SCOPUS 資料庫檢索之經驗分享

分享 2012 年的博士論文 - 『光學生化感測器之分子模版選擇性探討與藍光有機材料開發應用』的寫作經驗，在關鍵字所搜尋到的大量文章中，如何利用 Scopus 的分析工具幫助找出相關的研究主題文章，且如何利用Scopus 裡的分析數據整理成引用地圖，幫助了解在其研究領域中的發展趨勢與文章之貢獻度與受歡迎程度，最後選擇適合的期刊讓論文如期的發表在Tetrahedron 化學期刊中，得以順利的畢業。

　使用者經驗分享　 徐崇益博士 國立成功大學化學系所　 　

靜宜大學蓋夏圖書館433 台中市沙鹿區中棲路 200 號04 26328001

逢甲大學407 台中市西屯區文華路 100 號 04 2451 7250

國立成功大學701 台灣台南市東區大學路 1 號 06 275 7575 義守大學

840 高雄市大樹區學城路一段 1 號 07 657 7711

國立台灣科技大學106 台灣台北市大安區基隆路四段 43 號 02 2737 6195

長庚大學333 桃園縣龜山鄉文化一路 259 號03 211-8800

SCOPUS

STUDIED THEME ( 研究主題 )

Studies on the Selectivity of Molecular Imprinted Polymer for Optical Modulated Biosensing System/Development and Application of Organic Blue Emitter Materials. ( 光學生化感測器之分子模版選擇性探討與藍光有機材料開發應用 )

Keywords ； MIP 「分子模版」、 OLED 「有機發光二極體」

2

BLUE EMITTER MATERIAL

3

CONCEPTION-OLED

Synthesize material

Blue emitter material focus

preparation

Vertical quartz-tube evaporation device

purification

Excited deviceSingle-crystal XRD

4

1H-NMR (300MHz, CDCl3, ppm)13C-NMR (75MHz, CDCl3, ppm)2D-COSY

PR650 spectra scan photometerHP4156 programmable voltage–current source meter

JEOL JMS-700,  FAB+, m/zElementar vario EL Ⅲ

Spectrum RX1 FTIR spectrometerNTEGRA Spectra - AFM / Confocal Raman Imaging spectrometer

Differential scanning calorimetry (PerkinElmer DSC−7)(DSC, Perkin-Elmer Pyris Diamond)

Thermo-gravimetric analysis (TGA, Perkin-Elmer Pyris 1)(PYRIS Diamond TG/DTA-10)

Photoelectron spectroscopy(UPS, Riken Keiki AC-2)Cyclic voltammetry measurementsCV-CH Instruments-627C

Density functional theory (DFT) calculations at the B3LYP/6-31G* using Gaussian03)

Spontaneous emission transitionprobability formulaNi (t) = Ni0 exp(-Ait)

X-ray powder diffraction(XRD, Shimadzu XRD-700)Single-crystal X-rayBruker APEXII CCD diffractometer

UV–Visible spectrophotometer(Hitachi−U3010) Luminescence spectrophotometer(Hitachi−F4500)

Organic Light-

Emitting Device

NMRMass/

Element

Optical

Lifetime

Physical

Orbital

Crystal

Surface

OLED Analyzer Map

5

SUMMARIZE OLED

(1)

(2)

Update ︰ 11,324 on 0613/2013 11,533 on 0902/2013 11,638 on 10102013

(3)

6

ANALYZE RESULTS - OLED

學校名稱

國家別名

來源期刊

作者貢獻

國別指引

領域趨勢7

AUTHOR NAME : KEY WORD-OLED/TAIWAN

8

SUB-KEYWORDS FOR OLED

Electrode Hole transfer layer Electron transfer layer

Emitter layer

Phosphorescence Purity 9

Kim, Y. 2004 Park, Y. H. 2006Samal, G. S. 2009 Kim, K. S. 2009Shin, M. G. 2012 Hsu, C. Y. 2012

Rajeswaran, M. 2003Lee, M. T. 2005Jeon, S. O. 2008Kim, K. S. 2008Jeon, Y. M. 2009

Blue (802/1783)

Dibenzothiophene (28/76)

Red/Green(799/1187)

Pyrene (18/158)suzuki coupling(29/315)Molecular charge transfer(53/1135)donor-acceptor(46/381)single crystal(44/1086)monodisperse(18/190)

Blue (375/1540

)

Carbazole (253/642)

Red/Green (402/1354)

~2006(2154)

2007(545)

2008(387)

2009(612)

2010(488)

2011(348)

2012(366)

2013(364)

Total5344

OLED

Kirimura, K. 2002, Liu, H. 2008, Yang, F., 2008, Li, Y. Y. 2009, Xia, C. Y. 2009, Grisorio, R.2010, Nayak, P. K. 2010, Zafra, J. L. 2011, Hsu, C. Y. 2012

Chen, J. P. 2003, Lee, T. H. 2005, Seo, J. H. 2005, Guan, M. 2006, Kawakami, A. 2008, Tsuzuki, T. 2009, Cho, I. 2012, Li, Y.2012, Hsu, C. Y. 2012

11638(640)(948)(1560)(1509)(1325)(1376)(1204)(3072)

OLED MAP

OLED(5344/1163

8)

Purity(526/683) Electron

transfer layer

(1253/1744)

Emitter layer

(1038/2315)

Electrode(3381/2600

)

Phos-phorescen

ce(458/2139)

Hole transfer

layer(1265/1453

)

22.7%↑

23.4%↑

21.1%↑

22.1%↑

25.8%↑

16.9%↑

17.5%↑

Update ︰ 1010/2013

10

THERMAL EVAPORATOR PURIFICATION SYSTEM

Heater

Chamber

SubstratePressure gauge

Gas outletView-window

Quartz-tube

Sample holder

11

CRYSTAL STRUCTURE (THIOPHENE-X)

S

OO

I

I

Donor-B(OH)2

O

ONDonor : , , ,

palladium-catalyzed

Suzuki coupling

S

OO

D

D

12

  DBTO-MP DBTO-MF DBTO-PP

Along a-axis

Along b-axis

Along c-axis

  DBTO-MP DBTO-MF DBTO-PP

Inter-molecular distance

3D profile conformation

intermolecular charge transfer DBTO-MP DBTO-MF DBTO-PP

along a-axis electron conjugation good excellent poor

along b-axis

sequence of Intermolecular arrangement

excellent excellent poor

intermolecular distance (Å) 3.725 3.329 3.396

π-π stacking interactions negligible

little least

along c-axis

symmetry of Intermolecular conformation

good goodexcellen

t

3D profile conformation z-shape spiral bricksuperimposition of intermolecular interactions

poor excellent good

intramolecular charge transferDBTO-

MPDBTO-

MFDBTO-

PP  dihedral angles 28o 30o 33o

quantum efficiency donor and accepter effect more average averagequantum yield (%) 49 82 17

SUBMIT PAPER TO TETRAHEDRON

(1)

(2) (3)

(4)

(5)

16

TITLE: "FLUORESCENT OLIGOMERS OF DIBENZOTHIOPHENE S,S-DIOXIDE DERIVATIVES: THE INTERPLAY OF CRYSTAL CONFORMATIONS AND PHOTOPHYSICAL PROPERTIES" 01032012 Submitted original paper to Chemistry of Materials 01202012 Submitted original paper to Organic Electronics 02022012 Submitted original paper to Journal of Materials Chemistry 02162012 Submitted original paper to Tetrahedron 02182012 Ref. TET-D-12-00309 The interplay of crystal conformation and photophysical properties in dibenzothiophene-S,S-dioxide fluorescent

oligomers Dear Dr. Whang, Thank you for submitting your work to Tetrahedron. Before ……… We regret to inform you that your manuscript does not meet the Journal's required standard.

Please make changes/corrections as detailed in the comments below…….. Yours sincerely, D. Jones; Administrative Support Agent [24-Feb-11], Tetrahedron …………………………….. 04232012 Ms. Ref. No.: TET-D-12-00393R2 Title: Fluorescent Oligomers of Dibenzothiophene S,S-dioxide Derivatives: The Interplay of Crystal Conformations and

Photophysical Properties Tetrahedron Dear Dr. Thou-Jen Whang, I am pleased to confirm that your paper "Fluorescent Oligomers of

Dibenzothiophene S,S-dioxide Derivatives: The Interplay of Crystal Conformations and Photophysical Properties" has been accepted for publication in Tetrahedron and sent to the publisher. You should be receiving galley proofs within several weeks.

Thank you for submitting your work to this journal.; With kind regards, Kiyoshi Tomioka, PhD, Editor, Tetrahedron

17

MIP VS OLED

18

CO-AUTHORS

19

聚焦跨研究領域其合作者之能量

FIRST AUTHOR- HSU C. Y.

20

CONCEPTION-MIP

Thermometric

calorimeter

Molecularly imprinted polymers

imitate

preparation

Functional monomer

Cross-linkers

titrated to

Protein (hydrophilic, hydrophobic etc.)

EVAL Ploy (vinyl alcohol-co-ethylene)

Fe3O4 (magnetite nanoparticles)

Amino acid (Tyrosine, Phenylalanine etc.)21

Molecularly

Imprinted

Polymer

ITC

FL

AFM

SQUIDBET

Raman

Particle

2277 Thermal Activity Monitor, Thermometric AB and Scitech Software AB, Sweden

Model Slover P47H-PRO, NT-MDT, Moscow, Russia

Luminescence spectrophotometer (Hitachi−F4500)

Particle sizer (90Plus,Brookhaven Instruments Co., NY)

NOVA 1000e (Quantachrome Instruments, FL),Brunauer Emmett Teller (Quantachrome Instruments, Florida)

MPMS XL-7 system (Quantum Design, San Diego, CA)

NTEGRA Spectra - AFM / Confocal Raman Imaging spectrometer

Minimize Energy command in the MM2 menu(from software of Chem3D)

MIP Analyzer Map

22

SUMMARIZE MIP

(1)

(2)

(3)

Update : 4,057on 1014/2013

23

ANALYZE RESULTS - MIP

學校名稱

國家別名

來源期刊

作者貢獻

國別指引

領域趨勢

24

SUB-KEYWORDS FOR MIP

Amino acid Isothermal titration Microcontract

Cross-linking

Magnetic nanoparticle Protein25

Seong, H. 2002 Lin, H. Y. 2006El Kirat, K. 2009 Li, L., A. 2009Gao, R. X. 2010 Kryscio, D. R. 2012

Lin, J. M. 1997Vidyasankar, S. 1997Peng, H. 2001Weber, A.. 2002Zhang, L. Y. 2002~2003Lakshmi, D. 2006Tang, S. W.2006Lin, Y. C. 2007Mirmohseni, A. 2008Casey, C. N. 2010

Lin, H. Y. 2006Hsu, C. Y. 2006Zhou, X. 2007Kan, X. W. 2009Su, W. X. 2009Lee, M. H. 2010Gao, R. X. 2011

~2006(96)

2007(17)

2008(24)

2009(21)

2010(20)

2011(17)

2012(15)

2013(11)

Total229

MIP

Lin, H. Y. 2006, Lee, M. H.. 2008~2010 (6), Li, L., 2009, Su, W. X. 2009, Qu, P. 2010, Khadro, B. 2011

Kirchner, R.2002, Weber, A. 2002Cliff, M. J. 2003, Weber, A. 2004Wollner, K. 2007, Gue, A. M. 2008Dvorakova, G. 2010

4057(521)(525)(432)(342)(355)(254)(268)(1274)

MIP MAP

Molecularly

Imprinted Polymer

(229/4057)

Cross-linking

monomers

(124/578) Amino acid

(116/1101)

Microcontact

(0/41)

Magnetic nanoparticles (5/363)

Isothermal

titration calorimet

ry(0/27)

Protein(94/1422)

Update ︰ 0902/2013 Update ： 10142013

26

MAIN AUTHOR OF STUDIED THE MIP (TAIWAN)

27

(1)

(2)

期許：吃得下飯、睡得著覺、笑得出來！

伙伴協助者：

　　 　徐　 崇　 益

現在進行 著； 1. 科普計畫執行與推動、規劃繕擬與申請 2. 產學計劃案籌備與規劃、協助廠商申請 SBIR 　 E-mail : hsuyihsuyi@gmail.com； Skype:

hsuyi888

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