page 2 / 9 · nioxin cleanser system emergency telephone transportation (24 hr) chemtrec -...

Revision Date: 26-Apr-2012 Version 1

Material Safety Data Sheet

Issuing Date: 26-Apr-2012

Recommended use Personal Beauty Care Product

Manufacturer The Procter & Gamble CompanySharon Woods Technical Center11510 Reed Hartman HighwayCincinnati OH 45202.

OSHA Regulatory Status This material is not considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200)

1. PRODUCT AND COMPANY IDENTIFICATION

E-mail Address [email protected].

WHMIS Not subject to WHMIS classification

Product Name

Uses advised against All other uses

Principle Routes of Exposure Eye contact. Skin contact.

Nioxin Cleanser System

Emergency telephone Transportation (24 HR)CHEMTREC - 1-800-424-9300(U.S./ Canada) or 1-703-527-3887Mexico toll free in country: 01-800-681-9531.

Product ID:

General Hazards This is a personal care or cosmetic product that is safe for consumers and other usersunder normal and reasonably foreseeable use

92061445

2. HAZARDS IDENTIFICATION

_____________________________________________________________________________________________

Synonyms Nioxin Cleanser System 1 (92061445) * Nioxin Cleanser 2 (92061451) * Nioxin Cleanser 3(99426531) * Nioxin Cleanser 4 (92046875) * Nioxin Cleanser 5 (99473379) * NioxinCleanser 6 (99473380)

Emergency Overview

/ 9

Irritating to eyes

_____________________________________________________________________________________________92061445 - Nioxin Cleanser System Revision Date: 26-Apr-2012

Suitable Extinguishing Media

Special protective equipment forfire-fighters

As in any fire, wear self-contained breathing apparatus and full protective gear.

Dry chemical, CO 2, water spray or alcohol-resistant foam.

Flash Point

Unsuitable Extinguishing Media No information available.

Not applicable

5. FIRE-FIGHTING MEASURES

Special Hazard None in particular

1 - 5

General advice No hazards which require special first aid measures. When symptoms persist or in all casesof doubt seek medical advice.

Laureth-3 3055-94-5

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Ifsymptoms persist, call a physician. Remove contact lenses, if present, after the first 5minutes, then continue rinsing.

0.1 - 1

Poly(oxy-1,2-ethanediyl),alpha-sulfo-omega-(dodecyloxy)-, sodium salt (1:1)

9004-82-4

Sodium hydroxide (Na(OH))

Skin contact If skin problems occur, discontinue use. If symptoms persist, call a physician.

1310-73-2 0.1 - 1

5 - 10

Ingestion Clean mouth with water and afterwards drink plenty of water.

Mentha Arvensis Oil 68917-18-0 0.1 - 1

Inhalation Not an expected route of exposure.

Sulfuric acid monododecyl ester sodium salt (1:1)

1,2,3-Propanetriol 56-81-5 < 0.1

Protection of First-aiders Use personal protective equipment.

151-21-3 3 - 7

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name

Most important symptoms/effects,acute and delayed

None known.

1-Propanaminium,3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-coco

acyl derivs., inner salts

61789-40-0 1 - 5

CAS-No

Notes to physician Treat symptomatically.

4. FIRST AID MEASURES

Weight %

_____________________________________________________________________________________________

Citric acid

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77-92-9

_____________________________________________________________________________________________Revision Date: 26-Apr-201292061445 - Nioxin Cleanser System

Exposure Guidelines

Technical measures/Storageconditions

Keep out of the reach of children. Keep container tightly closed in a dry and well-ventilatedplace.

Engineering Measures Not applicable

Advice on safe handling

Chemical Name

Personal Protective Equipment

ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL

Eye Protection No special protective equipment required.

Keep out of the reach of children. Observe label precautions.

Sodium hydroxide(Na(OH))

Ceiling: 2 mg/m3

Hand Protection No special protective equipment required.

TWA: 2 mg/m3

(vacated) Ceiling: 2 mg/m3

IDLH: 10 mg/m3

Ceiling: 2 mg/m3

Mexico: Ceiling 2 mg/m3

Skin and body protection No special protective equipment required.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

1,2,3-Propanetriol TWA: 10 mg/m3 mist TWA: 15 mg/m3 mist, totalparticulate TWA: 5 mg/m3

mist, respirable fraction(vacated) TWA: 10 mg/m3

mist, total particulate(vacated) TWA: 5 mg/m3

mist, respirable fraction

Respiratory protection No special protective equipment required

Mexico: TWA 10 mg/m3

Thermal hazards Not applicable.

Chemical Name British Columbia Alberta Quebec

Hygiene measures Avoid contact with skin, eyes and clothing.

Ontario TWAEV


Environmental Exposure Controls No special environmental precautions required.

Ceiling: 2 mg/m3 Ceiling: 2 mg/m3 Ceiling: 2 mg/m3 CEV: 2 mg/m3

7. HANDLING AND STORAGE

1,2,3-Propanetriol TWA: 10 mg/m3 TWA: 3mg/m3

TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 10 mg/m3

Personal precautions

Advice for emergency responders Use personal protective equipment.

Methods for Containment No information available.

None under normal use conditions.

_____________________________________________________________________________________________

6. ACCIDENTAL RELEASE MEASURES

Methods for Cleaning up No information available.

/ 9

Environmental precautions Should not be released into the environment.


Chemical Name logPow

9. PHYSICAL AND CHEMICAL PROPERTIES

Sulfuric acid monododecyl ester sodium salt (1:1) 1.6Citric acid -1.72 at 20 °C

Appearance

Dodecanol (Alcohol C12) 5.361,2,3-Propanetriol -1.76VOC Content Products comply with US state and federal regulations for VOC content in consumer

products.

viscous liquidblue (cleansers 1 -4)clear (cleansers 5, 6)

10. STABILITY AND REACTIVITY

Reactivity None under normal use conditions.

Stability Stable under normal conditions.

Hazardous Polymerization Hazardous polymerization does not occur.

Physical State @20°C

Odor

Hazardous Reactions None under normal processing.

Conditions to Avoid None under normal processing.

Mint-like, Fruity

Materials to Avoid None in particular.

Hazardous Decomposition Products None under normal use.

liquid

.

Boiling point/boiling range

Soluble in water

.

Vapor pressure

Viscosity of Product

.

.

Values

No information available

Not applicable


Solubility in other solvents

.

pH VALUE

Flammability (solid, gas)

.

Bulk Density


upper flammability limit

Not applicable 100 °C


.

Vapor density

.


Partition coefficient: n-octanol/water


Note

Not applicable


.

.

.

.Evaporation rate

.

Autoignition temperature

Relative density

lower flammability limit


Property

1.0

Flammability Limits in Air

.

Melting/freezing point


.

_____________________________________________________________________________________________


Decomposition temperature

Flash Point

4.6 - 5.2

/ 9

Water solubility



Eye contact Irritating to eyes.

Sensitization No known effect.

Inhalation

Neurological Effects No known effect.Reproductive Toxicity The product contains no substances known to be hazardous to health in concentrations

which need to be taken into account.

No known effect based on information supplied.

Mutagenic Effects There are no known mutagenic chemicals in this product.Developmental Toxicity No known effect.Teratogenicity No known effect.

Principle Routes of Exposure Eye contact. Skin contact.

Carcinogenicity Contains no ingredients above reportable quantities listed as a carcinogen.

Skin contact No known effect based on information supplied.

11. TOXICOLOGICAL INFORMATION

Ingestion

Chronic Toxicity

_____________________________________________________________________________________________


Acute Toxicity

/ 9

Corrosivity No known effect.


EC50 48 h = 1.8 mg/LDaphnia magna

= 53 mg/L EC50 30 -100 mg/L EC50 = 117

mg/L EC50 3.59 -15.6 mg/L EC50

-

Acute Toxicity

1-Propanaminium,3-amino-N-(carboxymethyl)-N,N-dimethyl-, N-coco acyl

derivs., inner salts

EC50 72 h 1.0 - 10.0mg/L Desmodesmussubspicatus EC50 96

h = 0.55 mg/LDesmodesmus

subspicatus

LC50 96 h 1.0 - 10.0mg/L Brachydaniorerio LC50 96 h = 2mg/L Brachydaniorerio semi-static

- EC50 48 h = 6.5 mg/LDaphnia magna

1.0 - 10.0 mg/L EC50= 0.55 mg/L EC50

-

Citric acid - LC50 96 h = 1516mg/L Lepomis

macrochirus static

- EC50 72 h = 120 mg/LDaphnia magna

-

12. ECOLOGICAL INFORMATION

Chemical Name Toxicity to algae Toxicity to fish Toxicity tomicroorganisms

_____________________________________________________________________________________________

Toxicity to daphniaand other aquatic

invertebrates

Toxicity to otherorganisms

Ecotoxicity

/ 9

Sulfuric acid monododecylester sodium salt (1:1)

EC50 72 h = 53 mg/LDesmodesmus

subspicatus EC50 96h 30 - 100 mg/LDesmodesmus

subspicatus EC50 96h = 117 mg/L

Pseudokirchneriellasubcapitata EC50 96 h

3.59 - 15.6 mg/LPseudokirchneriellasubcapitata static

LC50 96 h 8 - 12.5mg/L Pimephales

promelas static LC5096 h 15 - 18.9 mg/L

Pimephales promelasstatic LC50 96 h 22.1

- 22.8 mg/LPimephales promelasstatic LC50 96 h 4.3 -

8.5 mg/LOncorhynchus mykiss

static LC50 96 h =4.62 mg/L

Oncorhynchus mykissflow-through LC50 96

h = 4.2 mg/LOncorhynchus mykissLC50 96 h = 7.97 mg/L

Brachydanio rerioflow-through LC50 96

h 9.9 - 20.1 mg/LBrachydanio rerio

semi-static LC50 96 h4.06 - 5.75 mg/L

Lepomis macrochirusstatic LC50 96 h 4.2 -

4.8 mg/L Lepomismacrochirus

flow-through LC50 96h = 4.5 mg/L Lepomismacrochirus LC50 96

h 5.8 - 7.5 mg/LPimephales promelasstatic LC50 96 h 10.2

- 22.5 mg/LPimephales promelassemi-static LC50 96 h

6.2 - 9.6 mg/LPimephales promelasLC50 96 h 13.5 - 18.3

mg/L Poeciliareticulata semi-static

LC50 96 h 10.8 - 16.6mg/L Poecilia

reticulata static LC5096 h = 1.31 mg/LCyprinus carpio

semi-static

-


15. REGULATORY INFORMATION

14. TRANSPORT INFORMATION

MEX

U.S. Federal Regulations

Not regulated

DOT

SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.

Not regulated

IATA

SARA 311/312 Hazard Categories

Not regulated

Acute Health Hazard noChronic Health Hazard noFire Hazard no

ICAO Not regulated

TDG Not regulated

IMDG/IMO Not regulated

Sodium hydroxide (Na(OH)) -

Persistence and degradability No information available.

Dodecanol (Alcohol C12) EC50 96 h = 0.62mg/L Desmodesmus

subspicatus

LC50 96 h = 1.01 mg/LPimephales promelasflow-through LC50 96

h = 0.1855 mg/LPimephales promelas

13. DISPOSAL CONSIDERATIONS

-

Bioaccumulative potential No information available.

EC50 48 h = 320 mg/LDaphnia magna

= 0.62 mg/L EC50

-

Waste from Residues / UnusedProducts

Household: Do not discharge product into natural waters without pre-treatment oradequate dilution.

LC50 96 h = 45.4 mg/LOncorhynchus mykiss

static

-

Contaminated packaging Dispose of in accordance with local regulations.

1,2,3-Propanetriol -

Mobility No information available.

LC50 96 h 51 - 57mL/L Oncorhynchus

mykiss static

- EC50 24 h > 500 mg/LDaphnia magna

-

_____________________________________________________________________________________________

- -

Other adverse effects

/ 9



Chemical Name Pennsylvania

Sudden Release of Pressure Hazard

Sulfuric acid sodium salt (1:2) X

Sodium hydroxide (Na(OH))

Chemical Name

Sodium hydroxide (Na(OH)) X

CWA - ReportableQuantities

CWA - Toxic Pollutants CWA - Priority Pollutants CWA - HazardousSubstances

1000 lb -

International Regulations


1000 lb - -

Canada

X

RQ 1000 lb final RQ RQ 454 kgfinal RQ

WHMIS Hazard ClassNot subject to WHMIS classification

U.S. State Regulations

CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substance under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and theMSDS contains all the information required by the CPR. This product is regulated by the Food and Drug Administration of HealthCanada and is therefore exempt from the requirements of CEPA.

Food and Drug Administration (FDA)The product described in this Material Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safeto use as per directions on container, box or accompanying literature (where applicable).

Reactive Hazard no

California Proposition 65This product is not subject to warning labeling under California Proposition 65

International Inventories

no

TSCA Exempt

Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air ActAmendments of 1990.


DSL Exempt

Chemical Name

NDSL Exempt

Hazardous Substances RQs

_____________________________________________________________________________________________

Extremely HazardousSubstances RQs

Clean Water ActThis product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21and 40 CFR 122.42):

/ 9

RQ


Legend

Perfumes contained with the products comply with appropriate IFRA guidance.

DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances ListTSCA - United States Toxic Substances Control Act Section 8(b) Inventory

16. OTHER INFORMATION

Issuing Date:

DisclaimerThe information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of itspublication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any other materials or in any process, unlessspecified in the text

_____________________________________________________________________________________________

26-Apr-2012

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Revision Date:

End of MSDS

26-Apr-2012

Issuing Date: 06-Jun-2012 Revision Date: 06-Jun-2012 Version 1



Manufacturer

OSHA Regulatory Status Consumer Products as defined by the U.S. Consumer Product Safety Act which are usedas intended (typical consumer duration and frequency) are exempt from the OSHA HazardCommunication Standard

The Procter & Gamble CompanySharon Woods Innovation Center11510 Reed Hartman HighwayCincinnati OH 45202



E-mail Address [email protected]

Principle Routes of Exposure Skin contact. Eye contact.

Product Name



Nioxin Scalp Therapy 1

Emergency telephone Transportation (24 HR)CHEMTREC - 1-800-424-9300(U.S./ Canada) or 1-703-527-3887Mexico toll free in country: 01-800-681-9531

Product ID:

_____________________________________________________________________________________________

92245785


Page 1 / 9

Synonyms System 1 Conditioner

Emergency Overview

_____________________________________________________________________________________________92245785 - Nioxin Scalp Therapy 1 Revision Date: 06-Jun-2012





Flash Point





1 - 5Quaternary ammonium compounds,

bis(hydrogenated tallow alkyl)dimethyl, chlorides



61789-80-8 0.1 - 1



Chemical Name


None known.


Mentha Arvensis Oil 68917-18-0


0.1 - 1

CAS-No


Weight %

glycerol 1-stearate 123-94-4 0.1 - 1

Skin contact

_____________________________________________________________________________________________

If skin problems occur, discontinue use. If symptoms persist, call a physician.

Page 2 / 9

Octadecanamide, N-[3-(dimethylamino)propyl]- 7651-02-7


_____________________________________________________________________________________________Revision Date: 06-Jun-201292245785 - Nioxin Scalp Therapy 1


Chemical Name





glycerol 1-stearate TWA: 10 mg/m3 exceptstearates of toxic metals


- -



Chemical Name British Columbia Alberta


Quebec Ontario TWAEV

Hygiene measures None under normal use condtions.

glycerol 1-stearate TWA: 10 mg/m3 TWA: 10 mg/m3 -

Environmental Exposure Controls See Section 6.

TWA: 10 mg/m3


Engineering Measures Not applicable.

Exposure Guidelines


Keep out of the reach of children. Keep containers tightly closed in a dry, cool andwell-ventilated place.





Methods for Containment

_____________________________________________________________________________________________

No information available.

Use personal protective equipment.

Page 3 / 9




VOC Content Products comply with US state and federal regulations for VOC content in consumerproducts.


Appearance


blue. viscous liquid .







Odor



Mint-like

liquid


Property

0.96


.





Flash Point

5

Water solubility

No information available .



Vapor pressure


Values





pH VALUE


Bulk Density



No information availableNo information available


Vapor density




Note



_____________________________________________________________________________________________

Evaporation rate

Page 4 / 9


Relative density



1240 mg/kg ( Rat ) 5 g/kg ( Rabbit ) -


Chronic Toxicity


Ingestion




Principle Routes of Exposure

Neurological Effects No known effect.

Eye contact No known effect based on information supplied.

Reproductive Toxicity The product contains no substances known to be hazardous to health in concentrationswhich need to be taken into account.

Skin contact. Eye contact.

Mutagenic Effects There are no known mutagenic chemicals in this product.Developmental Toxicity No known effect.

Product Information

Teratogenicity No known effect.Carcinogenicity Contains no ingredients above reportable quantities listed as a carcinogen.

Acute Toxicity Product does not present an acute toxicity hazard based on known or supplied information.

Inhalation

Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation


_____________________________________________________________________________________________

Quaternary ammoniumcompounds, bis(hydrogenatedtallow alkyl)dimethyl, chlorides

2000 mg/kg ( Rat ) 2000 mg/kg ( Rat )

Page 5 / 9

180 mg/L ( Rat ) 1 h

Mentha Arvensis Oil


Packing Group IIIDescription UN3082, Environmentally hazardous substance, liquid, n.o.s (Quaternary ammonium

compounds, bis(hydrogenated tallow alkyl)dimethyl, chlorides, Mentha Arvensis Oil), 9, III,

TDG

MEX UN/ID No UN3082Proper shipping name Environmentally hazardous substances, liquid, n.o.s.

UN/ID No UN3082

Hazard class 9


Packing Group III

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

DOT

Hazard class 9

Not regulated



Dispose of in accordance with local regulations.

Chemical Name Bioconcentration factor (BCF)

Ecotoxicity


Quaternary ammonium compounds, bis(hydrogenated tallow alkyl)dimethyl,chlorides

13

Quaternary ammoniumcompounds,

bis(hydrogenated tallowalkyl)dimethyl, chlorides

EC50 96 h = 0.1 mg/LDesmodesmus

subspicatus EC50 72h = 0.00046 mg/L

Pseudokirchneriellasubcapitata

LC50 96 h = 1.48 mg/LBrachydanio rerio

static

-


EC50 48 h = 0.32mg/L Daphnia magna

= 0.1 mg/L EC50 =0.00046 mg/L EC50

-

Acute Toxicity

Other adverse effects No information available



Chemical Name Toxicity to algae

Bioaccumulative potential



_____________________________________________________________________________________________

Toxicity to fish Toxicity tomicroorganisms

Page 6 / 9


invertebrates


UN3082, Environmentally hazardous substance, liquid, n.o.s (Quaternary ammoniumcompounds, bis(hydrogenated tallow alkyl)dimethyl, chlorides, Mentha Arvensis Oil), 9, III

Packing Group III

UN3082, Environmentally hazardous substance, liquid, n.o.s (Quaternary ammoniumcompounds, bis(hydrogenated tallow alkyl)dimethyl, chlorides, Mentha Arvensis Oil), 9, III,

EmS No. F-A, S-FDescription UN3082, Environmentally hazardous substance, liquid, n.o.s (Quaternary ammonium


Proper shipping name

ICAO

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

15. REGULATORY INFORMATIONU.S. Federal Regulations

UN/ID No UN3082

IATA



Hazard class


9

Acute Health Hazard no

Hazard class 9

Chronic Health Hazard no

Description

Fire Hazard no

Packing Group

Sudden Release of Pressure Hazard no

III

Reactive Hazard no

Packing Group

Description UN3082, Environmentally hazardous substance, liquid, n.o.s (Quaternary ammoniumcompounds, bis(hydrogenated tallow alkyl)dimethyl, chlorides, Mentha Arvensis Oil), 9, III,


III

Chemical Name Hazardous Substances RQs Extremely HazardousSubstances RQs

RQ

Edetic acid 5000 lb - RQ 5000 lb final RQ RQ 2270kg final RQ

IMDG/IMO


ERG Code 9L

UN/ID No


UN3082

UN/ID No UN3082

_____________________________________________________________________________________________


Page 7 / 9

Description

Hazard class 9


CWA - Toxic Pollutants

TSCA Exempt

Edetic acid

DSL Exempt

X

CWA - Priority Pollutants

NDSL Exempt

CWA - HazardousSubstances



Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory


DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List

Edetic acid 5000 lb


Canada

- -


X



Chemical Name





06-Jun-2012


Issuing Date:

_____________________________________________________________________________________________


06-Jun-2012

Page 8 / 9

Revision Date:

End of MSDS




Manufacturer







Product Name





Product ID:

_____________________________________________________________________________________________

92245783


Page 1 / 9


Emergency Overview






Flash Point









61789-80-8 0.1 - 1



Chemical Name


None known.


glycerol 1-stearate 123-94-4


0.1 - 1

CAS-No


Weight %


Skin contact

_____________________________________________________________________________________________


Page 2 / 9





Chemical Name







- -









TWA: 10 mg/m3



Exposure Guidelines








_____________________________________________________________________________________________



Page 3 / 9






Appearance


viscous liquid .







Odor



Mint-like

liquid


Property

0.96


.





Flash Point

5

Water solubility




Vapor pressure


Values





pH VALUE


Bulk Density





Vapor density




Note



_____________________________________________________________________________________________

Evaporation rate

Page 4 / 9


Relative density





Chronic Toxicity


Ingestion










Product Information



Inhalation



_____________________________________________________________________________________________


2000 mg/kg ( Rat ) 2000 mg/kg ( Rat )

Page 5 / 9

180 mg/L ( Rat ) 1 h

Mentha Arvensis Oil




TDG


UN/ID No UN3082

Hazard class 9


Packing Group III


DOT

Hazard class 9

Not regulated





Ecotoxicity



13







static

-



= 0.1 mg/L EC50 =0.00046 mg/L EC50

-

Acute Toxicity








_____________________________________________________________________________________________


Page 6 / 9


invertebrates



Packing Group III





ICAO



UN/ID No UN3082

IATA



Hazard class


9


Hazard class 9


Description

Fire Hazard no

Packing Group


III

Reactive Hazard no

Packing Group



III


RQ


IMDG/IMO


ERG Code 9L

UN/ID No


UN3082

UN/ID No UN3082

_____________________________________________________________________________________________


Page 7 / 9

Description

Hazard class 9



TSCA Exempt

Edetic acid

DSL Exempt

X


NDSL Exempt







Edetic acid 5000 lb


Canada

- -


X



Chemical Name





06-Jun-2012


Issuing Date:

_____________________________________________________________________________________________


06-Jun-2012

Page 8 / 9

Revision Date:

End of MSDS




Manufacturer







Product Name





Product ID:

_____________________________________________________________________________________________

92245786


Page 1 / 9


Emergency Overview






Flash Point









61789-80-8 0.1 - 1



Chemical Name


None known.


Mentha Arvensis Oil 68917-18-0


0.1 - 1

CAS-No


Weight %

glycerol 1-stearate 123-94-4 0.1 - 1

Skin contact

_____________________________________________________________________________________________


Page 2 / 9





Chemical Name







- -









TWA: 10 mg/m3



Exposure Guidelines








_____________________________________________________________________________________________



Page 3 / 9






Appearance









Odor



Mint-like

liquid


Property

0.96


.





Flash Point

5

Water solubility




Vapor pressure


Values





pH VALUE


Bulk Density





Vapor density




Note



_____________________________________________________________________________________________

Evaporation rate

Page 4 / 9


Relative density





Chronic Toxicity


Ingestion










Product Information



Inhalation



_____________________________________________________________________________________________


2000 mg/kg ( Rat ) 2000 mg/kg ( Rat )

Page 5 / 9

180 mg/L ( Rat ) 1 h

Mentha Arvensis Oil



compounds, bis(hydrogenated tallow alkyl)dimethyl, chlorides, Mentha Arvensis Oil), 9, III

TDG


UN/ID No UN3082

Hazard class 9


Packing Group III


DOT

Hazard class 9

Not regulated





Ecotoxicity



13







static

-



= 0.1 mg/L EC50 =0.00046 mg/L EC50

-

Acute Toxicity








_____________________________________________________________________________________________


Page 6 / 9


invertebrates



Packing Group III



compounds, bis(hydrogenated tallow alkyl)dimethyl, chlorides, Mentha Arvensis Oil), 9, III


ICAO



UN/ID No UN3082

IATA



Hazard class


9


Hazard class 9


Description

Fire Hazard no

Packing Group


III

Reactive Hazard no

Packing Group

Description UN3082, Environmentally hazardous substance, liquid, n.o.s (Quaternary ammoniumcompounds, bis(hydrogenated tallow alkyl)dimethyl, chlorides, Mentha Arvensis Oil), 9, III


III


RQ


IMDG/IMO


ERG Code 9L

UN/ID No


UN3082

UN/ID No UN3082

_____________________________________________________________________________________________


Page 7 / 9

Description

Hazard class 9



TSCA Exempt

Edetic acid

DSL Exempt

X


NDSL Exempt







Edetic acid 5000 lb


Canada

- -


X



Chemical Name





06-Jun-2012


Issuing Date:

_____________________________________________________________________________________________


06-Jun-2012

Page 8 / 9

Revision Date:

End of MSDS




Manufacturer







Product Name





Product ID:

_____________________________________________________________________________________________

92245784


Page 1 / 9


Emergency Overview






Flash Point









61789-80-8 0.1 - 1



Chemical Name


None known.


glycerol 1-stearate 123-94-4


0.1 - 1

CAS-No


Weight %


Skin contact

_____________________________________________________________________________________________


Page 2 / 9





Chemical Name







- -









TWA: 10 mg/m3



Exposure Guidelines








_____________________________________________________________________________________________



Page 3 / 9






Appearance









Odor



Mint-like

liquid


Property

0.96


.





Flash Point

5

Water solubility




Vapor pressure


Values





pH VALUE


Bulk Density





Vapor density




Note



_____________________________________________________________________________________________

Evaporation rate

Page 4 / 9


Relative density





Chronic Toxicity


Ingestion










Product Information



Inhalation



_____________________________________________________________________________________________


2000 mg/kg ( Rat ) 2000 mg/kg ( Rat )

Page 5 / 9

180 mg/L ( Rat ) 1 h

Mentha Arvensis Oil




TDG


UN/ID No UN3082

Hazard class 9


Packing Group III


DOT

Hazard class 9

Not regulated





Ecotoxicity



13







static

-



= 0.1 mg/L EC50 =0.00046 mg/L EC50

-

Acute Toxicity








_____________________________________________________________________________________________


Page 6 / 9


invertebrates



Packing Group III





ICAO



UN/ID No UN3082

IATA



Hazard class


9


Hazard class 9


Description

Fire Hazard no

Packing Group


III

Reactive Hazard no

Packing Group



III


RQ


IMDG/IMO


ERG Code 9L

UN/ID No


UN3082

UN/ID No UN3082

_____________________________________________________________________________________________


Page 7 / 9

Description

Hazard class 9



TSCA Exempt

Edetic acid

DSL Exempt

X


NDSL Exempt







Edetic acid 5000 lb


Canada

- -


X



Chemical Name





06-Jun-2012


Issuing Date:

_____________________________________________________________________________________________


06-Jun-2012

Page 8 / 9

Revision Date:

End of MSDS


Issuing Date: 27-May-2014 Revision Date: 27-May-2014 Version 1

1. PRODUCT AND COMPANY INFORMATION

Product ID: 98740661_NA

Product Name NIOXIN Scalp Optimizing Cleanser

Product Type Finished Product - Consumer (Retail) and Professional Use

Recommended Use Personal Beauty Care Product

Synonyms No information available

Manufacturer The Procter & Gamble CompanySharon Woods Innovation Center11510 Reed HartmanHighwayCincinnati OH 45241


Emergency Telephone Transportation (24 HR)CHEMTREC - 1-800-424-9300(U.S./ Canada) or 1-703-527-3887Mexico toll free in country: 800-681-9531

2. HAZARDS IDENTIFICATIONEmergency Overview Irritating to eyes

OSHA regulatory status Consumer Products as defined by the U.S. Consumer Product Safety Act which are usedas intended (typical consumer duration and frequency) are exempt from the OSHA HazardCommunication Standard. When used in a professional setting (at a much higher frequencyand duration than a typical consumer) this material would be considered hazardous by theOSHA Hazard Communication Standard (29 CFR 1910.1200).

WHMIS Not subject to WHMIS classification.

_____________________________________________________________________________________________

Principle routes of exposure Eye contact.

General hazards

Page 1 / 9

This is a personal care or cosmetic product that is safe for consumers and other usersunder normal and reasonably foreseeable use.

_____________________________________________________________________________________________98740661_NA - NIOXIN Scalp Optimizing Cleanser Revision Date: 27-May-2014



Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Ifsymptoms persist, call a physician.


Ingestion Clean mouth with water and afterwards drink plenty of water. Do NOT induce vomiting. Ifsymptoms persist, call a physician.

Inhalation Move to fresh air.

Protection of first-aiders Use personal protective equipment.


None known.

Notes to Physician Treat symptomatically.


Flash point Not Applicable

Suitable extinguishing media Dry chemical, CO 2, water spray or alcohol-resistant foam.

Extinguishing media which shall notbe used for safety reasons


Special hazard None known based on information supplied.


As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent) and full protective gear.


Personal precautions Avoid contact with the skin and the eyes.


Environmental precautions Household: Do not discharge product into natural waters without pre-treatment oradequate dilution. Non-household: Should not be released into the environment.


Hazardous ingredients

Chemical Name CAS-No Weight %Poly(oxy-1,2-ethanediyl),

alpha-sulfo-omega-(dodecyloxy)-, sodium salt (1:1)9004-82-4 5 - 10

Sulfuric acid monododecyl ester sodium salt (1:1) 151-21-3 3 - 7Amides, coco, N-hydroxyethyl 68140-00-1

_____________________________________________________________________________________________

1 - 5Zinc,

bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-, (T-4)-

13463-41-7 1 - 5

Page 2 / 9


Methods for containment Non-household: Prevent further leakage or spillage if safe to do so. Prevent product fromentering drains.

Methods for cleaning up Non-household: Contain spillage, and then collect with non-combustible absorbentmaterial, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container fordisposal according to local / national regulations (see section 13).


Advice on safe handling Keep out of the reach of children. Observe label precautions.




Exposure Guidelines

Chemical Name CAS-No ACGIH TLV OSHA PEL Mexico PELZinc oxide 1314-13-2 STEL: 10 mg/m3 respirable

fractionTWA: 2 mg/m3 respirable

fraction

TWA: 5 mg/m3 fumeTWA: 15 mg/m3 total dustTWA: 5 mg/m3 respirable

fraction(vacated) TWA: 5 mg/m3

fume(vacated) TWA: 10 mg/m3

total dust(vacated) TWA: 5 mg/m3

respirable fraction(vacated) STEL: 10 mg/m3

fume

Mexico: TWA 5 mg/m3

Mexico: TWA 10 mg/m3

Mexico: STEL 10 mg/m3

Chemical Name CAS-No Alberta Quebec Ontario TWAEV British ColumbiaZinc oxide 1314-13-2 TWA: 2 mg/m3

STEL: 10 mg/m3

TWA: 10 mg/m3

TWA: 5 mg/m3

STEL: 10 mg/m3

TWA: 2 mg/m3

STEL: 10 mg/m3

TWA: 2 mg/m3

STEL: 10 mg/m3

Legend: TLV - Threshold Limit ValueTWAEV - Time Weighted Average Exposure ValueACGIH: (American Conference of Governmental Industrial Hygienists)OSHA: (Occupational Safety & Health Administration)PEL - Permissible Exposure Limit



Eye Protection If splashes are likely to occur, wear:. Safety glasses with side-shields.


Skin and Body Protection No special protective equipment required.

Respiratory Protection No special protective equipment required.

Thermal hazards

_____________________________________________________________________________________________

Not applicable.

Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Use personalprotective equipment as required.

Page 3 / 9

Environmental exposure controls See section 6 for more information.



Physical State @20°C liquidAppearance white. opaque. viscous liquid.Odor Mint-like

Chemical Name Partition Coefficient (n-octanol/water)Sulfuric acid monododecyl ester sodium salt (1:1) < -2.03Zinc, bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-,(T-4)-

0.9

VOC Content (%) Products comply with US state and federal regulations for VOC content in consumerproducts.

Oxidizing properties No information available




Hazardous polymerization Hazardous polymerization does not occur.



Materials to avoid None in particular.


Property Values Note pH value 6.5 - 8.3Melting/freezing point No information availableBoiling point/boiling range No information availableFlash point Not ApplicableEvaporation rate No information availableflammability (solid, gas) No information availableFlammability Limits in AirUpper flammability limit No information availableLower Flammability Limit No information available

Vapor pressure No information availableVapor density No information availableRelative density No information availableWater solubility No information availableSolubility in other solvents No information availablePartition coefficient: n-octanol/waterNo information availableAutoignition temperature No information available .Decomposition temperature No information available

_____________________________________________________________________________________________

.Viscosity of Product No information available

Page 4 / 9

Bulk Density No information available



Product Information

Acute toxicity Irritating to eyes.

Principle routes of exposure Eye contact.

Inhalation No known effect based on information supplied.Skin contact No known effect based on information supplied.Ingestion No known effect based on information supplied.Eye contact Irritating to eyes.

Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 InhalationSulfuric acid monododecyl ester

sodium salt (1:1)151-21-3 977 mg/kg bw (OECD

401; rat)> 500 mg/kg bw (Read

across dataC10-16ASO4, NH4;guideline: Standard

Procedure #10; fixeddose procedure; rabbit;

based on activeingredient)

-

Zinc,bis[1-(hydroxy-kappaO)-2(1H)-pyridine

thionato-kappaS2]-, (T-4)-

13463-41-7 269 mg/kg bw (OECD401, rat)

> 2000 mg/kg bw (EPAOPP 81-2, rat)

1.03 mg/L air (OECD403, rat)

Zinc oxide 1314-13-2 > 5000 mg/kg bw (Similarto OECD 401; standard

acute method; rat)

> 2000 mg/kg bw (OECD402; standard acute

method; rat)

> 5.7 mg/L air (Similar toOECD 403; standard

acute method; rat; 4 h)Chronic Toxicity

Corrosivity No known effect.Sensitization No known effect.Neurological Effects No known effect.Reproductive toxicity The product contains no substances known to be hazardous to health in concentrations

which need to be taken into account.Germ cell mutagenicity There are no known mutagenic chemicals in this product.

_____________________________________________________________________________________________

Developmental toxicity No known effect.Teratogenicity

Page 5 / 9

No known effect.Carcinogenicity Contains no ingredients above reportable quantities listed as a carcinogen.



Ecotoxicity

Chemical Name CAS-No Toxicity to algae Toxicity to fish Toxicity toMicroorganisms

Toxicity todaphnia andother aquaticinvertebrates



151-21-3 > 120 mg/L(Guideline: DIN38412, part 9;Desmodesmus

subspicatus;static; freshwater;based on growth

rate)

29 mg/L (Similarto OECD 203;Pimephalespromelas;

flow-through;freshwater; based

on activeingredient)

EC50: 135 mg/L(Guideline not

indicated;activated sludge;static; freshwater;respiration rate)

LC50: 5.55 mg/L(Guideline not

indicated;Ceriodaphnia

dubia;flow-through;

freshwater; basedon active

ingredient)

-

Zinc,bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-,(T-4)-

13463-41-7 0.0013 mg/L(Guideline EPA

OPP 122-2, static,Skeletonema

costatum)

0.0026 mg/L (EPAOPP 72-1,

flow-through,Pimephalespromelas)

2.4 mg/L (OECD209, static,

activated sludge)

0.0082 mg/L (EPAOPP 72-2,

flow-through,Daphnia magna)

-

Zinc oxide 1314-13-2 IC50: 0.136 mg/L(OECD 201;

Pseudokirchneriella subcapitata;

static; freshwater;growth rate)

0.112 mg/L (Readacross data onZinc chloride;

ASTM, E-729-88;Thymallus

arcticus; static;freshwater)

EC50: > 1000mg/L (OECD 209;activated sludge

of a predominantlydomestic sewage;static; freshwater;respiration rate)

0.155 mg/L (Readacross data onZinc; US EPA821-R-02-012;Ceriodaphniadubia; static;freshwater)

EC10: 350 mg/kgsoil dw (Readacross data onzinc dichloride;ISO 11268-2;Eisenia fetida;

annelids; naturalsoil)





151-21-3 30 mg/L(Guideline: DIN38412, part 9;Desmodesmus

subspicatus;static; freshwater;based on growth

rate)

> 1.357 mg/L(Guideline not

indicated;Pimephalespromelas;

flow-through;freshwater; 42 d)

0.88 mg/L (Similarto

EPA-600/489/001and USEPA

OPPTS 850.1300;Ceriodaphnia

dubia;flow-through;

freshwater; 7 d)Zinc,bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-,(T-4)-

13463-41-7 NOEC: 0.46 µg/L(0.00046 mg/L)

NOEC: 1.22 µg/L(0.00122 mg/L)


activated sludge)

NOEC: 2.28 µg/L(0.00228 mg/L)

Zinc oxide 1314-13-2 0.024 mg/L(OECD 201;

Pseudokirchneriella subcapitata;

static; freshwater;growth rate)

0.039 mg/L (Readacross data onZinc chloride;OECD 215;

Oncorhynchusmykiss;

flow-through;freshwater)

NOEC: 0.1 mg/L(Guideline: ISO

DIS 9509;activated sludge

of a predominantlydomestic sewage;static; freshwater;

concentrationbased on element;

nitrification rate)

0.0056 mg/L(Read across data

on Zinc sulfate;EPA/600/R-95-136; Holmesimysis

costata;semi-static;saltwater)

0.0228 mg/L(Read across dataon Zinc chloride;

microcosm/mesocosm; flow-through;freshwater; 4 wk)

Persistence and degradability .

Chemical Name Ready Test Results Persistence and degradability

_____________________________________________________________________________________________

Sulfuric acid monododecyl ester sodium salt (1:1) 95 % (OECD 301 B; aerobic; activatedsludge, domestic, non-adapted; CO2evolution; meets 10 d window criteria)

87.3 % (Similar to OECD 314D; aerobic;natural water / sediment; CO2 evolution; 35

d)Zinc,

bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-,(T-4)-

Page 6 / 9

39% (OECD 301 B) t1/2: 17 hours (River water at ambienttemperature)

Bioaccumulative potential .




Household: Do not discharge product into natural waters without pre-treatment oradequate dilution. Non-household: Should not be released into the environment. Disposeof in accordance with local regulations.


California Hazardous Waste Codes(non-household setting)

331


DOT Not regulated

TDG Not regulated

MEX Not regulated

IATA Not regulated

ICAO Not regulated

IMDG Not regulated


SARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemicalor chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:.

Chemical Name CAS-No Weight % SARA 313 - ThresholdValues %

Carbonic acid, zinc salt (1:1) 3486-35-9 1.54077 1.0Zinc,


13463-41-7 1 1.0

SARA 311/312 Hazard CategoriesAcute Health Hazard YesChronic Health Hazard NoFire Hazard NoSudden release of pressure hazard NoReactive Hazard No

Chemical Name Bioconcentration factor (BCF)Zinc, bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-, (T-4)- 11 (OECD 305 E, Crassostrea virginica)

Zinc oxide 60960Mobility .

Chemical Name

_____________________________________________________________________________________________

KOC ValuesSulfuric acid monododecyl ester sodium salt (1:1) 446 (Guideline not indicated; HPLC estimation method; adsorption;

sediment; at 25 C)Zinc, bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-, (T-4)-

Page 7 / 9

Koc (adsorption): 2347 (Soil #1 sandy loam), 783 (Soil #2 loam),10632 (Sediment #1 sandy loam) and 3596 (Sediment #2 silt

loam); Koc (desorption): 3,293 (Soil #1 sandy loam), 873 (Soil #2loam), 21814 (Sediment #1 sandy loam) and 6523 (Sediment #2

silt loam)Other adverse effects No information available.


CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substance under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):.

Chemical Name CAS-No Hazardous Substances RQs Extremely HazardousSubstances RQs

Carbonic acid, zinc salt (1:1) 3486-35-9 1000 lb -hydrogen chloride 7647-01-0 5000 lb 5000 lb


Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product contains the following substance(s) which are either listed as hazardous air pollutants (HAPS) or VOC's per the CleanAir Act:.

Chemical Name CAS-No CAA (Clean Air Act) - 1990 Hazardous AirPollutants

hydrogen chloride 7647-01-0 X

Clean Water ActThis product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21and 40 CFR 122.42):.

Chemical Name CWA - ReportableQuantities


Carbonic acid, zinc salt(1:1)

1000 lb X - X

Zinc,bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kap

paS2]-, (T-4)-

- X - -

Zinc oxide - X - -

hydrogen chloride 5000 lb - - X

U.S. State Regulations (RTK).

Chemical Name New JerseyCarbonic acid, zinc salt (1:1) X

Zinc, bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-,(T-4)-

X

Chemical Name MassachusettsCarbonic acid, zinc salt (1:1) X

Chemical Name PennsylvaniaCarbonic acid, zinc salt (1:1) X

Zinc, bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-,(T-4)-

X

Zinc oxide XSulfuric acid sodium salt (1:2) X

hydrogen chloride XGlycerin X

_____________________________________________________________________________________________

Propylene glycol X

Page 8 / 9

Chemical Name Rhode IslandCarbonic acid, zinc salt (1:1) X


California Proposition 65This product is not subject to warning labeling under California Proposition 65.


Canada WHMIS Hazard ClassNot subject to WHMIS classification.

WHMIS StatementThis product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and theMSDS contains all the information required by the CPR. This product is regulated by the Food and Drug Administration of HealthCanada and is therefore exempt from the requirements of CEPA.


TSCAProduct is a personal care product and regulated under FDA.

CEPAP&G Canadian Regulatory reviewed finished products to ensure CEPA Compliance.


Legend TSCA - United States Toxic Substances Control Act Section 8(b) InventoryCEPA - Canadian Environmental Protection Act


Issuing Date:

_____________________________________________________________________________________________

27-May-2014Revision Date: 27-May-2014

Page 9 / 9


End of MSDS


Issuing Date: 27-May-2014 Revision Date: 27-May-2014 Version 1

1. PRODUCT AND COMPANY INFORMATION

Product ID: 92231187_NA

Product Name NIOXIN Scalp Optimizing Conditioner

Product Type Finished Product - Consumer (Retail) and Professional Use

Recommended Use Personal Beauty Care Product

Synonyms No information available

Manufacturer The Procter & Gamble CompanySharon Woods Innovation Center11510 Reed HartmanHighwayCincinnati OH 45241


Emergency Telephone Transportation (24 HR)CHEMTREC - 1-800-424-9300(U.S./ Canada) or 1-703-527-3887Mexico toll free in country: 800-681-9531

2. HAZARDS IDENTIFICATIONEmergency Overview

OSHA regulatory status Consumer Products as defined by the U.S. Consumer Product Safety Act which are usedas intended (typical consumer duration and frequency) are exempt from the OSHA HazardCommunication Standard. When used in a professional setting (at a much higher frequencyand duration than a typical consumer) this material would NOT be considered hazardous bythe OSHA Hazard Communication Standard (29 CFR 1910.1200).

WHMIS Not subject to WHMIS classification.

_____________________________________________________________________________________________

Principle routes of exposure None reasonably foreseeable.

General hazards

Page 1 / 8

This is a personal care or cosmetic product that is safe for consumers and other usersunder normal and reasonably foreseeable use.

_____________________________________________________________________________________________92231187_NA - NIOXIN Scalp Optimizing Conditioner Revision Date: 27-May-2014



Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Ifsymptoms persist, call a physician.


Ingestion Clean mouth with water and afterwards drink plenty of water. Do NOT induce vomiting. Ifsymptoms persist, call a physician.

Inhalation Move to fresh air.

Protection of first-aiders Use personal protective equipment.


None known.

Notes to Physician Treat symptomatically.


Flash point Not Applicable

Suitable extinguishing media Dry chemical, CO 2, water spray or alcohol-resistant foam.

Extinguishing media which shall notbe used for safety reasons


Special hazard None known based on information supplied.


As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent) and full protective gear.


Personal precautions None under normal use conditions.


Environmental precautions Household: Do not discharge product into natural waters without pre-treatment oradequate dilution. Non-household: Should not be released into the environment.


Hazardous ingredients

Chemical Name CAS-No Weight %1-Octadecanol 112-92-5 1 - 5


_____________________________________________________________________________________________

1 - 5Zinc,


13463-41-7 0.1 - 1

Page 2 / 8


Methods for containment Non-household: Prevent further leakage or spillage if safe to do so. Prevent product fromentering drains.

Methods for cleaning up Non-household: Contain spillage, and then collect with non-combustible absorbentmaterial, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container fordisposal according to local / national regulations (see section 13).


Advice on safe handling Keep out of the reach of children. Observe label precautions.




Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies.





Skin and Body Protection No special protective equipment required.

Respiratory Protection No special protective equipment required.

Thermal hazards

_____________________________________________________________________________________________

Not applicable.


Page 3 / 8

Environmental exposure controls See section 6 for more information.



Physical State @20°C liquidAppearance white. Off-white.Odor Mint-like

Chemical Name Partition Coefficient (n-octanol/water)1-Octadecanol 7.4 (Guideline: ASTM E 1147, HPLC method)Zinc, bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-,(T-4)-

0.9

VOC Content (%) Products comply with US state and federal regulations for VOC content in consumerproducts.

Oxidizing properties No information available




Hazardous polymerization Hazardous polymerization does not occur.



Materials to avoid None in particular.


Property Values Note pH value 4.0 - 5.5Melting/freezing point No information availableBoiling point/boiling range No information availableFlash point Not ApplicableEvaporation rate No information availableflammability (solid, gas) No information availableFlammability Limits in AirUpper flammability limit No information availableLower Flammability Limit No information available

Vapor pressure No information availableVapor density No information availableRelative density No information availableWater solubility No information availableSolubility in other solvents No information availablePartition coefficient: n-octanol/waterNo information availableAutoignition temperature No information available .Decomposition temperature No information available

_____________________________________________________________________________________________

.Viscosity of Product No information available

Page 4 / 8

Bulk Density No information available



Product Information

Acute toxicity Product does not present an acute toxicity hazard based on known or supplied information.

Inhalation No known effect based on information supplied.Skin contact No known effect based on information supplied.Ingestion No known effect based on information supplied.Eye contact No known effect based on information supplied.

Chemical Name CAS-No LD50 Oral LD50 Dermal LC50 Inhalation1-Octadecanol 112-92-5 > 2000 mg/kg bw (OECD

401, rat)> 2,000 mg/kg bw

(Rabbit)-

Octadecanamide,N-[3-(dimethylamino)propyl]-

7651-02-7 Low acute toxicity in ratswith a LD50 values

exceeding 2000 mg/kgbw

Low acute toxicity inrabbits with LD50 valuesexceeding 2000 mg/kgbw (read-across from

related substance)

-

Zinc,bis[1-(hydroxy-kappaO)-2(1H)-pyridine

thionato-kappaS2]-, (T-4)-

13463-41-7 269 mg/kg bw (OECD401, rat)

> 2000 mg/kg bw (EPAOPP 81-2, rat)

1.03 mg/L air (OECD403, rat)

Chronic Toxicity

Corrosivity No known effect.Sensitization No known effect.Neurological Effects No known effect.Reproductive toxicity The product contains no substances known to be hazardous to health in concentrations

which need to be taken into account.Germ cell mutagenicity There are no known mutagenic chemicals in this product.

_____________________________________________________________________________________________

Developmental toxicity No known effect.Teratogenicity

Page 5 / 8

No known effect.Carcinogenicity Contains no ingredients above reportable quantities listed as a carcinogen.




Ecotoxicity




1-Octadecanol 112-92-5 > 100 mg/L(OECD 201,

Scenedesmussubspicatus )

> 0.4 mg/L (EUMethod C.1,

Salmo gairdneri,semi-static)

EC0: > 10000mg/L

(Pseudomonasputida)

1700 mg/L(Guideline:

German IndustryStandard DIN

38412, Part 11;May 1984,

Daphnia magna,static)

-

Octadecanamide,N-[3-(dimethylamino)propyl]-

7651-02-7 ErC50 (72h) =0.14 mg/L

ErC10 (72h) =0.07 mg/L

LC50 (96h) = >0.1-<1 mg/L

NOEC = 0.1 mg/L

NOEC = 100 mg/L EC50 (48h) = 0.38mg/L

NOEC = 0.2 mg/L

-


13463-41-7 0.0013 mg/L(Guideline EPA

OPP 122-2, static,Skeletonema

costatum)

0.0026 mg/L (EPAOPP 72-1,

flow-through,Pimephalespromelas)


activated sludge)

0.0082 mg/L (EPAOPP 72-2,

flow-through,Daphnia magna)

-





13463-41-7 NOEC: 0.46 µg/L(0.00046 mg/L)

NOEC: 1.22 µg/L(0.00122 mg/L)


activated sludge)

NOEC: 2.28 µg/L(0.00228 mg/L)

Persistence and degradability .

Chemical Name Ready Test Results Persistence and degradability1-Octadecanol 67% (activated sludge, readily

biodegradable, but failing 10-day window)Half life: 1.1 day (sediment, primary

degradation, for readily bioavailable testmaterial), 34.7 day (sediment, primary

degradation, less bioavailable test material)Zinc,

bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-,(T-4)-

39% (OECD 301 B) t1/2: 17 hours (River water at ambienttemperature)

Bioaccumulative potential .

Chemical Name Bioconcentration factor (BCF)1-Octadecanol 100000 L/kg (Calculated value)

Zinc, bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-, (T-4)- 11 (OECD 305 E, Crassostrea virginica)Mobility .

Chemical Name KOC Values1-Octadecanol

_____________________________________________________________________________________________

471350 L/Kg (adsorption, batch equilibrium method)Octadecanamide, N-[3-(dimethylamino)propyl]- Koc = ~1,000-500,000

Zinc, bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-, (T-4)-

Page 6 / 8

Koc (adsorption): 2347 (Soil #1 sandy loam), 783 (Soil #2 loam),10632 (Sediment #1 sandy loam) and 3596 (Sediment #2 silt

loam); Koc (desorption): 3,293 (Soil #1 sandy loam), 873 (Soil #2loam), 21814 (Sediment #1 sandy loam) and 6523 (Sediment #2

silt loam)Other adverse effects No information available.



Household: Do not discharge product into natural waters without pre-treatment oradequate dilution. Non-household: Should not be released into the environment. Disposeof in accordance with local regulations.


California Hazardous Waste Codes(non-household setting)

561


DOT Not regulated

TDG Not regulated

MEX Not regulated

IATA Not regulated

ICAO Not regulated

IMDG Not regulated



SARA 311/312 Hazard CategoriesAcute Health Hazard NoChronic Health Hazard NoFire Hazard NoSudden release of pressure hazard NoReactive Hazard No

CERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material.


Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61)This product contains the following substance(s) which are either listed as hazardous air pollutants (HAPS) or VOC's per the CleanAir Act:.

Chemical Name CAS-No CAA (Clean Air Act) - 1990 Hazardous AirPollutants

2-Phenoxyethanol 122-99-6 X

_____________________________________________________________________________________________

Clean Water ActThis product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21and 40 CFR 122.42):.

Chemical Name

Page 7 / 8




Zinc,bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kap

paS2]-, (T-4)-

- X - -

U.S. State Regulations (RTK).

Chemical Name PennsylvaniaZinc, bis[1-(hydroxy-kappaO)-2(1H)-pyridinethionato-kappaS2]-,

(T-4)-X

2-Phenoxyethanol XBenzyl alcohol X

Propylene glycol X

California Proposition 65This product is not subject to warning labeling under California Proposition 65.


Canada WHMIS Hazard ClassNot subject to WHMIS classification.

WHMIS StatementThis product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and theMSDS contains all the information required by the CPR. This product is regulated by the Food and Drug Administration of HealthCanada and is therefore exempt from the requirements of CEPA.


TSCAProduct is a personal care product and regulated under FDA.

CEPAP&G Canadian Regulatory reviewed finished products to ensure CEPA Compliance.


Legend TSCA - United States Toxic Substances Control Act Section 8(b) InventoryCEPA - Canadian Environmental Protection Act


Issuing Date:

_____________________________________________________________________________________________

27-May-2014Revision Date: 27-May-2014

Page 8 / 8


End of MSDS

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