persiapan platinum_ruthenium ke padat polimer elektrolit membran dan aplikasi ke anoda dmfc

7/23/2019 Persiapan Platinum_Ruthenium Ke Padat Polimer Elektrolit Membran Dan Aplikasi Ke Anoda DMFC

1/12

UIJKBDBHF OIOM]@K

Wirsf`p`k Wd`tfkuoR]utlikfuo ji W`e`t Wbdfoir Idijtrbdft

Oiomr`k e`k @pdfj`sf ji @kbe` EONC

EFSYSYK BDIL 1

VYKF @FSV@L 1 73070573779

@O]FK@ ]BSV@E@ 1 73070573733

UIJKFJ JFOF@ J@OWYS W@DIOM@KH

YKF^I]SFU@S S]FXFA@V@

=703


2/12

Wirsf`p`k Wd`tfkuoR]utlikfuo ji W`e`t Wbdfoir Idijtrbdft

Oiomr`k e`k @pdfj`sf ji @kbe` EONC

K`bjb Nuafw`r` !$ J`zu`jf V`sue`$ Usutbou Fbrbf$ Qyuk Sfrbo`$ Vbslfkbrf

Ofy`z`jf

Efvfsf Jlusus Hriik Dfni Uijkbdbhf$ K`tfbk`d Fkstftuti bn @ev`kcie Fkeustrf

S`fks e`k Uijkbdbhf ,@FSU&$ 0/3/


3/12

pbdfoir idijtrbdft sid m`l`k m`j`r ,WINC&+ Simu`l oitbei jlusus y`ftu d`pfs`k

j`t`dfs p`k`s mirtij`k`k y`kh c`r` pirsfp`k piofs`l`kky` eikh`k pikhic`t`k$

pikyioprbt`k `tù tfkt` cit`j j`t`dfs y`kh oikh`keukh p`rtfjid j`t`dfs e`k

suspiksf pbdfoir idijtrbdft ji WIO + E`dò tudfs`k fkf$ jòf oikhò`tf idijtrbe`

lferbnfdfj eikh`k strujtur y`kh sò` sipirtf simiduoky` uktuj pbdfoir idijtrbdft

`fr idictrbdyzir$ e`rf tftfj efo`k` d`rut`k oit`kbd c`fr efp`sbj ji `kbe` e`dò

EONC tirsimut+

E`dò stuef simiduoky` $oitbei foprihk`sf/rieujsf ,F]& efjiom`khj`k

uktuj jbkt`j d`khsukh e`rf JIW e`k dbhò idijtrbe` y`kh mird`ju e`dò jbkefsf

m`s`l uktuj pbdfoir idijtrbdft `fr idictrbdyzir+ E`dò Oitbei F]$ oiomr`k

j`tfbk/tuj r eikh`k simu`l priixcl`khispisfis dbhò j`tfbkfj$ ofs`dky` ZWt

,KL3& 5_=*$ jiouef`k efrikeò e`dò d`rut`k rieujsf$ y`kh oikhur`khf e`k

oikhh`ktfj`k dbhò oikuau du`r pirouj``k oiomr`k+ Siou` prbsieur e`p`t

efd`juj`k ef m`w`l


4/12

oitbei rieujsf efjiom`khj`k bdil U`jik`j` e`k Ubrfj`f Z0 e`k d`rut`k jdbrfe` dbhò jieu`$ e`k pikhur`kh`kd`rut`k ,ofs+ K`ML5$

KL=KL=& eftiop`tj`k pè` o`sfkh/o`sfkh jieu` sfsf oiomr`k+ pirpèu`k

d`pfs`k Wt y`kh tirmiktuj pè` pirouj``k oiomr`k eikh`k piriomis`k rieujtbr

ji sfsf d`fk e`rf oiomr`k+ pèu`k ]u `tù Sk eikh`k Wt oikfkhj`tj`k `jtfvft`s

oit`kbd idijtrb/bjsfe`sf e`dò d`rut`k `sò sudn`t+

E`dò tudfs`k fkf$ idijtrbe` Wt]u$ y`kh s``t fkf efjik`d sim`h`f j`t`dfs

`kbe` y`kh p`dfkh `jtfn uktuj oit`kbd bjsfe`sf y`kh tirfj`t d`khsukh ji WIO

eikh`k oitbei F]+ Jioukhjfk`k e`rf `kbe` Wt]u efmu`t eikh`k oitbei F]

efsidfefjf eikh`k Bpir`sf EONC+

=+ Ijspirfoikt d

=+0+ Wirsf`p`k Wt]u ji JIW eikh`k oitbei F]

Hòm`r+ 0 è d`l riprisikt sf sjio`tfs e`rf oitbei F] uktuj pd tfkh

d`khsukh Wt]u ji oiomr`k K`nfbk+ Wiou`t`k Wt]u efd`juj`k pè` K`nfbk 008

pèu`k ,Eu Wbkt&$ y`kh oirup`j`k pirndubrbj`rmbk jl`s `sò sudnbk`t

c`tfbkixcl`khi oiomr`k eikh`k j`p`sft`s pirtuj`r`k fbk e`rf 7$676 x 07/3

iq+ h/0

e`k jitim`d`k 07

bC sidò` 9 aò uktuj

oikhike`pj`k Wt]u ,Hòm`r 0 ,ff&& pè` pirouj``k oiomr`k K`nfbk+ Sitid`l

eftri toikt pè` 0 O d`rut LCd `q e`k `fr sudfkh pè`


5/12

oikiktuj`k auod`l o`suj`k Wt e`k ]u jbopdijs e`dò oiomr`k+ @k`dfsfs FCW

auh` efd`juj`k uktuj oiopirbdil jbksiktr`sf Wt e`k ]u tiridusf e`dò

pikhur`kh`k `tù d`rut`k LCd+ Jbopbsfsf jfof` e`k piou`t`k auod`l Wt]u

e`d o pirsf`p`k jbopbsft eflftukh eikh`k oikhur khj`k auod`l idutfkh ef

d`khj`l pikhur`kh`k e`k tri`toikt LCd e`rf fkcbrpbr`tie auod`l e`dò d`khj`l

pirtuj`r`k fbk+

Hòm`r+0+

Sjio` riprisikt`sf e`rf jbopbsft Wt]u/WIO efmu`t eikh`k oitbei F]1

,f& d`khj`l pirtuj`r`k fbk$

,ff& d`khj`l pikhur`kh`k+

=+3+ Wirsf`p`k uktuj OI@ EONC

Wt]u efike`pj`k l`ky` pè` s`tu sfsf e`rf simu`l oiomr`k K`nfbk

eikh`k oitbei F] y`kh sò` efaid`sj`k ef `t`s e`k ef`pdfj`sfj`k ji `kbe` e`dò

EONC `+ Efd fk pfl`j$ t`k`p eujukh`k Wt lft o,e`rf Ablksbk2 " O`ttliy$

spisfnfj pirouj``k `ri` =8 o= h2 0& efhuk`j`k sim`h`f j`tbe` j`t`dfs+ mumuj

lftò Wt è`d`l pbdftitr`ndubrbitfdik` ,WUNI&/tirfj`t ,8 mir`t+)& efcòpur eikh`k

WUNI efspirsf e`k efliktfj`k pè` 9 ) mir`t+ ) d`rut`k K`nfbk ,@derfcl& uktuj

oiopirsf`pj`k tfkt` j`t dfs+ tfkt` j`t dfs fkf tirsim r ji WUNI jbsbkh uktuj


6/12

oiomiktuj 5 oh co/= mim`k e`rf Wt+ OI@ efsusuk bdil tr`ksnir eic`d Z=>$=8_

e`rf d`pfs`k j`t`dfs jisimir`kh d`pfs`k jbopbsft Wt]u /K`nfbk ftu+

=+5+ Iv`du`sf jfkira` EONC

Uli OI@ è`d`l p`k`s mirtij`k`k `kt`r` j`fk j`rmbk pikhuopud `rus

e`k efr`jft e`dò 07 co= tukhh`d sid+ D`rut`k oit`kbd ikcir ,0$7 O& efsòp`fj`k

ji `kbe` pè` 5 od ofk/0$ sie`khj`k bjsfhik y`kh tid`l efdiom`mj`k$ efjfrfo ji

j tbe` ,377 od ofk/0&+ Jurv` tih`kh`k currikt ,F/^& efpirbdil eikh`k

oikhhuk`j`k `rus hikir`tbr puds` ,Lbjutb Eikjb LC/005& e`k efhft`d

oudtfoitir+

3+ L`sfd e`k Efsjusf

3+0+ Wiomu`t`k e`k J`r`jtirfs`sf K`nfbk/Wt]u Jbopbsft

U`mid 0 oir`khjuo siauod`l eipbsft Wt]u e`k jbopbsfsf d`pfs`k Wt]u ef

K`nfb/ Wt]u jbopbsft efmu`t eikh`k oitbei F]+ Stbfjfboitrf efo`sujj`k

siauod`l ZWt ,KL3& 5_=* e`k Z]uCd ,KL3& 9_

=* eflftukh oikaèf 9$< x 07/> obd co/

=+ @k`dfsfs FCW oikukaujj`k m`lw` auod`l tibrftfs Wt e`k ]u d`khj`l prijursbr

y`kh efsir`p ef fbkixcl`khi fkf e`k dimfl e`rf


7/12

K`

ouk$ e`dò m`ky`j j`sus$ d`pfs`k pirtò`$ y`kh pirtò` j`df efsfop`k eikh`k


8/12

oitbei F]$ tirtutup eikh`k d`pfs`k dbhò jieu` bdil idijtrb/`tù idictrbdiss

pd`tfkh+ ]u `tù Fr efsfop`k sim`h`f dbhò jieu` efjik`d oikaèf `jtfn uktuj

ivbdusf bjsfhik e`dò pikidftf`k simiduoky`+ Mirtikt`kh`k eikh`k l`d fkf$ cb/

efsfop`k pèu`k Wt]u `tù Wt]u ef`khh`p sisu`f uktuj bjsfe`sf oit kbd

Z=$=3$=9_+ Wbd` \]E e`rf d`pfs`k Wt]u mirm`h`f Jbopbsft K`nfbk/Wt]u

eftukaujj`k pè` Hòm`r+ =+

Wbd` Wt d`pfs`k ,`& oikòpfdj`k ,000&$ ,=77&$ ,==7&$ ,300& e`k ,===&

rindijsf j`r`jtirfstfj wà`l mirpus`t jumfj ,Ncc& strujtur jrfst`d+ Wbd` ]u ,h&

sisu`f eikh`k y`kh ,077&$ ,070&$ ,007&$ ,073&$ e`k ,=70& rindijsf j`r`jtirfstfj

y`kh lijs`hbk d/pè`t ,lcp& jrfst d strujtur+ Wbd pukc`j jbopbsft eikh`k

jur`kh e`rf 38) ]u jbktik ,m$ c e`k e& y`kh ofrfp eikh`k Wt ourkf$ oisjfpuk

jbopbkik pukc`j y`kh efpirdu`s e`k mirhisir ji sfsf sueut mis`r efm`kefkhj`k

eikh`k oirij` y`kh Wt ourkf + Fkf mir`rtf pikhh`mukh`k ]u ji strujtur ncc+ Ef

sfsf d`fk$ ,070& pukc`j ]u lcp ftu tuop`kh tfkefl eikh`k ncc e`dò pbd` y`kh

jbopbsft eikh`k dimfl e`rf 9>) ]u jbktik ,i$n&$ oikukaujj`k còpur`k ncc e`k

lcp Wt]u n`si pèu`k+ L`sfd y`kh sò` efd`pbrj`k uktuj efeujukh pèu`k Wt]u

idictrbc`t dysts efsf`pj`k bdil musur oikc`fr Z37_ `tù eijbopbsfsf tiro`d

L=WtCd> e`k ]uCd3 Z30_+

Hòm`r+ 3 oikukaujj`k pikòp`kh oidfkt kh e`rf jbopbsft ,K`nfbk

Wt7+80]u7+=6& efpirbdil eikh`k SIO+ Oit`ddfc Wt `tù Wrbnfd jbksiktr`sf ]u


9/12

oidfkt`sf oiomr`k ef`k`dfsfs bdil IES efw`jfdf bdil aia`j y`kh dimfl rike`l+nbtb

fkf oikukaujj`k m`lw` jieu` Wt e`k p`rtfjid ]u sidijtfn efsfop`k eij`t

pirouj``k oiomr`k uktuj oiomiktuj 3/ 5 oo d`pfs`k tim`d+ Efstrfmusf Ofrfp

Wt]u efò`tf uktuj siou` jbopbsft y`kh tirc`ktuo e`dò U`mid 0+

Simu`l pikidftf`k simiduoky` tid`l oikidftf sipirtf efstrfmusf p`rtfjid

dbhò$ e`dò l`d oij`kfsoi pirtuj`r`k fbk e`k prbsis prisfpft`sf e`dò oitbei

F] + Wikyusuk`k K`nfbk Z33$35_ `tù jbopbsft @u /K`nfbk tid`l efhuk`j`k

sim`h`f cbktbl e`dò dftir`tur+ Jitfj` piroi`sf su`tu z`t pirieujsf aùl dimfl

cip`t e`rfpè` efnusf jbopdijs dbhò$ p`rtfjid dbhò y`kh efsfop`k ef e`dò

oiomr`k+ Sim`dfjky`$ afj` efnusf jbopdijs dbhò aùl dimfl cip`t e`rfpè`

piriomis`k rieujtbr$ p`rtfjid dbhò `j`k oikhike`p e`dò d`rut`k+ Bdil j`rik`

ftu$ mirpfjfr m`lw` pikhike`p`k sidijtfn Wt]u pè` pirouj``k efl`sfdj`k e`rf

efnusf sisu`f sifom`kh tfkhj`t jbopdijs prijursbr e`k z`t pirieujsf+

3+=+ Jfkira` EONC

Oitbei F] efd`juj`k l`ky` pè` s`tu sfsf Oiomr`k K`nfbk uktuj eipbsft

0$> oh co/=pèu`k Wt]u+ Jfkira` EONCs efiv`du`sf eikh`k Wt]u ,0$> oh co/=&

efsfop`k eikh`k oitbei F] sim`h`f `kbe` e`k Wt ,5+7 oh co /=& sim`h f j`tbe`+

Hòm`r+ 5 e`k 9 oiom`kefkhj`k jfkira` sid eikh`k mirm`h`f jbopbsfsf Wt]u ,Wt

Ourkf$ Wt7+8]u7+3$ Wt7+9]u7+9$ Wt7+3]u7+8& sim`h f Hòm`r+ 3+ SIO nbtb

jbopbsft dfkt`s/m`hf`k y`kh efsf`pj`k bdil Oitbei F]+


10/12

Uih`kh`k sid ,m`fj tih`kh`k r`khj`f`k tirmuj` e`k pè` jipè`t`k `rus

tfkhhf& sic`r` sfhkfnfj`k eftfkhj`tj`k pè` `kbe` Wt]u$ efm`kefkhj`k eikh`k Wt

ourkf `kbe` 57/0=7bC+ Wirmie``k e`dò sid tih`kh`k oikfkhj t eikh`k

oikfkhj`tky` sulu+ Sij`r`kh mirpfjfr m`lw` `jtfvft s ]u oikuau efsbsf tfn

èsbrpsf oit kbd oikfkhj`t pè` sulu tfkhhf Z3>_+ Wirm`kefkh`k `jtfvft`s

idijtrbj`t dftfj e`rf jbopbsfsf y`kh mirmie` e`rf pèu`k Wt]u dimfl ruoft+

Wt7+8]u7+3 oid`juj`k `jtfvft`s tirm`fj pè` r`p`t `rus tfkhhf ef jieu` >7 e`k

0=7b C$oisjfpuk sid tih`kh`k pè` r`p`t `rus rike`l ef m`w`l 7$7= @ co/=

oikfkhj`t ef urut`k Wt7+8]u7+3M " Wt7+3]u7+8M"Wt7+9]u7+9+ E`dò jim`ky`j`k

stuef$ pèu`k y`kh Wt]u eikh`k r`sfb 010 obd r efhuk`j`k sim`h`f

idictrbc`t`dysts pr`jtfs uktuj `kbe` EONC+ Kòuk$ e`dò j`sus Wt]u efmu`t

eikh`k oitbei F]$ r`sfb obd`r 78173 oikukaujj`k `jtfvft`s idijtrbj`t`dftfj

bptfouo uktuj oit`kbd bjsfe`sf$ y`kh jbksfstik eikh`k l`sfd pè` pèu`k Wt]u

tirstrujtur eikh`k m`fj efsf`pj`k bdil `rcoidtfkh+


11/12

Hòm`r+ > e`k 8 oikukaujj`k Jurv` " ^ uktuj OI@ eikh`k Wt7+8 ]u7+3 ,Wt/ ]u ?

81 3 e`dò r`sfb obd`r& `kbe` efsf`pj`k eikh`k oitbei F]+ Auod`l piou`t`k

Wt]u è`d`l 0$>$ 3$= e`k 5$< oh co/= sisu`f eikh`k s`tu$ eu` e`k tfh`

pikhud`kh`k e`rf o`sfkh/o`sfkh oitbei F]+

Oisjfpuk pikfkhj`t k Wt]u piou`t k e`rf 0$> sòp`f 3$= oh co/=

oikfkhj`tj`k tih`kh`k sid$ 5$< oh co=piou`t`k Wt]u oiofdfjf inij sim`dfjky`+

Jioirbsbt`k pè` tih`kh`k sid eikh`k `kbe` tirtfkhhf oiofdfjf Wt]u piou`t`kaùl dimfl oikbkabd ef 0=7bC+ d`pfs`k dbhò jieu` `tù jitfh` efsf`pj`k bdil

oitbei F] mirud kh y`kh du`s oikyim`r ji oiomr`k$ j`rik` pikhur kh`k

prijursbr dbhò oikyim`r e`rf e`dò oiomr`k tiraèf j`t`dftfs pè` l`rf pirtò`

d`pfs`k dbhò+

Jicikeirukh`k fkf oikukaujj`k m`lw` p`rtfjid Wt]u idijtrfj tirfsbd`sf

e`rf idijtrbe` è` ef j`dfj`k mird`pfs Wt]u d`pfs`k+ Bdil j`rik` ftu$ Wt]u

efsfop`k ef e`dò oiomr`k K`nfbk muruj oid`juj`k tfh` nukhsf jbkeujtfvft`s

prbtbk$ jbkeujtfvft`s dfstrfj$ e`k `jsisfmfdft`s m`l`k m`j`r+ Sid`fk oikurukj`k

pio`kn``t`k j`t`dfs$ efpirjfr`j`k mir`jfm`t n`t`d j`rik` d`pfs`k `kbe` tim`d

oikhlòm`t pidip`s`k mirjiom`kh CB=$ tirutò` e`dò bpir`sf pè` sulu

tfkhhf `tù eiksft`s `rus y`kh dimfl tfkhhf+

Jipè`t`k e`y` o`jsfouo è`d`l 7$05 X co/= simis`r 7$> co/= eikh`k

Wt7+8]u7+3 `kbe` ef EONC+ Jfkira` efpirbdil e`dò pikidftf`k fkf tfe`j

oikc`p`f tfkhj`t tirtfkhhf Z6$3


12/12

Wt]u k`kbp`rtfjid tirsim`r ef j`rmbk lftò+ Kòuk$ obrnbdbhf y`kh

efsuom`khj`k Wt]u efmu`t eikh`k oitbei F] oukhjfk efbptfo`dj`k$ e`dò l`d

piofdfl`k jbopdijs prijursbr e`k `hik pikhur`kh`k$ jbksiktr`sf e`k tiopir`tur

e`dò d`rut`k rieujsf$ pritri`toikt oiomr`k$ e`k d`fk+d`fk+

M`ru/m`ru fkf$ m`ky`j pikidftf`k tid`l efd`juj`k pè` pikhiom`kh`k

WIOs m`ru uktuj oikc`p`f jbkeujtfvft`s prbtbk tfkhhf$ piroi`mfdft`s oit`kbd

rike`l e`k mf y` rike`lvZ57_+ Oisjfpuk jist`mfd`k jfof` oirij` rikel$

oiomr ki mirm`sfs lferbj`rmbk tid`l oik`rfj jlususky` uktuj pio`kn``t`k

pè` sulu rike`l$ j`rik` oirij` oue`l efsfktisfs pè` l`rh` rike`l

efm`kefkhj`k eikh`k efjboirsf`dfs sfj`k pbdfoir pirndubrfk tie ,ofs+ K`nfbk$

Ndiofbk$ @cfpdix&+ Sid`fk ftu$ simu`l o`j`d`l m`ru oikhusudj`k eis`fk tumud`r

uktuj WINC e`dò r`khj` oikhbptfo`dj`k `jsis ue`r` ji j`tbe` + Oitbei F]

l`rus pir`d`t`k y`kh òpul uktuj oikir`pj`k m`l`k pbdfoir idijtrbdft eikh`k

p`k`s/risfstiksf `tù mirm`h`f miktuj ofsjfk ji WINC sfstio+

5+ Jisfopud`k

E`dò j`ry` fkf$ pèu`k Wt]u mirl`sfd efsfop`k d`khsukh pè` WIO eikh`k

oitbei F] oikhhuk`j`k ZWt ,KL3& 5_ = e`k Z]uCd ,KL3& 9_ =* eikh`k K`ML 5$

sim`h`f prijursbr Wt]u e`k rieujtbr$ o`sfkh/o`sfkh+ Mirpbrf e`k lferbnfdfj Wt]u

d`pfs`k sic`r` sidijtfn tirmiktuj ef pirouj``k oiomr`k+ Jid`y`j`k OI@ eikh`k

efsf`pj`k Wt]u uktuj `kbe` EONC auh` eftukaujj`k+ Oisjfpuk du`s pirouj``k

`jtfn jicfd e`rf d`pfs`k Wt]u$ EONC eikh`k 3$= oh co = Wt]u ,Wt1 ]u ? 78173

r`sfb obd`r& `kbe` efpòirj`k jipè`t`k jiju`t`k 7$05 X co= mirbpir`sf pè`

0=77

C e`k 7$3 OW`+ Jòf oikhusudj`k oitbei F]$ y`kh e`p`t efd`juj`k eikh`k

jbkefsf m`s`l pè` sulu rike`l$ sim`h`f pirsf`p`k oitbei uktuj `kbe` EONC+

persiapan platinum_ruthenium ke padat polimer elektrolit membran dan aplikasi ke anoda dmfc

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