partial report - rawan
TRANSCRIPT
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8/11/2019 Partial Report - Rawan
1/23
Grasim Cement, Raipu r
India
Pro ject No: 10-31017
Case No : 20100035
2010-05-14
Partial Report
FLSmidth A/S
R&D Centre DaniaDaniavej 49DK-9550 Mariager, DenmarkTel + 45 3618 1000Fax + 45 3618 [email protected]
FLSmidth Private Limited
R&D Centre Chennai34 Egattur, KelambakkamTamil Nadu 603103, IndiaTel +91 44 4748 1000Fax +91 44 2747 0301R&[email protected]
LABORATORY REPORT
mailto:[email protected]:[email protected] -
8/11/2019 Partial Report - Rawan
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Grasim Cement, RaipurIndia
Case No: 20100035 2010-05-14 Page 1 of 1
LABORATORY REPORTOrdered by: DKS-INCopies to : BLO-IN, SNE-IN, SSA-IN
SAMPLE DESCRIPTION
SAMPLE NAME SAMPLE NUMBER WEIGHT, KG DATE RECEIVED
Limestone 01 1500 2010-01-29
Clay 02 500 2010-01-29
Shale 03 425 2010-01-29
Iron Ore 04 150 2010-01-29
Coal Grade B 05 25 2010-01-29
Coal Grade C 06 25 2010-01-29
Pet Coke 07 25 2010-02-09
Fly Ash 10 60 2010-03-09
Clinker 11 600 2010-03-09
Gypsum 12 35 2010-03-09
Slag 13 150 2010-03-09
CONTENTS OF REPORT (ANALYSES / TESTS)
ENCL. NO. ITEM
1. Material Description2. Characterization of Materials
3. Analysis of Solid Fuel
4. Raw Mix Calculation
5. Burnability
6. Heat of Reaction
7. ATOX Vertical Roller Mill Test
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Grasim Cement, Raipur
IndiaEncl.: 1.1
Material Description - Sample as received
SAMPLE DESCRIPTION
ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
01 Limestone Limestone 20100035-01
INSPECTION
Received: 2010-02-12
Container: 5 Drum, steel
Weight, kg: 1500
COLOR
Munsell Color: Gray
Color Code: Gley1 6/N
BULK MATERIAL PROPERTIES
PROPERTY OF SAMPLE
MATERIAL CRUSHAB ILITY
PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)
Boulders
Cobbles Top size (mm)
Pebbles 100x50x40
Granules
Sand Average size (mm)
Silt 60x30x30
Clay
MINOR COMPONENTS ADDITIONAL INFORMATION
LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)
Doubleclick here to insert picture
The material smells
Moist
Caking
Dry
Only Plastic/Soft materials
Both fines materials and hard specimen
Only hard specimen
Very Weak - The material can be scratched by thumbnail
Weak - Knife cuts material
Very Strong - Requires many blows by hammer to break into specimens
Strong - Hand held specimens broken by single blow of hammer
None
Low
Medium
High
> 256
64 - 256
4 - 64
2 - 4
0.1 - 2
0.004 - 0.1
< 0.004
Yes No
Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm
Material wrapped up in Plastic
Case No: 20100035 2010-05-14 Page 1 of 1
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Grasim Cement, Raipur
IndiaEncl.: 1.2
Material Description - Sample as received
SAMPLE DESCRIPTION
ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
02 Clay Clay 20100035-02
INSPECTION
Received: 2010-02-12
Container: 2 Drum, steel
Weight, kg: 500
COLOR
Munsell Color: Yellow
Color Code: 10 YR 7/8
BULK MATERIAL PROPERTIES
PROPERTY OF SAMPLE
MATERIAL CRUSHAB ILITY
PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)
Boulders
Cobbles Top size (mm)
Pebbles 95x80x45
Granules
Sand Average size (mm)
Silt 50x30x25
Clay
MINOR COMPONENTS ADDITIONAL INFORMATION
LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)
Doubleclick here to insert picture
The material smells
Moist
Caking
Dry
Only Plastic/Soft materials
Both fines materials and hard specimen
Only hard specimen
Very Weak - The material can be scratched by thumbnail
Weak - Knife cuts material
Very Strong - Requires many blows by hammer to break into specimens
Strong - Hand held specimens broken by single blow of hammer
None
Low
Medium
High
> 256
64 - 256
4 - 64
2 - 4
0.1 - 2
0.004 - 0.1
< 0.004
Yes No
Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm
Material wrapped up in Plastic
Case No: 20100035 2010-05-14 Page 1 of 1
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Grasim Cement, Raipur
IndiaEncl.: 1.3
Material Description - Sample as received
SAMPLE DESCRIPTION
ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
03 Shale Shale 20100035-03
INSPECTION
Received: 2010-02-12
Container: 2 Drum, steel
Weight, kg: 425
COLOR
Munsell Color: Pink
Color Code: 5YR 7/4
BULK MATERIAL PROPERTIES
PROPERTY OF SAMPLE
MATERIAL CRUSHAB ILITY
PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)
Boulders
Cobbles Top size (mm)
Pebbles 110x60x25
Granules
Sand Average size (mm)
Silt 60x30x15
Clay
MINOR COMPONENTS ADDITIONAL INFORMATION
LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)
We Observed 3 Types of color Material Pink ,Yellow &White
Doubleclick here to insert picture
The material smells
Moist
Caking
Dry
Only Plastic/Soft materials
Both fines materials and hard specimen
Only hard specimen
Very Weak - The material can be scratched by thumbnail
Weak - Knife cuts material
Very Strong - Requires many blows by hammer to break into specimens
Strong - Hand held specimens broken by single blow of hammer
None
Low
Medium
High
> 256
64 - 256
4 - 64
2 - 4
0.1 - 2
0.004 - 0.1
< 0.004
Yes No
Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm
Material wrapped up in Plastic
Case No: 20100035 2010-05-14 Page 1 of 1
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IndiaEncl.: 1.4
Material Description - Sample as received
SAMPLE DESCRIPTION
ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
04 Iron Ore Iron Ore 20100035-04
INSPECTION
Received: 2010-02-12
Container: 4 Bag, plastic
Weight, kg: 150
COLOR
Munsell Color: Brown
Color Code: 7.5YR 4/3
BULK MATERIAL PROPERTIES
PROPERTY OF SAMPLE
MATERIAL CRUSHAB ILITY
PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)
Boulders
Cobbles Top size (mm)
Pebbles 50x25x15
Granules
Sand Average size (mm)
Silt 20x15x10
Clay
MINOR COMPONENTS ADDITIONAL INFORMATION
LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)
Doubleclick here to insert picture
The material smells
Moist
Caking
Dry
Only Plastic/Soft materials
Both fines materials and hard specimen
Only hard specimen
Very Weak - The material can be scratched by thumbnail
Weak - Knife cuts material
Very Strong - Requires many blows by hammer to break into specimens
Strong - Hand held specimens broken by single blow of hammer
None
Low
Medium
High
> 256
64 - 256
4 - 64
2 - 4
0.1 - 2
0.004 - 0.1
< 0.004
Yes No
Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm
Material wrapped up in Plastic
Case No: 20100035 2010-05-14 Page 1 of 1
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Grasim Cement, Raipur
IndiaEncl.: 1.5
Material Description - Sample as received
SAMPLE DESCRIPTION
ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
05 Coal Grade B Coal 20100035-05
INSPECTION
Received: 2010-02-12
Container: 1 Bag, plastic
Weight, kg: 25
COLOR
Munsell Color: Black
Color Code: 7.5YR 2.5/1
BULK MATERIAL PROPERTIES
PROPERTY OF SAMPLE
MATERIAL CRUSHAB ILITY
PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)
Boulders
Cobbles Top size (mm)
Pebbles 60x50x30
Granules
Sand Average size (mm)
Silt 30x15x10
Clay
MINOR COMPONENTS ADDITIONAL INFORMATION
LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)
Doubleclick here to insert picture
The material smells
Moist
Caking
Dry
Only Plastic/Soft materials
Both fines materials and hard specimen
Only hard specimen
Very Weak - The material can be scratched by thumbnail
Weak - Knife cuts material
Very Strong - Requires many blows by hammer to break into specimens
Strong - Hand held specimens broken by single blow of hammer
None
Low
Medium
High
> 256
64 - 256
4 - 64
2 - 4
0.1 - 2
0.004 - 0.1
< 0.004
Yes No
Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm
Material wrapped up in Plastic
Case No: 20100035 2010-05-14 Page 1 of 1
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Grasim Cement, Raipur
IndiaEncl.: 1.6
Material Description - Sample as received
SAMPLE DESCRIPTION
ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
06 Coal Grade C Coal 20100035-06
INSPECTION
Received: 2010-02-12
Container: 1 Bag, plastic
Weight, kg: 25
COLOR
Munsell Color: Black
Color Code: 7.5YR 2.5/1
BULK MATERIAL PROPERTIES
PROPERTY OF SAMPLE
MATERIAL CRUSHAB ILITY
PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)
Boulders
Cobbles Top size (mm)
Pebbles 70x50x25
Granules
Sand Average size (mm)
Silt 30x25x15
Clay
MINOR COMPONENTS ADDITIONAL INFORMATION
LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)
Doubleclick here to insert picture
The material smells
Moist
Caking
Dry
Only Plastic/Soft materials
Both fines materials and hard specimen
Only hard specimen
Very Weak - The material can be scratched by thumbnail
Weak - Knife cuts material
Very Strong - Requires many blows by hammer to break into specimens
Strong - Hand held specimens broken by single blow of hammer
None
Low
Medium
High
> 256
64 - 256
4 - 64
2 - 4
0.1 - 2
0.004 - 0.1
< 0.004
Yes No
Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm
Material wrapped up in Plastic
Case No: 20100035 2010-05-14 Page 1 of 1
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Grasim Cement, Raipur
IndiaEncl.: 1.7
Material Description - Sample as received
SAMPLE DESCRIPTION
ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
07 Pet Coke Petcoke 20100035-07
INSPECTION
Received: 2010-02-12
Container:
Weight, kg: 25
COLOR
Munsell Color: Black
Color Code: 7.5YR 2.5/1
BULK MATERIAL PROPERTIES
PROPERTY OF SAMPLE
MATERIAL CRUSHAB ILITY
PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)
Boulders
Cobbles Top size (mm)
Pebbles 45x40x20
Granules
Sand Average size (mm)
Silt 4mm
Clay
MINOR COMPONENTS ADDITIONAL INFORMATION
LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)
Doubleclick here to insert picture
1 Drum, steel small
The material smells
Moist
Caking
Dry
Only Plastic/Soft materials
Both fines materials and hard specimen
Only hard specimen
Very Weak - The material can be scratched by thumbnail
Weak - Knife cuts material
Very Strong - Requires many blows by hammer to break into specimens
Strong - Hand held specimens broken by single blow of hammer
None
Low
Medium
High
> 256
64 - 256
4 - 64
2 - 4
0.1 - 2
0.004 - 0.1
< 0.004
Yes No
Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm
Material wrapped up in Plastic
Case No: 20100035 2010-05-14 Page 1 of 1
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Grasim Cement, RaipurIndia
Encl.: 2.1
ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
01 Limestone Limestone 20100035-01
02 Clay Clay 20100035-02
03 Shale Shale 20100035-03
04 Iron Ore Iron Ore 20100035-04
PARAMETER METHOD UNIT 01 02 03 04
Moisture Content (105C) FLS-B21 % 0.1 5.1 1.0 1.8
SiO2 FLS-D03 % 11.47 40.76 61.85 5.07
Al2O3 FLS-D03 % 2.68 15.17 14.43 5.74
Fe2O3 FLS-D03 % 1.25 28.47 7.02 82.66
CaO FLS-D03 % 45.24 4.12 2.98 0.55
MgO FLS-D03 % 1.13 0.79 2.42 0.17
Mn2O3 FLS-D03 % 0.03 0.23 0.02 0.06
TiO2 FLS-D03 % 0.17 0.82 0.90 0.36
P2O5 FLS-D03 % 0.04 0.05 0.11 0.20
K2O FLS-D03 % 0.67 1.57 3.79 0.10
Na2O FLS-D03 % 0.16 0.63
SrO FLS-D03 % 0.01 0.01
LOI, 975 C FLS-D00 % 36.72 10.30 5.28 6.10
TOTAL FLS-D03 % 99.57 102.28 99.44 101.01
Sulphur, total FLS-D08 % 0.02 0.01 0.26 0.04
Organic Carbon FLS-D27 % 0.05 0.23 0.08 0.10
Chloride FLS-D07 % 0.006 0.001 0.002 0.002
Lime saturation factor (LSF) FLS-D03 % 125 3 2 1
Silica modulus (MS) FLS-D03 - 2.9 0.9 2.9 0.1
Iron modulus (MA) FLS-D03 - 2.1 0.5 2.1 0.1
Characterization of Materials
SAMPLE DESCRIPTION
Moisture
Chemical analyses
Case No: 20100035 2010-05-14 Page 1 of 1
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Grasim Cement, Raipur
IndiaEncl.: 3.1
ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
05 Coal Grade B Coal 20100035-0505.01 Coal Ash Coal Ash 20100035-05.01
PARAMETER METHOD UNITAs analysed
(air dried)As received Dry
Dry,
ash free
Dry, mineral
matter free
Analys is
Free moisture FLS-B21BS % 0.3Moisture in air-dried sample FLS-E03BS % 6.6Total moisture CALC-BS % 6.9Volatile matter FLS-E03BS % 30.2 30.1 32.3 46.5 42.8Ash FLS-E03BS % 28.5 28.4 30.5Fixed Carbon CALC-BS % 34.7 34.6 37.2 53.5 57.2Carbon FLS-E10 % 51.5 51.3 55.1 79.4 82.6Hydrogen FLS-E10 % 3.11 3.10 3.33 4.79 4.36
SulphurFLS-E09BS
% 0.48 0.48 0.51 0.74 0.86Nitrogen FLS-E10 % 1.14Oxygen CALC % 8.67CO2 FLS-D27 %
Mineral matter CALC-BS % 31.0 31.0Gross calorific value FLS-E08ISO kJ/kg 20559 20497 22012 31678 32994
FLS-E08ISO kcal/kg 4910 4896 5257 7566 7881Net calorific value FLS-E08ISO kJ/kg 19731 19665 21298 30651
FLS-E08ISO kcal/kg 4713 4697 5087 7321K2O FLS-D13 % 0.31
Na2O FLS-D13 % 0.02
Chloride FLS-D07BS % 0.007Hardgrove grindability index FLS-I08ISO
Wear Index FLS-I12BS mg/kg
(total hydrogen - hidden) % 3.85Safety index CALC 1
PARAMETER METHOD UNIT PARAMETER METHOD UNIT
Fineness (s ieve open ings) nalyses of ash
Residue on 40 mm Machine % SiO2 XRF % 65.06
Residue on 25 mm Machine % Al2O3 XRF % 23.09
Residue on 16 mm Machine % Fe2O3 XRF % 4.84
Residue on 8 mm Machine % CaO XRF % 1.54
Residue on 4 mm Machine % MgO XRF % 0.68
Residue on 2 mm Machine % Mn2O3 XRF % 0.07
Residue on 1 mm Machine % TiO2 XRF % 1.65
Residue on 500 m Machine %P
2O
5 XRF % 0.16Residue on 250 m Alpine % SrO XRF % 0.02
Residue on 200 m Alpine % LOI, 975 C % 0.74
Residue on 90 m Alpine % TOTAL % 99.06
Residue on 45 m Alpine %
1.07
1
1.54
1.6
Analysis of solid fuel
SAMPLE DESCRIPTION
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ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
06 Coal Grade C Coal 20100035-0606.01 Coal Ash Coal Ash 20100035-06.01
PARAMETER METHOD UNITAs analysed
(air dried)As received Dry
Dry,
ash free
Dry, mineral
matter free
Analys is
Free moisture FLS-B21BS % 0.3Moisture in air-dried sample FLS-E03BS % 6.1Total moisture CALC-BS % 6.4Volatile matter FLS-E03BS % 29.2 29.1 31.1 45.7 41.7Ash FLS-E03BS % 30.0 29.9 31.9Fixed Carbon CALC-BS % 34.7 34.6 37.0 54.3 58.3Carbon FLS-E10 % 52.5 52.3 55.9 82.2 85.7Hydrogen FLS-E10 % 3.19 3.18 3.39 4.99 4.53
SulphurFLS-E09BS
% 0.47 0.47 0.50 0.74 0.86Nitrogen FLS-E10 % 1.16Oxygen CALC % 6.58CO2 FLS-D27 %
Mineral matter CALC-BS % 32.7 32.6Gross calorific value FLS-E08ISO kJ/kg 20520 20458 21853 32113 33533
FLS-E08ISO kcal/kg 4901 4886 5220 7670 8009Net calorific value FLS-E08ISO kJ/kg 19690 19623 21128 31047
FLS-E08ISO kcal/kg 4703 4687 5046 7415K2O FLS-D13 % 0.39
Na2O FLS-D13 % 0.03
Chloride FLS-D07BS % 0.011Hardgrove grindability index FLS-I08ISO
Wear Index FLS-I12BS mg/kg
(total hydrogen - hidden) % 3.87Safety index CALC 1
PARAMETER METHOD UNIT PARAMETER METHOD UNIT
Fineness (s ieve open ings) nalyses of ash
Residue on 40 mm Machine % SiO2 XRF % 65.26
Residue on 25 mm Machine % Al2O3 XRF % 22.93
Residue on 16 mm Machine % Fe2O3 XRF % 4.92
Residue on 8 mm Machine % CaO XRF % 1.29
Residue on 4 mm Machine % MgO XRF % 0.69
Residue on 2 mm Machine % Mn2O3 XRF % 0.07
Residue on 1 mm Machine % TiO2 XRF % 1.51
Residue on 500 m Machine %P
2O
5 XRF % 0.16Residue on 250 m Alpine % SrO XRF % 0.03
Residue on 200 m Alpine % LOI, 975 C % 0.74
Residue on 90 m Alpine % TOTAL % 99.05
Residue on 45 m Alpine %
1.06
1
1.56
1.63
Analysis of solid fuel
SAMPLE DESCRIPTION
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ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
07 Pet Coke Petcoke 20100035-07
PARAMETER METHOD UNITAs analysed
(air dried)As received Dry
Dry,
ash free
Dry, mineral
matter free
AnalysisFree moisture FLS-B21BS % 0.6Moisture in air-dried sample FLS-E03BS % 0.9Total moisture CALC-BS % 1.5Volatile matter FLS-E03BS % 10.7 10.6 10.8 10.8 10.4Ash FLS-E03BS % 0.2 0.2 0.2Fixed Carbon CALC-BS % 88.2 87.7 89.0 89.2 89.6Carbon FLS-E10 % 87.2 86.7 88.0 88.2 90.6Hydrogen FLS-E10 % 3.65 3.63 3.68 3.69 3.86
Sulphur FLS-E09BS % 4.87 4.84 4.91 4.92 1.43Nitrogen FLS-E10 % 1.79Oxygen CALC % 1.39CO2 FLS-D27 %
Mineral matter CALC-BS % 2.9 2.9Gross calorific value FLS-E08ISO kJ/kg 35483 35270 35805 35878 36451
FLS-E08ISO kcal/kg 8475 8424 8552 8569 8706Net calorific value FLS-E08ISO kJ/kg 34686 34463 35023 35094
FLS-E08ISO kcal/kg 8285 8231 8365 8382K2O FLS-D13 %
Na2O FLS-D13 %
Chloride FLS-D07BS % 0.001Hardgrove grindability index FLS-I08ISO
Wear Index FLS-I12BS mg/kg
(total hydrogen - hidden) % 3.75Safety index CALC 8
PARAMETER METHOD UNIT PARAMETER METHOD UNIT
Fineness (sieve openings) Analyses of ash
Residue on 40 mm Machine % SiO2 XRF %
Residue on 25 mm Machine % Al2O3 XRF %
Residue on 16 mm Machine % Fe2O3 XRF %
Residue on 8 mm Machine % CaO XRF %
Residue on 4 mm Machine % MgO XRF %
Residue on 2 mm Machine % Mn2O3 XRF %
Residue on 1 mm Machine % TiO2 XRF %Residue on 500 m Machine % P2O5 XRF %
Residue on 250 m Alpine % SrO XRF %
Residue on 200 m Alpine % LOI, 975 C %
Residue on 90 m Alpine % TOTAL %
Residue on 45 m Alpine %
1.01
0.99
1.01
1.04
Analysis of solid fuel
SAMPLE DESCRIPTION
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RAW MIX CALCULATION
PLANT: Grasim Cement, Raipur Encl.: 4.1
CASE.NO.: Date:
Raw Mix Calculation Mix 1
Ed. 1, 29-03-2010 by DKS Clinker Mix M01 M02 M03 M04 F01 A01 F02 A02
Mix [% dry] 100.00 96.29 1.00 1.61 1.10 100.00 0.00 100.00
Mix [as analysed % wet] 100.00 96.29 1.00 1.61 1.10 100.00 0.00 100.00
Mix [as fired % wet] 100.00 0.00 100.00H2O (analysed) [% (wb)] 0.00 0.00 0.00 0.00 0.00 6.10 6.60 6.10
H2O (as fired) [% (wb)] 1.00 1.00 1.00
SiO 2[%] 21.44 12.51 11.47 40.76 61.85 5.07 65.26 65.06 65.26
Al2O 3 [%] 5.51 3.03 2.68 15.17 14.43 5.74 22.93 23.09 22.93
Fe 2O 3 [%] 3.94 2.51 1.25 28.47 7.02 82.66 4.92 4.84 4.92
CaO [%] 64.77 43.65 45.24 4.12 2.98 0.55 1.29 1.54 1.29
MgO [%] 1.72 1.14 1.13 0.79 2.42 0.17 0.69 0.68 0.69
Mn 2O 3 [%] 0.05 0.03 0.03 0.23 0.02 0.06 0.07 0.07 0.07
TiO 2[%] 0.35 0.19 0.17 0.82 0.90 0.36 1.51 1.65 1.51
P2O 5[%] 0.07 0.04 0.04 0.05 0.11 0.20 0.16 0.16 0.16
K2O [%] 1.13 0.72 0.67 1.57 3.79 0.10 0.39 0.31 0.39
Na 2O [%] 0.25 0.16 0.16 0.63 0.03 0.02 0.03
SrO [%] 0.02 0.01 0.01 0.01 0.03 0.02 0.03
SO 3 [%] 0.26 0.00
LOI [%] 35.61 36.72 10.30 5.28 6.10 0.74 0.74 0.74Total [%] 99.51 99.61 99.57 102.28 99.44 101.01 97.60 97.85 97.60
S Total [%] 0.11 0.02 0.02 0.01 0.26 0.04 0.47 0.48 0.47
S Pyrite [%] 0.00
Cl-[%] 0.010 0.006 0.006 0.001 0.002 0.002 0.011 0.007 0.011
F-[%] 0.00 0.00 0.00
Cr2O 3 [ppm] 0 0 0
Ash [%] 4.55 30.00 28.50 30.00
Hi (analysed) [kcal/kg] 4703 4713 4703
Exp. kiln heat cons. [kcal/kg] 702.0
LSF [%] 93.7 108.5 125.4 2.7 1.5 0.7
MS 2.27 2.26 2.92 0.93 2.88 0.06
MA 1.40 1.21 2.14 0.53 2.06 0.07
Na 2O eq. [%] 0.99 0.64 0.60 1.03 3.12 0.07
K2O eq. [%] 1.51 0.97 0.91 1.57 4.75 0.10
C3S [%] 52.00 M01: Limestone
C2S [%] 22.24 M02: ClayC3A [%] 7.93 M03: Shale
C4AF [%] 11.99 M04: Iron ore
C2F [%] 0.00 F01: Coal B
Free CaO [%] 1.50 F02: Coal C
Liq. Ph. 1450 C [%] 28.75
Liq. Ph. 1338 C [%] 27.96
M SO 3 0.23
Exc. SO 3 [g/100 kg] 0
Calc. rev. 08-01 / May 29, 2008 / CBMI
20100035
Total fuel+ash
2010-05-14
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Encl.: 5.1
ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
09 Raw Mix for Burnability Raw Mix
06.01 Coal Ash Coal Ash
PARAMETER METHOD UNIT 09
SiO2 FLS-D03 % 13.99
Al2O3 FLS-D03 % 3.61
Fe2O3 FLS-D03 % 2.59
CaO FLS-D03 % 42.42
MgO FLS-D03 % 1.12
Mn2O3 FLS-D03 % 0.03
TiO2 FLS-D03 % 0.23
P2O5 FLS-D03 % 0.05K2O FLS-D03 % 0.73
Na2O FLS-D03 % 0.10
SrO FLS-D03 % 0.01
LOI, 975 C FLS-D00 % 34.81
TOTAL FLS-D03 % 99.69
Fluoride FLS-D34 % 0.03
C3S in Clinker (Free CaO=0) FLS-D03 % 59
Lime saturation factor (LSF) FLS-D03 % 94
Silica modulus (MS) FLS-D03 - 2.3
Iron modulus (MA) FLS-D03 - 1.4
PARAMETER METHOD UNIT Coarse Medium Fine
Residue, 200 m, wet WET % 2.0 0.3 0.1
Residue, 125 m, wet WET % 3.0
Residue, 90 m, wet WET % 19.8 13.8 9.9
Residue, 90 m, alpine ALPINE % 20.2 14.3 10.0
Residue, 45 m, wet WET % 30.7
Free CaO after burning at 1400 C FLS-D23 % 1.1 0.8 0.7
Free CaO after burning at 1450 C FLS-D23 % 0.7 0.6 0.6
Free CaO after burning at 1500 C FLS-D23 % 0.5 0.5 0.5
Burnability Index FLS-D23 - 30 27 24Burnability Classification FLS-D23 - EASY EASY EASY
Burnabi l i ty test on Raw Mix with Coal As h
Burnability Test
SAMPLE DESCRIPTION
Character izat ion of Raw Mix w ith Coal As h (Coal Grade C)
Fineness on Raw Mix
20100035-06.01
20100035-09
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IndiaEncl.: 6.1
SAMPLE DESCRIPTION
ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER
09 Raw Mix
06 Coal
06.01 Coal Ash
PARAMETER UNIT * RESULT PARAMETER UNIT RESULT
Raw m ix Fuel: Coal
SiO2 % 12.51 Fuel in percentage of clinker % 14.9
Al2O3 % 3.03 Sulphur, total % 0.47
Fe2O3 % 2.51 Ash in percentage of fuel % 30.0
CaO % 43.65 Net calorific value ( Q net,p ) kJ/kg 19690
MgO % 1.14 kcal/kg 4703
SO3 % * 0.01 Heat consumption, clinker kJ/kg 2939
Loss on ignition (LOI) % 35.61 kcal/kg 702
TOTAL % 98.46 Analys is o f ash
CO2 % * 34.86 SiO2 % 65.26
K2O % 0.72Al2O3 % 22.93
Na2O % 0.16 Fe2O3 % 4.92
Sulphur, total % 0.02 CaO % 1.29
Water of crystallisation % * 0.86 MgO % 0.69
Carbon1) % * 0.05 K2O
2) % 1.30
Na2O2) % 0.10
CaCO3 % 77.93 CaSO4 % 0.02
MgCO3 % 1.09 Silica-combined CaO % 0.00Sulphur in pyrites % 0.02
RAW MIX ADJUSTMENT
PARAMETER UNIT RAW MIX ADJUSTMENT FUEL
SiO2 % 12.51 1.97 14.48
Al2O3 % 3.03 0.69 3.72
Fe2O3 % 2.51 0.15 2.66
CaO % 43.65 0.04 43.69
MgO % 1.14 0.02 1.16
SO3 (total) % 0.05 0.12 0.17
K2O % 0.72 0.04 0.76
Na2O % 0.16 0.00 0.16TOTAL % 63.77 3.03 T = 66.80
SULPHUR BA LANCE AND RAW MIX / CLINKER RATIO
Adjusted raw mix, total : T : 66.80
Volatilised : U = 50 U : 0.02
SO3 in clinker (calculated) : 0.22
Raw mix / clinker ratio F : 1.50
Remarks:
* Analytical results
1) Carbon as CO2is not included. 2) Calculated from analysis of solid fuel.
(loss of dust = 0 %) : F = 100 / ( T U ) :
% of sulphur in pyrites as SO3
CALCULATED VALUES
Heat of reaction
ADJUSTED RAW MIX
20100035-09Raw Mix for Burnability
Coal Grade C
Coal Ash
20100035-06
20100035-06.01
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CALCULATIONSContent
%
Conversion factors
kJ / kg / %
RAWMIX
kJ / kg
CLINKER
kJ / kg
RAWMIXCaCO3 77.93 -17.78 -1386
MgCO3 1.09 -15.10 -16
Water of crystallisation 0.86 -42.70 -37
Silica-combined CaO 0.00 -17.00 0
Alkali silicates (K2O + Na2O) 0.88 -14.80 -13
-1452 xF: -2174
Heat of fo rmat ion
Property Component Adj. RAWMIX
C3S CaO 43.69 -0.46 -20
C2S SiO2 14.48 21.43 310
C3A Al2O3 3.72 1.21 5
C4AF Fe2O3 2.66 2.46 7
SO3 from fuel and pyrites 0.14 59.60 8
309 xF: 463
Heat of combus t ion
Carbon 0.05 327.86 16
Sulphur in pyrites 0.02 129.14 2
18 xF: 28
Heat of reactio n
HEAT OF REACTION (A + B + C): -1683
-402
HEAT OF REACTION excl. HEAT OF COMBUSTION (A + B): -1711
-409( kcal / kg clinker )
Heat of combustion (C):
( kJ / kg clinker )
( kJ / kg clinker )
( kcal / kg clinker )
Heat of reaction
Heat of decompos it ion
Heat of decomposition (A):
Heat of formation (B):
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PLANT : Grasim Cement, Raipur Case. No.:MATERIAL : Rawmix Date :
PROJECT : VRM No. :
MILL FEED, COMPOSITION
M1 : 96.29%
M2 : 1.00%M3 : 1.61%
M4: 1.10%
SIEVE ANALYSIS - MOISTURE DETERMINATION :
Sample Id. : M1 M2 M3 M4 M5 M6 M7 M8 MIX
AS RECEIVED
Moisture : (%)
Sieve Residues :
: (%)
: (%)
40 mm : (%)
25 mm : (%)
16 mm : (%)
8 mm : (%)
4 mm : (%) 2 mm : (%)
1 mm : (%)
500 m : (%)
250 m : (%)
200 m : (%)
90 m : (%)
45 m : (%)
32 m : (%)
AFTER PRECRUSHING, -25mm
Moisture :
+4 mm : (%)
+4mm, max : (%)
-4 mm : (%)
-4 mm, max : (%)
Sieve Residues :
16 mm : (%)
8 mm : (%)
4 mm : (%)
2 mm : (%)
1 mm : (%)
500 m : (%)
250 m : (%)
200 m : (%)
90 m : (%)
45 m : (%)
32 m : (%)
AFTER PRECRUSHING, -16 mm Mill Feed
Sieve Residues :
8 mm : (%) 8.424 mm : (%) 49.94
2 mm : (%) 73.52
1 mm : (%) 85.42
500 m : (%) 91.91
250 m : (%) 95.16
200 m : (%) 95.54
90 m : (%) 96.97
45 m : (%)
32 m : (%)
et sieving :
90 m : (%)
45 m : (%)
Spec. Surf. (m/kg)
20100035
2010-04-14
ATOXIN10-11
Limestone
ClayShale
Iron ore
LABORATORY REPORT
F.L.Smidth Research Center - Chennai, IndiaVERTICAL MILL
Mill feed composition and Sieve analysis
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Encl.: 7.1 Page 2
PLANT : Grasim Cement, Raipur Case. No. :MATERIAL : Rawmix Date :
PROJECT : RM No. :MILL FEED, COMPOSITION
M1 : 96.29%
M2 : 1.00%
M3 : 1.61%
M4: 1.10%
TEST PARAMETERS
Mill : Moisture :
Revolutions : (rpm) 100 Mill feed : (%) 2.44
Grind. pres. : (bar) 90 Product : (%) 0.17
Grind. force : (kN) 26
(kN/m) 596Gas :
Quantity : (m/h) 996
Temp out : (C) 91
TEST RESULTS
Period 1 2 3 4 5 6 7
Separator : Static () 39 30 25 22
Dyn. press. (mmWg) 238 238 239 238
Grinding bed:
Average for rollers: (mm)
Power consumption :
Mean : (kW) 4.46 4.56 4.65 4.77
Total (spec.) : (kWh/t) 10.39 9.27 8.78 8.66
Production :
Total : (kg) 26.7 21.9 34.1 35.5
Rate : (t/h) 0.429 0.492 0.530 0.550
Sieve residue :
90 m : (%) 7.2 14.2 21.0 26.0
200 m : (%) 0.9 1.3 3.3 5.0
Grinding constants :
90 m : (kWh/t) 9.21 11.12 13.20 15.15
200 m : (kWh/t) 5.10 4.94 6.02 6.77
- Factor : 0.116 0.118 0.121 0.124
ABRASION TEST
Wear parts : brasion :
Table : Cromin 15 Table : (g) 0.3Rollers : Cromin 15 Roller 1 : (g) 0.1
Roller 2 : (g) 0.1
Test time (h) 1.37 Roller 3 : (g) 0.2
Average (net) (kW) 4.61 Total : (g) 0.7
Ground mat. (t) 0.662
Fineness, average : Table : (g/t) 0.5
90 m (%) 18.1 Rollers : (g/t) 0.6
TOTAL ABRASION 1.1 (g/t)
.5 (g/h)
.1 (g/kWh)
20100035
2010-04-14
ATOXIN10-11
Limestone
Clay
Shale
Iron ore
LABORATORY REPORT.
F.L.Smidth Research Center - Chennai, IndiaVERTICAL MILL
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Encl.: 7.1 Page 3
PLANT : Grasim Cement, Raipur Case.No. :MATERIAL : Rawmix VRM No.: Date :
PROJECT :
20100035
2010-04-14ATOXIN10-11
y = 0.0059Ln(x) + 0.1036
R2= 0.9261
0.000
0.010
0.020
0.030
0.040
0.050
0.060
0.070
0.080
0.090
0.100
0.110
0.120
0.130
0.140
0.150
0.0 5.0 10.0 15.0 20.0 25.0
Sieve residue 90 m, Alpine (%)
-Factor
Rawmix Log. (Rawmix)
LABORATORY REPORT
F.L.Smidth Research Center - Chennai, IndiaVERTICAL MILL
-factor vs. Sieve residue on 90m
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PLANT : Grasim Cement, Raipur Case.No. :MATERIAL : Rawmix VRM No.: Date :
PROJECT :
20100035
2010-04-14ATOXIN10-11
y = 0.3975e0.0132x
R2= 0.9609
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00
1.10
1.20
1.30
1.40
0.0 5.0 10.0 15.0 20.0 25.0
Sieve residue 90 m, Alpine (%)
Production(t/h)
Rawmix Expon. (Rawmix)
LABORATORY REPORT
F.L.Smidth Research Center - Chennai, IndiaVERTICAL MILL
Production rate vs. Sieve residue on 90m
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Grasim Cement, RaipurIndia
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