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© 2018 Activated Research Company, LLC © 2018 Activated Research Company, LLC Recent Advances in Catalysis for the Measurement of CO, CO 2 , and Formaldehyde Rajvi Mehta October 17, 2018 Gulf Coast Conference

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  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Recent Advances in Catalysis for the Measurement of CO, CO2, and

    Formaldehyde

    Rajvi Mehta

    October 17, 2018

    Gulf Coast Conference

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Measuring CO, CO2, & Formaldehyde

    • Applications• Ethylene/propylene

    production

    • Air quality

    • Transformer oil gas analysis

    • Renewable Fuels

    • Beverage

    • Catalysis

    2

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Measuring CO, CO2, & Formaldehyde

    • Applications• Ethylene/propylene

    production

    • Air quality

    • Transformer oil gas analysis

    • Renewable Fuels

    • Beverage

    • Catalysis

    • Analytical Techniques• GC-TCD

    • GC-MS

    • GC-Methanizer-FID

    3

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Packed Capillary

    Columns

    HP 5890 Agilent Intuvo

    GCs

    Photo Credit:http://hashahgroup.com/product_agilent_crosslab.php

    http://www.dot-red.com/gc-columns/fused-silica-capillary-gc-columns/http://www.aimanalytical.com/5890.html

    http://www.businesswire.com/news/home/20160830005184/en/Agilent-Technologies-Introduces-Transformational-Technology-Gas-Chromatography

    GC is Evolving to Meet Scientists’ Needs

    4

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Traditional Methanizers

    • 16+ parts• 2-6 hour installation

    5

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Recent Advances: Jetanizer™

    Traditional Methanizer Jetanizer

    16+ parts

    1 part

    6

    Agilent

    Shimadzu

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Jetanizer™: Simple Installation

    Traditional Methanizer Jetanizer

    2-6 hours 1-5 minutesInstallation time

    7

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Jetanizer™ vs. Methanizer

    8

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Jetanizer™: CO2 Analysis

    1 mL sample loop

    9

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Jetanizer™: Hydrocarbon Matrix

    1. Methane2. Ethylene3. Acetylene4. Ethane5. Propylene6. Propane

    Conventional FID Jet

    Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”

    10

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Jetanizer™: Hydrocarbon Matrix

    Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”

    1. Carbon monoxide2. Methane3. Carbon dioxide4. Ethylene5. Acetylene6. Ethane7. Propylene8. Propane

    11

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    CO2 in Confined Space

    Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”

    Front

    Rear

    38,000 feet, in flight for 2 h

    12

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    CO2 in Carbonated Beverages

    Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”

    Fresh drink

    Day old drink

    13

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Flue Gas Analysis

    Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”

    1. Methane2. CO2

    14

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Jetanizer™: Formaldehyde

    Luong, J., et al., Analytical Methods, “In-situ Methanation with Flame Ionization Detector for the Determination of Carbon Dioxide in Various Matrices.”

    1. Air2. Methane3. CO24. Ethane5. Formaldehyde6. Propane7. Butane8. Formaldehyde dimer9. Pentane10. Hexane

    10

    1

    2

    4

    5

    3

    6 97

    8

    15

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Polyarc® System: Universal Carbon Response

    Microreactor Design and

    Stainless Steel 3D Printing

    Expertise in Catalysis

    Design and Synthesis

    First and Only Commercial 3D Printed

    Microreactor

    16

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Polyarc® and Jetanizer™

    17

  • © 2018 Activated Research Company, LLC© 2018 Activated Research Company, LLC

    Questions?Thank you!

    ARC can be found at Booth #522.

    18