restricted substances guidance - afirm · pdf filerestricted substances guidance apparel and...

Restricted Substances Guidance

Apparel and Footwear International RSL Management Group

1 Version 03

Legal Statement

The Apparel and Footwear International RSL Management (AFIRM) Group has created the following Restricted Substance Guidance to assist and guide supply -chain participants seeking to increase product quality and safety, or reduce their environmental impact, by limiting the use of certain substances (“AFIRM RSL Guidance”). The AFIRM RSL Guidance constitutes information from AFIRM only, and does not represent any individual AFIRM member. The AFIRM RSL Guidance is a review of all AFIRM brand RSLs, in place on March 1, 2014 . The AFIRM RSL Guidance creates a compilation of commonly defined pairs of "lowest limit" plus corresponding "most suitable test method" established by and prevalent in AFIRM member companies. Individual brand RSLs may differ in specific parameters. Some examples of uses for the AFIRM RSL Guidance, depending on the objectives of the user, include: 1. Providing a tool for vendors to establish chemical management knowledge and processes. 2. Building base compliance with AFIRM member chemical restrictions. 3. Providing a common base for testing products, which may be accepted by multiple AFIRM brands.

AFIRM member companies determine and communicate to their vendors their testing requirements and acceptance of test reports.

Note: This AFIRM RSL Guidance is not intended and does not establish any industry standard of care. The AFIRM RSL Guidance may not always provide the most appropriate approach for any individual company’s chemical management program. Many brands have implementation guidelines, and suppliers must follow those guidelines, where required. The AFIRM RSL Guidance does not constitute legal advice and is not a substitute for legal advice. There is no warranty, express or implied, as to the completeness or utility of the information contained in the AFIRM RSL Guidance, including, without limitation, that the information is current and error -free. AFIRM disclaims liability or any kind whatsoever resulting from any use of or reliance on the AFIRM RSL Guidance.

The Apparel and Footwear International RSL Management (AFIRM) Group has created the following Restricted Substance Guidance to assist and guide supply -chain participants seeking to increase product quality and safety, or reduce their environmental impact, by limiting the use of certain substances (“AFIRM RSL Guidance”). The AFIRM RSL Guidance constitutes information from AFIRM only, and does not represent any individual AFIRM member. The AFIRM RSL Guidance is a review of all AFIRM brand RSLs, in place on March 1, 2014 . The AFIRM RSL Guidance creates a compilation of commonly defined pairs of "lowest limit" plus corresponding "most suitable test method" established by and prevalent in AFIRM member companies. Individual brand RSLs may differ in specific parameters. Some examples of uses for the AFIRM RSL Guidance, depending on the objectives of the user, include: 1. Providing a tool for vendors to establish chemical management knowledge and processes. 2. Building base compliance with AFIRM member chemical restrictions. 3. Providing a common base for testing products, which may be accepted by multiple AFIRM brands.

AFIRM member companies determine and communicate to their vendors their testing requirements and acceptance of test reports.

Note: This AFIRM RSL Guidance is not intended and does not establish any industry standard of care. The AFIRM RSL Guidance may not always provide the most appropriate approach for any individual company’s chemical management program. Many brands have implementation guidelines, and suppliers must follow those guidelines, where required. The AFIRM RSL Guidance does not constitute legal advice and is not a substitute for legal advice. There is no warranty, express or implied, as to the completeness or utility of the information contained in the AFIRM RSL Guidance, including, without limitation, that the information is current and error -free. AFIRM disclaims liability or any kind whatsoever resulting from any use of or reliance on the AFIRM RSL Guidance.

2 Version 03

http://www.afirm-group.com/wp-content/uploads/2013/04/AFIRMSupplierToolkitFinalVietnamese.pdf

http://www.afirm-group.com/wp-content/uploads/2013/04/AFIRMSupplierToolkit.pdf1.) More information about MATERIAL DEFINITIONS and related TEST PARAMETERS can be found at

For enhanced usability, practical implementation and material relevance the Toolkit in it's translations

Vietnamese:

http://www.afirm-group.com/members/

http://www.afirm-group.com/wp-content/uploads/2013/04/AFIRMSupplierToolkitFINALChinese.pdf

Links and References

Policy Statement

The AFIRM RSL Guidance creates a compilation of commonly defined pairs of "lowest limit" plus coresponding

"most suitable test method" established by and prevalent in AFIRM member companies. Individual brand RSLs

may differ in specific parameters. This Guidance should leverage AFIRM's mission:

"To reduce the use and impact of harmful substances in the apparel and footwear supply chain"

by providing one single set of information for a maximum and in-depth implementation within the supply chain.

Important notice

The following links may provide additional important information, and are recommended for pro-active and regular

visits

2.) For additional restricted substances with possible relevance: http://echa.europa.eu/

3.) For an overview of basic legal chemical limits and country of origin: http://www.apparelandfootwear.org/

4.) For regulated VOC's mainly the EC 842/2006

5.) For regulated VOC's EC 1005/2009

or the AFIRM Member Brand RSL's

Chinese:

Candidate List of SVHC's: http://echa.europa.eu/de/candidate-list-table

3 Version 03

http://www.afirm-group.com/wp-content/uploads/2013/04/AFIRMSupplierToolkitFinalVietnamese.pdf

http://www.afirm-group.com/wp-content/uploads/2013/04/AFIRMSupplierToolkit.pdf

http://www.afirm-group.com/supplierrsltool.htm

http://www.afirm-group.com/members/

http://www.afirm-group.com/wp-content/uploads/2013/04/AFIRMSupplierToolkitFINALChinese.pdf

http://echa.europa.eu/

http://echa.europa.eu/

http://www.apparelandfootwear.org/

http://www.apparelandfootwear.org/

http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2006:161:0001:0011:EN:PDF




http://echa.europa.eu/candidate-list-table

Where Are the Risks?

In the apparel and footwear supply chain, there are certain types of fibers and materials that are more likely to contain restricted substances. Many brands require

testing of products prior to shipment to assure that the shipment does not contain articles not in compliance with their RSL (see Section 5 ofthe AFIRM Supplier

Toolkit for more information on testing, and see Appendix C of the AFIRM Supplier Toolkit for a model testing program if your customer does not have its own testing

program). The following matrix highlights the restricted substance risks associated with different fibers and materials.

http://www.afirm-group.com/toolkit/

4 Version 03

http://www.afirm-group.com/toolkit/

Version Modifications Page

3 DIN EN ISO 105-E04 has been updated to the 2013 version. 6,7

3Antimony (total): measuring method has been updated from EN ISO 11885 (2009)

to EN ISO 17294-26

3Arsenic (extractable): added DIN EN ISO 17072-1 as preparation method for

leather6

3 Cadmium (total): added EN 1122 as preparation method 6

3 Chromium extractable: leather requirement removed 6

3 Ortho-phenylphenol (o-PP): leather lowest limit changed from 50 ppm to 500 ppm 8

3PCP/TeCP/TCP/other chlorinated phenols: draft DIN EN ISO 17070:2012 has

been added8

3 Pesticides: BVL L 00.00-34:2010-09 has been added 8

3Azo Amines: AAB preparation and analysis has been updated from 64 LFGB B

82:02-9 to EN 14362-3:2012 for textiles and EN ISO 17234-2:2011 for leather9

3Formaldehyde: for leather the JIS L 1041-1983A has been dropped. For paper EN

1541 has been dropped.9

3Organotins: CEN/ISO 16179 replaces generic preparation and use of ISO 17353

for measuring9,10

3 Phthalates: EN 15777 added as measuring method for textiles 10

3SCCP’s/MCCP’s: draft ISO/DIS 18219:2012 replaces generic preparation and

measuring methods.10

3NP, OP, NPEO’s, OPEO’s: prEN ISO 18218-1: 2012 replaces generic preparation

and measuring methods11

3 DMFa: limit changed from 1 ppm to 1000 ppm 11

3DMFa: final draft CEN ISO/TS 16189 replaces generic preparation and measuring

methods11

3 DMF: ISO/TS 16186 replaces generic preparation and measuring methods 11

3 Acetophenone: limit changed from 75 ppm to 50 ppm 12

3 2-Phenyl-2 propanol: limit changed from 75 ppm to 50 ppm 12

Change Log

5 Version 03

Colour Coding

Substance/Material Lowest LimitSuitable Method

Sample Prep

Suitable Method

Measuring

Colour

Coding

Textile 5 ppm;

10 ppm for recycled PES

EN ISO 105-E04 (2013) EN ISO 17294-2

Leather 5 ppm EN ISO 105-E04 (2013) EN ISO 17294-2

Trim parts, metal parts, jewelry 5 ppm;

10 ppm for recycled PES

EN ISO 105-E04 (2013) EN ISO 17294-2

Textile 260 ppm for 100 % Polyester,

130 ppm for 50 % PES

30 mg/kg (natural textile)

microwave digestion with

H2O2/HNO3

EN ISO 17294-2

Textile usage ban (0.2 ppm) (all) EN ISO 105-E04 (2013) EN ISO 17294-2

Leather usage ban (0.2 ppm) (all) DIN EN ISO 17072-1 EN ISO 17294-2

Textile 1 ppm (all) microwave digestion with

H2O2/HNO3

EN ISO 17294-2

Leather 1 ppm (all) microwave digestion with

H202/HNO3

EN ISO 17294-2

TLV/based on usage ban U.S. EPA/600/R-93/116 U.S. EPA/600/R-93/116

Textile 0.1 ppm EN ISO 105-E04 (2013) EN ISO 17294-2


H202/HNO3 or EN 1122

EN ISO 17294-2



EN ISO 17294-2

Trim parts 40 ppm microwave digestion with


EN ISO 17294-2

Textile 1 mg/kg textile and artificial

leather total, means chromium

3+ and Cr6+

EN ISO 105-E04 (2013) EN ISO 17294-2

Textile n.d. (0.5 ppm) EN ISO 105-E04 (2013) EN ISO 17294-2

Leather n.d. (3 ppm) CEN/TC 309 WG 2 N 138 § 64 LFGB 82.02-11

(2008)

Textile 1 ppm babies; 4 ppm adults EN ISO 105-E04 (2013) EN ISO 17294-2

Leather 1 ppm babies; 4 ppm adults EN ISO 105-E04 (2013) EN ISO 17294-2

Textile 25 ppm EN ISO 105-E04 (2013) EN ISO 17294-2

Leather 25 ppm EN ISO 105-E04 (2013) EN ISO 17294-2

Historically widely used / High Occurrence level and/or regulated by Law

Historic known usages / Mid Occurrence Level

Unlikely to be found, (and/or) not intentionaly used / Low Occurrence Level

Antimony (Sb) extractable (CAS-No.: 7440-36-0)

Chromium (Cr) extractable (CAS-No.:7440-47-3)

Chromium VI (CAS-No.: 18540-29-9)

Asbestos (CAS-No.: multiple)

Arsenic (As) total (CAS-No.: 7440-38-2)

Cadmium (Cd) total (CAS-No.:7440-43-9)

Copper (Cu) extractable (CAS-No.: 7440-50-8)

Cobalt (Co) extractable (CAS-No.: 7440-48-4)

Parameters

Cadmium (Cd) extractable (CAS-No.: 7440-43-9)

Arsenic (As) extractable (CAS-No.:7440-38-2)

Antimony (Sb) total (CAS-No.: 7440-36-0)

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Colour Coding


Sample Prep

Suitable Method

Measuring

Colour

Coding




Parameters

Textile Usage ban n.d. (0.2 ppm) EN ISO 105-E04 (2013) EN ISO 17294-2

Leather Usage ban n.d. (0.2 ppm) EN ISO 105-E04 (2013) EN ISO 17294-2


H202/HNO3

lead in paint and surface

coating: CPSIA Section 101

16 CFR 1303

EN ISO 17294-2


H202/HNO3



16 CFR 1303

EN ISO 17294-2

Trim parts 40 ppm (all) microwave digestion with

H202/HNO3



16 CFR 1303

EN ISO 17294-2

Textile n.d. (0.02 ppm) EN ISO 105-E04 (2013) EN ISO 17294-2

Leather n.d. (0.02 ppm) EN ISO 105-E04 (2013) EN ISO 17294-2

Trim parts n.d. in inks and dyes EN ISO 105-E04 (2013) EN ISO 17294-2

Textile 0.5 ppm (total) microwave digestion with

H202/HNO3

EN ISO 17294-2

Leather 0.5 ppm (total) microwave digestion with

H202/HNO3

EN ISO 17294-2

Textile 1 ppm babies; 4 ppm adults EN ISO 105-E04 (2013) EN ISO 17294-2

metals parts 0.5 µg/cm2/week prolonged

skin contact

0.2 µg/cm2/week (pierced part)

EN 12472:2005+

A1:2009

EN 1811

textile 500 ppm EN ISO 105-E04 (2013) EN ISO 17294-2

Textile 4.0 - 7.5 ISO 3071 ISO 3071

Leather 3.5 – 7.0 ISO 4045 ISO 4045

Selenium (CAS-No.: 7782-49-2)

Lead (Pb) extractable (CAS-No.: 7439-92-1)

Mercury (Hg) total (CAS-No.:7439-97-6)

Mercury (Hg) extractable (CAS-No.:7439-97-6)

Nickel (Ni) extractable/release (CAS-No.: 7440-02-0)

Lead (Pb) total (CAS-No.:7439-92-1)

pH-Value

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Colour Coding


Sample Prep

Suitable Method

Measuring

Colour

Coding




Parameters

Textile n.d. (0,05 ppm) § 64 LFGB B 82.02-08 or draft

DIN EN ISO 17070

§ 64 LFGB B 82.02-08 or

draft DIN EN ISO 17070

Leather n.d. (0,05 ppm) § 64 LFGB B 82.02-08 or draft

DIN EN ISO 17070

§ 64 LFGB B 82.02-08 or


Textile n.d. (0,05 ppm) § 64 LFGB B 82.02-08 or draft

DIN EN ISO 17070

§ 64 LFGB B 82.02-08 or


Leather n.d. 0,05 ppm) § 64 LFGB B 82.02-08 or draft

DIN EN ISO 17070

§ 64 LFGB B 82.02-08 or


Textile 50 ppm §64 BVL B 82.02.08 GC-MS LC-MS for

confirmation

Leather 500 ppm §64 BVL B 82.02.08 GC-MS LC-MS for

confirmation

Textile 1 ppm § 64 LFGB B 82.02-08 or draft

DIN EN ISO 17070

§ 64 LFGB B 82.02-08 or


Textile 0.05 ppm babies 0.5 ppm adults

(only when natural fibres are

involved)

§ 64 LFGB B 82.02-08 or draft

DIN EN ISO 17070

§ 64 LFGB B 82.02-08 or


Leather 0.05 ppm babies 0.5 ppm adults § 64 LFGB B 82.02-08 or draft

DIN EN ISO 17070

§ 64 LFGB B 82.02-08 or


Pesticides (CAS-No.: multiple)Textile n.d. (0,05 ppm) see test method ISO 15913/DIN 38407 F2

or

EPA 8082A/EPA 8151A

or BVL L 00.00-34:2010-

09

Leather < 0.5 ppm for each see test method ISO 15913/DIN 38407 F2

or

EPA 8082A/EPA 8151A

or BVL L 00.00-34:2010-

09

Ortho-phenylphenol (o-PP) (CAS-No.: 90-43-7)

Pentachlorophenol (PCP) (CAS-No.: 87-86-5)

Trichlorophenol (CAS-No.: 25167-82-2)

Tetrachlorophenol (TeCP) (CAS-No.: 25167-83-3 or 58-90-2)

other chlorinated Phenols (CAS-No.: multiple)

8 Version 03

Colour Coding


Sample Prep

Suitable Method

Measuring

Colour

Coding




Parameters

Textile n.d. (20 ppm) see test method Textile: accesible with and

without extraction (EU):EN

14362-1:2012

Leather(EU):CEN ISO/TS

17234

p-Aminoazobenzene:

EN14362-3:2012

Leather n.d. (20 ppm) see test method Textile: accesible with and

without extraction (EU):EN

14362-1:2012

Leather(EU):CEN ISO/TS

17234

p-Aminoazobenzene:

17234-2:2011

Textile n.d. (0,01 ppm) EPA 5035 EPA 8260 B

Leather n.d. (0,01 ppm) EPA 5035 EPA 8260 B

Textile 13 ppm (babies) 20 ppm adults see test method JIS L 1041-1983 A

(Japan Law 112) or EN

ISO 14184-1:2011

Leather 20 ppm (babies) 50 ppm adults see test method ISO 17226-2

Paper 150 ppm (EN 645 and EN

1541)

see test method EN 645

Wood 10 ppm see test method EN 717-3

Textile n.d. (5 mg/l) DIN 54231 DIN 54231

Leather n.d. (5 mg/l) DIN 54231 DIN 54231

Textile n.d. (5 ppm) DIN 54231 DIN 54231

Leather n.d. (5 ppm) DIN 54231 DIN 54231

Textile 1 ppm DIN 54232 DIN 54232

Textile 0.5 ppm (babies)

1 ppm (adults)

CEN/ISO 16179 CEN/ISO 16179

Leather 0.5 ppm (babies)

1 ppm (adults)

CEN/ISO 16179 CEN/ISO 16179

Textile n.d. (0.2 ppm) CEN/ISO 16179 CEN/ISO 16179

Leather n.d. (0.2 ppm) CEN/ISO 16179 CEN/ISO 16179

Formaldehyde (CAS-No.: 50-00-0)

Ozone depleting substances (CAS-No.: multiple)

Azo-amines (CAS-No.: multiple)

Navy Blue (EC #405-6654; Index 611-070-00-2) Blue Colorant

Monobutyltin (CAS-No.: not available)

Chlororganic carriers (CAS-No.: multiple)

Dibutyltin (CAS-No.: 13323-61-1 and 78-06-8)

Disperse and other forbidden dyes (CAS-No.: multiple)

9 Version 03

Colour Coding


Sample Prep

Suitable Method

Measuring

Colour

Coding




Parameters

Textile 1 ppm CEN/ISO 16179 CEN/ISO 16179

Leather 1 ppm CEN/ISO 16179 CEN/ISO 16179





Trim parts 1 ppm CEN/ISO 16179 CEN/ISO 16179

Textile Sum of all regulated

phthalates 500 ppm

CPSC-CH-C1001-09 GC-MS (confirmation with

LC-MS)

EN 15777

Leather Sum of all regulated

phthalates 500 ppm

CPSC-CH-C1001-09 GC-MS (confirmation with

LC-MS)

Textile n.d. (5ppm) TRIS, Bis(2,3-

dibromopropyl)phosphate:

extraction with methanol GC/M

TEPA:KOH digestion; GC-HS of

ethyleneimine

PBDEs, TBBP A: acetonitril

extraction , LC-DAD-MS and

confirmation with GC/MS

all others: methanol-extraction,

GC/MS

see pretreatment

Leather n.d. (5ppm) TRIS, Bis(2,3-

dibromopropyl)phosphate:

extraction with methanol GC/M

TEPA:KOH digestion; GC-HS of

ethyleneimine

PBDEs, TBBP A: acetonitril

extraction , LC-DAD-MS and

confirmation with GC/MS

all others: methanol-extraction,

GC/MS

see pretreatment

Textile n.d. (50 ppm) draft ISO/DIS 18219:2012 draft ISO/DIS 18219:2012

Leather n.d. (50 ppm) draft ISO/DIS 18219:2012 draft ISO/DIS 18219:2012

Textile 1000 ppm draft ISO/DIS 18219:2012 draft ISO/DIS 18219:2012

Leather 1000 ppm draft ISO/DIS 18219:2012 draft ISO/DIS 18219:2012

Sum of Short chained chloroparaffines C10 to C13 (SCCP) (CAS-No.: multiple)

Sum of Medium Chained (MCCP’s) C14-C17 (CAS-No.: multiple)

Sum of remaining organo tin compounds (CAS-No.: multiple)

Sum of Tri-substituted organotin compounds (CAS-No.: multiple)

Phthalates (CAS-No.: multiple)

Dioctyltin (CAS-No.: not available)

Flame retardants (CAS-No.: multiple)

10 Version 03

Colour Coding


Sample Prep

Suitable Method

Measuring

Colour

Coding




Parameters

Textile NP/OP: n.d. (10 ppm).;

NPEO/OPEOS: 100 ppm

prEN ISO 18218-1: 2012 prEN ISO 18218-1: 2012

Leather NP/OP: n.d. (10 ppm);

NPEO/OPEOS: 100 ppm

prEN ISO 18218-1: 2012 prEN ISO 18218-1: 2012

Textile 1 µg/m2 FprCEN/TS 15968 FprCEN/TS 15968

Leather 1 µg/m2 FprCEN/TS 15968 FprCEN/TS 15968

Textile n.d. (1 ppm) Extraction using organic solvent

(dichloromethane)

GC/MS

Leather n.d. (1 ppm) Extraction using organic solvent

(dichloromethane)

GC/MS

Textile 1000 ppm final draft CEN ISO/TS 16189 final draft CEN ISO/TS

16189

Leather 1000 ppm final draft CEN ISO/TS 16189 final draft CEN ISO/TS

16189

Textile n.d. (0.03 ppm) ISO/TS 16186 ISO/TS 16186

Leather n.d. (0.03 ppm) ISO/TS 16186 ISO/TS 16186

Trim parts n.d. (0.03 ppm) ISO/TS 16186 ISO/TS 16186

Textile sum of 18 acc. EPA 10 ppm

(all)

benzo[a]pyrene 1 ppm (all)

ZEK 01.2-08 ZEK 01.2-08

Plastic, Rubber, Paints & Surface

Coatings

sum of 18 acc. EPA 10 ppm

(all)


ZEK 01.2-08 ZEK 01.2-08

Leather sum of 18 acc. EPA 10 ppm

(all)


ZEK 01.2-08 ZEK 01.2-08

Textile usage ban FTIR

Leather usage ban FTIR

Trim parts usage ban FTIR

Textile n.d. (1 ppm) extraction with methanol DIN EN ISO 18857-2

(mod)

Leather n.d. (1 ppm) extraction with methanol DIN EN ISO 18857-2

(mod)

Trim parts/Polycarbonate only n.d. (1 ppm) extraction with methanol DIN EN ISO 18857-2

(mod)

PFOS (CAS Nr.:2795-39-3) / PFOA (CAS-No.: 3825-26-1)

Polyvinyl chloride (PVC) (CAS-No.: 9002-86-2)

Polycyclic aromatic hydrocarbons (PAH) (CAS-No.: multiple)

Dimethylfumarate (DMF) (CAS-No.: 624-49-7)

Dimethylformamide (DMFA) (CAS-No.: 68-12-2)

Triclosan (CAS-No.: 3380-34-5)

NP, OP and NPEO, OPEO (CAS Nr.: multiple)

Bisphenol-A (CAS-No.: 80-05-7)

11 Version 03

Colour Coding


Sample Prep

Suitable Method

Measuring

Colour

Coding




Parameters

PU (coating, finishing) n.d. (1 ppm) ISO 10383 mod. free: HPLC;

blocked: GC-MS with

injector block temperature

at 300 °C; confirmation at

180 °C

Textile 1 ppm solvent extraction GC/MS resp. LC/MS

Textile 0.1 ppm solvent extraction GC/MS

Leather 0.1 ppm solvent extraction GC/MS

Textile 1 ppm multiple headspace GC/MS

Leather 1 ppm multiple headspace GC/MS

Textile 10 ppm Headspace GC/MS

Leather 10 ppm Headspace GC/MS

Textile - PVC 1 ppm ISO 6401 ISO 6401

Leather - PVC 1 ppm ISO 6401 ISO 6401

Textile 50 ppm Solvent extraction GC/MS

Leather 50 ppm Solvent extraction GC/MS

Textile n.d. (0,1 ppm) Headspace Thermal Desorption GC/MS

Leather n.d. (0,1 ppm) Headspace Thermal Desorption GC/MS

textile 50 ppm Solvent extraction GC/MS

leather 50 ppm Solvent extraction GC/MS

Textiles 50 ppm solvent extraction GC/MS confirmation

LC/MS

EVA 50 ppm Extraction in methanol GC-MS

EVA 50 ppm Extraction in methanol GC-MS

Textile n.d. (0,5 ppm) DIN EN 12868;

BVL B 82.92-1:2008,

GB/T 24153-2009

Leather n.d. (0,5 ppm) DIN EN 12868;

BVL B 82.92-1:2008,

GB/T 24153-2009

Vinyl chloride- Monomer (CAR-Nr.: 75-01-4

Isocyanates (CAS-No.: multiple)

Biocides (CAS-No.: multiple)

Acrylates- Monomers (CAS-No.: multiple)

Acrylamide- Monomer (CAS-No.: 79-06-1)

N-Nitrosamine (CAS-No.: multiple)

2-Phenyl-2-propanol (CAS-No.: 617-94-7)

Acetophenone (CAS-No.: 98-86-2)

Biphenyl (CAS-No.: 92-52-4)

Sensitizing Isothiazolinones (CAS-No.: multiple)

Fluorinated Greenhouse Gases (CAS-No.: multiple)

Acrylonitrile- Monomers (CAS-No.: 107-13-1)

Ethyl acrylate (CAS-No.: 140-88-5)

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