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  • es EnvironmentalStrategiesPROVIDING BENEFITS

    www.environmentalstrategies.com.au

    > PROVIDING BENEFITSes

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 16021

    Document Information

    Client: Prysmian Power Cables & Systems Australia Pty Ltd

    Project: Groundwater Monitoring Event (GME) - Liverpool

    Project Number: 16021

    Report Title: February 2016 Groundwater Monitoring Event.

    1 Heathcote Road, Liverpool NSW

    Date: 19 February 2016

    Document Name: 16021RP01-Final

    Revision Number Revision 0

    Written By:

    Colin Biggs

    Environmental Scientist

    Reviewed By:

    Dean Stafford

    Senior Environmental Scientist

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 16021

    Table of Contents

    Executive Summary ............................................................................... i

    1 Introduction ................................................................................... 1

    2 Site Condition and Surrounding Environment ................................. 4

    3 Sampling and Analysis Plan and Sampling Methodology ................ 6

    4 Field Quality Assurance and Quality Control (QA/QC) .................... 7

    5 Laboratory QA/QC .......................................................................... 9

    6 Assessment Criteria ...................................................................... 10

    7 Results ......................................................................................... 12

    8 Conclusions and Recommendations ............................................. 14

    9 References ................................................................................... 15

    Appendices Appendix A Figures Appendix B Groundwater Result Summary Tables Appendix C Groundwater Field Sheets Appendix D Laboratory Certificates

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW i 16021

    Executive Summary

    Environmental Strategies Pty Limited (ES) was commissioned by Prysmian Cables & Systems Australia Pty Ltd (Prysmian) to conduct a Groundwater Monitoring Event (GME) in accordance with the ES (November 2013) Environmental Management Plan (EMP) for a portion of the site known as the coolant leak area located at 1 Heathcote Road, Liverpool NSW (the site). The site location is provided on Figure 1, Appendix A and the site layout in Figure 2, Appendix A.

    A coolant leak was first identified in February 2012 within Factory 2 of the site, where an estimated 10,000 – 11,000L of coolant (hydrocarbon/water mixture) was lost to the subsurface due to a fault that had developed within an in-ground concrete pit.

    Prysmian made a commitment to conduct monthly monitoring of groundwater around the in-ground pit for an initial three (3) month period with the last event occurring in February 2014. The data trends at the end of the three months of monitoring indicated that the groundwater was not impacted by the leaking pit.

    The NSW EPA voiced concerns that the identified petroleum hydrocarbons in the soil may migrate to underlying groundwater. ES concluded that the hydrocarbons in soil have not impacted underlying groundwater at the time and are unlikely to migrate into the deeper soil profile. Nevertheless, as a due diligence measure, the Remedial Action Plan (RAP) prepared by Prysmian Group (June 2013) recommended that ongoing groundwater monitoring be incorporated into the site’s EMP. A less frequent monitoring period was justified and a 12 monthly groundwater monitoring program was adopted. However if groundwater at any time is shown to have been impacted by the contaminants of concern as triggered by the assessment criteria, then contingency options will be assessed.

    This report presents the results of the 12 monthly GME.

    The results of the February 2016 GME are summarised as follows:

    Groundwater analytical results reported all contaminants of concern (total recoverable hydrocarbons (TRH), benzene, ethylbenzene, xylenes and naphthalene (BTEXN)) were either below laboratory limit of reporting (LOR) or the adopted groundwater acceptance criteria (GAC);

    With the exception of copper at MW4 (5ug/L), concentrations of heavy metals were reported below the GAC;

    Given that no hydrocarbons were reported above the adopted groundwater criteria, this indicates that groundwater has not been impacted by the leaking coolant tank.

    Based on the above conclusions, and the results of the ES (June 2013) Supplementary Soil and Groundwater Investigation, ES consider that the coolant leak has not impacted the underlying groundwater and recommends that no further groundwater monitoring (other than that conducted as part of the facility’s due diligence) is required.

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 1 16021

    1 Introduction

    1.1 Background

    Environmental Strategies Pty Limited (ES) was commissioned by Prysmian Cables & Systems Australia Pty Ltd (Prysmian) to conduct 12 monthly Groundwater Monitoring Events (GMEs) as specified in an ES (November 2013) Environmental Management Plan (EMP) for a portion of the site known as the coolant leak area located at 1 Heathcote Road, Liverpool NSW (the site). The site location is provided on Figure 1, Appendix A and the site layout in Figure 2, Appendix A.

    A coolant leak was first identified in February 2012 within Factory 2 of the site, where an estimated 10,000 – 11,000L of coolant (hydrocarbon/water mixture) was lost to the subsurface due to a fault that had developed within an in-ground concrete pit. Following submission of a pollution incident report and sampling plan by MJM Environmental, Benbow Environmental (BE) were commissioned in July 2012 to undertake an Environmental Site Assessment (ESA) to investigate the extent of the release.

    Investigations of soil and groundwater were undertaken by Benbow Environmental Pty Ltd (BE) and ES in 2013.

    The results of the BE (January 2013) Environmental Site Assessment and the ES (June 2013) Supplementary Soil and Groundwater Investigation can be summarised as follows:

    Soil results as reported by BE showed that sample locations 7, 8 and 9 contained contaminant concentrations below health based criteria but exceed the NEPM (2013) Commercial/Industrial Management Limits for coarse soil at depths ranging between 2 and 4.5m below ground level (bgl);

    Impacted soils are localised to the southern and eastern portion of the in-ground pit, between 2 and 4.5m bgl;

    The results of the ES soil investigation reported no exceedances of hydrocarbons in soil above the adopted criteria (or concentrations above laboratory detection limits) at depths greater than 4.5m bgl;

    Groundwater analytical results reported all contaminants of concern (TRH, BTEX, PAH and heavy metals) below laboratory reporting limits and the adopted groundwater acceptance criteria (GAC) with the exception of copper and zinc, for which reported concentrations were marginally above the GAC. ES consider that the concentrations of copper and zinc detected in groundwater are unlikely to be related to the coolant use/spill. The concentrations of copper and zinc are likely representative of local background levels and are unlikely to pose a risk to human health and the environment;

    No TRH concentrations were reported above the adopted groundwater criteria indicating that groundwater had not been impacted by the leaking coolant tank; and

    The soil and groundwater around the tank were considered suitable for the continued commercial/industrial land use.

    Following the submission of BE (January 2013), ES (June 2013) and a Remedial Action Plan (RAP) prepared by Prysmian (June 2013), the NSW EPA voiced concerns that the identified petroleum hydrocarbons in soil may migrate to underlying groundwater.

    A letter report was prepared by ES (August 2013) discussing the hydrocarbon impacted soil and its potential to migrate to the underlying groundwater. ES concluded that the hydrocarbons in soil have not impacted underlying groundwater and are unlikely to migrate into the deeper soil profile. Nevertheless, as a due diligence measure, the Remedial Action

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 2 16021

    Plan (RAP) prepared by Prysmian Group (June 2013) recommended that ongoing groundwater monitoring be incorporated into the site’s EMP with a contingency plan should groundwater impact be detected from this event in the future.

    Prysmian made a commitment to conduct monthly monitoring of groundwater around the in-ground pit for three (3) months. At the end of the three months of monitoring, the data trends indicated that the groundwater was not impacted by the leaking pit. For due diligence measures Prysmian decided that a 12 monthly groundwater monitoring program was justified providing that if groundwater at any time shows to have been impacted by the contaminants of concern as triggered by the assessment criteria, then contingency options will be assessed.

    This report presents the results of the February 2016 GME.

    1.2 Objective

    Within the original scope provided, the objective of the GME was to:

    Determine whether groundwater had been impacted from localised leak of ‘coolant’ and if these impacts, if present, exceeded the adopted human health and environmental criteria or otherwise.

    1.3 Scope of Works

    ES completed the following scope of works:

    Preparation of a Job Hazard Analysis (JHA);

    Gauging to depth of water (and light non-aqueous phase liquids (LNAPLs) if present) in five (5) monitoring wells;

    Measurement of field groundwater quality parameters (dissolved oxygen (DO), electrical conductivity (EC), pH, redox potential (Eh) and temperature) of stabilised purged groundwater;

    Sampling of groundwater from all five (5) accessible groundwater monitoring wells using micro-purge pump and submitted to NATA accredited laboratory Envirolab for analysis of Total Recoverable Hydrocarbons (TRH C6-C40), Benzene, Toluene, Ethylbenzene, Xylenes and naphthalene (BTEXN) and Arsenic, Cadmium, Chromium, Copper, Lead, Mercury, Nickel, Zinc (Metals);

    Collection of Quality Assurance and Quality Control (QA/QC) (collected at a rate of 1:20) including one duplicate, one triplicate and forward these to a NATA accredited laboratory for analysis;

    Assessment of analytical data against the following guidelines:

    - NEPC (2013) NEPM Investigation Levels for Soil and Groundwater; and

    - ANZECC (2000) 95% freshwater guidelines

    Preparation of a report detailing the findings of the GME.

    1.4 Limitations

    This report is based on the Scope of Work outlined in Section 1.3. ES prepared this report in a manner consistent with the normal level of care and expertise exercised by members of the environmental assessment profession.

    This report relates only to the objectives stated and does not relate to any other work undertaken for the Client. It is a report based on the concentrations of contaminants observed in groundwater only as reported to ES. These conditions stated in this report may change with time and space. The stated absence of any identified hazardous or toxic

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 3 16021

    materials on any part of the subject property should not be interpreted as a guarantee that such materials do not exist on the site.

    All conclusions regarding the property area are the professional opinions of ES, subject to the qualifications in the report. Whilst normal assessments of data reliability have been made, ES assumes no responsibility or liability for errors in any data obtained from regulatory agencies, statements from sources outside of ES, or developments resulting from situations outside the scope of this project. The client acknowledges that this report is for the exclusive use of the client.

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 4 16021

    2 Site Condition and Surrounding Environment

    2.1 Site Identification

    The site occupies an area of approximately 15.3 hectares and is currently owned by Prysmian.

    The site location is shown in Figure 1, Appendix A and the site layout at time of sampling is shown in Figure 2 and well locations are presented in Figure 3, Appendix A.

    Table 2.1 provides a summary of the site details. Result summary tables are included in Appendix B.

    Table 2.1: Summary of Site Details

    Characteristic Detail

    Property Street Address 1 Heathcote Road, Liverpool, NSW

    Property Lot / DP Lot 200, DP1009044

    Property Local Government Area

    Liverpool City Council

    Property Current Land use Commercial/Industrial

    Property Area 15.3 Ha

    Property Zoning Light Industrial (IN2)

    Coordinates for the approximate corners of the subject site

    (MGA 56)

    Easting: 308697.509

    Northing: 6244183.467

    Easting: 308723.284

    Northing: 6244172.381

    Easting: 308678.953

    Northing: 6244144.078

    Easting: 308705.477

    Northing: 6244132.76

    Subject Site Area Approximately 1,120m2

    The property is bounded to the south by Newbridge Road beyond which lies Moorebank Avenue, Georges River to the west, Joyce’s Foam products and Bridgewater Business Estate to the east and vacant land to the north.

    The subject site is bounded by Factory 1 to the west, the centre line of Factory 2 to the east, the access road to the south and the third bay (as specified by the saw tooth roofing panels) of Factory 2 to the North. The subject site area is approximately 1,120m2.

    2.2 Possible Contaminant Sources on the Site

    An inspection was limited to Factory 2 (the cable drawing building), refer to Figure 2, Appendix A for site layout. Possible contamination sources in this area included the coolant tank (which was replaced immediately after the leak was notified in February 2012) and the coolant mixture itself (Houghto Draw WD4100) which is stored in drums along the south wall, near to the second entrance door. The composition of the coolant includes several petroleum based compounds and additives and requires dilution with water. The time weighted exposure limit for Houghto Draw WD4100 is listed as 5 mg/m3.

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 5 16021

    Other potential sources on site include the copper wire which is used in the copper drawing process.

    2.3 Location of Chemical Spills On-site

    Excluding the coolant leak under investigation, no additional spills are known to have occurred within Factory 2 of the Prysmian facility.

    2.4 Local Sensitive Environments

    The nearest sensitive environmental receptors to the site are:

    Georges River located immediately to the west of the site; and

    Reserve land located immediately to the north of the site.

    2.5 Local Hydrogeology

    Based on previous GME events standing groundwater onsite was on average approximately 6m below ground surface. Following survey of the wells groundwater was calculated to flow in a north westerly direction towards the Georges River.

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 6 16021

    3 Sampling and Analysis Plan and Sampling Methodology

    This section outlines the methodology adopted by ES during the GME. This section also provides details on the sampling and analysis, description of field equipment used, decontamination procedures, field and laboratory quality assurance and control, laboratory analytical methods and sample preservation.

    3.1 Groundwater

    3.1.1 Groundwater Gauging, Purging and Sampling

    Groundwater gauging, purging and sampling was completed by ES’ Environmental Scientist Colin Biggs on 8th February 2016.

    Samples were collected from the five (5) wells in the vicinity of the reported coolant leak. Refer to Figure 3, Appendix A.

    Prior to sampling, all wells were gauged with an interface probe to measure groundwater levels and detect the presence of light non-aqueous phase liquids (LNAPL). All monitoring wells were then purged using a peristaltic pump to ensure minimal losses of volatile organic compounds.

    Water quality parameters recorded included pH, redox potential (Eh), electrical conductivity, dissolved oxygen and temperature. All wells were purged until groundwater parameters stabilised to within suitable limits.

    Samples were placed directly into appropriately preserved laboratory supplied sampling containers. The sample for metals analysis was filtered in the field using a 0.45micron millipore filter unit prior to analysis.

    Disposable tubing was used at each monitoring well and the interface probe was thoroughly decontaminated between gauging events with a phosphate free detergent (Decon 90) and rinsed with potable water. Field records of purging and sampling event are provided in Appendix C.

    3.1.2 Field QA/QC

    The following procedures were followed during fieldwork to ensure quality control:

    Water samples were collected in laboratory supplied bottles with Teflon seals;

    Samples were collected from disposable equipment to prevent cross contamination between sampling locations;

    Samples were placed in an ice-filled esky to keep them below 4oC in accordance with US EPA SW 846 and AS4482-2 (2005); and

    Samples were transferred to the laboratory under a completed chain-of-custody.

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 7 16021

    4 Field Quality Assurance and Quality Control (QA/QC)

    4.1 Chain of Custody

    Samples were transferred to the laboratory under chain-of-custody procedures. The details included on the chain-of-custody forms included the following:

    Job name and number Date results are required List of samples Preservation method Analysis required Release signature and date Date sampled Acceptance signature and date

    4.2 Statement of Duplicate Frequency

    The following are QA/QC samples were collected for this project:

    DUP1 and TRIP1 were a groundwater intra-laboratory and inter-laboratory duplicate of MW2.

    Precision of analytical techniques is measured by the relative percent difference (RPD) between duplicate results. Acceptable precision shown by intra-laboratory and inter-laboratory duplicate samples is:

    Precision is measured using the standard deviation ‘SD’ or Relative Percent Difference ‘%RPD’. Replicate data for field duplicates of organics is expected to be as follows:

    RPD criteria of 50% or less, for concentrations > or = 10 times EQL; RPD criteria of 75% or less, for concentrations between 5 and 10 times the EQL; and RPD criteria of 100% or less, for concentrations < 5 times EQL.

    Replicate data for field duplicates for inorganics, including metals is expected to be as follows:

    RPD criteria of 30% or less, for concentrations > or = 10 times EQL; RPD criteria of 75% or less, for concentrations between 5 and 10 times the EQL; and RPD criteria of 100% or less, for concentrations < 5 times EQL.

    A summary of the Relative Percent Differences (RPDs) calculations are presented in Table 2a, Appendix B. ES notes that RPDs were only calculated for groups of compounds with detections above the laboratory detection limits.

    All RPDs for groundwater were within acceptable ranges with the exception of the following;

    Primary sample (MW2) and DUP1 RPD exceedance 80% for Zinc

    The RPD exceedance for zinc marginally exceeds the 75% criteria. Given that the concentrations of all contaminants of concern were below the adopted GAC, ES considers the minor RPD exceedance does not affect the validity of the data collected.

    Overall, there is an acceptable level of agreement between original and duplicate samples indicating that field procedures were adequate in obtaining representative samples and minimising the potential for cross‐contamination.

    4.3 Background Sample Results

    Background samples were not collected as part of this investigation.

    4.4 Rinsate Sample Results

    A rinsate sample was not collected from the final decontamination of the interface probe and purged water bucket. Dedicated sampling materials and best practice sampling methods were

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 8 16021

    adequate to prevent the potential for cross contamination to occur during groundwater sampling.

    4.5 Trip Blank

    Trip Blank samples were not collected as part of this investigation.

    4.6 Trip Spike Results

    Trip Spike samples were not collected as part of this investigation.

    4.7 Field Instrument Calibration

    Field instruments were calibrated prior to use on site.

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 9 16021

    5 Laboratory QA/QC

    Chain-of-custody forms are included in Appendix E.

    5.1 Holding Times

    Holding times are included on the laboratory reports in Appendix E. All samples were received and analysed within the specified holding times.

    5.2 Laboratory Analytical Methods

    The analytical methods used by Envirolab are summarised below:

    Table 5.2: Envirolab Laboratory Methods for Water

    Analyte Method PQL (ug/kg)

    BTEXN Benzene Toluene Ethylbenzene Xylene Naphthalene

    Org-016 Water samples are analysed directly by purge and trap GC-MS

    1 1 1 3 1

    TRH C6-C10 >C10-C16 >C16-C34 >C34-C40

    Org-016 Water samples are analysed directly by purge and trap GC-MS GC.3 Water samples are extracted with Dichloromethane and analysed by GC-FID.

    10 50

    100 100

    Metals As Ca Cr Cu Ni Pb Zn Hg

    Metals-022 ICP-MS Determination of various metals by ICP-MS. Metals-021 CVAAS Determination of Mercury by Cold Vapour AAS.

    1

    0.1 1 1 1 1 1

    0.05

    5.3 Laboratory Accreditation for Analytical Methods Used

    The primary laboratory used for this project was Envirolab Services (Envirolab). Envirolab is accredited by NATA to ISO 17025, accreditation number 2901.

    The secondary laboratory used was ALS Sydney. ALS are accredited by NATA to ISO 17025, accreditation number 825.

    5.4 Percent Recoveries of Spikes and Surrogates

    Laboratory QA/QC is provided on the laboratory reports in Appendix D. All spikes and surrogates were within acceptable ranges.

    5.5 Laboratory duplicate results

    All Envirolab laboratory duplicates were within acceptable ranges. All ALS laboratory duplicates were within acceptable ranges.

    5.6 Laboratory blank results

    All Envirolab and ALS laboratory blank results were within acceptable ranges.

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 10 16021

    6 Assessment Criteria

    6.1 Rationale for Selection of Water Assessment Criteria

    In accordance with the NEPM (2013) Schedule B(6) The Framework for Risk Based Assessment of Groundwater Contamination it was necessary to determine the relevant environmental values and hence appropriate guideline assessment criteria for the site.

    To determine the most appropriate groundwater guideline the following environmental values have been considered and are presented in Table 6.1. These have been referenced from Appendix 2 of NSW DEC (2007) Guidelines for the Assessment and Management of Groundwater Contamination and the NEPM (2013) Schedule B (6).

    Table 6.1 Assessment of Environmental Values Associated with Site Groundwater

    Environmental Values

    ES Comment

    Aquatic Ecosystems (Freshwater)

    The closest surface water receptor is the Georges River located along the western boundary of the site. The Georges River would be classed as a beneficial receptor of groundwater and should be protected. This is classed as a freshwater environment.

    Human Uses (Drinking Water)

    No registered groundwater bores for domestic use were identified within 500km of the site. EC measurements of the groundwater monitoring bores indicated a TDS

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 11 16021

    Table 6.2 Groundwater Assessment Criteria

    Analyte GAC (ug/L) at Depth Source

    4 to C10-C16 (minus naphthalene)

    6,000

    NL

    NEPM (2013) HSL D 1

    NEPM (2013) HSL D 1

    Naphthalene 16 ANZECC (2000) 95% Freshwater

    Arsenic (V)

    Cadmium

    Chromium (VI)

    Copper

    Lead

    Nickel

    Zinc

    Mercury

    24

    0.7

    27

    1.3

    4.4

    7

    15

    0.1

    ANZECC (2000) 95% Freshwater

    ANZECC (2000) 95% Freshwater

    ANZECC (2000) 95% Freshwater

    ANZECC (2000) 95% Freshwater

    ANZECC (2000) 95% Freshwater

    ANZECC (2000) 95% Freshwater

    ANZECC (2000) 95% Freshwater

    ANZECC (2000) 95% Freshwater Notes: 1 The site’s geology consists of clayey sand. The HSLs for a sand matrix have been adopted for all depth profiles for the sake

    of conservatism NL – Non-limiting. No limit specified. HSL – Health Based Screening Level. Site standing groundwater is at approximately 5.86 to 6.25m below ground level. The 4 to

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 12 16021

    7 Results

    The following section presents an overview of the field observations for groundwater encountered during the February 2016 GME. Copies of groundwater sampling field sheets are included in Appendix C.

    7.1 Groundwater Gauging Results

    Groundwater gauging results are summarised below:

    LNAPL was not detected in any of the monitoring wells sampled; and Depth to groundwater ranged between 5.741m below top of casing (btoc) at MW1 and

    6.153m btoc at MW5. Refer to Table 1 Appendix B for corrected water relative levels (RLs).

    7.2 Groundwater Quality Results

    During sampling the groundwater was observed to be light brown to dark brown in colour, odourless with suspended clay particles. No sheens were observed in any of the purged water. The groundwater field parameters for the site are summarised in Table 7.2 below:

    Table 7.2: Physiochemical Field Parameters

    Monitoring well ID

    Date Temp (oC)

    pH

    pH units

    Dissolved Oxygen (ppm)

    Redox/ORP (mV)

    Conductivity

    (µS/cm)

    MW1 08/02/2016 23.2 5.54 3.15 229 700

    MW2 08/02/2016 21.3 5.79 2.57 164 287

    MW3 08/02/2016 20.3 5.64 1.96 174 472

    MW4 08/02/2016 21.2 5.31 1.29 250 561

    MW5 08/02/2016 21.2 5.29 0.94 218 305

    Table 7.2 indicates the following groundwater conditions: The temperature of the groundwater ranged from 21.2 to 23.2oC; pH ranged from 5.29 to 5.79 pH units indicating slightly acidic groundwater conditions; Dissolved oxygen in the groundwater ranged from 0.94 and 3.15 ppm indicating

    generally aerobic conditions; ORP (oxidation reduction potential) levels measured from 164 to 250mV (using a

    Ag/AgCl electrode), which indicates oxidising conditions. ORP (or Redox) is a measure of a water system’s capacity to either release or gain electrons in chemical reactions. The process of oxidation involves losing electrons while reduction involves gaining electrons; and

    Conductivity levels were between 287 and 700 (µS/cm), which indicates fresh groundwater conditions.

    The following presents a summary of results for groundwater samples. Result summary tables are included in Appendix B, with copies of laboratory certificates included in Appendix D.

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 13 16021

    7.3 Groundwater Analytical Results

    7.3.1 Heavy Metals

    Concentrations of heavy metals in all groundwater samples submitted for analysis were reported below the GAC with the exception of copper at MW4.

    7.3.2 BTEXN

    Concentrations of BTEXN in all groundwater samples submitted for analysis were reported below laboratory detection limits with the exception of Toluene (2µg/L) in MW 1 which is below the adopted GAC.

    7.3.3 TRH

    Concentrations of TRH in all groundwater samples submitted for analysis were reported below laboratory detection limits and the adopted GAC.

    7.3.4 Discussion

    The results of this investigation indicate that with the exception of a low level detection of Toluene in MW1, no detectable petroleum hydrocarbon contamination was present in any of the up-gradient or down-gradient monitoring well locations above the adopted groundwater acceptance criteria (GAC).

    The recent groundwater monitoring data was compared to that of the previous GME events that occurred in September 2013, December 2013, February 2014 and February 2015. Table 3 Appendix B shows a comparison of analytical results from these four rounds.

    ES consider that the concentrations of copper, nickel and zinc detected in groundwater are unlikely to pose a risk to human health and the environment and are likely representative of local background levels.

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 14 16021

    8 Conclusions and Recommendations

    8.1 Conclusions

    The following conclusions can be made from the February 2016 GME conducted at the site located at 1 Heathcote Road, Liverpool:

    Groundwater analytical results reported all contaminants of concern (TRH, and BTEXN) below laboratory detection limits and the adopted groundwater acceptance criteria (GAC)

    With the exception of copper at MW4 (5ug/L), concentrations of heavy metals were reported below the GAC. ES consider that the concentrations of copper, nickel and zinc detected in groundwater are unlikely to pose a risk to human health and the environment and are likely representative of local background levels;

    No TRH concentrations were reported above the adopted groundwater criteria indicating that groundwater has not been impacted by the leaking coolant tank;

    Toluene was detected above the LOR at one monitoring well (MW1); and

    This GME is the fifth (5) monitoring event after the preparation of the RAP and confirms the findings of the ES (June 2013) report, that the groundwater has not been impacted by the leaky coolant tank.

    8.2 Recommendations

    Based on the above conclusions, and the results of the ES (June 2013) Supplementary Soil and Groundwater Investigation, ES consider that the coolant leak has not impacted the underlying groundwater and recommends that no further groundwater monitoring (other than that conducted as part of the facility’s due diligence) is required.

    8.3 Extent of Uncertainties in the Results

    The sampling methodologies used by ES during this assessment have been designed to limit uncertainty in the results. ES is confident that the results of this assessment give an accurate representation of the current status of the site but note that in all subsurface investigations the potential remains for variation between sampling points and conditions different from that reported here may exist on site.

  • Prysmian Power Cables & Systems Australia Pty Ltd, February 2016 Groundwater Monitoring Event, 1 Heathcote Road, Liverpool, NSW 15 16021

    9 References

    Australian (2004) Drinking Water Guidelines

    ANZECC (2000) Australian and New Zealand Guidelines for Fresh and Marine Water Quality. Australian and New Zealand Environment and Conservation Council & National Health and Medical Research Council, Australia;

    ANZECC/NHMRC (1992) Australian and New Zealand Guidelines for the Assessment and Management of Contaminated Sites;

    Benbow Environmental Pty Ltd (January 2013) Environmental Site Assessment, 1 Moorebank Road, Liverpool, NSW 121081_Rep_Final

    Department of Environment and Climate Change (2009) Guidelines on the Duty to Report Contamination Under the Contaminated Land Management Act 1997;

    Environmental Strategies Pty Ltd (20 June 2013) Supplementary Soil and Groundwater Investigation, 1 Heathcote Road, Liverpool NSW. Ref:13055RP01_FINAL;

    Environmental Strategies Pty Ltd (6 November 2013) Groundwater Monitoring Event, 1 Heathcote Road, Liverpool NSW.Ref: 13055aRP01_FINAL;

    Environmental Strategies Pty Ltd (25 November 2013) Environmental Management Plan (EMP), 1 Heathcote Road, Liverpool NSW.Ref: 13055bRP01_EMP (Rev1) FINAL;

    Environmental Strategies Pty Ltd (13 January 2014) Groundwater Monitoring Event, 1 Heathcote Road, Liverpool NSW.Ref: 113055aRP02_FINAL;

    Environmental Strategies Pty Ltd (21 March 2014) Groundwater Monitoring Event, 1 Heathcote Road, Liverpool NSW.Ref: 13055aRP03_FINAL;

    Environmental Strategies Pty Ltd (11 February 2015) Groundwater Monitoring Event, 1 Heathcote Road, Liverpool NSW.Ref: 15001RP01_FINAL;

    National Environment Protection Council (1999) Revised National Environment Protection Measure (NEPM) 2013 – Assessment of Site Contamination Schedule B (1) and B (2);

    NSW Environment Protection Authority (2006) Guidelines for the Site Auditor Scheme Environment Protection Authority;

    NSW Environment Protection Authority (1995) Sampling Design Guidelines. Environment Protection Authority, Chatswood;

    NSW DEC (2007) Guidelines for the Assessment and Management of Groundwater Contamination;

    NSW DECC (2009) Guidelines on the Duty to Report Contamination under the Contaminated Land Management Act 1997.

  • APPENDIX A Figures

  • 1 FIGURESite Location

    HA1 Hand Auger Location

    KEY

    N

    TP24

    TP23TP22

    TP21

    TP19 TP18

    TP16TP17

    TP2TP3

    TP7

    TP6

    TP8

    TP4

    TP12 TP11 TP10TP14

    BH1/MW1

    BH2/MW2

    BH5/MW5

    TP13

    SP1SP2

    BH4/MW4

    Prysmian 1 Heathcote Road, Liverpool NSW

    Site Location

    SITE LOCATION

    N

  • 2Site Layout

    Prysmian1 Heathcote Road, Liverpool, NSW

    FIG

    UR

    E

    Groundwater Monitoring Well

    New Groundwater Monitoring Well

    Site Boudary

    MW17

    MW6

    MW7

    MW4

    MW32

    MW10A

    MW8

    MW9MW31

    MW15

    MW11MW5

    MW14 MW13

    MW1

    MW3

    MW2A

    MW33

    MW22

    MW18

    MW19 MW21

    MW20

    MW23

    MW24

    MW23MW25

    MW26MW27

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 65

    Toluene 514

    Ethylbenzene 558

    Xylene 2840

    Naphthalene 112

    ĖŌMÕŘPÑ Concentration (ug/L)

    Benzene 92

    Toluene 454

    Ethylbenzene 55

    Xylene 443

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 59

    Toluene 249

    Ethylbenzene 50

    Xylene 313

    MW12

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 2150

    Toluene 7480

    Ethylbenzene 1580

    Xylene 6700

    Naphthalene 223

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 92

    Toluene 454

    Ethylbenzene 55

    Xylene 443

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 637

    Toluene 1690

    Ethylbenzene 434

    Xylene 3670

    Naphthalene 128

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 5740

    Toluene 10400

    Ethylbenzene 1020

    Xylene 8780

    Naphthalene 136

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 12800

    Toluene 26000

    Ethylbenzene 1420

    Xylene 14000

    Naphthalene 246

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 37000

    Toluene 63100

    Ethylbenzene 2360

    Xylene 15500

    Naphthalene 301

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 16300

    Toluene 53200

    Ethylbenzene 2300

    Xylene 15500

    Naphthalene 235

    MW29Ė ŌMÕŘPÑ Concentration (ug/L)Benzene 16000

    Toluene 31400

    Ethylbenzene 2480

    Xylene 13800

    Naphthalene 222

    ĖŌMÕŘPÑ Concentration (ug/L)

    Benzene 2240

    Toluene 6660

    Ethylbenzene 923

    Xylene 9850

    Naphthalene 228

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 7030

    Toluene 12300

    Ethylbenzene 1150

    Xylene 9360

    Naphthalene 165

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 17400

    Toluene 34900

    Ethylbenzene 2280

    Xylene 13790

    Naphthalene 236

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 748

    Toluene 609

    Ethylbenzene 204

    Xylene 1270

    Naphthalene 81

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 69

    Toluene 525

    Ethylbenzene 337

    Xylene 1729

    Naphthalene 65

    Ė ŌMÕŘPÑ Concentration (ug/L)

    Benzene 65

    Toluene 514

    Ethylbenzene 558

    Xylene 2840

    Naphthalene 112

    ĖŌMÕŘPÑ Concentration (ug/L)

    Benzene 85

    Toluene 605

    Ethylbenzene 136

    Xylene 725

    Naphthalene 33

    0 50

    Metres

    SCALE

    Ĩ Ĭ Ģ İ OÒŃÔŌÑŒŒ ĂÖ Å

    0.71

    Ĩ Ĭ Ģ İ OÒŃÔŌÑŒŒ ĂÖ Å

    5.79

    Ĩ Ĭ Ģ İ OÒŃÔŌÑŒŒ ĂÖ Å

    0.008

    MW30

    Ĩ Ĭ Ģ İ OÒŃÔŌÑŒŒ ĂÖ Å

    0.015

    Factory 3

    KEY

    Factory 4 Factory 6 Factory 6 Factory 6

    Factory 1

    Factory 2

    Factory 3 Factory

    4

    Factory 5

    Factory 6 Factory

    7

    Factory 6

    Factory 6 Factory

    7

    Area of Concern

  • APPENDIX B Groundwater Results Summary Tables

  • Table 1: Survey Data

    Well ID TOC (m BGL) RL (Assumed Height Datum) DTW (m bTOC) Water RL

    MW1 0.015 8.23 5.741 2.489

    MW2 0.01 8.329 5.878 2.451

    MW3 0.023 8.179 5.85 2.329

    MW4 0.015 8.551 6.145 2.406

    MW5 0.016 8.483 6.153 2.33

    TOC - Top of casing

    RL - Relative Level

    bTOC - below top of casing

    BGL - below ground level

  • Table 2Results Summary

     16021Groundwater Monitoring Event

    Prysmian ‐ 1 Heathcote Road, Liverpool NSW

    Arsenic Cadmium Chromium Copper Lead Mercury Nickel ZincDissolved Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved

    µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L1 0.1 1 1 1 0.05 1 124 0.7 27 1.3 4.4 0.1 7 15

    Location Date Sampled Type Of Sample Metals-021 CV-AASMW1 8/02/2016 Water

  • Table 2Results Summary

     16021Groundwater Monitoring Event

    Prysmian ‐ 1 Heathcote Road, Liverpool NSW

    Location Date Sampled Type Of SampleMW1 8/02/2016 WaterMW2 8/02/2016 WaterMW3 8/02/2016 WaterMW4 8/02/2016 WaterMW5 8/02/2016 Water

    Number of Guideline Exceedances(Detects

    ANZECC (2000) 95% Freshwater NEPM (2013) HSL D Sand

    Minimum DetectsAverage Consentration Medium ConsentrationStandard DeviationNumber of Guideline Exceedances

    Number of SamplesNumber of DetectsMaximum ConsentrationMaximum DetectsMinimum Consentration

    TRH C6 - C10 TRH C6 - C10 TRH >C10 - C16 TRH >C10 - C16 TRH >C16 - C34 TRH >C34 - C40 less BTEX (F1) less Naphthalene (F2)

    µg/L µg/L µg/L µg/L µg/L µg/L10 10 50 50 100 100

    6 000 NLOrg-016 Org-016 Org-003 Org-003 Org-003 Org-003

  • Table 2Results Summary

     16021Groundwater Monitoring Event

    Prysmian ‐ 1 Heathcote Road, Liverpool NSW

    Location Date Sampled Type Of SampleMW1 8/02/2016 WaterMW2 8/02/2016 WaterMW3 8/02/2016 WaterMW4 8/02/2016 WaterMW5 8/02/2016 Water

    Number of Guideline Exceedances(Detects

    ANZECC (2000) 95% Freshwater NEPM (2013) HSL D Sand

    Minimum DetectsAverage Consentration Medium ConsentrationStandard DeviationNumber of Guideline Exceedances

    Number of SamplesNumber of DetectsMaximum ConsentrationMaximum DetectsMinimum Consentration

    Benzene Toluene Ethylbenzene m+p-xylene o-xylene Naphthalene

    µg/L µg/L µg/L µg/L µg/L µg/L1 1 1 2 1 1

    5 000 NL NL NL NL 16Org-016 Org-016 Org-016 Org-016 Org-016 Org-013

  • Table 2a

    RPD Exceedances

    16021

    Groundwater Monitoring Event

    Prysmian - 1 Heathcote Road, Liverpool NSW

    Arsenic Cadmium Chromium Copper Lead Mercury Nickel Zinc TRH C6 - C10

    Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved Dissolved

    µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L

    24 0.7 27 1.3 4.4 0.1 7 15

    MW2 8/02/2016 Water

  • Table 2a

    RPD Exceedances

    16021

    Groundwater Monitoring Event

    Prysmian - 1 Heathcote Road, Liverpool NSW

    TRH C6 - C10 TRH >C10 - C16 TRH >C10 - C16 TRH >C16 - C34 TRH >C34 - C40 Benzene Toluene Ethylbenzene m+p-xylene o-xylene Naphthalene

    less BTEX (F1) less Naphthalene (F2)

    µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L

    6 000 NL 5 000 NL NL NL NL 16

  • 16021

    Groundwater Monitoring Event

    Prysmian - 1 Heathcote Road, Liverpool NSW

    Table 3: Summary Groundwater Results

    Ars

    en

    ic (

    Fil

    tere

    d)

    Cad

    miu

    m (

    Fil

    tere

    d)

    Ch

    rom

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    Co

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    tere

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    Le

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    Me

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    Nic

    ke

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    ph

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    Ben

    ze

    ne

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    ylb

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    ne

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    ug/l ug/l ug/l ug/l ug/L ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l ug/l µg/L µg/L µg/L µg/L µg/L µg/L µg/L

    EQL 1 0.1 1 1 1 0.05 10 1 10 10 50 50 100 100 1 1 1 2 2 3 1

    ANZECC 2000 FW 95% 24 0.7 27 1.3 4.4 0.1 7 15 16

    HSL-A/B, 4m to

  • APPENDIX C Groundwater Field Sheets

  • APPENDIX D Laboratory Certificates

  • CERTIFICATE OF ANALYSIS 141327

    Client:

    Environmental Strategies Pty Ltd

    Suite 15201, Locomotive Workshop2 Locomotive StEveleighNSW 2015

    Attention: Dean Stafford, Colin Biggs

    Sample log in details:

    Your Reference: 16021No. of samples: 6 watersDate samples received / completed instructions received 09/02/16 / 09/02/16

    Analysis Details:

    Please refer to the following pages for results, methodology summary and quality control data.Samples were analysed as received from the client. Results relate specifically to the samples as received.Results are reported on a dry weight basis for solids and on an as received basis for other matrices.Please refer to the last page of this report for any comments relating to the results.

    Report Details:

    Date results requested by: / Issue Date: 16/02/16 / 16/02/16Date of Preliminary Report: Not IssuedNATA accreditation number 2901. This document shall not be reproduced except in full.Accredited for compliance with ISO/IEC 17025. Tests not covered by NATA are denoted with *.

    Results Approved By:

    Page 1 of 9Envirolab Reference: 141327Revision No: R 00

  • Client Reference: 16021

    vTRH(C6-C10)/BTEXN in Water Our Reference: UNITS 141327-1 141327-2 141327-3 141327-4 141327-5Your Reference ------------

    -MW1 MW2 MW3 MW4 MW5

    Date Sampled ------------ 08/02/2016 08/02/2016 08/02/2016 08/02/2016 08/02/2016Type of sample Water Water Water Water Water

    Date extracted - 09/02/2016 09/02/2016 09/02/2016 09/02/2016 09/02/2016

    Date analysed - 10/02/2016 10/02/2016 10/02/2016 10/02/2016 10/02/2016

    TRH C6 - C9 µg/L

  • Client Reference: 16021

    svTRH (C10-C40) in Water Our Reference: UNITS 141327-1 141327-2 141327-3 141327-4 141327-5Your Reference ------------

    -MW1 MW2 MW3 MW4 MW5

    Date Sampled ------------ 08/02/2016 08/02/2016 08/02/2016 08/02/2016 08/02/2016Type of sample Water Water Water Water Water

    Date extracted - 10/02/2016 10/02/2016 10/02/2016 10/02/2016 10/02/2016

    Date analysed - 10/02/2016 10/02/2016 10/02/2016 10/02/2016 10/02/2016

    TRH C10 - C14 µg/L

  • Client Reference: 16021

    HM in water - dissolved Our Reference: UNITS 141327-1 141327-2 141327-3 141327-4 141327-5Your Reference ------------

    -MW1 MW2 MW3 MW4 MW5

    Date Sampled ------------ 08/02/2016 08/02/2016 08/02/2016 08/02/2016 08/02/2016Type of sample Water Water Water Water Water

    Date prepared - 10/02/2016 10/02/2016 10/02/2016 10/02/2016 10/02/2016

    Date analysed - 10/02/2016 10/02/2016 10/02/2016 10/02/2016 10/02/2016

    Arsenic-Dissolved µg/L

  • Client Reference: 16021

    Method ID Methodology Summary

    Org-016 Soil samples are extracted with methanol and spiked into water prior to analysing by purge and trap GC-MS. Water samples are analysed directly by purge and trap GC-MS. F1 = (C6-C10)-BTEX as per NEPM B1 Guideline on Investigation Levels for Soil and Groundwater.

    Org-013 Water samples are analysed directly by purge and trap GC-MS.

    Org-003 Soil samples are extracted with Dichloromethane/Acetone and waters with Dichloromethane and analysed by GC-FID. F2 = (>C10-C16)-Naphthalene as per NEPM B1 Guideline on Investigation Levels for Soil and Groundwater (HSLs Tables 1A (3, 4)). Note Naphthalene is determined from the VOC analysis.

    Metals-022 ICP-MS Determination of various metals by ICP-MS.

    Metals-021 CV-AAS

    Determination of Mercury by Cold Vapour AAS.

    Page 5 of 9Envirolab Reference: 141327Revision No: R 00

  • Client Reference: 16021

    QUALITY CONTROL UNITS PQL METHOD Blank Duplicate Sm#

    Duplicate results Spike Sm# Spike % Recovery

    vTRH(C6-C10)/BTEXN in Water

    Base ll Duplicate ll %RPD

    Date extracted - 09/02/2016

    141327-1 09/02/2016 || 10/02/2016 LCS-W2 09/02/2016

    Date analysed - 10/02/2016

    141327-1 10/02/2016 || 10/02/2016 LCS-W2 10/02/2016

    TRH C6 - C9 µg/L 10 Org-016

  • Client Reference: 16021

    QUALITY CONTROL UNITS PQL METHOD Blank Duplicate Sm#

    Duplicate results Spike Sm# Spike % Recovery

    HM in water - dissolved Base ll Duplicate ll %RPD

    Mercury-Dissolved µg/L 0.05 Metals-021 CV-AAS

  • Client Reference: 16021

    Report Comments:

    Asbestos ID was analysed by Approved Identifier: Not applicable for this jobAsbestos ID was authorised by Approved Signatory: Not applicable for this job

    INS: Insufficient sample for this test PQL: Practical Quantitation Limit NT: Not testedNR: Test not required RPD: Relative Percent Difference NA: Test not required: Greater than LCS: Laboratory Control Sample

    Page 8 of 9Envirolab Reference: 141327Revision No: R 00

  • Client Reference: 16021

    Quality Control Definitions

    Blank: This is the component of the analytical signal which is not derived from the sample but from reagents, glassware etc, can be determined by processing solvents and reagents in exactly the same manner as for samples. Duplicate : This is the complete duplicate analysis of a sample from the process batch. If possible, the sampleselected should be one where the analyte concentration is easily measurable. Matrix Spike : A portion of the sample is spiked with a known concentration of target analyte. The purpose of the matrix spike is to monitor the performance of the analytical method used and to determine whether matrix interferences exist. LCS (Laboratory Control Sample) : This comprises either a standard reference material or a control matrix (such as a blanksand or water) fortified with analytes representative of the analyte class. It is simply a check sample. Surrogate Spike: Surrogates are known additions to each sample, blank, matrix spike and LCS in a batch, of compoundswhich are similar to the analyte of interest, however are not expected to be found in real samples.

    Laboratory Acceptance Criteria

    Duplicate sample and matrix spike recoveries may not be reported on smaller jobs, however, were analysed at a frequencyto meet or exceed NEPM requirements. All samples are tested in batches of 20. The duplicate sample RPD and matrixspike recoveries for the batch were within the laboratory acceptance criteria.Filters, swabs, wipes, tubes and badges will not have duplicate data as the whole sample is generally extracted during sample extraction.Spikes for Physical and Aggregate Tests are not applicable.For VOCs in water samples, three vials are required for duplicate or spike analysis.

    Duplicates: 5xPQL - 0-50% RPD is acceptable.Matrix Spikes, LCS and Surrogate recoveries: Generally 70-130% for inorganics/metals; 60-140%for organics (+/-50% surrogates) and 10-140% for labile SVOCs (including labile surrogates), ultra trace organics and speciated phenols is acceptable.

    In circumstances where no duplicate and/or sample spike has been reported at 1 in 10 and/or 1 in 20 samples respectively, the sample volume submitted was insufficient in order to satisfy laboratory QA/QC protocols.

    When samples are received where certain analytes are outside of recommended technical holding times (THTs), the analysis has proceeded. Where analytes are on the verge of breaching THTs, every effort will be made to analyse within the THT or as soon as practicable.

    Where sampling dates are not provided, Envirolab are not in a position to comment on the validityof the analysis where recommended technical holding times may have been breached.

    Page 9 of 9Envirolab Reference: 141327Revision No: R 00

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