safe handling and use - forane€¦ · give water to drink. get medical attention immediately....

SAFE HANDLING AND USE

CONTENTS

SECTION TOPIC PAGE

I About Arkema and Transcend™ 3

II Transcend™ additive as a Pure Component 4- 12

A. Product Identification and Safety Data 4

1. Safety Data 4

2. Product Specifications 5

3. Material Compatibility Tables 6-7

B. General Health and Safety Overview 8

1. Worker Protection and First Aid 8

2. Fire Prevention 9

C. Worker Practices/Handling Transcend™ additive 10

1. Storage 10

2. Spills and Disposal 11

3. Transportation/Deliveries and Packaging 11-12

III Customer Questionnaire 13

IV Bulk Delivery Instruction Form 14

V Safety Checklist 15

Fluorochemicals Foams, Solvents and Aerosols 2000 Market Street Philadelphia, PA 19103 Phone: 800-343-7940 • Fax: 215-419-7199 www.Transcendintothefuture.com

I. ABOUT ARKEMA AND TRANSCEND™

ARKEMA CORPORATE PROFILE

Arkema was launched on October 1,2004, as a result of the reorganizationof the chemicals business of Total, the fourth-largest oil and gas producerin the world and a world-class makerof chemicals.

Arkema has tremendous potential and counts on the experience andexpertise of its 18,600 employeesworldwide (2,600 in North America) to create a company of innovation,growth and performance.

With €5.2 billion ($6 billion) in salesworldwide (2004), 90 industrial sitesin more than 40 countries, and sixresearch and development centers,Arkema, formerly Atofina, is com-posed of three balanced business segments: Vinyl Products, IndustrialChemicals, and Performance Products.

With its internationally recognizedbrands, Arkema holds leadershippositions in its principal markets, with wide-ranging research expertise,a strong industrial base, and competitive teams. It aims to furtherits activities by pursuing its policy ofongoing improvement in safety andenvironmental protection, by puttingcustomers first, and by promotingindustrial reliability and enhancing itscompetitiveness to be among the bestin the industry.

Arkema is based in Paris, France. ItsNorth American business, Arkema Inc.,is based in Philadelphia, Pennsylvania.

www.arkemagroup.comwww.Arkema-Inc.com

TRANSCEND™ ADDITIVE TECHNOLOGY

Transcend™ additive is a specially formulated additive, a liquid at room temperature, which can be used to enhance the performance ofpolyurethane and polyisocyanuraterigid foams. The application ofTranscend™ additive technology,patented by Arkema Inc., has beenproven to reduce flame spread andsmoke generation in hydrocarbon and HFC (hydrofluorocarbon) blownurethane foams, as well as improvepolyol formulation processing by lowering viscosity and reducing vapor pressure.

Arkema Inc. is concerned about thehealth and safety of its customers and employees who use our products.Our goal, as a company that is committed to Responsible Care®

principles, is to ensure that we offerour customers the necessary information to safely use and disposeof our products. This brochure is apractical reference guide for the safeuse and handling of the Transcend™

additive.

This technical guidance manual is for general informational purposesonly. As every situation in which theTranscend™ additive technology can be used is unique, one shouldconsult qualified technical and engineering personnel to evaluateyour specific situation and answerspecific questions, which might proveunique to your application.

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This document and its references are intended for use in the United States. Regulatory references in

this brochure are intended to comply with the U.S. regulatory agencies.

Transcend™ is a trademark belonging to Arkema Inc.

Material Safety Data Sheets (MSDS)for the Transcend™ additive and anyspecific components used in creatingblends containing the Transcend™

additive should be consulted for additional health, safety, and environmental information.

Arkema Inc. disclaims all warranties,either expressed or implied, assumesno responsibility for the accuracy orcompleteness of the data containedherein, and will not be liable for anypersonal injury, property damage,environmental harm or legal noncompliance that may result fromreliance upon this document or yourmanagement of Transcend™ additivetechnology.

The Transcend™ additive, chemicalname trans-1,2-dichloroethylene, is aliquid at room temperature (b.p. 48°C)and is chemically stable under normaland anticipated storage and handlingconditions. The primary hazard fromthis liquid is flammability. TheTranscend™ additive is classified by the DOT (Department ofTransportation) as a Hazard Class 3,PG II flammable liquid.

II. PURE TRANSCEND™ ADDITIVE TECHNOLOGY(TRANS-1,2-DICHLOROETHYLENE)

A. PRODUCT IDENTIFICATION AND SAFETY DATA

1. SAFETY DATA

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CAS # 156-60-5

Molecular Formula C2H2Cl2

Physical Form Clear liquid

Molecular Weight, g/mol 96.94

Flash Point, °C - 12

Flammability Limits, % 6.7 – 18

Boiling Point, °C 48

Specific Gravity 1.256

Vapor Pressure 400 mm Hg @ 87°F (188.6°C)

Exposure Limits ACGIH TWA 200 ppm


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Customer Service: (800) 245-5858 Version May 31, 2005

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2. PRODUCT SPECIFICATIONS (TRANSCEND™ ADDITIVE)

Specifications Minimum Maximum

trans-1,2-dichloroethylene, % weight 99.7 100

cis-1,2-dichloroethylene, % weight 0 0.3

Other hydrochlorocarbons, % weight 0 0.1

Typical Properties

Specific Gravity 1.2565

Vapor Pressure 400 mm Hg @ 87°F

Flash Point, °C - 12

Color Clear Liquid (Visual)

3. MATERIAL COMPATIBILITY TABLES

Transcend™ additive (trans-1,2-dichloroethylene)Table 1: Material Compatibility at Room Temperature – % Weight Change

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Material Compatibility (% Weight change)

PLASTICS 5 min 24 hours 100 hours

ABS (polyacrylonitrile butadiene styrene) Attack* Attack* Attack*

PVC (polyvinyl chloride) 1.2 34.5 59.5

PET (polyethylene terephthalate) 0.1 1.0 1.1

HDPE (high density polyethylene) 0.2 6.2 10.8

LDPE (low density polyethylene) 1.0 25.3 29.0

HIPS (high impact polystyrene) Attack* Attack* Attack*

PP (polypropylene) 0.6 20.9 25.0

Nylon 66 (polyamide 6.6) 0.3 0.3 -0.1

PC (polycarbonate) 4.6 Attack* Attack*

PVDF (polyvinylidene fluoride) 0.0 0.1 0.2

ELASTOMERS 5 min 24 hours 100 hours

SBR (styrene butadiene) 10.7 132.3 138.5

EPDM 11.4 99.8 92.9

Neoprene (polychloroprene) 11.2 124.4 129.6

Hypalon 11.5 158.0 157.0

Silicone 16.9 205.7 208.6

Butyl Rubber (polyisobutene isoprene) 13.3 119.0 118.7

Natural Rubber 36.1 587.6 613.1

Viton® 0.1 3.3 6.4

Epichlorohydrin homopolymer 11.6 183.1 191.3

*Causes significant degradation

Viton® is a registered trademark belonging to E.I. Du Pont de Nemours & Co.


Table 2: Material Compatibility at Room Temperature – Linear Change(Sample Dimension: Length x Width x Thickness – 2.5” x 0.5” x 0.25”)

Material Compatibility (linear swell % change)

PLASTICS 5 min 24 hours 100 hours

ABS (polyacrylonitrile butadiene styrene) Attack* Attack* Attack*

PVC (polyvinyl chloride) -0.3 11.3 16.7

PET (polyethylene terephthalate) 0.0 -0.2 0.5

HDPE (high density polyethylene) 0.1 1.6 2.7

LDPE (low density polyethylene) 0.7 6.1 7.1

HIPS (high impact polystyrene) Attack* Attack* Attack*

PP (polypropylene) -0.1 4.3 5.7

Nylon 66 (polyamide 6.6) 0.1 0.0 2.0

PC (polycarbonate) 1.6 Attack* Attack*

PVDF (polyvinylidene fluoride) 0.0 0.1 0.0

ELASTOMERS 5 min 24 hours 100 hours

SBR (styrene butadiene) 2.5 33.7 33.1

EPDM 2.6 20.9 19.8

Neoprene (polychloroprene) 2.8 30.2 29.7

Hypalon 3.8 36.9 36.8

Silicone 4.8 41.7 43.3

Butyl Rubber (polyisobutene isoprene) 2.5 23.2 23.1

Natural Rubber 8.9 71.6 77.3

Viton® 0.0 1.1 2.9

Epichlorohydrin homopolymer 3.6 41.1 44.4

*Causes significant degradation.



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1. WORKER PROTECTION AND FIRST AID

SKINExposure of skin to the Transcend™

additive can cause skin irritation. Skin contact should be limited by wearing appropriate chemicalresistant protective clothing andchemical resistant gloves, such asViton® synthetic rubber or neoprene. A glove manufacturer representativeshould be consulted for actual gloveselection, as it depends upon workingrequirements and conditions.

If on skin: Immediately flush withplenty of water. Remove contaminatedclothing and shoes. Get medical atten-tion. Wash clothing before reuse.Destroy contaminated shoes.

EYEThe Transcend™ additive is moderatelyto severely irritating to eyes. Wearchemical goggles and have eye-flush-ing equipment available to preventaccidental contact with the eyes.

If in eyes: Immediately flush withplenty of water for at least 15 minutes.Get medical attention immediately.

RESPIRATORY PROTECTIONMild to severe lung injury may occur if the Transcend™ additive is drawninto the lungs (aspirated) during swallowing or during vomiting after

swallowing. Avoid breathing vapor ormist. When airborne exposure limitsare exceeded, use NIOSH approvedrespiratory protection equipmentappropriate to the material and/or its components. Consult respiratormanufacturer to determine the appropriate type of equipment for thegiven application. Observe respiratoruse limitations specified by NIOSH orthe manufacturer. For emergency andother conditions where exposure limitmay be significantly exceeded, use anapproved full-face positive-pressure,self-contained breathing apparatus or positive-pressure air line with auxiliary self-contained air supply.Respiratory protection programs mustcomply with 29 CFR § 1910.134.

If inhaled: Remove to fresh air. If notbreathing, give artificial respiration. If breathing is difficult, give oxygen.Get medical attention.

INGESTION:Based on acute toxicology studies,the Transcend™ additive is consideredto be slightly toxic if swallowed.

If swallowed: Do NOT induce vomiting.Give water to drink. Get medical attention immediately. NEVER GIVEANYTHING BY MOUTH TO AN UNCON-SCIOUS PERSON.

B. GENERAL HEALTH AND SAFETY OVERVIEW

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8 Transcend™ additive has a very low flash point (-12°C).


For medical assistance:Contact the Rocky MountainPoison Control Center at (866) 767-5089 (303) 623-5716

For chemical emergencies:Contact Chemtrec: (800) 424-9300 (24hrs) or (703) 527-3887

Exposure Limits

ACGIH TWA 200 ppm

OSHA TWA PEL 200 ppm (790 mg/m3)

Odor threshold reported as 0.08 –17 ppm

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2. FIRE PREVENTION

Do not use product around openflames or sparking equipment such as switches and motors. Prohibitsmoking and lighters in any areawhere the product is stored, trans-ported, or used. Do not use electronicdevices (including but not limited tocellular phones, computers, calculatorsand pagers) in or around any opera-tion unless the devices are certifiedintrinsically safe by an approvednational testing agency and complywith the safety standards required by the National Fire ProtectionAssociation (NFPA) Code 70 NationalElectric Code, and/or local codes and regulations that may be in effect. All electrical equipment and fittingsmust comply with NFPA 70 and localfire prevention regulations for thisclass of product.

IN CASE OF FIRECool non-involved containers byflooding with large quantities of wateruntil well after the fire is out. Use awater spray for dissipating vapors.Wear MSHA/NIOSH/NFPA approvedself-contained breathing apparatus orequivalent and full NFPA-compliantprotective gear (Bunker gear).

Use an approved fire-fighting suppression system including BCrated dry chemical, CO2, or halonextinguishers. Do NOT spray waterdirectly on Transcend™ additive firesas product will float on water andcould re-ignite on the surface ofwater. Avoid inhaling vapors. Fightfires from a maximum distance or useunmanned hose holders or monitornozzles. If this is impossible, withdrawfrom the area and let the fire burn.Contain or treat all runoff materials.

1. STORAGE

The information in this section refersto bulk storage of pure Transcend™

Additive, and does not necessarilyapply to the bulk storage ofTranscend™ additive after it has beenblended with another blowing agent.Due to the specific nature and proper-ties of any blends containing theTranscend™ additive, bulk storage of a blend may need to be treated differently than the pure components.

The particular design of the bulk storage tank system depends on several factors such as expected consumption and location within theplant. Tanks shall be built, designedand constructed in accordance withapplicable codes and standards. Foratmospheric tanks, refer to API stan-dards such as API-650 or API-620 (lowpressure storage tanks). For pressurevessels refer to the ASME PressureVessel Code, Section VIII. Transcend™

additive is a flammable liquid, NFPA30 Flammable and Combustible Codesshall apply to the storage, handling,and use of this material. In addition,tanks must comply with all state andfederal permitting regulations and anylocal construction ordinances.

The design should take into accountthe highest pressure which couldarise from pressurized unloading andthe maximum operating temperature.

Secondary containment should be provided. The dike should bedesigned with minimum surface areain case of a liquid spill. Provisionsshould be made to prevent spilled liquid from entering the drainage.

All electrical equipment in the storagearea must conform to the requirementsof the appropriate area electrical classification based on the potentialfire or explosion hazards of the product. Proper grounding and bond-ing techniques should be used toavoid electrostatic ignition hazards.Never weld, grind, or use sources ofignition on a tank or one of its compo-nents unless it has been specificallyprepared for that activity.

Tanks and related equipment shouldbe periodically inspected for leaksand signs of damage. It should benoted that even an empty tank con-tains residual amounts of the productand should be handled carefully.

C. WORKER PRACTICES—HANDLING TRANSCEND™ ADDITIVE

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2. SPILLS AND DISPOSAL

In case of a spill or leak, flammabilityis the primary concern.

Eliminate all sources of ignition in the vicinity of a spill or releasedvapors. Isolate the area. Permit onlytrained personnel wearing full protec-tive clothing and equipment to enterthe spill area. Terminate the leakimmediately, if possible. Prevent entryinto sewers, basements or confinedareas; dike if needed.

Using non-sparking tools, collect thecontaminated soil, debris, clothing,etc., into a DOT-approved drum for disposal. Flush the spill area thoroughly with water and wash allcontaminated equipment. All flushingand wash water must be containedand prevented from entering a waterway. Ventilate the area to disperse vapors.

Consult a regulatory specialist todetermine appropriate state or localreporting requirements, for assistancein waste characterization and/or hazardous waste disposal and otherrequirements listed in pertinent environmental permits.

3. TRANSPORTATION/DELIVERIESAND PACKAGING

BULK TANK TRUCKS:Bulk quantities of Transcend™ additivewill be delivered using a tank truck.These trucks are designed for thedelivery of flammable liquids and are typically made of stainless steel.Often, trailers meeting MC-307 specifications are used. The use oftrailers with higher pressure ratings is permissible.

Arkema conducts pre-delivery surveysand site audits as a part of our com-mitment to Responsible Care®. It isimportant to note in the pre-deliverysurvey any special driver instructionsor customer special requirements, andto identify delivery equipment lengthof the hoses required for the delivery.

DRUMS:Pure Transcend™ additive can also be delivered in 55-gallon steel drums.These drums are filled at the plantwithin specification and sealed to prevent contamination or evaporation.All drums will be properly labeled with product specific information and safety precautions. Carefully readand understand all the informationand warnings on the label prior tousing the product. Drums will containapproximately 540 lbs of product.

The 55-gallon drums are top unloaderswith two bungs, one with a 2 inchopening and the other with a 3/4 inchopening placed on opposite sides on the top. They are coated internallywith a phosphatized anti-rust liner.Drums are DOT approved for transportation and storage and constructed of, at a minimum, 20-gauge carbon steel.

Drums should be handled carefully in away that avoids deforming, puncturingor damaging them. They should bestored in a cool, dry place, preferablyindoors, in a well ventilated area andshould be stored sitting on one end.

Avoid stacking drums directly on top of each other. If drums need to be stored outside, they should be covered with plastic sheeting to avoidwater accumulation on the heads thatwould lead to rust. Avoid storingdrums under direct sunlight for longperiods of time.

Do not store drums of Transcend™

additive near flames, sparks, highintensity lights or very hot surfacessince its vapors are flammable andcould ignite. Do not use cutting orwelding torches on any drum whichcontains any amount of product, evenif it is empty, since residual vaporscould cause an explosion.

Drums should be disposed of appropriately. If drums are notcleaned after use, they should be handled as hazardous materials. If they are properly washed and disabled to prevent refilling, they can be disposed of as waste steel.

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Department of Transportation Transport Information

Product: Transcend™ additive

DOT Name: trans-1,2-Dichloroethylene

DOT Hazard Class: 3

UN Number: UN 1150

DOT Packaging Group: PG II

RQ: Reportable Quantity 1000 lbs/454 kg (1,2-trans-Dichloroethylene)

III. ARKEMA INC. TRANSCEND™ CUSTOMER QUESTIONNAIREUTILIZE THIS FORM WHEN PREPARING FOR TRANSCENDTM ADDITIVE DELIVERIES FROM ARKEMA INC.

Ship To: Customer Name Phone

Address

State Zip

Product Name (Please Circle): 1. Trans-1,2-dichloroethylene or 2. Trans-1,2-dichloroethylene blend

Did you receive and review a copy of Arkema Inc.’s MSDS for Trans-1, 2-dichloroethylene?

Do you have any comments, concerns, or questions about information contained on the MSDS?

Did you receive and review Arkema Inc.’s Safe Handling Brochure for Trans-1, 2-dichloroethylene?

Have all your employees who will be working with or in contact with Trans-1, 2-dichloroethylene been provided with the MSDS and Product Storage and Safe Handling Information?

If so, do they have any comments, concerns, or questions regarding this information?

Please list any comments:

Please review Arkema Inc.’s, Section III: Safety Checklist within the Transcend Safety Brochure prior to drum usage.

Name Date

Title

Signature Zip

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IV: ARKEMA INC. BULK DELIVERY INSTRUCTION FORMUTILIZE THIS FORM WHEN PREPARING FOR TRANSCENDTM ADDITIVE DELIVERIESFROM ARKEMA INC.

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Ship To: Customer Name Phone

Address

State Zip

Product Name: trans-1,2-dichloroethylene

Delivery Instructions: Special instructions

Date, time, etc.

Equipment: How many feet of hose needed:Electrical and Hose Connections Electrical and Hose Connections

Electrical Adapters

Hose Connections

Tank Capacity

Tank Percent Gauge or Sight Glass

Customer Contact: Company

Name Phone

Analysis and Arkema Inc. Weights to: Customer contact or chemist contact

Local Weights: Certified local scale weights

Directions to scale: Certified local scale directions

Directions to Plant: General directions off local major highways

Miscellaneous: Do you have a liquid and vent unloading line?

Do you have an explosion proof electrical receptacle?

Do you have dry nitrogen or a pump to unload our tank truck?

Is your storage tank grounded?

Any information to assistin bulk tank truck delivery

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V: SAFETY CHECKLIST

n Primary hazard of pure Transcend™

additive is flammability.

n Do not smoke near product.

n Consider electrical classification ofarea. Consult NFPA 70 for details.

n During transfer operations adequatefire protection must be in place.

n Pressure tanks built to ASME codeare preferred over atmospherictanks.

n Relief valve sizing should be to NFPA 30 standards and routed to an approved vapor recovery or flare system.

n Do not deform puncture or damagedrums in any way.

n Avoid storing drums under directsunlight for long periods of time.

n Do not store drums near flames,sparks or high intensity lights sinceflammable vapors could ignite.

n If possible, drums should be storedinside to avoid exposure to moisture,which could lead to rust.

n Do not cut or weld on or near drumssince residual vapors could cause anexplosion.

n Properly wash and disable drumsafter use and dispose of them assteel waste.

EMERGENCY PHONE NUMBERS:CHEMTREC: (800) 424-9300 (24 hrs)or (703) 527-3887

Medical: Rocky Mountain PoisonControl Center (866) 767-5089 (24 hrs)

Fluorochemicals Foams, Solvents and Aerosols 2000 Market Street Philadelphia, PA 19103 Phone: 800-343-7940 • Fax: 215-419-7199 www.Transcendintothefuture.com

BEFORE HANDLING THIS MATERIAL, READ AND UNDERSTAND THE MSDS (MATERIAL SAFETY DATA SHEET) FOR ADDITIONAL INFORMATION ON PERSONAL PROTECTIVE

EQUIPMENT AND FOR SAFETY, HEALTH AND ENVIRONMENTAL INFORMATION.

The statements, technical information and recommendations contained herein are believed to be accurate as of the date hereof. Since the conditions and methods of use of

the product and of the information referred to herein are beyond our control, Arkema expressly disclaims any and all liability as to any results obtained or arising from any

use of the product or reliance on such information; NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY,

EXPRESS OR IMPLIED, IS MADE CONCERNING THE GOODS DESCRIBED OR THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the

specific product designated and may not be applicable when such product is used in combination with other materials or in any process. The user should thoroughly test any

application before commercialization. Nothing contained herein constitutes a license to practice under any patent and it should not be construed as an inducement to infringe

any patient and the user is advised to take appropriate steps to be sure that any proposed use of the product will not result in patent infringement.


IN CASE OF EMERGENCYCall CHEMTREC at (800) 424-9300

FOR MEDICAL ASSISTANCECall Rocky Mountain Poison Control Center at (303) 623-5716

safe handling and use - forane€¦ · give water to drink. get medical attention immediately....

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