r123 grease, gum and tar remover - hugh...

R701 Spot Kit – R122/R123/R144/R153 of 26 Revision Dates – See individual documents Print Date 30/01/15

PRODUCT SPECIFICATION SHEET

R123 GREASE, GUM AND TAR REMOVER LABEL INSTRUCTIONS Product Description & Directions For Use

Grease, Gum & Tar Remover is a unique spotter based upon gentle solvents and citrus oil extracts. It removes many oil based spots and spills from carpets, fabrics and many hard surfaces. Its gelled formula prevents running and keeps it in contact with the spot for effective removal. Determine spot type. (Check application list on each bottle in the Spot Remover kit to determine the correct spot remover.) Pre-test the carpet, fabric or surface in a small inconspicuous area for dye sensitivity, colour fastness, or surface sensitivity to the spotter. Sponge or scrape up any surface spot material. Apply Grease, Gum & Tar Remover to the top surface of the spot with nozzle applicator. Avoid over application. Do not allow spotter to contact latex backing of carpet or fabric. Blot with clean white absorbent towel or scrape gently to remove residues. Do not rub. Repeat steps above as necessary. Rinse area with damp sponge and clear water to remove excess spotter. Brush fabric to align fibres. GREASE, GUM & TAR REMOVER is part of the Prochem Spot Remover Kit • Handy sized shrink-wrapped consumer kit with four spotting agents which are

effective on most common household stains. • Comes complete with nozzle applicators and easy to use quick reference guide.

pH Concentrate: 5.0 pH Diluted: Not applicable HANDLING AND SAFETY Harmful to aquatic life with long lasting effects. Repeated exposure may cause skin dryness or cracking. Contains limonene (d-limonene), citral, Dipentene. May produce an allergic reaction. Keep out of the reach of children. Avoid release to the environment. Wear protective gloves. IF IN EYES – Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Get medical advice/attention. Dispose of contents/container to appropriate waste site or reclaimer in accordance with local/regional/national/international regulations. Please consult the Safety Data Sheet before using this product. Product Specification Issue Date: 20th January 2015 IMPORTANT NOTICE: Prochem Europe Ltd. exclude liability for the following:- Accidents, incorrect use, exposure to extreme temperatures or conditions and unauthorised intervention. All forms of damage and special damage founded in tort (apart from death and personal injury) and contract law including but not limited to consequential loss, loss of income and losses incurred in reliance of the contract or through the use of the product. The statutory rights of consumers are unaffected. As against non-consumers, however, any implied term that this product will correspond with a description or a sample or that the product is of satisfactory quality is excluded. Individuals with potential allergic sensitivities should have their doctor review this or any other product before use. The information given is intended to be of assistance to users but is without guarantee. Variations can occur in application and users are advised to conduct their own tests. Suggestions for use neither give nor imply any guarantee as to the intended use.


SAFETY DATA SHEET

R123 GREASE, GUM AND TAR REMOVER

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product Name: Grease, Gum and Tar Remover Product Code: R123 Revision Date: 21st January 2015 Supplier: Hugh Crane (Cleaning Equipment) Ltd South Walsham Road, Acle Norwich NR13 3ES Telephone: 01493 750072 FAX 01493 751854 Emergency Action: In the event of a medical enquiry involving this product, please contact your doctor or local hospital accident and emergency department, who may seek advice from the UK NATIONAL POISONS INFORMATION SERVICE where our full product details are held.

Relevant Identified Uses of the Substance/Mixture and Uses Advised Against Identified uses: Grease, Gum & Tar Remover is a unique spotter based upon gentle solvents and citrus oil

extracts. It removes many oil based spots and spills from carpets, fabrics and many hard surfaces. Its gelled formula prevents running and keeps it in contact with the spot for effective removal. 2. HAZARDS IDENTIFICATION Classification of the substance or mixture Classification Physical hazards: Not Classified Health hazards: Elicitation - EUH208 Environmental hazards: Aquatic Chronic 3 - H412 Classification (67/548/EEC or 1999/45/EC)

R52/53,R66. Human health: May be slightly irritating to eyes. Prolonged or repeated contact with skin may cause irritation, redness and dermatitis. Deliberate excessive inhalation may cause headache, dizziness and breathing irritation. Ingestion may cause severe irritation of the mouth, the oesophagus and the gastrointestinal tract. Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis. Environmental: Harmful to aquatic life with long lasting effects. Inherently biodegradable. The product contains potentially bioaccumulating substances. Label elements Hazard statements: EUH208 Contains Dipentene, Citral, d-Limonene. May produce an allergic reaction.

H412 Harmful to aquatic life with long lasting effects. Precautionary statements: P102 Keep out of reach of children.

P273 Avoid release to the environment. P280 Wear protective gloves. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing. P313 Get medical advice/attention. P501 Dispose of contents / container in accordance with local / regional / national /

international regulations. Supplemental label information: EUH066 Repeated exposure may cause skin dryness or cracking. Detergent labelling ≥ 30% aliphatic hydrocarbons, < 5% non-ionic surfactants, < 5% perfumes, Contains

d-Limonene, Citral, Hexyl cinnamal, Linalool, Geraniol Other hazards: See section 8 for details of exposure limits. 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixtures SUBSTANCE CAS No EINECS NO

REACH Registration Number:

Classification Classification 67/548/EEC or 1999/45/EC

%W/W (EC RANGE)

Hydrocarbons, C11-C12, Isoalkanes, <2% Aromatics

64741-65-7 918-167-1 01-2119472146-39-0001 Flam. Liq. 3 - H226 Asp. Tox. 1 - H304 Aquatic Chronic 4 - H413

Xn;R65. R53,R66.

60-100%

C12-15 alcohol ethoxylate with 9MEO M Factor (Acute) = 1

68131-39-5 Acute Tox. 4 - H302 Eye Dam. 1 - H318 Aquatic Acute 1 - H400

Xn;R22. Xi;R41. N;R50.

<1%


SUBSTANCE CAS No EINECS NO

REACH Registration Number:

Classification Classification 67/548/EEC or 1999/45/EC

%W/W (EC RANGE)

D-Limonene M Factor (Acute) = 1 M Factor (Chronic) = 1

5989-27-5 227-813-5 Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

R10 R43 Xi;R38 N;R50/53

<1%

Citral

5392-40-5 226-394-6 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Eye Irrit 2 – H319

R43 Xi;R38

<1%

Dipentene M Factor (Chronic) = 1

138-86-3 205-341-0 Flam. Liq. 3 - H226 Skin Irrit. 2 - H315 Skin Sens. 1 - H317 Asp Tox 1 – H304 Aquatic Chronic 1 - H410

R10 R43 Xi;R38 N;R50/53

<1%

2-Aminoethanol

141-43-5 205-483-3 Acute Tox. 4 - H302 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Corr. 1B - H314 Eye Dam 1 – H318 STOT SE 3 - H335 Aquatic Chronic 3 - H412

C;R34 Xn;R20/21/22

<1%

Cyclohexane M Factor (Acute) = 1 M Factor (Chronic) = 1

110-82-7 203-806-2 Flam. Liq. 2 - H225 Skin Irrit. 2 - H315 STOT SE 3 - H336 Asp. Tox. 1 - H304 STOT SE 3 - H336 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

F;R11 Xn;R65 Xi;R38 R67 N;R50/53

<1%

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. 4. FIRST AID MEASURES Description of first aid measures Inhalation: Remove affected person from source of contamination. Move affected person to fresh air and

keep warm and at rest in a position comfortable for breathing. For breathing difficulties, oxygen may be necessary. Get medical attention.

Ingestion: Get medical attention immediately. Rinse mouth thoroughly with water. Never give anything by mouth to an unconscious person. Do not induce vomiting.

Skin contact: Wash skin thoroughly with soap and water. Get medical attention if any discomfort continues. Eye contact: Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention.

Most important symptoms and effects, both acute and delayed Ingestion: Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis. Skin contact: Product has a defatting effect on skin. May cause allergic contact eczema. Dryness and/or cracking.

Indication of any immediate medical attention and special treatment needed

If swallowed, especially in large quantities: Get medical attention immediately! 5. FIREFIGHTING MEASURES Extinguishing media: Use fire-extinguishing media appropriate for surrounding fire. Extinguish with foam, carbon dioxide, dry powder or water fog. Do not use water jet as an extinguisher, as this will spread the fire.

Special hazards arising from the substance or mixture Specific Hazards: This product is not flammable. The product contains organic solvents. Hazardous combustion products: Thermal decomposition or combustion may produce the following substances: Oxides of carbon. When heated, vapours/gases hazardous to health may be formed. Advice for firefighters Protective equipment for fire-fighters: Wear positive –pressure self- contained breathing apparatus (SCBA)and appropriate

protective clothing. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions: Wear protective clothing as described in Section 8 of this safety data sheet. Provide adequate general and local exhaust ventilation. No smoking, sparks, flames or other sources of ignition near spillage. Avoid contact with skin.


Environmental precautions Environmental precautions: Do not discharge into drains or watercourses or onto the ground.

Methods and material for containment and cleaning up Methods for cleaning up: Absorb in vermiculite, dry sand or earth and place into containers. Do not use sawdust or other combustible material. Waste should be treated as controlled waste. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. Flush contaminated area with plenty of water. Reference to other sections: For personal protection, see Section 8. For waste disposal, see Section 13.

7. HANDLING AND STORAGE Precautions for safe handling Usage precautions: Wear protective clothing as described in Section 8 of this safety data sheet. Wash hands

thoroughly after handling. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage precautions: Store at moderate temperatures in dry, well ventilated area. Store in closed original container at

temperatures between 5°C and 30°C. Avoid heat, flames and other sources of ignition. Static electricity and formation of sparks must be prevented. Keep only in the original container. Keep out of the reach of children. Wear protective clothing as described in Section 8 of this safety data sheet. Wash hands after handling. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using the product.

Conditions for safe storage, Store at moderate temperatures in dry, well ventilated area. Store in closed original container at including any incompatibilities: temperatures between 5°C and 30°C. Avoid heat, flames and other sources of ignition. Static electricity and formation of sparks must be prevented. Keep in original container. Keep out of reach of children.

Specific end use(s): The identified uses for this product are detailed in Section 1.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control Parameters Occupational Exposure Limits

Hydrocarbons, C11-C12, Isoalkanes, <2% Aromatics Long Term Exposure Limit (8hr TWA): SUP 150 ppm 1000 mg/m3

2-Aminoethanol

Long Term Exposure Limit (8hr TWA): WEL 1 ppm 2.5 mg/m3

Short Term Exposure Limit (15 min): WEL 3 ppm 7.6 mg/m3

SK

Cyclohexane

Long Term Exposure Limit (8hr TWA): WEL 100 ppm 350 mg/m3

Short Term Exposure Limit (15 min): WEL 300 ppm 1050 mg/m3

WEL = Workplace Exposure Limit SUP = Suppliers Recommendation SK = Can be absorbed through the skin

Exposure controls Protective equipment:

Appropriate engineering controls: Provide adequate ventilation. Eye/face protection: Side shield safety glasses are recommended when handling this product. Hand protection: Wear protective gloves. Solvent resistant nitrile gloves are recommended. Protective gloves should be inspected for wear before use and replaced regularly in accordance with the manufacturers specifications. Respiratory protection: No specific recommendations. Respiratory protection must be used if the airborne

contamination exceeds the recommended occupational exposure limit. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance: Viscous liquid Colour: White. Odour: Orange. Odour Threshold: Not determined. pH-Value, Conc. Solution: 5 Initial boiling point and range: 100°C Flash point: 82°C PMCC (Pensky-Martens Closed Cup). Evaporation rate: Not determined.


Upper/Lower Flammability/Explosive Limits: Not determined. Vapour pressure: Not determined. Vapour density: Not determined. Relative density: 0.804 Solubility: Slightly soluble in water. Partition Coefficient: Not determined. Viscosity: 0.0003362 m2/s 40°C Explosive properties: Not determined. Oxidising properties: Not applicable. Other information: None. 10. STABILITY AND REACTIVITY Reactivity: There are no known reactivity hazards associated with this product. Chemical stability: Stable at normal ambient temperatures. Possibility of hazardous reactions Not determined. Conditions to avoid: Protect against direct sunlight. Avoid heat, flames and other sources of ignition. Take precautionary measures against static discharges. Materials to avoid: Strong acids. Alkalis. Oxidising materials. Hazardous decomposition products: Thermal decomposition or combustion products may include the following substances: Oxides of carbon. High concentrations of vapour at high temperatures may create a respiratory hazard. 11. TOXICOLOGICAL INFORMATION Information on toxicological effects Toxicological effects: Deliberate excessive inhalation may cause headache, dizziness and breathing irritation. Ingestion may cause: systemic effects Nausea, vomiting. Diarrhoea. Aspiration hazard if swallowed. Entry into the lungs following ingestion or vomiting may cause chemical pneumonitis. Skin Corrosion/Irritation: Prolonged contact may cause redness, irritation and dry skin. Repeated exposure may cause skin dryness or cracking. Serious eye damage/irritation: May be slightly irritating to eyes. Respiratory or skin sensitisation: Contains: Limonene Citral Hexyl cinnamal Linalool Geraniol Germ cell mutagenicity: Genotoxicity – in Vivo - No effects expected based upon current data. Carcinogenicity: No effects expected based upon current data. Reproductive Toxicity: Reproductive toxicity – fertility - No effects expected based upon current data. Toxicological Information On Ingredients

HYDROCARBONS, C11-C12, ISOALKANES, <2% AROMATICS Acute Toxicity Oral Acute Toxicity Oral (LD50 mg/kg): 5,000.00 Species: Rat ATE Oral (mg/kg): 5,000.00

Acute Toxicity Dermal Acute Toxicity Dermal (LD50 mg/kg): 5,000.00 Species: Rabbit ATE Oral (mg/kg): 5,000.00

12. ECOLOGICAL INFORMATION 12.1 Toxicity: Harmful to aquatic life with long lasting effects.

Ecological Information On Ingredients

HYDROCARBONS, C11-C12, ISOALKANES, <2% AROMATICS Acute Toxicity Fish: LC50, : >100 mg/l Acute Toxicity - Aquatic Invertebrates: EC50 >100 mg/l Acute Toxicity - Aquatic Plants: IC50 >100 mg/l Acute Toxicity – Microorganisms: LC50 >100 mg/l Chronic Toxicity Fish Life Early Stage: Not available Chronic Toxicity - Aquatic Invertebrates: NOEC, >1.0 - <10mg/k, Freshwater invertebrates.

12.2 Persistence & Degradability Persistence & Degradability: Inherently biodegradable The product is degraded completely by photochemical oxidation. The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer.


12.3 Bioaccumulative potential: May accumulate in soil and water systems. Partition coefficient: Not determined.

Ecological information on ingredients. Ingredient Partition Coefficient HYDROCARBONS, C11-C12, ISOALKANES, <2% AROMATICS 6.7-7.2

12.4 Mobility in soil: Mobility: The product is insoluble in water and will spread on the water surface. The product contains organic solvents which will evaporate easily from all surfaces. Ecological information on ingredients. Ingredient Surface Tension HYDROCARBONS, C11-C12, ISOALKANES, <2% AROMATICS 23.5 mN/m @ 20ºC

12.5 Results of PBT and vPvB assessment: This product does not contain any PBT or vPvB substances. 12.6 Other adverse effects: None known. 13. DISPOSAL CONSIDERATIONS Waste treatment methods: Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. Do not discharge into drains, water courses or onto the ground. 14. TRANSPORT INFORMATION UN No.: Not classified for transportation. UN Proper Shipping Name: None Transport hazard class(es) Road (ADR): None Sea (IMDG): None Rail (RID): None Packing Group: None Environmental hazards: Environmentally Hazardous Substance/Marine Pollutant - NO Special precautions for user: None Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable

15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations: The Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No. 2677) (as amended). The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009 No. 716). EU legislation: Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended). Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Chemical safety assessment: No chemical safety assessment has been carried out. 16. OTHER INFORMATION Revision Date: 21st January 2015 Risk Phrases In Full: R10 Flammable. R11 Highly flammable R20 Harmful by inhalation R21 Harmful in contact with skin R22 Harmful if swallowed. R34 Causes burns. R37 Irritating to respiratory system. R38 Irritating to skin. R41 Risk of serious damage to eyes. R43 May cause sensitisation by skin contact. R50 Very toxic to aquatic organisms. R52 Harmful to aquatic organisms R53 May cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.


Hazard Statements In Full: EUH208 Contains Dipentene, Citral, d-Limonene. May produce an allergic reaction. H225 Highly flammable liquid and vapour.

H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H335 May cause respiratory irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. H413 May cause long lasting harmful effects to aquatic life. EUH066 Repeated exposure may cause skin dryness or cracking. Disclaimer: For additional information on safety, training and use of this product, contact the supplier. This product is intended for professional use only. The information given is intended to be of assistance to users but is without guarantee. Variations can occur in application and users are advised to conduct their own tests. Suggestions for use neither give nor imply any guarantee as to the intended use.

End of Safety Data Sheet


Composition / Information on Ingredients

R123 GREASE, GUM AND TAR REMOVER

Product Name: Grease, Gum and Tar Remover Product Code: R123 Revision Date: 03 Jan 2013 Supplier: Hugh Crane Cleaning Equipment Ltd South Walsham Rd, Acle, Norwich NR13-3ES Tel 01493 750072. www.hughcrane.co.uk Detergent Ingredient 1. Hydrocarbons, C11-C12, Isoalkanes, 2% Aromatics Information: 2. Water 3. Parfum 4. Alkyl Ester Solvent 5. C12-15 Pareth-9 6. d-Limonene 7. Citral 8. Carbomer 9. Hexyl Cinnamal 10. Linalool 11. Geraniol 12. Ethanolamine 13. Cyclohexane


Product Specification Sheet

R122 NEUTRAL SPOT REMOVER LABEL INSTRUCTIONS

Product Description & Directions For Use A powerful, safe neutral pH all purpose spot remover for use on all fibres including wool and stain-resistant nylon carpets. For best results, treat spots and spills as soon after occurrence as possible. Determine spot type. (Check application list on each spotter bottle in the Spot Remover kit to determine the correct spot remover.) Pretest carpet or fabric in a small inconspicuous area for dye sensitivity and colour fastness. Sponge or scrape up any surface spot material. Apply Neutral Spot Remover directly to spot with nozzle applicator. Blot with clean white absorbent cloth or paper towel. Do not rub. Deep spots may need light brushing. On larger spots, work from the outside of the spot toward the centre. Repeat above steps as necessary. Rinse area with damp sponge and clear water to remove excess spotter. Brush fabric to align fibres.

NEUTRAL SPOT REMOVER is part of the Prochem Spot Remover Kit • Handy sized shrink-wrapped consumer kit with four spotting agents which are effective on most common household stains. • Comes complete with nozzle applicators and easy to use quick reference guide.

pH Concentrate: 7.5 pH Diluted: Not applicable HANDLING AND SAFETY Keep out of the reach of children. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. If swallowed, seek medical advice immediately and show this container or label. IMPORTANT NOTICE: Prochem Europe Ltd. exclude liability for the following:- Accidents, incorrect use, exposure to extreme temperatures or conditions and unauthorised intervention. All forms of damage and special damage founded in tort (apart from death and personal injury) and contract law including but not limited to consequential loss, loss of income and losses incurred in reliance of the contract or through the use of the product. The statutory rights of consumers are unaffected. As against non-consumers, however, any implied term that this product will correspond with a description or a sample or that the product is of satisfactory quality is excluded. Individuals with potential allergic sensitivities should have their doctor review this or any other product before use. Please consult the Safety Data Sheet before using this product. Issue Date: 14/11/2013 The information given is intended to be of assistance to users but is without guarantee. Variations can occur in application and users are advised to conduct their own tests. Suggestions for use neither give nor imply any guarantee as to the intended use.


SAFETY DATA SHEET

R122 NEUTRAL SPOT REMOVER 1. IDENTIFICATION OF THE PRODUCT AND SUPPLIER Product Name: Neutral Spot Remover Product Code: R122 Revision Date: 12/11/2013 Supplier: Hugh Crane (Cleaning Equipment) Ltd South Walsham Road, Acle, Norwich NR13 3ES. Telephone (01493) 750072 Fax (01493) 751854 Emergency Action: In the event of a medical enquiry involving this product, please contact your doctor or local hospital accident and emergency department, who may seek advice from the UK National Poisons Information Service where our full product details are held. Relevant identified uses of the substance or mixture and uses advised against

A powerful, safe neutral pH all purpose spot remover for use on all fibres including wool and stain-resistant nylon carpets. 2. HAZARDS IDENTIFICATION Classification of the substance or mixture CLASSIFICATION (1999/45/EC): Not classified. Human Health: Contact with concentrate may cause mild transient irritation to eyes and skin. Limited

inhalation hazard at normal work temperatures. Inhalation may cause: Irritation of the nose and throat. Ingestion may cause: nausea.

Environment: This product is expected to be biodegradable.

Label Elements Risk Phrases: NC Not classified Safety Phrases: S2 Keep out of reach of children

S25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S46 If swallowed, seek medical advice immediately and show this container or label. Other hazards: See Section 8 for details of exposure limits. 3. COMPOSITION / INFORMATION ON INGREDIENTS

Substance Classification 67/548/EEC

Classification EC 1272/2008

EINECS No.

CAS No. %W/W (EC Range)

2-(2-methoxymethylethoxy) propanol

Not classified Not classified 254-104-2 345-0-94-8 1- 5%

Disodium maleate Xi R36 H319 Eye Irrit 2 206-738-1 371-47-1 < 3%

Sodium octane-1-sulphonate monohydrate

Xi R36/38 H315 Skin Irrit 2 H319 Eye Irrit 2

226-195-4 5324-84-5 < 3%

Anionic Surfactant Xi R36 H319 Eye Irrit 2 - 39354-45-5 < 3%

Alcohols, C7-21 ethoxylated Xi R38 R41 H315 Skin Irrit 2 H318 Eye Dam1

- 68991-48-0 <2%

The full text for all R-Phrases and Hazard Statements are displayed in Section 16. 4. FIRST AID MEASURES Description Of First Aid Measures Inhalation: Move into fresh air and keep at rest. Get medical attention if any discomfort continues. Ingestion: DO NOT induce vomiting. Immediately rinse mouth and drink plenty of water (200-300ml). Do not give victim anything to drink if they are unconscious. Get medical attention. Skin Contact: Wash skin thoroughly with soap and water. Seek medical attention if any skin irritation persists

after washing. Eye Contact: Immediately flush with plenty of water for up to15 minutes. Remove any contact lenses and

open eyes wide apart. Get medical attention if any discomfort continues.

Most important symptoms and effects, both acute and delayed: Ingestion: Ingestion may cause: Nausea, Diarrhoea. Skin Contact: Prolonged or repeated exposure may cause: skin irritation and dermatitis. Eye Contact: May cause: temporary eye irritation.


Indication of any immediate medical attention and special treatment needed

Treat symptomatically. 5. FIRE FIGHTING MEASURES Extinguishing Media: Product is not flammable. Use fire extinguishing media appropriate for surrounding materials.

Water spray, dry powder or carbon dioxide.

Special hazards arising from the substance or mixture Hazardous combustion Prods: Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Acids – organic. Sulphur dioxide. Unusual Fire & Explosion Hazards: None noted. Protective Eqpt for Fire Fighters: Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective Eqpt & Emergency procedures: Wear protective clothing as described in section 8 of this SDS. Environmental precautions: Do not discharge into drains, water courses or onto the ground. Methods and material for Collect with absorbent, non combustible material into suitable containers. Dispose of containment and cleaning up: waste and residues in accordance with local authority requirements. Reference to other sections: For Personal Protection see Section 8. For Waste Disposal, see Section 13. 7. HANDLING AND STORAGE Precautions for safe handling: Wear protective clothing as described in Section 8 of this Safety Data Sheet. Wash hands after handling. Wash contaminated clothing before reuse. Do not eat drink or smoke when using the product. Conditions for safe storage, Keep out of reach of children. Store in original closed container at temperatures between 5ºC Including any incompatibilities: and 30ºC. Specific end use(s): The identified uses for this product are detailed in section 1. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Name Standard TWA 8 Hours STEL – 15 Min Notes (2-methoxymethylethoxy)propanol WEL 5 PPM 308 mg/m3 Sk

WEL – Workplace Exposure Limit Sk – Can be absorbed through skin Exposure controls Protective Equipment: Engineering Measures: Provide adequate ventilation Respiratory Equipment: Not required in normal use. For situations where recommended exposure limits may be exceeded or where there is a risk of inhalation of fine spray mists, a suitable respirator face mask is recommended. Hand Protection: Nitrile gloves are recommended. Protective gloves should be inspected for wear before use

and replaced regularly in accordance with the manufacturers specifications. Eye Protection: Side shield safety glasses are recommended when handling this product. Hygiene Measures: Wash hands after handling. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties: Appearance: Clear liquid Colour: Colourless Odour: Sweetish. Floral citrus Solubility: Soluble in water Initial boiling point and boiling range: 100°C Relative Density: 1.014 Vapour Density (Air = 1): Not determined Vapour Pressure: Not determined Evaporation Rate: Not determined pH Concentrate: 7 .5 pH Diluted: Not applicable Viscosity: Not determined Flash Point °C: Not applicable Flammability Limit – Lower %: Not applicable Partition Coefficient (N-octanol / Water): Not determined


Explosive Properties: Not applicable Oxidising Properties: Not applicable Other Information: None. 10. STABILITY AND REACTIVITY Reactivity: There are no known reactivity hazards associated with this product. Chemical stability: Stable under normal temperatures, conditions and recommended use. Possibility of hazardous reactions: Not determined. Conditions to avoid: Store in original closed container at temperatures between 5ºC and 30ºC. Protect from

freezing and direct sunlight. Incompatible materials: No incompatible groups noted. Hazardous decomposition products: Thermal decomposition or combustion may liberate carbon oxides and other toxic gases

or vapours. Acids – organic. Sulphur dioxide. 11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute Toxicity: Ingestion may cause; nausea, diarrhoea. Limited inhalation hazard at normal work

temperatures. Skin Corrosion/ Irritation: Prolonged or repeated exposure cause; skin irritation and dermatitis. Serious Eye Damage/Irritation: Contact with concentrate may produce mild transient irritation if not promptly rinsed. Respiratory or Skin Sensitisation: Contains Citral, Linalool. Germ Cell Mutagenicity: No effects expected based upon current data. Carcinogenicity: No effects expected based upon current data. Reproductive Toxicity: No effects expected based upon current data.

Toxicological Information on Ingredients

Ingredient CAS No Acute Toxicity

2-(2-methoxymethylethoxy) propanol 34590-94-8 Oral LD50 5135 mg/kg Rat Dermal LD50 >20mg/kg Rabbit

Sodium octane-1-sulphonate monohydrate 5324-84-5 Oral LD50 >5000 mg/kg Rat

12. ECOLOGICAL INFORMATION Toxicity: This product is not expected to be hazardous to the environment. Ecological Information on Ingredients

Ingredient CAS No Ecotoxicity

2-(2-methoxymethylethoxy) propanol 34590-94-8 LC50 96hrs Fish >10000 mg/l EC50 48hrs Daphnia 1919 mg/l IC50 72hrs Algae >969 mg/l

Persistence and Degradability: The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Ecological Information on Ingredients

Ingredient Chemical Oxygen Demand

2-(2-methoxymethylethoxy) propanol 2.02

Bioaccumulative Potential: None known. Partition Co-effiecient: Not determined. Mobility in soil: Soluble in water. Results of PBT and vPvB assessment: This product does not contain any PBT or vPvB substances. Other adverse effects: None known. 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods: Dispose of waste and residues in accordance with local authority requirements. Empty

containers should be rinsed with water then crushed and disposed of at legal waste disposal site.

14. TRANSPORT INFORMATION UN No.: Not classified for transport. UN Proper Shipping Name: None

Transport Hazard Class(es) Road (ADR): None Sea (IMDG): None Rail (RID): None Packaging Group: None.


Environmental Hazards: None. Special Precautions for User: None. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable. 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: UK Regulatory References: The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Chemicals (Hazard Information & Packaging) Regulations. EU Legislation: Regulation (EC) No 1907/2006 of the European Parliament & of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation & Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC & repealing Council Regulation (EEC) No 793/93 & Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC & Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC & 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament & of the Council of 16 December 2008 on classification, labelling and packaging of substances & mixtures, amending & repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. Chemical Safety Assessment: No chemical safety assessment has been carried out..

16. OTHER INFORMATION Risk Phrases In Full: R36 Irritating to eyes R38 Irritating to skin R41 Risk of serious damage to eyes NC Not classified. Hazard Statements in Full: H318 Causes serious eye damage H319 Causers serious eye irritation H315 Causes skin irritation.

For additional information on safety, training and use of this product contact the supplier. This product is intended for professional use only. The information given is intended to be of assistance to users but is without guarantee. Variations can occur in application and users are advised to conduct their own tests. Suggestions for use neither give nor imply any guarantee as to the intended use.



R122 NEUTRAL SPOT REMOVER

Product Name: Neutral Spot Remover Product Code: R122 Revision Date 26/09/07 Below is a list of ingredients present in his formulation, in order for decreasing abundance by weight. Please note – this list corresponds to the most recent formulation of this product. If you require information on an older batch or formulation, please contact us for details

Water PPG-2 methyl ether Disodium Maleate Sodium octane-1-sulphonate monohydrate Disodium laureth sulfosuccinate Alcohols, C7-21 ethoxylated Sodium hexane-1-sulphonate monohydrate Isopropyl alcohol Tetra-alkyl ammonium chloride Parfum Citric acid DMDM hydantoin Citral Limonene Butylene glycol Iodopropynil butyl carbamate

Link to table of correspondence on INCI name and CAS no’s:

http://ec.curopa.eu.enterprise/cosmetics/html/cosm inci index.htm


PRODUCT SPECIFICATION SHEET

R144 BLOOD AND PROTEIN SPOT REMOVER LABEL INSTRUCTIONS Product Description & Directions For Use

Blood & Protein Spot Remover is a water based cleaner that removes many food stains, blood and other protein based stains. For best results, treat spots and spills as soon after occurrence as possible. Determine spot type (check application list on each spotter bottle in the kit to determine the correct remover.) Pre-test the carpet, fabric or surface in a small inconspicuous area for dye sensitivity & colour fastness.

Sponge or scrape up any surface spot material. Apply Blood & Protein Spot Remover directly to spot with nozzle applicator. Blot with clean white absorbent cloth or paper towel. Do not rub. Deep spots may need light brushing. On larger spots work from the outside of the spot toward the centre. Repeat steps above as necessary. Rinse area with damp sponge and clear water to remove excess spotter. Brush fabric to align fibres. BLOOD AND PROTEIN SPOT REMOVER is part of the Prochem Spot Remover Kit

• Handy sized shrink-wrapped consumer kit with four spotting agents which are effective on most common household stains. • Comes complete with nozzle applicators and easy to use quick reference guide.

pH Concentrate: 10.5 pH Diluted: Not applicable HANDLING AND SAFETY Keep out of the reach of children. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. If swallowed, seek medical advice immediately and show this container or label. Please consult the Safety Data Sheet before using this product. Product Specification Issue Date: 03/04/2012 IMPORTANT NOTICE: Prochem Europe Ltd. exclude liability for the following:- Accidents, incorrect use, exposure to extreme temperatures or conditions and unauthorised intervention. All forms of damage and special damage founded in tort (apart from death and personal injury) and contract law including but not limited to consequential loss, loss of income and losses incurred in reliance of the contract or through the use of the product. The statutory rights of consumers are unaffected. As against non-consumers, however, any implied term that this product will correspond with a description or a sample or that the product is of satisfactory quality is excluded. Individuals with potential allergic sensitivities should have their doctor review this or any other product before use. The information given is intended to be of assistance to users but is without guarantee. Variations can occur in application and users are advised to conduct their own tests. Suggestions for use neither give nor imply any guarantee as to the intended use.


R144 BLOOD AND PROTEIN REMOVER 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product Name: Blood and Protein Remover Product Code: R144 Revision Date: 21/11/2012 Supplier: Hugh Crane (Cleaning Equipment) Ltd South Walsham Road, Acle Norwich NR13 3ES Telephone: 01493 750072 FAX 01493 751854

Emergency Action: In the event of a medical enquiry involving this product, please contact your doctor or local hospital accident and emergency department, who may seek advice from the UK NATIONAL POISONS INFORMATION SERVICE where our full product details are held. Relevant Identified Uses Of The Substance Or Mixture And Uses Advised Against Identified uses: Blood & Protein Spot Remover is a water-based cleaner that removes many food stains, blood and other protein based stains. For best results, treat spots and spills as soon after occurrence as possible. 2. HAZARDS IDENTIFICATION Classification Of The Substance Or Mixture Classification (1999/45/EEC): Not classified. Human health: Splashes in the eyes may cause redness and irritation. Prolonged or repeated exposure may cause: skin irritation and dermatitis. Limited inhalation hazard at normal work temperatures. Product is alkaline and may be mildly corrosive to mucous membranes. Ingestion may cause: nausea Systemic Effects Environment: The product is expected to be biodegradable. Label Elements Risk Phrases: NC Not classified. Safety Phrases: S2 Keep out of the reach of children.

S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S46 If swallowed, seek medical advice immediately and show this container or label. Other hazards: See section 8 for details of exposure limits. 3. COMPOSITION/INFORMATION ON INGREDIENTS Mixtures SUBSTANCE CAS No EINECS NO

Classification EC 1272/2008

Classification 67/548/EEC

%W/W (EC RANGE)

(2-METHOXYMETHYLETHOXY)PROPANOL 34590-94-8 252-104-2 Not classified. Not classified. 1-5%

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. 4. FIRST AID MEASURES Description Of First Aid Measures Inhalation: Move into fresh air and keep at rest. Get medical attention if any discomfort continues. Ingestion: Do not induce vomiting. Immediately rinse mouth and drink plenty of water (200-300 ml). Do not

give victim anything to drink if they are unconscious. Get medical attention. Skin contact: Wash skin with soap and water. Get medical attention if irritation persists after washing. Eye contact: Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues. Most important symptoms and effects, both acute and delayed Skin contact: Prolonged skin contact may cause redness and irritation. Eye contact May cause temporary eye irritation. Indication of any immediate medical attention and special treatment needed

Treat Symptomatically. 5. FIREFIGHTING MEASURES Extinguishing media: This product is not flammable. Use fire-extinguishing media appropriate for surrounding

materials. Water spray, dry powder or carbon dioxide.


Special hazards arising from the substance or mixture Hazardous combustion products: Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or

vapours. Unusual Fire & Explosion Hazards: No unusual fire or explosion hazards noted. Advice for Firefighters Protective Eqpt for fire-fighters: No specific recommendations. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective Eqpt & Emergency procedures: Wear protective clothing as described in Section 8 of this safety data sheet. Environmental precautions: Do not discharge into drains, water courses or onto the ground. Methods and material for Collect with absorbent, non-combustible material into suitable containers. Dispose of waste and containment and cleaning up: residues in accordance with local authority requirements. Reference to other sections: For personal protection, see section 8. For waste disposal, see section 13. 7. HANDLING AND STORAGE Precautions for safe handling: Wear protective clothing as described in Section 8 of this safety data sheet. Wash hands after handling. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using the product. Conditions for safe storage, Keep out of the reach of children. Store in closed original container at temperatures between including any incompatibilities: 5°C and 30°C. Specific end use(s): The identified uses for this product are detailed in Section 1.2. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters

Name STD TWA 8 Hours STEL 15 Min Notes

(2-METHOXYMETHYLETHOXY)PROPANOL WEL 50 ppm 308 mg/m3 Sk SK

WEL = Workplace Exposure Limit. Sk = Can be absorbed through skin. Exposure Controls Protective equipment: Engineering measures: Provide adequate ventilation. Respiratory equipment: Not required in normal use. Hand protection: Nitrile gloves are recommended. Protective gloves should be inspected for wear before use

and replaced regularly in accordance with the manufacturers specifications. Eye protection: Not required in normal use. Hygiene measures: Wash hands after handling. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance: Clear liquid. Colour: Colourless. Odour: Mint Solubility: Soluble in water. Initial boiling point and boiling range: 100°C Relative density: 1.02 Vapour density (air=1): Not determined. Vapour pressure: Not determined. Evaporation rate: Not determined. pH-Value, Conc. Solution: 10.5 pH-Value, Diluted Solution: Not applicable. Viscosity: Not determined. Flash point: Not applicable. Flammability Limit - Lower(%): Not applicable. Partition Coefficient (N-Octanol/Water): Not determined. Explosive properties: Not applicable. Oxidising properties: Not applicable. Other information: None. 10. STABILITY AND REACTIVITY Reactivity: There are no known reactivity hazards associated with this product. Chemical stability: Stable under normal temperature conditions and recommended use. Possibility of hazardous reactions: Not determined.


Conditions to avoid: Store in closed original container at temperatures between 5°C and 30°C. Protect from freezing and direct sunlight. Incompatible materials Materials To Avoid: Strong oxidising substances. Hazardous decomposition products: Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. 11. TOXICOLOGICAL INFORMATION Information On Toxicological Effects Acute toxicity: Product is alkaline and may be mildly corrosive to mucous membranes. Ingestion may cause:

nausea Systemic Effects Limited inhalation hazard at normal work temperatures. Deliberate excessive inhalation may cause headache, dizziness and breathing irritation. Skin Corrosion/Irritation: Prolonged or repeated exposure may cause: skin irritation and dermatitis. Serious eye damage/irritation: May cause temporary eye irritation. Respiratory or skin sensitisation: None known. Germ cell mutagenicity: No effects expected based upon current data. Carcinogenicity: No effects expected based upon current data. Reproductive Toxicity: No effects expected based upon current data. Toxicological information on ingredients. Ingredient CAS Acute toxicity Species

(2-METHOXYMETHYLETHOXY)PROPANOL 34590-94-8 (Oral LD50) 5135 mg/kg (Dermal LD50) > 20 mg/kg

Rat Rabbit

12. ECOLOGICAL INFORMATION Toxicity: The product is not expected to be hazardous to the environment.

Ecological information on ingredients. Ingredient CAS Acute toxicity

(2-METHOXYMETHYLETHOXY)PROPANOL 34590-94-8 LC 50, 96 Hrs, Fish mg/l >10000 EC 50, 48 Hrs, Daphnia, mg/l 1919 IC 50, 72 Hrs, Algae, mg/l >969

Persistence And Degradability Degradability: The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Ecological information on ingredients.

Ingredient CAS Chemical Oxygen Demand (2-METHOXYMETHYLETHOXY)PROPANOL 34590-94-8 2.02

Bioaccumulative potential: Not known. Partition coefficient: Not determined. Mobility: The product is soluble in water. Results of PBT and vPvB assessment: This product does not contain any PBT or vPvB substances. Other adverse effects: None known. 13. DISPOSAL CONSIDERATIONS Waste treatment methods: Dispose of waste and residues in accordance with local authority requirements. Empty containers should be rinsed with water then crushed and disposed of at legal waste disposal site. 14. TRANSPORT INFORMATION UN number: Not classified for transportation. UN proper shipping name: None. Transport hazard class(es) ADR/RID/ADN Class: - IMDG Class: - Packing group: None. Environmental hazards Environmentally Hazardous Substance/Marine Pollutant: No. Special precautions for user: None. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable.


15. REGULATORY INFORMATION Safety, Health And Environmental Regulations/Legislation Specific For The Substance Or Mixture UK Regulatory References: The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Chemicals (Hazard Information & Packaging) Regulations. EU Legislation: Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. Chemical Safety Assessment: No chemical safety assessment has been carried out. 16. OTHER INFORMATION Risk Phrases In Full: NC Not classified. Hazard Statements In Full: Disclaimer: For additional information on safety, training and use of this product, contact the supplier. This product is intended for professional use only. The information given is intended to be of assistance to users but is without guarantee. Variations can occur in application and users are advised to conduct their own tests. Suggestions for use neither give nor imply any guarantee as to the intended use. End of Safety Data Sheet



R144 BLOOD AND PROTEIN REMOVER

Product Name: Blood and Protein Remover Product Code: R144 Revised: 17/09/2012 Supplier: Hugh Crane Cleaning Equipment Ltd South Walsham Rd, Acle, Norwich NR13-3ES Tel 01493 750072. www.hughcrane.co.uk Detergent Ingredient 1. Water Information: 2. PPG-2 Methyl Ether 3. 1-(2-Butoxy-1-Methylethoxy) Propan-2-ol 4. Ethanolomine 5. Sodium Xylene Sulphonate 6. Alcolhols C9-11 Ethoxylated 7. Sulfuric Acid, Mono-C10-16-Alkyl Esters Ammonium Salts 8. Parfum 9. DMDM Hydantoin 10. Alcohols, C12-14 11. Iodopropynyl Butylcarbamate 12. Methylisothiazolinone 13. Methylchloroisothiazolinone Risk Phrases: NC Not Classified Safety Phrases: S2 Keep out of reach of children S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves S46 If swallowed, seek medical advice immediately and show this container or label. Detergent Labelling <5% Anionic surfactants Information: Non-ionic surfactants Perfumes . Contains Iodopropynyl Butylcarbamate, DMDM Hydantoin, Methylisothiazolinone, Methylchloroisothiazolinone


Product Specification Sheet

R153 URINE SPOTTER & DEODORISER

LABEL INSTRUCTIONS Product Description & Directions For Use A powerful spotter that helps neutralise spots and odours caused by urine and other waste products on carpets and wet cleanable fabrics. For best results, treat affected area as soon after occurrence as possible. Determine spot type. Check application list on each spotter bottle in the kit to determine the correct spot remover. Pre-test carpet or fabric in a small inconspicuous area for dye sensitivity and colour fastness.

Sponge or scrape up any surface spot material. Apply Urine Spotter & Deodoriser directly to spot with nozzle applicator. Blot with clean white absorbent cloth or paper towel. Do not rub. Deep spots may need light brushing. On larger spots, work from the outside of the spot toward the centre. Repeat steps above as necessary. Rinse area with damp sponge and clear water to remove excess spotter. Brush fabric to align fibres. Urine Spotter may not be effective in removing old urine stains. URINE SPOTTER & DEODORISER is part of the Prochem Spot Remover Kit • Handy sized shrink-wrapped consumer kit with four spotting agents which are effective on most common household stains. • Comes complete with nozzle applicators and easy to use quick reference guide.

pH: 4.0, Ready-to-Use HANDLING AND SAFETY

Keep out of the reach of children. Do not get in eyes, on skin or on clothing. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. Get medical advice/attention. IF SWALLOWED: Immediately call a POISON CENTRE/Doctor. IMPORTANT NOTICE: Prochem Europe Ltd. exclude liability for the following:- Accidents, incorrect use, exposure to extreme temperatures or conditions and unauthorised intervention. All forms of damage and special damage founded in tort (apart from death and personal injury) and contract law including but not limited to consequential loss, loss of income and losses incurred in reliance of the contract or through the use of the product. The statutory rights of consumers are unaffected. As against non-consumers, however, any implied term that this product will correspond with a description or a sample or that the product is of satisfactory quality is excluded. Individuals with potential allergic sensitivities should have their doctor review this or any other product before use. Please consult the Safety Data Sheet before using this product. Issue Date: 09/12/2014 The information given is intended to be of assistance to users but is without guarantee. Variations can occur in application and users are advised to conduct their own tests. Suggestions for use neither give nor imply any guarantee as to the intended use.


SAFETY DATA SHEET

R153 URINE SPOTTER AND DEODORISER 1. IDENTIFICATION OF THE PREPARATION AND COMPANY Product Name: Urine Spotter and Deodoriser Product Code: R153 Revision Date: 09/12/2014 Company: Hugh Crane (Cleaning Equipment) Ltd South Walsham Road, Acle Norwich NR13 3ES

Tel 01493 750072 Fax 01493 751854 Emergency Action In the event of a medical enquiry involving this product, please contact your doctor or local hospital accident and emergency department who may seek advice from the UK NATIONAL POISONS INFORMATION SERVICE where our full product details are held. Identified Uses: A powerful spotter that helps neutralise spots and odours caused by urine and other waste

products on carpets and wet cleanable fabrics. For best results, treat affected area as soon after occurrence as possible.

2. HAZARDS IDENTIFICATION Classification of the substance or mixture Classification Physical Hazards: Not classified. Health Hazards: Not classified. Environmental Hazards: Not classified. Classification (67/548/EEC or 1999/45/EC) Human health: Contact with solution may cause mild transient irritation to eyes and skin. Considered to be a

low inhalation hazard at normal workplace temperatures. Product is acidic and may be mildly corrosive to mucous membranes. Ingestion may cause: irritation nausea Environmental: The product is expected to be biodegradable. Label Elements Hazard Statements: NC Not classified Precautionary Statements: P102 Keep out of reach of children.

P262 Do not get in eyes, on skin, or on clothing. P280 Wear protective gloves. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing. P313 Get medical advice/attention. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor.

Detergent labelling < 5% non-ionic surfactants, < 5% perfumes, Contains d-Limonene, DMDM Hydantoin, Iodopropynyl butylcarbamate, Methylchloroisothiazolinone, Methylisothiazolinone

Other hazards: See section 8 for details of exposure limits. 3. COMPOSITION / INFORMATION ON INGREDIENTS Composition Comments: None of the ingredients are required to be listed. 4. FIRST AID MEASURES Description Of First Aid Measures Inhalation: Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Get medical attention if any discomfort continues. Ingestion: Do not induce vomiting. Rinse mouth thoroughly with water. Give plenty of water to drink. Never give anything by mouth to an unconscious person. Get medical attention. Skin contact: Rinse immediately with plenty of water. Get medical attention if irritation persists after washing. Eye contact: Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide

apart. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.

Most important symptoms and effects, both acute and delayed: Ingestion: Product is acidic and may be mildly corrosive to mucous membranes. Ingestion may cause:

nausea, irritation. Skin Contact: Prolonged or repeated exposure may cause: skin irritation and dermatitis.


Indication of any immediate medical attention and special treatment needed Notes for the Doctor: If swallowed, get medical attention. 5. FIRE FIGHTING MEASURES Extinguishing Media: The product is not flammable. Use fire extinguishing media appropriate for surrounding fire.

Water spray, dry powder or carbon dioxide.

Special hazards arising from the substance or mixture Specific Hazards: No unusual fire or explosion hazards noted. Hazardous combustion Prods: Thermal decomposition or combustion products may include the following substances:

Oxides of carbon. Acids – organic. Advice for Firefighters Special Protective Eqpt for Fire Fighters: No specific recommendations. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Eqpt & Emergency Procedures Personal Precautions: Wear protective clothing as described in section 8 of this SDS. Environmental precautions: Do not discharge into drains, water courses or onto the ground.

Methods And Material For Containment And Cleaning Up Methods for Cleaning Up: Absorb spillage with non-combustible, absorbent material. Collect and place in suitable waste disposal containers and seal securely. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. Reference to other sections: For Personal Protection see Section 8. For Waste Disposal, see Section 13. 7. HANDLING AND STORAGE Precautions for safe handling: Wear protective clothing as described in Section 8 of this Safety Data Sheet. Wash hands after handling. Wash contaminated clothing before reuse. Do not eat drink or smoke when using the product. Conditions for safe storage, Keep out of reach of children. Store in original closed container at temperatures between 5ºC Including any incompatibilities: and 30ºC. Specific end use(s): The identified uses for this product are detailed in section 1. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control Parameters Occupational Exposure Limits Ingredient Comments: No exposure limits noted for ingredient(s). Exposure controls Protective Equipment: Appropriate Engineering Controls: Provide adequate ventilation Eye/Face Protection: Not required in normal use. Hand Protection: Wear protective gloves. Nitrile gloves are recommended. Protective gloves should be

inspected for wear before use and replaced regularly in accordance with the manufacturers specifications.

Hygiene Measures: Wash hands thoroughly after handling. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using the product. Respiratory Protection: Not required in normal use. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties: Appearance: Clear liquid Colour: Colourless Odour: Lemon, floral pH (Concentrated Solution): 4 Initial boiling point and range: 100°C Flash Point °C: Not applicable Evaporation Rate: Not determined Upper/Lower Flammability/Explosive Limits: Not applicable Vapour Pressure: Not determined Vapour Density: Not determined


Relative Density: 1.0 Solubility: Soluble in water Partition Coefficient: Not determined Viscosity: Not determined Explosive Properties: Not applicable Oxidising Properties: Not applicable Other Information: None. 10. STABILITY AND REACTIVITY Reactivity: There are no known reactivity hazards associated with this product. Chemical stability: Stable at normal ambient temperatures, and when used as recommended. Possibility of hazardous reactions: Not determined. Conditions to avoid: Store in original closed container at temperatures between 5ºC and 30ºC. Protect from freezing and direct sunlight. Incompatible materials: Strong oxidising substances. Hazardous decomposition products: Thermal decomposition or combustion products may include the following substances: Oxides of carbon. Acids – Organic. 11. TOXICOLOGICAL INFORMATION Information On Toxicological Effects Toxicological Effects: Product is acidic and may be mildly corrosive to mucous membranes. Ingestion may cause: nausea, irritation. Limited inhalation hazard at work temperatures. Skin Corrosion/ Irritation: Prolonged or repeated exposure may cause the following adverse effects: skin irritation and dermatitis. Serious Eye Damage/Irritation: Contact with concentrate may produce mild transient irritation if not promptly rinsed. Skin Sensitisation: Contains Limonene. Germ Cell Mutagenicity: Genotoxicity – In Vivo - No effects expected based upon current data. Carcinogenicity: No effects expected based upon current data. Reproductive Toxicity: Reproductive Toxicity – Fertility - No effects expected based upon current data.

12. ECOLOGICAL INFORMATION Toxicity: This product is not expected to be hazardous to the environment.

Persistence and Degradability Persistence & Degradability: The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Bioaccumulative Potential: Not known. Partition Co-efficient: Not determined.

Mobility in Soil Mobility: The product is soluble in water. Results of PBT and vPvB assessment: This product does not contain any PBT or vPvB substances. Other adverse effects: None known. 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods: Dispose of waste and residues in accordance with local authority requirements. Empty

containers should be rinsed with water then crushed and disposed of at legal waste disposal site.

14. TRANSPORT INFORMATION UN No.: Not classified for transportation. UN Proper Shipping Name: None

Transport Hazard Class(es) ADR/RID Class: - IMDG Class: -

Packing Group: None.

Environmental Hazards Environmentally Hazardous Substance/Marine Pollutant: None.

Special Precautions for User: None. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable.


15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: UK Regulatory References: The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) (as amended). The Chemicals (Hazard Information & Packaging for Supply) Regulations 2009 (SI 2009 No.716). EU Legislation: Regulation (EC) No 1907/2006 of the European Parliament & of the Council of 18 December

2006 concerning the Registration, Evaluation, Authorisation & Restriction of Chemicals (REACH) (as amended). Regulation (EC) No 1272/2008 of the European Parliament & of the Council of 16 December 2008 on classification, labelling and packaging of substances & Mixtures (as amended). Chemical Safety Assessment: No chemical safety assessment has been carried out.. 16. OTHER INFORMATION Risk Phrases In Full: NC Not classified. SDS Revision Date: R153 9th December 2014

For additional information on safety, training and use of this product contact the supplier. This product is intended for professional use only. The information given is intended to be of assistance to users but is without guarantee. Variations can occur in application and users are advised to conduct their own tests. Suggestions for use neither give nor imply any guarantee as to the intended use. End of Safety Data Sheet



R153 URINE SPOTTER AND DEODORISER

Product Name: Urine Spotter & Deodoriser Product Code: R153 Revision Date: 24/08/07

Below is a list of ingredients present in his formulation, in order for decreasing abundance by weight. Please note – this list corresponds to the most recent formulation of this product. If you require information on an older batch or formulation, please contact us for details

Water Alcohol ethoxylate with 9MEO Sodium lauryl sulphate Ammonium lauryl sulphate Glycolic acid Sodium xylene sulphate Parfum Limonene Methoxyacetic acid Butylene glycol Iodopropynil butyl carbamate Methylchloroisothiazolinone and methylisothiazolinone

Link to table of correspondence on INCI name and CAS no’s:

http://ec.curopa.eu.enterprise/cosmetics/html/cosm inci index.htm

r123 grease, gum and tar remover - hugh...

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