philips semiconductors - welcome to newmexico.gov

. ,

Philips Semiconductors

December 16, 1996

Mr. Benito Garcia New Mexico Environment Department Hazardous & Radioactive Materials Bureau 2044A Galisteo Street Santa Fe, NM 87505

Certified Mail No. Z 729 721 027

SUBJECT: Quarterly Progress Report

Dear Mr. Garcia:

In compliance with Philips Semiconductors' HSW A permit (NMD000709782-1 ), modified March 18, .!2??· t~ .l~eiftb~.f4~-~~~!x,,R~W"ess report as required The following progress has been made between ept er an'd:December 13, 1996.

• D.l (a) -A description of the work completed and an estimate of the percentage of work completed: Quarterly groundwater monitoring was completed on October 21 and 22 for this period Philips met with the City of Albuquerque (Doug Earp) to discuss their participation in RFI field activities associated with installing additional monitoring wells within and surrounding the former Coronado Municipal Landfill. The City has begun installation of the wells and has completed three of the four planned wells.

D. I (b) - Summaries of all findings, including summaries of laboratory data: A quarterly groundwater monitoring report (P AI; December 9, 1996) is included with this report for your files. This groundwater report includes analytical results for Appendix IX constituents for Philips' monitoring wells MW-1, MW-2, MW-3, and MW-4. The constituents found in the groundwater for this effort were barium, chromium, lead, zinc, dichlorodifluoromethane, bis(2-ethylhexyl)phthalate, and perchloroethylene. Chloromethane, which was detected during the last sampling period, was not detected this quarter. New compounds detected were zinc, lead, and bis(2-ethylhexyl)phthalate, a common laboratory contaminant. Copies of the third and fourth quarter analytical results reports are included with this letter.

D. I (c) - Summaries of all problems or potential problems encountered during the reporting period and actions taken to rectifY problems: No problems to report.

• D. I (d) -Projected work for the next reporting period: Quarterly groundwater monitoring will continue and groundwater samples will be obtained from wells MW-1, MW-2, MW-3, andMW-4 in January 1997. Preliminary samples of the new City wells (ABQ-2, ABQ-3, and ABQ-4) will be taken. A tour of the Facility has been scheduled with NMED fbr 12/17/96. NMED will be reviewing the draft RFI Workplan. Philips will address all NMED comments on the draft RFI Workplan when comments are received

Philips Semiconductors a North American Philips Company 920 I Pan American Freeway, NE Albuquerque, New Mexico 871 13 (505) 822-7000

• _lr

Mr. Benito Garcia, NMEO December 16, 1996

of2

• D. I (e) -Summaries of contacts pertaining to corrective action or environmental matters with representatives of the local community, public interest groups or State government during the reporting pen·od:

City of Albuquerque: Mr. Doug Earp of City of Albuquerque met with Melanie McKinley and John Kinker of Philips to discuss city-installed monitoring well locations. New Mexico Environment Department: Mr. Carl Will informed Melanie McKinley that he is the new permit contact at NMED replacing Stephanie Kruse and that the NMED Facility Manager will be Susan Hoise. Ms. Hoise will be copied on all relevant correspondence. Also, a Facility tour was set for 12/17/96.

D. I(/) - Changes in key project personnel during the reporting period: No Philips changes made.

D. I (g) - Summaries of all changes made in implementation during the reporting period: No changes made.

If you have any questions regarding this submission, please call our technical contact, Melanie McKinley at (505) 822-7634 or John Kinker at (505) 858-2781.

I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fme and imprisonment for knowing violations.

Sincerely,

p£~~tf. Plant Manager

(ENV648)

Enclosures

cc: w/ enclosures:

USEP A Region VI

w/o enclosures: Jim Cochran, Philips EHS Manager James Casey, Philips Legal Counsel Susan Hoines, NMED Environmental Department File

...

Reviewed by:

- ....

ANALYTICAL RESULTS

FOR

PROFESSIONAL ANALYSIS. INC.

QUANTERRA NO. 052189

NOVEMBER 12. 1996

0-- tt-'7 Tony Ciacco

(p_)uanterra Environmental Services

J ''1 ,.

J I I I I I a J i l

Table Of Contents

Standard Deliverable

• Table of Contents

• Narrative

• LIMs Report Key

• Sample Description

• Test Requests

• Analytical Results

• QC Summary

• Chain-of-Custody

• Miscellaneous

Total Number of Pages

Q&.antef.f.a Environmental Services

1

j . 1

]

. I __ j

!.".)

J

··1 "

)

I I I . ,

1

J l

J 2j

Introduction

lj)'\ ~uanterra

Environmental Services

This report presents the analytical results as well as sL 1pporting information to aid in the evaluation and interpretation of the data and is arranged in the fo 11 owing order:

o Sample Description Information o Analytical Test Requests o Analytical Results

Sample arrival and receipt:

The trip blanks. listed on chain of custody forms 69610 and 69611. did not originate from Quanterra.

All analyses at Quanterra are performed so that the maximum concentration of sample consistent with the method is analyzea Dilutions are at times r'equ11'ed to avoid saturation of the detector. to achieve linearity for a specific target compound. or to reduce matrix interferences. In this event. reporting limits are adjusted proportionately. Surrogate compounds may not be measurable in samples which have been diluted.

There were no reportable anomalies associated with the analyses by Method 524.2 .

The MS-QC (batch MS/MSD) RPO Acceptance Limits were exceeded for acenaphthene and pyrene.

There were no reportable anomalies associated with the analyses by Method BOBO.

2

!

1

]

1 ] ~ J

I I I : 1

i

J ]

~

J .

a. :

i ;

' -

Metals

IA)' . ~uanterra


Ther·e were no reportable anomalies associated with the metals analyses.

Sample Description Information

The Sample Description Information lists all of the samples received in this pmject together with the internal laboratory identification number assigned for each sample. Each project received at Quanterra is assigned a unique six digit number. Samples within the project are numbered sequentially. The laboratory identification number is a combination of the six digit project code and the sample sequence number.

Also given in the Sample Description Information is the Sample Type (matrix). Date of Sampling (if known) and Date of Receipt at the laboratory.

Analytical Test Requests

The Analytical Test Requests lists the analyses that were performed on each sample. The Custom Test column indicates where tests have been modified to conform to the specific requirements of this project.

3

··-,

J

' I ·~:.:.r

J I I I

]

IJ)\ ~uanterra


LIMs Repon Key

Section I DescriDtion Om:'Lem:r I Si2ll3IIII'C ~ miort DaI .. ative as a:milicable..

TaDaimd acss-!:'Cf:::::lc: betwc:n the I.ab ID and Sample Dcsc:iptiml Infiu 111arian C1ic::n ID, incinmng man±c. dm and time samp1=i,

and the date I=Ived for all samni:s in the moi=::. Lim sample r:snl%s, t:st mmponcms, n:;iw:ti:ng

Sample ADalysis R:sults Shc::s limits, dares piepared and analyzl::i. and my data auailii::rs. Pa..oes are CI ea,, i zed bv test.

QC LOT Assigmnc:m Rqxm I Cross-rcf:cnc: betwe::l lab IDs and applicable QC bail:!les <DCS. LCS. Blank. MS/SD. DU) Pert=ll ~and R.."'D r:salis. with ac=pcmce limits, fer the 1abomOiy d'aplicare c:mrral samples

DuiWc;nc Cam:rol Sample Rcpart fer eacli test ar: tabnlaICd in tbis IepCJit. These are. m:asm:s of ac::::IIacy and pre::isicm for cC test. A.=prmc: limits arc based tlpOII. Iaixnan:ny histeriC3l data. Pc:=~ resniis for a s:ingi.e !..abcnarory

Labommy Camrol Samp!: R:;xnt Comrol Sampie (If appli:aDle) are tabulaicd in tbis rcpor,,. wiil1 the appii:::ibie a=:ptanc: limits for eacll te:' ...

Per.:= :=v::j" anci R..PD l':Slliis fer mamx-Mattix Soikc'Mairix S - Daplicttc R::nort - pie - speQi= QC sampi:s anci ~ limirs. wbce

appili:lble. T.ois r:pon can be used to assess :natrix d:::!s on an rn.lvsis.

Singi: Camrcl Sampje R::pan I A taOularion of the sm:og::3Ie ~fer the blank fer ~ ami:vses. .

Method Blank R:pcrt I A stmimaiy of the resnlls of the mtlysis ai the I!IC"..hod blank for each t:St.

List of Abbr:viations and T enns

AbbrmatiOll I Term Abb~iation I Term

DCS Dcmlica!e Comrol Sal:tmle MSD I Matrix Soikc Ducifoare DU SamDlc DaDlicaic OCRml I Pn:::mation Batc!l EB Eaammctt Blank OCCaL...-orv I LIMs oc Cati:2DIV FB I Field Blank OCLot I DCSBaICh FD I FlCld Duplicate ND I Not Dc=:ted at or above the

n:tl0Itin2 limit e:xmesscd IDL I =~ D=Qon Umit

QCMatrix I Mmix of the laboramry com:rol samole!s)

LCS Labc11a1111v Comal Smmle RI.. l~Umit MB M::mcd Blank oc l·Qaali!:v Com:ral MDL M::mcd Der=icn Limit SA I Samele MS I MmixSDik= SD I Scike DIIDiicar.c RPD I Relative Perc:m Diffexcnc- TB I TriD Blank ppm (pan-pc:- mg/L ar mg/kg ('DSmlDy) ppb(pan-F- 1 • or ug/kg (USIJ3lly) million) billion) OU.AL " ··- -..-..:;; DU.. I Dilution Facer

"'·

4

-

l ! I

] , •

J ]

]

)

I I ii

t

I .l

. !

J .

Lab ID Cl i ent ID

052189-0001-SA MW-2 052189-0002-SA MW-5 052189-0003-SA MW-6 052189-0004-SA MW-1 052189-0005-TB Trip Blank 052189-0006-SA MW-3 052189-0007-SA MW-4 052189-0008-TB Trip Blank

IAJ\ ~uanterra Environmental Services

SAMPLE DESCRIPTION INFORMATION for

Professional Analysis, Inc.

Matrix

AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS

Sampled Received Date Time Date

21 OCT 96 10:14 22 OCT 96 21 OCT 96 10:34 22 OCT 96 21 OCT 96 10:46 22 OCT 96 21 OCT 96 17:30 22 OCT 96 21 OCT 96 18:00 22 OCT 96 22 OCT 96 09:11 23 OCT 96 22 OCT 96 12:03 23 OCT 96 22 OCT 96 11:50 23 OCT 96

5

I j

J i·

·•

J 1 ]

]

]

J J l

J ~1 ... ..1

Lab ID: 052189

0001 - 0002, 0004 ' 0006, 0007

0003 ' 0005, 0008

#A)\ ~uanterra

Group

ANALYTICAL TEST REQUESTS for

Professional Analysis, Inc.

Code Analysis Description

A Appendix IX Metals (Total) done by ICP Prep - Total Metals, ICP ICP Metals (Total) by Trace ICP Mercury, Cold Vapor AA (Total) Prep - Mercury, Cold Vapor AA (Total) Volatile Organics Prep-Volatile Organics by GC/MS Semivolatile Organics

Appendix IX List Prep - Semivolatile Organics by GC/MS Chlorinated Pesticides and PCB's

Appendix IX Li st Prep - Organochlorine Pesticides/PCBs

(Appendix IX)

B Volatile Organics Prep-Volatile Organics by GC/MS


Page I of I

Custom Test?

N N y N N N N N

N N

by GC N

N N

6

, ' '\ l

. I

i

I I I I g . .

I J

ii

Analytical Results

IJ)' ~uanterra Environmental Services

The analytical results for this project are presented in the following data tables. Each data table includes sample identification information. and when avcilable and appropriate. dates sampled. received. authorized. prepared and analyzed. The authorization date is the date when the project was defined by the client such that laboratory work could begin.

D~t~ sneets contain a 11st1ng of tne parameters measured in each test. the analytical results and the Quanterra reporting limit. Reporting limits are aajus~eo to reflect dilution of the sample. when appropriate. Solid and waste samples are reported on an "as received'' basis. i.e. no correction is made for moisture content.

The results from the Standard Quanterra QA/QC Program. which generates data which are independent of matrix effects. are provided subsequently.

7

. J

. 1

I I I I

. ,

Volatile Organics Method 524.2

Client Name: Client ID:

Professional Analysis, MW-2

Inc.

Lab ID: Matrix: Authorized:

Parameter

Benzene

052189-0001-SA AQUEOUS 22 OCT 96

Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec-Butyl benzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Dibromochloromethane DBCP (l,2-Dibromo-

3-chloropropane) EDB (1,2-Dibromoethane) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethyl benzene Hexachlorobutadiene Isopropylbenzene (Cumene) p-Isopropyltoluene (p-Cymene) Methylene chloride Naphthalene

Sampled: 21 OCT 96 Received: 22 OCT 96

Result

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

Units

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L

IJ~'\ ~uanterra Environmental Services

Prepared: 24 OCT 96 Analyzed: 01 NOV 96

Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

Dilution factor is 1.0. All results and limits are corrected for dilution.

{ ND = Not Detected

Reported By: Paul Smith Approved By: Audrey Cornell

'J ·l : l

I ~. ~ 0.:...

]

]

]

I I I

]

-



Professional Analysis, Inc. MW-2

Lab ID: Matrix:

052189-0001-SA AQUEOUS Sampled: 21 OCT 96 22 OCT 96 Received: 22 OCT 96 Authorized:

Parameter

n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m- & p-Xylenes o-Xylene

Surrogate

Toluene-dB 4-Bromofluorobenzene l,2-Dichloroethane-d4

Result

ND ND ND ND

7 .1 ND ND ND ND ND ND ND ND ND ND ND ND ND

Recovery

96 109 93

Units

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L

% % %

IJ)\ ~uanterra



Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

Limits

70-130 70-130 70-130

Dilution factor is 1.0.

ND = Not Detected

Reported By: Paul Smith

All results and limits are corrected for dilution.

Approved By: Audrey Cornell

(cont.)

9

·-·

l i

]

1 l ]

I I

' 1 :




Inc.


Parameter

Benzene

052189-0002-SA AQUEOUS 22 OCT 96




Result



Units


ug/L ug/L ug/L ug/L ug/L ug/l ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/l ug/L ug/L ug/L ug/L ug/L ug/L

Quanterra Environmental Services


Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0


ND = Not Detected


1(

~---

~ I i

J

]

l ., .

I ~)

]

J I I : 1

I

J l

J

' fl




Lab ID: Matrix:


Parameter


Surrogate


Result

ND ND ND ND 6.6

ND ND ND ND ND ND ND ND ND ND ND ND ND

Recovery

102 117 96

Units


% % %

#j)'\ ~uanterra



Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

Limits

70-130 70-130 70-130

Oil uti on factor is 1.0. All results and limits are corrected for dilution.

ND = Not Detected


(cont.)

11

... ·' J ;J ; .. j

--. !

j , ---,-

1

J

]

1 I I I

I

J

l

. !




Lab ID: 052189-0003-SA Matrix: AQUEOUS Sampled: 21 OCT 96

22 OCT 96 Received: 22 OCT 96 Authorized:

Parameter

Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec-Butyl benzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane cr.loroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Dibromochloromethane DBCP {l,2-Dibromo-

3-chloropropane) EDB (1,2-Dibromoethane) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethyl benzene Hexachlorobutadiene Isopropylbenzene {Cumene) p-Isopropyltoluene {p-Cymene) Methylene chloride Naphthalene

Result



Units



IA)'\ ~uanterra



Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0


ND = Not Detected


1 ~

---,, ..

' l ' 1-

J I I l I I. I · 1 _ j

J. J

_J_


ll)\ ~uanterra




Inc.


Parameter

052189-0003-SA AQUEOUS 22 OCT 96


Surrogate



ND = Not Detected



Result

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

Recovery

102 115

90

Units


% % %


Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1. 0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

Limits

70-130 70-130 70-130



(cont.)

13

,;:.'I

···~ ;..:.'f. ·'~

!

j

:·:t.· j

-·· r • . 1 -I 1 ]

1 I I . ,

1

J ]

I !



Professional Analysis, MW-I

Inc.


Parameter

Benzene

052189-0004-SA AQUEOUS 22 OCT 96




Result



Units



IAJ\ ~uanterra Environmental Services


Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0


ND = Not Detected




14

1 .J

] , Ir

J '1 A

]

]

I I I

J ti

J .

.

' ' .....


IJ)'\ ~uanterra




Inc.


Parameter

052189-0004-SA AQUEOUS 22 OCT 96

n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m- & p-Xylenes a-Xylene

Surrogate



ND = Not Detected



Result

ND ND ND ND 8.1


Recovery

100 113 90

Units


% % %


Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

Limits

70-130 70-130 70-130



(cont.)

15

., . '

. /

;_j

1 ]

I I

I. l

Client Name: Client ID: Lab ID: Matrix: Authorized:


Professional Analysis, Inc. Trip Blank 052189-0005-TB AQUEOUS Sampled: 21 OCT 96 22 OCT 96 Received: 22 OCT 96

Parameter Result Units

Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec-Butyl benzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Dibromochloromethane DBCP (l,2-Dibromo-






IJ)\ ~uanterra



Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0


ND = Not Detected


16

., ·1 .I

l l

J . 1 . '

l .J

)

l ]

I I I

.J ]

J

Q~ vuanterra Environmental Services


Client Name: Professional Analysis, Inc. Client ID: Trip Blank Lab ID: 052189-0005-TB Matrix: AQUEOUS Authorized: 22 OCT 96

Parameter


Surrogate

Toluene-dB 4-Bromofluorobenzene 1,2-Dichloroethane-d4


ND = Not Detected


Sampled: 21 OCT 96 Pre~ared: 24 OCT 96 Received: 22 OCT 96 Ana yzed: 01 NOV 96

Reporting Result Units Limit

ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0

Recovery Limits

98 % 70-130 118 % 70-130 92 % 70-130



(cont.)

17

"'-t Q'\ ,_I ~uanterra ::,:~


g Volatile Organics

Method 524.2

Client Name: Professional Analysis, Inc. Client ID: MW-3 Lab ID: 052189-0006-SA Matrix: AQUEOUS Sampled: 22 OCT 96 Pre~ared: 24 OCT 96 Authorized: 22 OCT 96 Received: 23 OCT 96 Ana yzed: 01 NOV 96

Reporting Parameter Result Units Limit

I Benzene ND ug/L 1.0 I Bromobenzene ND ug/L 1.0 !

.J Bromochloromethane ND ug/L 1.0 Bromodichloromethane ND ug/L 1.0

] Bromoform ND ug/L 1.0 Bromomethane ND ug/L 1.0 n-Butylbenzene ND ug/L 1.0 sec-Butyl benzene ND ug/L 1.0

I tert-Butylbenzene ND ug/L 1.0 Carbon tetrachloride ND ug/L 1.0 Chlorobenzene ND ug/L 1.0 Chloroethane ND ug/L 1.0

I Chloroform ND ug/L 1.0 Chloromethane ND ug/L 1.0 2-Chlorotoluene ND ug/L 1.0 4-Chlorotoluene ND ug/L 1.0

I Dibromochloromethane ND ug/L 1.0 DBCP (1,2-Dibromo-

ug/L 3-chloropropane) ND 2.0 EDB (1,2-Dibromoethane) ND ug/L 1.0

I Dibromomethane ND ug/L 1.0 1,2-Dichlorobenzene ND ug/L 1.0 1,3-Dichlorobenzene ND ug/L 1.0

~ 1,4-Dichlorobenzene ND ug/L 1.0 Dichlorodifluoromethane ND ug/L 1.0 1,1-Dichloroethane ND ug/L 1.0 1,2-Dichloroethane ND ug/L 1.0 1,1-Dichloroethene ND ug/L 1.0 cis-1,2-Dichloroethene ND ug/L 1.0

• j trans-1,2-Dichloroethene ND ug/L 1.0 1,2-Dichloropropane ND ug/L 1.0

J 1,3-Dichloropropane ND ug/L 1.0 2,2-Dichloropropane ND ug/L 1.0 1,1-Dichloro~ropene ND ug/L 1.0 cis-1,3-Dich oropropene ND ug/L 1.0

] trans-1,3-Dichloropropene ND ug/L 1.0 Ethyl benzene ND ug/L 1.0 Hexachlorobutadiene ND ug/L 1.0 Isopropylbenzene (Cumene) ND ug/L 1.0

• 1 p-Iso~ropyltoluene (p-Cymene) ND ug/L 1.0 Methy ene chloride ND ug/L 1.0 Naphthalene ND ug/L 1.0

! Dilution factor is 1.0. l All results and limits are corrected for dilution. I _J

ND = Not Detected

~·, ~~ .. Reported By: Paul Smith Approved By: Audrey Cornell . '

-Jt

:f

"' \

J

. J

'cl i

j

j

1 l 1 I I I

J ]

I l

-

Q'\ r/Uanterra Environmental Services


Client Name: Professional Analysis, Inc. Client ID: MW-3 Lab ID: 052189-0006-SA Matrix: AQUEOUS Authorized: 22 OCT 96

Parameter


Surrogate



ND = Not Detected


Sampled: 22 OCT 96 Pre~ared: 24 OCT 96 Received: 23 OCT 96 Ana yzed: 01 NOV 96


ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0

Recovery Limits

100 3 70-130 ll5 3 70-130

91 3 70-130



(cont.)

19

1 I

l l j

1 J I.

I

l l ; i

1 i

-.~·~ c:.I




Inc.


Parameter

Benzene

052189-0007-SA AQUEOUS 22 OCT 96




Result


ND ND ND ND ND ND 1.3


Units



IA~ ~uanterra Environmental Services


Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0


ND = Not Detected




2(

., • I

_ j

'l

J

' ]

I ] • l

\

l

~-1

~ ~· ,-,1 ·.1




Lab ID: Matrix:


Parameter


Surrogate


Result

ND ND ND ND 5.1


Recovery

100 110

92

Units


% % %



Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

Limits

70-130 70-130 70-130


ND = Not Detected


(cont.)

21

J 1.

l

i J

J I 1 ]

:."'! l ·~

_j.

I. ] ' 1 . -'

' j

i .:·, ... _._..



Parameter

Benzene

Professional Analysis, Trip Blank 052189-0008-TB AQUEOUS 22 OCT 96



Inc.


Result



Units





Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0


ND = Not Detected


22

J

-

J ]

I I 1

. l

. 1 ~

I I

~ . .



Parameter

Professional Analysis, Trip Blank 052189-0008-TB AQUEOUS 22 OCT 96


Surrogate

Toluene-dB 4-Bromofluorobenzene 1,2-Dichloroethane-d4

Inc.


Result

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

Recovery

95 115 90

Units


% % %



Reporting Limit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

Limits

70-130 70-130 70-130


ND = Not Detected


(cont.)

23

. j

l

]

1 I I

J. ]

11. • .l·

Semivolatile Organics Appendix IX List

Method 8270



Inc.


Parameter

052189-0001-SA AQUEOUS 22 OCT 96

Acenaphthene Acenaphthylene Acetophenone 2-Acetylaminofluorene 4-Aminobiphenyl Aniline Anthracene Aramite Benzo(a)anthracene Benzo!b)fluoranthene Benzo k)fluoranthene Benzo g,h,i)perylene Benzo(a)pyrene Benzyl alcohol 4-Bromophenyl phenyl ether Butyl benzyl phthalate 2-sec-Butyl-4,6-dinitro-phenol 4-Chloroanil ine bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether bis(2-Chloroisopropyl)ether 4-Chloro-3-methylphenol 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenyl phenyl ether Chrysene Dibenz(a,h)anthracene Dibenzofuran Di-n-butyl phthalate 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 3,3'-Dichlorobenzidine 2,4-Dichlorophenol 2,6-Dichlorophenol Diethyl phthalate Dimethoate p-Dimethylaminoazobenzene 7,12-Dimethylbenz(a)-anthracene 3,3'-Dimethylbenzidine a,a-Dimethylphenethyl-amine


Result

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

Units

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L

'Jeuanterra Environmental Services

Prepared: 23 OCT 96 Analyzed: 31 OCT 96

Reporting Limit

9.5 9.5 9.5

95 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5

19 9.5 9.5 9.5

48 9.5 9.5 9.5 9.5


ND = Not Detected

Reported By: Lisa Burgesser Approved By: Audrey Cornell

24

i

J

J l

l

1 ~

]

l I I ]

I ___ J

I .

_j-


Method 8270



Inc.


Parameter

052189-0001-SA AQUEOUS 22 OCT 96

2,4-Dimethylphenol Dimethyl phthalate 1,3-Dinitrobenzene 4,6-Dinitro-2-methylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octyl phthalate Di phenyl amine Disulfoton bis(2-Ethylhexyl)phthalate Ethyl methanesulfonate Famphur Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachlorophene Hexachloropropene Indeno(l,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Methyl parathion 2-Methylphenol 3/4-Methylphenol Naphthalene 1,4-Naphthoquinone 1-Naphthylamine 2-Naphthylamine 2-Nitroaniline 3-Nitroanil ine 4-Nitroanil ine Nitrobenzene 2-Nitrophenol 4-Nitrophenol


Result

ND ND ND ND ND ND ND ND ND ND 26 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

Units




Reporting Limit

9.5 9.5 9.5

48 48 9.5 9.5 9.5 9.5

48 9.5 9.5

48 9.5 9.5 9.5 9.5 9.5 9.5

9.5 9.5 9.5

19 9.5 9.5 9.5 9.5

48 9.5 9.5 9.5 9.5 9.5 9.5

48 48 48 9.5 9.5

48


ND = Not Detected


(cont.)

25

J 1

]

.i ]

I I I

J

I

• < i


Method 8270



Lab ID: 052189-0001-SA Matrix: AQUEOUS Sampled: 21 OCT 96 Authorized: 22 OCT 96 Received: 22 OCT 96

Parameter

4-Nitroquinoline-1-oxide N-Nitroso-di-n-butylamine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine N-Nitroso-di-n-propylamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine 5-Nitro-o-toluidine Parathion Pentachlorobenzene Pentachloroethane Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol 4-Phenylenediamine Phorate 2-Picoline Pron amide Pyrene Pyridine Safrole Sulfotepp 1,2,4,5-Tetrachloro-benzene 2,3,4,6-Tetrachlorophenol Thionazin 2-Toluidine 1,2,4-Trichlorobenzene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 0,0,0-Triethylphosphoro-thioate 1,3,5-Trinitrobenzene

Result

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

Units

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L

#j)), ~uanterra


Pre~ared: 23 OCT 96 Ana yzed: 31 OCT 96

Reporting Limit

95 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5

48 9.5 9.5

48 48 9.5 9.5 9.5

95 95 9.5 9.5 9.5

19 9.5

48 9.5

48 48 9.5 9.5

48 9.5 9.5 9.5


ND = Not Detected


(cont.)

2E

, )

I I I I :.I' ,: .

III

j _J

l J_ ·1

\ i..


Method 8270



Inc.


Parameter

052189-0001-SA AQUEOUS 22 OCT 96

Surrogate

Nitrobenzene-dS 2-Fluorobiphenyl Terphenyl-d14 Phenol-dS 2-Fluorophenol 2,4,6-Tribromophenol


Result

Recovery

91 89

121 88 88

102

Units

% % % % % %

IJ~\ ~uanterra Environmental Services


Reporting Limit

Limits

35-114 43-116 33-141 54-105 21-100 10-123

:l Dilution factor is 0.95. All results and limits are corrected for dilution.

~ Reported By: Lisa Burgesser Approved By: Audrey Cornell

(cont.)

27

~~ Q~ :; ~uanterra i~


:-:r : Semivolatile Organics

Appendix IX List Method 8270

- T

-i Client Name: Professional Analysis, Inc. Client ID: MW-5

1 Lab ID: 052189-0002-SA Matrix: AQUEOUS Sampled: 21 OCT 96 Pre~ared: 23 OCT 96 Authorized: 22 OCT 96 Received: 22 OCT 96 Ana yzed: 31 OCT 96

l Reporting f Parameter Result Units Limit --;

Acenaphthene ND ug/L 9.4 ' L - i Acenaphthylene ND ug/L 9.4 .......

Acetophenone ND ug/L 9.4

] 2-Acetylaminofluorene ND ug/L 94 4-Aminobiphenyl ND ug/L 9.4 . Aniline ND ug/L 9.4 Anthracene ND ug/L 9.4

] Aramite ND ug/L 9.4 Benzo(alanthracene ND ug/L 9.4 Benzo!b fluoranthene ND ug/L 9.4 Benzo k fluoranthene ND ug/L 9.4

l Benzo g,h,i)perylene ND ug/L 9.4 Benzo~a)~yrene ND ug/L 9.4 Benzy a coho 1 ND ug/L 9.4 4-Bromophen{l ~henyl ether ND ug/L 9.4

I Butyl benzy p thalate ND ug/L 9.4 2-sec-Butyl-4,6-dinitro-phenol ND ug/L 9.4 4-Chl oroanil ine ND ug/L 9.4 bis(2-Chloroethoxy)methane ND ug/L 9.4

I bis~2-Chloroethyl) ether ND ug/L 9.4 bis 2-Chloroisopropyl)ether ND ug/L 9.4 4-Chloro-3-methylphenol ND ug/L 9.4 2-Chloronaphthalene ND ug/L 9.4

I 2-Chlorophenol ND ug/L 9.4 4-Chlorophenyl phenyl ether ND ug/L 9.4 Chrysene ND ug/L 9.4

... Dibenz(a,h)anthracene ND ug/L 9.4 Dibenzofuran ND ug/L 9.4

_j- Di-n-butyl phthalate ND ug/L 9.4 1,2-Dichlorobenzene ND ug/L 9.4

1. 1,3-Dichlorobenzene ND ug/L 9.4 1,4-Dichlorobenzene ND ug/L 9.4 3,3'-Dichlorobenzidine ND ug/L 19 2,4-Dichlorophenol ND ug/L 9.4

]. 2,6-Dichlorophenol ND ug/L 9.4 Diethyl phthalate ND ug/L 9.4 Dimethoate ND ug/L 47 p-Dimethylaminoazobenzene ND ug/L 9.4

: 1 7,12-Dimethylbenz(a)-anthracene ND ug/L 9.4 3,3'-Dimethylbenzidine ND ug/L 9.4 a,a-Dimethylphenethyl-amine ND ug/L 9.4

1 Dilution factor is 0.94. All results and limits are corrected for dilution.

ND = Not Detected


2:

... ~

.., J

J '1

I

I I I I

·-}

J

]. : 1

'

·1

J_

A.·.= :. :i • .r

' -·


Method 8270



Inc.


Parameter

052189-0002-SA AQUEOUS 22 OCT 96

2,4-Dimethylphenol Dimethyl phthalate 1,3-Dinitrobenzene 4,6-Dinitro-2-methylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octyl phthalate Diphenylamine Disulfoton bis(2-Ethylhexyl)phthalate Ethyl methanesulfonate Famphur Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachlorophene Hexachloropropene Indeno(l,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Methyl parathion 2-Methylphenol 3/4-Methylphenol Naphthalene 1,4-Naphthoquinone 1-Naphthylamine 2-Naphthylamine 2-Nitroanil ine 3-Nitroanil ine 4-Nitroaniline Nitrobenzene 2-Nitrophenol 4-Nitropheno 1


Result


Units




Reporting Limit

9.4 9.4 9.4

47 47 9.4 9.4 9.4 9.4

47 9.4 9.4

47 9.4 9.4 9.4 9.4 9.4 9.4

9.4 9.4 9.4

19 9.4 9.4 9.4 9.4

47 9.4 9.4 9.4 9.4 9.4 9.4

47 47 47 9.4 9.4

47


ND = Not Detected


(cont.)

29

~ Q" ~:· vuanterra


'.71 Semivolatile Organics 1 (cont.) \ Appendix IX List

Method 8270

1 Client Name: Professional Analysis, Inc. Client ID: MW-5

] Lab ID: 052189-0002-SA Matrix: AQUEOUS Sampled: 21 OCT 96 Pre~ared: 23 OCT 96 Authorized: 22 OCT 96 Received: 22 OCT 96 Ana yzed: 31 OCT 96

: l Parameter Result Units

Reporting Limit

J 4-Nitroquinoline-1-oxide ND ug/L 94 N-Nitroso-di-n-butylamine ND ug/L 9.4 N-Nitrosodiethhlamine ND ug/L 9.4

I N-Nitrosodimet ylamine ND ug/L 9.4 N-Nitrosodiphenylamine ND ug/L 9.4 N-Nitroso-di-n-prop{lamine ND ug/L 9.4 N-Nitrosomethylethy amine ND ug/L 9.4

I N-Nitrosomorpholine ND ug/L 9.4 N-Nitrosopiperidine ND ug/L 9.4 N-Nitrosopyrrolidine ND ug/L 9.4 5-Nitro-o-toluidine ND ug/L 9.4

I Parathion ND ug/L 47 Pentachlorobenzene ND ug/L 9.4 Pentachloroethane ND ug/L 9.4 Pentachloronitrobenzene ND ug/L 47

I Pentachlorophenol ND ug/L 47 Phenacetin ND ug/L 9.4 Phenanthrene ND ug/L 9.4 Phenol ND ug/L 9.4

l 4-Phenylenediamine ND ug/L 94 Pho rate ND ug/L 94 2-Picoline ND ug/L 9.4 Pron amide ND ug/L 9.4

~ Pyrene ND ug/L 9.4

~- Pyridine ND ug/L 19 ~: .•

Safrole ND ug/L 9.4 Sulfotepp ND ug/L 47 1,2,4,5-Tetrachloro-benzene ND ug/L 9.4

i 2,3,4,6-Tetrachlorophenol ND ug/L 47 - ).

Thionazin ND ug/L 47

J 2-Toluidine ND ug/L 9.4 1,2,4-Trichlorobenzene ND ug/L 9.4 2,4,5-Trichlorophenol ND ug/L 47 2,4,6-Trichlorohhenol ND ug/L 9.4

]. 0,0,0-Triethylg osphoro-thioate ND ug/L 9.4 1,3,5-Trinitro enzene ND ug/L 9.4

. 1 .I

. I Dilution factor is 0.94. All results and limits are corrected for dilution . J ND = Not Detected

:·1 Reported By: Lisa Burgesser Approved By: Audrey Cornell

30 I -

i . 1

J il

I

J 'I ll

I I I. I

I

,J

. .1.

;l !-'.


Method 8270



Inc.


Parameter

052189-0002-SA AQUEOUS 22 OCT 96

Surrogate

Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14 Phenol-d5 2-Fluorophenol 2,4,6-Tribromophenol


Result

Recovery

93 90

125 94 93

111

Units

% % % % % %

Ii~" ~uanterra Environmental Services


Reporting Limit

Limits

35-114 43-116 33-141 54-105 21-100 10-123



(cont.)

31

-1 :J

I

]

].

I \J I ' 1

. ) :I-


Method 8270


Professional Analysis, MW-I

Inc.


Parameter

Acenaphthene

052189-0004-SA AQUEOUS 22 OCT 96

Acenaphthylene Acetophenone 2-Acetylaminofluorene 4-Aminobiphenyl Aniline Anthracene Aramite Benzo(a)anthracene Benzolb)fluoranthene Benzo k)fluoranthene Benzo g,h,i)perylene Benzo(a)pyrene Benzyl alcohol 4-Bromophenyl phenyl ether Butyl benzyl phthalate 2-sec-Butyl-4,6-dinitro-phenol 4-Chloroanil ine bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether bis(2-Chloroisopropyl)ether 4-Chloro-3-methylphenol 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenyl phenyl ether Chrysene Dibenz(a,h)anthracene Dibenzofuran Di-n-butyl phthalate 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 3,3'-Dichlorobenzidine 2,4-Dichlorophenol 2,6-Dichlorophenol Diethyl phthalate Dimethoate p-Dimethylaminoazobenzene 7,12-Dimethylbenz(a)-anthracene 3,3'-Dimethylbenzidine a,a-Dimethylphenethyl-amine


Result


Units


Quanterra Environmental SC'rvices


Reporting Limit

11 11 11

110 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 21 11 11 11 53 11 11 11 11

Dilution factor is 1.1. All results and limits are corrected for dilution .

ND = Not Detected


i - j

-'l . l -·.l ...J

]

J I I

l l . l

I j

j


Method 8270





Parameter

2,4-Dimethylphenol Dimethyl phthalate 1,3-Dinitrobenzene 4,6-Dinitro-2-methylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octyl phthalate Di phenyl amine Disulfoton bis(2-Ethylhexyl)phthalate Ethyl methanesulfonate Famphur Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachlorophene Hexachloropropene Indeno(l,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Methyl parathion 2-Methylphenol 3/4-Methylphenol Naphthalene 1,4-Naphthoquinone 1-Naphthylamine 2-Naphthylamine 2-Nitroanil ine 3-Nitroanil ine 4-Nitroanil ine Nitrobenzene 2-Nitrophenol 4-Nitrophenol

Result


Units




Reporting Limit

11 11 11 53 53 11 11 11 11 53 11 11 53 11 11 11 11 11 11

11 11 11 21 11 11 11 11 53 11 11 11 11 11 11 53 53 53 11 11 53


ND = Not Detected


(cont.)

33

f

j

~.·· J

]

J I 1-

I J "1

( '

F

J.


Method 8270



Inc.


052189-0004-SA AQUEOUS 22 OCT 96

Parameter

4-Nitroquinoline-1-oxide N-Nitroso-di-n-butylamine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine N-Nitroso-di-n-propylamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine 5-Nitro-o-toluidine Parathion Pentachlorobenzene Pentachloroethane Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol 4-Phenylenediamine Phorate 2-Picoline Pronamide Pyrene Pyridine Safrole Sulfotepp 1,2,4,5-Tetrachloro-benzene 2,3,4,6-Tetrachlorophenol Thionazin 2-Toluidine 1,2,4-Trichlorobenzene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 0,0,0-Triethylphosphoro-thioate 1,3,5-Trinitrobenzene


Result


Units


Quanterra Environmenral Services


Reporting Limit

llO ll ll ll 11 11 11 11 11 11 11 53 11 11 53 53 11 11 11

llO llO

11 11 11 21 11 53 11 53 53 11 11 53 11 11 11


ND = Not Detected


(cont.)

3L

_j

' 1 l

i J j

I I 1·

I I I

·J • '1 ,J

· 1 ' t

I I ~1


Method 8270



Inc.


Parameter

052189-0004-SA AQUEOUS 22 OCT 96

Surrogate

Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14 Phenol-d5 2-Fluorophenol 2,4,6-Tribromophenol


Result

Recovery

87 82

121 86 81 99

Units

% % % % % %

IA!'\ ~uanterra



Reporting Limit

Limits

35-114 43-116 33-141 54-105 21-100 10-123



(cont.)

35

' . ,

j

' . I :;..J

I I

1_

J_

-'l··

Sernivolatile Organics Appendix IX List

Method 8270



Inc.


Parameter

Acenaphthene

052189-0006-SA AQUEOUS 22 OCT 96

Acenaphthylene Acetophenone 2-Acetylaminofluorene 4-Arninobiphenyl Aniline Anthracene Aramite Benzo(a)anthracene Benzo!b)fluoranthene Benzo k)fluoranthene Benzo g,h,i)perylene Benzo(a)pyrene Benzyl alcohol 4-Brornophenyl phenyl ether Butyl benzyl phthalate 2-sec-Butyl-4,6-dinitro-phenol 4-Chloroanil ine bis(2-Chloroethoxy)methane bis(2-Chloroethyl) ether bis(2-Chloroisopropyl)ether 4-Chloro-3-methylphenol 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenyl phenyl ether Chrysene Dibenz(a,h)anthracene Dibenzofuran Di-n-butyl phthalate 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 3,3'-Dichlorobenzidine 2,4-Dichlorophenol 2,6-Dichlorophenol Diethyl phthalate Dimethoate p-Dirnethylaminoazobenzene 7,12-Dimethylbenz(a)-anthracene 3,3'-Dimethylbenzidine a,a-Dirnethylphenethyl-amine


Result


Units


I~}\ ~uanterra



Reporting Limit

9.5 9.5 9.5

95 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5

19 9.5 9.5 9.5

48 9.5 9.5 9.5 9.5


ND = Not Detected


36

_I

I I I I

I. I.

J

J.

It, ......


Method 8270



Inc.


Parameter

052189-0006-SA AQUEOUS 22 OCT 96

2,4-Dimethylphenol Dimethyl phthalate 1,3-Dinitrobenzene 4,6-Dinitro-2-methylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octyl phthalate Diphenylamine Disulfoton bis(2-Ethylhexyl)phthalate Ethyl methanesulfonate Famphur Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachlorophene Hexachloropropene Indeno{l,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Methyl parathion 2-Methylphenol 3/4-Methylphenol Naphthalene 1,4-Naphthoquinone 1-Naphthylamine 2-Naphthylamine 2-Nitroanil ine 3-Nitroaniline 4-Nitroanil i ne Nitrobenzene 2-Nitrophenol 4-Nitrophenol


Result


Units


IJ)'\ ~uanterra



Reporting Limit

9.5 9.5 9.5

48 48 9.5 9.5 9.5 9.5

48 9.5 9.5

48 9.5 9.5 9.5 9.5 9.5 9.5

9.5 9.5 9.5

19 9.5 9.5 9.5 9.5

48 9.5 9.5 9.5 9.5 9.5 9.5

48 48 48 9.5 9.5

48


ND = Not Detected


(cont.)

37

'JI Q' ~:-! id ~uanterra

Environmental . - Services

;"'$ - ~ Semivolatile Organics

Appendix IX List Method 8270

(cont.)

Client Name: Professional Analysis, Inc. Client ID: MW-3

~ j Lab ID: 052189-0006-SA Matrix: AQUEOUS Sampled: 22 OCT 96 Pre)ared: 23 OCT 96 Authorized: 22 OCT 96 Received: 23 OCT 96 Ana yzed: 31 OCT 96

Reporting Parameter Result Units Limit

i 4-Nitroquinoline-1-oxide ND ug/L 95 .l

,_j N-Nitroso-di-n-butylamine ND ug/L 9.5 N-Nitrosodiethylamine ND ug/L 9.5

3 N-Nitrosodimethylamine ND ug/L 9.5 N-Nitrosodiphenylamine ND ug/L 9.5 N-Nitroso-di-n-prop)lamine ND ug/L 9.5 N-Nitrosomethylethy amine ND ug/L 9.5

.1 N-Nitrosomorpholine ND ug/L 9.5 N-Nitrosopiperidine ND ug/L 9.5 N-Nitrosopyrrolidine ND ug/L 9.5 5-Nitro-o-toluidine ND ug/L 9.5

) Parathion ND ug/L 48 Pentachlorobenzene ND ug/L 9.5 Pentachloroethane ND ug/L 9.5 Pentachloronitrobenzene ND ug/L 48

I Pentachlorophenol ND ug/L 48 Phenacetin ND ug/L 9.5 Phenanthrene ND ug/L 9.5 Phenol ND ug/L 9.5

I 4-Phenylenediamine ND ug/L 95 Phorate ND ug/L 95 2-Picoline ND ug/L 9.5 Pronamide ND ug/L 9.5

ii Pyrene ND ug/L 9.5 Pyridine ND ug/L 19 Safrole ND ug/L 9.5

·.' Sulfotepp ND ug/L 48 1,2,4,5-Tetrachloro-benzene ND ug/L 9.5 2,3,4,6-Tetrachlorophenol ND ug/L 48 Thionazin ND ug/L 48

I 2-Toluidine ND ug/L 9.5 . j 1,2,4-Trichlorobenzene ND ug/L 9.5

2,4,5-Trichlorophenol ND ug/L 48 2,4,6-Trichloro~henol ND ug/L 9.5

1 0,0,0-Triethylg osphoro-thioate ND ug/L 9.5 1,3,5-Trinitro enzene ND ug/L 9.5

J Dilution factor is 0.95. All results and limits are corrected for dilution.

ND = Not Detected


. -; 31

i ;

. '

1 1

J

~J

J )

I I I , ~-

] ' l

i

q :" t :: I .. '


Method 8270



Inc.


Parameter

052189-0006-SA AQUEOUS 22 OCT 96

Surrogate

Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14 Phenol-dS 2-Fluorophenol 2,4,6-Tribromophenol


Result

Recovery

100 86

123 96 93

107

Units

% % % % % %

IJ)\ ~uanterra



Reporting Limit

Limits

35-114 43-116 33-141 54-105 21-100 10-123



(cont.)

39

1

-1

]

]

1 I I

I .

'

·1

~ !.

i;. •••


Method 8270

Client Name: Professional Analysis, Inc. Client ID: MW-4 Lab ID: 052189-0007-SA Matrix: AQUEOUS Sampled: 22 OCT 96 Authorized: 22 OCT 96 Received: 23 OCT 96

Parameter Result

Acenaphthene ND Acenaphthylene ND Acetophenone ND 2-Acetylaminofluorene ND 4-Aminobiphenyl ND Aniline ND Anthracene ND Aramite ND Benzo(a)anthracene ND Benzo!bJfluoranthene ND Benzo k fluoranthene ND Benzo g,h,i)perylene ND Benzo(a)~yrene ND Benzyl a cohol ND 4-Bromophenyl ~henyl ether ND Butyl benzyl p thalate ND 2-sec-Butyl-4,6-dinitro-phenol ND 4-Chloroanil ine ND bis(2-Chloroethoxy)methane ND bis~2-Chloroethyl) ether ND bis 2-Chloroisopropyl)ether ND 4-Chloro-3-methylphenol ND 2-Chloronaphthalene ND 2-Chlorophenol ND 4-Chlorophenyl phenyl ether ND Chrysene ND Dibenz(a,h)anthracene ND Dibenzofuran ND Di-n-but{l phthalate ND 1,2-Dich orobenzene ND 1,3-Dichlorobenzene ND 1,4-Dichlorobenzene ND 3,3'-Dichlorobenzidine ND 2,4-Dichlorophenol ND 2,6-Dichlorophenol ND Diethyl phthalate ND Dimethoate ND p-Dimethylaminoazobenzene ND 7,12-Dimethylbenz(a)-anthracene ND 3,3'-Dimethylbenzidine ND a,a-Dimethylphenethyl-amine ND

Units


ll~' ~uanterra Em-iron mental Services

Pre~ared: 23 OCT 96 Ana yzed: 31 OCT 96

Reporting Limit

9.5 9.5 9.5

95 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5

19 9.5 9.5 9.5

48 9.5 9.5 9.5 9.5


ND = Not Detected


40

-I

'

)

.J

I ]

i 'j

j_

] . t

I __,


Method 8270



Inc.


Parameter

052189-0007-SA AQUEOUS 22 OCT 96

2,4-Dimethylphenol Dimethyl phthalate 1,3-Dinitrobenzene 4,6-Dinitro-2-methylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octyl phthalate Di phenyl amine Disulfoton bis(2-Ethylhexyl)phthalate Ethyl methanesulfonate Famphur Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachlorophene Hexachloropropene Indeno(l,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Methyl parathion 2-Methylphenol 3/4-Methylphenol Naphthalene 1,4-Naphthoquinone 1-Naphthylamine 2-Naphthylamine 2-Nitroanil i ne 3-Nitroanil ine 4-Nitroaniline Nitrobenzene 2-Nitrophenol 4-Nitrophenol


Result


Units


~uanterra Environmental Services


Reporting Limit

9.5 9.5 9.5

48 48 9.5 9.5 9.5 9.5

48 9.5 9.5

48 9.5 9.5 9.5 9.5 9.5 9.5

9.5 9.5 9.5

19 9.5 9.5 9.5 9.5

48 9.5 9.5 9.5 9.5 9.5 9.5

48 48 48 9.5 9.5

48


ND = Not Detected


(cont.)

41

' 1

j

j .I I

J I I I

' . I

'

I. ]

-1.

-·


Method 8270





Parameter

4-Nitroquinoline-1-oxide N-Nitroso-di-n-butylamine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitrosodiphenylamine N-Nitroso-di-n-propylamine N-Nitrosomethylethylamine N-Nitrosomorpholine N-Nitrosopiperidine N-Nitrosopyrrolidine 5-Nitro-o-toluidine Parathion Pentachlorobenzene Pentachloroethane Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol 4-Phenylenediamine Phorate 2-Picoline Pronamide Pyrene Pyridine Safrole Sul fotepp 1,2,4,5-Tetrachloro-benzene 2,3,4,6-Tetrachlorophenol Thionazin 2-Toluidine 1,2,4-Trichlorobenzene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 0,0,0-Triethylphosphoro-thioate 1,3,5-Trinitrobenzene

Result


Units




Reporting Limit

95 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5 9.5

48 9.5 9.5

48 48 9.5 9.5 9.5

95 95 9.5 9.5 9.5

19 9.5

48 9.5

48 48 9.5 9.5

48 9.5 9.5 9.5


ND = Not Detected


(cont.)

42

'.:~ 1'

;.j

. I

~.-J

::• ;I

I

I

~ ... , I 1

c...l

] . .. . ·1

L


Method 8270



Inc.


Parameter

052189-0007-SA AQUEOUS 22 OCT 96

Surrogate

Nitrobenzene-dS 2-Fluorobiphenyl Terphenyl-dl4 Phenol-d5 2-Fluorophenol 2,4,6-Tribromophenol


Result

Recovery

88 81

113 88 87

100

Units

% % % % % %

IJ)\ ~uanterra



Reporting Limit

Limits

35-114 43-116 33-141 54-105 21-100 10-123

~ Dilution factor is 0.95. All results and limits are corrected for dilution.

f:l Reported By: Lisa Burgesser Approved By: Audrey Corne 11

(cont.;

...

"l l

I I .l '1 ii

" ll.

' l

1

Chlorinated Pesticides and PCB's Appendix IX List

Method 8080A

Client Name: Client ID: Lab ID:

Professional Analysis, Inc. MW-2 052189-0001-SA

Matrix: AQUEOUS Sampled: 21 OCT 96 22 OCT 96 Received: 22 OCT 96 Authorized:

Parameter

Aldrin Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260 alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) alpha-Chlordane gamma-Chlordane Chlorobenzilate 4,4'-DDD 4,4'-DDE 4,4'-DDT Di all ate Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide Isodrin Ke pone Methoxychlor Toxaphene

Surrogate

Tetrachloro-m-xylene Dibutyl chlorendate Decachlorobiphenyl

Result

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

Recovery

86 101 llO

Units

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L

3 3 3

I~~' ~uanterra Environmental Services


Reporting Limit

0.047 0.95 0.95 0.95 0.95 0.95 0.95 0.95 0.047 0.047 0.047 0.047 0.047 0.047 0.95 0.095 0.095 0.095 0.95 0.095 0.047 0.095 0.095 0.095 0.095 0.047 0.047 0.095 2.4 0.47 4.7

Limits

54-106 56-138 65-145


ND = Not Detected

Reported By: Houa Vue



44

= ... Q\ : .; wuanterra "~ "' = Environmental Services ,


Method 8080A

Client Name: Professional Analysis, Inc. Client ID: MW-5 Lab ID: 052189-0002-SA Matrix: AQUEOUS Sampled: 21 OCT 96 Pre~ared: 23 OCT 96 Authorized: 22 OCT 96 Received: 22 OCT 96 Ana yzed: 30 OCT 96

l Parameter Result Units

Reporting Limit

Aldrin ND ug/L 0.047 I Aroclor 1016 ND ug/L 0.95

:: j

Aroclor 1221 ND ug/L 0.95

1 Aroclor 1232 ND ug/L 0.95 Aroclor 1242 ND ug/L 0.95 Aroclor 1248 ND ug/L 0.95 Aroclor 1254 ND ug/L 0.95

I Aroclor 1260 ND ug/L 0.95 alpha-BHC ND ug/L 0.047 beta-BHC ND ug/L 0.047 delta-BHC ND ug/L 0.047

I gamma-BHC (Lindane) ND ug/L 0.047 alpha-Chlordane ND ug/L 0.047 gamma-Chlordane ND ug/L 0.047 Chlorobenzilate ND ug/L 0.95

I 4,4' -ODD ND ug/L 0.095 4,4'-DDE ND ug/L 0.095 4, 4' -DDT ND ug/L 0.095 Diallate ND ug/L 0.95

I Dieldrin ND ug/L 0.095 Endosulfan I ND ug/L 0.047 Endosulfan II ND ug/L 0.095 Endosulfan sulfate ND ug/L 0.095

d Endrin ND ug/L 0.095 Endrin aldehyde ND ug/L 0.095 . Heptachlor ND ug/L 0.047 Heptachlor epoxide ND ug/L 0.047

. l Isodrin ND ug/L 0.095 I

Ke pone ND ug/L 2.4 Methoxychlor ND ug/L 0.47

·~ Toxaphene ND ug/L 4.7

j_ Surrogate Recovery Limits , Tetrachloro-m-xylene 89 % 54-106 Dibutyl chlorendate 104 % 56-138

k·~ Decachlorobiphenyl 115 % 65-145

Oil ut ion factor is 0.95. All results and limits are corrected for dilution. j_

ND = Not Detected

~:1 :::· .. Reported By: Houa Vue Approved By: Audrey Cornell

45

·--

1 . i

]

J . l

.I

~ l

I I I I 1 ~

I I

...... _


Method 8080A


Parameter

Aldrin Aroclor IOI6 Aroclor I221 Aroclor I232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260 alpha-BHC beta-BHC delta-BHC

Professional Analysis, MW-I 052I89-0004-SA AQUEOUS 22 OCT 96

gamma-BHC (Lindane) alpha-Chlordane gamma-Chlordane Chlorobenzilate 4,4'-DDD 4,4'-DDE 4,4'-DDT Dial late Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide Isodrin Kepone Methoxychlor Toxaphene

Surrogate


Inc.

Sampled: 2I OCT 96 Received: 22 OCT 96

Result


Recovery

86 99

108

Units


% % %

IJ)'\ ~uanterra



Reporting Limit

0.053 I. I I. I I. I I. I I. I I. I 1.1 0.053 0.053 0.053 0.053 0.053 0.053 1.1 0.11 0.11 0.11 I. I 0.11 0.053 0.11 0.11 0.11 0.11 0.053 0.053 0.11 2.6 0.53 5.3

Limits

54-106 56-138 65-145


ND = Not Detected

Reported By: Houa Vue Approved By: Audrey Cornell

46

... '<:

\

• f

J

I I I ]

l i , T

'

I ]

' -~ J


Method 8080A


Parameter

Aldrin Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260 alpha-BHC beta-BHC delta-BHC

Professional Analysis, MW-3 052189-0006-SA AQUEOUS 22 OCT 96

gamma-BHC (Lindane) alpha-Chlordane gamma-Chlordane Chlorobenzilate 4,4'-DDD 4,4'-DDE 4,4'-DDT Dial late Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide Isodrin Kepone Methoxychlor Toxaphene

Surrogate


Inc.


Result

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO

Recovery

88 103 114

Units


% % %

IJ)\ ~uanterra



Reporting Limit

0.048 0.95 0.95 0.95 0.95 0.95 0.95 0.95 0.048 0.048 0.048 0.048 0.048 0.048 0.95 0.095 0.095 0.095 0.95 0.095 0.048 0.095 0.095 0.095 0.095 0.048 0.048 0.095 2.4 0.48 4.8

Limits

54-106 56-138 65-145


ND = Not Detected

Reported By: Houa Vue Approved By: Audrey Cornell

47

J l J

I I I I ii I

I J ~ 1 - j

J_

I_ .. '

.r

'. -


Method 8080A

Client Name: Client ID: Lab ID:

Professional Analysis, Inc. MW-4 052189-0007-SA

Matrix: AQUEOUS Sampled: 22 OCT 96 Authorized: 22 OCT 96 Received: 23 OCT 96

Parameter

Aldrin Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260 alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) alpha-Chlordane gamma-Chlordane Chlorobenzil ate 4,4'-DDD 4,4'-DDE 4,4'-DDT Dial late Dieldrin Endosulfan I Endosul fan II Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide Isodrin Ke pone Methoxychlor Toxaphene

Surrogate


Result


Recovery

91 105 120

Units


% 3 3

IJ)\ ~uanterra



Reporting Limit

0.047 0.95 0.95 0.95 0.95 0.95 0.95 0.95 0.047 0.047 0.047 0.047 0.047 0.047 0.95 0.095 0.095 0.095 0.95 0.095 0.047 0.095 0.095 0.095 0.095 0.047 0.047 0.095 2.4 0.47 4.7

Limits

54-106 56-138 65-145


ND = Not Detected

Reported By: Houa Vue



48

l

l

l .-; ~

J 'I 1 ]

I I ~ .. ,,

" j

1


Parameter

Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Mercury Nickel Selenium Silver Thallium Tin Vanadium Zinc

Metals Total Metals

Professional Analysis, Inc. MW-2 052189-0001-SA AQUEOUS Sampled: 21 OCT 96 22 OCT 96 Prepared: See Below

Result Qual Oil

ND ND 0.11

ND ND ND ND ND ND ND ND ND ND ND ND ND ND

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

RL Units

0.060 mg/L 0.010 mg/L 0.010 mg/L 0.0020 mg/L 0.0050 mg/L 0.010 mg/L 0.010 mg/L 0.020 mg/L 0.0030 mg/L

0.00020 mg/L 0.040 mg/L 0.0050 mg/L 0.010 mg/L 0.010 mg/L 0.10 mg/L 0.010 mg/L 0.020 mg/L

ND = Not Detected

II)' ~uanterra

Test Method

6010 6010 6010 6010 6010 6010 6010 6010 6010 7470 6010 6010 6010 6010 6010 6010 6010


Received: 22 OCT 96 Analyzed: See Below

Prepared Analyzed Date Date

24 OCT 96 29 OCT 96 24 OCT 96 30 OCT 96 24 OCT 96 29 OCT 96 24 OCT 96 29 OCT 96 24 OCT 96 29 OCT 96 24 OCT 96 29 OCT 96 24 OCT 96 29 OCT 96 24 OCT 96 29 OCT 96 24 OCT 96 30 OCT 96 29 OCT 96 30 OCT 96 24 OCT 96 29 OCT 96 24 OCT 96 30 OCT 96 24 OCT 96 29 OCT 96 24 OCT 96 30 OCT 96 24 OCT 96 29 OCT 96 24 OCT 96 29 OCT 96 24 OCT 96 29 OCT 96

· ~ Reported By: Doug Gomer Approved By: Richard Persichitte

J

·, ~.

4~

. l

J

I I I )

:1 ~ . i _J

j

I


Parameter


Metals Total Metals


Result Qual

ND ND 0.11


Oil

1. 0 1.0 1.0 1.0 1.0 1. 0 I. 0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

RL Units



·1 1 ND = Not Detected

--..;

IA)' ~uanterra

Test Method

6010 6010 6010 6010 6010 6010 6010 6010 6010 7470 6010 6010 6010 6010 6010 6010 6010

Environmental Senices




Reported By: Doug Gomer Approved By: Richard Persichitte

. I .. ;. 50

J l l. '

_j

]

I I J I !;.

~·-__ j

J_

1 .


Parameter


Metals Total Metals


Result Qual Oil

ND ND 0.19

ND ND 0.014

ND ND ND ND ND ND ND ND ND ND ND

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1. 0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

RL Units



ND = Not Detected

~~ ~uanterra

Test Method

6010 6010 6010 6010 6010 6010 6010 6010 6010 7470 6010 6010 6010 6010 6010 6010 6010

Emfronmental Services





51

: I l-

' i

Q


Parameter

Antimony Arsenic Barium Beryllium Cadmium Chromium

I Cobalt I Copper

Lead Mercury

I Nickel · · Selenium

Silver

I I .1· , .

~ " 1

I - ..J.

I. I.

Thallium Tin Vanadium Zinc

Metals Total Metals


Result Qua l Oil

ND 1.0 ND 1.0 0.060 1.0

ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 1.0 0.0033 1.0

ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 1.0 0. 035 1.0

RL Units



·1 ND = Not Detected -..i·

IA)\ ~uanterra

Test Method

6010 6010 6010 6010 6010 6010 6010 6010 6010 7470 6010 6010 6010 6010 6010 6010 6010





~ Reported By: Doug Gomer Approved By: Richard Persichitte

52

..

]

I J 1 l J

.r.

1

l.

' ~.

r. .....


Parameter


Metals Total Metals


Result Qual

ND ND 0.15


Oil

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 l.O· 1.0 1.0 1.0 1.0 1.0 1.0 1.0

RL Units



ND = Not Detected

If~ ~uanterra

Test Method

6010 6010 6010 6010 6010 6010 6010 6010 6010 7470 6010 6010 6010 6010 6010 6010 6010






s:

~:: 1'»uanle,••a c.::i ~ •••

~ ,,

~ QC LOT ASSIGNMENT REPORT i Volatile Organics by GC/MS

. Jl


j

l

Laboratory Sample Number

QC Lot Number QC Run Number (DCS)

I I J I I. I

J 1

052189-0001-SA 052189-0002-SA 052189-0003-SA 052189-0004-SA 052189-0005-TB 052189-0006-SA 052189-0007-SA 052189-0008-TB

QC Matrix

AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS

QC Category

524-MOD-A 524-MOD-A 524-MOD-A 524-MOD-A 524-MOD-A 524-MOD-A 524-MOD-A 524-MOD-A

(SCS/BLANK)

01 NOV 96-N2 01 NOV 96-N2 01 NOV 96-N2 01 NOV 96-N2 01 NOV 96-N2 01 NOV 96-N2 01 NOV 96-N2 01 NOV 96-N2 01 NOV 96-N2 01 NOV 96 .. N2 01 NOV 96-N2 01 NOV 96-N2 01 NOV 96-N2 01 NOV 96-N2 01 NOV 96-N2 01 NOV 96-N2

54

, I

I l

" J

]

1 1 ~--'

j

l J I

~-"1 i !

_.J

l. I. J J_

LABORATORY CONTROL SAMPLE REPORT Volatile Organics by GC/MS

Analyte

Category: 524-MOD-A Matrix: AQUEOUS QC Lot: OI NOV 96-N2 Concentration Units: ug/L

I,I-Dichloroethane Chloroform Bromodichloromethane Trichloroethene Benzene Toluene Chlorobenzene Ethyl benzene I,3-Dichlorobenzene Hexachlorobutadiene

Concentration Spiked Measured

QC Run: OI NOV 96-N2

IO.O 9.88 IO.O 9.65 IO.O 9.35 IO.O 9.88 IO.O 9.63 IO.O IO.I IO.O II. 0 IO.O I 1. 5 IO.O 11.1 10.0 11.2

IA~\ ~uanterra


Accuracy(%) LCS Limits

99 8I-I24 96 8I-ll8 93 8I-ll6 99 82-115 96 80-I23

IOI 83-118 110 79-I29 115 83-I31 111 83-126 112 76-135

~ Calculations are performed before rounding to avoid round-off errors in calculated results .

. , I 55 ......._

. i :: J

J 1.

I I )

J I I

l l . . ,

..

SINGLE CONTROL SAMPLE REPORT Volatile Organics by GC/MS

Analyte

Category: 524-MOD-A Matrix: AQUEOUS


QC Lot: 01 NOV 96-N2 QC Run: 01 NOV 96-N2 Concentration Units: ug/L

l,2-0ichloroethane-d4 4-Bromofluorobenzene Toluene-dB

10.0 10.0 10.0

9.05 10.6 9.90

IJ'§\ ~uanterra

Emironmental Services

Accuracy(%) SCS limits

90 85-107 106 88-119 99 91-111

Calculations are performed before rounding to avoid round-off errors in calculated results.

56

' ..

I I I I ] --,

'

f .f:

t.i

METHOD BLANK REPORT Volatile Organics by GC/MS

Analyte Result Units

Test: 524-5242-AP Matrix: AQUEOUS QC Lot: 01 NOV 96-N2 QC Run: 01 NOV 96-N2

Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec-Butyl benzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Dibromochloromethane DBCP (l,2-Dibromo-

3-chloropropane) EDB (1,2-Dibromoethane) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-0ichloropropene trans-1,3-Dichloropropene Ethyl benzene Hexachlorobutadiene Isopropylbenzene (Cumene) p-Isopropyltoluene (p-Cyrnene) Methylene chloride


ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND

0.28 ND ND ND

J =Result is detected below the reporting limit or is an estimated concentration.


ug/L ug/L ug/L ug/L ug/L ug/l ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L


Reporting L irnit

1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

J

57

'" Q\ • ~ 'VUanterra

Environmental Services ,

t '

METHOD BLANK REPORT Volatile Organics by GC/MS (cont.)

Reporting

_ j Analyte Result Units Limit

Test: 524-5242-AP

-l Matrix: AQUEOUS QC Lot: 01 NOV 96-N2 QC Run: 01 NOV 96-N2

Naphthalene ND ug/L 1.0

~J n-Propylbenzene ND ug/L 1.0 Styrene ND ug/L 1.0 1,1,l,2-Tetrachloroethane ND ug/L 1.0

I 1,1,2,2-Tetrachloroethane ND ug/L 1.0 Tetrachloroethene ND ug/L 1.0 Toluene ND ug/L 1.0 1,2,3-Trichlorobenzene ND ug/L 1.0

I 1,2,4-Trichlorobenzene ND ug/L 1.0 1,1,1-Trichloroethane ND ug/L 1.0 1,1,2-Trichloroethane ND ug/L 1.0 Trichloroethene ND ug/L 1.0

I Trichlorofluoromethane ND ug/L 1.0 1,2,3-Trichlorogropane ND ug/L 1.0 1,2,4-Trimethyl enzene ND ug/L 1.0 1,3,5-Trimethylbenzene ND ug/L 1.0

I Vinyl chloride ND ug/L 1.0 m- & p-Xylenes ND ug/L 1.0 o-Xylene ND ug/L 1.0

I Test: 524-5242-AP Matrix: AQUEOUS QC Lot: 01 NOV 96-N2 QC Run: 01 NOV 96-N2

~ Benzene ND ug/L 1.0 ' Bromobenzene ND ug/L 1.0

Bromochloromethane ND ug/L 1.0 :. 1 Bromodichloromethane ND ug/L 1.0

Bromoform ND ug/L 1.0 Bromomethane ND ug/L 1.0 n-Butylbenzene ND ug/L 1.0

~ sec-Butyl benzene ND ug/L 1.0 iJ. tert-Butylbenzene ND ug/L 1.0

Carbon tetrachloride ND ug/L 1.0 ,, Chlorobenzene ND ug/l 1.0 Chloroethane ND ug/L 1.0 Chloroform ND ug/L 1.0 Chloromethane ND ug/L 1.0

~ 1 2-Chlorotoluene ND ug/L 1.0 4-Chlorotoluene ND ug/L 1.0

I

J_

l ..... 'r'

58 --

. l

·;1

~ ) ' . i

"""

I I

]

I I . " ;.

i

.....J.

· 1 i


Analyte Result

Test: 524-5242-AP Matrix: AQUEOUS QC Lot: 01 NOV 96-N2 QC Run: 01 NOV 96-N2

Dibromochloromethane ND DBCP (l,2-Dibromo-

3-chloropropane) EDB (1,2-Dibromoethane) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethyl benzene Hexachlorobutadiene Isopropylbenzene (Cumene) p-Isopropyltoluene (p-Cymene) Methylene chloride Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene

ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

0.28 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND

Units

ug/L

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L

JJ J = Result is detected below the reporting limit or is an

estimated concentration.

@uanterra Environmental Services

Reporting Limit

1.0

2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0

J

59

i .j i

·-1

I

'j

1 , ]

j

]

l I I I

J 1 1 I

- j

-


Ana lyte

Test: 524-5242-AP Matrix: AQUEOUS

Result

QC Lot: 01 NOV 96-N2 QC Run: 01 NOV 96-N2

Vinyl chloride ND m- & p-Xylenes ND o-Xylene ND

Units

ug/L ug/L ug/L

IJ)'\ ~uanterra


Reporting Limit

1.0 1.0 1.0

60

j

.1

J

1 I I I I ~ - I

j_

I

•

MATRIX SPIKE/MATRIX SPIKE DUPLICATE QC REPORT Volatile Organics by GC/MS Project: 052189

Category: 524-MOO-A Modified Method-Drinking Water Volatiles Matrix: AQUEOUS Sample: 052189-0001 MS Run: 01 NOV 96-N2 Units: ug/L

Concentration Amount

Sample MS MSD Spiked Analyte Result Result Result MS MSD

1,1-Dichloroethane NO 10 9.9 10 10 Chloroform ND 9.9 9.9 10 10 Bromodichloromethane ND 9.6 9.6 10 10 Trichloroethene NO 10 10 10 10 Benzene ND 9.8 10 10 10 Toluene ND 10 10 10 10 Chlorobenzene ND 12 12 10 10 Ethyl benzene ND 13 12 10 10 1,3-0ichlorobenzene ND 11 11 10 10 Hexachlorobutadiene ND 12 12 10 10

ND = Not Detected

IA!' ~uanterra

%


Recov. ·RPO Recovery Accep. RPO Accept

MS MSD Limits MS-MSO Limits

102 99 60-140 3.0 20 99 99 60-140 0.5 20 96 96 60-140 0.5 20

102 100 60-140 2.2 20 98 101 60-140 2.5 20

104 102 60-140 1.9 20 116 118 60-140 1. 7 20 127 124 60-140 2.4 20 114 114 60-140 0.0 20 119 121 60-140 1. 7 20

~ Calculations are performed before rounding to avoid round-off errors in calculated results.

:... ·-

61

, t

- J

: l.

J

I I I I ]

~ ·1 __ J

I ]

1 j

~ 'i.

QC LOT ASSIGNMENT REPORT Semivolatile Organics by GC/MS

Laboratory Sample Number QC Matrix

052189-0001-SA AQUEOUS 052189-0002-SA AQUEOUS 052189-0004-SA AQUEOUS 052189-0006-SA AQUEOUS 052189-0007-SA AQUEOUS

QC Category

625-A 625-A 625-A 625-A 625-A

IJ!). ~uanterra

QC Lot Number (DCS)

23 OCT 96-04 23 OCT 96-04 23 OCT 96-04 23 OCT 96-04 23 OCT 96-04


QC Run Number (SCS/BLANK)


62

··I I

. I -. ]

I I I I I .. .,

·!

J

LABORATORY CONTROL SAMPLE REPORT Semivolatile Organics by GC/MS

Analyte

Category: 625-A Matrix: AQUEOUS QC Lot: 23 OCT 96-04 Concentration Units: ug/L

Phenol 2-Chlorophenol 1,4-Dichlorobenzene N-Nitroso-di-

n-propylamine 1,2,4-Trichlorobenzene 4-Chloro-3-methylphenol Acenaphthene 4-Nitrophenol 2,4-Dinitrotoluene Pentachlorophenol Pyrene


QC Run: 23 OCT 96-04

100 89.5 100 83.2

50.0 30.5

50.0 37.5 50.0 31.5 100 91.6

50.0 37.2 100 76.3

50.0 43.7 100 82.0

50.0 52.3

IA)' ~uanterra Environmental Services


90 45-109 83 47-111 61 32-103

75 49-107 63 44-102 92 50-115 74 47-109 76 40-127 87 46-118 82 30-136

105 52-115

~ Calculations are performed before rounding to avoid round-off errors in calculated results . .... 63

~ • . f 1

]

.i d

i I I I :I ii.

~-. I

I

J ]

:1 ::J , . ' ....

..... _

SINGLE CONTROL SAMPLE REPORT Semivolatile Organics by GC/MS

Analyte

Category: 625-A Matrix: AQUEOUS


QC Lot: 23 OCT 96-04 QC Run: 23 OCT 96-04 Concentration Units: ug/L

Nitrobenzene-d5 2-Fluorobiphenyl Terphenyl-d14 2-Fluorophenol Phenol-d5 2,4,6-Tribromophenol

100 100 100 200 200 200

97.0 87.0

118 180 183 200

#j)'\ ~uanterra


Accuracy(%} SCS Limits

97 49-113 87 43-104

118 33-139 90 21- 91 92 54-105

100 33-123


64

.. Q~ .. ~uanterra ·'·

;:·~ Environmental Services

l METHOD BLANK REPORT Semivolatile Organics by GC/MS

Reporting !

J Analyte Result Units Limit

Test: 8270CP-AP9-A

l Matrix: AQUEOUS QC Lot: 23 OCT 96-04 QC Run: 23 OCT 96-04

,-- ·• Acenaphthene ND ug/L 10 ·; Acenaphthylene ND ug/L 10 l ,, .. Acetophenone ND ug/L 10

2-Acetylaminofluorene ND ug/L 100

I 4-Aminobiphenyl ND ug/L 10 Aniline ND ug/L 10 Anthracene ND ug/L 10 Aramite NO ug/L 10

I Benzo~alanthracene ND ug/l 10 Benzo b fluoranthene ND ug/L 10 Benzo!k fluoranthene ND ug/L 10 Benzo g,h,i)perylene NO ug/l 10

] Benzo a)pyrene ND ug/L 10 Benzyl alcohol NO ug/L 10 4-Bromo~henyl

phenb ether ND ug/L 10

] Butyl enzyl phthalate ND ug/L 10 2-sec-Butyl-4,6-dinitro-

phenol ND ug/L 10 4-Chloroanil ine ND ug/L 10

I bis(2-Chloroethoxy) methane ND ug/L 10

bis~2-Chloroethyl) ether ND ug/L 10

I bis 2-Chloroisopropyl)

ether ND ug/L 10 4-Chloro-3-methylphenol ND ug/L 10 2-Chloronaphthalene ND ug/L 10

....... 2-Chlorophenol ND ug/L 10 4-Chlorophenyl

_j phenyl ether ND ug/L 10 Chrysene ND ug/L 10

j Dibenz(a,h)anthracene ND ug/L 10 Dibenzofuran ND ug/L 10 Di-n-butyl phthalate ND ug/l 10 1,2-Dichlorobenzene ND ug/L 10

] 1,3-Dichlorobenzene ND ug/L 10 1,4-Dichlorobenzene ND ug/L 10 3,3'-0ichlorobenzidine ND ug/L 20 2,4-Dichlorophenol ND ug/L 10 .. 2,6-Dichlorophenol ND ug/L 10

' 1 Diethyl phthalate ND ug/L 10 . ,

J I ,Jji_

65

--·

'.-J

J --, i

_ j

·1

P'"1 l i

:.:.J

METHOD BLANK REPORT Semivolatile Organics by GC/MS (cont.)

Analyte Result Units

Test: 8270CP-AP9-A Matrix: AQUEOUS QC Lot: 23 OCT 96-04 QC Run: 23 OCT 96-04

Dimethoate p-Dimethylaminoazobenzene 7,12-Dimethylbenz{a)-

anthracene 3,3'-Dimethylbenzidine a,a-Dimethylphenethyl-

amine 2,4-0imethylphenol Dimethyl phthalate 1,3-0initrobenzene 4,6-0initro-

2-methylphenol 2,4-Dinitrophenol 2,4-0initrotoluene 2,6-0initrotoluene Di-n-octyl phthalate Di phenyl amine Disulfoton bis(2-Ethylhexyl)

phthalate Ethyl methanesulfonate Famphur Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexachlorophene Hexachloropropene Indeno{l,2,3-cd)pyrene Isophorone Isosafrole Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate 2-Methylnaphthalene Methyl parathion 2-Methylphenol 3/4-Methylphenol Naphthalene

ND ND

ND ND

ND ND ND ND

ND ND ND ND ND ND ND

5.8 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND

J =Result is detected below the reporting limit or is an estimated concentration.

ug/L ug/L

ug/L ug/L

ug/L ug/L ug/L ug/L

ug/L ug/L ug/L ug/L ug/L ug/L ug/L

ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L


Reporting Limit

50 10

10 10

10 10 10 10

50 50 10 10 10 10 50

10 10 50 10 10 10 10 10 10

10 10 10 20 10 10 10 10 50 10 10 10

J

66

' Q" A r/Uanterra ;;;it Environmental Services

1 . l .

METHOD BLANK REPORT Semivolatile Organics by GC/MS (cont. )

' .... Reporting

j Analyte Result Units Limit

Test; 8270CP-AP9-A

1 Matrix; AQUEOUS QC Lot; 23 OCT 96-04 QC Run: 23 OCT 96-04

. l 1,4-Naphthoquinone ND ug/L 10 1-Naphthylamine ND ug/L 10

: .. J 2-Naphthylamine ND ug/L 10 2-Nitroaniline ND ug/L 50

I 3-Nitroanil ine ND ug/L 50 4-Nitroaniline ND ug/L 50 Nit robenzene ND ug/L 10 2-Nitrophenol ND ug/L 10

I 4-Nitropheno l ND ug/L 50 4-Nitroquinoline-1-oxide ND ug/L 100 N-Nitroso-di-n-butylamine ND ug/L 10 N-Nitrosodiethylamine ND ug/L 10

I N-Nitrosodimethylamine ND ug/L 10 N-Nitrosodiphenylamine ND ug/L 10 N-Nitroso-di-

n-propylamine ND ug/L 10

I N-Nitrosomethylethylamine ND ug/L 10 N-Nitrosomorpholine ND ug/L 10 N-Nitrosopiperidine ND ug/L 10 N-Nitrosopyrrolidine ND ug/L 10

I 5-Nitro-o-toluidine ND ug/L 10 Parathion ND ug/L 50 Pentachlorobenzene ND ug/L 10 Pentachloroethane ND ug/L 10

a Pentachloronitrobenzene ND ug/L 50 . Pentachlorophenol NO ug/L 50

Phenacetin ND ug/L 10 '"'1 Phenanthrene ND ug/L 10

Phenol ND ug/L 10 4-Phenylenediamine NO ug/L 100 Pho rate ND ug/L 100

. ' 2-Picoline ND ug/L 10

u4 Pronamide ND ug/L 10 Pyrene ND ug/L 10 Pyridine ND ug/L 20

] Safrole ND ug/L 10 Sulfotepp NO ug/L 50 1,2,4,5-Tetrachloro-

benzene NO ug/L 10 - l 2,3,4,6-Tetrachlorophenol ND ug/L 50

I Thionazin ND ug/L 50 ' ~

'· J

~ "'"*-

67

- ·1

'·'.I j

:I J

I I I J ~

METHOD BLANK REPORT Semivolatile Organics by GC/MS (cont.)

Analyte

Test: 8270CP-AP9-A Matrix: AQUEOUS

Result

QC Lot: 23 OCT 96-04 QC Run: 23 OCT 96-04

2-Toluidine 1,2,4-Trichlorobenzene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 0,0,0-Triethylphosphoro-

thioate 1,3,5-Trinitrobenzene

ND ND ND ND

ND ND

Units

ug/L ug/L ug/L ug/L

ug/L ug/L

ll!' ~uanterra Emfronmental Services

Reporting Limit

10 10 50 10

10 10

68

MATRIX SPIKE/MATRIX SPIKE DUPLICATE QC REPORT Semivolatile Organics by GC/MS Project: 052189

Category: 625-A Acid, Base and Neutrals by GC/MS. Matrix: AQUEOUS Sample: 052182-0002 MS Run: 23 OCT 96-04 Units: ug/L

Concentration

Sample MS MSD _ j Analyte Result Result Result

i Phenol ND 88 100 2-Chloro~henol ND 82 95 1,4-Dich orobenzene ND 27 30 N-Nitroso-di-;I n-propylamine ND 40 41 1,2,4-Trichlorobenzene ND 26 31

4-Chloro-3-

I methyl phenol ND 87 96 Acenaphthene ND 31 40 4-Nitrophenol ND 81 92 2,4-Dinitrotoluene ND 46 52

I Pentachlorophenol ND 96 110 Pyrene ND 44 57

I a

' J

] . T . j

ND = Not Detected

Amount Spiked

MS MSO

100 100 100 100

52 52

52 52

52 52

100 100 52 52

100 100 52 52

100 100 52 52

~!)\ ~uanterra

%


Recov. RPO Recovery Accep. RPO Accept

MS MSD Limits MS-MSD Limits

84 96 5-112 13 29 79 91 23-134 14 29 51 58 20-124 13 28

75· 79 1-230 3.5 24

49 60 44-142 19 27

84 92 22-147 9.3 27 59 77 47-145 26 24 78 89 1-132 13 51 88 100 39-139 13 22 92 104 14-176 12 34 85 110 52-115 25 23

d Calculations are performed before rounding to avoid round-off errors in calculated results.

,,, .. I

' i

69

, \

.J

I I I I I I

J ] : l

QC LOT ASSIGNMENT REPORT Semivolatile Organics by GC

Laboratory Sample Number

052189-0001-SA 052189-0002-SA 052189-0004-SA 052189-0006-SA 052189-0007-SA

QC Matrix

AQUEOUS AQUEOUS AQUEOUS AQUEOUS AQUEOUS

QC Category

8080-A 8080-A 8080-A 8080-A 8080-A

IJ)\ ~uanterra

QC Lot Number (DCS)



QC Run Number ( SCS/BLANK)


7(

_ .... ,,,

j

I I

I I

l ti

. ' ·/ ;

LABORATORY CONTROL SAMPLE REPORT Semivolatile Organics by GC

Analyte

Category: 8080-A Matrix: AQUEOUS QC Lot: 23 OCT 96-01 Concentration Units: ug/L

gamma-BHC (Lindane) Heptachlor Aldrin Dieldrin Endrin 4,4' -DDT

QC


Run: 23 OCT 96-01

0.200 0.186 0.200 0.185 0.200 0.174 0.500 0.428 0.500 0.455 0.500 0.441

IJ)'\ ~uanterra



93 81-117 92 72-125 87 69-112 86 77-111 91 83-122 88 76-125

Calculations are performed before rounding to avoid round-off errors in calculated results .

71

: _i

J

I J I I

I • __ I

J ]

I !

SINGLE CONTROL SAMPLE REPORT Semivolatile Organics by GC

Analyte

Category: 8080-A Matrix: AQUEOUS


QC Lot: 23 OCT 96-01 QC Run: 23 OCT 96-01 Concentration Units: ug/L


1.00 1.00

0.200

0.829 0.966 0.179

~J'j\ ~uanterra


Accuracy(%) SCS Limits

83 54-106 97 56-138 90 65-145


72

j

1

J I J I I ~ .

J I ""1

' ~

•t :i

I ~

METHOD BLANK REPORT Semivolatile Organics by GC

Analyte

Test: 8080-AP9-A Matrix: AQUEOUS QC Lot: 23 OCT 96-01 QC Run:

Aldrin Aroclor 1016 Aroclor 1221 Aroclor 1232 Aroclor 1242 Aroclor 1248 Aroclor 1254 Aroclor 1260 alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) alpha-Chlordane gamma-Chlordane Chlorobenzilate 4,4'-DDD 4,4'-DDE 4,4'-DDT Diallate Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide Isodrin Ke pone Methoxychlor Toxaphene

Result Units

23 OCT 96-01

ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L

IA~\ ~uanterra Environmental Services

Reporting Limit

0.050 1.0 1.0 1.0 1.0 1.0 1.0 1.0

0.050 0.050 0.050 0.050 0.050 0.050

1.0 0.10 0.10 0.10 1.0

0.10 0.050 0.10 0.10 0.10 0.10

0.050 0.050 0 .10 2.5

0.50 5.0

73

_ I -1

I _j

I I I I J J

MATRIX SPIKE/MATRIX SPIKE DUPLICATE QC REPORT Semivolatile Organics by GC Project: 052189

Category: Matrix:

8080-A Organochlorine Pesticides AQUEOUS

Sample: MS Run:

052161-0001 23 OCT 96-01

Units: ug/L

Concentration

Sample MS MSD Analyte Result Result Result

gamma-BHC (Lindane) ND 0.19 0.21 Heptachlor ND 0 .19 0.20 Aldrin ND 0.17 0.18 Dieldrin ND 0.44 0.47 Endrin ND 0.48 0.50 4,4' -DDT ND 0.47 0.49

ND = Not Detected

Amount Spiked

MS MSD

0.21 0.21 0.21 0.21 0.21 0.21 0.52 0.52 0.52 0.52 0.52 0.52

IJ)\ ~uanterra

%




94 99 32-127 6.5 20 91 95 34-111 6.2 20 81 88 42-122 9.7 20 86 90 36-146 6.1 20 92 96 30-147 5.7 20 91 94 25-160 5.0 20

~ Calculations are performed before rounding to avoid round-off errors in calculated results.

74

I ... ... J

- j

]

I I I I 1

1 . '

• 1

1 ~

• I

i • _._j.

QC LOT ASSIGNMENT REPORT Metals Analysis and Preparation

Laboratory Sample Number QC Matrix

052189-0001-SA AQUEOUS 052189-0001-SA AQUEOUS 052189-0001-SA AQUEOUS 052189-0002-SA AQUEOUS 052189-0002-SA AQUEOUS 052189-0002-SA AQUEOUS 052189-0004-SA AQUEOUS 052189-0004-SA AQUEOUS 052189-0004-SA AQUEOUS 052189-0006-SA AQUEOUS 052189-0006-SA AQUEOUS 052189-0006-SA AQUEOUS 052189-0007-SA AQUEOUS 052189-0007-SA AQUEOUS 052189-0007-SA AQUEOUS

QC Category

ICP-AT ICP-TRA-AT HG-CVAA-AT ICP-AT ICP-TRA-AT HG-CVAA-AT ICP-AT ICP-TRA-AT HG-CVAA-AT ICP-AT ICP-TRA-AT HG-CVAA-AT ICP-AT ICP-TRA-AT HG-CVAA-AT

IA!\ ~uanterra

QC Lot Number (DCS)

24 OCT 96-$2 24 OCT 96-$2 29 OCT 96-N2 24 OCT 96-52 24 OCT 96-$2 29 OCT 96-N2 24 OCT 96-S2 24 OCT 96-$2 29 OCT 96-N2 24 OCT 96-S2 24 OCT 96-$2 29 OCT 96-N2 24 OCT 96-$2 24 OCT 96-52 29 OCT 96-N2

Emironmenta! Services

QC Run Number (SCS/BLANK}

24 OCT 96-S2 24 OCT 96-S2 29 OCT 96-N2 24 OCT 96-S2 24 OCT 96,S2 29 OCT 96-N2 24 OCT 96-S2 24 OCT 96-S2 29 OCT 96-N2 24 OCT 96-S2 24 OCT 96-$2 29 OCT 96-N2 24 OCT 96-$2 24 OCT 96-S2 29 OCT 96-N2

75

i . j

]

1-J )

I I I I il _j

' l LI

LABORATORY CONTROL SAMPLE REPORT Metals Analysis and Preparation

Analyte

Category: ICP-AT Matrix: AQUEOUS QC Lot: 24 OCT 96-S2 Concentration Units: mg/L

Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Lithium Magnesium Manganese Molybdenum Nickel Potassium Selenium Silver Sodium Tin Titanium Vanadium Zinc

Analyte

Category: ICP-TRA-AT Matrix: AQUEOUS QC Lot: 24 OCT 96-S2 Concentration Units: mg/L

Antimony Arsenic Cadmium Lead Selenium Thallium


QC Run: 24 OCT 96-S2

2.00 2.09 0.500 0.498 2.00 1.97 2.00 2.00

0.0500 0.0527 1.00 1.03

0.0500 0.0493 50.0 49.8

0.200 0.202 0.500 0.520 0.250 0.257 1.00 1.03

0.500 0.558 1.00 0.944 50.0 49.1

0.500 0.494 1.00 1.00

0.500 0.496 50.0 47.9 2.00 2.02

0.0500 0.0495 50.0 49.9 2.00 2.05 1.00 0.993

0.500 0.501 0.500 0.496


QC Run: 24 OCT 96-S2

0.500 0.505 2.00 1.95

0.0500 0.0534 0.500 0.519 2.00 1.90 2.00 2 .10

IJJ\ ~uanterra Environmental Services

Accuracy(%} LCS Limits

104 80-116 100 80-115 99 80-115

100 80-114 105 80-120 103 80-120 99 80-119

100 80-114 101 80-116 104 80-114 103 80-120 103 80-120 112 80-119 94 80-120 98 81-120 99 80-116

100 80-120 99 80-114 96 80-120

101 80-120 99 80-119

100 80-120 103 80-120 99 80-120

100 80-116 99 80-120


101 80-120 98 80-120

107 80-120 104 80-120 95 80-120

105 80-120

:1 Calculations are performed before rounding to avoid round-off errors in calculated results.

76

7? ·-·;

1

· 1

I -. ]

I I I

. I !

]. ·.·. i

. ' j

LABORATORY CONTROL SAMPLE REPORT Metals Analysis and Preparation

Analyte Category: HG-CVAA-AT Matrix: AQUEOUS QC Lot: 29 OCT 96-N2 Concentration Units: mg/L

Mercury


QC Run: 29 OCT 96-N2

0.00100 0.000936

IA~\ ~uanterra

(cont.)



94 80-114


77

'.1: .. ' .. ·''ll _J:

;;

[

~

j : ,

.J ., . :.::

)

I I I I ~

I I

METHOD BLANK REPORT Metals Analysis and Preparation

Analyte

Test: ICP-AP9-AT Matrix: AQUEOUS QC Lot: 24 OCT 96-S2 QC Run:

Antimony Barium Beryllium Cadmium Chromium Cobalt Copker Ni c el Silver Tin Vanadium Zinc

Test: ICP-TRACE-AT Matrix: AQUEOUS QC Lot: 24 OCT 96-S2 QC Run:

Arsenic Lead Selenium Thallium

Test: HG-CVAA-7470-AT Matrix: AQUEOUS QC Lot: 29 OCT 96-N2 QC Run:

Mercury

Q' r/Uanterra Environmental SeITices


24 OCT 96-S2

ND mg/L 0.060 ND mg/L 0.010 ND mg/L 0.0020 ND mg/L 0.0050 ND mg/L 0.010 ND mg/L 0.010 ND mg/L 0.020 ND mg/L 0.040 ND mg/L 0.010 ND mg/L 0.10 ND mg/L 0.010 ND mg/L 0.020

24 OCT 96-S2

ND mg/L 0.010 ND mg/L 0.0030 ND mg/L 0.0050 ND mg/L 0.010

29 OCT 96-N2

ND mg/L 0.00020

78

. ~

J .J

f1 1 '

. j

J 'l 'l . I

_j

I I I I I ~

. i I I

-J

MATRIX SPIKE/MATRIX SPIKE DUPLICATE QC REPORT Metals Analysis and Preparation Project: 052189

Category: ICP-AT ICP Metals / Total Matrix: AQUEOUS Sample: 052189-0001 MS Run: 24 OCT 96-S2 Units: mg/L

Concentration

Sample MS MSD Analyte Result Result Result

Aluminum NA NA NA Antimony ND 0.497 0.500 Arsenic NA NA NA Barium 0.111 2.07 2.09 Beryllium ND 0.0512 0.0512 Boron NA NA NA Cadmium ND 0.0466 0.0459 Calcium NA NA NA Chromium ND 0.196 0.196 Cobalt ND 0.515 0.519 Copper ND 0.257 0.260 Iron NA NA NA Lead NA NA- NA Lithium NA NA NA Magnesium NA NA NA Manganese NA NA NA Molybdenum NA NA NA Ni eke 1 ND 0.481 0.489 Potassium NA NA NA Selenium NA NA NA Silver ND 0.0501 0.0520 Sodium NA NA NA Thallium NA NA NA Tin ND 2.04 1.98 Titanium NA NA NA Vanadium ND 0.S03 0.511 Zinc ND 0.487 0.495

NA= Not Applicable NC = Not Calculated, calculation not applicable. ND = Not Detected

Amount Spiked

MS MSD

2.00 2.00 0.500 0.500 2.00 2.00 2.00 2.00

0.05000.0500 1.00 1.00

0.05000.0500 50.0 50.0

0.200 0.200 0.500 0.500 0.250 0.250 1.00 1.00

0.500 0.500 1.00 1.00 50.0 50.0

0.500 0.500 1.00 1.00

0.500 0.500 so.a so.a 2.00 2.00

0.05000.0500 so.a so.a 2.00 2.00 2.00 2.00 1.00 1.00

o.soo 0.500 o.soo 0.500

#j)\ ~uanterra

%




NC NC 80-120 NC 20 99 100 80-120 0.5 20 NC NC 80-120 NC 20 98 99 80-120 1.1 20

102 102 80-120 0.0 20 NC NC 80-120 NC 20 93 92 80-120 1.4 20 NC NC 80-120 NC 20 98 98 80-120 0.0 20

103 104 80-120 0.7 20 103 104 80-120 1.2 20

NC NC 80-120 NC 20 NC NC 80-120 NC 20 NC NC 80-120 NC 20 NC NC 80-120 NC 20 NC NC 80-120 NC 20 NC NC 80-120 NC 20 96 98 80-120 1.6 20 NC NC 80-120 NC 20 NC NC 80-120 NC 20

100 104 80-120 3.7 20 NC NC 80-120 NC 20 NC NC 80-120 NC 20

102 99 80-120 3.3 20 NC NC 80-120 NC 20

101 102 80-120 1. 7 20 97 99 80-120 1.6 20


79

1 l

~j

I I I

I I :1

MATRIX SPIKE/MATRIX SPIKE DUPLICATE QC REPORT Metals Analysis and Preparation Project: 052189 (cont.)

Category: Matrix: Sample: MS Run: Units:

Analyte

Antimony Arsenic Cadmium Lead Selenium Thallium

Category: Matrix: Sample: MS Run: Units:

Analyte

Mercury

ICP-TRA-AT ICP Metals/ Total by Trace ICP AQUEOUS 052189-0001 24 OCT 96-S2 mg/L

Sample Result

NA ND NA ND ND ND

HG-CVAA-AT Mercury AQUEOUS 052160-0002 29 OCT 96-N2 mg/L

Sample Result

ND

Concentration

MS MSD Result Result

NA NA 2.0 2.0

NA NA 0.52 0.53 1.9 2.0 2.1 2.2

by CVAA I Total Mercury

Concentration

MS Result

0.00096

MSD Result

0.00096

f NA= Not Applicable '-'. NC= Not Calculated, calculation not applicable.

ND = Not Detected

Amount

IA)'\ ~uanterra

%


Recov. RPO

MS Spiked Recovery Accep. RPO Accept

MSD MS MSD Limits MS-MSD Limits

0.50 0.50 NC NC 80-120 NC 20 2.0 2.0 98 100 80-120 1.2 20

0.050 0.050 NC NC 80-120 NC 20 0.50 0.50 105 106 80-120 1.0 20 2.0 2.0 97 98 80-120 0.8 20 2.0 2.0 107 108 80-120 0.8 20

Amount % Recov. RPO Spiked Recovery Accep. RPO Accept

MS MSD MS MSD Limits MS-MSD Limits

0.00100.0010 96 96 80-114 0.0 10

~- Calculations are performed before rounding to avoid round-off errors in calculated results.

80 ......

J l

-

I Appendix

lj)\ ~uanterra


J . , .. : ~.~ W.-"·" ~·

L____;

Chain of Custody Record QUA-4124·1 Client

....

p \<Vfl--C:.5\ Ul\M ~c?.,\11,.~C:, Address 'l

~-··

~--

2\5\'S l-uiM yi t<A'\..A i3 \" d Swt-e.. Z\00 City

IS~eV'l)IZ/p~~ \ \ 0 A\ \;;>-t• "'Y• n ~A' ' Project Name ' ·'Ph-\ \i os 5,..-wU 'DYIA· 1 ,~ Giw Sµy\.f)\\ \\q 0-

CXJ

N ~

ContracVPurcllllse Order/Quote No.

Sample l.D. No. and Description

(Containers for each sample may be combined on one line)

,\ VV\w-z. 0

0

0

7. f\I\"" - 6" 3M'N-h

,4 0 """ w - \ 0 "-> ·-r·~, o f7-i \ tl.lv. .1L.

-

'

o,,.., .. .,.;,.,,..,. Hazard Identification

\

Date

10(2.t l'\b to/-z.l)qb \0 b,.,

0

1 '\t:> lv \"2, \qb

\ol I I

-z-d tl\I.. .. '

r.lhc~J -Projecl Manager

- ....

Son\'\ We.l.-'ux\e...

..... ~ L......J

r7;n~;)er~~3e~;;m~z.. / (505J~B3 - \'&W Site Contact Lab Contact

m~~'0-\n~ Torv.x ~/?\Ll.O Carrier/Waybilf Number -

~ ~ ~ ~ ~ . ~ Containers & t-l Matrix < Preservatives .

c " -g "" ~ ~ 8 (3 i§ u l: ~ ~ ~ Time ~ ~ ! ~ J: ~ ~~ U\ ;/ (/)

~

\ 0 \"\ )( ')( )C. ~ '/. 'f.. x to .34 x x 'f.. 'I- >< "){ )<.

10<.\b x 1)( 'j.

l 130 x '/.. ')(, '}.. x. 'I.. •t---

\~D() )( x x '

··Hazard OF1ammable 0 Skin Irritant 0PolsonB ~Unknown I Sample Disposal

0 Return To Client ~ Disposal By Lab 0 Archive For Turn Around Time Required QC Requirements (Specify)

0 24 Hours 0 48 Hours 0 7 Days 0 14 Days 0 21 Davs

.--J ~ ...... ,.~-'. ,, .... J

Quanterra

Date

\0 \-i.\ \qb Lab Number

Analysis (Attach list if more s oace is needed)

~ .f'l 9 0

~ :1 r >< 'f.. )( ~

'f.. '/..


Chain Of Custody Number

69610 Page ( of i

Special Instructions/ Conditions of Receipt

(A fee may be assessed if samples are retained Months longer than 3 months)

Time

J?'>J6" 1. Received By k'. ZA 1-1 l-U!:iz... ----=-~-=~==;:::;;-=-~~~-::::

Date , 1 Time

Co l.27/ 'I <O I o9 oo Time 2. Received ey Date• Time

3. Relinquished By Time 3. Received By Date Time

Comments

co 2-. coo letrS Q 6-S ;n I. '5 °c , 0~s:o 2. I ''c. _ _.DISTRIBUTION: WHITE - Stays with the Sample; CANARY - Returned to Client with Report; PINK - Field Copy

trtti -~·

jj.;;;.:....-

i ~·~ ~··->

Chain of Custody Record QUA-4124·1

Client

~.~...J ~~'--"'

P y-ufe..ss i o nt.:Ll Pn.t\, \l.lr-S i S Address u

2155 I _,.,.,~sl~e11 \3\lfd si..u+~ 2-100

.. - liiiill ...... .... ... Project Manager

.lohh V'\Je~~ Telephone Number (Ares Cods)/Fsx Number ·

(sos-)~3-oqi+z../ (t;o5)'&~3- ll3t.\-o

r;.·., ..• .,..,_:.../ ~~,,_.; .... ~ .;.:._:· ,,J

Quanterra

DBIB

to/z.t f qb Lab Number•


Chain 01 Custody Number

69611 Page I of l

City

1 S~sW\ ri~~,, o Sits Contact Lab Contact !l Analysis (Attach list if

A \ b VJ,~ IA I mvw ~'p-)nS'!M T~ C.\tt.uD more soace is needed)

(J'"

00

N L.()

Project Name I I

"Phllit:ii;/' - -.,: u:rndv....r.J.1n--<:., 61\/'1 S{)..NY)o\i ~ ContrscVPurc~ase Order/Quot• No. I .....

Sample l.D. No. and Description Date

(Containers for each sample may be combined on one line)

00 M\/\I .. 3 Io ( 2.l-I ~b o7 \V\W-4 \0 li:z,\qi.,

o <2> Tri P Bi\ n.N\.JL... (D /i-:z...l~b I .

-·

Possible Hazard Identification

Carrisr/Way!Jill Number

Matrix

'!! ti ~ ~ Time ~ ;,

o'l 11 x IZ.o3 '/.

(f50 x

D Non-Hazard 0Flammable 0 Skin Irritant 0PoisonB -g:J Unknown

I Sample Disposal

0 Return To Cl/ent Turn Around Time Required

0 48Hours 0 7Davs D t4Davs 0 21 Days Dother Date Tims

~

~ ~ Containers & > >

(/\ Preservatives N 0

oi @ 8 es ~6 ~ ~ ~ (3

~ ~ :t: ~ ~~ :§ lll 6o

)( )( ')( 'f. -;. x )I. x x x

x x

[El Dlsposat By Lab 0 Archive For QC Requirements (Specify)

1. Received By

I~ ');'),- q {;, 131~ ...... -·•·

Dais 1

Time 2. Received By

3. Relinquished By Date . Time I 3. Received By

Comments

~ Ot\.a. ~ QCCS.b / .. D<'C.. nl_C:.TRIAllTlnN· Wl-llTI= - C:tn11c with tho C:!:lmn/o· ri'JAll'JQV - O,of11,nnrl '" r"/il"lnl ..,;1h o ...... ,,.."". DIA.IV

~:-IJ ,.,.. __ ••

j .: 1 Special Instructions!

~ -!h Conditions of Receipt ~

~ (:) .s c-

~ ~~ :r-~

){ y.. >' x x '/.

(A fee may be assessed if samples are retained Months lonfl_er than 3 months)

Date Time

k:. tAH L Le:te.. \6 13 qlo 091') ,Dais Time

Date Time

~ii~,:~

philips semiconductors - welcome to newmexico.gov

Documents