resolution mepc.33(27) adopted on 17 march 1989. …

RESOLUTION MEPC.33(27) adopted on 17 March 1989. ADOPTION OF AMENDMENTS TO THE CODE FOR THE CONSTRUCTION AND EQUIPMENT OF SHIPS CARRYING DANGEROUS CHEMICALS IN BULK (BCH CODE)

RESOLUTION HEPC.33(27)

adopted on 17 March 1989

ADOPTION OF AMENDMENTS TO THE CODE FOR THE CONSTRUCTION AND EQUIPMENT OF SHIPS CARRYING DANGEROUS

CHEMICALS IN BULK (BCH CODE)

THE MARINE ENVIRONMENT PROTECTION COMMITTEE,

RECALLING article 38( a ) of the Convention on the International Maritime

Organization concerning the function of the Committee conferred upon it by

International Conventions for the Prevention and Control of Marine Pollution,

NOTING ar t ic le 16 of the Interna tional Convention for the Prevention of

Po llution from Ships , 1973 (hereinafter referred to as the "1973 Convention")

and article VI of the Protocol of 1978 relating to the I nternational

Convention for the Prevention of Pollution from Ships, 197 3 {hereinafter

referred to as the "1978 Protocol"}, wh ich together speci fy the amendment

procedure of the 1978 Protocol and confers upon the appropriate body of

the Organization the function of cons ider ing and adopting amendments to

the 1973 Convention, as modified by the 1978 Protocol (HARPOL 73 /78),

BEING DESIROUS of keeping the Code for the Construction and Equipment

of Ships Carrying Dangerous Chemicals in Bulk (nCH Code) up-to-date, and

compatible with the International Code for the Construction and Equipment

of Ships Carrying Dangerous Chemica ls in Bulk (ISC Code). as well as

appendices II and III of Annex II of HARPOL 73/78,

NOTING FURTHER resolution MEPC 32(27 ) by which the Committee adopted

amendment s to the IBC Code,


- 2 -

RECOGNIZING the need to bring the corresponding amendments to the

BCH Code into force on the date on which the amendments to the IRe Code enter

int o force.

HAVING CONSIDERED, at its twenty-seventh session, the amendments to the

BeH Code proposed by the Sub-Committee on Bulk Chemicals at its eighteenth

session and circulated in accordance with article 16 (2)(a) of the

1973 Convention,

1. ADOPTS in accordance with article 16(2)(d) of the 1973 Convention

amendments to the BeR Code, the text of which is se t out in the Annex to

the present resolution;

2. DETERMINES, in accordance with article 16(2)(£)(iii) of the

1973 Convention, that the amendments shall be deemed to have been accepted

on the date on which the conditions for the entry into force of the amendments

to the IRC Code adopted by the Committee by resolution HEPC 32(27) are met,

unless prior to that date, not less than one third of the Parties or the

Part ies, the combi ned me rchant fleets of which constitute not less than

fift y per cent of the gross t onnage of the world's merchant f leet , have

communica t ed to the Organization their Objec t ions to t he amendments;

3. INVITES the Parties to note that in accordance with article 16(2)(g)(ii)

of the 1973 Convention the amendments shall enter in to force six months after

their acceptance in accordance with paragraph 2 above;

4. REQUESTS the Secretary- Ge neral, in conformity with article 16(2)(e) of

the 1973 Convention, t o transmit to all Parties to the 1978 Protocol certified

copies of the present resolution and the text of the amendments contained in

the Annex;

5. REQUESTS FURTHER the Secretary-General to transmit to the Members of the

Organization which are not Parties to the 1978 Prot ocol copies of the

r esolution and its Annex.


- 3 -

ANNEX

AMENDMENTS TO THE CODE FOR THE CONSTRU CTION AND EQUIPMENT OF SHIPS CARRYING DANGEROUS

CHEMICALS IN BULK (BeH CODE)

Chapter III, Section E - FIRE PROTECTION: The introductory sentence is

amended to read;

"Fire-extinguishing media determined to be effective for certain products

are listed in column "I" in the table of chapter VI . "

and the same sentence which appears in the Explanatory Notes to chapter VI

under "Fire Protection" is deleted.

2 Regulation 3.14.2; The last sentence is amended to read; "Regular

protein foams should not be used".

3 Regulation 4.4 Acetone cyanohydrin

.1 The words "and Lactonitrile so l ut ion (80% or less)" are added to the

title .

• 2 The first sentence is amended t o read :

"Acetone cyanohydrin and Lactonitrile so l ution should

4 New regulation 4.22 Octy l nitrates

New regulation 4.22 Octyl nitrates is added as follows:

"4.22 Octyl nitrates, all isomers


- 4 -

4.22.1

The carriage temperature of the cargo should be maintained below

lOO · C to prevent the occurrence of a self-sustaining.

exothermic decomposition reaction .

4.22.2

The cargo may not be carried in independent pressure vessels

permanently affixed to the vessel's deck unless:

.1 the tank s are sufficiently insulated from fire; and

.2 the vessel has a water deluge system for the tank s such that

the cargo temperature is maintained below lOO· C and the

temperat ure rise in the tanks does not exceed I.S·C/hour for a

fire of 650·C (1200"F) ."

5 Chapter VI - Explanatory note for fire protect ion:

.1 a footnote is added to liD. dry chemical", as follows:

"Dry chemical powder systems when used may require an additional

water system for boundary cooling. This is normally provided in

sufficient quantitites by the standard fire ma i n system required by

regulation II-2/4 of th e 1974 saLAS Convention as amended."

.2 A n ew note is added as follows:

"Fu r ther information on t he suitability of fire-fight ing media

listed in column "1" of chapter VI may be found in column "1" of

chapter 17 i n the IBC Code."


- 5 -

6 Chapter VI - The Table

The Table of Summary of Minimum Requirements are replaced by the

fo llowing:


0 c, 0

0 , s ;; ~ ~.

~ " 0 ~

'" c. C. ~

.. , " i > v t ~ 0

" ,- 0_ ;: .. c c , ~ , 0 0 ~

0 c , C < ~ ~ ~ ~~ v

& " 0 • Special <: " c c c c • , ~ c requirements P"odu:.t :-'Jar.,,:: § f ~ !'. • < c W " • • ~ ~ ~ ~ , 0 > ~

a h 0 d • 9 h k 1 m

Acetic acid 0 S 2G Cont. No SP R F • 4.8.2 to 4.B.4, 4.8.6 to 4.B.8, 4 . 12 .6 , 4.17

Acetlc anhydrld(' 1715 0 s 2 2G Cont. No SP R F-T • 4 .S.2 to 4.8.4, 4.B.6 to 4.8.8, 4.12.6, 4. .17

Acetone cyanohydrin 1541 A sip 2 2G Cont. No St C T • 4.4, 4.9, 4.12.6, 4.13, 4. 14. 4.17 • 4.18

Acetonitrile 1646 III S 2 2G Cont. No SP R F-T • 4 . 9 Acrylamide solutlon (50% or less) 2014 0 S 2 2G Open No St C No No 4.9.3, 4.10, 4.14.1,

4. 15.1 , 4.18.1 Acrylic odd 2218 0 S 3 2G Cont. No SP R F-T • 4 .10, 4.12.6, 4.1B. ~

T'lcryloni tr ile 1093 B sip 2 2G Cont. No SP C F - T • 4.9, 4.1 0 , 4.12.3. 4.13.1. 4.14, 4.17

Adiponltrile 2205 0 S 2G Cont. No St R T • Alcohol (eI2-CIS) poly( 1-3) ethoxylates A P 2G Open No St 0 No • 4.14. Al cohol (eI2-CIS) poly(3-11) ethoxylates • P 2 2G O".n No St 0 No • '1.14. 1 Alcohol (C&-C17)(seconda ry ) poly ( 3-6) etho)(},lates • p 2 2G Ope n No St 0 No • 4 ,14.1 Alcohol (C6-C I7)(secondary) poly{7-12l ethoxylates B P 3 2G Open .0 St o No • 4.14.1. 5.2.5, 5.2.B AII-V t aery latp.-v lny\ pyridine copolyme r in toluene C P 3 2G Cont. No SP R F • 4.14.1 Alkyl benzene sulphon i c acid 2584, C SiP 3 2G Open No St 0 No B 5.2 .6, 5 2 . 7

2586 Alkyl benzene su lphonic acio, sod iUlll snlt so l ution C P ) 2G Open No St o No No 5 2 6 to 5.2.8 Allyl elcohal 1098 B sIp 2 2G Cont. No SP C f - T • 4 .9, 4 . 13.1, 4 .14, 4.11 Allyl chlonde 1100 B sIp 2 2G Cant. No SP C f -T • 4.9, 4.13.1, 4. 14. 4 .17 AlumInium chloride (30\ or less) /Hydrochloric acid 0 S 3 IG Cont. No St R T No 4. 8, 4. n( t) (20\ o r less) solution 2-(2-Affilnoethoxy ) ethanol 30SS 0 S 2G Open No St o No A,C,D 4 .14 .1 , 4.12.2


• b , d e f 9 h k m

Ami noethyl ethanolamlne (D) S ) 2G Open No St 0 No A 4.12. 1

N- Aminoethylpiperaz i ne 2815 ° S ) 2G Cont . No St R T A.e.D 4.12.2, 4.14.1

2-Amino-2-methyl- l-propanol (90\ or less) 0 S 3 2G Opeo No St ° No A 4.12.1

Ammonia aqueous (28\ or less) 2672(0 ) e SiP ) 2G Cont. No SP R T e 4.12.4, 4.12.9. 4.17{a)

Ammon i um nitrate solution (93\ or less) 0 S 2 1G Opeo No St 0 No No 4.8.4. 4.S.6, 4.12.10, 4.13.2, 4.14.1, 4.19

Ammonium sulphide solution (45\ or less) 2683 B sip 2 2G Cont . No SP e F-T A.e 4.9, 4.11, 4.12 .1. 4.13.1, 4.14. 4 .15.1, 4.17 • 4.18

Ammonium thiocyanate (25\ or less )/Armnonium (e) p ) 2G Opeo No St 0 No No

thiosulphate (20\ or less) solution Ammonium thiosulphate solution (60\ or less) (e) P 2G Opeo No St 0 No No 5.2.8

n- Amyl acetate 1104 e P 2G Cont. No SP R F A 4.14.1

sec-Amyl acetate 1104 e p ) 2G Cant. No SP R F A 4.14 . 1

Amyl acetate, commercial 1104 e p 3 2G Cont. No SP R F A 4.14.1

Aniline 1547 e SiP 2 2G Cont. No St e T A 4.9, 4 .13.1, 4.14

Aviation alkylates (ea paraffins and iso-paraff ins (e) p 2G Cont. No SP R F B 4.14.1

aPT 95 - 120°C) ~

Benzene and mixtUres having 10\ benzene or more 1114(s) C SiP 3 2G COnt. No SP R F-T B 4..9.1, 4..13.1. 5.2.8

8enzene s ulphonyl chloride 2225 0 S 3 2G COnt. No st R T B.O 4. .12.1 , 4.14.1

Benzyl acetate e P 3 2G Opeo No st 0 No A

Benzyl alcoho l C P 3 2G Open No st 0 No A

Benzyl chloride 1738 B sip 2 2G Cont. No St e T B 4..9, 4.10, 4.13.1, 4.14, 4.17

Butene oligome r B P 2G Open No St ° No A 4. .14.1

n- Butyl acetate 1123 e P 2G COnt. No SP R F A 4..14 .1


• b c d , f 9 h i k 1 m

n· Sut yL acrylate 2348 B SiP 2 2G Cont. No SP R F - T A iJ. 10,4.14.1,4 . 18.1,4. [8.2 Butylamine (all isomers) 1125. C sIp 2 2G Cont. No SP R F-T • <1 .9, 4.12.1. 4.12.2.

1214 <1.13.1, 4.14 .1, 4. 17 Su t y Ibenzenes (all isomers) 210'3 (A) P 2 2G Cont. No SP R F A <1.14.1 Butyl benz y l phthalate • P 2 2G Open No St o No A <1.14.1 n- Butyl butyrate (C ) P 3 2G Cant. No SP R F A <1.14.1 Butyl/Decyl/Celyl/Eicosyl methacrylate mixture 0 S ) 2G Cont. No St R No A,C,D 4.10, 4.18. 1, <1.18. 2 1.2-Butylene oXlde 3022 C SiP 2G Cont. Iner t SP R F ',C 4.7.1, <1. 7.2, <1.1. <I.

4.7.5, 4.7.8 to <1.7.11 , 4. i .13, 4.7.17. 4 .7. 19, <1.1.21. <1.14. 1

II-Butyl ether 11 49 C SiP ) 2G Cont. I nert SP R F-T ',0 4.2.1, 4.' Butyl methacrylate 0 S ) 2G Cant. No SP R F- T ',0 <1.10, 4.18.1, <I.1B.2 n- Butyraldehyde 1129 B SiP ) 2G Cont. No SP 0 F-T • 4.14.1, 4.15.1 Butyric acid 2820 0 S ) 2G Cont. No St R No • 4.8.2 to 4.8.4, 4 .8.6 to

4.B.B, 4.12.6 Calcium alkyl sallcylate C P 2G Open No St 0 No • 5.2.6, S.2.7

~ Calcium hypochlorite solution (15% or less) C SIP 3 2G Cont. No St R No No 4.12.5 , 4.15.1 Calcium hypochlorite solution (more than IS\ ) B SiP 3 2G Cont. No st R No No 4.12.5,4.J4.1. ll.IS.1 Calcium nllphthenate in mineral oil A P ) 2G Op'n No St 0 No • 4.14.1 Camphor oil 1130 B SiP 2 'G Cont. No SP 0 F B 4.14.1 Carbolic oi 1 • SiP 2 2G Cont. No St C F- T • 4 . 9, 4.14 Carbon di s ulphide 1131 B sip 2 lG Cont. Pad+lnert ",. C F- T C 4.1, 4.9, 4.14, 4 .17

NONE Carbon tetrachloride 1846 B SiP 3 'G Cont. No St C T No 4.9, 4.13.1, 4. 14. 1,

4.11


• b < d • 9 h k m

Cashew nut she ll 0,1 (untreat ed) D 5 2G Cont. No " R T B Cetyl/Eicosyl methacri'late mixtur e 11J 5 2G Open No " 0 No A. C, D <1.10. 4 .18. J, <1.18.2 th l orlna ted paraff i ns (elO-e13) A P 2G Open No St 0 No A <1.14 Chloro6cetie acid (80' or bssJ 1750 C SiP 2G Cont. No " ,"0 No 4 .8.2 . <1. 8.4. B.' t o

4.S .8, <1.9 .3. 4.12.6(;0:)' 4.14. 50 .2.8

Chlor obenzene llJ4 B SIP 2G Cont. NO SP R ' - T B 4.14.1 Chlor ororm 1888 B SI P 2G Cont. No St R T No 4.9, 4.14.1- 4.17 Chlorohydrlns (crude) 101 , 2G Cont. No SP C ' -T A • 9, <1 . 14 a-Chiaron 1 teaben ..:ene ]578 B SIP 2G Cont. No " C T 8 .C,D • 9, 4.11, 4 .1 4 , S 2.5,

S 2.8, SA.2.2 2- or 3-Chloropropionic aCId 2S11(k) IC) SIP 2G Op en No st 0 No A 4 .8.2 to 4.8 . 4, 4.8.6

4.8.8, 4.12 .6, 5 .2 . 6 5. 2 .8

chloro$u lpho nic acid 1754 C sip 1 2G Cont. No " C T No 4 . S . 2 to 4.8.8, 4.9, 4.14 • 4 . 15.2, • 17

m-Chlorotoluene 2238 B sIp 3 2G Cont . No SP R F-T B,C 4. 14 . 1 o-Chio rotoluene 22)8 A SIP 3 2G Cont. No SP R '-T B,C .. 14. 1 p- Chlorotolllene 22JS B SIP 2 2G Cent. No SP R '-T B,C , 14 .1. 5.2.S Chloroto luenes (lfIlxed isomers) 22JS A sI p 2 2G C~nt. No SP R '-T B,C 4 . 14. J Coal to< A sip 2 ' 2G C~nt. No St RNo B,O 4 . 14.1 Coel ta r naphtha so l vent B sip 2G C~nt . No SP R ' - T A,O 4.14.1 <:00 1 tar pi t c h (1OO1 ten) 0 5 lG Cont. No St R No B,D 4.1 4.1 Coconu t oil fatty acid C P 2G Ope' No St 0 No A 5.2.6 to 5. 2 .S Creosot e (collol tar) A SIP 2G Op"' No St 0 No B,D 4.14.1 Creosote (wood ) A 51' 2G Open No St 0 No B,D 4 . 14.1

°for ships constructed before the date of entry ir.to force of t!"le pruent 3I!Iendments whi Ch ere e"8eged solely OTI voY"3u between porb or te ..... tn~h within the State the nag of wnlen the ship Is entltleCl to ny, the ship-type requlreonent. appUes ten years after e ntry In to foro;.e o f the ilI!Iendlllen t s.

for ships constructeCl be fore the dale o f entr y Into force o f the present amenClO1ents, which are engageCl on voyages ( rom . t o or between port tenllinab within States other than the State the flag of ",hlch t he shi p is entitled to rty, the ship-type requi~ent applle, fJ.ve ynrs after the entry Into force o f the a'''endments, provlCled that the ship satisfies all the following conditIon:!:

1 the ,hlp has been regularly engaged In the trade of coal tar for a t least five years tlefore the date of entry into fo r<:e o f the present amendments; t ile ship Is solely engage d on restricted "oyages liS detenlllned by the AdmInistratIon; the Certifi cate of fItn!s!! i!! endorsed to the effect t h il. t the Ship 15 solely en~ged In ,uch r e5tricted voyages. wi th the e :< p lry Clate of the period of grace: and

~ the n~e year p.o;rlod of grace 15 agreed among t he CoverrUl"lent3 concerned.

to to

~


a h 0 d e f 9 h k m

cresols (all isomers) 2076 A sip 2 2G Open No St 0 No B <1.14 .1 Cresylic acid, sodium salt solution A sIp 2 2G Open No st 0 No No 4.12. 1, 4.14./ Crotonaldehyde 1143 B sIp 2 2G Cont. No SP R F-T A <1.9, 4.13.1, <1.14 .1,

4.15.1, 4.17 Cycloheptane 2241 (C) P 3 2G Cont. No SP R F A 4.14.1 Cyclohexane 1145 C P 3 2G Cont. No SP R F A 4.1<Ll. 5.2.8 Cyclohexanol C P 3 2G Open No st 0 No A 5.2.6, 5.2.8 Cyclohexanone 1915 0 S 3 2G Cont. No SP R F - T A 4.12.5 Cyclohexyl ace tale 2243 (B) P 2G Cont. No SP R F A 4.14 .1 Cyclohexylamine 2357 C sip 2G Cont. No SP R F -T A,D 4.12.1, 4.12.2 1, ,-Cyclopentadlene dimer (molten) B P 2G Cont. No SP R F A 4.14.1, 5.2.5. 5.2.8,

SA.2.2 Cyclopentane 1146 (C) P 3 2G Cont. No SP R F A 4.14 .1 Cyclopentene 2246 (B) P 2G Cont. No SP R F A 4.14 .1 p-Cymene 2046 C P 3 2G Cont . No SP R F A 4.14.1 Oecanoic acid C P 2G Open No st o No A 5.2.6 to 5.2.8 Decene B P 2G Cont. No SP R F A 4.14 .1 ~

Decyl acrylate A SiP 2 2G Open No St 0 No A,C,O 4.10, 4.12. 2 , 4. 14.1. a

4.18.1, 4.18.2 DeC'll alcohol (all .lsomers) B P 2G Open No St 0 No A 4.14.1, S.2.8(p) Dibutylamine C SiP 2G Cant. No SP R F-T B,D 4.12.4 Oibutyl phthalate A P 2 2G Open No st 0 No A 4.14.1 Oichlorobenzenes (all isomers) B SiP 2 2G Cant. No st R T B,D 4.12.5, 4. 14.1.

S.2.S(v), s.2.8(w), sA.2.2(x)

1,1-Dichloroelhane 2362 B sIp 3 2G Cont. No SP R F-T B 4.14.1, 4. 17


, b , d e 9 h i , m

Dichloroethy l ether 1916 B SiP 2 2G Cont. No SP R F-T A 4.12.5. 4.14.1 2,2-Dichloroisopropyl ether 2490 C SiP 2 2G Cont. No St R T B,C, O 4.9, 4 .12.5. 4.13.1,

4.14 Oichlorometh,me 1593 0 S 3 2G Cont. No St R T No 2. 4-Dichlorophenol 2021 A sip 2 2G Cont. o,y St R T B,C,D 4.12.1, 4.14.1 2 ,4- Dichlorophenoxyacetic acid, diethanolamine A sip 3 2G Open No St 0 No No 4.12.1. 4. 14.1 SA lt solution 2.4-0 i chlorophenoxyacetic acid. dimethylarnine salt A sip 3 2G Open No St 0 No No 4.12.1, 4.14.1

solution {70\ or less} 2. 4-Dichlorophenoxyacetic acid. A sip 3 2G Open No St 0 No No 4.12.1, 4 . 14.1 trii sapropanolamine salt solulion 1. 2- 0ichloropropane 1279 B sip 2 2G Cont. No SP R F-T B 4.9, 4.14.1 1,3- Dichloropropane B SiP 2 2G Cont. No SP R F-T B 4.9, 4.14.1 1. 3-0ich!oropropene 20 47 B sip 2 2G Cont. No SP C F- T B 4.9, 4.13, 4.14, 4.17

DichloropropenejDichloropropane mixtures B SiP 2 2G Cont. No SP C F-T B,e,D 4.9, 4.13, 4.14, 4.17 2,2-Dichioropropionic acid 0 S 3 2G Cont. Dry st R No A 4.8.2, 4.8.4, 4.8.6 to

4.B.8, 4.12.6(z) Diethano1amine tI l S 3 2G Open No St 0 No A 4.12.2 Diethylamine 1154 C sIp 3 2G Cont. No SP R F- T A 4.9, 4.12.1, 4.17 Diethylaminoethanol 2686 C sIP 3 2G Cont. No SP R F-T A,C 4 .12. 1, 4.12.2 Diethylbenz.ene 2049 C P 3 2G Cant. No SP R F A 4.14.1 Die thy l ene glycol methyl ether C P 3 2G Open No s t 0 No A Diethylenetriamine 2079 0 S 3 2G Open. No St o No A 4 .12.2 Die t hyl ether 1155 III S 2 IG Cant. Inert SP e F- T A 4.2 . 4.11, 4.12.9, 4.14,

4.11 Di-(2-ethyl hexyl) phosphorlc acid 1902 C SiP 2G Open No St o No B,e,D 4.12.2


• b , d e f 9 h i k 1 m

Diethyl phthalate e • 3 2G Open No St 0 No A Diethyl sulphate 1594 (B) S/' 2 2G Cont. No St C T A,a 4.12 . 3, -4.14 . 1 Diglycidyl ether of bisphenol A B • 3 2G Open No St 0 No A 4.14 .1, 5.2.5 Diglycidyl ether of bisphenol F B • 3 2G Open No St 0 No A 4.14.1, S.2.S Di -n-hexyl adipate B • 3 2G Open No St 0 No A -4.14.1 Diisobutylamine 2361 (e) SiP 2 2G Cont. No SP R F-T B, a 4.9.3, 4.12. 1, 4.14.1 Diisobutylene ::!OSO B P 3 2G Cont. No SP R F A -4.14.1 Diisobutyl phthalate B P 3 2G Open No St 0 No A -4.14.1. 5.2.5 Oiisopropanolamine e sIp 3 2G Opeo No St 0 No • 4.12.2. 5.2.6 to 5 2.B Oilsopropylamine 1156 e SiP 2 2G Cont. No SF C F-T A 4.9 , 4.12.2, 4.14. 4 .17 Diisopropylbenzene (all isomers) A P 2 2G Open No St 0 No • 4.14 . 1 N,N-Dimethylacetaroide solution ( 40\ 0' less) 0 S 3 2G Cont. No St R T B 4.9.1, 4. 12. <I. 4.13.1 Dimethyl adipate B P 3 2G Open No St 0 No A -4.14.1, 5.2.8 Dimethylamine solulion (45\ or less) 1160 e SiP 3 2G Cont. No SP R F-T e,a 4.9, 4.12 .1 . 4 .17 Dimethyiamine solution ( greater than '" but nct 1160 C siP 2 2G Cont. No SP e F-T A, C,D 4.9, 4.12.1, 4.13.1. gyeater than 55\) 4 .14, -4.17

~

Dimethylamine solution (greater than 55\ but not 1160 e sip 2 2G Cont. No SP C F-T A,C,D 4.9, 4.11, 4.12.1, ~

greater than 65\) 4.13.1. 4. 14, 4.17 N,N-DLmethylcycloh exylami ne 2264 C SiP 2 2G Cant. No SP R F-T A,C 4.9. 4 . 12.1, 4.13.1.

4.14.1 Dimethylethanolamine 2051 0 s 3 2G Cant. No SP R F-T A,O 4.12.2 Dimethylformamide 2265 ° S 3 2G Cant. No SF R F-T A,O Dimethyl glutarate e P 3 2G Open No St 0 No A Dimethyl hydrogen phosphite S 3 2G Cant. No st R T A,D 4 . 9 . 1 Dimethyl octanoic acid (e) P 3 2G Open No St 0 No • 5.2.7, 5.2.8 Dimethyl phthalate e • 3 2G Open No St 0 No •


a b c d e 9 h i j k m

Dimethyl succinate C P J 2G Open No St o No • 5.2.8

Dinitrotoluene (molten) 1600 B sip 2 2G Cont. No St C T • 4.9, 4 .13.1, 4.14, (1) S .2 . 5, 5. 2 .8, 51\.2.2(111)

l , 4-0ioxane 1165 0 S 2 2G Cont. No SP C F-T • 4.9, 4 .14

Dipentene 2052 C P J 2G Cont. No SP R F • 4 . 14. 1

Diphenyl A P 2G Open No St 0 No B 4.14

Oiphenyl/Diphenyl ether mixtures A P 2G Ope, No St 0 No B 4.14

Oiphenyl ether A P J 2G Ope, No St 0 No A 4.14.1

Dipheny l ether/Oiphenyl phenyl ether rni>cture A P J 2G Ope, No St 0 No A 4.14.1

Qiphenylmethane diisocyanate 2489 (B) SiP 2 2G Cont . Dey St C T(b) C(c), D 4.9, 4.12.5, 4.13.1, Ib) 4.1-4.1. 4.15.2, 5.2.5,

5.2.8, SA.2.2

Oiphenylol propane-epichlorohydrin resins B P 3 2G Ope' No St o No A 4.14.1, 5.2.5

Oi- n-propylamine 2383 C SiP 3 2G Cont. No SP R F-T A 4 .9 .3, 4. 12.2, 4.14.1

Dodeeene (all isomers) IB) P 3 2G Open No St 0 No A 4. 14 . 1 ~

~

Oodecyl alcohol B P J 2G Ope, No St 0 No A 4. 14.I. 5.2.5, 5.2.8, SA .2.2

Oodecyl. diphenyl ether disulphonate solution B sip 2G Open No St 0 No No 4.14.1, 5.2.5, 5.2.8, 5A.2.2

Oodecyl methacrylate III S 3 2G Open No st 0 No A,C 4 . 10

Dodecyl/Pent adecy l methacrylate mixture III S 3 2G Open No St 0 No A,C,D 4.10, 4.18. I, 4 . 18.2

Dodecyl phenol A P 1 2G Open No St o No A 4 . 14

Drilling brines, contai ni ng Zinc sal t s IA) p 2 2G Open No st ONo No 4.14.1

Epichlorohydr i n 2023 C SiP 2 2G Cont . No SP C F- T A 4.9, 4.13.1, 4.14, 4 .11

Ethanolami ne 249 1 0 S 3 2G Open No st 0 F-T A 4.12.2

2- Etho xye thy l ace tate 1112 C P J 2G Cant. No SP R F A 4.14.1


• b , d • f 9 h k 1 • Ethyl acrylate 1911 A SiP 2 2G Cont. No SP R f-T A 4. 10, 4.14.1, 4.17,

4.18.1, 4.18.2 Ethylamine 1036 (C) SIP 2 1G Cont. No SP C F-T C,D 4.9, 4 .11, 4.12.2, 4.17 Ethylamine solutions (72\ or less) 2270 (C) SiP 2 2G Cont. No SP C F-T A, C " .9, 4.11, 4. 12.1,

4.13 . l. 4.14. 4.17 Ethyl amyl ketone 2271 C P 3 2G Cont. No SP R F A " .14.1 Ethylbenzene 1175 C P 3 2G Cont . No sp R f A 4.14 . 1 N-Ethylbutylamine (C) SiP 3 2G Cont. No SP R F-T A '1.9.3, 4 .12 .1, ".14.1 Ethyl butyra te 1180 C P 3 2G Cont. No SP R F A 4.14.1 Ethylcyclohexane (C) P 3 2G Cont. No SP R f A 4.14.1 N-Ethylcyc l ohexylamine 0 S 3 2G Cont . No SP R F-T A,C 4 .12 . 1,4 . 14.1 Ethylene chlorohydrin 1135 C SiP 2 2G Cont. No SP C f-T 0 4 . 9, ".13.1. ".14. " .11 Ethy lene cyanohydr in ( 0) S 3 2G Open No st 0 No A Ethy lenediamine 1604 C Si P 2 2G Cont. No SP R f-T A 4 . 12 .2, 5.2.8 Ethylene dibromide 1£>05 B SiP 2 2G Cont. No st C T No 4.9, 4 . 14.1, 4 . 11, 5 . 2 . 8 Ethylene dichlori de 1184 B SiP 2 2G Cont . No SP R f-T B 4 .12.4, 4.14 -Ethylene glycol butyl ether acetate ' (C) P 3 2G Open No st 0 No A ~

Ethylene glycol diace tate C P 3 2G Op,n No St 0 No A Ethylene oxide/Propylene oxide mixture with an 2983 0 S 2 lG Cont. Inert SP C F-T A,C 4 .7, 4.9, 4 .11. 4.14 Ethylene oxide content of not more than 30\ in weight 2-Ethylhexyl acrylate B SiP 3 2G Op.n No st 0 No A 4 . 10, 4.14 .1, 4 .18.1,

4.18 .2 2-Ethy1hexylamine 2276 B SiP 2 2G Cont . .0 SP R F-T A 4.9, 4.12.2. 4.14.1 Ethylidene norbornene B SiP ) 2G Cont. No SP R F - T B,C , D 4.9.1, 4.12.4, 4 . 14 . 1,

4 . 15.1


• b c d e f 9 h j k m

Et hyl met hacrylate 2271 (D) S 2G Cont. No SP R F - T . , D 4 . 10, 4 .18 .1, 4 .18 . 2 o-Ethylphenol (A) sIp 2G Open No St 0 No • 4 . 14. 1 2- Ethyl-J-propylacrolein (S) sIP 3 2G Cont. No SP R F-T A 4.14. 1, 5.2.8 Et hy lto l uene (S) P 3 2G Cont. No SP R F A 4 . 14 .1 Ferric chloride sol ut ions 2582 C sIp ) 2G Open No St o No No 4.S, 4 .14.1, S.2 . B Ferr ic nitrate/Nitric acid solution C sIP 2 2G Cont. No St R T No 4. 8, 4. 14, 4.17 Formaldehyde solutions ( 4S\; or less) 1198{d) C sIp 3 2G Cont. No SP R F-T A 4 .15.1 , 4.17(e), 5.2.8

2209 Formic acid 1779 0 5 3 2G Cont . No SP R T(t) A 4 .S .2 to 4.S.4, 4.B . 6 to

4.B.8, 4.12.1, 4 .17 Fumaric adduct of rosin, water dispersion S P 3 2G Open No St o No No 4 . 14.1, 5.2.5 Furfural 1199 C SIp 3 2G Cont. No SP R F-T A 4 .IS .1 Fu rfuryl al cohol 267 4 C P 3 2G Open No St 0 No A

Glutaraldehyde soluti ons (50\ or less) 0 S 3 2G Open No St 0 No No 4.15.1 Glyci dyl ester of CIO trialkylacetic acid S P 3 2G Open No St o No A 4. 14.1 Hep t ane (all isomers) 1206 (C) P 3 2G Cont. No SP R F • 4 .14 .1 Heptanol (all isomers) (q) C P 3 2G COnt. No sp R F A 4 .14 . 1 ~ Heptene (all isomers) C P 3 2G Cont. No SP R F A 4 . 14.1 Heptyl aceta t e (S) P 3 2G Open No St 0 No • 4.14.1 Hexamethylenedi amine solution 1783 C sip 3 2G Cont. No St R T A 4 . 12.2, 4 . 14. 1 , 5.2 .8 Hexamethyleneimine 249:3 C SiP 2 2G Cont. No SP R F-T A, C 4.12.1. 4.12.2 Hexa ne (a ll isomers) 1208 (C) P ) 2G Cont. No SP R F A 4 .14 .1 Hexene (all isomers ) (C ) P 3 2G Cont. No SP R F • <1 . 14 .1 Hexy l acetate 1233 B P ) 2G Cont. No SP R F A 4 . 14.1 Hydroc hloric acid 17 89 0 S ) 1G Cont. No St • T No 4 .8, 4 . 11 (f) Hydrogen pe roxide solut i ons (over 8\ but no t ove r 201 4, C sIP 3 2G Cont . No St C No No 4.13.2, 4 .14.1, 4 .20.15 60\) 2984 to 4. 20.27


• b c d e 9 h k 1 m

Hydrogen peroxlde solutions (over 60\ but not ove r 2015 e sip 2 2G Cont. No St e No No 4 .14. 1, 4 .20 .1 to 70\) 4. 20 .14 2-Hydroxyethyl acrylat e B sip 2 2G Cont. No St e T A 4 .9 , 4. 10, 4 .14 .1,

4.18 . 1, 4 . 18. 2 Isoamy l acetate 1104 e P ) 2G Cont. No SP R F A 4. .14.1 Isobu tyl acetate 1213 e P J 2G Cont . No SP R F A 4 .14.1 Isobuty l acrylate 2521 B SiP 2 2G COnt. No SP R F-T A 4. .10 , 4. . 14 .1, 4. . 18 .1 ,

4.18.2 lsobutyraldehyde 2045 e sip J 2G Cont. No SP 0 F-T A 4.15.1 Isophoroned iamine 2289 0 S ) 2G Cont. No St R T A 4.12.2 Isophorone dilsocyanale 2290 B siP 2 2G Con t . Dry St e T C( c ),O 4.9, 4.12 .5, 4 . 13.1,

4.14 .1, 4.15.2 Isoprene 12 16 e Sip 3 2G Cont. No SP R F B 4.10, 4 . 11 , 4. .18 .1 ,

4 .18 .2 Isopropanolamine e sip J 2G Open No St o F- T A 4.12.2, 5 . 2.1, 5 .2 B -l sopropylamine 1221 e SIP 2 2G Cont. No SP C F-T e,o 4.9, 4 .11, 4 .12. 2, 4.14,

~

4 .17 lsopropylbenzene 1918 B P J 2G Cont. No SP R F A 4. 14.1 Isopropylcyclohexane Ie ) P J 2G Cont. No SP R F A 4.14.1, 5 . 2 .6 , 5 .2.7 Isopropyl ether 1159 0 S J 2G Cont. Inert SP R F A 4 .2.7, 4.10.3, 4.14 .1 lsoval eraldehyde 2058 e SiP J 2G Con t . Inert SP R F-T A 4.2.7, 4.15. I Lactonitrile solution (80\; or less) . 8 SiP 2 1G Cont. No St e T A,C, D 4.4 , 4.9, 4 .12.6, 4.13,

4 .14, 4 . 17 , 4 .18, 5.2.5 Lauric acid B P J 2G Open No St 0 No A 4.14.1,5.2.5,5.2.8,5A..2.2 Ma leic anhydr ide 2215 0 S J 2G Cont. No St R No A{gl, C Mercaptobenzothiazol , sodi um salt solution B SiP 3 2G Open No St 0 No No 4 .12.1 , 4 . 14.1, 5.2.8


• b c d e f 9 h k 1 m

Hesity1 oxide 1229 0 S 3 2G COnt. No SP R F-T • 4.14.1 Hetam sodium solution • SiP 3 2G Ope" No St o No No <. .12.1, 4. .14.1 Hethecrylic acid 253 1 0 S 3 2G COnt. No St R T • 4.10, 4 . 12.&, 4.16. 1 Hethacryloni t rile 3079 (8) sIP 2 2G Cont . No SP e F-T • 4.9, 4. .10. 4 .12.4 .

4.13.1, 4. 14 , 4.17

Methyl acrylate 1919 8 SiP 2 2G Cont. No SP R F-T 8 4 .10, 4.14.1, 4. .11, 4.18 . 1, 4.18. 2

Methylamine solutions (42\ or less) 1235 e SiP 2 2G Cont. No SP e F-T A,C,D 4.9, 4.12 .1, 4.13. 1, <1 .14. 4.17

Hethylamyl acetate 1233 (e) P 3 2G Cont. No SP R F A 4.14.1

Hethylamyl alcohol 2053 (e) P 2G Cont. No SP R F • 4.14.1

Methyl amyl kelone 1110 (e) P 3 2G Cont. No SP R F • 4.14.1 Methyl butyrate 1237 (e) P 3 2G Cont. No SP R F • 4.14.1 Helhylcyclohexane 2296 (e) P 3 2G Cont. No SP R F A 4. .14.1 Hethylcyc!opentadiene dimer (8) P 3 2G Cont. No SP R F 8 4. .14.1 2- Hethyl- 6- ethyl aniline e sip 3 2G Ope" No St 0 No B,C,D ::; 2-Hethy! - S-ethyl pyridine 2300 (B) SiP 3 2G Ope" No St o No 0 4.12.4, 4.14.1

Methyl fonnate 1243 0 S 2 2G Cant. No SP R F-T A 4 . 9, 4.11, 4.14, 4.11 Hethyl heptyl ketone B P 3 2G Cant. No SP R F • 4.14.1 2-Hethyl-2-hydroxy-3-butyne III S 3 2G Cant. No SP R F - T A,C,D 4.12.8,4.14.1

He thyl methacrylate 12 41 0 S 2 2G Cant. No SP R F- T B 4.10, 4.18.1, 4.18 2

2-He thy l -l -pentene 2288 e P 3 2G Cant. No SP R F • 4.14 .1 2-Hethylpyridine 2313 8 SiP 2 2G Cant. No SP e F ',e 4.9.3, 4.12.4, 4 . 14.1

4- Hethy l pyridine 2313 8 siP 2 2G Cont. No SP C F-T A,C,D 4.9.3, 4.12.4, 4.14, 5.2 .8

N-Methyl - 2- pyrro lidone B P 3 2G Ope" No st o No • 4.14.1


• b , d e f g h i k m

Methyl salicylate (B) P 2G Open No st o No A <1.14.1 alpha -Melhylstyrene 2303 A sip 2G COnt . No SP R F-T 0 <1. 10, <1.14. 1, <1.16.1,

4. 18.2 Morpholine :lOS4 0 5 2G Cont. No SP R F A 4. 12 2 Motor fue l anti-knock compounds 1649 • SiP IG Con t . No SP C F-T B,C 4.6, 4.9, 4.13.2, <1 .1 4 ,

<1 . 17 Naphthalene (molten) 2304 • SiP 2 2G Con t . No SP R No ',0 4. H.l Naphlheni c acid s A P 2 2G Ope n No St 0 No A 4.14.1 Neodecanoic acid C P 3 2G Open No 51 o No • 5.2.7 tHtratlng acid (mixt ure of suiphuT1C and nitric 1796 (C ) sIP 2 2G Cont. No St C T No <1 .8, 4.13 . 1, 4.14, acids) 4 .15.2, 4.17 Nitric acid (less than 70%) 2031 C sIp 2 2G Cont. No 51 R T No 4.8, 4.14, 4.17 NltriC acid (70\ and over) 2031, C SiP 2 2G Cont. No St C T No 4.B, 4.14, 4.17

20J2(h ) Njtrobenzene lE,e,2 B SIP 2 2G Cont. No 51 C T 0 4.9, 4.13, <1.14. 5.2.8 -o- Ni trophenol (molten) 1663 B SiP 2 2G Cont. No St C T A,C,D 4.9, 4 .14.1, 5 2 .5, ~

5.2.8, 51\.2 . 2 1- or 2-Nil ropropane 2608 0 5 3 2G Cont. No SP R F - T A Nitropropane (60\ )/Nitroethan~ (40\ ) mixture 0 5 3 2G Cont. NO SP R F- T A,C(n) 4.12.4 0 - 01" p-Nitl"ololu~nes 1664 .C siP 2 2G Cant. No st C T B 4.9, 4 . 13 .1, 4.14, 5.2.8 Nonane (all isomers) 1920 (C ) P 3 2G Cant. No SP R F B,C 4 . 14.1 Nonene B P 3 2G Cant. No SP R F R 4 .14.1 Nonyl alcohol (all isomers ) C P 3 2G Open No St 0 No A Nony lpheno 1 • P 2 2G Open No St 0 No • 4.14.1 Nonyl phenol paly{4-12) ethoxyla les B P 2G Open No St 0 No A 4.1 4 . L 5.2.5, 5.2.8,

5A.2.2(y)


"

, b c d • 9 h , ) k 1 m

NOX1 0 US llquid. N.Y, (1) n.o.s. ( trade neme .... A P 2G Open No St 0 No A 4.14 contains •• o j S T . 1. Cat.A" Noxious llquid, r. (2 ) n.o.s. (trade neme 0.', A P 2G Cont. No SP R r A 4.14 contains ... ) S.T .1, CaL A" Nox ious liquid, N.F. ()) n.o.s. (trade nem • .. " A P 2 2G Open No St 0 No A 4.14.1 contains ... ) 5.T. 2, Cat.A" Noxious liquid, r. (4 ) n.o.s. (trade neme -.-, A P 2 2G COnt. No SP R P A 4.14.1 contains ... ) S.T.2, CaLA" NOX1OUS liquid, N.F, (5) n.o.s. ( trade name a p 2 2G Open No St 0 No A 4.14 . 1 . (5.2.5, 5 .2.8 '''· contains ... ) S.T.2, CaLS" Noxious hquid. N.F , ( 6) n.o.s. (trade nam. a p 2 2G Open No St 0 No A 4.14.1, [5.2.5)"·, contains .. . ) S.T.2, Cat.B", mp l Soc+ 5.2.8, SA.2.2 Noxious liquid, F. (1) n .o.S. (trade neme a p 2 2G Cont. No SP R F A 4.14.1, [5.2.5, 5.2.Bi*-contains .. . ) S.T.2. eat.s" Nox ious liquid, F. (B) n.o.S. ( trade nerne a P 2 2G Cont. No SP R F A 4 . 14.1. {5 .2.S ,", contains ••• J S.T.2, CaLS" • mp lS"C-t- S.2.B, SA.2.2 Noxious liquid, N.F, (9) n.O.S. (trade neme ... , A P 3 2G Open No St o No A 4.14.1 contains ... ) S.T.3, Cat. A-Noxious liquid, F. (10) n.o.s. (trade nerne ... , A P 3 2G COnt. No SP R F A 4.14.1 contains ... ) S.T.3, Cat.A· Noxious liquid, N.F, (11) n.o.s. (trade neme .... a p 3 2G Open No St 0 No A 4.14.1, [5.2 .5,5.2.8]** contains ... ) S.T.3, Cat.B· Noxious liquid, N.F. (12) n. O. s . (trade neme ... , a P 3 2G Op.n No st 0 No A 4 . 14.I,[5.2.51**.5.2.0,5A..2.2 contains ... ) S.T .3 , Cat.B- , mp 15"C+ Noxious liquid, F. ( 13) n.o.s. (trade name ... , a P 3 2G COnt. No SP R F A 4.14.1, [5.2.5, 5.2.B]·" contains ... ) S.T.3, Cat.B·

In case of a specific n.o . s. cargo assessed as falling within this n.o.s. group that is carried on a ship, this entry. including the cargo's trade name and one or two principl e components, should be provided in the shipping document. Abbreviations used mean:

N.F: Flasl<j?)int eJeeeding rooe (closed cup test) f: flashooint oot exceeding 6O~C (closed cup test) n.o.s.: Not otherwise spec1rled

S. T: Cat. : m.p . :

Ship t.ype Pollutton category Mel tlng point

t. For hlgh viscosity or high melting point. cargoes.

~

~


a b , d e f 9 h i k m

Noxious liquid, F , (14 ) n.o.s. {trade name B P 3 2G Cont. No SP R F A 4.14.1, 15.2.5]** , contains ... j S.T.3, Cat. B"', mp lS"'C+ 5.2.8, SA.2.2 No:dous liquid, N.F, (15) n.o.s. ( trade name . .. , C P 3 2G Open No st 0 No A 15.2.6 to 5.2.8) *" contains ... j S.T.3, Cat. C· Noxious liquid, F , (16) n .o. s. (trade name G P 3 2G Cont . No SP R F A [5.2.6 to 5.2 .8)·" contains ... j S.T . 3 , CaLC" Octane (all i somers) 1262 (Gj P 2G Cont. No SP R F A 4.14.1

Octanol (all isomers) C P 3 2G Open No St o No A

Octene (all i somers) B P 3 2G Cont. No SP R F A 4.14.1 Oetyl a ldehyde s 1191 (B) P 3 2G Cont. No SP R F A 4.14.1, S.2.8 Oetyl nitrates (all isomers) A SiP 2 2G Open No st 0 No B -4.14. 1 , 4.1B, 4.22

Olefin mixtures (CS-C7) C P 3 2G Cont . No SP R F A 4.14 .1

Olefin mixtures (CS-C15 ) B P 3 2G Cont. No SP R F A 4.14.1 alpha - Ol etins (CG-CIS) mixtur es H P 3 2G Cont. No SP R F A 4 . 14.1, 5.2.5, 5. 2 . B Oleum 1831 C SiP 2 2G Cont. No St C T No 4.8 .2 to 4 . B.8, 4.9.1,

4.13 . 1, 4.14,4.15.2. 4.17 , 5.2.6. 5.2.7

N Palm nut oil fatty acid (C) P 3 2G Open No st o No B 5.2.6 to 5.2.8 0

Paraldehyde 1264 C SiP 3 2G Cant. No SP R F A 5.2 . 8 Pentachloroethane 166g- B SiP 2 2G Cant. No St R T No 4.9, 4.13.1, 4.14 . 1

1.3-Pentadiene C SIP 3 2G Cant. No SP R F-T B 4.10, 4.18 Pentane (all isomers ) 12&5· ( C) P 3 2G Cant. No SP R F A 4.14.1

Pentene (all isomers) C P 3 2G Cant. No SP R F A 4.14.1 Perchloroethylene 1691 B SiP 3 2G Cant. No St R T No 4.9.1. 4 . 9.2. 4.14.1

Phenol 231? B sip 2 2G Cant. No st C T A 4.9, 4.14, 5.2.5, 5.2.8, SA.2.2

• See footnote on page 19.

lJ For high v i scosity or high melting point cargoes.


, b c d e 9 h i k m

l~Phenyl-l-y.Ylyl ethane C P 3 2G Open No St 0 No • Phosphoric acid 1805 D 5 3 2G Open No St 0 No No 4.8.1 to 4 .S.4, 4.8.6 to 4.8.8

Phosphorus, yellow or white 1381, A SIP IG Cont. Pad-t.(Vent 5t C No C 4.5. 4.14, 4.11 2447 or Inert)

Phthalic anhydride (mollen) 2214 C 5/P 3 2G Cont. No 5t R No D 5.2.6 to 5.2.8 Pinene 2368 • P 3 2G Cont. No 5P R F A 4 .14.1 Polyethylene polyamines 2734(1) (C) SiP l 2G Open No St 0 No A 4.12.2, S.2.8

2"135 Polyferric sulphate solution (C) Sip 2G Open No St 0 No A 4.12.10 Polymethylene polyphenyl isocyanate 2206(i) D 5 2 2G Cont. Dry 5t C T(b) C{c ),O 4.9, 4.12.5, 4.14 .1,

2207 (b) 4.15.2 Potassium hydroxide solution 1814 C sip 3 2G Open No St 0 No No 4.12.1 (aa). 5.2.8 n- Propanolamine C SiP 3 2G Open No St 0 No A,D 4.12.2, 5.2.8 beta-Propiolactone D 5 2 2G Cont. No St R T A Propionaldehyde 1215 D 5 3 2G Cont. No SP R F -T A 4.13 .1, 4 .IS.1, 4.17 PropioniC acid 1848 D 5 3 2G Cont. No SP R F A 4.8.2 to 4.8.4, 4.S.6 to ~

~

4.8.8, 4.12.6, 4. 17 Propi onic anhydride 24'36 C 5/P 3 2G Cont . No St R T A 4 .12.6 Propionitrile 2404 C SiP IG Cont. No SP C F-T A,D 4.9, 4.13, 4.14 , 4.17 n-Propylamine 1277 C 5/P 2 2G COnt. Inert 5P C F-T C,D 4.9, 4 .12.2, 4.14, 4.11 n-Propylbenzene (C) P 3 2G Cont. No 5t R F A 4 . 14.1 Propylene dimer (C) P 2G Cont. No 5P R P A 4.14.1 Propylene oxide 1280 D S 2 2G Cont. Inert 5P C F-T A,C 4.7. 4.9.l. 4.11, 4.14 Propylene tetraJner 2850 • P 3 2G Cont. No SP R F A 4.14.1 Propylene trimer 2051 • P 3 2G COnt. No SP R F A 4.14.1


a b c d e 9 h j k 1 m

Pyridine 1282 D S 3 2G Cont. No SP R F R 4.12.4, 4.14 .1 Rosln 8 P 3 2G Open No St 0 No R 4.14.1, 5.2.5, S.2.S,

511..2.2 Rosin soap ( Oisproportionated) solutio n 8 P 3 2G Open No St 0 No R 4.14.1 Sodium borohydri de {IS\ or l ess )/SOdium hydroxide C sIP 3 2G Open No St 0 No No 4.12.1, 5.2.6 solution Sodium chlorate solulion (50\ or l ess) 2428 III S 3 2G Open No St 0 No No 4.1<1.1, 4.15. I, 4.21 Sodium dichromate solution (70\ or less) C siP 2 2G Open No st C No No 4.9.3, 4.12.2, 4 . 14 Sodium hydrogen sulphite solution (35\ o r less) 2693 D S 3 2G Open No st o No No Sodium hyd rosulph ide solution (45\ or less) 2949 8 SIP 3 2G Cont. Ve nt 0' St R T No 4.14. I, 4.1S.1, 5.2.8

Pad (gas) Sodium hydrosulphi de/Ammonium sulphide solut i on 8 sIP 2 2G Cont. No SP C f-T R,C 4.9, 4.11, 4.12.1 ,

4 .13 . 1, 4.14, 4.15.1. 4. 17 • 4.18

sodium hydroxide solu tion 1824 D S 3 2G Open No St 0 No No 4.12 . 1(aa) Sod i um hypochlor ite solution (1 5\ or l e ss ) 1791 C sip 3 2G Cont. No St R No No 4. 12.5, 4. 15.1 ~

Sodium nltrite solution 1500 B SiP 2 2G Open No St 0 No No 0:1 .9 . 3. (a), 4 .9.3 . (b), ~

0:1 .14 , 4.15.1 Sod ium thiocyanale solution ( 5&\ or less ) (8) P 2G Open No St 0 No No 4 .1 4 . 1 Styre ne monomer 2055 B SiP 2G Cont. No SP 0 F 8 0:1 . 10, 4 .12. 4 , 4.14.1,

4.18.1, 4. 16.2 Sulphur (molt en) 24 48 III S 3 lG Open vent or SP o F-T No 4. 3

Pad (gas) Sulphuric acid 18 30 C SiP 3 2G Open No St 0 No No 4 .6 , 4 .15.2 , 5.2.1,

5.2.8 SulphurIc acid, spent 1832 C SiP 3 2G Ope" No St 0 No No 4.8, 4. 15.2 , 5.2.7,

5.2.&


• b c d e 9 h k 1 • Tall oil (c rude and distilled) • P ) 2G Ope" No St 0 No A <1.14.1, 5.2.5, 5.2.8,

SA..2.2 Tall oil fatty acid (resin acids less than 20\ ) (e) P ) 2G Opeo No St 0 No A 5.2.6 to 5.2.6 Tall oil soap (disproportlona t ed) solution B P ) 2G Opeo No St o No A <1.14.1. 5.2.5, 5.2.8 Tetrac hloroethane 1702 B SiP ) 2G Cont. No St R T No 4.9, 4.13 .1, 4.14 .1 Tetraethylene pentamlne 2320 0 S ) 2G Ope" No St o No A 4 .12. 1 Tetrahydrofuran 2056 0 S ) 2G Cont. No SP R F-T A,O Tetrahydronaphthalene e P ) 2G Opeo No St 0 No A 1.2,3.5-Tetramethylbenzene (e) P ) 2G Opeo No st o No A Toluene 1294 e p ) 2G Cont. No SP R F A 4.14.1 Toluenediamine 1709 e Sip 2 2G Cont. No St e T a,c,o 4.9, 4.12.1, 4.13.1,

4.14, 4.17, 5.2.6, 5.2.8 Toluene diisocyanate 2078 e SIP 2 2G Cont. Dry St C F-T C(c),D 4.9, 4.12.4, 4.13 .1,

4.14, 4.15.2, 4 .17 . S.2.8 N

~

a - Toluidine 1706 e SiP 2 2G Cont. No St e T A,e 4 .9 , 4.13.1, 4.14 Tributyl phosphate B P ) 2G Open No St o No A <1.14.1 1.2,4-Trichlorobenzene 232 1 B SiP 2 2G Cont. No St R T e 4.14.1, S.2.B, SA.2 .2 l,l,l-Trichloroethane 283,1 B P ) 2G Opeo No St o No A 4.14.1 l,I, 2-Tr ichloroethane B SiP ) 2G Cont. No St R T No 4.9.1, 4 . 14 .1 Trichloroethylene 1710 B SiP ) 2G Cont . No St R T No 4.9, 4.13.1, 4.14.1,

4.15.1 1.2,3 - Tri c hloropropane B SiP 2 2G Cont. No St e T 8, C,D 4.9, 4.13.1, 4.14 l,l,2-Trichloro-l,2.2-Trifluoroethane e P ) 2G Ope" No St 0 No No Tric resyl phosphate (contain i ng l ess than " A P 2 2G Opeo No St 0 No A 4.14.1 o r tho-isOIIIer)


, b c d , f 9 h k 1 m

Tr ieresyt phosphate ( containi ng 1\ or more 2574(j) A sip 2G Cont. No s t C No 8 -4 .9.3 , -4 . 14 o rtho-isome r) Triethano l arl1.lne 0 S 3 2G Op," No St o No A 4 . 12. 1 Triethylamine 1296 C SiP 2 2G Cont . No SP R F-T B 4.9, 4 . 12.2, 4. 17 Tri e l hyl benzene A p 2 2G Open No St 0 No A 4 . 14.1 Tri ethy l e netet ramine 2259 0 S 3 2G Open No St 0 No A 4 . 12.1 Triethyl phosphite 2323 S 3 2G Cont. No sp R F- T A, D 4 . 9. 1 Tr ime thylacetic acid D S 2G Cont . No St R No A,C 4 .8.2 to 4.8.8, 4. 12 .6 Tr i methyl benzenes (al l isomers) 8 P 2G Cont . No SP R F A 4 . 14.1 Tr imethylhexamelhylenediamine (2,2,4- and 2327 D S 3 2G Ope n No St 0 No A ,e <1 . 12. 1 , 4 . 14 .1 2, 4 ,4-isorners) t rirne t hylhexamethylene diisocya nate (2.2 . 4- and 2328 B Sip 2 2G Cont. O,y st C T A,C(c ) 4 .9, 4.13 .1, 4.14 .I. 2,4, 4-isornec s) -4 .15. 2 2.2, 4- Tr imethyl-I.J-pen t aned i o l - l -isobutyrate e p 3 2G Open No St 0 No A Trime thyl phosphite 2329 S 3 2G Cont. No SP R F-T A,D 4 .9 . 1 , -4 .14. 1, -4. 15.2

~ ~

Trixyly l phosphate A p 1 2G Open No st o No A 4 . 14 TU rpentine 1299 8 P 3 2G Cont. No SP R F • 4 . 14 .1 Undecanoic acid Ie) P 3 2G Open No s t 0 No A 5 .2. 6 to 5.2 . 8 l -Undecene 8 P 3 2G Ope n No St 0 No A 4 . 14 . 1 Undecyl alcohol. B P 3 2G Open No St o No A 4.14.1, 5 .2.B. SA..2 .2( r) Urea/Ammonium nitrate sol ut ion (containing a qua e Si P 3 2G Cont . No SP R T A 4.12. 4. 4 . 12 .9 ammonia) n- Va lera ldehyde 2058 D S 3 2G COnt. I nert SP R F-T A 4 . 2 .1 , 4 _ 15. 1 Vi ny l acet a te 1301 C sIp 3 2G Cont . No SP 0 F A 4. 10, 4.18 . 1, 4 .18.2 Viny l e t hy l ethe r 1302 e SiP 2 1G Cont. Ine r t SP e F-T A 4 .2, 4.10 , 4 . 11, 4 . 12 B,

4 . 14, 4 . 11, 4 . 18 .1 , 4 . 18 . 2


MEPC 27/16 A.NNEX 4 Page 2S

• b , d e f 9 h i k 1 m

Vinylidene chloride 1303 B sip 2 2G Cont. Inert SP R F-T B 4.10, 4.11, 4.12. S, 4.14 .1, 4.11, 4.18.1, 4.18 .2

Vinyl neodecanoate B sip J 2G Opeo No St o No B 4.10, 4.14.1, 4. 15.1, 4.18.1, 4.16 .2

Vinyl toluene 2618 A SiP J 20 Cont. No SP R F D 4.10, 4.12. 1, 4 . 14.1. 4.16.1, 4. 18.2

White spir.it. low (lS-20\) aro!!lat ic 1300 (B) P 2 20 Cont. No SP R F A 4.14.1 Xy1enes 1307 C P J 20 Cont. No SP R F A 4.14 .1, S.2 .8(u) Xy1enol 2261 B sip 3 2G Open No st o No B 4.14 .1, 5.2.6, SA-.2.2 ~

~


- 26 -

7 Footnotes for the BC" Code:

a Provision 4.17 applies to Ammonia aqueous, 28% or les s but not belo~ 10%.

Ammonia aque ous (28% or less)

b If the product t o be carried contains flammable solvents such that the flashpoint does not exceed 60 · C c.c., then special electrical systems and a flammable vapour detector should be provided.

Diphenylmethane d iisocyana te Polymethylene polyphenyl isocyanate

c Although vater is suitable for extinguishing open-air fires involving chemicals to which this footnote app l ie s, vater should not be allo~ed to con taminate closed tanks containing these chemicals because of the risk of hazardous gas generation.

Diphenylmethane di isocyanate I sophorone diisocyanate Polymethylene polyphenyl isocyanate Toluene diisocyanate Trimethylhexamethylene diisocyanate (2,2,4- & 2,4,4-isomers)

d UN No.1198 only applies if fl3shpoint is below 60°C c . c .

Formaldehyde solution (45% or less)

e Provision 4.17 applies to Formaldehyde solutions 45% or less, but not belo~ 5%.

Formaldehyde solutions (45% or less )

Provision 4 . 17 applies to Hydrochloric acid not below 10%.

Alumi num chloride ()O% or less)/Hydrochlor i c acid (20% or less) solution Hydrochloric acid

g Dry chemica l cannot be used because of the possibility of an explosion .

Maleic anhydride

h UN No.2032 assigned to Red fuming nitric acid.

Nitric acid (70% and over)


- 27 -

UN number de pends on boiling poi nt of subst anc e.

Polyethylene polyamines Po lymethylene polyphenyl isocyanate

UN number as signed to this substance contain i ng more than 3% of ortho- isomer.

Tri c r esyl phospha t e ( con taining 1% or more ortho-isomer)

k UN number only applies to 2- Chlo r op r opionic acid.

2- or 3-Chloropropionic acid

Dinitrotoluene s hou ld not be carr ied in deck tanks.

Dinitrotoluene (mol ten )

m Temperature sensors should be used to monitor the cargo pump t empera t ure to detec t overheating due to pump failures.

Dinitrotoluene (molten )

n Dry chemical should not be used as a fire-fighting medi um.

Nitropropane (60%)/Ni troe thane (40%) mixt ure

o UN No.2672 refers to 10- 35% Ammonium solution.

Ammonia aqueous (28% or less)

p Applies to n-Decyl alcohol onl y .

Decyl alc ohol (all isomers)

q Requirements are based on t hose isomers having a flashpoint of 60w

C c.c., and the r efore the requirements based on f lammability woul d not apply to s uch isomers .

Hep t anol ( al l isomers)

r Provision 5A.2.2 applies to l-Undecyl a l cohol only.

Undecyl alcohol

s UN No.1114 applies t o Benzene.

Be nzene and mixtures havi ng 10% benzene o r more

t Confined s pace should be tested for both Formic acid vapours and Carbon monoxide gas, a decomposition pr oduct.

Formic acid


- 28 -

u App l i es to p- Xyle ne onl y.

Xyle nes

v Appl ies t o p-isomer and mixtu res containing p-isome r viscosity of which is 25 mPa . S at 20 "C .

Dichlorobenzenes (all isomers)

w Applies to p-isomer and mixtures containing p- isomer mel t ing point of which is O·C and above .

Dichlo r obenzenes (all isomers)

x Appl ies to e-isomer and mixtures containing p- i somer mel ting point of wh ich is 15 C and above.

Dic h lorobenzenes ( al l isomers )

y Applies onl y to products .... ith melting point of I s "C and above .

Nonyl phenol poly(4-12}et hoxyla t es

z Aluminium not pe r mitted.

Ch lo r oacetic ac id (80% or less ) 2,2-Dichloropropionic acid

aa Co ppe r , Brass and Bronze may be used .

Potassium hydroxide solution Sodium hydroxide solution

8 Chap t er VII of the BCM Code should be replaced by the following :

"CHAPTER VII - LI ST OF CHEM I CALS TO WHICH THE CODE DOES NOT APPLY

The following are products which are not conside red t o come wi th in the

scope of t he Code . Thi s lis t may be used as a guide i n conside ring bu lk

carriage of pr oducts whose hazards ha ve not yet been eva lua ted .

2 Although the products listed i n t his c hapter fall outside the scope of

the Code, the attention of Administrations is drawn to the fac t that some

safety pr ecaut ions ma y be needed for their safe transportation. Accordingly ,

Administrations should prescribe appropr iate safety reQuireme nts .


Product name

(column a)

UN number

(column b)

- 29 -

EXPLANATORY NOTES

In some cases, the product names may not be identical

with the names given in previous issues of the BeB Code or

the IBC Code (for explanation see index of chemicals ).

The number relating to each product shown in the

recommendations proposed by the United Nations

Committee of Experts on the Transport of Dangerous Goods.

UN numbers, wher e available, are given for information

only.

Pollution category The letter 0 means the pollution category assigned to

(column c) each product under Annex II of MARPOL 73/78. "Ill" means

the product was evaluated and found to f a ll outside the

categories A, B, C or D.

Pollution category in brackets indicates that the product

is provisional l y categorized and that further data are

necessary to comple te the evaluation of their pollution

hazards. Un til the hazard evaluation is completed, the

pollution category assigned is used.


- 30 -

a b c

UN Pollution number Category for

operational Product name discharge

(regulat ion 3 of Annex II)

Acetone 1090 III

Alcohols (Cl3 and above) III

Alcoholic beverages, n.o.s . 3065 III

Alkyl (C9-C17) benzenes (D)

Aluminium sulphate solution D

Aminoethyldiethanolaminel Aminoethylethanolamine solution III

2-Amino-2-hydroxymethyl- III l,3-propanediol solution (40% or less)

Ammonium sulphate solution D

n-Amyl alcohol 1105 D

sec-Amyl alcohol 1105 D


a

tert-Amyl alcohol

Amyl alcohol, primary

Animal and fish oils, n.o.s. including;

Cod liver oi 1 Sperm oil

Apple juice

Behenyl alcohol

Benzene tricarboxylic acid, trioctyl ester

Srake fluid base mix: (Poly (2 - 8) alkylene (C2-C) glycolsl Polyalkylene (C2-CIO) glycols monoalkyl (Cl-C4) ethers and their borate es ters)!1

sec-Butyl acetate

n-Butyl alcohol

sec-Butyl alcohol

tert-Butyl alcohol

Butylene glycol

Butyl stearate

- 31 -

b

1105 III

1105 D

D

III

III

III

D

1123 D

1120 III

1120 III

1120 III

D

III

l/ Use "Srake fluid base mix" as a proper name on the Shipping document.


•

gamroa-Butyrolactone

Calcium carbonate slurry

Calcium hydroxide slurry

Calcium nitrate/Magnesium nitrate / Potassium chloride solution

epsilon-Caprolactam (molten or aqueous solutions)

Cetyl/Stearyl alcohol

Chlorinated paraffins (C 14-C17) (with 52% chlorine)

Choline chloride solutions

Clay slurry

Coal s lurry

- 32 -

b

Coconut oil fatty acid methyl ester

Decahydronaphthalene 1147

Decylbenzene

Dextrose solution

D

III

D

III

D

III

III

D

III

III

D

(D)

D

III


- 33 -

a

Diacetone alcoho l

Diethylene glycol

Diethylene glycol butyl ether

Diethylene glycol butyl ether acetate

Diethylene glycol dibutyl ether

Diethylene glycol diethyl ether

Diethylene glycol ethyl ether

Diethylene glycol ethyl ether acetate

Diethylene glycol methyl ether acetate

Diethylenetriamine pentaacetic acid, pentasodium salt solution

Di-(2-ethyl hexy l ) adipate

Diheptyl phtha l ate

b

1148

,

o

o

III

III

(0 )

o

III

III

(0)

(0)

III

o

III


- 34 -

•

Dihexy l phtha l at e

1,4-Dihydro-9,l O-dihydroxy anthracene , disodium salt solution

Diisobutyl ketone

Diisodecyl phthalate

Diisononyl adipate

Diisooctyl phthalate

Diisopropyl napht halene

2,2-Dimethylp r opane-I,3-d iol

Dinonyl phthalate

Dioctyl phthalate

Dipropylene glycol

Dipropylene glycol methyl ether

Ditridecyl phthalate

Diundecyl phthalate

Dodecane (a ll isomers)

b

1157

,

III

D

D

D

o

II I

o

(D)

o

III

III

(D)

o

o

II I


•

Dodecenyl succinic acid, dipotassium salt solution

Dodecyl be nzene

Drilling brines:

Calcium bromide solution Calcium chloride solution Sodium chloride solution

2-E t hoxyet ha nol

Ethy l acetate

Ethyl acetoacetate

Ethyl a l cohol

Ethylene carbonat e

Ethylenediamine tetraacetic acid, tetrasodium salt solut ion

Ethylene glycol

Ethylene glyco l acetate

Ethylene glycol butyl ether

Ethylene glycol tert-butyl ether

Et hy l ene glycol isopropyl ether

Ethy l ene glyco l me thy l butyl ethe r

- 35 -

b

(0)

III

III

1171 o

1173 o

(0)

11 70 III

III

o

o

(0)

2369 III

III

o

o


- 36 -

• b

Ethylene g l ycol methyl ether 1188

Ethylene glycol methyl ether acetate 1189

Ethylene glycol phenyl ether

Ethylene glycol phenyl ether/ Diethylene glycol phenyl ether mixture

Ethylene-vinyl acetate copolymer (emulsion)

2-Ethylhexanoic acid

Ethyl pro pionate

Fatty acid (saturated Cl3 and above)

Ferric hydroxyethylethylene diamine tr iacetic acid, trisodium salt solution

Formamide

Glucose solution

Glycerine

Glycerol po l ya lkoxylate

1195

,

D

D

D

D

III

D

D

III

D

D

III

III

III


- 37 -

a b ,

Glyceryl triacetate (11 I)

Glycine, sodium salt solu tion 111

Glyoxal solution (40% or less) 0

n-Heptanolc acid 0

Hexamethylenediamine adipate (SO% in water) 0

Hex81l1ethylene glyco l III

Hexamethylenetetramine solutions 0

Hexanoic acid 0

Hexano 1 2282 0

Hexylene glycol III

N-{Hydroxyethyl) ethylenediamine triacetic acid, trisodium salt solution 0

Isoamyl alcohol llO5 0

Isobutyl alcoho l 1212 III

Isobutyl foma te 2393 0

lsophorone 0


•

I sopropyl acet at e

Isopropyl alcohol

Kaolin slurry

Lactic acid

Lard

Latex:

Carboxy lated styrene-but adiene copol ymer

Styrene-Butadiene rubber

Lignin su l phonic acid, sodium salt solution

Magnes i um chloride solution

Magnes i um hydroxide slurry

3-Methoxy-l-butanol

3-Methoxybutyl acetate

Methy l ace tate

Methy l acetoacetate

Methyl alcohol

- 38 -

b ,

1220 III

121 9 III

III

D

III

II I

III

III

III

III

D

1231 II I

D

1230 III


a

Methyl buteno1

Met hyl cert - butyl ether

Methyl butyl ketone

Methyl butynol

Methyl ethyl ke tone

Methyl isobutyl ketone

)-Methyl-)-methoxy butanol

3-Methyl-)-methoxy butyl acetate

Molasses

Naphthalene sulphonic acid/ Forma Ide hyde copolymer, sodium salt solution

Nitrilotriacetic acid, trisodium salt solution

Nonanoic acid (all i somers )

Nonyl methacrylate monomer

- 39 -

b c

(D)

2398 D

D

D

1193 III

1245 D

III

III

III

D

D

D

(D)


•

Noxious liquid , n. o. s. (17) (trade name •• . , contains ••• ) Cat . D .. !.I

Non- nox ious l i quid, n.o.S. ( 18) (trade name •••• contains ••• ) Appendix 11111

Octanoic acid (all isomers )

n-Oeey1 acetate

Octyl decyl adipate

Ol ef i ns ( e13 and a bove , all isomers)

Oleic acid

Palm oil fatty acid methyl ester

Palm stearin

n- Paraff in s (CIO-C20)

- 40 -

b c

D

III

D

1262 D

III

III

III

D

D

D

III

11 I n case of a s peci fic n.o . s. (not otherwise specified ) cargo assessed as falli ng within this n. o . s. grou p that i s carried on a ship , this entry, including th e cargo's trade name and one or two pr incip l e components , s hould be provided in the shipping document.


- 41 -

a b ,

Paraffin \.lax III

Pentaethylenehexamine D

Pentanoic acid D

Petrolatum (11 1)

Pol ya lumin ium chloride solution III

Poly butene III

Po l yethylene g l yco l 111

Polyethylene glyco l dimethyl ether III

Polypropylene glycol D

Polypropylene glycol methyl ether III

Polysiloxane III

n- Propyl acetate 1276 D

n-Propyl alcohol 1274 III

Propy lene/Butylene copolymer III

Propy lene g l ycol III

Propylene glycol ethyl ether (0)


- 42 -

a b

Propylene glycol methyl ether (0)

Propylene glycol monoalkyl ether (0)

Sodium aluminosilicate slurry III

Sodium carbonate solution o

Sodium silicate solution o

Sorbitol solution III

Sulpholane o

Tallow D

Tallow fatty acid (0 )

Tetraethylene glycol III

Tridecane III

Tridecanoic acid (III)

Triethylene g l ycol III

Triethylene glycol butyl ether III

Triethylene glycol ethyl ether (0 )

Triethylene glycol me t hyl ether (0)


- 43 -

,

Triisopropanolamine

Trimethylol propane polyethoxylate

Tripropylene glyco l

Tripropylene glycol methyl ether

Urea/Ammonium mono- and di-hydrogen phosphate/Potassium chloride solut ion

Urea / Ammonium ni trate sol ution

Urea/Ammonium phosphate solution

Urea formaldehyde re sin solution

Urea so lution

Vegetable oil, n.o. s . including: Castor oil, Coconut oil. Corn oi l, Cotton seed oi l, Groundnut oil, Linseed oil, Olive oi l. Palm nut oi l , Palm oil. Rape seed oi l , Ri ce bran oil. Saffloyer oil, Sesame oil, Soya bean oi l, Sunflover oil, Tung oil

Vegetable protein solution (hydrolysed)

Water

b

***

c

III

o

I II

(0)

(0)

o

o

III

III

o

II I

III


resolution mepc.33(27) adopted on 17 march 1989. …

Documents