petrogenesis of a migmatite, penobscot ......petrogenesis of the lucerne pluton. eriksson and wones...

295
PETROGENESIS OF A MIGMATITE, PENOBSCOT COUNTY, MAINE: ULTRAMETAMORPHISM OR INTRUSION? by Laura M. Russell Thesis submitted to the Graduate Faculty of Virginia Polytechnic Institute and State University in partial fulfillment of the requirements of the deg~ee o= MASTER OF SCIENCE APPROVED: S. Eriksson in Geological Sciences D. ~- Wones, Chairman D. A. Hewitt May, 1984 Blacksb~rg, Vi~ginia J .I D. Ri:nstidt

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Page 1: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

PETROGENESIS OF A MIGMATITE, PENOBSCOT COUNTY, MAINE:

ULTRAMETAMORPHISM OR INTRUSION?

by

Laura M. Russell

Thesis submitted to the Graduate Faculty of

Virginia Polytechnic Institute and State University

in partial fulfillment of the requirements of the deg~ee o= MASTER OF SCIENCE

APPROVED:

S. Eriksson

in

Geological Sciences

D. ~- Wones, Chairman

D. A. Hewitt

May, 1984

Blacksb~rg, Vi~ginia

J .I D. Ri:nstidt

Page 2: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

PETROGENESIS OF A MIGMATITE, PENOBSCOT COUNTY, MAINE:

ULTRAMETAMORPHISM OR INTRUSION?

by

Laura M. Russell

Committee Chairman: David R. Wones

Geological Sciences

(ABSTRACT)

The Clifton Migmatite crops out between the biotite

grade Bucksport Formation (predominantly calcareous

peli tic quartzite) on the west, the Lucerne Pluton

( bioti te granite) on the sou the a st, and the Parks Pond

Pluton (mafic granite to quartz syenite) on the

northeast. The Parks Pond crystallized at >1000° C.

The leucosomes are I-type (metaluminous, hornblende-

bearing inclusions, primary ti tani te, a 11 ani te,

hornblende, and apatite included in biotite or

hornblende),

biotite).

(Bucksport)

or S-type (tourmaline and red-brown

They are conformable with melanosome

layering, and vary in outcrop from 7-88~~

areally, and in ccmposi tion from tonali te to alkali

granite.

Igneous textures in leucosomes argue against a

solid-state origin, while biotite and plagioclase

analyses indicate that leucosomes were not generated by

in situ melting. Compositions of plagioclase (An-content

Page 3: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

33-28 in melanosome, 38-15

biotite (positive gradient

melanosome with approach

in adjacent leucosome) and

of Ti02 in bioti te of

to leu~osome) demonstrate

disequilibrium. It is argued that the Lucerne was not

involved, based on chronology and mineralogy, and

leucosomes are not injections of Parks Pond magma,

because they lack clinopyroxene, orthopyroxene, and

bioti te. from the Parks Pond. In the leucosomes,

different maximum An-contents of plagioclase, four

different orders of crystallization, and different

compositions suggest that they are multiple melts. 4/5

of analyzed leucosomes are well described as Bucksport

Formation minus restite.

Conclusions: 1) The Parks Pond partially melted the

Bucksport at depth. 2) Melts intruded by lit-par-lit

injection to present exposures. 3) Caution should be

exercised in applying I- and S-type criteria to melts of

calcareous sediments.

Page 4: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

Many than~:s go to David R. \'/ones, my advisor, for

his p3tient assistance in times of need and enthusiastic

support of new concepts. Critical re~i~ws by my ad~iscry

committee, S. Eriksson, J. D. Rimstidt, and D. A.

Hewitt, have improved the manuscript. Susan Eriksson

aided greatly with the field work in Maine, and provided

unpublished analyses of minerals from the Parks Pond

Pluton. I would also like to thank A. K. Sinha, for the

use of his XRF laboratory, and my fellow graduate

students, for their advice and tolerance.

Financial support was provided by a grant from Sigma

Xi, and N.S.F. Grant EAR 8206825 to David R. Wanes.

iv

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TABLE OF CONTENTS

Page·

INTRODUCTION. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

TEXTURES. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

MINERALOGY. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39

BULK CHEMISTRY. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65

TEMPERATURES AND PRESSURES .......................... 75

DISCUSSION .......................................... 91

FURTHER WORK. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 95

REFERENCES .......................................... 96

APPENDIX A .......................................... 101

APPENDIX B .......................................... 108

APPENDIX C .......................................... 19S

VITA ................................................ 290

V

Page 6: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

IUT?.ODUCTION

Iv'Iigmati tes are a twentieth-century e!1.igma.

Sederholm (1907) first focussed attention on these rocks

by coining thG term, and defining them as,

II .gneisses. • • I characteristic of which are two elements

of different genetic value, one, a schistose sediment or

foliated eruptive, the other, either formed by re-

solution of material like the first or by an injection

from without, 11 In the following years, he held that

injection of igneous material from below produced most

migmatites. Other workers, led by Holmquist ( 1921),

contended that partial melting in situ prevailed in the

genesis of migmatites.

Since then, migmatites have been extensively

examined. Most workers have come to agree that: l)

migmatite should be used as a descriptive, textural term,

rather than a genetic one, and 2) no single origin

belongs to the group of rocks classified as migmatites

(Dougan, 1979; McLellan, 1983; Misch, 1968; Harris, 1974;

Mehnert, 1971; White, 1966; Amit and Eyal, 1976; Olsen,

1977). At the present state of knowledge, migmatites may

be formed by any of the following: 1) rnetasomatism 2)

metamorphic differentiation 3) partial melting

injection.

or 4)

Mehnert (1971) suggested the nonqenetic definition:

Page 7: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

2

"~egascopically corr,posi te rock consisting of two or mc-,;::e

petrographically different parts, one is the country rock

in a more or less metamorphic stag2, the other is of

pegr:":a ti tic ap:..itic, 9ranitic, or gen2rally pli.;.tol:ic

appearance." Commonly, the metamorphic-appearing port.ion

of a migmati te is darker colored than the igneous-

appearing portion.

melanosome and the

Thus, Mehnert called the former a

latter a leucosome. Mehnert's

terminology and definitions are followed in this paper.

PREVIOUS WORK

Heretofore, the Clifton migmati te has neither been

mapped nor examined in detail. Otherwise, the immediate

area has been well studied. Trefethen (1950) conducted

preliminary mapping, followed by Cavalero (1965).

Subsequently, Wones ( 1980) mapped the entire Lucerne

Pluton and its environs. In 1982, Eriksson further

delineated the borders of the Parks Pond Pluton. Both

Cavalero (1965) and Wones (1980) investigated the

petrogenesis of the Lucerne Pluton. Eriksson and Wones

(1983) reported preliminary work on the petrogenesis of

the Parks Pond Pluton. Cavalero (1965) and Novak (1979)

studied reactions in nonmigmati tic por~ions of the

Lucerne's contact aureole.

GEOLOGIC SETTING

Figure 1 shows part of the Passagas3awakeag-

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3

Figure 1. Geologic map of field area.

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4

GEOLOGIC MAP OF PARKS PONO ANO VICINITY

PENOBSCOT COUNTY, MAINE by Louro M. Ruuell

after: Cavelero (1965), Erikuon (1982), and Wanu (1974-1978)

[TI] MIGMATITE

D BUCKSPORT FORMATION

------ •••••• CONTACT; solid where exposed, dashed where opproaimate, or dolled where concealed

0 300 .... ,..

, , ..., ,,/<::'

''--·-·- .... , ..

EXPLANATION

PLUTONIC ROCKS

G WCERNE PLUTON

D PARKS PONO PLUTON

I~ i ' \); I ;(7·1. I

J c: \ '

~ ~ " 7 \,~ '\J '--"2~<'

,_

<

Page 10: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

5

Bucksport structural block, a northeasterly trending

terrane that extands southeasterly to the faulted

Bucksport-Penobscot contact (Novak, 1979). To the

no rt:i.we :3 t, the ?assagassawakeag-Bucksport block

merges with the Waterville-Vassalboro block (Osberg,

1978) or is separated from it by the northeast-trending

Norumbega fault (Wones, 1980). To the northeast of

Figure 1, the Norumbega fault truncates the Parks Pond

and Lucerne Plutons; to the north, it separates the

Bucksport and the Vassalboro Formations.

To date, the Lucerne Pluton is the best-studied rock

in the area. It has been described by Wones (1980) as a

pinkish-white, coarse-grained, seri ate to porphyritic,

bioti te granite with rapaki vi textures. According to

two-feldspar geothermometry, it crystallized at 725°c.

Norms projected onto an An-Ab-Or ternary cluster around

experimentally determined eutectic compositions at

pressures of 1 kb. The Lucerne Pluton has been dated by

Rb/Sr, Pb, and K/Ar methods. All ages fall within

350-400 r.1y, but the preferred age is 380 my (Lux,

personal communication).

The Parks Pond Pluton is a dark green, fine-grained,

granular, r.1afic granite to quartz syenite that contai~s

hypersthene, diopside, and bioti te. Preliminary t1,,10-

pyroxene geother:nometry yields crystallization

Page 11: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

6

temperatu:-es of 1000° C (ErikssoYi and Wones, 1983). The

Parks ?ond PlutoYi is younger than the intruded Bucksport

Fo=~ation, y2t older t~an the Luc~rne Pluton. D2.k,?.s of

the latt~r intrude the Pa=ks Pend Pluton in two areas.

in addition, Eriksson (personal communication) has

determined a preliminary Rb/Sr age of 384 +/- 52 my (2

sigma).

The Bucksport Formation is a greyish-green

(calcareous) and black to reddish-brown (noncalcareous)

very fine-grained pelitic quartzite that has been

regionally metamorphosed to chlorite/biotite grade of the

greenschist facies. Within the contact aureoles of the

Lucerne and Parks Pond Plutons, the dominant phases are:

quartz + plagioclase + bioti te +/- clinopyroxene and

amphibole. No fossils have been found in the Bucksport;

a late Silurian/early Devonian age has been assigned

based on assumed equivalencies with the lithologically

similar Vassalboro and Flume Ridge Formations. The

former contains graptolites (Osberg, 1978), while the

latter is correlati·,re with the Waweig Formation and

Devonian intrusives (Ruitenberg and Ludman, 1977).

St:?::"ucturally and chronologically, the Bucksport

displays:

1) compositional layering (transposed bedding-Novak,

1979),

Page 12: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

7

2) the development of schistosi ty, parallel to

compositional layering, with approach to the Lucer~e or

Farks Pond Plutons,

3 ) mi no r c, pen f o l d s sup e rim po s e d c :1 i soc 1 i r:. a 1 f o L ls

(Cavalero, 1965),

4) quartz+/- calcite veins that typically cross cut

compositional layering,

5) small faults ( surficial exposure of 30-70

centimeters) that displace folds,

melanosomes by up to 5 centimeters.

leucosomes, and

The sense of

displacement is left-lateral, and right-lateral oblique-

slip.

6) minor mylonitization.

Compositional layers are distinguished in the field

by color-coding of greenish-grey for Ca-rich layers and

black to reddish-brown for Ca-poor layers (Fig. 2). The

latter become reddish-brown with approach to the Lucerne

(Novak, 1979) or Parks Pond Pluton, due to the presence

of red-brown biotite. Within the aureoles, calcareous

layers do not react with HCl. However, they have become

indurate, while noncalcareous layers are brittle and

fracture easily during sampling.

Novak (1979) estimates that 70-80% of the layers are

calcareous, and the remainder noncalcareous. This

estimate agrees with observations made in this study,

Page 13: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

8

Figure 2. Compositional layering in the Bucksport

Formation.

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10

e:{cept within the rr.igmati te, wher-e calcareous layer·s are

even :no re dominant. The sc arc 1 ty and fri ability of

noncalcareous layers has made tr-.eir :;ampling difficult.

Novak (J.979) claims that most of the layeri':g is

transposed bedding, noting that it is axial planar to the

NE-trending open folds. Strata range in thickness from

one meter to millimeters,

centimeters.

averaging about two

The migmatite consists of interlayers of melanosome

and leucosome. The melanosome closely resembles the

Buckport Formation. The leucosome is a black and white,

fine to medium grained, granular tonali te to alkali

feldspar granite/quartz-alkali feldspar syenite with

biotite +/- hornblende and mafic inclusions. The

migmatite is younger than the Bucksport Formation to the

west, but older than the Lucerne Pluton. The Lucerne

Plut0n cross-cuts poorly developed foliation in the

migmatite in the southern part of the mapped area shown

in Figure 1.

The migmati te only occurs in portions of the

aureoles of the Parks Pond and Lucerne Plutons. Tr.e

eastern margin of the Parks Pond Pluton is is covered by

swarr:p, e;..:cept about 200 r'.1eters east of the esti:na -c2d

contact, where an outcrop of the Bucksport Formation was

found. On the west, the Clifton Migmati te/Parks Pond

Page 16: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

11

contact is exposed in only one area (Fig. 3). No.::-th of

the area shown in Figure 1 the western edge of the Parks

Pond is completely covered by glacial till and soil.

Float suggests that the migmatite conti~ues northward.

There are ten exposures of the Lucerne/Bucksport

contact (Wanes, in press). The migmatite crops out at

only two out of these ten exposures: a) in the study

area (Fig. 1) b) 3 km to the SSW of the study area. The

latter occurs as a lens-shaped, 1. 2 by O. 1 km body that

contains material very similar to that found in this

study.

Leucosomes are predominantly conformable with

layering in the Bucksport (Fig. 4). Rarely, they cut

across melanosomes and terminate in wispy strands.

selvages are absent.

Mafic

The percentage of leucosome in outcrop varies from

7-88%. The exposure of outcrops within the migmatitic

zone is about 10%. Surprisingly, leucosomes do not

increase in area with approach to the Parks Pond and/or

Lucerne Plutons; the variation is apparently random. The

percentages of different rock types were visually

estimated, except for outcrops RMA and RMB, where 100

pciri.ts were counted on meter and/or half meter grids

(Fig. 5). Outcrop RMA is the sample location for #31 and

#32, while RMB is located where sample #8 was collected.

Page 17: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

12

Figure 3. Contact of the Clifton Migmatite with the Parks

Pond Pluton.

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Page 19: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

14

Figure 4. Conformable leucosome and rnelanosome layering.

Page 20: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

15

Page 21: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

16

Figure 5. Schematic diagrams of outcrops RMA and RMB. In

the lower portion of the sketch of RMA, melanosomes are

isoclinally folded, axial planar to compositional

layering. The orientation of the lines that symbolize

melanosomes approximates the strike of compositional

layering.

Page 22: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

:z: 0 >--< f-c::r: :z: c::r: _J

CL

>< w

~)

-u V1

0 C

IO

<lJ :E:

::::5 0 ,JJ E 0 V

1 0 u ::::5 <lJ

_.J

ill D -:

(1) ~

.j..) (1)

..... >

,--0

0. u

c::r:

~D

17

;:

~' z .j..) ,--::::5

. -· :::_~· ~"-

~ ...::

,;'

IO

LI..

"

~-~ .: -.:'

-: .

--C ,

,'

.. £ ~--... ~ -:.,. ..:·

Page 23: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

18

RMA contains 13% leucosome, 85% melanosome, and 2%

aplite. Ri'fJB .... . cor2c.a1ns 81% leucosome, 14;~ melanosome, 40; ... /,j

aplite, and 1% quartz veins.

The aplite occurs as white, fine-grained,

plagioclase and quartz-rich dikes that cross-cut the

Clifton Migmatite (Fig. 5).

Bedrock is well exposed in the northern and southern

portions of the studied area (Fig. 6). The center of the

area is occupied by Parks Pond and stream deposits. All

sample locations are plotted on Figure 6, except for #45

and #35-37.

north of #4 7.

#45 was sampled about 350 meters to the

#35-37 were collected from an outcrop on

the north side of lA, 0.88 kilometers west of the lA/46

intersection, 14 kilometers southwest of Parks Pond.

This is outside of the contact aureoles of the Parks Pond

Pluton and the Lucerne Pluton. #35-37 are samples of the

low-grade, regionally metamorphosed Bucksport Formation

Page 24: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

19

Figure 6. Map of sample locations and structure.

Page 25: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

0 300 meters

20

4 7•\-1°

: 6 ,9 • s: II : 10--i _1~3

7•' : i4,12 : 46 I

I • • I /

/ /

/ r40.41 , 43,44• f38,39 ,'

}, \-GB ,' /

/ /

Dmgp

DOb

.:2011: 21-23 1,( I • _.: - ' ' :°28 • ' .,'I ta2 ';10,19 29, r6 8 ,

I \33,341 I '\ I

31,32111,30 h,' 1' 1 e2 , a5

I

/

I .. 2 I

\ 8 t\ "'"

/

' ' 1 25 ' \::~,--6 ' .

/

, 27 \

'

/

"

' ...

"

, ... /

I'

42f I

I (

/

/ .:DOcm./ .. ··· Dgl

EXPLANATION

------ •••••• CONTACT, solid where exposed, dashed where approximate, or dotted where concealed

,~Jo

SAMPLING LOCATION FOR 3 ANO 4

STRIKE AND DIP OF COMPOSITIONAL LAYERING IN THE BUCKSPORT FM

VERTICAL COMPOSITIONAL LAYERING

Ogl LUCERNE PLUTON

Omgp PARKS PONO PLUTON (maf1c granite) quartz monzanite to quartz syenite

00cm CLIFTON MIGMATITE

00b BUCKSPORT FORMATION

Page 26: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

TEXTURES

Textural similarities in the Bucksport For~ation and

melanosomes include: the lack of porphyroblasts, a

general lack of poikilitic minerals, and the infrequent

occurrence of 120° angles at triple junctions. Closer

inspection reveals that 120° angles are well developed in

areas that lack phyllosilicates. Usually, the preferred

orientation of micas controls the shape of adjacent

grains (Hobbs et al., 1976).

The dominant, calcareous rocks exemplify typical

textural changes in the Bucksport Formation. Toward the

Parks Pond Pluton, the average grain size increases from

0.03 to 0.06 mm, simple compositional layering evolves

into gnei ssic banding, and the alignment of minerals

becomes more prominant. Macroscopic calcareous ( and

noncalcareous) layering noted in outcrop extends to the

microscopic scale. The microscopic layers are

millimeter-thick bands, distinguished by their alternate

modal mineralogies. At higher grades, dark bands (mostly

clinopyroxene + amphibole) are segregated from light ones

(plagioclase + quartz). Compositional layering is always

parallel to the alignment of minerals. Axes of quartz

grains appear to be subparallel at low grade ( sample

#13). At higher grades to the east, bioti te and

amphibole define a good schi stosi ty. Similar textural

21

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22

changes occur in the southern portion of the field area

with approach to the Lucerne Pluton.

In textural contrast to the melanosomes, leucosomes

contain many sub- to euhedral phases, are coarse-grained,

lack any obvious foliation, and minerals within the

leucosomes often contain inclusions. Within these bounds

they vary widely and nonsystematically. Most are

hypidiomorphic granular and range from O. 3 to 1. 8

millimeters in average grain size. However, samples 7B

and 25 are hypidiomorphic porphyritic, with on average

2.9 and 6.4 mm alkali feldspar phenocrysts set in 0.8 and

0. 9 mm matrices,

igneous textures.

respectively. Leucosomes display

This is indicated by subhedral quartz

( sample #39), euhedral plagioc lase, subhedral bioti te,

euhedral amphibole, and a sparsity of 0 120 angles at

triple junctions.

Inclusions within the leucosomes display metamorphic

characteristics. These inclusions typically contain:

oval clumps of randomly oriented, tiny sub- to anhedral

amphibole crystals interspersed with biotite +/- opaques,

iron oxides, apatite, zircon, plagioclase, titanite,

quartz and tourmaline. The tourmaline has brown cores

and clear rims, as does most tourmaline in the leucoscm8s

and me 1 ano some s . T · 1 · t · often subtend 120° rip e June ions

angles. The clumps are sometimes mineralogically zoned,

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23

as shown by large biotite plates aligned tangentially to

the inclusion, the concentration of bioti te toward the

rims, or clincpyroxene in the cores. The average grain

size of inclusions (0.1-0.35 mm) is always much smaller

than that of the surrounding leucosorne.

Leucosomes contain primary plagioclase + alkali

feldspar+ quartz+ biotite +zircon+ tourmaline+/-

apatite, titanite, allanite, and opaques. Chlori te +

saussurite +/- opaques and titanite occur as secondary

minerals. Commonly, plagioclase is subhedral and zoned,

alkali feldspar is anhedral and perthitic, and quartz is

anhedral. Sometimes zoned plagioclase and alkali

feldspar have distinct, possibly remnant cores.

Eleven leucosomes were examined for determination of

crystallization order. Four distinct orders were found

in these samples (Fig. 7). The interpretations were made

from textural observations. For example, the occurrence

of euhedral apatite in the cores of large, zoned

plagioclase crystals suggested that apatite crystallized

before plagioclase. This multiplicity of crystallization

orders suggests that leucosomes did not crystallize from

a single liquid, or that crystallization paths were

kinetically determined (Lofgren, 1977).

The leucosomes are modally heterogeneous and

nonsystematic (Fig. 8 and Table 1). The variation does

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Figure 7. Illustrations of crystallization order in the

leucosomes. Dashed lines represent subsolidus

crystallization, and dotted lines symbolize uncertainty.

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Sample #20A-l

Tourmaline Apatite

Zircon Titanite ----Biotite

Plagioclase Al lanite

Kspar ········· Quartz

Amphibole Chlorite - - --

Iron Oxides - -- -Hagma Rock

Sample #39 Tourma 1 ine

Apatite Zircon

Titanite - - - -Biotite

Plagioclase Al lanite

Kspar ~~~~~~~~~~~~~~~~~~

Chlorite Iron Oxides

Opaques

Magma

-- -· ___ .. - - --Rock

Sample #2C, 25, 27, 78, 9A, 11

Tourn11 line Apatite

Zircon Titanite I · · · · · · · · · · · · · · · ·- - - -Biotite

Plagioclase Al Jani te

Kspar Quartz ........ ,.1 ...... .

Chlorite - - - -Opaques - - - -

Hagma Rock

Sample #34, 4, 12 Tourma~-----

Apatite Zircon

Tittnite Biotite

Plagioc lase Ks par

Quartz Amphibole '"'"'" I ---. Iron Oxides - - - -

Opaques - - - -

Hagma Rock

N Vl

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26

Figure 8. Classification of leucosomes (based on

Streckeisen, 1973).

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27

CLASSIFICATION OF LEUCOSOMES

Q

+ + +

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TAH!.. 1 HO!JAI ANAIYSES OF l.EUCOSOHES (lOOO pointa)

2C 4 5 7B 8A 9A 11 12A 17A 18 20A 208 25 27 32C 34B 39

Quartz 32. 8 34.0 2 7. 7 13. 5 13. 9 27.9 2 7, 1 31. 9 23.0 23.3 20.0 18.9 18.0 18.7 27.8 17.6 34.3 Plagioclase 29.0 3 7. 7 2 9. 5 0.8 26.3 34.8 36.1 36.0 30.8 28.4 20.9 38.9 34. 3 45.0 29.0 52.2 21. 2 K-feldspar 32. 3 8.0 3 3. 6 5 3. 5 40.0 28.8 25.8 6. 7 2.8 29. 1 26.2 13. 5 32.2 14.8 22.6 13.0 44, 5 Amphibole 1. 1 0.2 -- 1. 2 4.5 -- -- 1. 0 3. 2 2. 4 3.0 1.1 5.0 0.5 -- 1. 3 --Biotite 2, 8 15. 9 1. 2 5. 5 4.2 6.3 0.6 11. 0 14.0 1. 9 10.0 6.0 6.7 17. 7 15.6 10.8 2.0 Epidote 0. 1 -- o. 1 -- o. 1 -- -- -- 0.2 tr 0.2 tr o. 1 tr tr 0.1 tr CPX -- -- -- tr -- -- -- -- -- -- -- tr -- -- -- -- --Titanite 0.4 o. 3 -- 0. 2 0. 3 o. 1 0.1 0.1 0.4 0.9 0.8 0.6 0.8 0.5 0.2 1. 0 o. 1 Apatite tr tr tr 0.2 0. 1 -- -- 0.2 -- 0.1 -- tr 0.1 0.1 -- 0.3 tr Tourmaline o. 3 tr 0.2 0.6 0.3 0.1 0.2 0.4 0.8 o. 3 0.6 0.8 0.5 0.4 0.5 tr o. 1 Zircon o. 2 0. 1 o. 1 0.1 o. 2 -- 0.2 tr tr tr tr tr 0.2 0.2 0.4 0.2 tr Opaques 0.1 0.3 0.8 o. 1 0. 1 0.2 -- 0.1 o. 2 -- -- -- o. 5 0.1 1. 1 0.5 tr Chlorite 0.9 1. 1 6.8 0.2 0.5 1. 8 6.1 0.5 0.3 1. 9 0.6 0.5 1. 6 1. 7 2.8 3.0 1. 5 Iron Oxides -- tr -- -- -- -- -- 0.1 o. 1 0.2 o. 1 -- tr tr -- -- tr

N

ENCLAVES :))

Amphibole -- 0. 7 -- 18.0 6.7 -- -- 3.2 13.3 7.2 13.1 6.8 Biotite -- 1. 7 -- 6.0 2.8 -- -- 9. l 10. 1 4.3 5. 1 12.9 Opaques -- tr -- tr tr -- -- tr o. 2 tr 0.2 Iron Oxides -- tr -- -- -- -- -- tr o. 1 -- --CPX -- -- -- 0, 1 -- -- -- -- 0.5 -- 0.3 Titanite -- -- -- -- -- -- -- tr tr tr Apatite -- -- -- tr tr -- -- tr -- tr Zircon -- -- -- tr tr -- -- tr -- tr Quartz -- tr -- -- -- -- -- tr tr Tourmaline -- -- -- -- tr

absent tr trace

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29

not correlate with distance from the Parks Pond or

Lucerne Plutons and follows no typical fractionation

trend (Hyndman, 1972). Additionally, leucosomes from the

northern and southern portions of the field area do not

belong to separate groups, with respect to their modal

mineralogies.

In the Bucksport Formation and the melanosomes,

reaction textures were infrequently observed. For this

reason, reactions were inferred from Vidale's (1969) ACMK

quaternary. The noncalcareous Bucksport Formation

exhibits a relatively simple series of reactions. The

topological change shown in Figure 9, going from sample

#37 to #14, suggests the reactions:

1) Albite (Ab)+ Calcite (Cc)+ Quartz (Q) +

Muscovite (Mu) + Chlorite (Chl) = Ca-plagioclase (Ca-

plag) + Biotite (Bt) + K-feldspar (Ksp) + Vapor (V)

2) Ab + Cc + Q + Mu = Ca-plag + Ksp + V

Concomittantly, the mole fraction of anorthite in

plagioclase rises from (0-2) to (27-57). The only

further change in mineralogy is the disappearance of

calcite.

The reaction sequence in the calcareous layers

begins with the same two reactions, plus reaction #3

(Fig. 10). From sample #35 to sample #13 the mole

fraction of anorthite in plagioclase rises from (1-2) to

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30

Figure 9. ACMK diagrams, illustrating reactions in the

noncalcareous Bucksport Formation.

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CaO cc

Sample #37

Al203

MgO

+ Quartz + Vapor + Ab

KAl02 ~ CaO cc

Ab+ Cc+ Q +Mu+ Chl =Ca-pl+ Bt + V Ab+ Cc+ Q +Mu= Ca-pl+ Ksp + V

Sample #14

Al203

MgO

+ Quartz + Vapor + Ab

KAl02 Ksp w .......

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32

Figure 10. ACMK diagrams, displaying reactions in the

calcareous Bucksport Formation.

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Sample #35 Sample #13

Alz03 Al2o3 + Quartz /1\ /1\ + Quartz + Vapor + Vapor + Ab Ah+ Cc+ Q +Mu+ Chl + Ca-plag + Bt + Ksp + V + Ab

Ab+ Cc+ Q +Mu= Ca-olag + Kso + V ~ ......

~~ ~ - ,.:-:-Ii f- -7 Kl :oz ~ CaO -4KAl02 r.c .,, ""' Ksp .,, .,, .,, Chl +Cc+ Q =Act+ Ca-plag + V

,_ IJ''l-1 I w w

/ lH V MgO MgO

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34

(30-37), and a topological change occurs that suggests

both reaction #1, #2, and:

3) Chl +Cc+ Q = Actinolite (Act) + Ca-plag + V

In this and other reactions involving K-feldspar,

the modal increase or decrease in K-feldspar doesnot

match that expected from the stoichiometries of the

reactions. It is a very minor phase in the Bucksport

Formation and the melanosomes. Novak ·(1979) discovered

the same discrepancy, and suggested that K-feldspar has

been dissolved and removed during metasomatism. Such a

process could have been driven by a concentration

gradient in K across the boundary between adjacent,

millimeter-thick layers in the Bucksport Formation and

the melanosomes.

discrepancy.

It is a reasonable explanation for the

Finally, clinopyroxene is formed. There is evidence

to suggest that it forms from both of the following:

4) Act+ Cc + Q = Clinopyroxene (Cpx) + CO2 + H20

and

5) Ksp +Act= Bt + Cpx + Q

Reaction #5 is suggested by a change in modes (Fig.

11, Table 2). With approach to the Lucerne Pluton,

biotite, clinopyroxene, and quartz increase, while

amphibole and K-feldspar decrease. Notably, K-feldspar

does not decrease enough to balance the increase in

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35

Figure 11. Modal evidence for reaction 5.

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CHANGES IN MODES WITH APPROACH TO LUCERNE PLUTON ij2

31A-1 39 33A 26A

Quartz 36

33

30

27

2ij

o-.51.

,...... 21 <tl

-0 0

::E 18

IS

12

9

6

3

0 Kspar 0 20 ij0 60 80 100 120 [ijO 160 180 200

Di stance from the Lucerne Pluton, in ~eters

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Table 2 MODAL ANALYSES OF MELANOSOMES (1000 pts}

38 46A lOA 3A 31A-l 33A 26A 228 Quartz 43.8 37.4 42.0 39.7 38.0 38.2 40. l 30.4 Plagioclase 29.9 33.7 38.4 31. 5 27.2 32.2 29.3 38.7 Amphibole 13.5 8.7 2.2 11.8 24. l 15.3 3.3 tr Bi otite 8.4 0.8 15.8 8.3 1.8 4.5 11. l 29. l K-feldspar l. l 2.4 0.7 1.0 3.8 2.2 1.4 0.5

L,J

Epidote tr 0.6 0.2 0.3 0.5 2.3 ....... --Cpx -- 7.9 0.5 4.9 0.3 2.4 10. 2 Titanite 0.6 2.8 0.2 1.4 2.5 2.4 1.5 Apatite tr tr tr -- -- 0.3 tr 0.2 Tounnal ine 0. 1 tr tr 0.4 0. 1 0. l tr 0.3 Zircon 0.5 -- 0.2 0.3 0.8 0.7 tr 0.2 Opaques 0.3 tr -- tr tr 0.2 0. 1 Ch 1 orite 1.8 5.3 tr 0.5 0.8 0.9 0.7 0.2 Iron Oxides -- 0.4 tr -- 0. l 0.3 -- 0.4

tr trace none

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38

biotite. Reaction #4 is suggested by Novak and the modes

in sample #44. The latter contains abundant

clinopyroxene, but less than 1% biotite. Reactions #1,

2, and 4 agree with those found by Novak (1979). Neither

reaction #3 nor reaction #5 was observed by Novak.

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MINERALOGY

Plagioclase

Zoning of plagioclase in the leucosomes is normal

for igneous rocks: calcic cores grade into sodic rims.

Zoning of plagioclase in melanosomes and in the Bucksport

Formation is both calcic to sodic and sodic to calcic.

The latter is observed with increasing grade, when low-

grade sodic plagioclse is armored and preserved. The

former may have resulted from retrograde metamorphism

associated with the intrusion of the Lucerne Pluton, or

cooling of leucosomes.

If in situ partial melting occurred, melanosomes

would be expected

plagioclase (Misch,

check this: 1) in

to contain refractory calcic

1968). There are two good places

the stratigraphically adjacent

to

melanosome #33 and leucosome #34, and 2) in sample #23,

which contains immediately adjacent melanosomes and

leucosomes. The plagioclase in sample #33 is more calcic

than the plagioclase in #34, and may have formed from in

situ melting or reaction with the leucosome. The

situation is reversed in sample #23 (Fig. 12). The

leucosome contains more calcic plagioclase than does the

immediately adjacent melanosome. it is unlikely that in

situ melting occurred in this sample.

In the leucosomes, the maximum anorthite-content of

39

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40

Figure 12. Compositions of plagioclase in adjacent

melanosome and leucosome, sample 23. The diagram is

based on 41 analyses of plagioclase from the melanosome

and 30 analyses from the leucosome. The data were

obtained during five separate microprobe traverses

(Tables 3 and 4).

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110.0

32.S

C: 30.0 ci::

~

~ ttl 27.5 ,.... ::, u Q) ,.... 25.0 C

:::E

22.S

20.0

l 7.S J 15.0

I

41

COMPOSITIONS OJ? PLAGIOCLASE IN ADJACENT MELANOSOME AND LEUCOSOME

SAMPLE 23

Leucosome

Melanosome

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Tabl<.: 3 SELECTED MICROPROBE ANALYSES AND STRUCTURAL FORMULAE OF PLAGIOCLASE

Leucosomes Melanosomes Bucksport Fm ----------------------------------------------------------- ------------------------------- --------------

8A 34 3A 31 14 27a 25a 9Aa Core Rim Core Rim Core Rim Core Rim Core Rim

Si02 61. 41 64.86 61. 59 58.27 62.79 61.67 64.37 55.99 56.52 57. 20 55.54 56.82 55.78

Ti02 0.02 0.04 0.04 0.00 0.06 0.03 0.02 0.02 0.04 0.06 0.03 0.06 0.02 Al 2o 3 23.98 21. 32 23.12 25.10 21. 98 25.61 21. 48 26.80 26.84 27.05 27.18 25.31 26.96 FeO 0.00 0.41 0.02 0.08 0.07 0.16 0.08 0.07 0.11 0.23 0.19 0.91 0.12 MnO o.oo 0.02 0.01 0.00 0.28 0.00 0.01 0.32 0.34 0.33 0.62 0.36 0.22 MgO 0.00 0.03 o.oo 0.08 0.00 0.00 o.oo 0.06 0.02 0.06 0.04 0.69 0.09 Cao 5.16 2.54 4.80 7.03 3.19 6.29 3.17 9.35 8.98 8.99 9.54 7.98 9.07 Na2o 8. 76 10. 43 8.61 7. 46 9.48 7.87 10.13 5.93 6.06 6. 73 6.34 6. 77 6.42 K20 0.08 0.17 0.10 0.10 0.18 0.26 0,04 0.18 0.16 0.16 0.19 0.30 0.11

..,.. N

Total 99.41 99.82 98.29 98.12 98.03 101. 89 99.30 98. 72 99.07 100.81 99,67 99.20 9fl.79

Si 2.740 2.870 2. 773 2.650 2.829 2.691 2.860 2. 549 2.561 2.554 2.519 2.584 2.540 Al 1. 261 1. 111 1. 227 1. 345 1.167 1. 317 1,125 1. 438 1. 433 1. 423 1.452 1. 357 1. 447 Ti 0.001 0.001 0.001 0.000 0,002 0.001 0,001 0.001 0.001 0.002 0.001 0.002 0.001 Sum 4.001 3.982 4.001 3.995 3.998 4.009 3.985 3.988 3.995 3.980 3.972 3.943 3.987 Fe 0.000 0.015 0,001 0,003 0.003 0.006 0.003 0.003 0,004 0.009 0,007 0.035 0.01)5 Mn 0.000 0.001 0.000 0.000 0.011 0.000 0,000 0,012 0.013 0,012 0,024 0.014 0.008 Mg 0.000 0.002 0.000 0,005 0,000 0.000 0,000 0,004 0.001 0.004 0,003 0.047 0.006 Ca o. 247 0.138 0,232 0.350 0.168 0.300 0.154 0.456 0.437 0.430 0,404 0.389 0.442 Na 0.758 0.895 0. 752 0.658 0.828 0.666 0.873 0,524 0.532 0.583 0.557 0.597 0.567 K 0.005 0.010 0.006 0.006 0.010 0.014 0.002 0,010 0.009 0,009 0.011 0.017 0.006 Sum 1.009 1. 043 0.990 l. 014 1.006 0.980 1.029 1.009 0.996 l, 04 7 1.066 1. 099 1. 035 0 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8,000 8.000 8.000 8.000 8.000 8.000 AN 24.45 11. 75 23,42 34, 05 15,52 30.18 14. 71 46,07 44,60 42,09 44.92 38.76 43.57 :\ote: Analyses with the superscript 'a' were used in two feldspar ge~thermometry. Fe is total iron.

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Table 4 SELECTED MICROPROBE ANALYSES AND STRUCTURAL FORMULAE OF ALKALI FELDSPAR

Leucosomes Melanosomes Bucksport Fm --------------------------------- --------------- ---------------25

9A Rim Core 27 31 33 44 14

Si0 2 64 .16 63.25 64 .12 65.03 64.53 65.24 65.14 64.94

Ti0 2 0.07 0.00 0.03 0.05 0.03 0,06 0.02 0.07

Al2o3 18.02 18.48 18.79 18.58 18.47 17,85 18.14 18.51

FeO 0.17 0.04 0.04 0.06 0.09 0.36 0.12 0.45

MnO 0.02 0.00 0.04 0.00 0.00 0.03 0.04 0.01

MgO 0.04 0.05 0.04 0.00 0.22 0.18 0.00 0.00

Cao 0.08 0.03 0.03 0.04 0.09 0,09 0.05 0.05

BaO ----- 0.58 0.55

Na2o 0.55 0.37 0.32 1.02 1.00 0.29 0.40 0.44 ~ I.,.}

K2o 15.49 15.55 14. 77 14.95 14.81 14. 72 15.96 15.59

Total 98.60 98.35 98.73 99.73 99.24 98.82 99.87 100,06

Si 3.001 2.980 2.989 2.997 2.990 3.026 3.010 2.994

Al 0.993 1. 026 1.032 1.009 1.008 0,975 0.988 1.006

Ti 0.002 0.000 0.001 0.002 0.001 0.002 0.001 0,002

Sum 3.997 4.005 4.022 4.007 3.999 4.003 3.998 4.002

Fe 0.007 0.002 0.002 0.002 0,003 0.014 0.005 0.017

Mn 0.001 0.000 0.002 0.000 0.000 0.001 0.002 0.000

Mg 0.003 0.004 0.003 0.000 0.015 0.012 0.000 0,000

Ca 0.004 0.000 0.001 0.002 0.023 0.005 0.002 0.002

Ba ----- 0.011 0.010

Na 0.050 0.034 0.029 0.091 0.090 0,026 0,036 0.039

K 0.924 0.934 0.878 0,879 0,875 0.871 0,941 0,917

Sum 0.988 0.985 0.925 0,974 0.988 0.929 0.985 0.976

0 8.000 8.000 8.000 8.000 8,000 8.000 8.000 8.000

Note: Fe is total iron.

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44

plagioclase varies greatly from sample to sample (Fig.

13). There is no spatial relationship between the

maximum anorthite-content of plagioclase and the distance

from either the Parks Pond or the Lucerne Pluton. The

variation in maxi_mum anorthi te-content implies separate

melts and/or restitic calcic plagioclase. A single melt

would produce a single maximum anorthi te-content for

plagioclase, either as primary crystallization or as

restitic plagioclase. Concurrently, it could result from

variable contamination.

Dissimilarities between plagioclase from the

leucosomes and plagioclase from the Lucerne Pluton argue

against consanguinuity (Fig. 13). The argument does not

stem from the presence of more calcic plagioclase in the

leucosomes, since this could be restitic remnant

plagioclase. Rather, the relevant contrast is the

general lack of sodic plagioclase in the leucosomes.

Magmas derived from the Lucerne by differentiation and

intrusion or simple intrusion would not show this

characteristic. Similarly, if the Lucerne Pluton had

provided heat to melt the Bucksport Formation,

plagioclase in the leucosomes would be at least as sodic

as plagioclase in the Lucerne Pluton (Misch, 1968). In

marked contrast, consanguinui ty between the Parks Pond

Pluton and the leucosomes cannot be ruled out based on

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45

Figure 13. Compositions of plagioclase, in the

leucosomes, the Lucerne Pluton (Wanes, 1980), and the

Parks Pond Pluton (Eriksson, unpublished data).

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46

COMPOSITIONS OF PLAGIOCLASE

9A 27

25

34 23 8A

Leucosomes

32

.. 'i' I I

Parks Pond Pluton

1_ucerne Pluton

.. I' I I' '"I

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47

the compositions of plagioclase.

Biotite

Three distinct compositional clusters of biotite are

displayed in Figure 14: 1) Fe and Al-rich biotite from

the Lucerne Pluton 2) Bioti te from melanosomes and

leucosomes, with intermediate Fe/Fe+ Mg and octahedral

Al and 3) Fe- and Al-poor biotite from the Parks Pond

Pluton. The distinct clusters demonstrate that biotite

in the leucosomes has not been inherited directly from

either the Lucerne or the Parks Pond Pluton. Within the

melanosome-leucosome group, biotites from the melanosomes

show a greater range in octahedral Al, while those from

the leucosomes show a greater range in Fe/Fe+ Mg.

In the Bucksport Formation and the melanosomes, with

approach to either the Lucerne or the Parks Pond Pluton,

the Ti and Fe/Fe + Mg content of bioti te fluctuates

erratically. This is in conflict with expected trends of

increase in Ti and decrease in Fe/Fe+ Mg with increasing

grade (Hyndman, 1972), and suggests: 1) local

compositional control and/or 2) local control of

temperature. Local control of temperature could result

from different conductivity in different rocks, different

degrees and kinds of devolatization reactions in the

rocks, and/or a different distribution of the heat source

(Lucerne Pluton, Parks Pond Pluton, or leucosomes) at the

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48

Figure 14. Representative compositions of biotites in

leucosomes, melanosomes, Lucerne P luton (Wanes, 1980),

and Parks Pond Pluton (Eriksson, unpublished data)

(Table 5) .

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49

REPRESENTATIVE COMPOSITION._S" OF IJIOTITES 0.95

0.90

0.85

0.60

o. 7S Lucerne Pl uton

Ol o. 70 L + Q1 0.65 u..

.......... Q1 u.. 0.60

0.55

0.50

O.ll5

.J~ • • Leucosomes

~· D

fl~cfJ ~ 0 o oo m D d] [5l

Melanosomes O.!lO

0,35 • o. 30 Parks Pond Pluton

0,25 ......... ~...-.--..........., .......... ~...........,.----~ ......... ~--,-.,~--,,~~..--.~....,.._~~~ o.oo 0.06 0.12 0.18 o.2u 0.30 o.36 0.4? 0.46 o.54

Moles of Octahedral Al

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Tabk 5 SELECTED HICROPROBE ANALYSES A:<;D STRt;ClllRAJ. FOR~nll.AE OF 'oIOTITE

____ Buckseort_Formation ____ _______________ Melanosomes ________________ Leucosomes ------------------------------------------14 45 26 3A 23 23 25 9A

Si02 37.70 (2.84) 38.59 (0.86) 36.10 (0.11) 36.73 (0.70) 37.57 (0.81) 37. 72 (0. 60) 36.97 (1.04) 36.11 (0.71)

Ti02 1.70 (0.45) 1.47 (0.17) 3.97 (0.04) 2.94 (0.07) 2.86 (0.60) 3.60 (0.29) 4.17 (0.24) 4.02 (0.31)

Al 203 17.41 (1.46) 14.75 (0.23) 14.15 (0.09) 14.69 (0.11) 14.68 (0.95) 14.08 (0.92) 14.18 (0.21) 14.52 (0.66)

FeO 16.29 (l.ll) 12.03 (0.10) 19.02 (0.16) 19.25 (0.36) 18.80 (0. 72) 19.34 (0.30) 21.06 (1.05) 21.67 (0.54)

HnO 0.21 (0.04) 0.17 (O. 02) 0.24 (0.04) 0.30 (0.02) 0.27 (0.08) 0.27 (0.08) 0.38 (0.05) 0.54 (0.06)

HgO 12. 30 (0. 97) 16. 90 (0. 74) 10.58 (0.13) 12.15 (0.65) 12.24 (1.04) ll.97 (0.82) 9.46 (0.69) 9.47 (0.69)

Cao 0.21 (0.20) 0.11 (0.04) 0.05 (0.01) 0.07 (0.02) 0.14 (0. 20) 0.12 (0.06) 0.06 (0.04) 0.12 (0.06)

BaO ----- ----- ----- ----- 0.21 (0.01) 0.82 (0.03) ----- ----- ----- ----- 0.24 (0.07) 0.16 (0.00)

Na2o 0.27 (0.42) 0.07 (0.01) 0.03 (0.01) 0.11 (0.05) 0.07 (0.13) 0.09 (0.06) 0.05 (0.01) 0.19 (0.06)

K2o 8.98 (0.64) 8.74 (0.63) 9.17 (0.04) 9.16 (0.09) 9.52 (0.80) 9.59 (0.49) 9.43 (0.38) 9.16 (0.19)

F ----- ----- ----- ----- 0.50 (0.03) 0.28 (0.03) ----- ----- ----- ----- 0.80 (0.02) 0.44 (0.00)

Cl ----- ----- ----- ----- 0.28 (0.00) 0.31 (0.01) ----- ----- ----- ----- 0.16 (0.00) 0.04 (0.00)

Total 94.88 (1.40) 92.71 (0.97) 94.30 (0.20) 96.81 (0. 75) 96.15 (2.20) 96.78 (0.46) 96.96 (1.13) 96.44 (1.01) V1 0

N 12 4 2 4 26 8 6 9

SI 5.650 5. 796 5.588 5.577 5.666 5.671 5.650 5.561

Al 2.350 2.204 2.412 2.423 2.334 2.329 2.350 2.439

Sum 8.000 8.000 8.000 8.000 8.000 &.000 8.000 8.000

Al 0. 724 0.398 0.169 0.206 0.274 0.165 0.204 0.195

Ti 0.168 0.166 0.461 0.336 0. 325 0.407 0.480 0.466 Fe 2.042 l. 501 2.462 2,445 2.371 2.431 2.692 2.790 Hn 0.027 0.022 0.032 0.038 0.034 0.035 0.049 0.070 Hg 2.749 3.784 2.442 2.750 2.751 2.683 2.155 2.173 Sum 5.710 5.871 5.566 5. 776 5.755 5. 722 5.580 5.694 Ca 0.034 0.018 0.009 0.012 0.023 0.019 0.009 0.019 Na 0.080 0.020 0.011 0.032 0.021 0.027 0.015 0.055 K 1. 716 1. 6 74 1.811 l. 775 1. 830 1.839 1.839 1.799 Ba ----- ----- 0.013 0.049 ----- ----- 0.015 0.010 Sum l. 831 I. 712 l. 844 l. 868 l. 874 1.884 1. 878 1.884 Cl ----- ----- 0.073 0.080 ----- ----- 0.042 0.010 F ----- ----- 0.024 0.138 ----- ----- 0.389 0.213 () 22 .000 22.000 22.000 22.000 22.000 22.000 22.000 22.000

Note: Fe Js total iron. N is t1umber of analyses. The maximum range from the average is included in parcnthcscR.

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surface or at depth.

Ti in biotite from the Bucksport Formation ranges

from 0.10 to 0.47 moles (based on recalculation to 22

oxygens). In comparison, biotites from the leucosomes

tend to be richer in Ti, and the range in Ti content is

less (0.38-0.50 moles).

Five traverses across contacts between melanosomes

and leucosomes in sample #23 reveal that Ti in biotite is

low in distal melanosomes, roughly increases toward the

contact, and continues to rise in the leucosomes with

di stance from melanosomes (Fig. 15) . Changes in Ti-

contents do not correlate with vacancies, or single

changes in tetrahedral or octahedral cations in the

bioti tes. If exchange did occur,

coupled or multiple substitution.

it was through a

The coupled or

multiple substitution of Ti in biotite is very common

(Abrecht and Hewitt, personal communication). The data

do suggest that diffusion occurred across the interface

between two dissimilar bodies, and thus add to the

argument against the production of sample 23 through in

situ partial melting. If the gradient in Ti reflects a

gradient in temperature, the trend resulted from

intrusion of the leucosome.

Amphibole

Amphibole compositions from the leucosomes, the

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52

Figure 15. Bioti te compositions from traverses across

contacts between melanosomes and leucosomes in sample 23.

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Q) .µ •,-.µ 0 .,-

c:::::l

!:: ,,-

•,-I-4-0 (/) <l)

,--0 ~

53

TRAVERSE ACROSS CONTACT· BETWEEN MELANOSOME AND LEUCOSOME IN SAMPLE 23 0.22

tJ 0.21

0.20

o. 19 D

o. 18

0.16

o. 15

O. lij

0.13

o. 12 -1800:J

D

D D

D

D

Leucosome

D

D

Melanosome

-12000 -6000 0

Distance from Contact, in Microns 0 is Contact

12001)

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54

Bucksport Formation and the melanosomes overlap, ranging

from actinoli te to hornblende (Figs. 16 and 17). The

range is complete in the leucosomes, but falters at about

7. 2 moles of Si in the Bucksport-melanosome group.

( based on recalculation to 23 oxygens) . Leake ( 1968)

suggests a miscibility gap at 7.2 moles of Si between

actinolite and hornblende, and that it is more pronounced

at low temperatures. Amphiboles in the leucosomes may

have formed formed at higher temperatures than those in

the Bucksport-melanosome group.

With increase in grade, the first amphibole to

appear in the Bucksport Formation is a slightly aluminous

actinoli te ( see sample #13, Table 6). Further toward

either the Lucerne or the Parks Pond Plutons, Al and Na+

K tend to increase irregularly, until hornblende is

developed in sample #3A, a gneissic melanosome sampled 50

meters from the Parks Pond Pluton. Fe/Fe+ Mg variation

in amphiboles is erratic and does not correlate with

distance from the plutons.

Figure 16 shows that the compositions of primary

amphiboles (amphiboles that appear to have crystallized

from a melt) overlap with the compositions of amphiboles

from the inclusions. In individual samples the two

amphiboles are usually compositionally distinct: primary

amphiboles tend to be lower in Al and Na+ K.

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55

Figure 16. Compositions of amphiboles in leucosomes

(Table 6) .

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7.

7. 7

7.6

7.5

7.~

7. 3

7.2

V) 7. I

6 7.0

Vl 6.9 QJ

O 11.B :::E:

6.7

6.6

6.S

6.~

6.3

6.2

6.1

56

AMPHIBOLES IN LEUCOSOMES

0

• 0~

d'o

Primary 0

~-= . 0 oo~ • oo

0~ 0. o 1 ~o

.o ·~ ~- 0 • • Inclusions •

0

J.9S 2.01 2.07 2.n 2.19 2.25 2.31 2.37 2.~3 2.49 2.55 2.61 Ca+ Na+ K

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57

Table 6

SELECTED MICROPROBE ANALYSES AND STRUCTIJRAL FORMULAE OF AMPHIBOLE

___ Buckseort_Formation~--- --------~elanosomes ________ __Leucosome __ _Inclusion __

13 44 33A 3A 8Aa 8Aa BA

5102 52.91 (0.70) 50.88 (2.04) 49.41 (l. 85) 43.59 (0.81) 46.89 54.06 :.a.22 (5.10)

T102 0.26 (0.10) 0.25 (0.22) 0.64 (0.59) l. 83 (0. 21) 1.05 0.18 0.93 (0.25)

Al 2o3 4.02 (0.85) 3.93 ( l. 89) 5.32 (2.69) 9.51 (0.43) 7.17 l. 64 6.67 (4. 39)

FeO 14.22 (0. 27) 17.55 (2. 04) 15.40 (0.58) 16.91 (0.89) 15.80 13.45 .15.42 (0. 90)

~o 0.33 (0.06) 0.47 (0.13) 0.36 (0.02) 0.41 (0.05) 0.48 0.56 0.56 (0.08)

MgO 13.19 (0.56) 11.09 ( l. 25) 13.27 (1.21) 10.53 (0.76) 12.22 15.09 12.13 (0.41)

Cao 12.09 (0.35) 12.72 (0.17) 12.21 (0.23) ll. 52 (0.26) 12.00 12. 77 12.09 (0. 4 7)

BaO 0.04 (0.01) 0.10 (0.02)

Na2o 0.34 (0.09) 0.30 (0.20) o. 71 (0.55) 1.18 (0.16) l. 21 0.25 0.95 (0.30)

K2o 0.33 (0.13) 0.26 (0.28) 0.48 (0.42) 1.19 (0.12) o. 72 0.12 0.61 (0.17)

F 0.08 (0.00) 0.12 (0.04)

Cl o.oo (0.00) 0.32 (0.08)

Total 97.81 (l. 04) 97.46 (l.87) 97.81 (0.35) 97.21 (1.53) 97.54 98.12 97.58 ( 1. 54)

N 3 5 3 6 1 11

Si 7.666 7.560 7.273 6.617 6.987 7.795 7.139

Al 0.334 0.440 o. 727 l.383 1.013 0.205 0.861

Sum 8.000 8.000 8.000 8.000 8.000 8.000 8.000

Al o. 353 0.249 0.196 0.318 o. 246 0.074 0.302

Ti 0.028 0.027 0.071 0.209 0.118 0.020 0.104

Fe 1.723 2.181 l.896 2.147 1. 969 1. 622 1.909

Mn 0.041 0.059 0.045 0.052 0.061 0.068 0.071

Mg 2.848 2.456 2.912 2.382 2. 714 3.243 2.677

Sum 4.993 4. 973 5.121 5.108 5.107 5.027 5.063

Ca l. 876 2.025 1. 926 l. 873 1. 916 1. 973 l. 918

Na 0.096 0.088 0.203 0.346 0.350 0.070 o. 272

K 0.061 0.049 0.091 0.230 0.137 0.022 0.115

Ba 0.002 0.006

Sum 2.036 2.162 2.219 2.453 2.402 2.065 2.305

Cl 0.000 0.091

F 0.037 0.058

0 23.CJOO 23.000 23.000 23.000 23,000 23.000 23.000 a These analyses are from the same crystal. ~ote: Fe is total iron. N ls number of analyses. The maximum range from the average is

included ln parentheses.

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58

Figure 17. Compositions of amphiboles in the Bucksport

Formation and melanosomes.

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59

AMPHIBOLES FROM MELANOSOMES AND THE BUCKSPORT FM a.a

7.9

7.8

7.7

7.6

7.5

•.,- '· ~ (/)

4- 7. 3 0

l/l 7. 2

a., ,-- 7.1 0

:::E 7.0

6. 9

6.8

6.7

6.6

6.5 1.86

0 0 0%_

oo ~o 0 •t 0 000 ~

Bucksport Fm O ~ • 0

0 ·~ • • • •

• •

Melanosomes

••• -: .. • • • •• 1.s2 1.9B 2.oq 2.10 2.16 2.22 2.28 2.3~ 2.qo 2.q6 2.s2

Ca+ Na+ K

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60

In contrast, the Fe/Fe+ Mg ratios for coexisting

primary amphiboles and amphiboles from inclusions are

usually identical. Wones (1980) suggests that biotite

would preserve its Al- and Si-contents but exchange Fe

and Mg with the melt. The data here for amphiboles

suggests the same process. Distinct metamorphic textures

in the inclusions argue against the idea that inclusions

are glomerocrysts. The inclusions may be xenoliths that

equilibrated with the melt with respect to Fe and Mg, or

they may be restite. The latter could be explained by

incongruent partial melting or no melting of the

amphibole in the inclusions.

The Fe/Mg ratios of amphiboles in sample #34 are not

identical. They are O. 69-0. 82 for primary amphiboles,

0.89-0.97 for amphiboles in the inclusions, and 0.55-0.93

for amphiboles in the adjacent melanosome #33. These

differences indicate that 1) inclusions have not

equilibrated with the leucosome 2) the inclusions are not

glomerocrysts 3) the inclusions are not xenoliths from

sample #33. The fact that amphiboles in inclusions have

higher Fe/Mg ratios than do primary amphiboles suggests

that the two groups of amphiboles are not related by

congruent melting. The inclusions may still represent

restite if melting was incongruent or if the amphiboles

within the inclusions were not involved in melting

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61

reactions.

Pyroxene

The compositions of amphiboles within individual

samples vary widely; in contrast, pyroxenes are fairly

homogenous. Pyroxenes from the Bucksport Formation and

the center of an inclusion in leucosome #17 are salites,

while clinopyroxenes from the Parks Pond Pluton are

salites to augites (Fig. 18). The subcalcic pyroxenes in

the Parks Pond Pluton are typical for those formed at

high temperatures. They coexist with hypersthene, and at

high temperatures the miscibility gap between

orthopyroxene and clinopyroxene narrows (Deer et al.,

1980). Salite from the inclusion plots very closely to

the group of pyroxenes from the melanosomes and the

Bucksport Formation, but far from the Parks Pond Pluton

group. Thus, if clinopyroxene from the inclusion was

inherited, it may have come from the Bucksport Formation

or the melanosomes, but probably not from the Parks Pond

Pluton. Fe/Mg ratios in clinopyroxene from the Bucksport

Formation and the melanosomes tend to decrease from low

to high grade.

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62

Figure 18. Compositions of pyroxenes in the Parks Pond

Pluton (Eriksson, unpublished data), the Bucksport

Formation, melanosomes, and an inclusion (Table 7).

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DI

EN

63

PYROXENES

Inclusion • >sc ~~

{. Bucksport Parks Fm Pond

Pluton

FS

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64

Table 7 HICROPROBE ANALYSES AND STRUCTURAL FORMULAE OF CLINOPYROXENE

Helanosomes Bucksport Fm In.clusion ---------------------------- 44 ---- ------------3A2 3A 26 17A

Si0 2 52.41 (0.61) 51.90 (0.22) 51.55 (0.39) 52.15 (0.59) 51.44 (0.23) Ti0 2 0.15 (0.05) 0.15 (0.01) 0.08 (0.04) 0.10 (0.05) 0.09 (0.01)

A1203 0.65 (0.15) 0.64 (0.02) 0.48 (0.17) 0.55 (0.37) 0.29 (0.18) FeO 9.94 (0.86) 9.81 (0.66) 11.54 (0. 4 7) 12.47 (0.73) 9.14 (0.27) HnO 0.68 (0.05) 0.59 (0.05) 0.57 (0.06) 0.60 (0.10) 1.24 (0.08) HgO 12.82 (0.29) 12.96 (0.19) 11.29 (0.15) 10.10 (1. 44) 12.77 (0.05) eao 23.09 (0.64) 23.20 (0.31) 22.64 (0.98) 23.41 (0.80) 24.29 (0. 36)

Na20 0.24 (0.01) 0.23 (0.05) 0.18 (0.03) 0.13 (O. 07) 0.09 (0.02) K2o 0.01 (0.01) 0.02 (0.01) 0.04 (0.18) 0.03 (0.02) 0.01 (0.01) Total 100.00 (0.59) 99.53 (0.07) 98.43 (0.56) 99.54 (1. 36) 99.36 (0.08)

N 4 2 9 10 2 Si 1. 975 1.967 1.989 1.998 1.962

Al 0.025 0.029 0.011 0.002 0.013

Sum 2.000 1.996 2.000 2.000 1. 975 Al 0.005 0.000 0.011 0.023 0.000

Ti 0.004 0.004 0.002 0.003 0.002 Fe 0.313 0.311 0.372 0.400 0.292

Mn 0.022 0.019 0.019 0.020 0.040 Hg o. 720 0.732 0.649 0.576 0.726

Sum 1.064 1.067 1.053 1.021 1.060 Ca 0.933 0.942 0.936 0.961 0.993 Na 0.017 0.017 0.014 0.010 0.007

K 0.001 0.001 0.002 0.001 0.000 Sum 0.950 0.961 0.952 0.971 1.000 0 6.000 6.000 6.000 6.000 6.000

Note: Fe is total iron. N is number of analyses. The maximum range from the average is included in parentheses.

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BULK CHEMISTRY

Most leucosomes are roughly similar in bulk

chemistry (Table 8). The exception is sample #34, which

is low in Si, Al, and K, but high in Na and the typically

refractory elements Ti, Fe, Mg, and Ca.

White and Chappell (1977) depend strongly on alumina

saturation to differentiate between I- and S-type

granites. They contend that 1) magmas inherit the

characteristics of their source 2) the sedimentary source

for S-types is mostly shale, from which Ca and Na have

been partially removed during weathering and 3) granites

with Al203/K20 + Na20 +Cao< 1.1 are probably I-type.

Many mineralogical criteria that Chappell and White use

to distinguish between I- and S-types, though empirical,

probably result from relatively low activities of Na20

and Cao in s-type magmas and higher activities in !-

types. However, if the source were a Ca-rich sediment,

such as the predominantly calcareous Bucksport Formation,

Cao would be concentrated in the magma; thus an S-type

magma could display I-type characteristics.

The leucosomes in this study display the following

I-type characteristics

1) Al203/K20 + Na20 + CaO < 1.1

2) Hornblende-bearing inclusions

3) Primary titanite, allanite and hornblende

65

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Table 8 ANALYSES OF MAJOR ELEMENTS

Leucosomes Melanosomes Bucksport Fonnation

---------------------------------------------------------------------------- ---------------------BA 9A 27 23 34 33 22A 46C 3A 26A 37A 47C l 3C

Si02 65.90 68.86 61.49 67.68 54.48 71.27 62. 72 68.32 69.85 71 . 01 54.31 70.91 70.23 Ti02 0.61 0.37 0.72 0.53 2.22 0.67 0.80 · 0.40 0.73 0.67 0.92 0.63 0.60 Al203 14.61 15. 31 18.03 14.82 13.55 10.70 16.00 14.31 11.69 10.80 19 .44 11.65 l 0.35 CJ'

CJ'

Fe203 3.66 2. 17 4.28 3.08 12. 15 3.81 5.63 2.47 3.81 4.06 8.03 3.68 3.42 MnO 0.10 0.07 0. 11 0.06 0. 17 0.08 0.08 0.08 0. 12 0.08 0.07 0.08 0.09 MgO 2.53 1.20 2. 19 2.34 3.29 2.82 3.77 l.94 2.61 3.13 5.42 2.70 2.38 CaO 3.28 2.40 4.29 2.64 6.95 5.63 2.91 2.21 6.23 5.24 0.68 5.60 4.38 Na20 2.64 2.82 2.74 2.82 3.23 1.45 2.83 2.32 2.20 l.99 l. 36 1.36 1.06 K20 4.99 4.95 4.28 4.06 l. 70 l.87 3. 17 6.11 0.96 1.51 3.67 2.84 5.48 P205 0.30 0. 15 0.33 0.21 0.37 0. 19 0 .17 0.18 0.23 0.19 0.16 0.19 0. 16 Loss 0.55 0.79 0.69 0.85 l.82 0.60 1.12 1.08 1.10 0.81 5.06 0.82 1.09

Total 99. 17 99.09 99. 15 99.09 99.92 99.09 99. 19 99.41 99.55 99.49 99.13 100.46 99.23

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67

4) Apatite occurring mostly as inclusions in biotite and

hornblende. Concurrently, they possess the S-type

characteristics of primary tourmaline and red-brown

biotite.

The hypothesis that the Bucksport melted to produce

the leucosomes was tested using Wright and Doherty' s

( 1970) mixing program. The following two assumptions

were made. 1) Arnphibole, biotite, and clinopyroxene from

the inclusions are resti tic phases. Arnphibole and

biotite are the predominant constituents of inclusions;

clinopyroxene occurs in the cores of some inclusions.

Compositions of these II resti tic" phases were not taken

from the inclusions themselves, because of textural

evidence that inclusions have reacted with their

surroundings. Instead, the average compositions of

amphibole, bioti te, and clinopyroxene from sample #3A

were used. Sample #3A is a fine-grained gneiss from the

Bucksport Formation that was sampled 50 meters from the

Parks Pond Pluton. 2) Melanosomes are unaltered

Bucksport. Assumption 2 was made because melanosomes do

not resemble mafic selvages, and are neither texturally

nor chemically distinguishable from other members of the

Bucksport Formation (Table 8).

The program uses least-squares analysis to solve the

equation aA + bB ... - nN - oO = Z. In the equation, a, b,

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68

n, and o are coefficients. For the problem presented

here, A and Bare the bulk chemistry of samples of the

Bucksport Formation (melanosomes are included in this

category), N and Oare microprobe analyses of biotite,

amphibole, and/or clinopyroxene, and Z is the calculated

bulk chemistry of a leucosome. The optimal solution is

some combination of factors from the left side of the

equation that will come closest to the actual bulk

chemistry of the leucosome.

100% for comparison.

Input was recalculated to

Table 9 shows the results for leucosome #23. The

"SOLUTION" row of 38.97% (Sample #47) + 74.73% (Sample

#22) - 13.69% (Amphibole) = the "CALC. 11 column of oxides.

The "DIFF. 11 column= the actual analysis of 23 minus the

calculated analysis. The "SENSITIV" row gives a standard

+/- error. Results for other leucosomes are displayed in

Figures 19 and 20.

While the solution for the anomalous sample #34 is

poor, it is fairly good for the other samples. Except

for #34, all solutions require a major contribution by a

low-Ca rock (sample #22, 46, or 37) diluted by one or

more high-Ca rocks (sample #47, 26, 13, and/or 3A). This

is consistent with results from melting experiments

(Winkler, 1965; Mehnert 1971). Calcareous metasediments

are more refractory than noncalcareous ones. As Winkler

Page 74: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

TABLE 9 Output for Sample #23

37 47 13 46 22 3A . 33 26 AMPH CPX BT 23 CALC . DIFF.

Si02 57.74 71.17 71. 56 69.48 63.95 70.97 72. 37 71. 96 46.26 52.17 38.51 68.90 69.19 -0.29 AI2o3 20.67 11. 70 10.55 14.56 16.32 11.88 10.87 10.95 9.07 0.65 15.40 15.09 5.51 -0.41

Fe203 8. 54 3.70 3.49 2.52 5.75 3.88 3.87 4.12 17.10 9.86 20.18 3.14 3.39 -0.25 HgO 5. 77 2. 71 2.43 1. 98 3.85 2.66 2.87 3.18 11.15 13.03 12. 74 2.39 2.41 -0.01

0\ CaO 0. 73 5.63 4.47 2.25 2.97 6.33 5. 72 5.32 11.85 23.32 0.08 2.69 2.79 -0.09 \()

Na2o 1. 45 1. 37 1.08 2. 36 2.89 2.24 1. 48 2.02 1.15 0.24 0.12 2.88 2.54 0.34

K20 3.91 2.86 5.59 6.22 3.24 0.98 1.90 1. 54 1.09 0.03 9.61 4.14 3.38 0.76 Ti0 2 0.98 0.64 0.62 0.41 0.82 0.75 0.69 0.68 1. 91 0.16 3.09 0.54 0.60 -0.05

P205 0.18 0.20 0.17 0.19 0.18 0.24 0.20 0.20 0.00 o.oo 0.00 0.22 0.21 0.01 MnO 0.08 0.09 0.10 0.09 0.09 0.13 0.09 0.09 0.46 0.60 0.32 0.07 0.04 0.04 SOWTION 0 38.97 0 0 74. 73 0 0 0 -13.69 0 0

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70

Figure 19. Schematic diagrams of subtraction of restite

from the Bucksport Formation to form calculated

leucosomes 8A and 9A.

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Bl

I 10-._,_ I 0 5-(\J ~

0 0

(\J 2 '-0 z en O'--a Q) 0 20 '-

"O 0 10'-x u 0 0.___11 ~o 10- -0 c,, -~ - 0 ~ "' 20

0

; 1:t

c:51 20L N 10

<( 0

35 40 45

22 SA 13 CPX 46 47

I 11 I I 19A 126 I I I I I I I I I 1 T I

"--~ " _,_ .J.p --- " " • ====== " -·J •

~~~A-0 •• "

.. --.') " " " - -'•.:> -- ----- .. --e) " -------. __ .) -t • • " "--•) -L "

50 55 60 65 70 75 - 55

wt. 0/o Si02

• RESTITE

.i BUCKSPORT FORMATION

e ACTUAL LEUCOSOME

0 CALCULATED LEUCOSOME

-- DIRECTION OF SUBTRACTION

....... J .. "

....... :)_ .. " ____.... ... .)" "

60 65 70

wt.% Si02

-I -...j ......

75

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72

Figure 20. Schematic diagrams of subtraction of restite

from the Bucksport Formation to form calculated

leucosomes 34 and 27.

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34 46 34 26 Bl 27 27 3A

0 N ~

l l I l I l l 10~ I e I I • I O • -[SCI .~QI I: j 0 •

2

11i3

5 ._ -

0 N

0 z ~ OF-----------------~_:_ __ _ a, O 20 e "0 O I-- • -o • " 0 "

-1-

·- u ,o~ • ~ I --1-

lgi=----------------- .~ • I • ~o ~ I 0

~ OI 0 ~

-1-·

" ~o -

.\ -3 01 . '° • r0 20 --0 -~ 10 e . ~~

2g~ • 0 • -r •~o ~ j

--

_._ " -•-o • " 0 " 0

N IOt- • <t

050 I I I

55 60 65

wt.% Si02

_._ I I

70 75 40

• RESTITE

A BUCKSPORT FORMATION

e ACTUAL LEUCOSOME

0 CALCULATED LEUCOSOME

-- DIRECTION OF SUBTRACTION

lil -I I l I l I

45 50 55 60 65 70 75

wt.% Si02

-..J w

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74

(1965) has suggested, given a layered sequence of rocks

with variable compositions (such as the Bucksport

Formation and the melanosomes), one would expect anatexis

to be selective.

Except for sample #34, one or more 'restitic' phases

are subtracted to produce the leucosomes. This would

occur if some restite were left behind as the magma left

its place of origin. In the excellent solution for

sample #23, amphibole is subtracted from sample #47 plus

sample #22. #23 actually crops out within #22, but the

solution requires the removal of amphibole. Melanosome

#22 does not contain amphibole. If the solution is

correct, in situ melting did not produce sample #23.

This agrees with the mineralogical evidence that sample

#23 did not result from in situ melting.

Since the Bucksport Formation and the melanosomes

are heterogeneous, it is likely that thA eight samples

used here as. input do not entirely represent the

variation in composition of these units. Sample #34 may

have been derived from a member of the Bucksport

Formation with an anomalous composition, such as a layer

rich in calcite, chlori te and ilmenite, but poor in

silica. That could account for the anomalous composition

of sample #34, which is high in Ca, Mg, Fe and Ti, and

low in Si.

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TEMPERATURES AND PRESSURES

Amphibole-Plagioclase Geothermometry

While the migmati te and the Bucksport Formation

generally lack assemblages for conventional

geothermometry, they frequently contain plagioclase and

amphibole. Perchuk (1966) and Spear (1981) have studied

the exchange of Na for Ca between plagioclase and

amphibole, for the purpose of determining temperature.

Spear's approach is purely empirical, while Perchuk

employs both empiricism and thermodynamic calculations to

estimate temperatures.

Estimations of temperatures based on their

geothermometers are listed in Table 10. Microprobe

analyses of the phases used to obtain these temperatures

are given in Tables 11 and 12. These are spot (focussed

beam) analyses of points on amphibole and plagioclase

grains a few microns apart. When available, temperatures

from Perchuk' s and Spear's work are similar, but

temperatures derived from Spear's work tend to be lower.

Temperatures derived from coexisting amphibole and

plagioclase from a single thin section vary up to 30° C.

Within a single lithologic sample (#3A, 3A2), they vary 0 up to 50 C. In Table 10, the slight decrease in

temperature from sample #3A to sample #47 represents a

traverse across the migmatite and the Bucksport

75

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26

3A2

3A

46

44

47

34

25

8A

76

Table 10

TEMPERATURES FROM AMPHIBOLE-PLAGIOCLASE GEOTHERMOMETRY

Perchuk

Melanosomes

605 630

585

Bucksport Formation

Leucosomes

410

Inclusion

440

Spear

490°c

530 560

525 510

510

500

490 495 490

490

--- outside of plotted temperatures

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Table 11

MICROPROBE ANALYSES OF AMPHIBOLE USED IN AMPHIBOLE-PLAGIOCLASE GEOTilERMOMETRY

26 3A2a 3A2b 3Aa 3Ab 46 44 47a 47b 4 7c 34 25 BA

Si0 2 51. 34 43.38 42.03 47. 45 44.79 49.02 49.03 52.63 49.96 52.43 52.85 46.28 44.48

Ti0 2 0.03 1.66 1. 99 0.56 1.17 3.01 0.22 0.35 0.24 0.44 0.36 1.02 1.07

A12o3 2.66 9.39 9.46 6.76 8.92 4.44 4.96 2.49 5.60 3.27 3.28 6.80 11.06

FeO 14.46 16.70 17.58 15.66 16.61 13.39 19.59 13.49 13.42 13.55 14.56 18.61 15.21

MnO 0.38 0.54 0.48 0.48 0.56 0.30 0.40 0.43 0.30 0.38 0.63 o. 70 0.51

MgO 13.28 10.27 12.22 12.22 10. 77 13.02 9.53 14.25 13.17 13. 77 14.54 10.42 11.01

CaO 12.50 11.66 12.36 12.36 11. 70 14.18 12.51 12.04 11.90 12.11 12.00 11. 35 11.48

Na2o 0.26 0.95 0.63 0.63 0.88 0.40 0.37 . o. 23 0.39 0.30 0.55 0.91 1.14

K20 0.14 1.08 0.61 0.61 1.02 0.29 0.31 0.19 0.25 0.24 0.24 0.66 0.74 -..J

Total 95.05 95.63 95.19 96.73 97.02 98.05 96.92 96.10 95.23 96.49 99.01 96. 75 96.70 -..J

Si 7.699 6.665 6.546 7.103 6.756 7.179 7.417 7.744 7.434 7.686 7.599 7.037 6.662

Al 0.301 1. 335 1.454 0.897 1.244 0.766 0.583 0.256 0.566 0.314 0.401 0.963 1. 338

Sum 8.000 8.000 8.000 8.000 8.000 7.946 8.000 8.000 8.000 8.000 8.000 8.000 l!.000

Al 0.169 0.365 0.282 0.295 0.342 0.000 0.301 0.175 0.416 0.251 0.155 0.255 0.614

Ti 0.003 0.192 0.233 0.063 0.201 0.332 0.025 0.039 0.027 0.049 0.039 0.117 0.121

Fe 1. 813 2.146 2.290 1.960 2.095 1. 640 2.478 1.660 1.670 1. 661 1. 751 2.366 1.905

Mn 0.048 0.070 0.063 0.061 o. 072 0.037 0.051 0,054 0.038 0,047 0.077 0.090 0.065

Mg 2.968 2.352 2.270 2. 726 2.422 2,842 2.149 3.125 2.921 3.009 3.116 2.361 2.458

Sum 5.003 5.125 5.138 5.106 5.131 4.851 5.004 5.053 5.071 5.016 5.137 5.190 5.162

Ca 2.008 1. 919 1. 926 1. 982 1.891 2.225 2,028 1.898 1. 897 1.902 1.849 1.849 1.842

Na 0.076 0.283 0.335 0.183 0.257 0,114 0.109 0.066 0.113 0.085 0.153 0.268 0.331

K 0.027 0.212 0.242 0.116 0.196 0.054 0.060 0.036 0.047 0.045 0.044 0.128 0.141

Sum 2.111 2.414 2.503 2.282 2.345 2.393 2.196 1.999 2.057 2.032 2.046 2.245 2.315

0 23.000 23.000 23.000 23.000 2).000 23,000 23.000 23.000 23.000 23.000 23.000 23.000 23.000

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Tabk 12 MICROPROBE ANALYSES OF PLAGIOCI.ASE USED l N AMPIIIBOI.E-PLAGIOCI.ASE GEOTHERMOMETRY

26 3A2a 1A2b 3Aa )Ab 46 44 47a 4 7b 47c 34 25 8A Si02 56.19 55.83 5 6.50 56.68 57.04 5 7. 83 59.75 52.49 51.92 52.97 62.28 64.86 65.25

Ti0 2 0.00 0.05 0.05 0.04 0.04 0.02 0.03 0.05 0.04 0.02 0.02 0.04 0.02 Al2o3 26.84 27. 21 27.03 26.01 26.85 25.83 25.80 30.09 30.43 27.98 24.14 21. 32 23.49 FeO 0.15 0.06 0.44 o. 28 0.20 0.22 0.23 0.31 0.15 0.52 0.09 0.41 0.38 MnO 0.00 0.02 0.01 0.01 0.04 0.00 0.01 0.02 0.00 0;03 0.03 0.02 0.04 MgO 0.00 o. 17 0.12 0.03 0.08 0.19 0.00 0.04 0.00 0.58 0.08 0.03 0.00 Cao 8.53 9.67 9. 33 8.56 9.09 9.03 7.87 12.54 12.46 12.38 5.74 2.54 0.51

Na20 6.83 5.87 5.84 6.89 6.17 6.61 7.07 4.00 4.09 4.01 8.18 10.43 10.63 K2o 0.18 0. 20 0.19 0.24 0.25 o. 26 0.19 0.11 0.18 0.06 0.29 0.17 0.07 ...... Total 98. 72 99.08 99.51 98.74 99.76 99.99 100.95 99.65 99.27 98.55 100.85 99.82 100.39

00

Si 2.556 2. 533 2.551 2.581 2.566 2.598 2.644 2.386 2.370 2.436 2.741 2.870 2.848 Al 1. 439 1. 455 1. 438 1.396 1. 423 1. 367 1. 345 1.612 1. 637 1. 516 1. 252 1.111 1. 208 Ti 0.000 0.002 0.002 0.001 0.001 0.001 0.001 0.002 0.001 0.001 0.001 0.001 0.001 Sum 3.995 3.989 3.990 3.978 3.991 3. 966 3.991 4,000 4.008 3.953 3.994 3.982 4.056 Fe 0.006 0.002 0.017 0.011 0.008 0.008 0.009 0.012 0.006 0.020 0.003 0.015 0.014 Mn 0.000 0.001 0.000 0.000 0.002 0.000 0.000 0.001 0.000 0.001 0.001 0.001 0.001 Mg 0.000 0.011 0.008 0.002 0.005 0.013 0.000 0.003 0.000 0.040 0.005 0.002 0.000 Ca 0.416 0.470 0.451 0.418 0.438 0.435 0.373 0.611 0.609 0.610 0.271 0.120 0.024 Na 0.602 0.516 o. 511 0,608 0.538 0.576 0.607 0.353 0.362 0.358 0.698 0.895 0.899 K 0.010 0.012 0. Oll 0.014 0.014 0.015 0.011 0.006 0.010 0.004 0.016 0.010 0.004 Sum 1. 034 1. 012 0.998 1. 053 1,005 1. 046 0.999 0.985 0.988 1.032 0.995 1.043 0.943 0 8.000 8.000 8.000 8.000 8.(1(,() 8.000 8.000 8.000 8.000 8,000 8.000 8.000 8.000

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79

Formation, going away from the Parks Pond Pluton.

The temperatures are much lower than anticipated.

Sample #3A, which was collected 50 meters from the Parks

Pond Pluton, yields temperatures 0 of only 510-630 C.

Sample #26, from the contact with the Lucerne Pluton,

gives only 490° C. From the work of Novak (1979) and

Jaeger ( 1959), it is estimated that the Parks Pond 0 contact was a minimum of 690 C, and the Lucerne contact

was a minimum of 580° C (see section on contact

temperatures). In this case, amphibole-plagioclase

geothermometry appears to be unreliable. The composition

of amphiboles is controlled by complicated, multivariate

exchanges that are not well understood.

Two-Feldspar Geothermometry

Alkali feldspars in the leucosomes are commonly

perthi tic and large enough to identify with the naked

eye. Some of these were extracted, crushed, and

pelletized. Annealing occurred after the pellets were 0 heated to 1000 C for 5 days, at atmospheric pressure.

XRD patterns obtained using an internal standard of CaF2

were then used to determine unit cell dimensions and

volume. Wright and Stewart (1968) have correlated these

quantities with structure and composition. The analyzed

alkali feldspars are maximum rnicroclines with high

orthoclase-contents.

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80

Stormer (1975) has empirically determined an alkali

feldspar-plagioclase geothermometer. It is slightly

sensitive to pressure; the pressure here is assumed to be

equal to one kilobar (see section on contact

temperatures) . Coexisting alkali feldspar and

plagioclase compositions are plotted in Figure 21.

The 450° C temperature for sample #25 is 40° higher

than the amphibole-plagioclase temperature for sample

#25. The 500° C temperature for sample #9A, which was

collected 90 meters from the Parks Pond Pluton, is

slightly lower than the 510-630 estimate for sample #3A,

which was collected 50 meters from the contact. The

calculated temperatures of 450 and 500° C for the

igneous-appearing leucosomes are lower than expected, and

probably represent subsolidus reequilibration. Alkali

feldspars tend to reequi librate at lower temperatures,

and these rocks probably underwent redistribution of Na.

Contact Temperatures

The migmatite occupies the contact aureole of the

Parks Pond Pluton, and portions of the contact aureole of

the Lucerne Pluton. The latter crystallized at 725° C

and 1-2 kb (Wones, 1980). The lowest curve in Figure 22

shows estimated temperatures in the contact aureole of

the Lucerne, assuming P H20 < Pf = Pt = 2kb (Novak,

1979). The reactions involving corundum and calcite took

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81

Figure 21. Mole fraction of albite in plagioclase plotted

against albite content of coexisting alkali feldspar.

Isotherms for coexisting sanidine and plagioclase at 1

kbar are from Stormer (1975).

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82

1.0--....-----~--,----,----~oooc soooc 600°C

0.8

Q) (J)

0 u 0.6 0 Cl 0 -0... C ·-Q) 0.4 --

£)

<{

f). Sample #25 0.2 0 Sample #9A

0 Sample #27

0.0----------------i.--..__-......_ _ _. 0.0 0.2 0.4 0.6

Al bite in Alkali Feldspar

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83

Figure 22. Novak's (1979) estimations of temperatures in

the contact aureole of the Lucerne Pluton.

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650

- ·r MUSC = CORUNDUM t K FELDSPAR (.) 0 - 600 w a::: ~ 5501 "J. ~ Tc = 625 /8 km tlu'ck <l:

MUSC1 ~ I 00 a::: ~ w + Q = ANO Ti = 625 /0 km 1/Jick a.. 500 + KFELOSPAR :E 1 w

~ LUCERNE MUStCC+Q, 450

400 ---~__...__.~__.~~---~~___,_~~---~~--~~---~~---~~--0 1000 2000 3000 4000

DISTANCE FROM CONTACT (FEET)

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85

place in the Bucksport Formation. Note that the country

rocks are estimated to have been at a maximum temperature 0 of 450 C. Since 1980, Wones (personal communication)

has more precisely delineated a pressure of 1 kb. This

would slightly depress the curves in Figure 22. Thus,

estimates of temperatures at the contact (Tc) and ambient

temperature of the country rocks (Ta) would be lowered.

In fact, Tc is lowered by 45° C (Evans, 1965).

probably 400-425° C.

Ta is

Jaeger (1959) assumes cooling totally by conduction,

no pore water vaporization, and negligible loss of heat

by devolatization in calculating the increase in

temperature experienced by country rocks directly

adjacent to an intrusion. The smallest increase

calculated by Jaeger (1959), based on the conductivities

of rocks, occurs at a gabbro-guartzite contact. Adjacent

to the Lucerne, the minimum calculated Tc for the

Bucksport Formation is 688-713° C (Table 13). This is

108-123° C higher than a 580° C estimate for the

corundum-producing reaction at 1 kb. This type of

discrepancy is mentioned by Novak and attributed to loss

of heat during devolatization reactions in the Bucksport

Formation.

Ta 0 of only 400 C at 3 km ( 1

geothermal gradient of 133° C/km.

kb) implies a

This may seem

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Ambient temperature

Increase in T due to conductive cooling of the pluton

Temperature at the contact

Minus 'devolatilization factor'

86

Table 13

CONTACT TEMPERATURES (based on Jaeger, 1959)

At the Bucksport/ Lucerne contact

400-425 °C

288 °C

688-713 oc

108-133 oc 580 °C

At the Bucksport/ Parks Pond contact

400-425 °C

398 °C

798-823 oc

108-133 oc 690 °C

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87

abnormally high. However, during Siluro-Devonian times

this area of Maine was intruded by several sequences of

plutons. Metamorphism here has been described as the low

pressure type. Miyashiro ( 1973) sketches a typical

geothermal gradient, for his low pressure baric type, of

100° C/km. Mehnert (1971) cites other examples of high

geothermal gradients: "Engel & Engel ( 1958) found 100°

C/km in the northwestern Adirondacks; Johnson ( 1963)

found values between 50 and 150° C /km in the Scottish

highlands, and Zwart (1962) as much as 150-180° C/km in

the central Pyrenees during the main metamorphic

evolution." Additionally, in modern, geothermal areas

the geothermal gradient is typically greater than 180°

C/km (Ellis and Mahon, 1977). Thus, a geothermal

gradient of 133° C/km for the study area is not

considered unreasonable.

The Parks Pond Pluton crystallized at> 1000° C and

an unresolved pressure (Eriksson and Wones, 1983). The

Parks Pond is older than the Lucerne, but probably not by

much. This is suggested by preliminary age dating and a

possible genetic relationship ( through heat transfer)

between the Parks Pond and Lucerne Pluton (Wones,

personal communication). Therefore, pressures are

estimated at 1 kb for the time of the Parks Pond's

intrusion.

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88

Tc at the Bucksport/Parks Pond contact is calculated

to have been 798-823° C (Table 13). However, Tc may have

been lowered by the same 'devolati lization factor'

believed to have been operative at the Lucerne/Buckport

contact. This would make Tc at the Bucksport/Parks Pond

contact 690° C. This is still higher than estimated

temperatures from two feldspar and amphibole-plagioclase

geothermometry, at 500° C and 510-630° C, respectively.

Melting Temperatures for the Bucksport Formation

Results from several melting experiments are given

in Table 14. There are three kinds of rocks listed:

granites, felsic or peli tic sedimentary rocks, and

calcareous sedimentary rocks. Three important inferences

have been made, based on this type of information

(Mehnert, 1971). 1) Calcareous sedimentary rocks begin

to melt at higher temperatures than do noncalcareous

rocks. 2) Typically, the compositions of sedimentary

rocks ar.e displaced from eutectic, granitic compositions.

3) The displacement is reflected in large melting ranges.

The Bucksport Formation is comparable in composition

to greywackes or clays+ calcite-bearing clays (Wones,

1974). The probability of melting the Bucksport

Formation is directly proportion to depth. At pressures

lower than the experimental 2 kb, assuming Pf = Pt,

eutectic temperatures are elevated. If the melting

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Table 14

MELTING TEMPERATURES pf= pt= 2kb

Westerly granite

eutectic

100% melting

Clays

eutectic

Greywackes

eutectic

70-95% melting

Calcite-bearing clays

eutectic

Calcite-bearing illitic clays

eutectic

40-50% melting

80% melting

(Mehnert, 1971)

695 °C

700 °C

680 °C

685 °C

780 °C

740 °C

700-720 °C

730 °C

810 °C

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90

curves for these materials are parallel to a typical

melting curve for granite, the elevation is 70° Cat 1

kb. The Bucksport Formation would probably not melt if:

1) Pf= Pt= 1 kb and 2) contact temperatures from either

plagioclase-amphibole geothermometry, two feldspar

geothermometry, or estimated temperatures based on Jaeger

and Novak's work, are correct. However, with increase in

depth to 6 km ( 2 kb), if the estimated geothermal

gradient of 133° C/krn persisted, Ta would increase to

800-850° C. At these temperatures the Bucksport

Formation probably would melt.

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DISCUSSION

Origin of the Clifton Migrnatite

The migrnatite was not solely produced through solid-

state processes.

1) Although melanosomes and inclusions in the leucosomes

display metamorphic textures, the leucosomes themselves

display igneous textures.

2) Metamorphic differentiation probably produced the

fine-grained gneisses in the Bucksport Formation, but

these are quite dissimilar to melanosome-leucosome

interlayers.

3) While there may have been convenient sources of fluids

( the Lucerne and the Parks Pond Plutons) for the

metasomatic generation of the leucosomes, Wones (1980)

argues that the Lucerne Pluton was a dry magma,· coronas

in the leucosomes are generally absent, and only two out

ten exposed Bucksport/Lucerne contacts exhibit

migmatites. However, at this time it is not known

whether or not the Parks Pond Pluton was saturated with

H20 during its cooling hi story ( Eriksson, personal

communication).

There are also several lines of evidence against

partial melting in situ:

1) Mineral disequilibria between adjacent melanosomes and

leucosomes.

91

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92

2) Closest fit solutions from the mixing program that

require removal of restite.

3) The occurrence of 81% leucosome at outcrop RMB. It is

unlikely that an 81% partial melt would remain at its

site of origin (van der Molen and Paterson, 1979).

An injection of igneous material remains as the most

probable origin for the migmati te. Two convenient

sources of such material are the Lucerne and Parks Pond

Plutons; neither is likely. The Lucerne Pluton cross

cuts the migmatite, and the compositions of its biotite

and plagioclase are quite dissimilar to compositions of

these phases in the leucosomes. There is no

chronological argument against the involvement of the

Parks Pond Pluton in production of the migmati te.

However, mineralogical evidence suggests that leucosomes

have inherited neither orthopyroxene, clinopyroxene, nor

biotite from the Parks Pond.

There is good evidence that the heterogeneous

leucosomes represent multiple melts:

1) They range from tonalite to alkali feldspar

granite/quartz-alkali feldspar syenite in composition.

2) They display at least four different orders of

crystallization.

3) The maximum anorthi te-content of plagioclase in

different leucosomes is quite different.

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93

From results of the mixing program, four out of five

analyzed leucosomes

Bucksport Formation

are successfully described as:

minus resti te. Under conditions

outlined before, the Parks Pond Pluton could have

partially melted the Bucksport Formation at depth.

Multiple melts from the heterogeneous Bucksport Formation

could then have risen, without homogenizing, to present

exposures.

Origin of the Inclusions

Chappell (1978) has described inclusions in the I-

type granites of the Moonbi district that are remarkably

similar to inclusions found in the Clifton Migmati te.

Both are mafic, relatively fine-grained, amphibole-rich,

frequently ovoid clusters of anhedral grains with a

recrystallized fabric and with sharp boundaries with the

surroundings. He maintains that these are restite.

White and Chappell (1977) identify a whole class of

similar I-type inclusions, and suggest the following

origin. Mel ting of I-type source material, such as

andesite or basalt, produces: melt+/- plagioclase +/-

orthopyroxene +/- clinopyroxene. On rising, the viscous

granitic magma retains the refractory phases. As it

rises, temperature decreases, the activity of H20

increases, and the restite reequilibrates with the magma

by reacting to hornblende. The frequent appearance of

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94

pyroxene in the cores of these inclusions is cited as

good evidence for the process. On the other hand, S-type

inclusions thought to be restite are typically rich in

cordierite, sillimanite, and garnet.

Inclusions in the Clifton Migmatite sometimes have

clinopyroxene in the cores. In the calcareous melanosome

layers, as the Lucerne and Parks Pond Plutons are

approached, clinopyroxene and hornblende are the last two

phases to appear. Thus they are. probably stable at high

temperatures, and would be resistant to melting. Fe/Mg

ratios in coexisting amphiboles from inclusions and

primary amphiboles are usually identical; inclusions have

equilibrated with the surroundings. It is likely that

these inclusions have followed the same process as White

and Chappell (1977) have described, except that they are

derived from the calcareous, metasedimentary Bucksport

Formation.

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95

FURTHER WORK

Further work in three areas would add much to the

results found in this study. 1) Gravity anomaly and

magnetic studies would help define the borders, in two

and three dimensions, of rocks in this region. Magnetic

studies would be especially helpful in delineating the

borders of the migrnatite in the central portion of the

field area, where outcrops are absent. Sweeney (1975;

1976) has done gravity anomaly studies of the Lucerne

Pluton, his studies are incomplete. The subsurface

extent of the Parks Pond Pluton is at present unknown.

2) The extent of the contact aureole surrounding the

Parks Pond Pluton has not been well defined in this

study.. Cavalero ( 1965) states that it extends up to 2. 7

km from the Parks Pond Pluton. This is in contrast to

the 1 km aureole surrounding the Lucerne Pluton (Novak,

1979). The difference may result from a particular

orientation of the Parks Pond Pluton at depth and/or

crystallization temperatures in the Parks Pond Pluton

that are much higher than those of the Lucerne Pluton.

3) Trace element and stable isotope studies could be used

to further test the hypothesis that the migmati te is

related by partial melting to the Bucksport Formation

(Dougan, 1981; O'Neil et al., 1977).

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REFERENCES

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Cavalero, R. A. (1965) Geology of the Clifton Township area in the Orono and Great Pond Quadrangles, Maine. Unpublished M.S. Thesis, University of Maine.

Chappell, B. W. (1978) Granitoids from the Moonbi District, New England Batholith, eastern Australia. Geological Society of Australia Journal, 25, 267-283.

Chappell, B. W. and White, A. J. (1974) Two contrasting granite types. Pacific Geology, 8, 173-174.

Deer, W. A., Howie, R. A., and Zussman, J. (1980) An Introduction to the Rock Forming Minerals. Longman Group, London.

Dougan, T. W. (1979) Compositional and modal relationships and melting reactions in some migmatitic metapelites from New Hampshire and Maine. American Journal of Science, 279, 897-935.

Dougan, T. W. (1981) Melting reactions and trace element relationships in selected specimens of migmatitic pelites from New Hampshire and Maine. Contributions to Mineralogy and Petrology, 78, 337-344.

Ellis, A. J. and Mahon, W. A. J. (1977) Chemistry and Geothermal Systems. Academic Press, New York.

Engel, A. E. and Engel, C. G. (1958) Progressive metamorphism and granitization of the major paragneiss, northwest Adirondak mountains, New York, 2. Bulletin of the Geological Society of America, 69, 1369-1413.

Eriksson, S. C. and Wones, D. R. (1983) The Parks Pond Pluton, eastern Maine: evidence for cratonization or orogenic activity? Northeast Geological Society of America Abstracts with Programs.

Evans, B. W. (1965) Application of a reaction-rate method to the breakdown equilibria of muscovite and muscovite plus quartz. American Journal of Science, 263, 647-667.

96

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97

Harris, N. B. W. (1974) Some migmatite types and their origins, from the Barousse Massif, Central Pyrenees. Geological Magazine, 111, 319-328.

Hobbs, B. E., Means, W. D. and Williams, P. F. (1976) An Outline of Structural Geology. Wiley, New York.

Holmquist, P. J. (1921) Typen und Nomenklatur der Adergesteine. Geologi ska Foreningen i Stockholm, Forhandlingar, 43, 612-631.

Hyndman, D. W. (1972) Metamorphic Rocks.

Petrology of Igneous McGraw-Hill, New York.

and

Jaeger, J. C. (1959) intrusive sheet. 44-54.

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Johnson, M. R. W. (1963) Some time relations of movement and metamorphism in the Scottish Highlands. Geologie en Mijnbouw, 42, 121-142.

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Lofgren, G. E. (1977) Dynamic crystallization experiments bearing on the origin of textures in impact-generated liquids. Proceedings of the Eighth Lunar Science Conference, 2, 2079-2095.

McLellan, E. L. (1983) Contrasting textures in metamorphic and anatectic migmati tes: an example from the Scottish Caledonides. Journal of Metamorphic Geology, l, 241-262.

Mehnert, K. R. (1971) Migmatites and the Origin of Granitic Rocks. Elsevier, Amsterdam.

Misch, P. (1968) Plagioclase compositions and non-anatectic origin of rnigrnatite gneisses in Northern Cascade Mountains of Washington State. Contributions to Mineralogy and Petrology, 17, 1-70.

Miyashiro, A (1973) Metamorphism and Metamorphic Belts. Wiley, New York.

Novak, S. W. ( 1979) Contact metamorphism of the Lucerne

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98

pluton, Hancock County, Maine. Unpublished M. S. Thesis, Virginia Polytechnic Institute and State University.

Olsen, S. N. ( 1977) Origin of the Bal ti more Gneiss migmatites at Piney Creek, Maryland. Bulletin of the Geological Society of America, 88, 1089-1101.

O'Neil, J. R., Shaw, S. E., and Flood, R.H. (1977) Oxygen and hydrogen isotope compositions as indicators of granite genesis in the New England Batholith, Australia. Contributions to Mineralogy and Petrology, 62, 313-328.

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99

rocks, southcentral Maine. Geological Society of America Bulletin, 87, 241-249.

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100

Zwart, H. J. (1962) On the determination of polymetamorphic mineral associations, and its applicatio"n to the Boso st area ( central Pyrenees). Geologische Rundschau 52, 38-65.

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APPENDIX A

Output from Mixing Program

...... 0 ......

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The hypothesis that the Bucksport Formation melted to produce the leucosomes was tested,

using Wright and Doherty's (1970) mixing program. The program uses least-squares analysis to

solve the equation aA + bB ... -nN - oO .•. = Z. In this case, A and Bare the bulk chemistry

of melanosomes or samples of the Bucksport Formation, N and Oare microprobe analyses of

biotite, amphibole and/or clinopyroxene, and Z is the calculated bulk chemistry of a leucosome.

In the equation, a, b, n, and o are coefficients. In these tables, columns labelled 37, 47,

13, 46, 22, 3A, 33, and 26 give the bulk chemistry of members of the Bucksport Fm or melano-

somes. Columns labelled AM, CP, and BT give average analyses of amphibole, cpx, and biotite,

respectively. Columns labelled 34, 27, BA, 23, or 9A give the actual bulk chemistry of a

leucosome. Columns labelled CALC. give the calculated analysis for a leucosome, Columns

labelled DIFF. give the difference between the calculated and actual analysis of a leuco-

some. Rows labelled SOLUTION give the calculated coefficients (or percentages). Rows

labelled SENSITIV give a standard error. See text for more information.

...... 0 N

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37 117 1 3 116 22 3A 33 26 AM GP BT 311 CALC. DI FF.

S102 57. 74 71 . 1 7 71.56 69,118 63.95 70.97 72.37 71. 96 46.26 52. 17 38.51 55. 711 70.88 -15. 13

AL203 20.67 11. 70 10. 55 111. 56 16.32 11. 88 10.87 10.95 9.07 0.65 15.40 13.87 12.52 1. 35

FE?.03 8. 511 3. 70 3,119 2.52 5.75 3.813 3.87 4. 12 17. 10 9.86 20. 18 12.44 3. 112 9.02

MGO 5. 77 2.71 2.43 1. 98 3.85 2.66 2.87 3. 18 11. 15 13.03 12. 111 3.37 2.65 0. 72

CAO 0. 73 5.63 1,. 47 2.25 2.97 6.33 5. 72 5.32 11. 85 23.32 0.08 7. 12 3.98 3. 111

NA20 1.45 1. 37 1. 08 2.36 2.89 2.24 1,118 2.02 1. 15 0.24 0. 12 3. 31 2. 1 7 1 . 111

K20 3. 91 2.86 5.59 6.22 3.24 0.98 1 . 90 1. 54 1 . 09 0.03 9.61 1 . 111 3.57 -1. 82 ...... 0

TI02 0.98 0.611 0.62 0.41 0.82 0. 75 0.69 0.68 1. 91 0. 16 3.09 2.28 0. 5 7 1. 72 w

P205 0. 18 0.20 0. 17 o. 19 0. 18 0. 211 0.20 0.20 0.00 0.00 0.00 0.00 0. 19 -o. 18

MNO 0.08 0.09 0. 10 0.09 0.09 0. 13 0.09 0.09 0.116 0.60 0.32 0. 18 0.09 0. 10

SOLUTION 0.00 0.00 0.00 43.53 0.00 o.oo 0.00 56. 118 0.00 0.00 0.00

SENSITIV 15. 73 20.76 21 . 13 20.69 18. 12 20.52 21.08 20.90 10.00 12. 70 7.90

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37 lj l 13 !16 22 3A 33 26 AM Cf' Bl ?I CAI.C. 0 II I.

SIO? 'j l. 111 7 1 . 1 I 71. 56 6'). 118 63.95 10.91 72.37 71. 96 !16. 26 52. 17 38. 51 62.43 611.211 - 1 . 80

AL203 20.67 1 1 . 70 10. 55 111. 56 16.32 11. 88 10. 87 10. 95 9.07 0.65 15 .110 18. 31 18. 09 0. 2 3

rr203 8. 511 3. 70 3 .119 2. 52 5. 75 3.88 3.87 11. 12 11. 10 9.86 20. 18 11. 35 '>. 7 1 - 1 . 3 'j

MGO 5. ll 2. 71 2 .113 1 . 98 3.85 2.66 2.£11 3. 18 I I. 15 1 3. 03 12. 711 2.23 3.97 - I. /3

CAO 0.13 5.63 11 • 111 2.25 2.97 6.33 5. 72 5.32 11. 85 23. 32 O. 08 11. 36 ? . 3 I ? .115

NA?.O I .115 1. 3' I . 08 2. 36 2.89 ? . ;>11 1. 118 ?.fl? 1. 15 0. ?11 ll. I? ?.19 1 . r,11 I. I') ...... 0

K?.O 3. 9 I 2.86 5.59 6.22 3. 211 0.98 I . 90 1. 511 1. 09 0.03 9.61 !1 . 3 'j 3 . 1 6 1. 19 ~

TI 02 0. 98 (). 611 0.62 0.11 I I). 8?. (). l ':> U.69 0.68 1. 91 o. 16 3.fl9 0. f 11 ll.66 0. 119

1'205 fl. 18 (). 21J 0. 1 7 (I. 1 <) o. 18 (). ?11 0.211 0.20 (I. ()I) () • I)( J (). (J(J II . :111 () . ;> ( I I). 1 'j

MIIO 0. 08 0.09 I)• l[J 0. 09 o. 09 (). 1 3 0.09 0 . 09 0. 11(, 0.60 (). 3? o. 1? (). IJ(, (I. 117

SOLU r I ori 77. 52 0.01) 17.86 0.00 0. 0(1 15. 1'.i (). 00 0. ()() (). ()() 0.00 -10.51

StNSI I IV 2.66 2.91 2.91 2.80 2. 71 ?. . 90 3 . ()(l 3.01 2.22 ?. . ()() ?. . 3?

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3 / ,, 1 1 3 116 22 3A B ?.6 AM CP 81 23 CALC. 0 IF F.

SIO;.> ') 1 . 11, 11 . 1 / 11. ?6 ()<). 11 ft 63. 95 70. 91 r;. 3, 11. 96 116. 26 ':>2. 1 7 38. ':> 1 68.90 69. 19 -0.?9

AL?.03 20.67 11. 70 10. '>5 1 IL 56 16.32 11.88 10. 8 / 10. 95 9.07 0.65 15 .1,0 15.09 5.51 -0 .111

rr 203 8. '.;11 3 . /(J 3. 1,9 ?. ':,2 5.75 3.88 3. R 1 11. 12 1 7. 10 9.86 20. 18 3. 111 3.39 -0.25

M(;O '.>. 7 I 2. 71 ?. . 113 1. 98 3.85 2.66 2. Bl 3. 18 11 . 15 13.03 12. 711 2.39 ?. . 1, 1 -0.01

CAO [) . / 3 5.63 IJ. lj] 2.25 2.97 6.33 5. 72 5.32 11. 85 23.32 0.08 2.69 2.19 -0.09

NA?O 1. 1,5 1. 3 1 1 . 08 2. 36 2.89 2. 211 1 .118 2. O? 1 . 1 ':> (). 211 (). 1 ;> 2.88 2. 511 o. 311 ..... 0

K?O 3. 91 2.86 'J. 59 6.?? 3. 211 0.98 1 . 90 1. ':>4 1 . 09 0. 03 9.61 IL 111 3.]8 0. 76 V,

I IO? 0.98 o. 611 0.6? (J • 1, 1 O.B2 o. 75 0.69 0.68 1. 91 0. 16 3.09 0.54 0.60 -0.05

P20'i II. HI 0.20 0. 1 7 O. 19 0. 18 0.211 0. 2() O.?O 0. 00 0. 00 0.00 0.22 0. 21 0.01

MNO 0. Oil 0.09 0 . 1 () 0.09 0.09 0. 13 0.09 0.09 0.116 0.60 o. 3? 0. o 7 (J • ()11 (). 011

SOI lJ T I ON (l. (l(l ]8. <J 1 (). ()() 0.00 /11. n 0. (I() 0 . f II I 0. 1111 -11. 69 o . on O. 011

S[NSITIV O. 118 1 . 02 0.98 O. 95 0. 9 3 1 . 05 1 . () ':> 1 . 0? 0. 72 0. 77 0. 56

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37 1, 7 1 3 116 22 3A 33 26 AM CP IH 8A CALC. DI f F.

S102 57. 11, 71. 17 71. 56 69.48 63.95 70.97 72.37 71. 96 46.26 52. 17 38.51 66.83 67.28 -0.45

Al.203 20.61 11. 70 10.55 111. 56 16.32 11. 88 10. 87 10.95 9.07 0.65 15.40 14.82 14 .1'7 0.35

F[;>OJ 8. 511 3. 70 3 .119 2.52 5. 75 3.88 3.87 4. 12 17 .10 9.86 20. 18 3. 72 4.53 -0.80

MGO 5. 77 2. 71 2 .113 1.98 3.85 2.66 2.87 3. 18 11 . 15 13.03 12.74 2.57 3.09 -0.51

CAO 0.73 5.63 11.117 2.25 2.97 6.33 5.72 5. 32 11. 85 23. 32 0.08 3. 3 3 3. 56 -0.22

Nl\?.O 1 . 115 1.37 1. 08 2.36 2.89 2. 211 1.118 2.02 1 . 1 5 0.24 0. 12 2.68 2.40 0.29

K20 3.91 2.86 5.59 6.22 3.24 0.98 1 . 90 1. 54 1. 09 0.03 9.61 5.06 ,-

3. 79 1. 28 0 O'

TI02 0.98 0. 611 0.62 0. 1, 1 0.82 0.75 0.69 0.68 1. 91 0. 16 3.09 0.62 0. 68 -0.05

P205 o. 18 0.20 o. 17 0. 19 0. 18 0. 21, 0.20 0.20 0.00 0.00 0.00 0.31 0. 18 0. 1 3

MNO 0.08 0.09 o. 10 0.09 0.09 0. 13 0.09 0.09 0.116 0.60 0. 32 0. 11 0.08 0.03

SOLUl I ON 0,00 0.00 3?.53 0.00 ·10. 85 0.00 0.00 0. 00 0.00 0.00 -3.36

SfNSITIV 0. 8 7 1. 1 3 1. 07 0.95 0.97 1. 18 1. 19 1. 20 1. 06 1. 23 0.10

Page 112: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

37 111 1 3 46 22 3A 33 26 AM CP BT 9A CALC. DIH.

S102 57. 711 71. 17 71.56 69.118 63.95 70.97 72.37 71. 96 46.26 52. 17 38.51 70.06 70.46 -0.40

AL203 20.67 11. 70 10.55 111. 56 16.32 11.88 10. 87 10.95 9.07 0.65 15 .1,0 15.58 14.62 0.97

f[203 fl. 511 3. 70 3 .1,9 2.52 5.75 3.88 3.87 4. 12 17. 10 9.86 20. 18 2.21 2 .113 -0.22

MGO 5. 77 2. 71 2 .1,3 1.98 3.85 2.66 2.87 3. 18 11 . 15 13.03 12.74 1. 23 1. 68 -0.45

CAO 0.73 5.63 11,111 2.25 2.97 6. 33 5. 72 5.32 11. 85 23.32 0.08 2.1,5 1,911 0.51

NA20 1, 1, 5 1.37 1. 08 2.36 2.89 2. 211 1 .118 2.02 1. 15 0.24 0. 12 2.87 2.32 0.55

K?O 3.91 2.86 5.59 6.22 3,211 0.98 1. 90 1. 'JII 1 . 09 0, 03· 9.61 5. 01, 5.87 -0.83 ...-0 -...J

H20 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

TI02 0.98 0.611 0.62 0. 111 0.82 0. 75 0.69 0.68 1. 91 0. 16 3.09 0.38 0 .116 -0.07

P205 0. 18 0.20 0. 17 0. 19 0. 18 0. 21, 0.20 0.20 0.00 0.00 0.00 o. 16 0.20 -0.03

MNO 0.08 0.09 0. 10 0.09 0.09 0. 13 0.09 0.09 0.46 0.60 o. 32 0.08 0.07 0.02

SOLUTION 0. !JO I(). 70 0.00 88. 31, 0.00 0.00 0.00 11. 89 o.oo -3.91 0.00

S£NS1TIV 0.60 0.90 0.98 0.88 0. 70 0.84 0.92 0.91 0.55 0.69 0. 63

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...... 0 co

APPENDIX B

Microprobe Analyses from Leucosomes

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SIIHPI.[ 811 IIHPlll80L[ ANALYSES I 2 3 4 5 6 7 8

5102 ,,8. 91 1,9.25 49.67 47.39 46.84 114.48 49.08 52.32 r 102 0.88 o. 70 o. 7l 1.02 1. 12 1.07 0.88 0.45 11203 5.85 5.31 5.01, 6.43 8.93 11.06 5, 71 3.56 rro 15. 18 14.95 15. 111 16.32 15.79 15.21 15. 511 13.85 HtlO 0.60 0.58 0.56 0.56 0.52 0.51 0.50 0.64 HGO 11. 92 11.92 12.40 11. 41 11. 28 11. 01 12. 55' 14.07 C/10 11. 86 12.04 11. 95 11. 97 11.86 11. 48 12.114 12.56 RAO u.o 0.0 0.0 0.0 o.o o.o 0.0 o.o NA20 0.92 0.69 o. 74 1.07 1.01 1. 14 0.99 0.40 k20 0.58 0.45 0.1,8 0.68 0.70 o. 711 0.57 0.25 r 0.0 o.o 0.0 o.o 0.0 0.0 0.0 0.0 Cl 0.0 0.0 o.o o.o o.o o.o 0.0 0.0 1120 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 SUl1 96. 76 95.89 96.71 96.85 98.05 96.70 98.26 98. 10 ·O= r+CL 0.0 0.0 o.o o.o o.o 0.0 0.0 o.o SUH 96. 76 95.89 96.71 96.85 98.05 96.70 98.26 98. 10

SI 7.268 . 7. 377 . 7.380 . 7. 119 • 6.917 • 6.662 • 7,220 . 7.582 • Ill o. 712 8.000 0.623 8.000 0.620 8.000 0.881 8.000 1.083 8.000 1.338 8.000 0. 780 8.000 0.418 8.000 Al o. 111, . 0.314 • 0.263 • 0.257 • 0.1171 • 0.614 • 0.209 • 0. 190 • TI 0.098 • 0.079 • 0.082 • o. 115 • o. 124 • 0.121 • 0.091 • 0.0119 • re 1.889 • I. 873 . 1.881 • 2.050 • 1.950 • 1. 905 . 1. 912 . 1. 679 • HN 0.076 . 0.074 • 0.070 • 0.071 • 0.065 • 0.065 • 0.062 . 0.079 . HG 2.6'•'1 5.021 2.661 5.000 2.7116 5.0•12 2.555 5.049 2.483 5.094 2.458 5.162 2. 752 5.032 3.039 5.035 CA 1.891 • I. 932 • 1.902 • 1.927 • 1.877 • 1. 8'42 • 1.961 • 1,950 . .... NA 0.265 • 0.200 • 0.213 • 0. 312 • 0.289 • 0. 331 • 0.282 • 0. 112 • 0 k 0.110 . 0.066 • 0.091 • 0.130 • 0.132 • 0.141 • o. 107 . 0.0'46 . ~

OA 0.0 2.267 0.0 2.218 0.0 2.207 o.o 2.368 0.0 2.298 o.o 2.315 0.0 2. 350 0.0 2. 109 CL o.o . 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 . 0.0 • r 0.0 • 0.0 • o.o • 0.0 • 0.0 • o.o • 0.0 • 0.0 • II o.o 0.0 0.0 o.o o.o o.o 0.0 0.0 o.o o.o o.o 0.0 o.o o.o o.o o.o 0 23. 000 • 23.000 • 23.000 • 23.000 • 23.000 • 23,000 • 23.000 • 23.000 • CAA 29.09 29.55 28.112 29.111 29.'4'4 29. 38 29. 32 211.91

ANT '40.68 40.69 41.61 38.69 38.95 39.20 41. 15 45.05 GRU 30.23 29.76 29.57 32. 13 31.61 31. '42 29.52 26.0'4

r/H 0. 7113 0.731 0.711 0.830 0.812 0.801 o. 717 0.578 r/FH 0.'426 0.'422 0.415 0,'4511 0.4'48 0.4115 0.'418 (l.366

I 811 TRAY>< INCLUS IIOL[ 1 50322 36'482 5 50128 37062 2 50283 36598 6 50089 37178 3 50244 3671'4 7 491196 3 7758 Ii 50205 36830 8 SCAN 2 X SAHE INC 49935 36842

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SAHrLE 6A AHPII I BOLE ANALYSES 9 10 11 12 13 111

SI02 47. 35 47 .40 47 .69 116. 22 50.12 46.33 TI o;> 1.06 I. 18 I. 16 0.93 1.15 o. 71 A2Ul 6.61 7 .61 7.01 6.67 8.60 ,,. 7l rro 16.01 15.99 15.62 t5.42 16.06 111. 78 MNO 0.55 Cl.56 0.67 0.56 0.61 0.52 MGO 12.08 12.26 12. 51, 12. 13 12.92 11.35 C/\0 12.1,11 12.09 12. Jll 12.09 12,110 11. 78 111\0 0.0 o.o o.o o.o o.o o.o NA20 0.99 1.25 1. 23 0.95 I. 19 0. 71 ~70 0.69 o.78 o. 76 0.61 0.76 0.45 r u.o 0.0 o.o 0.0 0.0 0.0 CL 0.0 0.0 o.o o.o o.o 0.0 1120 0.0 0.0 0.0 0.0 0.0 0.0 SUM 98.02 99.12 98.93 97. 58 103.81 91. J5 -Os F+CL 0.0 o.o 0.0 0.0 0.0 0.0 SUH 98.02 99. 12 98.93 97. 56 103.81 91. 35

SI 7.028 • 6.952 • 7 .002 • 7. 139 • 6.974 • 7.378 • Al 0.972 8.000 1.048 8.000 0.998 8.000 0.66t 8.000 1.026 8.000 0.672 8.000 AL 0.219 • 0.267 • 0.215 • 0. 302 • o. 3811 • 0.210 . TI o. 1111 . 0.130 • 0.126 • 0.1011 • o. 120 • 0.085 . I [ 1. 987 • 1.961 • 1.918 • 1.909 • 1.869 • 1. 955 • Hll 0.069 • 0.070 • 0.077 • 0.071 • 0.071 • 0.070 • HG 2.672 5.066 2.680 5,109 2. 7114 5.062 2.677 5.063 2.679. 5. 123 2.675 4.994 ...... Cl\ 1.985 • 1.900 • 1.935 • I. 918 • 1.649 • 1.991 • ...... NA 0.285 • 0.355 . 0.350 . 0.272 . 0.321 • 0.217 . 0 K 0. I 3 I • o. 1116 • o. 142 • 0.115 • o. 135 • 0.091 • BA 0.0 2.400 o.o 2.401 0.0 2.427 0.0 2.305 o.o 2.305 0.0 2. 305 Cl u.o . 0.0 • o.o • 0.0 • 0.0 • 0.0 • r 0.0 . o.o • o.o • 0.0 • o.o • o.o • H 0.0 0.0 0.0 0.0 0.0 0.0 o.o o.o 0.0 o.o 0.0 0.0 0 23.0011 • i!J .000 • 23.000 • 23.000 • 23.000 • 23 .000 •

C/\11 29.56 28. 74 28.99 29.18 211.59 29.82 Alli 39.111 40.54 41. 12 40. 71 41.41 39.95 GRU 30.63 30. 72 29.119 JO. 11 30.00 30.23

F/H 0. 769 0.758 o. 727 0. 740 0.724 0. 757 F/FH 0.435 0.431 0.421 0.425 0.420 0.113 I

9 50021 36922 12 AVERAGE 10 50192 37061 13 AVERAGE PLUS SIGMA 11 50276 37161 14 AVERAGE HINUS SIGHA

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SAHPL[ IIA AHPltlBOL[ ANALYSES 1 2 3 lj 5 6 7 8 5102 4 7 .08 117.01 49.ZZ 110.1111 119.70 115. 70 117. 33 118.011 TIO?. I. 29 1.26 o. 77 0.82 0.51 1.23 1. 15 1.07 A20J 6. 80 1.119 5.44 19.25 5.23 7 .65 7.25 6.70 f (O 16. 31 16.09 111.96 12.66 13. 77 16. 311 15.83 16. 37 HNO 0. 59 0.60 0.61 0.113 0.56 0.55 0.59 0.119 HGO 11. 32 12.21 12.611 9.32 14.06 11. 76 12. 15 11. 91 CAO 12.27 12.011 12.30 10.911 12. 16 12.23 12. 36 12.20 BAO o.o 0.0 o.o o.o 0.0 0.0 o.o o.o NA?O 1. 1 7 1.29 1.01 I. 03 0.62 1. 31 I. 10 0.97 ~20 o. 76 0.82 0.52 0.51 o. 32 0.85 0. 75 0.68 r 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 C:I. o.o 0.0 o.o 0.0 o.o 0.0 o.o o.o 11?.0 0.0 0.0 o.o 0.0 o.o o.o 0.0 o.o SUH 97. 59 98.85 91.111 95.80 96.93 97 .62 98.51 98.113 -Cl= f+CL 0.0 0.0 0.0 o.o 0.0 0.0 0.0 o.o SllH 97.59 96.65 97.117 95.80 96.93 97.62 98.51 98.113

SI 7. Ill/\ . 6.929 . 7 .277 • 6.066 . 7.318 • 6.8511 . 6.985 • 7.090 • Al 0.96•• 6.000 1.071 8.000 0. 723 8.000 1.9311 8.000 0.682 8.000 1. 1116 8.000 1.015 8.000 0.910 8.000 Al. 0.233 . 0.230 . 0.224 • 1.1136 • 0.226 • 0.206 • 0.246 • 0.255 • II 0. 11,5 . 0. 11,0 . 0.086 • 0.09Z • 0.056 . 0. 139 . 0.128 • o. 119 • ff. 2.036 . 1.963 . 1.650 . 1.573 • 1.696 . 2.050 . 1.954 • 2.020 • MN 11,075 . 0.0/5 . 0.076 . 0.054 . 0.070 • 0.070 • 0.074 • 0.061 • ~IC 2.n2 ~.013 2.663 5. 111 2.765 5.021 2.063 5.216 3.066 5. 134 2.629 5,093 2.673 5.074 2.620 5.076 C:11 1. 96~ . I. 906 . 1. 946 . 1. '/41 . 1.916 . 1. 965 • 1.954 . 1. 929 . ...... Ill\ 0. 339 . 0. 369 . 0.290 • 0.297 . o. 177 . 0.361 . 0.315 • 0.276 . ...... k II. 1115 . o. 154 • 0.096 • 0.097 • 0.060 • 0. 163 • 0.141 • 0. 126 . ...... Ill\ ll.O 2.4 .. 9 0.0 2. "31 0.0 2.336 0.0 2. 134 o.o 2. 156 0.0 2.509 0.0 2.410 o.o 2.335 CL 0.0 . 0.0 . 0.0 • o.o • o.o • o.o . 0.0 . 0.0 . ,. ll.O . 0.0 . 0.0 . 0.0 . 0.0 . 0.0 . 0.0 . o.o . II 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 0 7.3.000 . 73,000 . 23 .000 • 23.000 • 23.000 . 23.000 • 23.000 . 23.000 . CAI\ 29. 77 26.69 29.c.'6 32.06 28. JII 29.27 29.37 29.09 ANI 36.21 40. 35 4 I .82 37.99 45.56 39. 16 40.16 39.51 GRU 32.02 30.96 26.92 29.95 26.06 31.H 30.47 31.39

f/H 0.636 0.767 0.691 0.786 0.572 0.606 0.759 0. 795 f/fH 0.456 0.434 0.409 0.441 0. 364 0.446 0.431 0.1143 1 8 A q f~[[ AHPIRI\V 55398 11170 5 55592 114119 7 6 I\Q fR[[ AHP554Q6 11240 6 55689 11569 3 6A q JR[[ AHP5~Q95 11309 7 55737 11659 4 6A q JR[[ AHP55543 11379 8 TRAV X NOTH[R fREE AHP ALONG LENGTH or E

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SAMPLE 6A AMPIIIIIOL[ ANALYSES 9 10 11 12 1J 14 15 16 SIOZ 116.69 5 ... 06 46.62 46.94 47.83 47 .20 47 .62 50.32 T 1oz 1. 0'."> 0. 18 I. 15 0.85 1.04 0.95 0.95 1.25 A?.Ol 7. 1 7 1. 64 7.57 5.75 7 .45 6.56 7.28 10.93 f[O 15.80 13.45 16.28 15.38 16.01 15. 41 15.33 16.119 HNO O.li8 o. 56 O.li9 0.57 0.50 0.61 0.51i 0.60 HGO IZ.ZZ 15.09 11.68 12. 75 12. 17 12.30 12.26 13.51 CAO 12.00 12. 77 12. 19 12.16 12.29 12. 311 12. 16 12.511 llAO ll.O 0.0 o.o 0.0 0.0 0.0 0.0 o.o NAZO 1. 21 0.25 1. 18 0.75 1. 12 1.09 1.01 1.29 kZO 0. 1Z 0.12 0. 77 0.68 o. 77 0.66 0.611 0.811 r 0.0 0.0 0.0 0.0 0.0 o.o o.o o.o CL 0.0 0.0 o.o o.o 0.0 o.o 0.0 o.o HZO 0.0 0.0 o.o o.o o.o 0.0 0.0 0.0 SUM 97.54 98. 12 98. 1l 97.83 99. 18 97. 12 97.79 107.76 ·O= F+Cl o.o o.o o.o o.o 0.0 0.0 0.0 0.0 SUM 97.5 .. 98.12 98.13 97.83 99. 111 97 .12 97.79 107.76

SI 6.987 . 7.795 • 6.952 . 7.222 • 7,003 • 7.056 • 7 .0113 • 6.7119 • Al 1. 01 l 8.000 0.205 11.000 1.01111 8.000 o. 7711 8.000 0.997 11.000 0.91111 8.000 0.957 8.000 1. 251 11.000 Al 0.2 .. 6 . 0.0711 • 0.277 • 0.222 • 0.2811 • 0.211 • 0.312 • 0.1176 • Tl 0.118 . 0.020 . o. 128 • 0.0911 • o. 115 • 0.107 • 0.106 • o. 126 • F£ 1.969 . 1.622 . 2.022 . 1.898 • 1.960 • 1.926 . 1. 896 • 1.8119 • HN 0.061 . 0.068 • 0.062 • 0.071 • 0.062 • 0.077 . 0.068 • 0.068 • ...... HG 2. 71q '.>. 107 l. 21il 5.027 2.585 5.0711 2.804 5.090 2.656 5,081 2. 741 5.062 2. 702 5.0811 2.700 5.220 ...... CA 1,916 . 1.973 • 1.939 . 1.923 • 1.928 • 1,976 • 1.927 • 1.802 • N NA 0.350 . 0.070 . 0.340 • 0.215 • 0.3111 • o. 3f6 • 0.289 • 0.3311 • k 0.137 . 0.022 . 0.146 • o. 128 • o. 144 • 0.126 . 0.120 • o. 1113 • BA 0.0 2.402 0.0 2,065 o.o 2.425 0.0 2.265 o.o 2. 390 o.o 2.418 o.o 2.337 0.0 2.280 Cl o.o . o.o . o.o • o.o • 0.0 • 0.0 • o.o • 0.0 • r o.o . o.o . 0.0 • 0.0 • o.o • 0.0 • 0.0 • o.o • II 0.0 0.0 0.0 0.0 o.o o.o 0.0 0.0 o.o 0.0 0.0 0.0 o.o 0.0 o.o 0.0 0 23. 000 . 23. 000 . 23.000 • 23.000 • 23.000 • 23.000 . 23.000 • 23. 000 • CAA Z6. 11 28.57 29.35 28.71 29. 18 29.41 29.23 28.08 ANT 40.76 116.96 39. 12 111.88 40.20 110.78 40.97 42.06 GRU 30.48 211.47 l 1.53 29.111 30.61 29.81 29.80 29.117 F/H o. 7q8 0.521 0.806 0.102 0. 761 0.731 o. 727 o. 710 F/FM 0 ... 26 O. l4J 0.446 0.413 0.432 0.422 0.421 0 ... 15

9 55583 IOl16q 1J 56028 11029 10 55672 10577 111 56117 11142 11 55761 10690 15 AVERAG[ 12 55939 10916 16 AVERAGE PLUS SIGMA

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SAHPL[ 8A 17

SI02 114.9Z Tl02 0.6~ A20l l.6] f[O 14. 18 HPIO 0.49 HCO 11. 01 CAO 11. 78 BAO 0.0 NA20 0.7] 1<20 0.114 f 0.0 CL 0.(1 1120 o.o SUH 87.8] -0= f+CL 0.0 SUH 87.8]

SI 7. 404 AL 0. 596 a.ouo AL 0.110 . TI 0.081 . f[ 1.9511 • HN 0.068 . HG 2.704 4.918 CA 2.081 . NA 0.2JJ • I< 0.092 • BIi 0.0 2.406 CL o.o . f 0.0 . H 0.0 0.0 0 2] .000 .

CAA l0.57 ANT 39.72 CRU 29.71

f/H 0.748 f/fH 0.428

17 AV[RAC[ MINUS SIGMA

AMPtllOOL[ ANALYS[S

...... ...... w

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SAHPLC 8A rcLDSPAR ANALYSES I 2 3 II 5 6 7 8

SIC>;' 61. 31i 511.21 58.21 59.40 59.33 60.45 60.87 58.77 110?. ti. 0 I 0.02 0.0 0.04 0.03 0.03 0.02 0.0 A;.'OJ 7~. 18 2'.i.1111 25.48 24.29 24.112 24.24 23.76 25.23 f(O 0.05 0.05 0.07 o.o 0. 11 0.04 0.11 0.02 flll() II.Ill 0.01 o.o 0.02 0.03 0.01 0.01 0.02 ~1c;n o.o 0.03 0.0 0.0 0.0 o.o o.o 0.0 CAO 6.61 I. li9 7 .1,2 6.52 6.110 6.40 5.511 7. 15 llAO 0.0 o.o 0.0 o.o 0.0 0.0 o.o 0.0 NA20 7.90 7.03 7. 12 7.73 7.37 7.69 II. 04 6.99 1<20 o. 13 0.26 o. 17 0.16 0.23 0.10 0.21 o. 16 r 0.0 0.0 0.0 0.0 0.0 o.o 0.0 o.o Cl o.o 0.0 o.o o.o o.o 0.0 0.0 o.o SUM 101.1,3 911.911 911.47 98.16 98.72 98.96 98.60 98.34 -o-. f •CL 0.0 0.0 o.o 0.0 0.0 o.o 0.0 o.o SUH 101.111 98.98 98.47 98.16 98. 72 98.96 98.60 98.3"

SI 2.690 . 2.626 . 2.639 • 2.694 . 2.677 • 2. 713 • 2.739 • 2.660 • Ill. I.311 . 1.376 • 1.361 • 1.298 • 1.320 • 1,282 • 1.260 • 1. 346 • I I 0.000 Ii.Olli 0.001 11.003 o.o 3.999 0.001 3.993 0.001 3,9911 0.001 3.997 0.001 11.000 o.o 4.006 re 0.002 . 0.002 • 0.003 • 0.0 • 0.004 • 0.002 • 0.0011 • 0.001 • HN o.uoo . 0.000 • 0.0 • 0.001 . 0.001 • 0.000 • 0.000 • 0.001 . HG o.r, . 0.002 . O.J . o.o . o.o • 0.0 • o.o . 0.0 . CA 0.0 0.992 0.0 0.996 0.0 0.999 0.0 1.006 o.o 0.992 o.o 0.985 0.0 0.987 o.o 0.971 ...... BA 0.0 . 0.0 • 0.0 • o.o • o.o • 0.0 • 0.0 • o.o • ...... NA 0.672 . 0.615 • 0.626 • 0.680 • 0.645 • 0.669 • 0.701 • 0.613 • ~ I( 0.007 0.992 0.015 0.996 0.010 0,999 0.009 1.006 0.013 0.992 0.006 0.985 0.012 0.987 0.009 0.971 0 8.000 . 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • AN 3 I. 39 36.50 36.18 31. 50 33.32 31.32 27.38 35. 77 AB 67 .88 61.99 62.83 67 .58 65.34 68.10 71. 39 63.28 OR 0.73 I. 51 0.99 0.92 1. 34 0.511 1.23 0.95 CN 0.0 o.o o.o o.o o.o 0.0 o.o o.o

f/H o.o 1.125 o.o o.o o.o 0.0 0.0 0.0 f/rH 0.0 0.529 0.0 o.o o.o o.o 0.0 o.o 1 8A 3 !RAV X PLAC 58999 27299 5 511332 27124 2 58832 27255 6 57664 26950 3 58665 27212 7 57331 26863 4 581i99 27168 8 57927 270011

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sAHrLC 8,. fELDSPAR ANALYSES 25 ?.6 n 28 29 JO

Sl02 ~9. 19 60.1,3 60.71 60.42 62.17 58.68 I I 0~ 0.115 o.o•, O.Ol 0.02 o.or, o.o, "20) 25.07 23.61 23.79 24.17 25.30 23.04 r ro o.o,, O. II 0. Ill 0.08 0.13 0.03 HNO 0.21 o. 12 0.113 0.10 0.23 -0.02 HCO o.o O.Ol 0.07 0.02 0.05 -0.01 CAO 6.57 5.12 5.61 5. 111 1.09 4. 39 OAO 0.11 0.0 0.0 0.0 o.o 0.0 NA20 7.68 8.51 8.39 8.09 8.91 1.26 K?O o. 15 0.17 0.01 o. 19 0.30 0.08 I II.II 11.0 o.o 0.0 o.o 0.0 Cl 0.0 o.o 0.0 0.0 o.o 0.0 SIIH 98.96 98. Ill 99.211 98.811 104.21 93.118 •O• F+Cl 0.0 o.o o.o 0.0 o.o o.o SUH 98.96 98. 111 99.211 98.84 104.21 93.118

SI 2.667 . 2. 735 • 2. 7211 • 2. 717 • 2.675 • 2.763 • Al 1. Jll . 1.259 • 1.258 • I. 281 • 1.283 • 1.278 • JI 0.(102 l.999 0.001 J.996 0.001 J.983 0.001 J.998 0.001 3.959 0.000 II .OIi l r[ 0.0112 . 0.004 • 0.005 • 0.003 • 0.005 • 0.001 • HN 0.008 . 0.005 • 0.016 • o.ooi. • 0.008 • -0.001 • ..... ..... HG 0.0 . 0.002 • 0.005 • 0.001 • 0.003 • -0.001 • \J1 CA 0.0 I .006 0.0 1.016 0.0 l.OJO o.o 1.001 o.o 1.102 o.o 0.891 114 0.0 . o.o . 0.0 • 0.0 • 0.0 • o.o • NA 0.671 . 0. 1i.1 • 0.730 • 0.706 • 0.7 .. 3 • 0.665 • K 0.009 1.006 0.010 1.016 o.ooi. 1.0JO 0.011 1.001 0.017 1.102 0.005 0.891 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • AN l I .82 2i.. 71 26.87 27.83 30.07 24.811

AB 67. 3 I 7'-.32 72. 73 71.05 68.40 74.59 Oil 0.86 0.98 0.110 1. 12 1.53 0.57 CN o.o o.o 0.0 o.o 0.0 o.o F/H 0.0 11,330 4.613 5.675 4.233 2.810 r;rH 0.0 0.812 0.822 0,850 0.809 0.738

25 FURi 28 AVERAGE 26 FURi 29 AVERAGE PLUS SIGMA 27 fURI NEAR COG[FIHIS 30 AVERAGE HINUS SIGMA

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SAMPLE 8A FELDSPAR ANALYSES 1 2 3 4 5 6 7 8 SIC>? 6 I. 31, 58.21 58. 21 59.40 59.33 60.45 60.87 58. 77 110?. ll. 01 0.0-:! 0.0 0.011 0.03 0.03 · 0.02 0.0 Ai'OJ ;,; . 18 2~.1111 25.48 24.29 24.112 24.24 23. 76 25.23 r ro o.o~ o.o; 0.07 0.0 0.11 0.04 0. 11 0.02

rnlCl 0.111 (1.01 0.0 0.02 0.03 0.01 0.01 0.02 HCO u.o 0,0J o.o o.o o.o o.o o.o o.o CAO 6.61 1. 49 7 .112 6.52 6,80 6,110 5,58 7. 15 llAO o.u o.o o.o o.o o.o 0.0 0.0 o.o NA2U 7.90 7. OJ 7. 12 7.73 7.37 7.69 8.04 6.99 1<20 0. 13 0.26 o. 17 o. 16 0.23 0.10 0.21 0. 16 r o.u 0.0 o.o 0.0 0.0 0.0 0.0 o.o Cl 0.0 o.o 0.0 0.0 o.o o.o 0.0 0.0 SUM 101. IIJ 98.911 98,117 98, 16 98.72 98.96 98.60 98. 34 •Oc f +CL 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 SUM 101.1,J 98.98 98.47 98, 16 98.72 98.96 98.60 98,34 SI 2.690 . 2.626 . 2.639 . 2.694 . 2.677 • 2. 713 . 2.739 . 2.660 . Al. 1. 311 . 1,376 . 1.361 . 1.298 • 1.320 • 1.282 . 1.260 • 1.346 . TI U.000 11. 01)1 0.001 4.003 o.o 3.999 0.001 3.993 0.001 3.998 0.001 3. 997 0.001 4.000 0.0 4.006 FE 0.002 . 0.002 . 0.003 • 0.0 • 0.004 • 0.002 . 0.0011 . 0.001 . MN 0.000 . 0.000 • 0.0 . 0.001 . 0.001 • 0.000 . 0.000 . 0.001 MG o.n . 11.002 . 0.0 . o.o . o.o • 0.0 . o.o . 0.0 CA 0.0 0.992 0.0 0.996 0.0 0.999 0.0 1.006 0.0 0.992 o.o 0.985 0.0 0.987 0.0 0. 971

,_. BA o.o . 0.0 • 0.0 . o.o . 0.0 • 0.0 . 0.0 . 0.0 . ,_. NA 0.672 . 0.615 . 0.626 . 0.680 • 0.645 • 0.669 . 0.701 . 0.613 . °' K 0.0117 0.992 0.015 0.996 0.010 0.999 0.009 1.006 0.013 0,992 0.006 0.985 0.012 0.987 0.009 0.971 0 8.000 . 8.000 • 8.000 . 8.000 • 8,000 • 8.000 . 8.000 . 8.000 .

AN Jl.39 36.50 36. 18 31. 50 33.32 31. 32 27. 38 35. 77 AB 67 .88 61.99 62.83 67 ,58 65. 34 68. 10 71. 39 63.28 OR 0.73 1. 51 0.99 0.92 1. 34 0.58 1. 23 0.95 CN 0.0 0.0 0.0 0.0 o.o o.o 0.0 o.o F/M 0.0 1.125 0.0 o.o o.o o.o 0.0 0.0 f/FM 0.0 0,529 0.0 0.0 0.0 0.0 o.o 0.0

1 8A 3 TRAY X PLAG 58999 27299 5 58332 27124 2 58832 27255 6 57664 26950 3 58665 27212 7 57331 26863 4 58499 27168 8 57927 27009

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SAM rt [ 8A f[lOSPAR ANAlVS[S 9 ID 11 12 13 14 15 16 SI02 59.66 61. 41 61. 72 61.21 64.22 63. 15 58.27 62,95 110? 0.011 0.02 0.01 0.01 0.04 0.02 0.0 0.0 A;>O.l 211. / 3 24.09 23. 11 23.70 22.28 23. 11, 25. 10 22. 17 rto 0.011 U.U9 ll.09 0.05 0.04 0. 13 0.08 0.20 MNO 0.0 0.0 0.02 0.0 0.01 0.02 0.0 0. 14 MCO o.u 0.02 0.0 0.0 0.0 0.03 0.08 0.0 CAO 6.06 5. 71 11, 66 5.01 3.27 4. 18 7.03 3.46 llAO o.o 0.0 o.o 0.0 o.o 0.0 0.0 o.o NA20 7.57 7.96 8.68 8.41 9.62 9.47 7.46 9. 15 K20 0.18 0.28 o. 19 0.26 0.19 0.28 o. 10 0.62 f 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 Cl. 0.0 0.0 0.0 o.o 0.0 o.o o.o 0.0 SUM 98.28 99.58 98.48 98.65 99.67 100.42 98. 12 98.69 -0= f+Cl 0.0 0.0 o.o 0.0 0.0 0.0 0.0 0.0 SUM 98.28 99.58 98.118 98.65 99.67 100.42 98.12 98.69

SI 2.695 . 2.736 • 2. 775 . 2.750 • 2.840 • 2.787 • 2.650 . 2.824 . Al I. 316 . 1.265 • 1.224 • 1.255 • 1. 161 • 1.204 . 1.345 . 1.172 • TI 0.001 4.013 0.001 11,001 0.000 4.000 0.000 4.005 0.001 4.003 0.001 3.991 o.o 3.995 o.o 3.995 re 0.002 . 0.003 • 0.003 • 0.002 • 0.001 • 0.005 • 0.003 • 0.008 . MN 0.0 • 0.0 . 0.001 • 0.0 . 0.000 • 0.001 . 0.0 . 0.005 . ...... tlC 0.0 . 0.001 • 0.0 . 0.0 • 0.0 • 0.002 • 0.005 . 0.0 • ...... CA 0.0 0.968 o.o 0.981 0.0 0,996 0.0 0.990 0.0 0.992 o.o 1.031 0.0 1,014 o.o 1.010 ......., 8A o.o • o.o • 0.0 • o.o • 0.0 • o.o . 0.0 . 0.0 . NA 0.663 . 0.688 • 0.7!:,7 . 0.733 • 0.825 • 0.810 . 0.658 . o. 796 . K 0.010 0.968 0.016 0.981 0.011 0.996 0.015 0,990 0.011 0,992 0.016 1.031 0.006 1,014 0.035 1.010 0 8.000 • 8.000 • 8.000 • 8.000 . 8.000 • 8.000 • 8.000 • 8.000 .

AN 30. 34 27 .93 22.63 211. 39 15.64 19.31 34.05 16.67 AB 68.59 70.44 76.27 74 .10 83.28 79. 15 65.38 79. 77 OR I. 07 1.63 I. 10 1.51 1.08 1.54 0.58 3. 56 CH 0.0 0.0 o.o 0.0 o.o o.o o.o 0.0 f/M 0.0 2.525 0.0 0.0 o.o 2.810 0.561 0.0 f/fH 0.0 0.716 0.0 o.o o.o o. 738 0.359 0.0

9 58202 26677 13 HI SC PLAG 10 58340 26511 14 MISC PLAG 11 581109 26428 15 8A Pl CORE FINIS 12 5S477 26346 16 TWO RIM

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SAHPL[ 8A r£L0SPAR ANALYS[S 11 18 19 20 21 22 23 24 S102 62. 19 61.82 60.20 511.78 58.99 62.56 59.55 57.21 T 102 0.06 0.0 0.01 o.o 0.04 0.04 0.03 0.03 A20] 21.98 22.64 24.01 24.89 25.20 23.23 24.56 26.2& rco 0.01 0.07 0.10 O. T2 0.06 o.o o. T7 0.05 HHO 0.211 0.23 0.16 0.42 0. T 1 o. T7 0.15 0.24 HGO 0.0 0.06 0.02 0.04 0.0 0.0 o.o o. 11 CAO 3. 19 4.21 5.90 6.58 6.61 3.63 6. 15 7.98 BAO 0.0 0.0 0.0 0.0 o.o o.o 0.0 o.o NA20 9.,,8 8.87 7.80 7.68 7.63 9.59 7.82 6.90 KZO 0.111 0.29 o. 30 0.06 0.21 0.06 0.09 o. u r 0.0 o.o o.o o.o o.o 0.0 o.o o.o CL o.o 0.0 0.0 o.o o.o 0.0 0.0 o.o SUH 98.0] 98. 19 98.50 98.57 98.115 99.28 98.52 98.93 -0• r+CL 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 SUH 911.0] 98. 19 98.50 98.57 98.85 99.211 98.52 98.93

SI 2.1129 . 2.7119 • 2.7111 • 2.662 • 2.661 • 2.7116 • 2.690 • 2.591 • AL 1. 167 • 1.204 • 1.277 • 1. 3211 • 1. 339 • 1.219 • 1.308 • 1.402 • Tl 0.002 ],9911 o.o 3.993 0.000 3.996 o.o 3.991 0.001 4.002 0.001 4.007 0.001 3,999 0.001 3.994 re 0.003 . 0.003 • 0.004 • 0.005 • 0.002 • 0.0 • 0.006 • 0.002 • ..... HH 0.011 . 0.009 • 0.006 • 0.016 • 0.004 • 0.006 • 0.006 • 0.009 • ..... HG 0.0 • 0.004 • 0.001 • 0.003 • 0.0 • 0.0 • 0.0 • 0.007 • 00 CA 0.0 1.006 o.o 1.012 0.0 0.991 o.o 1.021 0.0 1.005 0.0 1.011 o.o 1.000 0.0 1.019 BA 0.0 • 0.0 • 0.0 • o.o . o.o • 0.0 • 0.0 • o.o • HA 0.828 • o. 776 • 0.683 • 0.674 • 0.667 • 0.8211 • 0.685 • 0.606 • K 0.010 1.006 O.OT7 1.012 0.017 D.997 0.003 1.021 0.012 1.005 0.003 1.011 0.005 1.000 0.0011 1.019 0 8.000 • 11.000 . 11.000 . 11.000 • 8.000 • 8.000 • 8.000 • 11.000 • AN 15.52 20.43 211.96 32.02 31.911 17 .24 30. 14 311.70 AB 83.44 77 .89 69.29 67.63 66.81 82.42 69.34 60.55 OR 1. 04 1.68 1. 75 0.35 1.21 o. 34 0.52 0.75 CH 0.0 0.0 0.0 0.0 o.o o.o o.o o.o F/H o.o 2.833 7.351 7.650 o.o 2.810 0.561 1.495 r;rH 0.0 0.739 0.1180 '0.884 o.o 0.7311 0.359 0,599

17 R IH 21 FUR 18 TWO COR[ 22 FURT 19 SAM[ 23 FURT 20 FURTH 211 FURT

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S/\HPL[ 8A rCLOSPAR ANALYSES 25 26 27 211 29 30

Sl02 59. 19 60.1,3 60.71 60.42 62.17 511,611 J 10;:.' O,ll'.> 0.0•1 0.03 0.02 0,04 0.01 1\20] 25.07 23.61 23.79 24.17 25.JO 23.04 rro o.o,, O. II o. 14 0.011 0.13 0,03 HNO 0.21 0.12 0.43 0.10 0.23 -0.02 HGO 0.(1 0,0J 0.01 0.02 0.05 -0.01 CAO 6. ';1 5. 12 5.61 5. 74 7.09 4.39 0110 o.n o.o 0.0 o.o 0.0 o.o Nll?.O 7.611 11.51 11. 39 11.09 11.91 7 .211 k?O o. 15 o. 17 0.07 0.19 0.30 0.011 I 11,ll 0.0 o.o o.o o.o o.o CL 0.0 o.o 0.0 o.o o.o 0.0 SUH 98.96 98. 14 99.211 911.84 104.21 93.41 •O: r+CL 0.0 o.o o.o o.o o.o 0.0 SUH 98.96 98.14 99.24 911.84 104.21 93.48

SI 2.667 . 2,735 • 2,724 • 2,717 • 2.675 • 2,763 • AL 1.331 • 1.259 • 1.258 • 1.281 • 1.283 • 1,278 • II 0.002 3.999 0.001 J,996 0.001 l, 9113 0.001 3.991 0.001 3,959 0.000 11.0111 re O.Otl2 . 0.0011 • 0.005 • 0.003 • 0.005 • 0.001 • ...... HN 0.0011 . 0.005 • 0,016 • 0.004 • 0.0011 • -0.001 • ...... · HG 0.0 . 0.002 • 0.005 • 0.001 • 0.003 • -0.001 • '° CA 0.0 1.006 0.0 1.016 0.0 1.030 0.0 1.001 o.o 1,102 o.o 0.891 HA 0.0 . o.o • o.o • 0.0 • o.o • o.o . IIA 0.671 . 0. 747 . 0.730 • 0.706 • 0.743 • 0.665 • k 0.009 1.006 0.010 1.016 0.004 1.030 0.011 1.001 0.017 1.102 0.005 0.1191 0 8.000 . 8.000 • 8.000 • 11.000 • 8.000 • 8.000 • AN 31.82 211. 71 26.117 27 .113 30.07 211.811 AB 67.31 711. 32 72. 73 71.05 611.110 711.59 011 0.86 0.98 0.110 1. 12 1.53 0.57 CN o.o o.o 0.0 0.0 o.o o.o

r/H 0.0 4.330 4.613 5.675 11.233 2,810 r/FH 0.0 0.812 0.822 0.1150 0.809 0,738 25 FURi 211 AVCRACC 26 FURi 29 AVCRACC PLUS SIGMA 27 FURi NEAR EOGEFINIS 30 AVCRACC HINUS SICHA

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SMIPL[ 8A FELDSPAR ANALYS[S 1 2 3 4 5 6 7

SID2 62. 75 64.97 64.29 64.72 64. 111 65.04 63.32 r 102 o.o~ 0.01, O.D6 0.05 0.05 0.06 0.04 A20J 18.26 18.118 17.96 17 ,87 18.24 111.611 17.85 rro 0.02 0.07 0.02 0.09 0.05 C.08 0.02 HNO 0.0 0,01 o.o 0.03 0.01 0.02 -o.oo HGO 0.0 0.0 0.0 O.D1 0.00 0.01 -o.oo CAO 0. 12 0.011 0.12 0.20 0.12 0.18 0.06 IIAO o.o o.o 0.0 o.o o.o o.o 0.0 NA20 O.lo9 0.58 0.55 1. 17 o. 70 0.97 0. 42 K20 15.01 15.48 15. 37 14.61 15.12 15.46 14.78 r 0.0 0.0 o.o o.o 0.0 o.o o.o CL 0.0 0.0 0.0 0.0 0.0 o.o 0.0 SUH 96.70 100.07 911. 37 98.75 98.47 100.46 96. 49 -0= r•CL 0.0 0.0 0.0 o.o 0.0 0.0 o.o SUH 96.70 100.07 98.37 98.75 98.47 100,46 96.49

SI 2.987 . 2.988 . 3.009 • 3.012 • 2.999 • 2.987 . 3.012 • AL 1.021, . 1.02] . 0.991 • 0.980 • 1.004 • 1.008 • 1,000 • I I 0.002 4.01] 0.001 4.013 0.002 4.002 0.002 3.994 0.002 11.005 0.002 3.997 0.002 4.014 f( 0.001 . 0.003 . 0.001 . 0.004 • 0.002 • 0.003 • 0.001 • HN 0.0 . 0.000 . o.o . 0.001 • 0.000 • 0.001 . -0.000 . -HG 0.0 . 0.0 . 0.0 . 0.001 . 0.000 • 0.000 • -0.000 . N CA 0.ll 0.96] 0.0 0.965 0.0 0.9l4 0.0 0.988 0.0 0.973 0.0 1.005 o.o 0.939 0 DA 0.0 . 0.0 . 0.0 . 0.0 • o.o • 0.0 • o.o . NA 0.045 . 0.052 . 0.050 . 0.106 • 0.06] • 0.087 . 0.039 . K 0. 911 0.963 Cl.908 0.965 0.918 0.974 0.867 0.988 0.901 0.973 0.905 1.00~ 0.897 0.939 0 8.000 . 8.000 . 8.000 • 8.000 • 8,000 • 8.000 . 8.000 .

AN 0.64 0.20 0.62 1,01 0.62 0.87 o. 34 AB 11. 70 5.38 5. 13 10.74 6.51 8.65 4.15 OR 94.67 94.42 94.25 88.24 92.87 90.48 95.50 CPI o.o o.o o.o 0.0 0.0 0.0 o.o F/H 0.0 4. JJO 4. 613 6. 7511 13. 495 8.1190 0.561 F/FH 0.0 0.812 0.822 0.871 0.931 0.895 o. 359

I 8A 5 KSP 5 AV[RAG[ 2 8A 5 KSP 6. AVERAGE PLUS SIGMA 3 8A 5 ~SP 4 8A 5 KSP

7 AVERAGE MINUS SIGMA

Page 126: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPl[ 6A I

5102 36.1111 1102 J.~9 A?03 I 3. 76 fEO 18. 75 HNO I. 12 HGO 12. '.,2 CAO 0.03 OAO 0.0 NA20 0.26 k20 6.61 r 0.0 CL o.o 1120 0.0 SUH 95.60 -0= r+CL 0.0 SUH 95.60

SI 5.605 . AL 2. 395 8.000 AL 0.010 . 11 0.410 . f[ 2.383 . ~IN 0. 144 . HG 2.8)6 5.844 CA 0.005 . NA 0.083 . k 1. 720 . UA 0.0 1.807 CL o.o . f 0.0 • II 0.0 0.0 0 22.000 .

r/H 0.691 r;rH 0.471

81

BIOTll[ ANALYSES 2

35.98 3.66

14.24 16.36 0.93

11. 68 0.06 0.0 0. 17 8.67 0.0 0.0 o.o

94. 15 o.o

911. 15

5.5'.'>9 . 2.441 8.000 o. 152 . 0.1,25 . 2.372 . 0. 122 . 2.736 5.808 0.010 • 0.051 • 1. 748 • o.o 1.809 o.o • 0.0 . o.o o.o

22.000 . 0.912 0.477

2 SAHE GRAINFINIS

..... N .....

Page 127: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIHPL[ 9A BIOTIT[ ANALYS[S 1 2 J 11 5 6 1 8

SI02 J6.82 J5.22 J5.92 35.60 36.23 36. 75 35.80 36. 36 r 102 11. 21 •1.02 11.18 Ii. 30 11. 33 Ii. 7.8 3 .80 3.39 A?.03 14. 18 14.01 14.112 14.00 14.62 15. 18 14.95 111.62 f[O 21. 71 21. 78 21. 32 21.20 21.69 21. 56 22.08 22.21 MIIO 0.55 0.50 0.50 0.53 0.60 0.511 0.55 0.58 MGO 9 ... 6 9.60 9.07 9. 39 9.63 9.01 9. J8 10. 16 C:110 o. 10 0.11 0. 12 0.11 0.01 0.06 0. 17 0.18 0110 o.o o.o 0.0 o.o 0.0 0.0 o.o o.o N/120 0.2?. o. , .. U.22 0.20 0. 11 0.22 0.25 0.19 K?.O 9.011 9.11 9.19 9.06 9.35 9. 27. 9.21 9.00 r 0.0 o.o 0.0 0.0 0.0 0.0 o.o 0.0 Cl 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0 11?0 0.0 o.o 0.0 0.0 0.0 0.0 0.0 o.o SUH 96.35 911. 1,9 911. 911 9r,.J9 96.63 96.82 96. 19 96.69 -0° f +Cl. 0.0 o.o 0.0 0.0 0.0 0.0 o.o 0.0 SUH 96. 35 91,.r,9 94.911 911.]9 96.6] 96.112 96.19 96.69 ,_.

SI 5.62/ . 5.524 . 5.581 . 5. 561 • 5.5J6 • 5.581 • 5.509 . 5.555 . N Al 7.. JI 1 8.000 7 ... 16 8.UOO 2.419 8.000 2.1133 8.000 2.4611 8.000 2.q19 8.000 2.491 8.000 :.>.1i115 8.000 N Ill u. 181 . 0. 1 IJ . 0.221 • 0. 1r,7 • 0.169 • 0.298 . 0.220 • 0. 187 • II o.r,91 . O.lf7q • o.r,e8 • 0.506 • 0.498 • 0.489 • O.lfqO . 0. 389 • . re 2. 775 • 2.857 • 2. 770 • 2. 772 • 2. 772 • 2. 738 • 2.8112 . 2.838 . Hfi 0.011 • 0.066 • 0.066 • 0.070 • 0.078 • 0.069 . 0.072 . 0.075 • MG 2. 155 5.67] 2.2 .. 11 5.7511 2. 100 5.645 2. 189 5.683 2. 193 5. 709 2.040 5.6311 2. 151 5.724 2. 314 5.803 CA 0.016 . 0.018 • 0.020 • 0.018 • 0.011 • 0.010 • 0.028 • 0.029 • NA 0.065 • o.or,J • 0.066 • 0.061 • 0.033 • 0.065 • 0.075 • 0.056 • K 1. 762 . 1.822 . 1.821 • 1. 807 • 1.822 • 1. 786 • 1.808 • 1. 75r, • 011 u.o 1.81111 0.0 1.883 0.0 1.907 0.0 1.886 0.0 1.866 0.0 1.861 0.0 1. 910 0.0 1.8•10 Cl 0.0 . 0.0 • o.o • o.o • o.o • 0.0 • 0.0 • o.o . r u.n • o.o • o.o • 0.0 • 0.0 . 0.0 • 0.0 . 0.0 • 11 0.0 0.0 o.o 0.0 0.0 0.0 o.o o.o 0.0 0.0 o.o o.o 0.0 0.0 o.o 0.0 0 7.7..000 • 22.000 . 22.000 • 22.000 • 22 •• 000 • 22.000 • 22.000 • 22.000 •

f/H I. J?.1 1. 30J 1. 350 1.299 1.299 1. J77 1. 35r, 1.259 f/lH 0.569 0.566 0.575 0.565 0.565 0.579 0.575 0.551

1 911 r, DI 5 9A Ii NOTH[R BT 2 9A ~ OT SIIH[ GRAIN 6 SAHE GRAIN J SAHE GRIIIN 7 9A II OPEN SEARCl1 BT r, SAHi' GRAIN 8 SAHE GRAIN

Page 128: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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SI\HPL[ 91\ rcLOSPAR ANALYSES 9 10 11 12 13 111 15 16

Sl02 59.811 59.66 60.117 57.63 511.80 56.02 60. 37 60. 78 1102 O.OJ 0.03 0.03 0.05 0.04 0.04 0.05 0.02 A?.03 211. 19 25.20 211. 20 27 .06 27.52 26. 75 23. 82 24.211 rtO 11.04 0.02 0. 14 0.10 0.26 0.08 0.09 0.02 ~1110 0.02 o.o 0.02 o.o 0.0 0.02 0.0 0.01 HGO o.o 0.0 o.o o.o o.o o.o 0.0 0.0 CAO 6.110 6.60 6.40 8.65 10.114 9. 16 6.23 6.35 RAO 0.0 0.0 o.o o.o o.o o.o o.o 0.0 Nl\20 7.78 7.61 7.58 6.48 4.96 6.12 7.58 7 .61 K20 0.20 0. 13 0.24 0.17 0.21 0. 14 0.21 0.24 r 0.0 o.o o.o o.o 0.0 0.0 0.0 0.0 CL 0.11 0.0 0.0 o.o 0.0 o.o o.o o.o SUH 98.50 99.25 99.08 100.14 98.23 98.33 98. 35 99.33 -o= r+ct. o.o o.o o.o 0.0 o.o 0.0 0.0 0.0 SUH 98.50 99.25 99.08 100. 14 98.23 98.33 98.35 99. 33 .....

SI 2. 7011 . 2.6111 . 2. 7111 • 2. 577 • 2.510 • 2.556 • 2. 726 • 2. 718 • N I\L 1.288 . I. 331 • 1.280 • 1.426 • 1.485 . 1.1138 • 1.267 • 1. 278 • u, TI 0,001 3.992 0.001 4.006 0.001 3.994 0.002 4.004 0.001 3 .997 0.001 3.996 0.002 3.995 0.001 3.997 re 0.002 . 0.001 • 0.005 • 0.004 • 0.010 • 0.003 • O.OOJ • 0.001 • HN 0.001 . 0.0 • 0.001 • 0.0 • o.o • 0.001 • o.o • 0.000 • HG 0.0 . o.o • 0.0 • o.o • 0.0 • o.o • o.o • 0.0 • CA (I, 310 . 0. 317 • o. 308 . 0.4111 • 0.512 • 0.448 . 0.301 • o. 304 • BA 0.0 • 0.0 • o.o • 0.0 • 0.0 • 0.0 • o.o • 0.0 • NA 0.681 • 0.661 • 0.660 • 0.562 • 0.440 • 0.541 • 0.6611 • 0.665 • K 0.012 1.005 0.007 0.987 0.014 0.987 0.010 0.990 0.012 0.975 0.008 1. 001 0.012 0.981 0.014 0.984 0 8.000 • 8.000 . 8.000 • 11.000 • 8.000 • 8.000 • 8.000 • 11.000 .

AN 30.89 32. 15 31. 37 112.03 53.09 44.90 30.85 30.95 AR 67 .96 67 .09 67. 2l 56.98 45.64 54.28 67.92 67 .65 OR 1. 15 0.75 1.40 0.911 1. 27 0.82 1.24 1. 39 CN 0.0 0.0 0.0 o.o o.o 0.0 0.0 0.0

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9 GROUP 2 T-RI\V SAHE GRAIN 27694 7541 13 28235 7261 10 279611 740 I 14 28325 7214 11 280511 7 354 15 28415 7168 12 211145 7307 16 28505 7121

Page 131: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

S/IHPI.[ 9A f[lDSPAR ANALYSES 11 18 19 20 21 22 2] 24

S102 59. 13 62. 19 51,66 57.87 60.01 61. 16 51.84 58.112 1102 0.011 0.02 0.02 o.o 0.03 o.o 0.01 0.02 11203 25.119 23.41 25.95 25.52 24.68 211. 10 25. 16 27 .21 rco 0.04 0.05 0.08 o. 11 .0.10 o. 15 o. 13 0.13 MNO 0.0 0.02 0.03 0.02 o.o 0.01 0.011 o.o HGO 0.0 o.o o.o 0.0 0.0 o.o 0.0 0.03 CAO 6. 19 5. 11 1.96 7.53 6.34 5.20 8. 311 9.21 0110 o.o 0.0 0.0 0.11 0.0 0.0 0.0 o.o NA20 , • 70 8.66 6.78 7 .0l 7.74 11.06 6. 45 6.19 1<?0 0.08 0.12 0.22 0.22 0. 14 0.56 0.23 0.18 r o.o o.o o.o 0.0 0.0 0.0 0.0 0.0 Cl. o.o 0.0 0.0 o.o 0.0 0.0 0.0 o.o SUM 99.27 99.611 98.70 98. 30 99.011 99.24 98.82 100.99 -0= f+Cl o.o 0.0 0.0 o.o 0.0 0.0 0.0 0.0 SUH 99.21 99.611 98.70 98.30 99.04 99.24 98.82 100.99

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AN ]2.61 211.64 38.85 36.71 30.91 25.43 41. 11 1111.65 /18 66.93 74.68 59.88 62.02 68.28 71.31 57. 511 54. J 1 OR 0.46 0.68 1.28 1.28 0.81 3.26 I. 35 1.04 CH 0.0 o.o 0.0 o.o o.o 0.0 0.0 0.0

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17 9112 IHAV X PlAG 20681 10977 21 1971i6 18 2031)1 10977 22 20612 9A 2 NOTIICR TR/IV X Pl.AG( SAM[ Pl 19 20120 23 20619 10585 20 199JJ 211 206211 10883

Page 132: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIHl'Lf 9A r[LOSPAR ANALYSES 25 26 27 28 29 30 31 32

5102 60.61 55. 12 61.0l 61. JO 60.85 59.112 61. 27 57. 57 r 102 0.02 0.03 0.03 0.01 0.01 0.03 0.011 0.01 1120] 2].81 26.26 23. 711 23.98 211.81 211.96 ?6. 1J 23.78 HO 0.05 0. 73 0.11 0.011 0.0 O. l l 0.211 -0.02 ~lllO 0.02 0.06 0.02 0.0] 0.0 0.01 0.03 -o.oo HGO O.il o.o 0.0 0.0 o.o 0.00 0.01 -o.oo C:110 6.08 10. 39 6.07 5.79 6.02 6.911 8.110 5.118 RAO o.o o.o 0.0 o.o 0.0 0.0 o.o 0.0 ll1120 l.68 5.63 7 .89 8. 19 7.92 7 .115 8. 311 6.56 K20 0.05 0.21 0.211 o. 16 o. 15 0.19 0.28 0.10 r 0.0 0.0 0.0 o.o o.o 0.0 0.0 0.0 Cl. o.o o.o 0.0 o.o 0.0 0.0 0.0 0.0 SUH 96.56 96.113 99. l 1 99.50 99.76 99.10 1011. 73 93.118 -0° F+Cl o.o o.o 0.0 o.o 0.0 0.0 0.0 o.o SUH 96.56 96.113 99.11 99.50 99. 76 99.10 1011. 73 93.118

SI 2. 731 . 2. 533 . 2. 735 . 2. 735 • 2.707 • 2.672 • 2.631 • 2.718 • Ill 1.26] . 1.1122 . 1.2511 • 1.261 • 1. 301 • 1.323 • 1.322 • 1. 323 • -TI 0.001 3.995 0.001 3.956 0.001 3.990 0.000 3.996 0.000 11.008 0.001 3.996 0.001 l.955 0.000 "· 0111 N rr 0.002 . 0.028 • 0.0011 • 0.001 • o.o • 0.0011 • 0.009 • -0.001 • -...J HN 0.001 . 0.002 • 0.001 • 0.001 • 0.0 • 0.001 • 0.001 • -0.000 • . HG 0.0 . o.o • 0.0 . o.o • 0.0 • 0.000 • 0.000 • -0.000 • CA 0.29] • 0.512 • 0.292 • 0.277 • 0.287 • O.Jlll • 0. 386 • 0.277 • HA 0.0 . 0.0 • o.o • 0.0 • 0.0 • 0.0 • o.o • 0.0 • NA 0.666 . 0.502 • 0.666 . 0.708 • 0.683 • 0.6119 • 0.6911 . 0.600 • K 0.003 0.967 0.012 l.056 0.014 0.996 0.009 0.997 0.009 0.979 0.011 0.999 0.015 1. 106 0.006 0.8112 0 6.000 . 8.000 • 8.000 • 11.000 • 11.000 • 8.000 • 11.000 • 11.000 .

AN 29.81 119.86 29.112 27.811 29. 32 33.61 35.25 J l. 311 110 69.90 1111.91 69.20 71.25 69.61 65.31 63.37 67 .96 OR 0.29 1.20 1. 311 0.92 0.87 1.08 l. 39 0.66 CN 0.0 0.0 o.o 0.0 0.0 o.o 0.0 o.o

f/H 0.0 0.0 0.0 o.o 0.0 6 7. 238 23.0119 2. Ill 1 r;rH 0.0 0.0 0.0 o.o 0.0 0.965 0.958 0. 709

25 20626 11032 29 20638 11776 26 20629 11161 30 AVERAGE 21 20631 11330 JI AVERAGE PLUS SlGHI\ 28 7.0636 11627 32 AVERAGE MINUS SIGMA

Page 133: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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Page 134: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPLE 17 810TIH ANALYSES 1 2 J 4 5 6 1

Sl02 J8.0J J7 .60 J7 .4J 36.97 J7. 51 37.89 J7.1J 1102 11. IU J .92 J.5J 3.48 J. 16 11.02 J. 50 A20J 111. 26 14.60 14.16 14.16 14.29 14.48 14. 11 HO 17.35 16.88 17.JO 16.911 17. 12 17. JJ 16.91 ~INO 0.28 o. JJ 0.26 0.2J 0.27 O.Jl 0.24 11GO lJ.1111 IJ.02 12.85 12.57 12.97 1 J.29 12.65 CAO 0.07 0.07 0.06 0.05 0.06 0.07 0.05 RAO o.o 0.0 0.40 O.J5 0.19 o. J8 -0.00 NA?O o. 12 o. 16 o. 16 0.20 0.16 0.19 0. 1J k20 8. 911 8. 8J 9.05 8.92 8.94 9.0J 8.86 r IJ.O o.o 0.50 0.54 0.26 0.52 -o.oo Cl 0.0 0.0 0.04 O.OJ 0.02 0.04 -o.oo 1170 0.0 0.0 -0.25 -0.26 -0.lJ -0.25 0.00 SUH 96.6J 95.41 95.49 94.18 95.43 91.21 9J. 59 -o.a r+Cl. o.o 0.0 0.22 0.2J o. 11 0.2J -o.oo SUH 96.6J 95.41 95.27 93.94 95.31 97.04 93.59

...... SI 5.6118 . 5.643 . 5.639 • 5.638 • 5.642 • 5.595 • 5.691 . N Al. 2. 352 8.000 2.357 8.000 2.361 8.000 2.362 8.000 2.J58 8.000 2.405 8.UOO 2. JU9 8.000 '° Al. 0. 1113 • 0.226 • 0. 153 • o. 182 • 0.176 • o. 113 • 0.241 • TI 0.1158 . 0.442 • 0.400 • 0.399 • 0.425 • 0.446 . 0.40J • re 2. 1~5 . 2. 119 • 2.180 • 2. 160 • 2. 153 • 2.1110 • 2. 168 • HN U.OJ5 • 0.0112 . O.OJJ • O.OJO • 0.035 • 0.039 • O.OJI • HG 2.9T5 5.766 2.913 5.741 2.886 5.652 2.857 5.629 2.908 5.697 2.924 5.662 2.891 5. 734 CA 0.011 • 0.011 • 0.010 • 0.008 • 0.010 • 0.011 • 0.009 • NA O.OJ5 . 0.0111 • 0.047 • 0.059 • 0.047 • 0.054 . 0.039 . I( 1. 701 . 1.690 . 1. 739 • 1. 735 • 1. 716 • 1. 700 • 1. 7JJ • !IA O.ll I. T41 o.o 1. 748 0.024 1.819 0.021 1.823 0.011 1.784 0.022 1. 181 -0.000 1. 781 Cl u.o • (J.0 • 0.010 • 0.008 . 0.004 • 0.009 • -0.000 • r ().(I . IJ.O • 0.238 • 0.260 . o. 124 • 0.243 . -0.000 • II 0.0 0.0 0.0 0.0 -0.2118 0.0 -0.268 o.o -o. 128 0.0 -0.252 0.0 0.000 0.0 0 ?.2.000 . 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 .

F/H 0.736 0. 742 0.767 0.767 0.753 o. 745 0. 760 r/FH 0.424 0.426 0.434 0.434 0.429 0.427 0.432

I 178 FR[[ BT 5 AVERAGE 2 178 FR[[ BT 6 AVERAGE PLUS SIGMA J 17 fRH DI 7 AVERAGE MINUS SIC.HA 4 SAH[ GRAIN

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SAHPL[ II FELDSPAR ANALYSlS 1 2 ) 4 5 6 1 8

5107 61. l I 60.02 68. )II 61.27 58. 76 58.64 59. 72 57 .68 r 102 0.011 0.01 0.04 0,0) 0.02 0.0) 0.02 0.0) A20l 24.57 24.60 20. 18 23.44 25.60 26. 38 26.09 26.59 HO 0.05 0.08 0.02 0.07 0.05 0.11 0.06 0.11 Hl40 0.0 0.01 0.0 0.03 o. 32 0.31 0.54 0. 3l HGO 0.09 0.04 0.0 0.16 0.0 0.02 0.03 o.o CAO 5.88 6.21 0.62 5.52 7.69 7.85 7 .62 8.07 BAO o.o 0.0 0.0 0.0 0.0 0.0 0.0 0.0 NA20 8.05 7. 77 10.99 7.82 7.14 7 .06 7.36 7 .02 K20 0.24 0.27 0. 11 0.29 0.18 o. 13 0.16 0.20 r 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Cl 0.0 o.o 0.0 0.0 o.o 0.0 0.0 o.o SUH 100.23 99.01 100.30 98.63 99.76 100.53 101. 60 100.03 -Os f+CL 0.0 0.0 o.o 0.0 o.o 0.0 0.0 o.o SUH 100.23 99.01 100.30 98.63 99.76 100.53 101.60 100.03

SI 2.716 . 2.697 . 2.974 • 2.753 . 2.635 • 2.611 . 2.631 • 2.587 • AL 1.283 . 1. 303 • 1.035 • 1. 241 • 1.353 • 1.)84 • 1. 355 • 1. 405 • ..... TI 0.001 4.001 0.000 4.000 0.001 4.010 0.001 3.995 0.001 3.988 0.001 3.996 0.001 3.9117 0.001 3.993 w rr 0.002 • 0.003 • 0.001 • 0.003 • 0.002 • 0.0011 . 0.002 • 0.001, • 0 HN o.o . 0.000 . 0.0 • 0.001 • 0.012 • 0.012 • 0.020 • 0.013 • HG 0.006 • 0.003 • o.o • 0.011 • 0.0 • 0.001 • 0.002 • o.o • CA 0.0 0.992 0.0 0.997 o.o 0.963 0.0 0.978 o.o 1.015 0.0 1.008 0.0 1.022 0.0 1.026 BA o.o . o.o • o.o • 0.0 • o.o • 0.0 • 0.0 • 0.0 • NA 0.692 • 0.677 • 0.927 • 0.681 • 0.621 • 0.609 . 0.629 . 0.610 • K 0.014 0.992 0.015 0.997 0.006 0.963 0.017 0.978 0.010 1.015 0.007 1.008 0.009 1.022 0.011 1.026 0 8.000 • 8.000 • 8.000 • II.ODO • 11.000 . 8.000 • 8.000 . 8.000 •

AN 28.36 30. 16 3.00 27. 58 36.93 37. 78 36.06 38.41 AO 70.26 68.28 96. 36 70. 70 62.04 61.48 63.03 60.46 Oil 1. 38 1.56 0.63 1. 72 1.03 0. 11, 0.90 1. I 3 CN 0.0 o.o 0.0 0.0 o.o o.o 0.0 o.o f/H 0.312 1.264 0.0 o. 352 o.o 11.8911 11. 351 0.0 f/FH 0.238 0.558 o.o 0.260 o.o 0.92?. 0.919 0.0

I 178 PtAG 5 Pl CORCFINIS 2 178 Pl.AG 6 TOW RIH 3 178 PLAG 7 BETTER COR[ 4 178 PLAG 8 BETTER CORE

Page 136: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAMPLE 17 r£LD5PAR ANALYS£S 9 10 11 12 13 111 15 16

SI02 57. 69 60. 36 59.20 59.52 59. 16 54.60 56.50 59. 17 f102 0.03 0.02 0.03 0.011 0.03 0.05 0.05 0.03 J\?03 26.96 25. 12 211.92 25.08 25.116 27.57 :?5.99 24.85 flO 0.03 0.111 0.06 0.09 0.07 0.09 0.03 0.02 HNO 0.26 0.18 0.0 0. 15 0.28 0.37 0.25 0.59 HGO o.o 0.0 0.0 o.o 0.0 0.0 0.07 0.01 CAO 6.82 6. 38 6.48 6.118 7.01 9.86 7 .112 6,118 BAO 0.0 o.o 0.0 0.0 o.o 0.0 0.0 0.0 NA20 6.61 7.85 7 .911 7.8J 7.63 6. 13 1. 31 1.90 1<20 0.09 0.27 0.21 0.28 0.29 0. 19 0.26 0.21 f 0.0 0.0 0.0 0.0 0.0 0.0 0.0 o.o Cl o.o 0.0 0.0 0.0 0.0 o.o 0.0 0.0 SUH 100. 77 100.21 98.811 99.51 99.93 96.86 99.88 99.26 -0= f+GL 0.0 0.0 0.0 0.0 0.0 0.0 o.o o.o SUM 100. 77 100.21 98.811 99.51 99.93 98.86 99.88 99.26

SI 2.516 . 2.6811 • 2.671 • 2.669 • 2.6117 • 2.1195 . 2.621 • 2.665 • AL 1. 1115 . 1. 316 . 1.325 . 1.325 • 1.3113 • 1. 1165 • 1. 372 • 1. 319 • ...... II 0.001 3.992 0.001 11.000 0.001 3.996 0.001 3.996 0.001 3.991 0.002 3. 962 0.002 3,9911 0.001 3.986 (;.)

ff 0.001 • 0.000 • 0.002 • 0.003 • 0.003 • 0.003 • 0.001 • 0.001 • ...... HN 0.1110 . 11.001 • 0.0 • 0.006 • 0.011 • 0.0111 • 0.009 • 0.023 • . HG o.o . 0.0 . o.o • o.o • o.o . 0.0 • 0.005 • 0.001 . CA 0.0 1.012 0.0 1 .003 0.0 1.022 0.0 1.021 o.o 1 .028 0.0 1.055 0.0 1.021 0.0 1.039 DA 0.0 • o.o • o.o • o.o • 0.0 • 0.0 • 0.0 • 0.0 • NA 0.516 . 0.676 . 0.6911 . 0.6811 • 0.662 • 0. 5113 • 0.635 . 0.690 • I< 0.005 1.012 0.015 1.00] 0.012 1.022 0.016 1.021 0.017 1.028 0.011 1 .055 0.015 1.021 0.012 1.039 0 8.000 . 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 •

AN 112.01 30.52 JO. 71 30. 76 Jl. 12 116.56 35.110 30.82 AR 57 .116 67 .95 66. 10 67.64 65.211 52: 38 63. 12 61.99 OR 0.51 1. 511 1. 18 1. 58 1 .63 1.07 1.118 1. 19 CN 0.0 o.o 0.0 0.0 o.o 0.0 0.0 0.0

f/M o. ]12 1 .2611 0.0 o. 352 o.o 11. 8911 2.270 311.650 f/fH 0.238 0.558 o.o 0.260 o.o 0.92? 0.6911 0.972

9 10W RIH 13 CORE 10 R IH 111 TOW RIH 11 RIM 15 TOW RIH 12 NOTtt PL 17 A CORE 16 RIH

Page 137: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIMl'l.f 11 FELDSPAR IINALYSlS 1 / 18 19 20

S102 60.110 59.68 62. 32 57.011 1102 0.08 O.OJ 0.05 0.02 A20) ?II. 19 25. 15 26.76 23.511 1ro (J. 07 0.06 0.09 O.OJ 11/lO 0.01 0.?2 0.110 0.011 MGO 0.08 O.OJ 0.07 -0.01 CIIO 5.56 6.70 8.60 11. 81 11110 0.0 0.0 o.o o.o N/120 8.5q 7. 71 8.70 6.71 k70 0. 13 0.21 0.27 0.111 r u.o u.u 0.0 0.0 Cl. 0.0 o.o 0.0 0.0 SUM 99. 12 99. 79 107 .26 92.32 -0= f+CL 0.0 o.o 0.0 0.0 SUM 99. 12 99.79 107.26 92. 32

SI 2. / 11 . 2.668 • 2.619 • 2. 7211 • ...... Ill I. 219 • I. 325 . 1.325 • 1.325 • w TI 0.003 3.993 0.001 3.9911 0.002 3.9116 0.001 11.0119 N

re 0.003 . 0.002 • 0.003 • 0.001 • HN 0.003 . 0.008 • 0.0111 • 0.001 • HG 0.005 . 0.002 • 0.005 • -0.001 . CA 0.0 1.029 o.o 1.013 0.0 1. 133 0.0 0.878 011 0.0 • o.o • 0.0 • 0.0 • NII 0. 71,3 . 0.668 • 0.709 • 0.622 • k 0.001 1.029 0.012 1.013 0.0111 1.133 0.009 0.878 0 8.000 • 8.000 • 8.000 • 8.000 •

IIN 26.27 32.07 Jll.85 28.08 AO 73.00 66. 75 63.85 70.93 OR 0. 7J 1. 18 I.JO 0.99 CN o.o o.o o.o o.o

f/H 0.968 5. JJ8 J.750 0.352 f/FH 0.497 0.8112 0.789 0.260

17 RIHFINIS 19 AVERAGE PLUS SIGH/I 18 AVERAGE 20 AVERAGE MINUS SIGMA

Page 138: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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Page 139: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SJIP1PLC 17 AMPII I DOLE ANAL VS[ S 9 10 11 1?.

5102 117 .82 50.07 52.36 47. 78 r 102 0.96 0.64 0.87 0.41 11203 6.45 11.82 6. 50 3. 14 lfO 13. 71 12.811 13.89 11. 87 HNO 0.40 n.1111 0.117 0.41 HGO 12.88 14.J6 15.54 13. 17 CIIO 11. 59 11.80 12.00 11.60 OAO 0.0 0.02 0.05 -0.01 N/120 I. 04 o. 11, 1.02 0.46 K?.O 0.67 0.1,6 0.64 0.28 f 0.26 0. 13 0.25 0.01 C:l 0.01 0.01 0.01 -o.oo 11?.0 -o. 13 -0.06 -o. 12 -0.01 SUH 95.66 96.30 103. 48 89. 12 -0= F+C:L 0.11 0.06 0. 11 o.oo SUH 95.55 96.?.5 103. 38 89.12

SI 7. 153 . 7.380 • 7. 195 . 7 .594 • Al 0.8•11 8.000 0.620 11.000 0.805 8.000 0.406 8.000 ..... Al 0.290 • 0.217 • 0.247 • 0.182 • w TI o. 108 • 0.071 • 0.090 • 0.049 . +" FF I. 715 • 1.588 • 1.596 . I. 578 • Htl O.U51 • 0.055 . 0.055 • 0.055 • HG 2. 812 5.035 3. 155 5.085 3. 18'1 5. 172 3. 121 4.985 CII 1. 851 . 1.864 . I. 767 • I. 976 • NA o. 302 • 0.211 • 0.271 • 0. 142 • K 0. 128 . 0.087 . o. 113 • 0.057 • 1111 o.o 2.287 0.001 2. 163 0.003 2. 153 -0.000 2.1n Cl. O.IJOJ . 0.001 . 0.003 • -0.000 . r 0. 123 . 0.060 • o. 107 • 0.006 • II -o. 126 0.0 -0.061 0.0 -o. 110 0.0 -0.006 0.0 0 23.000 • 23.000 . 23. 000 . 23.000 •

CIIA 28.61) 21.98 26. 76 29.36 Ali! 1,11.21 4 7. 36 48.23 46. 38 GRU 27. 19 24.66 25.01 24.26

F/H 0.615 0.521 0.519 0.523 F/fH 0.361 o. 342 0.341 0.343

9 NOIIIIR 11 AV[RAGt rLUS SIGMA 10 AV[RAG[ 12 AV[RAGE MINUS SIGMA

Page 140: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPLE II AH Pitt BOLE ANAL YS[S 1 ?. J It 5 6

5107 511. 511 511.6J 52.ltl 51. 18 52.05 50.JI 1102 0.67 0. 72 0.33 0.57 0.75 O. IIO A203 11. 5 7 5. 31 2.93 11. 27 5.26 3.?8 110 12.811 12.66 12.110 12.63 12.81 12.45 HNO o. 39 0.111 0. 78 0.53 o. 71 0. 35 H<;o 111.9~ 111. 37 15. lit llt.89 15.29 .,,. 119 CAO 11.911 11.96 12.60 12. 17 12.117 11. 86 DAO o.o o.o 0.0 0.0 0.0 0.0 PIA20 11.59 0.80 0. 37 0.59 0.76 0.111 k20 o. 35 0.46 0.21 0. lit 0.114 0.211 I 0.0 0.0 o.o 0.0 0.0 o.o Cl 0.0 0.0 0.0 0.0 0.0 0.0 11?0 o.o 0.0 o.o 0.0 o.o 0.0 SUH 96.60 91. 32 97. 37 97. 16 100.55 93. 76 -Os f+Cl. 0.0 0.0 0.0 o.o 0.0 0.0 SUH 96.60 97. 32 91. 37 97 .• 16 100.55 93. 78

SI I. 391 • 7. 312 • , . 611 • 7 .1160 • 7. 3114 • 7. 5611 • Al. II. (,l)J 6,0011 0.628 8.000 0. 389 8.000 0.540 8.000 0.656 8.000 0.416 8.000 AL 0. 166 • 0.283 • 0.112 • 0. 193 • 0.219 • 0.166 • ...... II 0.074 • 0.079 • 0.036 • 0.063 • 0.079 • 0.045 . w f( I. '.i73 . 1. 5112 • I, 506 • 1. 5ll0 • 1.512 • 1. 570 . V, HN 0.0118 . 0.051 • 0.096 • 0.065 • 0.0811 • 0.0411 • HG 3. 7611 5. 1ll4 3. 119 5.072 3.320 5,070 3.234 5,095 3.214 5.109 3.255 5.081 CA I. 814 • 1.866 • 1.960 • 1.900 • 1.886 • 1.916 • NA 0. 166 . 0.226 . 0.1011 • 0.166 • 0.209 • 0.120 • k 0.065 . 0.085 • 0.039 • 0.063 • 0.080 • 0.0116 . BA 0.0 2. 107 o.o 2. 177 0.0 2. 103 0.0 2.129 0.0 2. 174 o.o 2.061 Cl 0.0 . 0.0 • 0.0 • o.o • o.o • o.o • r 0.0 . 0.0 • 0.0 . o.o • o.o . 0.0 • II 0.0 0.0 0.0 0.0 0.0 o.o o.o 0.0 o.o 0.0 o.o 0.0 0 23.000 . 23.000 • 23.000 • 23 .000 • 23 .ooo • 23.000 •

CAA 27. 72 28. 37 28.48 28.19 28.16 28.23 ANI 46.29 47 .42 48.24 47 .99 48.00 47 .98 GRU 23.99 211.21 23.27 23.112 23.611 23.79

F/H 0.497 0.511 0.482 0.1196 0.497 0.1196 f/fH 0. 332 0.3311 0.325 0.332 0.332 o. 331

I 1 7B IR[[ AHPlt 4 AV[RAGE 2 I 7B FR[£ AHrll 5 AV[RAG[ PLUS SIGMA 3 116 CO[XIST WITII PX LOOKS PRIMARY? 6 AV[RAG[ MINUS SIGHA

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Page 143: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAtlPL[ 2) BIOTITC ANALYSES I 2 l II 5 6 1

SI02 )7.911 l7.89 )8.05 )6.115 l7 .68 )8. 17 l7 .20 l 10?. ] . IIR 3.66 ). 79 l.611 l.611 ). 75 3.5) A20J 111.06 111. 72 111. l 1 111. 14 14. 31 14.56 14.05 HO 18. 18 19.00 18.88 18.45 18.63 18.96 18.JO 11110 O. );> O. lU 0.28 0. 30 0.30 0.)1 0.29 11GO 11. 9'1 1?.39 12,26 11.96 12.15 12. ll 11. 97 CAO o.o, o. u 0.111 0.07 o. 10 0.111 0.07 BAO 0.0 0.0 0.0 0.0 o.o 0.0 o.o NA20 0. II 0.16 0. 12 0.12 0.13 0.15 o. 11 1(20 9.10 9.02 8.99 9.011 9.011 9.08 9.00 r 0.0 0.0 0.0 o.o 0.0 0.0 0.0 CL 0.0 o.o 0.0 o.o o.o 0.0 0.0 1170 0.0 0.0 o.o o.o 0.0 0.0 0.0 SUH 9~.25 97 .27 96.82 911.57 95.98 97 .1111 91,.51 ·O= F+CL 0.0 0.0 o.o o.o o.o o.o o.o SUH 95.25 97 .27 96.82 911.57 95.98 97 .411 94. 51

SI 5. 71111 • 5.633 • 5.679 • 5.6114 • 5.675 • 5.662 • 5.688 • ....... Al 2.256 8.000 2.)67 8.000 2. )21 8.000 2.)56 11.000 2.325 11.000 2.318 11.000 2.312 8.000 l.,)

Al. 0.253 . 0.?12 • 0.196 • 0.196 • 0.214 • 0.207 • 0.221 • Cl) TI 0. )96 . 0.1109 • 0.1125 . 0.419 • 0.1113 • 0.1119 • 0.406 . re 2.302 • 2. 362 • 2.)56 . 2.363 • 2. 3116 • 2.352 • 2. )110 • ~IN o. 0111 • 0.038 • 0.035 • 0.039 • 0.038 • 0.039 • O.Ol7 • HG 2. 706 5.697 2. 7116 5.767 2.727 5. 1110 2.730 5. 1111 2. 727 5. 7311 2.727 5. 71,11 2. 728 5. 732 CA 0.011 . 0.021 • 0.022 • 0.011 • 0.017 . 0.021 • 0.011 • NJ\ 0.032 . 0.0116 . 0.035 • 0.036 • 0.037 • 0.0112 . 0.032 . I( 1. 751 . 1. 710 . 1. 711 • 1. 766 • 1. 736 • 1. 718 • 1.755 • BA o.o 1.801 0.0 1. 711 0.0 1.768 0.0 1.813 0.0 1.790 0.0 1. 781 0.0 1. 7911 CL 0.0 • o.o • o.o • 0.0 • 0.0 • 0.0 • o.o • r 0.0 . 0.0 • 0.0 • 0.0 • o.o • 0.0 . 0.0 • H 0.0 0.0 0.0 o.o 0.0 0.0 0.0 o.o 0.0 0.0 o.o 0.0 0.0 0.0 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 .

r/11 0.866 0.8711 0.877 0.880 0.874 0.877 O.R71 r / r11 0.11611 0.466 0. 467 0.4611 0.466 0.467 0.466

1 23A GRAN I TE BT 5 AVCRAGC 2 23 BT or GRANITE 6 AVERAGE PLUS SIGMA l 23 BT or GRANITE 7 AV[RAGC MINUS SIGMA Ii ANOTHER GRANITE GRAIN, BIOTITC RIGHT AT

Page 144: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAMrLE 23 OIOTITE ANALYSES 1 2 3 II 5 6 7 8

5102 16. f,2 36.67 37.82 37.20 37. 75 37.01 37. 18 37 .65 110;• J .11? 3.118 3. 07 2. 73 2.63 2.92 3. 011 l.36 A;>OJ 13.811 111. 111 111. 56 lit. 62 15.118 lli.ll 111.119 15.01 no 111 .. l I 18.25 18.28 18.32 18.90 18.119 16.112 18.65 HNll o.21 0.29 0. 32 o. 32 0.31 0.26 0.29 0.32 HUil 1?.. 7•1 1i.05 13.08 12.83 12. 31 13 .86 12 .911 1J .111 CAO 0.09 0.09 0. 12 0. 10 0,26 0.2~ 0.1~ 0.23 BAO 0.0 o.o 0.0 0.0 o.o 0.0 o.u 0.0 NA?O 0.12 0.12 0.09 0.011 0.02 0.09 0. 06 o. 12 l<?O 9.112 9.26 9. 18 9.116 8.67 9.01 9. 17 9.113 I 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 CL 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 11?.0 0.0 0.0 0.0 0.0 o.o 0.0 o.o 0.0 SUH 9lt.6l 95. 15 96.52 95.62 96.33 96.22 95. 78 96. 18 -0= r+CI. ll.O 0.0 o.o o.o o.o 0.0 0.0 0.0 SllH 91t.63 95. 15 96.57. 95.62 96.31 96.22 95.78 98. 18

SI 5.610 . 5.566 • 5.655 • 5.6311 • 5.61i7 • 5.569 • 5.617 • 5.5511 • ...... Al 2. 390 8.000 2.1112 8.000 2.3115 8.000 2. 366 8.000 2.353 8.000 2.1111 8.000 2.383 8.000 2.11116 8.000 I.,..)

Al 0. 108 • 0.128 • 0.221 • 0.21ill • 0.375 • 0. 110 • 0.198 • o. 163 • \0 II o. 39lt . o. 399 • o. 3115 • o. 311 • 0.296 . 0.330 . o. 3116 • o. 371 • r[ 2 .1116 • 2. 326 • 2.266 • 2. 320 • 2. 361i • 2.327 • 2. 328 • 2.101 • ~IN 0.015 • 0.037 • 0.0111 • O.Olf 1 • 0.039 • 0.033 . 0.018 . 0.0110 . HG 2.909 5.792 2.919 5.809 2.915 5.807 2.896 5.812 2. 7115 5.819 3. 109 5.910 2.915 5.825 2.950 5.826 CA 0.015 • 0.015 • 0.019 • 0.016 • 0.0112 • 0.0110 • 0.025 • 0.036 • NA 0.036 • 0.035 • 0.026 • 0.012 • 0.006 • 0.026 . 0.021 • 0.0311 . I< 1. 8111 • 1.800 . 1. 751 • 1.827 • 1.651i • 1. 729 • 1.767 • 1. 775 • DA 0.0 1.891 0.0 1.850 o.o 1.796 0.0 1.855 o.o 1.702 o.o 1. 796 0.0 1. 81~ 0.0 l.81t5 CL 0.0 . 0.0 • 0.0 • 0.0 • o.o • 0.0 • 0.0 • 0.0 . r 0.0 . 0.0 . 0.0 • 0.0 • o.o • o.o • o.o • 0.0 • H 0.0 o.o 0.0 0.0 o.o o.o 0.0 0.0 0.0 0.0 o.o 0.0 0.0 o.o 0.0 0.0 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 .

F/H 0.818 0.810 0. 798 0.1115 0.876 o. 759 0.812 o. 7911 r/fH 0.1150 O.ltll7 0.111111 0,11119 0.1167 O.lt32 O.ltltll 0.11112

1 23A HEIA OT RIGHT AT BORDER 5 2lA AWAY FROM CONTACT META BT rROH SCAN 2 23A H[TA BT RIGHT AT BORDER 6 23A META BT l 23A HEIA 81 FURTHER FROM CONTACT 7 AVERAGE II 23A AWAY FROM CONTACT, META BT FROM SCAN 8 AVERAGE PLUS SIGMA

Page 145: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SNlrl.C 23 9

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SI '.>.6114 . /\L 2. 316 8.000 AL 0.235 • TI 0.317 • re 2.357 • HN 0.036 • HG 2.819 5.8211 CA 0.013 • N/\ 0.013 . k 1. 758 • D/\ 0.0 1. 783 CL 0.0 . r 0.0 • ll 0.0 0.0 0 22.000 •

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Page 146: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIHPl.l 2] BIOTIIE ANIILYS[S 1 2 l It 5 6 1 8

5102 ]8.]8 37. lit ]8. 10 ]8.05 ]6.91 38. 19 37.58 38. 12 I I 07 2.811 2.76 l.57 3.39 3.76 3.03 l.02 2.81t A?Ul ll. 37 1]. 111 13.27 13.61 13.60 13. 67 111. ?.It 13.62 110 19.39 18. 71 19.60 19.lt6 19.61 18.ltlt 19.08 18.51 tlNO 0.29 0.29 0.28 0.21 0.21t 0.25 0.25 0.28 MGO ll.02 13.28 12.79 12.05 12.29 12.90 12. 37 12.79 CIIO O. llt 0.15 O. llt 0.18 0.12 0.15 0.15 o. 19 n110 11.0 o.o 0.0 o.o 0.0 0.0 0.0 0.0 tll\20 0.08 0.10 o. 10 0.06 0.15 O.Olt 0.05 0.0•1 K?O 10. 31 10.32 10.08 9.66 9.611 9. 73 9. 111 9.56 r 0.0 o.o o.o o.o 0.0 0.0 0.0 0.0 CL 0.0 0.0 0.0 o.o o.o 0.0 0.0 0.0 11?0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 o.o SUH 97.82 96.09 97.93 96.67 96. 32 96.110 96.118 95.95 -0= F+CL 0.0 0.0 o.o o.o 0.0 0.0 0.0 0.0 SUH 97 .82 96.09 97.93 96.67 96.32 96.110 96.118 95.95

SI 5.7JO . 5.681 • 5.686 • 5. 730 • 5.605 • 5. 71t0 • 5.666 • 5.755 . Ill 2. 2/0 8.000 2. 319 8.000 2. 3 llt 8.000 2.270 8.000 2.395 8.000 2.260 8.000 2. 3Jl1 8.000 2.21t5 8.000 Al 0.083 • O.OJ7 • 0.020 • 0.11t5 • O.OJ9 • 0. 161 • 0.196 • 0.178 . ,_. 11 0. 319 • 0. J 16 • 0.1101 . o. 381t • 0.1,29 • 0. 31t2 • o. 31t2 . 0.322 • -I'--If 2.•121 • 2.381 • 2.ltlt6 • 2.lt51 • 2.1190 • 2.318 • 2.lt06 • 2. 337 . ,_. HN 0.037 . 0.037 • O.OJ5 • 0.027 • Ii. 031 • O.OJ2 • 0.032 • 0.036 . HG 2.898 5. 7'H 3.012 5.783 2.81t5 5.71t8 2.705 5.711 2.782 5. 771 2.890 5.7113 2. 780 5. 756 2.878 5.752 CA 0.022 • 0.021t • 0.022 • 0.029 • 0.020 • 0.021t • 0.0211 • 0.031 • NII 1).023 . 0.029 • 0.029 • 0.018 • 0.01111 • 0.012 • 0.015 • 0.012 • K 1.963 • 2.003 • 1.919 • 1.855 • 1.867 • 1.865 • I. 873 • 1. 8111 . 1111 0.0 2.009 0.0 2.057 o.o 1.970 o.o 1.902 0.0 I. 931 0.0 1.901 0.0 I. 912 0.0 1.883 Cl 0.0 • o.o . 0.0 • 0.0 • 0.0 • 0.0 • o.o • 0.0 • r 0.0 • 0.0 .. o.o .. o.o • 0.0 • 0.0 • 0.0 .. 0.0 .. II 0.0 0.0 o.o o.o o.o o.o 0.0 0.0 0.0 0.0 o.o 0.0 0.0 o.o 0.0 0.0 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 ..

F/H 0.8118 0.803 0.872 0.916 0.906 0.813 0.877 0.8211 F/FH O.lt59 O.ltll5 0.1166 o. lt78 0.1175 O.lllt8 O.lt67 0.1152

I 51t9J8 8600 5 386117 2 531157 8600 6 2751tO=X J lt9011t 7 26799 II 1111869 8 22356

Page 147: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAMPLE 23 BIOTIT[ ANALYSES 9 10 11 12 13 14 15 16

5102 36. 01, 36.67 31. 32 36.72 37.00 37.13 36. 17 37.52 1107. 2.61 3. 13 3.76 2.92 2.59 2. 72 2.75 2.60 A203 1 J.22 13. 63 13.26 111.116 111.66 111.87 111.95 15.26 r10 19. 13 16,811 19. 31 18.86 18.69 18.56 19.26 19.00 HNO 0.22 0.21 0.29 0.20 0.25 0.25 0.23 0.25 H<;o 11. 19 17., 53 12.22 11.56 11.59 11. 911 12.?2 11.22 CAO 0.0( 0.10 0.12 o. 311 0.211 o. 10 0.11 o. 14 OAO 0.0 o.o 0.0 o.o 0.0 o.o o.o 0.0 NA20 0.05 0.01 o. 13 0.08 a.oz 0.09 0.08 0.06 1(20 10.29 10,23 9.911 8.88 8.97 9,112 9.110 9, 30 r 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 f.L 0.0 0.0 o.o o.o o.o 0.0 0.0 0.0 lt?O 0.0 0.0 0.0 0.0 o.o o.o o.o 0.0 SUH 97 .08 95.61 96.37 911.04 911.21 95.08 91. 11 95.35 -0= f+CL 0.0 o.o 0.0 o.o o.o o.o 0.0 o.o SIJH 97 .08 95.61 96.37 911.011 911.21 95.08 97.17 95. 35

...... SI 5.720 . 5.636 • 5.663 . 5.660 • 5.681 • 5.658 • 5.689 • 5.697 • -"' AL 2.260 8.000 2.362 8.000 2. 337 8.000 2. 31,0 8.000 2,319 8.000 2. 3112 8.000 2. 311 8.000 2.303 8.000 N AL 0.063 • 0.095 • 0.0311 • 0.291 • 0. 369 • 0.328 • o. 3111 • 0.1127 . Tl 0. 325 • 0. 360 • 0.431 • 0.338 • 0.299 • 0, 312 • 0. 308 • 0.297 • f[ 2.1106 • 2.409 • 2.1151 • 2.431 • 2.400 • 2. 365 • 2.400 • 2.412 • HN 0.028 • 0.027 • 0.037 • 0.026 • 0.033 • 0.032 • 0.029 • 0.032 . HG 2.956 5. 111 2.8S6 5. 747 2.764 5. 717 2.656 5,743 2.652 5,753 2.712 5.749 2.714 5. 766 2.539 5. 707 CA 0.011 • 0.016 • 0.020 • 0.056 • 0.039 • 0.016 • 0.018 . 0.023 • NA 0.015 . 0.021 • 0.036 . 0.024 • 0.006 • 0.027 • 0.023 . 0.018 • K 1. 9111 • 1. 995 • 1. 9211 • 1. 746 • 1. 757 • 1.831 • 1.767 • 1.801 • DA 0.0 1. 999 o.o 2.033 o.o ; .982 0.0 1.826 0.0 1.802 0.0 1.8711 o.o 1.827 0.0 1. 841 CL 0.0 • 0.0 • o.o • o.o • o.o • 0.0 • 0.0 • o.o • r 0.0 • 0.0 • o.o • 0.0 • 0.0 • 0.0 • 0.0 . 0.0 . H 0.0 0.0 0.0 0.0 0.0 0.0 0.0 o.o o.o o.o 0.0 0.0 0.0 0.0 0.0 0.0 0 22.000 • 22.000 • 22,000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • r/H 0.623 0.653 0.900 0.925 0.917 0.6611 0.895 0.963

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10 261106 111 351161 11 335511 15 311771 12 365115 16 33706

Page 148: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIHrLE 2J OIOTITE ANALYSES '7 18 19 20 21 22 2J 24

SIU? JI .91 J7. 7J J6.:?6 J8. J2 J7 .6J J7. 51 J7 .112 J8.J8 1102 2. 12 2. 76 J.25 3.36 3.89 3. 51, 2.9!; 2.116 11203 15. 15 111. 9' 15.116 111. 69 111. ,, J 15.00 111.64 111. 69 ri:o 16.65 18,1111 18.93 19. 14 19. 12 19.00 19.52 111.IIJ HNO 0.29 0.26 0.25 0.25 0.29 0.26 0.26 0.31 HGO I I. IJ I 11.62 11. 13 11.811 11.60 11. 51 11. 76 12.06 CIIU O. lli o. 17 0.19 o. 15 0.09 0.011 0.111 o. 11 OAO 0.0 o.o u.o o.o 0.0 o.o 0.0 0.0 Nll?.O 0.07 0.09 0.07 0.07 0.06 0.08 0.03 0.07 K20 9. 111 9.40 9. 15 9.19 9.32 9.45 9. 14 9.43 r 0.0 o.o 0.0 o.o o.o 0.0 0.0 o.o Cl 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 117.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 SUH 96.02 95.114 94. 71 97.07 96.43 96.115 95.88 96. 34 -0= F+CL 0.0 o.o 0.0 o.o o.o 0.0 0.0 0.0 SUH 96.02 95.44 911. 71 97 .07 96.43 96.45 95.88 96. ]II

SI 5. 705 • 5. 7111 • 5.5511 • 5.707 • 5.660 • 5.639 . 5.667 • 5.748 . ,..... Al. 2.295 11.000 2.286 8,000 2.442 8.000 2.29] 8.000 2.340 11.000 2.361 11.000 2. 33J 8.000 2.252 8.000 ~

AL 0.387 • o. 375 • o. 354 • 0.265 • 0.218 • 0.296 . 0.260 • ·o. 341 . w Tl 0. 307 • 0. 317 • 0. J75 . 0.379 • 0.440 • 0.400 • O.J36 • 0. 322 . IC 2. 343 • 2. llil • 2.427 • 2. 384 • 2.405 • 2. 389 • 2.472 • 2.308 • HN 0.037 . O.OJl • 0.032 • 0.032 • O.OJ7 • 0.036 . O.OJ6 • 0.039 • HG 2.656 5. 7Jl 2.623 5.688 2. 5113 5. 731 2.6J7 5.716 2.601 5.701 2.579 5. 700 2.655 5. 779 2.692 5. 70] CA 0.1126 . 0.028 • 0.031 • 0.024 • 0.015 • 0.013 • 0.023 . 0.016 • NII 0.020 . 0.026 . 0.021 • 0.07.0 • 0.017 • 0.023 . 0.009 . 0.020 . K 1. 752 • 1.816 • 1. 769 • 1. 746 • 1.788 • 1,812 • 1. 766 • 1.801 • Ill\ o.o 1.798 0.0 1.8/0 0.0 I ,8111 0.0 1.790 0.0 1.820 o.o 1.848 0.0 1. 797 0.0 1.8]9 Cl 0.0 • o.o • o.o • o.o • 0.0 • 0.0 • o.o • o.o • r 0.0 • 0.0 • 0.0 • 0.0 • o.o • 0.0 . 0.0 • o.o • II 0.0 0.0 o.o 0.0 0.0 0.0 0.0 o.o 0.0 o.o o.o 0.0 o.o o.o 0.0 o.o 0 22.000 . n.ooo • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 •

F/H 0.695 0.905 0.967 0.916 0.939 0.91!0 0. 91,5 0.1172 F/FH 0.1112 0.475 0.492 0.478 0.41111 0.485 0.486 0.466

17 33351 21 24835 18 ]1932 22 24125 19 2909] 23 30ll8 20 28029 24 31353

Page 149: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAMl'tr 23 810111[ ANALYSES 2'., 26 27 211 29 30 31 32 SIO? JI. 16 J6.3'j 37. ,;5 36. 16 37.99 37 .22 37. 26 36.113 I lll2 2.87 2.911 3.1111 2. 77 2.14 2. 711 2. 72 2.82

A?Ol 15.05 111.96 15.25 15.116 15.63 15.00 15. 45 15.09 110 18. ~,. 111.06 18.59 19.10 111. 711 19.09 18.90 18.30 tlllO 0.29 0.28 0.26 o. 35 0.27 0.25 0.27 0.29 HGO 11. 711 12.41 12.02 12.95 12.76 12. 31i 12.38 12.58 CAO 0.08 0.08 O.O'j 0.10 o. 12 0.17 0. 13 0.12 IIAO 0.0 0.0 0.0 o.o o.o 0.0 o.o 0.0 IM?O 0.10 0.05 0.09 0.07 0.20 0.08 0.08 0.06 k:10 9.35 9.61 9.111 9.39 9.35 9.llli 9.111 9.6 .. r 0.0 o.u 0.0 0.0 o.o o.o 0.0 o.o Cl 0.0 0.0 0.0 o.o 0.0 o.o 0.0 0.0 11?0 u.o 0.0 o.o 0.0 0.0 0.0 0.0 0.0 su,1 95.20 96.72 96.66 98.35 97.211 96. 33 96.62 95. 73 -o, r+CL 0.0 o.o o.o 0.0 o.o o.o o.o 0.0 SUM 95.20 96. 72 96.66 98. 35 97.21i 96.33 96.62 95. 73 SI 5.653 . 5.714 • 5.617 . 5.613 • 5.61111 • 5.611 • 5.592 • 5.579 . Al 2. 3117 8.000 2.2116 8.000 2.J8J 8.000 2.387 11.000 2.356 11.000 2. 389 8.000 2.1108 8.000 2.1121 11.000 ,_. Al 0. 350 . 0. 31111 • 0. 305 • 0.293 • 0.381 • 0.275 • 0. 322 • 0.273 • .i,-II 0.328 . 0. 325 • 0. 387 • o. 306 • 0.239 • o. 311 • o. 307 • 0.321 • .i,-re 2.358 . 2.250 • 2. 326 • 2.350 • 2. 333 • 2.1107 • 2. 371 . 2. 318 • MN 0.037 • 0.035 . 0.033 • O.Oti4 • 0.034 • 0.032 • 0.031i • 0.037 • HG 2.661 5. 7311 2.756 5.711 2.680 5. 731 2.839 5.832 2.1126 5.1113 2. 773 5. 797 2. 768 5.802 2.8111 5.791 CA 0.013 . 0.013 • 0.008 • 0.016 • 0,019 • 0.027 . 0.021 • 0.019 • NA U.029 • 0.0111 • 0.026 . 0.020 • 0.058 • 0.023 • 0.023 • 0.018 . K 1.813 • 1.826 • 1. 795 • 1. 762 • 1,772 • 1.815 • 1.800 . 1.863 . BA 0.0 1.856 0.0 1.854 0.0 1.830 o.o 1. 797 o.o 1.81i9 0.0 1.866 0.0 1.8111i 0.0 1.900 CL 0.0 • 0.0 • o.o • 0.0 • o.o • o.o • o.o • 0.0 . r o.o . o.o • 0.0 • o.o • 0.0 • 0.0 • 0.0 • 0.0 . II 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 o.o 0.0 0.0 0.0 o.o o.o o.o o.o 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • F/H 0.900 0.829 0.880 0.8113 0.838 0.679 0.869 0.629

F/FH 0.11711 0.453 0.468 0.457 0.456 0.1168 0.1165 O.li53 25 31607 29 39032.5 26 33690 30 395117.5 27 351112 31 40143.5 28 3670:,li.5 32 43752. 5

Page 150: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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Page 152: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPLC 23 FELDSPAR ANALYSES 1 2 3 4 5 6

SI02 61. 58 60. 511 61.37 61.16 61. 61 60.71 1107. 0.0~ 0.03 ti. 03 0.04 0.05 0.03 A203 23.57 211. 62 24.56 24.25 24. 73 23. 77 rro 0. 11 0.17 O. J11 0.23 0. 31 o. 15 HNO 0.03 0.02 0.03 0.03 0.03 0.02 HGO 0.10 0.05 0.09 0.08 o. h) 0.06 GAO 6.33 6.65 6. 32 6.43 6.59 6.28 IIAO 0.0 0.0 0.0 0.0 0.0 o.o NA?.O 8.08 8. 13 7 .86 8.02 8. 14 7.91 K20 0.26 0.25 0.27 0.26 0.27 0.25 r 0.0 0.0 o.o o.o 0.0 0.0 CL 0.0 o.o 0.0 0.0 o.o 0.0 SUH 100. 17 100,116 100.87 100.50 10 I. 82 99. 17 -0• F+CL 0.0 0.0 0.0 o.o o.o o.o SUH 100. 17 100.116 100.87 100.50 101. 82 99, 17

SI 2. 731 . 2.690 • 2. 709 • 2.712 • 2.700 • 2. 724 • ...... Al 1.2111 . 1.289 • 1.278 • 1. 267 • 1.277 • I. 257 • ~

Tl 0.002 3.973 0.001 3.980 0.001 3.9118 0.001 3.9110 0.002 3. 9711 0.001 3.982 -...J H 0.006 • 0.006 • 0.013 • 0.008 • 0.011 • 0.005 • HN 0.001 . 0.001 . 0.001 • 0.001 . 0.001 • 0.001 . ~1G 0.007 . 0.00J . 0.006 • 0.005 • 0.007 • 0.0011 • CA 0.0 1.026 o.o 1.0111 0.0 1.006 o.o 1.025 0.0 1.035 0.0 1.014 BA 0.0 • 0.0 • o.o • o.o • 0.0 • 0.0 • NA 0.696 . 0,700 • 0.673 • 0.690 • 0.692 • 0.688 • K 0.015 1.026 0.014 1.0111 0.015 1.006 0.015 1.025 0.015 1,035 0.014 1.014 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 •

AN 29. 77 30.70 30.29 30.26 30.44 30.07 AB 68. 71 67.92 68.17 68.29 68.08 68.50 OR 1. 46 1. 37 1.54 1.46 1.48 1.44 CN 0.0 o.o 0.0 0.0 o.o o.o F/H 1. 124 2. 135 2. 309 1. 779 1.810 1.621 F/FH 0.529 0.681 0.698 0.640 0.652 0.619

I 23A H[IA PLAG RIGltl AT BORDER 4 AVERAGE 2 23A HETA PLAG RIGltT AT BORDER 5 AVERAGE Pl.US SIGMA 3 23A HCTA PLAG RIGHT AT BORDER 6 AVERAGE MINUS SIGMA

Page 153: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHrt.E 23 r[LOSPAR ANALYSES I 2 3 11

S IO? 63. !">? 63. 52 63. 52 63.52 1107 0.01, 0.011 0.011 0.011 A20J 17. ;_,5 17.25 17 .25 17 .25 r rn ll. llA 0.08 0.08 0.08 HIIU II.OIi 0.011 0.04 0.011 MGO 0.113 0.03 0.03 0.03 CAO 0.113 0.03 0.03 0.03 RAO 0.0 o.o o.o 0.0 NA?U 0.4?. 0.42 0.42 0.112 k?O 15.59 15.59 15.59 15.59 r 0.0 0.0 0.0 0.0 CL o.o o.o o.o o.o SUH 97 .on 97.00 97 .oo 97 .oo -Os r +Cl. 0.0 0.0 o.o o.o SUH 97.00 97.00 97 .oo 97 .OD

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f[ 0.003 • 0.003 • 0.003 • 0.003 • HN 0.002 . 0.002 • 0.002 • 0.002 • HG 0.002 • 0.002 • 0.002 • 0.002 • CA o.o 0.993 0.0 0.993 0.0 0.993 0.0 0.993 BA o.o • 0.0 • 0.0 • 0.0 • IIA 0.039 . 0.039 • 0.039 • 0.039 • k 0.9•16 0.993 0.946 0.993 0.9116 0.993 0.946 0.993 0 8.000 • 8.000 • 8.000 • 8.000 •

All 0.16 0.16 0.16 0.16 AB 3,93 3.93 3.93 3.93 OR 95.92 95.92 95,92 95.92 CH o.o 0.0 o.o 0.0

F/H 2.?54 2.2511 2.2511 2.2511 F/rH 0.693 0.693 0.693 0.693

1 KSPAR rROH SCAN AWAY FROM CONTACT 23A HE 3 AVERAGE PLUS SIGHA 2 AVERAGE Ii AVERAGE HINUS SIGHA

Page 154: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHrLE 23 r[LOSP/\R ANALYSES 1 2 l II 5 6 1

S102 61. ~8 59.112 61.81 62.1111 61. 31 62.115 60.18 1102 0.01, 0.01 O,OJ 0.011 O.Ol 0.011 0.02 1\203 211 .6'.", 23.87 22.53 211.25 23.82 211.62 23.03 rro 0.0 0.09 0.0 0.07 0.011 0.08 -o.oo HNO 0.0 0.02 0.02 0.02 0.01 0.02 0.01 HGO 0.111 0.01 o.or, 0.08 0.07 0.12 0.02 CAO 6.118 6. 18 11.911 5.87 5.87 6,1111 5.29 111\0 0.0 o.o o.o o.o 0.0 0.0 o.o NA20 8.00 8. 12 8. 79 8.10 8.25 II. 57 7 .911 1120 o. 13 0. 19 0.08 0.10 0.13 o. 17 0.08. r o.o 0.0 0.0 0.0 o.o o.o 0.0 CL 0.0 0.0 o.o 0.0 0.0 0.0 0.0 SUH 101 .02 97.91 98.211 100.97 99,53 102.51 96.56 -0= f+CL 0.0 0.0 o.o 0.0 0.0 0.0 0.0 SUH 101. 02 97.91 98.211 100.97 99.53 102.51 96.56

SI Z.1111 • 2.7011 • 2.787 • 2.741 • 2. 735 • 2. 7111 • 2.758 • AL 1. 278 • 1.280 • 1. 197 • 1,255 • 1.253 • 1.261 • 1.21111 • ,..... TI 0.001 l.989 0.000 l .985 0.001 3.985 0.001 l.997 0.001 3.989 0.001 3.976 0.001 11.002 .p-f [ 0.0 • 0.003 • 0.0 • 0,003 • 0.001 • 0.003 . -0.000 • \0 HN 0.0 . 0.001 . 0.001 • 0.001 • 0.001 • 0.001 • 0.000 • HG 0.009 • 0.001 • 0.003 • 0.005 • 0.0011 • 0.008 • 0.001 • CA 0.0 1.005 0.0 I.Olli 0.0 1.015 o.o 0.980 o.o 1.008 0.0 1.0112 0.0 0.972 8A 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • IIA 0.683 • 0.716 • o. 768 • 0.689 • 0.714 • o. 722 • 0.705 • I( 0.007 I .005 0.011 I .Olli 0.005 1. 015 0.006 0.980 0.007 1.008 0.009 1.0112 0.00'.i 0.972 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 •

AN J0.69 29.29 23.59 28.113 28.01 29. 10 26.78 AO 68.57 69.611 75.96 70.99 71.28 70.00 72. 72 OR 0. 7l 1.07 0.115 0.58 0.71 0.90 0.50 CN 0.0 o.o 0.0 o.o 0.0 0.0 0.0 r/M 0.0 6.186 0.2811 0.633 0.1159 0.505 0. 173 r /FM 0.0 0.861 0.221 0.388 o. 3111 0.336 o. 1117

I 23A IGNEOUS PLAG 5 AVERAGE 2 2lA IGNEOUS PLAG 6 AVERAGE PLUS SIGMA 3 23A IGNEOUS Pl.AG 7 AVERAGE MINUS SIGMA II 2JA IGNEOUS PLAG

Page 155: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SA14PLC 2J FELDSPAR ANALYS[S 1 2 3 4 5 6

5102 61. J3 61. 52 62. 75 61.117 62.50 61.24 T 102 0.06 0.05 O.OJ 0.05 0.06 O.OJ A;_>03· ?2.6•1 23.611 23. 13 23. 14 23.54 22.73 ICO o. 17 0.20 0.12 0.16 0.20 0. 13 HNO 0.01 0.02 o.o 0.01 0.02 0.00 HGO 0.02 0.0 0.11 0.04 0.09 -o.oo CIIO 6.05 6.50 •1. 72 5.76 6.51 5.00 11110 0.0 o.o o.o 0.0 o.o 0.0 NA20 8. JO 11.09 9,02 8.47 11.117 8.07 k20 0.28 0.19 0.21 0.23 0.27 0.19 r 0.0 o.o 0.0 0.0 o.o o.o Cl. 0.0 o.o 0.0 o.o 0.0 0.0 SUH 98.116 100.21 100.09 99. 72 102.05 97. 39 -o= r•cL 0.0 0.0 0.0 0.0 0.0 o.o SUH 98.86 100.21 100.09 99.72 102.05 97.39

SI 2.762 • 2. 734 • 2. 779 • 2.758 • 2. 735 • 2.782 • AL 1.201 • 1.238 • 1.207 • 1.215 • 1. 214 • 1. 217 • ...... TI 0.002 3.965 0.002 3.973 0.001 3.987 0.002 3.975 0.002 3.952 0.001 3.999 V,

re 0.006 . 0.007 • 0.0011 • 0.006 • 0.007 • 0.005 • 0 HN 0.000 . 0.001 • o.o • 0.000 • 0.001 • 0.000 • HG 0.001 • 0.0 • 0.007 • 0.003 • 0.006 • -0.000 • CA 0.0 1.0111 0.0 1.025 0.0 1.022 0.0 1.029 0.0 1.087 0.0 0.910 IIA 0.0 . 0.0 • 0.0 • 0.0 • 0.0 • 0.0 . NII 0. 725 • 0.697 • 0. 7711 • 0. 732 • o. 753 • 0. 711 • k 0.016 1.0111 0.011 1.025 0.012 1.022 0.013 1.029 0.015 1.0117 0.011 0.970 () 8.000 • 8.000 • 11.000 • 8.000 • 8.000 • 8.000 •

AN 26.27 30.112 22. 17 26.96 28.117 25.22 AB 70. 18 68.52 76.66 71. 78 70. 15 73.65 OH 1. 56 1.06 1. 17 1.26 1. 38 1. 13 CN o.o o.o 0.0 0.0 0.0 o.o f /H 5.053 6. 166 0.612 2.2116 1.321 0.505 r;rH 0.835 0.861 0. 380 0.692 0.569 0.336

1 2JA HEIA PLAG 4 AVERAGE 2 2JA HCIA PLAG 5 AVERAGE PLUS SIGMA 3 PLAG H[IA fROH SCAN or GRAINS AWAY fROH 6 AVERAGE MINUS SIGMA

Page 156: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

ShMPl [ ;>J ffLDSPAR ANALYSES I 2 3 4 5 6 7 8

S102 60.611 61.01 60. 11 61.49 61.02 59.28 60. 78 60.20 1102 11.02 0.03 0.112 0.011 0.011 0.03 0.011 0.01 1\203 21. 97 21. 79 22.110 22. 32 22.20 23.70 22.10 22.66 1[0 0.?6 0.29 0.25 0.23 0. 30 0.01 0.05 0.09 MNO o.o 0.01 o.o 0.01 0.01 0.01 0.01 0.01 MCO 0.25 0.0 0.0 o.o 0.0 o. 14 0.08 o.o C/\0 6.611 6. 311 7.05 6.llO 6. 77 8.16 7.30 7.00 (1,\0 0.0 o.o 0.0 0.0 0.0 0.0 o.o 0.0 Nh:'O 8.0 .. 8.36 8.09 8.37 7.99 7 .118 7. 711 8. 12 K?O 0.23 0.27 0.25 0.25 0.28 0.21 o. 32 0.20 f 0.1) o.o 0.0 0.0 0.0 o.o 0.0 0.0 Cl. 0.0 0.0 0.0 0.0 o.o 0.0 0.0 o.o SUH 98.05 98.10 98. 17 99. 11 98.61 99.02 98.112 98.29 -o.s F +CL 0.0 o.o 0.0 o.o o.o o.o o.o o.o SUH 98.05 98.10 98. 17 99.11 98.61 99,02 98.112 98.29

SI 2. 759 . 2. 775 • 2. 738 • 2.766 • 2.761 • 2.681 • 2.757 • 2. 735 • Al. I. 178 . 1.168 • 1.202 . 1. 183 • 1, 1811 • 1.263 • 1. 181 • 1.213 • ....... TI 0.001 3.938 0.001 3 .9113 0.001 3 .9111 0.001 3.951 0.001 3.9116 0.001 3.9116 0.001 3.939 0.000 3,9119 U1 FE 11.010 . U.011 • O.OIO • 0.009 • 0.011 • 0.000 • 0.002 • 0.003 • ....... MN 0.0 • 0.000 • 0.0 • 0.000 • 0.000 • 0.000 • 0.000 • 0.000 • HG 0.017 . 0.0 • 0.0 • 0.0 • 0.0 • 0.009 • 0.005 • o.o • Ch 0.0 1.073 0.0 1.073 o.o 1.0113 o.o 1.062 o.o 1.057 0.0 1.0711 o.o 1.062 0.0 1,072 8A 0.0 • 0.0 • o.o • o.o • o.o • 0.0 • 0.0 • 0.0 • NA o. 709 • o. 737 • 0. 7111 • 0. 730 • 0.701 • 0.656 . 0.681 • 0.715 • K 0.013 1.073 0.016 1.073 0.015 1.083 0.0111 1.062 0.016 1.057 0.012 1.0711 0.019 1.062 0.012 1.072 0 8.000 . 8.000 • 11.000 • 11.000 • II.ODO • 8.000 • II.ODO • 8.000 .

AN 30.911 29. 10 32.06 29. 30 31.110 37. 111 33.66 31.92 AB 61. 19 69.43 66.58 69. 311 67.06 61.68 611.58 67.00 OR 1.28 1.48 1. 35 1. 36 1.55 1. 111 1. 76 1.09 CN 0.0 0.0 0.0 o.o 0.0 o.o 0.0 o.o f/H 0.5811 6. 186 0.612 2.246 1. 321 0.081 0.1122 0.0 F/FH 0.368 0.861 0.380 0.692 0.569 0.075 0.297 o.o

I 57160 5 501195 2 511198 6 117533 3 52117 7 116793 4 51976 II 116052

Page 157: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAMPLE 23 FCLDSPAR ANALYSCS 9 10 II 12 ll Ill 15 16

5102 62.02 59.117 60.96 61. 39 611.87 61.116 61.82 60.111 TI02 0.011 0.0 0.0 0.20 0.0 0.01 0.01 0.0 11203 21. 55 211.09 22.52 22.56 20.110 22.511 22. 711 22.65 rro 0.06 0.03 0.01 0.01, 0.011 0.22 0.17 o. 16 HNO 0.0 0.0 0.0 o.o 0.02 0.0 0.01 0.0 HGO (l. 05 o. ll 0.20 0.17 0.06 0.011 0.0 o. 11 CAO 5.61 6.U?. ti. ll 6. 71 3.35 6.16 6.31 6.63 0110 0.0 o.o 0.0 o.o 0.0 o.o 0.0 o.o N/120 8.56 7.53 II. Ill 11.26 10. 111 8.55 II. 511 11.27 k20 0. 39 0.25 0.111 0.21 0.56 0. 30 0. 19 0.26 f 0.0 0.0 0.0 o.o 0.0 o.o o.o o.o CL 0.0 0.0 0.0 o.o o.o 0.0 0.0 o.o SUH 96.50 99.52 98.59 99,51, 99.86 99. 32 99. 79 96.22 -oc r+CL 0.0 0.0 o.o o.o o.o 0.0 0.0 0.0 SUH 98.50 99.52 98.59 99.511 99.86 99. 32 99. 79 98.22

SI 2.601 . 2.676 • 2.7511 • 2.750 • 2.876 • 2. 759 . 2.760 • 2. 735 • Ill. 1. 1117 • 1.277 • 1. 199 • 1. 191 • 1.087 • 1. 195 • 1. 196 • I. 2111 • ...... TI 0.001 3.950 0.0 3.953 0.0 3.953 0.007 3.9118 o.o 3.963 0.000 3,951, 0.000 3.957 0.0 3.9119 V,

re 0.002 . 0.001 • 0.000 • 0.001 • 0.001 • 0.0011 • 0.006 • 0.006 • N MN 0.0 . o.o . o.o • 0.0 • 0.001 • 0.0 • 0.000 • 0.0 • HG 0.003 • 0.009 • O.OIJ • 0.011 • 0.0011 • 0.003 • 0.0 • 0.007 • CA ll.O 1.061 0.0 1.0611 o.o 1.067 0.0 1.0611 0.0 1.070 0.0 1.069 0.0 1.059 o.o 1.061 811 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 .. NA 0.751 . 0.657 • o. 738 • o. 717 • 0.872 • 0. 71111 . 0. 739 • 0. 729 • k 0.022 1.061 0.0111 1.068 0.008 1.067 0.012 1.0611 0.033 1.070 0.017 1.069 0.011 1.059 0.015 1.081 0 11.000 • 8.000 • 8.000 • 8.000 • 11.000 • 8.000 • 8.000 .. 11.000 •

AN 26.65 36.55 29.10 30.63 111.96 211.01 28.69 30.27 IIB 71.22 62.10 70. 13 68.23 111.95 70. 36 70.28 68. 32 OR 2. 13 1. 36 o. 77 1 . 111 3.08 1.62 1.03 I." 1 CN 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0

r/H 0.673 0.129 0.028 o. 132 0.563 3.086 0.1122 0.1116 r/FH 0.'402 o. 115 0.027 0. 117 0.360 0.755 0.297 0.11119

9 IIJ831 ll 312lt2 10 111609 lit 25318 11 37166 15 2115711 12 35685 16 22201

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SAHPl[ ;'5 FELDSPAR ANALYSES 1 2 3 4 5 6 7 8

SI 02 (,5. 35 63.96 63. 7.5 64. 12 63. 70 63.91 64.05 64.69 1102 11.06 0.06 0. lJ 0.03 0.07 0.01 0.011 0.07 A?.O.l 18. 85 111. JU 16.411 111. 79 111.60 16.111 18. 5 7 18. 71 II 0 0.011 11.011 0.011 0.04 0.04 ll.116 0.011 0.05 11NO o. "l o.o 0.0 0.011 0.01 0.01 0.(11 0.03 H<iU u.o (I.OIi 0.05 0.04 0.02 O.llJ 0.011 0.06 CAO 0.01 0.06 0.0l 0.03 0.07 0.06 0.04 0.06 BAO 0.0 o.o 0.56 0.55 0.55 0.52 0. 37 0.63 NA?O 0.111 o. 43 0.37 0. 32 0.36 0.50 0.40 0.116 K20 15.26 14.60 15.55 lit. 77 15.09 15.27 15. 12 15.40 r 0.0 o.o 0.0 0.0 0.0 0.02 0.00 0.01 Cl. 11.0 o.o 0.0 0.01 0.0 0.0 0.00 0.01 SUH lll0.01 97. 73 96.35 96. 73 98.51 96. 76 98.66 100.21 -Os [+C:L 0.0 0.0 0.0 o.o 0.0 0.0 0.0 o.o SUH 1110. 0 I 97. 73 96. 35 96. 73 98.51 96.76 96.66 100.21

SI 2.999 . 3.002 . 2.960 . 2.989 • 2.985 • 2.990 • 2.991 . 2.9811 . Al 1.019 • 1.012 • 1.026 • 1.032 • 1.027 • 1.015 . 1.022 • 1.020 . TI 0.002 11. 020 0.002 4.016 0.0 11. 005 0.001 4.022 0.002 lt.0111 0.000 4.005 0.001 11.0111 0.002 4.1107 ,-. FE 0.002 • 0.002 • 0.002 • 0.002 • 0.002 • 0.002 • 0.002 ,I 0.002 • Vl HN 0.001 . 0.0 • 0.0 • 0.002 • 0.000 • 0.000 . 0.001 . 0.001 . w HG 0.0 • 0.006 • 0.004 • 0.003 • 0.001 • 0.002 . 0.003 . 0.0011 • CA 0.0 0.933 0.0 0.935 o.o 0.985 0.0 0.925 0.0 0.952 0.0 0.9lll 0.0 0.950 0.0 0.969 OA n.o • o.o • 0.011 . 0.010 • 0.010 • 0.010 • 0.007 • 0.011 • NA ().036 • 0.039 • 0.034 . 0.029 • 0.033 • 0.0115 . 0.036 . 0.041 . K 0.693 o.933 0.686 0.935 0.9311 0.965 0.878 0.925 0.902 0.952 0.911 0.9711 0.901 0.950 0.906 0.969 0 8.000 • 6.000 • 6.000 • 8.000 • 8.000 • 6.000 . 8.000 • 8.000 .

.AN 0.05 0.33 o. 15 0.16 0.37 o. 31 0.23 o. J3

.All 3.92 4.22 3.115 3. T 5 3.115 11.68 l.81 4.24 OR 96.03 95.46 95.31 95.60 95. 12 94.03 95.25 911.25 CN 0.0 0.0 1.09 1.09 1.07 0.96 0.71 T. 18

[/H -7. 2112 0.281 0.11119 1.129 1.406 1. 312 0.896 0.739 F/IH 1. 160 0.219 0.310 0.530 0.584 0.567 0.1172 0.1125

1 258 KSP.AII 5 RIH kSP 2 258 RAST[R or KSrAR 6 CORE 3 25 COG( KSP NCWO 7 AVER.AG[ 4 COHC--SHALL KSP 8 AVERAGE PLUS SIGMA

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SIIHPLC 23 rELOSPAR ANALYSES I 7 18 19 20 21 22 23 24

510<' 60.20 61. 91 61.40 60.95 62.117 62.01 60.42 63.43 r 102 0.05 0.02 0.04 0.02 0.01 0.01 0.01 0.02 1\703 22. 16 22.111 22.55 22.59 21.52 21. 79 22. 16 20.66 rr o 0.111, ll.2] 0.40 0.51 0.12 0.08 o. 11 0.15 HIW 0.0 0.0 0.01 0.01 0.0 0.02 0.0 0.03 HGO 0.11 0.24 o. 15 0.11 0.0 0.01 0.0 0.0 C/10 6. 77. 6.67 6.83 6.611 6. 18 6. 17 6. 71 3.95 01\0 o.o 0.0 0.0 o.o 0.0 0.0 o.o o.o N/120 8.28 8.32 8. 38 8.42 8.66 8.45 8.29 9.92 K20 0. 11 0.25 0.23 0.25 0. ]7 0.40 0.21 0.09 r 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0 Cl 0.0 0.0 o.o 0.0 0.0 o.o 0.0 0.0 SUH 98. 1 J 100.17 99.99 99.50 99.33 98,94 98.57 98.25 -o~ r•cL 0.0 0.0 0.0 0.0 o.o o.o 0.0 0.0 SUH 98. IJ 100. 17 99.99 99.50 99,33 98.94 98.57 98.25

SI 2. 744 • 2.760 • 2. 746 . 2. 741 . 2.802 • 2.791 • 2. 737 • 2.859 . Ill 1.190 • I. 179 • 1.188 • I. 197 • I. 137 • 1. 156 • 1. 215 • 1.097 • ...... TI 0.002 3.936 0.001 3.940 0.001 3.936 0.001 3. 938 0.000 3.940 0.000 3.948 0.000 3.952 0.001 3.957 V,

f[ 0.017 • 0.009 • 0.015 • 0.019 • 0.005 • 0.003 • 0.006 • 0.006 . ~

~IN o.o • o.o • 0.000 • 0.000 • o.o • 0.001 • 0.0 • 0.001 • HG 0.007 • 0.016 • 0.010 • 0.007 • o.o • 0.001 . o.o • 0.0 • CA 0.0 1.094 o.o 1.075 0.0 1.092 o.o 1.095 0.0 1.076 o.o 1.062 o.o 1.072 0.0 1.070 0A 0.0 • o.o • o.o • 0.0 • o.o • 0.0 • 0.0 • o.o • NII o. 732 • 0.718 • o. 727 • o. 734 • 0.753 • o. 737 • o. 728 • 0.867 • K 0.010 1.0911 0.0111 1. 075 0.013 1.092 0.014 1.095 0.021 1.076 0.023 1.062 0.012 1.072 0.005 1.070 0 8.000 . 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 •

/IN 30.68 30.29 J0.67 29.94 27.72 28. I l 30.55 17.95 AO 68.40 68. 36 68.10 68.71 70,30 69.70 68.31 81. 57 OR 0.92 I. 35 1.23 I. 34 1.98 2.17 I. 111 0.49 CH 0.0 o.o 0.0 0.0 o.o o.o 0.0 o.o r/H 2.2•14 0.538 I. 534 2.653 0.563 5.625 0.422 0.816 F/fH 0.692 o. 350 0.605 0.726 0. 360 0.849 0.297 0.449

17 23463 21 26826 18 247211 22 27667 19 25565 23 28508 20 25985 24 30190

Page 160: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHrLC 23 F[LOSPAR ANALYS[S 25 26 27

5102 61. 23 62.113 60.02 J 102 0.03 0.07 -0.01 A203 22. 311 23.03 21. 56 HO 0. 18 o. 32 0.011 HliO 0.111 0.111 -0.110 HCO 0.08 0.16 -0.00 CAO 6.115 7 .115 5.115 OAO 0.0 0.0 o.o liA20 8.38 8.96 7.80 K20 0,26 o. 36 0. 17 r 0.0 0.0 o.o CL o.o o.o 0.0 SUH 98.92 102.80 95.011 -0= F+CL 0.0 0.0 0.0 SUH 98.92 102.80 95.011

SI 2. 761 • 2.728 • 2.797 • Al. 1, 185 • 1.186 • 1. 1811 • T 1 0.001 3.9117 0.002 l.916 -0.000 3.980 re 0.007 • 0.012 • 0.002 • HN 0.000 • 0.001 • -0.000 • ......

V1 HG 0.005 • 0.010 • -0.000 • V1 CA 0.0 1.072 0.0 1. 150 0.0 0.988 DA 0.0 • 0.0 • o.o • NA o. 733 • 0.759 • o. 705 • K 0.015 1.072 0.020 1. 150 0.010 0.988 0 8.000 • 8.000 • 8.000 •

AN 29.41 30.92 27.58 AO 69. 16 67.31 71.112 on 1.-2 1. 78 1.00 CH 0.0 o.o 0.0

r/H 1. 356 1. 175 1. 5311 r/fH 0.516 0.5110 0.605

25 AVERAGE 27 AVERAGE MINUS SIGMA 26 AVCRAGE PLUS SIGMA

Page 161: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPLC 23 FELDSPAR ANALYSES 1 2 3 .. 5 6 1

SI02 611. 13 611. 38 611. 43 611.110 611.118 611.63 611. 311 I IO;> 0.03 0.05 0.06 0.07 0.05 0.07 0.011 A20J 16. T1 16.61 17.00 16.62 16.75 16.91 16.59 ,co 0.05 0.06 0.26 0.21 0.16 0.27 0.05 HNO 0.011 0.02 0.03 0.03 0.03 0.011 0.02 MGO o.or, o. 12 0.06 o.o 0.06 0.10 0.01 CAO 0.1111 ' 0.011 0.08 o.u<, 0.07 0.09 0.05 UAO o.o o.o o.o 0.0 o.o 0.0 0.0 NA20 0. 33 0.511 0.69 0.60 0.511 0.67 0.111 K20 17. 17 16.61 16.00 16.211 16.50 16.95 16.06 r O.tl ll.O 0.0 o.o o.o o.o 0.0 Cl. 0.0 o.o 0.0 0.0 0.0 o.o 0.0 SUH 99.26 98.113 98.61 98.29 98.65 99.71 97. 58 -0= f+CL O.ll 0.0 o.o o.o 0.0 0.0 0.0 SUH 99.26 98.113 98.61 98.29 98.65 99.71 97.58

SI 3.0311 • 3.036 • 3.027 • 3.039 • 3.0311 • 3.020 • 3.0118 . Al 0.926 . 0.923 • 0.9111 • 0.9211 • 0.929 • 0.931 . 0.926 • Tl 0.001 3.961 0.002 3.961 0.002 3.970 0.002 3.965 0.002 3.9611 0.002 3.953 0.001 3.976 I[ 0.002 • 0.002 • 0.010 • 0.011 • 0.006 • 0.010 • 0.002 • ~IN 0.002 . 0.001 • 0.001 • 0.001 . 0.001 • 0.001 • 0.001 . HG 0.003 • 0.008 • 0.001, • o.o • 0.0011 • 0.007 • 0.001 • ...... CA 0.0 1.068 o.o 1.062 o.o 1.0111 o.o 1.0117 0.0 1.055 0.0 1.0911 0.0 1.015 V1 DA 0.0 • o.o • o.o • 0.0 • 0.0 • 0.0 • 0.0 • O's NA 0.030 • 0.0119 • 0.063 • 0.055 • 0.0119 • 0.061 • 0.037 • K 1.026 1.068 0.999 1.062 0.959 1.0111 0.977 1.0117 0.990 1.055 1.010 1.0911 0.911 1.015 0 6.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 .

AN 0. Ill 0.19 0.39 0.29 o. 33 0.110 0.211 AB 2.83 II. 70 6.13 5. 30 11.72 5.67 3.70 on 96. 7'; 95.11 93.118 911 .111 911.95 93.93 96.05 CN o.o 0.0 o.o o.o o.o 0.0 o.o f/H 1.016 0.375 2.715 2.653 1,858 1.696 2.950 f/fH 0.5011 0.273 0.731 0.726 0.650 0.629 o. 7117

1 ll5312KSPARS 5 AVERAGE 2 112350 6 AVERAGE PLUS SIGMA J 22672 7 AVERAGE HINUS SIGMA 11 210112

Page 162: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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Page 163: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SI\HPL( 25 BIOIITE ANALYSES I 2 3 11 5 6 I II

S102 36.26 l7. 31 37. 52 35.911 36. 10 37. 27 36. 7i, 37. 311 1102 11. 27 11.25 4. 311 4. 31 4.41 11. 36 4. 33 4.39 11703 13 ... 6 13 .67 13.66 13.66 13.50 111. 26 I 3. 74 lit. 0 I l[O 71. 23 21.30 21. 39 22.03 20.50 20.69 21. 19 21.69 HNO 11.110 o. 32 0. 31, 0. 37 o. 36 0. 33 0. 35 0. 38 HGO 9.911 9. 36 9.59 9.52 10.27 9.116 9.69 10.01 CIIO 11.05 0. 10 0.06 0.05 0.06 0.0 .. 0.116 0.06 DAO ll.O o.o o.o 0.0 0.0 0.0 0.0 0.0 Nl\20 0.05 0.03 0.06 0.07 0.04 0.05 0.05 0.06 t<?O 9.22 9.06 9. 16 9.19 9.07 9.16 9. 15 9.20 r 0.0 o.o 0.0 o.o 0.0 0.0 0.0 0.0 Cl. 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 11?0 o.o 0.0 o.o o.o o.o 0.0 11.0 0.0 SUM 911.90 95.42 96.20 95.lfO 94.31 95.62 95.31 97.20 -o·, r +CL 0.0 0.0 o.o o.o o.o o.o 0.0 0.0 SUH 911 .90 95 ... 2 96.20 95.40 911. 31 95.62 95.31 97 .20

SI 5.631 . 5. 734 . 5. 721 • 5.578 • 5.619 • 5.697 . 5.6611 • 5.651 . ...... Al. 2. 369 6.000 2.266 6.000 2.279 11.000 2.422 6.000 2.361 8.000 2. 303 6.000 2.336 8.000 2. 349 11.000 \Jl Ill. (). 091 • 0.2l0 • o. 179 • o. 1 llf • 0.095 • 0.265 . o. 161 • o. 11f7 • 00 TI 0.1,99 . 0.1,91 • 0.502 • 0.503 • 0.516 • 0.501 • 0.502 .. 0.499 .. rr 2. 1'> 7 . 2. 736 . 2. 7211 • 2.656 • 2.668 • 2.6115 . 2. 732 • 2.1i.2 • HN 0.0';] . 0.042 . 0.044 .. 0.049 • o.oi.1 • 0.0111 • 0.046 . 0.049 • HG 2.301 5. 706 2. llflf 5.62 .. 2. 160 5.633 2.200 5. 722 2.362 5.709 2. 155 5.609 2.226 5.667 2.255 5.691 CA ll.006 . 0.016 • 0.013 . 0.008 • 0.010 • 0.007 . 0.010 . 0.014 • NII 0.015 • 0.009 • 0.018 • 0.021 • 0.012 • 0.015 • 0.015 . 0.016 • k 1. 626 . 1. 760 • 1.762 • 1.617 • 1.801 • 1. 786 • 1.796 • I. 774 • BIi 0.0 1. 650 0.0 1.605 0.0 1.612 0.0 1.847 0.0 I. 623 o.o 1.807 0.0 1. 824 0.0 1.606 Cl. o.o • 0.0 • o.o • 0.0 • o.o • 0.0 • 0.0 • 0.0 • r 0.0 . 0.0 • 0.0 • o.o • o.o • o.o • 0.0 . 0.0 . II 0.0 0.0 0.0 o.o 0.0 o.o o.o 0.0 0.0 0.0 0.0 0.0 o.o 0.0 o.o 0.0 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 . 22.000 . 22.000 • F/H 1.221 1.296 1.272 1.320 I. 1i,o 1.2117 I. 2116 1.238

r/rH 0.550 0.565 0.560 0.569 0.533 0.555 0.555 0.553 I 2511 8101 I TE 5 25C BT 2 25ll Bl 6 25C BT 3 258 Bl 7 AVERAGE 4 25 BT 8 AVERAGE PLUS SIGMA

Page 164: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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SAHPl[ 25 BIOTlTC ANALYSES 1 2 J 11 5 6 7 8

510? 18. 01 36. 7', 37. 111 36.87 36.52 36.117 36.97 37.lf9 i 102 11.111 J.99 11.IIO J. 97 ri.21 If.OU If. 17 11, 37 A20J 111. 38 111. 311 13.96 14. 39 llf.03 111.00 "' · 18 llf. 37 rco 21. 51f 20.90 20.211 22.11 20.911 20.61f 21.06 21.67 HNO 0.112 o. 35 0. l I 0.113 o. 37 0.111 0. 38 0.42 HGO 8.9~ 9.91f 10. 15 8.88 9.23 9.61 9.116 9.91f CAO 0.10 0.05 0.05 0.08 0.03 0.03 0.06 0.08 RAO u.o ll.O 0.0 O.ll 0. 31 0.17 0.08 0.20 NA20 0.U6 0.05 0.06 0.02 0.06 0.05 0.05 0.06 K2U 9. 16 9.81 9.lf7 9.41f 9. 30 9.42 9.113 9.63 r 0.0 o.o 0.0 0.0 o. 18 0.82 0.27 0.61f CL o.o 0.0 0.0 0.0 o. 16 0.16 0.115 0.13 1120 0.0 0.0 o.o 0.0 -0.lf I -0.42 -o. 111 -0. 31f SUH 97 .OJ 96. 18 95.82 96.19 95.59 95. 36 96.03 98.68 -0; f+Cl 0.0 o.u 0.0 0.0 0. 36 0. 38 0.1?. 0. 30 SUH 97.03 96. 18 95.82 96.19 95.23 91f.91 95.90 98.311

SI 5.735 . 5.622 . 5.675 . 5.657 • 5.601f • 5.602 • 5.6~0 • 5.582 • ..... Al. 2.265 8.000 2. 378 8.000 2.325 8.000 2.31f3 11.000 2.396 8.000 2. 398 8.000 2. 350 8.000 2.lf 18 8.000 CJ', Al 0.292 • 0.207 . o. 186 • 0.259 • o. 1111 • 0. 136 . 0.2011 . 0. 101f • 0 TI 0.500 • 0.459 • 0.505 • O.lf58 • O.lf93 • 0.462 • O.lf8ll • O.lf89 • re 2. 718 . 2.6711 • 2. 5811 • 2.837 • 2.687 • 2.651 • 2.692 • 2.698 . HN 0.0511 • 0.045 • 0.0110 • 0.056 • 0.048 • 0.053 • O.Olf9 . 0.0511 • H(; 2.013 5. 571 2.267 5.652 2. 309 5.6211 2.031 5.61f2 2. 111 5.lf80 2.200 5.502 2. 155 5.580 2.206 5.550 CA 0.016 • 0.008 • 0.008 • O.OIJ • 0.005 • 0.005 • 0.009 . O.Oll . NA 0.018 • 0.015 • 0.018 • 0.006 • 0.0111 • 0.015 . 0.015 . 0.019 . K 1. 763 • 1. 9111 • 1.841f • 1.8118 • 1.820 • 1. 8115 • 1.839 • 1.829 . RA 0.0 1.797 0.0 1.937 u.o 1.1170 o.o 1.867 0.019 1.862 0.010 1.876 0.005 1.868 0.012 1.872 CL 0.0 • 0.0 . 0.0 • 0.0 • 0.0112 • O.Olf2 • 0.014 . 0.032 • r o.o . 0.0 • o.o • 0.0 • o. 379 • 0. 398 • 0.129 . O. 303 . II 0.0 o.o o.o 0.0 0.0 o.o 0.0 0.0 -0.1120 0.0 -0.440 0.0 -o. 1113 0.0 -O. ll6 0.0 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • f/M 1. 377 1.200 1.136 1.lf25 1.296 1.229 1 .272 1.21111

f/fM 0.579 0.5115 0.532 0.588 0.5611 0.551 0.560 0.555 1 250 FRC[ OIOTITr 5 25 FR[[ BT NCWO 2 25C fR[[ RT 6 SAHE GRAIN 3 25 C fRH OT 7 AV[RAG[ II 25C fR[[ BT 8 AV[RAG[ PLUS SIGMA

Page 166: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAMPL[ 25_ ?

SIU;> 36. '•'• TIO? 3. 98 A203 13.99 rco 20.1,5 HNO 0.11, HGO 8.98 CAO 0.(1.l 0110 -0.01, HA~'O 0.011 K20 9.211 r -u. 11 CL -0.02 1120 0.06 SUH 93. 38 -0; f +CL -0.05 SUH 93. ~]

SI 5. 77.1 . Ill. 2.219 8.UllU Ill 0. ]09 • TI u.11 TU . re 2.(,85 . Hfl 0.01,5 . HG 2. 101 5.611 CA 0.005 • NII 0.011 . K 1. 8119 • BIi -0.002 1.863 Cl -0.006 . r -0.055 . II 0.061 0.0 0 22.000 .

f/H 1.299 f/fH ll.565

9 AVERAG[ HI NUS SI CJ-IA

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Page 167: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIMl'I I ?~ 810111[ ANALYSES 1 2 J ,, 5 6

S IO?. Jti.91 J<,. I 1 J(,.40 ]6.49 36. 811 36. 18 I 102 ,, .28 4.06 4.06 ,,. 1J ,,. 24 If. OJ 11?.03 111. 69 .... J{, 111. 09 111. 38 14.6] 14. 1J f[C) ;> 1. 11 20.67 20. 76 20.85 21.04 20.66 MNO 0. ]II 0. ]II 0. ]II 0. 34 o. J4 0.34 l~GO 9.62 9.40 9.26 9.11] 9.57 9.28 CAO 0.06 O.OJ O.OJ 0.04 0.05 O.OJ fl/\() II.II 0.27 0.50 0.26 0.46 0.05 N/120 11.01, 0.08 0.09 0.07 0.09 0.05 K20 9.06 9.2] 9, 1,, 9. 14 9.21 9.07 r o.o 0.92 o. 11, 0.55 0.95 0. 16 CL o.o 0.18 0.17 0.12 0.20 O.OJ 1170 o.o -0.48 -0.]9 -0.29 -0.50 -0.08 SUH 96. 11 95.2] 95. 19 95.51 97.09 9J.9J -0° f+CL 0.0 O.lll O.J5 0.26 0.45 0.07 SUH 96.11 94.81 94.84 95.25 96.65 93.86 ......

SI 5.6?.II • 5.559 • 5.610 • 5.598 • 5.551 • 5.647 • 0--Al 2. 376 8.000 2. 4111 8.000 2. ]90 8.000 2.402 8.000 2.449 8.000 2.J5J 8.000 N Al 0.7.61 . 0. 160 • 0.170 • 0.197 • 0.150 • 0.246 • 11 0.490 • 0.469 • o. 1171 • 0.477 • 0.481 • 0.473 • re 2.690 • 2.657 • 2.676 • 2.674 • 2.65] • 2.696 • MN 0.044 • 0.044 • 0.044 • 0.044 • O.OIIJ • 0.0•15 • HG 2. 185 5.669 2. 153 5.484 2. 127 5.1188 2. 155 5.548 2. 152 5,1179 2. 158 5.618 CA 0.010 • 0.005 • 0.005 • 0.007 • 0.009 • 0.0011 • NA 0.01..' • 0.0211 • 0.027 • 0.021 • 0.027 • 0.015 • K 1. 761 • 1.809 • 1. 797 • I. 789 • 1. 772 • 1.806 • BA 0.0 1. 782 0.016 1.855 0.030 1.859 0.015 1.832 0.027 1.835 0.003 1.828 CL 0.0 • 0.047 • 0.044 • 0.030 • 0.051 • 0.009 • r 0.0 • 0.11111 • 0. 361 • 0.268 • 0.454 • 0.077 • II 0.0 0.0 -0.494 0.0 -0.405 0.0 -0.299 o.o -0.505 o.o -0.086 0.0 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 •

r/H 1.251 1.254 1.279 1.261 1.25] 1.270 f/fH 0.556 0.556 0.561 0.558 0.556 0.559

I 25A BT CLUMP 4 AVERAGE 2 25 INCNEWO 5 AVCRAGC PLUS SIGH/\ J SAHE GRAIN 6 AVCRAGC MINUS SIGMA

Page 168: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPLC 25 FClDSPAR ANAlYSCS 1 2 l lj 5 6 7 8

SI02 61.08 59. 7l 57.,,,, 611. 8(, 61.9'1 61.82 61.00 59.36 110;, ll.ll2 0.02 f).011 0.011 0.011 0.1!11 0.01 O.Ol 11;•03 21,. 32 25.29 25.20 21. 32 25.20 25.,,0 23.28 2 ... 72 1 l 0 0. 13 0.11 ll. Ill 0.111 0.07 O.ll? 0. 13 0.06 f,IIIO 0.02 0.0•1 0.011 0.02 0.02 0.02 0.0 0. 39 HGO o. 19 11.0 0.07 0.03 0.06 0.08 0.0 0.0"/ CAO 6. 35 7 .21) 10. 17 2.511 6.55 6.50 6.16 7.23 DAO 0.0 0.0 0.0 0.0 o.o o.o 0.0 0.0 IIA20 , . 83 7. 31 6.92 10.113 8. 12 7.83 8.1111 7.38 K20 II. 38 ll.28 0.03 0.17 0.18 0.15 0.0 .. 0. 19 r ll.O 0.0 0.0 0.0 o.o o.o 0.0 o.o Cl 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 5011 100. 32 99.98 11)0.05 99.82 102. 18 101. 93 99.06 99.113 -0" I +Cl o.o o.o 0.1) o.o 0.0 0.0 o.o 0.0 SUH 100. 32 99.98 100.05 99.82 102.18 101. 93 99.06 99,r,3

SI ;>. 111 • 2.665 . 2.591 • 2.810 • 2.696 • 2.696 • 2. 1110 . 2.668 • ...... Al 1.272 • 1. 330 . 1.339 • 1. 111 • 1.293 • 1.305 • 1.232 • 1.309 • (j\

11 0.001 3.9811 0.001 3.995 0.001 3.931 0.001 3.982 0.001 3.993 0.001 11.002 0.000 3. 973 0.001 3.978 l,.)

I[ 0.005 • 0.0011 • 0.005 • 0.015 • 0.003 • 0.003 • 0.005 • 0.002 • HN 0.001 . 0.002 . 0.002 • 0.001 • 0.001 • 0.001 • 0.0 • 0.015 • HG ll.013 • 0.0 . 0.005 • 0.002 • 0.0011 • 0.005 • 0.0 . 0.005 • CA 0.0 1.015 0.0 0.998 o.o 1. 110 o.o 1.0113 o.o 1.009 0.0 0.98) 0.0 1.039 0.0 1.0211 011 0.0 • 0.0 • 0.0 . o.o • 0.0 • 0.0 • o.o • 0.0 • NA 0.6711 • 0.632 • 0.605 • 0.895 • 0.686 • 0.662 • o. 735 • 0.6113 • K 0.022 1.015 0.016 0.9911 0.002 1.110 0.010 1.0113 0.010 1.009 0.008 0.983 0.002 1.039 0.011 1.0211 0 8.000 • 8.000 . 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 •

AN 30.28 311.68 1111. 75 11. 75 30.52 31. 18 28.68 311,711 118 61. 56 63.71 55. 10 87. 31 68.118 67 .96 71. 10 611. 1"/ OR 2. 16 1.61 0.16 0.911 1.00 0.86 0.22 1.09 CH 0.0 o.o 0.0 0.0 o.o o.o 0.0 0.0

r/H 0.111111 o.o 1. 11117 8.0117 0.111111 o. 773 0.0 3.6117 r;rH o. 307 0.0 0.591 0.889 0.1158 0.1136 0.0 o. 785

1 25 Pll\G 5 25A RIH Of A PlAG 2 25 51\HC Pl.AG 6 25A CORC or PL.AG l 25C Pl.AG 7 25D PlAG II 25C ANOTltCR PlAG 8 CORE PlflHIS

Page 169: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAi-iPL[ 25 FELDSPAR ANALYS[S 9 10 11 12 13 111 15 16

SI02 ~ ~ ,,,, 60. 71 63.08 67.211 63. 111 63.06 61. 71 611. 11 I IO;> 0.02 0.01 0.01 0.01 0.01 0.01 0.02 0.03 A20J 25.116 23. 32 211. 21 21.06 23.96 23.32 23.98 25.33 11.() 0.116 11.08 0.10 0.07 0.09 0.011 0.11 0.20 MNO ll .. 19 0.1111 (),0 0.02 0.04 0.0 0. 10 0.26 MCO o.o~ 11.ll 0.02 O.OJ 0.011 0.05 0.05 0. 10 C/IU 1. (IJ 5. IU 5.31 2.911 5.69 5. ]6 6.(11 7 .111 ll/10 0.11 o.o 0.0 o.o o.o o.o o.o o.o H,VO 7 .111 8.68 8.112 10.04 8.211 8. 19 8.23 9. 18 K211 0. 1 l 0.06 0.09 0.07 0.08 0.27 0.15 0.25 r II.II o.o o.o o.o o.o 0.0 0.0 o.o Cl. 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 511H 99.59 98.110 101. 30 101.118 101. 29 100.30 100. 37 107.28 -o I +Cl II.Cl 11.0 o.o O.ll 0.0 o.o 0.0 0.0 SUM 99.59 98.IIO 101. 30 101.118 101. 29 100.30 100. 37 107.211

SI 2 .66•1 . 2. 71,11 . 2. 756 . 2.911 • 2. 761 • 2. 182 • 2. 733 • 2.685 • Al. I. J;>II • 1.2112 • 1.21,9 • 1.0711 • 1.235 • 1. 212 . 1.252 • 1.250 • ,_. 11 0.001 3.989 0.000 3.986 0.000 11.006 0.000 3.986 0.000 3.996 0.000 3.995 0.001 3.985 0.001 3.936 (J\

" 0.007. • 0.003 • 0.0011 • 0.003 • 0.003 . • 0.001 • 0.0011 • 0.007 • ~ Mil 0.015 • 0.017 • 0.0 • 0.001 • 0.001 • 0.0 . 0.0011 • 0.009 . HG 0.003 • 0.0 • 0.001 • 0.002 • 0.003 . 0.003 • 0.003 • 0.006 • CA 0.0 1.009 0.0 1.031 o.o 0.912 0.0 0.988 0.0 0.977 0.0 0.9711 o.o 1.012 o.o 1. 132 011 0.0 . o.o . o.o • 0.0 • 0.0 • o.o • 0.0 • 0.0 • HI\ 0. 61111 • 0. 761 . 0.713 • 0.843 • 0.699 • 0.701 • o. 101 • 0.7116 • I( 0. (1117 1.009 0.003 1.031 0.005 0.972 0.00•1 0.988 0.004 0.977 0.015 0.9711 0.009 1.012 0.013 1. I 32 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • AN Jl1. 111 24.11] 25.71 13.87 27 .119 26.111 28.50 31. 58

/18 65. 11 75.23 73. 77 85. 73 72.05 72.29 70.611 67 .22 011 0. 15 0.311 0.52 0. 39 0.116 1. 57 0.85 1.21 CH n.o 0.0 0.0 o.o 0.0 0.0 o.o o.o r/H 5. 106 0.0 2.805 1.688 1. 831 0.4119 2 .1171 2.720 r /rH 0.8]6 0.0 0. 737 0.628 0.6117 o. 310 0.712 o. 731

9 row RIM 13 CDGE Pl 10 RIHfllUS 111 25 NOTH Pl ClNTER 11 FINIS Pl CCNICR 15 AVCRACE 12 EOG[ Pl 16 AVERAGE PLUS SIGMA

Page 170: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SMIPl [ 25 1 /

5102 59. Jll 110?. 0.01 A203 22.63 rro ll.03 HNO -0.06 HGO o.nn CAO 11.21 DAO 0.0 NA20 I. 26 K20 0.05 r o.o Cl. u.u SUH 93.45 -0·• f +CL o.o SUH 93.45

SI 2.787 . Al. 1.253 . TI 0.000 4.041 FE 0.001 • MN -0.002 . MG 0.000 . CA 0.0 n.818 BA o.o • NA 0.663 • K 0.003 0.878 0 8.000 •

AN 21,. 14 AB 75.50 OR 0.36 CH 0.0

f/M -7.242 f/fM 1. 160

17 AV[RAG[ MINUS SIGMA

rn.osrAR ANALYS[S

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Page 171: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAM Pl F: 25 f[lDSPAR ANALYSES I 2 3 4 5 6 7 II

S102 6~.15 61. 96 61.7.5 64. 12 63. 70 63. 91 64. w, 64.69 1107. 0.116 U.06 0.0 0.03 0.07 0.01 0.011 0.07 A?.0.1 18. 85 Ill. JO 18.118 18. 79 18.60 18.41 18. 'j7 18. 71 110 0.04 0.011 0.011 0.011 0.04 0.06 0.011 o.o~ l!NO II. 11.1 ll.O ll.O u.011 0.01 0.01 0.(11 O.OJ MCiU u.o (1,011 0.05 O.ll4 0,02 O,UJ 0.011 0,06 CAO 0.01 0.06 0.Ul O.Ol 0.07 0.06 0.011 0.06 DAO 0.0 0.0 0,'j8 0.55 0.55 0.52 0. 37 0.63 NA?.0 0.111 0.43 o. 37 0. 32 0.36 O.'JO 0.40 0.116 K?.0 ,~.26 14.80 15.55

'"· 77 15.09 15.27 15. 17. 15.40

r 0.0 0.0 0.0 0.0 0.0 0.02 o.oo 0.01 Cl. 0.0 0.0 0.0 0.01 0.0 0.0 0.00 0.01 SUH lllO. 0 I 97. 7J 98.15 98. 73 98.51 98. 78 96.66 100.21 •Occ f+Cl 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 SUH 1011.01 97. 73 96. 35 96. 73 98.51 96. 76 98.611 100.21

SI 2. ')99 . 3.002 • 2.960 • 2.989 • 2.985 • 2.990 • 2.991 . 2.9811 . Al. 1.019 • 1.012 . 1.026 . 1.032 . 1.027 • 1.015 • 1.022 • 1.020 . I I 0.002 4.U20 0.002 4.016 0.0 11.U05 0.001 4.022 0.002 4.014 0.000 4.005 0.001 4.014 0.002 4.00/ ....... rE 0.002 • 0.002 • 0.002 • 0.002 • 0.002 • 0.002 • 0.002 • 0.002 . °' HN ().001 . 0.0 • 0.0 • 0.002 • 0.000 • 0.000 . 0.001 . 0.001 . °' HG 0.0 • 0.006 • 0.004 . 0.003 • 0.001 • 0.002 • 0.003 . 0.004 . CA 0.0 0.933 0.0 0.935 0.0 0.985 0.0 0.925 o.o 0.952 0.0 0.974 0.0 0.950 0.0 0.969 RA 0,0 . 0.11 • 0.01 I • 0.010 • 0.010 • 0.010 • 0.007 • 0.011 . NA 0.036 . 0.019 • 0.034 • 0.029 • 0.033 • 0.045 . 0.016 . 0.041 . K 0.893 0.933 0.886 0.935 0.934 0.985 0.878 0.925 0.902 0.952 0.91 I 0. 9111 0.901 0.950 0.906 0.969 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 11.000 • 8.000 •

AN 0.05 0.33 o. 15 0.16 0. 37 0.31 0.23 0. Jl AO 3.92 4.22 3.45 3. 15 3.45 4.68 3. 81 11.24 OR 96.03 95.46 95.31 95.60 95. 12 94.03 95.25 911.25 CN o.o o.o 1.09 1.09 1.07 0.98 0.71 I. 111

f/H -7 .242 0.261 0.449 1.129 1.406 1,317. 0.896 0. 739 f/fH 1.160 0.219 0.310 0.530 0.584 0.567 0.472 0.425

1 250 KSPAH 5 RIH KSP 2 258 RASl[R or KSrAR 6 CORE 3 25 EOG[ KSP N[WO 7 AVERAGE ~ CORE·•SHAl.L KSP II AVERAGE PLUS SIGH/I

Page 172: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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Si\Hrl [ 25 AHrlll BOLE ANAL VS[S I 2 J II 5 6 1 8

S102 ~0.~1 116.28 116.99 1111.58 116.21 115.911 116. 75 118.58 1102 0.511 1.02 1.0J 1.118 1. 29 I. 22 1.09 1.110 A20J ,,.66 6.81 6.05 7 .119 7.0J 6.116 6.112 7.32 I f 11 17. 911 18.61 18.18 19.06 111. 61 17 .9J 18.'ll 111.82 HNII "· 11 o. 70 o. 72 0.80 0.75 o. 70 o. 111 o. 711 Hc:o 11. 111 Ill. 1,2 10.61 9.60 11. 12 9.75 10.119 11. 17 CAO 11. 5J 11. J".> 11. 611 11.12 11.40 11. 17 11. J 7 11. 55 DAO 0.0 0.0 0.0 o.o o.o 0.0 o.o o.o Ni\20 0.6J 0.91 0.82 1. 29 1. 17 I, 17 1.00 1.21 K?.O o. J6 0.66 o.66 0.90 o. 76 0.40 0.62 0.81 r 0.0 0.0 O.ll 0.0 o.o 0.0 0.0 11.0 CL 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 11?.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 SUM 98.111 96. 76 96.90 96.J2 98. 36 911, 74 96.91 101.66 ·O= F+CL 0.0 o.o o.o o.o 0.0 o.o 0.0 0.0 SUM 98.111 96. 76 96.90 96. 32 98.36 911. 711 96.91 101. 66

SI 7 .11111 • 7.0J6 . I. 1211 • 6.868 • 6.910 • 7. 110 • 7.080 . 7.0IJ . AL o.~53 8.000 0.96'• 8.000 0.876 8.000 I. 1 J2 8.000 1.070 8.000 0.890 8.0110 0.912 8.000 0.98"1 11.000 -Al. ll.257 • 0.256 • 0.205 • 0.228 • 0. 172 • 0.288 • o. 2111 • 0.258 • "' 11 0.055 • 0. 117 . o. 117 . o. 171 • 0.145 • 0.1112 . 0.1211 • o. 152 • co f[ 2.217 . 2. J66 • 2. JJO • 2.1156 • 2. 3J3 • 2.121 . 2. J36 . 2.272 • MN 0.096 . 0.090 . 0.092 . o. 1011 . 0.095 • 0.092 . 0.095 . 0.095 . MG ?..521 5. 1116 2.361 5,190 2. 198 5. 1111 2.2011 5. 163 2.11811 5.230 2.2119 5.091 2. J71 5. 161 2.IIOJ 5.179 CA 1. 821 • 1.8119 • 1.891 • 1.835 • 1.831 • 1 .852 • 1 .8116 • 1. 787 • NA 0. 180 . 0.268 . 0.2111 . 0.385 • 0. JIIO . 0.351 . 0.29J • 0, JIiii • K 0.068 • 0. 128 • 0. 128 • 0.177 • o. 1115 • 0.079 • 0. 121 • 0.150 . DA 0.0 2,069 o·.o 2.2115 0.0 2.259 0.0 2. 398 0.0 2. 316 0.0 2.282 0.0 2.260 0.0 2.280 CL 0.0 • 0.0 • 0.0 • 0.0 • o.o • 0.0 . 0.0 . 0.0 • r 0.0 . 0.0 • 0.0 • 0.0 • 0.0 • o.o • o.o • 0.0 . H 0.0 0.0 0.0 o.o o.o 0.0 o.o o.o o.o o.o 0.0 0.0 o.o 0.0 o.o 0.0 0 2J. 000 • 21.000 • 2J. 000 • 23.000 • 23.000 • 23.000 . 23. 000 . 23.000 • CAA 27. JI 27. 7J 28. 17 27.81 27. 15 28.114 21. 11 27. 25

ANT 37.88 35.112 35. 7l 33,IIO 16.811 311.51 35.66 16.65 GRU 311, 76 36.85 36. 10 38.79 36.01 J7 .011 36.57 36. 10

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I 25C IIB 'FR[[' 5 250 FR[[ HB 2 25C 110 6 25C FREE AHPII SEARCII 3 250 FREE 118 1 AVERAGE II 250 FR[[ IIB II AV[RAG[ PLUS SIGMA

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SIIHPL [ 25 AHPIII llOLC ANAL YS[S 1 2 J 11 5 6 7 8

SIU?. •16. I 7 45.22 .• , .. 50 116.01 48.J5 46.05 47.J5 44. 75 I IO? 1.1111 I, 6r> 1.1111 1. 18 0.59 1.25 1. 62 0.89 .l\?0.1 8. ')5 9.01 8.69 6. 11 5.21 7 .65 9. 1 I 6. 18 110 19. JI 19,'jl1 1').27 18. J5 17 .94 18.89 19.5J 18.26 tlNCl 0. (,(, o. 11 0. 72 0.60 0.66 0.68 0. 111 0.62 H(:O 9,0,,? 9,'.iJ 9, ]f, 9.88 10,119 9.87. 10. JII 9,25 CIIO I I. 5' I 1,115 11.61 11.61 11. 76 11, 60 11, 711 11. 50 UAO 0.0 0.0 0.0 0.10 0.04 0,03 0.07 -0.01 NA20 1. 28 1.23 1. 37 1. 01 0.78 1. 13 1. J5 0.92 K?O 11.95 0.99 0.99 0.72 0.46 0.82 1.03 0.61 r 0.0 0.0 0.0 0. 32 0.28 0. 12 0.27 -0.03 Cl 0.0 0.0 0.0 0.11 0.05 0.03 0.08 -0.01 1120 0.0 0.0 0.0 -o. 18 -o. 111 -0.06 -o. 15 0.02 SUH 99.H 99.lt'.", 91.9'.i 96.112 96.81 98.01 lOJ.06 92.96 -0= F •CL 0.0 0.0 0.0 0.16 0. 13 0.06 o. 13 -0.01 SUH 99. J7 99.45 97 .95 96.26 96. 74 97 .95 102.93 92.98

SI 6.869 • 6.743 . 6. 751 • 7.020 • 7.281 • 6.932 • 6. 777 • 7. 103 . Ill 1. 131 8.000 1. 251 8.000 1.2119 8.000 0.980 8.000 0.719 8.000 1.068 8.000 1. 22] 8.000 0.897 8.000 Al o. 367 • 0.336 • o. 305 • 0.226 • 0.205 • 0.288 • o. 314 • 0.259 • II o. 157 • 0. 185 • 0.164 • o. 135 • 0.067 • 0.1112 • 0. 1711 • 0. 106 • ...... F[ 2.1110 . 2.437 . 2.11115 • 2.341 . 2.259 • 2. 379 . 2. 337 . 2.11211 • -..J

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CAA 28.70 28.22 28.85 28.92 28.38 28.61 27.88 29.40 /INF 32.51 32.68 J2.J6 34.2J 36.56 J3.68 311. 42 32.90 GRU 38.80 39. 10 38.79 36.85 J5.05 J7, 71 37. 71 37. 70

F/H 1. 1911 1. 196 1. 199 1.017 0.959 1. 119 1.096 1. 1•16 F/FH 0.5114 0. 5115 0.5115 0.518 0.489 0.528 0.523 0. 530,

1 25A 110 r ROM CCN1 [R or INCLUSION 5 25 INC AMP 2 25A 110 INCLUSION 6 AV[RAG[ J 25A llll INCLUSION 7 AV[RAG[ PLUS SIGMA 4 25 INC AHPN[\10 8 AV[RAG[ HINUS SIGMA

Page 176: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHrL[ 27 r[LDSPAR ANALYSES 1 2 l 11 5 6 7 8

SIU? (,II. 19 61. 12 58.116 59. lO 511.65 59.07 60.26 61.41 T 10;, ll .11] 0.05 0.011 0.03 0.04 0.02 O.lll 0.02 A?Ol 25.08 211.48 26.62 26.36 26.25 25.98 25.86 23.98 I C:O 0.08 0.06 0. 19 o. 12 o. 1 l o. 10 0.06 0.0 tlNO 0.07 0.0 0.01 0.01 0.02 0.04 0.02 0.0 HCO 0.01 0.0 o.o 0.01 0.0 0.0 0.06 o.o CI\O 6.8•1 6.•19 11.119 8.22 8.00 8.23 1.27 5. 16 BAO 0.0 o.o 0.0 o.o 0.0 o.o 0.0 0.0 NA?O 7. 76 7 .62 6.60 6.96 6.87 7 .Ol 7.66 8. 16 k?O 0. 16 o. 1l O. ll 0.25 0.34 0.18 0.09 0.08 r 0.0 o.o o.o o.o 0.0 o.o 0.0 0.0 Cl. o.o o.o 0.0 o.o 0.0 0.0 0.0 0.0 SUI~ JOO. 17 99.95 101. 111 101. 26 100.30 100.65 101.29 99.41 -0 • f+CL o.o 0.0 0.0 0.0 o.o 0.0 0.0 0.0 SUH 100.17 99.95 101.14 101. 26 100. 30 100.65 101. 29 99. 41

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AB 66.64 67.48 57.35 59.66 59.66 60. 10 65.27 75. 10 OIi 0.90 0. 76 1.89 1.41 1.911 1.01 0.50 0.45 CH 0.0 0.0 o.o 0.0 0.0 0.0 0.0 0.0 r/H 5.625 o.o 0.0 7.301 0.0 0.0 o. 750 0.0 f/fH 0.849 o.o 0.0 0.880 o.o o.o 0.429 0.0

I IIIAV X PLAG 110 I 30116 39814 5 29662 388 77 2 311002 39580 6 29549 386112 3 29889 39345 7 29435 38408 II 29775 39 II I 8 29322 38173

Page 177: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SMll'I.[ 71 F[LOSPAR ANALYS£S 9 10 11 12 13 14 1'.", 16

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AN 36.55 311.110 38.115 311.76 39.00 31.113 52.25 119.33 AB 62.88 611.118 60.26 63.50 59.93 67 .110 116.87 119.86 OR 0.56 0.72 1.29 1. 711 1.07 1. 17 0.88 0.62 CN 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0

r/H 5.625 1.964 6.762 7.301 o.o 5.651 1.262 1.010 r;rH 0.849 0.663 0.871 0.880 0.0 0.850 0.5511 0.502

9 29208 37939 13 28642 36 76 7 10 29095 l7 705 14 EDGE PLr IN IS 11 28868 37236 15 27 Pl CORE 12 28755 37001 16 TOW RIH

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SAHl'l [ 7.1 F[LOSPAR ANALYS(S I 2 J •1 5 6 7 8

S107 63. ?6 61.09 65.03 63.19 611.09 67.79 66. 18 66.11 I 10? ll. OJ o.oJ 0.05 0.07 0.03 0.04 0. 10 o.o A:'03 18. 17 19.00 18.58 18.16 18.82 19.09 18.60 19.00 110 11.01 0.0 0.06 0.04 0.05 o.o 0.05 0.03 MIW 0.0 o.n 0.0 0.04 0.011 0.0 0.01 0.02 MC.II 0.05 0.0 0.0 0.02 0.0 0.0 o.o 0.03 C:AO 0.06 0.12 0.04 0.11 0.05 0.10 0.0] 0.14 IIAO IJ.O 0.0 o.o 0.0 0.0 0.0 0.85 I. 04 NA20 0.41 8.46 1.02 0.66 1. 50 10.70 0.53 0.44 K20 15.6Z 4. 70 14.95 15.20 14.33 o. 79 14. 79 14. 32 r 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 Cl 0.0 o.o 0.0 o.o 0.0 0.0 0.0 0.0 SUH 98.31 99.110 99.73 98.09 98.91 98.51 101. 14 101.13 -o• r+ct. o.o o.o o.o 0.0 0.0 o.o 0.0 0.0 SUH 98. 31 99,IIO 99. 73 98.09 98.91 98.51 101. 14 101.13

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AN 0.31 0.57 0.20 0.57 0.25 0.119 IJ. 16 o. 76 AB 3.82 72.82 9.38 6. 16 13.69 911. 90 5.07 . 4. 34 OR 95.87 26.61 90.42 93.28 86.06 4.61 93. 12 92.83 CN 0.0 o.o 0.0 0.0 0.0 0.0 1.64 2.07

F/~1 0.112 1. 750 3.182 2.259 o.o 5.651 1.262 0.9110 f/fH 0.101 0.636 0.761 0.693 0.0 0.850 0.558 0.485

I 27 2 KSP 5 27 2 KSP 2 Z1 2 KSP 6 27 2 KSP l 27 2 KSP 7 NfW KSP 4 27 2 KSP 8 SAM£ KSP

Page 180: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPL[ 27 f(lOSPAR ANALYSES 9 10 11

SIO? 6'i.~O 66.92 611.09 1102 n.u11 0.07 O.U2 A20] 18.68 19.02 18. ll II O II.Ill o.n~ ll.01 ~mo 0.01 0.03 -0.00 MGO 0.(11 0. (13 -0.01 GAO 0.011 o. 12 0.011 HAO 0.211 0.6~ -o. 18 NA:>O 2.96 6.84 -0.91 K20 11.811 17. 19 6.48 r 0.0 0.0 0.0 Cl o.n o.o 0.0 SUH 99.111) 111). 93 81.88 -Os r+CI. 0.0 0.0 o.o SUH 99,110 110.93 87 .88 . . 3. 129 • ......

SI 2.999 2.883 -J Al 1.007 • 0.966 • 1.055 • V, Tl 0.002 11. 008 0.002 3.851 0.001 11. 185 fE 0.001 . 0.002 • 0.000 • HN 0.001 • 0.001 • -0.000 • HG 0.001 • 0.002 • -0.000 • CA 0.001, • 0.006 • 0.002 • !IA 0.004 • 0.011 . -0.003 . NA 0.263 • 0.571 • -0.086 • K 0.691 0.965 0.945 1. 537 0.4011 0.316 0 8.000 . 11.000 • e.ooo •

AN CJ. 41 0.36 0. 71 AB 27.34 37.28 -27. 21 OR 71. 81 61.65 127.56 CN 0.44 0. 71 -1.06

f/H 1.972 1. 535 3.182 f/FH 0.663 0.606 0. 761

9 AVERAGE 11 AVERAGE HINUS SIGHA 10 AVERAGE PLUS SIGHA

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SI\HPL[ 27 BIOTIJ[ ANALYS[S 1 2 3 4 5 6 7 8

5102 36.01 J'.j, 75 36.09 35. 79 35.61 35.63 36.10 35. 16 110;> ,,.1;, 11.7.8 11. 31, 11.28 4. 16 4.22 4. 17 4.15 1120} 111. 211 111. 4 7 14. 114 13.86 13.97 14.26 13.80 13.91 I [O ;>0.98 20.90 20.95 20.29 21,117 21.112 21. 28 21.15 HIIO 0 .... o.~o 0.112 0.113 0.41 0.43 0.111 0.142 11GO 9.?3 10.22 10. 10 10.42 10.20 10. 39 10.26 10.25 (;110 U.05 0.05 U.O'j 0.05 0. 11 0.09 0. 111 o. 13 n110 0.0 0.0 o.o o.o o.o o.o o.o o.o IIA20 (). 11, 0.16 0. 13 0.10 0.19 0. 19 0.20 0. 19 ~20 9.011 9.06 9.08 9.29 9. 13 9.02 9.05 9.06 r 0.0 o.o 0.0 o.o 0.0 0.0 o.o o.o CL 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 1120 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SUH 911.92 95. 39 95. 30 94.51 95.25 95.65 95.111 94.42 ·O= r+CL 0.0 0.0 o.o 0.0 0.0 o.o 0.0 o.o SU~I 911. 9;> 95.39 95.30 94.51 95.25 95.65 95.41 94.42 ......

SI 5.')77 . 5.514 • 5. 567 • 5.566 • 5. 5211 • 5.496 • 5.576 • 5.502 . -...J AL 2.4;>3 8.000 2.486 8.000 2.433 8.000 2.434 8.000 2.476 8.000 2.504 · 8.000 2.11211 8.000 2.1198 8.000 °' Al. o. 176 • 0. 1143 • 0. 138 • 0.106 • 0.078 • 0.088 • 0.088 . 0.067 • TI 0.480 • 0.496 • 0.503 • 0.501 . 0.485 • 0.490 . 0.484 • 0.488 . rE 2.717 • 2.696 • 2.703 • 2.639 • 2. 785 • 2. 763 • 2.749 • 2. 768 • HN 0.054 . 0.065 • 0.055 • 0.057 • 0.054 • 0.056 . 0.054 • 0.056 . HG 2.2n 5.719 2.349 5.750 2. 322 5. 721 2.415 5. 717 2.359 5.761 2. 389 5.786 2.362 5. 737 2.391 5. 770 CA ll.008 • 0.008 • 0.008 • .0.008 • 0.018 • 0.015 • 0.023 • 0.022 • NII 0.042 . 0.048 • 0.039 • 0.030 • 0.057 • 0.057 . 0.060 . 0.058 . K 1. 786 • 1. 782 • I. 787 • 1. 8113 • 1.807 • I. 775 • 1. 783 • 1.808 • 811 0.0 1.836 0.0 1.838 0.0 1.834 o.o 1. 881 0.0 1.882 0.0 1.846 o.o 1.866 0.0 1.888 CL 0.0 • o.o • 0.0 • 0.0 • o.o • o.o • 0.0 • 0.0 • r 0.0 • o.o • o.o • 0.0 • 0.0 • o.o • 0.0 . o.o • II 0.0 o.o 0.0 o.o 0.0 0.0 0.0 0.0 o.o 0.0 o.o 0.0 0.0 o.o 0.0 o.o 0 22.000 • 22.000 . 22.000 • 22.000 • 22.000 . 22.000 • 22.000 . 22.000 .

r /H 1.209 I. 175 1. 187 1. 116 1. 204 1. 180 1. 186 1. 181 r;rM 0.547 0.540 0.543 0.527 0.546 0.5111 o. 543 0.541

1 27 ) BT 5 27 OlrFERCNT BT 2 51\H[ GRAIN 6 SAHE GRAIN 3 SAM[ GRAIN 7 SAME GRAIN 4 SAH[ GRAIN 8 SAHE GRAIN

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S1114rL[ 21 BIOTIT[ ANALVSlS 9 10 11 12 13 Ill 15 16

S102 36.46 36. <'3 36.42 31.69 37.91 36.22 36.96 35.46 r 102 11. 211 11.25 3. 16 3. 71 3.79 4.11 11. 3? 3.91 11201 111.011 13.76 13.61 llt.60 14. 35 14.06 Ill. 36 13.80 I ro 20. 70 21. 13 2C. 71 20.41 20.29 20.90 21. 28 20.52 MNU u.110 0.117 0.110 0.37 0. 36 0.112 o.••5 o. 39 HGO 10. 36 10.37 10.110 9.97 10.02 10.22 10.39 10.06 C/10 0, 15 o. 12 0.09 o. 13 0.14 0.10 0.14 0.06 11110 0.0 0.0 0.0 0. 17 0.19 0.03 0.09 -0.04 N/120 0.19 0.16 0. 15 0.25 o. 19 0.17 0.21 o. 14 k?O 9.02 9.16 9.10 9.03 9.07 9.09 9.16 9.01 r 0.0 0.0 o.o o. 36 0.33 0.05 o. 16 -0.07 Cl. 0.0 o.o 0.0 0.06 0.10 0.01 0.05 -0.02 1120 o.o 0.0 0.0 -0.20 -o. 18 -0.03 -0. 10 0.04 SUM 95.58 95.67 911.66 96.65 96.56 95. 36 97. 50 93.26 -Os f+CL 0.0 o.o 0.0 0.18 0.16 0.03 0.09 -0.04 SIIH 95.58 95.67 94.66 96.117 96.42 95.36 91.112 93. 30

SI 5.596 . 5.579 . 5.651 . 5.661 • 5. 716 • 5.581 • 5.570 . 5.593 . ...... Al 2.402 6.000 2.421 6.000 2.349 6.000 2. 319 8.000 2.284 8.000 2.419 6.0110 2.430 8.000 2.407 6.000 -...J Al 0. 1 ]7 . 0.079 . o. 139 • 0.275 • 0.265 • 0. 137 . 0.119 • o. 157 • -...J Tl 0.1189 . 0.492 • 0.441 • 0.421 • 0.430 • 0.477 . 0.489 • 0.464 • f[ 2.657 • 2. 721 • 2.687 • 2.580 • 2.558 • 2.694 . 2.681 . 2.707 • Mil 0.052 . 0.061 • 0.053 • 0.0111 • 0.049 • 0.055 . 0.058 • 0.052 . MG 2.370 5.705 2.380 5. 734 2.405 5. 724 2.240 5.563 2.252 5.553 2. 346 5. 710 2.332 5.678 2. 365 5. 744 CA 0.025 • 0.020 • 0.015 • 0.021 • 0.023 • 0.017 • 0.022 • O.Oll • tiA 0.1151 • 0.046 • 0.045 • 0.073 • 0.056 • 0.051 . 0.061 . 0.042 . k I. 166 • I. 799 • 1.801 • I. 736 • 1. 7114 • 1. 786 . 1.759 . 1.813 • llA u.o 1.647 0.0 1.661 0.0 1.661 0.010 1.640 0.011 1.634 0.002 1.655 0.005 1.846 -0.002 1.863 CL 0.0 • o.o • 0.0 • 0.020 • 0.026 • 0.004 • 0.012 • -0.005 • r ll.O • 0.0 • 0.0 • 0. 181 • o. 157 • 0.027 • 0.087 . -0.037 • II 0.0 0.0 0.0 0.0 o.o 0.0 -0.202 0.0 -0.183 o.o -0.030 0.0 -0.099 0.0 0.042 o.o 0 22.000 • 22.000 • 22.000 * 22.000 * 22.000 * 22.000 • 22.000 • 22.000 * f /H 1.143 1. 169 I. 139 1.173 1. 156 1. 171 I. 174 1. 167

r /rH 0.533 0.539 0.533 0.540 0.537 0.539 0.540 0.538 9 rRcc ororrn 13 SAM[ BT

HJ SIIHE r.1111 IN 14 AVCRAG[ 11 BT INT[RGR WI AHP 15 AVCRAG[ PLUS SIGH/I 1? N[W 81 fRH 16 AV[RAG[ MINUS SIGMA

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S/\HrL[ 2 7 AflPIII BOLE ANAL YSCS 1 2 3 11 5 6 1 8

SIO?. l1(,. l1J 47. 10 119.00 118. 32 118.00 47. 77 48.66 46.66 110?. 0.96 0.87 o. 78 0.93 0.96 0.90 0.97 0.63 11?.0l 5.61 5.25 5. 17 6.42 6.66 5.86 6.46 5.26 rco 16.110 16.82 16.66 17.68 17. 81 17. 15 17 .611 16.6/ mm 0. / I 0. 79 0.82 0.69 0. 711 o. 75 0.60 0. 70 HGO 11. ) I 11.140 12.05 10.58 10.23 11. 11 11. 76 10.47 CAO 11.81 11. 78 11.83 11.411 11.10 11.59 11. 88 11. 31 8/\0 0.0 0.0 o.o 0.01 0.05 0.01 0.03 -0.01 N/120 1.69 1.110 1. 59 0.99 0.96 1. 37 1. 72 1.01 K20 0.65 0.58 0.51 0.62 0.67 0.61 0.66 0.55 r 0.0 o.o 0.0 o. 12 0. 16 0.06 o. 13 -0.01 Cl o.o 0.0 0.0 0.04 0.05 0.02 0.04 -o.oo 11;'!0 0.0 0.0 0.0 -0.07 -0.09 -0.03 -0.07 0.01 SUH 96. 37 95.99 98.41 97. 77 97.30 97. 17 100.69 93.64 -Os r+CL 0.0 0.0 0.0 0.06 0.08 0.03 0.06 -0.01 SUH 96.H 95.99 98.41 97.71 97 .22 97. 14 100.63 93.65

SI 7 .073 • 7.180 • 7.250 • 7. 199 • 7. 190 • 7. 179 . 7.075 • 7.291 • AL 0.927 8.000 0.820 8.000 0.750 8.000 0.801 8.000 0.810 8.000 0.821 8.000 0.925 8.000 o. 709 8.000 Ill 0. 116 • o. 124 • o. 152 • 0.326 • 0. 365 • 0.217 • o. 181 • 0.255 • 11 o. 110 . 0.100 • 0.087 • 0.104 • o. 108 • 0.102 • 0.106 • 0.097 . ..... H 2.140 • 2. 11,4 • 2.062 • 2.203 • 2.231 • 2. 156 . 2. 144 . 2. 168 . -..J HN 0.092 • 0.102 • o. 103 • 0.087 • 0.094 • 0.095 • 0.098 • 0.092 . CXl HG 2. 566 5.025 2.590 5.060 2.658 5.060 2.350 5.070 2.284 5.082 2. 490 5.060 2. 5117 5.077 2.1128 5.042 CA 1.926 • 1.924 • 1.875 • 1.826 • 1. 781 • 1.866 • 1.849 • 1.885 • NA 0.558 • 0.414 • 0.456 • 0.286 • 0.279 • 0.398 . 0.485 . 0. 305 • K 0. 126 • 0. 113 . 0.096 • o. 118 • 0.128 • 0. 116 • 0. 123 • 0.109 • DA 0.0 2.612 0.0 2.451 o.o 2.428 0.001 2.231 0.003 2. 191 0.001 2.381 0.002 2.459 -0.000 2.298 CL 0.0 • 0.0 • 0.0 • 0.010 • 0.013 • 0.005 • 0.010 • -0.001 • f o.o • o.o • o.o • 0.057 • 0.076 • 0.027 . 0.058 . -0.007 • II 0.0 0.0 0.0 o.o 0.0 0.0 -0.067 0.0 -0.088 0.0 -0.031 0.0 -0.068 o.o 0.008 o.o 0 23 .000 • 23. 000 . 23.000 • 23. 000 • 23.000 • 23.000 • 23. 000 • 23. 000 • CAI\ 28.6'."> 28.46 26.00 28.211 27.88 28.25 27. 86 28.67 ANT 38. 17 38.31 39.68 36. 34 35.74 37 .68 38.36 36.94

GRU 33.18 33.23 32. 32 35.42 36.38 34.07 33.78 34. 39 r/H 0.869 0.867 0.614 0.975 1. 018 0.904 0.881 0.931 r ;rH 0.465 0.464 0.449 0.494 0.504 0.475 0.1168 0.482

l 27 AMP INTCRGROWN WITH BT 5 SAM[ GRAIN 2 SAHC 6 AVERAGE 3 SAHE 1 AVERAGE PLUS SIGHI\ 4 N(W AMP INTERGROWN WI BT 8 AVERAGE MINUS SIGMA

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SIIHl'l I: ]7. BlOIITE ANALYSES I 2 3 lj 5 6 7 II

S102 37. IJ J6. 16 36. J6 16.08 37.55 ]7,611 J5. 72 16.111 1107. J. 511 3.6] 3.23 3.2ti 1.112 3.52 3. 112 3.ti9 117.0J 111. 10 15.05 Ill. 311 111. 31 111. 96 lti.67 lti.53 15.28 HO 18. 3l 111. ll 18.55 18.22 17.99 18.23 17. 76 18. 13 ~INO 0.?11 0.33 0. J5 0.28 0.31 o. 32 0.2] 0.32 MGO 12.1111 12. 13 11.80 12.59 1].26 12.91 12.811 12.til C/10 0. 18 o. 10 o. 11 o. 16 0.09 0.111 0.09 0.08 11110 o.o 0.0 0.0 0.0 0.0 o.o 0.0 0.0 111120 n. 11 0.15 0.011 o. 10 o. 11 0.08 0.03 0.08 K20 8.81 8.9ti 9.05 8. 77 9.25 9.20 9. 10 9.02 r fJ.O o.o 0.0 o.o o.o 0.0 0.0 0.0 CL 0.0 o.o 0.0 0.0 o.o 0.0 0.0 0.0 11?0 0.0 0.0 o.o 0.0 0.0 o.o 0.0 o.o SIJH 911, Y2 95,112 9].87 93.75 96.9ti 96.11 93. 72 95.62 -o- f+CI. O.IJ o.o o.o 0.0 0.0 o.o 0.0 0.0 SUH 911.92 95,1,2 93.87 93.75 96.9ti 96. 77 93. 72 95.62

SI 5.651 . 5,568 • 5.620 • 5. 573 • 5,587 • 5.616 . 5,519 • 5.557 • ..... /IL ;>, .111? 8.000 2.11]2 8.000 2.380 8.000 2.ti27 8.000 2.ti13 8.000 2. J8lj 11.000 2.481 11.000 2.ti4J 8.000 -...J Al CJ. 180 . 0.255 • 0.239 • 0.177 • 0.209 • 0.195 . o. 1611 • 0.275 • \0 II O.l!05 • 0.41 J • 0.]75 • O. l76 • o. 383 • 0. 395 • 0.397 • 0. 396 . fE 2. 33J . 2.322 • 2.398 • 2.353 • 2.238 • 2.275 • 2.295 • 2.289 . HN 0.0]6 . O.Oti2 • 0,0116 • 0.0]7 • 0.039 • o.otio • 0.030 • 0.0111 • MG 2.822 5. 111 2. 7l9 5. 771 2. 719 5. 777 2.898 5.8ti2 2.940 5.810 2.88ti 5. 789 2.957 5.8ti3 2. 792 5. 793 CA 0.029 • 0.016 • 0.018 • 0.026 • O.Olti • 0.022 • 0.015 • 0.013 . NA 0.032 . o.oti4 • 0.012 • 0.030 • 0.032 • 0.023 . 0.009 . 0.023 . K I, 710 . 1. 727 • 1. 7811 . 1,728 • 1, 755 • 1. 751 . 1. 793 . 1,737 • BA 0.0 I. 112 0.0 1. 788 0.0 1.81ti 0.0 1.78ti 0.0 1.801 0.0 1. 796 0.0 1.817 0.0 '· 773 Cl 0.0 . 0.0 • 0.0 • 0.0 • o.o • 0.0 • o.o • o.o • r 0.0 . 0.0 • o.o • 0.0 • o.o • 0.0 . 0.0 . o.o • II 0.0 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 o.o 0.0 0.0 0.0 o.o 0.0 o.o 0 2?.000 . 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 •

f/H o. 81,0 0.863 0.899 0.825 o. 775 0.80] o. 786 0.8lti f/fH 0.456 o.ti6J O.ti73 o.ti52 o.ti36 O.llti5 O.lll!O 0.1155

1 32C fRH 81 5 32C BT 2 328 AT 6 32C BT J 32A Bl 7 32C BT ti 32A Bl 8 32C BT

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SAHPlf 32 BIOTIT[ ANALYSES 9 111 11 12 1l

5102 36.63 36.68 36. 111 l7. 31 36. 17 1102 J.2J 3.28 3.40 3.54 3.26 A20l 14,60 14. 74 14.66 15.00 14. 32 HO 18.21 18.35 18.21 18.42 18.00 HPIO 0.27 0.25 0.29 0. 33 0.26 HGO 11. 19 12.10 12.37 12.95 11.80 CAO 0.07 0.06 o. 11 o. 15 0.07 BAO 0.27 0.23 0.05 0.15 -0.05 NA;>O 0.09 0. 111 0.09 o. 1l 0.06 k20 9.02 9.18 9.03 9, 19 8.88 r 0.29 0.15 0.06 0.19 -0.06 Cl 0.04 0.114 0.01 0.02 -0.01 1120 -0. 15 -o. 111 -0.03 -o. 10 0.03 SUH 93. 76 95.22 95.00 97.27 92. 73 -0° F+CL o. 13 0.16 0.03 0.09 -0.03 SUH 93.63 95.07 94.97 97. 18 92.76 ......

SI 5.652 . 5,577 • 5.592 . 5, 5111 • 5.639 • 00 Al 2, 3118 8.000 2.423 8.000 2.408 8,000 2,453 11.000 2.361 11.000 0 Al o. 3116 . 0.2111 • 0.222 . 0. 175 • 0.210 • T I 0. 315 • 0.375 . 0. 389 . o. 396 • 0.382 • rr 2.350 . 2. 333 • 2. 318 • 2.?90 • 2. 348 • HN 0.035 . 0.032 . 0.038 • 0.0112 • 0.034 • HG 2. 573 5.639 2.742 5.701 2.807 5. 774 2.869 5. 771 2. 743 5,777 CA 0.012 • 0.010 • 0.018 • 0.023 • 0.012 • NA 0.027 . 0.0111 • 0.027 • 0.037 • 0.017 • K 1. 775 . 1. 780 • 1. 7511 • l. 71,2 • 1, 767 • BA 0.016 1.830 0.014 1. 8115 0.003 1.802 0.009 1.1111 -0.003 1.792 Cl (J,(J10 . 0.010 • 0.002 • 0.006 • -0.002 • r u. 1112 . 0. 168 • 0.031 . 0.091 • -0.032 • II -o. 152 o.o -o. 179 0.0 -0.033 0.0 -0.097 o.o 0.034 0.0 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 •

F/H 0.927 0.863 0.839 o. 813 0.1168 F/FH 0.481 0.463 0.456 0.4411 0.465

9 32 FR£[ BIN[WO 12 AV[RAG[ PLUS SIGHA 10 SAHE GRAIN 13 AVERAGE HINUS SIGHA 11 AV[HAG[

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SAMl'L [ )2 f[LOSPAR ANALYSES 1 .? l 4 5 6 7 8

SI02 '.>6.01 '.,6.96 58.8) 58.81 58.4) 58.04 '.>5. 2) 54.21 1102 0.0l 0.011 0.02 0.02 O.Ol 0.02 0.011 0.0) 1120) 26. 811 27 .00 211.92 25.72 26.02 26.2) 27 .08 21.96 rro 0.06 0.10 0.07 0.02 0.09 0.10 0.05 0.09 MIIO 0.01 0.0 0.0 0.02 0.0 o.o 0.0 o. 1 l MGO 0. 11 0.08 0.07 0.02 0.0 0.08 0.0 0.05 CAO 9. 19 9.21 6.96 1.119 7 .42 8.00 9.66 11.15 ()AO 0.0 0.0 o.o o.o o.o o.o o.o 0.0 NA20 6. )9 6.0'., 7.21 6.94 6. 7l 6. 71 5.67 5.02 1<20 0.15 0.25 o. 36 0.24 0.31 0.26 0.25 0.21 r o.o 0.0 0.0 0.0 o.o 0.0 0.0 0.0 CL 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 SUH 100. 79 99.69 98.44 99.28 99.03 99.44 97 .98 98.85 ·O= r+CL 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0 SUH 100.79 99.69 98.44 99.28 99.03 99.44 97 .98 98.85

SI 2.'.>80 • 2.563 . 2.665 • 2.6112 • 2.631 • 2.610 • 2.53) • 2.477 • Al 1.407 • 1. 431 • 1. 330 • 1.361 • 1. 381 • 1.390 • 1.463 . 1.505 • ...... II 0.001 3.988 O.U01 3.995 0.001 3.996 0.001 4.004 0.001 4.013 0.001 4.000 0.001 3.997 0.001 3.983 co re 0.002 • 0.0011 • 0.003 • 0.001 • 0.003 • 0.004 • 0.002 • 0.003 • ...... MN 0.000 . 0.0 • o.o . 0.001 • 0.0 • 0.0 • 0.0 • 0.005 • HG 0.007 • 0.005 • 0.005 • 0.001 • o.o • 0.005 • 0.0 • 0.003 .. CA 0.0 1.007 0.0 0.995 0.0 0.999 0.0 0.981 0.0 0.967 0.0 0.9911 0.0 0.995 0.0 1.015 BA 0.0 • o.o • o.o • o.o • o.o • 0.0 • o.o • o.o • NA 0.5'.>1 • 0.528 . 0.633 • 0.604 • 0.588 • o. 585 • 0.5011 • 0.445 • I( 0.0119 1.001 0.014 0.995 0.021 0.999 0.014 0.981 0.018 0.967 0.015 0.994 0.015 0.995 0.012 1.015 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 . 8.000 •

AN 43.90 45.02 34.06 36.83 37.16 39. 12 47. 78 54.43 AB 55.24 53.52 63.811 61. 76 60.99 59. 37 50. 75 114. 35 OIi 0.85 1.45 2.10 1. 41 1. 85 1. 51 1. 47 1.22 CN o.o o.o 0.0 0.0 0.0 0.0 0.0 0.0

f/H 0. 358 0.701 o.561 1. 129 0.0 o. 701 0.0 2.487 f/fM 0.263 0.412 0.359 0.530 0.0 0.412 0.0 0. 713

1 320 Pl.AG 5 32A RIM or PLAG 2 32C rLAG 6 CORC or PLAG 3 32C PLAG 7 32C Pl.AG 4 3?A PIAG 8 32C Pl CORE FINIS

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S/IMl'L f 3l FELDSPAR ANALYSES 9 10 II 12 1l 111 15 16

SIO? ~11. 11 59. 19 58.67 59. 36 52.91 511.61 51,. 59 6D.l16 110;> IJ.Clll IJ.011 O.D3 0.04 0.03 D.06 CJ. 06 0.02 1170] ?I .<>6 25.04 211.89 25.01 28.02 28.66 ?.8. 16 211. 63 If 0 D. II 0.06 O. ID 0.03 0.10 0.08 o. 1l 0.011 MIW Cl. 18 0.56 0. 32 0.10 0.58 0. 14 0. 30 o. 33 MCiO 0.07 0.02 0.08 0.08 0.03 o.o 0.06 0.04 CIIO 11. 07 7. 59 7.26 7.56 10.97 11.28 10.96 6.51 ll/10 0.0 0.0 0.0 o.o o.o o.o 0.0 o.o l'i/\20 5.22 7.26 7.08 7.08 4.97 5.10 5.06 7.44 k20 o. 19 O. II 0. 311 0.28 o. 18 0. 19 0.211 0.42 I O.ll 0.0 o.o o.o 0.0 0.0 0.0 0.0 Cl o.o IJ.O o.o o.o 0.0 o.o 0.0 0.0 SUl1 98.65 99.87 98.77 99.54 97. 79 100.12 99.56 99.69 •O · f+CL 0.0 0.0 o.o o.o 0.0 0.0 0.0 0.0 SUH 98.65 99.87 98. 77 99.54 97.79 100. 12 99.56 99.89

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SAHrl[ Jl1 OIOTIT[ ANALYSES 1 7 l II 5 6 1 8

SI02 JI. 92 J /. 04 36.94 36.87 36.85 31.12 Jl.5l 36.72 1102 l.88 J.79 ].6;> J.76 3. 11 3. 16 3.85 3.68 A203 14.22 111.117 111.40 111. 38 111.62 111.112 111.55 111.29 rro 18.92 18.66 18.67 18.89 19.811 19.00 19. IIJ 18.56 HNO 0.31 O. JO 0.27 0. 311 0.31 o. 31 0.33 0.28 HGO 12. l 1 11.29 11.04 11.08 11. 27 11.IIO 11.86 10.93 CAO 0.05 0.02 0.02 0.04 0.07 0.04 0.06 0.02 DAO 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0 NA20 0.01 0.06 0.09 0.08 0.08 0.08 0.09 0.01 K20 9.25 9.00 9.06 9. 17 9.16 9. 13 9.22 9.04 r 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 Cl 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0 1120 0.0 o.o 0.0 0.0 o.o o.o 0.0 0.0 SUH 96.93 911.6] 911. 11 911.61 95.97 95.25 96.91 9l. 59 -o,- F+CL o.o 0.0 o.o 0.0 0.0 0.0 0.0 o.o SUH 96.93 911.63 911. 11 911.61 95.91 95.25 96.91 93.59

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1 311B BT 'rRCE' 5 FREE BT 2 FREE BT LAST PL 6 AVERAGE l FR([ Bl 7 AVERAGE PLUS SIGHA Ii FREE Bl 8 AVERAGE MINUS SIGMA

Page 192: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPU Jl1 BIOTIT[ ANALYSES 1 2 l 4 5 6 7

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I 311A BT RIHHING AHPIIIBOLE INCLUSION 5 AVERAGE 2 ]411 BT RIMMING AHPIIIBOLE INCLUSION 6 AVERAGE PLUS SIGMA l 311 BT CLUSTER NEWO 7 AVERAGE HINUS SIGMA 4 SAHC GRAIN

Page 193: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIHPLC )II rELDSPAR ANALYSES I 2 l 11 5 6 1 8

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AN 31. 99 ll.59 32.62 )2.50 27.118 32.09 311. 511 )1. 55 AB 67 .26 65. 19 66.02 66. 15 70.87 66.311 63.75 66.67 OR o. 75 1.22 1. )6 1. 35 1.65 1. 56 1. 71 1.78 CN 0.0 o.o u.o o.o 0.0 o.o 0.0 0.0

1/H 0.0 5. 3111 0. 125 0.9611 0.81111 11. 510 2.687 0.0 r;rH 0.0 0.842 0.111 0.1191 0.1158 0.819 0.129 o.o

1 111c rnos 5 3110 PLAG 2 )lj0 A Pll\G NEI\R RIM 6 Pl RIM 311 flNIS l )l1C PLAG 7 TOW CORE II JljC DlffERENT PLAG 8 GORHINIS

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SIIHPl.[ )II rCLDSPAR ANALYSES 9 10 11 17. 1l 11, 15 16

S102 65. 19 61. 70 611. 86 67.)2 50.111, 62. )2 61.67 611. H 1102 0.0 0.0 0.0 0.0 O.Ol 0.02 II. Ol 0.02 A20J 21. ll 23.12 20.98 20.811 28.68 25, 10 25.61 n.•18 rro 0.22 0.11 0.02 0.01 0.22 0. 1 l 0.16 0.08 HNO 0.0 0.02 0.0 0.0 O.Ol 0.01 0.0 0.01 HGO 0.0 0.0 0.0 0.0 0.01 0.0 0.0 0.0 CIIO 2.60 6.02 I. 81 1.20 111.83 6.20 6.29 ). 17 BAO 0.0 0.0 0.0 o.o o.o 0.0 0.0 0.0 N/120 10.07 9.111 10. 71 11.111 11.81 8.06 1. 81 10.1) 1<20 11.06 0.05 0.05 0.05 0.02 O. ll 0.26 0.011 r 0.0 0.0 0.0 0.0 0.0 0.0 0.0 o.o Cl 0.0 o.o 0.0 0.0 0.0 o.o 0.0 0.0 SUH 99.117 100.119 98.113 100.56 99.07 102.15 101.89 99. lO -oc r+CL 0.0 0.0 0.0 0.0 0.0 o.o 0.0 o.o SUH 99.117 100.119 98.lll 100.56 99.07 102.15 101.89 99.30

SI 2.88) • ?.7111 • 2.896 • 2.933 . 2. 3110 • 2. 712 • 2.691 • 2.860 • i\l 1. 11? . I. 211 . 1. 1011 . 1.070 • 1. 568 • 1.287 . I. 311 . I. 125 • II 11.0 3.995 0.0 l.952 0.0 11.000 o.o 11.00) 0.001 3.909 0.001 11.000 0.001 11.009 0.001 3.985

,_. r[ 0,01)6 . 0.0011 • O.UOl . 0.000 • 0.009 • 0.005 . 0.006 . 0.00) • CIJ HN 0.0 • 0.001 . 0.0 • o.o • 0.001 • 0.000 . 0.0 • 0.000 • I.O

HG o.o . 0.0 • 0.0 . 0.0 • 0.001 • 0.0 . 0.0 • o.o . CA n.o 0.996 0.0 1.110 0.0 1.017 o.o 1.000 0.0 I.181 o.o 0.991 0.0 0.980 o.o 1.029 811 o.o . 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • o.o • 0.0 • 1111 0.8611 . 0.816 • 0.927 • 0.9111 • 0.11)3 . 0.680 . 0.666 . 0.873 • I( 0.0()) 0.998 0.00) 1.110 0.00) 1.017 0.003 1,000 0.001 I. 181 0.017 0.991 0.0111 0.980 0.002 1.029 0 8.0UO . 8.000 • 8.000 . 8.000 • 8.000 • 8.000 . 8.0UO • 8.000 •

IIN 12.1111 25.93 8.52 5.60 62.95 29. 31 )0. 18 111. 71 110 87 .21 7).81 91.20 911. 12 )6.95 68.95 68. ll 85.07 on O. lll 0.26 0.28 0.28 0. 10 1. 711 1.119 0.22 Cit 0.0 0.0 0.0 0.0 o.o 0.0 o.o 0.0

r/H 0.0 5. lll 1 o. 125 0.9611 111.0•18 11.510 2.687 o.o F/rM 0.0 o. 8112 0. 111 0.1191 0.9)11 0.819 0. 729 0.0

9 LAS I Pl. 1l TOW CCNTCR Ill GEttlCR Ill NOTHCR PL rr NIAR RIH or SAH[ 15 SAHE PT 12 OACI< lOW CENTER 16 COG[ or SAHE

Page 195: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIHPI l 311 FELDSPAR ANALYS[S 11 18 19 20 21 22 7l 24

SIO;> 66.59 56. 16 60.31 57. 19 60.82 59.57 60.28 61. 30 1102 u.o 0.0 o.o 0.0 0.02 0.02 0.01 0.0 11203 20. 1 7 23. 11 211.24 24.51 25.91 211. 811 25.117 25.36 rco 0.05 o.o O.OJ 0. 11 0.16 0.09 0.04 0.09 HIIO 0.02 11.0 o.o o.o o.o 0.01 0.0 0.01 HGII 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 CAO 1 .25 5.44 5,52 8.61 6.95 6.92 7 .21 6.68 11110 0.11 0.0 o.o 0.0 0.0 0.0 0.0 0.0 N/120 10.80 7. 72 8.54 7.95 7.29 7 .111 7. J7 7.64 K20 0.09 0.14 0.07 0.011 o. J2 0. 19 0.25 o. l5 r 0.0 0.0 o.o 0.0 0.0 o.o o.o 0.0 Cl 0.0 0.0 o.o 0.0 o.o 0.0 u.o 0.0 SUH 98.97 92.57 98.71 98.41 101.47 99.05 I00.6J IOI.Ill -Os r+CL 0.0 o.o 0.0 0.0 o.o 0.0 0.0 o.o SUH 98.9/ 92.57 98.71 98.111 101.117 99.05 100.63 101.113

SI 2. 9117 . 2.691 . 2. 714 • 2.618 • 2.669 • 2.679 . 2.669 • 2.690 . ...... Ill 1.052 . 1.J08 . 1.286 . 1.322 • 1. J40 • 1. 316 . 1.329 • I. 311 . \D TI 0.0 3.999 0.0 4.005 o.o 11.000 0.0 3.940 0.001 11.009 0.001 J.996 0.000 3.998 u.o 11.001 0 re 0.002 • o.o • 0.001 • 0.0011 • 0.006 • O.OOJ • 0.001 • O.OOJ • Mil 0.001 • o.o • o.o • o.o • o.o • 0.000 • 0.0 . 0.000 . . MG u.o . o.o • 0.0 • 0.0 • o.o • 0.0 • 0.0 . 0.0 • CA 0.0 0.994 o.o 1.007 0.0 1.017 0.0 1. 134 0.0 0.971 0.0 0.9911 0.0 0.990 0.0 0.987 81\ o.o . o.o . o.o • o.o • 0.0 • o.o • o.o • o.o . Ill\ 0.927 . 0.719 . 0.745 . 0.706 • 0.620 • 0.6116 . 0.633 • 0.650 • I( 0.005 0. 991, 0.009 1.007 0.0011 1.017 0.002 1. 1311 0.018 0.971 0.011 0.994 0.014 0.990 0.020 0.987 0 8.000 . 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 . 8.000 •

1111 5.98 21. 79 26.21 J7. 36 33.86 JJ. 67 JII. 59 31. 93 AD 9J.51 71.J6 73. 39 62. 43 64.28 65.23 6J.98 66.08 UR 0.51 0.85 0.110 0.21 1.86 1. IO I. 43 1.99 CII 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0

r /H o.o 5.J41 o. 125 0.964 111.048 4.510 2.68/ 0.0 r;rH 0.0 0.842 o. 111 0.1191 0.9JII 0.819 0. 729 0.0

17 TOWARD CENl[R 21 Nf/lR EDGE 18 [OGE or NEW PL 22 NOTII PL 19 EDGE or PL 23 TOW CEIITCR 20 TOW CENTER 211 CLOSER 10 CEIIIER

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SI\Hl'l [ ]11 FELDSPAR ANAlYS[S 2'j 26 21 28 29 30 3 I 32

S102 !>8.69 61. 63 6J.8'j ':.1 .66 68.52 63.93 '.>9 .1111 61.06 1102 11.0 (I.01 0.0 0.02 0.0 0.0 o.o 0.01 A;>OJ 26.85 25.011 22.91 25.01 20.67 22.23 211. 18 211. OJ 11 O 0. 17 0. 19 0.0 o. 111 0.02 0.11 0.08 0.10 HtlO 0.0 0.01 0.0 0.0 0.0 0.01 o.o 0.02 Hc;o 0.112 0.0 0.0 0.0 0.0 0.0 (1.0 0.01 C:1\0 8.117 6.22 J.112 9.26 0. 59 J.63 6.17 5.87 11110 o.o o.o 0.0 0.0 0.0 o.o 0.0 0.0 NA20 6.117 7.96 9.67 7.50 11.119 9. 19 8.10 8. 311 K20 0.211 0.26 0.08 O.OJ 0.06 0.05 0.06 0.16 r (I,() 0.0 0.0 0.0 0.0 0.0 o.o o.o Cl 0.0 0.0 0.0 o.o o.o 0.0 0.0 o.o SUH 101. 11 101. 32 99.93 99.62 101. 35 99. 75 98.67 99.60 -a- r+cL o.o 0.0 o.o o.o 0.0 0.0 0.0 o.o SUH 101. 11 10 I. 32 99.1:3 99.62 101. 35 99.7!; 98.67 99.60

SI 2.6UII . 2. ,O'j • 2.811 • 2.608 • 2.956 • 2.831 • 2.690 • 2. 726 • Ill 1. 399 . 1.295 • 1. 191 . 1. ]JJ • 1.051 • 1.160 • 1.288 . 1.2611 • ,..... l I 0.0 11. OOJ 0.000 11.001 o.o 11.009 0.001 3.9111 o.o 11.001 o.u J.991 o.o l. 971! 0.000. J.990 '° rr 0.1106 . 0.007 . o.o • 0.005 • 0.001 • 0.0011 . O.OOJ • 0.0011 • ,..... HN 0.0 . 0.000 . 0.0 • o.o • o.o • 0.000 • o.u . 0.001 • HG 0.001 . 0.0 . 0.0 • D.O • D.O • o.o • o.o . 0.001 • (;I\ 0.0 0.977 0.0 0.992 o.o 0.993 0.0 l. 113 0.0 0.992 o.o 1.020 0.0 1.0115 0.0 1.017 IIA 0.0 • 0.0 • o.o • 0.0 • 0.0 • 0.0 . 0.0 • 0.0 • NII 0.':.55 . 0.671 • 0.827 • 0.658 • 0.961 • 0.8110 • 0. 710 • 0. 722 • K 0.0111 0.977 0.0l'j 0.992 0.005 0.993 0.002 l. 113 0.003 0.992 0.003 1.020 O.OOJ 1.0ll'j 0.009 1.017 0 8.000 • 8.000 • II.ODO . II.ODO • 8.000 • 8.000 • 8.000 • 8.000 •

I\N 111. 39 29. 71 16.27 110.119 2.75 16.96 JI .119 27.73 All 51.21 68.81 83. 2'/ 59, 35 96.92 82. 76 68.18 71. 35 on 1.110 1.118 0.115 0.16 0. J3 0.28 o. JJ 0.91 CN 0.0 0.0 o.o 0.0 0.0 o.o 0.0 0.0

F/H 11, 169 5, Jli 1 0.125 0.9611 111.0118 11,510 2.681 5.1116 r;rH 0.827 0.8112 0.111 0.1191 0.9311 0.819 0. 729 0.1137

25 ClOS[R 10 CENl[R 29 TOW CENT 26 EDGE JO PR GD CENT 27 [DG[ or NEW Pl J 1 EDGE 28 TOW CENT 32 AVERAGE

Page 197: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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Page 198: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHrU 311 rELDSPAR ANALYSES I 2 3 •• 5 6 7 8

Sl02 611. 84 64.411 62. 79 611.29 63. 51 63.97 64. 71 63.24 1102 0.05 0.05 0.0 0.01 o.o 0.02 0.05 -o.oo 11703 19.08 19.03 19.21 18.91 18.61 18.9f 19. 17 18. 76 rco 0.06 0.2, 0.05 0.06 0.05 0.10 0. 18 0.01 HNO 0.02 0.02 0.01 0.02 0.01 0.02 0.02 0.01 HGO 0.07 0.07 0.05 0.05 0.02 0.05 0.07 0.03 CAO U.07 0.06 0,07 0.03 0.03 0.05 o.o, 0.03 1!110 o.u o.u 0.96 0.69 1. 03 0.54 0.99 0.08 NA20 0.21 0.46 0.48 o. 37 0. 47 0.41 0.1,9 0.33 K20 15.76 15.28 15. 13 14. 74 15.21 15.22 15.55 14.90 r 0.0 0.0 0.01 0.0 0.02 0.01 0.01 -o.oo Cl 0.0 o.o o.o 0.0 0.0 0.0 0.0 0.0 SUH 100.22 99.68 98.75 99. 17 98.94 99.35 101. 30 97 .41 -0= r+CL 0.0 0.0 0.0 o.o o.o o.o 0.0 0.0 SUH 100.22 99.611 98.75 99. 17 911.94 99.35 101. 30 97 .111

SI 2.980 . 2.976 • 2.950 • 2.986 • 2.918 • 2.914 • 2.966 • 2.983 • Al 1.03] • 1. 036 . 1.064 • 1.035 • 1.028 • 1.039 . 1. 035 • 1.0113 • TI 0.002 11. 015 0.002 4.014 0.0 4.014 0.000 4.021 0.0 4.006 0.001 4.014 0.002 4.003 -0.000 4.026 ...... H 0.002 • 0.010 • 0.002 . 0.002 • 0.002 • 0.004 . 0.001 . 0.000 • \D HN 0.001 • 0.001 • 0.000 . 0.001 • 0.000 • 0.001 • 0.001 • o.uoo • w HG 0.005 . 0.005 • 0.004 . 0.003 • 0.001 • 0.004 . 0.005 • 0.002 • CA 0.0 0.959 0.0 0.960 0.0 0.978 0.0 0.927 0.0 0.916 o.o 0.960 0.0 0.981 0.0 0.933 RA 0.0 • 0.0 • 0.018 • 0.013 • 0.019 • 0.010 • 0.018 • 0.002 . NII 0.0211 . 0.041 • 0.044 • 0.033 • 0.043 • 0.037 . 0.0114 . 0.030 • K 0.9211 0.959 0.900 0.960 0.907 0.918 0.873 0.927 0.910 0.976 0.903 0.960 0.909 0.987 0.896 0.933 0 8.000 • 8.000 • 8.000 • 11.000 • 11.000 • 8.000 • 11.000 • 8.000 .

AN 0. 36 0.31 0.36 o. 16 0.15 0.27 0. 35 0.18 118 2.53 4. 36 4.50 3.62 4. 39 3.88 4.47 3.24 OR 97. 11 95.32 93.32 94.85 93.51 94.82 93. 35 96.41 CN 0.0 0.0 1.112 1. 36 1.95 1.03 1.82 0.17

r/H 0.641 2. 321 0.675 0.901 1.687 1.232 1.638 0. 385 f/fH 0.391 0.699 0.403 0.474 0.628 0.552 0.621 0.278

1 34 HLDS KSPAR 5 HIDOLC PT 2 340 KSPAR 6 AVERAGE 3 NEWO KSP RIH 7 AVERAGE PLUS SIGMA 4 311 CORE kSP 8 AVERAGE MINUS SIGMA

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SIIHPl.C ]II IIHPll I BOLE ANAL YSC S 1 2 l 4 5 6

SI02 116.61 1,11.66 1111.68 45.34 116.28 1111. 39 T 102 1.06 1.02 0.92 1.00 1.06 0.911 A20l 7.88 8,11 I 8.50 8.26 8,511 1. 99 HO 17. 111 17. 43 17.22 17 .26 17.39 1 7. 111 HIIO 0.58 0.511 0.49 0.511 0.57 0.50 HGO 11. 17 10.111 10. ]6 10.65 11.02 10.28 CAO 11. f2 11. 31 11.23 11.112 11.6] 11.21 0110 0.0 0.06 0.06 0.011 0.07 0.01 NA20 I. 18 1. ]11 1.38 I. 30 I. 39 1.21 K20 0.82 0.90 0.91 0.88 0.92 0.811 f 0.0 0.25 0.23 0.16 0.27 0.05 Cl o.o 0.05 0.08 0.04 0.08 0.01 H?O 0.1) -o. 13 -o. 13 -0.09 -o. 15 ·0.02 SUH 98.22 96.25 95,93 96.80 99.06 94.54 •O= f+Cl 0.0 0.12 0. 11 0.08 o. 13 0.02 SUH 98.22 96. 13 95.82 96. 72 98.93 94.52

SI 6.9115 • 6.815 • 6.831 • 6.8611 • 6.11110 • 6.889 • Al 1.055 11.000 1. 185 8.000 1. 169 8.000 1. 136 11.000 1.160 8.000 I. 111 8.000 Al 0.326 . 0.327 • 0.362 • 0.339 • 0.327 • 0.350 • ...... TI 0. 119 • o. 117 • o. 106 • 0.1111 • o. 1111 • 0.110 • '° re 2. 133 . 2.224 • 2.202 • 2. 186 • 2.149 • 2.225 . .p.. HN 0.073 . 0.070 • 0.063 • 0.069 • 0.072 • 0.066 . HG 2.477 5. 129 2. 368 5. 106 2.361 5,094 2.40] 5.110 2.427 5.093 2. ]77 5.1211 CA 1. 869 . 1.849 • 1. 840 • 1. 853 • 1.1142 • 1.863 . NA o. 3110 • 0. ]96 • 0.41.19 • o. 382 • o. 397 • 0. 365 • K 0. 156 . o. 175 • o. 177 • 0. 169 • 0.173 • 0.166 . BA o.o 2. 365 0.004 2.1124 0.0011 2.1130 0.002 2.1106 0.0011 2.1117 0.001 2. 395 Cl o.o • 0.013 • 0.021 • 0.011 • 0.019 • 0.003 . r 0.0 . 0.121 . 0.111 • 0.077 • 0.128 • 0.023 . H 0.0 0.0 -o. 134 o.o -o. 132 o.o •0.088 o.o -o. 1117 o.o -0.026 0.0 0 23.000 • 23.000 . 23.000 . 23.000 • 23.000 • 23.000 •

CAA 28.52 28.110 28.45 28.116 28.39 ?8.53 ANI 37.81 36.37 36.51 36.91 37 .110 36.IIO GRU 33.67 35.23 35.03 34.63 311.22 35.07

F/H 0.890 0.969 0.959 0,938 0.915 0.9611 F/FH 0.471 0.492 0.1190 0.11811 0.1178 0.1191

I ]l1A IIHPII INCLUSION 4 AVERAGE 2 34 INC IIHP NEWO 5 AVERAGE PLUS SIGMA J I NC AHPANOTIIER 6 AVERAGE MINUS SIGMA

Page 200: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SI\HPL[ Jl1 I\HPIIIBOL[ ANALYSES 1 ? l 11 5

SIO;> ~7..8~ ~l.61 52.2] 52.8~ 51.61 110? 0. ]6 0.20 0.?8 o. ]6 0.20 /\?OJ 1.28 ].69 ].lf8 3.69 3.28 r i:o 111. ~6 17. 111 15.85 17. llf llf.56 l·IIIO 0.63 (). '.">l 0.58 0.63 0.53 MGO 111. 511 . 12. 17 13.35 llf. 51f 12. 17 CI\O 17..00 12.25 12. 13 12.25 12.00 111\0 o.o u.o 0.0 0.0 0.0 141\?0 (I. 5'.> 0.113 u.119 0.55 O.lf3 K?O 11.24 0.2] 0.21f 0.21f 0.23 r 0.0 0.0 o.o o.o o.o Cl. 11.0 o.o 0.0 0.0 o.o 11?0 o.o 0.0 0.0 0.0 0.0 SUH 99.01 96.25 98.63 102.25 95.01 •Ile F+CL o.o o.o o.o 0.0 0.0 SUl1 99.01 96.25 96.63 102.25 95.01

SI I. 599 . 1. 511 • 7. 5118 • 7.lf52 • 7. 733 • 1\1 U.41ll 6.000 IJ.lf2] 8.000 O.lf 12 8.000 o. 5118 8.000 0.267 8.000 ....... l\l 0. 155 . 0.216 • 0.185 • 0.065 • 0.312 • \D l I 0.0]9 . 0.022 • 0.0]1 • 0.038 • 0.023 • Vl F[ I. 75 I . 2. IOlf • 1.926 • 2.021 . 1.6211 • HII 0.071 • 0.066 • 0.071 • 0.075 • 0.067 • HG 3. 116 5.137 ?.66] 5.071 2.692 5. lOlf J.056 5.256 2.718 lf.91flf C:I\ I. 51,9 . 1. 927 • I. 887 • 1.851 • 1.926 • 141\ o. 15] . 0.1?2 • o. 138 • 0.150 • 0.125 • K 0.01,11 . O.Olfl . O.Olflf . O.Olf3 • O.Olflf • OA o.o 2.0lf6 0.0 2.092 0.0 2.069 0.0 2.0lfti 0.0 2.095 Cl 0.0 • 0.0 • o.o • 0.0 • 0.0 • r o.o . o.o . o.o . 0.0 . 0.0 • II 0.0 0.0 o.o 0.0 o.o o.o 0.0 0.0 0.0 0.0 0 23.000 . 23. 000 . 23. 000 • 23.000 • 23.000 •

CI\A ?1.22 28.50 27 .85 26.113 29.117 /\NI 115.88 39. 39 112.68 lf].611 If I. 58 GRU 26.91 32. 10 29.117 29.911 28.911

r/H 0.586 0.815 0.691 0,686 0.696 r/fH 0. 370 O.lfll9 O.lf08 0.1107 0.1110

I 3~0 I\HPIIIB 1 fREE' ti AV[RAGE PLUS SIGH/\ 7. 3110 AHPIIIB 5 AVERAGE HINUS SIGHA 3 AVERAGE

Page 201: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

.._. '° 0\

APPENDIX C

Microprobe Analyses from the Bucksport Formation and Melanosomes

Page 202: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

BUCKSPORT FORMATION

Calcareous samples: 13, 35, 47, 45

Noncalcareous samples: 14, 37

MELANOSOMES

Calcareous samples: 3, 3A2, 46, 44, 26, 31, 33A

Noncalcareous samples: 22

...... \0 -....J

Page 203: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

5Af.1Pll 3 AHPII I BOLE ANAL YSC S 1 2 3 " 5 6 7 8

510?. •13.60 II]. 511· 1111.40 1111. Ill 42.80 43.09 43. 59 ,,,,. 15 110?. 2.04 1. 67 1. 88 1.68 1.90 1.81 1. 83 1.96 A;>O] 9. 92 9.80 8.88 8.66 9.911 9.811 9.51 10.03 I fO 16.911 17 .80 16.60 16. 39 16.88 16.88 16.91 17. 35 ~11,0 0.42 0.112 0.116 0. 38 0. 38 0. 39 0.1, 1 0.411 MGO 11.29 10.24 10.67 10. 75 10.08 10. 13 10.53 10.95 CAO 11. 78 11. 72 11. 18 11. 21 11.60 11.63 11. 52 11. 76 OAO O.ll o.o 0.09 0. 10 0.12 0.10 0.07 0.12 NA20 1. 16 0.96 1.JII 1. 23 1. 19 1. 18 1. 18 1.29 K20 1. 25 1. 16 1.09 1.03 1. 31 1. 30 1. 19 1. 30 r O.ll o.o o. 16 0.09 0.10 0. 13 0.08 o. 14 Cl 0.0 0.0 0. 37 0.31 O. JJ 0.40 0.23 0.40 11?0 0.0 0.0 -o. 17 -o. 12 -o. 13 -o. 16 -o. 10 -o. 17 SUM 98.110 97.31 96.95 95.85 96.50 96.72 96.95 99. 72 -0= F+CL 0.0 0.0 o. 15 o. 11 0. 12 0.14 0.09 o. 15 SUM 98.40 97. 31 96.80 95.711 96. 38 96.57 96.87 99.57

SI 6. 5211 • 6.603 • 6.715 • 6.7117 • 6.5115 • 6.569 • 6.617 . 6. 531 . Al 1.1176 8.000 1. 397 8.000 1.285 8.000 1.253 8.000 1.•155 8.000 1.1111 8.000 1. 383 8.000 1.,169 8.000 AL 0.2711 • 0.355 • 0.297 • 0.307 • 0.337 • 0. 337 • 0.318 • 0.280 . TI 0.?30 • 0. 190 • 0.2111 • o. 193 • 0.219 • 0.208 • 0.209 • 0.218 • ...... rr 2. 120 • 2.258 . 2.100 . 2.095 • 2. 159 • 2. 152 • 2. 1117 • 2. 147 • \0 MN 0.053 • 0.054 • 0.059 • 0.01,9 • 0.049 • 0.050 • 0.052 • 0.055 • 00 HG <'.518 5. 1911 2. 315 5. 172 2.405 5.075 2.449 5.093 2.298 5.061 2. 302 5.049 2. 38<' 5. 108 2.415 5. 115 CA 1.889 . 1.904 • 1.812 • 1.836 . 1.901 • 1.900 • 1.873 • 1.863 . NA 0. 337 • 0.282 • 0. 393 • 0. 365 • 0.353 • 0. 3119 . 0.346 • 0. 370 • K 0.239 . 0.2211 • 0.210 • 0.201 • 0.256 • 0.253 • 0.230 • 0.244 . DA 0.0 2.464 0.0 2.1111 0.005 2.1120 0.006 2.1107 0.007. 2.516 0.006 2.507 0.0011 2.454 0.007 2.485 CL o.o • 0.0 • 0.095 • 0.080 • 0.086 • o. 103 • 0.060 • o. 101 • r 0.0 . 0.0 • 0.077 • 0.044 • 0.048 • 0.063 • 0.038 • 0.066 . It 0.0 0.0 o.u 0.0 -o. 171 0.0 -o. 1211 o.o -o. 1311 0.0 -o. 166 0.0 -0.099 o.o -o. 167 o.o 0 23. 000 • 23 .000 • 23.000 • 23.000 • 23.000 • 23.000 . 23 .000 . 23.000 • CAA 28. 70 29. 16 28.42 28.55 29.67 29.66 29.02 28.76

ANf 38.27 35.411 37. 73 38.09 35.87 35.94 36.90 37 .27 GRU 33 .03 35.110 33.86 33. 35 311.47 34.39 34.08 33.98 F/H 0.863 0.999 0.897 0.876 0.961 0.957 0.9211 0.912 F/FH 0.463 0.500 0.1173 0.467 0.1190 0.1189 0.480 0.1177

1 3 AHPII 5 AMP 2 3 AHPII 6 JA AMP 3 N[WO BIG FRCE AMP 1 AVCRAGE 11 3 AHPSAHC GltA IN 8 AVERAGE PLUS SIGMA

Page 204: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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Page 205: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPI.C 3 PYROXlNE ANALYSES 1 2 3 II 5

5107. 51.69 52. 12 51.90 52.12 51.69 r 102 0.15 0. 16 0. 15 0.16 o. 15 A;>03 0.62 0.66 0.611 0.66 0.62 11 U lll. II I 9. 111 9.81 10.117 9,111 HIIO 0.611 0.55 0.59 0.611 0.55 1-u:o 12. 18 13. 15 12.96 13. 15 12. 78 CAO 22.90 23. 51 23.20 23.51 22.90 11AO 0.0 0.0 o.o 0.0 0.0 NA;:"O 0.19 0.28 0.23 0.28 o. 19 1120 0.112 U.03 0.02 0.03 0.02 r 0.0 0.0 0.0 0.0 0.0 Cl. 0.0 0.0 0.0 0.0 o.o SUH 99.116 99.60 99.53 101.02 98.011 -0= r+CL O.ll 0.0 0.0 0.0 0.0 SUH 99.116 99.60 99.53 101. 02 98.011

SI 1.966 . 1.969 • 1.96l • 1.9511 • 1. 981 • N Al. 0.028 1. 993 0.029 1.998 0.029 1.996 0.029 1.983 0.019 2.000 0 AL ll.O . o.o • 0.0 • o.o • 0.009 • 0 11 0.0011 . 0.005 • 0.0011 • 0.005 • 0.00'1 • f[ 0. 333 • 0.289 • 0. 311 • 0.328 • 0.293 • ~IN 0.021 . 0.018 • 0.019 • 0.020 • 0.018 • HG 0.1211 1.082 0. 7110 1.051 0.732 1.067 0.735 1.088 o. 730 1.053 CA 0.933 . 0.952 • 0.9'12 • 0.91111 • 0.9'10 • BA 0.0 . 0.0 . o.o . 0.0 • 0.0 • NA 0.0111 . 0.021 . 0.017 . 0.020 . 0.0111 • K 0.001 0.9118 0.001 0.973 0.001 0.961 0.001 0.966 0.001 0.955 0 6.000 . 6.000 • 6.000 • 6.000 • 6.000 •

WO '16.110 117 .62 117 .01 '16. 57 117.116 EN 36.02 37.05 36.5'1 36.211 36.85 rs 17. 58 15.33 16.116 17. 19 15.69

f/H 0.11118 O. IJ 111 0.1150 0.11711 0.1126 f/rH 0. 328 0.293 0. 311 0. 322 0.299

1 JC PX II AVERAGE PLUS SIGHA 2 JC PX 5 AVERAGE MINUS SIGMA 3 AVERAGE

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SJ\HrL[ 3 F[LDSrAR ANALYS[S 1 2 3 ,, 5 6 7 8

S102 57. u•1 57 .06 55.84 58.52 58.29 56.611 51.1111 57. 22 I 107. 0.011 0.011 0.03 0.02 0.04 0.04 0.011 0.04 ll?Ol 26.65 27.46 26.63 21. 511 26.99 26.01 26.96 26.48 f[O 0.20 o. 15 0.11 O. JO 0.07 0.28 0. 311 o. 1 J MNO 0. (111 O.Ol 0.01 0.011 0.01 0.01 0.011 O. J 1 HGO 0.06 0.111 0.05 0.20 0. 32 0.03 0.03 0.0 CIIO 9.119 6.92 9.40 6.91 9.23 11.65 6. 61 6.85 0110 0.0 o.o 0.0 0.0 o.o 0.0 0.0 0.0 NJ\20 6. 11 6. 16 6.23 6.112 6.115 6.69 6.115 6.44 1<20 0.25 0.23 0. 111 0.22 0.16 0.24 0.22 0.20 r 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 Cl 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 SIIH 99. 76 100.21 96.114 102.23 101. 56 98.63 100.61 99.67 -0= F•CL 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SUH 99. 76 100.21 96. 44 102.23 101. 56 96.63 100.61 99.67

SI 2.566 . 2.553 • 2.550 • 2,566 • 2. 574 • 2.579 . 2. 5711 . 2.578 • Ill_ J. l12J . 1.11116 . 1.llll • 1.1124 • 1. 404 • 1.395 • 1.416 • 1.406 • N II 0.001 J.991 0.001 11.002 0.001 3.984 ll. 001 J.992 0.001 3.980 0.001 l.915 0.001 J. 991 0.0111 J.986 0 rr. 0.006 . 0.006 • 0.004 • 0.011 • 0.003 • 0.011 • 0.014 • 0.005 . ,..... HN 0.002 • 0.001 • 0.000 • 0.001 • 0.000 • 0.000 . 0.002 • 0.012 • HG 0.005 • 0.009 . 0.003 • 0.013 • 0.021 • 0.002 . 0.002 . o.o • CII 0.0 1.005 0.0 0.993 0.0 1.028 o.o 1,006 0.0 1.023 0.0 1.057 0.0 1.010 0.0 1.018 BA 0.0 • 0.0 • o.o • o.o • 0.0 • 0.0 . 0.0 • 0.0 • NII 0.536 • 0.536 • 0.552 • 0.546 • 0.552 • 0.606 . 0.551 • 0.563 • I( 0.0111 1.005 0.013 0.993 0.006 1.026 0.012 1.006 0.010 1.023 0.014 1.057 0.012 1.010 0.011 1.018 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 .

AN 411, 23 43. 77 45. 10 43.02 Ill. 71 40.41 42.64 42.67 AB 54. 32 54.88 54. 10 55,72 55.27 58.25 56. 10 56. 18 OR 1.45 1. lli 0.80 1.26 1.01 1.JJ 1.26 1. 15 CN 0.0 0.0 0.0 o.o o.o 0.0 o.o 0.0

F/H 1.667 0. 723 1. 3118 0.955 0.1110 5.426 7.865 o.o F/FH 0.626 0.420 0. 5711 0.1169 o. 123 0.61111 0.667 0.0

1 30 PLIIG 5 JC PLAG 2 JD PLAG 6 JC PLAG

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Page 207: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPLr 3 r£LDSPAR ANALYSES Q 10 II 12 13 111 Vi 16

SI02 ~6.23 •;1.111 5 I. 12 56. 32 56.311 55.99 56.'.",2 56.96 110? o.ur, 0.02 0.02 0.01 0.03 o.o:> 0.011 0.03 A?Ol 26. ,, 26.611 26. 75 26.16 26.80 26.80 26.84 26.77 HO 0.22 0.12 0. 12 0.18 0.21 0.07 0.11 o. 18 MUO 0.61 0.10 o. 32 0. 13 0.15 o. 32 0. 34 0. 16 MGO o.n 0.05 0.0 0.06 0.03 0.06 0.02 0.07 CAO 9. 13 8.81 8. 711 8.93 9. 35 9. 35 8.98 9.02 IIAO o.o 0.0 0.0 0.0 0.0 0.0 0.11 0.0 NA20 6.21 6.37 6. 3'."> 6. 11 5.911 5.93 6.06 6.28 k:?O 0.21 0.211 0.22 0.23 0.21 0.18 0. 16 0.21 f 0.0 o.o 0.0 o.o o.o 0.0 o.o o.o Cl. 0.0 0.0 0.0 o.o o.o o.o 0.0 0.0 SIIM 99. IIO 99. 78 99.64 98.15 99.06 98. 72 99.07 99.69 -0° f+CI 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 SUH 99. II() 99.78 99.64 98.15 99.06 98.72 99.07 99.69

51 2.550 • 2.582 • 2. 573 • 2.576 • ;?.556 • 2.549 • 2.561 . 2.566 • AL 1. 1,21 . 1.1109 . 1.420 • 1.410 • 1.lt32 • 1.ltl8 • 1.ltll • 1.1121 • N 11 0.002 3. 979 0.001 3.992 0.001 3.994 0.001 3.986 0.001 3.989 0.001 3.988 0.001 3.995 0.001 3.988 0 If. 0.008 • U.0115 . 0.005 • 0.007 • 0.008 • 0.003 • 0.004 • 0.007 • N Mil 0.023 • O.OOlt • 0.012 • 0.005 • 0.006 • 0.012 . 0.013 • 0.006 • HG 0.0 . 0.003 . 0.0 • 0.004 . 0.002 • O.OOlt . 0.001 • 0.005 • CA o.o 1.035 0.0 1.005 0.0 1.006 0.0 1.009 o.o 1.005 0.0 1.009 0.0 0.996 o.o 1.014 IIA 0.0 . o.o • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • NA o. 51,e • 0.555 . 0.555 • 0.5lt2 • 0.522 • 0.524 • 0.532 • 0.549 • K 0.012 1.035 O.Ollt 1.005 0.013 1.006 0.013 1.009 0.012 1.005 0.010 1.009 0.009 0.996 0.012 1.0111 0 8.000 . 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • AN 1111. 21 42.72 lt2.65 4lt.08 45.95 lt6.07 lllt.60 It]. 71

AB 54.58 55.89 56.07 51t.57 52.82 52.87 54.116 55.09 OR 1.21 1. 39 1.28 1. 35 1. 23 1.06 0.95 1.20 CH 0.0 o.o o.o o.o 0.0 0.0 0.0 0.0 r/H 1. 661 2.483 1. 3lt8 2.914 6.769 3.685 12. 146 2.696 f/rH 0.628 0.713 o. 57lt 0.71t5 0.871 0.787 0.927 0. 729

9 RIH 13 RIH 111 CORE 111 PL cone 11 RI Hr IN 15 15 RIH 12 ]A Pl COR[ 16 AVERAGE

Page 208: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

5AHPl £ J FCLUSPAR ANALYSES 17 18

5102 5 7. 111 'j6. 18 1102 0.01, 0.02 A20J ?1. 16 26.J9 lfO 0.26 O.U'J mm 0, JII -0.01 HGU IJ. 16 -0.01 ·cAO 9. 211 8. 79 BAO 0.0 u.o HA~O 6.n 6.0!i K20 11.21, u. 18 r 0.0 0.0 Cl 0.0 0.0 SUH 101. 10 97.68 -Ila F+CL o.o o.o SU11 101. 70 97.68

SI 2. 557 • 2.576 . Al. 1. 1117 . 1.1,25 • II 0.001 J. 9/5 0.001 1,.002 re 0.010 . O.OOJ • 11fl O.Oll • -0.000 . HG 0.010 • -0.001 . CA 0.0 1.01111 0.0 0.982 OA 0.0 • 0.0 • IIA (I, 559 • 0. 5J7 • K 0.01 J 1.0111, 0.010 0.982 0 8.000 • 8.000 •

AN IIJ.J5 1,11.09 AB 55. Jl 511.85 OIi 1. Jl 1.06 CN 0.0 o.o F/H 2. 166 2.118J r/rH 0.6811 0.71J

17 AVERAG[ PLUS SIGMA 18 AVERAGE MINUS SIGMA

N 0 w

Page 209: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIMl'L f l IIHrtl I BOU ANAL YSl S I 2 3 II 5

SIO? 115.06 1,1,. 79 1111. 93 115.06 111,. 79 110;, 1. 9?. 1. 77 1.115 1.92 1. 77 A20J 8. 11 8.92 8.81 8.92 8.71 rl 0 16.62 16.61 16.61 16.62 16.61 MIW 0.1,1 0.116 0.1111 0.116 0.113 MGO 10.90 10. 77 10.63 10.90 10. 77 CI\O 11. 33 11. 70 11. 51 11. 70 11. ll ll/10 0.0 0.0 0.0 0.0 0.0 N/120 1. 311 0.88 1. 11 1. lll 0.88 K20 1. 08 1.02 1.05 1.08 1.02 r 0.0 0.0 0.0 0.0 o.o CL o.o 0.0 0.0 0.0 0.0 11;10 o.o 0.0 0.0 o.o 0.0 SUM 97.111 96.92 97. 16 98.02 96.31 -o, F+CL 0.0 0.0 0.0 o.o o.o SUM 97.111 96.92 97. 16 98.02 96.31

SI 6. 773 . 6. 760 . 6.767 • 6. 738 • 6. 796 • Al 1,221 8.000 1.2110 8.000 1.233 8.000 1.262 8.000 1.2011 11.000 N AL 0.315 • O. lll I • 0. 331 • 0. 309 • 0.353 • 0 TI 0.217 • 0.201 • 0.209 • 0.216 • 0.202 • .i,.. Fl 2.088 . 2.091 • 2.092 • 2.077 • 2.106 • MN 0.055 • 0.059 . 0.057 • 0.058 . 0.055 • flG .... ,1111 5. 116 2,1123 5. 126 2.1132 5. 121 2.1128 5.089 2.1136 5,153 Cl\ 1.8211 • 1.892 . 1.858 . 1. 8711 • 1.8112 . NII 0. 390 . 0.258 • 0.1211 • 0. 388 . 0.259 • K 0.207 • o. 196 • 0.202 • 0.206 • o. 197 • (IA 0.0 2.1121 0.0 2. 3116 0.0 2. 3811 0.0 2.1168 0.0 2.298 CL 0.0 . n.o • 0.0 • o.o • o.o • r o.o • 0.0 . 0.0 • 0.0 • 0.0 • ·II 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 o.o 0 23.000 . 23.000 • 23 .000 • 23. 000 • 23. 000 • CAA 28.116 29.211 28.85 29.10 28.60

/IN I 36.09 37.115 37. 77 37. 72 37.82 GRU 33. 1111 Jl.31 33.38 ll. 17 ll.58

Fifi 0.818 0.890 0.8811 0.879 0.888 f/FM 0.1167 0.1111 0.1169 0.11611 0.1110

I lD lfl[l M1PII II AVERAGE PLUS SIGMA 2 30 FR[[ AMPII 5 AVERAGE MINUS SIGMA l AV[RAG[

Page 210: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIHPL[ J AHPIIIDOLE ANALYS[S 1 2 J II

SIO? '• 7. '•5 117 .115 111.115 117 .115 1107. ll.56 0.56 0. 56 0.56 11201 6. 76 6. 76 6.76 6.76 HO 15.<,6 15.66 15.66 15.66 ~1110 1),118 0.118 0.118 0.118 MGO 12.22 12.22 12 . .12 12.22 CAO 12.16 12.J6 12.16 12. J6 IIAO ll.O 0.0 0.11 o.o N/120 0.63 0.6J 0.6J 0.6J ~20 0.61 0.61 0.61 0.61 r 0.0 0.0 0.0 o.o CL 0.0 0.0 0.0 o.o 1120 0.0 0.0 o.o 0.0 SUH 96. 73 96.7J 96. 73 96. 73 •0• f +CL 0.0 o.o 0.0 0.0 SUH 96. 73 96. 7J 96. 73 96.73

SI 7. 103 • 7. 103 . 7. 103 • 7. 103 • N Ill. 0.897 8.000 0.897 8.000 0.897 11.000 0.897 8.000 0 AL 0.295 • 0.295 • 0.295 • 0.295 • Vl TI 0.063 . 0.063 . 0.063 • 0.063 • re 1.960 • 1.960 • 1.960 • 1.960 • HN 0.061 . 0.061 • 0.061 • 0.061 • MG 2. 726 5.106 2. 726 5.106 2.726 5. 106 2.726 5.106 CA 1. 9112 • 1.982 . 1.982 • 1.982 • NA o. 18i . o. 183 • o. 1113 . 0. 183 • I( 0.11 • 0. 116 • o. 116 • 0. 116 • BIi 0.0 2.282 0.0 2.282 0.0 2.282 o.o 2.282 CL o.o • o.o • o.o • 0.0 • r 0.0 • o.o • 0.0 • 0.0 . II o.o 0.0 o.o 0.0 o.o 0.0 o.o o.o 0 23.000 • 23.000 • 23 .ooo . 2J. 000 •

CAI\ 29.45 29.45 29.115 29.115 ANT 110.51 110. 51 110.51 110.51 GRU JO.OJ JO.OJ JO.OJ JO.OJ

F/H 0.741 0. 7111 0. 741 o. 741 F/FH 0.426 0.1126 0.426 0.1126

1 JC AHPH RIHHING PX J AV[RAG[ PLUS SICHA 2 AVCRAC[ II AV[RACC HINUS SICHA

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S/\1-11'1 f J 9

S 10<' •11. (Ill 1102 1. 70 ll?OJ 8.98 I IO 16.118 MNO (I. 36 M<.;ll 10. 10 CIIO 11.26 11110 0.112 Nll;>O 1.06 I<;>() 1. 08 r 0.02 Cl 0.117 11?0 -0.03 Slll-1 ?II. 19 -Us I +Cl ll.02 SllM 911. 16

SI 6. 706 Ill 1.29" 11.000 Ill 0. J~ I . 11 0. 199 . f I. 2. 11,7 . Mil 0.050 . HG 2. 31,r, ~.100 CA 1.8811 . 1111 ll. ]21 . I< 0.216 . 011 11.001 2 .1122 Cl 0.018 . I 0.009 . It -0.027 0.0 0 23.000 .

CIIA 29.31 /\Ill ]6.50 <.;RU 3~. 19

f/H 0.9H f/rH 0.1,51,

9 AV[RAGE MINUS SIGH/\

AHl'IIIBOI.E ANALYSES

N 0 (J'\

Page 212: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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Page 213: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPl[ JA2 PYROXENE ANALY~[S I 2 3 4 5 6 7

SIU? 52.2] 52. 14 52.26 53.02 52.11 I 52. 77 52.06 r 10;, 0.20 0. 16 0. 15 0. 11 o. 15 0. 19 o. 12 A?OJ o. /2 0.80 0.51 0.59 0.65 o. 17 0.511 110 Ill. 60 9. 32 111. 56 9.07 9.94 10.69 9. 18 tlNO 0.67 0.62 0. 73 0. 70 0.66 o. 72 0.611 tlGO 12.61 12.46 13.05 1 l. 11 12.82 1 J .09 12.55 CAO 22. JO 23.30 2].011 2J. 7J 23.09 23.61 22,57 RAO 0.0 0.0 0.0 0.0 0.0 o.o 0.0 NA20 0.211 0.24 0.22 0.25 0.211 0.25 0.23 ~?O 11.01 0.01 11.02 0.01 0.01 0.02 0.01 r 0.0 o.o o.o o.o 0.0 0.0 0.0 Cl. 0.0 0.0 0.0 0.0 o.o 0.0 o.o SUH 99.811 99.05 100.511 100. 59 100.00 102. 10 97.91 -0• r +Cl 0.0 0.0 o.o 0.0 0.0 o.o 0.0 SUH 99.811 99.05 100.511 100.59 100.00 102.10 97.91

SI I. 915 . 1.980 . 1.966 • 1.980 • 1. 975 . 1. 957 . 1. 995 • AL 0.025 2.000 0.020 2.000 0.023 1.989 0.020 2.000 0.025 2.000 0.034 1.990 0.005 2.000 N AL IJ.007 . 0.015 • 0.0 • 0.006 • 0.005 • 0.0 • 0.019 • 0 TI 0.006 . 0.005 • 0.0011 . 0.003 • 0.004 • 0.005 • 0.004 • CXl rr 0. ]112 . 0,296 . 0.332 • 0.283 • 0.313 • o. 332 . 0.2911 • Hll 0.021 . 0.020 • U.023 . 0.022 • 0.022 • 0.023 . 0.021 • HG 0.7111 1.090 o. 705 1.0111 o. 732 1.092 o. 730 1.0115 0.720 1.064 o. 724 1.083 o. 717 1.0511 CA 0.904 • 0.9118 • 0.929 • 0.950 • 0.933 • 0.938 • 0.927 • 111\ o.o . 0.0 . 0.0 . 0.0 • 0.0 • o.o • 0.0 • PIA 0.018 . 0.018 . 0.016 • 0.018 . 0.017 • 0.018 . o.on . I( 0.000 0.922 0.000 0.966 0.001 0.946 0.000 0.968 0.001 0.950 0.001 0.957 0.000 0.944 0 6.000 . 6.000 • 6.000 • 6.000 • 6.000 . 6.000 • 6.000 •

WO 45.62 48. 14 46.07 47 .84 46.91 46.54 47. 31 £N 36.06 35.81 36. 30 36.77 36.24 35.89 36.60 rs 16.33 16.04 17 .63 15. 39 16.85 17. 57 16.09

F/H 0.508 0.4118 0.486 0.419 0.465 0.489 0.439 f/fH 0. 337 0.309 0. 327 0.295 0. 317 0. 329 0. 305

I 31\2 CPX O OR A PUDD 5 AVERAGE 2 3A2 D OR A CPX Pll0D 6 AVERAGE PLUS SIGMA .l JA2C CPX WUOD 7 AVERAGE HINUS SIGMA 4 JA2C CPX WUOO

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SM11'L[ 3112 F[LDSPAR AHALYS[S 1 2 3 II 5 6

5102 55.83 55.71 56.50 56.01 56. 36 55.67 TIil?. o.os 0.03 0.05 0.04 0.05 0.03 A?.O] ;>/. 21 21. .?6 27 .03 27.17 27.27 27 .07 r ro 0.06 0.16 0.411 0.22 0.38 0.06 HNO O.U2 0.0 0.01 0.01 0.02 o.oo HCO o. 17 0. 1~ o. 12 0.15 0.17 o. 13 CAO 9. 6 r 9. 72 9.33 9.57 9. 75 9.110 DAO 0.0 0.0 0.0 0.0 0.0 0.0 NA?.O 5.87 5. 70 5.811 5.80 5.88 5. 7J k70 0.20 0. 15 0.19 0.18 0.20 o. 16 r 0.0 o.o 0.0 0.0 o.o o.o Cl u.o 0.0 0.0 0.0 0.0 0.0 SUH 99.08 98.88 99.51 99. 16 100.07 98.211 •I>= f +Cl IJ.U 0.0 0.0 0.0 0.0 0.0 SUH 99.08 98.88 99.51 99. 16 100.07 98.211

SI 2.533 . 2.531 • 2,551 • 2.538 • 2.535 . 2.5112 • Al 1.1155 • 1.1160 . 1,1138 • 1.451 • 1.4115 • 1.456 • N II 0.002 3.989 0.001 3.992 0.002 3.990 0.001 3.991 0.002 3.982 0.001 3. 999 0 re 0.002 • 0.006 . 0.017 • 0.008 • 0.0111 • 0.002 • \0 MN 0.001 . 0.0 . 0.000 • 0.000 . 0.001 • 0.000 • HG 0.011 . 0.010 • 0.008 • 0.010 • 0.011 • 0.009 • CA 0.1110 • 0.1173 . 0.1151 . 0.465 • 0.1170 • 0.1160 • DA 0.0 • 0.0 • 0.0 • o.o • o.o • 0.0 • NA 0.516 • 0.502 • o. 511 • 0.510 • 0. 513 • 0.507 . K 0.012 1.012 0.009 1.000 0.011 0.998 0.010 1.0011 0.012 1.020 0.009 0.987 0 8.000 • 8.000 • 8.000 • 8.000 • 11.000 • 8.000 •

AN 117. 10 48.09 116.36 117. 18 117.26 47. lU AB 51. 711 51.03 52.51 51. 76 51. 57 51.95 OR I. 16 0.88 I. 12 1.06 I. 16 0.94 CN 0.0 0.0 0.0 0.0 O.Q 0.0

F/H 0.265 0.598 2.105 0.880 1. 31,0 o. 271 F/FH 0.209 o. 3711 0.678 0.1168 0.573 0.2111

1 3112 DOR A PLAG II AVERAGE 2 3112 0 OR A PLAG 5 AVERAG[ PLUS SIGMA 3 3112 B PLAG 6 AVERAGE MINUS SIGHJI

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SAl1Pl[ 31\2 AHPHIBOLE ANALYSES I 2 J II 5

SI02 112 .03 112 .68 112.35 112.68 112.0J TI02 I. ')8 I. 79 1.88 1.98 I. 79 A?03 9.116 8.79 9. IJ 9.116 IL 79 rrn 17.58 16.95 17. 26 17.58 16.95 MNO 0.48 0.42 0.115 0.48 0.42 HGO 9. 711 10.30 10.04 10. JO 9. 78 CAO I I. 511 I I. 311 I I .44 I I. 54 I 1. Jlt RAO 0.0 o.o o.o 0.0 o.o NA20 I. II I. 16 I. 1 J 1. 16 1. 11 K20 I. 22 I. 10 I. 16 1.22 I. 10 r o.o 0.0 0.0 o.o o.o CL 0.0 0.0 0.0 0.0 0.0 1120 0.0 o.o 0.0 o.o o.o SUH 95. 18 91,. 53 94.85 96,IIO 93.31 ·O= r+CL 0.0 0.0 0.0 0.0 0.0 SUH 95. 18 94.53 911.85 96.40 93.31

SI 6. 5'16 • 6.657 • 6.602 • 6.553 • 6.652 • Al. 1.11511 8.000 I. 343 8.0011 1.398 8.000 1. 447 11.000 1. 3411 8.000 N AL 0.283 . 0.273 • 0.278 • 0~265 • 0.291 • ...... TI 0.232 . 0.210 • 0.221 • 0.229 . 0.213 • 0 re 2.2?0 • 2.211 • 2.250 • 2.257 • 2.243 • HN 0.063 • 0.055 • 0.059 • 0.062 • 0.056 • HG 2.270 5. 1311 2.395 5. 1411 2. 333 5. 141 2.357 5. 171 2.307 5. I I I CA I .926 • 1.1195 . 1. 910 • I. 898 • 1.923 • NA 0. 335 . 0. 351 . 0. 3113 . o. 345 • 0. 341 • K 0.242 . 0.219 • 0.231 • 0.239 • 0.222 • BA 0.0 2.503 0.0 2.465 0.0 2.4811 o.o 2.483 0.0 2.1185 CL o.o • o.o • 0.0 • 0.0 • 0.0 • F 0.0 . 0.0 . 0.0 • 0.0 • o.o • II 0.0 0.0 o.o 0.0 0.0 0.0 0.0 o.o o.o 0.0 0 23. 000 • 23 .000 • 23.000 • 23.000 • 23 .000 •

CAA 29.40 28.91 29. 15 28.87 29.45 ANT 311.67 36.52 35.60 35.85 35.33 GRU 35.93 34.57 35.25 35.28 35.22

F/H I .036 0.9116 0.990 0.984 0.997 r;rH 0.509 0.486 0.498 0.496 0.1199

I 102 FREE AHPII 4 AVERAGE PLUS SIGMA 2 3A2 D FREE AHPH 5 AVERAGE MINUS SIGMA 3 AVERAGE

Page 216: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SNIPLC JA2 AHPll I OOLC ANAL YS[S 1 2 J II 5 6

SI02 IIJ. 12 117. 19 Ill.JO 1111. 56 116.42 112. 70 1102 1. 61 1, 1 J 1.66 1. 55 1. 86 1. 211 A?OJ 9.116 8. 7J 9. 39 9.19 9.52 8.86 f 10 16.91 16. 38 16. 70 16.68 16.92 16.1111 HflO 0.51 0.50 0.51t 0.52 0.53 0.50 HGO 9.88 11. 11 10.27 10.112 10.93 9.91 CAO 11. Jll 12.110 11.66 11.65 11. 911 11. J7 DAO 0.0 0.0 0.0 0.0 0.0 0.0 NA?O 1. 11 o. 711 0.95 0.93 1.08 o. 78 1<20 1. 07 0.87 1.08 1.01 1. 10 0.91 F O.ll 0.0 0.0 0.0 o.o o.o Cl 0.0 0.0 0.0 o.o 0.0 o.o lt:'O 0.0 0.0 0.0 0.0 o.o o.o SUH 95.29 98.65 95.63 96.52 100. JJ 92. 72 ·O= F+Cl 0.0 0.0 o.o o.o 0.0 0.0 SUH 95.29 98.65 95.63 96.52 100.33 92. 72

SI 6.6% . 6.9113 • 6.665 • 6. 758 . 6.761 • 6. 755 . Al. 1. Jl1II 8.000 1.057 8.000 1.335 8.000 1.2112 8.000 1.239 8.000 1.2115 8.000 Al 0. ]1 / • 0.1156 • 0.365 • 0.1101 • o. 395 • 0.1107 . N TI 0. 217 . o. 125 • 0.192 • o. 177 • 0.2011 • 0. 1118 . ..... I l 2. 191 • 2.015 • 2.1116 . 2. 116 • 2.061 • 2. 1 75 . ..... HN 0.067 . 0.062 . 0.070 • 0.066 . 0.066 • 0.067 . ~IG 2.273 5. 125 2.1136 5.096 2. 352 5. 125 2.355 5. 115 2. 373 5.099 2.336 5.132 CA 1.869 • 1.892 • 1. 919 • 1.893 • 1.863 • I. 927 • NA 0. 332 • 0.211 • 0.283 • 0.2711 • 0.306 • 0.21t0 . I< 0. 211 • 0.163 . 0.212 • 0. 195 • 0.205 • 0.1811 . OA o.o 2.1112 o.o 2.266 0.0 2.11111 0.0 2. 362 0.0 2.3711 0.0 2. 350 Cl 0.0 . o.o . 0.0 • 0.0 • 0.0 • 0.0 . r 0.0 • o.o • 0.0 • 0.0 • o.o • 0.0 • II 0.0 o.o O.ll 0.0 o.o o.o o.o 0.0 0.0 0.0 0.0 0.0 0 23. 000 • 23.000 • 23.000 • 23. 000 • 23.000 • 23. 000 .

CAA 29.20 29.53 29.59 29.ltll 29.28 29.62 ANI 35.52 JO.OJ 36.25 36.62 37. JO 35.91 GRU 35.27 32.1111 311. 16 33.93 33.113 311. 117

F/H 0.993 0.853 0.91t2 0.927 0.896 0.960 f/fH 0.lt98 0.1160 0.1185 0.1181 0.1173 0.1190

1 AHPII RIMMING WlJOOS II AV[RAG[ 2 AHl'tt RIMMING WUODS 5 AV[RAGE Pl.US SIGMA J JA? D OR A AHPII RI HM I tlG PUDDS 6 AV[RAG[ HI NUS SI Gf1A

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SAHPL[ 13 M1PII I DOLE ANAL YSC S I 2 3 11 5 I\

SI02 52.60 53. 6 I 52.53 52.91 53.111 52 .112 110?. o. Jl 0.09 II. 3(> 0.26 o. 38 0. 111 A203 11. ?1 ?.99 11. 61 1,.02 4.RO J. 21, rro 111. 1,9 11,. or, 111. 16 14.22 14.112 14. 01 MIW 0. 39 0.28 11.33 0. 33 o. 38 0.29 HGO 13. ·,~ 13. 21, 12.56 13. 19 JJ.67 1;>. 71 C:/\0 12.1,1, 12.01 II. 81 12.09 12.35 11.82 11/\0 o.u 0.0•1 0.03 0.02 0.04 0.01 NA?O 0. 36 0.21, 0.1,3 o. 311 0.1,2 o. 2(, k20 0.28 11.25 o.•16 0.33 0.112 U.;>11 r o.o 0.08 0.118 U.05 0.09 11.02 Cl o.o 0.0 0.0 0.0 0.0 o.o 11?0 0.0 -0.011 -0.011 -0.03 -0.011 -0.01 SUH 9R.8~ 96. 19 97 .60 91. 75 100. 311 95. 16 -Oc r +Cl 0.0 U.03 0.03 0.02 0.04 0.01 SUH 98.85 96. 76 97.'H 97. 73 100.30 95. 15

SI I .1j6l1 . 1.818 . 7 .619 . 7 .666 . 7.550 • 7. 789 . N M n. 436 8.000 II. 182 8.000 0.381 8.00U o. 334 8,000 0.450 8.000 0.211 8.()00 ...... Al IJ.278 . O. 3 31 . 0.451 . 0. 353 • 0. 350 • 0. 357 . N II 0.03(, . O.UllJ • 0.039 • (1.028 . 0.040 . 0,016 . rr. 1 . /11 J . 1. 70 7 . 1. 111 . 1. 723 . 1. 705 . 1. ,,, 1 . HN o. 0118 . 0.035 . 0.01,1 . 0.01,1 • 0.045 • U.Ul6 • HG 2. 9111 5.051 2.816 11. 961 2. 719 11. 96 7 2. 8118 11.993 2.880 5.020 2.815 11. 965 CA 1. 917 . I. 816 . I. 835 . 1.876 • 1.870 • 1.882 . IIA 0. 100 • 0.068 . 0. 121 • 0.1196 . 0.116 . 0.0/6 . k 0.051 . 0.0116 . 0.085 • 0.061 • 0.076 . u.0115 . RA u.o 2.068 0.002 1.993 0.002 2.u1,1 0.001 2.035 0.002 2.065 11.0110 2.0011 CL 0.0 . 0.0 . 0.0 • 0.0 • 0.0 • O.CJ . r ().0 . 0.037 . 0.037 . 0.0211 . 0.0111 . 0.007 . II 0.0 0.0 -o. 037 0.0 -o. 037 o.o -0.0211 0.0 -0.041 0.0 -0.007 0.0 0 ;>J. 1100 • 23. 000 • 23.000 • 23.000 . 23. 000 • 23.000 .

CAA 28.01 28.89 29.01 28.92 28.11 29.07 ANI 1111.29 1111. JO 43.08 lll.90 1,,,. 30 111.1,n r.nu 26.90 26.81 27.85 27.18 26.92 21.115

f/H 0.601 0.605 0.6116 0.619 0.608 0.631 r/rH o. 378 0. 377 0. 393 o. 382 0. 378 O.381

1 13C AHPII 4 AV[RAGC 2 NCW AHP 5 AVCRAG[ PLUS SIGMA 3 A 6 AVCRAGE MINUS SIGHA

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SMIPL ( lJ FCLOSPI\R I\NALYS[S l 2 l 11 5 6 1

510? 65 . . 111 611.118 611. 11 611.99 611. 111 65.20 611. 29 1102 ll. llJ 0.011 U.05 0.05 0.04 0.05 0.03 l\20J 1 /. 11 / 11.911 16.86 17. 18 17. 36 11. 16 16.91 Jf O 11.23 0. 38 0.08 0.21 0.22 0. 33 o.n MIIO 0.011 0.0 0.0 0.011 0.02 0.011 0.0 HGO (J. 1l) 0.2l 0.12 0.20 0.16 0.22 0.11 CIIO O.O'J 0.011 0.05 0.06 0.05 0.06 0.011 0110 11.0 o.o 0.0 o.o o.o 0.0 0.0 IIA20 0.111 o. 35 o. 39 o. 33 0.37 0.40 0.33 K?.O 15.59 15.62 16. 72 16.97 16.22 16.85 15.60 r 11.0 0.0 0.0 0.0 0.0 o.o 0.0 Cl 0.0 0.0 0.0 0.0 0.0 o.o 0.0 SUH 99.?.6 99.011 98.44 100.02 99.20 100.91 97.49 -Oc r +CL 0.0 o.o . o.o 0.0 o.o o.o 0.0 SUH 99.26 99.08 98. 44 100.02 99.20 100.91 91.49

SI 3. IJJ?. . 3.003 • J.027 . 3.020 • 3.021 • J.003 • 3.0IIO . AL 0.955 . 0.985 . 0.9l7 • 0.941 • 0.955 . 0.9611 • 0.945 . II 0.001 3.989 0.001 3.989 0.002 3.966 0.002 3.963 0.001 3.977 0.002 3.968 0.001 3.9116 N rr U.0119 . 0.015 . 0.003 • 0.008 . 0.009 • 0.013 • 0.005 . ,_.. Hfl 0.002 . 0.0 • 0.0 . 0.002 • 0.001 . 0.002 . 0.0 • w MG 0.001 . 0.016 . 0.008 . 0.0111 • 0.011 . 0.015 • 0.008 . CA 0.002 . 0.002 . 0.003 . 0.003 • 0.002 • 0.003 . 0.002 . Ill\ Cl. U . o.o . o.o • o.o • 0.0 • 0.0 . 0.0 • NII 0.03/ . 0.032 . O.Ol6 . 0.029 • 0.033 • 0.036 . O.OJO . I< 0. 92l 0.980 0.928 0.992 1.006 1.056 1.006 1.061 0.966 1.022 0.990 1.0511 0.9111 0.986 0 8.000 . 11.000 . 8.000 • 8.000 .. 8.000 • 11.000 . 8.000 .

All 0.26 0.21 0.211 0.29 0.25 0.27 0.22 1\0 3.8J J.29 3.42 2.78 J.32 3.49 J. 13 011 95.91 96.51 96. Jl1 96.93 96.113 96.23 96.64 CN o.o 0.0 0.0 o.o 0.0 0.0 0.0

F/H 1. 518 0.927 O. l74 o. 703 0.847 0.964 0.613 F/FH 0.603 0.481 0.272 0.1113 0.459 0.1191 o. 380

l I JC KSrAn 5 AVERAGE 2 13c 1<sr11H 6 AVERAGE PLUS SIGH/\ J IJC l<Sr 1 AVERAGE HINUS SIGH/\ 11 1 JC SCAN l<SP

Page 219: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPLr 13 rcLOSPAR ANALYS[S I 2 3 11 5 6

5102 60.119 59. 32 60. 10 59.97 60,116 59. •18 r 102 0.03 o.u 0.0 0.01 0.02 -o. (JI) A20J 22.02 24.35 23.78 23. 38 21,. 38 22.39 HO 0. 10 0. 19 0.03 0.11 o." 0.01, HIW 0. 03 0.02 0.01 0.02 0.03 II. 0 I HGO 0.03 0.08 0. 13 0.08 0.12 0.04 CAO 6.55 8. 12 7.39 7.35 7.99 6. 71 UAO 0.0 0.0 0.0 o.o 0.0 0.0 N/\20 7 .116 7. 43 7. 53 7, IIJ 7. 52 7.43 K20 1. 611 0. 13 0.27 0.68 1. 36 -0.00 r o.o o.o 0.0 o.o o.o 0.0 Cl 11.0 0.0 o.o 0.0 0.0 0.0 SUH 98. 35 99.611 99. 211 99.08 102.05 96. 11 -0= f +CL 0.0 0.0 u.o o.o 0.0 0.0 SUH 98. 35 99.64 99.24 99.08 102.05 96. 11

SI 2. 759 . 2.666 • 2.703 • 2.109 • 2.670 • 2. 750 . N Al 1.163 . 1.290 • 1.260 . 1.245 • 1.269 • 1.220 . .....

TI 0.001 3. 9113 0.0 3.956 0.0 3.964 0.000 3,954 0.001 3.940 -0.000 3.970 ~ f[ 0.0011 • 0.001 . 0.001 . 0.0011 • 0.006 • 0.002 • HN 0.001 . 0.001 • 0.000 • 0.001 . 0.001 • 0.000 • HG 0.007. . 0.005 . 0.009 . 0.005 • 0.008 • O.OOJ . GA u. ]20 . 0.]91 . o. J!",6 . 0. 356 . 0.378 • u. 332 . OA 0.11 • 0.0 . 0.0 . o.o . 0.0 • 11.() . NA 0.660 . 0.6118 • 0.651 . 0.655 . 0.6111! • 0.666 . K 0.095 1.082 0.007 1.0!">9 0.015 1.038 0.039 1.060 0.077 1.114 -0.000 1.003 0 8.000 . 8.000 • 8.000 • 8.000 . 11.000 • 8.000 .

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51\MPI £ 111 BIOTITE ANALYSES I 2 3 lj 5 6 1 11

SIO? 36. '.> 1 37 .62 36. 19 36.50 36.02 39.51 37.89 37.39 1107 1.911 1. 5 3 1. 35 1.69 1. 59 0.95 1.60 1. 52 11203 17. Jl 11. 76 18.87 17. 311 17.83 17. 70 16. 71 16.80 rr.o 16.28 15.117 16. 31 16.26 17 .40 16.02 16. 30 16.08 mm Cl. 19 0.23 0.20 0.24 0.25 0. 19 o. 19 0.21 H<;O 12. /8 12.91 12. 33 13.27 12.37 11.99 12.61 12.36 C./10 0.20 0.29 0. 36 0.08 o. 15 o. 10 o. 12 0.11 AIIO o.u o.o 0.0 0.0 0.0 0.0 o.o 0.0 IIA20 U.22 0,116 0.69 0.09 0.111 o. 11 0.07 0.05 k20 8.88 9.26 8.55 9.21 8.46 9.l7 9.211 9.62 f 0.0 0.0 0.0 0.0 o.o 0.0 ().0 0.0 Cl. 0.0 o.o 0.0 o.o o.o 0.0 0.0 o.o 1170 0.0 0.0 o.o o.o 0.0 0.0 o.o 0.0 SUH 911. 32 95.53 911.85 911.68 911. 21 95.911 911, 73 911.111 -o- f +Cl o.o o.o 0.0 0.0 0.0 0.0 0.0 o.o SUM 911, 32 95.53 94.85 94.68 94.21 95.94 911. 73 94.14

SI 5.521 . 5.593 • 5.436 . 5.506 • 5.471 • 5.819 . 5.693 • 5.6611 • AL ?.1119 8.000 2 .1w1 8.000 2.5611 8.000 2.4911 8.000 2.529 8.000 2. 181 8.UOO 2. JO 7 8.000 2. 332 11.000 /\l 0.61)/ • 0. 704 • 0. 775 . 0.589 • 0.662 • 0.891 • 0.652 • 0.669 • r I 0.221 . 0. 1'/ I • 0. 152 • 0.192 • o. 182 • 0.105 . 0. 181 . 0. 173 • ff 2.059 . 1.923 • 2.049 . 2.051 • 2.210 • 1.973 • 2. 01111 • 2.039 • MN 0.11211 . 0.029 . 0.025 • 0.031 . 0.032 • 0.024 . 0.0211 . 0.027 • HG 2.881 5.792 2.861 5.688 2. 760 5. 762 2.9811 5.846 2.800 5.886 2.632 5.626 2.8211 5. 729 2. 793 5. 701 N CA 0.032 . 0.0116 . 0.058 • 0.013 • 0.0211 • 0.016 • 0.019 • 0.0111 . ..... NII 0.065 . 0. Ill • 0.201 • 0.026 • 0.0111 • 0.031 • 0.020 • 0.015 . 'I K I. 71 l . 1. /56 • 1.638 • 1. 772 . I. 639 • 1.760 • 1. 771 . 1.860 . OIi 0.0 1.810 0.0 1.935 0.0 1.897 o.o 1.811 0.0 1. 704 o.o I. 807 0.0 1.811 0.0 1.893 CL o.o • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • r 0.0 . 0.0 • 0.0 • 0.0 • o.o • 0.0 . 0.0 • 0.0 • It 0.0 o.o 0.0 0.0 0.0 o.o o.o o.o 0.0 0.0 0.0 0.0 o.o 0.0 o.o 0.0 0 22.000 • 22.000 • 22.00(' • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 •

f/H o. 723 0.682 0. 751 0.698 0.801 0. 759 0. 734 0. 7110 r/rH 0.1120 0.1106 0.1129 0.411 0.11115 0.431 0.4?.J 0.425

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SI\MPl [ 111 01or1rc ANALYSlS 9 10 11 12 1J 11, 15

S1U2 38.23 ll0.511 38.28 37. 70 37. 70 38.99 36.41 fl02 1.1,9 1.20 1. 38 1. 70 1. •19 1. ,,, 1.25 1'203 1 I. Ul 16.39 11. 68 11.46 17. ll 1 18.03 16. /8 rco 16.61 16. 11, 16. 38 16.23 16.29 16. 72 15.87 HIIO 0.25 u. 18 0.23 0.20 0.21 0.24 o. 19 Ml;O 11.?.5 12.54 11.66 11. 59 12.30 12.87 11. 71, CI\O 0.111 0.11 0.111 0.23 0.21 0.33 0.10 fiAO o.o 0.0 0.0 0.0 0.0 o.o 0.0 Nl\20 0. 56 0.08 0.53 0.30 0.27 0.49 0.06 k20 8. 17 9.10 8.68 9.21 8.98 9. 39 8.57 r 0.0 0.0 0.0 o.o o.o 0.0 o.o CL 0.0 0.0 0.0 o.o o.o 0.0 0.0 11?.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SUH 911, ()II 96.28 95.23 911.62 94.88 98.81 90.95 -0= f +CL 0.0 0.0 0.0 0.0 o.o o.o 0.0 SUH 911.04 96.28 95.23 94.62 94.88 98.81 90.95

SI !'>. 765 • 5.938 . 5,703 . 5.671 • 5,650 • 5.619 . 5.68•1 • AL 2.235 8.000 2.062 8.000 2.297 8.000 2. 329 8.000 2.350 8.000 2. 361 8.000 2. 316 8.000 ,\l_ 0.787 . 0.766 . 0.807 • o. 765 • o. 724 • 0.680 • 0. 771 • TI 0. 169 • o. 132 • o. 155 • 0.192 • 0.168 • 0.189 • o. 11,7 • H 2. 102 • 1.977 • 2.041 • 2.042 • 2.01,2 • 2.015 . 2.072 • HII 0.032 • 0.022 • 0.029 • 0.025 • 0.027 • 0.029 • 0.025 • N HG 2.529 5.619 2.738 5.635 2.589 5.621 2.598 5.623 2. 7119 5.710 2. 764 5.677 2. 732 5.71l6 ..... CA 0.066 • 0.011 • 0.065 • 0.037 . . 0.0311 • 0.051 • 0.016 • 00 NA 0.164 . 0.023 • o. 153 . 0.087 • 0.080 . o. 136 • 0:011 . k 1. 5 71 • 1.700 • 1.6119 • 1.767 • 1.716 • 1. 726 • 1. 706 • 8,\ 0.0 1,801 0.0 1. 7110 0.0 1.868 o.o 1.892 0.0 1. 831 0.0 1.915 0.0 1. 739 CL 0.0 . 0.0 . o.o • 0.0 • o.o • o.o • 0.0 • r 0.0 . 0.0 • 0.0 • 0.0 • 0.0 • o.o • 0.0 . II o.o 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 0.0 o.o o.o o.o 0 22.000 . 22.000 • 22.000 • 22.000 • 22.000 • 22.000 . 22.000 •

f/H 0.8 .... 0. 730 o. 799 0. 796 0.753 0. 7110 o. 161 F/FH O.ll58 0.1122 0.4114 O.llll3 0.1130 0.425 0.1134

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SAIIPl[ '" f(LOSPAR ANALYSLS I 2 l 11 5 6

SI02 611 ,91, 65.0'1 66. 16 65. 18 65.91 611. 81 110?. o.o, 0.11 0.06 0.08 o. 10 ll.06 A?O} 18. 51 18.10 18. 61 18.119 18.6 .. 18. l .. 110 o.•15 0.21 0.24 0. l I 0.41 0.21 HIIO I). 01 0.0 0.0 o.oo 0.01 -0.00 HGO 0.0 0.19 0.02 0.07 0.16 -0.02 CAO 0.05 0.19 0.10 0. 18 O.ll 0.01 DAO 0.0 0.0 0.0 0.0 0.0 0.0 NA20 o.,, .. 0.78 o.•12 0.55 0. 71 0.18 K20 15.59 14. 21 15. "l 15. 10 15.68 I ... 51 r 0.0 0.0 0.0 0.0 0.0 O.Cl Cl 0.11 0.0 0.0 0.0 0.0 0.0 SUH 11111.116 99.ll IOI. 10 100.16 10 I. 98 96, }If -o I +Cl IJ.11 0.0 0.0 0.0 0.0 0.0 SUH I00.06 99.ll 101, IO 100. 16 101. 98 98. 111

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SI\MPL[ 111 f[LOSPAR ANALYSLS I 2 3 lj 5 6 1 6

SI02 55. ll 5l. 1(, 52.15 56.60 511. 93 58.1111 ">I. r, 7 6l .67 110;_, 0.06 0.01 0.03 0.02 0.02 o.u11 0.03 U.03 l\?03 26.57 26. 76 26.96 211. 62 27. 26 l6. 21 26.116 22.111 rro 0. ~··

Cl. II U.26 o. 17 0.27 0.26 0. Iii 0.12 MNO 0.0 0.011 0.0 0.0 0.02 0.03 !J. OJ O.OJ MGO u. J•, !l. 16 0.0 0.0 0.20 O.IJJ 0.0 0.08 CAO 9.06 6.116 11. 93 7.36 9.63 7. 67 6.62 6. 19 111\0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Nl\20 6. 17 6.66 11.611 7. 17 5.611 7. 16 6.IIJ 6.62 k20 0. 35 0.10 0. 15 0. 111 o. 16 0.17 0.12 0. 39 r 0,0 o.o 0.0 o.o 0.0 o.o o.o 0.0 Cl 0.0 o.o 0.0 0.0 o.o 0.0 0.0 0.0 SUM 96.112 99.116 96.911 98.26 96. 35 100.0J 99.60 98.511 -o= f+CI. 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 SUM 98.42 99.118 98.911 96.28 98.35 IOU.OJ 99.60 98.511

SI 2 .';35 . 2. 5111 . 2.1117 • 2.661 • 2.515 • 2 .6 Ill . 2.569 • 2.606 • Al 1.1,35 • 1.1121 . 1. 565 . 1.328 . 1. II 71 • 1. 361 . 1.1102 . I. 163 . TI 0.002 3. 911 U.OOIJ 3.996 O.OUI J.98J 0.001 3.990 0.001 3.966 0.001 3.997 0.001 J.993 0.001 3. 992 ff 0.021 • 0.0011 . 0.010 . 0.006 • 0.010 • 0.010 . 0.005 • 0.0011 . MN 0.0 . 0.002 . 0.0 . 0.0 • 0.001 • 0.001 . 0.001 . 0.001 . MG 0.023 • 0.011 . 0.0 . 0.0 . 0.0111 • 0.002 • 0.0 • 0.005 • CA 0.1,116 . 0.1106 . 0.566 • 0.356 • 0.1172 • 0. 366 • 0.1,25 • 0.297 . N IIA 0.0 • 0.0 • o.o • o.o • o.o • 0.0 . 0.0 . 0.0 . N Ill\ 0.5116 . 0.562 . 0.1130 • 0.631 . 0.518 • 0.623 . 0.561 . 0.575 • 0 k 0.0;>0 1.056 0.006 1.012 0.009 1.035 0.008 1.0011 0.011 1.026 0.010 1.013 0.007 0.999 0.022 0.905 0 6.000 . 6.000 • 8.000 . 8.000 • 8.000 • 8.000 . 8.000 . 6.000 •

AN 113.95 111.01 51. 11 35.90 117. 16 36. 16 112.82 JJ.22 All 51,.01, 56.112 1, 1. 91 63.29 51. 77 62.27 56.119 611.29 Oil 2.02 0.58 0.86 0.81 1.05 0.97 0.69 2.119 CN 0.0 0.0 0.0 0.0 0.0 0.0 o.o o.o

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SIIHf'LE 111 f[LUSPAR ANALYSfS 9 10 11 I?. IJ , .. ,., 16

SI02 58. 3'.> 61. 32 6).011 61. 56 62.55 56.82 55. 78 56.03 1102 0.21 0.05 0.05 0.04 0.05 ll.06 0.02 0.05 11203 211. 211 211.1,0 23. 78 211. 01, 23.66 25.Jl 26.96 26.55 HO 0.90 0.11 0. II 0.2 .. 0.21 0.91 0. 12 0. 31 HNO 0.02 0.011 0.0 o.o 0.0 o. 36 0.22 0.09 HGO 0. 111 0.0 0.0 0.06 0.0 0.69 0.09 0. 10 CAO 6.8 .. 6. 19 5.96 6.31 5 ... 1 7.98 9.07 9. '" UAO o.o 0.0 0.0 o.o 0.0 0.0 0.0 0.0 N/120 7.35 1.6 .. 1.66 1 ... 9 7. 54 6.11 6.112 6.18 K20 0.118 0.211 0. 1 J 0.22 0.87 0. JO 0. 11 0.21 r 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0 CL 0.0 0.0 0.0 0.0 o.o o.o o.o 0.0 SUH 99. 15 100. 19 100. 73 99.96 100.29 99.20 98. 79 98.66 -0= f+CL 0.0 o.o 0.0 0.0 0.0 o.o 0.0 0.0 SlJH 99.15 100. 19 100. 73 99.96 100.29 99.20 98. 79 98.66

SI 2.61111 . 2. 720 . 2. 7611 • 2. 731j • 2.767 • 2.584 • 2.5 .. 0 . 2.554 • AL 1.2911 . 1.215 • 1.230 • 1.258 . 1.233 • I. 35 f • 1. .. 1, 1 • 1 ... 26 • TI 0.008 3.9116 0.002 3.997 0.002 ... 000 0.001 3.993 0.002 ... 002 0.002 3. 9113 0.001 3.987 0.002 3.9112 f[ 0.0111 . 0.012 • O.OOlj • 0.009 • 0.008 • 0.035 • 0.005 • 0.012 . HN 0.001 • 0.002 . 0.0 • 0.0 • o.o • 0.011, • 0.008 • 0.003 . HG 0.050 • o.o • 0.0 . 0.004 • 0.0 • o.o .. , • 0.006 . 0.007 • N CA 0.332 . 0.2911 • 0.280 • o. 300 • 0.256 • 0.389 . 0 ... 42 • 0 ..... 6 • N BA o.o . o.o • o.o • o.o • 0.0 • 0.0 . 0.0 • 0.0 • ..... NA 0.6 .. 6 . 0.6'.>7 . 0.652 . 0.6 .. 5 • 0.6 .. 7 • 0.597 . 0.567 . 0.5 .. 6 • K 0.028 1.090 O.Ollj 0.978 0.007 0.9 .... 0.012 0.971 0.0 .. 9 0.960 0.017 1.099 0.006 1.035 0.012 1.027 0 8.000 . 8.000 • 8.000 • 8.000 . 11.000 • 8.000 . 8.000 • 11.000 •

AN 33.02 10.1,9 29.8" 31.35 26.93 38. 76 .. 3. 57 ""·"3 AO 64.22 68.10 69. 39 67.35 67.92 59.50 55.80 5 ... 36 OR 2.76 I. 41 o. 77 1. 30 5.16 I. 73 0.63 1.22 CN 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0

f/H 0.698 0.528 0.0 2.21, .. 0.811j 1.036 2. 137 2.251 f/fH 0 ... 11 0.31i5 o.o 0.692 o,i,119 0.509 0.681 0.692

9 PLBEGIN 13 Pl 10 PL 1 .. PL FINIS CORE II Pl 15 RIM 12 PL 16 CORE

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SIIHPU 111 FELDSPAR ANALYSlS 1/ HI 19 20

SI02 56. 72 58.21 61. 17 55.26 1102 0.01 0.05 o. 10 0.00 11701 26.91 25.61 27 .26 23.97 ffO 0.20 0.30 0.55 0.06

.11110 0.'.>8 0.09 0.211 -0.07 HGO IJ.Ol 0. 15 0. J7 -0.08 CIIO 8.76 1. 91 9.56 6. 30 11110 0.0 0.11 0.0 o.o NA20 6. 13 6.75 7.47 6.02 K20 o. 12 0.25 0.114 0.06 r 0.0 0.0 0.0 o.o Cl. 0.0 0.0 o.o 0.0 SUH 100. 14 99. 31, 107. 15 91. 53 -0= F+CL 0.0 o.o o.o 0.0 SUH 100. 14 99. ]11 107. 15 91. 53

SI 2.551 • 7. (,;> l . 2.580 . 2.673 . Al 1. 1179 . I. Hill . I. J'.,'., • 1.366 • II O.UOI 3.9112 0.0112 J. 9Ar> 0.001 1. 918 0.000 4.039 f( 0.008 . 0. 011 . 0. (119 . 0.003 • HN 0.0~? • 0.001 . 0.0119 . -0.003 . HG 0.1102 . O.f/lU . 0.023 • -0.006 . c~ 0.1177 . o. ]8] • 0.43? . 0.326 . N n• ,,.o . "·" . o.o • 0.0 • N Pill o.~111 . U.'.,89 • 0.611 • 0.565 . N K 0.1/0/ 1.11•18 0.0111 1. 0 II ,:l ,,;•,, I.118 0.0011 0.889 0 n .OWi . 11.non . 8.000 • 8.000 .

1111 ,, , . S,5 in. on 40.51 36.116 1111 •, 7.,, ~'}. 13 57.27 63. 10 un n.f,A 1. 4 7 2.21 0.45 <:H "·" 0.0 0.0 o.o 1/'1 111. 721 1.118] 1. 187 2.2411 I /IH 0.9]6 0.597 0.543 0.692

17 RIH 19 AV[RAG[ PLUS SIGMA 18 AVERAGE 20 AVERAGE HINUS SIGMA

Page 228: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIHPI[ ?2 BIOTII[ ANAI.YSfS 1 2 3 4 5 6 -, 8

Sl!l2 .l6.<,•1 36. 12 36.36 36.6(1 36.79 36. 77 36.32 36.81 110? 2.65 ?..112 2.61 2.31 2. 16 2.58 2. 75 3.23 l\;'OI 16. 1•1 16.•16 1,. 12 I 7 .25 16.61 16.86 16.411 16.89 110 11. tl?. 1 /. 411 17. 3CI 17 .21 17.60 16.88 17. 71 17 .49 HflO 0.?.6 0.2•1 0.211 0.2ll 0.20 0.25 0.211 0.211 ~,co 12. 17 12.611 12.29 11.411 12.24 11. J3 11. J3 11. 18 r.110 ll. 111 0.25 0.09 0.07 0.06 0.05 0.07 0.08 UAO 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1111?0 0.07 o. 14 0.08 0.06 0.08 0.10 o. 14 0.04 K?O 9.119 9. 12 9. 39 9. 38 9. 36 9.35 9.28 9.29 r 11.0 0.0 o.o 0.0 0.0 O.ll 0.11 0.0 r.1. 0.0 0.0 0.0 o.o o.o 0.0 0.11 0.0 11~0 O.ll n.o 0.0 0.0 0.0 0.0 o.o 0.0 StlH 9'.,. ?ll 911.83 95.48 94.52 95. 10 911. 17 911.211 95.25 •O• r+CL n.o 0.0 0.0 o.o 0.0 0.0 0.0 0.0 SUM 95.20 94.83 95.48 94.52 95.10 94. 17 911.28 95.25

SI ~,.~Jl . 5.486 . 5.476 • 5.557 • 5.565 • 5.596 . 5.554 . 5.551 • N AL 2.1163 8.0011 2. 5111 8.000 2. 5211 8.000 2. 443 8.000 2.435 8.000 2.404 8.000 2.4116 8.000 2.449 8.000 N Ill. o.411 . 0.433 • 0.515 . 0.643 • 0.525 • 0.619 . 0.516 • 0.552 • w TI 0.301 • 0.276 • 0.296 • 0.264 • 0.246 • 0.295 • 0.316 • 0.366 • H 2. 151 . 2.215 . 2. 179 • 2. 185 . 2.226 • 2. 148 • 2.265 . 2.206 • Htl 0.036 . 0.031 . 0.031 • 0.026 • 0.026 • 0.032 • 0.031 . 0.031 • MC; ?. • 6 7<, 5. 775 2.862 5.817 2. 759 5. 779 2.589 5.706 2. 760 5.783 2.570 5.665 2.5112 5. 710 2. 513 5.6611 CA O.U23 . 0.041 . 0.015 • 0.011 • 0.010 • 0.008 • 0.011 • 0.013 • NII U.021 • 0.041 • 0.023 • 0.018 • 0.023 • 0.030 • 0.0112 . 0.012 • K 1.829 • 1. 767 • 1.804 • 1. 816 • 1.806 • 1. 815 • 1.810 . 1. 787 • 1!11 0.0 1. 872 0.0 1.8119 0.0 1.8112 0.0 1.845 0.0 1 .839 0.0 1.853 o.o 1.863 o.o 1. 811 CL 0.0 . u.o • 0.0 • o._o • o.o • 0.0 • 0.0 . 0.0 • r 0.0 • 0.0 • 0.0 • 0.0 • 0.0 . 0.0 • o.o . o.o . ti 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 o.o o.o 0.0 0.0 0.0 0.0 0.0 0.0 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 •

F/H 0. 760 o. 785 0.801 0.854 0.816 0.8118 0.889 0.890 F/FH 0.432 0.440 0.445 0.461 0.449 0.459 0.471 0.471

1 220 Bl 5 50509.5 2 728 Bl 6 119019.5 3 2ze or 7 48273. 5 II BT START50881.5 8 47528.5

Page 229: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SN1Pl£ 22 BIOflfE ANALYSES 9 10 11 12 1J 111 15 16

SI02 3 7. 18 36. 72 36.96 37.02 35.75 36.90 36. 32 36.119 110? 3. 11 3.62 2.68 2.63 2. 70 2.51 3.61 3.26 11203 16.09 16.02 17.36 16.36 16.89 16.80 16. 35 16.00 rio 16.08 17. JO 16.92 17.87 17 .II I 17.28 17. 79 17 .112 MNO 0.72 0.21 0.72 0.27 0.22 0.26 0.22 0.23 HGO 11.,,2 11.03 11. 52 11.59 11.50 11. 71 10.62 11. 91 CAO o.o•, 0.09 0.09 0.06 0.06 0.06 0.011 0.09 RIIO o.o 0.0 o.o 0.0 0.0 0.0 0.0 0.0 NA20 0.06 0.08 0.09 0.06 0. 10 0.06 0.011 0.09 k20 9. J? 9.112 9.50 9.39 9.113 9.21 9.26 9.28 f O.IJ 0.0 o.o 0.0 0.0 0.0 0.0 0.0 Cl 0.0 o.o 0.0 0.0 o.o 0.0 0.0 0.0 11?0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 SUH 96. 18 911.119 95.311 95.25 911.06 911.79 911.29 911.83 •Oc f+CL 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SUH 96. 18 911.119 95.311 95.25 911.06 911.79 911.29 911 .83

N SI 5.510 • 5,591 • 5.5'.">4 • 5,598 • 5.481 • 5.583 • 5.553 • 5. 5111 • N AL 2.1130 8.000 2.1109 8.000 2.11~6 8.000 2.1102 8.000 2.519 8.000 2.1117 8.000 2.11117 8.000 2.11!'>9 8.000 ~

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f/fH 0.473 0.471 0.455 0.468 0.462 0.457 0.488 0.453

9 39705.5 13 JI! 117. 5 10 38587.5 14 START 2 35285.5 11 35601. 5 15 110215.5 12 352311.5 16 411148.5

Page 230: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHrLC 22 BIOTIT[ ANALYSES I 7 18 19 20 21 22 23 24

$102 .16. Ill 36.24 J5.91 37 .oo H.08 J6.50 J6. 76 J6.65 1102 ].II') J. 18 J. 51, 3.611 3.J9 2.4J 2.,,8 2. 38 A201 16.99 16.6J 17. 33 16. 38 16.81 16.83 17 .22 16.39 rro 17. 51 18.05 17. 10 17. 111 17.56 17. 71 16. J8 17 .66 HNO IJ. 23 o. 18 0.25 0.18 0.20 0. 19 0. 18 0.21 HGO 11. J J 11. 23 10. 59 11.26 11, 18 11. 88 12. 19 11.49 CAO 11.11 0.07 0.09 0. Ill o. 17 0.07 0. 12 0. 18 DAO 0.0 0.0 0.0 0.0 o.o o.o 0.0 o.o NA20 0.06 0.01, o. 12 0.09 0. 1l 0.08 0.05 0.10 K?.O 9. 18 9.21 9.42 9.20 8.94 9.26 9.2J 9, 16 r 0.0 o.o 0.0 0.0 o.o o.o o.o 0.0 Cl 0.0 0.0 o.o 0.0 o.o 0.0 0.0 0.0 1120 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SUH 911, 91 911, 83 911, 35 91,.99 95.46 91,,95 94.61 94.22 •Oc f+CL 0.0 0.0 o.o 0.0 o.o o.o 0.0 0.0 SUH 911, 91 94.83 94.35 911.99 95.46 911,95 94.61 911.22

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Page 231: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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SIIMPL [ 22 r[LDSPAR ANALYS[S 11 18 19 20 21 22 23 24

S102 ~9.J~ 60. 57 61. 20 58.36 58.86 61.21 62.35 58.26 110;> ll. OJ CJ.05 ll.06 O.OJ 0.011 0.03 0.06 0.02 J\;'(Jl 7'j, I(, ?11.<,1 25.02 26.02 26.78 24.20 211. 2 J 25.1111 110 II.?(, 0.1,1 O. JO 0.211 o. 39 0. 13 0. J 1 ll. 08 HIHI u. (JI o.o o.o o.o 0.01 0.04 0.03 0.16 I-ICCJ 0.11 o.o 0.02 o.o 0.11 O.OJ 0.0 0.06 CIIO 6. 811 6. 40 6.43 7.74 6.32 6. JO 5.47 7.70 11110 o.o o.o o.o 0.0 o.o 0.0 0.0 0.0 f4/\;10 7. ?I 7.43 7.49 6.82 7.56 7.50 1. 90 7. 01 K?O 0. 18 0.22 0.19 0.22 o. 16 o. 17 0.26 0.09 I 0.11 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Cl 0.0 0.0 o.o o.o o.o 0.0 o.o 0.0 SUH 99.04 99.69 100.71 99.43 100.23 99.61 100.61 99.26 -o, r +Cl. 0.0 0.0 0.0 o.o 0.0 o.o 0.0 0.0 SUM ')9.011 99.69 100. 71 99.43 100.23 99.61 100.61 99.26

SI 2.669 . 2. 703 . 2. 701 .. 2.623 • 2.618 • 2. 727 • 2. 747 • 2.623 . N AL 1. 333 . 1.294 • 1. 301 . 1. 378 • 1.4011 • 1.270 • 1. 258 • 1. 373 . N

II 0.001 11.003 0.002 J.999 0.002 4.0011 0.001 4.002 0.001 4.024 0.001 J.998 0.002 4.006 0.001 3.996 \.0 If 0.010 • 0.015 • 0.011 • 0.009 • 0.015 • 0.005 • 0.011 • 0.003 • HN 0.000 . 0.0 . 0.0 • 0.0 • 0.000 • 0.002 . 0.001 . 0.006 . HG 0.0 . 0.0 • 0.001 • 0.0 • 0.00'7 • 0.002 • 0.0 • 0.0011 . Cl\ IJ.ll 0.9T9 o.o o. 911 0.0 0.968 0.0 0.989 0.0 0.985 0.0 0.967 0.0 0.960 o.o 1.002 Ill\ o.o . 0.0 . 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 . NII 0.629 . o. 6113 • 0.6111 . 0.5911 • 0.652 . 0.6118 . 0.675 . 0.612 . K 0.010 0.979 0.013 0.911 0.011 0.968 0.013 0.989 0.009 0.985 0.010 0.967 0.015 0.960 0.005 1.002 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 •

IIN 311. 03 31.83 31.82 38.05 31. 30 31. 38 27.25 37.58 AB 611.91 66.87 67 .06 60.67 6T. 16 67 .61 71. 21 61.90 on 1. 07 1. 30 1. 12 1.29 0.911 1.01 1. 511 0.52 CN 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0

r/H 3. 1,32 o. 795 8.416 1.011 2.0111 3. 189 2.638 2.263 urH o.n11 0.1143 0.894 0.503 0.671 0. 761 0. 725 0.6911

1 7 Pl. 21 Pl 18 Pl. 22 PL 19 Pl. 23 PL 20 Pl 24 CORHINIS

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SAMPl.l 22 F[LDSPAR ANALYSES 25 .?6 21 .?8 l9 30 31 32

s Ill?. 58. '.>8 51. ]II 58. 69 59. 77 58.'.,2 56.111 59. 36 55.97 r ro;, 0.03 ll.O 0.01 0.02 0.04 0.011 0.02 0.05 A;>OI 211.66 25.91 25. 11 25.95 26.99 27.05 26.23 21.00 Fl 0 0.10 0.14 0.10 0.18 o. 14 0.23 0. 38 0.09 HtW 0.26 o. 17 0. 15 0.40 0. 18 0.26 0.22 0.06 HGO 0.0 0.0 0.0 0.0 0,09 0.09 0.011 0.05 CAO 6.90 8.00 6.8•1 7.00 8.56 9.22 6.88 9.07 DAO 0.0 o.o 0.0 o.o o.o 0.0 0.0 0.0 NA?O 1. 36 6.88 7. 30 7.49 6.58 6. 34 7.50 5.90 K20 fl. 10 o. 14 0.19 0.20 o. 12 0.12 o. 13 o. 18 r 0.0 0.0 o.o 0.0 0.0 0.0 0.0 0.0 Cl. o.o 0.0 0.0 0.0 o.o 0.0 0.0 o.o SUM 98.01 98.64 98. 39 101.01 101. 22 99,16 100. 16 98. 37 -0= F+CI 0.0 ll.O 0.0 0.0 o.o 0.0 o.o o.o SUH 98.01 98.64 98. 39 101.01 101. 22 99. 76 100.76 98. 37

SI 2.667 . 2.6011 • 2.660 • 2.644 • 2.589 • 2,544 • 2.632 • 2.551 • Al. 1.323 . 1.390 . 1. 3111 • 1.353 • 1,407 . 1.438 • 1.371 • 1. 450 . N TI 0.001 3.991 0.0 3.993 0.000 11.001 0.001 3.998 0.001 3.997 0.001 3.984 0.001 4.003 0.002 11.003 w re 0.004 • 0.005 • 0.004 • 0.007 • 0.005 • 0.009 • 0.014 . 0.003 • 0 HN 0.011 • 0.001 • 0.006 • 0.015 • 0.001 • 0.010 . 0.008 • 0.002 . HG 0.0 . o.o • o.o . o.o • 0.006 • 0.006 • 0.003 • 0.003 . CA 0.0 1.007 0.0 1.015 0.0 0,9911 0.0 1.007 o.o 0.995 0.0 1.032 0.0 1.004 0.0 0.9114 8A 0.0 • 0.0 • 0.0 . 0.0 • 0.0 • 0.0 . o.o • 0.0 • NA 0.650 • 0.606 • 0.6111 • 0.6•12 . 0.5611 • o. 5511 . 0.6115 . 0.521 • K 0.006 1.007 0.008 1,015 0.011 0.9911 0.011 1.007 0.007 0.995 0.007 1.032 0.007 1.0011 0.010 0.984 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 .

AN 33. 93 38.80 33. 73 33.67 II 1. 53 1111.25 33.39 115.114 AB 65.119 60. 39 65. 15 65.19 57.77 55,06 65.86 53.119 OR 0.59 0.81 1. 12 1. 15 0.69 0.69 0.75 1.07 CN o.o o.o o.o 0.0 0.0 0.0 0.0 o.o F/H 3 .1132 o. 795 8.1116 1.011 2.009 J.076 8.1156 1.692 r;rH 0. 774 0.11111 0.894 0.503 0.668 0.755 0.894 0.629

25 RtH 29 RIH 26 CORE 30 CORE 27 RIH 31 RIH 28 CORE 32 CORE

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S/IHPLC 22 r uosrAn IINIIL vsrs 33 34 35 36 J7 38

5102 60.?4 59.21 59.60 59.45 60.81 58.0J T 102 0.01, O.OJ IJ.01 0.07 O.?I -0.01 A;>OJ ..,.,. 71 211. J/ 211. 11 25.26 26. 16 24.35 f[O 0.11 0.1? o. 36 0.28 0.111 0.08 MNO 0.51 U.27 0.11 0.08 O.?I -0.04 MCO 0.02 0.07 0.01 0.06 0.20 -0.08 C/10 6.60 5.82 6.83 6.96 7.811 6. 11 0110 0.0 0.0 0.0 0.0 0.0 0.0 111120 7.82 8.23 7. 77 7.JO 7.78 6.82 K20 0.111 0.28 11.20 0.21 o. 38 0.011 r 0.0 0.0 0.0 o.o o.o 0.0 Cl. 0.0 0.0 0.0 0.0 0.0 0.0 SUH 100. 19 98.48 99.49 99.67 104.09 95.26 -0= F+CL 0.0 0.0 o.o 0.0 o.o 0.0 SUH 100. 19 98.48 99.49 99.67 104. 09 95.26

SI 2.684 . 2.666 • 2.616 . 2.661 • 2.628 . 2.697 . N Al. 1.298 • I. JOI • 1.307 • 1. 332 • I.JJI . 1.334 . w TI 11.001 J.983 0.001 J.969 0.000 J.983 0.002 J.996 0.007 J.965 -0.1102 4.0211 .._. re 0.004 • 0.007 . 0.014 • 0.010 • 0.017 • 0.003 • HN 0.019 . 0.008 • 0.0 . 0.003 • 0.008 • -0.002 . HG 0.001 . 0.005 • 0.001 • 0.0011 • 0.013 • -0.005 . CA 0.0 1.023 0.0 1.042 0.0 1.030 0.0 0.997 0.0 1.071 o.o 0.918 BA 0.0 • 0.0 . 0.0 • o.o • 0.0 • 0.0 . NA 0.676 • 0.723 • 0.676 • 0.634 • 0.651 • 0.615 • K 0.008 1.023 0.016 1.042 0.011 1.030 0.012 0.997 0.021 1.071 0.002 0.918 0 8.000 . 8.000 • 8.000 • 11.000 • 8.000 • 8.000 •

AN 31.55 27 .65 32. JJ 34.06 34.91 JJ.OJ AB 67 .65 70.76 66.55 64.71 63.06 66. 71 OR 0.80 1.58 1. 1J 1.23 2.0J 0.26 CN 0.0 o.o 0.0 0.0 0.0 o.o

r/H 17. 577 J.309 20.199 J.291 1.910 J.076 F/FH 0.946 0.768 0.953 0.767 0.656 0. 755

JJ CORE 36 AVERAGE 34 RIH J7 AVERAGE PLUS SIGMA 35 RIHFINIS 311 AVERAGE HINUS SIGMA

Page 237: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAMPI I: 26 UIOIIIC ANALYSCS I ? 3 1, 5

SIO;> 36 .CIC, 36.21 36. 10 3(,.21 36.00 1102 If. 01 l. CJ?. 3. 91 11.01 3.92 Ai'Ol 111 .116 111.?•1 111.15 111. ;.,11 111. 06 HO 111. 6(, 19. 18 19.02 19. 18 18.86 MNO 0.21 0.211 0.24 0.28 0.21 m;o Ill. 11 111.•16 10.58 10. 71 10.116 C:110 0.U5 11.06 0.05 0.06 0.05 11110 0.20 0.22 0.21 0.22 0.20 111120 0.03 0.011 0.03 0.011 0.03 1<70 9.?.I 9.111 CJ. 17 9.21 9. 111 f 0.11, 0.53 0.50 0.53 0.111 C:l U.28 0.28 0.28 0.28 0.28 1170 -0.79 -n.3?. -0.31 -o. 32 -0.29 SUM 93.80 94.24 9l1. 02 94.65 93.39 -o.- r•c:1 o.:.>6 0.29 0.27 0.29 0.26 SIIH 93. 51, 93.95 93. 75 911. 36 93. 1J N

SI 5. '>811 . 5.592 . 5.508 . 5. 570 . 5.606 • w Al 2.41(, 8.0111) 2 .111)8 8.UOU 2.1112 8.000 2.1130 8.000 2.3911 8.000 N Al o. 1~'' . 0. 183 • o. 169 . 0. 152 . 0.186 • TI C,.•168 . 0.1,55 • 0.1161 . 0.1164 . 0.459 • rr 7. 4111 • 2. 1117 . 2.1162 . 2.1161 • 2.456 • MN 0.026 . 0.031 • 0.032 • 0.036 • 0.028 • HG 2.1116 5. 573 2. 1,06 5.560 2.11112 5.566 2.1156 5.575 2.1128 5.557 CA 0.008 . IJ.010 • 0.009 • 0.010 • 0.008 • NA 11.110'} . 0.012 . 0.011 . 0.012 • 0.009 • " 1.6?2 . I. 800 . 1.811 • I. 807 • 1.815 . BA 11.017 1.852 0.(113 1.836 0.013 1.844 O.Oll 1.842 0.012 1.845 Cl o. 11111 . 0.013 . 0.073 • 0.073 • 0.014 • r 0.231 . 0.259 . 0.2115 • 0.258 • 0.231 • If -o. 304 0.0 -0.332 0.0 -0.318 o.o -0.331 0.0 -0.305 0.0 0 2?.000 • 22.000 . 22.000 . 22.000 . 22.000 .

f/H 0.999 1.01111 1.021 1.020 1.023 r /rH 0.500 0.511 0.505 0.505 0.506

1 ur " AVERAGE PLUS SIGMA 2 SAHE GIIAIN 5 AVERAGE MINOS SIGMA 3 AVERAGE

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SAHPI l 76 PYROX£NC ANALYSES 1 7 l 11 5 6 7 8

SIU;/ 51.92 51.]4 51.94 51.60 51.44 51.07 51. 44 51.62 1102 0. 11 0.08 0.03 0.12 0.10 0.09 0.02 0.07 117.03 0.52 0.60 o. ;,3 0.58 0.65 0.61 0. 15 0.117 rro 11. 81 1;,.01 11.10 11.98 11.84 11.6;> 10.81 11. 37 ~INO o. 51 0.55 0.119 0.61 0.511 0.63 o.6l 0.57 m;o 11.41 10.96 11.;>0 11.211 11. l 1 11. 35 11.]5 11. ]5 CAO n.38 n.10 23. 5] 22.113 2;>.50 2".115 ;>]. 6;> 22.48 11AO 0.04 0.08 0.05 0.09 0.06 0.12 0.011 0.0 NA;>O 0.21 0.21 0.12 o. 18 0.22 0.21 0.06 0.21 1(;>0 0.02 o.o;, 0.02 0.02 0.22 0.02 O.O;> o.o;, r 0.0 0.01 0.02 o.o o.o o.o 0.0 0.0 Cl. 0.0 0.0 0.0 0.0 0.0 0.0 0.0 o.o SUH 98.99 97.95 98.71 98.85 98.88 98. 17 98. 111 98.16 -o, r+CL 0.0 0.0 0.0 0.0 o.o 0.0 0.0 o.o SUH 98.99 97 .95 98. 71 98.85 98.88 98. 17 98. 111 98.16

SI 1.991 . 1.992 • 1.996 • 1.985 • 1.980 • 1.979 • 1.990 • 1.993 • AL 0.00? 2.000 0.008 2.000 0.001, 2.000 0.015 2.000 o.o;,o 2.000 0.021 2.000 0.001 1. 997 0.007 2.000 N AL 0.0111 • 0.019 • 0.007 • 0.012 • 0.009 • 0.001 • o.o • 0.015 • w TI 0.00] • 0.002 • 0.001 • 0.00] • 0.00] • 0.00] . 0.001 • o.oo;, . w rr 0. 379 • 0. ]90 • 0.357 • 0.385 • 0.381 • 0. 377 • o. 350 • 0. 367 • MN 0.019 • 0.018 • 0.016 . 0.020 • 0.018 • 0.021 . 0.021 . 0.019 • HG 0.652 1.066 0.6]4 1. 06] 0.6112 1.022 0.6115 1.065 0.649 1.060 0.656 1.062 0.655 1.0;>6 0.653 1.056 CA 0.919 • 0.919 • 0.969 • 0.925 • 0.928 • 0.9]2 • 0.919 • 0.9]0 • OA 0.001 • 0.001 • 0.001 • 0.001 • 0.001 • 0.002 • 0.001 . 0.0 • HA 0.016 . 0.016 • 0.009 . O.Oll • 0.016 • 0.016 . 0.005 • 0.016 . I( 0.001 0.9]6 0.001 0.937 0.001 0.980 0.001 0.9110 0.011 0.956 0.001 0.951 0.001 0.985 0.001 0.9117 0 6.000 • "6.000 • 6.000 • 6.000 • 6.000 . 6.000 • 6.000 . 6.000 •

WO •16. 70 46.87 118.86 46.8] 46.97 116.96 48.86 47.23 EN 3]. 12 ]2. 33 3;>.]5 32.64 32.85 33.03 3;>.66 33. 17 rs 20. 18 20.80 18. 79 20.53 20.18 20.01 18.48 19.59

r/H 0.609 0. 611] 0.581 0.629 0.6111 0.606 o. 566 0.591 r;rH 0.379 0.391 0.367 0.386 0.381 0. 377 0.361 0. 371

1 PX H[WO ALL Fil£ 5 PX ;> PX 6 PX 3 PX 7 PX 4 PX 8 PX

Page 239: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

S111il'l£ 26 PYROX[N[ ANALYS[S 9 10 II 12

S102 51. 60 51. 55 51. 81 51.29 TIO;> o. 12 0.08 0.12 0.05 A20J 0.49 0.118 0.6•1 0. 31 rro 11. 36 11.54 11. 93 · 11.15 HNO 0.'>•1 0.51 0.61 0.53 HGO 11. 411 11.29 11. 43 11. 15 CAO 22.24 22,611 23. 15 22. 12 IIAO 0.03 0.06 0.09 0.02 tlA20 0.22 0.18 0.23 o. 13 K20 0.02 0.04 0.11 -0.02 r o.o 0.00 0.01 -o.oo CL 0.0 0.0 0.0 o.o SUH 98.06 98.43 100, 1 l 96.74 -0• f+CL o.o 0.0 o.o o.o SUH 98.06 98.113 HlO. 13 96.74

SI 1.991 . 1.989 . 1. 912 • 2;006 . N w AL o. 001 2.00U 0.011 2.000 0.028 2.000 0.0 2.006 .p..

AL 0.016 . 0.011 . 0.001 . 0.014 • Tl 0. 003 . U.002 • O.OOJ . 0.001 • rr 0, 36 I . 0.372 . 0.380 • 0.365 • Mti 0.018 . 0.019 . 0.0?0 • 0.017 • MG 0.6'.,9 1.062 0.6119 1. 053 0.648 1.053 0.650 1.048 CA o.no . 0.936 . 0.944 . 0.927 • BA 0.1100 . 0.001 . 0.001 • 0.000 . PIA 0.016 . 0.014 . 0.017 • 0.010 • K 0.001 fl. '.IJII 0.002 0.952 0.005 0.968 -0.001 0.936 0 6.000 . 6.000 . 6.000 • 6.000 •

WO 116.81 47. 35 47 .40 4 7. 31 Ell 33.54 32.86 32.54 33.18 FS 19.59 19.79 20.06 19.51

f/H o. 5811 0.602 0.617 0.588 f/fH 0. 369 0.376 0.381 0.370

9 PX II AVERAGE PLUS SIGMA 10 AV[RAC£ 12 AVERAGE MINUS SICHA

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SI\Hl'l [ ?(, C:lll OR II [ ANAL YS[ S 1 ?. 3 11

Sl02 27. 56 27. 56 27. 56 27. 56 1102 0.07 0.07 0.07 0.07 11203 19.02 19.02 19.02 19.02 f IO ;>J .115 23.115 23.85 23.85 HNO 0.47 0.47 0.117 0.41 H(;() 15.118 15.08 15.08 15.08 C:1\0 o. 11 o. 17 0. 17 o. 17 111\0 0.08 0.08 0.08 0.08 141\7.0 0.02 0.02 0.02 0.02 K20 0.03 0.03 0.03 0.03 r o. 17 0. 17 0.17 o. 17 Cl 0.0 o.o 0.0 0.0 11;,o 11. 21 11.21 11.21 11. 21 SUH 9 f. 73 91. 73 97. 73 97. 73 -0• f+CL o.o, 0.07 0.07 o.o, SUH 91.66 97 .66 97 .66 97.66

N 51 2.919 • 2.919 . 2.919 • 2.919 • w Al 1.0111 4.000 1. 081 4.000 1.0l'1 4.000 1. 081 4.000 lJl Al. 1.292 . I .292 • 1.292 • I .292 • II 0.006 . 0.006 • 0.006 • 0.006 • rr 2. 112 . 2.112 • 2. I 12 • 2. 112 • MN 0.0112 . 0.042 • 0.0112 • 0.042 • HG 2. 3110 . 2.380 . 2. 380 . 2. 380 • C:I\ 0.0 5.863 0.0 5.863 0.0 5.863 0.0 5.863 NA 0.0011 . 0.0011 • 0.0011 • 0.0011 • K 0.0011 . 0.004 . 0.004 • 0.004 • llA 0.003 5.863 0.003 5.863 0.003 5.863 0.003 5.863 CL O.ll • 0.0 • 0.0 . o.o • r 0.0~7 • 0.057 • 0.057 • 0.057 • II 7. 943 8.000 7.943 8.000 7.943 8.000 7.943 8.000 0 18.000 • 18.000 • 18.000 . 18.000 •

f/H 0.905 0.905 0.905 0.905 f/fH 0.475 0.475 0.475 0.475

1 Clll 3 AVCRAGE PLUS SIGMA 2 AVERAG[ 4 AVERAGE MINUS SIGMA

Page 241: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIHPLC 26 F£lDSPAR ANlllYSfS 1 2 3 4 5 6 1 8

S102 611,611 68.07 58. 47 56. 19 59.65 59.60 63. 86 57.78 1102 0.01 o.o 0.0 0.0 0.01 0.02 o.u 0.02 11203 23.25 20.66 25.52 26.84 25.53 25.02 23. 71 26. 10 flO 0. 18 0.01 0.67 0.15 0.08 0. 11 0. 19 0.09 HNO o.o 0.0 0.01 0.0 0.02 0.01 0.0 0.03 HGO 0.01 o.o 0.01 0.0 0.0 0.0 0.02 0.0 CIIO 3. 511 0.61 7 ,92 8.53 6.89 6.40 4.22 7.85 8110 0.0 0.0 0.01 0.07 0.01 0.09 0.0 0.07 N/120 9.44 11.28 6.44 6.83 7.62 7. 8'I 9. 71 7.07 l<?O o. 111 0.05 0.12 0.18 0.14 0.29 0.09 0.19 r u.o o.o o.o o.o 0.01 0.0 0.0 0.0 Cl 0.06 o.o o.o . 0.0 0.0 o.o 0.0 0.0 SUH 101.21 100.68 99. 17 98.79 99.95 99. 38 IOI. 80 99.20 -0= f+CL 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 SUH 101.21 100.68 99.17 98. 79 99.95 99.38 101. 80 99.20

SI 2.816 . 2.955 • 2.636 . 2.556 • '2.660 • 2.675 • 2. 779 • 2.608 . N

AL 1. 193 . I. 057 • 1. 356 . I. 439 • 1.341 • I. 323 • 1.216 . 1. 388 . w Tl 0.000 4.009 0.0 4.012 o.o 3.992 0.0 3.995 0.000 4.001 0.001 3. 999 o.o 3.995 0.001 3.991 0\ rr 0.007 • 0.000 • 0.025 • 0.006 • 0.003 • 0.004 • 0.007 • 0.003 • HN 0.0 . o.o • 0.000 • u.o • 0.001 • 0.000 . 0.0 • 0.001 • HG 0.001 . 0.0 . 0.001 • 0.0 • o.o • 0.0 • 0.0111 . 0.0 • CA o.o 0.911 0.0 0.981 o.o 0.979 o.o 1.036 o.o 1.000 o.o 1.013 0.0 1.029 0.0 1.015 811 0.0 . 0.0 • 0.000 • 0.001 • 0.000 • 0.002 • o.o • 0.001 • NA 0.797 . 0.949 • 0.563 • 0.602 • 0.659 • 0.682 • 0.819 . 0.619 • K 0.008 0.977 0.003 0.981 0.007 0.979 0.010 1.036 0.008 1.000 0.017 1.013 0.005 1.029 0.011 1. 015 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8,000 •

AN 17 .03 2.89 110. 16 40.37 33.05 30.53 19.27 37 ,57 All 82. 17 96.82 59.10 58,49 66. 14 67.67 80.24 61.23 on 0.80 0.28 o. 72 1.01 0.80 1.65 0.49 1.08 CH 0.0 0.0 0.02 0. 12 0.02 0. 16 0.0 0. 12

F/H 10.099 0.0 38. 160 o.o 0.0 0.0 5.330 o.o f /fH 0.910 o.o 0.974 0.0 0.0 0.0 0.842 0.0

1 Pl 5 Pl 2 IIR 6 Pl 3 PL 7 Pl 4 Pl 8 PL

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SIIHrLC 26 rELOSrAR ANAlYSlS 9 10 ll 12 13

S102 57 .63 ,7.28 60.32 611.00 56.63 1102 0.02 o.o 0.01 0.02 -o.oo /120] ;,7. ll 26.68 25.06 26.99 23. Ill no 0.21 o. l7 0.19 0. 36 0.01 HllO o.o 0.0 0.01 0.02 -o.oo 11GO 0.01 0.01 0.01 0.01 -o.oo CIIO 8.ll 8.411 6.27 II. 79 l.76 11110 0.02 o.o O.Ol 0.06 -0.01 NA20 6.85 6.60 7.97 9.5\ 6.42 K20 0.16 0.16 0.15 0.21 0.09 r 0.01 o.o 0.00 0.01 -o.oo Cl. 0.01 o.o 0.01 0.02 -0.01 SUH 100.54 99. 34 100.01 109.96 90.05 -Oc r +CL 0.0 0.0 o.o 0.0 o.o SUH 100.54 99. lll 100.01 109.96 90.05

SI 2.569 . 2.583 . 2.685 • 2.627 . 2.754 • N Al. 1. 435 • 1. 417 • 1. l 15 . 1. 305 • 1.326 • w II 0.001 4.005 0.0 4.000 0.000 4.000 0.001 3.933 -0.000 4.081 ....... re 0.008 • 0.006 • 0.007 . 0.012 • 0.001 • Hli 0.0 • 0.0 • 0.000 • 0.001 • -0.000 • HG 0.001 . 0.001 • 0.000 • 0.001 • -0.000 • Cl\ 0.0 1.007 0.0 I. 001 o.o 1.004 0.0 I. 169 0.0 0.807

"" 0.000 • 0.0 • 0.000 . 0.001 . -0.000 • NII 0.592 . 0.577 • 0.688 • 0.757 • 0.606 • K 0.009 l .007 0.009 l.001 0.009 1.004 0.011 1.169 0.006 0.807 0 8.000 . 8.000 • 8.000 • 8.000 • 11.000 •

/IN 39.75 41.02 JO.OJ JJ.44 24.25 /10 59.JO 58.05 69.05 65.51 75.06 OR 0.91 0.93 0.87 0.96 0.70 CN O.Ol 0.0 0.05 0.08 -0.02

r/H 11.783 9.538 18.056 16.638 o.o r;rH 0.922 0.905 0.9411 0.9113 o.o

9 r1. 12 AVERAGE PlllS SIGH/\ 10 Pl 13 AVERAGE MINUS SIGMA 11 IIV[RIIG[

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SMIPI.[ 7.6 IIHPIII DOL[ IINAL YS[S I 2 3 ,, 5

s10;, '>I. 34 50.21 50. 11 51.34 50.21 f 10? 11.03 0.06 0.04 0.06 0.03 11203 ?.66 •1.88 3. 77 4.811 2.66 f 10 fl1.f16 15. 71 15.08 15. 71 14.46 HIIO (J. 38 o. 32 0. 35 0. 38 0. 32 HGO 13.7.6 11. 50 12.39 13.28 11. 50 CI\O 12.50 12.06 12.28 12.50 12.06 01\0 0.09 o.o 0.()4 0.09 0.00 NA20 IJ.26 0.68 0.47 0.611 0.26 K70 0. 11, 0.28 0.21 0.28 0.14 r 0.25 0. 23 0.24 0.25 0.23 C:L n.o o.o 0.0 0.0 0.0 ff?O -o. 12 -o. 11 -o. 11 -o. 12 -o. 11 SUH 95.27 95.82 95.55 99.33 91. 76 -o= r •r:1. 0.11 0.10 0.10 0.11 0.10 SUH 95. 17 95.72 95.45 99.23 91.66

SI 7.678 . 7.508 . 7.593 • 7 .412 • 7.787 • N Ill. 0. 322 8.000 0.492 8.000 0.407 8.000 0.586 11.000 0.2ll 11.000 w AL o. 1116 . IJ.368 • 0.257 • 0.2•12 • 0.273 • 00 TI 0.00J . 0.007 . 0.005 . 0.007 • 0.003 • f[ 1.8118 . 1.96'> . 1.886 . 1.897 . 1.875 . HN 0.0•18 . 0.041 • 0.044 . 0.046 • 0.042 . HG 2.960 11.966 2.563 li.943 2. 762 4.955 2.858 5.049 2.658 4.853 C:A 2.003 . 1.932 . 1.967 • 1. 933 • 2.004 • NI\ 0.075 . o. 197 • o. ll6 • 0.190 • 0.0711 • K 0.027 • 0.053 • 0.040 • 0.052 • 0.028 • OIi 0.005 2.110 0.0 2. 183 0.003 2.146 0.005 2. 180 0.000 2. 110 CL o.o . 0.0 . o.o . o.o • 0.0 • r 0.118 • 0. 109 . 0. 114 • 0.114 • O. l ll • ff -o. 118 o.o -o. 109 o.o -o. 114 o.o -o. 114 0.0 -0. l ll 0.0 0 23.000 • 23.000 • 23.000 • 23 .000 • 23.000 .

CAA ?9. )7 29.72 29.54 28. 71 J0.•16 ANf 43.41 39.43 41. 47 42.43 40.40 GRU 27.22 30.85 28.99 28.86 29.14

f /M 0.627 0.782 0.699 0.680 o. 721 f/fM 0.365 0.439 0.411 0.405 0.419

I A 4 AV[RAG[ PLUS SIGH/I 2 A 5 AVERAG[ MINUS SIGMA 3 AVERAG[

Page 244: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHrLE 26 1

5102 38. 12 1102 0. 16 A20J 26.61 r201 1.99 HllO 0.59 HGO 0.2J CAO 23.08 IIAO o.o NA20 0.0. ~20 0.02 r 0.0 CL 0.0 H20 1.89 SUH 98.69 -0= F+CL o.o SUH 98.69

SI J.Oll • AL o.o. 3.0ll AL 2.1,19 • TI 0.010 • HG 0.027 • HJ+ 0.475 . HN 0.0110 3.030 CA 1.955 • I( 0.002 • NA o.o . BA 0.0 I. 957 CL 0.0 0.0 r 0.0 o.o II 1.000 1.000 0 13.000 .

PS 15.88 Cl 82.80 PD I. 32

1 [P rlNIS

£P1D0TE ANALYSES (OIi CALCULATED) 2

38.611 1.01,

24.09 8.52 I. 17 0.93

23.08 0.0 0.01 0.01 0.0 0.0 1.90

99. 39 o.o 99.39

l.054 • 0.0 3.0511 2.21,3 . 0.062 • 0.110 • 0.507 . 0.018 J.000 1.9511 • 0.001 • 0.002 • o.o 1.957 o.o o.o 0.0 0.0 1.000 1.000

13.000 • 17. 91 19. 37.

2. 77

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Page 245: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAMPLE 31 DIOTIT[ ANALYSES I 2 3 4 5 "6 1 8

SI02 37.00 37.05 37. 13 36.93 37 .20 37 .63 37. 16 37. 39 1102 3.53 J. 19 3. 48 3.114 3.42 3.118 3.52 3.65 A203 111. 17 14. 3 I 14.58 15.40 14.65 111. 69 14.63 15.02 rro 18.66 18.65 18.60 17.52 11.63 17 .98 18. 17 18.66 HNO 0.20 0.22 0.21 0.23 0.23 o. 18 0.21 0.23 HGO 11. 43 11.92 12.28 12.44 12.70 12. 10 12. 14 12.55 CAO 0. 10 0. 13 0.08 0.16 0.07 0. 18 0.12 0.16 BAO o.o 0.0 0.0 0.0 0.0 0.0 0.0 0.0 IIA20 0.05 0. 10 0.06 0.06 0.02 0.03 0.05 0.08 k20 9.53 9. 19 9.40 9.25 9. 11 9.19 9.28 9.42 f 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 CL 0.0 0.0 o.o o.o 0.0 o.o 0.0 0.0 11?0 0.0 0.0 0.0 o.o o.o 0.0 0.0 0.0 SUH 91,. 61 95. 36 95.82 95.43 95.03 95.46 95.29 97. 15 -o~ r+cL 0.0 o.o 0.0 0.0 0.0 0.0 o.o 0.0 SUH 94.61 95.36 95.82 95.43 95.03 95.116 95.29 97.15

SI 5.676 • 5.631 • 5.616 • 5. 573 . 5.635 • 5.679 • 5.635 • 5. 573 • Al 2. 3211 8.000 2. 369 8.000 2. 384 8.000 2.427 8.000 2.365 8.000 2. 321 8.000 2.365 8.000 2.427 8.000 Al 0.237 • 0. 194 • 0.215 • 0. 311 • 0.251 • 0.291 • 0.250 • 0.212 • II 0.1101 • 0.433 • o. 396 • 0. 390 • 0. 390 . 0.395 • 0.402 . 0.409 • . f[ 2. 394 • 2. 310 . 2.353 . 2.211 • 2.2311 • 2.269 . 2. 305 • 2. 326 • HN 0.026 . 0.028 . 0.027 • 0.029 . 0.030 . 0.023 . 0.027 • 0.029 • HG 2.613 5.678 2. 700 5. 726 2.768 5.758 2. 798 5. 740 2.868 5.171 2. 722 5.700 2. 7115 5. 729 2. 788 5. 764 N CA 0.016 • 0.021 . 0.013 • 0.026 • 0.011 • 0.029 • 0.019 • 0.026 • p. NA 0.015 • 0.029 • 0.018 • 0.018 • 0.006 • 0.009 • 0.016 • 0.023 • 0 k 1.865 . 1.781 . I. 813 . 1.780 • 1. 760 • 1. 769 . 1.795 . I. 791 • BA o.o 1.896 0.0 1.832 o.o 1. 61111 o.o 1.824 0.0 1. 771 0.0 1. 807 0.0 1.830 o.o 1.840 Cl 0.0 . 0.0 • o.o • 0.0 • 0.0 • o.o • 0.0 • 0.0 • r 0.0 . 0.0 . 0.0 • 0.0 • 0.0 . 0.0 . 0.0 • 0.0 • II 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0 22.000 • 22.000 • 22.000 . 22.000 • 22.000 • 22.000 . 22.000 • 22.000 •

f/H 0.926 0.888 0.860 0.801 0. 789 0.842 0.849 0.845 f/fH 0.481 0.470 0.462 0.445 0.441 0.1157 0.459 0.458

1 31 BT 5 31 BT 2 31 Bl 6 31 BT l 31 RT 7 AVERAGE 4 31 BT 8 AVERAGE PLUS SIGMA

Page 246: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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Page 247: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIHPLE 31 rELOSPIIR ANALYSES I 2 3 II 5 <, 1 8

Sl02 611. 53 611.68 611,211 611. 12 57.20 55. 511 56.81 56. 10 1102 0.03 0.05 0.06 0.06 0.06 0.03 0.02 0.03 11203 18.117 17.90 18. 10 16.1111 27 .05 27.18 21. 61 21. 811 rm 0.09 0.07 0.11 0.68 0.23 0, 19 0.21 0.20 MNO 0.0 0.01, 0.05 0.0 0.33 0.62 (I, 18 0.05 HGO 0.22 0.28 0. 18 0.52 0.06 0.011 0.02 0.02 CIIO 0.09 0.1,1 0.11 0.08 8.99 9. 51, 9.55 9.52 0110 0.0 o.o o.o o.o 0.0 0.0 0.0 0.0 NA20 1.00 0.110 0.116 o. 30 6. 73 6. 311 6.211 6.05 K20 14.81 15. 18 15.39 16.65 0.16 0.19 0. 11 0.20 r 0.0 0.0 o.o 0.0 o.o 0.0 0.0 0.0 Cl. 0.0 0.0 o.o 0.0 0.0 o.o 0.0 o.o SUH 99.211 99.01 98.70 98.85 100.81 99.67 100.93 100.01 ·O= f+CL 0.0 0.0 o.o 0.0 o.o 0.0 o.o o.o SUH 99,21, 99.01 98.70 98.85 100.81 99.67 100.93 100.01

SI 2.990 • J.006 • 2.999 • 3.022 . 2.5511 • 2.519 • 2. 531, . 2.523 • Ill. 1,008 . 0.980 . 0.996 . 0.913 • 1,1,23 • 1.1152 . 1.11511 . 1.1,15 • 11 0.001 3.999 O.OU2 J.989 0.002 3.997 0.002 3.937 0.002 3.980 0.001 3. 972 0.001 3.989 0.001 3.999 re 0.003 • 0.003 • 0.0011 • 0.027 • 0.009 • 0.007 • 0.010 • 0.008 • HN 0.0 . 0.002 . 0.002 . 0.0 • 0.012 • 0.11211 • 0.001 • 0.002 • HG 0.015 . 0.019 • 0.013 • 0.037 • 0.004 • 0.003 • 0.001 • 0.001 • N CA 0.0 0.988 0.0 0.980 0.0 0.982 0.0 1.096 0.0 1.047 0.0 1.066 0.0 1.0211 0.0 1.008 .p.. BA 0.0 . 0.0 • 0.0 • 0.0 • o.o • o.o • o.o • o.o • N NA 0.090 . 0.036 • 0.042 • 0.021 • 0.583 • 0.557 • o. 51,u . 0.527 • K 0.875 0.988 0.900 0.980 0.916 0.962 1.001 1.096 0.009 1.0117 0.011 1.066 0.010 1.0211 0.011 1.008 0 8.000 . 8.000 . 8.000 • 8.000 • 8.000 • 8.000 . 8.000 . 8.000 .

AN 0.116 2. 1l 0.57 0. 39 42.09 1111.92 115.38 115.98 AO 9.21 l. 77 4.32 2.66 57 .02 511.02 53.66 52.87 OR 90.21 94. 10 95. 11 96.95 0.89 1.06 0.96 1. 15 CN o.o 0.0 0.0 0.0 o.o 0.0 0.0 0.0

f/H 0.230 0.221 0.501 0. 7311 5.276 11. 1173 12.689 7.031 r/fH 0. 187 0.181 o. 33ft 0.423 0.8111 0.920 0.921 0.875

1 3111 KSPIIR 5 Pl CORH IN IS 2 3 IA KSPIIR 6 RIM 3 311\ KPAR 7 CORE II 31 KSP 8 RIH

Page 248: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIMPI [ ]I FELDSPIIR ANALYSES 9 10 II 12 13

5102 51. 59 56.1111 59. 72 63.57 55.88 1102 0.02 0.01, 0.04 0.06 0.02 1120] 26.88 27. 11, 23.117 28. 19 18. 75 f I 0 0.22 o. 16 0.22 0. ]9 0.06 MNO IJ.22 o. 14 0.16 0.35 -0.02 MGO 0.02 0.05 0.14 0. ]0 -0.01 C/10 9.02 9.119 5.68 10.18 I. 18 [1110 o.o 0.0 0.0 0.0 0.0 NA20 6.28 5.99 ].98 6.80 I. 16 k?O o. 17 0. 17 6.ll 13.8] -1.21 f 0.0 o.o o.o 0.0 o.o Cl 0.0 0.0 0.0 0.0 0.0 SUM 100.1,;, 99.62 99. 73 123.66 75.79 -o, f+CL 0.0 0.0 o.o 0.0 o.o $UM 100.1,2 99.62 99. 7l 12].66 75.79

SI 2. 5 /11 • 2.546 . 2. 722 • 2.488 • J.050 • Ill 1.1116 . 1. 44 l . 1.260 . I.JOO . 1.206 • 11 0.0111 l.990 0.001 l.990 0.001 l.984 0.002 l.789 0.001 4.257 re 0.008 • 0.006 . 0.008 • 0.013 • 0.00] • MN 0.008 • 0.005 . 0.006 • 0.011 • -0.001 • MG 0.001 . O.UOl . 0.010 . 0.017 . -0.001 • N CA 0.0 1.0011 0.0 1.007 0.0 1.020 0.0 1.674 o.o 0.108 +" IIA o.o . 0.0 . o.o . 0.0 • 0.0 • l,J

NII o. 5,,,, . 0.5211 . 0. 352 . 0.516 • 0. 123 . K 0.010 1.004 0.010 1.007 0.]67 1.020 0.690 1.674 -0.085 0.1011 0 8.000 . 8.000 . 8.000 • 11.000 • 11.000 •

/IN It]. 81 46.22 27. 86 26. Ill 64. ]4 IIR ~5.20 52.79 35.31 31.58 114.60 on 0.98 0.99 36.lll 42.211 -711.911 Ctl 0.0 0.0 o.o o.o 0.0

F/M 12.42] l.387 1. 540 I. 3911 5.276 f/fH 0.925 o. 772 0.606 0.5113 0.1141

9 CORE 12 AVERAGE PLUS SIGMA 10 RIMFIPIIS 13 AVERAGE MINUS SIGMA II AV[RAG[

Page 249: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPI.[ 31 AHPIIIBOLE MlAL YS[S 1 2 l 4 5

510?. 51.,, 51.84 51.80 51.811 51. 77 1107 0.1,0 0. 36 0.111 0.48 0. 38 A:>O J i.n l. 16 l. 34 3.76 2.92 IHI 12.6] 13.116 1 J .OIi 13.46 12.63 MNO 0.24 0. 34 0.29 O. llf 0.211 l~GO 13.58 111. 56 111. 0 7 111. 56 13.58 CAO 12.62 12.20 12.111 12.62 12.20 llAO 0.0 0.0 0.0 0.0 0.0 NA20 0. 18 0.11·1 0.32 O.IIJ 0.18 K20 0.23 0. JO 0.26 0.30 0.23 I 0.0 0.0 0.0 0.0 0.0 r.t 0.11 0.0 o.o o.o 0.0 11?0 n.O 0.0 0.0 o.o 0.0 SUH 911. 65 97. JI 95.98 97.83 94. 13 -o- r+CL 0.0 0.0 o.o 0.0 o.o SUH 911. 65 97. J 1 95.98 97.83 911. 13

SI 1. 118 . 7.553 . 7.635 . 7.5211 • 1. 1118 • Al. 0.282 8.000 0.11117 8.000 0.365 8.000 0.1176 8.000 0.252 8.000 Al 0.231 . 0. 198 • 0.215 • 0. 167 • 0.263 • Tl 0,0511 . 0.0112 . 0.048 • 0.052 • 0.043 . I[ 1. 575 • 1.6110 . 1.608 • 1.6311 • 1.581 • HN 0.030 • 0.0112 • 0,036 • 0.042 • 0.030 • HG 3.018 11,908 3. 162 5.084 J.091 4.997 3.150 5,0115 3.029 If. 9117

N CA 2.016 . 1.9011 • 1.959 • 1.963 • 1. 956 • NA 0.057. . 0. 133 . 0.093 • o. 132 • 0.052 • ~

K 0.01111 . 0.056 . 0.050 . 0.056 • O.Olflf • ~

BA 0.0 2.112 o.o 2.093 o.o 2.102 0.0 2.150 0.0 2.052 CL 0.0 . 0.0 • o.o • o.o . o.o • I 0.0 . 0.0 . o.o • o.o • 0.0 • II 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0 23. 000 • 23.000 • 23.000 • 23. 000 • 23 .000 •

CAA JO. 31 26.22 29.2"1 28.91 29.65 ANT 115.46 116.85 116. 17 116.110 115.92 CHU 211. 18 24.92 211.56 211.68 211.112

r/H 0.532 0.532 0.532 0.532 0.532 F/[H 0.3117 0.347 0. 347 0. 3117 0. 347

1 31A AHPII II AV[RACE PIUS SIGMA 2 31A AHPII 5 AV[RAC[ MINUS SIGMA 3 AVERAGE

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SI\HPL[ 331\ I\HPlt I BOLE APl/\1. VS[ S I ?. J Ii 5 6

S102 115. 78 51.26 51. 18 1,9.111 51. 9"1 46.811 1102 I. ?.l "· ;,r 0. 43 o.64 1.06 o. 27. 1\203 8.01 11.110 l. 55 5.32 7.25 1.19 IHJ l'.,.98 1'.>.18 111. 85 15. 40 15.86 111.911 MNO 0. 36 0. 38 0.15 o. 36 0. 38 0. 35 HC:O 11. 86 13. 118 111. 118 IJ.27 111.35 12. 19 C/\0 11.90 12.29 12.1111 12.21 12.1111 11.9A IIAO o.o o.u 0.0 u.o 0.0 o.u NA20 I. 26 0.112 0.115 o. 71 1. 10 0. 32 K?O 0.90 U.28 0.27 0.118 0.78 0.19 r 0.0 o.o 0.0 0.0 0.0 0.0 CL o.o o.o 0.0 0.0 o.o 0.0 11;,o 0.0 o.o 0.0 o.o o.o 0.(J SUH 97.28 98.16 98.00 97.81 105.20 90.IIJ •O• f+CL o.o 0.0 0.0 0.0 o.o o.o SUH 97 .28 98. 16 98.00 97. 81 105.20 90.113

SI 6. 861 . 7. II 711 • 7. 1173 • 7 .273 • 7. 105 • 7.469 • AL 1.119 8.000 0.526 8.000 0.527 8.000 o. 727 8.000 0.895 8.000 0.511 8.000 N Al U.216 • 0.230 • 0.0811 • 0.196 • 0.2711 • o. 105 . ~

TI o. 139 . 0.030 • 0.0111 • 0.071 • 0.109 • o. 027 . V,

f [ 2.003 • 1.875 • 1.813 • 1.896 .. I. 8111 • 1.992 • HN 0.0116 • 0.047 • 0.0111 • 0.0115 • 0.01111 • 0.0111 . HG 2.6119 5. 112 2.930 5. 112 3. 151 5. 139 2.912 5.121 2.925 5. 165 2.898 5.010 CA 1. 911 • 1.920 • I. 9116 . 1.926 • 1.822 . 2.0111 • NA 0.166 . 0. 119 • 0. 127 • 0.201 • 0.291 • 0.099 • K O. I 12 . 0.052 . 0.050 • 0.091 • o. 136 • 0.038 . Ill\ 0.0 2.11119 0.0 2.091 o.o 2. 1211 0.0 2.219 0.0 2.2119 0.0 2. 18'> Cl. u.o . 0.0 . 0.0 • o.o • o.o • 0.0 • r 0.0 • 0.0 • 0.0 • 0.0 . o.o • o.o • It 0.0 o.o 0.0 0.0 0.0 0.0 o.o 0.0 o.o 0.0 0.0 0.0 0 23. 000 • 23. 000 • 23.000 • 21. 000 • 23.000 • 23.000 .

CAI\ 28.91 ?8. 35 27.99 211.110 27.59 29.31 AtH 110.09 113.26 45. 32 42.96 1111.29 41 .119 GRU l 1.00 28. 39 26. 70 28.611 28. 13 ?.9.20

f/H o. 7/J 0.656 0.5119 0.667 0.635 o. 1011 f/fH 0.1136 0.196 0.371 O.IIOO 0. 388 0.1113

1 3]A 118 ASSOCIATED WI TIC PROBCO BT Ii AVERAGE 2 311\ 110 5 AVERAGE PLUS SIGH/\ l ]]A 118 6 AVERAGE HIHUS SIGHA

Page 251: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIHPL[ 33A OIOTITE ANALYS(S 1 2 3 1, 5 6 I 8

5102 37, 10 36. 71 36.86 37,311 36.lt6 37. 35 36. 77 36.60 1102 3. 611 lt.06 3.92 3. 51t 3.65 3. 97 3.55 3.66 11203 15. 21 15.lt2 lit. 70 llt.57 llt.59 15.03 lit. 97 lit. 75 rro 18.93 19.57 19.00 19. 18 19.lt6 19.82 19.60 19.95 HNO 0.29 0.27 0.23 0.20 0.22 0.22 0.23 0.22 HGO 11.63 10. 78 I 1.lt6 11.02 11.65 11.82 11.90 10.ltll CAO 0.07 0. 13 0. 13 0.06 0.07 0. 111 (I, 12 O.Olt OAO 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0.27 NA20 0. II 0.07 0.06 0.08 o. 11 0.08 0.08 o. 10 K?.O 8.97 6.31t 9.45 8.96 9.27 6. 73 6.62 9, 39 r 0.0 0.0 0.0 o.o 0.0 o.o 0.0 o. 39 Cl 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0. 16 1170 0.0 o.o 0.0 o.o 0.0 0.0 o.o -0.22 SUH 95.95 95, 37 95.63 91t.95 95.50 97. 16 95.611 95.97 -0• F +CL 0.0 0.0 0.0 o.o 0.0 0.0 o.o 0.20 SUH 95.95 95. 37 95.83 911.95 95.50 97. 16 95.611 95.77

SI 5.595 . 5.569 . 5,5911 . 5.6911 • 5.567 • 5, 5111 • 5.5611 • 5.597 • N Al 2 ,1&05 6.000 2.1111 8.000 2,1,06 8.000 2. 306 8.000 2.1133 8.000 2.1126 8.000 2.436 8.000 2.403 8.000 "" Al. 0.?.96 . o. 326 • 0.221 • o. 313 • 0. 190 • 0.217 • o. 2311 • 0.2111 • 0\ II 0. II 13 . 0.1165 • 0.11111 • o.1to6 • 0.1119 • O.ltll6 . 0.11011 . O.lt21 • ff ? . 367 • 2.1183 • 2.410 • 2.11116 • 2.1183 • 2.1173 . 2.1160 . 2.538 • HN 0.037 . 0.035 • 0.030 • 0.026 • 0.028 • 0.028 • 0.0?9 • 0.026 • HG 2. 6111 5. 1119 2.1138 5. 7117 2.591 5,699 2.505 5.695 2.650 5. 771 2.629 5. 793 2.6811 5.832 2.367 5,595 CA 0.011 • 0.021 • 0.021 • 0.010 • 0.011 • 0.022 . 0,019 . 0.007 • NA 0.032 . 0.021 • 0.018 • 0.0211 • 0.033 • 0.023 • 0.023 • 0.029 • I( 1. 725 • 1. 6111 • 1.828 • I. 7113 • 1.8011 • 1.662 • 1.6611 • 1.822 • BIi o.o 1. 769 0.0 1.656 0.0 1.867 0.0 1. 776 o.o 1.8118 o.o 1. 707 0.0 1. 707 0.016 1. 8711 Cl 0.0 . 0.0 • o.o • 0.0 • 0.0 • 0.0 . o.o . 0.0111 • r o.o . 0.0 . 0.0 . o.o • 0.0 • 0.0 • 0.0 • 0.188 • II 0.0 o.o 0.0 0.0 o.o 0.0 o.o 0.0 0.0 0.0 0.0 0.0 o.o 0.0 -0.229 0.0 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 . 2?.000 •

F/H 0.927 1.033 0.9112 0.987 0,9116 0.951 0.935 1.0611 F/FH 0.1161 0.506 0,1185 0.1197 0.1187 O.lt88 0.1183 0.520

1 33A 81 5 33 Bl 2 3311 BI 6 33 BT 3 33A Bl 7 33 Bl It 33 BT IIIT ERGROWN WI Ill 118 8 NEWO BT

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SAM Pl E 3 lil BIOTITC ANALYSES 9 10 11

SI02 36.93 37 .22 36.611 r 102 J.75 J.95 3.56 11203 111. 90 15. 19 111.62 rro 19.1111 19.79 19.09 MNO 0.23 0.26 0.21 MGO 11. Jl1 11.83 10.811 CAO 0.09 o. lJ 0.06 IIAO 0.03 0.12 -0.06 Ni\20 0.09 0.10 0.01 K20 8.97 9. lJ 8.60 r 0.05 o. 16 -0.06 Cl 0.02 0.07 -0.0J 1170 ·CJ. OJ -o. 10 0.05 SUM 95.82 96.08 93. 56 •Os r +CL U.OJ ll.09 -0.011 SUM 95.60 97 .99 93.61

SI 5. 5911 . ~). 5211 . 5.668 • AL 2.111)6 6.000 2.1116 8.000 2. 332 8.000 Al. 0.255 . 0. 161 • 0.332 • II 0.1128 • 0.11110 • 0.11111 • I[ 2.1163 • 2.1156 • 2.1170 • MN O.UJO . 0.033 • 0.027 . MG 2.560 5. 735 2.618 5. 728 2.500 5.7113 CA 0.015 . 0.021 • 0.010 • NA 0.025 . 0.030 • 0.021 • K 1. 732 • 1. 767 • 1.697 • BA 0.002 1. 775 0.007 1.625 -0.003 1. 7211 CL 0.005 . 0.018 . -0.009 • f 0.02) . 0.063 • -0.039 • II ·0.078 0.0 -o. 102 0.0 0.0116 0.0 0 n.ooo . 22.000 • 22.000 •

1/M 0.9111 0.951 0.999 r / rM 0.1,93 0.1167 0.500

9 AV[RAG[ IO AV[RAG[ PL.US SIGMA

11 AVERAGE MINUS SIGMA

N .i::---..J

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SAHl'L£ 3JA FELDSPAR ANALYSES I 7 l 4

Sl02 65.24 65,24 65.24 65.24 r 102 0.06 0.06 0.06 0.06 A203 17.85 17.85 17.85 17 .85 HO 0.]6 O. l6 0.36 0. 36 HNO O.Ol 0.03 0.03 0.03 HGO 0.18 o. 18 0. 18 0, 18 CAO 0.09 0.09 0.09 0.09 BAO 0.0 0.0 o.o 0.0 NA20 0.29 0.29 0.29 0.29 K20 14,72 111. 72 111. 72 14.72 r 0.0 o.o 0.0 0.0 Cl. 0.0 0.0 0.0 o.o SUH 98.82 98.82 98.82 98.82 -0= F+CL o.o 0.0 0.0 0.0 SUH 98.82 98.82 98.82 98.112

SI 3.026 . 3.026 . 3.026 • 3.026 • N .I'-Al 0.975 . 0.975 • 0.975 . 0.975 • 00 TI 0.002 11.003 0.002 11.003 0.002 11.00J 0.002 11.003

F[ 0.014 . 0.0111 • 0.0111 • 0.0111 • HN 0.001 • 0.001 • 0.001 • 0.001 • HG 0.012 • 0.012 • 0.012 • 0.012 • CA 0.0 0.929 o.o 0.929 0.0 0.929 o.o 0.929 BA 0.0 • o.o • o.o • o.o • NA 0.026 • 0.026 • 0.026 • 0.026 • K 0.871 0.929 0.871 0.929 0.871 0.929 o. 871 0.929 0 8.000 • 8.000 . 8.000 • 8.000 •

AN 0.50 0,50 0.50 0.50 AB 2.89 2.89 2.89 2.89 OR 96.61 96.61 96.61 96.61 CH o.o 0.0 0.0 0.0

F/H 1.217 1.217 1.211 1. 217 F/FH 0.549 0.549 0.549 0.5119

1 JJA KSrAR 3 AVERAGE rLUS SI GHA 2 AVCRAG( II AV[RAG( MINUS SIGMA

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SI\HPLE 33A rCLOSPAR AHALYSCS 1 2 3 lj 5 6 ., II

SI02 58.119 59.119 61.118 59.611 60. 32 ~9.92 60.28 61. 17 1107. 0.011 O.Ol 0.06 0.08 0.02 0.011 0.03 0.05 A20l 26.52 25.117 211. 85 25. 111 211.97 26.25 211. 19 211. 15 rro o. 12 0.20 0.11 o. 11 0.15 o. 10 0.07 0.10 HIIO 0.02 0.03 0.02 o.o 0.01 0.01 0.02 0.02 HGO 0.0 0.05 0. 11 o.o 0. 19 0.08 0.08 0.12 CI\O , . 33 7.80 5.91 6.53 6. 17 ·,. 27 6.86 6.58 llAO 0.0 0.0 0.0 0.0 o.o 0.0 0.0 o.o Hl\20 7.27 7.38 8.35 7. 73 7 .90 7.52 7. 91 7.75 1<20 o. 17 0.26 0. 16 0.27 0.20 0.23 0.21 0.22 r 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 CL o.o 0.0 0.0 o.o 0.0 0.0 0.0 0.0 SUM 99.96 100. 7 I 101. 05 99.50 99.93 101.112 99.65 100. 16 -o= r~ct. 0.0 0.0 0.0 o.o 0.0 0.0 0.0 o.o SUH 99.96 100. 71 101. 05 99.50 99.93 101. 112 99.65 100.16

SI 2.613 • 2.6411 • 2. 706 . 2.671 • 2.686 . 2.637 • 2.698 • 2.717 • AL 1.396 . 1. 3311 • 1.289 . 1.327 • 1. J 10 • 1. 362 • 1.276 . I .2611 • N TI 0.001 11.011 0.001 J.979 0.002 3.996 0.003 11.001 0.001 3.997 0.001 1,.000 0.001 3. 975 0.002 3.983 .i::--rr 0.0011 • 0.007 • 0.0011 • 0.0011 • 0.006 • 0.001, • 0.003 • 0.0011 • '° HN 0.001 . 0.001 • 0.001 . o.o • 0.000 • 0.000 . 0.001 . 0.001 . HG 0.0 • 0.003 • 0.007 . o.o • 0.013 • 0.005 • 0.005 . 0.008 • CA 0.0 0.996 0.0 1.0311 0.0 1.012 o.o 1.0011 0.0 1.006 0.0 1.007 0.0 1.036 0.0 1.005 RA o.o . 0.0 . 0.0 . 0.0 • 0.0 • o.o • 0.0 • 0.0 • HI\ 0.630 . o.636 • 0.712 • 0.671 • 0.682 . 0.6112 . 0.686 • 0.667 • K 0.010 0.996 0.015 1.0311 0.009 1.012 0.015 1.0011 0.011 1.006 0.013 1.007 0.012 1.036 0.012 1.005 0 8.000 . 8.000 . 8.000 • 8.000 • 11.000 • 8.000 • 11.000 • 8.000 •

I\H 35. 113 36. 311 27.86 31. 33 29.80 311. 3 7 32.02 31.53 All 63. 59 62.22 71.211 67. 12 69.05 611. ]II 66.81 67. 21 OR 0.98 1.1111 0.90 1.511 1.15 1.29 1. 17 1.26 CN o.o 0.0 0.0 0.0 0.0 0.0 0.0 0.0

f/H 1. 2 I 7 2.585 0.6611 1.217 0.1173 0.172 0.633 0.562 rtrH 0.5119 0.721 0.399 0.549 0.321 0.436 0. 388 0.360

1 33A Pl AG 5 JJ PLAG 2 331\ PLI\G 6 33 PLAG 3 331\ PLAG 7 33 PLAG 4 JJA PLAG II JJ PLAG

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SI\Ml'I f J JI\ I HOS PAR AtlAl YS£5 9 1(J II 12 13 14 15 16

SI02 611. I() 56.1111 59.09 60.30 59.26 51. 61 511.116 57. 12 110? Cl.04 0.02 0.08 0.0? O.OJ 0.06 0.05 0.05 A?.03 211.61 26.118 25. 17 24. 74 25. 71 26.35 25.116 26,115 lfO 0.,, 0.111 0.211 0.20 0.26 o. ,., 0.011 o. 13 tlNO CI.O 0.02 0.0 o. 15 0.25 0.52 0. 31 0.55 m;o CJ.2U 0.0 0.0 0.09 0.04 0.02 0.01 o.o CAO 6. 52 9.09 7.64 6.54 6.116 8. ,., 7 .29 8. 35 IIAO u.o 0.0 0.0 0.0 0.0 0.0 o.o o.o Nl\20 1. 91 6.61 7 .23 1.19 7. 64 6.95 1.64 6. 16 K?O 11.11, 0.22 0.21, 0.24 0.15 o. 16 0.16 0.18 r 0.0 0.0 0.0 0.0 0.0 0.0 0.0 o.o Cl. o.o 0.0 0.0 o.o 0.0 0.0 0.0 0.0 SUH 99.75 99.86 99. 7l 100.07 100.20 100. 37 99.86 99.59 -0° f+Cl 0.0 o.o 0.0 o.o o.o 0.0 0.0 0.0 SUH '19.75 99.86 99.73 100.07 100.20 100. 37 99.86 99.59

SI 2.686 . 2.560 . 2.650 . 2.687 • 2.643 • 2. 5811 • 2.622 • 2.5/8 • Al 1.296 . 1.426 . I. 330 • 1.299 . 1. 351 • 1.391 . 1.367 . 1. i.01 . N TI 0.001 3.963 0.001 3.966 0.003 3.983 0.001 3.987 0.001 3.995 0.002 3.977 0.002 3.990 0.002 3.986 Vl I£ 0.006 . o.ow, • 0.011 • 0.007 • 0.010 • 0.006 . 0.003 . 0.005 • 0 MN o.o . 0.001 . o.o • 0.006 • 0.009 . 0.020 . 0.012 . 0.021 • HG 0.013 . 0.0 . 0.0 . 0.006 • 0.003 • 0.001 • 0.001 • 0.0 • CA 0.0 1.030 0.0 1,031, o.o 1.020 0.0 1.0111 o.o 1.019 0.0 1.047 0.0 1.039 0.0 1.031 llA 0.0 • 0.0 • 0.0 • 0.0 • o.o • 0.0 . 0.0 • 0.0 • NA 0.691 • 0. 577 • 0.629 • 0.673 • 0.661 . 0.6011 . 0.664 . 0.591 • K 0.006 1.030 0.013 1.034 0.014 1.020 0.0111 1.0111 0.009 1.019 0.009 1.047 0.009 1.039 0.010 1.031 0 8.DOO . 8.000 • 8.000 • 8.000 • 8.000 • 6.000. • II.ODO . 8.000 •

AN 30.89 t,2.65 36. 3 7 31.26 32.88 39.88 34.22 40. 15 AB 68. 32 56. 12 62.27 67. 38 66.26 59.22 64.89 58.82 on o. 19 1. 23 1. 36 1. 37 0.86 0.90 0.89 1.03 CH o.o o.o 0.0 o.o o.o 0.0 0.0 0.0

f/H 0.1177 2.585 0.664 2. 194 7 .199 19,544 22. 105 0.562 r / r11 0.323 0.721 o. 399 0.687 0.878 0.951 0.957 0. 360

9 33 PlAG 13 RIM 10 Pl. BEGIN 14 HOTII 33A CORE II Pl 15 RIM 12 33A Pl COREflNIS 16 HOHi Pl CORE

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SAHPL[ 3lA rELDSPAR ANALYSES 11 18 19 20 21 22 23 211

SI02 59.92 60. 17 58.27 57. 78 58.118 59.25 60.119 58.01 1102 0.02 0.03 0.02 0.04 0.06 0.011 0.06 0.02 A203 211. 93 2•1. 39 25.34 26.06 25.68 25.11 I 26.20 211.61 flO o. 16 0. 18 o. 17 0. 12 o. 111 0.15 0.20 0.10 HNO o.o 0.30 0.09 0.18 0.011 o. 12 U.29 -0.05 HGO 0.10 0.06 0.011 0.04 0.0 0.06 0.12 -o.oo CAO 6.61 6.64 7. 47 8.01 7.63 7.22 8.02 6.112 DAO 0.0 o.o o.o o.o 0.0 o.o 0.0 o.o NA20 1. 61 7.78 7. 36 6.81 7. 19 7 .119 7 .92 7.05 K20 0. 15 0. 17 0.20 0.11 0.20 o. 19 0.23 0. 15 r 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 Cl. o.o o.o o.o 0.0 0.0 o.o 0.0 0.0 SUH 99.58 99. 72 98.96 99. 15 99.112 99.93 103.53 96.lll -0= r+CL 0. (I 0.0 0.0 0.0 o.o 0.0 o.o 0.0 SUH 99.58 99. 72 98.96 99. 15 99.42 99.91 103. 53 96. 311

Si 2.680 . 2.693 . 2.635 • 2.608 • 2.630 • 2.649 • 2.624 . 2.675 • Al. 1.3111 . 1.286 • 1.350 . 1.386 • 1. 361 . 1. 339 . 1. 339 . 1.339 . N Tl 0.001 3 .995 0.001 3.980 0.001 l.986 0.001 l.995 0.002 3.993 0.001 3.989 0.002 l.966 o. 0111 4.015 \J1

re 0.006 . 0.007 • 0.006 • 0.005 • 0.005 • 0.006 • 0.007 . 0.0011 • ,_. HN 0.0 • 0.011 . 0.003 • 0.007 • 0.002 • 0.005 • 0.011 • -0.002 • HG 0.007 . 0.0011 . 0.003 • 0.003 • 0.0 • 0.0011 • 0.008 • -0.000 .. CA o.o 1.0011 o.o 1.025 0.0 1.031 0.0 1.004 0.0 1.013 0.0 1.020 0.0 1.077 0.0 0.959 BA o.o . o.o • 0.0 • 0.0 • o.o • 0.0 . 0.0 • 0.0 • NA 0.665 . 0.675 . 0.6115 • 0.596 • 0.627 • 0.649 . 0.666 • 0.630 • K 0.0119 1.0011 0.010 1.025 0.012 1.031 0.006 1.004 0.011 1.013 0.011 1.020 0.013 1.077 0.009 0.959 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 •

AN 37..05 31.74 35.53 39. 14 36.54 311.38 35.112 Jl.17 AB 61.09 67 .29 63.34 60.22 62.32 611. 53 63.35 65.90 OR 0.86 0.97 1. 13 0.64 1. 14 1.09 1.23 0.93 CH 0.0 o.o o.o 0.0 0.0 o.o 0.0 0.0

r/H 0.898 11.525 3.663 4.240 7. 199 2.615 2. 360 0.562 r;rH 0.1173 0.819 0.786 0.809 0.878 o. 723 0. 702 0.360

17 RIH 21 RIH 18 NO Ill PL CORE 22 AVERAGE 19 RIH 23 AVERAGE PLUS SIGMA 20 JlA PL CORE 21, AVERAGE MINUS SIGMA

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SIIHPl.[ JJII IIHPIIIBOL[ ANIIIYS[S I 2 J .. 5 6 1 8

5102 115.08 115.112 115.08 115.08 53. Jl1 119. 76 117.29 50.118 1102 1. JO 1. 32 1. It I 1.07 0.16 0.112 0.95 1. ltl 11203 8.116 8.35 8. 79 8.32 2.00 5.50 6.90 9.36 flO 15.63 17. 12 17. 19 16.38 13.75 lit. 92 15.83 17.06 HIW 0.37 0.110 0. 39 O.ltlt 0.37 0. 35 o. 39 0.1,2 HGO 11. 51 11. 711 10.611 11.02 lit. ltJ 11.19 11. 75 13.00 CIIO 12.01 12.0lt 11.97 11.119 12.10 11. JO 11. 82 12. 13 11110 0.0 o.o o.o 0.08 0.11 o. 12 0.05 0. IO N/120 0.92 1.27 1.28 1.23 O.JO 0.511 0.92 I. J 1 1<20 0.91 0.95 0.97 0.96 0.111 1. lit O.Blt I. 17 r 0.0 o.o o.o 0. lit 0.10 0.10 0.06 0.11 CL 0.0 o.o 0.0 0.09 0.02 0.03 0.02 0.06 1120 0.0 0.0 0.0 -0.09 -0.05 -0.05 -0.03 -0.07 SUH 96. 19 98.61 97.72 96.21 96. 77 95.32 96.80 106.511 -o, r+CL 0.0 o.o 0.0 0.08 0.05 0.05 O.OJ 0.06 SUH 96. 19 98.61 97. 72 96. 13 96.72 95.27 96. 77 106.118

SI 6.823 . 6. 762 . 6. 7711 • 6.8117 • 7.797 • 7 .11811 • 7.085 • 6.873 • Al 1. 177 8.000 1. 2311 8.000 1.226 8.000 1. 153 8.000 0.203 8.000 0.516 8.000 0.915 8.000 1. 127 8.000 Ill 0. 332 • 0.2;>7 • 0. J30 • 0. 337 • 0. 1112 • 0.1159 • 0.303 • 0. 3711 • N TI 0.1116 • 0. 148 • 0.159 • o. 122 • 0.018 • 0.048 • 0. 107 • 0.1116 • f[ 1. 976 • 2. 132 . 2.160 • 2.081 • 1.681 • 1.877 • 1.963 • 1.9112 • . \Jl

N MN 0.0111 • 0.050 • 0.050 • 0.057 • 0.0116 • 0.0115 • 0.0119 • 0.0118 • MG 2. 597 5. 103 2.605 5. 162 2.383 5.082 2.1195 5.091 3. 11111 5.0JO 2.509 lt.937 2.625 5.067 2.639 5. 150 CA 1.9118 • 1.921 . 1.927 • 1.870 • 1.895 • 1.821 • 1.897 • 1.769 • NA 0.2(0 . o. 367 . 0. 373 • 0. 362 • 0.085 • o. 157 • 0.268 . o. Jl15 • I( 0. 176 . 0.180 • 0.186 . 0.186 • 0.026 • 0.219 • 0.161 • 0.203 • BA o.o 2. 393 0.0 2.1168 0.0 2.li86 0.005 2.1123 0.006 2.013 0.007 2.2011 0.003 2. 330 0.006 2. 322 CL o.o . o.o . o.o . 0.023 • 0.005 • 0.008 • 0.006 • O.OIJ • r o.o . 0.0 • 0.0 . 0.067 • 0.0116 • 0.0118 • 0.027 • 0.0119 • II o.o 0.0 0.0 o.o o.o o.o -0.090 o.o -0.051 0.0 -0.055 0.0 -0.033 0.0 -0.062 0.0 0 23. 000 • 23.000 • 23.000 • 23. 000 • 23. 000 • 23.000 • 23.000 • 23.000 •

Cl\/\ 29.611 28.63 29.56 28. 76 28.01 29. 13 28.911 27 .65 ANT 39.52 311.811 36.55 38. J7 116.117 110. 13 110.05 ltl .211 GRU 30.83 32.53 Jl.89 32.117 25.52 30. 711 31.01 31. 11

F/M 0. 780 0.838 0.927 0.857 0.5119 0. 766 o. 1111 0.7511 F/FH 0.1138 0.1156 0.1181 0.1161 o. 355 0,11311 0.1136 0.1,30

I J)II 118 fROH 118-BT INTERGRO\IIH 5 NOTltCR AMP 2 33 IIHPII 6 JJ AMP J 33 IIHPII 7 AVERAGE It 3 3 ANE\10 8 AVERAGE PLUS SIGMA

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SM1rl£ llA 9

5102 ,.,,. 11 I 102 o.i,1 A203 ,,. •15 1£0 11,. 61 HNO 0. 36 HGO IO. 51 CAO II. 51 RAO -0.00 NA20 0. 511 k20 0.52 r -o.oo Cl. -0.01 1120 0.00 SUH 87 .06 -o, F+CL -o.oo SUH 61.01

SI 7. 3,,,. . AL 0.656 8.000 Al. 0.217 • TI 0.058 • re 2.03" • HN 0.050 . HG 2.608 ,,. 967 CA 2.053 • NA 0. 115 • I( 0.111 . BA -0.000 2. 339 CL -0.002 • r -0.001 • II 0.003 o.o 0 23. 000 •

CAA 30 ..... MIT 38.66 GRU 30.90

r/H o. 799 r/lH 0 .......

9 AVERAGE MINUS SIGMA

AHPIIIBOU ANALYSES

N Vl w

Page 259: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHPL[ 35 BIOTIT[ ANALYSES 1 2 3 4 5

5102 37. 61 36. 76 37.29 37.81 36.78 r 102 I, 93 1.88 1.90 1. 93 1.88 A203 17. ~·· 17. 51, 17. 51, 17.54 17 ,51, 110 16.67 17.46 17. 16 17.46 16.87 MNO o. 10 o." o." o." o. 10 MGO 11.99 11.96 11. 9 7 11.99 11.96 CAO 0.06 0.06 0.06 0.06 0.06 IIAO 0.0 0.0 0.0 0.0 o.o NA20 O.Ul 0.06 0.04 0.06 0.03 k20 8.57 6.27 8.42 6.57 8.27 r 0.0 0.0 0.0 o.o 0.0 CL o.u u.u 0.0 o.o o.o 1120 o.o 0.0 o.o 0.0 o.o SUM 94.90 91l. 12 94.51 95.53 93.119 ·O= r+CL 0.0 0.0 0.0 0.0 o.o SOM 911. 90 911. 12 911 .51 95.53 93.IJ9

SI 5.652 . 5.566 . 5.610 . 5.632 . 5.566 • N Al. 2. 3118 6.000 2.1,32 8.000 2. 390 8.000 2. 368 8.000 2.1112 8.000 V1 Al. 0. 11,2 . 0.697 • 0. 720 • o. 711 • 0.729 • .i,-Tl 0. 217 • 0.2111 . 0.216 • 0.216 • 0.215 . r[ 2. 109 • 2.210 . 2. 159 • 2. 175 • 2. 11flf • MN ll. 013 • O.Ollf • 0.013 • O.Ollf • 0.013 • HG 2.672 5.7!;3 2.699 5.634 2.665 5.793 2.662 5. 776 2.709 5.609 CA 0.010 . 0.010 • 0.010 • 0.010 • 0.010 • IIA 0.009 • 0.016 • 0.013 • 0.017 • 0.009 • k I. 634 • I. 597 . 1.616 . 1.628 • 1.603 • BA 0.0 1.652 o.o 1.624 0.0 1.636 o.o 1.655 0.0 1. 621 CL 0.0 • o.o • o.o • 0.0 • o.o • r 0.0 • 0.0 • 0.0 • o.o • 0.0 • II 0.0 0.0 o.o 0.0 0.0 0.0 0.0 o.o 0.0 0.0 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 •

r/M 0. 794 0.624 0.609 0.622 o. 796 F/FM O.lflf3 0.452 0.41J7 0.451 0.443

I J5C OT If AVERAGE PLUS SIGMA 2 35C BT 5 AVERAGE MINUS SIGMA 3 AVfRAGC

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MHPl[ 35 r[LOSPAR ANALYS[S I 2 3 II 5 6 7 8

5102 69.6'> 69.68 68.511 66.03 67.96 68. 37 69.12 67 .03 1102 0.0 0.05 0.011 0.05 0.03 0.03 0.05 0.02 A20] 18. 78 19.06 18.67 20.00 20.95 19.119 20. 36 18.63 1[0 o. 16 0.09 0.22 0. 39 0.22 0.22 0. 32 0.12 HNO 0.02 0.01 0.01 0.0 0.0 0.01 0.02 0.00 HGO o.o 0.0 o.o 0.05 0.0 0.01 0.03 -0.01 CAO o. 10 0.29 0.27 0.39 o. :!'O 0.25 0.35 0. 15 (1110 0.0 o.o 0.0 0.0 0.0 o.o o.o 0.0 N/120 10. 78 11.03 11.02 11. 72 11. 511 11.22 11. 57 10.87 k20 0.06 0.07 0.06 0.12 0.07 0.08 0.10 0.05 r 0.0 o.o 0.0 o.o o.o 0 .. 0 o.o 0.0 Cl. 0.0 0.0 0.0 0.0 o.o o.o o.o 0.0 SUH 99.55 100.28 98.83 98.75 100.97 99.68 102.50 96.85 -0= r+CL 0.0 0.0 0.0 o.o 0.0 o.o 0.0 0.0 SUH 99.55 100.28 98.8] 98.75 100.97 99.68 102.50 96.85

SI 3.0111 • 3.025 • 3.023 • 2.939 • 2.9115 • 2.995 • 2.915 • 3.015 • Al 0.966 • 0.975 • 0.970 . 1.0119 • 1.070 • 1.006 • 1.0211 . 0.987 • II 0.0 11.007 0.002 11.002 0.001 3.995 0.002 3.989 0.001 11.015 0.001 11.002 0.002 11.000 0.001 11.003 N f[ 0.006 • 0.003 . 0.008 • 0.015 • 0.008 • 0.008 . 0.011 . 0.0011 • \Jl MN 0.001 • 0.000 • 0.000 • 0.0 . 0.0 • 0.000 . 0.001 . 0.000 • \Jl HG 0.0 . o.o . o.o • 0;003 • 0.0 • 0.001 . 0.002 . -0.001 . CA 0.0 0.927 o.o 0.9119 0.0 0.967 0.0 1.055 0.0 0.991 0.0 0.911 0.0 0.992 0.0 0.962 BA 0.0 • 0.0 • o.o • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • NA 0.912 • 0.928 • 0.9112 • 1.011 • 0.969 • 0.953 • 0.957 • 0.9118 • K 0.003 0.927 0.001\ 0.9119 0.003 0.967 0.007 1.055 0.0011 0.991 0.0011 0.911 0.005 0.992 0.003 0.962 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 . 8.000 • 8.000 .

AN 0.51 1.113 1. 33 1. 79 0.911 1.21 1.62 o. 77 AB 99. 13 98. 16 98. 32 97.55 98.66 98. 35 91. 83 98.91 OR o. 36 0.111 o. 35 0.66 0.39 0.1111 0.55 o. 32 CN o.o o.o 0.0 0.0 0.0 0.0 0.0 o.o f/H o.o o.o 0.0 11.376 0.0 12.571\ 6. 191 o.o f/lH 0.0 0.0 o.o 0.8111 0.0 0.926 0.861 0.0

I ALBll[START 5 ALBIH 2 Al.BITE 6 AVERAGE 3 Al.RITE 1 AV[RAGE PLUS SIGHA II ALRI H 8 AVERAGE MINUS SIGMA

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S/\Hrl £ 15 CIILORITE ANALYSES 1 2 3 4 5

SIO? 12.02 26.0/ JO. 115 32.62 26.07 I 10~ 11.11, 0.09 0. I 3 o. 16 0.09 /\?OJ 21. 10 21.66 21. 36 21.66 21. 10 fl I) ?0.116 21.2J 20.65 21. 23 20.46 HIIO 0. IR 0. 15 0.16 o. 16 o. 15 MC,Cl 13.02 15,115 14.23 15.45 13.02 C:/\Cl Cl.36 0.60 0.49 0.60 0.38 11/\0 n.o 0.0 0.0 0.0 0.0 Pl/\?O ll.0/ 0.02 0.04 0.01 0.02 ~20 I . 111 0.04 0.59 1. 14 0.04

' 0.0 0.0 0.0 0.0 0.0 Cl 0.0 0.0 0.0 0.0 o.o 11:>0 1?.01 11.65 11. 66 12.54 11.18 SUH 101.1,0 98.96 100. 16 105.85 94.51 -o·.· r +CL 0.0 0.0 0.0 o.o o.o SUH 101.110 98.96 100. 16 105.65 911,51

SI 3. 257 . ?.866 • 3.075 • 3,135 • 3.007 • N /\l. o. 11,3 1, .0110 I. 1111 11.000 0.925 4.000 0.865 4.000 0.993 4.000 \Jl Al I. 725 . I. 510 • 1.619 • 1. 573 • 1.671 • 0-, I I 0.012 . 0.007 . 0.009 • 0.011 • 0.007 . re 1.696 • I .62~ • 1,761 • 1.696 • 1.1133 . ~,,. 0.015 • 0.013 • 0.014 • 0.015 • 0.014 • HG 1.926 . 2. 366 . 2. 143 . 2.200 . 2.079 • CA o.o 5.574 o.o 5.796 0.0 5.664 0.0 5,709 o.o 5.657 ll/\ O.OIJ . 0.004 • 0.009 • 0.013 • 0.004 . K o, 141, • 0.005 • 0.076 • 0. 139 • 0.005 • 0/\ 0.0 5.574 0.0 5.796 0.0 5.68li 0.0 5,709 o.o 5,657 Cl 0.0 • 0.0 . o.o • 0.0 • 0.0 • r 0.0 • 0.0 • o.o • o.o • 0.0 • II 6.000 8.000 8.000 6.-000 8.000 8.000 8.000 8.000 8.000 8.000 0 16.000 • 16.000 • 18.000 • 111.000 • 18.000 •

f/H 0.890 0. 776 0.626 0. 778 0.886 1/FH o. 471 0.1,37 O.li53 0.437 O.li70

I CltLORIIE SIART lj AVERAGE PLUS SIGMA ? CIILORII[ 5 AVERAGE MINUS SIGHII 3 AVERAGE

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SAHPL[ Jl f[LUSPAR ANALYS[S I 2 3 .. 5 6 1 8

S102 6 7. 55 67. 70 66.98 67. 79 67. 10 69.92 68.89 69.61 1102 0.01 0.02 0.01 0.0 0.02 0.03 0.02 0.02 A203 19.21 19.55 19.611 19.65 19.22 18.50 19.80 :w. 14 lfO 0.57 0.23 0.20 0. 14 0.16 0.19 0.25 0. 30 HNO 0.0 o.u 0.0 0.011 0.01 o.o 0.0 0.01 HGO 0.0 o.o 0.05 a.or, 0.0 o.o 0.11 0.04 CAO U.25 0.18 0.46 0. 311 0.10 0.23 o. 13 o. 35 DAO o.o 0.0 0.0 0.0 o.o o.o 0.0 0.0 NA20 11.28 11.16 11. 34 11.48 11.44 10.90 11.28 11.26 1<20 0.06 0.08 0.07 0.05 0.05 0.10 0.06 0.11 r 0.0 0.0 0.0 o.o 0.0 o.o o.o 0.0 Cl 0.0 0.0 0.0 0.0 0.0 o.o 0.0 o.o SIJH 98.99 98.92 98.75 99.53 98. 10 99.87 100.43 101.84 -0- f•CL 0.0 0.0 0.0 0.0 0.0 o.o 0.0 o.o SUH 98.99 98.92 98.75 99.53 98. 10 99.87 100.43 101.84

SI 2.987 . 2.988 • 2.969 • 2.919 • 2.989 • 3.046 . 2.993 . 2.985 • Al. 1.001, . 1.017 • 1.026 . 1.01/ . 1.009 • 0.950 • 1.014 . 1.018 • I I 0.000 3.992 0.001 4.006 0.000 3.995 o.o 3.996 0.001 3.999 0.001 3.997 0.001 4.007 0.001 4.004 F[ 0.021 . 0.008 • 0.007 • 0.005 • 0.006 • 0.007 • 0.009 • 0.011 • HN 0.0 . 0.0 • 0.0 . 0.001 • 0.000 • o.o . 0.0 . 0.000 • HG 0.0 . o.o . 0.003 • 0.0113 • o.o • 0.0 • o.o . 0.003 • CA 0.012 . 0.009 . 0.022 . 0.016 . 0.005 • 0.011 • 0.006 . 0.016 . N BA 0.0 . o.o . o.o • o.o • o.o • 0.0 • 0.0 • 0.0 • U1 NA 0.967 • 0.955 . 0.975 • 0.978 . 0.988 • 0.921 . 0.950 • 0.936 . -..J K 0.003 1.003 (I.OW> 0. 911 0.11011 I. 011 0.003 1.006 0.003 1.002 0.006 0.9111j 0.003 0.969 0.006 0.972 0 8.000 . 11.000 . 8.000 • 8.0011 . 8.000 . 8.000 . 8.000 . 8.000 •

AN I ?I 0.1111 2.18 1.61 0.48 1. 15 o.63 1.68 All 911.115 98.66 97 ... 2 98. 11 99.24 98.26 99.02 91.69 on fl. 31, 0.117 0.110 0.28 0.29 0.59 0.35 0.63 CN o.o 0.0 o.o o.o 0.0 0.0 o.o o.o

UH II.fl 0.0 2.21111 2.532 o.o 0.0 0.0 ,,. 350 r/fH 0.0 0,0 0.692 o. 717 0.0 o.o 0.0 0.813

I IIUH 3 7 Al BI I [ 5 37 AB 2 flUH ] 7 All 6 PLAG 3 37 All 7 PL BEGIN 4 3 7 AB 8 PL

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SIIHrl[ 31 fELOSPAR ANALYSES 9 10 11

SI02 66. 19 69.25 67. 13 1102 0.02 0.02 0.01 11203 19.117 19.93 19.01 f ( 0 0,25 0. 38 0. 13 HIIO 0.01 0.02 -0.01 MGU 0.02 0.011 -o.oo CIIO 11.25 0. 37 n. 111 11110 o.o o.n 0.0 111120 I 1. ;>/ 11 . 1,1, 11. 10 K?O 0.01 0.09 0.05 r o.o 0.0 o.o Cl o.o 0.0 0.0 SUH 99.55 101. 511 97.56 -o, f+CL 0.0 0.0 0.0 SUH 99.55 101. 511 91 .56

SI 2.992 . 2.983 . 3.001 • Ill 1. 001 • 1.012 • 1.002 • Tl 0.1101 3.999 0.001 3.996 0.000 11.003 rr 0.009 • 0.0111 • 0.005 . MIi 0.000 . 0.001 • -0.000 • HG 0.001 . 0.002 • -0.000 • N Cl\ 0.012 . 0.017 * 0.007 • U1 1111 o.o . 0.0 * 0.0 • 00 IIA 0.959 . 0.955 . 0.962 • K 0.001, 0.985 0.005 0.9911 0.003 0.976 0 6.000 . 8.000 • 6.000 •

AN 1.23 1. 711 0.69 AB 96.35 97. 73 99.00 OR o.~2 0.53 0.30 CN o.o o.o 0.0

f/H 9.067 6.055 2.21111 f/fH 0.901 0.858 0.692

9 IIV[RIIGE 11 AVCRAGC HINUS SIGMA 10 AVERAGE PLUS SIGMA

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SAHrt.[ J7 CIILOR I TC ANAL VS[ S I ;, J 11 5 6 1 II

5102 30.33 28.05 27.13 32.Jl 3J.98 27. 39 31.54 30. 19 r 102 O. II 0.11 0.11 0.08 0.07 0.0•1 0.08 0.09 11203 20.111 20. 19 21.63 21. 11 26.58 23. 75 21. 28 22.?4 HO 19.1,0 21. 32 21.11) 20.22 15.27 21.69 19.89 19.89 HIIO o. 12 o. 13 0.111 0.07 0.12 0.08 0.09 0. 11 HGO 111.26 16. 13 15.03 14.211 11.95 15. 311 12.69 111.23 CIIO 0.21 0.26 o. 16 0.12 0.37 0.26 0.25 0.211 llAO 0.0 0.0 0.0 0.13 0.21 IJ.22 0.2] 0.11 N/120 0.93 O.OJ 0.06 0.0 0.0 0.0 0.01 0.15 K20 0. 30 0.03 0.08 0.08 1 • 111 o. 13 o. 15 0.27 r 0.0 0.0 0.0 o.o 0.0 0.0 (). 0 0.0 CL 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0 11;,o 11.64 11.119 11. 52 12.12 12.58 11.84 11. 72 11. 811 SUH 97. 83 97.711 97.89 101. 14 102.27 100. 711 97. 93 99. 36 -0= r+Cl 0.0 0.0 o.o 0.0 0.0 0.0 0.0 0.0 SUH 97.83 91. 111 97.89 10 I. 14 102.27 100. 74 91.93 99. 36

SI J. 1;,3 . 2.925 . 2.0811 • 3. 19J • 3.231 • 2.712 • 3.225 • J.054 • Ill 0.8"11 4.000 1. 015 11.000 1.116 11.000 0.807 4.000 0.763 11.000 1.228 11. 000 0. 775 11.000 0.9•16 4.000 Al 1.606 • 1.1105 • 1. 536 • 1.728 • 2.221 • 1.604 . I. 789 • 1. 705 . 11 0.009 . 0.009 • 0.009 • 0.006 • 0.005 • O.OOJ . 0.006 . 0.007 • re 1.670 . 1.859 • 1.8611 • 1. 671 • 1.217 • 1. 835 • I. 701 • 1.683 • HN 0.010 • 0.011 • 0.012 . 0.006 . 0.010 • 0.007 • 0.008 • 0.009 . N HG 2. 188 . 2. 501 • 2. J30 . 2.098 • 1. 697 • 2. J 14 . 1. 9 311 . 2. 1116 • V, CA O.OJO • 0.029 . 0.018 • 0.013 • O.OJ8 • 0.028 • 0.021 . 0.026 • '° NII 0. 186 • 0.006 . 0.012 . O.ll . 0.0 • 0.0 . 0.002 . 0.029 . K O. lll9 . 0.004 • 0.011 • 0.010 . 0. 139 • 0.017 . 0.020 • 0.015 • n11 0.0 5. 738 0.0 5.830 0.0 5.791 0.005 5.537 0.008 5. 333 0.009 5.816 0.009 5.1196 0.0011 5.61111 CL 0.0 • 0.0 • o.o . o.o . 0.0 • o.o . 0.0 • 0.0 . r 0.0 • 0.0 • 0.0 • 0.0 • o.o • 0.0 • 0.0 • o.o • II 6.001) 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 8.000 0 16.000 . 16.000 . 18.000 • 18.000 • 18.000 • 18.000 • 18.000 • 18.000 •

1/H 0. 768 0. 7116 0.805 0.799 o. 723 o. 796 0.883 o. 788 F/FH 0.1134 0.1121 0.4116 0.4411 0.1120 0.11113 0."69 0.11111

1 JT ClllOIII I[ 5 Cltl 2 31 CIILORIT[ 6 CIIL l CIII. BF.GIN 7 Cltl 4 NEW CIIL 8 AVERAGE

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51\HPlE 37 CIILOR I TE ANALYSES 9 10

S102 32.56 27 .82 J 102 0.11 0.06 11203 211.11 lO. 17 rro 21.911 17.84 MIIO 0. ll 0.08 HGO l~.60 12.87 CAO 0. 32 0. 17 RAO 0.22 0.01 NA20 0.111 -o. 17 k20 0.64 -0.09 r u.o o.o Cl 0.0 o.o 117.0 12.95 10. 711 SUH 109.22 89.51 -Oc f+CL o.o o.o SUH 109.22 89.51

SI 3.013 . J. 103 . AL 0.987 11.000 0.897 11.000 AL 1.665 . I. 7511 . l I 0.008 . 0.005 • re 1.698 . I. 6611 • HN 0.010 • 0.008 • HG 2. 152 . 2. 139 • r.11 0.031 . 0.020 . PIA 0.0811 • -0.037 . k 0.075 . -0.013 • OIi 0.008 5. 731 0.000 5.5110 Cl. 0.0 • 0.0 • I 0.0 . 0.0 • II 8.000 8.000 8.000 8.000 0 18.000 . 18.000 .

f/H 0. 794 o. 781 f/FH 0.11111 0.439

9 AVERAGE PLUS SIGMA 10 AVERAGE HINUS SIGMA

N

°' 0

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5AHPL[ II- ~PHIBOL[ ANALYS[S 1 2 J II s 6 7 8 5102 51. 93 II&, 117 52.92 S2.0II 119.0J 50.88 52.66 119. 10 TI02 0. 211 0. 117 0.10 0.20 0.22 0.25 o. 37 o. 12 A20J J. 50 5.82 2.81 2.58 11.96 J.93 5. 19 2.68 HO 18. 82 17. JI 16.22 IS.el 19.59 17.55 19.01 16. 10 HNO 0. 56 0.35 o. Ill 0.60 0.110 0.117 0.56 0.37 HCO 10.97 10.51 12. l" 12, 10 9.53 11, 09 12. 1 J 10.05 CAO 12.es 12.60 12. 76 12.89 12. 51 12. 72 12.87 12.58 BAO o.o 0.0 o.o 0.0 0.0 0.0 0.0 o.o NA20 0.22 0.50 0.26 0.17 o. 37 0. JO 0.112 0. 19 K20 o. 2 .. 0.52 0.12 0.11 0.31 0. 26 0.111 o. 11 r 0.0 o.o 0.0 o.o 0.0 0.0 o.o o.o CL o.o 0.0 o.o 0.0 0.0 o.o o.o o.o H20 0.0 0.0 0.0 o.o 0.0 o.o o.o o.o SUH 99. JJ 96.55 97. 96 96.52 96.92 97.116 103.61 91. JO •O• r•CL o.o 0.0 0.0 o.o 0.0 o.o o.o 0.0 SUH 99. lJ 96.55 97.96 96.52 96.92 97.116 103.61 91. JO

SI 7.602 . 7. JOI . 7. 719 . 7.7311 • 7 .1117 . 7.560 • 7.387 • 7.755 . AL 0.398 8.000 0.699 e.ooo 0.261 8.000 0.266 8.000 0.583 8.000 0.11 .. 0 8.000 0,613 8.000 0.2 .. 5 8.000 AL o. 206 . 0. Jl4 . 0.223 • 0, 185 • 0. 301 . 0. 2 .. 9 • 0.2115 . 0.25" . TI 0.026 . 0.051 . 0.011 . 0.022 • 0.025 . 0.027 . 0.039 • 0.015 . re 2. JOii . 2. 181 . 1, 98 .. • 1.967 • 2.1178 . 2. 181 • 2.230 • 2,127 . HN 0.069 . 0.0115 . 0.053 . 0.076 • 0.051 . 0.059 • 0.067 . 0.050 . HG 2. 39 .. 5,000 2.360 11.972 2.690 ... 961 2.680 11,931 2.1119 5,0011 2.456 4.973 2,536 5. 116 2.367 4.812 N CA 2.016 • 2. Oll . 1.999 . 2,052 • 2.028 . 2.025 • 1. 934 . 2,128 . "' l(A 0.062 ·• o. 1116 . 0.074 . 0,049 . 0. 109 . o.oee . o. 115 . 0.057 . ..... K 0.045 • 0. 100 . 0.022 . 0.021 • 0.060 . 0.0 .. 9 . 0.073 • 0.022 . BA 0.0 2. 12J 0.0 2.279 0.0 2.095 0.0 2.122 o.o 2. 196 o.o 2. 162 0.0 2. 122 o.o 2.208 CL 0.0 . 0.0 . 0.0 . o.o . o.o . 0.0 . 0.0 • 0.0 . r 0.0 . 0.0 . o.o • 0.0 . o.o . o.o . o.o . o.o . H o.o 0.0 0.0 0.0 0.0 o.o o.o 0.0 o.o o.o o.o 0.0 o.o 0.0 0.0 0.0 0 23. 000 • 23. 000 . 2 l. 000 • 23. 000 • 23.000 . 23.000 • 23 .000 . 23 .000 . CM 29. 72 30. 72 29. 72 J0.29 30.211 JO. 1 J 28.58 J 1.90 ANT 35.29 35.65 39.99 39.56 32.0" 36.511 37 .117 35. 118 CRU J ... 99 JJ.62 J0.28 30.15 37.72 JJ. 3J JJ.95 32.62

f/H 0.992 0.9 .. 3 0.757 0.762 1. 177 0,912 0,906 0.920 r;rH 0.1198 0,1185 o. 1131 o.,,JJ o. 5111 0,1177 O.IIH 0. 1179 1 114 AHPH s A 2 A 6 AV[RAC( J A 7 AV[RAC[ PLUS SICHA II A e AV[RAC[ HINUS SICHA

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SAHPL( 44 ,vROX[N( ANALYS(S 1 2 3 4 5 6 7 8 SIOZ 51.95 51. 12 52. 13 52, 10 52.53 52.61 52.50 51. 85 Tl02 0.10 o. 15 0.03 0.111 0.08 0.09 0.08 0.15 A203 0.65 0.118 0.58 0.92 0.05 0.28 o. 7J 0.118 rco 12.89 12.112 11. 88 12.56 12.39 11, 78 12.89 13. 20 HNO o. 70 0.61 0.66 0.61 0.66 0.60 0.55 0.55 HCO 10.20 10.67 10.57 9,116 9. 30 9. 118 9.511 9.65 CAO 2l.96 23.70 211. 21 23. 75 23.89 211.08 22.29 2l.03 BAO 0.0 0.0 o.o o.o o.o o.o 0.0 o.o NA20 o. 13 o. 111 o. 15 0.20 0.05 0.13 0.07 o. 18 K20 0.02 0.02 0.02 0.02 0.02 0.02 0.05 0.03 F 0.0 0.0 0.0 o.o 0.0 0.0 o.o 0.0 CL o.o 0.0 o.o o.o o.o 0.0 0.0 o.o SUH 100.60 99.31 100.23 99.76 98.97 99.07 98. 70 99. 12 •O= F+CL 0.0 0.0 o.o o.o 0.0 o.o o.o o.o SUH 100.60 99.31 100.23 99.76 98.97 99.07 98.70 99.12

51 1,978 . 1,970 . 1.9811 . 1.993 . 2.0211 . 2.020 • 2.021 . 2.000 • AL 0.022 2.000 0.022 1.992 0.016 2.000 0.007 2.000 0.0 2.0211 o.o 2.020 0.0 2.021 0.0 2.000 AL 0.007 • 0.0 . 0.010 • 0.035 • 0.002 . 0,013 . 0.033 . 0.022 . TI 0.003 . 0.004 . 0.001 . 0.0011 . 0.002 • 0.003 . 0.002 • 0.004 • FC 0.1110 • 0.400 . o. 378 . 0.402 . 0.399 • 0. 378 . 0.415 • 0,426 • MN 0.023 . 0.020 . 0.021 . 0.020 . 0.022 • 0.020 . 0.018 • 0.018 • HC 0.579 1.022 0.613 1.038 0.600 1.009 0.540 1.000 0.534 0.960 0.5112 0,956 0.5117 1.016 0,555 1,025 N CA 0.977 . 0.979 . 0.987 • 0,9711 • 0.986 . 0.991 • 0.919 . 0,952 • "' BA o.o • o.o . 0.0 • o.o • o.o . o.o • o.o • o.o . N NA 0.010 . 0.010 . 0.011 • 0.015 . 0.004 . 0.010 . 0.005 • 0.013 . K 0.001 0.988 0.001 0.990 0.001 0.999 0.001 0.989 0.001 0.991 0.001 1.001 0.002 0.927 0.001 0.967 0 6.000 . 6.000 . 6.000 • 6.000 • 6.000 . 6.000 . 6.000 . 6.000 .

WO 119. 13 118.65 49.70 50.32 50.81 51. 30 118,110 48.80 (N 29. 10 30.47 30. 19 27.88 27. 52 28. 10 28.82 28,115 FS 21. 77 20.89 20. 11 21. 79 21.68 20.60 22.79 22. 75 f/14 0.748 0.686 0.666 0.782 0.788 0.733 0.791 0.800 F/FH o. 1128 0.1107 o. 400 0,1139 0. 1141 0.423 0.442 0.1144

1 44 SCAN PX 5 PX 2 44 SCAN PX 6 PX l 44 PX 7 PX 4 PXB[CIN 8 PX

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S~PLC 44 PVROX[HC AHALYSCS 9 10 11 12 11 S102 52.01 52.74 52. 15 52.61 51.70 1102 0. 10 0.07 0.10 o. 14 0.06 A20l o. 71 0.62 0.55 0.79 0.12 rco 12.90 11.84 12.47 12.96 11.99 HNO 0.57 0.52 0.60 0.66 0.55 HCO 10.56 11.54 10. 10 10.79 9.40 CAO 21. 71 23. 44 21.41 24. 19 22.61 OAO 0.0 0.0 o.o o.o 0.0 NA20 0.1J 0.10 0. 11 0.17 0.08 ~20 0.05 O.Ol O.Ol 0.04 0.02 r 0.0 o.o o.o 0.0 o.o CL 0.0 0.0 0.0 0.0 0.0 SUH 98.78 100.90 99.54 102,ll 96.76

•O= f•CL o.o 0.0 0.0 o.o 0.0 SUH 98.78 100.90 99.54 102.31 96.76 SI 2.002 . 1. 985 . 1 .998 . 1 .968 . 2.029 • AL 0.0 2.002 0.015 2.000 0.002 2.000 0.032 2,000 o.o 2.029 "L O.OlJ . 0.012 • 0.021 . 0.003 • 0.015 • II 0.001 . 0.002 . 0.001 . 0.004 • 0.002 . re 0.415 . 0. 371 . 0.400 . 0.405 • 0.194 . MH 0.019 . 0.017 . 0.020 . 0.021 . 0.018 • N HC 0.606 1. 075 0.647 1.050 0.576 1 .021 0.602 1.034 0.550 0.978 0\ c ... 0.896 . 0.945 . 0.961 . 0.969 • 0.951 . w 8,. 0.0 . 0.0 . o.o . o.o • o.o . "" 0.010 . 0.007 . 0.010 • 0.012 • 0.006 • K 0.002 0.908 0.001 0.954 0.001 0.971 0.002 0,984 0.001 0,959 0 6.000 . 6.000 . 6.000 • 6.000 • 6.000 • WO 46.29 47 .69 49.11 48.54 49.71

[H 11.30 32.67 29.47 30.12 28.75 rs 22.41 19.64 21.41 21. 14 21.52 f/H o. 716 0.601 o. 727 o. 708 0.749 f / f H 0. 417 o. 375 o. 421 0.415 0.428

9 ,x 12 AVCRACC PLUS SICHA 10 PX 11 AV[RAC( HIHUS SIGMA 11 AVCRACC

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SJV<PL( 44 (CLDSPAR AHALVS[S 1 2 3 .. 5 6 7 8 S 102 6J. 32 64.80 65.65 64.40 65. 10 64.55 65. 14 65.30 I 102 0.07 0.04 0.05 0.06 0.05 0.06 0.02 o.oa A20) 1 7. 38 18. 14 17.90 111. 15 18. 10 18.50 18. 14 18.1'7 f[O 0.06 o. 16 o. 15 0.08 0.10 0.07 o. 12 0.25 "4k0 O.Ol 0.02 0.03 0.01 0.0 0.02 0.04 0.03 "1C,O 0. 40 o.o 0.0 o.o o.o 0.01 0.0 0.0 C""1 0.07 o. 10 0.04 0.09 o. 16 0.09 0.05 0.06 OAO 0.0 o.o o.o o.o 0.0 o.o· o.o 0.0 HAiO 0. 48 o. 46 o. )9 0.80 1.94 0. JO 0.40 0. 38 •20 15.52 15.57 15.75 15.00 1J. 77 15.85 15.96 15,94 r 0.0 0.0 o.o o.o 0.0 o.o 0.0 0.0 CL o.o 0.0 0.0 0.0 0.0 o.o 0.0 o.o SUM 97.ll 99.29 99.99 95.59 99.22 99.45 99.87 100.51 -o::r r•cL 0.0 0.0 o.o o.o 0.0 o.o 0.0 0.0 SUH 97. ll 99.29 99.99 98.59 99.22 99.45 99.57 100.51

SI J.005 . l.007 . 3.024 . 3.004 . J,007 • 2.994 • J,010 • 2.999 . AL 0.972 . o. 992 . 0.972 . 0.995 . 0.985 . 1.011 • 0,985 . 0.999 . II 0.002 l. 979 0.001 4.001 0.002 3.995 0.002 4,004 0.002 3.994 0.002 4.007 0.001 3.998 0.003 4.001 f( 0.002 . 0.006 . 0.006 . 0.003 . 0.004 • 0.003 • 0.005 • 0.010 • H~ 0.001 . 0.001 . 0.001 . 0.000 . o.o . 0.001 . 0,002 . 0.001 • MG 0.025 . 0.0 . o.o • 0.0 • o.o • 0.001 . o.o . o.o • CA 0. 001, . 0.005 . 0.002 . 0.004 . o.ooa • 0.004 . 0.002 . 0.003 • N OA o.o . o.o . 0.0 . 0.0 . o.o . 0.0 • o.o . o.o • CJ' kA 0.0111, . 0.041 . 0.035 . 0.072 . o. 174 • 0.027 . 0.036 . 0.034 • +' • 0.939 1,019 0. 922 0.975 0.927 0.971 0.892 0.973 0.811 0.991 0.935 0.973 0.941 0.955 0.934 0.951 0 a.ooo . 8.000 . 5.000 . a.ooo . a.ooo • 8.000 . 8.000 . a.ooo • AN 0. 36 0.51 0.20 o. 46 o.ao 0.46 0.25 0.30 AB 4. 47 4.25 3.61 7. 46 17.50 2.78 3.66 3.49 OR 95. 17 95.21 96. 18 92.07 51.70 96.75 96.09 96.21 CN o.o o.o o.o o.o o.o o.o o.o o.o

f/M 0. 127 0.0 o.o o.o o.o 5'.064 o.o 0.0 f/fH o. 113 o.o o.o o.o o.o 0.835 o.o o.o 1 44 kSPAR 'kS 2 •SB(GIN 6 KS l •s 7 1(8 4 •s • kl

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s,u,nc 44 FCLDSPAR AHALYSCS 9 10 11 12

S102 64.95 611.110 6S.4l 64.17 1102 0.04 o.os 0.07 0.04 A20J 111. J6 18. 1J 18.45 17.111 rco 0.06 o. 12 o. 18 0.06 HNO 0.01 0.02 O.OJ 0.01 HGO 0.0 o.os o. 17 -0.08 CAO 0.08 o.oa 0.12 0.05 BAO 0.0 o.o o.o 0,0 NA20 0.47 0.62 I. II o. 14 •20 15.80 15.47 16. 1J 14.110 r 0.0 o.o 0.0 0.0 Cl 0.0 o.o o.o 0.0 SIIH 99. 77 99.J4 IOI, 611 96.99 ·O= r•CL 0.0 0.0 o.o o.o SUH 99. 77 99.34 101.68 96.99

SI l.002 . l.006 . 2.98) . 3.029 . AL 1.000 . 0.991 • 0.991 • 0.991 • 11 0.001 4.003 0.002 l.998 0.002 l.976 0.001 4.021 re 0.002 . 0.005 • 0.001 . 0.002 • >4N 0.000 . 0.001 • 0.001 . 0.000 . HC 0.0 • 0.00] . 0.012 • -0.006 • N CA 0.004 . 0.004 • 0.006 . 0.002 • 0\ BA 0.0 . 0.0 . o.o • o.o • V, HA 0.042 . 0.056 • 0,0911 . 0.01] • K 0.931 0.9&0 0.915 0.984 0.9311 1.061 0.892 0.904 0 8.000 . 11.000 • 11.000 . 11.000 .

AH 0,41 o. 42 o. 54 0.27 AB 4. 31 s. 76 9.40 I. 42 OR 95.29 91.112 90.0S 98.30 CH o.o 0.0 0.0 0.0 r /H 0. 127 1.700 0.686 0.0 r/rH o. 113 0.630 0,401 o.o

9 KS II AVCRAC[ PLUS SIOMA 10 AV[RAC[ 12 AVCRAG[ HINUI SIOMA

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S•HPL[ 44 rCLOSPAR AHALY5[1 1 2 ) II ' 6 7 8 s,02 65. l7 58.1111 56.82 46.6, '7 .04 50.115 54. 9) 511.89 1102 0.02 0.0) 0.0) 0.011 0.01 0.02 0.0) 0.08 A20) 19. 81 26.65 25. 55 )1. 40 27.25 ) 1. 81 27.50 29.45 rro o. 16 o. 16 o. 211 0.29 0.21 0.2) 0.06 0.22 MWO 0.02 0.04 o.o 0.02 0.02 0.011 0.05 0.05 MGO o.o 0.0 0.21 0,26 0.02 o.o o.o o.o c•o J. 90 8,111 9.18 17. 77 9. II 1 15.)0 10.28 11, t,J B•O 0.0 o.o o.o 0.0 o.o 0.0 0.0 0.0 ••20 9.21 6.88 6.50 I. 72 5.50 2.89 5.)6 5.21 •20 0.06 o. IJ o. 18 0.02 1.00 0.05 0.06 0.08 r 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 r.L 0.0 o.o o.o o.o 0.0 o.o 0.0 o.o 'iUM 98.55 100.74 98.71 98.17 100.46 100.79 98. 27 101.41 -o, r•cL o.o o.o o.o o.o 0.0 0.0 0.0 0.0 ~UH 98.55 100.74 911.71 911. 17 100.46 100.79 911.27 10 I, 111

SI 2. 920 . 2.5911 . 2.51111 . 2. 192 • 2,556 . 2.2115 . 2.51) • 2,446 • "L 1 .04) . 1.)96 . 1.371 • 1. 739 • I. 4)9 • 1.698 . I. 482 . 1. 546 • II 0.001 J. 96) 0.001 l.995 0.001 l.961 0.001 l.9)2 0.000 J.995 0.001 J. 98) 0.001 l.996 0.00) ).995 r c 0.006 • 0.006 . 0.009 • 0.011 . 0.0011 • 0.009 • 0.002 • 0.0011 • "" 0.001 . 0.002 . 0.0 . 0.001 . 0.001 . 0.002 . 0.002 . 0.002 • MC 0.0 . o.o . 0.014 . 0.0111 . 0.001 • 0.0 . 0.0 . 0.0 • c• 0. 187 . 0.401 . 0.11411 • 0.895 • 0.452 • 0.742 . 0.504 . 0.546 . N II• 0.0 . 0.0 . 0.0 . 0.0 . o.o . o.o . 0.0 . o.o • a-, ~· 0. 798 . 0.59) . 0.574 . o. 157 . 0.4711 . 0.254 . 0.475 . 0.1150 • a-, . O.OOJ 0.994 0.007 1.0011 0.010 1.056 0.001 1. 08) 0.057 0.997 0.00) 1.009 0.004 0.9117 0.005 1.010 0 8.000 . 11.000 . II.ODO . 8,000 • 8.000 . 8.000 . 8.000 • 8.000 . "H 18.90 40.02 4),)9 85.00 45,711 74. JI 51. 27 54.55 AB 80. 76 59.24 55.60 14.89 48,42 25. 110 48.)7 115.00 OR O. l5 0.74 1.01 0, 11 5.79 0.29 0. )6 0.45 CH o.o 0.0 o.o o.o o.o 0.0 o.o o.o

r/H o. 127 1,700 0.641 0.670 6.460 5.064 0.0 o.o r;rH o. 113 0.6)0 o. 391 0.1101 0.866 0.835 o.o o.o 1 44 PLAC 5 PL BCCIH 2 44 PLAC 6 PL l 44 PLAC 7 PL 4 44 SCAJI PL 8 PL

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SAMPL[ 44 rCLOSPAR ANALYSCS 9 10 11 12 1l 14 15 16 5102 55.65 47. 64 411.90 56.75 59.75 53.61 55.64 56.75 Ti02 0.01 0.03 0.0 .. 0.02 O.Ol 0.03 0.04 0.03 A20J 27. OJ 32.70 ll.92 26.69 25.80 30.07 27 .06 26.94 rco 0 ... 5 0. 21, 0. 30 0.20 0.23 0.11 0. 56 0.011 MNO 0.04 0.02 0.02 0.02 0.01 0.0 0.06 0.02 HCO 0.0 0.0 o.o o.o 0.0 o.o 0. 311 0.0 CAO 10 ... 6 15.52 15.75 9.711 7.87 13. 10 10.79 9. 72 BAO 0.0 0.0 0.0 o.o o.o 0.0 0.0 o.o NA20 5.2 .. 1. 97 2.1,9 5.113 7.07 4. 14 5.H 6. 13 ~?.O 0. 12 0.06 0.03 o. 12 0.19 0.10 0.08 o. 19 r o.o 0.0 0.0 o.o 0.0 0.0 0.0 0.0 CL 0.0 0.0 0.0 o.o 0.0 o.o o.o 0.0 SUM 99.00 98. 18 99.45 99 ... 1 100.95 101, 16 99.911 99.86 -o= r•cL 0.0 0.0 o.o o.o o.o 0.0 0.0 0.0 SUM 99.00 98.18 99. ••5 99.111 100.95 101.16 99.98 99,116

SI 2.531 . 2.217 . 2.250 . 2,563 . 2. 6 .... . 2 ... 01 • 2. 51 .. • 2,55" • AL I. 41,9 . I. 793 . I. 7 l 1 . I. .. 21 • I. l .. 5 . I. 587 • , ..... o . I. 429 . TI 0.000 l.980 0.001 4.011 0.001 3.982 0.001 3.985 0.001 l.991 0.001 l.989 0.001 3.955 0.001 l.9114 re 0.017 . 0.009 . 0.012 . 0.008 . 0.009 . o.oo .. • 0.021 . 0.003 . MN 0.002 . 0.001 . 0.001 . 0.001 • 0.000 . 0.0 . 0.002 . 0.001 . HC 0.0 . o.o . o.o • o.o • o.o . o.o • 0.026 . 0.0 . N

0\ CA 0.510 • o. 77 .. . 0. 776 • 0.473 . 0. 373 . 0.629 . 0.522 . 0 ... 69 . -..J BA 0.0 . 0.0 . 0.0 . 0.0 • 0.0 . 0.0 . o.o • 0.0 NA 0 ... 62 . 0. 178 . 0.222 . o. 511 • 0.607 . 0.359 . 0.470 . 0.535 k 0.007 0.997 0.00 .. 0.965 0.002 1. 013 0.007 0.999 0.011 0.999 0.006 0.998 0.005 1.046 o. 011 1.018 0 8.000 . a.ooo • a.ooo • a.ooo • 11.000 . 8.000 • 8,000 . 11.000 . AN 52.08 81. 02 77 .62 lj7. 77 37. 67 63.25 52, 37 46.20 AB "7. 21 18.61 22.21 51, 53 61.24 36.17 "7, 17 52.72 OR 0.71 O. l 7 0, IS o. 70 I.OS 0.57 0 ... 6 I.OIi CH o.o 0.0 o.o o.o o.o o.o 0.0 0.0

r/M 0. 127 I. 700 o. 6111 0.670 6.460 5.06 .. 0.917 -0. 0 r/FM 0. 113 0.630 0. 391 o.•101 o.&66 0,1135 0.478 o.o 9 PL 13 PL 10 PL 1 .. PL

11 PL 15 PL 12 PL 16 PL

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SAl'IPL( 44 rCLOSPAR ANALYSES 17 18 19

5102 54,9) )9,57 50. 34 TI02 0.0] 0.0) 0.02 A203 27.98 31.09 24.86 HO 0.2] o. 36 o. 11 HNO 0.0] 0.04 0.01 HGO 0.05 o. 17 -0.06 CAO 11. 17 14.60 7.74 BAO 0.0 0.0 o.o NA20 5.09 7.06 3. 1 l K20 0.15 0. 38 •0.07 r 0.0 0.0 0.0 CL 0.0 0.0 0.0 SUH 99.69 113. 30 86.08 •O• r+CL 0.0 0.0 0.0 SUH 99.69 113. 30 86.08

SI 2.488 . 2 .41] . 2.582 . Al 1.492 . 1. 484 . 1,503 • TI 0.001 l.981 0.001 J.899 0.001 4.086 re 0.009 . 0.012 . 0.005 • HN 0.001 . 0.002 • 0.000 . HG 0.004 . 0.010 • ·0.005 • CA 0.542 . 0.634 • 0.425 • BA 0.0 . 0.0 . o.o • NA 0.447 • 0,551, • 0.311 • K 0.009 1.011 0.020 1.231 ·0.005 o. 7JJ 0 8.000 • 8.000 • 8.000 • AN 5,.29 52.47 58.09

AB 1i,:82 45.91 42.51f OR \ 0.89 1.62 ·0.63 CN 0.0 0.0 o.o r/H 2.69] 1.335 0.641 r;rH o. 729 o. 572 0.391

17 AV(RAG( 18 AV[RAG[ PLUS SIGHA 19 AVtRAGt HINUS SIGMA

N 0\ co

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SAMPL( 44

5102 1

42.08 0.08 1102

AZ03 rzo3 MNO MCO CAO BAO NA20 •ZO r CL H20 SUM

27.92 3. 12 0.09 0.27

22.63 0.0 0.02 0.02 0.0 0.0 1. 94

·O• f+CL SUM

98. 17 0.0

98. 17

SI 3. 248 AL o.o J.248 AL 2.540 . Tl 0.005 MG 0.031 H3+ 0. 181 . MN 0.006 2.763 CA 1. 872 . • 0.002 . NA O.OOJ . BA o.o 1. 877 CL o.o • r o.o o.o H 1.000 1.000 0 13.000 .

PS 6.65 CZ 93. 14 PO 0.22

1 C

c,,oorc ANALYSES (OH CALCULATCDI

N 0\ \0

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S"MPLE 115 BIOTIT[ ANALYSES I 2 3 II 5 6 7

S107. 39.115 38.68 J7. 77 38.117 38.59 39. 19 37.99 110;! I .. l'J 1.611 1.112 1.117 1. 117 1. 56 1. 36 A;•oJ 111. J? 111. 73 111. 9 3 111. 75 111. 70 14. 90 111.'.>0 r ro 12. o•, 12.01 11. l? 12.03 11.95 12.09 11.82 Htm 0. I 7 o. 16 0. 18 0. 17 o. 17 0.16 0.16 MC:O 16. ,~ 16.60 17 .611 16.63 16.90 17. 33 16.118 c"o 0.09 u. 111 0.06 o. 1, o. 11 0.1, 0.07 n"o Cl. 0 o.o 0.0 0.0 0.0 o.o 0.0 N"70 0.06 0.08 0.07 0.06 0.07 0.08 0.06 K20 9.31 8.68 8.58 8.33 8. 111 9. 13 8.35 F 0.0 0.0 o.o o.o 0.0 0.0 o.o CL 0.0 o.o 0.0 o.o 0.0 0.0 o.o 1120 0.0 0.0 o.o o.o 0.0 0.0 0.0 SUM 93.68 92.72 92. 37 92.06 92.71 911. 61 90.81 -0= F+CL 0.0 0.0 0.0 0.0 0.0 o.o 0.0 SUM 93.68 92. 72 92. J7 92.06 92.71 911.61 90.81

SI 5.876 • 5.606 • 5.694 • 5.806 • 5. 796 • 5. 777 • 5.815 . N AL 2. 1211 8.000 2.1911 8.000 2.306 8.000 2. 194 8.000 2.2011 8.000 2.223 8.000 2. 165 11.000 -.J

AL 0.1102 • 0. 1112 • 0. 3116 • 0.430 • 0. 398 • o. 365 • 0.1132 • 0 TI 0.1'.>1 . 0. 185 • 0.161 • 0. 167 • 0.166 • 0. 175 . o. 157 • FE 1. 501 . 1. 508 . 1.1178 • 1. 518 • 1. 501 • 1.1190 . I. 513 . MN 0.021 • 0.020 . 0.023 • 0.022 • 0.022 • 0.022 • 0.021 • MG 3.719 5.795 3. 7111 5.839 3.964 5.972 3. 7111 5.878 3.784 5.871 3.808 5.660 3.759 5.881 CA 0.0111 . 0.023 • 0.010 • 0.0211 • 0.018 • 0.023 . 0.012 • NA 0.017 . 0.023 • 0.020 • 0.018 • 0.020 • 0.022 • 0.018 . I< 1. 780 • 1.662 • 1.650 • 1.6011 • 1.6711 • 1. 716 . 1. 631 • BA 0.0 1.812 0.0 1. 708 0.0 1.680 0.0 1.645 0.0 1. 712 0.0 1. 761 o.o 1.661 Cl. 0.0 • 0.0 . 0.0 • 0.0 • 0.0 • o.o . o.o • r 0.0 . 0.0 • o.o • 0.0 • 0.0 • 0.0 . o.o • ti o.o 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 o.o o.o 0.0 o.o 0.0 0 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 • 22.000 •

f/M 0.1109 0.411 0.379 0.412 0.402 0. 391 o. 408 f/l°M 0.290 0.291 0.275 0.292 0.287 0.2811 0.290

1 45 SCAN BT 5 AVERAGE 2 115 SCAN BT 6 AVERAGE PLUS SIGMA 3 115 SCAN er .., AVERAGE MINUS SIGMA 4 45 SCAN BT

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5AHPLE 115 FELDSPAR ANALYSES 1 2 3 11 5 6 7

5102 56.62 59.22 59.20 59,56 59. 15 59.49 56.61 1102 0.02 0.011 0.02 0.04 0.03 0.04 o.o;, A203 7?. 72 21.89 22.93 21.81 22.34 22.83 21.84 rm 0.7.1 0. 15 o. 17 0.211 0.19 0.23 0.16 HUO o.n? 0.11 0.0 0.03 0.01 0.03 -o.on HCO 0.09 0.0 0.01 o. 13 0.06 o. 11 0.00 CAO 7 .on 6,911 7. 16 5.98 6. 77 7.23 6.31 DAO 0.0 0.0 o.o o.o o.o 0.0 0.0 NA20 1. 77 7. 70 7 .65 8.06 7.19 7.95 7 .611 K20 0. 12 0.42 0. 12 0.16 0.20 U.ll 0.06 r o.u 0.0 0.0 0.0 0.0 0.0 o.o Cl. 0.0 o.u o.o 0.0 0.0 o.o 0.0 SUH 96.57 96. 36 97.26 96.01 96.55 96. 211 911.86 ·O• f+CL 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SUH 96.57 96.36 97.26 96.01 96.55 96.211 911.86

51 2.713 . 2.746 . 2. 717 • .• 2. 762 • 2.735 • 2. 712 . 2.758 N Al. 1,7.39 . 1. 196 • 1,240 . 1,192 • 1.217 • 1.227 • 1. 207 . -..J

TI 0.001 3.952 0.001 3.9411 0.001 3.958 0.001 3.956 0.001 3.953 0.001 3. 9110 0.001 3.965 ...... f[ 0.006 • 0.006 . 0.007 • 0.009 • 0.007 • 0.009 • 0.006 . MN 0.001 • 0.0 • o.o • 0.001 . 0.000 • 0.001 • -0.000 • HG 0.006 . 0.0 • 0.001 • 0.009 • 0.004 • 0.008 . 0.000 • CA 0.0 1,066 0.0 1.068 0.0 1. 0117 0.0 1.051 0.0 1,0511 0.0 1.093 0.0 1.022 IIA 0.0 . o.o • 0.0 • 0.0 • 0.0 • 0.0 • o.o • NA 0.697 . 0.692 • 0.6111 • 0. 77.5 • 0.699 . 0.703 . 0.6911 • K 0.007 1.066 0.025 1.068 0.007 1.047 0.009 1. 051 0.012 1.058 0.019 1.093 0.005 1.022 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 .

I\N 33.01 32.117 ll. 66 28.81 32.06 32.85 31. 19 AB 66.31 65. 19 65.116 70.27 66.79 65. J7 611. 311 OR 0.67 2. 311 0.68 0.92 1. 16 1. 19 0. 47 CN 0.0 0.0 0.0 o.o 0.0 o.o 0.0

F/H 1. 1135 0.0 9.538 1. 167 2.002 1.269 29.246 f/fH 0.589 0.0 0.905 0.539 0.667 0.559 0.967

1 115 PLAC 5 AVERAGE 2 45 PLAG 6 AVERAGE PLUS SIGMA 3 115 Pl.AC 7 AVERAGE HINUS SIGMA 4 45 PLAG

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SIIHPl.f 115 1

S102 ~II. 12 1107 Cl. I~ fl?Ol ?..9J 110 7. IJ<J HIIO 0.1,1 m;o 18. Tl

.(;/10 1;,. J(, 11110 II.CJ NA?O "· 7 J K20 0. 1 J f tl.O Cl. O.ll 11;•0 0.0 SUH 'l 7. 65 -Oc f+Cl 0.0 SUH 91. 65

SI /. 705 . Ill. 0.295 8.000 Al o. 191 . r I 0.016 ff Cl. 91, 1 MN 0.0119 . HG J.931 5. 128 CA 1.865 . HA ll.063 . K U.021 • IIA 0.0 1. 951 Cl 0.0 . r 0.0 . II 0.0 IJ.O 0 23. 000 .

CAA 27 .118 Alli 57. 93 GRU 1~.59

1/H 0.25?. f/fH 0.201

I 115 AHPlllll

AHPlllOOL[ ANALYS(S

N -..J N

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SMIPLE 46 HLOSPIIII ANIILYSES 1 2 3 4

510?. 62.95 62.95 62.95 62.95 110?. 0.0•1 0.04 0.04 0.04 11?.0J 19.58 19.58 19.58 19.50 ,ro 0.116 0.06 0.06 0.06 MPIO 0.0 0.0 0.0 0.0 Hl;O 0. 16 0.16 0. 16 0. 16 r.110 2.32 2. 32 2. 32 2. 32 0110 o.o 0.0 0.0 0.0 Nll?.O 2.23 2.23 2.23 2.23 K;'O 11 .05 11.05 11.05 I 1.05 I 0.0 0.0 0.0 o.o Cl. 0.0 o.o 0.0 o.o SIJH 98.39 98. 39 98. 39 98. 39 -o, r+CL 0.0 0.0 0.0 0.0 SlJH 98.39 98. 39 98. 39 98. 39

SI 2.918 • 2.918 . 2.918 • 2.918 • Ill 1.010. . 1.010 . 1.070 • 1.070 • II 0.001 3.989 0.001 3.989 0.001 3.989 0.001 3.989 r£ 0.002 . 0.002 . 0.002 • 0.002 • Hfl 0.0 . 0.0 . o.o • 0.0 • N HG 0.011 . 0.011 • 0.011 • 0.011 • -...J

CA 0. I 15 . 0.115 • 0.115 • o. 115 • l,..)

RII 0.0 • 0.0 • 0.0 • o.o • NA 0.200 . 0.200 • 0.200 • 0.200 • K 0.653 0.982 0.653 0.982 0.653 0.982 o.653 0.982 0 11.(100 . 8.000 • 8.000 • 8.000 •

IIN 11 .89 11. 89 11.119 11.89 IIR 20.68 20.68 20.68 20.68 OR 67 .42 67.42 67.112 67.112 CN o.o o.o o.o 0.0

f/H 0.210 0.210 0.210 0.210 r/fH o. 1711 0. 1111 0. 1711 0.1711

1 4611 KSPAR? 3 AVERAGE PLUS SIGMA 2 AVERAGE II AVERAGE MINUS SIGH/\

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SAHrLE 116 FELDSPAR ANALYSES 1 2 3 4 5 6 7 8

SI02 58.36 59.62 64. 77 59. 111 57.83 58. 72 61.90 58.02 r 107 0.05 0.04 0.02 0.011 0.02 0.011 0.03 0.02 A203 25.28 23.92 21. ll 21!.83 25.83 25. 73 23. 18 26.52 Fl 0 U.50 0.0'; 0.0 0.10 0.22 0.111 0. 17 0. 32 HNO 0.03 0.01 0.011 0.01 o.o 0.02 o. 111 0.32 HGO 0.21 0.04 0.12 0.08 0.19 0.111 11.03 0.05 CAO 7. 75 5.92 2 .811 7. 37 9.03 ti. 33 II. 711 8. 70 DAO 0.0 o.o 0.0 o.o o.o 0.0 0.0 0.0 NA?.0 7 .02 7 .1111 9. 511 7.119 6.61 6.111 9. 15 6.95 1(20 0.09 1.49 0.84 0.211 0.26 0.811 0. 11 0. 16 r 0.0 o.o 0.0 0.0 0.0 o.o 0.0 0.0 Cl. 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SUH 99.35 98.53 99.50 99.90 99.99 100. 37 99.45 10 I. 06 -o- r+CL o.o o.o 0.0 o.o 0.0 0.0 0.0 o.o SUH 99.35 98.53 99.50 99.90 99.99 100.37 99.45 10 I. 06

SI 2.630 • 2. 707 • 2.873 .. 2.670 • 2,598 .. 2.624 .. 2.764 • 2.582 .. Al 1. 343 • 1.280 .. 1. 115 .. 1.308 .. 1.361 • 1. 355 • 1.220 • 1. 391 .. TI 0.002 J. 9111 0.001 J.988 0.001 3.989 0.001 3.980 0.001 3.966 0.001 3.980 0.001 3.985 0.001 3.9711 F[ 0.019 .. 0.002 • o.o • D.004 • 0.008 .. 0.005 • 0.006 . 0.012 • N HII 0.001 • 0.000 • 0.002 .. 0.000 .. o.o .. 0.001 .. 0.005 • 0.012 • -...J HG 0.018 . 0.003 .. 0.008 .. 0.005 .. 0.013 • 0.009 • 0.002 • 0.003 . ~ CA 0. 374 . 0.288 • o. 135 • 0.353 . 0.1135 .. o. 399 .. 0.227 • 0.1115 .. (IA 0.0 .. o.o .. 0.0 .. 0.0 • 0.0 • 0.0 .. 0.0 .. 0.0 .. NA 0.613 .. 0.655 .. 0.821 .. 0.649 • 0.576 • 0,555 .. o. 792 .. 0.600 .. K 0.005 I. 031 0.086 1, 0111 0.048 1.013 0.014 1.025 0.015 1.0116 0.048 1.017 0.006 1.039 0.009 1.051 0 8.000 .. 8.000 • 8.000 .. 8.000 .. 8.000 .. 8.000 • 8.000 .. 8.000 ..

AN 37.69 21.98 13.46 34.75 112.39 39.80 22. 12 110. 53 AD 61. 79 63.63 81.80 63.90 56. 15 55.42 71. 21 58.59 OR 0.52 8.38 4. 71! 1. 35 1.115 4.78 0.61 0.89 Ctl 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 f/H 1. 102 0,8113 0. 189 0.172 0.650 0,6112 5.831 7 .228 f/fH 0.5211 0.1158 0.159 0.1136 0.394 0. 391 0.854 0.816

I 46A PLAG 5 464 PLAG 2 l16A PLAG 6 116A PLAG 3 46A PLAG 7 CORH INIS 4 l16A PLAG 8 RIH

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SAHPL[ 116 rLLDSrAn ANALYS[S 9 10 11 12 13

5102 56.49 56. 62 59.21 61. 59 56.82 110;, o.o~ 0.02 0. OJ 0.04 0.02 A20) 26.% 2'.>.87 211. 911 26.56 2J.JJ 110 0. 19 0.19 0. 19 0. 32 0.05 Hirn ll.08 0.22 0.09 o. 19 -0.02 ,n;o 0.0 0.01, 0.10 0.18 0.02 CAO 9.44 8. 19 7.21 9.21 5.21 OAO 0.0 o.o 0.0 0.0 o.o NA20 6.51 6. 77 1.19 8.lll 6.35 1<20 o. 11 0. 11, o.•,3 0.88 -0.01 I 0.11 0.0 0.0 o.o 0.0 CJ ll.O 0.0 o.o o.o 0.0 SUM 99.89 98.06 99.61 107. •12 91.80 •O• r•CL O.IJ 0.0 0.0 0.0 o.o SUH 99.89 98.06 99.61 107 .42 91.80

SI 2. 51,6 • 2.591 . 2.659 . 2.600 • 2. 726 • Al 1.1132 . 1.195 . 1. 120 . 1. 121 • 1. J 19 • TI 0.002 J.980 0.001 3 .986 0.001 3.980 0.001 3.922 0.001 4.046 Ff 0.007 • 0.007 • 0.007 • 0.011 • 0.002 • N mi O.OOJ . 0.009 . O.OOJ . 0.007 . -0.001 • -..J ~IG 0.0 . O.OOJ • 0.006 • 0.011 • 0.001 • V, CA o.•1'.>6 . 0.401 . 0. Jl18 • 0.417 • 0.269 • [IA 0.0 • 0.0 • 0.0 . 0.0 • o.o • NA 0.569 . 0.601 . 0.643 • 0.690 • 0.591 • I( 0.010 1.0115 0.008 1.029 0.025 1.0lJ 0.047 1. 181 -0.001 0.862 0 8.000 . 8.000 • 11.000 . 8.000 • 8.000 •

AN 1,11.01 J9. 74 34.24 J6. 16 31. 31 AB 51,,99 59.45 63.31 59. 75 68. 75 OR 0.911 0.81 2.45 4.09 -0.07 CH 0.0 0.0 0.0 0.0 o.o

F/H 1. !02 5.791 1.6111 1. 619 1. 337 F / 114 o. 5211 0.853 0.617 0.621 0.572

9 HOTlt CORE 12 AVERAGE PLUS SIGHA JO RHIF 11115 13 AVERAGE MINUS SJGHA 11 AVERAGE

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SAMPI t f16 AHPIIIBOL[ IINIILYS[S 1 2 J 4 5

SIO? 5ll. 75 50. '/5 50. 75 50.75 50. 75 I Ill;> 0.111 0.111 0.41 0.111 0.41 11:'0l •1. ?J 11.9J If. 9J 11. 9J IJ. 9J 110 14. 18 111. 16 14. 18 14.18 14.16 MtlO (). 3'.j 0.35 O.J'.i o. 35 o. 35 llf.O 111. 911 14.98 111. 98 111. 98 14.911 C/10 12. 111 12. 111 12. 74 12. 74 12. 111 11110 ll.O o.u 0.0 0.0 0.0 ll/120 0.61 0.61 0.61 0.61 0.61 K20 0.110 0.40 0.1,0 0.40 0.1,0 I 0.0 o.o 0.0 0.0 0.0 CL o.u 0.0 0.0 0.0 0.0 1170 ll.O ll. 0 0.0 0.0 0.0 SUH 99. 35 99. 35 99.35 99. 35 99. 35 •0; I +CL O.ll 0.0 0.0 0.0 o.o SUH 99. 35 99. J5 99.35 99.35 99.35

SI 7. 3UII . 7.304 • 7.304 • 7.304 • 7. 3011 • Ill. 0.696 8.000 0.696 8.000 fl.696 8.000 0.696 8.000 0.696 8.000 Al. o. 1110 • U.140 . 0.1110 • o. 140 • 0.140 . TI o.0•111 . 0.01111 • 0.0114 . 0.044 • 0.0411 . H 1. 70 7 . 1. 707 . 1. 707 • 1. 707 • 1.707 • N HN O.OIIJ . 0.043 • 0.043 • 0.043 • 0.043 • -.....J HG 3.213 5. 1117 3.213 5. 147 3.213 5. 147 3. 213 5. 147 3.213 5. 147 "' C/1 1.964 • 1.964 • 1.964 • 1.964 • 1.9611 • NII ll. 170 • 0.170 . 0.170 • 0.170 • 0.170 • K 0.073 • 0.073 • 0.073 • .0.073 • 0.073 . BA 0.0 2.208 0.0 2.208 0.0 2.208 o.o 2.208 0.0 2.208 Cl o.u • o.o . 0.0 • 0.0 • o.o • r 0.0 • 0.0 • 0.0 • 0.0 . 0.0 • It 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0 23.000 • 23.000 • 23.000 • 23.000 • 23.000 •

CAA l8.36 28. 36 28.36 26. 36 28. 36 ANT 46.39 46.39 46.39 116. 39 46.39 GRU 25.25 25.25 25.25 25.25 25.25

f/H 0.5411 0. 51111 0.5114 o. 5411 o. 5411 1/FH U. 352 0.352 0.352 0. 352 0. 352

1 46 SCAN AHPH OR PX .. AV[RAG[ Pl.US SIGHA ? 46 SCAN PX OR AHPII 5 AV[RAG[ MINUS SIGHA 3 AVERAGE

Page 282: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

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Page 283: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SIIMrtf 111 r[LOSPAR ANALYSES 1 2 3 II 5 6 I 8

SI02 611. 15 611. 15 611. 33 63.76 63. 33 611. 112 611. 63 66.26 r 10;:, 0. 03 0.03 0.02 0.02 0.05 0.03 0.02 0.011 A203 18. 12 18. 111 17. 15 18.06 18.59 18. 10 18.32 17.88 1 ro 0.25 0.28 II. 15 0.19 0.22 0.11 0.211 0.03 HIW 0.08 0.0 0.01 0.01 0.0 0.02 0.0 0.0 ~IGCJ 0.0 0.02 0.011 0.12 0.011 0.08 o.o 0.05 CAO 0.16 0.05 0.05 0.10 0.115 O.OB 0.09 0.01 IIAO 0.0 0.0 O.IJ 0.0 0.0 0.0 0.0 o.o N/\20 O. ll1 0.211 0. 113 0.22 0. 79 0.511 0.116 0. 30 K20 15.75 15.86 15.59 15.611 111.65 15. 12 15.32 15.56 r o.o 0.0 o.o 0.0 0.0 o.o 0.0 0.0 Cl. 0.0 0.0 0.0 0.0 0.0 o.o o.o 0.0 SUH 98.88 98.81 98.37 98. 12 98. 12 98.50 99.011 100. 19 -0= F+CL 0.0 o.o 0.0 o.o 0.0 o.o 0.0 0.0 SUH 98.88 98.81 98. 37 98. 12 98.12 98.50 99.011 100.19

SI 2. 99"/ . 2.999 . 3.015 • 2.996 • 2.912 • 3.001 • 3.003 . 3.036 • AL 0.998 • 0.999 . 0.980 . 1. 001 • 1.028 • 0.996 . 1.003 • 0.965 • 11 0.001 3.996 0.001 3.999 0.001 3.996 0.001 II.ODO 0.002 11.002 0.001 II.ODIi 0.001 11.007 0.001 11.00l re 0.010 • 0.011 • 0.006 • 0.007 • 0.009 • 0.0011 • 0.008 • 0.001 • N HN 0.003 • o.o . 0.000 . 0.000 • 0.0 • 0.001 • 0.0 • o.o • -..J HG o.o • 0.001 • 0.003 . 0.008 • 0.003 • 0.006 • 0.0 • 0.003 • CX) CA 0.008 • 0.003 • 0.003 • 0.005 • 0.023 • 0.0011 • 0.0011 • 0.003 • 8/\ 0.0 . 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 • 0.0 . NA 0.031 • 0.025 . 0.039 • 0.020 . 0.072 • 0.0119 . 0.0111 . 0.021 . K 0.939 0.990 0.9116 0.986 0.932 0.983 0.938 0.979 0.877 0.983 0.900 0.9611 0.908 0.962 0.909 0.91111 0 8.000 . 8.000 . 8.000 • 8.000 • .8.000 • 8.000 • 8.000 . 8.000 •

AN 0.82 0.26 0.26 0.52 2. 33 0.112 0.117 0. 37 AO 3. 15 2.61 11.01 2.08 7 .110 5. 13 1,. 311 2.811 OR 96.03 97. 111 95. 73 97.39 90.27 91,. 45 95.19 96.80 CN 0.0 o.o 0.0 0.0 0.0 0.0 0.0 0.0

F/H 0.0 7.855 2.2116 0.936 3.086 0.9111 0.0 0. 337 r/rH o.o 0.887 0.692 0.1183 0.755 o.,,77 0.0 0.252

1 117 SCAN KSP 5 117 SCAN2 kSP 2 117 l<SP 6 117 SCAN2 kSP 3 117 KS 7 117 SCAN2 kSP •1 117 l<SP 8 KS

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SAHPL( 117 fCLDSPAR ANALYSES 9 10 11 12 13 111 15 16

SI02 65.30 65. 16 65.28 65. 33 65.62 611.16 611. 23 63.83 1102 0.06 0.07 0.05 0.07 0.07 0.02 0.06 0.16 A203 18. 19 18,UO 19.00 18.lll 18. 32 I 7, 58 19.65 16. 32 lrO 0. 11 0.16 0.11 0.116 0. 32 0.1111 (), 15 0.56 HllO O,O;> 0.011 0.01 0.03 0.01 0.01 0.0 0.011 MGO 0.0 0.01 0.08 o.o 0.05 o. 38 0.07 0. 17 CAO 0.03 0.011 0. 11 0.06 0.09 o. 33 o. 78 0.23 BAO 0.0 0.0 0.0 o.o 0.0 0.0 o.o 0.0 NA20 0.28 o. 30 0.60 0.39 o. 37 0.27 0.53 0.119 K20 15.75 15.88 15.113 15.811 15.60 15.36 111.113 111.90 F 0.0 0.0 0.0 0.0 0.0 0.0 0.0 o.o CL 0.0 0.0 0.0 o.o o.o 0.0 o.o 0.0 SUM 99. 711 99.66 100.67 100.61 100.115 98.59 100. 10 98.70 -o~ f+CL 0.0 0.0 0.0 0.0 0.0 o.o 0.0 0.0 SUH 99. 711 99.66 100.67 100.61 100.115 98.59 100. 10 98.70

SI 3.0111 i, 3.015 • 2.9611 . 2,996 • 3.008 • 3.005 . 2.9116 • 2.981 • Al. U.969 . 0.981 • 1.0211 • 0.997 • 0.990 • 0.970 • 1.073 • 1.008 • TI 0.002 11.006' 0.002 3.999 0.002 11.010 0.002 3:997 0.002 11.000 0.001 3.975 0.002 11.021 0.006 3.995 f[ 0.001, . 0.006 • 0.0011 • 0.018 • 0.012 • 0.019 • 0.006 • 0.022 • N HN 0.001 • 0.002 • 0.000 • 0.001 • 0.000 • 0.000 . 0.0 • 0.002 • HG 0.0 • 0.001 • 0.005 • o.o • 0.003 • 0.027 • 0.005 • 0.012 . . ......,

'° CA 0.001 • 0.002 • 0.005 • 0.003 • 0.004 • 0.017 • 0.038 • 0.012 • BA 0.0 • 0.0 • o.o • o.o • o.o • 0.0 . 0.0 • 0.0 • NA 0.025 . 0.027 • 0.053 • 0.035 • 0.033 • 0.025 • 0.0117 • 0.01111 • K 0.927 0.959 0.937 0.974 0.900 0.968 0.927 0.9811 0.912 0.966 0.917 1.0011 0.81111 0.9110 0.888 0.979 0 8.000 . 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 •

All 0.16 0.21 0.56 o. 31 0.47 1. 73 11.12 1. 22 AO 2.63 2. 79 5.55 3.60 3.116 2.56 5.07 11. 70 UR 97 .22 97 .01 93.89 96.10 96.07 95. 72 90.81 911.08 CN o.o 0.0 0.0 0.0 0.0 0.0 0.0 0.0

f/H 0.0 11.250 0.8113 0.936 3.705 0. 7211 1.202 1.982 f/FH 0.0 0.918 0.1157 0.1183 0. 787 0.1120 0.5116 0.665

9 KS 13 KS 10 KS 111 KS 11 KS 15 KS 12 KS 16 KS

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SIIHrll 11 / f[lOSrllR ANALYSlS 1 / Ill 19 21J 21 22

510;> 611. 51 65. 19 61.92 6•1.6•1 65 .111 61.111 1107. 0.06 0.0 0.01 0.05 0.08 0.01 A:>Ol 18.10 11. 31 18.22 18.211 111. 76 11. 11 II 0 11.11 0.06 0.06 0.21 0.16 0.07 HIIO 0.01 0.0} o.o 0.02 O.Oti -0.00 ~IGO 0.08 0.0 0.01 0.06 0.15 -0.02 CAO· 0.01, 0.08 o.ori o. 15 O.lJ -0.0l !\AO o.o 0.0 0.01 0.00 0.00 -0.110 NA~'O U. Jl II.Iii 0.51 o. "' 0.55 0.26 K20 15.56 111. 116 15.118 15.18 15.112 111. 91

' 0.0 0.0 0.0 0.0 0.0 0.0 Cl 0.0 0.0 0.0 0.0 o.o 0.0 SIJH 99.07. 98. '" 98.28 99. 16 101. 50 96.81 -o., r+CI. o.o 0.0 0.0 o.o o.o o.o SIJH 99.02 98. Iii 98.28 99.16 10 I. 50 96.111

SI 3.001 . l.060 . 2.998 . J.002 • 2.979 • J.026 . AL 1. lllll . 0,9119 • 1.007 . 0.998 . 1.007 • 0.989 . II 0.00? 11.006 0.0 11.009 0.000 ti.005 0.002 11.002 0.003 3.988 0.000 11.015 rr 0.001, . 0.002 . 0.002 • 0.008 • O.Olti • O.OOJ . ~IN 0.000 • 0.001 . o.o . 0.001 • 0.001 • -0.000 • N HG 0.006 . o.o • 0.002 • 0.0011 • 0.010 • -0.00? • 00 CA 0.002 . 0.0011 . 0.002 • 0.008 • 0.016 • -0.002 • 0 HA u.o • 0.0 . 0.000 • 0.000 • 0.000 • -0.000 . PiA 0.010 . 0.031 • O.Oti6 . O.OJ7 • 0.0119 • 0.025 • K 0.9?J 0.965 0.858 0.902 0.926 0.919 0.911 0.969 0.919 1.009 0.902 0.9:>7 0 8.0011 . 8.000 . 8.000 . 8.000 • 8.000 • 8.000 .

Ati 0.21 O.llti 0.21 o. 79 1.66 -o. 11 1111 l. 12 11. 11 "· 76 3.89 ti.9J 2. 7l Oil 96.67 95.•1 11 95.02 95. 32 93.111 97 .1111 CN 0.0 0.0 0.02 0.00 0.01 -(J. 00

f/H 0.8111 11.250 I. 122 1.993 1. lj611 · o. 1211 f/FH 0.1157 0.918 0.529 0.666 0.591i 0.1120

11 KS 20 AVERAGE 18 N[Wll KSP 21 AV[RAG[ PIUS SIGMA 19 ti I KSP 22 AVERAGE MINUS SIGMA

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SIIHPl[ 117 r[lOSPAR ANAlVS[S 1 2 J 4 5 6 l 8

S102 119. 83 52.JO 56. 17 52.92 56.22 56.31 58.66 56.05 110? 0.02 0.02 0.0 0.04 0.0 0.04 O.OJ 0.011 A20l JO.II) 29.110 26. 75 JO. 54 27.48 26. 711 26.31 28. 79 rco 0.19 0.16 0.06 0.17 0.50 0. 1l 0.19 0.18 HNO 0.05 o.o O.Ol 0.02 0.02 0.01 O.OJ o.o MGO 0.06 0.11 0.02 o.o 0.06 o. 13 0.011 0.0 CAO 111. OJ 12.05 9.::>8 12. 19 .9.07 8. 16 8.26 11.00 ()AO 0.0 0.0 0.0 0.0 0 .. 0 o.o 0.0 0.0 NA20 l.28 4.50 6.01 4.56 6.16 6. 35 6.55 5. 10 K20 0. 36 0.13 0.24 0.12 0.21 0. 16 0.19 0.17 r 0.0 0.0 0.0 0.0 0.0 0.0 0.0 o.o Cl o.o 0.0 0.0 0.0 o.o 0.0 0.0 0.0 SUH 98.25 98.67 98.56 100.56 99. 72 98.63 100.26 101. l3 -0= r+Cl 0.0 0.0 o.o o.o o.o o.o 0.0 o.o SUH 98.25 98.67 98.56 100.56 99.72 98.63 100.26 101.l]

SI 2.315 . 2.401 • 2,558 • 2. )84 • 2.536 • 2.561 . 2.615 • 2.490 . Al 1.666 . I. 590 . 1.436 . 1.621 • 1.460 • 1.433 . 1,382 • 1. 507 . ll 0.001 l.981 0.001 J.992 o.o l.994 0.001 11.006 0.0 l,996 0.001 J,995 0.001 J. 998 0.001 l.999 re 0.001 • 0.006 . 0.002 • 0.006 • 0.019 • 0.005 • 0.007 • 0.007 • N HN 0.002 • 0.0 . 0.001 • 0.001 • 0.001 • 0.000 • 0.001 • o.o • 00 HG 0.0011 . 0.008 . 0.001 • 0.0 • 0.004 • 0.009 . 0.003 . 0.0 .. ...... CA 0.698 . 0.593 . 0.1153 • 0.588 • 0.1138 • 0.1121 • 0.395 . 0.5211 • DA o.o . 0.0 . 0.0 • o.o • 0.0 • o.o . 0.0 • 0.0 . HA 0.295 . 0.1101 • 0.531 • 0. 398 • 0.539 . 0.560 • 0.566 . 0.1139 . K 0.021 1,028 0.008 1.0111 0.0111 1.002 0.007 1.001 0.012 1.013 0.009 1.010 0.011 0.982 0.010 0.979 0 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 • 8.000 . 8.000 •

AN 68. 79 59.22 115.IIO 59.22 1111. 32 112.65 40.61 53.811 AB 29. 10 110.02 53,20 110.09 54.46 56.21 56.28 45. 17 on 2. 10 0.76 1.40 0.69 1.22 0.93 1. 11 0.99 CN 0.0 0.0 o.o o.o 0.0 0.0 0.0 0.0

r/H 2.250 0.616 2.536 1.993 11.665 0.605 l.091 1.982 r/rH 0.692 0.449 0.717 0.666 0.629 0. 371 0. 756 0.665

1 117 PLAG 5 117 SCAN2 PlAG 2 41 PlAG 6 47 SCAN2 PLAG l 117 SCAN2 PlAG 7 PLSTART II 4 7 SCAN 2 PLAG 8 PL

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S/\HPLC 111 FELDSPAR ANALYSES 9 10 11 12 1l 111 15 16

SI02 58.61 59.J2 51.91 52.97 58. 38 51.92 511. 37 52.119 I I 02 0.011 0.06 o. 1 J 0.02 O.OJ 0.011 0.03 0.05 A203 21.011 21.011 28.03 27 .98 26.01 JO.II] 28.8J 30.09 rro 0. 17 o. 11 0.20 0.52 0.22 o. 15 0. 15 0. JI HUD 0.02 0.03 0.0 0.03 0.01 0.0 0.01 0.02 HGO 0.06 o.o 0.011 0.58 o.o 0.0 0.0 0.011 CAO 8.22 8.56 9. 38 12.J8 7.95 12.116 10.88 12. 511 RAO 0.0 0.0 o.o o.o 0.0 o.o o.o 0.0 HA?O 6.58 6.29 6.01 11.0l 6. 18 li.09 11.82 Ii.DO K20 0. 18 0.16 0.16 0.06 0.62 0.111 0. 11 0.11 r 0.0 0.0 o.o o.o o.o 0.0 o.o 0.0 Cl. o.o 0.0 0.0 o.o 0.0 o.o o.o o.o SUH 1110. 92 101.63 101. 92 98.55 99.liO 99.27 99.26 99.65 •O= r+CL o.o 0.0 0.0 o.o o.o 0.0 0.0 0.0 SUH 100.92 101.63 101. 92 98.55 99.liO 99.27 99.26 99.65

SI 2.596 • 2.606 • 2. 5118 • 2.li36 • 2.625 • 2.310 . 2. 467 • 2. 386 • AL 1.1111 . 1.1100 . 1.453 • 1.516 . 1. 3711 • 1.637 . 1. 541 • 1.612 • II 0.001 4.008 0.002 4.008 O.OOli 4.005 0.001 3.953 0.001 4.005 0.001 li.008 0.001 11.009 0.002 4.000 I[ 0.006 . 0.006 . 0.007 • 0.020 • 0.008 • 0.006 . 0.006 . 0.012 • Hfi 0.001 • 0.001 . o.o • 0.001 • 0.000 • 0.0 • 0.000 . 0.001 • N HG 0.0011 . o.n . 0.003 • 0.0110 • o.o • o.o . 0.0 • 0.003 • 00 CA o. 390 . 0.1103 . 0.442 • 0.610 • 0.383 • 0.609 . 0.529 . 0.611 • N OA 0.0 . 0.0 • 0.0 . 0.0 • o.o • 0.0 • 0.0 . o.o • HA 0.565 • 0.5J6 • 0.518 • o. 3511 • 0.539 • o. 362 . 0.11211 • 0.353 • K 0.010 0.976 0.009 0.955 0.009 0.979 0.004 1.032 0.036 0.966 0.010 0.988 0.010 0.969 0.006 0.985 0 11.000 • 11.000 • 8.000 • 8.000 • 8.000 • 11.000 • 8.000 . 8.000 •

/\Ii liO. 41 112.52 45.63 62.82 40.01 62.07 511.94 62.99 AB 58. 511 56.54 5J.li4 36.82 56.28 36.87 1111.011 36. 36 on 1.05 0.95 0.93 0.36 3.71 1.01 1.02 0.66 CN o.o o.o 0.0 o.o 0.0 0.0 0.0 o.o

F/H 1. 7 79 0.816 2.805 0.532 11.865 0.605 3.091 11.632 f/fH o. 6110 0.4119 o. 737 0.347 0.829 o. 377 0.756 0.822

9 Pl. 13 PL 10 Pl. 14 PL 11 Pl 15 PL 12 PL 16 Pl

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SAHPL[ 111 f[LOSPAR ANALYS[S 17 18 19 20 21 22

5102 56.59 5,,. 36 57 .85 55,113 58. 12 52. 75 1102 o.o,, o.o,, 0.08 0.011 0.07 0.01 A20] 26.55 29. 16 26.1111 28. 11 29.62 26.59 rr.o 0.16 0.21 0. 12 0.21 o. 32 0.09 HHO o.o o.o 0.0 0.01 0.03 0.00 HGO O.OJ o.o 0.0 0.06 o. 19 -0.07 CAO 8.92 11.19 7.89 10.26 12. 111 8. 39 DAO o.o 0.0 o.o 0.0 o.o 0.0 NA20 11, 78 11.85 6.118 5.30 6.33 11.27 1<70 2.31 0.21 0.25 0.32 0.80 -o. 17 r 0.0 0.0 o.o 0.0 o.o 0.0 Cl o.o 0.0 0.0 0.0 o.o 0.0 SUH 99.38 100.02 99. 11 99,711 107 .61 91. 81 -0= f+Cl. 0.0 0.0 0.0 0.0 0.0 0.0 SUH 99. 38 100.02 99.11 99.711 107.61 91.87

SI 2. 572 • 2.1152 • 2.606 • 2.502 • 2.1161 • 2,5119 • Al. 1.1,22 • 1. 550 • 1.1,011 • 1.1,95 • 1.1178 • 1. 5 Ill . TI 0.001 J.995 0.001 11.0011 0.003 It.OU 0.001 3.998 0.002 3.9111 0.000 l1,061f re 0.006 • 0.008 • 0.005 • 0.008 • 0.011 • O.OOlf • N HN o.o • 0.0 . o.o • 0.001 • 0.001 • 0.000 .

00 HG 0.002 • 0.0 • 0.0 • 0.0011 . 0.012 • •0.005 .. w CA O.IIJl1 • o. 541 • 0.381 • 0.496 • 0.551 • 0.11311 • DA 0.0 . o.o . o.o . 0.0 • 0.0 • 0.0 . NA 0.1121 • 0.11?11 . 0.566 • 0.4611 • 0.519 . O,IIOO • I( 0. 1311 0.998 0.012 0.985 0.014 0.966 0.018 0.991 O.Olfl 1. 138 -0.010 0.823 0 8.000 • 8.000 • 8.000 • 8.000 • 8,000 • 8.000 •

AN 113.90 55.35 39.62 50.75 lf9.lf6 52. 77 AB 112.57 Ill. II 1 58.88 47. 110 46.66 118.5'• OR 13. 53 1.211 1.49 1.86 3.88 -1.26 CN o.o o.o o.o o.o o.o 0.0

F/H 2.992 0.816 2.805 2.035 1.0112 0.605 f /FH 0.750 0.11119 o. 737 0.671 0.510 o. 377

17 Pl. 20 AVCRAGE 18 Pl 21 AV[RAGE PLUS SIGMA 19 Pl. 22 AVCRAGE HINUS SIGMA

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SIIMl'L[ 11 f 111-11'11 IDOL[ /\NIil. YSC S 1 ;, 3 II 5 6 1 II

S102 '.">2. 40 51.n 53.68 511.66 56.35 51. 55 51.61 52.113 I I 02 0.22 0.21, 0. 11 0. 13 0.19 0.29 1. 12 0.1111 11?03 2. 76 3.68 3.26 2.22 2.113 11. 115 3. 32 3.27 no 12.56 12.63 15. 911 16.88 13.611 111. 86 13. 51, 13.56 MfW O. H 0.110 0.118 0.116 0.37 o. 311 o. J7 o. 38 Mr.O 111. 78 15. 19 11.99 12.511 13.78 13 .66 13.08 13. 77 C/10 11. 93 11.92 12.112 12.50 12.23 12.35 12.69 12.11 11110 O.CJ 0.0 o.o 0.0 o.o 0.0 o.o o.o N/120 0.26 0.35 o. 16 0.111 0.22 U.32 0.24 0. 30 1120 CJ.20 ll.21 IJ.111 0. Iii 0.17 0.21 0.22 0.211 r o.o 0.0 0.0 0.0 0.0 0.0 0.0 o.o Cl 0.0 0.0 0.0 0.0 0.0 0.0 o.o o.o 11;,o 0.0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 SUM 95.118 96.511 98. 18 99.67 99. 38 98.03 96. 19 96.50 -0• f+CL 0.0 0.0 o.o o.o o.o o.o 0.0 o.o SUM 95.118 96.511 98.18 99.67 99.38 9!!.03 96. 19 96.50

SI 7.725 . 7.582 . 7.792 . 7.845 • 7.953 • 1.1191 . 7.615 • 7.665 • Al 0.2/'., 8.000 0.418 8.000 0.208 8.000 0. 155 8.000 0.0117 8.000 0.503 8.000 o. 385 8.000 o. 315 8.000 Ill 0.2011 • 0.216 • o. 350 • 0.220 • 0. 357 • 0.259 • 0. 192 . 0.250 • TI 0.02•1 . 0.026 . 0.012 • 0.0111 • 0.020 • 0.032 . 0. 124 . 0.0119 • re 1. 5118 • 1.5112 • 1.935 • 2.026 • 1. 610 . 1.807 • 1.671 • 1.662 . N HN 0.0116 . 0.049 • 0.059 • 0.056 • 0.0411 • 0.0112 . 0.0116 • 0.0117 . 00 HG 3 .2118 5.071 3.306 5. 140 2.5911 4.950 2.683 11.999 2.899 11.930 2.961 5. 101 2.877 ,,. 910 3.009 5.017 ~

CA I. 8811 . 1.865 • 1.932 • 1.922 • 1 . 8119 • 1.924 • 2.006 • 1.902 • HI\ II. ff/4 . 0.099 . 0.01,5 . 0.039 • 0.060 • 0.090 . 0.069 . 0.0115 . I( 0.038 • 0.039 • 0.026 • 0.026 • 0.031 • 0.039 • 0.0111 . 0.0115 . OA 0.0 1.996 0.0 2.003 0.0 2.003 0.0 1.987 0.0 1.9110 0.0 2.053 0.0 2.116 0.0 2.032 Cl 0.0 • 0.0 . 0.0 • o.o • o.o • o.o • o.o . 0.0 • f u.o . 0.0 • o.o • 0.0 • o.o • 0.0 . o.o • 0.0 • II o.u 0.0 0.0 0.0 o.o 0.0 0.0 0.0 o.o o.o o.o 0.0 0.0 0.0 o.o 0.0 0 23. 000 • 23.000 • 23.000 • 23.000 • 23. 000 • 23.000 • 23. 000 • 23.000 •

CAIi 28.01 27. 58 29.63 28.75 28.89 28.57 30.40 26. 73 IINI 48.26 118.89 39.79 110.12 115.28 Ill. 97 111. 59 115.45 GRU, 23.71 23.511 30.58 31. 111 25.811 27 .46 2(,.02 25.82

f/H 0.491 0.1181 o. 769 0. 776 o. 571 0.625 0.597 0. 568 f/fH 0. 329 0. 325 0.435 0.437 0.363 0. 3811 o. 3711 o. 362

1 117 SC/\ll2 A? 5 PORA 2 11 7 SCAN2 IIHP? 6 PORA 3 START 7 PORA 4 PORA 8 PORA

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SIIHPL[ 117 IIHPIII BOLE ANAL YSCS 9 10 II 12 13 111 15 16

S102 11').96 52.61 50. 54 51.29 5J. 76 54.08 511. OJ 54. 19 110;, 0.211 U. l5 0.2l 0. 14 o. 17 0.01 0.05 0.18 11201 5.60 2.119 4.52 J.57 2.16 3.31 6.26 3.32 , , 0 13.42 IJ.119 I 3. 711 12.61 13.116 I 3. 72 I 1. 11 12. 16 HNO 0. 30 0.113 0.37 0.31 o. 37 0.11 0.11 0.09 f1CO I 3. I 7 111.25 13.61 14.14 111. 911 11.116 12. 19 13.56 CAO 11 .90 12.011 12.88 12.62 12.77 11.87 12.28 11.86 0110 0.0 0.0 0.0 0.0 o.o 0.23 o. 11 0.21 N/120 o. 39 0.23 0.46 0.25 0.26 0.03 0.0 0. 36 k20 0.25 0.19 0.211 0.83 0.12 0.211 0.21 0.0 r u.o 0.0 o.o o.o o.o o.o 0.0 0.0 C:I O.CI 0.0 0.0 0.0 0.0 0.0 0.0 o.o 1170 o.o 0.0 o.o o.o 0.0 0.0 o.o 0.0 SlJH 95.21 96. 10 96.59 91.16 98.21 97. 111 97.61 96.51 -o, f"+CI. o.o 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SlJH 95.21 96. 10 96.59 97.76 98.21 97. Ill 97.61 96.53

SI 7. 11311 . 1. 11111 . 7 .456 • 7.695 . 7. 738 . 7 .8311 • 7.69 11 • 7.858 • Ill II. '.,66 8.00() 0.256 8.000 0.5114 8.000 o. 305 8.000 0.262 8.000 0. 166 8.000 0. J06 8.000 0. 1112 8.000 Ill 0.416 . 0. 175 • 0.242 • 0.303 • o. 138 • 0.403 . o. 7115 • 0.425 • 11 0.027 • 0.039 • 0.026 • 0.015 • 0.018 • 0.008 • 0.005 . 0.020 • 1£ I. 670 . 1.660 • 1.695 • 1. 523 • 1.620 • 1.662 . 1.395 • I. 5111 • N HN 0.038 • 0.0511 . 0.046 • 0.038 • 0.0115 • 0.013 . 0. 013 • 0.011 • 00 HG 7.921 5.011 3. 125 5.053 2.993 5.001 3.043 4.922 3.205 5.027 2.906 4.992 2. 715 11.873 2.931 11.934 Vl C/1 I .897 . 1.898 • 2.036 • 1.952 • 1.969 • 1.842 • 1.8711 • 1.843 • NA 0. I 13 . 0.066 . 0. 132 • 0.070 • 0.073 • 0.008 • 0.0 . 0.101 • I( 0.0111 • 0.036 . 0.045 • o. 153 • 0.022 • 0.01,4 • 0.038 • 0.0 • BA o.o 2.057 o.o 1.999 0.0 2.213 0.0 2. 175 o.o 2.0611 0.013 1.908 0.009 1.921 0.012 I .956 CL 0.0 . 0.0 . 0.0 . 0.0 . 0.0 • 0.0 . 0.0 • 0.0 . r ll.O • o.o • 0.0 • 0.0 • 0.0 • 0.0 • o.o • 0.0 • II o.o 0.0 o.o 0.0 0.0 o.o 0.0 o.o o.o o.o 0.0 o.o 0.0 0.0 0.0 0.0 0 23.000 . 23. 000 • 23.000 • 23.000 • 23.000 • 23. 000 • 23.000 • 21.000 •

CIIA "9. 07 28. 11 J0.07 29. 78 28. 79 28.68 JI .25 29. 10 ANT 411. 76 116. 39 411.21 116.112 46.86 45.211 115.27 46.29 GIIU 26. 17 25.411 25.72 23.80 24.35 26.08 23.48 211.61

f/H 0.585 0.5118 0.582 0.513 0.520 0. 571 0.519 0.532 f/FH o. 369 0. 354 0.368 O.J39 o. 342 0.366 0. 341 0. 3117

9 PORA 13 A 10 POR/1 111 NCW AHP I I All[GIN 15 A 12 II 16 A

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SIIHl'U 47 IIHPttlBOLE ANALYSES 17 18 19 20 21 22 2J 24

5107. 55. 15 5J. 611 50.99 50.88 51.22 52.81 54.114 51. 17 1102 ll.05 0.11 0.26 0.26 0.211 0.24 0.116 0.02 11?.0J 2. JO 2.91 3. 7l 11.06 3.86 l. 51 4. 54 2.49 110 12.56 14.06 111. 111 111.18 13. 83 13.68 14 .82 12.55 HNO 0.10 0.08 0.]8 o. 36 0.37 o. 31 . 0.114 0.19 HGO 111. 06 12.68 12.88 1 ].611 13.56 13.611 14.38 12.81 CIIO 12. 3] 12.29 11.91 12.05 12.07 12.24 12.55 11.93 RAO 0.20 0.27 0.02 0.04 0.06 0.06 0.15 -0.0] Nll?O 0.01 11.02 0.111 0.411 0.58 0.26 0.41 o. 10 K20 0. 11 0. 13 11.28 0.28 0.26 0.22 0. 37 0.07 r o.o 0.0 0.06 0.12 o. 13 0.01 0.05 -0.02 CL 0.0 0.0 0.0 0.01 0.0 0.00 0.00 -o.oo 1120 0.0 0.0 -0.03 -0.06 -0.06 -0.01 -0.0l 0.01 SUH 96.87 96.25 95.03 96.26 96. 12 96.911 102.59 91.29 -o- f+Cl 0.0 o.o 0.03 0.05 0.05 0.01 0.02 -0.01 SUH 96.87 96.25 95.01 96.21 96.06 96,9] 102.56 91. 30

SI 7.960 • 1.868 . 7 .628 • 7.523 . 7. 571 • 7.701 • 7 .5112 • 1.818 • Al. 0.01,0 8.000 0. 132 8.000 o. 3 72 8.000 0.477 8.000 0.1129 8.000 0.299 8.000 0.458 8.000 0.122 8.000 Al 0. 351 . o. 382 • 0.285 • 0.2]0 • 0.211] • 0. 305 . 0.28] . 0. 329 . T 1 0.005 • 0.012 . 0.029 . 0.029 • 0.027 • 0.027 • 0.0118 • 0.003 • rr 1.516 • 1. 725 • 1. 769 • I. 75] • 1.710 • 1.668 • I. 716 • 1.615 • HN 0.012 • 0.010 • 0.0118 • 0.045 • 0.046 • 0.039 • 0.051 . 0.0211 • N HG J.025 4.909 2. 772 4.901 2.872 5.003 3.006 5.064 2,987 5.013 2.955 4.994 2.970 5.068 2.9111) 11.911 (X)

CA I. 907 . I. 932 • 1.909 • 1. 909 • 1.911 • 1.912 · • 1.862 • 1. 968 • °' NA 0.003 . 0.006 . 0.119 • 0.126 • 0.166 . 0.073 • 0.111 . 0.031 . K 0.020 . 0.024 . 0.05] . 0.053 • 0.049 • 0.041 • 0.066 • 0.0111 . RA 0.011. 1.941 0.016 1.977 0.001 2.082 0.002 2.090 0.00] 2. 130 11.003 2.030 0.008 2.0111 -0.002 2.011 Cl 0.0 • o.o • 0.0 • 0.003 • 0.0 • 0.000 • 0.001 • -0.000 • r o.o • 0.0 • 0.028 • 0.056 • 0.061 • 0.007 . 0.023 • -0.011 . II 0.0 0.0 0.0 0.0 -0.028 o.o -0.059 0.0 -0.061 o.o -0.007 0.0 -0.021, 0.0 0.012 0.0 0 2J .000 • 2] .ooo • 23,000 • 23.000 • 2],000 • 2].000 • 2].000 • 23.000 •

CAA 29.52 30.00 28.93 28.113 28.72 29.09 28.22 J0.06 ANT 116.82 4].06 4],5] 1111. 78 114.89 114.95 115.00 1111.90 GttU 23.66 26.94 27.511 26. 79 26. ]9 25.96 26.79 25.04

r/H 0.505 0.626 0.6]] 0.598 0.588 0.578 0.595 0.558 f/fH 0.336 o. ]85 0.388 0.374 0.370 o. 366 0. 37] 0.358

17 II 21 47 AMP 18 II 22 AV£RIIGE 19 NEWO IIHP 23 AVERAGE Pl.US SIGH/I 20 117 AMP 24 AVERAGE HINUS SIGMA

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SAHr1r 41 E PI DOTE ANALYSES ( Ott CAL CULA I £0) 1 2 3 1, 5 6 1 8

Sl02 38. 35 38.02 J1. 85 39.51 39.03 38.52 38.83 38.06 f IO? o. 18 0.40 0. 12 0.28 o. 17 0. 36 0. 12 0.01 h203 21.1,5 24.)5 25.94 26.06 28. 16 23.93 26.76 26.85 I ;>O] 5. 18 8.86 7. 58 7.74 5.51 9.81 6.92 6. 16 ~lNO 0.111 0.05 0.05 0.06 0. 12 0.06 0. 32 0. 12 m;o II. 1J 0.18 0.02 0. 12 0.14 o. 12 U.03 0. 12 C/\0 ?3. 73 23.45 2).20 23.95 23.98 23.80 211. 1J 24.50 Jl/\0 0.0 0.0 0.0 0.0 0.0 o.o 0.0 o.o N/\20 o.o~ 0.06 0. 18 0.03 0.03 0.08 0.02 0.06 K?O ll. O?. 0.02 0.10 0.08 0.02 0.02 0.02 0.02 f 0.0 0.0 0.0 o.o 0.0 0.0 0.0 0.0 Cl 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 1170 1.88 1.86 1.86 1.92 1.92 1.88 1. 91 1.88 SUH 91. 11 97 .25 96.90 99.75 99.08 98.58 99.06 97 .84 -0= r+Cl o.o 0.0 0.0 0.0 o.o o.o o.o o.o SUH 91. 11 91. 25 96.90 99.75 99.08 98.58 99.06 97.84

SI 3.0511 . 3.062 . ] .011] • 3.082 • J.042 • 3.071 . ].01,9 • 3.025 • I\L. 0.0 3.050 o.o 3.062 o.o 3.043 0.0 3.082 0.0 3.042 0.0 3.071 0.0 3.049 0.0 3.025 l\l 2. 573 . 2.311 . 2.1158 • 2. 396 • 2.586 • 2.248 • 2.476 . 2.515 . 11 0.01 l . 0.021, . O.OU7 • 0.016 • 0.010 . 0.022 • 0.001 • 0.004 • HG 0.015 . 0.022 . 0.002 . 0.014 • 0.016 • 0.014 • 0.001, . 0.014 • N 1£3+ 0. 310 • o. 537 • 0.1159 . 0.4511 • 0. 323 . o. 589 . 0.409 . o. 368 • CX)

HN 0.009 2.918 0.003 2.897 0.003 2.929 0.004 2.884 0.008 2.9411 0.004 2.877 0.021 2.917 0.008 2.910 -..J

CA 2.072 • 2.024 • 1.999 . 2.002 • 2.003 • 2.0ll • 2.030 • 2.087 • K 0.002 • 0.002 . 0.010 • 0.008 • 0.002 • 0.002 • 0.002 • 0.002 • NA 0.008 • 0.009 . 0.028 • 0.005 • 0.005 • 0.012 • 0.003 . 0.009 • Ill\ 0.0 2.032 0.0 2.035 o.o 2.037 0.0 2.014 0.0 2.009 0.0 2.0111 0.0 2.035 0.0 2.098 Cl. o.o . o.o . o.o • 0.0 • o.o • 0.0 . o.o • o.o . r 0.0 0.0 0.0 0.0 0.0 0.0 o.o o.o 0.0 o.o 0.0 0.0 0.0 0.0 0.0 o.o It 1.000 1.000 I .000 I .000 I .000 1.000 1.000 1.000 1.000 1.000 I .000 1.000 I .000 I .000 I .000 I .000 0 ll .000 . 13 .ooo . 13 .ooo • 13 .ooo • 13.000 • 13.000 • 13 .ooo • 13.000 •

PS 111. 72 18.83 15. 71 15.92 I I .08 20. 12 14 .07 12. 74 CZ 88.95 81 .05 84. 18 83.94 88.65 79. 14 85.20 86.98 PD 0. 33 o. 12 0.12 0. 14 0.27 o. 14 o. 73 0.28

I [PIO 5 E 2 EPIO 6 E 3 E 7 E " [ 8 E

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Slll11'lr 117 [PIDOI[ ANALYS[S (OH CIILCUlATEOI ? 10 11 12 13 111 1~ 16

SI02 3,. 61) 39. 111 38.55 39.01 39. 71 38.611 3?. 71 111 .08 1107 0.08 0. 21 II.OR o. 10 0.15 0.11 0. 10 0.08 1120) ?.8. 7U 211. l 1 26. 311 211.116 26.60 26.09 ?11. 70 26. 12 f?Ol ~. IR 7 .115 1,. 71 6.119 5.61 5.92 R.21 6. 36 mw U.29 u. 15 0.08 0. 17 0.22 0.10 0. 10 o. 11 MGO t). 0 I 0.20 0.22 0.0 0.116 u.u o. 111 0.06 CAO 23.81 211. 13 211.113 211.37 211. 19 23.90 23.111 ? 1. 78 11110 o.o o.o 0.0 0.0 0.0 0.0 0.29 0.1111 NA20 o. 19 O.IJ o.o o.o 0.03 0.02 0.0 0.0 K20 11.01 0.02 0.02 0.01 0.01 0.03 0.02 0.68 r 0.0 0.0 o.o 0.0 o.o o.o 0.0 0.0 Cl 0.0 o.o 0.0 0.0 0.0 0.0 o.o 0.0 1170 1. 90 1.87 1. 87 1.86 1.92 1. 87 1.89 1.91 SUH 9/1.113 91.1111 96. JO 96.53 98.90 96.68 98.36 98.62 •O= f+CL 0.0 0.0 0.0 o.o 0.0 0.0 o.o 0.0 SUH 98.11] 97 .1111 96.JO 96.53 98.90 96.68 98. 36 98.62

SI 2.963 . J. 129 • J.U95 . J. 1118 • 3. 106 • J.096 . J. 1119 . J.2111 • Al 0.031 3.000 0.0 J. 129 o.o 3.095 0.0 J. 1118 0.0 J. 106 o.o J.096 0.0 J. 1119 0.0 3.2111 Al ?. . 62 7 • 2.292 . 2.1192 . 2.323 • 2.1151 • 2.11611 . 2. 305 • 2.1108 • 11 0.005 • 0.013 • 0.005 . 0.006 • 0.009 • 0.007 . 0.006 • 0.005 . HG 0.008 . 0.0211 . 0.026 • o.o • 0.0511 • o.o • 0.017 . 0.007 . N f[3+ o. 3113 . 0.11119 . 0.285 • o. 3911 • 0.330 • 0. 357 • 0.1189 • 0.3711 . CX)

11N 0.019 3.002 0.010 2. 788 0.005 2.813 0.012 2. 7311 0.015 2.858 0.007 2.8)11 0.007 2.823 0.001 2.802 CX)

CA 2.010 • 2.069 • 2. 101 • 2.1011 • 2.027 • 2.052 • 1. 963 • 1.826 • ~ 0.001 . 0.002 • 0.002 • 0.001 • 0.001 • 0.003 . 0.00? . 0.068 • NA 0.029 . o.o • 0.0 • 0.0 • 0.005 . 0.003 . 0.0 . 0.0 • BA 0.0 2.0110 o.u 2.071 u.o 2. 1011 0.0 2.105 o.o 2.032 o.u 2.058 0.009 1.974 0.013 1.907 Cl 0.0 • 0.0 • 0.0 . 0.0 • 0.0 • 0.0 • 0.0 • 0.0 . r 0.0 0.0 0.0 0.0 0.0 o.o o.o o.o 0.0 0.0 o.o 0.0 0.0 0.0 0.0 o.o H 1.000 1.000 1.000 1.000 1.000 1.000 1.000 1.000 1.000 1.000 1.000 1.000 1.000 1.000 1.000 1.000 0 13. 000 . 13 .000 • 13.000 • 13.000 • 13.000 • 13.000 . 13.000 . 13.000 •

PS 11. 32 16. 31 10.23 111. 43 11. 81 12.63 17 .117 13.112 CZ 88.011 83. 32 89.58 85. 15 87 .67 87. 13 82.29 86. 32 PD 0.611 o. 37 0.20 0.43 0.52 0.211 0.211 0.26

9 [ 13 [ 10 E 111 E 11 [ 15 E 12 [ 16 E

Page 294: PETROGENESIS OF A MIGMATITE, PENOBSCOT ......petrogenesis of the Lucerne Pluton. Eriksson and Wones (1983) reported preliminary work on the petrogenesis of the Parks Pond Pluton. Cavalero

SAHrl.[ 41 [PIOOIC ANALYSCS (OIi CALCULAICD) 17 18 19 20

SI02 J9. 18 J8.81 J9. 70 J8.05 1102 0.08 0.16 0.26 0.06 A20] 25 . .,4 26.0J 21. 36 211. 11 120] 7.9J 6. 811 8. 19 5.118 m,o 0.05 o. 13 0.21 0.05 HGO 0. 12 o. 13 0.23 0.02 C:/\0 2?. 111 23.72 211. 39 23.05 IIAO 0.115 0.01 0.22 -0.08 NA20 0.(1 0.04 0.10 -0.0\ K70 O.OJ 0.01 0.22 -0.09 F o.o 0.0 0.0 0.0 Cl 0.0 0.0 o.o 0.0 11;,o 1.89 1.89 1. 97 1.81 SUH 98.21 97 .911 102.85 93.011 -Os F+CL 0.0 0.0 o.o o.o SUH 98.21 91.911 102. 85 93.04

SI ] . Ill'., . 3 .ue11 • 3 .019 • 3. 155 • Al 0.11 J. 105 0.0 J.084 o.o J.019 0.0 J. 155 Al 2 .111111 • 2.4)4 • 2.451 • 2.415 • N II 0.005 . 0.009 . 0.015 . 0.004 • (X) MG 0.014 . 0.015 • 0.026 • 0.002 • \() r[J+ 0.111) . 0.408 • 0.469 • 0. ]112 • HN 0.0l)J 2.899 0.009 2.875 0.013 2.974 0.004 2. 767 CA I. 911 . 2.016 • 1.981 • 2.0118 • K 0.003 . 0.001 . 0.021 • -0.009 • NA 11.0 . 0.001 . 0.015 . -0.002 • IIA o. n 111 1.9118 0.002 2.032 0.001 2.030 -0.003 2.034 Cl o.o . 0.0 • o.o • 0.0 • F u.o 0.0 0.0 0.0 o.o 0.0 o.o 0.0 II 1.000 1.000 1.000 1.000 1.000 1.000 1.000 1.000 0 11.000 • 13 .000 • 13.0IJO • 13.000 •

rs 16.42 14.32 15.97 12.40 C:l 83.46 85. 38 83.51 87. 41 PO 0.12 0. 30 0.46 o. 13

11 [ 19 AVERAGE PLUS SIGHA 18 AV[RAG[ 20 AVERAGE MINUS SIGMA

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The vita has been removed from the scanned document