plasticizer chemical content - nan ya petrochemicals 1st div

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南亞化工一部產品 Our Products Portfolio 可塑劑 Plasticizers 鄰苯二甲酸二(2-乙基已基)酯 DEHP (Di-2-Ethylhexyl Phthalate) 鄰苯二甲酸二異壬酯 DINP (Di-Isononyl Phthalate) 鄰苯二甲酸二異癸酯 DIDP (Di-Iso-Decyl Phthalate) 鄰苯二甲酸二丁酯 DBP (Di-Butyl Phthalate) 已二酸二(2-乙基已基)酯 DOA (Di 2-Ethylhexyl Adipate) 已二酸二異壬酯 DINA (Di-Isononyl Adipate) 偏苯三酸三辛酯 TOTM (Tris (2-Ethylhexyl) Trimellitate) 1,2環已烷二羧酸異壬酯 DHIN (1, 2-Cyclohexane Dicarboxylic Acid, di-Isononyl Ester) 1,2環已烷二羧酸異辛酯 DHEH (Bis(2-Ethylhexyl) Cyclohexane-1, 2-Dicarboxylate) 鄰苯二甲酐 PA (Phthalic Anhydride) 醇類 Alcohols 異辛醇 2EH (2-Ethylhexanol) 異丁醇 IBA (Isobutanol) 異壬醇 INA (Isononanol) 抗氧化劑及改質劑 Anti- Oxidants and Modifiers 受阻酚系抗氧化劑 NYNOX-1010/ 1010G 受阻酚系抗氧化劑 NYNOX-1076/ 1076G 抗氧化劑 NYNOX-BLENDS 氯化聚乙烯 NYCPE 81136 氯化聚乙烯 NYCPE 91136 硬化劑 Curing Agent 四氫酞酐 THPA (Tetra Hydro-Phthalic Anhydride) 六氫酞酐 HHPA1 (Hexa Hydro-Phthalic Anhydride) 甲基四氫酞酐 MTHPA2 (Methtyl Tetra Hydro-Phthalic Anhydride) 甲基六氫酞酐 4MHHPA (Methtyl Hexa Hydro-Phthalic Anhydride)

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Page 1: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

南亞化工一部產品 Our Products Portfolio

可塑劑 Plasticizers

鄰苯二甲酸二(2-乙基已基)酯 DEHP (Di-2-Ethylhexyl Phthalate)

鄰苯二甲酸二異壬酯 DINP (Di-Isononyl Phthalate)

鄰苯二甲酸二異癸酯 DIDP (Di-Iso-Decyl Phthalate)

鄰苯二甲酸二丁酯 DBP (Di-Butyl Phthalate)

已二酸二(2-乙基已基)酯 DOA (Di 2-Ethylhexyl Adipate)

已二酸二異壬酯 DINA (Di-Isononyl Adipate)

偏苯三酸三辛酯 TOTM (Tris (2-Ethylhexyl) Trimellitate)

1,2環已烷二羧酸異壬酯 DHIN (1, 2-Cyclohexane Dicarboxylic Acid, di-Isononyl Ester)

1,2環已烷二羧酸異辛酯 DHEH (Bis(2-Ethylhexyl) Cyclohexane-1, 2-Dicarboxylate)

鄰苯二甲酐 PA (Phthalic Anhydride)

醇類 Alcohols

異辛醇 2EH (2-Ethylhexanol)

異丁醇 IBA (Isobutanol)

異壬醇 INA (Isononanol)

抗氧化劑及改質劑 Anti- Oxidants and Modifiers

受阻酚系抗氧化劑 NYNOX-1010/ 1010G

受阻酚系抗氧化劑 NYNOX-1076/ 1076G

抗氧化劑 NYNOX-BLENDS

氯化聚乙烯 NYCPE 81136

氯化聚乙烯 NYCPE 91136

硬化劑 Curing Agent

四氫酞酐 THPA (Tetra Hydro-Phthalic Anhydride)

六氫酞酐 HHPA1 (Hexa Hydro-Phthalic Anhydride)

甲基四氫酞酐 MTHPA2 (Methtyl Tetra Hydro-Phthalic Anhydride)

甲基六氫酞酐 4MHHPA (Methtyl Hexa Hydro-Phthalic Anhydride)

Page 2: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

鄰苯二甲酸二(2-乙基已基)酯

DEHP (Di-2- Ethylhexyl Phthalate)

說明 Description

DEHP是由2-Ethylhexanol與Phthalic Anhydride

酯化而成。DEHP與PVC的相容性極佳,可塑化效

率高且兼具各種可塑劑之平均性能。為使用在PVC

加工上,用量最大的可塑劑。

規格 Specifications (一般級A)

色 相 Appearance APHA 25 Max

酸 價 Acid Value mgKOH/g 0.05 Max

比 重 Specific Gravity 20/20℃ 0.986±0.003

水 分 Moisture Wt % 0.05 Max

酯化價 Esterification Number mgKOH/g 287±3

酯含量 Ester Content Wt % 99.0 Min

物性 Physical Properties

分子式 Molecular Formula C24H38O4

構造式 Structural Formula

分子量 Molecular Weight g/mole 390

沸 點 Boiling Point (760mmHg) ℃ 386

閃火點 Flash Point ℃ 210

粘 度 Viscosity (30℃) cps 43

流動點 Freezing Point ℃ -53

用途 Usage

● 電線電纜 ● 膠皮膠布 ● 手套 ● 鞋子 ● 建材

● 醫療器材 ● PVC可塑糊等。

■ 4–1

DEHP is produced by esterifying 2-Ethylhexanol

and Phthalic Anhydride. It is highly compatible

with PVC and has an excellenat plasticizing

efficiency and average characteristc of

various plasticizers. In PVC processing, the

consumption of DEHP is the highest among all

plasticizers.

● Wires & Cables ● Leather & Clothes ● Gloves

● Shoes ● Construction Materials

● Medical devices ● PVC Plastisols, etc.

C

C

O-C8H17

O

O

==

O-C8H17

Page 3: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

鄰苯二甲酸二(2-乙基已基)酯

DEHP (Di-2- Ethylhexyl Phthalate)

鄰苯二甲酸二(2-乙基已基)酯

DEHP (Di-2- Ethylhexyl Phthalate)

說明 Description

DEHP是由2-Ethylhexanol與Phthalic Anhydride

酯化而成。DEHP與PVC的相容性極佳,可塑化效

率高且兼具各種可塑劑之平均性能。為使用在PVC

加工上,用量最大的可塑劑。

規格 Specifications (絕緣級B)

色 相 Appearance APHA 25 Max

酸 價 Acid Value mgKOH/g 0.05 Max

酯化價 Esterification Number mgKOH/g 287±3

酯含量 Ester Content Wt % 99.0 Min

加熱減量 Heating Loss 125℃x3hr % 0.20 Max

比 重 Specific Gravity 20/20℃ 0.986±0.003

折射率 Refractive Index 25℃ 1.485±0.003

絕緣抵抗 Volume Resistivity 30℃ Ω.com 3x10" Min

物性 Physical Properties

分子式 Molecular Formula C24H38O4

構造式 Structural Formula

分子量 Molecular Weight g/mole 390

沸 點 Boiling Point (760mmHg) ℃ 386

閃火點 Flash Point ℃ 210

粘 度 Viscosity (30℃) cps 43

流動點 Freezing Point ℃ -53

用途 Usage

● 電線電纜 ● 膠皮膠布 ● 手套 ● 鞋子 ● 建材

● 醫療器材 ● PVC可塑糊等。

■ 4–1

DEHP is produced by esterifying 2-Ethylhexanol

and Phthalic Anhydride. It is highly compatible

with PVC and has an excellenat plasticizing

efficiency and average characteristc of

various plasticizers. In PVC processing, the

consumption of DEHP is the highest among all

plasticizers.

● Wires & Cables ● Leather & Clothes ● Gloves● Shoes ● Construction Materials ● Medical devices ● PVC Plastisols, etc.

C

C

O-C8H17

O

O

==

O-C8H17

Page 4: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

鄰苯二甲酸二(2-乙基已基)酯

DEHP (Di-2- Ethylhexyl Phthalate)

說明 Description

DEHP是由2-Ethylhexanol與Phthalic Anhydride

酯化而成。DEHP與PVC的相容性極佳,可塑化效

率高且兼具各種可塑劑之平均性能。為使用在PVC

加工上,用量最大的可塑劑。

規格 Specifications (手套級C)

色 相 Appearance APHA 25 Max

酸 價 Acid Value mgKOH/g 0.05 Max

酯化價 Esterification Number mgKOH/g 287±3

酯含量 Ester Content Wt % 99.0 Min

比 重 Specific Gravity 20/20℃ 0.986±0.003

折射率 Refractive Index 25℃ 1.485±0.003

水 分 Moisture Wt % 0.05 Max

物性 Physical Properties

分子式 Molecular Formula C24H38O4

構造式 Structural Formula

分子量 Molecular Weight g/mole 390

沸 點 Boiling Point (760mmHg) ℃ 386

閃火點 Flash Point ℃ 210

粘 度 Viscosity (30℃) cps 43

流動點 Freezing Point ℃ -53

用途 Usage

● 電線電纜 ● 膠皮膠布 ● 手套 ● 鞋子 ● 建材

● 醫療器材 ● PVC可塑糊等。

■ 4–1

DEHP is produced by esterifying 2-Ethylhexanol

and Phthalic Anhydride. It is highly compatible

with PVC and has an excellenat plasticizing

efficiency and average characteristc of

various plasticizers. In PVC processing, the

consumption of DEHP is the highest among all

plasticizers.

● Wires & Cables ● Leather & Clothes ● Gloves

● Shoes ● Construction Materials

● Medical devices ● PVC Plastisols, etc.

C

C

O-C8H17

O

O

==

O-C8H17

Page 5: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

說明 Description

DINP是由Iso-Nonanol與Phthalic Anhydride酯化

而成。在許多方面DINP的塑化性質與DEHP類似。

然而DINP本身所具備的低揮發性與低可塑化效率,

使得DINP在一些應用上頗佔優勢。DINP屬一般用

途的可塑劑,與DEHP比較,它擁有較低的可塑化

效率、移行性、水萃取率及稍高的膠化溫度與電

子阻抗。DINP低揮發性,不僅能延長產品壽命還

能降低製程中的蒸發逸散。以DINP來取代具有較

高可塑化效率及比重的DEHP,往往可以節省相當

的體積成本費用。

規格 Specifications

色 相 Appearance APHA 25 Max

酸 價 Acid Value mgKOH/g 0.05 Max

酯化價 Esterification Number mgKOH/g 267±5

酯含量 Ester Content Wt % 99.0 Min

加熱減量 Heating Loss 125℃x3hr Wt % 0.10 Max

比 重 Specific Gravity 20/20℃ 0.974±0.005

折射率 Refractive Index 25℃ 1.484±0.003

物性 Physical Properties

分子式 Molecular Formula C26H42O4

構造式 Structural Formula

分子量 Molecular Weight g/mole 419

沸 點 Boiling Point (760mmHg) ℃ 403

閃火點 Flash Point ℃ 213

粘 度 Viscosity (30℃) cps 45

流動點 Freezing Point ℃ -50

用途 Usage

● 電線電纜 ● 膠皮膠布 ● 手套 ● 鞋子 ● 建材

● 塑膠製品 ● 食品包裝、玩具及吹氣

■ 4–2

DINP is produced by esterifying Isononanol and Phthalic Anhydride. DINP's plasticizing characteristic is similar to that of DEHP in many ways. However, DINP's low volatility and low plasticizing efficiency are advantageous in some applications. DINP is a plasticizer for general purpose. To compare with DEHP, its plasticizing efficiency, migration and water extraction rate are lower and its gelation temperature and electric resistivity are midly higher. DINP's low volatility not only prolongs the service life of product but also reduces the evaporation during process. DINP can be used to substitute DEHP, of which the plasticizing efficiency and specific gravity is higher, to save a considerable cost per volume.

● Wires & Cables ● Leather & Clothes ● Gloves● Shoes ● Construction Materials ●Plastic Products ● Food Wrapping, Toys and Plastic Inflation Products ● PVC Plastisols, etc.

C

C

O-C9H19

O

O

==

O-C9H19

鄰苯二甲酸二(2-乙基已基)酯

DEHP (Di-2- Ethylhexyl Phthalate)

鄰苯二甲酸二異壬酯

DINP (Di- Isononyl Phthalate)

Page 6: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

鄰苯二甲酸二異癸酯

DIDP (Di- Iso-Decyl Phthalate)

說明 Description

DIDP是由Iso-Decanol與Phthalic Anhydride酯化

而成。DIDP的低揮發性與優良低溫特性,使得

DIDP被應用在不同種的加工上。DINP具有良好的

電子阻抗及高溫特性,因此在PVC電纜上廣泛的

運用,尤其在高溫級電纜方面。與DEHP比較,使

用DIDP於PVC加工上膠化溫度需提高5-10℃。因

此在加工條件上必須作一些調整,調整的方式視

所使用的製程與設備而定。一般成品均會添加抗

氧化劑丙二酚,以提高耐熱性,並且可以抑制氧

化作用防止變色、分解及發揮。

規格 Specifications

色 相 Appearance APHA 30 Max

酸 價 Acid Value mgKOH/g 0.07 Max

酯化價 Esterification Number mgKOH/g 251±3

酯含量 Ester Content Wt % 98.5% Min

加熱減量 Heating Loss 125℃x3hr Wt % 0.10 Max

絕緣抵抗 Volume Resistivity 30℃ Ω-cm 2.0x10 E11 Min

比 重 Specific Gravity 20/20℃ 0.968±0.003

折射率 Refractive Index 25℃ 1.483±0.003

BPA Content Wt % 0.5±0.1

物性 Physical Properties

分子式 Molecular Formula C28H46O4

構造式 Structural Formula

分子量 Molecular Weight g/mole 446

沸 點 Boiling Point (760mmHg) ℃ 420

閃火點 Flash Point ℃ 231

粘 度 Viscosity (30℃) cps 72

流動點 Freezing Point ℃ -50

用途 Usage● 電線電纜 ● 膠皮膠布 ● 手套 ● 鞋子

● 建材 ● PVC可塑糊等。

■ 4–3

DIDP is produced by esterifying Iso-Decanol and Phthalic Anhydride. DIDP's low volatility and superior low-temperature characteristic make it applicable to various processes. Its excellent electric resistivity and high-temperature characteristic make it widely applied to the manufacturing of PVC cable especially cable of high temperature level. To compare with DEHP in PVC processing, DIDP's gelation temperature required is 5-10℃ higher than that of DEHP. Therefore, some adjustment in processing conditions must be made. The method of adjustment varies according to the production process adoped and equipment used. Generally speaking, most DIDP are added with antioxidant Bisphenol A to increase heat resistance, control oxidation and prevent discoloration, decomposition and evaporation.

● Wires & Cables ● Leather & Clothes ● Gloves● Shoes ● Construction Materials ● PVC Plastisols, etc.

C

C

O-C10H21

O

O

==

O-C10H21

Page 7: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

鄰苯二甲酸二丁酯

DBP (Di- Butyl Phthalate)

說明 Description

DBP由Butanol與Phthalic Anhydride酯化而成。

DBP與PVC的相容性良好,可塑化效率高。低劑

量即可達到相當的柔軟性,是一種泛用的一次可

塑劑,常做為膠化促進劑之用,其缺點為揮發性

高,成型時重量損失大。耐老化性差,耐寒性不

佳,電氣阻抗差,耐久性差;易移行,低溫急速

脆化,溶劑抽出性高。

規格 Specifications

色 相 Appearance APHA 40 Max

酸 價 Acid Value mgKOH/g 0.05 Max

酯化價 Esterification Number mgKOH/g 399-407

酯含量 Ester Content Wt % 99.0 Min

加熱減量 Heating Loss 125℃x3hr Wt % 1.0 Max

絕緣抵抗 Volume Resistivity 30℃ Ω-cm -

比 重 Specific Gravity 20/20℃ 1.045-1.051

物性 Physical Properties

分子式 Molecular Formula C16H22O4

構造式 Structural Formula

分子量 Molecular Weight g/mole 270

沸 點 Boiling Point (760mmHg) ℃ 340

閃火點 Flash Point ℃ 170

粘 度 Viscosity (30℃) cps 15

流動點 Freezing Point ℃ -35

用途 Usage

● 水管 ● 塑膠板 ● 塗料 ● 乙烯地磚

● 聚醋酸乙烯酯接著劑等。

■ 4–8

DBP is produced by esterifying Butanol

and Phthalic Anhydride. DBP has excellent

compatibility with PVC and has high plasticizing

efficiency. A considerable low dosage is

enough to reach satisfactory flexiblity. It is a

primary plasticizer for general purpose and

often used as gelation agent. Its defect is

higher volatility which would causes great loss

during compounding. Its aging resistance, cold

resistance, electric resistivity, and durability

are inferior. It is easy to migration and embrittle

in low temperature, its solvent extractability is

high.

● Hoses ● Plastic Plates ● Paints

● Vinyl Tiles ● Poly-VinylAcetate adhesives, etc.

C

C

O-C4H9

O

O

==

O-C4H9

Page 8: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

已二酸二(2-乙基已基)酯

DOA (Di 2-Ethylhexyl Adipate)

說明 Description

DOA是由2-Ethylhexanol與Adipic Acid酯化而成,

是非鄰苯二甲酸酯可塑劑。DOA具備良好的低溫

性質與PVC糊的特徵,並且為FDA所許可的食用

級可塑劑。為使用量最大的耐寒可塑劑;在柔軟

度相當的成品中,DOA的揮發率比DEHP高。

DOA具有較低的電子低抗,因此符合反靜電加工

產品,如輸送帶、地板材料等。

規格 Specifications

色 相 Appearance APHA 30 Max

酸 價 Acid Value mgKOH/g 0.06 Max

酯化價 Esterification Number mgKOH/g 302±3

酯含量 Ester Content Wt % 99.0 Min

加熱減量 Heating Loss 125℃x3hr Wt % 0.2 Max

比 重 Specific Gravity 20/20℃ 0.926±0.003

折射率 Refractive Index 25℃ 1.446±0.003

物性 Physical Properties

分子式 Molecular Formula C22H42O4

構造式 Structural Formula

分子量 Molecular Weight g/mole 371

沸 點 Boiling Point (760mmHg) ℃ 335

閃火點 Flash Point ℃ 192

粘 度 Viscosity (30℃) cps 9.6

流動點 Freezing Point ℃ -70

用途 Usage

● 電線電纜.膠皮膠布 ● 手套 ● 鞋子

● 建材 ● PVC可塑糊 ● 潔美膠膜等。

■ 4–9

DOA is produced by esterifying 2-Ethylhexanol

and Adipic Acid, non-phthalate plasticizer.

DOA has excellent low temperature and

PVC plastisol characteristics and is an edible

plasticizer approved by FDA. Its consumption

is the highest among all cold resisting

plasticizers. For finished products of equal

flexibility, DOA's volatility is higher than that

of DEHP. DOA has a lower electric resistivity

which makes it suitable for the manufacturing

of anti- static processed products such as

conveying belt and floor material, etc.

● Wires & Cables ● Leather & Clothes ● Gloves ● Shoes ● Construction Materials● PVC Plastisols ● Food Wrapping, etc.

Bu EtO

OOO

BuEt

Page 9: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

已二酸二異壬酯

DINA (Di- Isononyl Adipate)

說明 Description

DINA由IsoNonanol與Adipic Acid酯化而成。其可

塑性效率與相同,但耐寒性及耐揮發性則優於

DOA,且為非鄰苯二甲酸酯可塑劑。

規格 Specifications

色 相 Appearance APHA 30 Max

酸 價 Acid Value mgKOH/g 0.06 Max

酯化價 Esterification Number mgKOH/g 282±3

酯含量 Ester Content Wt % 99.0 Min

加熱減量 Heating Loss 125℃x3hr Wt % 0.10 Max

比 重 Specific Gravity 20/20℃ 0.923±0.005

折射率 Refractive Index 25℃ 1.449±0.003

物性 Physical Properties

分子式 Molecular Formula C24H46O4

構造式 Structural Formula

分子量 Molecular Weight g/mole 399

沸 點 Boiling Point (5mmHg) ℃ 227

閃火點 Flash Point ℃ 242

粘 度 Viscosity (30℃) cps 14

流動點 Freezing Point ℃ -63

用途 Usage

● 電線電纜 ● 膠皮膠布 ● 手套 ● 鞋子

● 建材 ● PVC可塑糊 ● 潔美膠膜

● 耐寒PVC製品等。

■ 4–10

DINA is produced by esterifying Isononanol

and Adipic Acid. Its plasticizing efficiency is the

same as that of DOA but its cold resistance

and volatility resistance are superior to those of

DOA. it is non-phthalate plasticizer.

● Wires & Cables ● Leather & Clothes ● Gloves

● Shoes ● Construction Materials

● PVC Plastisols ● Food Wrapping

● Cold-resisting Products, etc.

Bu

O

O

O

O

Bu

Page 10: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

偏苯三酸三辛酯

TOTM (Tris (2-Ethylhexyl) Trimellitate)

說明 Description

TOTM是由2-Ethylhexanol與Trimellitic Anhydride

酯化而成。TOTM具備低揮發性、低移行性、良好

的電子抵抗及耐熱性。TOTM使用在電線電纜上,

可通過美國UL62 105℃級的檢查。TOTM移行性及

耐水萃取性均較DIDP低,在相同的柔軟度與DEHP

作比較,TOTM具有較低的耐寒性。在PVC可塑糊

方面,在柔軟度相同的條件下,以TOTM基底的可

塑糊黏度比DIDP低。在穩定性方面,TOTM與

DEHP作比較,TOTM可塑糊具較少的變化,即較

穩定。

規格 Specifications

色 相 Appearance APHA 100 Max

酸 價 Acid Value mgKOH/g 0.20 Max

酯化價 Esterification Number mgKOH/g 308±5

酯含量 Ester Content Wt % 98.5% Min

加熱減量 Heating Loss 125℃x3hr Wt % 0.15 Max

絕緣抵抗 Volume Resistivity 30℃ Ω-cm 1.0x10 E11 Min

比 重 Specific Gravity 20/20℃ 0.992±0.005

折射率 Refractive Index 25℃ 1.483±0.005

BPA Content Wt % 0.5±0.1

物性 Physical Properties

分子式 Molecular Formula C33H54O6

構造式 Structural Formula

分子量 Molecular Weight g/mole 547

沸 點 Boiling Point (760mmHg) ℃ 430

閃火點 Flash Point ℃ 426

粘 度 Viscosity (30℃) cps 244

流動點 Freezing Point ℃ -55

用途 Usage

● 電線電纜 ● 膠皮膠布 ● 手套 ● 鞋子

● 建材 ● PVC可塑糊等。

■ 4–11

TOTM is produced by esterifying 2-Ethylhexanol and Trimellitic Anhydride.TOTM has low volatility and low migration and its eletric resistivity and heat resistance are excellent. The wire and cable to which TOTM is applied in the process can pass USA UL 62 105℃ class. TOTM's migration and water extraction are lower than those of DIDP. To compare with DEHP at the same flexibility, TOTM's cold resistance is lower. With respect to PVC plastisol, under the condition of same flexibility, the viscosity of plastisol made with TOTM base is lower to that made with DIDP. As regards stability, since TOTM plastisol changes less than DEHP, it is considered more stable than DEHP.

● Wires & Cables ● Leather & Clothes ● Gloves● Shoes ● Construction Materials● PVC Plastisols, etc.

C

C

O-C8H17H17O8O

O

O

=

O

=

=

C

O-C8H17

Page 11: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

1,2環已烷二羧酸異壬酯

DHIN (1,2-Cyclohexane Dicarboxylic Acid,di- Isononyl Ester)

說明 Description

DHIN由異壬醇及六氫酐酐酯化而成。是為非苯二

甲酸酯可塑劑。DHIN具有低移行性,且適合於敏

感性應用,特別是食品包裝材、密封材、兒童玩

具、醫療器材及吹氣塑膠製品。

認證 Certificates台灣專利 Taiwan Patent NO.I307692

日本食品衛生 JHPA J-8229

SGS測試認證 CR/2010/30481;CE/2010/36305;CE/2010/38161

規格 Specifications色 相 Appearance APHA 25 Max

酸 價 Acid Value mgKOH/g 0.05 Max

酯化價 Esterification Number mgKOH/g 263±5

酯含量 Esterification Number Wt % 99.50 Min

加熱減量 Heating Loss 125℃±3℃x3hr Wt % 0.10 Max

真空比重 Specific Gravity 20/20℃ 0.950±0.005

折射率 Refractive Index 20℃ 1.461±0.003

含水分 Water Content Wt % 0.05 Max

苯二甲酸酯 Phthalate Content Wt % 未檢出(Not Detected)

金屬含量 Metal Content As,Pb,Cr,Sn,Cd, mg/Kg 未檢出(Not Detected)

Hg,Sb,Se,Ba

其 他 Others PHOS,PFOA,PBBs, mg/Kg 未檢出(Not Detected)

PBDEs,PAHs

物性 Physical Properties分子式 Molecular Formula C26H48O4

構造式 Structural Formula

分子量 Molecular Weight g/mole 425.6

沸 點 Boiling Point (~5.25mmHg) ℃ 240~250

閃火點 Flash Point ℃ Approx. 224

粘 度 Viscosity (25℃) cps 47

流動點 Freezing Point ℃ -54

用途 Usage● 食品包裝材 ● 兒童玩具 ● PVC可塑糊

● 醫療器材 ● 非苯二甲酸酯塑膠製品...等。

■ 4–15

DHIN is produced by esterifying Isononanol and Cyclohexane-1, 2-dicarboxylic anhydride, a non- Phthalate plasticizer.DHIN has low migration and is suitable for sensitive applications. It is especially suitable for foodstuffs wrapping, lid seals, children toys, medical devices and plastic inflation products.

● Applications Involving Contact with Food● Children Toys ● PVC Plastisols ● Medical devices ● Non-phthalate Plastic Products/Articles,... etc.

C

C

O-C9H19

O

O

==

O-C9H19

Page 12: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

1,2環已烷二羧酸異辛酯

DHEH (Bis(2-Ethylhexyl) Cyclohexane-1,2- Dicarboxylate)

說明 Description

DHEH由異辛醇(2-乙基己醇)及六氫酐酐酯化而成。

是為非苯二甲酸酯可塑劑。DHEH與DHIN兩者之

間的加工特(性)質區別,在許多方面類似如DEHP

與DINP。與DHIN比較,其可塑化效率及延伸率較

佳。適用於食品包裝材、兒童玩具、醫療器材及

吹氣塑膠製品。

認證 Certificates台灣專利 Taiwan Patent NO.I307692

SGS測試認證 CR/2010/30482;CE/2010/36306;CE/2010/38162

FDA 21 CFR 175.105正表列(Positive List)

規格 Specifications色 相 Appearance APHA 25 Max

酸 價 Acid Value mgKOH/g 0.05 Max

酯化價 Esterification Number mgKOH/g 282±3

酯含量 Esterification Number Wt % 99.50 Min

加熱減量 Heating Loss 125℃±3℃x3hr Wt % 0.20 Max

真空比重 Specific Gravity 20/20℃ 0.953±0.005

折射率 Refractive Index 20℃ 1.457±0.003

含水分 Water Content Wt % 0.05 Max

苯二甲酸酯 Phthalate Content Wt % 未檢出(Not Detected)

金屬含量 Metal Content As,Pb,Cr,Sn,Cd, mg/Kg 未檢出(Not Detected)

Hg,Sb,Se,Ba

其 他 Others PHOS,PFOA,PBBs, mg/Kg 未檢出(Not Detected)

PBDEs,PAHs

物性 Physical Properties分子式 Molecular Formula C24H44O4

構造式 Structural Formula

分子量 Molecular Weight g/mole 396.6

沸 點 Boiling Point (~7.5mmHg) ℃ 240~250

閃火點 Flash Point ℃ Approx. 220

粘 度 Viscosity (25℃) cps 33.5

流動點 Freezing Point ℃ -50

用途 Usage

● 食品包裝材 ● 兒童玩具 ● PVC可塑糊

● 醫療器材 ● 非苯二甲酸酯塑膠製品...等。

■ 4–16

DHEH is produced by esterifying 2-EthylHexanol and Cyclohexane-1, 2-dicarboxylic anhydride, a non- Phthalate plasticizer.The processing characteristic difference between DHEH and DHIN is similar to that between DEHP and DINP in many ways. To compare with DHIN, its plasticizing efficiency and elongation are better. It is suitable for foodstuffs wrapping, children toys, medical devices and plastic inflation products.

C

C

O-C8H17

O

O

==

O-C8H17

● Applications Involving Contact with Food● Children Toys ● PVC Plastisols ● Medical devices ● Non-phthalate Plastic Products/ Articles,... etc.

Page 13: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

鄰苯二甲酐

PA (Phthalic Anhydride)

說明 Description

鄰苯二甲酐是由鄰二甲苯經部份氧化反應而成。

在室溫為白色結晶片狀形態,與水接觸會形成酸。

鄰苯二甲酐主要用以製造鄰苯二甲酸酯類,以作

為PVC加工之可塑劑。

規格 Specifications

凝固點 Solidification Point ℃ ≧130.8 Min

純 度 Purity wt % >99.8 Min

酸酸含量 Phthalic Acid wt % <0.50 Max

熔融色相 Hazen Number (Color) APHA ≦20 Max

加熱安定性 Heat Hazen Number APHA ≦50 Max

物性 Physical Properties

分子式 Molecular Formula C8H4O

構造式 Structural Formula

分子量 Molecular Weight g/mole 148.12

沸 點 Boiling Point (760mmHg) ℃ 285

閃火點 Flash Point ℃ 152

包裝 Packing

液態槽車; Molten:Tank truck;片狀袋裝: 750kg、600kg、500kg、25kg Flake Bag: 750kg、600kg、500kg、25kg

用途 Usage

● 可塑劑原料

● 不飽和聚酯樹酯原料、醇酸樹酯原料

● 染料、驅蟲劑、耐燃劑、…等

■ 4–21

Phthalic Ahydride (PA) is produced by the partial oxidation from orth-xylene. At room temperature it forms white crystal like flakes. In contact with water it results phthalic acid. Phthalic Anhydride is widely used to make phthalate esters used as plasticizers in PVC, Polyvinyl chloride, processing.

● Plasticizers ● Unsaturated polyester and Alkyd resin.● Dyes、Pigments、Insecticides、Fire

retardants、…etc

C

C

O

O

==

O

Page 14: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

異辛醇

2EH (2-Ethylhexanol)

說明 Description

異辛醇(2EH)是由正丁醛進行縮合反應,再經由氫

化反應及蒸餾精餾等過程而產生,其反應物正丁

醛則由丙烯及合成氣經由LP OXO反應形成。2EH

是無色特殊氣味的可燃性液體微溶於水可與多數

有機溶劑互溶。

規格 Specifications

純 度 Purity Wt % ≧99.5

色 相 Color APHA ≦5

硫酸色相 Sulfuric Acid Color APHA ≦20

酸 價 Acidity Wt % ≦0.01

醛含量 Aldehydes Wt % ≦0.05

水份 Water Wt % ≦0.1

物性 Physical Properties

分子式 Molecular Formula C8H17OH

構造式 Structural Formula

分子量 Molecular Weight g/mole 130

顏色 Color 無色液體(Colorless)

沸點 Boiling Point ℃ 183.5

凝固點 Solidifying Point ℃ -76

閃火點(Flash Point) ℃ 81.1

比重 Specific Gravity 20/20℃ 0.83

蒸汽壓 Vapor Pressure 20℃ mm Hg 0.36

折射率 Refractive Index 20℃ 1.43

黏度 Viscosity 20℃ cps 9.8

用途 Usage

● 苯二甲酸二辛酯、己二酸雙辛酯、偏苯三酸三

辛酯、丙烯酸異辛酯之原料

■ 4–23

2EH is produced by processing aldolization,

hydrogenation, distillation and refinement from

n-butyraldehyde that is formed by the LP OXO

reaction of propylene and synthesis gas. 2EH

is flammable and colorless liquid with specific

odor , it is dissolved in water slightly, but can be

dissolved in most organic solvents.

● Raw material for DEHP(Di-2- Ethylhexyl Phthalate)、DOA (Di 2-Ethylhexyl Adipate)、TINTM(Tri-(2-Ethylhexyl) Trimellitate) 、 EHA(2-Ethylhexyl Acrylate)

CH3– CH2– CH2– CH2– CH– CH2– OH ︱ CH2– CH3

Page 15: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

異辛醇

2EH (2-Ethylhexanol)

異丁醇

IBA (Isobutanol)

說明 Description

南亞2EH廠異丁醇(IBA)是由異丁醛進行氫化反應、

蒸餾及精餾而成,它是一種無色有甜味的液體,

可溶於水、醇類及醚類,可作為有機合成上化學

中間物及作為塗料的溶劑。

規格 Specifications

純 度 Purity Wt % ≧99.5

色 相 Color APHA ≦5

酸 價 Acidity Wt % ≦0.005

醛含量 Aldehydes Wt % ≦0.1

水份 Water Wt % ≦0.1

物性 Physical Properties

分子式 Molecular formula C4H9OH

構造式 Structural Formula

分子量 Molecular weight g/mole 74.14

顏色 Color 無色液體 (Colorless)

沸點 Boiling point ℃ 107

凝固點 Solidifying point ℃ -10

閃火點 Flash point ℃ 37.7

比重 Specific Gravity 20/20℃ 0.803

蒸汽壓 Vapor pressure 20℃ mmHg 8.8

折射率 Refractive index 20℃ 1.3955

黏度 Viscosity 20℃ cps 6.68

用途 Usage

● 油漆溶劑、添加劑

■ 4–24

Isobutanol(IBA) of Nan Ya 2EH plant is

produced from iso-butyraldehyde by processing

hydrogenation、distillation and refinement. It is

a colorless liquid with sweet odor, which can be

solved in water, alcohol and ether and can be a

medium in organic synthesis and be a solvent

for paint.

● Solvent for paints、Additives

CH3 – CH2– CH2 – OH ︱ CH3

Page 16: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

異壬醇

INA (Isononanol)

說明 Description

異壬醇(INA)是由辛烯進行甲醯化反應,再經由氫

化反應及蒸餾精餾等過程而產生,辛烯則由丁烯

經由雙聚合反應形成。異壬醇是無色具特殊氣味的

可燃性液體微溶於水可與多數有機溶劑互溶。

規格 Specifications比 重 Specific Gravity 20/20℃ 0.836~0.848

純 度 Purity Wt % ≧99.5

色 相 Color APHA ≦10

硫酸色相 Sulfuric Acid Colo APHA ≦30

蒸餾範圍 Distillation Range

初沸點 Initial Bpt ℃ ≧199.0

乾點 Dry Pt ℃ ≦210.0

水份 Water Wt ﹪ ≦0.05

物性 Physical Properties分子式 Molecular Formula C9H19OH

構造式 Structural Formula 異構物(Isomer):

10 % n-nonyl alcohol

35-40 % methyloctyl alcohol

40-45 % dimethylheptyl alcohol

5-10 % methylethylhexyl

分子量 Molecular weight g/mole 144

顏色 Color 無色液體 (Colorless)

沸點 Boiling point ℃ 199~210

凝固點 Solidifying point ℃ <-75

閃火點 Flash point ℃ 80~96

比重 Specific Gravity 20/20℃ 0.83

蒸汽壓 Vapor pressure 20℃ hpa 0.119~0.026

折射率 Refractive index 20℃ 1.429

黏度 Viscosity 20℃ cps 13

用途 Usage● 苯二甲酸二壬酯、己二酸雙壬酯、偏苯三酸三

壬酯之原料

NYNOX- 1010/ 1010G

INA is produced by processing hydroformalation, hydrogenation, distillation and refinement from octenes that is formed by the dimerization of butanes. INA is flammable and colorless liquid with specific odor , it is dissolved in water slightly, but can be dissolved in most organic solvents.

● Raw material for DINP(Di-Isononyl

Phthalate)、DINA (Di- Isononyl Adipate) 、

TINTM(Tri-Isononyl Trimellitate)

Page 17: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

異壬醇

INA (Isononanol)

受阻酚系抗氧化劑

NYNOX- 1010/ 1010G

說明 Description

NYNOX-1010/1010G是泛用塑膠(PVC, PE, PP,

ABS, PS....等)及工程塑膠(PC)等產品的高效

能添加劑,屬於受阻酚系,主要功能在於防止或

延遲因氧化造成的物性變化與分解。

規格 Specifications

外 觀 Appearance 白色粉末/粒狀 (White Powder/ Granule)

熔 點 Melting Point (DSC) ℃ 110.0~125.0

灰 份 Ash wt % ≦0.1 MAX

揮發度 Volatile Matter wt % ≦0.5 MAX

溶解性 Solubility 室溫下 10g溶於100ml甲苯中為澄清液 10g in 100ml Toluene is clear at room temperature

溶液色相 Color of Solution APHA ≦25 Transmittance at 1cm cell 425nm: ≧95% 500nm: ≧97%

熔融色相 Color of Solution APHA ≦200

熱安定性 Heat Stability ≦1 GARDNER

有效成份 ASSAY wt % ≧98.0

物性 Physical Properties

分子式 Chemical Formula C73H108O12

構造式 Structural Formula

分子量 Molecular Weight g/mole 1176

密 度 Density 20℃ g/mole 1.15

分解溫度 Decomposition temperature >220℃

水溶解力 Solubility in water 不溶 insoluble

蒸汽壓 Vapor pressure 20℃ Pa ~10-10

包裝 Packing

20公斤袋裝 Packed normally in 20kg bags

用途 Usage

● 聚合物加工與製造過程氧化劣解的防止● 增加產品使用期限與長期的耐熱性

■ Tetrakis methylene (3,5- di- tert- butyl- 4- hydroxyl propoinate) Methane

NYNOX-1010/1010G is a highly effective additives to the commodity plastics (like PVC, PE, PP, ABS, PS...etc) and engineering plastics (like PC, POM, PA...etc), belong to hindered phenolic antioxidant. The purpose of NYNOX-1010/1010G is to prevent or delay the oxidation to secure utilization quality and protects these substances against thermo-oxidative degradation.

● Protect polymer against thermo-oxidative degradation during manufacture and processing ● Increase the service life time and heat resistance of finished articles

tBu

O

OO

O

tBu

tBu

tBu

tBu

tBu

tBu

tBu

OO

OO

OHOH

OHOH

Page 18: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

受阻酚系抗氧化劑

NYNOX- 1076/ 1076G

說明 Description

NYNOX-1076/1076G是泛用塑膠(PVC, PE, PP,

ABS, PS....等)及工程塑膠(PC)等產品的高效

能添加劑,屬於受阻酚系,主要功能在於防止或

延遲因氧化造成的物性變化與分解。

規格 Specifications

外 觀 Appearance 白色粉末/片狀 (White Powder/ flake)

熔 點 Melting Point (DSC) ℃ 50.0~55.0

灰 份 Ash wt % ≦0.1

揮發度 Volatile Matter wt % ≦0.5

溶解性 Solubility 室溫下 10g溶於100ml甲苯中為澄清液 10g in 100ml Toluene is clear at room temperature

溶液色相 Color of Solution APHA ≦25 Transmittance at 1cm cell 425nm: ≧97% 500nm: ≧97%

熔融色相 Color of Solution APHA ≦100

熱安定性 Heat Stability ≦1 GARDNER

有效成份 ASSAY wt % ≦99.0

物性 Physical Properties

分子式 Chemical Formula C35H62O3

構造式 Structural Formula

分子量 Molecular Weight g/mole 531

密 度 Density 20℃ g/cm3 1.02

水溶解力 Solubility in water 不溶 insoluble

蒸汽壓 Vapor pressure 20℃ Pa ~2.5 x10-7

包裝 Packing

2包20公斤袋裝放於紙箱內 20kgsx2 bags inside the 50kgs paper carton

用途 Usage

● 聚合物加工與製造過程氧化劣解的防止● 增加產品使用期限與長期的耐熱性

■ Octadecyl- 3- (3,5- di- tert- butyl- 4- hydroxyl)- propoinate

NYNOX-1076/1076G is a highly effective additives to the commodity plastics (like PVC, PE, PP, ABS, PS...etc) and engineering plastics (like PC, POM, PA...etc), belong to hindered phenolic antioxidant. The purpose of NYNOX-1076/1076G is to prevent or delay the oxidation to secure utilization quality and protects these substances against thermo-oxidative degradation.

● Protect polymer against thermo-oxidative degradation during manufacture and processing ● Increase the service life time and heat resistance of finished articles

(CH3)3C

CH2CH2-COOC18H37

(CH3)3C

HO

Page 19: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

抗氧化劑

NYNOX- BLENDS

說明 Description

混合型抗氧化劑是聚烯烷加工安定劑,由受阻酚

系與磷系抗氧化劑預混合組成。

規格 Specifications

NYNOX-B110 50±2% NYNOX 1010 50±2% NYNOX 168

NYNOX-B210 33±2% NYNOX 1010 67±2% NYNOX 168

NYNOX-B310 25±2% NYNOX 1010 75±2% NYNOX 168

NYNOX-B410 20±2% NYNOX 1010 80±2% NYNOX 168

NYNOX-B201 33±2% NYNOX 1076 67±2% NYNOX 168

NYNOX-B401 20±2% NYNOX 1076 80±2% NYNOX 168

包裝 Packing

20公斤袋裝 Packed normally in 20kg bags

2~3包20公斤袋裝放於紙箱內 20kgsx2~3 bags inside the 60kgs paper carton

用途 Usage

NYNOX-B110 改善聚烯經(HDPE/LLDEP/PP)經時熱安定性 Improved ployolefin (HDPE/LLDEP/PP) long terms heat stability

NYNOX-B210 平衡聚烯經(HDPE/LLDEP/PP)經時與加工安定性 Balance of long-terms and processing stability for ployolefin (HDPE/LLDEP/PP)

NYNOX-B310 改善聚烯經(HDPE/LLDEP/PP)加工安定性 Improved processing stability for ployolefin (HDPE/LLDEP/PP)

NYNOX-B410 提供聚烯經(HDPE/LLDEP/PP)優越的加工安定性 Supply superior processing stability for ployolefin (HDPE/LLDEP/PP)

NYNOX-B201 平衡聚烯經(HDPE/LLDEP/PP)經時與加工安定性 Balance of long-terms and processing stability for ployolefin (HDPE/LLDEP/PP)

NYNOX-B401 提供聚烯經(HDPE/LLDEP/PP)優越的加工安定性 Supply superior processing stability for ployolefin (HDPE/LLDEP/PP)

■ 混合型抗氧化劑

NYNOX-BLENDS are premixed processing

stabilizer for polyolefin, assembled by phenolic

antioxidant and phosphite antioxidant.

Page 20: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

氯化聚乙烯

NYCPE 81136

說明 Description

氯化聚乙烯(CPE)是由高密度聚乙烯(HDPE)

氯化反應製得,依不同HDPE原料規格及氯化度,

可得到類橡膠到硬塑膠不同特性的產品,並根據這

些特性可依不同的用途廣泛應用作為PVC/ABS與

彈性體等改質劑。

規格 Specifications

氯含量 Chlorine Content 36±1%

熔化熱 Heat of Fusion ≦1.5 cal/g

揮發份 Volatiles ≦0.3%

物性 Physical Properties

水溶解度 Solubility in water 不溶 Insoluble

味 道 Odor 無味 No odor

形 狀 Form 粉末 Powder

顏 色 Color 灰白 Off- White

成份 Cowponies

氯化聚乙烯 Chlorinated Polyethylene >90%

滑石粉(不含石綿) Talc, No Asbestos Fibers <7%

硬脂酸鈣 Calcium Stearate <3%

包裝 Packing

20公斤袋裝及太空包500公斤 Available in powder packed normally in 20kg

bags or 500kg jumbo bags

用途 Usage

● 軟質PVC膜與硬質PVC板、管、膠粒 ● ABS

● 電線電纜 ● 射出押出成型等之耐衝擊改質劑

■ 氯化聚乙烯 Chlorinated Polyethylene

The chlorinated polyethylene (CPE) is a synthrtic material which is prepared from the substitution reaction of high- density polyethylene and chlorine. By changing the type of raw HDPE, degree of chlorination, it is possible to obtain the wide variety of characters from rubber like to hard plastic form. And depending on each characteristic, the chlorinated polyethylene can be used in various usages such as a modifier of PVC and ABS, elastomer and the like.

● Impact modification of flexible film, and rigidly

PVC sheet, pipe, granule ● ABS ● Cable

● Injection molding and extruded profiles.

Page 21: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

氯化聚乙烯

NYCPE 91136

說明 Description

氯化聚乙烯(CPE)是由高密度聚乙烯(HDPE)

氯化反應製得,依不同HDPE原料規格及氯化度,

可得到類橡膠到硬塑膠不同特性的產品,並根據這

些特性可依不同的用途廣泛應用作為PVC/ABS與

彈性體等改質劑。

規格 Specifications

氯含量 Chlorine Content 36±1%

熔化熱 Heat of Fusion ≦0.5 cal/g (<2j/g)

揮發份 Volatiles ≦0.3%

物性 Physical Properties

水溶解度 Solubility in water 不溶 Insoluble

味 道 Odor 無味 No odor

形 狀 Form 粉末 Powder

顏 色 Color 灰白 Off- White

比 重 Specific Gravity ~1.15

成份 Cowponies

氯化聚乙烯 Chlorinated Polyethylene >90%

滑石粉(不含石綿) Talc, No Asbestos Fibers <7%

硬脂酸鈣 Calcium Stearate <3%

包裝 Packing

20公斤袋裝及太空包500公斤 Available in powder packed normally in 20kg

bags or 500kg jumbo bags

用途 Usage

● 軟質PVC膜與硬質PVC板、管、膠粒 ● ABS

● 電線電纜 ● 射出押出成型等之耐衝擊改質劑

■ 氯化聚乙烯 Chlorinated Polyethylene

The chlorinated polyethylene (CPE) is a synthrtic material which is prepared from the substitution reaction of high- density polyethylene and chlorine. By changing the type of raw HDPE, degree of chlorination, it is possible to obtain the wide variety of characters from rubber like to hard plastic form. And depending on each characteristic, the chlorinated polyethylene can be used in various usages such as a modifier of PVC and ABS, elastomer and the like.

● Impact modification of flexible film, and rigidly

PVC sheet, pipe, granule ● ABS ● Cable

● Injection molding and extruded profiles.

Page 22: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

四氫酞酐

THPA (Tetra Hydro-Phthalic Anhydride)

說明 Description

THPA由馬來酸酐和1,3-丁二烯經由Diels-Alder

縮合反應而成,主要作為不飽和樹脂和醇酸樹脂

的改質劑,可改善樹脂的空乾性、光澤性及密著

性,提高製品品質。

規格 Specifications

熔融色相 Molten Color APHA < 70

凝固點 Solidification Point ℃ > 100

殘酸量 Free Acid Content Wt % < 1.0

純 度 Purity Wt % > 99.5

物性 Physical Properties

分子式 Molecular Formula C8H8O3

構造式 Structural Formula

分子量 Molecular Weight g/mole 152.2

比 重 Specific Gravity 140/20℃ 1.147

沸 點 Boiling Point (760mmHg) ℃ 290

閃火點 Flash Point ℃ 157

THPA具有潮解性,儲存時應遠離水氣,容器開封 THPA is hydroscopic and should be protected 後應盡快使用 from light and moisture.

包裝 Packing

25公斤袋裝, 500公斤太空包裝 25 Kg bags , 500Kg jumbo bags

用途 Usage

● 不飽和聚酯樹脂、醇酸樹脂的改質劑。● 環氧樹脂硬化劑、可塑劑、接著劑、…等。

■ 4–17

THPA is produced by Diels-Alder condensation with maleic anhydride and 1, 3-butadiene. THPA is used mainly as a modifier for unsaturated polyester and alkyd resin to replace part of phthalic anhydride. It can improve the quality of resins and particularly their reactivity in the presence of air and their light fastness.

● As a modifier for unsaturated polyester and

alkyd resin.● Epoxy resin curing agents、Plasticizers、

Adhesives、…etc.

C

CO

O

O

==

Page 23: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

四氫酞酐

THPA (Tetra Hydro-Phthalic Anhydride)

六氫酞酐

HHPA1 (Hexa Hydro Phthalic Anhydride)

說明 Description

HHPA由THPA經由高壓氫化反應而成,主要作為

不飽和樹脂和醇酸樹脂的改質劑,可改善樹脂的空

乾性、光澤性及密著性,提高製品品質。

規格 Specifications

熔融色相 Molten Color APHA < 40

凝固點 Solidification Point ℃ > 34

殘酸量 Free Acid Content Wt % < 1.0

純 度 Purity Wt % > 99.0

物性 Physical Properties

分子式 Molecular Formula C8H10O3

構造式 Structural Formula

分子量 Molecular Weight g/mole 154.2

比 重 Specific Gravity 20/20℃ 1.23

沸 點 Boiling Point (100mmHg) ℃ 203

閃火點 Flash Point ℃ 152

HHPA具有潮解性,儲存時應遠離水氣,容器開封 HHPA is hydroscopic and should be protected 後應盡快使用 from light and moisture.

包裝 Packing

53加侖鍍鋅鐵桶 ( 220 Kg/Drum ) 53 Gallon Zinc plated Drum

用途 Usage

● 不飽和聚酯樹脂、醇酸樹脂的改質劑。● 環氧樹脂硬化劑、可塑劑、接著劑、…等。

■ 4–18

HHPA is produced by hydrogenation from THPA. THPA is used mainly as a modifier for unsaturated polyester and alkyd resin. It can improve the quality of resins and particularly their reactivity in the presence of air and their light fastness.

● As a modifier for unsaturated polyester and

alkyd resin.● Epoxy resin curing agents、Plasticizers、

Adhesives、…etc.

C

CO

O

O

==

Page 24: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

甲基四氫酞酐

MTHPA2 (Methtyl Tetra Hydro Phthalic Anhydride)

說明 Description

MTHPA2由馬來酸酐和異戊二烯經由Diels-Alder

縮合反應而成,主要作為環氧樹脂硬化劑相較胺

類硬化劑而言,具有低黏性、低色相、低揮發性

及較長的potlife 週期。在電氣性及機械強度方面

也較胺類硬化劑為佳。

規格 Specifications

外 觀 Appearance 淡黃色透明液體 Liquid with light color

色 相 Color Less than 150 APHA

酐當量 Anhydride Equivalency g/mole 155~170

殘酸量 Free Acid Content Wt % Less than 1.0

黏 度 Viscosity at 25℃ cps 50~75

比 重 Specific Grarity at 20℃ 1.20±0.03

物性 Physical Properties

分子式 Molecular Formula C9H10O3

構造式 Structural Formula

平均分子量 Average Molecular Weight g/mole 164~166

沸 點 Boiling Point (10mmHg) ℃ 155

閃火點 Flash Point ℃ 147

凝固點 Solidification Point ℃ <-15

MTHPA2具有潮解性,儲存時應遠離水氣,容器 MTHPA2 is hydroscopic and should be protected 開封後應盡快使用 from light and moisture.

包裝 Packing

53加侖鍍鋅鐵桶 ( 220 Kg/Drum ) 53 Gallon Zinc plated Drum

用途 Usage

● 環氧樹脂硬化劑、無溶劑塗料、積層板劑、環 氧接著劑…等。

■ 4–19

MTHPA2 is produced by Diels-Alder condensation with maleic anhydride and isoprence. It is used mainly as a hardener for epoxy resin. Compared with amine hardener, MTHPA2 is low viscosity liquid of light color and low in volatility. Potlife is considerably.

● Epoxy resin curing agents、Sovent

free paints、Laminated boards、Epoxy

adhesives、…etc..

C

CH3C

O

O

O

==

Page 25: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

甲基六氫酞酐

4MHHPA (Methtyl Hexa Hydro Phthalic Anhydride)

說明 Description

4MHHPA由MTHPA經由高壓氫化反應而成,主要

作為環氧樹脂硬化劑,相較胺類硬化劑而言,具有

低黏性、低色相、低揮發性及較長的potlife週期。

在電氣性及機械強度方面也較胺類硬化劑為佳。

規格 Specifications

外 觀 Appearance 無色透明液體 Colorless Liquid

色 相 Color APHA < 15

酐當量 Anhydride Equivalency g/mole 165~175

殘酸量 Free Acid Content Wt % < 0.5

黏 度 Viscosity at 25℃ cps < 60

比 重 Specific Gravity 20/20℃ 1.14±0.02

4MHHPA含量 Content Wt % > 98.5

物性 Physical Properties

分子式 Molecular Formula C9H12O3

構造式 Structural Formula

平均分子量 Average Molecular Weight g/mole 168.2

沸 點 Boiling Point (20mmHg) ℃ 168

閃火點 Flash Point ℃ 145

凝固點 Solidification Point ℃ -29

4MHHPA具有潮解性,儲存時應遠離水氣,容器 4MHHPA is hydroscopic and should be protected

開封後應盡快使用 from light and moisture.

包裝 Packing

53加侖鍍鋅鐵桶或烤漆鐵桶 ( 220 Kg/Drum ) 53 Gallon Zinc plated Drum or Steel Drum.

用途 Usage

● 環氧樹脂硬化劑, 主要用在電子及電氣領域。

■ 4–20

4MHHPA is produced by hydrogenation from MTHPA. It is used mainly as a hardener for epoxy resin. To compare with amine hardener, 4MHHPA is low viscosity liquid of light color and low in volatility. Potlife is considerably longer than amines. Electrical and mechanical properties of cured resins compare favorably with these based on amine hardeners.

● Epoxy resin curing agents, Mainly used in

electric and electron field.

C

CH3C

O

O

O

==

甲基四氫酞酐

MTHPA2 (Methtyl Tetra Hydro Phthalic Anhydride)

Page 26: Plasticizer Chemical Content - NAN YA PETROCHEMICALS 1st Div

(2011. 08. 300)

ELECTRONIC MATERIAL DIV.

ADDRESS:201,TUN HWA N. ROAD, TAIPEI, TAIWAN, R.O.C.

TEL:(886-2)2712-2211 EXT 8258 FAX:(886-2)2718-2258