safety data sheet floor protector plus+ - resin

Version 1, Date 11/08/2015

SAFETY DATA SHEET

Floor Protector PLUS+ - Resin

According to Regulation (EU) No 453/2010 According to Regulation (EC) No 1907/2006

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier Product name Floor Protector PLUS+ - Resin 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Supplier Eli-Chem Resins UK Ltd

Astra House The Common Guildford Road Cranleigh, Surrey GU6 8RZ +44 (0)1483 2666 36 or 37 Fax: +44 (0)1483 428850 [email protected]

1.4. Emergency telephone number +44 (0)1483 2666 36 or 37 Office Hours Only

SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) R43. R52/53. 2.2. Label elements Contains Labelling

Risk Phrases

Safety Phrases

2.3. Other hazards

Aspartic Acid, N, N'-(methylenebis(2-methyl-4,1-cyclohexanediyl))bis-, 1,1',4,4'-tetraethyl ester

Irritant

R43 May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

S24 Avoid contact with skin. S37 Wear suitable gloves. S60 This material and its container must be disposed of as hazardous waste.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

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2-METHOXY-1-METHYLETHYL ACETATE < 1%

CAS-No.: 108-65-6 EC No.: 203-603-9

Classification (EC 1272/2008) Classification (67/548/EEC)

Flam. Liq. 3 - H226 R10

Aspartic Acid, N, N'-(methylenebis(2-methyl-4,1-cyclohexanediyl))bis-, 1,1',4,4'-tetraethyl ester 60-100%

CAS-No.: 136210-32-7 EC No.: 412-060-9


Skin Sens. 1 - H317 R43,R52/53.

Aquatic Chronic 3 - H412

Decanedioic acid,1,10-bis(1,2,2,6,6-pentamethyl-4-piperidinyl) ester < 1%

CAS-No.: 41556-26-7 EC No.:


Skin Sens. 1 - H317 N;R51/53.

Aquatic Chronic 2 - H411 R43.

DI-ISOBUTYL KETONE 1-5%

CAS-No.: 108-83-8 EC No.: 203-620-1


Flam. Liq. 3 - H226 R10

STOT SE 3 - H335 Xi;R37

ETHYLBENZENE < 1%

CAS-No.: 100-41-4 EC No.: 202-849-4


Flam. Liq. 2 - H225 F;R11

Acute Tox. 4 - H332 Xn;R20

fumaric acid diethyl ester 1-5%

CAS-No.: 623-91-6 EC No.:


Acute Tox. 4 - H302 Xn;R22.

Solvent naphtha(petroleum), light aromatic,<0.1% benzene 10-30%

CAS-No.: 64742-95-6 EC No.: 265-199-0

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Flam. Liq. 3 - H226 Xn;R65.

EUH066 Xi;R37.

STOT SE 3 - H335, H336 N;R51/53.

Asp. Tox. 1 - H304 R10,R66,R67.

Aquatic Chronic 2 - H411

XYLENE < 1%

CAS-No.: 1330-20-7 EC No.: 215-535-7


Flam. Liq. 3 - H226 R10

Acute Tox. 4 - H312 Xn;R20/21

Acute Tox. 4 - H332 Xi;R38

Skin Irrit. 2 - H315 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures Inhalation Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues.

Ingestion NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get medical attention if any

discomfort continues. Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water.

Get medical attention if any discomfort continues. Eye contact Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly

wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media Extinguishing media This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials. 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Special Fire Fighting Procedures Avoid breathing fire vapours. NOTE! Use air-supplied respirators to protect against gases\fumes.

SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet. 6.2. Environmental precautions Do not discharge into drains, water courses or onto the ground. 6.3. Methods and material for containment and cleaning up Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean

spillage area. Do not contaminate water sources or sewer. 6.4. Reference to other sections

SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

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Avoid spilling, skin and eye contact. 7.2. Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container.

Storage Class Chemical storage. 7.3. Specific end use(s)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Name STD TWA - 8 Hrs STEL - 15 Min Notes

2-METHOXY-1-METHYLETHYL ACETATE WEL 50 ppm 274 mg/m3 100 ppm 548 mg/m3 Sk

DI-ISOBUTYL KETONE OES 25 ppm 148 mg/m3

ETHYLBENZENE OES 100 441 125 552 ppm(Sk) mg/m3(Sk) ppm(Sk) mg/m3(Sk)

Solvent naphtha(petroleum), light aromatic,<0.1% OES 600 mg/m3 benzene

XYLENE OES 50 ppm(Sk) 220 100 441

mg/m3(Sk) ppm(Sk) mg/m3(Sk)

WEL = Workplace Exposure Limit. Sk = Can be absorbed through skin. Ingredient Comments WEL = Workplace Exposure Limits

8.2. Exposure controls

Protective equipment

Process conditions

Provide eyewash station.

Engineering measures Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours.

Respiratory equipment No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air

contamination exists. Hand protection Use suitable protective gloves if risk of skin contact.

Eye protection If risk of splashing, wear safety goggles or face shield.

Other Protection Wear appropriate clothing to prevent any possibility of skin

contact. Hygiene measures DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly

remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or

smoke.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance Liquid Colour Colourless to pale yellow. Odour Slight odour. Solubility Immiscible with water

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Floor Protector PLUS+ - Resin Initial boiling point and boiling range >200C Relative density 1.9 Flash point >60C

9.2. Other information

Volatile Organic Compound (VOC) System: EU limit for this product (cat A/j): 500g/l (2010). This product contains < 120g/l VOC.

SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity 10.2. Chemical stability Stable under normal temperature conditions. 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Avoid excessive heat for prolonged periods of time. 10.5. Incompatible materials 10.6. Hazardous decomposition products Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2).

SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects

Toxicological information No data recorded. General information This product has low toxicity. Only large volumes may have adverse impact on human health. Inhalation Irritating to respiratory system. Ingestion May cause discomfort if swallowed. Skin contact May cause sensitisation by skin contact. Irritating to skin. Eye contact Irritating to eyes.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 12.1. Toxicity

12.2. Persistence and degradability Degradability The product is not readily biodegradable. 12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

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SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,

ADR/RID). Road Transport Notes Not Classified. Rail Transport Notes Not classified. Sea Transport Notes Not classified. Air Transport Notes Not classified. 14.1. UN number 14.2. UN proper shipping name 14.3. Transport hazard class(es) Transport Labels

No transport warning sign required. 14.4. Packing group 14.5. Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No.

14.6. Special precautions for user 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Approved Code Of Practice Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for

Supply. Guidance Notes Workplace Exposure Limits EH40. CHIP for everyone HSG(108). 15.2. Chemical Safety Assessment

SECTION 16: OTHER INFORMATION Revision Date 03/06/2015 Revision 1 Supersedes date N/A

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Floor Protector PLUS+ - Resin Risk Phrases In Full

R10 Flammable. R20/21 Harmful by inhalation and in contact with skin. R20 Harmful by inhalation. R22 Harmful if swallowed. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R11 Highly flammable R37 Irritating to respiratory system. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R66 Repeated exposure may cause skin dryness or cracking. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. Hazard Statements In Full

H315 Causes skin irritation. H226 Flammable liquid and vapour. H332 Harmful if inhaled. H302 Harmful if swallowed. H312 Harmful in contact with skin. H412 Harmful to aquatic life with long lasting effects. H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H317 May cause an allergic skin reaction. H336 May cause drowsiness or dizziness. H335 May cause respiratory irritation. EUH066 Repeated exposure may cause skin dryness or cracking. H411 Toxic to aquatic life with long lasting effects.

Disclaimer

This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in

any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty

guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such

information for his own particular use.

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Version 1, Dated 11/08/2015

SAFETY DATA SHEET

Floor Protector PLUS+ - Curing Agent

According to Regulation (EU) No 453/2010 According to Regulation (EC) No 1907/2006

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1. Product identifier Product name Floor Protector PLUS+ - Curing Agent 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Supplier Eli-Chem Resins UK Ltd

Astra House The Common Guildford Road Cranleigh, Surrey GU6 8RZ +44 (0)1483 2666 36 or 37 Fax: +44 (0)1483 428850 [email protected]

1.4. Emergency telephone number +44 (0)1483 2666 36 or 37 Office Hours Only

SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Xn;R20. Xi;R37. R43. 2.2. Label elements Contains Labelling

Risk Phrases

Safety Phrases 2.3. Other hazards

Aliphatic polyisocyanate 28182-81-2

Harmful

R20 Harmful by inhalation. R37 Irritating to respiratory system. R43 May cause sensitisation by skin contact.

S24 Avoid contact with skin. S37 Wear suitable gloves. S51 Use only in well-ventilated areas. S60 This material and its container must be disposed of as hazardous waste. P4 Contains isocyanates. See information supplied by the manufacturer.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixtures

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Aliphatic polyisocyanate 28182-81-2 60-100%

CAS-No.: 28182-81-2 EC No.:


Acute Tox. 4 - H332 Xn;R20.

Skin Sens. 1 - H317 Xi;R37.

STOT SE 3 - H335 R43.

HEXAMETHYLENE-DI-ISOCYANATE < 1%

CAS-No.: 822-06-0 EC No.: 212-485-8


Acute Tox. 3 - H331 T;R23

Skin Irrit. 2 - H315 R42/43

Eye Irrit. 2 - H319 Xi;R36/37/38

Resp. Sens. 1 - H334

Skin Sens. 1 - H317

STOT SE 3 - H335 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: FIRST AID MEASURES

4.1. Description of first aid measures Inhalation Move the exposed person to fresh air at once. Get medical attention. Provide rest, warmth and fresh air. When breathing is difficult,

properly trained personnel may assist affected person by administering oxygen. Ingestion DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Remove victim immediately

from source of exposure. Get medical attention immediately! Provide rest, warmth and fresh air. Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water.

Get medical attention promptly if symptoms occur after washing. Eye contact Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly

wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed

SECTION 5: FIREFIGHTING MEASURES

5.1. Extinguishing media Extinguishing media Use fire-extinguishing media appropriate for surrounding materials. 5.2. Special hazards arising from the substance or

mixture 5.3. Advice for firefighters

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up

Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Do not contaminate water

sources or sewer. 6.4. Reference to other sections

2 / 5


SECTION 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above

accepted level. 7.2. Conditions for safe storage, including any incompatibilities

Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. 7.3. Specific end use(s)

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Name STD TWA - 8 Hrs STEL - 15 Min Notes

Aliphatic polyisocyanate 28182-81-2 0.02 mg/m3 0.07 mg/m3

HEXAMETHYLENE-DI-ISOCYANATE MEL 0.02 0.07 mg/m3(Sen) mg/m3(Sen)

8.2. Exposure controls

Protective equipment

Engineering measures Provide adequate general and local exhaust ventilation.

Respiratory equipment No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational

exposure limit. Hand protection Use protective gloves.

Eye protection Wear approved safety goggles.

Other Protection Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact.

Hygiene measures DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly

remove any clothing that becomes contaminated. Wash promptly with soap & water if skin becomes contaminated. Use appropriate skin

cream to prevent drying of skin. When using do not eat, drink or smoke.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

9.2. Other information

Volatile Organic Compound (VOC) System: EU limit for this product (cat A/j): 500g/l (2010). This product contains < 120g/l VOC.

SECTION 10: STABILITY AND REACTIVITY

10.1. Reactivity

10.2. Chemical stability

Stable under normal temperature conditions. 10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

Avoid contact with acids and oxidising substances.

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10.5. Incompatible materials 10.6. Hazardous decomposition products Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).

SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Inhalation Harmful by inhalation. May cause irritation to the respiratory system. Ingestion Harmful if swallowed. Skin contact Harmful in contact with skin. Irritating to skin. Eye contact Irritating to eyes. Target Organs Skin Eyes Respiratory system, lungs

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity No negative effects on the aquatic environment are known. 12.1. Toxicity

12.2. Persistence and degradability

12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB

assessment 12.6. Other adverse effects

SECTION 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods Dispose of waste and residues in accordance with local authority requirements.

SECTION 14: TRANSPORT INFORMATION General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,

ADR/RID). Road Transport Notes Not Classified Rail Transport Notes Not classified. Sea Transport Notes Not classified. Air Transport Notes Not classified. 14.1. UN number 14.2. UN proper shipping name 14.3. Transport hazard class(es)

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Transport Labels No transport warning sign required.

14.4. Packing group 14.5. Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No.

14.6. Special precautions for user 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code

SECTION 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716).

Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply.

Guidance Notes Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyone HSG(108). 15.2. Chemical Safety Assessment

SECTION 16: OTHER INFORMATION Revision Date 03/06/2015 Revision 1 Supersedes date N/A Risk Phrases In Full

R20 Harmful by inhalation. R36/37/38 Irritating to eyes, respiratory system and skin. R37 Irritating to respiratory system. R42/43 May cause sensitisation by inhalation and skin contact. R43 May cause sensitisation by skin contact. R23 Toxic by inhalation. Hazard Statements In Full

H319 Causes serious eye irritation. H315 Causes skin irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. H331 Toxic if inhaled.

Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such

information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its

accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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safety data sheet floor protector plus+ - resin

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