Canada Registration Number DIN 02415070
Right to KnowRegardless of hazard classification, Seventh Generation discloses all intentionally added ingredients and, if applicable incidental ingredients ≥1% on the product label. Please refer to Section 3. of this SDS for ingredient listing.
OtherFragrances used in this product comply with applicable International Fragrance Association (IFRA) guidance.
California Prop 65 This product is not subject to the labeling requirements of California’s Proposition 65.
California Air Resources Board (CARB) Meets applicable California Air Resource Board requirements for consumer products.
Canada
Domestic Substances List (DSL)This product complies with the inventory requirements under Canada’s Domestic Substances List (DSL) or Non-Domestic Substances List (NDSL) or is otherwise in compliance with the New Substances Notification (NSN) regulations or exemptions.
Toxic Substances Control Act (TSCA) This product complies with the inventory requirements of the U.S. Toxic Substances Control Act (TSCA).
U.S.
EPA Registration Number 84683-3-86066California DPR Registration Number 84683-3-ZA-86066
Section 15: Regulatory Information
IATA (Air Transport) Not regulated.IMDG (Marine Transport) Not regulated.
U.S. States (Surface Transport)
Not regulated as finished product.
Regulated in some states if the product is disposed of in its original form as waste by commercial users/handlers. Refer to Section 13. for applicable state waste codes.
Canadian TDG (Surface Transport) Not regulated.
U.S. DOT (Surface Transport) Not regulated.
Section 14: Transport Information
Empty Packaging
Revision Date 28 May 2015
Please note: This product is manufactured and marketed for consumer use and should be used as directed on the product label for the intended purpose. Seventh Generation warrants that this product conforms to our standard specification when released to the market and when used according to directions. To the best of our knowledge, the information contained herein is accurate. However, we do not assume any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any product is the sole responsibility of the user. All products may present unknown hazards and should be used with requisite caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Other abbreviations used in this document:
Revision Note Revised format as per OSHA 2012 and WHMIS 2015.
Page 5 of 6
Page 34 of 132Page 34 of 132Page 34 of 132Page 34 of 132
SAFETY DATA SHEET
End of Safety Data Sheet
DOT – (U.S.) Department of TransportationEPA – (U.S.) Environmental Protection AgencyIARC – International Agency for Research on CancerNTP – (U.S. Department of Health and Human Services) National Toxicology ProgramOSHA – (U.S.) Occupational Safety and Health AdministrationTDG – (Canadian) Transport of Dangerous GoodsWHMIS – (Canadian) Workplace Hazardous Materials Information System
Page 6 of 6
Page 35 of 132Page 35 of 132Page 35 of 132Page 35 of 132
Expo White Board Cleaner
CHEMTREC (U.S. and Canada) 1-800-424-9300
SAFETY DATA SHEET
Product name
Emergency telephone number (with hours of operation)
Section 1. Identification:
:
Manufacturer : Newell Rubbermaid3500 Lacey Road, 10th FloorDowners Grove, IL 60515USA800-323-0749 or 630-829-2500
Material uses : Cleaning solutions.
Section 2. Hazards identification
Not classified.Classification of the substance or mixture
:
Signal word : Not applicable
Hazard statements : No known significant effects or critical hazards.
Precautionary statements
Prevention : Not applicable.
Response : Not applicable.
Storage : Not applicable.
Disposal : Not applicable.
GHS label elements
General : Read label before use. If medical advice is needed, have product container or label at hand.
OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product.
Hazards not otherwise classified
: None known.
Section 3. Composition/information on ingredients
3-butoxypropan-2-ol 2 - 5 5131-66-8
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Substance/mixture : Mixture
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 1/8
Page 36 of 132Page 36 of 132Page 36 of 132Page 36 of 132
Expo White Board Cleaner
Section 3. Composition/information on ingredients
Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled.
Description of necessary first aid measures
Specific treatments : No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Ingestion
Skin contact : No known significant effects or critical hazards.
No known significant effects or critical hazards.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
No specific data.
No specific data.
:
:
:
Eye contact : No specific data.
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxide
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 2/8
Page 37 of 132Page 37 of 132Page 37 of 132Page 37 of 132
Expo White Board Cleaner
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions for safe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
:
:
Protective measures Put on appropriate personal protective equipment (see Section 8).:
Precautions for safe handling
None.
Section 8. Exposure controls/personal protection
Environmental exposure controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
Control parameters
Individual protection measures
Occupational exposure limits
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 3/8
Page 38 of 132Page 38 of 132Page 38 of 132Page 38 of 132
Expo White Board Cleaner
Section 8. Exposure controls/personal protection
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.Odor
pH
Clear.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Not available.
Not available.
Not available.
Viscosity Not available.
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Not available.
Burning rate Not applicable.:
Burning time : Not applicable.
SADT Not available.:
Decomposition temperature : Not available.
Solubility in water : Not available.
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 4/8
Page 39 of 132Page 39 of 132Page 39 of 132Page 39 of 132
Expo White Board Cleaner
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
3-butoxypropan-2-ol LD50 Dermal Rabbit 3100 mg/kg -
Product/ingredient name Result Species Dose Exposure
Carcinogenicity
No known significant effects or critical hazards.
Mutagenicity
No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Reproductive toxicity
No known significant effects or critical hazards.
Irritation/Corrosion
No known significant effects or critical hazards.
Sensitization
No known significant effects or critical hazards.
Information on the likely routes of exposure
Delayed and immediate effects and also chronic effects from short and long term exposure
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Aspiration hazard
No known significant effects or critical hazards.
Information on toxicological effects
: Not available.
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 5/8
Page 40 of 132Page 40 of 132Page 40 of 132Page 40 of 132
Expo White Board Cleaner
Section 11. Toxicological information
No known significant effects or critical hazards.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Potential chronic health effects
Numerical measures of toxicity
Dermal 63798.6 mg/kg
Route ATE value
Acute toxicity estimates
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
3-butoxypropan-2-ol 1.2 - low
Toxicity
No known significant effects or critical hazards.
Persistence and degradability
No known significant effects or critical hazards.
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 6/8
Page 41 of 132Page 41 of 132Page 41 of 132Page 41 of 132
Expo White Board Cleaner
Section 14. Transport information
-
-
-
-
-
-
-
Not regulated.
-
-
Not regulated. Not regulated.
- - -
DOT Classification
IMDG IATA
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
No. No. No.
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
:
TDG Classification
Not regulated.
-
-
-
No.
-
Mexico Classification
Not regulated.
-
-
-
No.
-
Section 15. Regulatory informationU.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted.
SARA 311/312
Classification : Not applicable.
3-butoxypropan-2-ol 2 - 5 Yes. No. No. Yes. No.
Name % Fire hazard
Sudden release of pressure
Reactive Immediate (acute)health hazard
Delayed (chronic)health hazard
Composition/information on ingredients
The following components are listed: Propylene glycol butyl ether
Not controlled under WHMIS (Canada).
None of the components are listed.
Canada
WHMIS (Canada)
Canadian lists
Canadian NPRI
CEPA Toxic substances :
:
:
Canada inventory : All components are listed or exempted.
This product does not contain Chemicals known to State of California to cause cancer, birth defects, or reproductive harm.
California Prop. 65
Section 16. Other informationHistory
Date of issue/Date of revision
Version
Prepared by
Date of previous issue
:
:
:
:
8/5/2015
No previous validation
1
Product Safety.
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 7/8
Page 42 of 132Page 42 of 132Page 42 of 132Page 42 of 132
Expo White Board Cleaner
Section 16. Other information
Since the user's working conditions are not known by us, the information supplied on this safety data sheet is based on our current level of knowledge and on national and community regulations. The mixture must not be used for other uses than those specified in section 1 without having first obtained written handling instructions. It is at all times the responsibility of the user to take all necessary measures to comply with legal requirements and local regulations. The information in this safety data sheet must be regarded as a description of the safety requirements relating to the mixture and not as a guarantee of the properties thereof.
Indicates information that has changed from previously issued version.
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientUN = United Nations
Date of issue/Date of revision : 8/5/2015 Date of previous issue : No previous validation Version : 1 8/8
Page 43 of 132Page 43 of 132Page 43 of 132Page 43 of 132
NA
FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015
1 / 9
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name
: FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER
Product code : 200000038598
: B02703630000
Manufacturer or supplier's details Company : Colgate-Palmolive Co
300 Park Avenue New York, NY 10022
Telephone : US: Consumer Affairs - 1-800-468-6502
Emergency telephone number
: For emergencies involving spill, leak, fire, exposure or acci-dent call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887.
Medical Emergency (24HR):
For MEDICAL EMERGENCIES involving this product call: (888) 489-3861
Recommended use of the chemical and restrictions on use Recommended use
: Formulated all purpose cleaner for household use.
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview Appearance
liquid
Colour
purple
GHS Classification Skin irritation
: Category 2
Eye irritation
: Category 2A
Skin sensitisation
: Category 1
GHS Label element Hazard pictograms
:
Signal word : Warning
Page 44 of 132Page 44 of 132Page 44 of 132Page 44 of 132
NA
FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015
2 / 9
Hazard statements
: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation.
Precautionary statements
: Prevention: P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear eye protection/ face protection. P280 Wear protective gloves. Response: P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ atten-tion. P362 Take off contaminated clothing and wash before reuse. Disposal: P501 Dispose of contents/ container to an approved waste dis-posal plant.
Potential Health Effects Inhalation
: No adverse effects due to inhalation are expected.
Skin
: May cause skin irritation upon prolonged contact.
Eyes
: Causes eye irritation on direct contact.
Ingestion
: May be harmful if swallowed in large quantities.
Aggravated Medical Condi-tion
: None known.
Carcinogenicity: IARC
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by ACGIH.
OSHA
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by OSHA.
NTP
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen
Page 45 of 132Page 45 of 132Page 45 of 132Page 45 of 132
NA
FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015
3 / 9
by NTP.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components Chemical Name CAS-No. Concentration (%) (C10-C16) Alkylbenzenesulfonic acid 68584-22-5 >= 1 - < 5
SECTION 4. FIRST AID MEASURES
If inhaled
: Remove victim to fresh air. Get medical attention, if symp-toms persist.
In case of skin contact
: Flush skin with large amounts of water. If irritation develops and persists, get medical attention.
In case of eye contact
: Flush eyes with water at least 15 minutes. Get medical atten-tion if eye irritation develops or persists.
If swallowed
: Drink 8 ounces of clear water. Get medical attention.
Most important symptoms and effects, both acute and delayed
: Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media
: Use water spray, alcohol-resistant foam, dry chemical or car-bon dioxide.
Hazardous combustion prod-ucts
: No hazardous combustion products are known
Special protective equipment for firefighters
: Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-tive equipment and emer-gency procedures
: Use personal protection recommended in Section 8 of the SDS.
Methods and materials for containment and cleaning up
: Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of wa-ter.
SECTION 7. HANDLING AND STORAGE
Page 46 of 132Page 46 of 132Page 46 of 132Page 46 of 132
NA
FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015
4 / 9
Conditions for safe storage
: Store at controlled room temperature at 20-25°C (68-77°F).
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters Contains no substances with occupational exposure limit values.
Engineering measures : In an industrial work environment, no special precautions or control measures are required.
Personal protective equipment Respiratory protection
: No personal respiratory protective equipment normally re-quired.
Protective measures
: In an industrial work environment, if a splash is likely, chemi-cal goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary.
Hygiene measures
: In an industrial work environment, avoid eye and prolonged skin contact.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: liquid
Colour
: purple
pH
: 7
Flash point
: No data available
SECTION 10. STABILITY AND REACTIVITY
Possibility of hazardous reac-tions
: Hazardous polymerisation does not occur.
Incompatible materials
: Strong oxidizing agents
Hazardous decomposition products
: None known.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity Not classified based on available information.
Page 47 of 132Page 47 of 132Page 47 of 132Page 47 of 132
NA
FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015
5 / 9
Product: Acute oral toxicity
: Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method
Acute inhalation toxicity
: Acute toxicity estimate : > 10 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method
Components: (C10-C16) Alkylbenzenesulfonic acid: Acute oral toxicity
: LD50 (Rat): 1,460 mg/kg Method: No information available.
Acute inhalation toxicity
: LC50 (Rabbit): > 1.9 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403
Acute dermal toxicity
: LD50 (Rabbit): > 5,000 mg/kg Method: OECD Test Guideline 402
Skin corrosion/irritation Causes skin irritation.
Components: (C10-C16) Alkylbenzenesulfonic acid: Result: Corrosive after 1 to 4 hours of exposure
Serious eye damage/eye irritation Causes serious eye irritation.
Components: (C10-C16) Alkylbenzenesulfonic acid: Result: Irreversible effects on the eye
Respiratory or skin sensitisation Skin sensitisation: May cause an allergic skin reaction. Respiratory sensitisation: Not classified based on available information.
Components: (C10-C16) Alkylbenzenesulfonic acid: Exposure routes: Inhalation Remarks: No data available Exposure routes: Dermal Result: May cause sensitisation by skin contact.
Germ cell mutagenicity Not classified based on available information.
Page 48 of 132Page 48 of 132Page 48 of 132Page 48 of 132
NA
FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015
6 / 9
Carcinogenicity Not classified based on available information.
Reproductive toxicity Not classified based on available information.
STOT - single exposure Not classified based on available information.
STOT - repeated exposure Not classified based on available information.
Aspiration toxicity Not classified based on available information.
Further information
Product: Remarks: This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS.
SECTION 12. ECOLOGICAL INFORMATION
The product has not been tested as a whole for environmental toxicity. However, environmental infor-mation on the ingredients in this product have been reviewed by the Environmental, Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evalua-tion is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients (i.e., surfactants are biode-gradable) or testing conducted on the final product (i.e., This product is biodegradable).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods Waste from residues : Any disposal practice must be in compliance with local, state
and federal laws and regulations (contact local or state envi-ronment agency for specific rules). Do not dump in sewers, any body of water or on the ground.
SECTION 14. TRANSPORT INFORMATION
DOT : Not regulated. TDG : Not regulated. IATA : Not regulated.
Page 49 of 132Page 49 of 132Page 49 of 132Page 49 of 132
NA
FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015
7 / 9
IMDG : Not regulated.
International Regulation
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
National Regulations
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ (lbs)
Calculated product RQ (lbs)
Sulfuric Acid 7664-93-9 1000 * Sulfuric Acid 7664-93-9 100 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
Components CAS-No. Component RQ (lbs)
Calculated product RQ (lbs)
Sulfuric Acid 7664-93-9 1000 *
*: Calculated RQ exceeds reasonably attainable upper limit. SARA 302
: No chemicals in this material are subject to the reporting re-quirements of SARA Title III, Section 302.
SARA 313
: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta-ble 116.4A: SODIUM HYDROXIDE 1310-73-2 Sulfuric Acid SULFURIC ACID The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: SODIUM HYDROXIDE 1310-73-2
Page 50 of 132Page 50 of 132Page 50 of 132Page 50 of 132
NA
FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015
8 / 9
Sulfuric Acid SULFURIC ACID This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
Massachusetts Right To Know Sulfuric Acid SULFURIC
ACID
Pennsylvania Right To Know WATER Water 2-PHENOXYETHANOL 122-99-6 SODIUM HYDROXIDE 1310-73-2 Sulfuric Acid SULFURIC
ACID
New Jersey Right To Know WATER Water PROPYLENE GLYCOL PROPYL ETHER 1569-01-3 (C10-C16) Alkylbenzenesulfonic acid 68584-22-5
California Prop 65 : This product does not contain any chemicals known to State
of California to cause cancer, birth defects, or any other re-productive harm.
The components of this product are reported in the following inventories: TSCA
: All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
Page 51 of 132Page 51 of 132Page 51 of 132Page 51 of 132
NA
FABULOSO ALL PURPOSE CLEANER LIQUID LAVENDER This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000398 Revision Date: 05/22/2015
9 / 9
SECTION 16. OTHER INFORMATION
Further information NFPA: HMIS III:
Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or im-plied, as to the accuracy, reliability or completeness of the information and assumes no re-sponsibility for injury, damage or loss resulting from the use of the material.
Flammability
Hea
lth
Instability
1 1
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1 0
2
Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
Page 52 of 132Page 52 of 132Page 52 of 132Page 52 of 132
SAFETY DATA SHEET
Issuing Date: 24-Feb-2015 Revision Date: 24-Feb-2015 Version 1
1. IDENTIFICATION
Product Name Febreze Air Effects - Sun Baked
Product ID: 92351338_RET_NG
Product Type: Finished Product - Consumer (Retail) Use Only
Recommended Use Air freshener
Restrictions on Use Safe to use around dogs and cats. As with other care products, not for use around birds.
Synonyms Febreze Air Effects - Summer Fruit Bouquet (92351338_A_RET_NG)Febreze Air Effects - Seaside Spring & Escape (92351338_B_RET_NG)Febreze Air Effects - Wintry Mint (96892319_RET_NG)Febreze Air Effects - Pumpkin Bliss (92350451_RET_NG)Febreze Air Effects - Pumpkin Harvest 92350451_A_RET_NG)Febreze Air Effects - Vanilla Latte (92350912_RET_NG)Febreze Air Effects - Pumpkin Harvest (92350912_A_RET_NG)Febreze Air Effects - Fluffy Vanilla (92350912_B_RET_NG)Febreze Air Effects - Cozy Vanilla Sugar (92350912_C_RET_NG)Febreze Air Effects - Morning Herbs & Mist (92351003_RET_NG)Febreze Air Effects - Turquoise Sea & Shimmer (92351003_A_RET_NG)Febreze Air Effects - New Zealand Springs (92351003_B_RET_NG)
Manufacturer PROCTER & GAMBLE - Fabric and Home Care Division. Ivorydale Technical Centre.5289 Spring Grove Avenue, Cincinnati, Ohio 45217-1087 USA
E-mail Address [email protected]
Emergency Telephone Transportation (24 HR)CHEMTREC - 1-800-424-9300(U.S./ Canada) or 1-703-527-3887Mexico toll free in country: 800-681-9531
2. HAZARD IDENTIFICATION
"Consumer Products", as defined by the US Consumer Product Safety Act and which are used as intended (typical consumerduration and frequency), are exempt from the OSHA Hazard Communication Standard (29 CFR 1910.1200). This SDS is beingprovided as a courtesy to help assist in the safe handling and proper use of the product.
This product is classifed under 29CFR 1910.1200(d) and the Canadian Hazardous Products Regulation as follows:.
Not Classified.
Hazard Statements None
Hazard pictograms None
Page 1 / 7
Page 53 of 132Page 53 of 132Page 53 of 132Page 53 of 132
92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015
3. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredients are listed according to 29CFR 1910.1200 Appendix D and the Canadian Hazardous Products Regulation
4. FIRST AID MEASURES
First aid measures for different exposure routes
Eye contact Rinse with plenty of water. Get medical attention immediately if irritation persists.
Skin contact Rinse with plenty of water. Get medical attention if irritation develops and persists.
Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately ifsymptoms occur.
Inhalation Move to fresh air. If symptoms persist, call a physician.
Most important symptoms/effects,acute and delayed
None under normal use conditions.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Dry chemical, CO 2, alcohol-resistant foam or water spray. Dry chemical. Alcohol-resistantfoam.
Unsuitable Extinguishing Media None.
Special hazard None known.
Special protective equipment forfire-fighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent) and full protective gear.
Specific hazards arising from thechemical
None.
Precautionary Statements -Prevention
None
Precautionary Statements -Response
None
Precautionary Statements -Storage
None
Precautionary Statements -Disposal
None
Hazards not otherwise classified(HNOC)
None
Chemical Name Synonyms Trade Secret CAS-No Weight %Ethanol
Page 2 / 7
- No 64-17-5 1 - 5
Page 54 of 132Page 54 of 132Page 54 of 132Page 54 of 132
92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions Use personal protective equipment. Do not get in eyes, on skin, or on clothing.
Advice for emergency responders Use personal protective equipment as required.
Environmental precautions Keep out of waterways. Do not discharge product into natural waters without pre-treatmentor adequate dilution.
Methods and materials for containment and cleaning up
Methods for containment Absorb with earth, sand or other non-combustible material and transfer to containers forlater disposal. Prevent product from entering drains. Prevent further leakage or spillage ifsafe to do so.
Methods for cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,earth, diatomaceous earth, vermiculite) and place in container for disposal according tolocal / national regulations (see section 13).
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling Use personal protective equipment as required. Keep container closed when not in use.Never return spills in original containers for re-use. Keep out of the reach of children.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible products None known.
Aerosol Classification Level 1
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines .
Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PELEthanol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm
TWA: 1900 mg/m3
(vacated) TWA: 1000 ppm(vacated) TWA: 1900
mg/m3
Mexico: TWA 1000 ppmMexico: TWA 1900 mg/m3
Chemical Name CAS-No Alberta Quebec Ontario TWAEV British ColumbiaEthanol 64-17-5 TWA: 1000 ppm
TWA: 1880 mg/m3
TWA: 1000 ppmTWA: 1880 mg/m3
STEL: 1000 ppm STEL: 1000 ppm
No relevant exposure guidelines for other ingredients
Page 3 / 7
Exposure controls
Engineering Measures Distribution, Workplace and Household Settings:Ensure adequate ventilation
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Where reasonably practicable this should be achieved by the use of local exhaustventilation and good general extraction
Page 55 of 132Page 55 of 132Page 55 of 132Page 55 of 132
92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015
Personal Protective Equipment
Eye Protection Distribution, Workplace and Household Settings:No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Use appropriate eye protection
Hand Protection Distribution, Workplace and Household Settings:No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Protective gloves
Skin and Body Protection Distribution, Workplace and Household Settings:No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):Wear suitable protective clothing
Respiratory Protection Distribution, Workplace and Household Settings:No special protective equipment required
Product Manufacturing Plant (needed at Product-Producing Plant ONLY):In case of insufficient ventilation wear suitable respiratory equipment
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State @20°C AerosolAppearance clearOdor ScentedOdor threshold No information available
VOC Content (%) Products comply with US state and federal regulations for VOC content in consumerproducts.
10. STABILITY AND REACTIVITY
Property Values Note pH value 4.7 - 5.3Melting/freezing point No information availableBoiling point/boiling range No information availableFlash point 51.6 - 60 °C / 125 - 140 °FEvaporation rate No information availableFlammability (solid, gas) No information availableFlammability Limits in AirUpper flammability limit No information availableLower Flammability Limit No information available
Vapor pressure No information availableVapor density No information availableRelative density 0.987 - 1.0Water solubility No information availableSolubility in other solvents No information availablePartition coefficient: n-octanol/waterNo information availableAutoignition temperature No information available .Decomposition temperature No information available .Viscosity of Product No information available
Page 4 / 7
Page 56 of 132Page 56 of 132Page 56 of 132Page 56 of 132
92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015
Reactivity None under normal use conditions.
Stability Stable under normal conditions.
Hazardous polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.
Conditions to Avoid None under normal processing.
Materials to avoid None in particular.
Hazardous Decomposition Products None under normal use.
11. TOXICOLOGICAL INFORMATION
Product Information Information on likely routes of exposure
Inhalation No known effect.Skin contact No known effect.Ingestion No known effect.Eye contact No known effect.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Acute toxicity No known effect.Skin corrosion/irritation No known effect.Serious eye damage/eye irritation No known effect.Skin sensitization No known effect.Respiratory sensitization No known effect.Germ cell mutagenicity No known effect.Neurological Effects No known effect.Reproductive toxicity No known effect.Developmental toxicity No known effect.Teratogenicity No known effect.STOT - single exposure No known effect.STOT - repeated exposure No known effect.Target Organ Effects No known effect.Aspiration hazard No known effect.Carcinogenicity No known effect.
Component Information
Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 InhalationEthanol 64-17-5 10470 mg/kg bw (OECD
401)> 15800 mg/kg bw (Rabbit) 116.9 mg/L air (//OECD
403)
12. ECOLOGICAL INFORMATION
Ecotoxicity
The product is not expected to be hazardous to the environment.
Persistence and degradability No information available.
Bioaccumulative potential No information available.
Mobility No information available.
Page 5 / 7
Other adverse effects No information available.
13. DISPOSAL CONSIDERATIONS
Page 57 of 132Page 57 of 132Page 57 of 132Page 57 of 132
92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015
Waste treatment
Waste from Residues / UnusedProducts
Aerosol cans, when disposed as waste, are regulated as D003 reactive hazardous waste insome States because of their potential to explode when heated. Check with your Stateenvironmental agency for guidance.
Contaminated packaging Disposal should be in accordance with applicable regional, national and local laws andregulations.
California Hazardous Waste Codes(non-household setting)
331
14. TRANSPORT INFORMATION
DOT UN no UN1950UN Proper shipping name AerosolsDescription UN1950, Aerosols, 2.2 , Ltd. Qty.Hazard Class 2.2Emergency Response GuideNumber
126
IMDG UN Number UN1950UN Proper shipping name AerosolsDescription UN1950, Aerosols, 2.2 , Ltd. Qty.Transport hazard class(es) 2.2EmS-No F-D, S-U
IATA UN no UN1950UN Proper shipping name Aerosols, non-flammableDescription UN1950, Aerosols, non-flammable, 2.2 , Ltd. Qty.Hazard Class 2.2ERG Code 2LIATA comment Can also be shipped as ID8000 Consumer Commodity
15. REGULATORY INFORMATIONU.S. Federal Regulations
SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
CERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material
Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air ActAmendments of 1990.
Page 6 / 7
Clean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42)
Page 58 of 132Page 58 of 132Page 58 of 132Page 58 of 132
92351338_RET_NG - Febreze Air Effects - Sun Baked Revision Date: 24-Feb-2015
California Proposition 65This product is not subject to warning labeling under California Proposition 65.Ethanol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage.
U.S. State Regulations (RTK)
Chemical Name CAS-No New JerseyEthanol 64-17-5 X
Chemical Name CAS-No MassachusettsEthanol 64-17-5 X
Chemical Name CAS-No PennsylvaniaEthanol 64-17-5 X
Dipropylene Glycol 25265-71-8 X
International Inventories
United StatesAll intentionally-added components of this product(s) are listed on the US TSCA Inventory.
CanadaThis product is in compliance with CEPA for import by P&G.
Legend TSCA - United States Toxic Substances Control Act Section 8(b) InventoryCEPA - Canadian Environmental Protection Act
16. OTHER INFORMATION
Issuing Date: 24-Feb-2015Revision Date: 24-Feb-2015DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of itspublication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any other materials or in any process, unlessspecified in the text
Page 7 / 7
End of SDS
Page 59 of 132Page 59 of 132Page 59 of 132Page 59 of 132
Form N051 Page 1
5332 Dansher Road Countryside, Illinois 60525
MATERIAL SAFETY DATA SHEET
Revision Date: 8/16/2005 MSDS No: N-051 Emergency Phones: 708-579-8100 (NYCO) 800-424-9300 (CHEMTREC) PLEASE NOTE: This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT-TO-KNOW regulations. Also make this information available to any employee who requests it. It is your obligation to comply with these regulations.
SECTION I - PRODUCT IDENTITY PRODUCT NAME: Lemon Shine Furnature Polish Formula: Lemon oil and silicone emulsion with hydrocarbon propellant for use on furnature Chemical Type: Lemon oil and silicone emulsion
HMIS RATINGS
Health = 1 (Slight) Flammability = 2 (Moderate)
Reactivity = 0 (Minimal) Protection = A (Safety Glasses)
SECTION II - HAZARDOUS INGREDIENTS
CARCINOGEN PERCENT TLV (OSHA,TP,IARC) Propane 1-5% 1000 ppm No CAS No. 74-98-6 n-Butane 1-5% 600 ppm No CAS No. 106-97-8
SECTION III - CHEMICAL AND PHYSICAL
Appearance and Odor: Lemon Odor, Cone Spray Boiling Point: N/A Evaporation Rate (Ether = 1): <1 Melting Point: N/A pH: 10.0-11.0 Spec. Gravity (H20 = 1): <1 Water Solubility: 10% Vapor Density (Air = 1): >1 Vapor Pressure (psig): 117 @ 130F
SECTION IV - FIRE AND EXPLOSION HAZARDS
Aerosol Flammability: Product is not required to be labeled as flammable as described in 16 CFR 1500.3 and 1500.45. Flash Point (Method): <0F (Propellant) None even until boiling (Conc) Explosion Limits: Upper: 9.5 Lower: 1.9 Extinguishing Media: Carbon Dioxide, foam and/or dry chemical may be used. Special Firefighting Procedures and Hazards: Containers should be cooled with water to prevent vapor pressure build up. Use equipment or
shielding, as required, to protect personnel from bursting, rupturing or venting containers. Unusual Fire and Explosion Hazards: At evelated temperatures (over 54C or 130F) containers exposed to direct flame or heat contact should be
cooled with water to prevent weakening or container structure.
SECTION V - REACTIVITY INFORMATION
Stable: Unstable:
Precautions: Incompatibility: Avoid heat, open flame and oxidizing agents.
Hazardous Decomposition Products: Carbon Monoxide in small amounts and additional toxic chemicals may be formed in small amounts Conditions to Avoid: Do not store above 54C or 130F. Keep away from heat, direct sunlight, open flames or sparks. Dropping of containers may cause bursting. Hazardous Polymerization: Occurs: Does Not Occur:
Page 66 of 132Page 66 of 132Page 66 of 132Page 66 of 132
Form N025 Page 2
SECTION VI - HEALTH HAZARDS - PROTECTIVE MEASURES - FIRST AID Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical
attention. Skin: Remove contaminated clothing. Flush skin with water followed by washing with soap and water. If irritation occurs, get
medical attention. Do not use clothing until cleaned. Eyes: Flush eyes with plents of water for 15 minutes while holding eye lids wide open. Get medical attention if irritation persists. Ingestion: Get medical attention. Most likely routes of entry: Inhilation, eyes, and skin
Other Important Medical or Precautionary Information: None
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE Spills and Leaks: Remove all sources of ignition and ventilate area. Soak up spill wiht an inert absorbent and place into a designed disposal container. Consult local regulatory agency for proper disposition of material. Storage and Handling: Avoid breathing vapor. Keep away from heat and flame. Use with adequate ventilation. Do not puncture or incinerate containers. Do not expose to direct sunlight or store at temperatures above 130F (54C). Store as level 1 Aerosol (NFPA 30B) Waste Disposal: Do not puncture or incinerate containers. When contents are depleted continue to depress button until all gass is expelled. Dispose of container in acordance with local, state, and federal regulations. Empty Containers: Dispose in accordance with local, state, and federal regulations. Other Precautions: Please read and follow the directions on the product label; THey are your best guide to using this product in the most effective way, and give the necessary safety precautions to protect you health.
SECTION VIII - REGULATORY INFORMATION Respiratory Protection: None required if good ventilation is maintained. If exposure exceeds occupational exposure limits (Sect. II), use a NIOSH
approved repirator to prevent overexposure. Ventilation: General ventilation is adequate under normal conditions. Mechanical ventilation is optional. Protective Gloves: Chemical resistant gloves are recommended - consult glove manufacturer to determine the proper type for a specific operation.
Eye Protection: Chemical safety glasses are recommended.
Other Protective Clothing or Equipment: Wear impervious clothing to prevent skin contact.
Work/Hygienic Practices: Ensure stict sanityar conditions are conformed to when working around chemicals. Protective clothing and equipment
should be in accordance with 29 CFR 1910.132 and 1910.133.
Reportable for SARA Title III, S.313 (Form R):
The information herein has been compiled from sources believed to be reliable and is accurate to the best of our knowledge. However, NYCO Products Company cannot give any guarantees regarding information from other sources, and expressly does not make any warranties, nor assumes any liability, for its use.
Page 67 of 132Page 67 of 132Page 67 of 132Page 67 of 132
NA
MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015
1 / 7
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name
: MURPHY OIL SOAP WOOD CLEANER SPRAY RTU
Product code : 200000041735
: B02955850000
Manufacturer or supplier's details Company : Colgate-Palmolive Co
300 Park Avenue New York, NY 10022
Telephone : US: Consumer Affairs - 1-800-468-6502
Emergency telephone number
: For emergencies involving spill, leak, fire, exposure or acci-dent call CHEMTREC (24hr) at (800) 424-9300 or (703) 527-3887.
Medical Emergency (24HR):
For MEDICAL EMERGENCIES involving this product call: (888) 489-3861
Recommended use of the chemical and restrictions on use Recommended use
: Formulated all purpose cleaner for household use.
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview Appearance
liquid
Colour
orange
GHS Classification Not a hazardous substance or mixture.
GHS Label element Not a hazardous substance or mixture.
Potential Health Effects Inhalation
: No adverse effects due to inhalation are expected.
Skin
: May cause skin irritation upon prolonged contact.
Eyes
: Causes eye irritation on direct contact.
Ingestion
: May be harmful if swallowed in large quantities.
Aggravated Medical Condi- : None known.
Page 68 of 132Page 68 of 132Page 68 of 132Page 68 of 132
NA
MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015
2 / 7
tion
Carcinogenicity: IARC
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
ACGIH
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by ACGIH.
OSHA
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by OSHA.
NTP
No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components No hazardous ingredients
SECTION 4. FIRST AID MEASURES
If inhaled
: Remove victim to fresh air. Get medical attention, if symp-toms persist.
In case of skin contact
: Flush skin with large amounts of water. If irritation develops and persists, get medical attention.
In case of eye contact
: Flush eyes with water at least 15 minutes. Get medical atten-tion if eye irritation develops or persists.
If swallowed
: Drink 8 ounces of clear water. Get medical attention.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media
: Use water spray, alcohol-resistant foam, dry chemical or car-bon dioxide.
Hazardous combustion prod-ucts
: No hazardous combustion products are known
Special protective equipment for firefighters
: Self-contained breathing apparatus and full protective clothing should be worn when fighting chemical fires.
Page 69 of 132Page 69 of 132Page 69 of 132Page 69 of 132
NA
MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015
3 / 7
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec-tive equipment and emer-gency procedures
: Use personal protection recommended in Section 8 of the SDS.
Methods and materials for containment and cleaning up
: Cover with inert, absorbent material and remove to disposal container. Spill area may be slippery. Flush with plenty of wa-ter.
SECTION 7. HANDLING AND STORAGE
Conditions for safe storage
: Store at controlled room temperature at 20-25°C (68-77°F).
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters Contains no substances with occupational exposure limit values.
Engineering measures : In an industrial work environment, no special precautions or control measures are required.
Personal protective equipment Respiratory protection
: No personal respiratory protective equipment normally re-quired.
Protective measures
: In an industrial work environment, if a splash is likely, chemi-cal goggles may be needed. Prolonged skin contact may require protective gloves. For consumer use, no unusual precautions are necessary.
Hygiene measures
: In an industrial work environment, avoid eye and prolonged skin contact.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: liquid
Colour
: orange
pH
: 10.0
Flash point
: > 100 °C
Density
: 1.0 g/cm3
Page 70 of 132Page 70 of 132Page 70 of 132Page 70 of 132
NA
MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015
4 / 7
SECTION 10. STABILITY AND REACTIVITY
Possibility of hazardous reac-tions
: Hazardous polymerisation does not occur.
Incompatible materials
: Strong oxidizing agents
Hazardous decomposition products
: None known.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity Not classified based on available information.
Product: Acute oral toxicity
: Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method
Skin corrosion/irritation Not classified based on available information.
Serious eye damage/eye irritation Not classified based on available information.
Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information.
Germ cell mutagenicity Not classified based on available information.
Carcinogenicity Not classified based on available information.
Reproductive toxicity Not classified based on available information.
STOT - single exposure Not classified based on available information.
STOT - repeated exposure Not classified based on available information.
Aspiration toxicity Not classified based on available information.
Further information
Product: Remarks: This product has not been tested as a whole. However, this formula was reviewed by expert toxicologists in the Product Safety Assurance Department of Colgate-Palmolive and is determined to be safe for its intended use. This review has taken into consideration available
Page 71 of 132Page 71 of 132Page 71 of 132Page 71 of 132
NA
MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015
5 / 7
safety-related information including information on individual ingredients, similar formulas and potential ingredient interactions. This review is a component of the hazard determination used to prepare the statements in Section 3 of the SDS.
SECTION 12. ECOLOGICAL INFORMATION
The product has not been tested as a whole for environmental toxicity. However, environmental infor-mation on the ingredients in this product have been reviewed by the Environmental, Health and Safety group of Colgate-Palmolive and determined to have an acceptable environmental profile. This evalua-tion is based on available information on individual ingredients, interactions of ingredients, and similar ingredients. Biodegradability claims are supported by data on ingredients (i.e., surfactants are biode-gradable) or testing conducted on the final product (i.e., This product is biodegradable).
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods Waste from residues : Any disposal practice must be in compliance with local, state
and federal laws and regulations (contact local or state envi-ronment agency for specific rules). Do not dump in sewers, any body of water or on the ground.
SECTION 14. TRANSPORT INFORMATION
DOT : Not regulated. TDG : Not regulated. IATA : Not regulated. IMDG : Not regulated.
International Regulation
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied.
National Regulations
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
Components CAS-No. Component RQ (lbs)
Calculated product RQ (lbs)
Page 72 of 132Page 72 of 132Page 72 of 132Page 72 of 132
NA
MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015
6 / 7
FORMALDEHYDE 50-00-0 100 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
Components CAS-No. Component RQ (lbs)
Calculated product RQ (lbs)
FORMALDEHYDE 50-00-0 100 *
*: Calculated RQ exceeds reasonably attainable upper limit. SARA 302
: No chemicals in this material are subject to the reporting re-quirements of SARA Title III, Section 302.
SARA 313
: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489).
Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Ta-ble 116.4A: SODIUM HYDROXIDE 1310-73-2 FORMALDEHYDE 50-00-0 The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: SODIUM HYDROXIDE 1310-73-2 FORMALDEHYDE 50-00-0 This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
Massachusetts Right To Know FORMALDEHYDE 50-00-0 HYDROGEN PEROXIDE 7722-84-1
Pennsylvania Right To Know WATER Water SODIUM HYDROXIDE 1310-73-2
New Jersey Right To Know WATER Water Sodium tallate 61790-45-2
California Prop 65 : This product does not contain any chemicals known to State
of California to cause cancer, birth defects, or any other re-productive harm.
The components of this product are reported in the following inventories:
Page 73 of 132Page 73 of 132Page 73 of 132Page 73 of 132
NA
MURPHY OIL SOAP WOOD CLEANER SPRAY RTU This industrial Safety Data Sheet is not intended for consumers and does not address consumer use of the product. For information regarding consumer applications of this product, refer to the product label. Version 1.1 SDS Number: 660000000403 Revision Date: 05/22/2015
7 / 7
TSCA
: All ingredients in this product are listed on the TSCA Inventory or are not required to be listed on the TSCA Inventory.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) In accordance with OSHA 29 CFR 1910.1048 formaldehyde is not listed in Section 3 of this MSDS, however, formaldehyde is regulated by State and Federal regulations at varying concen-trations. State and Federal information can be found above in Section 15.
SECTION 16. OTHER INFORMATION
Further information NFPA: HMIS III:
Disclaimer: The information on this sheet is limited to the material identified and is believed by the Colgate-Palmolive Company to be correct based on its knowledge and information as of the date noted. Colgate makes no representation, guarantee or warranty, expressed or im-plied, as to the accuracy, reliability or completeness of the information and assumes no re-sponsibility for injury, damage or loss resulting from the use of the material.
Flammability
Hea
lth
Instability
2 1
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
1 0
2
Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
Page 74 of 132Page 74 of 132Page 74 of 132Page 74 of 132
Safety Data Sheet Office Max Compressed Gas Duster
Section 1. Identification
Product Identifier Office Max Compressed Gas DusterSynonyms OM96090, OM96091, OM96092, OM04736, OM04737Manufacturer Stock Numbers
N/A
Product Cas 75-37-6 Recommended use Dust RemovalUses advised against Use Only as Directed - Read label instructions carefully. Keep out of reach of
children. Intentional misuse by deliberately concentrating and/or inhaling contents may be fatal.
Manufacturer Contact
Address Falcon Safety Products, Inc. 25 ImClone Drive Branchburg, NJ, 08876 USA
Phone Emergency Phone Fax
(908) 707-4900 (800) 498-7192 N/A
Section 2. Hazards Identification
Classification FLAMMABLE GASES - Category 2 GASES UNDER PRESSURE - Compressed gas
Signal Word WarningPictogram
Hazard Statements Contains gas under pressure; may explode if heated
Flammable gas Precautionary Statements
Response Eliminate all ignition sources if safe to do so. Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
Prevention Do not spray on an open flame or other ignition source. Keep away from heat. Pressurized container: Do not pierce or burn, even after use.
Storage Protect from sunlight. Store in a well-ventilated place. Store at temperatures not exceeding 120 degrees F/49 degrees C
Disposal N/A
Page 1 of 8Page 75 of 132Page 75 of 132Page 75 of 132Page 75 of 132
Occupational exposure limits, if available, are listed in Section 8.
General Keep out of reach of children Ingredients of unknown toxicity
0%
Hazards not Otherwise Classified
N/A
No Data Available
Section 3. Ingredients
CAS Ingredient Name Weight % 75-37-6 Ethane, 1,1-difluoro- 100 %
Section 4. First-Aid Measures
General Advice Never give anything by mouth to an unconscious person. When symptoms persist or in all cases of doubt, seek medical advice.
Inhalation Remove from exposure, lie down. Move to fresh air. Keep patient warm and at rest. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention.
Skin Take off all contaminated clothing immediately. Flush area with lukewarm water. Do not use hot water. If frostbite has occurred, call a physician.
Eye Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion Is not considered a potential route of exposure.Most important symptoms/effects, acute and delayed
Anaesthetic effects: light-headedness, irregular heartbeat with a strange sensation in the chest, heart thumping, apprehension, feeling of fainting, dizziness or weakness.
Protection of First-aiders If potential for exposure exists refer to Section 8 for specific personal protective equipment.
Notes to Physician Because of possible disturbances of cardiac rhythm catecholamine drugs, such as epinephrine, which may be used in situations of emergency life support, should be used with special caution.
Page 2 of 8Page 76 of 132Page 76 of 132Page 76 of 132Page 76 of 132
Section 5. Fire Fighting Measures
Suitable Extinguishing Media
Water spray, water fog, dry chemical, alcohol resistant foam, carbon dioxide (CO2)
Unsuitable Extinguishing Media
No applicable data available.
Specific Hazards Flammable. This substance's fire decomposition by-products will include hydrofluoric acid and possibly carbonyl flouride. Avoid contact with these materials, which are toxic and irritating. Evacuate personnel immediately in the event of a fire involving this substance. Vapors may form explosive mixtures with air. Vapors are heavier than air and may spread along floors. Vapors or gases may travel considerable distances to ignition source and flash back.
Special protective equipment for firefighters
Use personal protective equipment. Wear neoprene gloves during cleaning up work after a fire. Exposure to decompositon products may be a hazard to health.
Further Information Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Cool containers/tanks with water spray.
Section 6. Accidental Release Measures
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up.
Safeguards (Personnel) Evacuate personnel to safe areas. Ventilate the area. Refer to protective measures listed in sections 7 and 8.
Spill Clean-up If this product is spilled and not recovered, or is recovered as a waste for treatment and disposal, the CERCLA Reportable Quantity is 100 lbs. (release of an Unlisted Hazardous Waste with the Characteristic of Ignitability). Evaporates. Ventilate area using forced ventilation, especially low or enclosed places where heavy vapors might collect.
Accidental Release Measures
Wear self-contained breathing apparatus (SCBA).
Section 7. Handling and Storage
Handling (Personnel) Avoid breathing vapors or mist. Avoid contact with skin, eyes and clothing. Provide sufficient air exchange and/or exhaust in work rooms. For personal protection see section 8. Handle in accordance with good industrial hygiene and safety practice.
Handling (Physical Aspects) Vapors are heavier than air and may spread along floors. Vapors may form flammable mixture with air. The product should only be used in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropirate standard. No sparking tools should be used. Take measures to prevent the build up of electrostatic charge. Keep away from open flames, hot surfaces and sources of ignition. When using DO NOT SMOKE. Do not use in areas where vapors may accumulate such as paper shredders.
Dust Explosion class Not applicableStorage Keep container tightly closed and in a dry, well-ventilated location. Store in original
container. The product has an indefinite shelf life when stored properly. Storage Period Recommended shelf life - 10 years provided product is stored in a dry location as
directed.Storage Temperature Do not expose to temperatures above 120 degrees F (49 degrees C) as
overheating could cause can to burst. DO NOT leave in direct sunlight or enclosed vehicle.
Page 3 of 8Page 77 of 132Page 77 of 132Page 77 of 132Page 77 of 132
Section 8. Exposure Controls/Personal Protection
Occupational Exposure Limits
Ingredient Name ACGIH TLV OSHA PEL STEL
Ethane, 1,1-difluoro- N/A N/A N/A
Personal Protective Equipment
N/A
Engineering controls Ensure adequate ventilation, especially in confined areas. Use respiratory protection if needed.
Eye/Face Protection Wear safety glasses with side shields. Direct contact with liquid may cause frostbite.
Respiratory Protection For rescue use self-contained breathing apparatus. Vapors are heavier than air and can cause suffication by reducing oxygen available for breathing.
Skin and body protection As required by employer code. If there is risk of skin contact, wear protective clothing, gloves, etc. Direct contact with liquid can cause frostbite.
General Hygiene Considerations
Handle in accordance with good industrial hygiene and safety practices.
Page 4 of 8Page 78 of 132Page 78 of 132Page 78 of 132Page 78 of 132
Section 9. Physical and Chemical Properties
Physical State GasColor ClearOdor slight, ether-
likeOdor Threshold No applicable
data availableSolubility Water -
SlightlyPartition coefficient Water/n-octanol N/AVOC% N/AViscosity No applicable
data availableSpecific Gravity 0.91Density lbs/Gal 0.9Pounds per Cubic Foot N/AFlash Point <-58°F (<-50°
C)FP Method N/APh NeutralMelting Point No applicable
data availableBoiling Point -13 °F (-25 °
C) Boiling Range N/ALEL 3.9UEL 16.9Evaporation Rate No applicable
data availableFlammability FlammableDecomposition Temperature N/AAuto-ignition Temperature No applicable
data availableVapor Pressure 5,960 KPa at
77F (25C)Vapor Density 2.4 at 77F
(25C) (Air=1)
Section 10. Stability and Reactivity
Reactivity Stable under recommended storage conditions.Chemical Stability The product is chemically stable under recommended storage conditions.Conditions to Avoid Aerosol containers are unstable at temperatures above 120 degrees F/49 degrees
CIncompatible Materials Incompatible products include Alkali metals, Alkaline earth metals, powdered
metals, powdered metal salts.Hazardous Decomposition Products
Decomposition products are hazardous. This material can be decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming hydrofluoric acid and possibly carbonyl fluoride.
Page 5 of 8Page 79 of 132Page 79 of 132Page 79 of 132Page 79 of 132
Section 11. Toxicological Information
Component Analysis - LC50 1,1-Difluoroethane - > 64000 ppm ratComponent analysis - Oral LD50
1,1-Difluoroethane - 1500 mg/kg rat
Effects of Acute Exposure - Eye
Contact with liquid may cause frostbite
Effects of Acute Exposure - Skin
Contact with liquid may cause frostbite
Effects of Acute Exposure - Inhalation
Excessive intentional inhalation may cause respiratory tract irritation and central nervous system effect (headaches, dizziness). Vapors may cause dizziness or suffocation.
Effects of Acute Exposure - Ingestion
Not a normal route of exposure
Sensitization Non-hazardous by WHMIS/OSHA criteria.Carcinogenicity Not classifiable as a human carcinogen. Animal testing did not show carcinogenic
effects. None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC, NTP, or OSHA as a carcinogen.
Mutagenicity Animal testing did not show any mutagenic effects. Did not cause genetic damage in cultured bacterial cells. Tests on mammalian cell cultures showed mutagenic effects.
Reproductive Toxicity No toxcicity to reproduction. Animal testing showed no reproductive toxicity.Teratogenicity Animal testing showed no developmental toxicity.Further Information Cardiac sensitization threshold limit: 405000 mg/m3
Section 12. Ecological Information
Aquatic Toxicity 1,1-Difluoroethane 96 h LC50 : Fish 295.78 mg/l 96 h EC50 : Algae 47.76 mg/l 48 h EC50 : Daphnia (water flea) 146.7 mg/l
Section 13. Disposal
Waste Disposal Methods Comply with applicable Federal, State/Provincial and Local Regulations. May be a RCRA Hazardous waste due to the ignitability characteristic. Do not puncture or incinerate container.
Contaminated Packaging Not Available
Page 6 of 8Page 80 of 132Page 80 of 132Page 80 of 132Page 80 of 132
Section 14. Transport Information
UN Number 1030UN Proper Shipping Name 1,1-DifluoroethaneDOT Classification 2.1Packing Group N/APackaging Exceptions Note: Falcon Safety Products has been granted a DOT special permit. A copy of
DOT Special Permit SP-11516 can be obtained by calling Falcon Safety Products, Inc. at 908-707-4900.
Transportation of Dangerous Goods (TDG - Canada)
Proper Shipping name: 1,1-Difluoroethane Hazard Class: 2.1 UN number: 1030 Packaging Exceptions: Limited quantity (containers up to 125mL)
IATA/ICAO (Air) Proper Shipping Name: 1,1-Difuoroethane. Hazard Class: 2.1. UN Number: 1030. Maximum Net Quantity Packaging: Cargo Aircraft only - 150 kg maximum (forbidden on passenger aircraft). Maximum Net Quantity packaging cargo only: 150 kg.
IMDG (Marine Transport) Proper Shipping Name: 1,1-DIFLUOROETHANE. Hazard Class: 2.1. UN Number: 1030.
Additional Information TDG Canada: Falcon Safety Products has been granted Equivalency Certificate SU 9211 (ren. 1) by the TCSS, TDGD to offer for transport by road, rail and marine.
Section 15. Regulatory Information
Canadian Federal Regulations
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations.
WHMIS Status ControlledWHMIS Classification Class A - Compressed Gas, Class B - Division 1 - Flammable GasTSCA On the inventory, or in compliance with the inventory.SARA 313 Regulated Chemical(s)
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
US Federal Regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
NJ Right to Know Regulated Chemical(s)
Substances on the New Jersey Workplace Hazardous Substance List present at a concentration of 1% or more (0.1% for substances identified as carcinogens, mutagens or teratogens): 1,1-Difluoroethane.
California Prop. 65 This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm.
Canada Domestic Substances List (DSL)
This product is listed on the DSL inventory list and complies with the inventory requirements administered by the governing country.
Page 7 of 8Page 81 of 132Page 81 of 132Page 81 of 132Page 81 of 132
Section 16. Other Information
Revision Date 4/28/2015
Disclaimer Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document.
Prepared By Falcon Safety Products, Inc. 908-707-4900
Page 8 of 8Page 82 of 132Page 82 of 132Page 82 of 132Page 82 of 132
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL
Version 2.0 Print Date 05/22/2014
Revision Date 05/21/2014 MSDS Number 350000017409
1/8
1. PRODUCT AND COMPANY IDENTIFICATION
Product information
Trade name : PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL
Use of the Substance/Mixture
: Furniture Polish/Cleaner
Company : S.C. Johnson and Son, Limited 1 Webster Street Brantford ON N3T 5R1
Emergency telephone number
: 24 Hour Transport & Medical Emergency Phone (866) 231-5406 24 Hour International Emergency Phone (952) 852-4647 24 Hour Canadian Transport Emergency Phone (CANUTEC) (613) 996-6666
2. HAZARDS IDENTIFICATION
Emergency Overview Appearance / Odor : yellow / liquid / pleasant
Immediate Concerns
: Caution Avoid contact with skin, eyes and clothing. May be harmful if swallowed.
Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion.
Eyes : May cause:
Mild eye irritation
Skin : Prolonged or repeated contact may dry skin and cause irritation.
Inhalation : Excessive exposures may affect human health, as follows: Inhalation may cause central nervous system effects.
Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort. Aspiration hazard if swallowed - can enter lungs and cause damage.
Aggravated Medical Condition
: Persons with pre-existing skin disorders may be more susceptible to irritating effects.
Page 83 of 132Page 83 of 132Page 83 of 132Page 83 of 132
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL
Version 2.0 Print Date 05/22/2014
Revision Date 05/21/2014 MSDS Number 350000017409
2/8
3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous chemicals present at or above reportable levels as defined by OSHA 29 CFR 1910.1200 or the Canadian Controlled Products Regulations are listed in this table:
Chemical Name CAS-No. Weight percent
Hydrocarbons, C16-C20, n-alkanes, isoalkanes, cyclics, <2% aromatics
64742-46-7 30.00 - 60.00
White Mineral Oil, (Petroleum)
8042-47-5 30.00 - 60.00
Citrus, Extract 94266-47-4 1.00 - 5.00
For additional information on product ingredients, see www.whatsinsidescjohnson.com.
4. FIRST AID MEASURES
Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.
Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.
Inhalation : Remove to fresh air. If breathing is affected, get medical attention.
Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately.
5. FIREFIGHTING MEASURES
Suitable extinguishing media
: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Specific hazards during firefighting
: Container may melt and leak in heat of fire.
Further information : Fight fire with normal precautions from a reasonable distance.
Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus.
Flash point : 102 °C
Page 84 of 132Page 84 of 132Page 84 of 132Page 84 of 132
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL
Version 2.0 Print Date 05/22/2014
Revision Date 05/21/2014 MSDS Number 350000017409
3/8
215.6 °F Method: Tag Closed Cup (TCC)
Lower explosion limit : Note: not applicable
Upper explosion limit : Note: not applicable
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Material can create slippery conditions.
Personal precautions : No special precautions required.
Environmental precautions : Outside of normal use, avoid release to the environment.
Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Dike large spills. Clean residue from spill site.
7. HANDLING AND STORAGE
Handling
Advice on safe handling : Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS.
Advice on protection against fire and explosion
: Normal measures for preventive fire protection.
Storage
Requirements for storage areas and containers
: Keep container closed when not in use. Keep in a dry, cool and well-ventilated place.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits
Components CAS-No. mg/m3
ppm
Non-standard
units
Basis
White Mineral Oil, (Petroleum)
8042-47-5 5 mg/m3
-
-
ACGIH TWA
Personal protective equipment
Page 85 of 132Page 85 of 132Page 85 of 132Page 85 of 132
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL
Version 2.0 Print Date 05/22/2014
Revision Date 05/21/2014 MSDS Number 350000017409
4/8
Respiratory protection
No personal respiratory protective equipment normally required.
Hand protection
: No special requirements.
Eye protection
No special requirements.
Skin and body protection
: No special requirements.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : liquid
Color : yellow
Odor : pleasant
pH : not applicable
Boiling point : no data available
Freezing point : no data available
Flash point : 102 °C 215.6 °F Method: Tag Closed Cup (TCC)
Evaporation rate : no data available
Flammability (solid, gas) : Does not sustain combustion.
Lower explosion limit : not applicable
Upper explosion limit : not applicable
Vapour pressure : no data available
Density : 0.8424 g/cm3 at 40 °C
Water solubility : negligible
Viscosity, dynamic : 24 mPa.s at 40 °C
Page 86 of 132Page 86 of 132Page 86 of 132Page 86 of 132
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL
Version 2.0 Print Date 05/22/2014
Revision Date 05/21/2014 MSDS Number 350000017409
5/8
Viscosity, kinematic : 28.5 mm2/s at 40 °C
Volatile Organic Compounds Total VOC (wt. %)*
: 1.1 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations
10. STABILITY AND REACTIVITY
Conditions to avoid : Direct sources of heat.
Materials to avoid : Strong oxidizing agents
Materials to avoid : None known.
Hazardous decomposition products
: Thermal decomposition can lead to release of irritating gases and vapours.
Hazardous reactions : Stable under recommended storage conditions.
11. TOXICOLOGICAL INFORMATION
Acute oral toxicity : LD50 Calculated > 5,000 mg/kg
Acute inhalation toxicity : no data available
Acute dermal toxicity : no data available
Chronic effects Carcinogenicity : no data available
Mutagenicity : None Anticipated Reproductive effects : no data available
Teratogenicity : no data available
Page 87 of 132Page 87 of 132Page 87 of 132Page 87 of 132
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL
Version 2.0 Print Date 05/22/2014
Revision Date 05/21/2014 MSDS Number 350000017409
6/8
Sensitisation : Substance is not a sensitizer.
12. ECOLOGICAL INFORMATION
Ecotoxicity effects : no data available
13. DISPOSAL CONSIDERATIONS
Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist.
14. TRANSPORT INFORMATION
Please refer to the Bill of Lading/receiving documents for up-to-date shipping information. Land transport
U.S. DOT and Canadian TDG Surface Transportation: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Sea transport
IMDG: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Air transport
ICAO/IATA: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None.
15. REGULATORY INFORMATION
Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.
Page 88 of 132Page 88 of 132Page 88 of 132Page 88 of 132
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL
Version 2.0 Print Date 05/22/2014
Revision Date 05/21/2014 MSDS Number 350000017409
7/8
Notification status : All ingredients of this product comply with the New Substances
Notification requirements under the Canadian Environmental Protection Act (CEPA).
California Prop. 65 : This product is not subject to the reporting requirements under California's Proposition 65.
Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.
16. OTHER INFORMATION
HMIS Ratings
Health 1
Flammability 1
Reactivity 0
NFPA Ratings
Health 1
Fire 1
Reactivity 0
Special -
This information is being provided in accordance with Occupational Safety and Health Administration (OSHA) and Canada’s Workplace Hazard Material Information System (WHMIS) regulations. The information supplied is designed for workplaces where product use and frequency of exposure exceeds that established for the labeled consumer use.
Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.
Prepared by SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)
Page 89 of 132Page 89 of 132Page 89 of 132Page 89 of 132
Material Safety Data Sheet
according to ANSI Z400.1- 2004 and 29 CFR 1910.1200
PLEDGE® FURNITURE CLEANER & POLISH WITH NATURAL ORANGE OIL
Version 2.0 Print Date 05/22/2014
Revision Date 05/21/2014 MSDS Number 350000017409
8/8
Page 90 of 132Page 90 of 132Page 90 of 132Page 90 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
1 / 14
SECTION 1. IDENTIFICATION
Product name
: PURELL® Hand Sanitizing Wipes
Manufacturer or supplier's details
Company name of supplier
: GOJO Industries, Inc.
Address
: One GOJO Plaza, Suite 500 Akron OH 44311
Telephone
: 1 (330) 255-6000
Emergency telephone
: 1-800-424-9300 CHEMTREC
Recommended use of the chemical and restrictions on use
Recommended use
: Hand Sanitizer
Restrictions on use
: This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids
: Category 3
Eye irritation
: Category 2A
GHS Label element
Hazard pictograms
:
Signal Word
: Warning
Hazard Statements
: H226 Flammable liquid and vapor. H319 Causes serious eye irritation.
Page 91 of 132Page 91 of 132Page 91 of 132Page 91 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
2 / 14
Precautionary Statements
: Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/ attention. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards
Vapors may form explosive mixture with air.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture
: Mixture
Hazardous ingredients
Chemical Name CAS-No. Concentration (%)
Ethanol 64-17-5 >= 10 - < 20
Benzethonium chloride 121-54-0 >= 0.1 - < 1
SECTION 4. FIRST AID MEASURES
General advice
: In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice.
If inhaled
: If inhaled, remove to fresh air. Get medical attention if symptoms occur.
In case of skin contact
: Wash with water and soap as a precaution. Get medical attention if symptoms occur.
In case of eye contact
: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lens, if worn.
Page 92 of 132Page 92 of 132Page 92 of 132Page 92 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
3 / 14
Get medical attention.
If swallowed
: If swallowed, DO NOT induce vomiting. Get medical attention if symptoms occur. Rinse mouth thoroughly with water.
Most important symptoms and effects, both acute and delayed
: Causes serious eye irritation.
Protection of first-aiders
: First Aid responders should pay attention to self-protection, and use the recommended personal protective equipment when the potential for exposure exists.
Notes to physician
: Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
: Water spray Alcohol-resistant foam Dry chemical Carbon dioxide (CO2)
Unsuitable extinguishing media
: High volume water jet
Specific hazards during fire fighting
: Do not use a solid water stream as it may scatter and spread fire. Flash back possible over considerable distance. Vapors may form explosive mixtures with air. Exposure to combustion products may be a hazard to health.
Hazardous combustion prod-ucts
: Carbon oxides
Specific extinguishing methods
: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Remove undamaged containers from fire area if it is safe to do so. Evacuate area.
Special protective equipment for fire-fighters
: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
: Remove all sources of ignition. Use personal protective equipment. Follow safe handling advice and personal protective equipment recommendations.
Environmental precautions : Discharge into the environment must be avoided.
Page 93 of 132Page 93 of 132Page 93 of 132Page 93 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
4 / 14
Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained.
Methods and materials for containment and cleaning up
: Non-sparking tools should be used. Soak up with inert absorbent material. Suppress (knock down) gases/vapors/mists with a water spray jet. For large spills, provide diking or other appropriate containment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container. Clean up remaining materials from spill with suitable absorbent. Local or national regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which regulations are applicable. Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures
: See Engineering measures under EXPOSURE CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation
: Use with local exhaust ventilation. Use only in an area equipped with explosion proof exhaust ventilation.
Advice on safe handling
: Avoid inhalation of vapor or mist. Do not swallow. Do not get in eyes. Avoid prolonged or repeated contact with skin. Handle in accordance with good industrial hygiene and safety practice. Non-sparking tools should be used. Keep container tightly closed. Keep away from heat and sources of ignition. Take precautionary measures against static discharges. Take care to prevent spills, waste and minimize release to the environment.
Conditions for safe storage
: Keep in properly labeled containers. Keep tightly closed. Keep in a cool, well-ventilated place. Store in accordance with the particular national regulations. Keep away from heat and sources of ignition.
Materials to avoid
: Do not store with the following product types: Strong oxidizing agents
Page 94 of 132Page 94 of 132Page 94 of 132Page 94 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
5 / 14
Organic peroxides Flammable solids Pyrophoric liquids Pyrophoric solids Self-heating substances and mixtures Substances and mixtures which in contact with water emit flammable gases Explosives Gases
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters
Ingredients CAS-No. Value type (Form of exposure)
Control parameters / Permissible concentration
Basis
Ethanol 64-17-5 TWA 1,000 ppm 1,900 mg/m3
NIOSH REL
TWA 1,000 ppm 1,900 mg/m3
OSHA Z-1
STEL 1,000 ppm ACGIH
Hazardous components without workplace control parameters
Ingredients CAS-No.
Benzethonium chloride 121-54-0
Engineering measures : Minimize workplace exposure concentrations. Use only in an area equipped with explosion proof exhaust ventilation. Use with local exhaust ventilation.
Personal protective equipment
Respiratory protection
: General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection.
Hand protection Material : Impervious gloves Material : Flame retardant gloves
Page 95 of 132Page 95 of 132Page 95 of 132Page 95 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
6 / 14
Remarks
: Choose gloves to protect hands against chemicals depending on the concentration specific to place of work. Breakthrough time is not determined for the product. Change gloves often! For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Wash hands before breaks and at the end of workday.
Eye protection
: Wear the following personal protective equipment: Safety goggles
Skin and body protection
: Select appropriate protective clothing based on chemical resistance data and an assessment of the local exposure potential. Wear the following personal protective equipment: Flame retardant antistatic protective clothing. Skin contact must be avoided by using impervious protective clothing (gloves, aprons, boots, etc).
Hygiene measures
: Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Wash contaminated clothing before re-use.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
: impregnated cloth
Color
: colorless, clear, cloudy
Odor
: citrus
Odor Threshold
: No data available
pH
: 4.0 - 7.5
Melting point/freezing point
: No data available
Initial boiling point and boiling range
: No data available
Flash point
: 37.8 °C
Evaporation rate
: No data available
Flammability (solid, gas)
: Not applicable
Upper explosion limit
: No data available
Lower explosion limit
: No data available
Vapor pressure
: No data available
Relative vapor density : No data available
Page 96 of 132Page 96 of 132Page 96 of 132Page 96 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
7 / 14
Density
: 0.9780 g/cm3
Solubility(ies) Water solubility
: soluble
Partition coefficient: n-octanol/water
: Not applicable
Autoignition temperature
: No data available
Decomposition temperature
: The substance or mixture is not classified self-reactive.
Viscosity Viscosity, kinematic
: No data available
Explosive properties
: Not explosive
Oxidizing properties
: The substance or mixture is not classified as oxidizing.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
: Not classified as a reactivity hazard.
Chemical stability
: Stable under normal conditions.
Possibility of hazardous reac-tions
: Flammable liquid and vapor. Vapors may form explosive mixture with air. Can react with strong oxidizing agents.
Conditions to avoid
: Heat, flames and sparks.
Incompatible materials
: Oxidizing agents
Hazardous decomposition products
: No hazardous decomposition products are known.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Inhalation Skin contact Ingestion Eye contact
Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity
: Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method
Page 97 of 132Page 97 of 132Page 97 of 132Page 97 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
8 / 14
Ingredients:
Ethanol: Acute oral toxicity
: LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity
: LC50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapor
Benzethonium chloride: Acute oral toxicity
: LD50 (Rat): 295 mg/kg Method: OECD Test Guideline 401
Skin corrosion/irritation
Not classified based on available information.
Product:
Result: No skin irritation
Ingredients:
Ethanol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Benzethonium chloride: Species: Rabbit Result: Corrosive after 1 to 4 hours of exposure
Serious eye damage/eye irritation
Causes serious eye irritation.
Ingredients:
Ethanol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405
Respiratory or skin sensitization
Skin sensitization: Not classified based on available information. Respiratory sensitization: Not classified based on available information.
Product:
Assessment: Does not cause skin sensitization.
Ingredients:
Ethanol: Test Type: Local lymph node assay (LLNA) Routes of exposure: Skin contact Species: Mouse Result: negative Benzethonium chloride:
Page 98 of 132Page 98 of 132Page 98 of 132Page 98 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
9 / 14
Test Type: Magnusson-Kligman-Test Routes of exposure: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative
Germ cell mutagenicity
Not classified based on available information.
Ingredients:
Ethanol: Genotoxicity in vitro
: Test Type: In vitro mammalian cell gene mutation test Result: negative
Genotoxicity in vivo
: Test Type: Rodent dominant lethal test (germ cell) (in vivo) Species: Mouse Application Route: Ingestion Result: negative
Benzethonium chloride: Genotoxicity in vitro
: Test Type: Bacterial reverse mutation assay (AMES) Result: negative
Carcinogenicity
Not classified based on available information.
Ingredients:
Benzethonium chloride: Species: Rat Application Route: Skin contact Exposure time: 2 Years Result: negative IARC
No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
OSHA
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino-gen by OSHA.
NTP
No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Not classified based on available information.
Ingredients:
Ethanol: Effects on fertility
: Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion
Page 99 of 132Page 99 of 132Page 99 of 132Page 99 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
10 / 14
Method: OECD Test Guideline 416 Result: negative
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Repeated dose toxicity
Ingredients:
Ethanol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y
Aspiration toxicity
Not classified based on available information.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients:
Ethanol: Toxicity to fish
: LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h
Toxicity to daphnia and other aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): > 1,000 mg/l Exposure time: 48 h
Toxicity to algae
: EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Exposure time: 72 h Method: OECD Test Guideline 201
Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)
: NOEC (Daphnia magna (Water flea)): 9.6 mg/l Exposure time: 9 d
Toxicity to bacteria
: EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h
Benzethonium chloride: Toxicity to fish
: LC50 (Oncorhynchus mykiss (rainbow trout)): 1.15 mg/l Exposure time: 96 h Method: OECD Test Guideline 203
Toxicity to daphnia and other aquatic invertebrates
: EC50 (Daphnia magna (Water flea)): 0.22 mg/l Exposure time: 48 h Method: OECD Test Guideline 202
Page 100 of 132Page 100 of 132Page 100 of 132Page 100 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
11 / 14
Toxicity to algae
: EC50 (Pseudokirchneriella subcapitata (green algae)): 0.12 mg/l Exposure time: 72 h Method: OECD Test Guideline 201
M-Factor (Acute aquatic tox-icity)
: 1
Toxicity to bacteria
: EC50: 35.70 mg/l Exposure time: 3 h Method: OECD Test Guideline 209
Persistence and degradability
Ingredients:
Ethanol: Biodegradability
: Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d
Benzethonium chloride: Biodegradability
: Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 301B
Bioaccumulative potential
Ingredients:
Ethanol: Partition coefficient: n-octanol/water
: log Pow: -0.35
Benzethonium chloride: Partition coefficient: n-octanol/water
: log Pow: 1.08
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not burn, or use a cutting torch on, the empty drum.
Page 101 of 132Page 101 of 132Page 101 of 132Page 101 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
12 / 14
SECTION 14. TRANSPORT INFORMATION
International Regulation
UNRTDG Not regulated as a dangerous good
IATA-DGR Not regulated as a dangerous good
IMDG-Code Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR Not regulated as a dangerous good
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards
: Fire Hazard Acute Health Hazard
SARA 302
: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313
: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
US State Regulations
Pennsylvania Right To Know
Water 7732-18-5 70 - 90 %
Ethanol 64-17-5 10 - 20 %
Propan-2-ol 67-63-0 0.1 - 1 %
New Jersey Right To Know
Water 7732-18-5 70 - 90 %
Ethanol 64-17-5 10 - 20 %
D-Glucitol, ethoxylated 53694-15-8 1 - 5 %
Page 102 of 132Page 102 of 132Page 102 of 132Page 102 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
13 / 14
California Prop 65 This product does not contain any chemicals known to the
State of California to cause cancer, birth, or any other reproductive defects.
The ingredients of this product are reported in the following inventories:
REACH
: All ingredients (pre-)registered or exempt.
TSCA
: All chemical substances in this product are either listed on the TSCA Inventory or are in compliance with a TSCA Inventory exemption.
DSL
: All chemical substances in this product comply with the CEPA 1999 and NSNR and are on or exempt from listing on the Canadian Domestic Substances List (DSL).
AICS
: All ingredients listed or exempt.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA)
SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS III:
Full text of other abbreviations
ACGIH : USA. ACGIH Threshold Limit Values (TLV) NIOSH REL : USA. NIOSH Recommended Exposure Limits OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants ACGIH / STEL : Short-term exposure limit NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek OSHA Z-1 / TWA : 8-hour time weighted average
Flammability
Health
Insta
bility
2
2
0
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
2
0
2
Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic
Page 103 of 132Page 103 of 132Page 103 of 132Page 103 of 132
SAFETY DATA SHEET
PURELL® Hand Sanitizing Wipes
Version 1.0
Revision Date: 03/30/2015
MSDS Number: 80013-00001
Date of last issue: - Date of first issue: 03/30/2015
14 / 14
Sources of key data used to compile the Material Safety Data Sheet
: Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen-cy, http://echa.europa.eu/
Revision Date
: 03/30/2015
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-formation and belief at the date of its publication. The information is designed only as a guid-ance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provid-ed relates only to the specific material identified at the top of this SDS and may not be valid when the SDS material is used in combination with any other materials or in any process, un-less specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, in-cluding an assessment of the appropriateness of the SDS material in the user’s end product, if applicable. US / Z8
Page 104 of 132Page 104 of 132Page 104 of 132Page 104 of 132
#19617 Page: 1 of 6 Issue date 11-February-2015
SAFETY DATA SHEET
1. Product and Company Identification
Product identifier Sani-Cloth HB Germicidal Disposable Wipe SDS0042
Other means of identification Not available
Recommended use Hard, Nonporous Surface Disinfectant
Recommended restrictions For Professional and Hospital Use
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Company name
Address
Professional Disposables International, Inc.
Two Nice-Pak Park,
Orangeburg, NY 10962-1376
Telephone 1-845-365-1700 (M-F 9am - 5pm)
Emergency phone number 1-800-999-6423
2. Hazards Identification
Physical hazards
Health hazards
Environmental hazards
OSHA defined hazards
Label elements
Hazard symbol
Not classified.
Not classified.
Not determined.
Not classified.
None.
Signal word None.
Hazard statement The mixture does not meet the criteria for classification.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response Wash hands after handling.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise
classified (HNOC) None known.
Supplemental information Not applicable.
3. Composition/Information on Ingredients
Mixtures
Chemical name Common name and synonyms
CAS number %
Benzyl-C12-18-alkyldimethyl ammonium chlorides
Quaternary ammonium compounds, C12-14-alkyl[(ethylphenyl)methyl]di methyl, chlorides
68391-01-5
85409-23-0
0.07
0.07
4. First Aid Measures
Inhalation Not a normal route of exposure.
Skin contact If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control centre or doctor for treatment advice. Have the product container or label with you when calling a poison control center or doctor, or going for treatment.
Page 105 of 132Page 105 of 132Page 105 of 132Page 105 of 132
#19617 Page: 2 of 6 Issue date 11-February-2015
Eye contact Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if
present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
Ingestion Do not induce vomiting. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention.
Most important
symptoms/effects, acute and
delayed
Indication of immediate
medical attention and special
treatment needed
Direct contact with eyes may cause temporary irritation.
Treat patient symptomatically.
General information If you feel unwell, seek medical advice (show the label where possible). Show this safety data
sheet to the doctor in attendance. Avoid contact with eyes, skin and clothing. Keep out of reach of children.
5. Fire Fighting Measures
Suitable extinguishing media Treat for surrounding material.
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
None known.
Firefighters should wear a self-contained breathing apparatus.
Firefighters should wear full protective clothing including self contained breathing apparatus.
In the event of fire, cool product with water spray.
Specific methods Cool product exposed to flames with water until well after the fire is out.
General fire hazards No unusual fire or explosion hazards noted.
6. Accidental Release Measures
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS.
Prevent entry into waterways, sewers or confined areas. Pick up and discard towel. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
7. Handling and Storage
Precautions for safe handling Use good industrial hygiene practices in handling this material. Do not reuse towelette. Do not reuse the empty container. When using do not eat or drink.
Conditions for safe storage,
including any incompatibilities
Store in a closed container away from incompatible materials. Store away from incompatible materials (see Section 10 of the SDS). Keep out of reach of children.
8. Exposure Controls/Personal Protection
Occupational exposure limits No exposure limits noted for ingredient(s).
Biological limit values No biological exposure limits noted for the ingredient(s).
Exposure guidelines This material does not have established exposure limits.
Appropriate engineering
controls
Ensure adequate ventilation.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear gear as deemed necessary. Follow label directions.
Skin protection
Hand protection Wear as deemed necessary, follow label directions.
Other As required by employer code.
Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene
considerations
Handle in accordance with good industrial hygiene and safety practice. Washing with soap and water after use is recommended as good hygienic practice to prevent possible eye irritation from hand contact. When using do not eat or drink.
Page 106 of 132Page 106 of 132Page 106 of 132Page 106 of 132
#19617 Page: 3 of 6 Issue date 11-February-2015
9. Physical and Chemical Properties
Appearance Liquid saturated on wipe
Physical state Solid.
Form Liquid saturated on wipe
Color White
Odor Mild quat
Odor threshold Not available.
pH 10.75 (liquid)
Melting point/freezing point Not available.
Initial boiling point and boiling
range
Not available.
Pour point Not available.
Specific gravity 1.0027 g/mL (liquid)
Partition coefficient
(n-octanol/water)
Not available.
Flash point > 212.0 °F (> 100.0 °C) Tag Closed Cup (Liquid)
Evaporation rate Not available.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Flammability limit - upper
(%)
Not available.
Not available.
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.
Solubility(ies) Wipe is not soluble
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
10. Stability and Reactivity
Reactivity May react with incompatible materials.
Possibility of hazardous
reactions
Hazardous polymerization does not occur.
Chemical stability Stable under recommended storage conditions.
Conditions to avoid Avoid temperatures exceeding the flash point. Do not mix with other chemicals.
Contact with incompatible materials.
Incompatible materials Acids. Oxidizers. Caustics.
Hazardous decomposition
products
May include and are not limited to: Oxides of carbon. Chloride compounds Ammonia.
11. Toxicological Information
Information on likely routes of exposure
Ingestion Not applicable under normal conditions of use.
Inhalation Health injuries are not known or expected under normal use.
Skin contact Prolonged skin contact may cause skin irritation.
Eye contact Health injuries are not known or expected under normal use.
Symptoms related to the
physical, chemical and
toxicological characteristics
Symptoms may include stinging, tearing, redness, swelling of the eyes, and blurred vision. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms may include stomach distress, nausea or vomiting.
Information on toxicological effects
Acute toxicity
Page 107 of 132Page 107 of 132Page 107 of 132Page 107 of 132
#19617 Page: 4 of 6 Issue date 11-February-2015
Components Species
Benzyl-C12-18-alkyldimethyl ammonium chlorides (CAS 68391-01-5)
Acute
Dermal
LD50 Rat
Inhalation
LC50 Not available
Oral
LD50 Mouse
Test Results
2000 mg/kg
1420 mg/kg
150 mg/kg
Rat 240 mg/kg
Quaternary ammonium compounds, C12-14-alkyl[(ethylphenyl)methyl]dimethyl, chlorides (CAS 85409-23-0)
Acute
Dermal
LD50 Not available
Inhalation
LC50 Not available
Oral
LD50 Rat 300 - 2000 mg/kg
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Exposure minutes Not available.
Erythema value Not available.
Oedema value Not available.
Serious eye damage/eye
irritation
Direct contact with eyes may cause temporary irritation.
Corneal opacity value Not available.
Iris lesion value Not available.
Conjunctival reddening
value
Not available.
Conjunctival oedema value Not available.
Recover days Not available.
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity Non-hazardous by OSHA criteria.
Carcinogenicity Non-hazardous by OSHA criteria.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity Non-hazardous by OSHA criteria.
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Not classified.
Not classified.
Aspiration hazard Not classified.
Chronic effects Non-hazardous by OSHA criteria.
Further information This product has no known adverse effect on human health.
12. Ecological Information
Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment. See below
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Mobility in general Not available.
Page 108 of 132Page 108 of 132Page 108 of 132Page 108 of 132
#19617 Page: 5 of 6 Issue date 11-February-2015
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal Considerations
Disposal instructions Dispose of used towelette in trash. Do not flush in toilet.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code This product is not a hazardous waste.
Waste from residues / unused
products
Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Empty packaging may be disposed in trash.
14. Transport Information
U.S. Department of Transportation (DOT)
Not regulated as dangerous goods.
15. Regulatory Information
US federal regulations This product is NOT known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use.
PRECAUTIONARY STATEMENTS: Hazard to humans and domestic animals. CAUTION: Causes moderate eye irritation. Harmful if absorbed through skin. Avoid contact with eyes, skin or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, or tobacco. Remove contaminated clothing and wash before reuse.
EPA Reg. # 61178-4-9480 EPA Est. # 9480-NY-1.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No
SARA 302 Extremely No
hazardous substance
SARA 311/312 Hazardous No
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act
(SDWA)
Food and Drug
Administration (FDA)
Not regulated.
Not regulated.
US state regulations This product is not subject to warning labeling under the California Proposition 65 regulation.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
Page 109 of 132Page 109 of 132Page 109 of 132Page 109 of 132
#19617 Page: 6 of 6 Issue date 11-February-2015
US - Texas Effects Screening Levels: Listed substance
Benzyl-C12-18-alkyldimethyl ammonium chlorides (CAS 68391-01-5)
US. Massachusetts RTK - Substance List
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Not regulated.
US. Rhode Island RTK
Not regulated.
Listed.
Country(s) or region Inventory name On inventory (yes/no)*
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)
16. Other Information
Yes
LEGEND
Severe 4
Serious 3
Moderate 2
Slight 1
Minimal 0
HEALTH / 1
0 FLAMMABILITY 0
1 0 PHYSICAL HAZARD 0
PERSONAL X
PROTECTION
Disclaimer The information in the sheet was written based on the best knowledge and experience currently
available. Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document.
Issue date 11-February-2015
Further information For any questions surrounding this SDS, please contact the supplier/manufacturer listed on the first page of the document.
It is a violation of Federal law to use this product in a manner inconsistent with its labeling. Not for use on skin. Not a baby wipe. For use on hard surfaces only.
Revision 0. Bulk Liquid # 4BQ08401.
Other information This Safety Data Sheet was prepared to comply with the current OSHA Hazard Communication
Standard (HCS) adoption of the Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
Prepared by Dell Tech Laboratories, Ltd. Phone: (519) 858-5021
Page 110 of 132Page 110 of 132Page 110 of 132Page 110 of 132
Material Safety Data Sheet: SHINE M UP AEROSOLSAMPLE, CAN CLSupercedes Date 02/23/2006 Issuing Date 11/18/2009
1. PRODUCT AND COMPANY IDENTIFICATION Product Name SHINE M UP AEROSOLSAMPLE, CAN CL Product Code 5056Recommended Use Cleaning agent Chemical Nature AerosolInformation on Manufacturer Emergency Telephone Number CERTIFIED LABS, DIV. OF NCH CORP. CHEMTREC ® 800-424-9300BOX 152170 IRVING, TEXAS 75015
2. HAZARDS IDENTIFICATION
Emergency Overview CAUTION
May be harmful if inhaledMay cause skin irritationMay cause eye irritation
May be harmful if swallowedContents under pressure
Color Off -white Physical State Liquid Odor AmmoniacalPotential Health Effects Principle Route of Exposure Skin contact, Eye contact, Inhalation.Primary Routes of Entry InhalationAcute Effects Eyes May cause eye irritation. Skin May cause skin irritation. Inhalation May cause irritation of respiratory tract. Inhalation may cause central nervous system effects. Symptoms and signs include
headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting, and diarrhea.Chronic Toxicity Occupational health effects due to inhalation of mineral dusts incorporating crystalline silica (quartz, cristobalite, tridymite), crystalline
silicates (kaolin, talc) graphite or coal, Kidney injury may occur, May cause cancer after repeated inhalation of spray or dust.Target Organ Effects Eyes, Skin, Respiratory system, Central nervous system, Heart, Liver, Kidney, Lungs.Aggravated Medical Conditions Respiratory disorders, Skin disorders, Liver disorders, Kidney disorders, Heart disease.Potential Environmental Effects See Section 12 for additional Ecological information.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Component CAS-NoCrystalline Silica (Quartz) 14808-60-7
Propane 74-98-6Butane 106-97-8
Ammonium tallate 68132-50-3
4. FIRST AID MEASURES General Advice Avoid contact with skin, eyes, and clothing. Avoid breathing vapors, mist, or gas.Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. Get medical attention if irritation develops and persists.Skin Contact Wipe up with absorbent material (e.g. cloth, fleece). Wash off immediately with plenty of water. Get medical attention if irritation
develops and persists. Wash contaminated clothing before re-use.Inhalation If inhaled, remove to fresh air. Get medical attention if symptoms occur.Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention if symptoms occur.Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES Flash Point >212°F/>100°C Method Seta closed cupAutoignition Temperature No information available.
Flammability Limits in Air % Propellant. Upper 1.8 Lower 9.5Suitable Extinguishing MediaFoam. Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.Specific Hazards Arising from the ChemicalSolvent vapors are heavier than air and may spread along floors. Vapors may ignite and explode. Material can create slippery conditions. Flame extension: 0 inches / 0 cm and Burnback: 0 inches / 0 cm.Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.Aerosol Level (NFPA 30B) - 1NFPA Health 2 Flammability 1 Instability 0HMIS Health 2 Flammability 1 Instability 0
6. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with skin, eyes, and clothing. Remove all sources of ignition.Environmental Precautions Prevent further leakage or spillage if safe to do so.
Page 1 / 4 Page 111 of 132Page 111 of 132Page 111 of 132Page 111 of 132
Methods for Containment Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).
Methods for Cleaning Up Pick up and transfer to properly labeled containers.Neutralizing Agent Not applicable.
7. HANDLING AND STORAGE Handling Avoid contact with skin, eyes, and clothing. Avoid breathing dust/fume/gas/mist/vapours/spray. Contents under pressure. Do not
puncture.Storage Keep in a dry, cool and well-ventilated place. Keep away from open flames, hot surfaces and sources of ignition.Storage Temperature Minimum 35°F/2°C Maximum 120°F/49°CStorage Conditions Indoor X Outdoor Heated Refrigerated
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines
Component ACGIH TLV OSHA PEL NIOSHCrystalline Silica (Quartz) TWA: 0.025 mg/m3 No data available IDLH: 50 mg/m3 TWA: 0.05 mg/m3
Propane TWA: 1000 ppm TWA: 1800 mg/m3 TWA: 1000 ppm IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3
Butane TWA: 1000 ppm No data available TWA: 1900 mg/m3 TWA: 800 ppm
Ammonium tallate No data available No data available No data available Engineering Measures Ensure adequate ventilation, especially in confined areas.Personal Protective Equipment Eye/Face Protection Safety glasses with side-shields. Skin Protection For prolonged or repeated contact, use protective gloves Respiratory Protection In case of inadequate ventilation wear respiratory protection.General Hygiene Considerations Ensure that eyewash stations and safety showers are close to the workstation location. Wash contaminated clothing before re-use.
9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Viscosity ViscousColor Off -white Odor AmmoniacalAppearance Opaque pH @10% -10Specific Gravity 1.180 Evaporation Rate 12.3 (Butyl acetate=1)Percent Volatile (Volume) 76.4 VOC Content (%) 6.5VOC Photoreactive (Y/N) Yes Vapor Pressure 136.9 mmHg @ 70 °FVapor Density 1.3 (Air = 1.0) Solubility Completely solubleBoiling Point/Range 212°F/100°C
10. STABILITY AND REACTIVITY Chemical Stability Stable under normal conditions. Hazardous polymerization does not occur.Conditions to Avoid Heat, flames, and sparks.Incompatible Products Oxidizing agents, Acids, Highly halogenated compounds, Fluorinated hydrocarbons.Hazardous Decomposition Products Carbon oxides, Nitrogen oxides (NOx).Possibility of Hazardous Reactions Dangerous fumes form when mixed with other products. Chlorine.
11. TOXICOLOGICAL INFORMATION Product Information No information available.
Component Information Acute toxicity
Component LD50 Oral LD50 Dermal LC50 Inhalation Draize Test OtherCrystalline Silica (Quartz) 500 mg/kg ( Rat ) no data available no data available no data available no data available
Propane no data available no data available 658 mg/L ( Rat ) 4 h no data available no data availableButane no data available no data available 658 mg/L ( Rat ) 4 h no data available no data available
Ammonium tallate no data available no data available no data available no data available no data available Chronic Toxicity
Component Mutagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effects
Crystalline Silica (Quartz) no data available no data available no data available no data available eyes, respiratory system (in animals: lung cancer)
Propane no data available no data available no data available no data available CNSButane no data available no data available no data available no data available CNS
Ammonium tallate no data available no data available no data available no data available no data available Carcinogenicity
Component ACGIH IARC NTP OSHA OtherCrystalline Silica (Quartz) A2 Group 1 Known X not applicable
Propane not applicable not applicable not applicable not applicable not applicableButane not applicable not applicable not applicable not applicable not applicable
Ammonium tallate not applicable not applicable not applicable not applicable not applicable
5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009
Page 2 / 4 Page 112 of 132Page 112 of 132Page 112 of 132Page 112 of 132
12. ECOLOGICAL INFORMATION Product Information No information available.
Component Information
Component Toxicity to Algae Toxicity to Fish Microtox Water Flea log PowCrystalline Silica (Quartz) no data available no data available no data available no data available N/A
Propane no data available no data available no data available no data available 2.3Butane no data available no data available no data available no data available 2.89
Ammonium tallate no data available no data available no data available no data available N/A Persistence and Degradability No information available.Bioaccumulation No information available.Mobility No information available.
13. DISPOSAL CONSIDERATIONS Product Disposal Dispose of in accordance with local regulations.Container Disposal Contents under pressure. Do not puncture. Empty remaining contents. Empty containers should be taken for local recycling, recovery
or waste disposal.
14. TRANSPORT INFORMATION DOT DOT Proper Shipping Name Consumer commodity Hazard Class ORM-D Description Consumer commodity ,ORM-D TDG Proper shipping name Aerosols Hazard Class 2.1 UN-No UN1950 Description AEROSOLS,2.1,UN1950, LTD QTY ICAO UN-No UN1950 Proper Shipping Name Aerosols Hazard Class 2.1 Shipping Description Aerosols,UN1950, LTD QTY IATA UN-No UN1950 Proper Shipping Name Aerosols, flammable Hazard Class 2.1 ERG Code 10L Shipping Description UN1950,Aerosols, flammable,2.1, LTD QTY IMDG/IMO Proper Shipping Name Aerosols Hazard Class 2 UN-No UN1950 EmS No. F-D, S-U Shipping Description UN1950, Aerosols,2, LTD QTY
15. REGULATORY INFORMATION Inventories TSCA CompliesDSL Complies U.S. Federal Regulations SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization
Acute Health Hazard
Yes
Chronic Health Hazard
Yes
Fire Hazard
No
Sudden Release of Pressure Hazard
Yes
Reactive Hazard
No
CERCLA
Component Hazardous Substances RQs CERCLA EHS RQs
Crystalline Silica (Quartz) Not applicable Not applicable
Propane Not applicable Not applicable
5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009
Page 3 / 4 Page 113 of 132Page 113 of 132Page 113 of 132Page 113 of 132
Butane Not applicable Not applicable
Ammonium tallate Not applicable Not applicable
Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard ClassA Compressed gases, D2A Very toxic materials.
16. OTHER INFORMATION Prepared By Dan HollasSupercedes Date 02/23/2006Issuing Date 11/18/2009Reason for Revision No information available.Glossary No information available.List of References. No information available.CERTIFIED LABS, DIV. OF NCH CORP. assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product in a manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the product. The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.
5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL5056 - SHINE M UP AEROSOLSAMPLE, CAN CL Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009Issuing Date 18-Nov-2009
Page 4 / 4 Page 114 of 132Page 114 of 132Page 114 of 132Page 114 of 132
Static Free™ Hand Guard™
Antistatic agents
Liquid.
Chemtrec - 1-800-858-4043CANTUC (Canadian Transportation): (613) 996-6666Emergency phone: (800) 858-404324/7
SAFETY DATA SHEET
GHS product identifier
Other means of identification
Product type
Emergency telephone number (with hours of operation)
Section 1. Identification:
:
:
:
Supplier's details : Chemtronics8125 Cobb Center DriveKennesaw, GA 30152
Tel. 770-424-4888 or toll free 800-645-5244
Static Free™ Hand Guard™
Relevant identified uses of the substance or mixture and uses advised against
Not applicable.
Section 2. Hazards identification
Not classified.Classification of the substance or mixture
:
Signal word : No signal word.
Hazard statements : No known significant effects or critical hazards.
Precautionary statements
Prevention : Not applicable.
Response : Not applicable.
Storage : Not applicable.
Disposal : Not applicable.
GHS label elements
Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 82.5%
OSHA/HCS status : While this material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200), this SDS contains valuable information critical to the safe handling and proper use of the product. This SDS should be retained and available for employees and other users of this product.
Hazards not otherwise classified
: None known.
Section 3. Composition/information on ingredients
Other means of identification
: Antistatic agents
CAS number : Not applicable.
Substance/mixture
Product code : C805
CAS number/other identifiers
: Mixture
Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 1/11
Page 115 of 132Page 115 of 132Page 115 of 132Page 115 of 132
Static Free™ Hand Guard™
Section 3. Composition/information on ingredients
stearic acid 1 - 5 57-11-4glycerol 1 - 2 56-81-5octadecan-1-ol 1 - 2 112-92-5
Ingredient name CAS number%
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs.
Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur.
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
:
:
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.
Description of necessary first aid measures
Specific treatments : No specific treatment.
Most important symptoms/effects, acute and delayed
Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.
Harmful if swallowed.:Ingestion
Skin contact : No known significant effects or critical hazards.
May cause eye irritation.:Eye contact
Over-exposure signs/symptoms
Skin contact
Ingestion
Inhalation No specific data.
Adverse symptoms may include the following:nausea or vomitingdiarrhea
No specific data.
:
:
:
Eye contact : Adverse symptoms may include the following:irritationrednesswatering
Potential acute health effects
See toxicological information (Section 11)
Indication of immediate medical attention and special treatment needed, if necessary
Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 2/11
Page 116 of 132Page 116 of 132Page 116 of 132Page 116 of 132
Static Free™ Hand Guard™
Section 5. Fire-fighting measures
Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Hazardous thermal decomposition products
Specific hazards arising from the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxides
In a fire or if heated, a pressure increase will occur and the container may burst.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment for fire-fighters
Use an extinguishing agent suitable for the surrounding fire.
Extinguishing media
:
:
:
None known.
Suitable extinguishing media
:
Unsuitable extinguishing media
:
Special protective actions for fire-fighters
:
Section 6. Accidental release measures
Environmental precautions
Personal precautions, protective equipment and emergency procedures
Stop leak if without risk. Move containers from spill area. Prevent entry into sewers,water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Large spill :
Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Small spill :
Methods and materials for containment and cleaning up
For non-emergency personnel
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Section 7. Handling and storage
Advice on general occupational hygiene
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
:
Protective measures Put on appropriate personal protective equipment (see Section 8).:
Precautions for safe handling
Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 3/11
Page 117 of 132Page 117 of 132Page 117 of 132Page 117 of 132
Static Free™ Hand Guard™
Section 7. Handling and storageConditions for safe storage,including any incompatibilities
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.
:
glycerol OSHA PEL (United States, 2/2013). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 15 mg/m³ 8 hours. Form: Total dustOSHA PEL 1989 (United States, 3/1989). TWA: 5 mg/m³ 8 hours. Form: Respirable fraction TWA: 10 mg/m³ 8 hours. Form: Total dust
Section 8. Exposure controls/personal protection
Ingredient name Exposure limits
Hand protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side-shields.
Eye/face protection
Respiratory protection :
:
:
Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
:
Environmental exposure controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.
Appropriate engineering controls
: Good general ventilation should be sufficient to control worker exposure to airborne contaminants.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :
Control parameters
Individual protection measures
Occupational exposure limits
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 4/11
Page 118 of 132Page 118 of 132Page 118 of 132Page 118 of 132
Static Free™ Hand Guard™
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative density
Vapor density
Solubility
Liquid. [Viscous liquid.]
0°C (32°F)
1
Not available.
Not available.
Not available.
Pleasant.Odor
pH
White.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Not available.
Not available.
7.2
Viscosity Not available.
Not available.Odor threshold
Partition coefficient: n-octanol/water
:
:
:
:
:
:
:
:
:
:
:
:
:
:
:
Appearance
Boiling point : 100°C (212°F)
Flammability (solid, gas) : Not available.
Lower and upper explosive (flammable) limits
: Not available.
Decomposition temperature : Not available.
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
No specific data.
:
:
:
Incompatible materials :
Possibility of hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Section 11. Toxicological information
Acute toxicity
stearic acid LD50 Dermal Rabbit >5 g/kg -LD50 Oral Rat 4600 mg/kg -
glycerol LD50 Oral Rat 12600 mg/kg -octadecan-1-ol LD50 Oral Rat >5000 mg/kg -
Product/ingredient name Result Species Dose Exposure
Irritation/Corrosion
Information on toxicological effects
Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 5/11
Page 119 of 132Page 119 of 132Page 119 of 132Page 119 of 132
Static Free™ Hand Guard™
Section 11. Toxicological information
Carcinogenicity
Not available.
Mutagenicity
Not available.
Teratogenicity
Not available.
Reproductive toxicity
Not available.
stearic acid Skin - Mild irritant Human - 72 hours 75 milligrams Intermittent
-
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
-
glycerol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams
-
Skin - Mild irritant Rabbit - 24 hours 500 milligrams
-
octadecan-1-ol Eyes - Mild irritant Rabbit - 24 hours 100 milligrams
-
Skin - Mild irritant Man - 48 hours 30 Percent
-
Skin - Mild irritant Rabbit - 24 hours 500 milligrams
-
Product/ingredient name Result Score Exposure Observation
Sensitization
Not available.
Species
Information on the likely routes of exposure
Inhalation : Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure.
Harmful if swallowed.:Ingestion
Skin contact : No known significant effects or critical hazards.
May cause eye irritation.:Eye contact
Symptoms related to the physical, chemical and toxicological characteristics
Skin contact
Inhalation No specific data.
No specific data.
:
:
Eye contact : Adverse symptoms may include the following:irritationrednesswatering
Specific target organ toxicity (single exposure)
Specific target organ toxicity (repeated exposure)
Not available.
Not available.
Aspiration hazard
Not available.
: Not available.
Potential acute health effects
Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 6/11
Page 120 of 132Page 120 of 132Page 120 of 132Page 120 of 132
Static Free™ Hand Guard™
Section 11. Toxicological information
Not available.
No known significant effects or critical hazards.General :
No known significant effects or critical hazards.Carcinogenicity :
No known significant effects or critical hazards.Mutagenicity :
No known significant effects or critical hazards.Teratogenicity :
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Ingestion Adverse symptoms may include the following:nausea or vomitingdiarrhea
:
Potential chronic health effects
Delayed and immediate effects and also chronic effects from short and long term exposure
Numerical measures of toxicity
Oral 26833.3 mg/kgDermal 58333.3 mg/kg
Route ATE value
Acute toxicity estimates
Potential immediate effects
: Not available.
Short term exposure
Potential delayed effects : Not available.
Potential immediate effects
: Not available.
Long term exposure
Potential delayed effects : Not available.
Section 12. Ecological information
LogPow BCF Potential
Bioaccumulative potential
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
stearic acid 8.23 238 to 288 lowglycerol -1.76 - lowoctadecan-1-ol 7.4 - high
Toxicity
Not available.
Persistence and degradability
Soil/water partition coefficient (KOC)
: Not available.
Mobility in soil
Not available.
Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 7/11
Page 121 of 132Page 121 of 132Page 121 of 132Page 121 of 132
Static Free™ Hand Guard™
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction.Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
Section 14. Transport information
-
-
-
-
-
-
-
Not regulated.
-
-
Not regulated. Not regulated.
- - -
DOT Classification
IMDG IATA
UN number
UN proper shipping name
Transport hazard class(es)
Packing group
Additional information
Environmental hazards
Special precautions for user
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No. No. No.
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
: Not available.
:
TDG Classification
Not regulated.
-
-
-
No.
-
ADR/RID
Not regulated.
-
-
-
No.
-
Mexico Classification
Not regulated.
-
-
-
No.
-
Section 15. Regulatory informationU.S. Federal regulations :
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)
: Not listed
Clean Air Act Section 602 Class I Substances
: Not listed
Clean Air Act Section 602 Class II Substances
: Not listed
DEA List I Chemicals (Precursor Chemicals)
: Not listed
TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Commerce control list precursor: 2,2',2''-nitrilotriethanol
Not determined.
Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 8/11
Page 122 of 132Page 122 of 132Page 122 of 132Page 122 of 132
Static Free™ Hand Guard™
Section 15. Regulatory information
The following components are listed: TRIETHANOLAMINE; GLYCERINE MIST
WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer.
Massachusetts :
retinyl palmitate Yes. No. No. No.
Ingredient name Cancer Reproductive No significant risk level
Maximum acceptable dosage level
California Prop. 65
DEA List II Chemicals (Essential Chemicals)
: Not listed
New York : None of the components are listed.
New Jersey : The following components are listed: TRIETHANOLAMINE; ETHANOL, 2,2',2"-NITRILOTRIS-; GLYCERIN; 1,2,3-PROPANETRIOL; PROPYLENE GLYCOL; 1,2-PROPANEDIOL
Pennsylvania : The following components are listed: ETHANOL, 2,2',2"-NITRILOTRIS-; 1,2,3-PROPANETRIOL; 1,2-PROPANEDIOL
State regulations
SARA 302/304
SARA 304 RQ : Not applicable.
No products were found.
Composition/information on ingredients
SARA 311/312
Classification : Not applicable.
stearic acid 1 - 5 Yes. No. No. Yes. No.glycerol 1 - 2 No. No. No. Yes. No.octadecan-1-ol 1 - 2 No. No. No. Yes. No.
Name % Fire hazard
Sudden release of pressure
Reactive Immediate (acute)health hazard
Delayed (chronic)health hazard
Composition/information on ingredients
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Inform Consent (PIC)
Not listed.
Triethanolamine Schedule III Listed
Ingredient name List name Status
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
International lists
National inventory
Australia : All components are listed or exempted.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 9/11
Page 123 of 132Page 123 of 132Page 123 of 132Page 123 of 132
Static Free™ Hand Guard™
Section 15. Regulatory informationEurope : Not determined.
Japan : Not determined.
Republic of Korea : Not determined.
Malaysia : Not determined.
New Zealand : All components are listed or exempted.
Philippines : All components are listed or exempted.
Taiwan : Not determined.
Section 16. Other information
5/18/2015.
History
Date of printing
Date of issue/Date of revision
Version
Date of previous issue
:
:
:
:
Indicates information that has changed from previously issued version.
References : Not available.
Key to abbreviations : ATE = Acute Toxicity EstimateBCF = Bioconcentration FactorGHS = Globally Harmonized System of Classification and Labelling of ChemicalsIATA = International Air Transport AssociationIBC = Intermediate Bulk ContainerIMDG = International Maritime Dangerous GoodsLogPow = logarithm of the octanol/water partition coefficientMARPOL 73/78 = International Convention for the Prevention of Pollution From Ships,1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)UN = United Nations
5/18/2015.
No previous validation.
1
Hazardous Material Information System (U.S.A.)
0
0
0
00
0
National Fire Protection Association (U.S.A.)
Health
Special
Instability/Reactivity
Flammability
Health
Flammability
Physical hazards
Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 10/11
Page 124 of 132Page 124 of 132Page 124 of 132Page 124 of 132
Static Free™ Hand Guard™
Section 16. Other information
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Notice to reader
Date of issue/Date of revision : 5/18/2015. Date of previous issue : No previous validation. Version : 1 11/11
Page 125 of 132Page 125 of 132Page 125 of 132Page 125 of 132
Date Printed: 7/4/2015 Product: M282-3928
Safety Data Sheet
1. Identification
Product Information: M282-3928
Product Name: ULTRA® MARK ICELAND DAWN
Recommended Use: Surface Preparation or Protection
Mohawk Finishing Products
Division of RPM Wood Finishes Group, Inc.
22 South Center Street
Hickory, NC 28602
USA
Supplied by:
Company Phone No: (800) 522-8266
Emergency Phone No. CHEMTREC: (800) 424-9300
(703) 527-3887 (Collect calls are accepted)International Emergency No. CHEMTREC:
2. Hazards Identification
GHS Classification
Carc. 1B, Eye Dam. 1, Flam. Liq. 2, Muta. 1B, Skin Irrit. 2
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTS
Flammable Liquid, category 2 H225 Highly flammable liquid and vapour.
Skin Irritation, category 2 H315 Causes skin irritation.
Serious Eye Damage, category 1 H318 Causes serious eye damage.
Germ Cell Mutagenicity, category 1B H340 May cause genetic defects.
Carcinogenicity, category 1B H350 May cause cancer.
GHS LABEL PRECAUTIONARY STATEMENTS
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P233 Keep container tightly closed.
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Page 1 / 7
Page 126 of 132Page 126 of 132Page 126 of 132Page 126 of 132
Date Printed: 7/4/2015 Product: M282-3928
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P310 Immediately call a POISON CENTER or doctor/physician.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
GHS SDS PRECAUTIONARY STATEMENTS
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
3. Composition/Information on ingredients
Chemical Name CAS-No. Wt. % GHS Symbols GHS Statements
ethanol 64-17-5 40-55 GHS02 H225
butanol 71-36-3 10-25 GHS02-GHS05-
GHS07
H226-302-315-318-332-335-336
pm acetate 108-65-6 10-25 GHS02-GHS07 H226-332
titanium dioxide 13463-67-7 2.5-10 No Information No Information
isopropanol 67-63-0 1.0-2.5 GHS02-GHS07 H225-302-319-336
carbon black 1333-86-4 1.0-2.5 GHS02 H251
aliphatic hydrocarbons 8052-41-3 0.1-1.0 GHS08 H304-340-350-372
aliphatic petroleum distillates 64742-88-7 0.1-1.0 GHS06-GHS08 H304-331-372
ethylbenzene 100-41-4 0.1-1.0 GHS02-GHS07-
GHS08
H225-304-332-373
The text for GHS Hazard Statements shown above (if any) is given in the "Other information" Section.
4. First-aid Measures
FIRST AID - EYE CONTACT: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
FIRST AID - SKIN CONTACT: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If
skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse.
FIRST AID - INGESTION: IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF exposed or if you feel unwell: Call a POISON
CENTER or doctor/physician.
FIRST AID - INHALATION: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable
for breathing. IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician.
5. Fire-fighting Measures
SPECIAL FIREFIGHTING PROCEDURES: Evacuate all persons from the fire area to a safe location. Move non-burning material, as
feasible, to a safe location as soon as possible. Fire fighters should be protected from potential explosion hazards while
extinguishing the fire. Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. Thoroughly
Page 2 / 7
Page 127 of 132Page 127 of 132Page 127 of 132Page 127 of 132
Date Printed: 7/4/2015 Product: M282-3928
decontaminate all protective equipment after use. Containers of this material may build up pressure if exposed to heat (fire). Use
water spray to cool fire-exposed containers. Use water spray to disperse vapors if a spill or leak has not ignited. DO NOT extinguish
a fire resulting from the flow of flammable liquid until the flow of the liquid is effectively shut off. This precaution will help prevent the
accumulation of an explosive vapor-air mixture after the initial fire is extinguished.
FIREFIGHTING EQUIPMENT: This is a NFPA/OSHA Class 1B or less flammable liquid. Follow NFPA30, Chapter 16 for fire
protection and fire suppression. Use a dry chemical, carbon dioxide, or similar ABC fire extinguisher for incipeint fires. Water may be
used to cool and prevent rupture of containers that are exposed to heat from fire.
6. Accidental Release Measures
ENVIRONMENTAL MEASURES: No Information
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations
found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the
special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred,
and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits.
Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled
product to enter public drainage system or open waterways.
7. Handling and Storage
HANDLING: Avoid inhalation and contact with eyes, skin, and clothing. Wash hands thoroughly after handling and before eating or
drinking. In keeping with safe handling practices, avoid ignition sources (smoking, flames, pilot lights, electrical sparks); ground and
bond containers when transferring the material to prevent static electricity sparks that could ignite vapor and use spark proof tools
and explosion proof equipment. Empty containers may retain product residue or vapor. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose container to heat, flame, sparks, static electricity, or other sources of ignition. Any of these actions can
potentially cause an explosion that may lead to injury.
STORAGE: Keep containers closed when not in use. Store in cool well ventilated space away from incompatible materials.
8. Exposure Controls/Personal Protection
Ingredients with Occupational Exposure Limits
Chemical Name ACGIH TLV-TWA ACGIH-TLV STEL OSHA PEL-TWA OSHA PEL-CEILING
ethanol N.D. 1000 ppm 1000 ppm N.D.
butanol 20 ppm N.D. 100 ppm N.D.
pm acetate N.D. N.D. N.D. N.D.
titanium dioxide 10 mg/m3 N.D. 15 mg/m3 N.D.
isopropanol 200 ppm 400 ppm 400 ppm N.D.
carbon black 3 mg/m3 N.D. 3.5 mg/m3 N.D.
aliphatic hydrocarbons 100 ppm N.D. 500 ppm N.D.
aliphatic petroleum distillates N.D. N.D. N.D. N.D.
ethylbenzene 20 ppm N.D. 100 ppm N.D.
Further Advice: MEL = Maximum Exposure Limit OES = Occupational Exposure Standard SUP = Supplier's Recommendation
Sk = Skin Sensitizer N.E. = Not Established N.D. = Not Determined
Personal Protection
RESPIRATORY PROTECTION: A NIOSH-approved air-purifying respirator with the appropriate cartridge may be
permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air-purifying respirators is limited. Use a positive-pressure, air supplied respirator if there is
potential for an uncontrolled release, exposure levels are not known or any other circumstances where air-purifying
Page 3 / 7
Page 128 of 132Page 128 of 132Page 128 of 132Page 128 of 132
Date Printed: 7/4/2015 Product: M282-3928
respirators may not provide adequate protection.
SKIN PROTECTION: Wear chemical resistant footwear and clothing such as gloves, an apron or a whole body suit as
appropriate.
EYE PROTECTION: Wear chemical-resistant glasses and/or goggles and a face shield when eye and face contact is
possible due to splashing or spraying of material.
OTHER PROTECTIVE EQUIPMENT: No Information
HYGIENIC PRACTICES: It is good practice to avoid contact with the product and/or its vapors, mists or dust by using
appropriate protective measures. Wash thoroughly after handling and before eating or drinking.
9. Physical and Chemical Properties
Colored Liquid LIQUIDAppearance: Physical State:
Moderately Strong Alcohol Not determinedOdor: Odor Threshold:
0.916 Not determinedDensity, g/cm3: pH:
Not determined Not determinedFreeze Point, °F: Viscosity:
Not determinedPartition Coefficient, n-octanol/
water: Not determinedSolubility in Water:
Not determined Not determinedDecomposition temperature, °F: Explosive Limits, %:
> 100 °F 55 ° FBoiling Range, °F: Flash Point, °F:
Supports Combustion Not determinedCombustibility: Auto-Ignition Temperature, °F:
Faster than Diethyl Ether Not determinedEvaporation Rate: Vapor Pressure, mmHg:
Not determinedVapor Density:
N.I. = No Information
10. Stability and reactivity
STABILITY: Stable under normal conditions.
CONDITIONS TO AVOID: Heat, flames and sparks.
INCOMPATIBILITY: Acids, Bases, Oxidizing agents
HAZARDOUS DECOMPOSITION PRODUCTS: Not determined.
Page 4 / 7
Page 129 of 132Page 129 of 132Page 129 of 132Page 129 of 132
Date Printed: 7/4/2015 Product: M282-3928
11. Toxicological information
Practical Experiences
EMERGENCY OVERVIEW: No Information
EFFECT OF OVEREXPOSURE - EYE CONTACT: No Information
EFFECT OF OVEREXPOSURE - INGESTION: No Information
EFFECT OF OVEREXPOSURE - INHALATION: No Information
EFFECT OF OVEREXPOSURE - SKIN CONTACT: No Information
CARCINOGENICITY: May cause cancer.
This product contains Titanium Dioxide, which is listed by IARC as possibly carcinogenic to
humans (Group 2B). This listing is based on inadequate evidence of carcinogenicity in humans
and sufficient evidence in experimental animals. This classification is relevant when exposed
to titanium dioxide in dust or powder form only, including cured product that is subject to
sanding, grinding, cutting, or other surface preparation activities.
PRIMARY ROUTE(S) OF ENTRY:
Eye Contact, Skin Contact
Acute Toxicity Values
The acute effects of this product have not been tested. Data on individual components are tabulated below
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
64-17-5 ethanol 7060 mg/kg Rat N.I. 124.7 mg/L Rat
71-36-3 butanol 700 mg/kg Rat 3402 mg/kg Rabbit 8000 mg/l Rat
108-65-6 pm acetate 8532 mg/kg Rat >5000 mg/kg Rabbit >20 mg/L
13463-67-7 titanium dioxide >10000 mg/kg Rat >10000 mg/kg Rabbit >20 mg/l
67-63-0 isopropanol 1870 mg/kg Rat 4059 mg/kg Rabbit 72.6 mg/L Rat
1333-86-4 carbon black >5000 mg/kg Rat >3000 mg/kg Rabbit >20 mg/l
8052-41-3 aliphatic hydrocarbons >5000 mg/kg Rat >3160 mg/kg Rat 21 mg/L Rat
64742-88-7 aliphatic petroleum distillates >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat
100-41-4 ethylbenzene 3500 mg/kg Rat 15400 mg/kg Rabbit 17.2 mg/L Rat
N.I. = No Information
12. Ecological information
ECOLOGICAL INFORMATION: Ecological evaluation of this material has not been performed; however, do not allow the product to
be released to the environment without governmental approval/permits.
13. Disposal Information
Product
DISPOSAL METHOD: Waste from this material may be a listed and/or characteristic hazardous waste. Dispose of material,
contaminated absorbent, container and unused contents in accordance with local, state, and federal regulations.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Follow personal protective equipment recommendations
found in Section VIII. Personal protective equipment needs must be evaluated based on information provided on this sheet and the
special circumstances created by the spill including; the material spilled, the quantity of the spill, the area in which the spill occurred,
Page 5 / 7
Page 130 of 132Page 130 of 132Page 130 of 132Page 130 of 132
Date Printed: 7/4/2015 Product: M282-3928
and the training and the expertise of employees in the area responding to the spill. Never exceed any occupational exposure limits.
Shut off ignition sources; including electrical equipment and flames. Do not allow smoking in the area. Do not allow the spilled
product to enter public drainage system or open waterways.
14. Transport Information
SPECIAL TRANSPORT PRECAUTIONS: No Information
DOT: CONSUMER COMMODITY
IATA: ID8000, CONSUMER COMMODITY, 9
IMDG: LIMITED QUANTITY UN1263
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
SARA SECTION 313
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS-No.
butanol 71-36-3
isopropanol 67-63-0
TOXIC SUBSTANCES CONTROL ACT
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA components exist in this product.
U.S. State Regulations:
CALIFORNIA PROPOSITION 65 CARCINOGENS
WARNING: This product contains a chemical known to the State of California to cause cancer.
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductiveharm.
Page 6 / 7
Page 131 of 132Page 131 of 132Page 131 of 132Page 131 of 132
Date Printed: 7/4/2015 Product: M282-3928
16. Other Information
5/16/2015Supersedes Date:Revision Date: 7/4/2015
Reason for revision: Product Composition Changed
Datasheet produced by: Regulatory Department
HMIS Ratings:
Health: 2 Flammability: 3 Reactivity: 0 Personal Protection: X
Volatile Organic Compounds, gr/ltr: 683
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H251 Self-heating: may catch fire.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H340 May cause genetic defects.
H350 May cause cancer.
H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS05
GHS06
GHS07
GHS08
The information on this sheet corresponds to our present knowledge. It is not a specification and it does not guarantee specific
properties. The information is intended to provide general guidance as to health and safety based upon our knowledge of the
handling, storage, and use of the product. It is not applicable to unusual or non-standard uses of the product where instructions
and recommendations are not followed.
Page 7 / 7
Page 132 of 132Page 132 of 132Page 132 of 132Page 132 of 132