recyclable packaging with excellent packaging integrity ... · regeneration recyclable packaging...
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Regeneration
Recyclable packaging with excellent packagingintegrity, puncture energy and optics
Full PE laminated solution to replace multi-material laminates
• Improve mechanical recyclability
• Qualified to use How2Recycle® label
Substrate: OPET, OPP,
OPA Adhesive + printing
Sealant layer:Coex PE
Substrate:Coex PE
Adhesive + printing
Sealant layer:Coex PE
Store drop-off program in the U.S.A
Note: Label is applicable in the U.S.A.; for illustrative purposes only.
MDO (machine direction orientation) Technology
• MDO is a process by which a film is oriented in machine direction. There are typically 4 steps involved:
• Pre-heating
• Stretching
• Annealing
• Cooling
• Orientation can be made in line with the film making or off-line
MDO PE substrate vs. other substrates
• MDO PE substrate solution using Enable™ 4002 performance polymers
• Excellent optics• Similar haze/gloss properties to BOPP/BOPA• Up to 50% haze increase vs. formulation with HDPE in
the skin • Up to 67% haze increase vs. non-MDO PE substrate
• Great modulus• Up to 28% downgauge vs. non-MDO PE substrate• Both flexo and rotogravure printability
*MDO PE (Enable) with Enable 4002 in the skin (MDO ratio 4.8) and MDO PE (HDPE) with HDPE in the skin (MDO ratio 6); HDPE (0.961d, 0.7 MI) **All data from tests performed by or on behalf of ExxonMobil
Glo
ss (G
U)
Abs
olut
e m
odul
us, M
D (N
/mm
)
Haze (%)
160
120
80
40
020
0
10
20
30
40
50
60
15 10 5 0
BOPET (12 μm)Non-MDO PE (35 μm) MDO PE (Enable, 25 μm)MDO PE (HDPE, 20 μm) BOPP (20 μm) BOPA (15 μm)
MDO PE (5L) /PE solution for SUPs
5L MDO PE substrate solution using Enable™ 4002 performance polymers
• Exceptional optics with stretch ratio 4.6
• Excellent MD modulus (similar to BOPA/BOPP)
• Great processability ( high bubble stability; Easy separation)
5L MDO PE/ PE solution using Exceed™ XP 8784, Exceed™ 1012 and Enable 4002 performance polymers
• Excellent bag drop performance
• Great puncture energy
• Exceptional tensile strength
MDO PE (5L) /PE solution for SUPs
Bag-drop non-breakage [0-100%]
Bending stiffnessaverage [0-
150mN.mm]
Haze of Substrate[25-0%]
MD Modulus ofSubstrate [0-
60N/mm]
Dart impact [0-2000g]
Puncture energy [0-12mJ]
Tensile strength MD[0-100N]
* HDPE could be added to the inner skin for heat resistance in slide 53** Packaging performance depends on equipment and end-user requirements*** All data from tests performed by or on behalf of ExxonMobil
C8-LLDPE (0.92d, 1.0MI); C8-mLLDPE (0.916d, 1MI); HDPE (0.961d, 0.7 MI)In entire package for all solutions unit of density is g/cc and unit for MI is g/10min
Substrate Sealant
Enable 4002 / HDPE / Exceed XP 8656 / HDPE/ Enable 4002* (1/1/2/1/1, MDO 4.6, 25 µm)
Exceed XP 8784 / Exceed XP 8784+ 30% HDPE / Exceed 1012 (1/2/1, 120 µm)
BOPA ( 15 µm ) C8-mLLDPE / C8-LLDPE + 25% HDPE / C8-mLLDPE (1/2/1, 120 µm)BOPET ( 12 µm )
MDO PE (5L) /PE solution for SUPs
Bag-drop non-breakage rate (%)
Puncture energy (mJ)
Tensile strength MD (N)
Bending stiffness average (mN.mm)
Dart impact (N)
Haze of substrate (%)
MD Modulus of substrate (%)
*All data from tests performed by or on behalf of ExxonMobil
up to 100%Bag drop non-breakage rate
up to 1.7xPuncture energy vs. BOPET/PE
up to 1.2xTensile strength vs. BOPET/PE
BOPET/PE BOPA/PE PE/PE
0N/mm 10N/mm 20N/mm 30N/mm 40N/mm 50N/mm 60N/mm
0mJ 2mJ 4mJ 6mJ 8mJ 10mJ 12mJ
0N 20N 40N 60N 80N 100N
0mN.mm 30mN.mm 60mN.mm 90mN.mm 120mN.mm 150mN.mm
0g 400g 800g 1200g 1600g 2000g
0%5%10%15%20%25%
0% 20% 40% 60% 80% 100%
Sealing properties
MDO PE/PE solution using Exceed™ XP, Exceed™ 1012 and Enable™ performance polymers can offer:
• Great seal strength
• Excellent sealing initiation temperature
• High hot tack force
• Narrow sealing widow compared to BOPET/PE or BOPA/PE due to low heat resistance of PE film itself
0
20
40
60
80 100 120 140 160
Seal strength curve**
T (ºC)
F(N
/15m
m)
**Seal strength may be affected by bond strength
0
5
10
15
20
25
80 100 120 140 160
Hot tack curve***
FN
/30m
m)
***Film shrink and melt observed starting at 125ºC for MDO PE/PE and 120ºC for non-MDO PE/PE; hot tack test capability limited to below 20N
T(ºC)
Substrate Sealant
Enable 4002 / HDPE / Exceed XP 8656 / HDPE / Enable 4002 (1/1/2/1/1, MDO 4.6, 25 µm)
Exceed XP 8784 / Exceed XP 8784+ 30% HDPE/ Exceed 1012 (1/2/1, 60 µm)
Enable 4002 + 40% HDPE/ Exceed XP 8656 / Enable 4002 + 40% HDPE (1/1/1, MDO 4.3, 25 µm)
Exceed XP 8784 / Exceed XP 8784+ 30% HDPE / Exceed 1012 (1/2/1, 60 µm)
Exceed 1327 + 40% HDPE / 20% Enable 4009 + 80% HDPE / Exceed 1327 + 40% HDPE (1/2/1, 35 µm)
Exceed XP 8784 / Exceed XP 8784+ 30% HDPE/ Exceed 1012 (1/2/1, 50 µm)
BOPA ( 15 µm ) C8-mLLDPE / C8-LLDPE + 25% HDPE / C8-mLLDPE (1/2/1, 60 µm)BOPET ( 12 µm )
C8-LLDPE (0.92d, 1.0MI); C8-mLLDPE (0.916d, 1MI); HDPE (0.961d, 0.7 MI)*All data from tests performed by or on behalf of ExxonMobil
Performance polyethylene product portfolio
■ Exceed™ XPwhen eXtreme Performance matters
Step-out mechanical performance and excellent processability
■ Exceed™
for superior performance
Outstanding mechanical and sealing properties combined with best-in-class optics
■ Enable™
for optimum solutions
Excellent bubble stability with HAO properties
Processability
Mec
hani
cal p
rope
rtie
s
LLDPELLDPEblends LDPE
blends LDPE
Exceed™
Enable™
Exceed™ XP
#RethinkRecycle
19_EXXO_6505_Porto Event_poster PE_90x135cmv7.indd 1 13/05/2019 15:43