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  • 8/11/2019 Partial Report - Rawan

    1/23

    Grasim Cement, Raipu r

    India

    Pro ject No: 10-31017

    Case No : 20100035

    2010-05-14

    Partial Report

    FLSmidth A/S

    R&D Centre DaniaDaniavej 49DK-9550 Mariager, DenmarkTel + 45 3618 1000Fax + 45 3618 [email protected]

    FLSmidth Private Limited

    R&D Centre Chennai34 Egattur, KelambakkamTamil Nadu 603103, IndiaTel +91 44 4748 1000Fax +91 44 2747 0301R&[email protected]

    LABORATORY REPORT

    mailto:[email protected]:[email protected]
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    Grasim Cement, RaipurIndia

    Case No: 20100035 2010-05-14 Page 1 of 1

    LABORATORY REPORTOrdered by: DKS-INCopies to : BLO-IN, SNE-IN, SSA-IN

    SAMPLE DESCRIPTION

    SAMPLE NAME SAMPLE NUMBER WEIGHT, KG DATE RECEIVED

    Limestone 01 1500 2010-01-29

    Clay 02 500 2010-01-29

    Shale 03 425 2010-01-29

    Iron Ore 04 150 2010-01-29

    Coal Grade B 05 25 2010-01-29

    Coal Grade C 06 25 2010-01-29

    Pet Coke 07 25 2010-02-09

    Fly Ash 10 60 2010-03-09

    Clinker 11 600 2010-03-09

    Gypsum 12 35 2010-03-09

    Slag 13 150 2010-03-09

    CONTENTS OF REPORT (ANALYSES / TESTS)

    ENCL. NO. ITEM

    1. Material Description2. Characterization of Materials

    3. Analysis of Solid Fuel

    4. Raw Mix Calculation

    5. Burnability

    6. Heat of Reaction

    7. ATOX Vertical Roller Mill Test

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    Grasim Cement, Raipur

    IndiaEncl.: 1.1

    Material Description - Sample as received

    SAMPLE DESCRIPTION

    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    01 Limestone Limestone 20100035-01

    INSPECTION

    Received: 2010-02-12

    Container: 5 Drum, steel

    Weight, kg: 1500

    COLOR

    Munsell Color: Gray

    Color Code: Gley1 6/N

    BULK MATERIAL PROPERTIES

    PROPERTY OF SAMPLE

    MATERIAL CRUSHAB ILITY

    PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)

    Boulders

    Cobbles Top size (mm)

    Pebbles 100x50x40

    Granules

    Sand Average size (mm)

    Silt 60x30x30

    Clay

    MINOR COMPONENTS ADDITIONAL INFORMATION

    LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)

    Doubleclick here to insert picture

    The material smells

    Moist

    Caking

    Dry

    Only Plastic/Soft materials

    Both fines materials and hard specimen

    Only hard specimen

    Very Weak - The material can be scratched by thumbnail

    Weak - Knife cuts material

    Very Strong - Requires many blows by hammer to break into specimens

    Strong - Hand held specimens broken by single blow of hammer

    None

    Low

    Medium

    High

    > 256

    64 - 256

    4 - 64

    2 - 4

    0.1 - 2

    0.004 - 0.1

    < 0.004

    Yes No

    Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm

    Material wrapped up in Plastic

    Case No: 20100035 2010-05-14 Page 1 of 1

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    IndiaEncl.: 1.2

    Material Description - Sample as received

    SAMPLE DESCRIPTION

    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    02 Clay Clay 20100035-02

    INSPECTION

    Received: 2010-02-12

    Container: 2 Drum, steel

    Weight, kg: 500

    COLOR

    Munsell Color: Yellow

    Color Code: 10 YR 7/8

    BULK MATERIAL PROPERTIES

    PROPERTY OF SAMPLE

    MATERIAL CRUSHAB ILITY

    PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)

    Boulders

    Cobbles Top size (mm)

    Pebbles 95x80x45

    Granules

    Sand Average size (mm)

    Silt 50x30x25

    Clay

    MINOR COMPONENTS ADDITIONAL INFORMATION

    LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)

    Doubleclick here to insert picture

    The material smells

    Moist

    Caking

    Dry

    Only Plastic/Soft materials

    Both fines materials and hard specimen

    Only hard specimen

    Very Weak - The material can be scratched by thumbnail

    Weak - Knife cuts material

    Very Strong - Requires many blows by hammer to break into specimens

    Strong - Hand held specimens broken by single blow of hammer

    None

    Low

    Medium

    High

    > 256

    64 - 256

    4 - 64

    2 - 4

    0.1 - 2

    0.004 - 0.1

    < 0.004

    Yes No

    Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm

    Material wrapped up in Plastic

    Case No: 20100035 2010-05-14 Page 1 of 1

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    Material Description - Sample as received

    SAMPLE DESCRIPTION

    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    03 Shale Shale 20100035-03

    INSPECTION

    Received: 2010-02-12

    Container: 2 Drum, steel

    Weight, kg: 425

    COLOR

    Munsell Color: Pink

    Color Code: 5YR 7/4

    BULK MATERIAL PROPERTIES

    PROPERTY OF SAMPLE

    MATERIAL CRUSHAB ILITY

    PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)

    Boulders

    Cobbles Top size (mm)

    Pebbles 110x60x25

    Granules

    Sand Average size (mm)

    Silt 60x30x15

    Clay

    MINOR COMPONENTS ADDITIONAL INFORMATION

    LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)

    We Observed 3 Types of color Material Pink ,Yellow &White

    Doubleclick here to insert picture

    The material smells

    Moist

    Caking

    Dry

    Only Plastic/Soft materials

    Both fines materials and hard specimen

    Only hard specimen

    Very Weak - The material can be scratched by thumbnail

    Weak - Knife cuts material

    Very Strong - Requires many blows by hammer to break into specimens

    Strong - Hand held specimens broken by single blow of hammer

    None

    Low

    Medium

    High

    > 256

    64 - 256

    4 - 64

    2 - 4

    0.1 - 2

    0.004 - 0.1

    < 0.004

    Yes No

    Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm

    Material wrapped up in Plastic

    Case No: 20100035 2010-05-14 Page 1 of 1

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    Material Description - Sample as received

    SAMPLE DESCRIPTION

    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    04 Iron Ore Iron Ore 20100035-04

    INSPECTION

    Received: 2010-02-12

    Container: 4 Bag, plastic

    Weight, kg: 150

    COLOR

    Munsell Color: Brown

    Color Code: 7.5YR 4/3

    BULK MATERIAL PROPERTIES

    PROPERTY OF SAMPLE

    MATERIAL CRUSHAB ILITY

    PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)

    Boulders

    Cobbles Top size (mm)

    Pebbles 50x25x15

    Granules

    Sand Average size (mm)

    Silt 20x15x10

    Clay

    MINOR COMPONENTS ADDITIONAL INFORMATION

    LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)

    Doubleclick here to insert picture

    The material smells

    Moist

    Caking

    Dry

    Only Plastic/Soft materials

    Both fines materials and hard specimen

    Only hard specimen

    Very Weak - The material can be scratched by thumbnail

    Weak - Knife cuts material

    Very Strong - Requires many blows by hammer to break into specimens

    Strong - Hand held specimens broken by single blow of hammer

    None

    Low

    Medium

    High

    > 256

    64 - 256

    4 - 64

    2 - 4

    0.1 - 2

    0.004 - 0.1

    < 0.004

    Yes No

    Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm

    Material wrapped up in Plastic

    Case No: 20100035 2010-05-14 Page 1 of 1

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    Material Description - Sample as received

    SAMPLE DESCRIPTION

    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    05 Coal Grade B Coal 20100035-05

    INSPECTION

    Received: 2010-02-12

    Container: 1 Bag, plastic

    Weight, kg: 25

    COLOR

    Munsell Color: Black

    Color Code: 7.5YR 2.5/1

    BULK MATERIAL PROPERTIES

    PROPERTY OF SAMPLE

    MATERIAL CRUSHAB ILITY

    PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)

    Boulders

    Cobbles Top size (mm)

    Pebbles 60x50x30

    Granules

    Sand Average size (mm)

    Silt 30x15x10

    Clay

    MINOR COMPONENTS ADDITIONAL INFORMATION

    LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)

    Doubleclick here to insert picture

    The material smells

    Moist

    Caking

    Dry

    Only Plastic/Soft materials

    Both fines materials and hard specimen

    Only hard specimen

    Very Weak - The material can be scratched by thumbnail

    Weak - Knife cuts material

    Very Strong - Requires many blows by hammer to break into specimens

    Strong - Hand held specimens broken by single blow of hammer

    None

    Low

    Medium

    High

    > 256

    64 - 256

    4 - 64

    2 - 4

    0.1 - 2

    0.004 - 0.1

    < 0.004

    Yes No

    Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm

    Material wrapped up in Plastic

    Case No: 20100035 2010-05-14 Page 1 of 1

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    Material Description - Sample as received

    SAMPLE DESCRIPTION

    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    06 Coal Grade C Coal 20100035-06

    INSPECTION

    Received: 2010-02-12

    Container: 1 Bag, plastic

    Weight, kg: 25

    COLOR

    Munsell Color: Black

    Color Code: 7.5YR 2.5/1

    BULK MATERIAL PROPERTIES

    PROPERTY OF SAMPLE

    MATERIAL CRUSHAB ILITY

    PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)

    Boulders

    Cobbles Top size (mm)

    Pebbles 70x50x25

    Granules

    Sand Average size (mm)

    Silt 30x25x15

    Clay

    MINOR COMPONENTS ADDITIONAL INFORMATION

    LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)

    Doubleclick here to insert picture

    The material smells

    Moist

    Caking

    Dry

    Only Plastic/Soft materials

    Both fines materials and hard specimen

    Only hard specimen

    Very Weak - The material can be scratched by thumbnail

    Weak - Knife cuts material

    Very Strong - Requires many blows by hammer to break into specimens

    Strong - Hand held specimens broken by single blow of hammer

    None

    Low

    Medium

    High

    > 256

    64 - 256

    4 - 64

    2 - 4

    0.1 - 2

    0.004 - 0.1

    < 0.004

    Yes No

    Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm

    Material wrapped up in Plastic

    Case No: 20100035 2010-05-14 Page 1 of 1

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    Material Description - Sample as received

    SAMPLE DESCRIPTION

    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    07 Pet Coke Petcoke 20100035-07

    INSPECTION

    Received: 2010-02-12

    Container:

    Weight, kg: 25

    COLOR

    Munsell Color: Black

    Color Code: 7.5YR 2.5/1

    BULK MATERIAL PROPERTIES

    PROPERTY OF SAMPLE

    MATERIAL CRUSHAB ILITY

    PROPORTION OF FINES GRAIN-SIZE SCA LE (m m)

    Boulders

    Cobbles Top size (mm)

    Pebbles 45x40x20

    Granules

    Sand Average size (mm)

    Silt 4mm

    Clay

    MINOR COMPONENTS ADDITIONAL INFORMATION

    LABORATORY SUGGESTIONS (MATERIAL CONSIDERATIONS)

    Doubleclick here to insert picture

    1 Drum, steel small

    The material smells

    Moist

    Caking

    Dry

    Only Plastic/Soft materials

    Both fines materials and hard specimen

    Only hard specimen

    Very Weak - The material can be scratched by thumbnail

    Weak - Knife cuts material

    Very Strong - Requires many blows by hammer to break into specimens

    Strong - Hand held specimens broken by single blow of hammer

    None

    Low

    Medium

    High

    > 256

    64 - 256

    4 - 64

    2 - 4

    0.1 - 2

    0.004 - 0.1

    < 0.004

    Yes No

    Flowability Max moisture Load strength Sample contains 10 or more specimens larger that 35 mm

    Material wrapped up in Plastic

    Case No: 20100035 2010-05-14 Page 1 of 1

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    Encl.: 2.1

    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    01 Limestone Limestone 20100035-01

    02 Clay Clay 20100035-02

    03 Shale Shale 20100035-03

    04 Iron Ore Iron Ore 20100035-04

    PARAMETER METHOD UNIT 01 02 03 04

    Moisture Content (105C) FLS-B21 % 0.1 5.1 1.0 1.8

    SiO2 FLS-D03 % 11.47 40.76 61.85 5.07

    Al2O3 FLS-D03 % 2.68 15.17 14.43 5.74

    Fe2O3 FLS-D03 % 1.25 28.47 7.02 82.66

    CaO FLS-D03 % 45.24 4.12 2.98 0.55

    MgO FLS-D03 % 1.13 0.79 2.42 0.17

    Mn2O3 FLS-D03 % 0.03 0.23 0.02 0.06

    TiO2 FLS-D03 % 0.17 0.82 0.90 0.36

    P2O5 FLS-D03 % 0.04 0.05 0.11 0.20

    K2O FLS-D03 % 0.67 1.57 3.79 0.10

    Na2O FLS-D03 % 0.16 0.63

    SrO FLS-D03 % 0.01 0.01

    LOI, 975 C FLS-D00 % 36.72 10.30 5.28 6.10

    TOTAL FLS-D03 % 99.57 102.28 99.44 101.01

    Sulphur, total FLS-D08 % 0.02 0.01 0.26 0.04

    Organic Carbon FLS-D27 % 0.05 0.23 0.08 0.10

    Chloride FLS-D07 % 0.006 0.001 0.002 0.002

    Lime saturation factor (LSF) FLS-D03 % 125 3 2 1

    Silica modulus (MS) FLS-D03 - 2.9 0.9 2.9 0.1

    Iron modulus (MA) FLS-D03 - 2.1 0.5 2.1 0.1

    Characterization of Materials

    SAMPLE DESCRIPTION

    Moisture

    Chemical analyses

    Case No: 20100035 2010-05-14 Page 1 of 1

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    IndiaEncl.: 3.1

    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    05 Coal Grade B Coal 20100035-0505.01 Coal Ash Coal Ash 20100035-05.01

    PARAMETER METHOD UNITAs analysed

    (air dried)As received Dry

    Dry,

    ash free

    Dry, mineral

    matter free

    Analys is

    Free moisture FLS-B21BS % 0.3Moisture in air-dried sample FLS-E03BS % 6.6Total moisture CALC-BS % 6.9Volatile matter FLS-E03BS % 30.2 30.1 32.3 46.5 42.8Ash FLS-E03BS % 28.5 28.4 30.5Fixed Carbon CALC-BS % 34.7 34.6 37.2 53.5 57.2Carbon FLS-E10 % 51.5 51.3 55.1 79.4 82.6Hydrogen FLS-E10 % 3.11 3.10 3.33 4.79 4.36

    SulphurFLS-E09BS

    % 0.48 0.48 0.51 0.74 0.86Nitrogen FLS-E10 % 1.14Oxygen CALC % 8.67CO2 FLS-D27 %

    Mineral matter CALC-BS % 31.0 31.0Gross calorific value FLS-E08ISO kJ/kg 20559 20497 22012 31678 32994

    FLS-E08ISO kcal/kg 4910 4896 5257 7566 7881Net calorific value FLS-E08ISO kJ/kg 19731 19665 21298 30651

    FLS-E08ISO kcal/kg 4713 4697 5087 7321K2O FLS-D13 % 0.31

    Na2O FLS-D13 % 0.02

    Chloride FLS-D07BS % 0.007Hardgrove grindability index FLS-I08ISO

    Wear Index FLS-I12BS mg/kg

    (total hydrogen - hidden) % 3.85Safety index CALC 1

    PARAMETER METHOD UNIT PARAMETER METHOD UNIT

    Fineness (s ieve open ings) nalyses of ash

    Residue on 40 mm Machine % SiO2 XRF % 65.06

    Residue on 25 mm Machine % Al2O3 XRF % 23.09

    Residue on 16 mm Machine % Fe2O3 XRF % 4.84

    Residue on 8 mm Machine % CaO XRF % 1.54

    Residue on 4 mm Machine % MgO XRF % 0.68

    Residue on 2 mm Machine % Mn2O3 XRF % 0.07

    Residue on 1 mm Machine % TiO2 XRF % 1.65

    Residue on 500 m Machine %P

    2O

    5 XRF % 0.16Residue on 250 m Alpine % SrO XRF % 0.02

    Residue on 200 m Alpine % LOI, 975 C % 0.74

    Residue on 90 m Alpine % TOTAL % 99.06

    Residue on 45 m Alpine %

    1.07

    1

    1.54

    1.6

    Analysis of solid fuel

    SAMPLE DESCRIPTION

    Case No: 20100035 2010-05-14 Page 1 of 1

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    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    06 Coal Grade C Coal 20100035-0606.01 Coal Ash Coal Ash 20100035-06.01

    PARAMETER METHOD UNITAs analysed

    (air dried)As received Dry

    Dry,

    ash free

    Dry, mineral

    matter free

    Analys is

    Free moisture FLS-B21BS % 0.3Moisture in air-dried sample FLS-E03BS % 6.1Total moisture CALC-BS % 6.4Volatile matter FLS-E03BS % 29.2 29.1 31.1 45.7 41.7Ash FLS-E03BS % 30.0 29.9 31.9Fixed Carbon CALC-BS % 34.7 34.6 37.0 54.3 58.3Carbon FLS-E10 % 52.5 52.3 55.9 82.2 85.7Hydrogen FLS-E10 % 3.19 3.18 3.39 4.99 4.53

    SulphurFLS-E09BS

    % 0.47 0.47 0.50 0.74 0.86Nitrogen FLS-E10 % 1.16Oxygen CALC % 6.58CO2 FLS-D27 %

    Mineral matter CALC-BS % 32.7 32.6Gross calorific value FLS-E08ISO kJ/kg 20520 20458 21853 32113 33533

    FLS-E08ISO kcal/kg 4901 4886 5220 7670 8009Net calorific value FLS-E08ISO kJ/kg 19690 19623 21128 31047

    FLS-E08ISO kcal/kg 4703 4687 5046 7415K2O FLS-D13 % 0.39

    Na2O FLS-D13 % 0.03

    Chloride FLS-D07BS % 0.011Hardgrove grindability index FLS-I08ISO

    Wear Index FLS-I12BS mg/kg

    (total hydrogen - hidden) % 3.87Safety index CALC 1

    PARAMETER METHOD UNIT PARAMETER METHOD UNIT

    Fineness (s ieve open ings) nalyses of ash

    Residue on 40 mm Machine % SiO2 XRF % 65.26

    Residue on 25 mm Machine % Al2O3 XRF % 22.93

    Residue on 16 mm Machine % Fe2O3 XRF % 4.92

    Residue on 8 mm Machine % CaO XRF % 1.29

    Residue on 4 mm Machine % MgO XRF % 0.69

    Residue on 2 mm Machine % Mn2O3 XRF % 0.07

    Residue on 1 mm Machine % TiO2 XRF % 1.51

    Residue on 500 m Machine %P

    2O

    5 XRF % 0.16Residue on 250 m Alpine % SrO XRF % 0.03

    Residue on 200 m Alpine % LOI, 975 C % 0.74

    Residue on 90 m Alpine % TOTAL % 99.05

    Residue on 45 m Alpine %

    1.06

    1

    1.56

    1.63

    Analysis of solid fuel

    SAMPLE DESCRIPTION

    Case No: 20100035 2010-05-14 Page 1 of 1

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    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    07 Pet Coke Petcoke 20100035-07

    PARAMETER METHOD UNITAs analysed

    (air dried)As received Dry

    Dry,

    ash free

    Dry, mineral

    matter free

    AnalysisFree moisture FLS-B21BS % 0.6Moisture in air-dried sample FLS-E03BS % 0.9Total moisture CALC-BS % 1.5Volatile matter FLS-E03BS % 10.7 10.6 10.8 10.8 10.4Ash FLS-E03BS % 0.2 0.2 0.2Fixed Carbon CALC-BS % 88.2 87.7 89.0 89.2 89.6Carbon FLS-E10 % 87.2 86.7 88.0 88.2 90.6Hydrogen FLS-E10 % 3.65 3.63 3.68 3.69 3.86

    Sulphur FLS-E09BS % 4.87 4.84 4.91 4.92 1.43Nitrogen FLS-E10 % 1.79Oxygen CALC % 1.39CO2 FLS-D27 %

    Mineral matter CALC-BS % 2.9 2.9Gross calorific value FLS-E08ISO kJ/kg 35483 35270 35805 35878 36451

    FLS-E08ISO kcal/kg 8475 8424 8552 8569 8706Net calorific value FLS-E08ISO kJ/kg 34686 34463 35023 35094

    FLS-E08ISO kcal/kg 8285 8231 8365 8382K2O FLS-D13 %

    Na2O FLS-D13 %

    Chloride FLS-D07BS % 0.001Hardgrove grindability index FLS-I08ISO

    Wear Index FLS-I12BS mg/kg

    (total hydrogen - hidden) % 3.75Safety index CALC 8

    PARAMETER METHOD UNIT PARAMETER METHOD UNIT

    Fineness (sieve openings) Analyses of ash

    Residue on 40 mm Machine % SiO2 XRF %

    Residue on 25 mm Machine % Al2O3 XRF %

    Residue on 16 mm Machine % Fe2O3 XRF %

    Residue on 8 mm Machine % CaO XRF %

    Residue on 4 mm Machine % MgO XRF %

    Residue on 2 mm Machine % Mn2O3 XRF %

    Residue on 1 mm Machine % TiO2 XRF %Residue on 500 m Machine % P2O5 XRF %

    Residue on 250 m Alpine % SrO XRF %

    Residue on 200 m Alpine % LOI, 975 C %

    Residue on 90 m Alpine % TOTAL %

    Residue on 45 m Alpine %

    1.01

    0.99

    1.01

    1.04

    Analysis of solid fuel

    SAMPLE DESCRIPTION

    Case No: 20100035 2010-05-14 Page 1 of 1

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    RAW MIX CALCULATION

    PLANT: Grasim Cement, Raipur Encl.: 4.1

    CASE.NO.: Date:

    Raw Mix Calculation Mix 1

    Ed. 1, 29-03-2010 by DKS Clinker Mix M01 M02 M03 M04 F01 A01 F02 A02

    Mix [% dry] 100.00 96.29 1.00 1.61 1.10 100.00 0.00 100.00

    Mix [as analysed % wet] 100.00 96.29 1.00 1.61 1.10 100.00 0.00 100.00

    Mix [as fired % wet] 100.00 0.00 100.00H2O (analysed) [% (wb)] 0.00 0.00 0.00 0.00 0.00 6.10 6.60 6.10

    H2O (as fired) [% (wb)] 1.00 1.00 1.00

    SiO 2[%] 21.44 12.51 11.47 40.76 61.85 5.07 65.26 65.06 65.26

    Al2O 3 [%] 5.51 3.03 2.68 15.17 14.43 5.74 22.93 23.09 22.93

    Fe 2O 3 [%] 3.94 2.51 1.25 28.47 7.02 82.66 4.92 4.84 4.92

    CaO [%] 64.77 43.65 45.24 4.12 2.98 0.55 1.29 1.54 1.29

    MgO [%] 1.72 1.14 1.13 0.79 2.42 0.17 0.69 0.68 0.69

    Mn 2O 3 [%] 0.05 0.03 0.03 0.23 0.02 0.06 0.07 0.07 0.07

    TiO 2[%] 0.35 0.19 0.17 0.82 0.90 0.36 1.51 1.65 1.51

    P2O 5[%] 0.07 0.04 0.04 0.05 0.11 0.20 0.16 0.16 0.16

    K2O [%] 1.13 0.72 0.67 1.57 3.79 0.10 0.39 0.31 0.39

    Na 2O [%] 0.25 0.16 0.16 0.63 0.03 0.02 0.03

    SrO [%] 0.02 0.01 0.01 0.01 0.03 0.02 0.03

    SO 3 [%] 0.26 0.00

    LOI [%] 35.61 36.72 10.30 5.28 6.10 0.74 0.74 0.74Total [%] 99.51 99.61 99.57 102.28 99.44 101.01 97.60 97.85 97.60

    S Total [%] 0.11 0.02 0.02 0.01 0.26 0.04 0.47 0.48 0.47

    S Pyrite [%] 0.00

    Cl-[%] 0.010 0.006 0.006 0.001 0.002 0.002 0.011 0.007 0.011

    F-[%] 0.00 0.00 0.00

    Cr2O 3 [ppm] 0 0 0

    Ash [%] 4.55 30.00 28.50 30.00

    Hi (analysed) [kcal/kg] 4703 4713 4703

    Exp. kiln heat cons. [kcal/kg] 702.0

    LSF [%] 93.7 108.5 125.4 2.7 1.5 0.7

    MS 2.27 2.26 2.92 0.93 2.88 0.06

    MA 1.40 1.21 2.14 0.53 2.06 0.07

    Na 2O eq. [%] 0.99 0.64 0.60 1.03 3.12 0.07

    K2O eq. [%] 1.51 0.97 0.91 1.57 4.75 0.10

    C3S [%] 52.00 M01: Limestone

    C2S [%] 22.24 M02: ClayC3A [%] 7.93 M03: Shale

    C4AF [%] 11.99 M04: Iron ore

    C2F [%] 0.00 F01: Coal B

    Free CaO [%] 1.50 F02: Coal C

    Liq. Ph. 1450 C [%] 28.75

    Liq. Ph. 1338 C [%] 27.96

    M SO 3 0.23

    Exc. SO 3 [g/100 kg] 0

    Calc. rev. 08-01 / May 29, 2008 / CBMI

    20100035

    Total fuel+ash

    2010-05-14

    Case No.20100035 2010-05-14 Page 1 of 1

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    Encl.: 5.1

    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    09 Raw Mix for Burnability Raw Mix

    06.01 Coal Ash Coal Ash

    PARAMETER METHOD UNIT 09

    SiO2 FLS-D03 % 13.99

    Al2O3 FLS-D03 % 3.61

    Fe2O3 FLS-D03 % 2.59

    CaO FLS-D03 % 42.42

    MgO FLS-D03 % 1.12

    Mn2O3 FLS-D03 % 0.03

    TiO2 FLS-D03 % 0.23

    P2O5 FLS-D03 % 0.05K2O FLS-D03 % 0.73

    Na2O FLS-D03 % 0.10

    SrO FLS-D03 % 0.01

    LOI, 975 C FLS-D00 % 34.81

    TOTAL FLS-D03 % 99.69

    Fluoride FLS-D34 % 0.03

    C3S in Clinker (Free CaO=0) FLS-D03 % 59

    Lime saturation factor (LSF) FLS-D03 % 94

    Silica modulus (MS) FLS-D03 - 2.3

    Iron modulus (MA) FLS-D03 - 1.4

    PARAMETER METHOD UNIT Coarse Medium Fine

    Residue, 200 m, wet WET % 2.0 0.3 0.1

    Residue, 125 m, wet WET % 3.0

    Residue, 90 m, wet WET % 19.8 13.8 9.9

    Residue, 90 m, alpine ALPINE % 20.2 14.3 10.0

    Residue, 45 m, wet WET % 30.7

    Free CaO after burning at 1400 C FLS-D23 % 1.1 0.8 0.7

    Free CaO after burning at 1450 C FLS-D23 % 0.7 0.6 0.6

    Free CaO after burning at 1500 C FLS-D23 % 0.5 0.5 0.5

    Burnability Index FLS-D23 - 30 27 24Burnability Classification FLS-D23 - EASY EASY EASY

    Burnabi l i ty test on Raw Mix with Coal As h

    Burnability Test

    SAMPLE DESCRIPTION

    Character izat ion of Raw Mix w ith Coal As h (Coal Grade C)

    Fineness on Raw Mix

    20100035-06.01

    20100035-09

    Case No: 20100035 2010-05-14 Page 1 of 1

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    IndiaEncl.: 6.1

    SAMPLE DESCRIPTION

    ID SAMPLE NAME MATERIAL TYPE SAMPLE NUMBER

    09 Raw Mix

    06 Coal

    06.01 Coal Ash

    PARAMETER UNIT * RESULT PARAMETER UNIT RESULT

    Raw m ix Fuel: Coal

    SiO2 % 12.51 Fuel in percentage of clinker % 14.9

    Al2O3 % 3.03 Sulphur, total % 0.47

    Fe2O3 % 2.51 Ash in percentage of fuel % 30.0

    CaO % 43.65 Net calorific value ( Q net,p ) kJ/kg 19690

    MgO % 1.14 kcal/kg 4703

    SO3 % * 0.01 Heat consumption, clinker kJ/kg 2939

    Loss on ignition (LOI) % 35.61 kcal/kg 702

    TOTAL % 98.46 Analys is o f ash

    CO2 % * 34.86 SiO2 % 65.26

    K2O % 0.72Al2O3 % 22.93

    Na2O % 0.16 Fe2O3 % 4.92

    Sulphur, total % 0.02 CaO % 1.29

    Water of crystallisation % * 0.86 MgO % 0.69

    Carbon1) % * 0.05 K2O

    2) % 1.30

    Na2O2) % 0.10

    CaCO3 % 77.93 CaSO4 % 0.02

    MgCO3 % 1.09 Silica-combined CaO % 0.00Sulphur in pyrites % 0.02

    RAW MIX ADJUSTMENT

    PARAMETER UNIT RAW MIX ADJUSTMENT FUEL

    SiO2 % 12.51 1.97 14.48

    Al2O3 % 3.03 0.69 3.72

    Fe2O3 % 2.51 0.15 2.66

    CaO % 43.65 0.04 43.69

    MgO % 1.14 0.02 1.16

    SO3 (total) % 0.05 0.12 0.17

    K2O % 0.72 0.04 0.76

    Na2O % 0.16 0.00 0.16TOTAL % 63.77 3.03 T = 66.80

    SULPHUR BA LANCE AND RAW MIX / CLINKER RATIO

    Adjusted raw mix, total : T : 66.80

    Volatilised : U = 50 U : 0.02

    SO3 in clinker (calculated) : 0.22

    Raw mix / clinker ratio F : 1.50

    Remarks:

    * Analytical results

    1) Carbon as CO2is not included. 2) Calculated from analysis of solid fuel.

    (loss of dust = 0 %) : F = 100 / ( T U ) :

    % of sulphur in pyrites as SO3

    CALCULATED VALUES

    Heat of reaction

    ADJUSTED RAW MIX

    20100035-09Raw Mix for Burnability

    Coal Grade C

    Coal Ash

    20100035-06

    20100035-06.01

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    CALCULATIONSContent

    %

    Conversion factors

    kJ / kg / %

    RAWMIX

    kJ / kg

    CLINKER

    kJ / kg

    RAWMIXCaCO3 77.93 -17.78 -1386

    MgCO3 1.09 -15.10 -16

    Water of crystallisation 0.86 -42.70 -37

    Silica-combined CaO 0.00 -17.00 0

    Alkali silicates (K2O + Na2O) 0.88 -14.80 -13

    -1452 xF: -2174

    Heat of fo rmat ion

    Property Component Adj. RAWMIX

    C3S CaO 43.69 -0.46 -20

    C2S SiO2 14.48 21.43 310

    C3A Al2O3 3.72 1.21 5

    C4AF Fe2O3 2.66 2.46 7

    SO3 from fuel and pyrites 0.14 59.60 8

    309 xF: 463

    Heat of combus t ion

    Carbon 0.05 327.86 16

    Sulphur in pyrites 0.02 129.14 2

    18 xF: 28

    Heat of reactio n

    HEAT OF REACTION (A + B + C): -1683

    -402

    HEAT OF REACTION excl. HEAT OF COMBUSTION (A + B): -1711

    -409( kcal / kg clinker )

    Heat of combustion (C):

    ( kJ / kg clinker )

    ( kJ / kg clinker )

    ( kcal / kg clinker )

    Heat of reaction

    Heat of decompos it ion

    Heat of decomposition (A):

    Heat of formation (B):

    Encl.: 6.1

    Case No: 20100035 2010-05-14 Page 2 of 2

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    Encl.: 7.1 Page 1

    PLANT : Grasim Cement, Raipur Case. No.:MATERIAL : Rawmix Date :

    PROJECT : VRM No. :

    MILL FEED, COMPOSITION

    M1 : 96.29%

    M2 : 1.00%M3 : 1.61%

    M4: 1.10%

    SIEVE ANALYSIS - MOISTURE DETERMINATION :

    Sample Id. : M1 M2 M3 M4 M5 M6 M7 M8 MIX

    AS RECEIVED

    Moisture : (%)

    Sieve Residues :

    : (%)

    : (%)

    40 mm : (%)

    25 mm : (%)

    16 mm : (%)

    8 mm : (%)

    4 mm : (%) 2 mm : (%)

    1 mm : (%)

    500 m : (%)

    250 m : (%)

    200 m : (%)

    90 m : (%)

    45 m : (%)

    32 m : (%)

    AFTER PRECRUSHING, -25mm

    Moisture :

    +4 mm : (%)

    +4mm, max : (%)

    -4 mm : (%)

    -4 mm, max : (%)

    Sieve Residues :

    16 mm : (%)

    8 mm : (%)

    4 mm : (%)

    2 mm : (%)

    1 mm : (%)

    500 m : (%)

    250 m : (%)

    200 m : (%)

    90 m : (%)

    45 m : (%)

    32 m : (%)

    AFTER PRECRUSHING, -16 mm Mill Feed

    Sieve Residues :

    8 mm : (%) 8.424 mm : (%) 49.94

    2 mm : (%) 73.52

    1 mm : (%) 85.42

    500 m : (%) 91.91

    250 m : (%) 95.16

    200 m : (%) 95.54

    90 m : (%) 96.97

    45 m : (%)

    32 m : (%)

    et sieving :

    90 m : (%)

    45 m : (%)

    Spec. Surf. (m/kg)

    20100035

    2010-04-14

    ATOXIN10-11

    Limestone

    ClayShale

    Iron ore

    LABORATORY REPORT

    F.L.Smidth Research Center - Chennai, IndiaVERTICAL MILL

    Mill feed composition and Sieve analysis

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    Encl.: 7.1 Page 2

    PLANT : Grasim Cement, Raipur Case. No. :MATERIAL : Rawmix Date :

    PROJECT : RM No. :MILL FEED, COMPOSITION

    M1 : 96.29%

    M2 : 1.00%

    M3 : 1.61%

    M4: 1.10%

    TEST PARAMETERS

    Mill : Moisture :

    Revolutions : (rpm) 100 Mill feed : (%) 2.44

    Grind. pres. : (bar) 90 Product : (%) 0.17

    Grind. force : (kN) 26

    (kN/m) 596Gas :

    Quantity : (m/h) 996

    Temp out : (C) 91

    TEST RESULTS

    Period 1 2 3 4 5 6 7

    Separator : Static () 39 30 25 22

    Dyn. press. (mmWg) 238 238 239 238

    Grinding bed:

    Average for rollers: (mm)

    Power consumption :

    Mean : (kW) 4.46 4.56 4.65 4.77

    Total (spec.) : (kWh/t) 10.39 9.27 8.78 8.66

    Production :

    Total : (kg) 26.7 21.9 34.1 35.5

    Rate : (t/h) 0.429 0.492 0.530 0.550

    Sieve residue :

    90 m : (%) 7.2 14.2 21.0 26.0

    200 m : (%) 0.9 1.3 3.3 5.0

    Grinding constants :

    90 m : (kWh/t) 9.21 11.12 13.20 15.15

    200 m : (kWh/t) 5.10 4.94 6.02 6.77

    - Factor : 0.116 0.118 0.121 0.124

    ABRASION TEST

    Wear parts : brasion :

    Table : Cromin 15 Table : (g) 0.3Rollers : Cromin 15 Roller 1 : (g) 0.1

    Roller 2 : (g) 0.1

    Test time (h) 1.37 Roller 3 : (g) 0.2

    Average (net) (kW) 4.61 Total : (g) 0.7

    Ground mat. (t) 0.662

    Fineness, average : Table : (g/t) 0.5

    90 m (%) 18.1 Rollers : (g/t) 0.6

    TOTAL ABRASION 1.1 (g/t)

    .5 (g/h)

    .1 (g/kWh)

    20100035

    2010-04-14

    ATOXIN10-11

    Limestone

    Clay

    Shale

    Iron ore

    LABORATORY REPORT.

    F.L.Smidth Research Center - Chennai, IndiaVERTICAL MILL

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    Encl.: 7.1 Page 3

    PLANT : Grasim Cement, Raipur Case.No. :MATERIAL : Rawmix VRM No.: Date :

    PROJECT :

    20100035

    2010-04-14ATOXIN10-11

    y = 0.0059Ln(x) + 0.1036

    R2= 0.9261

    0.000

    0.010

    0.020

    0.030

    0.040

    0.050

    0.060

    0.070

    0.080

    0.090

    0.100

    0.110

    0.120

    0.130

    0.140

    0.150

    0.0 5.0 10.0 15.0 20.0 25.0

    Sieve residue 90 m, Alpine (%)

    -Factor

    Rawmix Log. (Rawmix)

    LABORATORY REPORT

    F.L.Smidth Research Center - Chennai, IndiaVERTICAL MILL

    -factor vs. Sieve residue on 90m

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    Encl.: 7.1 Page 5

    PLANT : Grasim Cement, Raipur Case.No. :MATERIAL : Rawmix VRM No.: Date :

    PROJECT :

    20100035

    2010-04-14ATOXIN10-11

    y = 0.3975e0.0132x

    R2= 0.9609

    0.00

    0.10

    0.20

    0.30

    0.40

    0.50

    0.60

    0.70

    0.80

    0.90

    1.00

    1.10

    1.20

    1.30

    1.40

    0.0 5.0 10.0 15.0 20.0 25.0

    Sieve residue 90 m, Alpine (%)

    Production(t/h)

    Rawmix Expon. (Rawmix)

    LABORATORY REPORT

    F.L.Smidth Research Center - Chennai, IndiaVERTICAL MILL

    Production rate vs. Sieve residue on 90m

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