safety data sheet hand sanitizer gel - promo brands · 2 gbz/t 160.1~gbz/t 160.81- 2004...
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Safety Data Sheet
HAND SANITIZER GELVersion:V1.0.0.1 Report No.:NAR20LC1I
Creation Date:2020/03/10 Revision Date:2020/03/10
*Prepared according to EU regulation No. 2015/830
| Product identifier
Product Name Hand Sanitizer Gel
CAS No. Not applicable
EC No. Not applicable
Molecular Formula Not applicable
REACH Registration Number -
| Recommended use of the chemical and restrictions on useRecommended use Hand Sanitizer
Restrictions on use This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet.
| Details of the supplier of the Safety Data SheetName of the company
Address of the company
Post code
Telephone number
Fax number
E-mail address
| Emergency phone numberEmergency phone
number 0754-89862302
| CLP classification according to Regulation(EC)No. 1272/2008Flammable Liquids Category 2
| Label elements
Hazard pictograms
Signal word Danger
Identification
Hazards identification2
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| Hazard statementsH225 Highly flammable liquid and vapor
Prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water [or shower].
Storage
P403+P235 Store in a well-ventilated place. Keep cool.
Disposal
P501 Dispose of contents/container in accordance with local/regional/national/ international regulations.
| Other hazardsNot applicable
Component Cas No. Concentration (weight percent, %)
ALCOHOL 64-17-5 75
AQUA 7732-18-5 24.2
CARBOMER 9007-16-3 0.4
TRIETHANOLAMINE 102-71-6 0.4
| Description of first aid measures
General advice Immediate medical attention is required. Show this safety data sheet (SDS) to the doctor in attendance.
Eye contact First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Skin contact Remove contaminated clothes. Rinse and then wash skin with water and soap.
Ingestion Rinse mouth. Refer for medical attention.
Inhalation Fresh air, rest.
Protecting of first-aiders Ensure that medical personnel are aware of the substance involved. Take precautions to protect themselves and prevent spread of contamination.
| Precautionary statements
COMPOSITION/INFORMATION ON INGREDIENTS
First aid measures
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| Most important symptoms and effects, both acute and delayed1 Please see section 11.
| Indication of any immediate medical attention and special treatment needed1 Treat symptomatically.
2 Symptoms may be delayed.
| Extinguishing mediaSuitable extinguishing
media Use extinguishing agent suitable for type of surrounding fire.
Unsuitable extinguishing media No special notes.
| Specific hazards arising from the substance or mixture1 May expansion or decompose explosively when heated or involved in fire.
2 Development of hazardous combustion gases or vapor possible in the event of fire.
| Advice for firefighters
1 As in any fire, wear self-contained breathing apparatus(MSHA/NIOSH approved or equivalent) and full protective gear.
2 Fight fire from a safe distance, with adequate cover.
3 Prevent fire extinguishing water from contaminating surface water or the ground water system.
| Personal precautions, protective equipment and emergency procedures
1 Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures against static discharges.
2 Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.
3 Use personal protective equipment. Avoid breathing vapors, mist or gas.
| Environmental precautions1 Prevent further leakage or spillage if safe to do so.
2 Discharge into the environment must be avoided.
| Methods and materials for containment and cleaning up
1 Absorb spilled material in dry sand or inert absorbent. In case of large amount of spillage, contain a spill by bunding.
2 Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
3 Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.
| Advice on safe handling For personal protection see section 8. Keep away from heat and flame. Use with local exhaust ventilation. Avoid contact with eyes.
Firefighting measures
Accidental release measures
Handling and storage
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| Conditions for safe storage, including any incompatibilities
1 Keep containers tightly closed.
2 Keep containers in a dry, cool and well-ventilated place.
3 Keep away from heat/sparks/open flames/hot surfaces.
4 Store away from incompatible materials and foodstuff containers.
Components with workplace control parameters
Component Country/Region Limit value - Eight hours Limit value - Short term
ppm mg/m³ ppm mg/m³
ALCOHOL 64-17-5
USA - OSHA 1000 1900 - -
South Korea 1000 1900 - -
Ireland - - 1000 -
Germany (AGS) 500 960 1000 1920
Denmark 1000 1900 2000 3800
Australia 1000 1880 - -
Biological limit values
Biological limit values No relevant regulations
Monitoring methods
1 EN 14042 Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents.
2 GBZ/T 160.1~GBZ/T 160.81-2004 Determination of toxic substances in workplace air(Series standard).
Derived No effect level(DNEL)
Component Route of exposure
DNEL for Workers Acute effects
(local) Acute effects
(systemic) Chronic
effects(local) Chronic effects
(systemic)
ALCOHOL 64-17-5
Inhalation No data available No data available No data available 950 mg/mP
3
Oral No data available No data available No data available No data available
Dermal No data available No data available No data available No data available
AQUA 7732-18-5
Inhalation No data available No data available No data available No data available
Oral No data available No data available No data available No data available
Dermal No data available No data available No data available No data available
CARBOMER 9007-16-3
Inhalation No data available No data available No data available No data available
Oral No data available No data available No data available No data available
Dermal No data available No data available No data available No data available
TRIETHANOLAMINE 102-71-6
Inhalation No data available No data available 5 mg/m P
3 5 mg/m P
3
Oral No data available No data available No data available No data available
Dermal No data available No data available No data available No data available
Exposure controls/personal protection
| Control parameters 8
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| Personal protection equipment
General requirement
Eye protection Tightly fitting safety goggles (approved by EN 166(EU) or NIOSH (US).
Hand protection Wear protective gloves(such as butyl rubber), passing the tests according to EN 374(EU), US F739 or AS/NZS 2161.1 standard.
Respiratory protection If exposure limits are exceeded or if irritation or other symptoms are experienced, use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges.
Skin and body protection Wear fire/flame resistant/retardant clothing and antistatic boots.
| Physical and chemical propertiesAppearance Gelatinous
Odor No information available
Odor threshold No information available
pH 7.0(20℃, 10g/L, ALCOHOL ) Melting point/freezing
point(℃) -117(ALCOHOL )
Initial boiling point and boiling range(℃) 79(ALCOHOL )
Flash point(Closed cup,℃) 22
Evaporation rate No information available
Flammability Highly flammable Upper/lower explosive
limits[%(v/v)] Upper limit:19(ALCOHOL );Lower limit:3.3(ALCOHOL )
Vapor pressure 5.8kPa(ALCOHOL )
Vapor density(Air=1) 1.6(ALCOHOL ) Relative
density(Water=1) 0.79(ALCOHOL )
Solubility(mg/L) Miscible with water(ALCOHOL ) n-octanol/water
partition coefficient -0.32(ALCOHOL )
Auto-ignition temperature(℃) 363(ALCOHOL )
Decomposition temperature(℃) ≥700(ALCOHOL )
Viscosity(mm P
2P/s) No information available
Explosive properties Not explosive
Oxidizing properties Not oxidizing
| Stability and reactivity
Reactivity Contact with incompatible substances can cause decomposition or other chemical reactions.
Chemical stability Stable under proper operation and storage conditions.
Physical and chemical properties
Stability and reactivity
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Possibility of hazardous reactions
In contact with oxidants causes severe reactions, and may cause a fire or explosion. In contact with active metals (alkali metals, Na, Ca etc.) causes a reaction and release hydrogen.
Conditions to avoid Incompatible materials, heat, flame and spark.
Incompatible materials Oxidants, alkali metals, alkaline earth metals and aluminum. Alkali, sodium, calcium, and other active metal, halogen, metal oxide, nonmetal oxide, acyl halide and metal phosphide.
Hazardous decomposition products
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
| Acute toxicity Component Cas No. LDR50R(oral) LDR50R(dermal) LCR50R(inhalation,4h)
ALCOHOL 64-17-5 7060mg/kg(Rat) No information
available 39mg/L(Mouse)
TRIETHANOLAMINE 102-71-6 5846mg/kg(Mouse) No information
available No information
available
CARBOMER 9007-16-3 4100mg/kg(Rat) No information
available No information
available
| Carcinogenicity
ID Cas No. Component IARC NTP
1 64-17-5 ALCOHOL Category 1 Not Listed
2 7732-18-5 AQUA Not Listed Not Listed
4 9007-16-3 CARBOMER Not Listed Not Listed
5 102-71-6 TRIETHANOLAMINE Category 3 Not Listed
| Others
CHLORHEXIDINE DIGLUCONATE DISINFECTANT GEL
Skin corrosion/irritation Based on available data, the classification criteria are not met Serious eye
damage/irritation Causes serious eye irritation(Category 2)
Skin sensitization Based on available data, the classification criteria are not met
Respiratory sensitization Based on available data, the classification criteria are not met
Reproductive toxicity Based on available data, the classification criteria are not met
STOT-single exposure Based on available data, the classification criteria are not met
STOT-repeated exposure Based on available data, the classification criteria are not met
Aspiration hazard Based on available data, the classification criteria are not met
Germ cell mutagenicity Based on available data, the classification criteria are not met Reproductive
toxicity(additional) Based on available data, the classification criteria are not met
| Acute aquatic toxicity Component Cas No. Fish Crustaceans Algae
Toxicological information
Ecological information
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ALCOHOL 64-17-5 LCR50R:11000mg/L
(96h)(Fish) ECR50R:9950mg/L
(48h)(Crustaceans) No information
available
TRIETHANOLAMINE 102-71-6 LCR50R:11800mg/L
(96h)(Fish) ECR50R:610mg/L
(48h)(Crustaceans) No information
available
| Chronic aquatic toxicity
Chronic aquatic toxicity No information available
| Persistence and degradability Component Cas No. Persistence (water/soil) Persistence (air)
ALCOHOL 64-17-5 Low(Half-life = 2.17 days) Low(Half-life = 5.08 days)
AQUA 7732-18-5 Low Low
CARBOMER 9007-16-3 Low Low
TRIETHANOLAMINE 102-71-6 Low Low
| Bioaccumulative potential Component Cas No. Bioaccumulative potential comments
ALCOHOL 64-17-5 Low Log KROWR=-0.31
AQUA 7732-18-5 Low Log KROWR=-1.38
CARBOMER 9007-16-3 Low Log KROWR=0.4415
TRIETHANOLAMINE 102-71-6 Low BCF=4
| Mobility in soil Component Cas No. Mobility in soil Soil Organic Carbon-Water
Partitioning Coefficient (Koc)
ALCOHOL 64-17-5 High 1
AQUA 7732-18-5 Low 14.3
CARBOMER 9007-16-3 High 1.201
TRIETHANOLAMINE 102-71-6 Low 10
| Results of PBT and vPvB assessment Component Cas No. Results of PBT and vPvB assessment
(according to (EC) No 2015/830)
ALCOHOL 64-17-5 not PBT/vPvB
AQUA 7732-18-5 not PBT/vPvB
CARBOMER 9007-16-3 not PBT/vPvB
TRIETHANOLAMINE 102-71-6 not PBT/vPvB
| Disposal considerations
Waste chemicals Before disposal should refer to the relevant national and local laws and regulation. Recommend the use of incineration disposal.
Contaminated packaging
Containers may still present chemical hazard when empty. Keep away from hot and ignition source of fire. Return to supplier for recycling if possible.
Disposal considerations 13
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Disposal recommendations Refer to section 13.1and 13.2.
| Label and Mark
Transporting Label
Marine pollutant None
| IMDG-CODE
UN number 1170
UN proper shipping name ETHANOL (ETHYL ALCOHOL)or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
Transport hazard class 3 Transport subsidiary
hazard class None
Packing group Ⅱ
Special provisions 144
Limited quantities 1L
Excepted quantities E2 Marine pollutant(Yes or
no) No
EmS No. F-E,S-D
| ICAO/IATA-DGR
UN number 1170
UN proper shipping name ETHANOL (ETHYL ALCOHOL)or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
Transport hazard class 3 Transport subsidiary
hazard class None
Packing group Ⅱ
Excepted quantities E2 Passenger and Cargo
Aircraft Limited Quantity Packing Instructions
Y341
Passenger and Cargo Aircraft Limited Quantity Maxium net Quantity per
Package
1 L
Passenger and Cargo Aircraft Packing
Instructions 353
Passenger and Cargo Aircraft Maxium net
Quantity per Package 5 L
Cargo Aircraft Packing Instructions 364
Cargo Aircraft Maxium net 60 L
Transport information 14
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Quantity per Package
Special provisions A3、A58、A180
ERG code 3L
| UN-ADR
UN number 1170 UN proper shipping
name ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION)
Transport hazard class 3 Transport subsidiary
hazard class None
Packing group Ⅱ
Special provisions 144|601
Limited quantities 1 L
Excepted quantities E2
Packing instructions P001|IBC02|R001
Special packing provisions
-
Mixed packing provisions
MP19
Protable tanks and bulk containers instructions
T4
Protable tanks and bulk containers special
provisions TP1
ADR tank code LGBF
ADR tank special provisions
-
Vehicle for tank carriage FL
Transport category(Tunnel restriction code)
2 (D/E)
Special provisions for carriage(Packages)
-
Special provisions for carriage(Bulk)
-
Special provisions for carriage(Loading,
unloading and handling) -
Special provisions for carriage(Operation)
S2|S20
Hazard identification No.
33
Notes None
| International chemical inventory
Component EINECS TSCA DSL IECSC NZIoC PICCS KECI AICS ENCS
ALCOHOL √ √ √ √ √ √ √ √ √
AQUA √ √ √ √ √ √ √ √ √
CARBOMER × × × √ √ √ × × ×
Regulatory information 15
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TRIETHANOLAMINE √ √ √ √ √ √ √ √ √
【EINECS】 European Inventory of Existing Commercial Chemical Substances
【TSCA】 United States Toxic Substances Control Act Inventory
【DSL】 Canadian Domestic Substances List
【IECSC】 China Inventory of Existing Chemical Substances
【NZIoC】 New Zealand Inventory of Chemicals
【PICCS】 Philippines Inventory of Chemicals and Chemical Substances
【KECI】 Existing and Evaluated Chemical Substances
【AICS】 Australia Inventory of Chemical Substances
【ENCS】 Existing And New Chemical Substances
| Information on revision
Creation Date 2020/03/10
Revision Date 2020/03/10
Reason for revision -
| Disclaimer
This Safety Data Sheet (SDS) was prepared according to REACH Regulation The data included was derived from international authoritative database and provided by the enterprise. Other information was based on the present state of our knowledge. We try to ensure the correctness of all information. However, due to the diversity of information sources and the limitations of our knowledge, this document is only for user’s reference. Users should make their independent judgment of suitability of this information for their particular purposes. We do not assume responsibility for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product.
HAND SANITIZER GEL
ALCOHOL:75%;AQUA:24.2%;CARBOMER:0.4%;TRIETHANOLAMINE:0.4%
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Highly flammable liquid and vapor
【Prevention】 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Keep container tightly closed.
Ground and bond container and receiving equipment.
Use non-sparking tools.
Take action to prevent static discharges.
Wear protective gloves/protective clothing/eye protection/face protection.
【Response】 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water [or shower]. 【Storage】
Store in a well-ventilated place. Keep cool.
【Storage】 Dispose of contents/container in accordance with local/regional/national/ international regulations.
Please refer to design report of safety data sheet
Supplier:Guangdong Yawei Biological Technology Co., Ltd. Tel:0754-85510732 Address:Southeast side of Xiushui Road, Laimei Industrial Zone, Chenghai District,
Shantou, Guangdong Post code:515821
Emergency phone number:0754-89862302
Danger