report 2017 annual report overburden groundwater

REPORT

2017 ANNUAL REPORT

OVERBURDEN GROUNDWATER EXTRACTION

AND TREATMENT SYSTEM Southeastern Area - East Side Shoreham Facility

Minneapolis, Minnesota

(VIC Program Site ID VP5080)

Soo Line Shoreham Yard (SF) (SR380)

Submitted to:

Minnesota Pollution Control Agency 520 Lafayette Road North

St. Paul, MN 55155

Submitted by:

Golder Associates Inc.

200 Century Parkway, Suite C

Mt. Laurel, New Jersey, USA 08054

+1 856 793-2005

June 2018

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Distribution List 1 E-copy - Minnesota Pollution Control Agency

1 Copy/1 E-copy - Canadian Pacific

1 CD - Ashland, Inc.

1 E-copy - Stinson Leonard Street

1 E-copy - Integral Consulting Inc.

1 E-copy - Shoreham Area Advisory Committee

1 Copy - Golder Associates Inc.

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Table of Contents

1.0 INTRODUCTION .............................................................................................................................................. 1

2.0 OVERVIEW ...................................................................................................................................................... 1

3.0 SYSTEM OPERATION .................................................................................................................................... 3

3.1 Extraction Well Operation and Sampling ............................................................................................. 3

3.2 System Maintenance ............................................................................................................................ 4

4.0 PERFORMANCE EVALUATION ..................................................................................................................... 5

4.1 Hydraulic Performance ......................................................................................................................... 5

4.2 Extraction System Shutdown and Rebound Testing............................................................................ 6

4.3 Routine Semi-annual Groundwater Sampling ...................................................................................... 7

5.0 CONCLUSIONS ............................................................................................................................................... 8

6.0 REFERENCES ................................................................................................................................................. 9

TABLES

Table 1 Well Construction Information

Table 2 VOC Concentrations in Groundwater Extraction Wells - Quarterly

Table 3 Total VOC Mass Removed

Table 4 Southeastern Area Groundwater Extraction System Shutdown Analytical Results - 2017

FIGURES

Figure 1 Southeast Area Well Location Map

Figure 2 Cumulative cVOC Mass Removal

Figure 3 Groundwater Level Monitoring in Shallow Zone Wells

Figure 4 Groundwater Level Monitoring in Intermediate Zone Wells

Figure 5 Groundwater Level Monitoring in Deep Zone and OPD Wells

Figure 6 Groundwater Potentiometric Contours – March 2017

Figure 7 Groundwater Potentiometric Contours – May 2017

Figure 8 Groundwater Potentiometric Contours – August 2017

Figure 9 Groundwater Potentiometric Contours – October 2017

Figure 10 Groundwater Potentiometric Contours Cross Section – May 2017

Figure 11 Groundwater Potentiometric Contours Cross Section – October 2017

Figure 12 cVOC Post Shutdown Monitoring

Figure 13 Total cVOC Isoconcentration Contours – October 2017

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APPENDICES

Appendix A Time-History Concentration Graphs

Appendix B Laboratory Results

ABBREVIATIONS cVOCs chlorinated volatile organic compounds (sum of PCE, TCE, cis-1,2-DCE, 1,1,1-TCA, 1,1-DCA, 1,1-DCE and vinyl chloride) DCA dichloroethane DCE dichloroethene gpm gallons per minute L liter PCE tetrachloroethene TCA trichloroethane TCE trichloroethene µg micrograms VOCs volatile organic compounds

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1.0 INTRODUCTION

This 2017 Annual Report has been prepared by Golder Associates Inc. (Golder) on behalf of the Soo Line

Railroad Company doing business as Canadian Pacific (CP). The purpose of this report is to document the

operation of the overburden groundwater remedial system in the southeastern area of the East Side Shoreham

Facility in Minneapolis, Minnesota (Facility). The design of the system was presented in the Overburden

Groundwater Remedial Design Report (Golder, 2007; Design Report) submitted to the Minnesota Pollution

Control Agency (MPCA) in April 2007 and approved by MPCA on April 30, 2007. The construction of the system

was documented in the Response Action Implementation and Monitoring Report (Golder, 2009; RAIR) submitted

to MPCA in April 2009 and subsequently approved. As detailed in the Design Report and the RAIR, the purpose

of the system is to address groundwater contamination in shallow overburden near the Roundhouse and deep

overburden between the Roundhouse and the intersection of Central Avenue and 28th Avenue, NE. The RAIR

documented system operation from startup (November 8, 2007) through September 2008. Annual Reports have

documented system operations from October 2008 to 2016 (Golder, 2010, 2011, 2012, 2013, 2014a, 2015a,

2016a, 2017). This 2017 Annual Report documents system operation from January 2017 through December

2017. This report has been prepared in accordance with MPCA Voluntary Investigation and Cleanup (VIC)

Guidance Document #18 (MPCA, 2002).

In 2017, a work plan, submitted by CP and approved by MPCA, (Golder 2015c) was implemented for the

shutdown and rebound testing of extraction wells RW06-27-BR, RW07-38-I, RW06-28-I, and RW07-40-SP. The

shutdown and rebound testing protocol was initiated on July 21, 2017 and continued through the rest of 2017.

Extraction well RW07-39-SP remains in operation.

2.0 OVERVIEW

As stated in the Design Report and consistent with MPCA guidance, the overburden groundwater pumping

system was designed to contain contaminated groundwater on an interim basis during upgradient source removal

activities until it could be demonstrated that the groundwater plume was stable or decreasing in size, and would

remain so without further pumping. The remainder of this section is a general overview, as presented in the

RAIR, of the geologic setting, contaminant profile prior to pumping operation, system construction, and remedial

goals.

As previously described in VIC Site reports, the geology in the vicinity of the Facility is comprised of overburden

units including surficial alluvium, till, outwash, and lacustrine clay. Bedrock units include the Ordovician St. Peter

sandstone, St. Peter mudstone, and the Shakopee dolomite of the Prairie du Chien group (OPD), any of which

can directly underlie the overburden depending on location. For the purposes of remedial design, groundwater

has been assigned to the shallow overburden, intermediate overburden, deep overburden, and OPD bedrock.

Shallow wells are screened between 793 and 823 feet above mean sea level (ft amsl) in near surface lithologies,

including glacial till, outwash, and St. Peter Sandstone. Deep wells are screened between 659 and 699 ft amsl

(approximately 70 feet to 150 feet beneath the water table) and correspond primarily to deep outwash in the

bedrock valley or equivalent depth in the mudstone unit of the St. Peter Sandstone outside of the bedrock valley.

Intermediate wells generally fall between these two designations and are screened between 728 and 805 ft amsl,

primarily in outwash and St. Peter Sandstone. Shakopee wells are screened between 614 and 636 ft amsl

(approximately 50 feet beneath the top of the OPD). Wells monitored in these four zones are further detailed in

Section 4.1.

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The most significant impacts, prior to remediation, in overburden groundwater in the southeastern area at shallow

and intermediate depths were located beneath a portion of the Roundhouse footprint at elevations generally

greater than 775 ft msl. Geologically, glacial till, shallow outwash, and St. Peter Sandstone units are present

within the area of influence of the intermediate depth pumping wells. Active soil source removal by soil

excavation (Golder, 2015b) and soil vapor extraction (SVE) was completed in the Southeastern Facility area by

CP (Golder, 2014b). The soil source removal, together with the pumping system, has reduced the concentrations

in shallow/intermediate overburden groundwater and contained the migration of chlorinated volatile organic

compounds (cVOCs) from the Roundhouse area (Golder, 2010, 2011, 2012, 2013, 2014a, 2015a, 2016a, 2017).

The most significant impacts in deep overburden in the southeastern area prior to system operation were located

between the Roundhouse and the intersection of 28th Avenue and Central Avenue at elevations generally below

775 ft msl. Geologically, the middle and deep outwash are present within the area of influence of the deep

overburden pumping system. The soil source removal, together with the pumping system, has reduced the

concentrations in the deep overburden groundwater and contained the migration of the cVOC plume.

The approved Design Report defined the performance goals for the pumping system, which included the

demonstration of hydraulic capture, plume stability, and attenuation. The Design Report also included the results

of pumping tests and groundwater modeling used to design the capture zones for the system, based on

addressing groundwater containing contaminant levels exceeding 100 ug/L of cVOCs. Plume stability was

defined as a steady state condition where the plume is no longer increasing in extent, and can be demonstrated

by overall stable concentration trends over time in wells located within and surrounding the plume. Attenuation

was defined as an overall decrease in plume mass over time and can be demonstrated by decreasing

concentration trends, particularly in wells located within the “core” of the plume, where impacts are highest. The

three pumping systems were designed to be operated throughout source removal activities until the associated

(shallow/intermediate overburden or deep overburden) groundwater plume was stable or decreasing in size and

would continue to do so without further pumping.

The southeastern area groundwater extraction and treatment system design included the following primary

elements:

Five (5) extraction wells, each equipped with an electric, submersible groundwater pump.

Two (2) below-grade, double-walled force mains for conveyance of deep overburden groundwater to the

treatment building.

Three (3) above-grade, heat-traced and insulated force mains for conveyance of intermediate overburden

groundwater to the treatment building.

Treatment building with secondary containment. A below-grade, gravity discharge pipeline runs from the

treatment building to an on-facility manhole located southeast of the treatment building. The manhole links

to the city sanitary sewer, conveying the effluent to the Metropolitan Council Environmental Services (MCES)

treatment plant. In December 2009, the system was modified to bypass the pre-treatment system and

discharge directly to the sanitary sewer system (as detailed in the 2009 Annual Report) as MCES discharge

limitations were satisfied without pre-treatment.

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Following successful completion of the Soil Vapor Extraction (SVE) source removal operations and substantial

concentration reductions in extraction well concentrations, CP proposed the shutdown of four of the five extraction

wells in 2015. MPCA approved the shutdown and rebound testing proposal on May 7, 2017, and CP ceased

groundwater extraction at extraction wells RW06-27-BR, RW-06-28-I, RW-07-38-I, and RW-07-40-SP on July 21,

2017.

The current layout of the system is shown in Figure 1, and construction of the southeastern area groundwater

extraction and treatment system was documented in the RAIR (Golder, 2009). Construction details of all pumping

and monitoring wells associated with the East Side Extraction and Treatment system are summarized in Table 1.

3.0 SYSTEM OPERATION

The southeastern area pump and treat system has been operating continuously since November 9, 2007 except

for brief periods of shutdown related to maintenance. On July 21, 2017, the approved shutdown and rebound

testing of extraction wells RW06-27-BR, RW07-38-I, RW06-28-I, and RW07-40-SP was initiated and continued

through the rest of 2017, while extraction well RW07-39-SP remained in operation (see Section 4.2).

3.1 Extraction Well Operation and Sampling

Total volumes of water extracted from each well during the reporting period, together with average flow rates

during operational periods are as follows:

RW07-39-SP: 720,310 gallons, 1.37 gpm average

RW07-40-SP: 646,851 gallons, 2.22 gpm average

RW06-28-I: 1,341,223 gallons, 4.61 gpm average

RW07-38-I: 2,630,118 gallons, 9.03 gpm average

RW06-27-BR: 3,936,341 gallons, 13.5 gpm average

The total volume extracted from all five wells during 2017 was 9,274,843 gallons.

The effluent from each extraction well was sampled during the first two quarters. After four wells were shut down

in July 2017, the active well (RW07-39-SP) and inactive wells (RW07-40-SP, RW06-28-I, RW07-38-I, and RW06-

27-BR) were sampled in the 3rd quarter and only the active well (RW07-39-SP) was sampled in the 4th quarter.

Table 2 presents the VOC concentrations detected for each sampling event. Table 3 presents the mass removed

quarterly and total mass removed through December 2017. Mass removal calculations were based on the

average of concentrations determined at the beginning and end of each sampling period and the volume

extracted during that time. Complete laboratory data are provided in Appendix B. VOCs detected in the

groundwater stream include 1,1-DCA, 1,1-DCE, cis-1,2-DCE, PCE, 1,1,1-TCA, and TCE. A total of 9.0 pounds of

VOCs were removed from the groundwater during the reporting period, and a cumulative total of 385 pounds has

been removed since commissioning the system on November 8, 2007 through December 18, 2017. The

cumulative mass removal of cVOCs since startup through the current reporting period is shown on Figure 2.

During the reporting period, PCE constituted the largest mass of contaminants removed (3.29 pounds), followed

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by 1,1-DCA (1.67 pounds), cis-1,2 DCE (1.63 pounds), 1,1,1-TCA (1.49 pounds), 1,1-DCE (0.49 pounds) and

TCE (0.46 pounds).

3.2 System Maintenance

During the current reporting period (January 2017 to December 2017), the following operation and maintenance

issues were addressed:

Equipment Repairs and Maintenance

April 3-5: A scheduled well rehabilitation (see below for description) of RW06-28-I, RW07-39-SP, RW07-40-SP, and RW07-38-I was conducted by Stevens Drilling and Environmental (SDE). A new pump, motor, and electrical lead was also installed in RW07-39-SP.

September 5-8: A scheduled well rehabilitation of RW06-28-I, RW07-39-SP, RW07-40-SP, and RW07-38-I was conducted by SDE.

November 13: Flashing was installed to close a gap between the interior walls and containment lip within the treatment building.

December 4-7: A scheduled well rehabilitation of RW07-39-SP was conducted by SDE.

Outside of these noted maintenance events, all five extraction wells pumped continuously until July 21 and RW07-

39-SP pumped continuously throughout the reporting period.

Well Rehabilitation

The process of well rehabilitation included the following mechanical and chemical treatment steps. First, the drop

pipes, pumps and motors were removed from each well for mechanical cleaning, followed by the introduction of a

chemical solution comprised of Aquaclear® AE and Aquaclear® MGA into the wells. Aquaclear® AE is a liquid

blend of acids and acid enhancers used to remove biological and bacterial fouling. Aquaclear® MGA is a dry

blend of granular acid and additives for the removal of mineral scaling including from iron, manganese, and

carbonate. The acid treatment was surged mechanically within the wells using surge blocks, and the wells were

then left undisturbed for 24 hours. At the conclusion of the 24-hour period, each well was redeveloped.

The process of redevelopment included alternately pressurizing and depressurizing the water in each well via

vertical movement of a surge block to break loose particulates within the screen and well packing, and then using

a pump to purge the well water into an aboveground container until the groundwater was observed to be clear.

Containerized water from redevelopment was tested with a calibrated pH meter, and sodium bicarbonate slowly

added as necessary, until the pH was within permit limits. The water was then discharged to the East Side

treatment building sump and co-mingled with the effluent stream, which is then routed to the MCES sanitary

sewer for disposal.

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4.0 PERFORMANCE EVALUATION

4.1 Hydraulic Performance

The hydraulic performance of the pumping system is assessed based on the groundwater levels measured in

monitoring wells within four monitoring zones previously defined for the VIC Site (i.e. Shallow zone, Intermediate

zone, Deep zone and OPD1). Groundwater elevations were measured quarterly (March 3, May 12, August 15-16

and October 6-7) by the Site data collection and data management consultant (AMEC Foster Wheeler) including

the following wells in the Southeastern Area groundwater extraction system monitoring network:

Shallow zone: MW-406D, MW00-41-T, MW00-42-T, MW00-43-T, MW02-46-T, MW04-155-T, MW04-24-T,

MW04-25-T, MW04-27-T, MW04-28-T, MW04-31-T, MW04-33-T, MW04-95-T and MW06-01-T

Intermediate zone: MW-403D, MW02-46-I, MW04-28-I, MW04-31-SP, MW04-33-SP, MW06-01-I, MW06-

248-I, MW06-29-I, MW07-41-I, MW07-42-I

Deep zone: MW00-42-MS, MW00-43-BR, MW02-46-BR, MW03-56-BR, MW04-26-BR, MW04-29-BR,

MW04-30-BR and MW06-01-BR

OPD2: MW02-01-OPD, MW03-61-OPD, MW04-28-OPD and MW05-01-OPSH

The groundwater extraction well water levels are measured monthly by Golder Associates.

Figure 1 shows the monitoring and extraction well locations. Hydrographs beginning in March 2007 are shown in

Figures 3 to 5 for the monitoring wells in each of the four monitoring zones. From 2007 to 2010, water levels were

generally stable from year to year, with seasonal variations evident during the year, particularly during August,

which typically exhibited lower water levels than those observed during the rest of the year. In 2011, water levels

rose several feet on average and have continued to rise since 2013, with less seasonal variations. Increasing

water levels persisted during 2017, with a marked increase in water levels in the Shallow zone during quarters 3

and 4, following the shutdown of extraction wells. The same trends are generally exhibited for the Intermediate to

the Deep zone with minor variations, (Figure 3). Water levels in the deeper zones (Figures 4 and 5), generally

vary over a smaller range and exhibit less variability from well to well.

Contours of groundwater level were developed as one line of evidence in evaluating capture zones, based on

synoptic groundwater elevations. Figures 6 to 9 depict the groundwater equipotentials for each of the four

quarters in 2017 in the three overburden monitoring zones. The groundwater contours indicate similar flow

patterns and zones of pumping influences for the first two monitoring periods of 2017 as have been observed

since start up and reported in the RAIR and the subsequent Annual Reports (Golder, 2010, 2011, 2012, 2013,

2014a, 2015a, 2016a). Following the shutdown of four extraction wells, the overall increasing trend in sitewide

groundwater elevation was evident. Groundwater remained depressed in the vicinity of the operating extraction

well, with a smaller capture zone commensurate with the reduced cumulative pumping rate.

Figures 10 and 11 present hydrogeologic cross sections including all of the pumping wells, with Figure 10

presenting the May 2017 data under fully pumping conditions and October 2017 after the shutdown of four

1 Refer to AMEC (2015) for a complete discussion of the monitoring zones. 2 Select OPD wells are included for downgradient hydraulic monitoring control. No pumping is conducted in the OPD.

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extraction wells. It is noted that upward gradients between the OPD and deep outwash are evident in May 2017,

while the natural downward gradients are evident in October 2017.

In summary, the hydraulic performance data for 2017 show that during the first half of the year the pumping

systems operated as originally designed, and following the shutdown in July 2017 the remaining extraction well

provided continued mass removal in the overburden aquifer.

4.2 Extraction System Shutdown and Rebound Testing

As presented in the Shutdown Evaluation Memorandum (Golder 2015c), substantial concentration reductions in

extraction and monitoring well concentrations have been achieved during full-scale operation of the groundwater

extraction system. The shutdown and rebound testing plan, approved by MPCA on May 7, 2017, included

groundwater sampling to evaluate rebound of VOCs in groundwater. Shallow, intermediate and deep well

sampling was conducted in the following wells:

Shallow well MW04-95-T

Intermediate wells RW07-39-SP, RW07-40-SP, RW06-28-I, MW04-28-I, MW07-41-I and MW07-42-I

Deep wells MW00-43-BR, MW04-30-BR and MW04-29-BR

The wells listed were sampled monthly for VOCs over three months following shutdown using low flow procedures

in accordance with the Site SOP.

Sampling was conducted on August 15, September 22, and October 9-17, 20173. Total cVOC concentrations for

each monitoring well and inactive pumping well included in the testing plan prior to shutdown (May or June 2017)

and for the three months immediately following shutdown (August, September, and October 2017) are presented

in Figure 12 and concentrations for all sampled wells are listed for all wells in Table 4. In the Shallow zone, total

cVOC concentrations continued to decline following shutdown. In the Intermediate zone total cVOCs in

monitoring well MW04-28-I increased during the August event immediately following shutdown, but demonstrated

a decreasing trend in subsequent months. In the deep zone, only monitoring well MW04-30-BR exhibited an

increase in total cVOC concentration during the rebound testing. Immediately following shutdown the total cVOC

concentration increased from 20 ug/L in May 2017 to 74.7 ug/L in August 2017. Concentrations increased further

during the second monthly sampling event following shutdown to a total cVOC concentration of 265.1 ug/L, but

then decreased in the third sampling event to 179 ug/L.

Other wells in the vicinity of the extraction wells were sampled in the May/June 2017 and October 2017 semi-

annual events and the cVOC results are listed below:

MW06-29-I: 347 ug/L, (May) 106 ug/L (October)

MW00-42-MS: 35 ug/L, (May) 27 ug/L (October)

RW06-27-BR: 118 ug/L, (June) 12 ug/L (October)

MW04-26-BR: 187 ug/L, (May) 506 ug/L (October)

3 The October 2017 sampling event comprised sampling of monitoring wells by AMEC October 9-12, and sampling of extraction wells by Golder on October 17.

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MW02-01-OPD: 17 ug/L, (May) 20 ug/L (October)



These results also indicate the lack of rebound throughout the Southeast Area. In particular, it is noted that the

OPD wells display an overall lack of rebound, indicating that while some rebound occurred in deep overburden

(BR) wells, the OPD was not affected.

Based on the continued decline of total cVOCss in all monitoring wells except MW04-30-BR and MW04-28-I,

which exhibited a short term increase following pump shutdown followed by declines in concentration, the

rebound sampling will continue as outlined in Golder, 2015c.

4.3 Routine Semi-annual Groundwater Sampling

Groundwater sampling events were conducted semi-annually for the Site by the data collection and data

management consultant (AMEC Foster Wheeler) on May 2-8 and October 9-13, 2017. These data are reported

annually (AMEC, 2018).

Isopleths of total cVOCs for the October 2017 sampling event are presented for each monitoring zone in Figure

13. In the Shallow zone, total cVOCs were less than 100 ug/L in all network monitoring wells. In the Intermediate

zone, only a single area remains above 100 ug/L near MW06-29-I and RW07-39-SP, with a maximum

concentration of 405.8 ug/L. In the deep zone, a discrete area above 100 ug/L is present near MW04-26-BR and

MW04-30-BR with a maximum concentration of 506.59 ug/L. The areas of total cVOCs over 100 ug/L have

decreased substantially in both magnitude and extent over time. Areas above 10,000 ug/L were historically

present during pre-pumping conditions, with maximum concentrations in the Shallow, Intermediate and Deep

zones of 3,890 ug/L (MW04-95-T), 13,250 ug/L (MW04-28-I), and 14,090 ug/L (MW04-30-BR), respectively.

Contaminant mass reduction over time is documented in the concentration-time graphs for the southeastern area

monitoring well network presented in Appendix A, which includes the historical data and the data collected during

this reporting period. The data show that key monitoring wells in the vicinity of pumping wells have exhibited

substantial declines in contaminant levels, of between 98% and >99%, since pumping was initiated.

Monitoring wells MW07-42-I and MW07-41-I, proximal to pumping wells RW06-28-I, RW07-39-SP and

RW07-40-SP, have shown decreases in cVOCs from 3,875 ug/L to 35 ug/L (>99%) and from 5,800 ug/L to

58 ug/L (99%), respectively, since pumping was initiated. In MW06-29-I, which is installed at a deeper

interval near these pumping wells, cVOCs concentrations have been variable but overall have decreased

from 193 ug/L (prior to pumping) to 105 ug/L in October 2017.

Monitoring well MW04-28-I, proximal to the Intermediate zone pumping well RW07-38-I, also exhibits

substantially reduced concentrations of cVOCs. Total cVOC concentrations have decreased over two orders

of magnitude from 13,250 ug/L (May 2006) prior to pumping to 59.3 ug/L in October 2017 (>99%).

Monitoring wells proximal to the Deep zone pumping well also exhibit decreasing trends in cVOCs under

pumping conditions. Prior to pumping, cVOC concentrations of deep outwash well MW04-30-BR were as

high as 14,090 ug/L (October 2006) and have decreased by approximately two orders of magnitude to 179

ug/L in October 2017, a decrease of over 98% from the concentration prior to startup. Total cVOC

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concentrations in Deep outwash well MW00-43-BR decreased over two orders of magnitude from 895 ug/L

prior to the system start up (May 2006) to 6.3 ug/L in October 2016, a >99% decrease.

Total cVOC concentrations in bedrock OPD monitoring well MW02-01-OPD, located near RW06-27-BR but

with a deeper well screen (within the Shakopee), decreased from 908 ug/L observed under pre-pumping

conditions (October 2007) to 20.4 ug/L in October 2017, a 98% decrease.

These results from wells within the plume “core”, the areas of highest concentration, indicate that significant

reductions (from 98% to >99%) are occurring, consistent with achieving the system performance goals.

A few peripheral wells in the monitoring network have exhibited variable trends in cVOC concentrations:

A relatively small zone of contaminated groundwater between the area north of the Roundhouse and the

former Waste Reclamation Area is currently monitored by wells MW04-24-T, MW06-01-I, and MW-403D

(See Figure 1). This area was not designed for active remediation due to the presence of naturally declining

concentrations. For example, monitoring well MW-21A had declined from 435 g/L in 1993 to 83 g/L in

October 2012 (an 81% decrease since 1993) and was decommissioned in 2012 (MPCA, 2012). MW04-24-T

has maintained a steadily downward trend in concentration (Appendix A). Well MW-403D has exhibited

stable cVOC concentrations since system startup. Monitoring well MW06-01-I is part of a three well cluster

that also includes a shallower well (MW06-01-T) and a deeper well (MW06-01-BR). Total cVOCs have not

been detected in the shallower zone in MW06-01-T. Total cVOC concentration trends in the deeper well,

MW06-01-BR, are variable, ranging generally between 10 ug/L and 100 ug/L (13.4 g/L in October 2017). In

MW06-01-I, cVOC concentrations have exhibited variability under pumping conditions but exhibit a

downward trend overall since 2012, with a substantial decrease in 2017 to 47.9 g/L, a 94% reduction.

Given the substantial reductions in groundwater concentrations throughout the plume core as a result of pumping,

minor variability in concentrations on the fringes of the plume are not significant with respect to the overall

reduction achieved in plume mass.

5.0 CONCLUSIONS

The overburden groundwater remedial system in the southeastern area of the East Side Shoreham Facility was

operated and maintained in accordance with the design objectives in 2017, and, in addition, an approved

shutdown/rebound testing program was initiated. Shutdown of four of the five extraction wells commenced in July

2017 with rebound monitoring well sampling indicating no adverse impact of partial shutdown. Groundwater

capture at RW07-39-SP remains consistent with that anticipated in design, and 385 pounds of VOCs have been

removed from the groundwater since the startup of the system, with 9.0 pounds being removed in 2017. Wells

within the plume core, monitoring the most contaminated areas prior to operation, exhibit decreases of cVOC

concentrations of 98% to 99% since the start of system operation. Extraction wells RW06-27-BR, RW07-38-I,

RW06-28-I, and RW07-40-SP continued to exhibit decreases of total cVOCs between December 2016 and July

2017. Similarly, extraction well RW07-39-SP continues to show decreases of total VOCs from December 2016 to

December 2017. Semi-annual monitoring of groundwater quality will continue, along with monthly effluent

monitoring, during 2018. The shutdown monitoring program will continue in 2018 with sampling events in January

and May 2018.

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6.0 REFERENCES AMEC Environmental and Infrastructure, Inc., 2018. 2017 Annual Groundwater Monitoring Report, East Side

Shoreham Facility, (MPCA Superfund Program No. SR380, MPCA VIC Site No. 5080), Canadian Pacific, Minneapolis, Minnesota.

Geomega and Golder Associates Inc., 2007. Summary and Users Guide for Joint Outwash Remediation Model, and Source Files. March 14, 2007.

Golder Associates, 2007. Overburden Groundwater Remedial Design, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA April 2007.

Golder Associates, 2009. Response Action Implementation and Monitoring Report, Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA April 2009.

Golder Associates, 2010. 2009 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA August 2010.

Golder Associates, 2011. 2010 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA August 2011.

Golder Associates, 2012. 2011 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA June 2012.

Golder Associates, 2013. 2012 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA May 2013.

Golder Associates, 2014a. 2013 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA May 2014.

Golder Associates, 2014b. Response Action Implementation Report, Soil Vapor Extraction Systems, Former Waste Reclamation Area and Roundhouse/Shops Areas, East Side Shoreham Yard Facility, Minneapolis, Minnesota. Submitted to MPCA May 2014.

Golder Associates, 2015a. 2014 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA April 2015.

Golder Associates, 2015b. Soil Response Action Completion Report, Former Waste Reclamation Area, Roundhouse/Shops Area, East Side Shoreham Yard Facility, Minneapolis, Minnesota. Submitted to MPCA June 2015.

Golder Associates, 2015c Shutdown Evaluation of Southeastern Area Groundwater Extraction and Treatment System, Shoreham Yard Facility, Minneapolis, Minnesota. Submitted to MPCA June 2015.

Golder Associates, 2016a. 2015 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA April 2016.

Golder Associates, 2017. 2016 Annual Report Overburden Groundwater Extraction and Treatment System, Southeastern Area, East Side Shoreham Facility, Minneapolis, Minnesota. Submitted to MPCA April 2017.

Minnesota Pollution Control Agency, 2002. Guidance Document #18, Response Action Plan/Response Action Implementation Report, 17 pp, revised February 2002.

June 2018 023-6105.018

10

Minnesota Pollution Control Agency, 2012. Electronic mail communication from Andrew Nichols, MPCA to Claire Mackler, Golder Associates, cc to Tom Frame, City of Minneapolis, LeeAnn Thomas, CP, James Vondracek, Ashland, Steve Helgen, Integral, Steve Finn, Golder, July 31, 2012.

g:\projects\2002 projects\023-6105 cpr\east side groundwater 2017 annual rpt\es annual rpt (6-28-18).docx

Table 1

Well Construction Information

Annual Report Overburden Groundwater Extraction and Treatment System

Southeastern Area - East Side Shoreham Facility, Minneapolis, MN

023-6105June 2018

Site Well ID*

[ft amsl] [inches] [ft amsl] [depth bgs] [ft amsl] [depth bgs] [ft amsl]

RW06-27-BR* 854.1 6 Stainless Steel 856.53 155 699.1 195 659.1 Outwash

RW06-28-I* 855.1 4 Stainless Steel 857.89 70 785.1 90 765.1 Outwash

RW07-38-I* 854.08 6 Stainless Steel 856.44 90 764.1 110 744.1 Outwash

RW07-39-SP* 854.76 4 Stainless Steel 857.69 45.1 809.7 65.1 789.7 St. Peter Sandstone

RW07-40-SP* 854.85 4 Stainless Steel 857.71 45.2 809.7 65.2 789.7 St. Peter Sandstone

MW00-41-T 853.4 2 Stainless Steel 857.67 39 814.4 49 804.4 St. Peter Sandstone

MW00-42-MS 854.6 2 Stainless Steel 856.88 140 714.6 150 704.6 Outwash/St. Peter Mudstone

MW00-42-T 854.4 2 Stainless Steel 857.31 37 817.4 47 807.4 Outwash

MW00-43-BR 854.3 2 Stainless Steel 856.27 160 694.3 170 684.3 Outwash

MW00-43-T 854.3 2 Stainless Steel 856.85 37 817.3 47 807.3 Glacial Till/Outwash

MW02-01-OPD 854.8 2 Stainless Steel 857.26 220 634.8 240 614.8 Shakopee


MW02-46-I 853.6 2 Stainless Steel 853.32 100 753.6 110 743.6 Outwash

MW02-46-T 853.6 2 Stainless Steel 853.41 40 813.6 50 803.6 Outwash

MW03-56-BR 852.78 2 Stainless Steel 852.26 179 673.8 189 663.8 St. Peter Mudstone


MW04-155-T 853.6 2 Stainless Steel 855.53 33 820.6 43 810.6 Till Sand/St Peter Sandstone

MW04-24-T 854.57 2 Stainless Steel 856.43 33 821.6 43 811.6 Glacial Till

MW04-25-T 854.3 2 Stainless Steel 856.57 33 821.3 43 811.3 Till Silt





MW04-28-T 854.1 2 Stainless Steel 856.19 33 821.1 43 811.1 Outwash/Lacustrine/Outwash



MW04-31-SP 855.6 2 Stainless Steel 858.25 60 795.6 70 785.6 St. Peter Sandstone

MW04-31-T 855.2 2 Stainless Steel 857.91 34 821.2 44 811.2 St. Peter Sandstone

MW04-33-SP 853.8 2 Stainless Steel 855.21 52 801.8 62 791.8 St. Peter Sandstone

MW04-33-T 853.8 2 Stainless Steel 855.38 33.5 820.3 43.5 810.3 Glacial Till


MW05-01-OPSH 855.1 2 Stainless Steel 855.30 219 636.1 239 616.1 Shakopee


MW06-01-BR 854.01 2 Stainless Steel 855.47 176 678.0 180 674.0 St Peter Mudstone/Outwash

MW06-01-I 853.97 2 Stainless Steel 855.53 110.5 743.5 125.5 728.5 Outwash

MW06-01-T 853.92 2 Stainless Steel 855.43 31 822.9 41 812.9 Glacial Till



MW07-41-I 854.84 2 Stainless Steel 857.24 50.3 804.5 60.3 794.5 Glacial Till/Outwash

MW07-42-I 855.02 2 Stainless Steel 857.35 52.8 802.2 62.8 792.2 Outwash

MW-301 853.8 2 Stainless Steel 855.56 37 816.8 47 806.8 Till Silt/St Peter Sandstone

MW-403D 853.8 2 Stainless Steel 856.51 49 804.8 59 794.8 Outwash

MW-406D 856.0 2 Stainless Steel 855.94 53 803.0 63 793.0 Outwash

* Groundwater Recovery Well

Ground

Surface

Well

DiameterScreen Material

Screened Unit

Screened Interval

Top of Well Screen Bottom of Well Screen

Top of

Riser

Elevation

G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2017 Annual Rpt\

Table 1 Well Construction.xlsx Page 1 of 1

0236105018June 2018

Well

IdentificationDate 1,1,1 TCA 1,1 DCA 1,1 DCE

cis-1,2

DCE PCE TCE

[m/d/y] [mg/l] [mg/l] [mg/l] [mg/l] [mg/l] [mg/l]

3/15/17 9.6 18.1 5.3 26.0 24.4 6.3

6/15/17 12.5 21.3 6.1 42.7 28.1 7.5

9/22/17 2.4 0.7 1.2 0.3 11.0 0.5

12/18/17 N/S N/S N/S N/S N/S N/S

3/15/17 6.8 14.4 3.8 5.6 25.8 4.4

6/15/17 8.2 14.3 3.8 7.4 27.4 5.0

9/22/17 5.3 8.1 2.5 1.8 13.6 1.4

12/18/17 N/S N/S N/S N/S N/S N/S

3/15/17 8.8 13.8 3.5 5.9 9.1 1.3

6/15/17 22.9 23.1 6.1 14.5 17.1 2.6

9/22/17 1.5 5.8 0.8 0.5 5.4 0.0

12/18/17 N/S N/S N/S N/S N/S N/S

3/15/17 134.0 68.7 26.3 42.4 259.0 17.2

6/15/17 143.0 79.8 25.8 59.6 219.0 16.6

9/22/17 71.0 56.3 20.7 38.7 183.0 10.5

12/18/17 65.6 41.1 13.7 24.8 189.0 9.8

3/15/17 22.1 25.5 6.7 16.3 46.0 4.1

6/15/17 19.9 19.3 5.1 18.8 44.0 3.8

9/22/17 7.3 2.2 1.5 1.3 39.5 2.8

12/18/17 N/S N/S N/S N/S N/S N/S

N/S: Not sampled Checked by: COM

RW07-40-SP

Table 2

VOC Concentrations in Groundwater Extraction Wells - Quarterly

2017 Annual Report Overburden Groundwater Extraction and Treatment System


RW06-27-BR

RW07-38-I

RW06-28-I

RW07-39-SP

G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2017 Annual Rpt\Tables 2 and 3 and Fig 2 from SE VOC Removal2.xlsx

6/28/2018 Page 1 of 1

0236105018June 2018

Well

IdentificationDate 1,1,1 TCA 1,1 DCA 1,1 DCE

cis-1,2

DCE PCE TCE

[lbs] [lbs] [lbs] [lbs] [lbs] [lbs]

3/15/17 0.144 0.270 0.075 0.401 0.398 0.098

6/15/17 0.163 0.290 0.084 0.506 0.387 0.102

9/22/17 0.044 0.064 0.021 0.126 0.115 0.023

12/18/17 0.000 0.000 0.000 0.000 0.000 0.000

3/15/17 0.071 0.149 0.038 0.060 0.272 0.043

6/15/17 0.076 0.145 0.038 0.066 0.269 0.047

9/22/17 0.027 0.044 0.012 0.018 0.081 0.013

12/18/17 0.000 0.000 0.000 0.000 0.000 0.000

3/15/17 0.035 0.057 0.014 0.023 0.044 0.006

6/15/17 0.080 0.093 0.024 0.051 0.066 0.010

9/22/17 0.025 0.030 0.007 0.016 0.023 0.003

12/18/17 0.000 0.000 0.000 0.000 0.000 0.000

3/15/17 0.179 0.087 0.033 0.055 0.337 0.022

6/15/17 0.242 0.130 0.045 0.089 0.417 0.030

9/22/17 0.169 0.107 0.037 0.077 0.317 0.021

12/18/17 0.107 0.076 0.027 0.050 0.291 0.016

3/15/17 0.061 0.058 0.016 0.040 0.119 0.010

6/15/17 0.054 0.058 0.015 0.045 0.116 0.010

9/22/17 0.011 0.009 0.003 0.008 0.035 0.003

12/18/17 0.000 0.000 0.000 0.000 0.000 0.000

1.488 1.668 0.490 1.631 3.285 0.455 9.0 lbs total

0.585 lbs/Mgal

Total Removed [lbs]

RW06-27-BR

RW07-38-I

RW06-28-I

RW07-39-SP

RW07-40-SP

Table 3

Total VOC Mass Removed

2017 Annual Report Overburden Groundwater Extraction and Treatment System



6/28/2018 Page 1 of 1

Table 4

Southeastern Area Groundwater Extraction System Shutdown Analytical Results - 2017


023-6105June 2018

1,1,1-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Tetrachloroethene Trichloroethene Vinyl Chloride TOTAL

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L

5/3/2017 0.54 0.6 1.2 ND 5.6 ND ND 7.9

8/15/2017 ND ND 1.3 ND 5.8 ND ND 7.1

9/21/2017 ND 0.75 1.6 ND 5.6 ND ND 8.0

10/12/2017 ND 0.38 J 1.1 ND 4.8 ND ND 6.3

5/3/2017 7.4 5.5 1.5 1.9 9.8 3.1 ND 29.2

5/3/2017 7.7 6.0 1.5 2.1 9.9 3.1 ND 30.3

8/15/2017 3.4 22.1 3.3 9.2 31.3 6.9 ND 76.2

9/21/2017 3.6 16.4 2.6 8 27 7.1 ND 64.7

10/10/2017 3.5 3.5 1.5 7.5 32.3 11.0 ND 59.3

10/10/2017 2.8 3.7 0.94 J 8.5 30.5 10.7 ND 57.1

5/4/2017 ND 4.7 ND 3.5 ND 3.9 ND 12.1

8/15/2017 ND 4.7 1.5 3.4 ND 7.3 ND 16.9

9/21/2017 ND 4.4 1.5 2.5 ND 6.5 ND 14.9

10/10/2017 ND 6 1.6 3.9 ND 8.4 ND 19.9

5/5/2017 2.7 1.6 2.3 1.2 8.5 3.7 ND 20.0

8/15/2017 10.8 8.3 5 6.6 39.7 4.1 ND 74.5

9/21/2017 16.1 21.1 13.6 25.9 161 27.4 ND 265.1

10/13/2017 13.7 11 8.3 20.2 105 20.8 ND 179.0

5/1/2017 6.6 0.42 0.48 0.55 46.2 3.5 ND 57.8

8/15/2017 6.4 ND ND ND 47.4 3.6 ND 57.4

9/21/2017 5.7 0.67 0.61 0.57 34.8 3 ND 45.4

10/12/2017 6.5 0.51 J 0.66 J 0.57 J 41 3.2 ND 52.4

5/8/2017 4.1 1.4 ND 3.0 61.3 8.6 ND 78.4

8/15/2017 3.1 0.85 ND 4.7 54.1 6.9 ND 69.7

8/15/2017 3.2 1.0 ND 5.1 52.9 7.4 ND 69.6

9/21/2017 2.5 1.4 ND 4.3 36.4 4.6 ND 49.2

9/21/2017 2.6 1.5 ND 4.9 37.8 5.5 ND 52.3

10/11/2017 3.5 1.6 ND 6.2 39.8 6.5 ND 57.6

5/4/2017 3.5 0.64 ND 0.74 40.2 2.5 ND 47.6

8/15/2017 1.9 ND ND ND 32 1.7 ND 35.6

9/21/2017 ND ND ND ND 27.7 1.4 ND 29.1

10/11/2017 2.5 0.38 J ND 0.39 J 29.7 1.8 ND 34.8

Sample Location

MW04-30-BR

MW04-95-T

MW07-41-I

MW07-42-I

Sample Date

WELLS FROM SHUTDOWN WORK PLAN

MW00-43-BR

MW04-28-I

MW04-29-BR

G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2017 Annual Rpt\Figure 12 and Table 4.xlsx

6/28/2018 Page 1 of 2

Table 4

Southeastern Area Groundwater Extraction System Shutdown Analytical Results - 2017


023-6105June 2018

1,1,1-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Tetrachloroethene Trichloroethene Vinyl Chloride TOTAL

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/LSample Location Sample Date

WELLS FROM SHUTDOWN WORK PLAN6/15/2017 22.9 23.1 6.1 14.5 17.1 2.6 ND 86.3

8/15/2017 6.1 10.0 2 3.6 10.2 1.1 ND 33.0

9/22/2017 1.9 6.2 0.9 0.72 5.8 0.51 ND 16.0

10/17/2017 2.2 6.4 0.89 J 0.68 J 6.2 ND ND 16.4

6/15/2017 143 79.8 25.8 59.6 219 16.6 ND 543.8

8/15/2017 83.1 50.3 17.4 33.6 234 12.5 ND 430.9

9/22/2017 86 79.1 23.8 35.5 213 12.3 ND 449.7

10/17/2017 73.7 45.0 14.8 30.6 192 10.6 ND 366.7

10/17/2017 83.3 50 15.9 31.6 213 12.0 ND 405.8

6/15/2017 19.9 19.3 5.1 18.8 44.0 3.8 ND 110.9

8/15/2017 10.2 10.0 2.6 7.4 49.6 3.5 ND 83.3

9/22/2017 9.1 3.2 1.9 1.9 40.1 3.0 ND 59.2

10/17/2017 12 1.8 1.7 1.6 40.3 2.9 ND 60.3

Notes and Abbreviations:

ND - not detected

ug/L - micrograms per liter

COC - contaminant of concern

VOCs - volatile organic compounds

1. Pre-shutdown samples are dated May and June 2017.

2. Only site-specific COCs are shown. Additional detected VOCs (acetone, chloroethane, trans-1,2-dichloroethene) are not shown.

3. Detected results are bolded.

4. Samples with the same date indicate a primary and duplicate sample

RW07-39-SP

(remains pumping)

RW07-40-SP

RW06-28-I

G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2017 Annual Rpt\Figure 12 and Table 4.xlsx

6/28/2018 Page 2 of 2

MW05-15-T

ST. ANTHONY CEMETERY

MN

65

CE

NTR

AL

AV

E

29TH AVE. NE

28TH AVE. NE

27TH AVE. NE

RW06-28-I

RW06-27-BR

RW07-40-SP

RW07-39-SP

RW07-38-I

4" PVC SEWER DISCHARGE

TREATMENT BUILDING

(2) SECONDARY CONTAINED 1-1/2" x 3"HDPE INFLUENT PIPELINES VENTED "T"

EXISTING SEWER MANHOLE

MW00-41-T

MW00-42-MSMW00-42-T

MW00-43-BRMW00-43-T

MW02-01-OPD

MW02-46-BR

MW02-46-I

MW02-46-T

MW03-56-BR MW03-61-OPD

MW04-24-T

MW04-25-T

MW04-26-BR

MW04-27-T

MW04-28-I

MW04-28-OPDMW04-28-T

MW04-29-BR

MW04-30-BR

MW04-31-SPMW04-31-T

MW04-33-SPMW04-33-T

MW-403D

MW04-95-T

MW06-01-I

MW06-01-TMW06-01-BR

MW06-29-I

MW07-42-I

MW07-41-I

MW06-248-I

SEE NOTE 3

AB

F

G C E

A

A'

RAIL SPUR

MW05-01-OPSH

MW05-06-T

MW04-155-T

MW05-01-MS

MW05-05-T

MW02-03-T

MW-406D

MW00-40-T

MW00-40-MS

MW-301

1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGITAL CAD FILENEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N, R24W HENNEPINCO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.

2.) PROPERTY LINE AND ROW FROM DIGITAL CAD FILE NEW_BASE_8_00-propertyline.dwg PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.

3.) EAST SIDE SHOREHAM SITE AREAS FROM FIGURE 2, "AREA AND LEAKSITELOCATION MAP", STATUS OF RECOGNIZED ENVIRONMENTAL CONDITIONS REPORT,EAST SIDE SHOREHAM FACILITY, AMEC EARTH AND ENVIRONMENTAL, INC. APRIL 2004.AREA G, PROPOSED IN THAT REPORT, IS MODIFIED AND INCLUDED HERE. AREA ASUBDIVIDED AS SHOWN IN FIGURE 2-1 OF PHASE II SUPPLEMENTAL REMEDIALINVESTIGATION REPORT, IT CORPORATION, MAY 2001. NOTE THAT THE AREABOUNDARIES ARE APPROXIMATE ONLY, ARE SHOWN FOR ILLUSTRATIVE PURPOSESONLY, AND DO NOT NECESSARILY REPRESENT AN INTERPRETATION OF THE EXTENTOF POTENTIAL ENVIRONMENTAL IMPACTS OR KNOWN CONTAMINATION.

4.) LOCATION OF WELLS PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.

5.) RAILROAD TRACK LOCATED EAST OF ROUNDHOUSE AREA DIGITIZED FROM FIGURE1, TITLED "TRACK LAYOUT AND EXCAVATION AREA," PROVIDED BY IT CORPORATION,DATED MAY 2001.

DRIVEWAY

RAILROAD TRACKS

FENCE

FOUNDATION OR SLAB

WOODS OUTLINE

WALL

SIDEWALK

ROAD

TRAIL

FACILITY BOUNDARY

TREE

MONITORING WELL

0150 150

SCALE FEET

SOUTHEAST AREAWELL LOCATION MAP

SOO LINE SHOREHAM FACILITYMINNEAPOLIS, MINNESOTA

FIGURE 1

023-6105 0236105BU68

AS SHOWN 0JIH 06/28/18

RG 06/28/18

JIH 06/28/18

ACK 06/28/18

Dra

win

g fil

e: 0

2361

05B

U68

.dw

g

Jun

28,

201

8 - 2

:37p

m

TITLE

DESIGN

PROJECT No. FILE No.

CADD

CHECK

REVIEW

SCALE

PROJECT

REVISION DESCRIPTION CADD CHK RVWDESDATEREV

REV.

NJ Authorization #24GA28029100

LEGEND

REFERENCES

EXTRACTION WELL (INACTIVE)

CROSS SECTION DESIGNATIONA

OTHER SITE MONITORING WELL

EXTRACTION WELL (ACTIVE)

0236105June 2018


6/28/2018 Page 1 of 1

0

50

100

150

200

250

300

350

400

450

Nov-07 Nov-08 Nov-09 Nov-10 Nov-11 Nov-12 Nov-13 Nov-14 Nov-15 Nov-16 Nov-17 Nov-18

Mas

s R

em

ove

d[l

bs]

Figure 2Cumulative cVOC Mass Removal

East Side Shoreham Overburden Groundwater Extraction and Treatment System

Total cVOC Removal =

023-6105June 2018


Figures 3, 4 & 5 (2017).xlsx

814

816

818

820

822

824

826

828

830

832

2006 2008 2010 2012 2014 2016 2018

Ele

vati

on

(ft

msl)

Figure 3Groundwater Level Monitoring in Shallow Zone Wells

2017 Annual Report, Southeast Area

MW-406D MW00-41-T MW00-42-T MW00-43-T MW02-46-T MW04-155-T MW04-24-T

MW04-25-T MW04-27-T MW04-28-T MW04-31-T MW04-33-T MW04-95-T MW06-01-T

023-6105June 2018


Figures 3, 4 & 5 (2017).xlsx

814

816

818

820

822

824

826

828

2005 2006 2008 2009 2010 2012 2013 2014 2016 2017 2019

MW

Ele

vati

on

(ft

msl)Figure 4

Groundwater Level Monitoring in Intermediate Zone Wells2017 Annual Report, Southeast Area

MW-403D MW02-46-I MW04-28-I MW04-31-SP MW04-33-SP

MW06-01-I MW06-248-I MW06-29-I MW07-41-I MW07-42-I

023-6105June 2018


Figures 3, 4 & 5 (2017).xlsx

814

816

818

820

822

824

826

2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018

MW

Ele

vati

on

(ft

msl)Figure 5

Groundwater Level Monitoring In Deep Zone and OPD Wells2017 Annual Report, Southeast Area

MW00-42-MS MW00-43-BR MW02-46-BR MW03-56-BR MW04-26-BR MW04-29-BR

MW04-30-BR MW06-01-BR MW02-01-OPD MW03-61-OPD MW04-28-OPD MW05-01-OPSH

MW05-01-MS

824.61

824.57

824.58

824.43

824.50

823.84

824.51

824.50

MN

65

CE

NTR

AL

AV

E

28TH AVE. NE

27TH AVE. NE

JAC

KS

ON

ST.

PO

LK S

T.

MW03-56-BR

MW00-42-MS

MW06-01-BR

MW04-29-BR

MW00-43-BR

MW04-30-BR

824

824

MW05-01-MS

824.1824.2

824.3

824.5824.6MW04-26-BR

824.6

824.5ST. ANTHONY

CEMETERY

824.4

824.42MW02-46-BR

NMRW06-27-BR

MW05-01-MS

MW04-155-T

MN

65

CE

NTR

AL

AV

E

30TH AVE. NE

29TH AVE. NE

28TH AVE. NE

27TH AVE. NE

QU

INC

Y S

T.

JAC

KS

ON

ST.

PO

LK S

T.

825

826

826

825.5

825

MW-406D

MW-301

MW04-31-T

MW04-27-TMW04-25-T

MW04-155-TMW05-05-T

MW06-01-T

MW05-06-T

MW02-46-T

MW00-41-T

MW04-95-T

MW04-33-T

MW04-24-T

MW05-15-T

824.49

825.12

825.45

825.01824.76

825.22

824.50

824.79

824.97

825.22

826.48

824.90

824.78

824.99

825.54

824.42

825.68

MW02-03-T

MW00-40-T

826.5MW00-43-T

826.66

825.5

826

825 825.5826

MW00-42-T826.62

826.33

MW04-28-T

ST. ANTHONYCEMETERY

MW04-155-T

824.37

825.30824.54

824.50

825.02

824.38

824.46

824.43

824.43

824.33

NM

NM

NM

MN

65

CE

NTR

AL

AV

E

29TH AVE. NE

28TH AVE. NE

27TH AVE. NE

MO

NR

OE

HO

WA

RD

QU

INC

Y S

T.

JAC

KS

ON

ST.

825

825

824.

5

824.5

NM

MW06-29-I

MW06-248-I

MW07-42-I

MW-403D

MW04-31-SP

MW04-28-I

MW02-46-I

MW00-40-MS

MW04-33-SPMW06-01-I

RW07-38-I

RW07-39-SP

RW07-40-SP

RW06-28-I

824.52MW07-41-I

ST. ANTHONYCEMETERY

DRIVEWAY

DRAIN OR SHORELINE

RAILROAD TRACKS

FENCE

FOUNDATION OR SLAB

WOODS OUTLINE

WALL

SIDEWALK

ROAD

TRAIL

TREE

MONITORING WELL

0300 300

SCALE FEET

GROUNDWATER POTENTIOMETRIC CONTOURSMARCH 2017


FIGURE 6

023-6105 0236105BU64


RG 06/28/18

JIH 06/28/18

ACK 06/28/18

Dra

win

g fil

e: 0

2361

05B

U64

.dw

g

Jun

28,

201

8 - 2

:23p

m

TITLE

DESIGN


CADD

CHECK

REVIEW

SCALE

PROJECT


REV.


LEGEND1.) GROUNDWATER LEVELS MEASURED MARCH 14-15, 2017.

2.) CONTOURS AT 1-FT INTERVAL (ONLY) PROVIDED BY AMEC, AS SHOWN IN 2016 VIC ANNUAL GROUNDWATER MONITORING REPORT.

NOTES


1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 & 11 T29N,R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC. ROADS SOUTH OF 27TH AVENUE NE PROVIDED BYAMEC EARTH AND ENVIRONMENTAL, INC.

2.) PROPERTY LINE AND ROW FROM DIGITAL CAD FILE NEW_BASE_8_00-property line.dwg PROVIDED BY AMEC EARTH ANDENVIRONMENTAL, INC.


4.) RAILROAD TRACK LOCATED EAST OF ROUNDHOUSE AREA DIGITIZED FROM FIGURE 1, TITLED "TRACK LAYOUT AND EXCAVATIONAREA," PROVIDED BY IT CORPORATION, DATED MAY 2001.

REFERENCES

(820.74)

SHALLOW

GROUNDWATER ELEVATION(FT AMSL)

INTERMEDIATE

DEEP

820 GROUNDWATER CONTOUR

ABANDONED MONITORING WELL


MW-407D

JAC

KS

ON

ST.


MN

65

30TH AVE. NE

29TH AVE. NE

28TH AVE. NE

27TH AVE. NE

QU

INC

Y S

T.

PO

LK S

T.

CE

NTR

AL

AV

E

825

826827

826.5

825.5

825.5826

826.5

826

826.5

MW04-95-T

MW-406D

MW-301

MW04-33-T

MW04-31-T

MW04-28-T

MW04-27-T MW04-25-T

MW02-03-T

MW00-43-TMW00-42-T

MW00-41-T

MW06-01-TMW05-06-T

MW02-46-T

MW04-155-T

MW05-05-T

MW05-15-T

MW04-24-TMW00-40-T825.82

825.53

825.40

825.37

825.27

825.84

825.35

825.36827.07

827.28826.68

825.32

825.55

826.94

825.30

824.94

825.50

825.56

826.42

825.37

JAC

KS

ON

ST.


MN

65

28TH AVE. NE

27TH AVE. NE

MO

NR

OE

HO

WA

RD

QU

INC

Y S

T.

CE

NTR

AL

AV

E

825

825.25

825.5

825.5

825.57

825.02

825.05

825.08

825.31

825.05

825.35

825.33

824.86

825.24

825.40

NM

NM

NM

NM

MW06-29-I

MW06-248-I

MW07-41-I

MW04-33-SP

MW04-31-SP

MW04-28-I

MW02-46-I

MW00-40-MS

MW-403D

MW06-01-I

MW07-42-I

825

RW06-28-I

RW07-39-SP

RW07-40-SP

RW07-38-I825

MW05-01-MS

MW-407D

JAC

KS

ON

ST.


MN

65

28TH AVE. NE

27TH AVE. NE

PO

LK S

T.

*

824.56

825.54

825.47

825.20

825.50

825.60

825.01

825.44

825.34

CE

NTR

AL

AV

E

RW06-27-BR

824

825

825

824.75

824.5

825.25825.5

825.25825.5

824.75

824.5

MW03-56-BR

MW00-42-MS

MW06-01-BRMW04-26-BR

MW02-46-BR

MW00-43-BR

MW04-30-BR

825.25MW04-29-BR

DRIVEWAY

DRAIN OR SHORELINE

RAILROAD TRACKS

FENCE

FOUNDATION OR SLAB

WOODS OUTLINE

WALL

SIDEWALK

ROAD

TRAIL

TREE

0300 300

SCALE FEET

GROUNDWATER POTENTIOMETRIC CONTOURSMAY 2017


FIGURE 7

023-6105 0236105BU65


RG 06/28/18

JIH 06/28/18

ACK 06/28/18

Dra

win

g fil

e: 0

2361

05B

U65

.dw

g

Jun

28,

201

8 - 2

:34p

m

TITLE

DESIGN


CADD

CHECK

REVIEW

SCALE

PROJECT


REV.


LEGEND1.) GROUNDWATER LEVELS MEASURED MAY 1, 2017.


NOTES





REFERENCES

SHALLOW

INTERMEDIATE

DEEP

MONITORING WELL


(820.74) GROUNDWATER ELEVATION(FT AMSL)





MN

65

CE

NTR

AL

AV

E

30TH AVE. NE

29TH AVE. NE

28TH AVE. NE

27TH AVE. NE

QU

INC

Y S

T.

JAC

KS

ON

ST.

PO

LK S

T.

826.42

826.22

825.33

825.38

825.66

825.03

826.58

825.83

829.56

825.82

NM

NM

825.16

NM

825.73

829.42

830.31

825.89

825.76

824.99

MW04-95-T

MW-406D

MW-301

MW04-33-T

MW04-31-T

MW04-25-T

MW04-24-T

MW00-42-T

MW00-41-T

MW04-155-TMW05-05-T

MW06-01-TMW05-06-T

MW02-46-T

MW-3

MW00-40-T

MW04-27-T

MW05-15-T

MW00-43-T

MW02-03-T

825.91

826

826

825

825

830

826827828829

MW04-28-T


MN

65

CE

NTR

AL

AV

E

29TH AVE. NE

28TH AVE. NE

27TH AVE. NE

MO

NR

OE

HO

WA

RD

QU

INC

Y S

T.

JAC

KS

ON

ST.

824.98

825.04

NM

825.10

825.27

826.06825.01

825.75

825.39

825.36

NM

NM

NM

NM

RW07-39-SP

RW07-38-I

RW07-40-SP

MW-403D

MW04-31-SP

MW04-28-I

MW00-40-MS

MW04-33-SP

MW02-46-I

MW06-248-I

MW06-01-I

MW07-42-I

MW07-41-I

826

825

826

825

825.

5

825.5

825.44MW06-29-I

RW06-28-I


MN

65

CE

NTR

AL

AV

E

28TH AVE. NE

27TH AVE. NE

JAC

KS

ON

ST.

PO

LK S

T.

824.87

825.34

824.81

824.59

MW00-42-MS

MW05-01-MS

MW03-56-BR

824.91MW04-29-BR

825.05MW02-46-BR

825

824.

9

824.

8

824.7

824.6

825

824.9

824.

8

824.

7

824.

6

824.8

825.04NM

RW06-27-BR

MW04-30-BR

MW00-43-BR

824.87MW06-01-BR

MW04-26-BR824.78

DRIVEWAY

DRAIN OR SHORELINE

RAILROAD TRACKS

FENCE

FOUNDATION OR SLAB

WOODS OUTLINE

WALL

SIDEWALK

ROAD

TRAIL

TREE

0300 300

SCALE FEET

GROUNDWATER POTENTIOMETRIC CONTOURSAUGUST 2017


FIGURE 8

023-6105 0236105BU66


RG 06/28/18

JIH 06/28/18

ACK 06/28/18

Dra

win

g fil

e: 0

2361

05B

U66

.dw

g

Jun

28,

201

8 - 2

:35p

m

TITLE

DESIGN


CADD

CHECK

REVIEW

SCALE

PROJECT


REV.


LEGEND1.) GROUNDWATER LEVELS MEASURED AUGUST 10-11, 2017.


NOTES





REFERENCES

SHALLOW

INTERMEDIATE

DEEP

MONITORING WELL







MN

65

CE

NTR

AL

AV

E

30TH AVE. NE

29TH AVE. NE

28TH AVE. NE

27TH AVE. NE

QU

INC

Y S

T.

JAC

KS

ON

ST.

PO

LK S

T.

827.97

826.50

825.68

825.78

826.12

825.38

826.55

826.39

831.15

826.99

NM

NM

825.43

NM

826.20

831.10837.78

NM

826.22

MW04-95-T

MW-406D

MW-301

MW04-33-T

MW04-31-T

MW04-28-T

MW04-25-T

MW04-24-T

MW00-42-T

MW00-41-T

MW04-155-T MW05-05-T

MW06-01-T

MW05-06-T

MW02-46-T

MW-3

MW02-03-T

MW04-27-T

MW05-15-T

825.30

826.20

826

826

MW00-40-T

831 830

829

828

827

827

MW00-43-T


MN

65

CE

NTR

AL

AV

E

29TH AVE. NE

28TH AVE. NE

27TH AVE. NE

MO

NR

OE

HO

WA

RD

QU

INC

Y S

T.

JAC

KS

ON

ST.

825.32

823.39

NM

825.35

825.82

825.59

826.42825.32

826.19

825.73

NM

NMNM

RW07-38-I

MW-403D

MW06-29-I

MW04-31-SP

MW04-28-I

MW00-40-MS

MW04-33-SP

MW02-46-I

MW06-248-I

MW06-01-I

MW07-42-I

826

825.77MW07-41-I

RW06-28-I

RW07-40-SPNM

RW07-39-SP

825.7

582

5.5

826

825.

75

825.

5


MN

65

CE

NTR

AL

AV

E

28TH AVE. NE

27TH AVE. NE

JAC

KS

ON

ST.

PO

LK S

T.

825.31

825.11

825.68

825.08

824.87

825.19

825.16

NM

825.35

MW00-42-MS

MW05-01-MS

MW03-56-BR

RW06-27-BR

MW04-29-BR

MW00-43-BR

MW06-01-BR

MW04-26-BR

MW04-30-BR

MW02-46-BR825.35

825825.1

825.3825.4

825.5

825.

6

825.

7

82582

5.182

5.282

5.3

825.2

DRIVEWAY

DRAIN OR SHORELINE

RAILROAD TRACKS

FENCE

FOUNDATION OR SLAB

WOODS OUTLINE

WALL

SIDEWALK

ROAD

TRAIL

TREE

0300 300

SCALE FEET

GROUNDWATER POTENTIOMETRIC CONTOURSOCTOBER 2017


FIGURE 9

023-6105 0236105BU67


RG 06/28/18

JIH 06/28/18

ACK 06/28/18

Dra

win

g fil

e: 0

2361

05B

U67

.dw

g

Jun

28,

201

8 - 2

:36p

m

TITLE

DESIGN


CADD

CHECK

REVIEW

SCALE

PROJECT


REV.


LEGEND1.) GROUNDWATER LEVELS MEASURED OCTOBER 5-6, 2017.


NOTES





REFERENCES

SHALLOW

INTERMEDIATE

DEEP

MONITORING WELL






WA A'

E

CENTRALAVENUE

ROUND HOUSE

RW06-28-I

RW07-40-SP

RW07-39-SP

ELE

VA

TIO

N (F

T - M

SL)

600

650

700

900

850

800

600

650

700

ELE

VA

TIO

N (F

T - M

SL)

900

850

800

750 750

MW04-95-T

F F

A A A

T T

OW

OPD

MW06-29-I

PROJECTED 42 ft. NE

PROJECTED 19 ft. SW MW04-28-TPROJECTED 5 ft. SW

MW04-28-IPROJECTED 8 ft. NE

MW04-28-OPD

MW02-01-OPD

MW00-43-T

MW04-30-BRPROJECTED 19 ft. SW

OSP-MUDSTONE

PROJECTED 38 ft. SW


MW07-41-I

MW04-29-BRPROJECTED 46 ft. NE

RW07-38-IPROJECTED 27 ft. NE MW00-43-BR

PROJECTED 2 ft. NE

PROJECTED 23 ft. NE

PROJECTED 1 ft. SW

PROJECTED 2 ft. SW

PROJECTED 11 ft. SW

PROJECTED 5 ft. SW

OSP-SANDSTONE

RW06-27-BR

OW

CL

OW

CL

(825.08)

(824.47)

(827.28)

(825.66)

(825.08)

(825.34)

(825.47) (825.44)

(825.02)

(827.07)

(822.70)

(814.59)(819.98)

825.36

(823.31)

(825.62)

(813.43)825.0825.5

825.5

826.0

827.

0

825.

0

825.

1

825.2

825.3

GROUNDWATERPOTENTIOMETRIC CONTOURS

CROSS SECTIONMAY 2017

10SOO LINE SHOREHAM FACILITY

Dra

win

g fil

e: 0

2361

05B

U69

.dw

g

Jun

28,

201

8 - 2

:38p

m

023-6105

0236105BU69

0

AS SHOWN

06/28/18

JIH

RG

JIH

ACKFIGURE

DATE

CHECK

REVIEW

DESIGN

CADD

SCALE

REV.

FILE No.

PROJECT No.

TITLENJ Authorization #24GA28029100

LEGEND

MW00-45-T

NOTESSTRATIGRAPHIC LABELS

F

A

T

OW

OSP

OPD

OW(R)

816.5

BOTTOM OF BOREHOLE

WELL IDENTIFICATION

TOP OF BOREHOLE

1.) ALL GEOLOGIC CONTACTS INTERPOLATED BETWEEN BOREHOLES.

2.) DASHED GEOLOGIC CONTACTS ARE INFERRED.

3.) GROUNDWATER LEVELS MEASURED MAY 11, 2017. RW WELLSMEASURED MAY 15, 2017.

SCREEN INTERVAL

FILL

ALLUVIUM

GLACIAL TILL

OUTWASHDEPOSITS

GLACIO-LACUSTRINE CLAY (CL)

ST PETER SANDSTONE(SANDSTONE AND

MUDSTONE MEMBERS)

PRAIRIE DU CHIEN

OUTWASH DEPOSITS(REWORKED SANDSTONE)

GROUNDWATER EQUIPOTENTIAL(FT AMSL)

070 70

HORIZONTAL SCALE FEET050 50

VERTICAL SCALE FEET

VERTICAL EXAGGERATION = 1.4X

WATER TABLE

WA A'

E

CENTRALAVENUE

ROUND HOUSE

RW06-28-I

RW07-40-SP

RW07-39-SP

ELE

VA

TIO

N (F

T - M

SL)

600

650

700

900

850

800

600

650

700

ELE

VA

TIO

N (F

T - M

SL)

900

850

800

750 750

MW04-95-T

F F

A A A

T T

OW

OPD

MW06-29-I

PROJECTED 42 ft. NE

PROJECTED 19 ft. SW MW04-28-TPROJECTED 5 ft. SW


MW04-28-OPDMW02-01-OPD

MW00-43-T

MW04-30-BRPROJECTED 19 ft. SW

OSP-MUDSTONE

PROJECTED 38 ft. SW


MW07-41-I

MW04-29-BRPROJECTED 46 ft. NE

RW07-38-IPROJECTED 27 ft. NE MW00-43-BR

PROJECTED 2 ft. NE

PROJECTED 23 ft. NE

PROJECTED 1 ft. SW

PROJECTED 2 ft. SWPROJECTED 11 ft. SW

PROJECTED 5 ft. SW

OSP-SANDSTONE

RW06-27-BR

OW

(830.10)

(824.98)

(825.31)

(825.16) (825.11)

(825.82)

(831.78)

(825.97)

(819.93)

NM

(825.59)

(824.93)

(824.85)

(825.73)(825.77)

(826.39)

(825.59)

CL

CL

OW

826.

382

6.2

826.

182

6.0

825.

9

825.9825.8 825.7

825.6

825.5

825.4825.3

825.2

825.1

825.0

830.0825.7

825.6

825.5

825.4

825.2825.1825.0

825.3

GROUNDWATERPOTENTIOMETRIC CONTOURS

CROSS SECTIONOCTOBER 2017

11SOO LINE SHOREHAM FACILITY

Dra

win

g fil

e: 0

2361

05B

U70

.dw

g

Jun

28,

201

8 - 2

:46p

m

023-6105

0236105BU70

0

AS SHOWN

06/28/18

JIH

RG

JIH

ACKFIGURE

DATE

CHECK

REVIEW

DESIGN

CADD

SCALE

REV.

FILE No.

PROJECT No.

TITLENJ Authorization #24GA28029100

LEGEND

MW00-45-T

NOTESSTRATIGRAPHIC LABELS

070 70

HORIZONTAL SCALE FEET050 50

VERTICAL SCALE FEET

VERTICAL EXAGGERATION = 1.4X

F

A

T

OW

OSP

OPD

OW(R)

816.5

BOTTOM OF BOREHOLE

WELL IDENTIFICATION

TOP OF BOREHOLE

1.) ALL GEOLOGIC CONTACTS INTERPOLATED BETWEEN BOREHOLES.

2.) DASHED GEOLOGIC CONTACTS ARE INFERRED.

3.) GROUNDWATER LEVELS MEASURED OCTOBER 5-6, 2017. RW WELLSMEASURED OCTOBER 17, 2017.

SCREEN INTERVAL

FILL

ALLUVIUM

GLACIAL TILL

OUTWASHDEPOSITS

GLACIO-LACUSTRINE CLAY (CL)

ST PETER SANDSTONE(SANDSTONE AND

MUDSTONE MEMBERS)

PRAIRIE DU CHIEN

OUTWASH DEPOSITS(REWORKED SANDSTONE)

GROUNDWATER EQUIPOTENTIAL(FT AMSL)

WATER TABLE

023-6105June 2018

G:\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2017 Annual Rpt\;Figure 12 and Table 4.xlsx

0

50

100

150

200

250

300

4/1/2017 6/1/2017 8/1/2017 10/1/2017 12/1/2017

CO

NC

ENTR

ATI

ON

(U

G/L

)

Figure 12CVOC Post Shutdown Monitoring

2017 Annual Report, Southeast Area

MW00-43-BR MW04-28-I MW04-29-BR MW04-30-BR MW04-95-T

MW07-41-I MW07-42-I RW06-28-I RW07-40-SP

CP PUMPING SHUTDOWN


MN

65

CE

NTR

AL

AV

E

30TH AVE. NE

29TH AVE. NE

28TH AVE. NE

27TH AVE. NE

QU

INC

Y S

T.

JAC

KS

ON

ST.

PO

LK S

T.

MW04-95-T

MW04-33-T

MW04-31-T

MW04-28-T

MW04-27-TMW04-25-T

MW04-24-T

MW00-42-T

MW00-41-T

MW04-155-T

MW06-01-TND

19.54

ND

7.50

3.75

64.44

18.40

NS

84.50

MW00-43-T

52.44

7.00

20.70


MN

65

CE

NTR

AL

AV

E

29TH AVE. NE

28TH AVE. NE

27TH AVE. NE

MO

NR

OE

HO

WA

RD

QU

INC

Y S

T.

JAC

KS

ON

ST.

100

37.20

16.98

34.77

57.60

25.17

14.80RW06-28-I

105.50

72.50

97.90

59.30

RW07-38-INS

MW-403D

MW04-33-SP

MW04-31-SP

MW06-29-IMW06-01-I

MW04-28-IMW07-41-I

MW07-42-I60.30

RW07-40-SP

MW06-248-I

(SEE NOTE 3)

405.80RW07-39-SP


MN

65

CE

NTR

AL

AV

E

28TH AVE. NE

27TH AVE. NE

JAC

KS

ON

ST.

PO

LK S

T.

RW06-27-BR

10013.40

19.90

26.80

6.2811.90

179MW04-29-BR

MW00-42-MS

MW06-01-BR

MW00-43-BR

MW04-30-BR

506.54MW04-26-BR

DRIVEWAY

DRAIN OR SHORELINE

RAILROAD TRACKS

FENCE

FOUNDATION OR SLAB

WOODS OUTLINE

WALL

SIDEWALK

ROAD

TRAIL

TREE

MONITORING WELL

0300 300

SCALE FEET

TOTAL CVOCISOCONCENTRATION CONTOURS

OCTOBER 2017


FIGURE 13

023-6105 0236105BU71


RG 06/28/18

JIH 06/28/18

ACK 06/28/18

Dra

win

g fil

e: 0

2361

05B

U71

.dw

g

Jun

28,

201

8 - 2

:47p

m

TITLE

DESIGN


CADD

CHECK

REVIEW

SCALE

PROJECT


REV.


LEGEND


1.) TOTAL CVOC DATA FOR MONITORING WELLS IS FROM OCTOBER 9-12, 2017 SAMPLING EVENT.

2.) TOTAL CVOC DATA FOR PUMPING WELLS IS FROM OCTOBER 17, 2017 SAMPLING EVENT.

3.) AREA ADJACENT TO FORMER ASHLAND LEASE AREA IS NOT CONTOURED.

4.) TOTAL CVOC = SUM OF 1,1,1-TCA, 1,1-DCA, 1,1-DCE, CIS-1,2-DCE, PCE, AND TCE.

NOTES

54 TOTAL CVOC CONCENTRATION(ug/L)

ND NOT DETECTED

SHALLOW

INTERMEDIATE

DEEP

1.) BASE MAP NORTH OF 27th AVENUE NE FROM DIGITAL CAD FILE NEW_BASE_2_2001.dwg, TITLED "PORTIONS OF SECTIONS 2 &11 T29N, R24W HENNEPIN CO., MN", PROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC. ROADS SOUTH OF 27TH AVENUE NEPROVIDED BY AMEC EARTH AND ENVIRONMENTAL, INC.



4.) RAILROAD TRACK LOCATED EAST OF ROUNDHOUSE AREA DIGITIZED FROM FIGURE 1, TITLED "TRACK LAYOUT ANDEXCAVATION AREA," PROVIDED BY IT CORPORATION, DATED MAY 2001.

REFERENCES100 CVOC CONTOUR (ug/L)

NO CVOC CONCENTRATIONSABOVE 100 ug/L


APPENDIX A

Time-History Concentration Graphs

Figure A-1 023-6105June 2018

\\mtlaurel\Data\PROJECTS\2002 Projects\023-6105 CPR\East Side Groundwater 2017 Annual Rpt\Appendix A\2017 ConcentrationVsTimeGraphs(PnT).xlsm

6/6/2018 Page 1 of 32

CP PUMPING STARTUP

0

1

2

3

4

5

6

7

8

9

10

CO

NC

ENTR

ATI

ON

(U

G/L

)

TIME

MW00-41-T

Total CVOC

1,1,1-TRICHLOROETHANE

1,1-DICHLOROETHANE

1,1-DICHLOROETHENE

CIS-1,2-DICHLOROETHENE

TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP Pumping Shutdown

Total CVOC_ND_only

1,1,1-TRICHLOROETHANE_ND_only

1,1-DICHLOROETHANE_ND_only

1,1-DICHLOROETHENE_ND_only

CIS-1,2-DICHLOROETHENE_ND_only

TETRACHLOROETHENE_ND_only

TRICHLOROETHENE_ND_only

VINYL CHLORIDE_ND_only

Non-detects are plotted at the reporting limit

CP PUMPING SHUTDOWN

Figure A-2 023-6105June 2018


6/6/2018 Page 2 of 32

CP PUMPING SHUTDOWN

0

20

40

60

80

100

120

140

160

180

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW00-42-MS

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-3 023-6105June 2018


6/6/2018 Page 3 of 32

CP PUMPING SHUTDOWN

0

5

10

15

20

25

30

35

40

45

50

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW00-42-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-4 023-6105June 2018


6/6/2018 Page 4 of 32

CP PUMPING SHUTDOWN

0

100

200

300

400

500

600

700

800

900

1000

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW00-43-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-5 023-6105June 2018


6/6/2018 Page 5 of 32

CP PUMPING SHUTDOWN

0

20

40

60

80

100

120

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW00-43-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-6 023-6105June 2018


6/6/2018 Page 6 of 32

CP PUMPING SHUTDOWN

0

100

200

300

400

500

600

700

800

900

1000

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW02-01-OPD

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-7 023-6105June 2018


6/6/2018 Page 7 of 32

CP PUMPING SHUTDOWN

0

20

40

60

80

100

120

140

160

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW03-56-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-8 023-6105June 2018


6/6/2018 Page 8 of 32

CP PUMPING SHUTDOWN

0

100

200

300

400

500

600

700

800

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW03-61-OPD

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-9 023-6105June 2018


6/6/2018 Page 9 of 32

CP PUMPING SHUTDOWN

0

20

40

60

80

100

120

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-155-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-10 023-6105June 2018


6/6/2018 Page 10 of 32

CP PUMPING SHUTDOWN

0

20

40

60

80

100

120

140

160

180

200

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-24-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-11 023-6105June 2018


6/6/2018 Page 11 of 32

CP PUMPING SHUTDOWN

0

2

4

6

8

10

12

14

16

18

20

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-25-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-12 023-6105June 2018


6/6/2018 Page 12 of 32

CP PUMPING SHUTDOWN

0

100

200

300

400

500

600

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-26-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-13 023-6105June 2018


6/6/2018 Page 13 of 32

CP PUMPING SHUTDOWN

0

50

100

150

200

250

300

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-27-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-14 023-6105June 2018


6/6/2018 Page 14 of 32

CP PUMPING SHUTDOWN

0

2000

4000

6000

8000

10000

12000

14000

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-28-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-15 023-6105June 2018


6/6/2018 Page 15 of 32

CP PUMPING SHUTDOWN

0

50

100

150

200

250

300

350

400

450

500

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-28-OPD

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-16 023-6105June 2018


6/6/2018 Page 16 of 32

CP PUMPING SHUTDOWN

0

2

4

6

8

10

12

14

16

18

20

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-28-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-17 023-6105June 2018


6/6/2018 Page 17 of 32

CP PUMPING SHUTDOWN

0

100

200

300

400

500

600

700

800

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-29-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-18 023-6105June 2018


6/6/2018 Page 18 of 32

CP PUMPING SHUTDOWN

0

2000

4000

6000

8000

10000

12000

14000

16000

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-30-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-19 023-6105June 2018


6/6/2018 Page 19 of 32

CP PUMPING SHUTDOWN

0

10

20

30

40

50

60

70

80

90

100

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-31-SP

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-20 023-6105June 2018


6/6/2018 Page 20 of 32

CP PUMPING SHUTDOWN

0

10

20

30

40

50

60

70

80

90

100

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-31-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-21 023-6105June 2018


6/6/2018 Page 21 of 32

CP PUMPING SHUTDOWN

0

20

40

60

80

100

120

140

160

180

200

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-33-SP

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-22 023-6105June 2018


6/6/2018 Page 22 of 32

CP PUMPING SHUTDOWN

0

20

40

60

80

100

120

140

160

180

200

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-33-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-23 023-6105June 2018


6/6/2018 Page 23 of 32

CP PUMPING SHUTDOWN

0

500

1000

1500

2000

2500

3000

3500

4000

4500

5000

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW04-95-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-24 023-6105June 2018


6/6/2018 Page 24 of 32

CP PUMPING SHUTDOWN

0

100

200

300

400

500

600

700

800

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW05-01-OPSH

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-25 023-6105June 2018


6/6/2018 Page 25 of 32

CP PUMPING SHUTDOWN

0

20

40

60

80

100

120

140

160

180

200

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW06-01-BR

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-26 023-6105June 2018


6/6/2018 Page 26 of 32

CP PUMPING SHUTDOWN

0

200

400

600

800

1000

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW06-01-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-27 023-6105June 2018


6/6/2018 Page 27 of 32

CP PUMPING SHUTDOWN

0

5

10

15

20

25

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW06-01-T

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-28 023-6105June 2018


6/6/2018 Page 28 of 32

CP PUMPING SHUTDOWN

0

50

100

150

200

250

300

350

400

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW06-29-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-29 023-6105June 2018


6/6/2018 Page 29 of 32

CP PUMPING SHUTDOWN

0

20

40

60

80

100

120

140

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW06-248-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-30 023-6105June 2018


6/6/2018 Page 30 of 32

CP PUMPING SHUTDOWN

0

1000

2000

3000

4000

5000

6000

7000

8000

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW07-41-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-31 023-6105June 2018


6/6/2018 Page 31 of 32

CP PUMPING SHUTDOWN

0

1000

2000

3000

4000

5000

6000

7000

8000

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW07-42-I

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

Figure A-32 023-6105June 2018


6/6/2018 Page 32 of 32

CP PUMPING SHUTDOWN

0

20

40

60

80

100

120

140

160

180

200

CO

NC

ENTR

ATI

ON

(U

G/L

)

MW-403D

Total CVOC


1,1-DICHLOROETHANE

1,1-DICHLOROETHENE


TETRACHLOROETHENE

TRICHLOROETHENE

VINYL CHLORIDE

CP PUMPING

CP PUMPING SHUTDOWN

Total CVOC_ND_only









CP PUMPING STARTUP

APPENDIX B

Laboratory Results

#=CL#

March 22, 2017

LIMS USE: FR - ALISON ZOLLLIMS OBJECT ID: 40146807

40146807Project:Pace Project No.:

RE:

Alison ZollGolder Associates Inc.744 Broad Street25th FloorNewark, NJ 07102

023-6105-017 CP-SHOREHAM YARD

Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on March 16, 2017. Theresults relate only to the samples included in this report. Results reported herein conform to the mostcurrent, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, whereapplicable, unless otherwise noted in the body of the report.

If you have any questions concerning this report, please feel free to contact me.

Sincerely,

Laurie [email protected]

Project Manager(920)469-2436

Enclosures

REPORT OF LABORATORY ANALYSISThis report shall not be reproduced, except in full,

without the written consent of Pace Analytical Services, LLC.

Pace Analytical Services, LLC1241 Bellevue Street - Suite 9

Green Bay, WI 54302(920)469-2436

Page 1 of 28

#=CP#

CERTIFICATIONS

Pace Project No.:Project:

40146807023-6105-017 CP-SHOREHAM YARD

Green Bay Certification IDs1241 Bellevue Street, Green Bay, WI 54302Florida/NELAP Certification #: E87948Illinois Certification #: 200050Kentucky UST Certification #: 82Louisiana Certification #: 04168Minnesota Certification #: 055-999-334New York Certification #: 12064North Dakota Certification #: R-150

Virginia VELAP ID: 460263South Carolina Certification #: 83006001Texas Certification #: T104704529-14-1Wisconsin Certification #: 405132750Wisconsin DATCP Certification #: 105-444USDA Soil Permit #: P330-16-00157Federal Fish & Wildlife Permit #: LE51774A-0




Green Bay, WI 54302(920)469-2436

Page 2 of 28

#=SS#

SAMPLE SUMMARY


40146807023-6105-017 CP-SHOREHAM YARD

Lab ID Sample ID Matrix Date Collected Date Received

40146807001 031517-0800-200 Water 03/15/17 08:00 03/16/17 09:00

40146807002 RW07-39-SP-0317-100 Water 03/15/17 14:50 03/16/17 09:00

40146807003 RW07-40-SP-0317-100 Water 03/15/17 14:55 03/16/17 09:00

40146807004 RW06-28-I-0317-100 Water 03/15/17 15:00 03/16/17 09:00

40146807005 RW07-38-I-0317-100 Water 03/15/17 15:05 03/16/17 09:00

40146807006 RW06-27-BR-0317-100 Water 03/15/17 15:08 03/16/17 09:00

40146807007 SE EFFLUENT Water 03/15/17 15:13 03/16/17 09:00




Green Bay, WI 54302(920)469-2436

Page 3 of 28

#=SA#

SAMPLE ANALYTE COUNT


40146807023-6105-017 CP-SHOREHAM YARD

Lab ID Sample ID MethodAnalytesReported LaboratoryAnalysts

40146807001 031517-0800-200 EPA 8260 71 PASI-GHNW

40146807002 RW07-39-SP-0317-100 EPA 8260 71 PASI-GHNW


40146807004 RW06-28-I-0317-100 EPA 8260 71 PASI-GHNW

40146807005 RW07-38-I-0317-100 EPA 8260 71 PASI-GHNW

40146807006 RW06-27-BR-0317-100 EPA 8260 71 PASI-GHNW

40146807007 SE EFFLUENT EPA 8260 71 PASI-GHNW

SM 2540D 1 PASI-GJMN

EPA 410.4 1 PASI-GTJJ




Green Bay, WI 54302(920)469-2436

Page 4 of 28

#=AR#

ANALYTICAL RESULTS


40146807023-6105-017 CP-SHOREHAM YARD

Sample: 031517-0800-200 Lab ID: 40146807001 Collected: 03/15/17 08:00 Received: 03/16/17 09:00 Matrix: Water

Parameters Results Units DF Prepared Analyzed CAS No. QualMDLPQL

Analytical Method: EPA 82608260 MSV

Acetone <3.0 ug/L 03/17/17 17:07 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 03/17/17 17:07 107-05-15.0 2.2 1Benzene <0.50 ug/L 03/17/17 17:07 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 03/17/17 17:07 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 03/17/17 17:07 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 03/17/17 17:07 75-27-41.0 0.50 1Bromoform <0.50 ug/L 03/17/17 17:07 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 03/17/17 17:07 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 03/17/17 17:07 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 03/17/17 17:07 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 03/17/17 17:07 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 03/17/17 17:07 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 03/17/17 17:07 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 03/17/17 17:07 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 03/17/17 17:07 75-00-31.0 0.37 1Chloroform <2.5 ug/L 03/17/17 17:07 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 03/17/17 17:07 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 03/17/17 17:07 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 03/17/17 17:07 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 03/17/17 17:07 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 03/17/17 17:07 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 03/17/17 17:07 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 03/17/17 17:07 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 03/17/17 17:07 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 03/17/17 17:07 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 03/17/17 17:07 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 03/17/17 17:07 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 03/17/17 17:07 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 03/17/17 17:07 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 03/17/17 17:07 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 03/17/17 17:07 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 03/17/17 17:07 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 03/17/17 17:07 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 03/17/17 17:07 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 03/17/17 17:07 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 03/17/17 17:07 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 03/17/17 17:07 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 03/17/17 17:07 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 03/17/17 17:07 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 03/17/17 17:07 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 03/17/17 17:07 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 03/17/17 17:07 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 03/17/17 17:07 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 03/17/17 17:07 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 03/17/17 17:07 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 03/17/17 17:07 108-10-15.0 2.1 1


without the written consent of Pace Analytical Services, LLC.Date: 03/22/2017 01:38 PM


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Methyl-tert-butyl ether <0.17 ug/L 03/17/17 17:07 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/17/17 17:07 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/17/17 17:07 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/17/17 17:07 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/17/17 17:07 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/17/17 17:07 79-34-51.0 0.25 1Tetrachloroethene <0.50 ug/L 03/17/17 17:07 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/17/17 17:07 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/17/17 17:07 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/17/17 17:07 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/17/17 17:07 120-82-15.0 2.2 11,1,1-Trichloroethane <0.50 ug/L 03/17/17 17:07 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/17/17 17:07 79-00-51.0 0.20 1Trichloroethene <0.33 ug/L 03/17/17 17:07 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/17/17 17:07 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/17/17 17:07 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/17/17 17:07 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/17/17 17:07 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/17/17 17:07 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 03/17/17 17:07 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/17/17 17:07 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/17/17 17:07 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 102 % 03/17/17 17:07 460-00-470-130 1Dibromofluoromethane (S) 107 % 03/17/17 17:07 1868-53-770-130 1Toluene-d8 (S) 99 % 03/17/17 17:07 2037-26-570-130 1




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Sample: RW07-39-SP-0317-100 Lab ID: 40146807002 Collected: 03/15/17 14:50 Received: 03/16/17 09:00 Matrix: Water



Acetone <7.4 ug/L 03/17/17 17:51 67-64-150.0 7.4 2.5Allyl chloride <5.4 ug/L 03/17/17 17:51 107-05-112.5 5.4 2.5Benzene <1.2 ug/L 03/17/17 17:51 71-43-22.5 1.2 2.5Bromobenzene <0.58 ug/L 03/17/17 17:51 108-86-12.5 0.58 2.5Bromochloromethane <0.85 ug/L 03/17/17 17:51 74-97-52.5 0.85 2.5Bromodichloromethane <1.2 ug/L 03/17/17 17:51 75-27-42.5 1.2 2.5Bromoform <1.2 ug/L 03/17/17 17:51 75-25-22.5 1.2 2.5Bromomethane <6.1 ug/L 03/17/17 17:51 74-83-912.5 6.1 2.52-Butanone (MEK) <7.4 ug/L 03/17/17 17:51 78-93-350.0 7.4 2.5n-Butylbenzene <1.2 ug/L 03/17/17 17:51 104-51-82.5 1.2 2.5sec-Butylbenzene <5.5 ug/L 03/17/17 17:51 135-98-812.5 5.5 2.5tert-Butylbenzene <0.45 ug/L 03/17/17 17:51 98-06-62.5 0.45 2.5Carbon tetrachloride <1.2 ug/L 03/17/17 17:51 56-23-52.5 1.2 2.5Chlorobenzene <1.2 ug/L 03/17/17 17:51 108-90-72.5 1.2 2.5Chloroethane <0.94 ug/L 03/17/17 17:51 75-00-32.5 0.94 2.5Chloroform <6.2 ug/L 03/17/17 17:51 67-66-312.5 6.2 2.5Chloromethane <1.2 ug/L 03/17/17 17:51 74-87-32.5 1.2 2.52-Chlorotoluene <1.2 ug/L 03/17/17 17:51 95-49-82.5 1.2 2.54-Chlorotoluene <0.53 ug/L 03/17/17 17:51 106-43-42.5 0.53 2.51,2-Dibromo-3-chloropropane <5.4 ug/L 03/17/17 17:51 96-12-812.5 5.4 2.5Dibromochloromethane <1.2 ug/L 03/17/17 17:51 124-48-12.5 1.2 2.51,2-Dibromoethane (EDB) <0.44 ug/L 03/17/17 17:51 106-93-42.5 0.44 2.5Dibromomethane <1.1 ug/L 03/17/17 17:51 74-95-32.5 1.1 2.51,2-Dichlorobenzene <1.2 ug/L 03/17/17 17:51 95-50-12.5 1.2 2.51,3-Dichlorobenzene <1.2 ug/L 03/17/17 17:51 541-73-12.5 1.2 2.51,4-Dichlorobenzene <1.2 ug/L 03/17/17 17:51 106-46-72.5 1.2 2.5Dichlorodifluoromethane <0.56 ug/L 03/17/17 17:51 75-71-82.5 0.56 2.51,1-Dichloroethane 68.7 ug/L 03/17/17 17:51 75-34-32.5 0.60 2.51,2-Dichloroethane <0.42 ug/L 03/17/17 17:51 107-06-22.5 0.42 2.51,1-Dichloroethene 26.3 ug/L 03/17/17 17:51 75-35-42.5 1.0 2.5cis-1,2-Dichloroethene 42.4 ug/L 03/17/17 17:51 156-59-22.5 0.64 2.5trans-1,2-Dichloroethene 1.0J ug/L 03/17/17 17:51 156-60-52.5 0.64 2.5Dichlorofluoromethane <0.53 ug/L 03/17/17 17:51 75-43-42.5 0.53 2.51,2-Dichloropropane <0.58 ug/L 03/17/17 17:51 78-87-52.5 0.58 2.51,3-Dichloropropane <1.2 ug/L 03/17/17 17:51 142-28-92.5 1.2 2.52,2-Dichloropropane <1.2 ug/L 03/17/17 17:51 594-20-72.5 1.2 2.51,1-Dichloropropene <1.1 ug/L 03/17/17 17:51 563-58-62.5 1.1 2.5cis-1,3-Dichloropropene <1.2 ug/L 03/17/17 17:51 10061-01-52.5 1.2 2.5trans-1,3-Dichloropropene <0.57 ug/L 03/17/17 17:51 10061-02-62.5 0.57 2.5Diethyl ether (Ethyl ether) <5.6 ug/L 03/17/17 17:51 60-29-712.5 5.6 2.5Ethylbenzene <1.2 ug/L 03/17/17 17:51 100-41-42.5 1.2 2.5Hexachloro-1,3-butadiene <5.3 ug/L 03/17/17 17:51 87-68-312.5 5.3 2.5Isopropylbenzene (Cumene) <0.36 ug/L 03/17/17 17:51 98-82-82.5 0.36 2.5p-Isopropyltoluene <1.2 ug/L 03/17/17 17:51 99-87-62.5 1.2 2.5Methylene Chloride <0.58 ug/L 03/17/17 17:51 75-09-22.5 0.58 2.54-Methyl-2-pentanone (MIBK) <5.4 ug/L 03/17/17 17:51 108-10-112.5 5.4 2.5




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Methyl-tert-butyl ether <0.44 ug/L 03/17/17 17:51 1634-04-42.5 0.44 2.5Naphthalene <6.2 ug/L 03/17/17 17:51 91-20-312.5 6.2 2.5n-Propylbenzene <1.2 ug/L 03/17/17 17:51 103-65-12.5 1.2 2.5Styrene <1.2 ug/L 03/17/17 17:51 100-42-52.5 1.2 2.51,1,1,2-Tetrachloroethane <0.45 ug/L 03/17/17 17:51 630-20-62.5 0.45 2.51,1,2,2-Tetrachloroethane <0.62 ug/L 03/17/17 17:51 79-34-52.5 0.62 2.5Tetrachloroethene 259 ug/L 03/17/17 17:51 127-18-42.5 1.2 2.5Tetrahydrofuran <5.1 ug/L 03/17/17 17:51 109-99-912.5 5.1 2.5Toluene <1.2 ug/L 03/17/17 17:51 108-88-32.5 1.2 2.51,2,3-Trichlorobenzene <5.3 ug/L 03/17/17 17:51 87-61-612.5 5.3 2.51,2,4-Trichlorobenzene <5.5 ug/L 03/17/17 17:51 120-82-112.5 5.5 2.51,1,1-Trichloroethane 134 ug/L 03/17/17 17:51 71-55-62.5 1.2 2.51,1,2-Trichloroethane <0.49 ug/L 03/17/17 17:51 79-00-52.5 0.49 2.5Trichloroethene 17.2 ug/L 03/17/17 17:51 79-01-62.5 0.83 2.5Trichlorofluoromethane <0.46 ug/L 03/17/17 17:51 75-69-42.5 0.46 2.51,2,3-Trichloropropane <1.2 ug/L 03/17/17 17:51 96-18-42.5 1.2 2.51,1,2-Trichlorotrifluoroethane <2.0 ug/L 03/17/17 17:51 76-13-112.5 2.0 2.51,2,4-Trimethylbenzene <1.2 ug/L 03/17/17 17:51 95-63-62.5 1.2 2.51,3,5-Trimethylbenzene <1.2 ug/L 03/17/17 17:51 108-67-82.5 1.2 2.5Vinyl chloride <0.44 ug/L 03/17/17 17:51 75-01-42.5 0.44 2.5m&p-Xylene <2.5 ug/L 03/17/17 17:51 179601-23-15.0 2.5 2.5o-Xylene <1.2 ug/L 03/17/17 17:51 95-47-62.5 1.2 2.5Surrogates4-Bromofluorobenzene (S) 102 % 03/17/17 17:51 460-00-470-130 2.5Dibromofluoromethane (S) 107 % 03/17/17 17:51 1868-53-770-130 2.5Toluene-d8 (S) 100 % 03/17/17 17:51 2037-26-570-130 2.5




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Acetone <3.0 ug/L 03/17/17 12:15 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 03/17/17 12:15 107-05-15.0 2.2 1Benzene <0.50 ug/L 03/17/17 12:15 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 03/17/17 12:15 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 03/17/17 12:15 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 03/17/17 12:15 75-27-41.0 0.50 1Bromoform <0.50 ug/L 03/17/17 12:15 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 03/17/17 12:15 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 03/17/17 12:15 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 03/17/17 12:15 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 03/17/17 12:15 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 03/17/17 12:15 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 03/17/17 12:15 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 03/17/17 12:15 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 03/17/17 12:15 75-00-31.0 0.37 1Chloroform <2.5 ug/L 03/17/17 12:15 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 03/17/17 12:15 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 03/17/17 12:15 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 03/17/17 12:15 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 03/17/17 12:15 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 03/17/17 12:15 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 03/17/17 12:15 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 03/17/17 12:15 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 03/17/17 12:15 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 03/17/17 12:15 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 03/17/17 12:15 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 03/17/17 12:15 75-71-81.0 0.22 11,1-Dichloroethane 25.5 ug/L 03/17/17 12:15 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 03/17/17 12:15 107-06-21.0 0.17 11,1-Dichloroethene 6.7 ug/L 03/17/17 12:15 75-35-41.0 0.41 1cis-1,2-Dichloroethene 16.3 ug/L 03/17/17 12:15 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 03/17/17 12:15 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 03/17/17 12:15 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 03/17/17 12:15 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 03/17/17 12:15 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 03/17/17 12:15 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 03/17/17 12:15 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 03/17/17 12:15 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 03/17/17 12:15 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 03/17/17 12:15 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 03/17/17 12:15 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 03/17/17 12:15 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 03/17/17 12:15 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 03/17/17 12:15 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 03/17/17 12:15 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 03/17/17 12:15 108-10-15.0 2.1 1




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Methyl-tert-butyl ether <0.17 ug/L 03/17/17 12:15 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/17/17 12:15 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/17/17 12:15 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/17/17 12:15 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/17/17 12:15 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/17/17 12:15 79-34-51.0 0.25 1Tetrachloroethene 46.0 ug/L 03/17/17 12:15 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/17/17 12:15 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/17/17 12:15 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/17/17 12:15 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/17/17 12:15 120-82-15.0 2.2 11,1,1-Trichloroethane 22.1 ug/L 03/17/17 12:15 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/17/17 12:15 79-00-51.0 0.20 1Trichloroethene 4.1 ug/L 03/17/17 12:15 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/17/17 12:15 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/17/17 12:15 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/17/17 12:15 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/17/17 12:15 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/17/17 12:15 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 03/17/17 12:15 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/17/17 12:15 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/17/17 12:15 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 100 % 03/17/17 12:15 460-00-470-130 1Dibromofluoromethane (S) 107 % 03/17/17 12:15 1868-53-770-130 1Toluene-d8 (S) 99 % 03/17/17 12:15 2037-26-570-130 1




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Sample: RW06-28-I-0317-100 Lab ID: 40146807004 Collected: 03/15/17 15:00 Received: 03/16/17 09:00 Matrix: Water







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40146807023-6105-017 CP-SHOREHAM YARD

Sample: RW06-27-BR-0317-100 Lab ID: 40146807006 Collected: 03/15/17 15:08 Received: 03/16/17 09:00 Matrix: Water



Acetone <3.0 ug/L 03/17/17 13:22 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 03/17/17 13:22 107-05-15.0 2.2 1Benzene <0.50 ug/L 03/17/17 13:22 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 03/17/17 13:22 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 03/17/17 13:22 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 03/17/17 13:22 75-27-41.0 0.50 1Bromoform <0.50 ug/L 03/17/17 13:22 75-25-21.0 0.50 1Bromomethane <2.4 ug/L 03/17/17 13:22 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 03/17/17 13:22 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 03/17/17 13:22 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 03/17/17 13:22 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 03/17/17 13:22 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 03/17/17 13:22 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 03/17/17 13:22 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 03/17/17 13:22 75-00-31.0 0.37 1Chloroform <2.5 ug/L 03/17/17 13:22 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 03/17/17 13:22 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 03/17/17 13:22 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 03/17/17 13:22 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 03/17/17 13:22 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 03/17/17 13:22 124-48-11.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 03/17/17 13:22 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 03/17/17 13:22 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 03/17/17 13:22 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 03/17/17 13:22 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 03/17/17 13:22 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 03/17/17 13:22 75-71-81.0 0.22 11,1-Dichloroethane 18.1 ug/L 03/17/17 13:22 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 03/17/17 13:22 107-06-21.0 0.17 11,1-Dichloroethene 5.3 ug/L 03/17/17 13:22 75-35-41.0 0.41 1cis-1,2-Dichloroethene 26.0 ug/L 03/17/17 13:22 156-59-21.0 0.26 1trans-1,2-Dichloroethene 0.34J ug/L 03/17/17 13:22 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 03/17/17 13:22 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 03/17/17 13:22 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 03/17/17 13:22 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 03/17/17 13:22 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 03/17/17 13:22 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 03/17/17 13:22 10061-01-51.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 03/17/17 13:22 10061-02-61.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 03/17/17 13:22 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 03/17/17 13:22 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 03/17/17 13:22 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 03/17/17 13:22 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 03/17/17 13:22 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 03/17/17 13:22 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 03/17/17 13:22 108-10-15.0 2.1 1




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ANALYTICAL RESULTS


40146807023-6105-017 CP-SHOREHAM YARD




Methyl-tert-butyl ether <0.17 ug/L 03/17/17 13:22 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 03/17/17 13:22 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 03/17/17 13:22 103-65-11.0 0.50 1Styrene <0.50 ug/L 03/17/17 13:22 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 03/17/17 13:22 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 03/17/17 13:22 79-34-51.0 0.25 1Tetrachloroethene 24.4 ug/L 03/17/17 13:22 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 03/17/17 13:22 109-99-95.0 2.0 1Toluene <0.50 ug/L 03/17/17 13:22 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 03/17/17 13:22 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 03/17/17 13:22 120-82-15.0 2.2 11,1,1-Trichloroethane 9.6 ug/L 03/17/17 13:22 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 03/17/17 13:22 79-00-51.0 0.20 1Trichloroethene 6.3 ug/L 03/17/17 13:22 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 03/17/17 13:22 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 03/17/17 13:22 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 03/17/17 13:22 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 03/17/17 13:22 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 03/17/17 13:22 108-67-81.0 0.50 1Vinyl chloride 0.32J ug/L 03/17/17 13:22 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 03/17/17 13:22 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 03/17/17 13:22 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 102 % 03/17/17 13:22 460-00-470-130 1Dibromofluoromethane (S) 110 % 03/17/17 13:22 1868-53-770-130 1Toluene-d8 (S) 100 % 03/17/17 13:22 2037-26-570-130 1




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ANALYTICAL RESULTS


40146807023-6105-017 CP-SHOREHAM YARD

Sample: SE EFFLUENT Lab ID: 40146807007 Collected: 03/15/17 15:13 Received: 03/16/17 09:00 Matrix: Water







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ANALYTICAL RESULTS


40146807023-6105-017 CP-SHOREHAM YARD





Analytical Method: SM 2540D2540D Total Suspended Solids

Total Suspended Solids <0.95 mg/L 03/17/17 15:262.0 0.95 1

Analytical Method: EPA 410.4 Preparation Method: EPA 410.4410.4 COD

Chemical Oxygen Demand <13.4 mg/L 03/22/17 12:0103/22/17 09:2144.8 13.4 1




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QUALITY CONTROL DATA


40146807023-6105-017 CP-SHOREHAM YARD

Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.

QC Batch:QC Batch Method:

Analysis Method:Analysis Description:

250460EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40146807001, 40146807002, 40146807003, 40146807004, 40146807005, 40146807006, 40146807007

Parameter UnitsBlankResult

ReportingLimit Qualifiers

METHOD BLANK: 1478426Associated Lab Samples: 40146807001, 40146807002, 40146807003, 40146807004, 40146807005, 40146807006, 40146807007

Matrix: Water

AnalyzedMDL

1,1,1,2-Tetrachloroethane ug/L <0.18 1.0 03/17/17 08:520.181,1,1-Trichloroethane ug/L <0.50 1.0 03/17/17 08:520.501,1,2,2-Tetrachloroethane ug/L <0.25 1.0 03/17/17 08:520.251,1,2-Trichloroethane ug/L <0.20 1.0 03/17/17 08:520.201,1,2-Trichlorotrifluoroethane ug/L <0.81 5.0 03/17/17 08:520.811,1-Dichloroethane ug/L <0.24 1.0 03/17/17 08:520.241,1-Dichloroethene ug/L <0.41 1.0 03/17/17 08:520.411,1-Dichloropropene ug/L <0.44 1.0 03/17/17 08:520.441,2,3-Trichlorobenzene ug/L <2.1 5.0 03/17/17 08:522.11,2,3-Trichloropropane ug/L <0.50 1.0 03/17/17 08:520.501,2,4-Trichlorobenzene ug/L <2.2 5.0 03/17/17 08:522.21,2,4-Trimethylbenzene ug/L <0.50 1.0 03/17/17 08:520.501,2-Dibromo-3-chloropropane ug/L <2.2 5.0 03/17/17 08:522.21,2-Dibromoethane (EDB) ug/L <0.18 1.0 03/17/17 08:520.181,2-Dichlorobenzene ug/L <0.50 1.0 03/17/17 08:520.501,2-Dichloroethane ug/L <0.17 1.0 03/17/17 08:520.171,2-Dichloropropane ug/L <0.23 1.0 03/17/17 08:520.231,3,5-Trimethylbenzene ug/L <0.50 1.0 03/17/17 08:520.501,3-Dichlorobenzene ug/L <0.50 1.0 03/17/17 08:520.501,3-Dichloropropane ug/L <0.50 1.0 03/17/17 08:520.501,4-Dichlorobenzene ug/L <0.50 1.0 03/17/17 08:520.502,2-Dichloropropane ug/L <0.48 1.0 03/17/17 08:520.482-Butanone (MEK) ug/L <3.0 20.0 03/17/17 08:523.02-Chlorotoluene ug/L <0.50 1.0 03/17/17 08:520.504-Chlorotoluene ug/L <0.21 1.0 03/17/17 08:520.214-Methyl-2-pentanone (MIBK) ug/L <2.1 5.0 03/17/17 08:522.1Acetone ug/L <3.0 20.0 03/17/17 08:523.0Allyl chloride ug/L <2.2 5.0 03/17/17 08:522.2Benzene ug/L <0.50 1.0 03/17/17 08:520.50Bromobenzene ug/L <0.23 1.0 03/17/17 08:520.23Bromochloromethane ug/L <0.34 1.0 03/17/17 08:520.34Bromodichloromethane ug/L <0.50 1.0 03/17/17 08:520.50Bromoform ug/L <0.50 1.0 03/17/17 08:520.50Bromomethane ug/L <2.4 5.0 03/17/17 08:522.4Carbon tetrachloride ug/L <0.50 1.0 03/17/17 08:520.50Chlorobenzene ug/L <0.50 1.0 03/17/17 08:520.50Chloroethane ug/L <0.37 1.0 03/17/17 08:520.37Chloroform ug/L <2.5 5.0 03/17/17 08:522.5Chloromethane ug/L <0.50 1.0 03/17/17 08:520.50cis-1,2-Dichloroethene ug/L <0.26 1.0 03/17/17 08:520.26cis-1,3-Dichloropropene ug/L <0.50 1.0 03/17/17 08:520.50




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40146807023-6105-017 CP-SHOREHAM YARD




METHOD BLANK: 1478426Associated Lab Samples: 40146807001, 40146807002, 40146807003, 40146807004, 40146807005, 40146807006, 40146807007

Matrix: Water

AnalyzedMDL

Dibromochloromethane ug/L <0.50 1.0 03/17/17 08:520.50Dibromomethane ug/L <0.43 1.0 03/17/17 08:520.43Dichlorodifluoromethane ug/L <0.22 1.0 03/17/17 08:520.22Dichlorofluoromethane ug/L <0.21 1.0 03/17/17 08:520.21Diethyl ether (Ethyl ether) ug/L <2.2 5.0 03/17/17 08:522.2Ethylbenzene ug/L <0.50 1.0 03/17/17 08:520.50Hexachloro-1,3-butadiene ug/L <2.1 5.0 03/17/17 08:522.1Isopropylbenzene (Cumene) ug/L <0.14 1.0 03/17/17 08:520.14m&p-Xylene ug/L <1.0 2.0 03/17/17 08:521.0Methyl-tert-butyl ether ug/L <0.17 1.0 03/17/17 08:520.17Methylene Chloride ug/L 0.89J 1.0 03/17/17 08:520.23n-Butylbenzene ug/L <0.50 1.0 03/17/17 08:520.50n-Propylbenzene ug/L <0.50 1.0 03/17/17 08:520.50Naphthalene ug/L <2.5 5.0 03/17/17 08:522.5o-Xylene ug/L <0.50 1.0 03/17/17 08:520.50p-Isopropyltoluene ug/L <0.50 1.0 03/17/17 08:520.50sec-Butylbenzene ug/L <2.2 5.0 03/17/17 08:522.2Styrene ug/L <0.50 1.0 03/17/17 08:520.50tert-Butylbenzene ug/L <0.18 1.0 03/17/17 08:520.18Tetrachloroethene ug/L <0.50 1.0 03/17/17 08:520.50Tetrahydrofuran ug/L <2.0 5.0 03/17/17 08:522.0Toluene ug/L <0.50 1.0 03/17/17 08:520.50trans-1,2-Dichloroethene ug/L <0.26 1.0 03/17/17 08:520.26trans-1,3-Dichloropropene ug/L <0.23 1.0 03/17/17 08:520.23Trichloroethene ug/L <0.33 1.0 03/17/17 08:520.33Trichlorofluoromethane ug/L <0.18 1.0 03/17/17 08:520.18Vinyl chloride ug/L <0.18 1.0 03/17/17 08:520.184-Bromofluorobenzene (S) % 101 70-130 03/17/17 08:52Dibromofluoromethane (S) % 111 70-130 03/17/17 08:52Toluene-d8 (S) % 98 70-130 03/17/17 08:52

Parameter UnitsLCS

Result% RecLimits Qualifiers% RecConc.

1478427LABORATORY CONTROL SAMPLE:LCSSpike

1,1,1-Trichloroethane ug/L 50.750 101 70-1311,1,2,2-Tetrachloroethane ug/L 48.150 96 67-1301,1,2-Trichloroethane ug/L 49.450 99 70-1301,1,2-Trichlorotrifluoroethane ug/L 53.850 108 50-1501,1-Dichloroethane ug/L 50.850 102 70-1331,1-Dichloroethene ug/L 51.950 104 70-1301,2,4-Trichlorobenzene ug/L 46.850 94 70-1301,2-Dibromo-3-chloropropane ug/L 47.150 94 50-1501,2-Dibromoethane (EDB) ug/L 49.950 100 70-1301,2-Dichlorobenzene ug/L 47.650 95 70-130




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40146807023-6105-017 CP-SHOREHAM YARD


Parameter UnitsLCS



1,2-Dichloroethane ug/L 48.050 96 70-1301,2-Dichloropropane ug/L 49.150 98 70-1301,3-Dichlorobenzene ug/L 47.750 95 70-1301,4-Dichlorobenzene ug/L 47.750 95 70-130Benzene ug/L 49.350 99 60-135Bromodichloromethane ug/L 48.050 96 70-130Bromoform ug/L 41.450 83 70-130Bromomethane ug/L 38.050 76 33-130Carbon tetrachloride ug/L 50.550 101 70-138Chlorobenzene ug/L 48.250 96 70-130Chloroethane ug/L 43.950 88 51-130Chloroform ug/L 48.650 97 70-130Chloromethane ug/L 45.750 91 25-132cis-1,2-Dichloroethene ug/L 51.050 102 69-130cis-1,3-Dichloropropene ug/L 47.250 94 70-130Dibromochloromethane ug/L 45.550 91 70-130Dichlorodifluoromethane ug/L 42.050 84 23-130Ethylbenzene ug/L 50.950 102 70-136Isopropylbenzene (Cumene) ug/L 51.050 102 70-140m&p-Xylene ug/L 102100 102 70-138Methyl-tert-butyl ether ug/L 51.050 102 66-138Methylene Chloride ug/L 49.650 99 70-130o-Xylene ug/L 49.750 99 70-134Styrene ug/L 50.150 100 70-133Tetrachloroethene ug/L 48.050 96 70-138Toluene ug/L 50.550 101 70-130trans-1,2-Dichloroethene ug/L 50.150 100 70-131trans-1,3-Dichloropropene ug/L 46.150 92 69-130Trichloroethene ug/L 50.650 101 70-130Trichlorofluoromethane ug/L 54.450 109 50-150Vinyl chloride ug/L 53.350 107 49-1304-Bromofluorobenzene (S) % 102 70-130Dibromofluoromethane (S) % 106 70-130Toluene-d8 (S) % 100 70-130

Parameter UnitsMS

Result% RecLimits Qual% RecConc.

1478486MATRIX SPIKE & MATRIX SPIKE DUPLICATE:

MSSpikeResult

40146807003

1478487

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 50 111 70-134111 0 205022.1 77.4 77.41,1,2,2-Tetrachloroethane ug/L 50 101 67-13098 2 2050<0.25 50.4 49.11,1,2-Trichloroethane ug/L 50 101 70-130100 1 2050<0.20 50.3 50.01,1,2-Trichlorotrifluoroethane ug/L 50 115 50-150116 1 2050<0.81 57.6 58.11,1-Dichloroethane ug/L 50 110 70-134107 2 205025.5 80.5 79.01,1-Dichloroethene ug/L 50 111 68-136110 1 20506.7 62.4 61.8




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40146807023-6105-017 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40146807003

1478487

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,2,4-Trichlorobenzene ug/L 50 96 62-13997 1 2050<2.2 48.3 48.81,2-Dibromo-3-chloropropane

ug/L 50 101 50-15098 3 2050<2.2 50.3 49.1

1,2-Dibromoethane (EDB) ug/L 50 102 70-130102 0 2050<0.18 51.2 51.01,2-Dichlorobenzene ug/L 50 97 70-13097 0 2050<0.50 48.5 48.71,2-Dichloroethane ug/L 50 104 70-130104 1 2050<0.17 51.8 52.21,2-Dichloropropane ug/L 50 99 70-130102 2 2050<0.23 49.7 50.81,3-Dichlorobenzene ug/L 50 98 70-13199 2 2050<0.50 48.8 49.61,4-Dichlorobenzene ug/L 50 97 70-13098 1 2050<0.50 48.5 49.1Benzene ug/L 50 106 57-138106 0 2050<0.50 53.1 53.2Bromodichloromethane ug/L 50 98 70-13099 1 2050<0.50 48.8 49.4Bromoform ug/L 50 87 70-13086 1 2050<0.50 43.4 43.0Bromomethane ug/L 50 86 33-13090 4 2750<2.4 43.0 44.9Carbon tetrachloride ug/L 50 97 70-138111 13 2050<0.50 48.4 55.3Chlorobenzene ug/L 50 98 70-13099 1 2050<0.50 48.9 49.4Chloroethane ug/L 50 95 51-13096 2 2050<0.37 47.3 48.0Chloroform ug/L 50 104 70-130104 1 2050<2.5 52.5 52.8Chloromethane ug/L 50 97 25-13296 1 2050<0.50 48.5 48.0cis-1,2-Dichloroethene ug/L 50 110 61-140108 2 205016.3 71.5 70.3cis-1,3-Dichloropropene ug/L 50 98 70-13098 1 2050<0.50 48.8 49.1Dibromochloromethane ug/L 50 94 70-13095 1 2050<0.50 46.8 47.3Dichlorodifluoromethane ug/L 50 88 23-13088 1 2050<0.22 44.1 43.8Ethylbenzene ug/L 50 103 70-138104 0 2050<0.50 51.7 51.8Isopropylbenzene (Cumene) ug/L 50 103 70-152104 1 2050<0.14 51.7 52.2m&p-Xylene ug/L 100 103 70-140105 1 20100<1.0 103 105Methyl-tert-butyl ether ug/L 50 110 66-139110 1 2050<0.17 55.2 54.9Methylene Chloride ug/L 50 104 70-130104 0 2050<0.23 52.1 52.1o-Xylene ug/L 50 101 70-134102 1 2050<0.50 50.6 51.1Styrene ug/L 50 102 70-138102 1 2050<0.50 50.8 51.1Tetrachloroethene ug/L 50 99 70-148102 1 205046.0 95.7 96.8Toluene ug/L 50 103 70-130104 1 2050<0.50 51.4 52.0trans-1,2-Dichloroethene ug/L 50 107 70-133108 1 2050<0.26 53.6 54.1trans-1,3-Dichloropropene ug/L 50 95 69-13096 0 2050<0.23 47.6 47.8Trichloroethene ug/L 50 103 70-131103 1 20504.1 55.5 55.9Trichlorofluoromethane ug/L 50 116 50-150117 1 2050<0.18 57.9 58.5Vinyl chloride ug/L 50 112 49-133113 0 2050<0.18 56.2 56.54-Bromofluorobenzene (S) % 101 70-130101Dibromofluoromethane (S) % 111 70-130110Toluene-d8 (S) % 99 70-13099




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40146807023-6105-017 CP-SHOREHAM YARD




250526SM 2540D

SM 2540D2540D Total Suspended Solids

Associated Lab Samples: 40146807007



METHOD BLANK: 1478958Associated Lab Samples: 40146807007

Matrix: Water

AnalyzedMDL

Total Suspended Solids mg/L <0.48 1.0 03/17/17 15:250.48

Parameter UnitsLCS



Total Suspended Solids mg/L 110100 110 80-120

Parameter UnitsDup

ResultMaxRPD QualifiersRPDResult

401468180011478960SAMPLE DUPLICATE:

Total Suspended Solids mg/L 240 2 5236




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40146807023-6105-017 CP-SHOREHAM YARD




250761EPA 410.4

EPA 410.4410.4 COD





Matrix: Water

AnalyzedMDL

Chemical Oxygen Demand mg/L <13.4 44.8 03/22/17 12:0013.4

Parameter UnitsLCS



Chemical Oxygen Demand mg/L 506500 101 90-110

Parameter UnitsMS



MSSpikeResult

40146769001

1479921

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 10000 102 90-110101 0 10100003380 13600 13500

Parameter UnitsMS



MSSpikeResult

40146862001

1479923

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 526 106 90-110105 1 1052616.1J 574 569




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#=QL#

QUALIFIERS


40146807023-6105-017 CP-SHOREHAM YARD

DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES

Pace Analytical Services - Green BayPASI-G




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#=CR#

QUALITY CONTROL DATA CROSS REFERENCE TABLE


40146807023-6105-017 CP-SHOREHAM YARD

Lab ID Sample ID QC Batch Method QC Batch Analytical MethodAnalyticalBatch

40146807001 250460031517-0800-200 EPA 826040146807002 250460RW07-39-SP-0317-100 EPA 826040146807003 250460RW07-40-SP-0317-100 EPA 826040146807004 250460RW06-28-I-0317-100 EPA 826040146807005 250460RW07-38-I-0317-100 EPA 826040146807006 250460RW06-27-BR-0317-100 EPA 826040146807007 250460SE EFFLUENT EPA 8260

40146807007 250526SE EFFLUENT SM 2540D

40146807007 250761 250817SE EFFLUENT EPA 410.4 EPA 410.4




Green Bay, WI 54302(920)469-2436

Page 26 of 28

Pag

e 27

of 2

8CHAIN-OF-CUSTODY I Analytical Request Document / \< The Chain-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. l.D f e (" ""'- ~ cy ~Q

14 ltJro

7 •• •••••r---·---·--··· Page: l of / Section A Section B Section C

Required Client Information: Required Project Information: Invoice Information:

Company: G : / ,..J As l.}C fl"' :s..ocJ a E-e5 Report To: A- a ~ i) "'\ 2._"U Attention:

Address: /1-'t ./-. 4 ..... nf /\/J Copy To: Company Name: REGULA TORY AGENCY

Address: r NPDES r- GROUND WATER r· DRINKING WATER

Email To: l i/I (;;;;, ,-.U Purchase Order No.: Pace Quote UST RCRA OTHER

't.~5.n" 20 "" -r.r••.-. Reference:

P~~e1 ~ £1.f5 ~11uJFax: Project Name: CP-~lit?>rc ~W"\ '(t/i.--q Pace Project Site Location Miii Manager:

Requested Due Date/TAT: Project Number: Cn ... 3-6/0f"·<? t 7 Pace Profile #: STATE:

Requested Analysis Filtered (YIN) -Section D Matrix Codes ~ a::- z

Required Client Information MATBIX I CQDE :;; COLLECTED Preservatives ):: .'l 0

Drinking Water ow ro () z Water WT 8 II 0

() COMPOSITE COMPOSITE ;:::

Waste Water WW "O ro END/GRAB () z START w Product p ~ ~ -'

~ Soil/Solid SL "' -'

! (!) 0 Cf) ...

SAMPLE ID Oil OL II () a: ... Q)

Wipe WP Q_ I- w Ill c:

w <I: z QI ·~ (A-Z.0-9/,-) Air AR Cl w 0..

~ "O ... :c Sample IDs MUST BE UNIQUE Tissue TS 0 0.. :;; Q) .!!! 0 u 0 i:: w z c: Other OT I- 0 ~ ~ ""' >< w w 0 Q) 0 c: ro 'It (.) (/) "' V') ::> a: -' -' (!: 0 0 I N ro ~ ca 0 0 "O ::;; I- 0.. 0.. lL -0 Cf) .c: Q) c I- ·u; w <( :;; :;; 0 a. Cf) ct)' - .c: ;;:; !: <I: < C: N z U ro Q) - c( Q) ::;: en DATE TIME DATE TIME en 'It :::>I I IZ z :::;:; 0 ... 0::: Pace Project No.I Lab l.D.

1 6>3 IS-17--©<66\9 ·- '2-010 iVr ~ 'l/ l'l/17 <?<600 2- '-X ~ "'IOMJJ lj ' 2

~ "()"2-;

;I) (!ff

~\./&7-3'1-S P -<9~17 - lt9<S? 11.t,-o ) '.)r- ~-'IOM/vft 3 ( \.J~7- 't&-SP ©~i 7 -llt)()i l~).f

4 I, \4fJ 6 2-<6 -I -~ '!>17 - \ ()lrv IS-00 s 5 P-...Wfl7-3'6-I-CS1>17 -l6>ai 1)05 CfJ

oo· 6 A.'W~6-2-7-r:,fl-<:s;"317- 1&<9 l l)o<6 '1J7 7 SE" CffLVE MT ' 1•J ,v \S-13

8

9

10

11

12

ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE

A-llil\ Ph~U1 0.s I Crilrlrr 3/trtt7 i£tl 1

r~C '!>-1~17

/Akfblw B··i&-n .

SAMPLER NAME AND SIGNATURE

PRINT Name of SAMPLER:

SIGNATURE of SAMPLER:

' 3~ J })C

' )>C

3 "' ) ")~ "f.. ;<

TIME ACCEPTED BY I AFFILIATION

l6f 6 Al.l\1lld1t.,,,_/ PA/ ,t=: ,

/&sC A "'

txltJO .Y.J JLtl./I k ~ rL V()& {I

DATE Signed (MM/DD/VY):

*Important Note: By signing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5% per month for any invoices not paid within 30 days.

f { I ..

/' .... ,, '.') }Al '11 c_ 4, 'iO!Aivfj 1-1 Lri tr A

I f I

DATE TIME SAMPLE CONDITIONS

3/rr1ri- l~_,lh 12-·ef- '¥ /\) ·y '

;1<pt_ tfluV :.f.5 'I 'I y

~ t5 ~ " .s

~ >- 0

c "O 0 - £-·- 0 () z "'z 0. t) 'C >: ~~ E " ",,_ ~ .S! () ;;; E

"' "' en en

F-ALL-Q-020rev.07, 15-May-2007

of 28

Sample Condition Upon Receipt Pace Analytical Services, Inc. 1241 Bellevue Street, Suite 9

Green Bay, WI 54302

WOl"40146807 II II II I Ill llll I II II Ill

Custody Seal on Cooler/Box Present: es no Seals intact: f?-yes r no

Custody Seal on Samples Present: r yes rJl'no Seals intact: r yes - no

40146807

Packing Material: lf-subble Wrap If-Bubble Bags r None r Other

Thermometer Used S ~ 8 Type of Ice:~ Blue Dry None Ji(:...samples on ice, cooling process has begun

Cooler Temperature Uncorr: ~ 6 /Corr: '/. _3 Biological Tissue is Frozen: r yes

Temp Blank Present: ~es rno r no Person examiningca2>

Temp should be above freezing to 6°C for all sample except Biota. Date: 3-I -I Frozen Biota Samples should be received s 0°C. Comments: Initials:

Chain of Custody Present: [;i!l'Yes ONo ON/A 1.

Chain of Custody Filled Out: ~Yes 0No ON/A 2.

Chain of Custody Relinquished: r/ves 0No ON/A 3.

Sampler Name & Signature on COC: 0Yes ;1No ON/A 4.

Samples Arrived within Hold Time: ~es ONo ON/A 5.

- VOA Samples frozen upon receipt 0Yes ONo DatefTime:

Short Hold Time Analysis (<72hr): OYes li1fNo ON/A 6.

Rush Turn Around Time Requested: OYes .!2fNo ON/A 7.

Sufficient Volume: ,t:lYes ONo ON/A 8.

Correct Containers Used: >2fves ONo ON/A 9.

-Pace Containers Used: ~es ONo ON/A

-Pace IR Containers Used: 0Yes ONo ,IZJN/A

Containers Intact: ~:s ONo ON/A 10.

Filtered volume received for Dissolved tests OYes ONo ~N/A 11.

Sample Labels match COC: ~wo ON/A 12.

-Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked.

/Jves ONo r HN03 J7 H2S04 rNaOH r NaOH +ZnAct (Non-Compliance noted in 13.) ON/A 13. Ail c"O~t-;;n~i=s-;;-e;;;d"ing prese;;aiion ~r~ tou;,ci to be-in - - -. - - - - - - - - -compliance with EPA recommendation. ¢'ves ONo ON/A (!:!~9~CH2S~s2;}1aqJ::!£n~~l_!:.9.:. ~aOf:l ~12) ______________

' exceptions:®Ar. colifonn, TOC, TOX, TOH, Initial wh:::J< ~Lab Std #ID of l~~te1 O&G, WIDROW, Phenolics, OTHER: i:;x'es ONo complete preservative me:

Headspace in VOA Vials ( >6mm): 0Yes jl1No ON/A 14 .

Trip Blank Present: .z1Ves ONo ON/A 15.

Trip Blank Custody Seals Present c;iWes ONo ON/A

Pace Trip Blank Lot # (if purchased): 31tJ j

Client Notification/ Resolution: "3-/fpt7 5141 If checked, see attached form for additional comments U

Project Manager Review: L Date: 3\ 1 y\q ---------~·---------------

F-GB-C-031-Rev.03 (9April2015) SCUR Form

#=CL#

February 20, 2017



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on February 16, 2017.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.


Sincerely,

Laurie [email protected] Manager

Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS


40145763023-6105-017 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 16

#=SS#

SAMPLE SUMMARY


40145763023-6105-017 CP-SHOREHAM YARD


40145763001 021517-0800-200 Water 02/15/17 08:00 02/16/17 08:50





Green Bay, WI 54302(920)469-2436

Page 3 of 16

#=SA#



40145763023-6105-017 CP-SHOREHAM YARD


40145763001 021517-0800-200 EPA 8260 71 PASI-GHNW





Green Bay, WI 54302(920)469-2436

Page 4 of 16

#=AR#

ANALYTICAL RESULTS


40145763023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 5 of 16

#=AR#

ANALYTICAL RESULTS


40145763023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 6 of 16

#=AR#

ANALYTICAL RESULTS


40145763023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 7 of 16

#=AR#

ANALYTICAL RESULTS


40145763023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 16

#=QC#



40145763023-6105-017 CP-SHOREHAM YARD




248527EPA 8260

EPA 82608260 MSV

Associated Lab Samples: 40145763001, 40145763002



METHOD BLANK: 1468527Associated Lab Samples: 40145763001, 40145763002

Matrix: Water

AnalyzedMDL





Green Bay, WI 54302(920)469-2436

Page 9 of 16

#=QC#



40145763023-6105-017 CP-SHOREHAM YARD





Matrix: Water

AnalyzedMDL

Dibromochloromethane ug/L <0.50 1.0 02/17/17 08:200.50Dibromomethane ug/L <0.43 1.0 02/17/17 08:200.43Dichlorodifluoromethane ug/L <0.22 1.0 02/17/17 08:200.22Dichlorofluoromethane ug/L <0.21 1.0 02/17/17 08:200.21Diethyl ether (Ethyl ether) ug/L <2.2 5.0 02/17/17 08:202.2Ethylbenzene ug/L <0.50 1.0 02/17/17 08:200.50Hexachloro-1,3-butadiene ug/L <2.1 5.0 02/17/17 08:202.1Isopropylbenzene (Cumene) ug/L <0.14 1.0 02/17/17 08:200.14m&p-Xylene ug/L <1.0 2.0 02/17/17 08:201.0Methyl-tert-butyl ether ug/L <0.17 1.0 02/17/17 08:200.17Methylene Chloride ug/L <0.23 1.0 02/17/17 08:200.23n-Butylbenzene ug/L <0.50 1.0 02/17/17 08:200.50n-Propylbenzene ug/L <0.50 1.0 02/17/17 08:200.50Naphthalene ug/L <2.5 5.0 02/17/17 08:202.5o-Xylene ug/L <0.50 1.0 02/17/17 08:200.50p-Isopropyltoluene ug/L <0.50 1.0 02/17/17 08:200.50sec-Butylbenzene ug/L <2.2 5.0 02/17/17 08:202.2Styrene ug/L <0.50 1.0 02/17/17 08:200.50tert-Butylbenzene ug/L <0.18 1.0 02/17/17 08:200.18Tetrachloroethene ug/L <0.50 1.0 02/17/17 08:200.50Tetrahydrofuran ug/L <2.0 5.0 02/17/17 08:202.0Toluene ug/L <0.50 1.0 02/17/17 08:200.50trans-1,2-Dichloroethene ug/L <0.26 1.0 02/17/17 08:200.26trans-1,3-Dichloropropene ug/L <0.23 1.0 02/17/17 08:200.23Trichloroethene ug/L <0.33 1.0 02/17/17 08:200.33Trichlorofluoromethane ug/L <0.18 1.0 02/17/17 08:200.18Vinyl chloride ug/L <0.18 1.0 02/17/17 08:200.184-Bromofluorobenzene (S) % 91 70-130 02/17/17 08:20Dibromofluoromethane (S) % 98 70-130 02/17/17 08:20Toluene-d8 (S) % 100 70-130 02/17/17 08:20

Parameter UnitsLCS







Green Bay, WI 54302(920)469-2436

Page 10 of 16

#=QC#



40145763023-6105-017 CP-SHOREHAM YARD


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40145763002

1468530

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

Page 11 of 16

#=QC#



40145763023-6105-017 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40145763002

1468530

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 101 50-150103 2 2050<2.2 50.5 51.3





Green Bay, WI 54302(920)469-2436

Page 12 of 16

#=QL#

QUALIFIERS


40145763023-6105-017 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES





Green Bay, WI 54302(920)469-2436

Page 13 of 16

#=CR#



40145763023-6105-017 CP-SHOREHAM YARD


40145763001 248527021517-0800-200 EPA 826040145763002 248527SE EFFLUENT EPA 8260




Green Bay, WI 54302(920)469-2436

Page 14 of 16

Pag

e 15

of 1

6UPPER MIDWEST REGIO~ f ~/" MN: 612-607~700 WI: 9\~69-24b Je't'YI

~vJ '·· . I Quote#: i ··--___-

{Please Print Clearly)

Company Name:

Branch/Location:

Project Contact:

1ceAnaJytical• www.paoelabaoom

of

,1LJS/ltJ3

Phone: CHAIN OF CUSTODY Mail To Contact:

*Preservation Codes Project Number: A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#:

Data Package Options (bltlable)

D EPA Level Ill

0 EPA Level lV

MS/MSD 0 On your sample

(billable) 0 NOT needed on

your sample

PACE LAB# CLIENT FIELD ID

Regulatory Program:

H=Sodium Bisulfate Solution

FILTERED? (YES/NO)

Matrix Codes A=Alr W=Water B = Biota OW = Drinking Water

DATE

GW:::: Ground Water SW = Surface Water

o 2. l S' l 7-0WO -2-()() I .,,/rr-/111 e>S~ Se eft\v...e ~t ll./'5/111\t 155"

Rush Turnaround Time Requested- Prelims (Rush TAT subject to approval/surcharge)

Date Needed: Transmit Prelim Rush Results by (complete what you want):

Emall#1:

Emall#2: ,Telephone:

Fax:

Samples on HOLD are subject to

special pricing and release of llablllty

r.01 !lAl?7.!un2006l

!=Sodium Thiosulfate J=Other

DatefTime: IReceived By:

Mall To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

~;rm DatefTime:

Date!Time:

LAB COMMENTS (lab Use Only)

Profile#

~ \)

PACE Project No.

(~jS 4ovl.f 67lt?3

I o oc Receipt Temp= , 3 Sample Receipt pH

OK/ Adjusted

I .DoDlet:.

/ \ itosb£ Seal

of 16


Green Bay, WI 54302 -~An-alyticat (-~aa Project#:

(Client Name: G2\ J.pr .. W0#:40145763 If 1111 111111 II 11111111 Courier: r Fed Ex UPS i Client r Pace ::>ther: \ J.,,)(t \tc()

Tracking#: L C: 2- v

Custody Seal on Cooler/Box Present: yes - no Seals inta~es r no 40145763

Custody Seal on Samples Present: r ye~ no Seals intact: r yes - no

Packing Material: p-!:3ubble Wrap _v.-aU'bble Bags r~ . r Other

Thermometer Used S )2. -{ 0 Type of Ice: Yyet .. lue Dry None ....-p-samples on ice, cooling process has begun

Cooler Temperature Uncorr: 3 /Corr·"3 10 ogical Tissue is Frozen: r yes

Temp Blank Present: ~s rno rno :::o;:+ij\}tents:

Temp should be above freezing to 6°C for all sample except Biota. Initials: ~ Frozen Biota Samples should be received s o•c. Comments:

Chain of Custody Present: ~es ONo ON/A 1.

Chain of Custody Filled Out: ,Z!Yes ONo ON/A 2.

Chain of Custody Relinquished: ¢'es ONo ON/A 3.

Sampler Name & Signature on COC: O'fes ONo ON/A 4.

Samples Arrived within Hold Time: ~ONo ON/A 5.

- VOA Samples frozen upon receipt 0Yes ONo Datemme:

Short Hold Time Analysis (<72hr): 0Yes r.:JNo' ON/A 6.

Rush Tum Around Time Reauested: 0Yes ~ON/A 7.

Sufficient Volume: _,i;a<(es ONo ON/A 8.

Correct Containers Used: 0Yes ONo ON/A 9.

-Pace Containers Used: )2l'Yes ONo ON/A

-Pace IR Containers Used: Oves ONo l;JNrA

Containers Intact: ,,eiYe~ ONo ON/A 10.

Filtered volume received for Dissolved tests Oves ONo~A 11.

Sample Labels match COC: ~s ONo ON/A 12.

-Includes date/time/ID/Analysis Matrix: w All containers needing preservation have been checked.

rHN03 r H2S04 rNaOH r NaOH +ZnAct (Non-Compliance noted in 13.) 0Yes ONo ptliiiA 13. ---- -- - --------- -------- ----- ------ --All containers needing preservation are found to be in ~ compliance with EPA recommendation. OYes ONo /A (!:!,t'9~· H2E§~ NaC2':!+Zn~_?~9.:. ~~':! ~12) ______________ exceptions: OA, lifonn, TOC, TOX, TOH, ~ Initial when l~ab Std #ID of l~iatet O&G, WIDR . , enolics, OTHER: Yes 0No completed preservative ime:

Headspace in VOA Vials ( >6mm ): 0Yes ~ ON/A 14.

Trip Blank Present: ffies 0No ON/A 15.

Trip Blank Custody Seals Present ~ ONo ON/A

Pace Trip Blank Lot# (if purchased): .... )'l? Client Notification/ Resolution: If checked, see attached form for additional comments LJ

Project Manager Review: Date: V/n.efo F-GB-C-031-Rev.03 (9Apri12015) SCUR Form

#=CL#

January 30, 2017



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on January 20, 2017.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.


Sincerely,

Laurie [email protected] Manager

Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS


40144685023-6105-017 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 16

#=SS#

SAMPLE SUMMARY


40144685023-6105-017 CP-SHOREHAM YARD


40144685001 011917-0800-200 Water 01/19/17 08:00 01/20/17 08:45





Green Bay, WI 54302(920)469-2436

Page 3 of 16

#=SA#



40144685023-6105-017 CP-SHOREHAM YARD


40144685001 011917-0800-200 EPA 8260 71 PASI-GLAP

40144685002 SE EFFLUENT EPA 8260 71 PASI-GLAP




Green Bay, WI 54302(920)469-2436

Page 4 of 16

#=AR#

ANALYTICAL RESULTS


40144685023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 5 of 16

#=AR#

ANALYTICAL RESULTS


40144685023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 6 of 16

#=AR#

ANALYTICAL RESULTS


40144685023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 7 of 16

#=AR#

ANALYTICAL RESULTS


40144685023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 16

#=QC#



40144685023-6105-017 CP-SHOREHAM YARD




246856EPA 8260

EPA 82608260 MSV





Matrix: Water

AnalyzedMDL





Green Bay, WI 54302(920)469-2436

Page 9 of 16

#=QC#



40144685023-6105-017 CP-SHOREHAM YARD





Matrix: Water

AnalyzedMDL


Parameter UnitsLCS







Green Bay, WI 54302(920)469-2436

Page 10 of 16

#=QC#



40144685023-6105-017 CP-SHOREHAM YARD


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40144751001

1459633

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 50 108 70-134111 3 2050<0.50 53.9 55.31,1,2,2-Tetrachloroethane ug/L 50 94 67-13097 4 2050<0.25 46.8 48.61,1,2-Trichloroethane ug/L 50 101 70-130104 3 2050<0.20 50.6 51.91,1,2-Trichlorotrifluoroethane ug/L 50 117 50-150118 1 2050<0.81 58.6 59.21,1-Dichloroethane ug/L 50 103 70-134101 2 2050<0.24 51.7 50.61,1-Dichloroethene ug/L 50 107 68-136110 3 2050<0.41 53.3 54.9




Green Bay, WI 54302(920)469-2436

Page 11 of 16

#=QC#



40144685023-6105-017 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40144751001

1459633

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 50 104 50-150104 0 2050<2.2 52.2 52.2

1,2-Dibromoethane (EDB) ug/L 50 107 70-130108 1 2050<0.18 53.7 54.11,2-Dichlorobenzene ug/L 50 106 70-130105 0 2050<0.50 52.8 52.51,2-Dichloroethane ug/L 50 102 70-130106 4 2050<0.17 51.1 53.11,2-Dichloropropane ug/L 50 102 70-130105 2 2050<0.23 51.1 52.41,3-Dichlorobenzene ug/L 50 104 70-131104 0 2050<0.50 52.1 52.21,4-Dichlorobenzene ug/L 50 95 70-130102 6 2050<0.50 47.7 50.8Benzene ug/L 50 109 57-138112 3 20500.65J 55.0 56.7Bromodichloromethane ug/L 50 104 70-130105 1 2050<0.50 51.9 52.4Bromoform ug/L 50 103 70-130104 1 2050<0.50 51.6 52.1Bromomethane ug/L 50 116 33-130114 2 2750<2.4 58.1 56.8Carbon tetrachloride ug/L 50 108 70-138112 3 2050<0.50 54.2 56.1Chlorobenzene ug/L 50 105 70-130105 0 2050<0.50 52.6 52.6Chloroethane ug/L 50 107 51-130114 6 2050<0.37 53.7 56.8Chloroform ug/L 50 106 70-130109 2 2050<2.5 53.2 54.3Chloromethane ug/L 50 113 25-132116 3 2050<0.50 56.7 58.2cis-1,2-Dichloroethene ug/L 50 106 61-140109 3 20502.5 55.3 56.9cis-1,3-Dichloropropene ug/L 50 103 70-130107 3 2050<0.50 51.7 53.3Dibromochloromethane ug/L 50 103 70-130106 3 2050<0.50 51.7 53.1Dichlorodifluoromethane ug/L 50 75 23-13076 1 2050<0.22 37.4 38.0Ethylbenzene ug/L 50 114 70-138114 0 2050<0.50 57.5 57.3Isopropylbenzene (Cumene) ug/L 50 119 70-152119 1 2050<0.14 59.3 59.6m&p-Xylene ug/L 100 117 70-140116 2 20100<1.0 118 116Methyl-tert-butyl ether ug/L 50 107 66-139111 4 2050<0.17 53.4 55.7Methylene Chloride ug/L 50 98 70-130101 3 2050<0.23 49.2 50.5o-Xylene ug/L 50 118 70-134116 2 2050<0.50 59.0 58.1Styrene ug/L 50 111 70-138110 1 2050<0.50 55.5 54.8Tetrachloroethene ug/L 50 107 70-148105 2 2050<0.50 53.6 52.7Toluene ug/L 50 111 70-130113 2 2050<0.50 55.9 56.9trans-1,2-Dichloroethene ug/L 50 103 70-133107 4 2050<0.26 51.4 53.5trans-1,3-Dichloropropene ug/L 50 100 69-13099 0 2050<0.23 49.8 49.6Trichloroethene ug/L 50 108 70-131110 2 20508.0 61.9 63.0Trichlorofluoromethane ug/L 50 115 50-150117 2 2050<0.18 57.4 58.6Vinyl chloride ug/L 50 112 49-133115 2 2050<0.18 56.0 57.44-Bromofluorobenzene (S) % 98 70-13097Dibromofluoromethane (S) % 98 70-13099Toluene-d8 (S) % 98 70-13099




Green Bay, WI 54302(920)469-2436

Page 12 of 16

#=QL#

QUALIFIERS


40144685023-6105-017 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES





Green Bay, WI 54302(920)469-2436

Page 13 of 16

#=CR#



40144685023-6105-017 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 14 of 16

Pag

e 15

of 1

6

Company Name:

Branch/Location:

Project Contact:

Phone:

~ ..sr= REGION Cf •

UPPER MIDWEST Wt ·-·6_; e e"' ~ • ' .ll./LI li 8 S' . 012.001-1100 !-Wl I MN. _

J I Quote#: I 1ceAnalytical 0

www.pBC(llabs.com

*Preservation Codes

CHAIN OF CUSTODY - I mau •o'-omac.: I I Project Number: A=None B=HCL C=H2S04 D=HN03 E=DI Water F=Melhanol G=NaOH

Mail To Company:

Project Name:

Project State:

Sampled By (Print):

Sampled By (Sign):

PO#:

Data Package Options (blllable)

D EPALevellll

D EPA Level IV



your sample

PACE LAB# I CLIENT FIELD ID

011~11-osoo-i.oo

SE &ffl""e"

Regulatory Proaram:


FILTERED? (YES/NO)

PRESERVATION (CODE)*

Matrix Codes A= Air W =Water B = Biota OW = Drinking Watar C = Charcoal GW = Ground Water 0 = Oil SW = Surface Water S =Soil WW= Waste Water SI = Sludae WP = Wi

DATE I TIME

1/fq_// 7 I O-ioO I 'vV 1/11/11113051 '""

Rush Turnaround Time Requested - Prelims (Rush TAT subject to approval/surcharge)


Emai1#1:

11#2: one:


speclal pricing and release of llablllty

C019a(27Jun2006)

Relinquished By:

!=Sodium Thiosulfate J=Olher

OatefTime:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

Date!Time:

LAB COMMENTS Profile#

I. If' PACE Project No.

4o I LJ4l.P<ff' oc

venoon a.o 06lf41os

of 16

aAnalyticat Sample Condition Upon Receipt Pace Analytical Services, LLC. - Green Bay WI

1241 Bellevue Street, Suite 9 Green Bay, WI 54302

Client Name: . tjO/det Courier: Fed Ex r UPS - Client r Pace Other: wa /f CQ Tracking #: a . - f

Project #:r

Custody Seal on Cooler/Box Present: es no Seals intact: K'yes r no

Custody Seal on Samples Present: r yes ~o Seals intact: yes no

W0#:40144685 1111111111111111111111 4014468!!5

Packing Material: r Bubble Wrap l}tBubble Bags r None Other

Thermometer Used ~j.1 Type of lce:6DBlue Dry None ~ Samples on ice, cooling process has begun

Cooler Temperature Uncorr: /Corr: ~ Biological Tissue is Frozen: yes

Temp Blank Present: J(yes no r no Person e1J~~nin~contents: Date: /~J-Temp should be above freezing to 6°C.

Biota Samples may be received at :s; o·c. Comments: lnitials: ---'=ti........,..._ __ _

Chain of Custody Present:

Chain of Custody Filled Out:

Chain of Custody Relinquished:

Sampler Name & Signature on COC:

Samples Arrived within Hold Time:

- VOA Samples frozen upon receipt

Short Hold Time Analysis (<72hr):

Rush Turn Around Time Requested:

Sufficient Volume:

Correct Containers Used:

-Pace Containers Used:

-Pace IR Containers Used:

Containers Intact:

Filtered volume received for Dissolved tests

Sample Labels match COC:

-Includes date/time/ID/Analysis Matrix:

\;.lv,bs ONo ON/A 1.

~1es ONo ON/A 2.

¥Yes ONo ON/A 3.

~s ONo ON/A 4.

·wes ONo ONtA 5.

Oves ONo Date/Time:

Oves ~ ON/A 6.

0Yes ti:Qi ON/A 7.

lJGes ONo ON/A 8. tf s5

ONo ON/A 9.

t:p;e ONo ON/A

0Yes ONo

'K{Yes ONo ON/A 10.

OYes ONo ~11. r;;6es ONo ON/A 12.

w All containers n.eeding preservation have been checked. ~ (Non-Compliance noted in 13.) 0Yes ONo A 13. ---- ---~-- ---- -- -- -- -- --- --- --- -- --- -All containers needing preservation are found to be in compliance with EPA recommendation. Oves ONo f\Ll<l/l

HN03 r H2S04 NaOH NaOH +ZnAct

(HN03, H2S04 s2; NaOH+ZnAct <::9, NaOH <::12) ~· e;;eptio~s~ ~~f~~. TOC~ roi. TOH, - - - - - - - - -~-..L'l - - - - - - _ ..,.ln'""it""ia..,..l _w,...he_n ___ .,..IL_a,_b """st-d""'#""10-o""'f------.11~uat""',e1,...--------1 O&G, WID~Phenolics, OTHER: ~7' 0No completed preservative Time:

Headspace in VOA Vials ( >6mm):

Trip Blank Present:

Trip Blank Custody Seals Present

Pace Trip Blank Lot# (if purchased):

Client Notification/ Resolution:

Person Contacted:

Oves ~o Oves ~ DYes ONo

-------------------Comments/ Resolution:

ON/A 14.

ON/A 15.

~

If checked, see attached form for additional comments D Date/Time:

------------------------------------------------------------~

Project Manager Review:

F-GB-C-031-Rev.04 (12Dec2016) SCUR.xls Pace Analytical Services LLC. - Green Bay WI

Date: 1lt.o(n

#=CL#

December 28, 2017



RE:


0236105018 CP-SHOREHAM YARD

Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on December 19, 2017.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 17

#=CP#

CERTIFICATIONS








Green Bay, WI 54302(920)469-2436

Page 2 of 17

#=SS#

SAMPLE SUMMARY




40162587001 121817-0800-200 Water 12/18/17 08:00 12/19/17 08:45





Green Bay, WI 54302(920)469-2436

Page 3 of 17

#=SA#





40162587001 121817-0800-200 EPA 8260 71 PASI-GLAP







Green Bay, WI 54302(920)469-2436

Page 4 of 17

#=AR#

ANALYTICAL RESULTS






Acetone <3.0 ug/L 12/26/17 13:57 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/26/17 13:57 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/26/17 13:57 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/26/17 13:57 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/26/17 13:57 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/26/17 13:57 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/26/17 13:57 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 12/26/17 13:57 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/26/17 13:57 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/26/17 13:57 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/26/17 13:57 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/26/17 13:57 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/26/17 13:57 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/26/17 13:57 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/26/17 13:57 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/26/17 13:57 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/26/17 13:57 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/26/17 13:57 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/26/17 13:57 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/26/17 13:57 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/26/17 13:57 124-48-15.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/26/17 13:57 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/26/17 13:57 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/26/17 13:57 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/26/17 13:57 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/26/17 13:57 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/26/17 13:57 75-71-81.0 0.22 11,1-Dichloroethane <0.24 ug/L 12/26/17 13:57 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/26/17 13:57 107-06-21.0 0.17 11,1-Dichloroethene <0.41 ug/L 12/26/17 13:57 75-35-41.0 0.41 1cis-1,2-Dichloroethene <0.26 ug/L 12/26/17 13:57 156-59-21.0 0.26 1trans-1,2-Dichloroethene <0.26 ug/L 12/26/17 13:57 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/26/17 13:57 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/26/17 13:57 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/26/17 13:57 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/26/17 13:57 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/26/17 13:57 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/26/17 13:57 10061-01-55.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/26/17 13:57 10061-02-6 L220.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/26/17 13:57 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/26/17 13:57 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/26/17 13:57 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/26/17 13:57 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/26/17 13:57 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/26/17 13:57 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/26/17 13:57 108-10-120.0 2.1 1


without the written consent of Pace Analytical Services, LLC.Date: 12/28/2017 09:00 AM


Green Bay, WI 54302(920)469-2436

Page 5 of 17

#=AR#

ANALYTICAL RESULTS










Green Bay, WI 54302(920)469-2436

Page 6 of 17

#=AR#

ANALYTICAL RESULTS






Acetone <3.0 ug/L 12/26/17 16:35 67-64-120.0 3.0 1Allyl chloride <2.2 ug/L 12/26/17 16:35 107-05-15.0 2.2 1Benzene <0.50 ug/L 12/26/17 16:35 71-43-21.0 0.50 1Bromobenzene <0.23 ug/L 12/26/17 16:35 108-86-11.0 0.23 1Bromochloromethane <0.34 ug/L 12/26/17 16:35 74-97-51.0 0.34 1Bromodichloromethane <0.50 ug/L 12/26/17 16:35 75-27-41.0 0.50 1Bromoform <0.50 ug/L 12/26/17 16:35 75-25-25.0 0.50 1Bromomethane <2.4 ug/L 12/26/17 16:35 74-83-95.0 2.4 12-Butanone (MEK) <3.0 ug/L 12/26/17 16:35 78-93-320.0 3.0 1n-Butylbenzene <0.50 ug/L 12/26/17 16:35 104-51-81.0 0.50 1sec-Butylbenzene <2.2 ug/L 12/26/17 16:35 135-98-85.0 2.2 1tert-Butylbenzene <0.18 ug/L 12/26/17 16:35 98-06-61.0 0.18 1Carbon tetrachloride <0.50 ug/L 12/26/17 16:35 56-23-51.0 0.50 1Chlorobenzene <0.50 ug/L 12/26/17 16:35 108-90-71.0 0.50 1Chloroethane <0.37 ug/L 12/26/17 16:35 75-00-31.0 0.37 1Chloroform <2.5 ug/L 12/26/17 16:35 67-66-35.0 2.5 1Chloromethane <0.50 ug/L 12/26/17 16:35 74-87-31.0 0.50 12-Chlorotoluene <0.50 ug/L 12/26/17 16:35 95-49-81.0 0.50 14-Chlorotoluene <0.21 ug/L 12/26/17 16:35 106-43-41.0 0.21 11,2-Dibromo-3-chloropropane <2.2 ug/L 12/26/17 16:35 96-12-85.0 2.2 1Dibromochloromethane <0.50 ug/L 12/26/17 16:35 124-48-15.0 0.50 11,2-Dibromoethane (EDB) <0.18 ug/L 12/26/17 16:35 106-93-41.0 0.18 1Dibromomethane <0.43 ug/L 12/26/17 16:35 74-95-31.0 0.43 11,2-Dichlorobenzene <0.50 ug/L 12/26/17 16:35 95-50-11.0 0.50 11,3-Dichlorobenzene <0.50 ug/L 12/26/17 16:35 541-73-11.0 0.50 11,4-Dichlorobenzene <0.50 ug/L 12/26/17 16:35 106-46-71.0 0.50 1Dichlorodifluoromethane <0.22 ug/L 12/26/17 16:35 75-71-81.0 0.22 11,1-Dichloroethane 41.1 ug/L 12/26/17 16:35 75-34-31.0 0.24 11,2-Dichloroethane <0.17 ug/L 12/26/17 16:35 107-06-21.0 0.17 11,1-Dichloroethene 13.7 ug/L 12/26/17 16:35 75-35-41.0 0.41 1cis-1,2-Dichloroethene 24.8 ug/L 12/26/17 16:35 156-59-21.0 0.26 1trans-1,2-Dichloroethene 0.47J ug/L 12/26/17 16:35 156-60-51.0 0.26 1Dichlorofluoromethane <0.21 ug/L 12/26/17 16:35 75-43-41.0 0.21 11,2-Dichloropropane <0.23 ug/L 12/26/17 16:35 78-87-51.0 0.23 11,3-Dichloropropane <0.50 ug/L 12/26/17 16:35 142-28-91.0 0.50 12,2-Dichloropropane <0.48 ug/L 12/26/17 16:35 594-20-71.0 0.48 11,1-Dichloropropene <0.44 ug/L 12/26/17 16:35 563-58-61.0 0.44 1cis-1,3-Dichloropropene <0.50 ug/L 12/26/17 16:35 10061-01-55.0 0.50 1trans-1,3-Dichloropropene <0.23 ug/L 12/26/17 16:35 10061-02-6 L220.0 0.23 1Diethyl ether (Ethyl ether) <2.2 ug/L 12/26/17 16:35 60-29-75.0 2.2 1Ethylbenzene <0.50 ug/L 12/26/17 16:35 100-41-41.0 0.50 1Hexachloro-1,3-butadiene <2.1 ug/L 12/26/17 16:35 87-68-35.0 2.1 1Isopropylbenzene (Cumene) <0.14 ug/L 12/26/17 16:35 98-82-81.0 0.14 1p-Isopropyltoluene <0.50 ug/L 12/26/17 16:35 99-87-61.0 0.50 1Methylene Chloride <0.23 ug/L 12/26/17 16:35 75-09-21.0 0.23 14-Methyl-2-pentanone (MIBK) <2.1 ug/L 12/26/17 16:35 108-10-120.0 2.1 1




Green Bay, WI 54302(920)469-2436

Page 7 of 17

#=AR#

ANALYTICAL RESULTS






Methyl-tert-butyl ether <0.17 ug/L 12/26/17 16:35 1634-04-41.0 0.17 1Naphthalene <2.5 ug/L 12/26/17 16:35 91-20-35.0 2.5 1n-Propylbenzene <0.50 ug/L 12/26/17 16:35 103-65-11.0 0.50 1Styrene <0.50 ug/L 12/26/17 16:35 100-42-51.0 0.50 11,1,1,2-Tetrachloroethane <0.18 ug/L 12/26/17 16:35 630-20-61.0 0.18 11,1,2,2-Tetrachloroethane <0.25 ug/L 12/26/17 16:35 79-34-51.0 0.25 1Tetrachloroethene 189 ug/L 12/26/17 16:35 127-18-41.0 0.50 1Tetrahydrofuran <2.0 ug/L 12/26/17 16:35 109-99-95.0 2.0 1Toluene <0.50 ug/L 12/26/17 16:35 108-88-31.0 0.50 11,2,3-Trichlorobenzene <2.1 ug/L 12/26/17 16:35 87-61-65.0 2.1 11,2,4-Trichlorobenzene <2.2 ug/L 12/26/17 16:35 120-82-15.0 2.2 11,1,1-Trichloroethane 65.6 ug/L 12/26/17 16:35 71-55-61.0 0.50 11,1,2-Trichloroethane <0.20 ug/L 12/26/17 16:35 79-00-51.0 0.20 1Trichloroethene 9.8 ug/L 12/26/17 16:35 79-01-61.0 0.33 1Trichlorofluoromethane <0.18 ug/L 12/26/17 16:35 75-69-41.0 0.18 11,2,3-Trichloropropane <0.50 ug/L 12/26/17 16:35 96-18-41.0 0.50 11,1,2-Trichlorotrifluoroethane <0.81 ug/L 12/26/17 16:35 76-13-15.0 0.81 11,2,4-Trimethylbenzene <0.50 ug/L 12/26/17 16:35 95-63-61.0 0.50 11,3,5-Trimethylbenzene <0.50 ug/L 12/26/17 16:35 108-67-81.0 0.50 1Vinyl chloride <0.18 ug/L 12/26/17 16:35 75-01-41.0 0.18 1m&p-Xylene <1.0 ug/L 12/26/17 16:35 179601-23-12.0 1.0 1o-Xylene <0.50 ug/L 12/26/17 16:35 95-47-61.0 0.50 1Surrogates4-Bromofluorobenzene (S) 96 % 12/26/17 16:35 460-00-461-130 1Dibromofluoromethane (S) 96 % 12/26/17 16:35 1868-53-767-130 1Toluene-d8 (S) 98 % 12/26/17 16:35 2037-26-570-130 1




Chemical Oxygen Demand 18.6J mg/L 12/27/17 12:0612/27/17 08:5847.2 14.2 1




Green Bay, WI 54302(920)469-2436

Page 8 of 17

#=QC#







277861EPA 8260

EPA 82608260 MSV





Matrix: Water

AnalyzedMDL





Green Bay, WI 54302(920)469-2436

Page 9 of 17

#=QC#








Matrix: Water

AnalyzedMDL


Parameter UnitsLCS







Green Bay, WI 54302(920)469-2436

Page 10 of 17

#=QC#





Parameter UnitsLCS



1,2-Dichloroethane ug/L 17.720 88 70-1311,2-Dichloropropane ug/L 20.320 101 80-1201,3-Dichlorobenzene ug/L 20.420 102 70-1301,4-Dichlorobenzene ug/L 20.320 102 70-130Benzene ug/L 19.020 95 73-145Bromodichloromethane ug/L 19.220 96 70-130Bromoform ug/L 15.120 75 67-130Bromomethane ug/L 13.120 66 26-128Carbon tetrachloride ug/L 18.720 93 70-133Chlorobenzene ug/L 21.020 105 70-130Chloroethane ug/L 16.020 80 58-120Chloroform ug/L 20.120 101 80-121Chloromethane ug/L 13.020 65 40-127cis-1,2-Dichloroethene ug/L 18.620 93 70-130cis-1,3-Dichloropropene ug/L 17.120 85 70-130Dibromochloromethane ug/L 14.920 75 70-130Dichlorodifluoromethane ug/L 9.220 46 20-135Ethylbenzene ug/L 20.520 103 87-129Isopropylbenzene (Cumene) ug/L 20.920 105 70-130m&p-Xylene ug/L 41.540 104 70-130Methyl-tert-butyl ether ug/L 14.320 72 66-143Methylene Chloride ug/L 16.620 83 70-130o-Xylene ug/L 19.920 99 70-130Styrene ug/L 20.020 100 70-130Tetrachloroethene ug/L 19.720 98 70-130Toluene ug/L 20.020 100 82-130trans-1,2-Dichloroethene ug/L 20.120 100 75-132trans-1,3-Dichloropropene ug/L 13.9 L220 69 70-130Trichloroethene ug/L 21.320 107 70-130Trichlorofluoromethane ug/L 18.420 92 76-133Vinyl chloride ug/L 15.320 77 57-1364-Bromofluorobenzene (S) % 104 61-130Dibromofluoromethane (S) % 98 67-130Toluene-d8 (S) % 97 70-130




Green Bay, WI 54302(920)469-2436

Page 11 of 17

#=QC#







277770SM 2540D






Matrix: Water

AnalyzedMDL


Parameter UnitsLCS



Total Suspended Solids mg/L 98.0100 98 80-120

Parameter UnitsDup



Total Suspended Solids mg/L 24.8 R18 526.8

Parameter UnitsDup



Total Suspended Solids mg/L 50.0 4 552.0




Green Bay, WI 54302(920)469-2436

Page 12 of 17

#=QC#







278002EPA 410.4

EPA 410.4410.4 COD





Matrix: Water

AnalyzedMDL


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40162474001

1634039

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

Chemical Oxygen Demand mg/L 526 106 90-110109 2 1052686.2 646 659

Parameter UnitsMS



MSSpikeResult

40162587002

1634041

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

Page 13 of 17

#=QL#

QUALIFIERS



DEFINITIONS

DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.ND - Not Detected at or above adjusted reporting limit.TNTC - Too Numerous To CountJ - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.MDL - Adjusted Method Detection Limit.PQL - Practical Quantitation Limit.RL - Reporting Limit.S - Surrogate1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.LCS(D) - Laboratory Control Sample (Duplicate)MS(D) - Matrix Spike (Duplicate)DUP - Sample DuplicateRPD - Relative Percent DifferenceNC - Not Calculable.SG - Silica Gel - Clean-UpU - Indicates the compound was analyzed for, but not detected.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.TNI - The NELAC Institute.

LABORATORIES


ANALYTE QUALIFIERS

Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results may be biased low.L2RPD value was outside control limits.R1




Green Bay, WI 54302(920)469-2436

Page 14 of 17

#=CR#






40162587002 277770SE EFFLUENT SM 2540D





Green Bay, WI 54302(920)469-2436

Page 15 of 17

Pag

e 16

of 1

7(Please Print Clearly)

Company Name:

Branch/Location:

Project Contact:

Phone:

Project Number:

Project Name:

Project State:

Sampled By (Print}:

Sampled By (Sign):

PO#:

Ot..)(; [O)O

('p --S l...o re k~""' 'f.i..-d

Regulatory Program:

UPPER MIDWEST REGION

1ceAnalytical 41 MN: 612-607-1700 w_ I:(!;;'(// _9-2436 ~

/ 0( ,/ t CJ:.'' ""--

WWW.pace/ab!S.00/11

CHAIN OF CUSTODY •Preservation Coc!es

A=None B=HCL C=H2S04 D=HND3 E=DI Waler F=Methanol G=NaOH

H=Sodium Bisulfate Solution l=Sodium Thiosuffate J=Other

FILTERED? (YES/NO)

PRESERVATION (CODE)•

uote#: Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Data Package Options (billable)

Matrix Codes A=Air

0 EPA Level II! B =Biota

EPA Level IV

W=Water \r'\ \n Invoice To Phone:

of

DI (t;2t;<i'1 I

MS/MSD

0 On your sample


your sample

C= Charcoal O=Oil S=Soil

OW = Drinking Water GW =Ground Water SW = Surface Water WW =Waste Water WP=Wi r

Cl 0 \J LAB COMMENTS Profile#

PACE LAB# I CLIENT FIELD ID

l l.\ g I 7-0-660 - l..OO s ~ 12 ff{ ~ -r "'t


Date Needed:

Transmit Prelim Rush Results by (complete what you want):


special pricing and release of Hablllty

C019a(27 Jun2006)

Date/Time:

Relinquished By: Datemme: Received By: Datemme:

of 17

Sample Condition Upon Receipt Pace Analytical Services, LLC. - Green Bay WI 1241 Bellevue Street, Suite 9

Green Bay, WI 54302

aceAn{4'/ ica( /.

1 / _ Project #:

/Client Name: ~ 0 CU? r l?A I,,,,/";, Courier: Fed Ex r u:s - Mr:::...e.ace Other: tll~ Tracking#: / D ?" c;} L_7 ::> Custody Seal on Cooler/Box Present: ~es no Seals intact: rJf. yes no

Custody Seal on Samples Present: r yes ~ Seals intact: yes no

W0#:40162587 II 11111111111111111111 40162587

Packing Material: tKBubble Wrai:> rf"Bubble Bags None Other

Thermometer Used ~(4Jg Type of le@ Blue Dry None il'<Samples on ice, cooling process has begun

Cooler Temperature Uncorr: 5 /Corr:S Biological Tissue is Frozen: yes

Temp Blank Present: t;l' yes no no

Temp should be above freezing to 6°C. Biota Samples may be received at s: 0°C. Comments:





. Samples Arrived within Hold Time:




Sufficient Volume:




Containers Intact:



-Includes date/time/ID/Analysis Matrix:

J;ZfYes ONo ON/A 1.

ONo ON/A 2.

,llfves ONo ON/A 3.

~Yes ONo ON/A 4.

fJYes ONo ON/A 5.

OYes ONo Date/Time:

jlf ves ONo ON/A 6.

0Yes [}No ON/A 7. ,

j;i!Yes ONo ON/A 8.

yfves ONo ON/A 9.

~es ONo ON/A

OYes ONo QfJIA rtfes ONo ON/A 10.

0Yes ONo .J;2f'N/A 11.

ON/A 12.

All containers needing preservation have been checked. (No~-9~~1~a~:_ ~oted_i~ 2:·~ ___________ -/-Y':.~ 0 ~~ _o_N~~ 13.

HN03 rH2S04 NaOH NaOH +ZnAct

All containers needing preservation are found to be in complian~A recommendation. rf es ONo ON/A } (~92~~ Na<?lj+Zn~9~9.:. ~aOlj ~12) _____ !._· ________ ~~~:--'7'1-..,...,r-:~~~-:------'T'l'<':=-i--------t exceptions: VOA. coliform, TOC, TOX. TOH, .-/.'. Initial wtie,,,Pt:J( I J JLab Std #ID of 1uate/ O&G, WIDROW, Phenolics, OTHER: OYes LflNo complet::-'~ .VVjpreservative jTime:


Trip Blank Present:


Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution:

0Yes ONo fjN!A 14.

OYes

OYes

' ONo ~/A 15.

ONo JN/A

Person Contacted: Date/Time: --------------Comments/ Resolution:

If checked, see attached form for additional comments 0

---------------------------------------~



oate: <2 \Ci'"' I

#=CL#

November 28, 2017



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on November 21, 2017.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 17

#=CP#

CERTIFICATIONS


40161216023-6105-017 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 17

#=SS#

SAMPLE SUMMARY


40161216023-6105-017 CP-SHOREHAM YARD


40161216001 112017-0800-200 Water 11/20/17 08:00 11/21/17 08:55





Green Bay, WI 54302(920)469-2436

Page 3 of 17

#=SA#



40161216023-6105-017 CP-SHOREHAM YARD


40161216001 112017-0800-200 EPA 8260 71 PASI-GLAP





Green Bay, WI 54302(920)469-2436

Page 4 of 17

#=AR#

ANALYTICAL RESULTS


40161216023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 5 of 17

#=AR#

ANALYTICAL RESULTS


40161216023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 6 of 17

#=AR#

ANALYTICAL RESULTS


40161216023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 7 of 17

#=AR#

ANALYTICAL RESULTS


40161216023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 17

#=QC#



40161216023-6105-017 CP-SHOREHAM YARD




275071EPA 8260

EPA 82608260 MSV





Matrix: Water

AnalyzedMDL





Green Bay, WI 54302(920)469-2436

Page 9 of 17

#=QC#



40161216023-6105-017 CP-SHOREHAM YARD





Matrix: Water

AnalyzedMDL


Parameter UnitsLCS



1,1,1-Trichloroethane ug/L 50.749.6 102 70-1301,1,2,2-Tetrachloroethane ug/L 51.349.6 103 70-1301,1,2-Trichloroethane ug/L 54.549.6 110 70-1301,1,2-Trichlorotrifluoroethane ug/L 60.249.6 121 50-1501,1-Dichloroethane ug/L 52.249.6 105 71-1321,1-Dichloroethene ug/L 55.249.6 111 75-1301,2,4-Trichlorobenzene ug/L 49.949.6 101 70-1301,2-Dibromo-3-chloropropane ug/L 44.849.6 90 63-1231,2-Dibromoethane (EDB) ug/L 55.949.6 113 70-1301,2-Dichlorobenzene ug/L 52.049.6 105 70-130




Green Bay, WI 54302(920)469-2436

Page 10 of 17

#=QC#



40161216023-6105-017 CP-SHOREHAM YARD


Parameter UnitsLCS



1,2-Dichloroethane ug/L 51.849.6 104 70-1311,2-Dichloropropane ug/L 56.249.6 113 80-1201,3-Dichlorobenzene ug/L 51.549.6 104 70-1301,4-Dichlorobenzene ug/L 54.049.6 109 70-130Benzene ug/L 53.249.6 107 73-145Bromodichloromethane ug/L 54.249.6 109 70-130Bromoform ug/L 50.349.6 101 67-130Bromomethane ug/L 39.550 79 26-128Carbon tetrachloride ug/L 51.349.6 103 70-133Chlorobenzene ug/L 55.649.6 112 70-130Chloroethane ug/L 52.850 106 58-120Chloroform ug/L 50.949.6 103 80-121Chloromethane ug/L 45.550 91 40-127cis-1,2-Dichloroethene ug/L 50.049.6 101 70-130cis-1,3-Dichloropropene ug/L 50.549.6 102 70-130Dibromochloromethane ug/L 49.549.6 100 70-130Dichlorodifluoromethane ug/L 43.650 87 20-135Ethylbenzene ug/L 54.049.6 109 87-129Isopropylbenzene (Cumene) ug/L 55.149.6 111 70-130m&p-Xylene ug/L 11499.2 115 70-130Methyl-tert-butyl ether ug/L 48.449.6 98 66-143Methylene Chloride ug/L 50.949.6 103 70-130o-Xylene ug/L 54.449.6 110 70-130Styrene ug/L 55.549.6 112 70-130Tetrachloroethene ug/L 58.149.6 117 70-130Toluene ug/L 55.649.6 112 82-130trans-1,2-Dichloroethene ug/L 55.149.6 111 75-132trans-1,3-Dichloropropene ug/L 48.749.6 98 70-130Trichloroethene ug/L 55.849.6 113 70-130Trichlorofluoromethane ug/L 54.050 108 76-133Vinyl chloride ug/L 53.350 107 57-1364-Bromofluorobenzene (S) % 93 61-130Dibromofluoromethane (S) % 97 67-130Toluene-d8 (S) % 97 70-130

Parameter UnitsMS



MSSpikeResult

40161216002

1618308

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,1,1-Trichloroethane ug/L 49.6 103 70-134106 1 2049.664.9 116 1171,1,2,2-Tetrachloroethane ug/L 49.6 102 70-130106 4 2049.6<0.25 50.7 52.51,1,2-Trichloroethane ug/L 49.6 117 70-130112 4 2049.6<0.20 58.0 55.41,1,2-Trichlorotrifluoroethane ug/L 49.6 120 50-150117 3 2049.6<0.81 59.7 57.91,1-Dichloroethane ug/L 49.6 97 71-13398 1 2049.643.3 91.4 91.91,1-Dichloroethene ug/L 49.6 112 75-136112 0 2049.614.7 70.4 70.3




Green Bay, WI 54302(920)469-2436

Page 11 of 17

#=QC#



40161216023-6105-017 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40161216002

1618308

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.

1,2,4-Trichlorobenzene ug/L 49.6 102 70-130105 3 2049.6<2.2 51.1 52.41,2-Dibromo-3-chloropropane

ug/L 49.6 91 63-12394 3 2049.6<2.2 45.0 46.6

1,2-Dibromoethane (EDB) ug/L 49.6 115 70-130115 0 2049.6<0.18 57.1 57.31,2-Dichlorobenzene ug/L 49.6 104 70-130103 0 2049.6<0.50 51.4 51.31,2-Dichloroethane ug/L 49.6 101 70-131101 1 2049.6<0.17 50.2 49.91,2-Dichloropropane ug/L 49.6 113 80-120115 2 2049.6<0.23 55.9 56.91,3-Dichlorobenzene ug/L 49.6 105 70-130104 1 2049.6<0.50 51.8 51.51,4-Dichlorobenzene ug/L 49.6 109 70-130109 0 2049.6<0.50 54.1 53.8Benzene ug/L 49.6 108 73-145105 3 2049.6<0.50 53.5 52.0Bromodichloromethane ug/L 49.6 112 70-130112 0 2049.6<0.50 55.4 55.4Bromoform ug/L 49.6 105 67-130102 2 2049.6<0.50 52.0 50.8Bromomethane ug/L 50 84 26-12986 2 2050<2.4 42.0 43.0Carbon tetrachloride ug/L 49.6 102 70-134100 2 2049.6<0.50 50.6 49.7Chlorobenzene ug/L 49.6 112 70-130114 2 2049.6<0.50 55.5 56.6Chloroethane ug/L 50 102 58-120102 0 2050<0.37 51.1 50.9Chloroform ug/L 49.6 102 80-121101 0 2049.6<2.5 50.4 50.3Chloromethane ug/L 50 92 40-12889 3 2050<0.50 45.9 44.5cis-1,2-Dichloroethene ug/L 49.6 96 70-130101 3 2049.626.0 73.6 76.1cis-1,3-Dichloropropene ug/L 49.6 103 70-130105 2 2049.6<0.50 51.3 52.3Dibromochloromethane ug/L 49.6 104 70-130101 3 2049.6<0.50 51.5 49.9Dichlorodifluoromethane ug/L 50 84 20-14684 0 2050<0.22 41.8 41.9Ethylbenzene ug/L 49.6 112 87-129110 1 2049.6<0.50 55.3 54.6Isopropylbenzene (Cumene) ug/L 49.6 113 70-130113 0 2049.6<0.14 55.9 55.9m&p-Xylene ug/L 99.2 118 70-130115 2 2099.2<1.0 117 115Methyl-tert-butyl ether ug/L 49.6 96 66-14396 1 2049.6<0.17 47.7 47.4Methylene Chloride ug/L 49.6 99 70-13099 0 2049.6<0.23 49.0 49.1o-Xylene ug/L 49.6 110 70-130109 1 2049.6<0.50 54.4 53.9Styrene ug/L 49.6 112 70-130113 0 2049.6<0.50 55.8 55.8Tetrachloroethene ug/L 49.6 126 70-130126 0 2049.6208 270 270Toluene ug/L 49.6 112 82-131112 0 2049.6<0.50 55.6 55.7trans-1,2-Dichloroethene ug/L 49.6 109 75-135110 0 2049.6<0.26 54.3 54.3trans-1,3-Dichloropropene ug/L 49.6 97 70-130100 3 2049.6<0.23 48.0 49.6Trichloroethene ug/L 49.6 116 70-130116 0 2049.611.2 68.9 68.7Trichlorofluoromethane ug/L 50 105 76-150102 3 2050<0.18 52.4 51.1Vinyl chloride ug/L 50 103 56-143104 1 2050<0.18 51.7 52.24-Bromofluorobenzene (S) % 100 61-13097Dibromofluoromethane (S) % 96 67-13096Toluene-d8 (S) % 97 70-130100




Green Bay, WI 54302(920)469-2436

Page 12 of 17

#=QL#

QUALIFIERS


40161216023-6105-017 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES





Green Bay, WI 54302(920)469-2436

Page 13 of 17

#=CR#



40161216023-6105-017 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 14 of 17

Pag

e 15

of 1

7

Company Name:



Emall#1:

Email#?.:

Telephone:

Fax:


special pricing and release of liability

C019a(27 Jun2006)

!ceAnalytical• WWW. parelabs.com

A=None B;HCL C=H2S04

H=SocUum Bisulfate Solution

FILTERED? (YES/NO)


Relinquished By:

!=Sodium Thiosulfate

Datemme:


MN: 612-607~0

~ F=Methanol G=NaOH

J=Other

Received By:

WI: 920-469-2436

Quote#:

Mail To Contact:

Mail To Company:

Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

CLIENT COMMENTS

Date!Time:

LAB COMMENTS (lab Use Only)

f3

I fo of

Profile#

-·........ ~--~~~~~--•c D

version 6.o osff4too

of 17

'1ol bt21 te •"'~) Document Name: Revised Date: 28Sep2016

Pace Analytical Minneapolis Cooler Transfer Check List Page 1 of 1

Document Number: Issuing Authority: F-MN-C-214-Rev.01 Pace Minnesota Quality Office

Minneapolis Service Center Cooler Transfer Check List

Client:

Destination Lab:

Giul ~r f)ssa>l c--._,-fe~

C=J~

Received with Custody Seal: Yes ~

Custody Seal Intact: Yes No®

Temp Read Corrected Temp Correction Factor

Temperature C: '20. ~ 2P . 2- -O , 2.. IR Gun.Zfi (~ · Samples on ice, cooling process has begun

Rush/Short Hold: \-J / h

Containers Intact: @ No

Re-£and Re)~{ /

Temp Blank Included: No

Shipped By/Date:

Notes:

of 17


Green Bay, WI 54302

ace Analytical'' (client Name: _____ Gz_· ...... o __ l ___ ci_ur ________ _

Project#:"

Courier: Fed Ex r UPS Client r Pace Other: I.Ah l±ce Tracking #: I 5'(o 3 lo Z (o- 3 Custody Seal on Cooler/Box Present: p' yes no Seals intact: rj yes no

Custody Seal on Sam~les Present: yes p' no Seals intact yes no

Packing Material: r Bubble Wrap Bubble Bags r None Other

WOl.40161216 1111111111111111111111 40161216

Samples on ice, cooling process has begun Thermometer Used '5 (2 -I \ Type of Ice@ Blue Dry None

Cooler Temperature Uncorr: () /Corr: 0 Biological Tissue is Frozen: yes

Temp Blank Present: yes r no no Person examining contents: Date: U- ~l - IZ Temp should be above freezing to 6°C. Initials: 14<__

Biota Samples may be received at s 0°C. Comments:

Chain of Custody Present ltfves 0No ON/A 1.

Chain of Custody Filled Out • ii{ves ONo ON/A 2.

Chain of Custody Relinquished: 'JZlves ONo ON/A 3.

Sampler Name & Signature on COC: tJves ONo ON/A 4.

Samples Arrived within Hold Time: ¢'ves ONo ON/A 5.

- VOA Samples frozen upon receipt OYes ONo Date/Time:

Short Hold Time Analysis (<72hr): OYes ¢No ON/A 6.

Rush Turn Around Time Requested: OYes • i;,lNo ON/A 7.

Sufficient Volume: ¢'ves ONo ON/A 8.

Correct Containers Used: J21ves ONo ON/A 9.

-Pace Containers Used: ;{ves ONo ON/A

-Pace IR Containers Used: 0Yes ONo NIA

Containers Intact: .¢'ves ONo ON/A 10.

Filtered volume received for Dissolved tests 0Yes ONo ANIA 11.

Sample Labels match COC: Jlfves 0No ON/A 12. C!~u:f- I I~ o•n 2 - vkJ s, ~cU'J n .

-Includes date/time/ID/Analysis Matrix: I A. 1 S!lfJC ~;!!~ , vt cn'h..r -fu s.ti~ SCU11f w.s c.11n-. ,, .J~ C\11\ 11-7.I- II /'4'?

All containers needing preservation have been checked. t r HN03 £/r1H2S04 NaOH NaOH +ZnAct (Non-Compliance noted in 13.) 0Yes ONo NIA 13. Att containers needing preserV"aiion are found to be -in - - - - - - - - - - -

compliance with EPA recommendation. Oves ONo )21N/A (~SJ~. H~ s_2i, Na<2~+Z~9~9.:. ~aOf:! ~12) ______________ exceptions VO coliform, TOC, TOX, TOH, p Initial when I Lab Std #ID of 1uate1 O&G, WIDROW, Phenolics, OTHER: Yes 0No completed preservative Time:

Headspace in VOA Vials ( >6mm): 0Yes ¢No ON/A 14.

Trip Blank Present: J21ves ONo ON/A 15.

Trip Blank Custody Seals Present pfves ONo ON/A

Pace Trip Blank Lot# (if purchased): 3~ Client Notification/ Resolution: If checked, see attached form for additional comments D

Person Contacted: Date/Time: --------------Comments/ Resolution: ---------------------------~-~--~--~-~~~



Date:

#=CL#

October 25, 2017



RE:



Dear Alison Zoll:Enclosed are the analytical results for sample(s) received by the laboratory on October 18, 2017.The results relate only to the samples included in this report. Results reported herein conform to themost current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.


Sincerely,



Enclosures




Green Bay, WI 54302(920)469-2436

Page 1 of 16

#=CP#

CERTIFICATIONS


40158847023-6105-017 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 2 of 16

#=SS#

SAMPLE SUMMARY


40158847023-6105-017 CP-SHOREHAM YARD


40158847001 101717-0800-200 Water 10/17/17 08:00 10/18/17 08:40





Green Bay, WI 54302(920)469-2436

Page 3 of 16

#=SA#



40158847023-6105-017 CP-SHOREHAM YARD


40158847001 101717-0800-200 EPA 8260 71 PASI-GLAP





Green Bay, WI 54302(920)469-2436

Page 4 of 16

#=AR#

ANALYTICAL RESULTS


40158847023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 5 of 16

#=AR#

ANALYTICAL RESULTS


40158847023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 6 of 16

#=AR#

ANALYTICAL RESULTS


40158847023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 7 of 16

#=AR#

ANALYTICAL RESULTS


40158847023-6105-017 CP-SHOREHAM YARD








Green Bay, WI 54302(920)469-2436

Page 8 of 16

#=QC#



40158847023-6105-017 CP-SHOREHAM YARD




271412EPA 8260

EPA 82608260 MSV





Matrix: Water

AnalyzedMDL





Green Bay, WI 54302(920)469-2436

Page 9 of 16

#=QC#



40158847023-6105-017 CP-SHOREHAM YARD





Matrix: Water

AnalyzedMDL


Parameter UnitsLCS







Green Bay, WI 54302(920)469-2436

Page 10 of 16

#=QC#



40158847023-6105-017 CP-SHOREHAM YARD


Parameter UnitsLCS




Parameter UnitsMS



MSSpikeResult

40158847002

1596374

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.





Green Bay, WI 54302(920)469-2436

Page 11 of 16

#=QC#



40158847023-6105-017 CP-SHOREHAM YARD


Parameter UnitsMS



MSSpikeResult

40158847002

1596374

MSDResult

MSD% Rec RPD RPD

MaxMSDMSSpikeConc.


ug/L 49.6 80 63-12393 15 2049.6<2.2 39.6 46.2

1,2-Dibromoethane (EDB) ug/L 49.6 105 70-130103 3 2049.6<0.18 52.3 50.91,2-Dichlorobenzene ug/L 49.6 106 70-130105 0 2049.6<0.50 52.5 52.21,2-Dichloroethane ug/L 49.6 110 70-131110 1 2049.6<0.17 54.4 54.71,2-Dichloropropane ug/L 49.6 93 80-12095 1 2049.6<0.23 46.2 46.91,3-Dichlorobenzene ug/L 49.6 106 70-130104 2 2049.6<0.50 52.7 51.61,4-Dichlorobenzene ug/L 49.6 104 70-130102 1 2049.6<0.50 51.4 50.7Benzene ug/L 49.6 92 73-14594 2 2049.6<0.50 45.9 46.7Bromodichloromethane ug/L 49.6 112 70-130110 2 2049.6<0.50 55.4 54.4Bromoform ug/L 49.6 98 67-13096 1 2049.6<0.50 48.4 47.7Bromomethane ug/L 50 72 26-12974 3 2050<2.4 35.9 36.8Carbon tetrachloride ug/L 49.6 119 70-134117 2 2049.6<0.50 59.0 57.8Chlorobenzene ug/L 49.6 106 70-130105 1 2049.6<0.50 52.5 52.2Chloroethane ug/L 50 78 58-12085 8 2050<0.37 39.2 42.3Chloroform ug/L 49.6 103 80-121104 0 2049.6<2.5 51.2 51.4Chloromethane ug/L 50 57 40-12856 1 2050<0.50 28.4 28.1cis-1,2-Dichloroethene ug/L 49.6 106 70-130106 0 2049.631.0 83.6 83.6cis-1,3-Dichloropropene ug/L 49.6 87 70-13089 3 2049.6<0.50 43.0 44.3Dibromochloromethane ug/L 49.6 106 70-130104 2 2049.6<0.50 52.6 51.5Dichlorodifluoromethane ug/L 50 70 20-14666 5 2050<0.22 34.9 33.2Ethylbenzene ug/L 49.6 108 87-129108 1 2049.6<0.50 53.8 53.4Isopropylbenzene (Cumene) ug/L 49.6 114 70-130113 1 2049.6<0.14 56.7 56.0m&p-Xylene ug/L 99.2 107 70-130108 1 2099.2<1.0 106 107Methyl-tert-butyl ether ug/L 49.6 91 66-14393 1 2049.6<0.17 45.4 46.0Methylene Chloride ug/L 49.6 91 70-13087 4 2049.6<0.23 44.9 43.2o-Xylene ug/L 49.6 109 70-130109 0 2049.6<0.50 54.2 54.0Styrene ug/L 49.6 101 70-13099 1 2049.6<0.50 50.0 49.3Tetrachloroethene ug/L 49.6 114 70-130107 1 2049.6215 271 268Toluene ug/L 49.6 98 82-131100 2 2049.6<0.50 48.6 49.8trans-1,2-Dichloroethene ug/L 49.6 96 75-13598 2 2049.60.41J 48.0 49.1trans-1,3-Dichloropropene ug/L 49.6 87 70-13082 6 2049.6<0.23 43.3 40.7Trichloroethene ug/L 49.6 115 70-130108 5 2049.611.7 68.8 65.4Trichlorofluoromethane ug/L 50 112 76-150110 2 2050<0.18 56.2 54.9Vinyl chloride ug/L 50 72 56-14373 1 2050<0.18 36.0 36.54-Bromofluorobenzene (S) % 103 61-130101Dibromofluoromethane (S) % 100 67-13098Toluene-d8 (S) % 95 70-13098




Green Bay, WI 54302(920)469-2436

Page 12 of 16

#=QL#

QUALIFIERS


40158847023-6105-017 CP-SHOREHAM YARD

DEFINITIONS


LABORATORIES





Green Bay, WI 54302(920)469-2436

Page 13 of 16

#=CR#



40158847023-6105-017 CP-SHOREHAM YARD






Green Bay, WI 54302(920)469-2436

Page 14 of 16

Pag

e 15

of 1

6(Please Print Clearly) Company Name:

Branch/Location:

Project Contact:

Project State:

Sampled By (Print):

Sampled By (Sign):

Regulatory Program:

A=Air B Biota C =Charcoal O=Oil

\ UPPER MIDWEST REGION

}

\}) MN: 612-607-1700 WI: 920-469-243~ c ~

1 Quote#:

Mail To Contact:

*'Preservation Codes B=HCL C=H2S04 D=HN03 E=DI Water F=Methanol G=NaOH Mail To Company:

FILTERED? (YES/NO)

PRESERVATION (CODE)'

!=Sodium Thiosulfate J=Other Mail To Address:

Invoice To Contact:

Invoice To Company:

Invoice To Address:

Invoice To Phone:

On your sample

(billable) D NOT needed on

your sample S=Soil SI= Sfudoe CLIENT

COMMENTS LAB COMMENTS (Lab Use Only}

Profile#


Date Needed:

2 -'14t>N'L.P • ..-1..\Q·Ml _, B,

PACE Project No.

1"53~ z.5

Transmit Prelim Rush Resulls by (complete what you want): - - - - - Receipt Temp= I '7 l Email #1: Relinquished By: Date/Time:

Email #2: U-XlJ- t'o lD /I if/ n



C019a(27 Jun2006)

•<>~liornu'""~ By: Datemme:

Relinquished By: Daterrime:

0$'\.fV R(ll1(WJ GUj Ktf.t Received By:

Received By:

DatefTime:

/O/lY//l CJ;Nv Date!Time:

Daterrime:

Sample Receipt pH

OK I Adjusted

•c

of 16


Green Bay, WI 54302

I Project#:'

{Client Name:__.. __________________ _

Courier: Fed Ex Client r Pace Other:_uJ_o.,Q,_tl_v ___ _

Tracking#:--------------------Custody Seal on Cooler/Box Present:yYes no Seals intact: p-yes no

Custody Seal on Samples Present: r yesY no Seals intact: r yes - no

W0#:40158847 1111111111111111111111 40158847

Packing Material: Bubble Wrap yBubble Bags r None Other

Thermometer Used ~-{JV Type of Ice: f;j) Blue Dry None -r--Samples on ice, cooling process has begun

Cooler Temperature Uncorr: 1 /Corr: 1....-:j Biological Tissue is Frozen: yes

Temp Blank Present: l/Y~s no no Person examining contents:

Temp should be above freezing to 6°C. Date: I ch.sh\ Initials: ~fYI\) Biota Samples may be received at s 0°C. Comments:

Chain of Custody Present: ~es 0No ON/A 1 .

Chain of Custody Filled Out: ..iaYes 0No ON/A 2.

Chain of Custody Relinquished: ,..0'Yes 0No ON/A 3 .

Sampler Name & Signature on COG: ..0'Yes ONo ON/A 4.

Samples Arrived within Hold Time: )1Yes 0No ON/A 5.

- VOA Samples frozen upon receipt OYes 0No Date/Time:

Short Hold Time Analysis (<72hr): OYes~o ON/A 6.

Rush Turn Around Time Requested: OYes ~o ON/A 7.

Sufficient Volume: Zves 0No ON/A 8. co2 on\v\ l!-1 ltj es 111 Correct Containers Used: ~es ONo ON/A 9.

-Pace Containers Used: pes 0No ON/A

-Pace IR Containers Used: OYes 0No ~

Containers Intact: ffies 0No ON/A 10.

Filtered volume received for Dissolved tests OYes 0No J1'N1A 11.

Sample Labels match COG: fa es ONo ON/A 12.


OYes 0No~A HN03 H2S04 NaOH NaOH +ZnAct (Non-Compliance noted in 13 .) 13. ------ -------- -- -------- -- --- ---- ----All containers needing preservation are found to be in compliance with EPA recommendation. OYes ONo )'.'.(NIA

(t:!,tJ9:3:..!:!~2~ ~Qlj~n~,9~9.!. ~aOlj ~12) ______________ exceptions: , coliform, TOC, TOX, TOH, ftri Initial when I Lab Std #ID of luate1 O&G, WIDROW, Phenolics, OTHER: Yes 0No completed preservative Time:

Headspace in VOA Vials ( >6mm): 0Yes_6o ON/A 14.

Trip Blank Present: ,Jlfves 0No ON/A 15.

Trip Blank Custody Seals Present J!fves ONo ON/A

Pace Trip Blank Lot# (if purchased): ~ Client Notification/ Resolution: If checked, see attached form for additional comments D

Person Contacted: Date/Time: --------------Comments/ Resolution: -----------------------------------------



Date: __ f0_\ ... t .... r,..\y,.) ____ _