perstorp - plasticizer for sensitive pvc applications
DESCRIPTION
"New Unique Plasticizer for Sensitive PVC Applications" was presented at PVC 2014 in Brighton,TRANSCRIPT
New Unique Plasticiser for Sensitive PVC Applications PVC 2014, Brighton
Perstorp contributes to a better more sustainable world by delivering innovative chemical solutions
Table of Contents Introduction to Perstorp
Perstorp in the PVC industry
Perstorp plasticisers
New Unique plasticiser – Pevalen™
Summary
Perstorp in brief World leader in several sectors of the specialty chemicals market
Pioneer in formalin chemistry, plastics and surface materials
Perstorp was formed in 1881, over 130 years of winning formulas
Since December 2005 controlled by PAI partners, a leading European private equity company
Annual turnover of more than 10 billion SEK in 2013
About 1,400 employees in 22 countries
Production plants in Europe, Asia and North America
Sales offices in all major markets
Perstorp in the PVC industry
Perstorp is a fully integrated plasticiser producer based on the west coast of Sweden since 1980’s
Perstorp exited the DOP business in 2012 Storage facilities in UK, Belgium, Germany and Portugal to serve
Europe Focus on European market and sustainable growth Member of ECPI, VinylPlus and founding member of PlasticiserPlus
Perstorp believes in plasticisers
Perstorp is making its largest investment in history
Based on our own technology and backwardly integrated in raw materials
It will be on stream in Q1 2015
Two plasticizers in the product tree, EmolteneTM 100 and PevalenTM
This investment will increase the production by 150 000 MT
EmolteneTM 100 PevalenTM Investment for a more
sustainable future
Versatile general PVC plasticiser
Established C10 (DPHP) GP plasticiser
Excellent versatility and flexibility
Expands lifespan of end products
High technical performance, with tough outdoor resistance
High performance polyolester plasticiser
Highly efficient in providing softness
Easy to process and use
Low volatility ensuring no VOC and consistent properties
New capacity for Valeraldehyde and its derivatives
Strengthen our production platform
Fully integrated an secure supply chain
Ability to offer competitive and safe products
Innovative plasticiser for sensitive applications
Flexible, versatile & safe
Emoltene™ 100 and Pevalen™ focus on different markets
Emoltene™ 100 - Durable applications
– Wire and cables – Films & sheets e.g. roofing membranes, pool
and pond liners – Coated fabrics; e.g. tarpaulins – Automotive interiors
Pevalen™ - Sensitive applications
– Coated fabrics; e.g. table cloths, protective clothing
– Films & sheets; e.g. office materials, furniture foils
– Flooring; e.g. public buildings, hospitals, domestic
– Plastisols; e.g. wall paper, toys – Moulded parts; e.g. grips, hoses
Pevalen ™ shows low intial viscosity Pevalen ™ has excellent viscosity stability
Plastisol Viscosity resin P15
0
2
4
6
8
10
12
14
2.5 202
hours
100 2.5 2024
hours
100 2.5 205
days
100
Pas
DINP
Pevalen™
Plastisol Viscosity resin P2170
0
2
4
6
8
10
12
2.5 202 hours
100 2.5 2024
hours
100 2.5 20 5days
100
Pas
DINP
Pevalen™
Pevalen ™ shows low intial viscosity Pevalen ™ has excellent viscosity stability
Pevalen ™ has faster gelation than other plasticiser
Rheology
1
10
100
1000
10000
100000
1000000
25 75 125 175
Elas
tic
Mod
ulus
G',
Pa
Temperature, C°
Pevalen™
DINP
DOTP
DINCH
Pevalen ™ yields PVC with lower hardness values
Pevalen ™ is a very efficient plasticiser
Hardness
68
70
72
74
76
78
80
82
P15- Pevalen™ P15- DINP P2170 - Pevalen™ P2170 - DINP
Shor
e A
Pevalen ™ yields softer films Strain is at high level with Pevalen ™
Tensile measurement PevalenTM
PVC quality
Stress at 100% strain (N/mm2)
Stress at 200% strain (N/mm2)
Stress at 300% strain (N/mm2)
Max stress (N/mm2)
Strain at break (%)
Pevikon P2170 8.0 (0.5) 13 (0.8) 17 (1.2) 24 (2.8) 440 (47) Pevikon P1412 7.3 (0.3) 11 (0.6) 15 (0.8) 21 (2.2) 430 (37) Vinnolit P70 7.1 (0.4) 11 (0.5) 15 (0.7) 21 (1.5) 440 (13) Solvin 367 NF 8.2 (1.0) 13 (1.6) 18 (2.4) 23 (4.8) 400 (79)
DINP PVC quality
Stress at 100% strain (N/mm2)
Stress at 200% strain (N/mm2)
Stress at 300% strain (N/mm2)
Max stress (N/mm2)
Strain at break (%)
Pevikon P2170 7.3 (0.2) 11 (0.3) 15 (0.5) 20 (2.3) 430 (69) Pevikon P1412 8.1 (0.5) 12 (0.8) 16 (1.1) 21 (2.3) 430 (37) Vinnolit P70 7.7 (0.3) 12 (0.4) 15 (0.6) 20 (0.9) 420 (28) Solvin 367 NF 8.8 (0.4) 13 (0.7) 18 (0.8) 26 (1.5) 480 (29)
Both plasticisers gives full transparency in resin P15 In resin P2170 Pevalen ™ has better compatibility
Clarity DINP PevalenTM
P15 P2170
Pevalen ™ yields film with less initial colour In P15 Pevalen ™ is equal in heat stability to DINP In P2170 Pevalen ™ is more sensitive to heat
Thermal stability
DINP
PevalenTM
P217
0 P1
5 DINP
PevalenTM
Pevalen™ is unaffected in the QUV environment
QUV
0
10
20
30
40
50
60
70
80
0 h 500 h 1000 h 1500 h
Yel
low
inde
x, Y
i DINP
DINCH
DOTP
Pevalen™
Pevalen ™ gives an unique combination of high plasticising efficiency and low volatility
Unique property combination
66
67
68
69
70
71
72
73
74
75
76
77
0 0,5 1 1,5 2 2,5
Har
dnes
s, S
hore
A
Volatility, %
DUP
PEVALEN™
DINCH
DOTP
TOTM
Pevalen ™ gives good fogging properties
Fogging
0
0,5
1
1,5
2
2,5
3
0
10
20
30
40
50
60
70
80
90
TOTM PEVALEN™ DINCH DOTP
Ref
lect
omet
ric,
%
Gra
vim
etri
c, m
g
Summary
Perstorp is a reliable supplier of Emoltene™ 100, the major type of plasticiser for wire & cable, film & sheets and automotive interior
Perstorp is an innovative company developing a polyol ester plasticiser - Pevalen™
Pevalen™ has a good compromise on shelf life and ease of fusion
Pevalen™ retains the visual appearance by improved clarity and low yellowing
Pevalen™ has a unique combination of high efficiency and low volatility
The low volatility is reflected in the good fogging values Pevalen™ brings
Acknowledgement
My very special thanks to INEOS Chlor Vinyls Vulcaflex S.p.A
Thank You for your attention!
Anders Magnusson Market Development Manager Don’t hesitate to contact me if you have any questions! [email protected] Perstorp Group