recyclable packaging with excellent packaging integrity ... · regeneration recyclable packaging...

1
Regeneration Recyclable packaging with excellent packaging integrity, puncture energy and optics Full PE laminated solution to replace multi-material laminates • Improve mechanical recyclability • Qualified to use How2Recycle ® label Substrate: OPET, OPP, OPA Adhesive + printing Sealant layer: Coex PE Substrate: Coex PE Adhesive + printing Sealant layer: Coex PE Store drop-off program in the U.S.A Note: Label is applicable in the U.S.A.; for illustrative purposes only. MDO (machine direction orientation) Technology • MDO is a process by which a film is oriented in machine direction. There are typically 4 steps involved: • Pre-heating • Stretching • Annealing • Cooling • Orientation can be made in line with the film making or off-line MDO PE substrate vs. other substrates • MDO PE substrate solution using Enable 4002 performance polymers • Excellent optics • Similar haze/gloss properties to BOPP/BOPA Up to 50% haze increase vs. formulation with HDPE in the skin Up to 67% haze increase vs. non-MDO PE substrate • Great modulus Up to 28% downgauge vs. non-MDO PE substrate • Both flexo and rotogravure printability *MDO PE (Enable) with Enable 4002 in the skin (MDO ratio 4.8) and MDO PE (HDPE) with HDPE in the skin (MDO ratio 6); HDPE (0.961d, 0.7 MI) **All data from tests performed by or on behalf of ExxonMobil Gloss (GU) Absolute modulus, MD (N/mm) Haze (%) 160 120 80 40 0 20 0 10 20 30 40 50 60 15 10 5 0 BOPET (12 μm) Non-MDO PE (35 μm) MDO PE (Enable, 25 μm) MDO PE (HDPE, 20 μm) BOPP (20 μm) BOPA (15 μm) MDO PE (5L) /PE solution for SUPs 5L MDO PE substrate solution using Enable 4002 performance polymers • Exceptional optics with stretch ratio 4.6 • Excellent MD modulus (similar to BOPA/BOPP) • Great processability ( high bubble stability; Easy separation) 5L MDO PE/ PE solution using Exceed XP 8784, Exceed 1012 and Enable 4002 performance polymers • Excellent bag drop performance • Great puncture energy • Exceptional tensile strength MD Bag-drop non- breakage [0-100%] Bending stiffness average [0- 150mN.mm] Haze of Substrate [25-0%] MD Modulus of Substrate [0- 60N/mm] Dart impact [0- 2000g] Puncture energy [0- 12mJ] Tensile strength MD [0-100N] * HDPE could be added to the inner skin for heat resistance in slide 53 ** Packaging performance depends on equipment and end-user requirements *** All data from tests performed by or on behalf of ExxonMobil C8-LLDPE (0.92d, 1.0MI); C8-mLLDPE (0.916d, 1MI); HDPE (0.961d, 0.7 MI) In entire package for all solutions unit of density is g/cc and unit for MI is g/10min Substrate Sealant Enable 4002 / HDPE / Exceed XP 8656 / HDPE/ Enable 4002* (1/1/2/1/1, MDO 4.6, 25 μm) Exceed XP 8784 / Exceed XP 8784+ 30% HDPE / Exceed 1012 (1/2/1, 120 μm) BOPA ( 15 μm ) C8-mLLDPE / C8-LLDPE + 25% HDPE / C8-mLLDPE (1/2/1, 120 μm) BOPET ( 12 μm ) MDO PE (5L) /PE solution for SUPs Bag-drop non-breakage rate (%) Puncture energy (mJ) Tensile strength MD (N) Bending stiffness average (mN.mm) Dart impact (N) Haze of substrate (%) MD Modulus of substrate (%) *All data from tests performed by or on behalf of ExxonMobil up to 100% Bag drop non-breakage rate up to 1.7x Puncture energy vs. BOPET/PE up to 1.2x Tensile strength vs. BOPET/PE BOPET/PE BOPA/PE PE/PE 0N/mm 10N/mm 20N/mm 30N/mm 40N/mm 50N/mm 60N/mm 0mJ 2mJ 4mJ 6mJ 8mJ 10mJ 12mJ 0N 20N 40N 60N 80N 100N 0mN.mm 30mN.mm 60mN.mm 90mN.mm 120mN.mm 150mN.mm 0g 400g 800g 1200g 1600g 2000g 0% 5% 10% 15% 20% 25% 0% 20% 40% 60% 80% 100% Sealing properties MDO PE/PE solution using Exceed XP, Exceed 1012 and Enable performance polymers can offer: • Great seal strength • Excellent sealing initiation temperature • High hot tack force • Narrow sealing widow compared to BOPET/PE or BOPA/PE due to low heat resistance of PE film itself 0 20 40 60 80 100 120 140 160 Seal strength curve ** T (ºC) F (N/15mm) **Seal strength may be affected by bond strength 0 5 10 15 20 25 80 100 120 140 160 Hot tack curve *** F N/30mm) ***Film shrink and melt observed starting at 125ºC for MDO PE/PE and 120ºC for non-MDO PE/PE; hot tack test capability limited to below 20N T(ºC) Substrate Sealant Enable 4002 / HDPE / Exceed XP 8656 / HDPE / Enable 4002 (1/1/2/1/1, MDO 4.6, 25 μm) Exceed XP 8784 / Exceed XP 8784+ 30% HDPE/ Exceed 1012 (1/2/1, 60 μm) Enable 4002 + 40% HDPE/ Exceed XP 8656 / Enable 4002 + 40% HDPE (1/1/1, MDO 4.3, 25 μm) Exceed XP 8784 / Exceed XP 8784+ 30% HDPE / Exceed 1012 (1/2/1, 60 μm) Exceed 1327 + 40% HDPE / 20% Enable 4009 + 80% HDPE / Exceed 1327 + 40% HDPE (1/2/1, 35 μm) Exceed XP 8784 / Exceed XP 8784+ 30% HDPE/ Exceed 1012 (1/2/1, 50 μm) BOPA ( 15 μm ) C8-mLLDPE / C8-LLDPE + 25% HDPE / C8-mLLDPE (1/2/1, 60 μm) BOPET ( 12 μm ) C8-LLDPE (0.92d, 1.0MI); C8-mLLDPE (0.916d, 1MI); HDPE (0.961d, 0.7 MI) *All data from tests performed by or on behalf of ExxonMobil Performance polyethylene product portfolio Exceed XP when eXtreme Performance matters Step-out mechanical performance and excellent processability Exceed for superior performance Outstanding mechanical and sealing properties combined with best-in-class optics Enable for optimum solutions Excellent bubble stability with HAO properties Processability Mechanical properties LLDPE LLDPE blends LDPE blends LDPE Exceed Enable Exceed XP #RethinkRecycle 19_EXXO_6505_Porto Event_poster PE_90x135cmv7.indd 1 13/05/2019 15:43

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Page 1: Recyclable packaging with excellent packaging integrity ... · Regeneration Recyclable packaging with excellent packaging integrity, puncture energy and optics Full PE laminated solution

Regeneration

Recyclable packaging with excellent packagingintegrity, puncture energy and optics

Full PE laminated solution to replace multi-material laminates

• Improve mechanical recyclability

• Qualified to use How2Recycle® label

Substrate: OPET, OPP,

OPA Adhesive + printing

Sealant layer:Coex PE

Substrate:Coex PE

Adhesive + printing

Sealant layer:Coex PE

Store drop-off program in the U.S.A

Note: Label is applicable in the U.S.A.; for illustrative purposes only.

MDO (machine direction orientation) Technology

• MDO is a process by which a film is oriented in machine direction. There are typically 4 steps involved:

• Pre-heating

• Stretching

• Annealing

• Cooling

• Orientation can be made in line with the film making or off-line

MDO PE substrate vs. other substrates

• MDO PE substrate solution using Enable™ 4002 performance polymers

• Excellent optics• Similar haze/gloss properties to BOPP/BOPA• Up to 50% haze increase vs. formulation with HDPE in

the skin • Up to 67% haze increase vs. non-MDO PE substrate

• Great modulus• Up to 28% downgauge vs. non-MDO PE substrate• Both flexo and rotogravure printability

*MDO PE (Enable) with Enable 4002 in the skin (MDO ratio 4.8) and MDO PE (HDPE) with HDPE in the skin (MDO ratio 6); HDPE (0.961d, 0.7 MI) **All data from tests performed by or on behalf of ExxonMobil

Glo

ss (G

U)

Abs

olut

e m

odul

us, M

D (N

/mm

)

Haze (%)

160

120

80

40

020

0

10

20

30

40

50

60

15 10 5 0

BOPET (12 μm)Non-MDO PE (35 μm) MDO PE (Enable, 25 μm)MDO PE (HDPE, 20 μm) BOPP (20 μm) BOPA (15 μm)

MDO PE (5L) /PE solution for SUPs

5L MDO PE substrate solution using Enable™ 4002 performance polymers

• Exceptional optics with stretch ratio 4.6

• Excellent MD modulus (similar to BOPA/BOPP)

• Great processability ( high bubble stability; Easy separation)

5L MDO PE/ PE solution using Exceed™ XP 8784, Exceed™ 1012 and Enable 4002 performance polymers

• Excellent bag drop performance

• Great puncture energy

• Exceptional tensile strength

MDO PE (5L) /PE solution for SUPs

Bag-drop non-breakage [0-100%]

Bending stiffnessaverage [0-

150mN.mm]

Haze of Substrate[25-0%]

MD Modulus ofSubstrate [0-

60N/mm]

Dart impact [0-2000g]

Puncture energy [0-12mJ]

Tensile strength MD[0-100N]

* HDPE could be added to the inner skin for heat resistance in slide 53** Packaging performance depends on equipment and end-user requirements*** All data from tests performed by or on behalf of ExxonMobil

C8-LLDPE (0.92d, 1.0MI); C8-mLLDPE (0.916d, 1MI); HDPE (0.961d, 0.7 MI)In entire package for all solutions unit of density is g/cc and unit for MI is g/10min

Substrate Sealant

Enable 4002 / HDPE / Exceed XP 8656 / HDPE/ Enable 4002* (1/1/2/1/1, MDO 4.6, 25 µm)

Exceed XP 8784 / Exceed XP 8784+ 30% HDPE / Exceed 1012 (1/2/1, 120 µm)

BOPA ( 15 µm ) C8-mLLDPE / C8-LLDPE + 25% HDPE / C8-mLLDPE (1/2/1, 120 µm)BOPET ( 12 µm )

MDO PE (5L) /PE solution for SUPs

Bag-drop non-breakage rate (%)

Puncture energy (mJ)

Tensile strength MD (N)

Bending stiffness average (mN.mm)

Dart impact (N)

Haze of substrate (%)

MD Modulus of substrate (%)

*All data from tests performed by or on behalf of ExxonMobil

up to 100%Bag drop non-breakage rate

up to 1.7xPuncture energy vs. BOPET/PE

up to 1.2xTensile strength vs. BOPET/PE

BOPET/PE BOPA/PE PE/PE

0N/mm 10N/mm 20N/mm 30N/mm 40N/mm 50N/mm 60N/mm

0mJ 2mJ 4mJ 6mJ 8mJ 10mJ 12mJ

0N 20N 40N 60N 80N 100N

0mN.mm 30mN.mm 60mN.mm 90mN.mm 120mN.mm 150mN.mm

0g 400g 800g 1200g 1600g 2000g

0%5%10%15%20%25%

0% 20% 40% 60% 80% 100%

Sealing properties

MDO PE/PE solution using Exceed™ XP, Exceed™ 1012 and Enable™ performance polymers can offer:

• Great seal strength

• Excellent sealing initiation temperature

• High hot tack force

• Narrow sealing widow compared to BOPET/PE or BOPA/PE due to low heat resistance of PE film itself

0

20

40

60

80 100 120 140 160

Seal strength curve**

T (ºC)

F(N

/15m

m)

**Seal strength may be affected by bond strength

0

5

10

15

20

25

80 100 120 140 160

Hot tack curve***

FN

/30m

m)

***Film shrink and melt observed starting at 125ºC for MDO PE/PE and 120ºC for non-MDO PE/PE; hot tack test capability limited to below 20N

T(ºC)

Substrate Sealant

Enable 4002 / HDPE / Exceed XP 8656 / HDPE / Enable 4002 (1/1/2/1/1, MDO 4.6, 25 µm)

Exceed XP 8784 / Exceed XP 8784+ 30% HDPE/ Exceed 1012 (1/2/1, 60 µm)

Enable 4002 + 40% HDPE/ Exceed XP 8656 / Enable 4002 + 40% HDPE (1/1/1, MDO 4.3, 25 µm)

Exceed XP 8784 / Exceed XP 8784+ 30% HDPE / Exceed 1012 (1/2/1, 60 µm)

Exceed 1327 + 40% HDPE / 20% Enable 4009 + 80% HDPE / Exceed 1327 + 40% HDPE (1/2/1, 35 µm)

Exceed XP 8784 / Exceed XP 8784+ 30% HDPE/ Exceed 1012 (1/2/1, 50 µm)

BOPA ( 15 µm ) C8-mLLDPE / C8-LLDPE + 25% HDPE / C8-mLLDPE (1/2/1, 60 µm)BOPET ( 12 µm )

C8-LLDPE (0.92d, 1.0MI); C8-mLLDPE (0.916d, 1MI); HDPE (0.961d, 0.7 MI)*All data from tests performed by or on behalf of ExxonMobil

Performance polyethylene product portfolio

■ Exceed™ XPwhen eXtreme Performance matters

Step-out mechanical performance and excellent processability

■ Exceed™

for superior performance

Outstanding mechanical and sealing properties combined with best-in-class optics

■ Enable™

for optimum solutions

Excellent bubble stability with HAO properties

Processability

Mec

hani

cal p

rope

rtie

s

LLDPELLDPEblends LDPE

blends LDPE

Exceed™

Enable™

Exceed™ XP

#RethinkRecycle

19_EXXO_6505_Porto Event_poster PE_90x135cmv7.indd 1 13/05/2019 15:43