safety data sheet shockstar ms, shockstar ts (25- 1000 ms) · the safety data sheet is in...

The safety data sheet is in accordance with Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC)No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction ofChemicals (REACH)

SECTION 1: Identification of the substance / mixture and of the company /undertakingDate issued 16.11.2015

Revision date 01.08.2017

1.1. Product identifierProduct name Shockstar MS, Shockstar TS (25-1000 ms)

1.2. Relevant identified uses of the substance or mixture and uses advised againstUse of thesubstance/preparation

Borehole detonators for initiation of industrial explosives.

The chemical can be used bythe general public

No

1.3. Details of the supplier of the safety data sheetManufacturerCompany name Austin Detonator s.r.o.

Postcode 755 01

City Vsetin

Country Czech Republic

ImporterCompany name OY FORCIT AB

Postal address P.O.Box 19

Postcode 10901

City Hanko

Country Finland

Tel +358 (0)207 440 400

E-mail [email protected]

1.4. Emergency telephone numberEmergency telephone Tel: countrywise telephone number

Description: National poison information center / National helpdesk

SAFETY DATA SHEETShockstar MS, Shockstar TS (25-

1000 ms)

Shockstar MS, Shockstar TS (25-1000 ms) of 12

This safety data sheet has been created with Eco Publisher (EcoOnline) Revision date 01.08.2017

mailto:[email protected]

SECTION 2: Hazards identification

2.1. Classification of substance or mixtureClassification according toRegulation (EC) No 1272/2008[CLP / GHS]

Expl. 1.1; H201

Acute tox. 4; H302

Carc. 2; H351

Repr. 1A; H360Df

STOT RE2; H373

Aquatic Acute 1; H400

Aquatic Chronic 2; H411

2.2. Label elements

Hazard Pictograms (CLP)

Signal word Danger

Hazard statements H201 Explosive; mass explosion hazard.H302 Harmful if swallowed.H351 Suspected of causing cancer. H360Df May damage the unborn child. Suspected of damaging fertility.H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life.H411 Toxic to aquatic life with long lasting effects.

Precautionary statements P201 Obtain special instructions before use.P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Nosmoking.P250 Do not subject to grinding/shock/friction.P308+P313 IF exposed or concerned: Get medical advice / attention.P370+P380 In case of fire: Evacuate area.P372 Explosion risk in case of fire.P401 Store in dry and well ventilated areas, in temperatures between -30 ◦C and +40 ◦C.P501 Disposal of contents/container must be in accordance with corresponding localregulations for disposal of packages and explosives.

Other Label Information (CLP) Explosives are labeled and packaged in accordance with the requirements for explosives only.

2.3. Other hazardsPBT / vPvB The mixture doesn’t meet the criteria for classification as PBT or vPvB substances and

mixtures.

Other hazards Risk of explosion, an uncontrolled explosion may cause great physical damage.In the assembled detonator, the hazardous substances are enclosed in a metal case thatcannot be disassembled. These substances can be released only by detonation in the form ofpost-detonation reaction products.

SECTION 3: Composition/information on ingredients



3.2. MixturesSubstance Identification Classification Contents1,3,5-Trinitroperhydro-1,3,5-triazine (RDX)

CAS no.: 121-82-4EC no.: 204-500-1

Expl. 1.1; H201Acute tox. 3; H301Aquatic Chronic 3; H412

2 – 20 %

Pentaerythritol tetranitrate CAS no.: 78-11-5EC no.: 201-084-3Index no.: 603-035-00-5

Unst. Expl.;H200 0,3 – 1,1 %

Lead azide CAS no.: 13424-46-9EC no.: 236-542-1Index no.: 082-003-00-7

Unst. Expl.;H200Repr. 1A;H360DfAcute Tox. 4;H332Acute Tox. 4;H302STOT RE 2;H373Aquatic Acute 1;H400Aquatic Chronic 1;H410Note : E

0,4 – 6,4 %

Lead tetroxide CAS no.: 1314-41-6EC no.: 215-235-6

Repr. 1A; H360DfCarc. 2; H351Acute tox. 4; H332Acute tox. 4; H302STOT RE2; H373Aquatic Acute 1; H400 M-factor 10Aquatic Chronic 1; H410 M-factor 1

1,8 – 11,9 %

Zirconium powder (pyrophoric) CAS no.: 7440-67-7EC no.: 231-176-9Index no.: 040-001-00-3

Water-react. 1;H260Pyr. Sol. 1;H250

≤ 0,6 %

Description of the mixture Depending on the type, the nonelectric assembled detonator contains also various othercomponents, such as plastic tube, plug and other plastic components. These components donot contain dangerous substances.

Remarks, substance Zirkonium powder: The mixture is introduced in the market as a solid substance. The mixtureis not in contact with air or water. The classification Water-react. 1H260 a Pyr.Sol. 1 H250 isnot relevant for this mixture.

Substance comments The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measuresGeneral In the assembled detonator, the mixture is enclosed in a metal case that cannot be

disassembled. If used in accordance with section 1.2, the exposition is not possible. Theexposition can occur only in case of detonation in the form of post-detonationreaction products. Detonation may cause burns and injuries. In case of any suspicion, seek medical advice.

Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medicaladvice/attention.

Skin contact Shrapnel from detonation may cause burns and wounds, possibly blood poisoning. Getmedical advice/attention.

Eye contact Shrapnel from detonation may cause great damage, immediately consult an ophthalmologist.



Ingestion Rinse mouth thoroughly. Get medical attention.

4.2. Most important symptoms and effects, both acute and delayedInformation for healthpersonnel

Symptoms do not necessarily appear immediately. Patients should therefore be kept undermedical observation for at least 48 hours.

General symptoms and effects Injuries, burns, irritation of respiratory system, headache.

4.3. Indication of any immediate medical attention and special treatment neededMedical treatment Not determined.

Other Information If any health troubles appear or in case of doubt, please contact a doctor and provide theinformation from this safety sheet.

SECTION 5: Firefighting measures

5.1. Extinguishing mediaSuitable extinguishing media DO NOT fight fire when fire reaches explosives. Explosion risk in case of fire.

5.2. Special hazards arising from the substance or mixtureHazardous combustionproducts

If a building containing the product is on fire, a high risk of explosion is involved. Perform anurgent evacuation of the building and its surroundings. Notify the emergency services. Do notinhale the smoke because it contains heavy metals (lead). The combustion residues and contaminated extinguishing liquids must be disposed ofaccording to valid regulations.

5.3. Advice for firefightersFire fighting procedures DO NOT fight fire when fire reaches explosives. Leave danger zone immediately.

Special protective equipmentfor firefighters

During the fire of the product, keep the safe distance, use suitable breathing protection(isolation device), or self-contained breathing apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency proceduresGeneral measures The measures to be taken in case of accidental leakage (e.g. traffic accident) depend on the

scale of the accident and an expert opinion of a specialist. Warn away trespassers. Eliminate all ignition sources if safe to do so. Evacuate the area dueto possible explosion.

Personal protection measures Avoid contact with skin and eyes. For personal protection, see section 8.

6.2. Environmental precautionsEnvironmental precautionarymeasures

Do not discharge into drains, water courses or onto the ground.

6.3. Methods and material for containment and cleaning upCleaning method Pick up the spilled product mechanically using spark-free tools. Collect the product in

approved and properly labeled containers. Disposal of a damaged product may be performedonly by an authorized person. Disposal of the contaminated material must be in accordancewith section 13.



6.4. Reference to other sectionsOther instructions Fire-fighting, see Section 5.

Personal protection, see Section 8.2.

SECTION 7: Handling and storage

7.1. Precautions for safe handlingHandling Handle the products with increased care. Keep away from heat/sparks/open flame and hot

surfaces. Use non sparking handtools and explosion-proof electric equipment. Do not smokeor use open fire, or other sources of ignition.

7.2. Conditions for safe storage, including any incompatibilitiesStorage Store locked up. Store in a dry place. Store in a well ventilated place in temperatures from -

30°C to +40°C. Do not store together with drugs, foodstuffs, drinks and forage. Do not storetogether with other explosives.

7.3. Specific end use(s)Specific use(s) See Section 1.2

SECTION 8: Exposure controls/personal protection

8.1. Control parametersOther Information aboutthreshold limit values

Lead and inorganic compounds (as Pb), CAS: 7439-92-1:0,15 mg/m3 (inhalable aerosol), EU0,05 mg/m3 (total dust), USA

8.2. Exposure controls

Safety signs

Precautionary measures to prevent exposureAppropriate engineeringcontrols

Follow the usual basic precautions for handling explosives. Avoid inhaling of gases after thedetonation.

Eye / face protectionEye protection Goggles/face shield are recommended.

Hand protectionHand protection Anti-static gloves are recommended.

Skin protectionSkin protection (except hands) Use clothes that are suitable for work and do not accumulate static charge (preferred fabric:

cotton).

Respiratory protection



Respiratory protection Do not breathe fumes after detonation. Dust filter P2 (for fine dust).

Hygiene / environmentalSpecific hygiene measures When using do not eat, drink or smoke. Wash hands always after work, before eating,

drinking, smoking or going to the bathroom.

Appropriate environmental exposure controlEnvironmental exposurecontrols

Use the product according to the given instructions.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical propertiesPhysical state Solid.

Odour Odourless.

Odour limit Comments: Not relevant.

pH Status: In delivery stateComments: Not relevant.

Melting point / melting range Value: 142 °CComments: (PETN)

Boiling point / boiling range Comments: Not relevant.

Flash point Comments: Not relevant.

Evaporation rate Comments: Not relevant.

Flammability (solid, gas) The mixture is flammable.

Explosion limit Comments: Not relevant.

Vapour pressure Comments: Not relevant.

Vapour density Comments: Not relevant.

Specific gravity Comments: Not relevant.

Solubility description Insoluble in water.

Solubility in fat None.

Partition coefficient: n-octanol/water

Comments: Not relevant.

Spontaneous combustability Value: 190 °CComments: (PETN)

Decomposition temperature Comments: Not determined.

Viscosity Comments: Not relevant.

Explosive properties Velocity of detonation: 8750 m/s (RDX).

Oxidising properties Not relevant.

9.2. Other information

Other physical and chemical propertiesComments Not determined.



SECTION 10: Stability and reactivity

10.1. ReactivityReactivity No dangerous reactions known under conditions of normal use.

10.2. Chemical stabilityStability Stabile when used and stored according to the instructions.

10.3. Possibility of hazardous reactionsPossibility of hazardousreactions

May detonate if heated to temperature above 100 °C. May malfunction upon long-termexposure of Al-shell to acidic environment.

10.4. Conditions to avoidConditions to avoid May detonate with impact or friction. May detonate if exposed to open fire, radiant heat, high

frequency or electrostatic energy.

10.5. Incompatible materialsMaterials to avoid Acids and alkalis.

10.6. Hazardous decomposition productsHazardous decompositionproducts

Detonation gasses containing lead, NOx.

SECTION 11: Toxicological information

11.1. Information on toxicological effectsSubstance 1,3,5-Trinitroperhydro-1,3,5-triazine (RDX)

Acute toxicity Type of toxicity: AcuteEffect Tested: LD50Route of exposure: OralValue: 100 mg/kgAnimal test species: Rat

Substance Pentaerythritol tetranitrate

Acute toxicity Type of toxicity: AcuteEffect Tested: LD50Route of exposure: OralValue: 1660 mg/kgAnimal test species: rat

Substance Lead tetroxide

Acute toxicity Type of toxicity: AcuteEffect Tested: LD50Route of exposure: OralValue: > 10000 mg/kgAnimal test species: rat

Type of toxicity: AcuteEffect Tested: LD50Route of exposure: Dermal



Value: > 2000 mg/kgAnimal test species: rat

Type of toxicity: AcuteEffect Tested: LC50Route of exposure: Inhalation.Value: > 5,05 mg/lAnimal test species: rat

Substance Zirconium powder (pyrophoric)

Acute toxicity Type of toxicity: AcuteEffect Tested: LD50Route of exposure: OralValue: > 5000 mg/kgAnimal test species: rat

Type of toxicity: AcuteEffect Tested: LC50Route of exposure: Inhalation.Value: > 4,3 mg/lAnimal test species: rat

Other information regarding health hazardsGeneral The toxicological information applies to the uncartridged product mass.

Assessment of acute toxicityclassification

The mixture is classified as acute toxic – category 4. Harmful if swallowed.

Skin corrosion / irritation, otherinformation

Based on available data, the classification criteria are not met.

Assessment eye damage orirritation, classification

Based on available data, the classification criteria are not met.

Inhalation Based on available data, the classification criteria are not met.

Sensitisation Based on available data, the classification criteria are not met.

Carcinogenicity The mixture is classified as carcinogenic – category 2.

Teratogenic properties Based on available data, the classification criteria are not met.

Reproductive toxicity May damage the unborn child. Suspected of damaging fertility Kat. 1A

STOT-single exposure Based on available data, the classification criteria are not met.

STOT-repeated exposure The mixture is classified as toxic – category 2. May cause damage to organs throughprolonged or repeated exposure.

Other adverse Toxicologicaleffects

Not determined.

Symptoms of ExposureOther Information Lead and its compounds are partly deposited inside body, especially bones. After long-term

and high exposition, a chronic lead poisoning disease may develop, which is exhibited byfailure of hemoglobin production, encephalopathy and also by paralysis of peripheral nerves.Lead and its compounds are known for their bioaccumulative effect and lead to irreversiblehealth damage. Further lead and its compounds may damage unborn child and reproductioncapability of humans.

SECTION 12: Ecological information



12.1. ToxicitySubstance 1,3,5-Trinitroperhydro-1,3,5-triazine (RDX)

Acute aquatic, fish Value: 26 – 57 mg/lTest duration: 96 hMethod: LC50


Acute aquatic, fish Value: 926 mg/lTest duration: 96 hSpecies: Pimephales promelasMethod: LC50


Acute aquatic, fish Value: 0,1 mg/lTest duration: 96 hMethod: LC50

Substance Zirconium powder (pyrophoric)

Acute aquatic, fish Value: > 20 mg/lTest duration: 96 hSpecies: Oncorhynchus mykissMethod: LC50


Acute aquatic, algae Value: 0,05 mg/lTest duration: 72 hMethod: IC50

Substance 1,3,5-Trinitroperhydro-1,3,5-triazine (RDX)

Acute aquatic, Daphnia Value: 28 mg/lTest duration: 48 hSpecies: DaphniaMethod: EC50


Acute aquatic, Daphnia Value: 292 mg/lTest duration: 48 hSpecies: Daphnia magnaMethod: EC50


Acute aquatic, Daphnia Value: 0,98 mg/lTest duration: 48 hMethod: EC50

12.2. Persistence and degradabilityPersistence and degradability Biodegradation in water: PETN: The substance is readily biodegradable.

12.3. Bioaccumulative potentialBioaccumulative potential PETN:

Octanol/Water partition coefficient: 2,4Bioconcentration factor (BCF): 17



12.4. Mobility in soilMobility PETN:

Koc value: 650 (low mobility in soil)RDX:Koc value: 63-270 (medium to high mobility in soil)

12.5. Results of PBT and vPvB assessmentPBT assessment results This product does not contain any PBT or vPvB substances.

12.6. Other adverse effectsOther adverse effects /Remarks

Not relevant.

SECTION 13: Disposal considerations

13.1. Waste treatment methodsSpecify the appropriatemethods of disposal

Dispose in accordance with corresponding regulations. Disposal of defect or damagedproduct is performed in accordance with instruction from manufacturer or in accordance withlocal regulation. Disposal may be performed only by an authorized person. During disposal ofdamaged or rejected products the material must be separated and collected into enclosablecontainers resisting to climate and weather conditions. Avoid release to the environment.Contaminated packages are disposed in accordance with corresponding local regulations fordisposal of packages and explosives.Empty packages are handed over to company authorized to recycle packages.

Product classified ashazardous waste

Yes

SECTION 14: Transport information

14.1. UN numberADR / RID / ADN 0360

IMDG 0360

ICAO/IATA 0360

Comments Even UN number 0500 (1.4S) can be used depending on the packaging.

14.2. UN proper shipping nameADR / RID / ADN DETONATOR ASSEMBLIES, NON-ELECTRIC

IMDG DETONATOR ASSEMBLIES, NON-ELECTRIC

ICAO/IATA DETONATOR ASSEMBLIES, NON-ELECTRIC

14.3. Transport hazard class(es)ADR / RID / ADN 1.1B

IMDG 1.1B

ICAO/IATA 1.1B

Comments Even hazard class 1.4S (UN number 0500) can be used.



14.4. Packing groupComments Not determined.

14.5. Environmental hazardsComments Not determined.

14.6. Special precautions for userSpecial safety precautions foruser

Not determined.

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

IMDG / ICAO / IATA Other informationEmS F-B, S-X

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance ormixtureLegislation and regulations According to chapter VII and VIII of directive 1907/2006 of the European Parliament and the

Council the mixtures and substances contained in the mixture, do not need to be authorized.Lead azide (CAS: 13424-46-9) and lead tetroxide (CAS 1314-41-6) are included in the SVHCCandidate List. Following will be a procedure to authorize this substance for use, according toitem 59 of REACH directive.

Comments For professional users only.

15.2. Chemical safety assessmentCSR required No

SECTION 16: Other informationList of relevant H-phrases(Section 2 and 3).

H200 Unstable explosives.H201 Explosive; mass explosion hazard.H250 Catches fire spontaneously if exposed to air.H260 In contact with water releases flammable gases which may ignite spontaneously.H301 Toxic if swallowed.H302 Harmful if swallowed.H332 Harmful if inhaled.H351 Suspected of causing cancer H360Df May damage the unborn child. Suspected of damaging fertility.H373 May cause damage to organs through prolonged or repeated exposure H400 Very toxic to aquatic life.H410 Very toxic to aquatic life with long lasting effects.H411 Toxic to aquatic life with long lasting effects.H412 Harmful to aquatic life with long lasting effects.

Classification according toRegulation (EC) No 1272/2008[CLP / GHS]

Expl. 1.1; H201Acute tox. 4; H302Carc. 2; H351Repr. 1A; H360DfSTOT RE2; H373



Aquatic Acute 1; H400Aquatic Chronic 2; H411

Training advice Training for handling and use of explosives and detonators.

Key literature references andsources for data

Material safety data sheet from the product manufacturer. Directive (EC) No 1907/2006 (REACH)Regulation (EC) No 1272/2008 (CLP)

Information which has beenadded, deleted or revised

New product name

Comments The information in this MSDS is based on the present state of our knowledge. It does notrepresent any guarantee with regard to product properties or their suitability for particular uses.Because the use of this information and instructions or the conditions of use of the product isnot at our control, it is the user’s duty to specify the circumstances for the safe use of theproduct.



safety data sheet shockstar ms, shockstar ts (25- 1000 ms) · the safety data sheet is in...

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