newtowncreek.infonewtowncreek.info/docs2/2 remedial investigation... · 3958 6th ave. nw seattle wa...

3958 6th Ave. NW Seattle WA 98107

P: 206-632-6206 F: 206-632-6017

E: [email protected] www.brooksrand.com

Report of Trace Metals Analyses in Water Samples Project: Anchor/Newtown Creek

(Alpha Job Number L1204660) Samples Collected: March 19-21, 2012 Report Date: April 20, 2012 Prepared for: Cindy McQueen Alpha Analytical 320 Forbes Blvd. Mansfield, MA 02048 Brooks Rand Labs Project ID: AAL-MN1101

BRL Report 1212016

of 274

Table of Contents

Case Narrative ..................................................................................................................3

Report Information.............................................................................................................6

Sample Information ...........................................................................................................7

Batch Summary .................................................................................................................8

Sample Results .................................................................................................................9

Accuracy & Precision Summary .......................................................................................12

Method Blanks & Reporting Limits ...................................................................................17

Instrument Calibration ......................................................................................................22

Sample Containers ...........................................................................................................27

Shipping Containers .........................................................................................................33

Sample Calculations.........................................................................................................34

Chain-of-Custody Forms ..................................................................................................35

Waybills ............................................................................................................................38

Total Mercury Data Sequence 1200235, Batch B120480 ................................................41

Total Mercury Data Sequence 1200251, Batch B120509 ................................................67

Methylmercury Data Sequence 1200258, Batch B120524 ...............................................93

Methylmercury Data Sequence 1200272, Batch B120565 .............................................145

Selenium Data Sequence 1200243, Batch B120537 .....................................................176

BRL Report 1212016

of 274

Case Narrative

Shipping and Receiving Water samples included in this report were received by Brooks Rand Labs (BRL) on three (3) different days and logged-in to one (1) work order:

BRL Work Order Number

Date Received

Time Received

Number of Samples

Cooler Temp

1212016 3/21/2012 9:30 AM 4 2.4 °C 3/22/2012 9:30 AM 5 1.0 °C 3/23/2012 9:30 AM 4 2.9 °C

The chain-of-custody (COC) forms requested analysis for total and di ssolved mercury (Hg), methylmercury (MeHg), and total and dissolved selenium (Se). A container was not submitted for MeHg analysis for sample SW-RB-20120321. A split was taken from the corresponding THg sample bottle and was preserved and logged-in for MeHg analysis. The samples were received and stored securely according to BRL standard operating procedures (SOP) and EPA methodology.

Preservation and Holding Time All method and SOP requirements for preservation and holding time were satisfied.

Total Mercury in Water by EPA Method 1631 (BRL SOP #BR-0006) All samples are prepared and anal yzed in accordance with EPA Method 1631. Samples are oxidized with bromine monochloride (BrCl) and then analyzed with stannous chloride (SnCl2) reduction, single gold amalgamation, and c old vapor atomic fluorescence spectroscopy (CVAFS) detection using a BRL Model III CVAFS Mercury Analyzer.

The results have not been method blank-corrected, contrary to the method described in the calculations section of the relevant BRL SOPs and may have been evaluated using reporting limits that have been adjusted to account for sample aliquot size. Please refer to the Sample Results page for sample-specific MDLs, MRLs, and other details. Sample results greater than the MDL, but less than or equal to the MRL, have been reported qualified B.

Sequence 1200235, Batch B120480 Instrument calibration, meeting all quality control criteria, was successfully achieved on the day of sample analysis.

All data was reported without further qualification and a ll associated quality control sample results met the acceptance criteria.

BRL Report 1212016

of 274

Sequence 1200251, Batch B120509 The analysis of the 4th calibration standard produced an abnormal peak shape; however, this calibration standard result still yielded a 100% recovery. All calibration standard recoveries in this sequence ranged from 99% to 101%. On this basis, reanalysis of the calibration standard was not warranted. Instrument calibration, meeting all quality control criteria, was successfully achieved on the day of sample analysis.

Sample SW-RB-20120321 (1212016-21) was identified as a rinse blank and y ielded a detectable Hg concentration of 0.77 ng/L. Since half of this sample was split off for MeHg analysis (see Shipping and Receiving section above), reanalysis of this sample for confirmation was not possible.


Methylmercury in Water by EPA Method 1630 (BRL SOP #BR-0011) Water samples are prepared by distillation. Distillates are analyzed by ethylation, Tenax trap collection, gas chromatography separation, isothermal decomposition, and c old vapor fluorescence spectroscopy (CVAFS).

The results have not been method blank-corrected, contrary to the method described in the calculations section of the relevant BRL SOPs and may have been evaluated using reporting limits that have been adjusted to account for sample aliquot size. Please refer to the Sample Results page for sample-specific MDLs, MRLs, and other details. Sample results equal to our less than the MDL have been reported at the MDL and qualified U. Sample results greater than the MDL, but less than or equal to the MRL, have been reported qualified B.

Sequence 1200258, Batch B120524 Instrument calibration, meeting all quality control criteria, was successfully achieved on the day of sample analysis. CCV6 and CCBA were part of a group of samples that were not ethylated. These samples were reanalyzed in sequence 1200272 (batch B120565), and CCV6 and CCBA were not reported.

The first method blank, B120524-BLK1, produced a high result (0.045 ng/L) that was determined to be a Grubb’s Outlier at < 5% risk of false rejection. As this BLK was detectable, and as the data for this project is being reported without the benefit of method blank-correction, all data was judged against this outlier BLK result. Most of the reported data is below the MDL and has not been further qualified. However, all detectable results that produced a concentration that was within 10x of the concentration of BLK1 have been reported qualified X as per BRL’s Comprehensive Quality Control Plan.

Samples 1212016-23 and 1212016-25 were not ethylated prior to analysis and have not been reported from this sequence/batch. The samples were rebatched for analysis in sequence 1200272 (batch B120565).


BRL Report 1212016

of 274



Trace Metals EPA Method 1638 modified (BRL SOP #BR-0060) Analysis is performed by EPA Draft Method 1638 (modified) using inductively coupled plasma - mass spectrometry (ICP-MS). Prior to analysis, the samples are preserved to 1% with ultra-pure nitric acid. Furthermore, samples for total recoverable analysis are heated overnight at 85 °C. Aliquots of digested sample are analyzed utilizing internal standardization. This method incorporates ionization of the sample in an inductively-coupled RF plasma, with detection of the resulting ions by mass spectrometer on t he basis of their mass-to-charge ratio. ICP-MS interference correction equations and background correction were applied. Raw data (counts-per-second) are reported prior to application of background correction. The results have not been method blank-corrected, contrary to the method described in the calculations section of the relevant BRL SOPs and may have been evaluated using reporting limits that have been adjusted to account for sample aliquot size. Please refer to the Sample Results page for sample-specific MDLs, MRLs, and ot her details. Due to the salinity of the samples, all samples were analyzed at a dilution. All sample results produced concentrations of Se that are equal to our less than the dilution-adjusted MDL and ha ve been r eported at the dilution-adjusted MDL and qualified U.


In instances when the native sample and/or the corresponding duplicate (DUP) produced non-detectable results the relative percent difference (RPD) was not calculated (N/C).


We certify that this data package is in compliance with the terms and conditions of the contract, both technically and f or completeness, for other than the conditions detailed above. BRL, an accredited laboratory, certifies that the reported results of all analyses for which BRL is NELAP accredited meet all NELAP requirements. For more details, please see the Report Information page in your report. Please feel free to contact us if you have any questions regarding this report.

___________________________ Michelle L. Briscoe

VP of Analytical Services [email protected]

___________________________ Amanda Royal

Project Manager [email protected]

BRL Report 1212016

of 274

Project ID: AAL-MN1101

PM: Amanda Royal

Client PM: Cindy McQueen

Client PO: Signed LSA

Definition of Data Qualifiers(Effective 9/23/09)

Laboratory AccreditationBRL is accredited by the National Environmental Laboratory Accreditation Program (NELAP) through the State of Florida

Department of Health, Bureau of Laboratories (E87982) and is certified to perform many environmental analyses. BRL is

also certified by many other states to perform environmental analyses. For a current list of our

accreditations/certifications, please visit our website at <http://www.brooksrand.com/default.asp?contentID=586>. Results

reported relate only to the samples listed in the report.

Report Information

BLK

BRL

BS

CAL

CCV

CRM

D

DUP

ICV

MSD

ND

NR

PS

REC

RPD

RSD

SCV

SOP

method blank

Brooks Rand Labs

laboratory fortified blank

calibration standard

continuing calibration verification

certified reference material

dissolved fraction

duplicate

initial calibration verification

matrix spike duplicate

non-detect

non-reportable

post preparation spike

percent recovery

relative percent difference

relative standard deviation

secondary calibration verification

standard operating procedure

MDL

MRL

MS

method detection limit

method reporting limit

matrix spike

SRM

T

COC

standard reference material

total recoverable fraction

chain of custody record

Common Abbreviations

These qualifiers are based on those previously utilized by Brooks Rand, Ltd., those found in the EPA SOW ILM03.0,

Exhibit B, Section III, pg. B-18, and the USEPA Laboratory Data Validation Functional Guidelines for Evaluating Inorganic

Analyses; USEPA; July 2002. These supersede all previous qualifiers ever employed by BRL.

Detected by the instrument, the result is > the MDL but ≤ the MRL. Result is reported and considered an estimate.B

E An estimated value due to the presence of interferences. A full explanation is presented in the narrative.

H Holding time and/or preservation requirements not met. Result is estimated.

J Estimated value. A full explanation is presented in the narrative.

J-M Duplicate precision (RPD) for associated QC sample was not within acceptance criteria. Result is estimated.

J-N Spike recovery for associated QC sample was not within acceptance criteria. Result is estimated.

M Duplicate precision (RPD) was not within acceptance criteria. Result is estimated.

N Spike recovery was not within acceptance criteria. Result is estimated.

R Rejected, unusable value. A full explanation is presented in the narrative.

U Result is ≤ the MDL or client requested reporting limit (CRRL). Result reported as the MDL or CRRL.

X Result is not BLK-corrected and is within 10x the absolute value of the highest detectable BLK in the batch.

Result is estimated.

Field Quality Control SamplesPlease be notified that certain EPA methods require the collection of field quality control samples of an appropriate type

and frequency; failure to do so is considered a deviation from some methods and for compliance purposes should only be

done with the approval of regulatory authorities. Please see the specific EPA methods for details regarding required field

quality control samples.

3958 6th Avenue NW Seattle WA 98107 · P(206) 632-6206 · F(206) 632-6017 · [email protected] · www.brooksrand.com

BRL Report 1212016

of 274


PM: Amanda Royal



Sample Information

Report Matrix Type ReceivedSampledSample Lab IDAlias

1212016-01WC001SW-C-20120319 03/19/2012 03/21/2012SampleWaterL1204660-01

1212016-02WC001SW-C-20120319 03/19/2012 03/21/2012SampleWaterL1204660-01

1212016-03WC001SW-A-20120319 03/19/2012 03/21/2012SampleWaterL1204660-03

1212016-04WC001SW-A-20120319 03/19/2012 03/21/2012SampleWaterL1204660-03

1212016-05NC068SW-A-20120319 03/19/2012 03/21/2012SampleWaterL1204660-05


1212016-07NC068SW-C-20120319 03/19/2012 03/21/2012SampleWaterL1204660-07


1212016-09MC008SW-A-20120320 03/20/2012 03/22/2012SampleWaterL1204660-11

1212016-10MC008SW-A-20120320 03/20/2012 03/22/2012SampleWaterL1204660-11

1212016-11DK011SW-C-20120320 03/20/2012 03/22/2012SampleWaterL1204660-13

1212016-12DK011SW-C-20120320 03/20/2012 03/22/2012SampleWaterL1204660-13

1212016-13DK011SW-A-20120320 03/20/2012 03/22/2012SampleWaterL1204660-15

1212016-14DK011SW-A-20120320 03/20/2012 03/22/2012SampleWaterL1204660-15





1212016-19EB010SW-A-20120321 03/21/2012 03/23/2012SampleWaterL1204660-22

1212016-20EB010SW-A-20120321 03/21/2012 03/23/2012SampleWaterL1204660-22

1212016-21SW-RB-20120321 03/21/2012 03/23/2012Rinse BlankDIWL1204660-24

1212016-22SW-RB-20120321 03/21/2012 03/23/2012Rinse BlankDIWL1204660-24






BRL Report 1212016

of 274


PM: Amanda Royal



Batch Summary

Analyte Prepared Analyzed SequenceBatchLab Matrix Method

B12048003/23/2012 04/03/2012 1200235Water EPA 1631Hg

B12050903/30/2012 04/09/2012 1200251Water EPA 1631Hg

B12052404/09/2012 04/11/2012 1200258Water EPA 1630MeHg

B12056504/16/2012 04/18/2012 1200272Water EPA 1630MeHg

B12053704/03/2012 04/05/2012 1200243Water EPA 1638 DRCSe


BRL Report 1212016

of 274


PM: Amanda Royal



Sample Results

Sample Sequence Result MDL MRL Unit BatchQualifierAnalyte FractionReport Matrix

DK011SW-A-20120320

ng/L6.94T 1200235B120480Water 0.520.201212016-13 Hg

ng/L4.52D 1200235B120480Water 0.400.151212016-14 Hg

ng/L0.019T U 1200258B120524Water 0.0480.0191212016-13 MeHg

µg/L1.16T U 1200243B120537Water 3.431.161212016-13 Se

µg/L1.16D U 1200243B120537Water 3.431.161212016-14 Se

DK011SW-C-20120320

ng/L2.42T 1200235B120480Water 0.530.201212016-11 Hg

ng/L0.28D B 1200235B120480Water 0.400.151212016-12 Hg


µg/L1.16T U 1200243B120537Water 3.431.161212016-11 Se

µg/L1.16D U 1200243B120537Water 3.431.161212016-12 Se

EB010SW-A-20120321

ng/L8.87T 1200251B120509Water 0.540.201212016-19 Hg

ng/L1.17D 1200251B120509Water 0.400.151212016-20 Hg

ng/L0.159T X 1200258B120524Water 0.0510.0201212016-19 MeHg

µg/L0.929T U 1200243B120537Water 2.750.9291212016-19 Se

µg/L0.929D U 1200243B120537Water 2.750.9291212016-20 Se

MC008SW-A-20120320

ng/L3.71T 1200235B120480Water 0.540.201212016-09 Hg

ng/L0.40D B 1200235B120480Water 0.400.151212016-10 Hg

ng/L0.066T X 1200258B120524Water 0.0490.0201212016-09 MeHg

µg/L1.16T U 1200243B120537Water 3.431.161212016-09 Se

µg/L1.16D U 1200243B120537Water 3.431.161212016-10 Se

NC034SW-A-20120321

ng/L3.63T 1200251B120509Water 0.540.201212016-23 Hg

ng/L0.55D 1200251B120509Water 0.400.151212016-24 Hg

ng/L0.056T 1200272B120565Water 0.0500.0201212016-23 MeHg

µg/L1.16T U 1200243B120537Water 3.431.161212016-23 Se

µg/L1.16D U 1200243B120537Water 3.431.161212016-24 Se


BRL Report 1212016

of 274


PM: Amanda Royal



Sample Results


NC034SW-C-20120321

ng/L32.1T 1200251B120509Water 0.540.201212016-25 Hg

ng/L1.02D 1200251B120509Water 0.410.151212016-26 Hg

ng/L0.081T 1200272B120565Water 0.0510.0201212016-25 MeHg

µg/L1.16T U 1200243B120537Water 3.431.161212016-25 Se

µg/L1.16D U 1200243B120537Water 3.431.161212016-26 Se

NC046SW-A-20120320

ng/L3.06T 1200235B120480Water 0.490.181212016-15 Hg

ng/L0.36D B 1200235B120480Water 0.400.151212016-16 Hg


µg/L1.16T U 1200243B120537Water 3.431.161212016-15 Se

µg/L1.16D U 1200243B120537Water 3.431.161212016-16 Se

NC046SW-C-20120320

ng/L4.77T 1200235B120480Water 0.510.191212016-17 Hg

ng/L0.29D B 1200235B120480Water 0.400.151212016-18 Hg


µg/L1.16T U 1200243B120537Water 3.431.161212016-17 Se

µg/L1.16D U 1200243B120537Water 3.431.161212016-18 Se

NC068SW-A-20120319

ng/L4.30T 1200235B120480Water 0.510.191212016-05 Hg

ng/L0.29D B 1200235B120480Water 0.400.151212016-06 Hg


µg/L1.16T U 1200243B120537Water 3.431.161212016-05 Se

µg/L1.16D U 1200243B120537Water 3.431.161212016-06 Se

NC068SW-C-20120319

ng/L4.97T 1200235B120480Water 0.530.201212016-07 Hg

ng/L0.28D B 1200235B120480Water 0.400.151212016-08 Hg


µg/L1.16T U 1200243B120537Water 3.431.161212016-07 Se

µg/L1.16D U 1200243B120537Water 3.431.161212016-08 Se


BRL Report 1212016

of 274


PM: Amanda Royal



Sample Results


SW-RB-20120321

ng/L0.77T 1200251B120509DIW 0.400.151212016-21 Hg

ng/L0.21D B 1200251B120509DIW 0.410.151212016-22 Hg

ng/L0.020T U 1200258B120524DIW 0.0490.0201212016-21 MeHg

µg/L0.023T U 1200243B120537DIW 0.0690.0231212016-21 Se

µg/L0.023D U 1200243B120537DIW 0.0690.0231212016-22 Se

WC001SW-A-20120319

ng/L3.31T 1200235B120480Water 0.540.201212016-03 Hg

ng/L0.34D B 1200235B120480Water 0.400.151212016-04 Hg


µg/L1.16T U 1200243B120537Water 3.431.161212016-03 Se

µg/L1.16D U 1200243B120537Water 3.431.161212016-04 Se

WC001SW-C-20120319

ng/L8.97T 1200235B120480Water 0.540.201212016-01 Hg

ng/L0.32D B 1200235B120480Water 0.400.151212016-02 Hg

ng/L0.022T X, B 1200258B120524Water 0.0500.0201212016-01 MeHg

µg/L1.16T U 1200243B120537Water 3.431.161212016-01 Se

µg/L1.16D U 1200243B120537Water 3.431.161212016-02 Se


BRL Report 1212016

of 274


PM: Amanda Royal



Accuracy & Precision Summary

Batch: B120480

Analyte Result UnitsNative Spike REC & Limits RPD & Limits

Method: EPA 1631

Lab Matrix: Water

Sample

Certified Reference Material (1213013, NIST 1641d 1000x dilution)B120480-SRM1

15.68 101%ng/L 85-115Hg 15.83

Matrix Spike (1212016-01)B120480-MS2

40.05 108%ng/L 71-125Hg 52.398.97

Matrix Spike Duplicate (1212016-01)B120480-MSD2

40.18 109%ng/L 71-125 240.7%Hg 52.788.97

Matrix Spike (1212016-17)B120480-MS3

18.90 104%ng/L 71-125Hg 24.404.77


19.14 105%ng/L 71-125 242%Hg 24.824.77


BRL Report 1212016

of 274


PM: Amanda Royal




Batch: B120509


Method: EPA 1631

Lab Matrix: Water

Sample

Certified Reference Material (1213013, NIST 1641d 1000x dilution)B120509-SRM1

15.68 100%ng/L 85-115Hg 15.65

Matrix Spike (1212016-19)B120509-MS1

40.38 101%ng/L 71-125Hg 49.668.87


40.23 100%ng/L 71-125 241%Hg 49.188.87

Matrix Spike (1212016-23)B120509-MS3

13.36 99%ng/L 71-125Hg 16.823.63


13.43 98%ng/L 71-125 240.2%Hg 16.863.63


BRL Report 1212016

of 274

Project ID: AAL-MN1101 Client PM: Cindy McQueen PM: Amanda Royal Client PO: Signed LSA


Accuracy & Precision Summary Batch: B120524 Lab Matrix: Water Method: EPA 1630

Sample Analyte Native Spike Result Units REC & Limits RPD & Limits B120524-BS1 Laboratory Fortified Blank (1211027) MeHg 1.001 0.871 ng/L 87% 67-133

B120524-BS2 Laboratory Fortified Blank (1211027) MeHg 0.9891 0.888 ng/L 90% 67-133

B120524-MS2 Matrix Spike (1212016-11) MeHg ND 0.05091 0.060 ng/L 82% 65-135

B120524-MSD2 Matrix Spike Duplicate (1212016-11) MeHg ND 0.04917 0.065 ng/L 96% 65-135 8% 35

BRL Report 1212016

of 274


PM: Amanda Royal




Batch: B120537


Method: EPA 1638 DRC

Lab Matrix: Water

Sample

Laboratory Fortified Blank (1210062)B120537-BS1

4.040 102%µg/L 75-125Se 4.107

Certified Reference Material (1132016, NIST 1643e)B120537-SRM1

11.97 103%µg/L 75-125Se 12.32

Duplicate (1212016-05)B120537-DUP1

µg/L 20N/CSe NDND

Matrix Spike (1212016-05)B120537-MS1

50.51 107%µg/L 75-125Se 54.80ND


50.51 105%µg/L 75-125 202%Se 53.91ND

Duplicate (1212016-09)B120537-DUP2

µg/L 20N/CSe 1.385ND

Matrix Spike (1212016-09)B120537-MS2

50.51 110%µg/L 75-125Se 56.21ND


50.51 106%µg/L 75-125 203%Se 54.36ND

Duplicate (1212016-19)B120537-DUP3

µg/L 20N/CSe NDND

Matrix Spike (1212016-19)B120537-MS3

50.51 95%µg/L 75-125Se 48.55ND


50.51 92%µg/L 75-125 203%Se 47.03ND


BRL Report 1212016

of 274


PM: Amanda Royal




Batch: B120565


Method: EPA 1630

Lab Matrix: Water

Sample


1.005 94%ng/L 67-133MeHg 0.944


0.9854 90%ng/L 67-133MeHg 0.882

Matrix Spike (1213006-01)B120565-MS1

0.2525 107%ng/L 65-135MeHg 0.289ND


0.2504 106%ng/L 65-135 352%MeHg 0.284ND


BRL Report 1212016

of 274


PM: Amanda Royal



Method Blanks & Reporting Limits

Batch: B120480

Method: EPA 1631

Matrix: Water

Analyte: Hg

Result UnitsSample

B120480-BLK1 ng/L0.10

B120480-BLK2 ng/L0.03

B120480-BLK3 ng/L0.04

B120480-BLK4 ng/L0.03

MDL: 0.15Average: 0.05 Standard Deviation: 0.03

Limit: 0.10Limit: 0.50 MRL: 0.40


BRL Report 1212016

of 274


PM: Amanda Royal




Batch: B120509

Method: EPA 1631

Matrix: Water

Analyte: Hg

Result UnitsSample

B120509-BLK1 ng/L0.08

B120509-BLK2 ng/L0.09

B120509-BLK3 ng/L0.09

B120509-BLK4 ng/L0.06


Limit: 0.10Limit: 0.50 MRL: 0.40


BRL Report 1212016

of 274


PM: Amanda Royal




Batch: B120524

Method: EPA 1630

Matrix: Water

Analyte: MeHg

Result UnitsSample

B120524-BLK1 ng/L0.045

B120524-BLK2 ng/L0.007

B120524-BLK3 ng/L0.010

B120524-BLK4 ng/L0.003


Limit: 0.015Limit: 0.045 MRL: 0.049


BRL Report 1212016

of 274


PM: Amanda Royal




Batch: B120537

Method: EPA 1638 DRC

Matrix: Water

Analyte: Se 78

Result UnitsSample

B120537-BLK1 µg/L0.010

B120537-BLK2 µg/L0.009

B120537-BLK3 µg/L0.005

B120537-BLK4 µg/L0.012


Limit: 0.023Limit: 0.069 MRL: 0.069


BRL Report 1212016

of 274


PM: Amanda Royal




Batch: B120565

Method: EPA 1630

Matrix: Water

Analyte: MeHg

Result UnitsSample

B120565-BLK1 ng/L0.002

B120565-BLK2 ng/L-0.001

B120565-BLK3 ng/L0.007

B120565-BLK4 ng/L0.007


Limit: 0.015Limit: 0.045 MRL: 0.051


BRL Report 1212016

of 274


PM: Amanda Royal



Instrument Calibration

Sequence: 1200235

Method: EPA 1631Instrument: THG-10

Date: 04/03/2012

Total Mercury and Mercury Speciation by CVAFS

Analyte: Hg

REC & LimitsResultTrue ValueLab ID Units1200235-IBL1 5.26 pg of Hg

1200235-IBL2 5.25 pg of Hg

1200235-IBL3 5.27 pg of Hg

1200235-IBL4 5.03 pg of Hg

1200235-CAL1 25.00 25.86 pg of Hg 103%

1200235-CAL2 100.0 99.45 pg of Hg 99%

1200235-CAL3 500.0 483.5 pg of Hg 97%

1200235-CAL4 2500 2440 pg of Hg 98%

1200235-CAL5 10000 9888 pg of Hg 99%

1200235-ICV1 1568 1583 pg of Hg 101% 85-115

1200235-CAL6 500.0 504.1 pg of Hg 101%

1200235-CCB1 5.00 pg of Hg

1200235-CCV1 500.0 499.8 pg of Hg 100% 77-123

1200235-CCB2 3.75 pg of Hg

1200235-CCV2 500.0 524.8 pg of Hg 105% 77-123

1200235-CCV3 500.0 498.1 pg of Hg 100% 77-123

1200235-CCV4 500.0 498.7 pg of Hg 100% 77-123


BRL Report 1212016

of 274


PM: Amanda Royal




Sequence: 1200243

Method: EPA 1638 DRCInstrument: ICP-MS-2

Date: 04/05/2012

Trace Metals by ICP-DRC-MS

Analyte: Se 78

REC & LimitsResultTrue ValueLab ID Units1200243-ICB1 0.000 µg/L

1200243-CAL1 0.05000 0.049 µg/L 98%

1200243-CAL2 0.1000 0.104 µg/L 104%

1200243-CAL3 0.2500 0.245 µg/L 98%

1200243-CAL4 1.000 0.996 µg/L 100%

1200243-CAL5 5.000 5.106 µg/L 102%

1200243-CAL6 25.00 24.98 µg/L 100%

1200243-CAL7 125.0 124.9 µg/L 100%

1200243-CAL8 500.0 489.3 µg/L 98%

1200243-ICB2 0.133 µg/L

1200243-ICV1 10.00 10.31 µg/L 103% 85-115

1200243-ICB3 0.026 µg/L

1200243-IBL1 0.016 µg/L

1200243-IBL2 0.013 µg/L

1200243-IBL3 0.019 µg/L

1200243-IBL4 0.025 µg/L

1200243-SCV1 11.97 12.32 µg/L 103% 75-125

1200243-CCV1 1.000 1.029 µg/L 103% 75-125

1200243-CCB1 0.025 µg/L

1200243-CCV2 1.000 0.970 µg/L 97% 75-125

1200243-CCB2 0.005 µg/L

1200243-CCV3 1.000 0.980 µg/L 98% 75-125

1200243-CCB3 0.015 µg/L

1200243-CCV4 1.000 1.018 µg/L 102% 75-125

1200243-CCB4 0.0008 µg/L

1200243-CCV5 1.000 1.001 µg/L 100% 75-125

1200243-CCB5 0.007 µg/L

1200243-CCV6 1.000 0.979 µg/L 98% 75-125

1200243-CCB6 0.007 µg/L

1200243-CCV7 1.000 1.006 µg/L 101% 75-125

1200243-CCB7 0.005 µg/L

1200243-CCV8 5.000 5.352 µg/L 107% 75-125

1200243-CCB8 0.006 µg/L


BRL Report 1212016

of 274


PM: Amanda Royal




Sequence: 1200251

Method: EPA 1631Instrument: THG-05

Date: 04/09/2012


Analyte: Hg

REC & LimitsResultTrue ValueLab ID Units1200251-IBL2 4.37 pg of Hg

1200251-IBL3 3.99 pg of Hg

1200251-IBL4 3.64 pg of Hg

1200251-CAL1 25.00 24.95 pg of Hg 100%

1200251-CAL2 100.0 100.7 pg of Hg 101%

1200251-CAL3 500.0 505.8 pg of Hg 101%

1200251-CAL4 2500 2482 pg of Hg 99%

1200251-CAL5 10000 9911 pg of Hg 99%

1200251-ICV1 1568 1565 pg of Hg 100% 85-115

1200251-CCB1 8.66 pg of Hg

1200251-IBL5 5.17 pg of Hg

1200251-CCV2 500.0 487.8 pg of Hg 98% 77-123

1200251-CCV3 500.0 468.4 pg of Hg 94% 77-123


BRL Report 1212016

of 274


PM: Amanda Royal




Sequence: 1200258

Method: EPA 1630Instrument: MMHG-09

Date: 04/11/2012


Analyte: MeHg

REC & LimitsResultTrue ValueLab ID Units1200258-IBL1 0.144 pg MeHg

1200258-IBL2 0.121 pg MeHg

1200258-IBL3 0.141 pg MeHg

1200258-CAL1 0.5005 0.491 pg MeHg 98%

1200258-CAL2 1.001 0.999 pg MeHg 100%

1200258-CAL3 2.002 1.888 pg MeHg 94%

1200258-CAL4 10.01 9.682 pg MeHg 97%

1200258-CAL5 50.05 49.92 pg MeHg 100%

1200258-CAL6 250.2 258.6 pg MeHg 103%

1200258-CAL7 1001 1086 pg MeHg 109%

1200258-CCB1 0.817 pg MeHg

1200258-ICV1 99.99 101.5 pg MeHg 102% 80-120

1200258-CCB2 1.40 pg MeHg

1200258-CCV1 25.02 25.38 pg MeHg 101% 67-133

1200258-CCB3 0.453 pg MeHg

1200258-CCB4 0.374 pg MeHg

1200258-CCB5 0.197 pg MeHg

1200258-CCV2 25.02 25.20 pg MeHg 101% 67-133

1200258-CCB6 0.230 pg MeHg

1200258-CCV3 25.02 24.32 pg MeHg 97% 67-133

1200258-CCB7 0.115 pg MeHg

1200258-CCV4 25.02 23.60 pg MeHg 94% 67-133

1200258-CCB8 0.456 pg MeHg

1200258-CCV5 25.02 23.07 pg MeHg 92% 67-133

1200258-CCB9 0.161 pg MeHg

1200258-CCV7 25.02 23.41 pg MeHg 94% 67-133

1200258-CCBB 0.148 pg MeHg


BRL Report 1212016

of 274


PM: Amanda Royal




Sequence: 1200272

Method: EPA 1630Instrument: MMHG-09

Date: 04/18/2012


Analyte: MeHg

REC & LimitsResultTrue ValueLab ID Units1200272-IBL1 0.128 pg MeHg

1200272-IBL2 0.060 pg MeHg

1200272-IBL3 0.177 pg MeHg

1200272-CAL1 0.5005 0.466 pg MeHg 93%

1200272-CAL2 1.001 1.025 pg MeHg 102%

1200272-CAL3 2.002 1.918 pg MeHg 96%

1200272-CAL4 10.01 9.321 pg MeHg 93%

1200272-CAL5 50.05 51.74 pg MeHg 103%

1200272-CAL6 250.2 260.5 pg MeHg 104%

1200272-CAL7 1001 1099 pg MeHg 110%

1200272-CCB1 0.796 pg MeHg

1200272-ICV1 99.99 109.9 pg MeHg 110% 80-120

1200272-CCB2 1.35 pg MeHg

1200272-CCV1 25.02 23.85 pg MeHg 95% 67-133

1200272-CCB3 0.419 pg MeHg

1200272-CCB4 0.298 pg MeHg

1200272-CCB5 0.196 pg MeHg

1200272-CCV2 25.02 25.94 pg MeHg 104% 67-133

1200272-CCB6 0.087 pg MeHg

1200272-CCV3 25.02 25.12 pg MeHg 100% 67-133

1200272-CCB7 0.173 pg MeHg

1200272-CCV4 25.02 24.64 pg MeHg 98% 67-133

1200272-CCB8 0.181 pg MeHg

1200272-CCV5 25.02 25.15 pg MeHg 101% 67-133

1200272-CCB9 0.124 pg MeHg


BRL Report 1212016

of 274


PM: Amanda Royal



Sample Containers

Lab ID: 1212016-01 Report Matrix: Water

Sample Type: Sample Received: 03/21/2012Sample: WC001SW-C-20120319

Collected: 03/19/2012

Comments: DIL Se: 50x

Ship. Cont.pHP-LotPreservationLotSizeContainerDesA 71470160

10

Coolernone n/a250 mLBottle FLPE Hg-T

B 71470160

10

Cooler1 mL 9N H2SO4 (PP) 1208042 <2250 mLBottle FLPE Hg-SP

C 1048890 Cooler0.1% HNO3 (BRL) 1202050 <2125 mLBottle HDPE ICP-W


Sample Type: Sample Received: 03/21/2012Sample: WC001SW-C-20120319




10


B 1048890 Cooler0.1% HNO3 (BRL) 1202050 <2125 mLBottle HDPE ICP-W


Sample Type: Sample Received: 03/21/2012Sample: WC001SW-A-20120319




10


B 71470160

10




Sample Type: Sample Received: 03/21/2012Sample: WC001SW-A-20120319




10




BRL Report 1212016

of 274


PM: Amanda Royal



Sample Containers


Sample Type: Sample Received: 03/21/2012Sample: NC068SW-A-20120319




10


B 71470160

10








10




Sample Type: Sample Received: 03/21/2012Sample: NC068SW-C-20120319




10


B 71470160

10








10




BRL Report 1212016

of 274


PM: Amanda Royal



Sample Containers


Sample Type: Sample Received: 03/22/2012Sample: MC008SW-A-20120320




10

Cooler 2none n/a250 mLBottle FLPE Hg-T

B 71470160

10

Cooler 21 mL 9N H2SO4 (PP) 1208042 <2250 mLBottle FLPE Hg-SP

C 1048890 Cooler 20.1% HNO3 (BRL) 1202050 <2125 mLBottle HDPE ICP-W


Sample Type: Sample Received: 03/22/2012Sample: MC008SW-A-20120320




10


B 1048890 Cooler 20.1% HNO3 (BRL) 1202050 <2125 mLBottle HDPE ICP-W


Sample Type: Sample Received: 03/22/2012Sample: DK011SW-C-20120320




10


B 71470160

10




Sample Type: Sample Received: 03/22/2012Sample: DK011SW-C-20120320




10




BRL Report 1212016

of 274


PM: Amanda Royal



Sample Containers


Sample Type: Sample Received: 03/22/2012Sample: DK011SW-A-20120320




10


B 71470160

10




Sample Type: Sample Received: 03/22/2012Sample: DK011SW-A-20120320




10








10


B 71470160

10








10




BRL Report 1212016

of 274


PM: Amanda Royal



Sample Containers






10


B 71470160

10








10




Sample Type: Sample Received: 03/23/2012Sample: EB010SW-A-20120321




10


B 71470160

10




Sample Type: Sample Received: 03/23/2012Sample: EB010SW-A-20120321




10




BRL Report 1212016

of 274

Project ID: AAL-MN1101 Client PM: Cindy McQueen PM: Amanda Royal Client PO: Signed LSA


Sample Containers Lab ID: 1212016-21 Report Matrix: DIW Collected: 03/21/2012 Sample: SW-RB-20120321 Sample Type: Rinse Blank Received: 03/23/2012 Des Container Size Lot Preservation P-Lot pH Ship. Cont. Bottle FLPE Hg-T A 250 mL 71470160 none n/a Cooler 3 10 Bottle FLPE Hg-SP B 125 mL 71402520 0.5 mL 9N H2SO4 (BRL) 1208042 <2 N/A 10 Bottle HDPE ICP-W C 125 mL 1048890 0.1% HNO3 (BRL) 1202050 <2 Cooler 3

Lab ID: 1212016-22 Report Matrix: DIW Collected: 03/21/2012 Sample: SW-RB-20120321 Sample Type: Rinse Blank Received: 03/23/2012 Des Container Size Lot Preservation P-Lot pH Ship. Cont. Bottle FLPE Hg-T A 250 mL 71470160 none n/a Cooler 3 10 Bottle HDPE ICP-W B 125 mL 1048890 0.1% HNO3 (BRL) 1202050 <2 Cooler 3

Lab ID: 1212016-23 Report Matrix: Water Collected: 03/21/2012 Sample: NC034SW-A-20120321 Sample Type: Sample Received: 03/23/2012 Comments: DIL Se: 50x Des Container Size Lot Preservation P-Lot pH Ship. Cont. Bottle FLPE Hg-T A 250 mL 71470160 none n/a Cooler 3 10 Bottle FLPE Hg-SP B 250 mL 71470160 1 mL 9N H2SO4 (PP) 1208042 <2 Cooler 3 10 Bottle HDPE ICP-W C 125 mL 1048890 0.1% HNO3 (BRL) 1202050 <2 Cooler 3

Lab ID: 1212016-24 Report Matrix: Water Collected: 03/21/2012 Sample: NC034SW-A-20120321 Sample Type: Sample Received: 03/23/2012 Comments: DIL Se: 50x Des Container Size Lot Preservation P-Lot pH Ship. Cont. Bottle FLPE Hg-T A 250 mL 71470160 none n/a Cooler 3 10 Bottle HDPE ICP-W B 125 mL 1048890 0.1% HNO3 (BRL) 1202050 <2 Cooler 3

BRL Report 1212016

of 274


PM: Amanda Royal



Sample Containers






10


B 71470160

10








10



Shipping Containers

Cooler

Tracking No: 1Z 19E 18E 01 4806 6254 via UPS

Temperature: 2.4 °C

Coolant Type: Ice

Description: Cooler

Damaged in transit? No

Returned to client? No

Custody seals present? No

Custody seals intact? No

COC present? Yes

Received: March 21, 2012 9:30

Cooler 2



Coolant Type: Ice

Description: Cooler 2





COC present? Yes


Cooler 3



Coolant Type: Ice

Description: Cooler 3





COC present? Yes



BRL Report 1212016

of 274

Sample Calculations

Page 1 of 1

CVAFS

EPA 1631, Water

𝐶𝐶𝐶𝐶𝐶𝐶𝐴𝐴 ∗ 𝐼𝐼

1− (𝑅𝑅𝐵𝐵𝐵𝐵𝐶𝐶𝐵𝐵 /100%)− �

𝐵𝐵𝑓𝑓𝐴𝐴𝐴𝐴𝐴𝐴

∗ 𝑅𝑅𝐵𝐵𝐵𝐵𝐶𝐶𝐵𝐵 �

C – result produced at the instrument, pg F – final volume of the sample preparation, mL D – dilution factor of any dilution of the preparation made at the instrument A – analyzed volume of the prep or dilution of the prep, mL Bf - the mean of the method blank instrument results, pg AAV - the mean of the analyzed volumes of the method blanks, mL RBrCl – percentage of BrCl in the sample preparation I – aliquot of sample prepared, mL.

EPA 1630, Water

𝐶𝐶𝐶𝐶𝐶𝐶𝐴𝐴 − 𝐵𝐵𝐶𝐶𝑑𝑑

𝐴𝐴𝑑𝑑𝐼𝐼

∗ 𝐸𝐸

C – result produced at the instrument, pg F – final volume of the sample preparation, mL D – dilution factor of any dilution of the preparation made at the instrument A – analyzed volume of the prep or dilution of the prep, mL B – the mean of the method blank instrument result, pg Fd – default final prep volume for the method used for the method blanks, 58 mL Ad – default analyzed volume for the method used for the method blanks, 30 mL E – the empirically derived correction factor I – aliquot of sample prepared, mL.

ICP-MS Metals

EPA 1638, Water

(𝐶𝐶 − 𝐶𝐶𝑠𝑠𝐵𝐵)𝐶𝐶

𝐼𝐼 − (𝐼𝐼 ∗ 𝑅𝑅𝑁𝑁/100%)

C – concentration of the sample preparation, corrected for the dilution at the instrument, µg/L Ds – dilution factor of the sample B – the mean of the method blank instrument result, µg/L F – final volume of the prep, mL I – aliquot of sample prepared, mL (this volume includes the HNO3 used in the prep of the sample) RN – percentage of HNO3 in the sample preparation

BRL Report 1212016

of 274

BRL Report 1212016

of 274

ANALYSIS SEQUENCE

Analysis STD ID CommentsDueOrder BRL Project #Lab Number

1200235

THG-10Instrument:

Batch # Source ID

Brooks Rand Labs

1200235-IBL1 QC 11200235 -

1200235-IBL2 QC 21200235 -

1200235-IBL3 QC 31200235 -

1200235-IBL4 QC 41200235 -

1200235-CAL1 QC 5 12130061200235 -

1200235-CAL2 QC 6 12130071200235 -

1200235-CAL3 QC 7 12130081200235 -

1200235-CAL4 QC 8 12130091200235 -

1200235-CAL5 QC 9 12130101200235 -

1200235-ICV1 QC 10 12130121200235 -

B120480-SRM1 QC 11B120480 -

1200235-CAL6 QC 12 12130081200235 -

B120480-BLK1 QC 13B120480 -

1200235-CCB1 QC 141200235 -

B120480-BLK2 QC 15B120480 -

B120480-BLK3 QC 16B120480 -

B120480-BLK4 QC 17B120480 -

1200235-CCV1 QC 18 12130111200235 -

1200235-CCB2 QC 191200235 -

1212026-01 Hg-W-BrCl-CVAFS-TR 20B120480 MEL-YA0801 4/3/2012

1212026-01 Hg-W-BrCl-CVAFS-NoMB-Diss 21 BatchQCB120480 MEL-YA0801 1/1/1980

1212026-01 Hg-W-BrCl-CVAFS-NoMB-TR 22 BatchQCB120480 MEL-YA0801 1/1/1980

1212027-01 Hg-W-BrCl-CVAFS-TR 23B120480 MEL-YA0801 4/3/2012

1212011-02 Hg-W-BrCl-CVAFS-TR 24B120480 AXS-BC1201 4/11/2012

1212016-01 Hg-W-BrCl-CVAFS-TR 25 BatchQCB120480 AAL-MN1101 1/1/1980

1212016-01 Hg-W-BrCl-CVAFS-NoMB-Diss 26 BatchQCB120480 AAL-MN1101 1/1/1980

Page 1 of 3Printed: 4/4/2012 3:33:21PM

BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200235

THG-10Instrument:

Batch # Source ID

Brooks Rand Labs

1212016-01 Hg-W-BrCl-CVAFS-NoMB-TR 27B120480 AAL-MN1101 4/10/2012







B120480-MS1 QC 34B120480 1212026-01

B120480-MSD1 QC 35B120480 1212026-01

B120480-MS2 QC 36B120480 1212016-01

B120480-MSD2 QC 37B120480 1212016-01

1212011-02RE1 Hg-W-BrCl-CVAFS-TR 38 Added 4/4/2012 by MSUB120480 AXS-BC1201 4/11/2012

1200235-CCV2 QC 39 12130111200235 -






1212016-02 Hg-W-BrCl-CVAFS-NoMB-Diss 45B120480 AAL-MN1101 4/10/2012




1211017-01 Hg-W-BrCl-CVAFS-TR 49 reconstituted freeze dried urine samplesB120480 INS001 4/11/2012



B120480-MS3 QC 52B120480 1212016-17


BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200235

THG-10Instrument:

Batch # Source ID

Brooks Rand Labs

B120480-MSD3 QC 53B120480 1212016-17

1200235-CCV3 QC 54 12130111200235 -






1200235-CCV4 QC 60 12130111200235 -


BRL Report 1212016

of 274

BRL Report 1212016

of 274

Peak ReportBatch Number: B120480

Method Number: CVAFS BR-0006Project Number(s): 1200235 Date Analyzed: 4/3/12Instrument ID: BR-10 Analyst Name: MSU

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes1 IBL SEQ-IBL1 1 55,470 5.26 5.26 < 40 accept

Notes

Date:Time:

4/3/1212:15 PM

Peak rt Area1 1.19 55,470

0

200

400

600

800

1,000

0 1 2 3

1


Notes

Date:Time:

4/3/1212:20 PM


0

200

400

600

800

1,000

0 1 2 3

1


Notes

Date:Time:

4/3/1212:34 PM

Peak rt Area1 1.16 55,5512 2.56 12

0

200

400

600

800

1,000

0 1 2 3

1 2

Page 1 of 19 (Peak Report)

Mercury Guru ver 4.6 © 1995-2011 Brooks Rand LLC

BRL Report 1212016

of 274




Notes

Date:Time:

4/3/1212:44 PM


0

200

400

600

800

1,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes5 CAL SEQ-CAL1 1 327,429 25.9 103 80-120 accept

Notes

Date:Time:

4/3/1212:56 PM

Peak rt Area1 1.19 327,429

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes6 CAL SEQ-CAL2 1 1,103,065 99.4 99.4 80-120 accept

Notes

Date:Time:

4/3/121:02 PM

Peak rt Area1 1.15 1,103,065

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes7 CAL SEQ-CAL3 1 5,151,337 484 96.7 80-120 reject

Notes

Date:Time:

4/3/121:11 PM

Peak rt Area1 1.14 5,151,3372 1.66 1,339,500

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1 2

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes8 CAL SEQ-CAL4 1 25,773,763 2,440 97.6 80-120 accept

Notes

Date:Time:

4/3/121:17 PM

Peak rt Area1 1.18 25,773,763

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1


Notes

Date:Time:

4/3/121:21 PM

Peak rt Area1 1.15 104,280,648

0

400,000

800,000

1,200,000

1,600,000

2,000,000

0 1 2 3

1



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes10 ICV SEQ-ICV1 1 16,735,916 1,580 101 85-115 accept

Notes

Date:Time:

4/3/121:25 PM

Peak rt Area1 1.16 16,735,916

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes11 CAL SEQ-CAL6 1 5,367,831 504 101 80-120 accept

Notes

Date:Time:

4/3/121:30 PM

Peak rt Area1 1.19 5,367,831

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes12 S B120480-BLK1 1 157,668 9.75 0.00 < HS accept

Notes

Date:Time:

4/3/121:38 PM

Peak rt Area1 1.20 157,668

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes13 CCB SEQ-CCB1 1 52,702 5.00 5.00 < 40 accept

Notes

Date:Time:

4/3/121:42 PM


0

200

400

600

800

1,000

0 1 2 3

1


Notes

Date:Time:

4/3/121:48 PM

Peak rt Area1 1.19 90,0482 2.00 1623 2.58 6,0314 2.59 769

0

200

400

600

800

1,000

0 1 2 3

1 2 34


Notes

Date:Time:

4/3/121:52 PM


0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/3/121:56 PM


0

200

400

600

800

1,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes17 CCV SEQ-CCV 1 5,323,211 500. 100. 77-123 accept

Notes

Date:Time:

4/3/122:49 PM

Peak rt Area1 1.16 5,323,211

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes18 CCB SEQ-CCB 1 39,560 3.75 3.75 < 40 accept

Notes

Date:Time:

4/3/122:53 PM

Peak rt Area1 1.13 39,5602 1.66 3483 1.86 5414 1.96 1,2735 2.07 2,5546 2.19 3,7407 2.33 10,3008 2.60 23,5259 2.70 7,948

10 2.84 25,80811 2.97 4,669

0

200

400

600

800

1,000

0 1 2 3

1 2 3 4 5 6 7 8 9 10 11



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes19 S 1212026-01 1 10,162,132 959 0.00 < HS accept

Notes

Date:Time:

4/3/123:01 PM

Peak rt Area1 1.16 10,162,132

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/3/123:05 PM

Peak rt Area1 1.18 5,561,408

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes21 S 1212011-02 1 251,475 18.7 0.00 < HS accept

Notes

Date:Time:

4/3/123:10 PM

Peak rt Area1 1.16 251,475

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/3/123:15 PM

Peak rt Area1 1.15 7,061,836

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/3/123:20 PM

Peak rt Area1 1.14 2,641,427

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes24 S 1212016-05 2 3,643,585 340. 0.00 < HS accept

Notes

Date:Time:

4/3/123:24 PM

Peak rt Area1 0.76 5132 1.18 3,643,585

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1 2



BRL Report 1212016

of 274




Notes

Date:Time:

4/3/123:36 PM

Peak rt Area1 1.18 3,984,189

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/3/123:40 PM

Peak rt Area1 1.18 2,966,396

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1


Notes

Date:Time:

4/3/123:45 PM

Peak rt Area1 1.15 1,975,773

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/3/123:50 PM

Peak rt Area1 1.14 5,654,909

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes29 S B120480-MS1 1 59,606,278 5,650 0.00 < HS accept

Notes

Date:Time:

4/3/123:56 PM

Peak rt Area1 1.14 59,606,278

0

400,000

800,000

1,200,000

1,600,000

2,000,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes30 S B120480-MSD1 1 60,798,174 5,760 0.00 < HS accept

Notes

Date:Time:

4/3/124:00 PM

Peak rt Area1 1.16 60,798,174

0

400,000

800,000

1,200,000

1,600,000

2,000,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/3/124:04 PM

Peak rt Area1 1.17 41,421,187

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1


Notes

Date:Time:

4/3/124:08 PM

Peak rt Area1 1.14 41,593,013

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes33 S 1212011-02RE1 1 2,016,037 186 0.00 < HS accept

Notes

Date:Time:

4/3/124:15 PM

Peak rt Area1 1.18 2,016,037

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes34 CCV SEQ-CCV 1 5,585,908 525 105 77-123 accept

Notes

Date:Time:

4/3/124:21 PM

Peak rt Area1 1.14 5,585,908

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/3/124:25 PM

Peak rt Area1 1.20 2,677,657

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1


Notes

Date:Time:

4/3/124:29 PM

Peak rt Area1 1.22 3,988,027

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/3/124:36 PM

Peak rt Area1 1.19 2,408,8342 1.70 4,968

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1 2


Notes

Date:Time:

4/3/125:10 PM

Peak rt Area1 1.14 392,638

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1


Notes

Date:Time:

4/3/125:14 PM

Peak rt Area1 1.17 408,122

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/3/125:22 PM

Peak rt Area1 1.17 361,204

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1


Notes

Date:Time:

4/3/125:29 PM

Peak rt Area1 1.17 347,811

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes42 S 1211017-01 1 22,194,132 2,100 0.00 < HS accept

Notes

Date:Time:

4/3/125:34 PM

Peak rt Area1 1.12 22,194,132

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/3/125:38 PM

Peak rt Area1 1.15 3,589,189

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/3/125:45 PM

Peak rt Area1 1.10 40,693,085

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1


Notes

Date:Time:

4/3/125:50 PM

Peak rt Area1 1.13 20,468,098

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/3/125:56 PM

Peak rt Area1 1.13 20,554,965

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes47 CCV SEQ-CCV 1 5,305,185 498 99.6 77-123 accept

Notes

Date:Time:

4/3/126:00 PM

Peak rt Area1 1.17 5,305,185

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/3/126:05 PM

Peak rt Area1 1.20 473,626

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/3/126:10 PM

Peak rt Area1 1.20 348,126

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1


Notes

Date:Time:

4/3/126:17 PM

Peak rt Area1 1.20 4,790,1882 2.75 3583 2.78 779

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1 23


Notes

Date:Time:

4/3/126:22 PM

Peak rt Area1 1.17 428,880

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/3/126:26 PM

Peak rt Area1 1.18 357,482

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes53 CCV SEQ-CCV 1 5,311,726 499 99.7 77-123 accept

Notes

Date:Time:

4/3/126:32 PM

Peak rt Area1 1.12 5,311,7262 1.40 53,1583 2.25 9,3834 2.34 12,217

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1 2 3 4

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes54 S DIW 1 118,647 6.05 0.00 < HS accept

Notes

Date:Time:

4/3/126:37 PM

Peak rt Area1 1.12 118,647

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes55 S A 1 117,313 5.93 0.00 < HS accept

Notes

Date:Time:

4/3/126:42 PM

Peak rt Area1 1.12 117,313

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes56 S B 1 149,414 8.97 0.00 < HS accept

Notes

Date:Time:

4/3/126:47 PM

Peak rt Area1 1.14 149,414

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200251

THG-05Instrument:

Batch # Source ID

Brooks Rand Labs

1200251-IBL1 QC 11200251 -

1200251-IBL2 QC 21200251 -

1200251-IBL3 QC 31200251 -

1200251-IBL4 QC 41200251 -

1200251-CAL1 QC 5 12130061200251 -

1200251-CAL2 QC 6 12130071200251 -

1200251-CAL3 QC 7 12130081200251 -

1200251-CAL4 QC 8 12130091200251 -

1200251-CAL5 QC 9 12130101200251 -

1200251-ICV1 QC 10 12130121200251 -

B120509-SRM1 QC 11B120509 -

1200251-CCV1 QC 12 12130111200251 -

B120509-BLK1 QC 13B120509 -

1200251-CCB1 QC 141200251 -

B120509-BLK2 QC 15B120509 -

B120509-BLK3 QC 16B120509 -

B120509-BLK4 QC 17B120509 -

1200251-IBL5 QC 181200251 -




1212016-19 Hg-W-BrCl-CVAFS-Diss 22 BatchQCB120509 AAL-MN1101 1/1/1980



1213025-05 Hg-W-BrCl-CVAFS-TR 25B120509 ECA-GJ1001 4/9/2012

1214016-01 Hg-W-BrCl-CVAFS-TR 26B120509 H2M-MV1101 4/6/2012


BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200251

THG-05Instrument:

Batch # Source ID

Brooks Rand Labs



1213025-01 Hg-W-BrCl-CVAFS-Diss 29 BatchQCB120509 ECA-GJ1001 1/1/1980

1213025-01 Hg-W-BrCl-CVAFS-NoMB-Diss 30 BatchQCB120509 ECA-GJ1001 1/1/1980

1213025-01 Hg-W-BrCl-CVAFS-NoMB-TR 31 BatchQCB120509 ECA-GJ1001 1/1/1980

1213037-01 Hg-W-BrCl-CVAFS-TR 32B120509 HCL-MU0801 4/4/2012

1213030-01 Hg-W-BrCl-CVAFS-TR 33B120509 MAX-CA1201 4/9/2012

1213009-09 Hg-W-BrCl-CVAFS-Diss 34B120509 ACC-SJ1201 4/6/2012



1214016-01RE1 Hg-W-BrCl-CVAFS-TR 37 Added 4/9/2012 by TKEB120509 H2M-MV1101 4/6/2012

B120509-MS1 QC 38B120509 1212016-19

B120509-MSD1 QC 39B120509 1212016-19

B120509-MS2 QC 40B120509 1213025-01

B120509-MSD2 QC 41B120509 1213025-01

1213009-09RE1 Hg-W-BrCl-CVAFS-Diss 42 Added 4/9/2012 by TKEB120509 ACC-SJ1201 4/6/2012


1200251-CCV2 QC 44 12130111200251 -





1212016-23 Hg-W-BrCl-CVAFS-Diss 49 BatchQCB120509 AAL-MN1101 1/1/1980





BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200251

THG-05Instrument:

Batch # Source ID

Brooks Rand Labs






1212011-04 Hg-W-BrCl-CVAFS-Diss 58 BatchQCB120509 AXS-BC1201 1/1/1980

1212011-04 Hg-W-BrCl-CVAFS-NoMB-Diss 59 BatchQCB120509 AXS-BC1201 1/1/1980

1212011-04 Hg-W-BrCl-CVAFS-NoMB-TR 60 BatchQCB120509 AXS-BC1201 1/1/1980




B120509-MS3 QC 64B120509 1212016-23

B120509-MSD3 QC 65B120509 1212016-23

B120509-MS4 QC 66B120509 1212011-04

B120509-MSD4 QC 67B120509 1212011-04


1200251-CCV3 QC 69 12130111200251 -











BRL Report 1212016

of 274

BRL Report 1212016

of 274


Method Number: CVAFS BR-0006Project Number(s): 1200251 Date Analyzed: 4/9/12Instrument ID: BR-05 Analyst Name: TE

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes1 IBL SEQ-IBL1 1 50,029 4.96 4.96 < 40 reject

Notes

Date:Time:

4/9/1210:34 AM

Peak rt Area1 1.03 50,0292 1.25 14,269

0

200

400

600

800

1,000

0 1 2 3

1 2


Notes

Date:Time:

4/9/1210:38 AM


0

200

400

600

800

1,000

0 1 2 3

1


Notes

Date:Time:

4/9/1210:42 AM


0

200

400

600

800

1,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/1210:46 AM


0

200

400

600

800

1,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes5 CAL SEQ-CAL1 1 294,760 24.9 99.8 80-120 accept

Notes

Date:Time:

4/9/1210:52 AM

Peak rt Area1 1.08 294,760

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1


Notes

Date:Time:

4/9/1210:56 AM

Peak rt Area1 1.06 1,058,254

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/1211:01 AM

Peak rt Area1 1.04 5,142,494

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/9/1211:06 AM

Peak rt Area1 1.10 25,065,924

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1


Notes

Date:Time:

4/9/1211:11 AM

Peak rt Area1 1.02 99,950,545

0

400,000

800,000

1,200,000

1,600,000

2,000,000

0 1 2 3

1



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes10 ICV SEQ-ICV1 2 15,824,450 1,570 99.8 85-115 accept

Notes

Date:Time:

4/9/1211:15 AM

Peak rt Area1 0.18 4222 1.04 15,824,450

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1 2

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes11 CCV SEQ-CCV 1 5,125,287 504 101 77-123 accept

Notes

Date:Time:

4/9/1211:19 AM

Peak rt Area1 1.02 5,125,287

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/9/1211:24 AM

Peak rt Area1 1.05 121,770

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes13 CCB SEQ-CCB1 1 87,300 8.66 8.66 < 40 accept

Notes

Date:Time:

4/9/1211:31 AM


0

200

400

600

800

1,000

0 1 2 3

1


Notes

Date:Time:

4/9/1211:43 AM

Peak rt Area1 1.08 131,041

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1


Notes

Date:Time:

4/9/1211:47 AM

Peak rt Area1 1.04 136,630

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/1211:51 AM

Peak rt Area1 1.04 101,076

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1


Notes

Date:Time:

4/9/1211:58 AM


-100

100

300

500

700

900

0 1 2 3

1


Notes

Date:Time:

4/9/1212:02 PM

Peak rt Area1 1.04 816,548

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/1212:16 PM

Peak rt Area1 1.08 255,404

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1


Notes

Date:Time:

4/9/121:18 PM

Peak rt Area1 1.10 6,666,857

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/9/121:22 PM

Peak rt Area1 1.05 173,051

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/121:30 PM

Peak rt Area1 1.07 151,351

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1


Notes

Date:Time:

4/9/121:37 PM

Peak rt Area1 1.07 3,348,974

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/9/121:43 PM

Peak rt Area1 0.56 2032 1.06 1,839,350

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1 2



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/121:52 PM

Peak rt Area1 1.10 2,811,197

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/9/121:59 PM

Peak rt Area1 1.09 961,627

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes27 S 1213009-09 1 35,098 -0.811 0.00 < HS accept

Notes

Date:Time:

4/9/122:03 PM


-200

0

200

400

600

800

0 1 2 3

1



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes28 S 1213009-11 1 41,590 -0.167 0.00 < HS accept

Notes

Date:Time:

4/9/122:08 PM


-200

0

200

400

600

800

0 1 2 3

1


Notes

Date:Time:

4/9/122:14 PM

Peak rt Area1 1.08 1,206,608

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes30 S 1214016-01RE1 1 579,651 53.2 0.00 < HS accept

Notes

Date:Time:

4/9/122:19 PM

Peak rt Area1 1.08 579,651

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/122:23 PM

Peak rt Area1 1.07 37,238,446

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1


Notes

Date:Time:

4/9/122:28 PM

Peak rt Area1 1.07 37,013,897

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes33 S B120509-MS2 1 10,096,033 997 0.00 < HS accept

Notes

Date:Time:

4/9/122:34 PM

Peak rt Area1 1.04 10,096,033

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes34 S B120509-MSD2 1 10,032,048 991 0.00 < HS accept

Notes

Date:Time:

4/9/122:39 PM

Peak rt Area1 1.04 10,032,048

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1


Notes

Date:Time:

4/9/122:43 PM

Peak rt Area1 1.06 437,113

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1


Notes

Date:Time:

4/9/122:50 PM


-200

0

200

400

600

800

0 1 2 3

1



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes37 CCV SEQ-CCV2 1 4,961,170 488 97.6 77-123 accept

Notes

Date:Time:

4/9/122:55 PM

Peak rt Area1 1.07 4,961,170

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/9/123:00 PM

Peak rt Area1 1.08 158,769

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1


Notes

Date:Time:

4/9/123:04 PM

Peak rt Area1 1.04 141,202

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/123:08 PM


-200

0

200

400

600

800

0 1 2 3

1


Notes

Date:Time:

4/9/123:14 PM

Peak rt Area1 1.08 2,772,793

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/9/123:19 PM

Peak rt Area1 1.07 588,983

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/123:23 PM

Peak rt Area1 1.06 24,158,035

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes44 S 1212016-26 1 1,055,719 100. 0.00 < HS accept

Notes

Date:Time:

4/9/123:27 PM

Peak rt Area1 1.06 1,055,719

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1


Notes

Date:Time:

4/9/123:34 PM


-300

-100

100

300

500

700

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/123:39 PM


-300

-100

100

300

500

700

0 1 2 3

1


Notes

Date:Time:

4/9/123:44 PM

Peak rt Area1 1.07 2,773,098

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/9/123:48 PM

Peak rt Area1 1.07 652,190

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/123:54 PM

Peak rt Area1 1.03 518,427

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1


Notes

Date:Time:

4/9/123:59 PM

Peak rt Area1 1.05 123,859

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3

1


Notes

Date:Time:

4/9/124:03 PM

Peak rt Area1 1.04 12,740,286

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/9/124:08 PM

Peak rt Area1 1.07 12,693,420

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1


Notes

Date:Time:

4/9/124:15 PM

Peak rt Area1 1.11 12,645,571

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1


Notes

Date:Time:

4/9/124:21 PM

Peak rt Area1 1.08 12,296,063

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3

1



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes55 S 1213009-13RE1 1 1,249,002 120. 0.00 < HS accept

Notes

Date:Time:

4/9/124:26 PM

Peak rt Area1 1.08 1,249,002

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1

Run Trap Type Name/ID M B Peak Peak Area Analyzed Result Final Result QA Results Criteria Notes56 CCV SEQ-CCV3 1 4,765,620 468 93.7 77-123 accept

Notes

Date:Time:

4/9/124:39 PM

Peak rt Area1 1.02 4,765,620

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3

1


Notes

Date:Time:

4/9/124:43 PM

Peak rt Area1 0.18 1,8052 0.36 2053 1.08 1,892,287

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3

1 2 3



BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200258

MMHG-09Instrument:

Batch # Source ID

Brooks Rand Labs

1200258-IBL1 QC 11200258 -

1200258-IBL2 QC 21200258 -

1200258-IBL3 QC 31200258 -

1200258-CAL1 QC 4 12120281200258 -

1200258-CAL2 QC 5 12120291200258 -

1200258-CAL3 QC 6 12120301200258 -

1200258-CAL4 QC 7 12120311200258 -

1200258-CAL5 QC 8 12120321200258 -

1200258-CAL6 QC 9 12120331200258 -

1200258-CAL7 QC 10 12120341200258 -

1200258-CCB1 QC 111200258 -

1200258-ICV1 QC 12 12110081200258 -

1200258-CCB2 QC 131200258 -

1200258-CCV1 QC 14 12120351200258 -

1200258-CCB3 QC 151200258 -

1200258-CCB4 QC 161200258 -

1200258-CCB5 QC 171200258 -

B120596-BLK1 QC 18B120596 -

B120596-BLK2 QC 19B120596 -

B120596-BLK3 QC 20B120596 -

B120596-BLK4 QC 21B120596 -

B120596-BS1 QC 22B120596 -

B120596-BS2 QC 23B120596 -

B120596-BS3 QC 24B120596 -

B120596-BS4 QC 25B120596 -

B120596-BS5 QC 26B120596 -


BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200258

MMHG-09Instrument:

Batch # Source ID

Brooks Rand Labs

B120596-BS6 QC 27B120596 -

1200258-CCV2 QC 28 12120351200258 -

1200258-CCB6 QC 291200258 -

B120596-BS7 QC 30B120596 -

B120596-BS8 QC 31B120596 -

B120596-BS9 QC 32B120596 -

B120596-BSA QC 33B120596 -

B120596-BSB QC 34B120596 -

B120596-BSC QC 35B120596 -

B120596-BSD QC 36B120596 -

B120596-BSE QC 37B120596 -

1200258-CCV3 QC 38 12120351200258 -

1200258-CCB7 QC 391200258 -

B120524-BLK1 QC 40B120524 -

B120524-BLK2 QC 41B120524 -

B120524-BLK3 QC 42B120524 -

B120524-BLK4 QC 43B120524 -

1212016-21 MeHg-W-Dist-NoMB-TR 44B120524 AAL-MN1101 4/10/2012

B120524-BS1 QC 45B120524 -

B120524-BS2 QC 46B120524 -

1213011-17 MeHg-W-Dist-TR 47B120524 UME-OR1201 4/18/2012



1200258-CCV4 QC 50 12120351200258 -

1200258-CCB8 QC 511200258 -

1212014-03 MeHg-W-Dist-TR 52B120524 SFE-OA1103 4/12/2012


BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200258

MMHG-09Instrument:

Batch # Source ID

Brooks Rand Labs

1212014-04 MeHg-W-Dist-TR 53B120524 SFE-OA1103 4/12/2012

1212014-04 MeHg-W-Dist-NoMB-TR 54 BatchQCB120524 SFE-OA1103 1/1/1980

B120524-MS1 QC 55B120524 1212014-04

B120524-MSD1 QC 56B120524 1212014-04







1200258-CCV5 QC 63 12120351200258 -

1200258-CCB9 QC 641200258 -

B120524-MS2 QC 65B120524 1212016-11

B120524-MSD2 QC 66B120524 1212016-11









1200258-CCV6 QC 75 12120351200258 -

1200258-CCBA QC 761200258 -




BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200258

MMHG-09Instrument:

Batch # Source ID

Brooks Rand Labs


1212016-11 MeHg-W-Dist-TR 80 BatchQCB120524 AAL-MN1101 1/1/1980





B120524-MS3 QC 85B120524 1213006-15

B120524-MSD3 QC 86B120524 1213006-15



1200258-CCV7 QC 89 12120351200258 -

1200258-CCBB QC 901200258 -






B120524-MS4 QC 96B120524 1213006-31

B120524-MSD4 QC 97B120524 1213006-31



1200258-CCV8 QC 100 12120351200258 -

1200258-CCBC QC 1011200258 -

B120566-BLK1 QC 102B120566 -

B120566-BLK2 QC 103B120566 -

B120566-BLK3 QC 104B120566 -


BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200258

MMHG-09Instrument:

Batch # Source ID

Brooks Rand Labs

B120566-BLK4 QC 105B120566 -

1200258-CCBD QC 1061200258 -

B120566-SRM1 QC 107B120566 -

1211036-02 MeHg-B-KOH/Me 108B120566 ACF-SH1201 6/25/2012

B120566-DUP1 QC 109B120566 1211036-02

B120566-MS1 QC 110B120566 1211036-02

B120566-MSD1 QC 111B120566 1211036-02

1200258-CCV9 QC 112 12120351200258 -

1200258-CCBE QC 1131200258 -

1214009-01 MeHg-B-KOH/Me 114B120566 UME-OR1201 4/25/2012




1200258-CCVA QC 118 12120351200258 -

1200258-CCBF QC 1191200258 -


BRL Report 1212016

of 274

BRL Report 1212016

of 274

Peak ReportBatch Number: B120524, B120596, B120566

Method Number: CVAFS BR-0011Project Number(s): 1200258 Date Analyzed: 4/11/12Instrument ID: BR-09 Analyst Name: AC

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes1 A Rins Rinse 2 62 0.203 0.00 0.00 < 0.05 accept

Notes

Date:Time:

4/11/1212:51 PM

Peak rt Height1 0.52 5522 1.12 623 2.44 356

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes2 B Rins Rinse 2 49 0.161 0.00 0.00 < 0.05 accept

Notes

Date:Time:

4/11/1212:58 PM

Peak rt Height1 0.53 6492 1.10 493 2.43 300

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes3 C Rins Rinse 2 46 0.151 0.00 0.00 < 0.05 accept

Notes

Date:Time:

4/11/121:05 PM

Peak rt Height1 0.52 8202 1.14 463 2.44 241

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes4 A CB SEQ-IBL 2 44 0.144 0.144 < 1.4 accept

Notes

Date:Time:

4/11/121:11 PM

Peak rt Height1 0.52 5352 1.10 443 2.45 2084 3.75 15 3.77 46 4.20 117 4.42 1

-100

100

300

500

700

900

0 1 2 3 4 5

1 2 3 45 6 7

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes5 B CB SEQ-IBL 2 37 0.121 0.121 < 1.4 accept

Notes

Date:Time:

4/11/121:18 PM

Peak rt Height1 0.53 5882 1.10 373 2.44 203

-100

100

300

500

700

900

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes6 C CB SEQ-IBL 2 43 0.141 0.141 < 1.4 accept

Notes

Date:Time:

4/11/121:25 PM

Peak rt Height1 0.52 8142 1.12 433 2.45 169

-200

0

200

400

600

800

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes7 A STD SEQ-CAL1 2 191 0.491 98.2 65-135 accept

Notes

Date:Time:

4/11/121:31 PM

Peak rt Height1 0.52 5382 1.13 1913 2.45 208

-200

0

200

400

600

800

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes8 B STD SEQ-CAL2 2 346 0.999 99.9 65-135 accept

Notes

Date:Time:

4/11/121:38 PM

Peak rt Height1 0.52 5332 1.12 3463 2.43 185

-300

-100

100

300

500

700

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes9 C STD SEQ-CAL3 2 617 1.89 94.4 65-135 accept

Notes

Date:Time:

4/11/121:45 PM

Peak rt Height1 0.52 7352 1.14 6173 2.47 275

-300

-100

100

300

500

700

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes10 A STD SEQ-CAL4 2 2,993 9.68 96.8 65-135 accept

Notes

Date:Time:

4/11/121:51 PM

Peak rt Height1 0.52 5182 1.13 2,9933 2.47 170

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes11 B STD SEQ-CAL5 2 15,260 49.9 99.8 65-135 accept

Notes

Date:Time:

4/11/121:58 PM

Peak rt Height1 0.53 5112 1.12 15,2603 2.44 196

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes12 C STD SEQ-CAL6 2 78,871 259 103 65-135 accept

Notes

Date:Time:

4/11/122:05 PM

Peak rt Height1 0.52 7522 1.14 78,8713 2.44 307

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes13 A STD SEQ-CAL7 2 331,161 1,090 109 65-135 accept

Notes

Date:Time:

4/11/122:11 PM

Peak rt Height1 0.53 9782 1.13 331,1613 2.43 318

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes14 B CCB SEQ-CCB 2 249 0.817 0.817 < 1.4 accept

Notes

Date:Time:

4/11/122:18 PM

Peak rt Height1 0.52 5232 1.11 2493 2.44 161

-600

-400

-200

0

200

400

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes15 C ICV SEQ-ICV 2 30,998 102 102 80-120 accept

Notes

Date:Time:

4/11/122:25 PM

Peak rt Height1 0.52 8062 1.14 30,9983 2.47 2,616

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes16 A CCB SEQ-CCB 2 426 1.40 1.40 < 1.4 accept

Notes

Date:Time:

4/11/122:31 PM

Peak rt Height1 0.52 7502 1.13 4263 2.47 193

-700

-500

-300

-100

100

300

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes17 B CCV SEQ-CCV 2 7,778 25.4 102 67-133 accept

Notes

Date:Time:

4/11/122:38 PM

Peak rt Height1 0.52 4962 1.12 7,7783 2.44 2164 4.58 23

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3 4

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes18 C CCB SEQ-CCB 2 138 0.453 0.453 < 1.4 accept

Notes

Date:Time:

4/11/122:45 PM

Peak rt Height1 0.52 7682 1.14 1383 2.46 164

-800

-600

-400

-200

0

200

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/122:51 PM

Peak rt Height1 0.52 6552 1.13 1143 2.46 147

-900

-700

-500

-300

-100

100

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/122:58 PM

Peak rt Height1 0.52 4802 1.12 603 2.44 281

-900

-700

-500

-300

-100

100

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes21 C S B120596-BLK1 2 264 0.730 0.00 < HS accept

Notes

Date:Time:

4/11/123:05 PM

Peak rt Height1 0.52 7332 1.14 2643 2.46 903

-1,000

-800

-600

-400

-200

0

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes22 A S B120596-BLK2 2 118 0.251 0.00 < HS accept

Notes

Date:Time:

4/11/123:11 PM

Peak rt Height1 0.52 5962 1.13 1183 2.47 662

-1,000

-800

-600

-400

-200

0

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes23 B S B120596-BLK3 2 72 0.101 0.00 < HS accept

Notes

Date:Time:

4/11/123:18 PM

Peak rt Height1 0.52 4502 1.11 723 2.44 511

-1,100

-900

-700

-500

-300

-100

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/123:25 PM

Peak rt Height1 0.52 6942 1.14 1053 2.47 556

-1,100

-900

-700

-500

-300

-100

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes25 A S B120596-BS1 2 446 1.33 0.00 < HS accept

Notes

Date:Time:

4/11/123:31 PM

Peak rt Height1 0.52 5802 1.13 4463 2.47 515

-1,200

-1,000

-800

-600

-400

-200

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes26 B S B120596-BS2 2 405 1.19 0.00 < HS accept

Notes

Date:Time:

4/11/123:38 PM

Peak rt Height1 0.53 4582 1.12 4053 2.45 602

-1,200

-1,000

-800

-600

-400

-200

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes27 C S B120596-BS3 2 272 0.757 0.00 < HS accept

Notes

Date:Time:

4/11/123:45 PM

Peak rt Height1 0.52 6652 1.15 2723 2.48 428

-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/123:51 PM

Peak rt Height1 0.52 5732 1.13 4143 2.46 5364 4.90 11

-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2 3 4


Notes

Date:Time:

4/11/123:58 PM

Peak rt Height1 0.53 4122 1.12 3973 2.45 385

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/124:05 PM

Peak rt Height1 0.52 6332 1.14 4313 2.46 479

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes31 A CCV SEQ-CCV 2 7,723 25.2 101 67-133 accept

Notes

Date:Time:

4/11/124:11 PM

Peak rt Height1 0.52 5292 1.13 7,7233 2.47 1614 4.81 12

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3 4


Notes

Date:Time:

4/11/124:18 PM

Peak rt Height1 0.52 4002 1.11 703 2.45 144

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/124:25 PM

Peak rt Height1 0.52 6302 1.14 3943 2.47 1,598

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/124:31 PM

Peak rt Height1 0.52 5202 1.14 4143 2.47 499

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes35 B S B120596-BS9 2 3,130 10.1 0.00 < HS accept

Notes

Date:Time:

4/11/124:38 PM

Peak rt Height1 0.52 3932 1.12 3,1303 2.45 5634 3.78 34

-1,000

0

1,000

2,000

3,000

4,000

0 1 2 3 4 5

1 2 3 4

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes36 C S B120596-BSA 2 418 1.24 0.00 < HS accept

Notes

Date:Time:

4/11/124:45 PM

Peak rt Height1 0.52 5772 1.15 4183 2.46 4884 4.07 155 4.44 276 4.93 0

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 3 4 5 6



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes37 A S B120596-BSB 2 1,933 6.21 0.00 < HS accept

Notes

Date:Time:

4/11/124:51 PM

Peak rt Height1 0.52 5362 1.13 1,9333 2.47 1,4804 4.86 0

-1,500

-500

500

1,500

2,500

3,500

0 1 2 3 4 5

1 2 3 4

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes38 B S B120596-BSC 2 788 2.45 0.00 < HS accept

Notes

Date:Time:

4/11/124:58 PM

Peak rt Height1 0.52 4202 1.12 7883 2.45 4684 3.94 15 3.97 16 4.94 0

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 3 45 6

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes39 C S B120596-BSD 2 753 2.33 0.00 < HS accept

Notes

Date:Time:

4/11/125:05 PM

Peak rt Height1 0.52 6052 1.14 7533 2.47 3884 4.28 15 4.30 1

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 3 45



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes40 A S B120596-BSE 2 697 2.15 0.00 < HS accept

Notes

Date:Time:

4/11/125:11 PM

Peak rt Height1 0.52 5352 1.13 6973 2.48 3644 3.63 15 3.66 16 4.24 24

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 3 45 6

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes41 B CCV SEQ-CCV 2 7,454 24.3 97.3 67-133 accept

Notes

Date:Time:

4/11/125:18 PM

Peak rt Height1 0.53 3762 1.12 7,4543 2.44 266

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/125:25 PM

Peak rt Height1 0.52 6102 1.11 353 2.45 2314 3.94 15 3.96 1

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 3 45



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/125:31 PM

Peak rt Height1 0.52 5122 1.13 3583 2.47 1,0574 4.31 15 4.33 1

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 3 45


Notes

Date:Time:

4/11/125:38 PM

Peak rt Height1 0.52 3992 1.12 933 2.44 5624 4.74 15 4.76 1

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 3 45


Notes

Date:Time:

4/11/125:45 PM

Peak rt Height1 0.52 6162 1.15 1113 1.73 14 1.75 15 2.46 650

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 34 5



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/125:51 PM

Peak rt Height1 0.52 4962 1.13 623 2.47 5134 4.85 15 4.87 1

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3 45

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes47 B S 1212016-21 2 63 0.0711 0.00 < HS accept

Notes

Date:Time:

4/11/125:58 PM

Peak rt Height1 0.52 3862 1.09 633 2.45 2774 3.65 25 3.69 16 4.54 17 4.56 1

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3 45 67

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes48 C S B120524-BS1 2 6,059 19.7 0.00 < HS accept

Notes

Date:Time:

4/11/126:05 PM

Peak rt Height1 0.52 6062 1.14 6,0593 2.46 2,082

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes49 A S B120524-BS2 2 6,328 20.6 0.00 < HS accept

Notes

Date:Time:

4/11/126:11 PM

Peak rt Height1 0.52 5012 1.13 6,3283 2.47 538

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes50 B S 1213011-17 2 5,583 18.2 0.00 < HS accept

Notes

Date:Time:

4/11/126:18 PM

Peak rt Height1 0.53 4072 1.12 5,5833 2.44 729

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes51 C S 1213011-18 2 6,378 20.8 0.00 < HS accept

Notes

Date:Time:

4/11/126:25 PM

Peak rt Height1 0.53 7522 1.14 6,3783 2.46 14,970

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes52 A S 1213011-19 2 22,272 72.9 0.00 < HS accept

Notes

Date:Time:

4/11/126:31 PM

Peak rt Height1 0.52 5442 1.13 22,2723 2.46 7944 4.25 15 4.27 1

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3 45


Notes

Date:Time:

4/11/126:38 PM

Peak rt Height1 0.53 4122 1.12 7,2353 2.42 2374 4.60 15 4.62 2

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3 45


Notes

Date:Time:

4/11/126:45 PM

Peak rt Height1 0.52 6432 1.14 1393 2.45 283

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes55 A S 1212014-03 2 1,851 5.94 0.00 < HS accept

Notes

Date:Time:

4/11/126:51 PM

Peak rt Height1 0.52 5262 1.13 1,8513 2.46 1,088

-1,500

-500

500

1,500

2,500

3,500

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes56 B S 1212014-04 2 1,185 3.75 0.00 < HS accept

Notes

Date:Time:

4/11/126:58 PM

Peak rt Height1 0.52 3992 1.12 1,1853 2.44 946

-1,500

-500

500

1,500

2,500

3,500

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes57 C S B120524-MS1 2 9,984 32.6 0.00 < HS accept

Notes

Date:Time:

4/11/127:05 PM

Peak rt Height1 0.52 6062 1.14 9,9843 2.46 879

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes58 A S B120524-MSD1 2 10,792 35.3 0.00 < HS accept

Notes

Date:Time:

4/11/127:11 PM

Peak rt Height1 0.52 5082 1.13 10,7923 2.46 9974 4.55 15 4.57 1

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3 45


Notes

Date:Time:

4/11/127:18 PM

Peak rt Height1 0.52 3762 1.11 3073 2.43 1,128

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes60 C S 1212016-03 2 260 0.717 0.00 < HS accept

Notes

Date:Time:

4/11/127:25 PM

Peak rt Height1 0.52 6142 1.14 2603 2.46 823

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes61 A S 1212016-05 2 272 0.757 0.00 < HS accept

Notes

Date:Time:

4/11/127:31 PM

Peak rt Height1 0.52 4762 1.13 2723 2.46 564

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/127:38 PM

Peak rt Height1 0.52 3612 1.11 1633 2.44 1,003

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/127:45 PM

Peak rt Height1 0.53 5892 1.14 6193 2.46 1,183

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/127:51 PM

Peak rt Height1 0.52 4582 1.13 2833 2.46 557

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/127:58 PM

Peak rt Height1 0.52 3352 1.11 7,0743 2.43 235

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/128:05 PM

Peak rt Height1 0.52 5692 1.13 493 2.45 359

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes67 A S B120524-MS2 2 574 1.75 0.00 < HS accept

Notes

Date:Time:

4/11/128:11 PM

Peak rt Height1 0.52 4622 1.13 5743 2.46 526

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes68 B S B120524-MSD2 2 611 1.87 0.00 < HS accept

Notes

Date:Time:

4/11/128:18 PM

Peak rt Height1 0.52 3282 1.11 6113 2.44 617

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/128:25 PM

Peak rt Height1 0.52 5422 1.14 2123 2.46 635

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/128:31 PM

Peak rt Height1 0.52 4372 1.13 2523 2.46 666

-1,600

-1,400

-1,200

-1,000

-800

-600

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/128:38 PM

Peak rt Height1 0.53 3432 1.12 2493 2.44 1,222

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes72 C S 1212016-19 2 1,226 3.89 0.00 < HS accept

Notes

Date:Time:

4/11/128:45 PM

Peak rt Height1 0.53 5832 1.14 1,2263 2.46 974

-1,500

-500

500

1,500

2,500

3,500

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes73 A S 1212016-23 0 -0.136 0.00 < HS accept

Notes

Date:Time:

4/11/128:51 PM

Peak rt Height1 0.52 438

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes74 B S 1212016-25 0 -0.136 0.00 < HS accept

Notes

Date:Time:

4/11/128:58 PM


-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes75 C S 1213006-01 0 -0.136 0.00 < HS accept

Notes

Date:Time:

4/11/129:05 PM


-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/129:11 PM


-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes77 B CCV SEQ-CCV 0 -0.136 -0.542 67-133 reject

Notes

Date:Time:

4/11/129:18 PM

Peak rt Height1 0.52 3202 2.33 13 2.36 14 2.72 20

-1,500

-1,300

-1,100

-900

-700

-500

0 1 2 3 4 5

1 23 4

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes78 C CCB SEQ-CCB 0 0.00 0.00 < 1.4 accept

Notes

Date:Time:

4/11/129:25 PM

Peak rt Height1 0.52 5452 3.53 23 3.56 1

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 23



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/129:31 PM


-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes80 B S 1213006-07 0 -0.136 0.00 < HS accept

Notes

Date:Time:

4/11/129:38 PM


-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1


Notes

Date:Time:

4/11/129:45 PM

Peak rt Height1 0.52 5372 1.14 2043 2.46 6674 4.24 15 4.26 1

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3 45



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/129:51 PM

Peak rt Height1 0.52 4272 1.12 2153 2.45 547

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/129:58 PM

Peak rt Height1 0.53 3322 1.12 2373 2.43 506

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/1210:05 PM

Peak rt Height1 0.52 5282 1.14 1863 2.45 745

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes85 A S B120524-MS3 2 510 1.54 0.00 < HS accept

Notes

Date:Time:

4/11/1210:11 PM

Peak rt Height1 0.52 4132 1.13 5103 2.46 740

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes86 B S B120524-MSD3 2 408 1.20 0.00 < HS accept

Notes

Date:Time:

4/11/1210:18 PM

Peak rt Height1 0.52 3022 1.11 4083 2.42 369

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/1210:25 PM

Peak rt Height1 0.52 5232 1.14 2173 2.46 807

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/1210:31 PM

Peak rt Height1 0.52 4162 1.12 1823 2.45 605

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/1210:38 PM

Peak rt Height1 0.53 3112 1.12 7,1773 2.44 191

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/1210:45 PM

Peak rt Height1 0.52 5082 1.13 453 2.44 203

-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/1210:51 PM

Peak rt Height1 0.52 4592 1.12 3763 2.45 2,825

-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/1210:58 PM

Peak rt Height1 0.53 3392 1.12 2473 2.44 2,269

-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/1211:05 PM

Peak rt Height1 0.52 4872 1.14 1763 2.45 489

-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/1211:11 PM

Peak rt Height1 0.52 4242 1.12 2013 2.45 542

-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes95 B S B120524-MS4 2 512 1.54 0.00 < HS accept

Notes

Date:Time:

4/11/1211:18 PM

Peak rt Height1 0.52 3002 1.11 5123 2.43 598

-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes96 C S B120524-MSD4 2 501 1.51 0.00 < HS accept

Notes

Date:Time:

4/11/1211:25 PM

Peak rt Height1 0.52 4972 1.14 5013 2.45 623

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/11/1211:31 PM

Peak rt Height1 0.52 4042 1.12 1793 2.45 848

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/11/1211:38 PM

Peak rt Height1 0.53 3072 1.11 1953 2.43 795

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes99 C CCV SEQ-CCV 2 7,166 23.4 93.5 67-133 accept

Notes

Date:Time:

4/11/1211:45 PM

Peak rt Height1 0.52 4782 1.14 7,1663 2.44 175

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes100 A CCB SEQ-CCB 2 52 0.171 0.171 < 1.4 acceptNotes

Date:Time:

4/11/1211:51 PM

Peak rt Height1 0.52 3912 1.12 523 2.45 1904 4.91 15 4.93 1

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3 45

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes101 B S B120566-BLK1 2m 44 0.00875 0.00 < HS acceptNotes

Date:Time:

4/11/1211:58 PM


2m 1.12 443 1.12 24 2.44 176

-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2m3 4

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes102 C S B120566-BLK2 2 46 0.0153 0.00 < HS acceptNotes

Date:Time:

4/12/1212:05 AM

Peak rt Height1 0.52 4642 1.13 463 2.44 2214 3.01 15 3.80 16 3.83 1

-1,400

-1,200

-1,000

-800

-600

-400

0 1 2 3 4 5

1 2 3 4 56



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes103 A S B120566-BLK3 2 45 0.0120 0.00 < HS acceptNotes

Date:Time:

4/12/1212:11 AM

Peak rt Height1 0.52 3862 1.14 453 1.43 14 1.97 85 2.08 16 2.45 2737 3.61 18 3.63 19 4.88 1

10 4.90 1-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2 3 4 5 6 78 910

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes104 B S B120566-BLK4 2 47 0.0186 0.00 < HS acceptNotes

Date:Time:

4/12/1212:18 AM

Peak rt Height1 0.52 2762 1.07 473 2.44 2324 4.24 23

-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2 3 4

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes105 C S SEQ-CCB 2 42 0.00219 0.00 < HS acceptNotes

Date:Time:

4/12/1212:25 AM

Peak rt Height1 0.52 4592 1.10 423 2.46 2074 4.55 15

-1,300

-1,100

-900

-700

-500

-300

0 1 2 3 4 5

1 2 3 4



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes106 A S B120566-SRM1 2 75,560 248 0.00 < HS acceptNotes

Date:Time:

4/12/1212:31 AM

Peak rt Height1 0.52 4762 1.12 75,5603 2.45 6604 4.63 25 4.67 1

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3 4 5

1 2 3 45

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes107 B S 1211036-02 2 222,889 731 0.00 < HS acceptNotes

Date:Time:

4/12/1212:38 AM

Peak rt Height1 0.52 2,0652 1.11 222,8893 2.43 85,441

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes108 C S B120566-DUP1 2 218,840 718 0.00 < HS acceptNotes

Date:Time:

4/12/1212:45 AM

Peak rt Height1 0.53 1,5572 1.14 218,8403 2.45 86,829

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes109 A S B120566-MS1 2 385,586 1,260 0.00 < HS rejectNotes

Date:Time:

4/12/1212:51 AM

Peak rt Height1 0.52 2,3412 1.12 385,5863 2.46 96,504

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes110 B S B120566-MSD1 2 389,287 1,280 0.00 < HS rejectNotes

Date:Time:

4/12/1212:58 AM

Peak rt Height1 0.52 3,0092 1.11 389,2873 2.44 93,018

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes111 C CCV SEQ-CCV 2 9,217 30.1 120. 67-133 acceptNotes

Date:Time:

4/12/121:05 AM

Peak rt Height1 0.52 9392 1.14 9,2173 2.46 1,145

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes112 A CCB SEQ-CCB 2 543 1.78 1.78 < 1.4 rejectNotes

Date:Time:

4/12/121:11 AM

Peak rt Height1 0.52 1,0542 1.12 5433 2.45 400

-1,200

-1,000

-800

-600

-400

-200

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes113 B S 1214009-01 2 4,987 16.2 0.00 < HS acceptNotes

Date:Time:

4/12/121:18 AM

Peak rt Height1 0.52 1,4332 1.11 4,9873 2.43 1,631

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes114 C S 1214009-02 2 2,368 7.63 0.00 < HS acceptNotes

Date:Time:

4/12/121:25 AM

Peak rt Height1 0.52 7752 1.14 2,3683 2.45 1,588

-1,000

0

1,000

2,000

3,000

4,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes115 A S 1214009-03 2 2,293 7.39 0.00 < HS acceptNotes

Date:Time:

4/12/121:31 AM

Peak rt Height1 0.52 9102 1.12 2,2933 2.45 2,720

-1,000

0

1,000

2,000

3,000

4,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes116 B S 1214009-04 2 2,085 6.70 0.00 < HS acceptNotes

Date:Time:

4/12/121:38 AM

Peak rt Height1 0.52 1,1322 1.11 2,0853 2.43 2,711

-1,000

0

1,000

2,000

3,000

4,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes117 C CCV SEQ-CCV 2 7,142 23.3 93.2 67-133 acceptNotes

Date:Time:

4/12/121:45 AM

Peak rt Height1 0.52 7312 1.14 7,1423 2.45 231

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes118 A CCB SEQ-CCB 2 114 0.374 0.374 < 1.4 acceptNotes

Date:Time:

4/12/121:51 AM

Peak rt Height1 0.52 7572 1.13 1143 2.45 220

-1,200

-1,000

-800

-600

-400

-200

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200272

MMHG-09Instrument:

Batch # Source ID

Brooks Rand Labs

1200272-IBL1 QC 11200272 -

1200272-IBL2 QC 21200272 -

1200272-IBL3 QC 31200272 -

1200272-CAL1 QC 4 12160371200272 -

1200272-CAL2 QC 5 12160381200272 -

1200272-CAL3 QC 6 12160391200272 -

1200272-CAL4 QC 7 12160401200272 -

1200272-CAL5 QC 8 12160441200272 -

1200272-CAL6 QC 9 12160421200272 -

1200272-CAL7 QC 10 12160431200272 -

1200272-CCB1 QC 111200272 -

1200272-ICV1 QC 12 12160461200272 -

1200272-CCB2 QC 131200272 -

1200272-CCV1 QC 14 12160451200272 -

1200272-CCB3 QC 151200272 -

1200272-CCB4 QC 161200272 -

1200272-CCB5 QC 171200272 -

B120642-BLK1 QC 18B120642 -

B120642-BLK2 QC 19B120642 -

B120642-BLK3 QC 20B120642 -

B120642-BLK4 QC 21B120642 -

B120642-BS1 QC 22B120642 -

B120642-BS2 QC 23B120642 -

B120642-BS3 QC 24B120642 -

B120642-BS4 QC 25B120642 -

B120642-BS5 QC 26B120642 -

Page 1 of 6Printed: 4/19/2012 11:28:11AM

BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200272

MMHG-09Instrument:

Batch # Source ID

Brooks Rand Labs

B120642-BS6 QC 27B120642 -

1200272-CCV2 QC 28 12160451200272 -

1200272-CCB6 QC 291200272 -

B120642-BS7 QC 30B120642 -

B120642-BS8 QC 31B120642 -

B120642-BS9 QC 32B120642 -

B120642-BSA QC 33B120642 -

B120642-BSB QC 34B120642 -

B120642-BSC QC 35B120642 -

B120642-BSD QC 36B120642 -

B120642-BSE QC 37B120642 -

1200272-CCV3 QC 38 12160451200272 -

1200272-CCB7 QC 391200272 -

B120565-BLK1 QC 40B120565 -

B120565-BLK2 QC 41B120565 -

B120565-BLK3 QC 42B120565 -

B120565-BLK4 QC 43B120565 -

B120565-BS1 QC 44B120565 -

B120565-BS2 QC 45B120565 -

1212016-23RE1 MeHg-W-Dist-NoMB-TR 46 From B120524 by MSU on 04/13/12B120565 AAL-MN1101 4/10/2012



B120565-MS1 QC 49B120565 1213006-01RE1

1200272-CCV4 QC 50 12160451200272 -

1200272-CCB8 QC 511200272 -

B120565-MSD1 QC 52B120565 1213006-01RE1


BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200272

MMHG-09Instrument:

Batch # Source ID

Brooks Rand Labs




1214002-43 MeHg-W-Dist-Diss 56B120565 AEC-WE1203 4/24/2012

B120565-MS2 QC 57B120565 1214002-43

B120565-MSD2 QC 58B120565 1214002-43


1214002-50 MeHg-W-Dist-TR 60B120565 AEC-WE1203 4/24/2012


1200272-CCV5 QC 62 12160451200272 -

1200272-CCB9 QC 631200272 -











1200272-CCV6 QC 74 12160451200272 -

1200272-CCBA QC 751200272 -



1214018-01 MeHg-W-Dist-TR 78B120565 EBM-OA1001 4/26/2012


BRL Report 1212016

of 274

BRL Report 1212016

of 274


Method Number: CVAFS BR-0011Project Number(s): 1200272 Date Analyzed: 4/18/12Instrument ID: BR-09 Analyst Name: BJT

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes1 A Rins Rinse u 30 0.113 0.00 0.00 < 0.05 accept

Notes

Date:Time:

4/18/1211:04 AM

Peak rt Height1 0.52 4772 2.46 300u 1.08 30

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2u

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes2 B Rins Rinse 2 26 0.0981 0.00 0.00 < 0.05 accept

Notes

Date:Time:

4/18/1211:11 AM

Peak rt Height1 0.52 3852 1.15 263 1.41 14 2.45 168

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3 4

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes3 C Rins Rinse u 16 0.0603 0.00 0.00 < 0.05 accept

Notes

Date:Time:

4/18/1211:17 AM

Peak rt Height1 0.52 4482 1.92 13 1.94 14 2.46 1145 4.01 36 4.04 2u 1.07 16

0

200

400

600

800

1,000

0 1 2 3 4 5

1 23 4 56u



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes4 A CB SEQ-IBL 2 34 0.128 0.128 < 1.4 accept

Notes

Date:Time:

4/18/1211:24 AM

Peak rt Height1 0.52 4782 1.14 343 1.39 14 2.48 140

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3 4

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes5 B CB SEQ-IBL u 16 0.0603 0.0603 < 1.4 accept

Notes

Date:Time:

4/18/1211:31 AM

Peak rt Height1 0.52 3392 2.43 1183 3.24 1u 1.14 16

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3u

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes6 C CB SEQ-IBL 2 47 0.177 0.177 < 1.4 accept

Notes

Date:Time:

4/18/1211:37 AM

Peak rt Height1 0.52 4432 1.20 473 2.48 127

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes7 A STD SEQ-CAL1 2 156 0.466 93.3 65-135 accept

Notes

Date:Time:

4/18/1211:44 AM

Peak rt Height1 0.52 4522 1.14 1563 2.47 144

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes8 B STD SEQ-CAL2 2 304 1.02 102 65-135 accept

Notes

Date:Time:

4/18/1211:51 AM

Peak rt Height1 0.52 3062 1.12 3043 2.40 119

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes9 C STD SEQ-CAL3 2 541 1.92 95.9 65-135 accept

Notes

Date:Time:

4/18/1211:57 AM

Peak rt Height1 0.52 4392 1.15 5413 2.49 192

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes10 A STD SEQ-CAL4 2 2,504 9.32 93.2 65-135 accept

Notes

Date:Time:

4/18/1212:04 PM

Peak rt Height1 0.52 3822 1.14 2,5043 2.46 185

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes11 B STD SEQ-CAL5 2 13,753 51.7 103 65-135 accept

Notes

Date:Time:

4/18/1212:11 PM

Peak rt Height1 0.52 3252 1.12 13,7533 2.45 497

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes12 C STD SEQ-CAL6 2 69,104 260. 104 65-135 accept

Notes

Date:Time:

4/18/1212:17 PM

Peak rt Height1 0.53 5012 1.15 69,1043 2.48 1,763

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes13 A STD SEQ-CAL7 2 291,333 1,100 110. 65-135 accept

Notes

Date:Time:

4/18/1212:24 PM

Peak rt Height1 0.52 9902 1.14 291,3333 2.48 6,194

0

100,000

200,000

300,000

400,000

500,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/1212:31 PM

Peak rt Height1 0.52 3332 1.12 2113 2.44 80

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes15 C ICV SEQ-ICV 2 29,163 110. 110. 80-120 accept

Notes

Date:Time:

4/18/1212:37 PM

Peak rt Height1 0.52 5012 1.15 29,1633 2.47 993

0

20,000

40,000

60,000

80,000

100,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/18/1212:44 PM

Peak rt Height1 0.52 6432 1.14 3593 2.48 136

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/1212:51 PM

Peak rt Height1 0.53 3242 1.12 6,3563 2.45 296

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/1212:57 PM

Peak rt Height1 0.52 4682 1.16 1113 2.43 104

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/18/121:04 PM

Peak rt Height1 0.52 5312 1.12 793 2.50 101

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/121:11 PM

Peak rt Height1 0.52 2572 1.12 523 2.46 294

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/121:17 PM

Peak rt Height1 0.52 4302 1.12 963 2.48 347

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/18/121:24 PM

Peak rt Height1 0.52 5282 1.16 793 2.47 374

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/121:31 PM

Peak rt Height1 0.52 2792 1.12 763 2.45 194

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/121:37 PM

Peak rt Height1 0.52 4162 1.16 983 2.47 858

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/18/121:44 PM

Peak rt Height1 0.52 4792 1.13 3523 2.46 326

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/121:51 PM

Peak rt Height1 0.52 2762 1.12 3883 2.45 618

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/121:57 PM

Peak rt Height1 0.52 4202 1.15 3453 2.47 589

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/18/122:04 PM

Peak rt Height1 0.52 4502 1.14 3643 2.48 423

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/122:11 PM

Peak rt Height1 0.52 3242 1.12 4433 2.46 2,620

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/122:17 PM

Peak rt Height1 0.52 4042 1.15 3023 2.47 585

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes31 A CCV SEQ-CCV 2 6,910 25.9 104 67-133 accept

Notes

Date:Time:

4/18/122:24 PM

Peak rt Height1 0.52 4682 1.14 6,9103 2.48 332

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes32 B CCB SEQ-CCB u 23 0.0867 0.0867 < 1.4 accept

Notes

Date:Time:

4/18/122:31 PM

Peak rt Height1 0.53 2672 2.44 163u 1.10 23

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2u


Notes

Date:Time:

4/18/122:37 PM

Peak rt Height1 0.52 3982 1.15 3583 2.48 580

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/18/122:44 PM

Peak rt Height1 0.52 4462 1.14 4263 2.48 958

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/122:51 PM

Peak rt Height1 0.52 2532 1.12 2,3843 2.46 3624 4.62 15 4.64 1

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3 4 5

1 2 3 45

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes36 C S B120642-BSA 2 315 1.07 0.00 < HS accept

Notes

Date:Time:

4/18/122:57 PM

Peak rt Height1 0.52 4292 1.15 3153 1.75 24 1.78 15 2.48 6546 4.57 17 4.60 2

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 34 5 67



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes37 A S B120642-BSB 2 621 2.22 0.00 < HS accept

Notes

Date:Time:

4/18/123:04 PM

Peak rt Height1 0.52 4452 1.14 6213 2.48 570

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes38 B S B120642-BSC 2 576 2.05 0.00 < HS accept

Notes

Date:Time:

4/18/123:11 PM

Peak rt Height1 0.52 2632 1.13 5763 2.47 315

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes39 C S B120642-BSD 2 659 2.36 0.00 < HS accept

Notes

Date:Time:

4/18/123:17 PM

Peak rt Height1 0.52 3692 1.15 6593 2.48 286

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes40 A S B120642-BSE 2 698 2.51 0.00 < HS accept

Notes

Date:Time:

4/18/123:24 PM

Peak rt Height1 0.52 4322 1.14 6983 2.48 626

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes41 B CCV SEQ-CCV 2 6,693 25.1 100. 67-133 accept

Notes

Date:Time:

4/18/123:31 PM

Peak rt Height1 0.52 2862 1.13 6,6933 2.46 406

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/123:37 PM

Peak rt Height1 0.52 3672 1.16 463 2.48 172

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/18/123:44 PM

Peak rt Height1 0.52 4452 1.13 473 2.48 245

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes44 B S B120565-BLK2 2 25 -0.0277 0.00 < HS accept

Notes

Date:Time:

4/18/123:51 PM

Peak rt Height1 0.52 2642 1.12 253 2.46 422

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/123:57 PM

Peak rt Height1 0.52 3602 1.14 743 2.48 335

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/18/124:04 PM

Peak rt Height1 0.52 3872 1.13 733 2.48 3544 3.45 38

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3 4


Notes

Date:Time:

4/18/124:11 PM

Peak rt Height1 0.53 2912 1.13 5,4913 2.46 1,315

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes48 C S B120565-BS2 2 5,538 20.8 0.00 < HS accept

Notes

Date:Time:

4/18/124:17 PM

Peak rt Height1 0.52 3662 1.15 5,5383 2.50 383

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes49 A S 1212016-23RE1 2 391 1.35 0.00 < HS accept

Notes

Date:Time:

4/18/124:24 PM

Peak rt Height1 0.52 3782 1.14 3913 2.49 435

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes50 B S 1212016-25RE1 2 528 1.87 0.00 < HS accept

Notes

Date:Time:

4/18/124:31 PM

Peak rt Height1 0.53 3012 1.13 5283 1.65 294 2.47 2,087

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3 4

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes51 C S 1213006-01RE1 2 166 0.504 0.00 < HS accept

Notes

Date:Time:

4/18/124:37 PM

Peak rt Height1 0.52 3482 1.15 1663 2.48 393

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes52 A S B120565-MS1 2 1,769 6.55 0.00 < HS accept

Notes

Date:Time:

4/18/124:44 PM

Peak rt Height1 0.52 3992 1.14 1,7693 2.48 622

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/124:51 PM

Peak rt Height1 0.52 2632 1.13 6,5673 2.46 332

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/124:57 PM

Peak rt Height1 0.53 3662 1.16 483 2.45 111

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/18/125:04 PM

Peak rt Height1 0.52 3892 1.14 1,6983 2.49 559

0

1,000

2,000

3,000

4,000

5,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes56 B S 1213006-03RE1 2 167 0.508 0.00 < HS accept

Notes

Date:Time:

4/18/125:11 PM

Peak rt Height1 0.53 2292 1.12 1673 2.46 693

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes57 C S 1213006-05RE1 2 157 0.470 0.00 < HS accept

Notes

Date:Time:

4/18/125:17 PM

Peak rt Height1 0.52 3422 1.15 1573 2.48 417

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274



Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes58 A S 1213006-07RE1 2 255 0.840 0.00 < HS accept

Notes

Date:Time:

4/18/125:24 PM

Peak rt Height1 0.52 3492 1.13 2553 2.48 569

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/125:31 PM

Peak rt Height1 0.53 2542 1.11 1213 2.45 344

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes60 C S B120565-MS2 2 6,381 23.9 0.00 < HS accept

Notes

Date:Time:

4/18/125:37 PM

Peak rt Height1 0.52 3322 1.15 6,3813 2.48 577

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/18/125:44 PM

Peak rt Height1 0.52 3492 1.14 6,1073 2.48 519

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/125:51 PM

Peak rt Height1 0.52 2072 0.85 13 1.13 854 2.46 506

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3 4


Notes

Date:Time:

4/18/125:57 PM

Peak rt Height1 0.52 3202 1.15 1863 2.48 593

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3



BRL Report 1212016

of 274




Notes

Date:Time:

4/18/126:04 PM

Peak rt Height1 0.52 3372 1.13 843 2.48 371

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3

Run Trap Type Name/ID M B Peak Peak Height Analyzed Result Final Result QA Results Criteria Notes65 B CCV SEQ-CCV 2 6,701 25.1 101 67-133 accept

Notes

Date:Time:

4/18/126:11 PM

Peak rt Height1 0.52 2362 1.12 6,7013 2.45 326

0

5,000

10,000

15,000

20,000

25,000

0 1 2 3 4 5

1 2 3


Notes

Date:Time:

4/18/126:17 PM

Peak rt Height1 0.52 3272 1.14 333 2.48 1304 4.80 28

0

200

400

600

800

1,000

0 1 2 3 4 5

1 2 3 4



BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200243

ICP-MS-2Instrument:

Batch # Source ID

Brooks Rand Labs

1200243-ICB1 QC 11200243 -

1200243-CAL1 QC 2 12120781200243 -

1200243-CAL2 QC 3 12120791200243 -

1200243-CAL3 QC 4 12120801200243 -

1200243-CAL4 QC 5 12120811200243 -

1200243-CAL5 QC 6 12120821200243 -

1200243-CAL6 QC 7 12120831200243 -

1200243-CAL7 QC 8 12120841200243 -

1200243-CAL8 QC 9 12120851200243 -

1200243-ICB2 QC 101200243 -

1200243-ICV1 QC 11 12020021200243 -

1200243-ICB3 QC 121200243 -

1200243-IBL1 QC 131200243 -

1200243-IBL2 QC 141200243 -

1200243-IBL3 QC 151200243 -

1200243-IBL4 QC 161200243 -

1200243-SCV1 QC 17 11340311200243 -

1200243-CCV1 QC 18 12120811200243 -

1200243-CCB1 QC 191200243 -

B120485-BLK1 QC 20B120485 -

B120485-BLK2 QC 21B120485 -

B120485-BLK3 QC 22B120485 -

B120485-BLK4 QC 23B120485 -

B120485-BS1 QC 24B120485 -

B120485-SRM1 QC 25B120485 -

B120485-SRM2 QC 26B120485 -


BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200243

ICP-MS-2Instrument:

Batch # Source ID

Brooks Rand Labs

B120485-SRM3 QC 27B120485 -

1200243-CCV2 QC 28 12120811200243 -

1200243-CCB2 QC 291200243 -

1211036-01 As-S-RARBomb-DRC 30B120485 ACF-SH1201 4/4/2012

1211036-01 Se-S-RARBomb-DRC 31B120485 ACF-SH1201 4/4/2012

B120485-DUP1 QC 32B120485 1211036-01

B120485-MS1 QC 33B120485 1211036-01

B120485-MSD1 QC 34B120485 1211036-01

1200243-CCV3 QC 35 12120811200243 -

1200243-CCB3 QC 361200243 -

B120537-BLK1 QC 37B120537 -

B120537-BLK2 QC 38B120537 -

B120537-BLK3 QC 39B120537 -

B120537-BLK4 QC 40B120537 -

B120537-BS1 QC 41B120537 -

B120537-SRM1 QC 42B120537 -

1212016-21 Se-FW-Oven-DRC-NoMB-TR 43B120537 AAL-MN1101 4/10/2012

1212016-22 Se-FW-Oven-DRC-NoMB-Diss 44B120537 AAL-MN1101 4/10/2012



1200243-CCV4 QC 47 12120811200243 -

1200243-CCB4 QC 481200243 -




1212016-05 Se-FW-Oven-DRC-NoMB-Diss 52 BatchQCB120537 AAL-MN1101 1/1/1980


BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200243

ICP-MS-2Instrument:

Batch # Source ID

Brooks Rand Labs

B120537-DUP1 QC 53B120537 1212016-05

B120537-MS1 QC 54B120537 1212016-05

B120537-MSD1 QC 55B120537 1212016-05



1200243-CCV5 QC 58 12120811200243 -

1200243-CCB5 QC 591200243 -




B120537-DUP2 QC 63B120537 1212016-09

B120537-MS2 QC 64B120537 1212016-09

B120537-MSD2 QC 65B120537 1212016-09






1200243-CCV6 QC 71 12120811200243 -

1200243-CCB6 QC 721200243 -








BRL Report 1212016

of 274

ANALYSIS SEQUENCE


1200243

ICP-MS-2Instrument:

Batch # Source ID

Brooks Rand Labs

B120537-DUP3 QC 79B120537 1212016-19

B120537-MS3 QC 80B120537 1212016-19

B120537-MSD3 QC 81B120537 1212016-19

1200243-CCV7 QC 82 12120811200243 -

1200243-CCB7 QC 831200243 -








1200243-CCV8 QC 91 12120821200243 -

1200243-CCB8 QC 921200243 -











1200243-CCV9 QC 103 12120821200243 -

1200243-CCB9 QC 1041200243 -


BRL Report 1212016

of 274

BRL Report 1212016

of 274

Sample InformationReport Title: QUANTITATIVE ANALYSIS REPORT Batch ID: Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002 Tuning File: C:\Elandata\Tuning\Default.tun Optimization File: C:\Elandata\Optimize\Default.dac Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Calibration Type: External Calibration

Calibration Analyte MassCurve Type Slope Intercept Correlation Coefficient Std 1 Conc AsO 91Weighted Linear 0.004 -0.000 0.999232 0.025000 Se 78Weighted Linear 0.000 -0.000 0.999674 0.050000 Se 77Weighted Linear 0.000 -0.000 0.998008 0.050000> Rh 103Weighted Linear Br 79Weighted Linear Cl 35Weighted Linear C 13Weighted Linear

BRL Report 1212016

of 274

Sample ID: SEQ-ICB1 Report Date/Time: Friday, April 06, 2012 12:27:33

Quantitative Analysis - Brooks Rand Labs ICP-MS Summary Report

Sample ID: SEQ-ICB1 Sample Description: Batch ID: Sample Date/Time: Thursday, April 05, 2012 17:07:39 Diluted To Volume (mL): Aliquot Volume (mL): Autosampler Position: 1 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002

Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 2 20.4 ug/L Se 78 5 2 36.1 ug/L Se 77 2 1 31.2 ug/L>>>> Rh 103 398528 4323 1.1 ug/L Br 79 3 1 43.3 ug/L Cl 35 278 26 9.5 ug/L C 13 1493 46 3.1 ug/L

Int Std % Recovery Analyte Mass Int Std % Recovery AsO 91 Se 78 Se 77> Rh 103 Br 79 Cl 35 C 13

BRL Report 1212016

of 274

Sample ID: SEQ-CAL1 Report Date/Time: Friday, April 06, 2012 12:27:35


Sample ID: SEQ-CAL1 Sample Description: Batch ID: Sample Date/Time: Thursday, April 05, 2012 17:09:07 Diluted To Volume (mL): Aliquot Volume (mL): Autosampler Position: 2 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-CAL1.003 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002

Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 46 2 5.1 0.000088 0.0242 ug/L Se 78 5 11 1 13.2 0.000015 0.0491 ug/L Se 77 2 3 1 34.6 0.000005 0.0469 ug/L>>>> Rh 103 398528 391532 5558 1.4 391531.585266 ug/L Br 79 3 7 3 43.3 3.333336 ug/L Cl 35 278 276 24 8.8 -2.500095 ug/L C 13 1493 1464 15 1.0 -28.338860 ug/L


BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 96 2 1.6 0.000215 0.0536 ug/L Se 78 5 19 2 12.3 0.000037 0.1045 ug/L Se 77 2 7 1 17.6 0.000012 0.1131 ug/L>>>> Rh 103 398528 393052 2018 0.5 393051.835812 ug/L Br 79 3 2 1 86.6 -1.666667 ug/L Cl 35 278 266 6 2.4 -12.500471 ug/L C 13 1493 1521 53 3.5 28.338917 ug/L


BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 410 27 6.5 0.001023 0.2412 ug/L Se 78 5 41 1 2.0 0.000092 0.2451 ug/L Se 77 2 13 2 14.1 0.000028 0.2460 ug/L>>>> Rh 103 398528 390298 1792 0.5 390298.449467 ug/L Br 79 3 0 0 -3.333334 ug/L Cl 35 278 265 18 6.6 -13.333821 ug/L C 13 1493 1533 73 4.8 40.841507 ug/L


BRL Report 1212016

of 274






BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 8530 130 1.5 0.021999 5.1119 ug/L Se 78 5 780 9 1.1 0.002002 5.1055 ug/L Se 77 2 231 6 2.7 0.000591 5.0171 ug/L>>>> Rh 103 398528 387238 2410 0.6 387237.878237 ug/L Br 79 3 6 1 24.7 2.500001 ug/L Cl 35 278 282 34 12.2 3.333476 ug/L C 13 1493 1439 70 4.9 -53.343376 ug/L


BRL Report 1212016

of 274






BRL Report 1212016

of 274





Int Std % Recovery Analyte Mass Int Std % Recovery AsO 91 Se 78 Se 77> Rh 103 98.074 Br 79 Cl 35 C 13

BRL Report 1212016

of 274

Sample ID: SEQ-ICV1 Report Date/Time: Friday, April 06, 2012 12:27:58


Sample ID: SEQ-ICV1 Sample Description: Batch ID: Sample Date/Time: Thursday, April 05, 2012 17:22:48 Diluted To Volume (mL): Aliquot Volume (mL): Autosampler Position: 10 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICV1.012 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002

Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 8795 250 2.8 0.021991 5.1100 ug/L Se 78 5 1621 21 1.3 0.004047 10.3082 ug/L Se 77 2 481 10 2.1 0.001201 10.1833 ug/L>>>> Rh 103 398528 399388 4643 1.2 399388.401925 ug/L Br 79 3 2 3 173.2 -1.666667 ug/L Cl 35 278 288 26 9.2 9.167003 ug/L C 13 1493 1507 90 5.9 14.169686 ug/L


BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 18 6 31.2 0.000017 0.0077 ug/L Se 78 5 7 1 12.5 0.000006 0.0265 ug/L Se 77 2 2 0 6.9 0.000001 0.0186 ug/L>>>> Rh 103 398528 387159 3903 1.0 387158.578003 ug/L Br 79 3 1 1 173.2 -2.500001 ug/L Cl 35 278 268 11 4.2 -10.000380 ug/L C 13 1493 1458 48 3.3 -35.006702 ug/L


BRL Report 1212016

of 274

Sample ID: SEQ-IBL1 Report Date/Time: Friday, April 06, 2012 12:28:03


Sample ID: SEQ-IBL1 Sample Description: Batch ID: Sample Date/Time: Thursday, April 05, 2012 17:27:58 Diluted To Volume (mL): Aliquot Volume (mL): Autosampler Position: 101 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-IBL1.014 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002



BRL Report 1212016

of 274






BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 11 3 28.6 -0.000001 0.0035 ug/L Se 78 5 7 1 21.8 0.000005 0.0250 ug/L Se 77 2 3 1 18.4 0.000003 0.0352 ug/L>>>> Rh 103 398528 385614 3229 0.8 385613.609464 ug/L Br 79 3 6 4 65.5 2.500002 ug/L Cl 35 278 267 31 11.8 -11.667068 ug/L C 13 1493 1481 30 2.0 -11.668974 ug/L


BRL Report 1212016

of 274

Sample ID: SEQ-SCV1 Report Date/Time: Friday, April 06, 2012 12:28:13


Sample ID: SEQ-SCV1 Sample Description: 5x Batch ID: Sample Date/Time: Thursday, April 05, 2012 17:33:52 Diluted To Volume (mL): 5.00 Aliquot Volume (mL): 1 Autosampler Position: 105 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-SCV1.018 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002



BRL Report 1212016

of 274

Sample ID: SEQ-CCV1 Report Date/Time: Friday, April 06, 2012 12:28:16


Sample ID: SEQ-CCV1 Sample Description: Batch ID: Sample Date/Time: Thursday, April 05, 2012 17:38:44 Diluted To Volume (mL): Aliquot Volume (mL): Autosampler Position: 5 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-CCV1.019 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002



BRL Report 1212016

of 274

Sample ID: SEQ-CCB1 Report Date/Time: Friday, April 06, 2012 12:28:18


Sample ID: SEQ-CCB1 Sample Description: Batch ID: Sample Date/Time: Thursday, April 05, 2012 17:40:13 Diluted To Volume (mL): Aliquot Volume (mL): Autosampler Position: 1 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-CCB1.020 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002

Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 14 3 18.9 0.000008 0.0055 ug/L Se 78 5 7 1 14.4 0.000005 0.0247 ug/L Se 77 2 2 1 33.3 0.000002 0.0257 ug/L>>>> Rh 103 398528 389014 2686 0.7 389014.284380 ug/L Br 79 3 3 1 43.3 -0.000000 ug/L Cl 35 278 273 16 5.7 -5.833562 ug/L C 13 1493 1508 33 2.2 15.836377 ug/L


BRL Report 1212016

of 274

Sample ID: B120485-BLK1 Report Date/Time: Friday, April 06, 2012 12:28:21


Sample ID: B120485-BLK1 Sample Description: 50x Batch ID: B120485 Sample Date/Time: Thursday, April 05, 2012 17:41:43 Diluted To Volume (mL): 5.00 Aliquot Volume (mL): 0.1 Autosampler Position: 106 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\B120485-BLK1.021 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002

Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 8 2 21.7 -0.000007 0.1014 ug/L Se 78 5 7 1 17.0 0.000006 1.3014 ug/L Se 77 2 4 2 52.8 0.000005 2.6562 ug/L>>>> Rh 103 398528 377606 3375 0.9 377605.689269 ug/L Br 79 3 8 4 45.8 5.000004 ug/L Cl 35 278 341 53 15.7 62.502609 ug/L C 13 1493 1403 22 1.5 -89.183524 ug/L


BRL Report 1212016

of 274






BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 4 1 26.6 -0.000017 -0.0088 ug/L Se 78 5 7 1 8.0 0.000007 1.4606 ug/L Se 77 2 3 1 16.4 0.000004 2.2699 ug/L>>>> Rh 103 398528 370004 4155 1.1 370003.719634 ug/L Br 79 3 10 3 25.0 6.666673 ug/L Cl 35 278 308 8 2.5 30.001116 ug/L C 13 1493 1355 58 4.3 -137.525396 ug/L


BRL Report 1212016

of 274

Sample ID: B120485-BS1 Report Date/Time: Friday, April 06, 2012 12:28:31


Sample ID: B120485-BS1 Sample Description: 50x Batch ID: B120485 Sample Date/Time: Thursday, April 05, 2012 17:47:37 Diluted To Volume (mL): 5.00 Aliquot Volume (mL): 0.1 Autosampler Position: 110 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\B120485-BS1.025 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002



BRL Report 1212016

of 274

Sample ID: B120485-SRM1 Report Date/Time: Friday, April 06, 2012 12:28:33


Sample ID: B120485-SRM1 Sample Description: 50x Batch ID: B120485 Sample Date/Time: Thursday, April 05, 2012 17:49:06 Diluted To Volume (mL): 5.00 Aliquot Volume (mL): 0.1 Autosampler Position: 111 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\B120485-SRM1.026 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002



BRL Report 1212016

of 274






BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 11 8 72.2 0.000001 0.0039 ug/L Se 78 5 4 1 26.7 -0.000002 0.0052 ug/L Se 77 2 2 1 43.3 0.000002 0.0253 ug/L>>>> Rh 103 398528 378030 1434 0.4 378030.430960 ug/L Br 79 3 8 3 33.3 4.166670 ug/L Cl 35 278 248 8 3.2 -30.001055 ug/L C 13 1493 1448 50 3.5 -45.008583 ug/L


BRL Report 1212016

of 274

Sample ID: 1211036-01 Report Date/Time: Friday, April 06, 2012 12:28:46


Sample ID: 1211036-01 Sample Description: 50x Batch ID: B120485 Sample Date/Time: Thursday, April 05, 2012 17:56:31 Diluted To Volume (mL): 5.00 Aliquot Volume (mL): 0.1 Autosampler Position: 114 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\1211036-01.031 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002



BRL Report 1212016

of 274

Sample ID: B120485-DUP1 Report Date/Time: Friday, April 06, 2012 12:28:49


Sample ID: B120485-DUP1 Sample Description: 50x Batch ID: B120485 Sample Date/Time: Thursday, April 05, 2012 17:58:00 Diluted To Volume (mL): 5.00 Aliquot Volume (mL): 0.1 Autosampler Position: 115 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\B120485-DUP1.032 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002



BRL Report 1212016

of 274

Sample ID: B120485-MS1 Report Date/Time: Friday, April 06, 2012 12:28:51


Sample ID: B120485-MS1 Sample Description: 50x Batch ID: B120485 Sample Date/Time: Thursday, April 05, 2012 17:59:28 Diluted To Volume (mL): 5.00 Aliquot Volume (mL): 0.1 Autosampler Position: 116 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\B120485-MS1.033 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002



BRL Report 1212016

of 274

Sample ID: B120485-MSD1 Report Date/Time: Friday, April 06, 2012 12:28:54


Sample ID: B120485-MSD1 Sample Description: 50x Batch ID: B120485 Sample Date/Time: Thursday, April 05, 2012 18:00:57 Diluted To Volume (mL): 5.00 Aliquot Volume (mL): 0.1 Autosampler Position: 117 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\B120485-MSD1.034 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002



BRL Report 1212016

of 274






BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 13 5 35.3 0.000007 0.0052 ug/L Se 78 5 5 1 15.9 0.000002 0.0151 ug/L Se 77 2 2 1 45.4 0.000001 0.0205 ug/L>>>> Rh 103 398528 372498 9667 2.6 372497.950297 ug/L Br 79 3 7 4 57.3 3.333336 ug/L Cl 35 278 253 24 9.5 -25.000869 ug/L C 13 1493 1501 40 2.7 8.334934 ug/L


BRL Report 1212016

of 274



Sample ID: B120537-BLK1 Sample Description: Batch ID: B120537 Sample Date/Time: Thursday, April 05, 2012 18:05:27 Diluted To Volume (mL): Aliquot Volume (mL): Autosampler Position: 201 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\B120537-BLK1.037 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002

Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 7 1 8.7 -0.000011 0.0012 ug/L Se 78 5 4 1 15.3 -0.000000 0.0101 ug/L Se 77 2 2 1 44.1 -0.000000 0.0065 ug/L>>>> Rh 103 398528 379677 1857 0.5 379677.016211 ug/L Br 79 3 0 0 -3.333334 ug/L Cl 35 278 268 27 10.0 -10.000354 ug/L C 13 1493 1550 45 2.9 57.511370 ug/L


BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 5 3 52.9 -0.000015 0.0002 ug/L Se 78 5 4 1 32.2 -0.000001 0.0089 ug/L Se 77 2 3 2 62.2 0.000003 0.0304 ug/L>>>> Rh 103 398528 380814 204 0.1 380813.543342 ug/L Br 79 3 3 3 100.0 -0.833333 ug/L Cl 35 278 282 26 9.3 3.333454 ug/L C 13 1493 1514 27 1.8 21.670842 ug/L


BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 8 2 30.1 -0.000008 0.0018 ug/L Se 78 5 4 0 10.6 -0.000003 0.0046 ug/L Se 77 2 2 1 50.9 0.000002 0.0232 ug/L>>>> Rh 103 398528 378828 2151 0.6 378828.388241 ug/L Br 79 3 3 0 0.0 -0.833334 ug/L Cl 35 278 240 5 2.1 -38.334654 ug/L C 13 1493 1469 122 8.3 -23.337277 ug/L


BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 8 4 50.0 -0.000007 0.0020 ug/L Se 78 5 5 1 13.4 0.000000 0.0123 ug/L Se 77 2 2 1 28.4 0.000001 0.0139 ug/L>>>> Rh 103 398528 379763 1771 0.5 379762.750677 ug/L Br 79 3 2 1 86.6 -1.666667 ug/L Cl 35 278 237 9 3.7 -41.668089 ug/L C 13 1493 1486 31 2.1 -6.668008 ug/L


BRL Report 1212016

of 274

Sample ID: B120537-BS1 Report Date/Time: Friday, April 06, 2012 12:29:11


Sample ID: B120537-BS1 Sample Description: Batch ID: B120537 Sample Date/Time: Thursday, April 05, 2012 18:11:21 Diluted To Volume (mL): Aliquot Volume (mL): Autosampler Position: 205 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\B120537-BS1.041 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002



BRL Report 1212016

of 274



Sample ID: 1212016-21 Sample Description: Batch ID: B120537 Sample Date/Time: Thursday, April 05, 2012 18:12:49 Diluted To Volume (mL): Aliquot Volume (mL): Autosampler Position: 206 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\1212016-21.042 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002

Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 12 2 17.8 0.000002 0.0042 ug/L Se 78 5 4 1 21.7 -0.000001 0.0086 ug/L Se 77 2 2 1 56.8 0.000001 0.0133 ug/L>>>> Rh 103 398528 384740 1985 0.5 384739.503245 ug/L Br 79 3 6 1 24.7 2.500001 ug/L Cl 35 278 234 23 9.7 -44.168146 ug/L C 13 1493 1520 23 1.5 27.505317 ug/L


BRL Report 1212016

of 274



Sample ID: 1212016-22 Sample Description: Batch ID: B120537 Sample Date/Time: Thursday, April 05, 2012 18:14:18 Diluted To Volume (mL): Aliquot Volume (mL): Autosampler Position: 207 Sample File: C:\Elandata\Sample\2012\4-12\1200243.sam Method File: C:\Elandata\Method\2012\4-12\1200243-0062-ICPMS2-mel.mth Dataset File: C:\Elandata\DataSet\Data\2012\4-12\1200243\1212016-22.043 Calibration File: C:\Elandata\System\2012\4-12\1200243.cal Blank File: C:\Elandata\DataSet\Data\2012\4-12\1200243\SEQ-ICB1.002

Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 8 3 33.1 -0.000008 0.0019 ug/L Se 78 5 4 2 51.4 -0.000001 0.0075 ug/L Se 77 2 2 1 57.1 0.000000 0.0114 ug/L>>>> Rh 103 398528 385103 1840 0.5 385102.834988 ug/L Br 79 3 3 3 100.0 -0.833333 ug/L Cl 35 278 248 18 7.1 -30.834404 ug/L C 13 1493 1507 39 2.6 14.169403 ug/L


BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 65 3 4.4 0.000163 2.0785 ug/L Se 78 5 6 0 5.7 0.000004 1.0781 ug/L Se 77 2 2 1 48.3 0.000003 1.5373 ug/L>>>> Rh 103 398528 341272 3502 1.0 341272.389490 ug/L Br 79 3 1344 122 9.1 1340.951428 ug/L Cl 35 278 294 15 5.1 15.833902 ug/L C 13 1493 1563 109 7.0 70.847826 ug/L


BRL Report 1212016

of 274






BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 9 1 6.7 -0.000007 0.0021 ug/L Se 78 5 3 1 23.0 -0.000004 0.0008 ug/L Se 77 2 2 1 28.6 0.000000 0.0094 ug/L>>>> Rh 103 398528 406098 3029 0.7 406097.509894 ug/L Br 79 3 15 11 76.4 11.666686 ug/L Cl 35 278 295 33 11.1 16.667304 ug/L C 13 1493 1740 54 3.1 247.552047 ug/L


BRL Report 1212016

of 274






BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 11 2 19.5 -0.000003 0.0031 ug/L Se 78 5 4 1 13.3 -0.000002 0.0065 ug/L Se 77 2 1 1 48.0 -0.000002 -0.0049 ug/L>>>> Rh 103 398528 414362 1356 0.3 414361.758092 ug/L Br 79 3 13 1 10.8 10.000011 ug/L Cl 35 278 306 43 14.1 27.501094 ug/L C 13 1493 1655 76 4.6 162.533412 ug/L


BRL Report 1212016

of 274






BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 39 7 17.2 0.000077 1.0787 ug/L Se 78 5 4 1 36.0 -0.000002 0.3547 ug/L Se 77 2 2 1 37.8 0.000001 0.6673 ug/L>>>> Rh 103 398528 366688 2996 0.8 366688.494003 ug/L Br 79 3 1545 84 5.4 1541.822141 ug/L Cl 35 278 356 38 10.7 77.503227 ug/L C 13 1493 1765 120 6.8 272.558237 ug/L


BRL Report 1212016

of 274






BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 9 2 24.0 -0.000008 0.0018 ug/L Se 78 5 5 0 3.4 -0.000002 0.0074 ug/L Se 77 2 2 1 38.5 0.000001 0.0170 ug/L>>>> Rh 103 398528 432832 1549 0.4 432831.685815 ug/L Br 79 3 19 5 27.2 15.833358 ug/L Cl 35 278 303 9 2.9 24.167552 ug/L C 13 1493 1867 44 2.4 374.248371 ug/L


BRL Report 1212016

of 274






BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 12 2 16.7 -0.000002 0.0033 ug/L Se 78 5 4 1 20.0 -0.000002 0.0052 ug/L Se 77 2 1 1 47.2 -0.000001 -0.0018 ug/L>>>> Rh 103 398528 446813 3419 0.8 446813.467576 ug/L Br 79 3 18 9 51.5 14.166689 ug/L Cl 35 278 301 19 6.3 22.500832 ug/L C 13 1493 1901 124 6.5 408.423990 ug/L


BRL Report 1212016

of 274




Concentration Results Analyte Mass Blank Int Mean Meas Int Mean Meas Int SD Meas Int RSD Net Int Mean Conc Mean Sample Unit AsO 91 11 15 4 27.6 0.000004 0.1881 ug/L Se 78 5 4 0 9.5 -0.000003 0.1267 ug/L Se 77 2 1 0 20.4 -0.000001 -0.0094 ug/L>>>> Rh 103 398528 447871 5572 1.2 447870.634921 ug/L Br 79 3 13 4 28.6 10.000011 ug/L Cl 35 278 328 35 10.8 49.168626 ug/L C 13 1493 1842 83 4.5 349.242560 ug/L


BRL Report 1212016

of 274

newtowncreek.infonewtowncreek.info/docs2/2 remedial investigation... · 3958 6th ave. nw seattle wa...

Documents