PAA(Polyallylamines) Series is water-soluble cationic polymers withprimary amino group in the molecular structure which was commercialized byNittobo Medical for the first time worldwide in the 80th.

Grade MolecularWeight(Mw) Conc.(%) Molecular Structure

PAA-01 1,600 15

PAA-03 3,000 20

PAA-15C 15,000 15

PAA-HCl-03 3,000 40

PAA-HCl-3L 15,000 50

PAA-HCl-10L 150,000 40

PAA-D11-HCl 100,000

PAA-D41-HCl 20,000

PAA-D19-HCl 40,000 21

※Please feel free to contact us if you have any question about derivatives of these grades, unlisted grades as well as grades listed in table.

《Uses and Applications of PAA Series》Fiber and Textile ：Fixing agent for direct and reactive dyes, Antistatic agentInk-jet Printing ：Improvement of coloring, fade-resistance and water-proofness of ink colorsMetal Treatment ：Metal processing oil additive, Metal chelating agentElectric Materials ：Various cleaner and resist additiveOthers ：Aldehydes absorbent, Pigment and ink additive,

Polymer bridging agent, etc.

Copolymers of Primary and Secondary Amine （CAS.No.97939-72-5）

40

Homo Polymers of Primary Amine (Free Base Type) （CAS. No. 30551-89-4）

Homo Polymers of Primary Amine (Hydrochloride Salt Type) （CAS.No.71550-12-4）

CH2 CH

CH2

NH2 n

CH2 CH

CH2

NH2 HCl n

CH2 CH

CH2

NH2 HCl

CH2 CH CH

CH2 CH2N HCl

CH2

Hl m n

PAS Series consisits of water-soluble, cationic homo and copolymers of diallylamine(DAA)salts unit, being broadly used in the areas where cationic property in a state of aqueous solution.Various types of grades are available to meet a variety of application.Now new grades with different molecular weight have been added to fully respond to requestof ｃustomers.New grades will help you develop the new product with their unique properties.

Grade MolecularWeight(Mw) Conc.(%) Molecular Structure

PAS-M-1 20,000 50

PAS-H-1L 8,500

PAS-H-5L 30,000

PAS-H-10L 200,000

PAS-J-81L 10,000

PAS-J-81 180,000

PAS-92 5,000 20

PAS-A-1 5,000 24

PAS-A-5 4,000 40

PAS-880 40,000 35

※Please feel free to contact us if you have any question about derivatives of these grades, unlisted grades as well as grades listed in table.《Uses and Applications of PAS Series》Fiber and Textile ：Fixing agent for direct and reactive dyes, Agent for heavy shadingInk-jet Printing ：Improvement of coloring, fade-resistance and water-proofness of ink colorsPaper Making ：Fixing, sizing and retention of filler or pigment agentMetal Treatment ：Corrosion inhibitor for picking acids, Surface brightner for zincificationWaste Water Disposal ：Polymer flocculant, Emulsion breaker, Decoloring agentOthers ：Paint additive, Epoxy resin hardner, etc.

Polyamine Derivative with Epichlorohidrine （CAS.No.75665-34-8）

Copolymer of Secondary Amine and Sulfur Dioxide （CAS.No.170427-76-6）

Copolymers of Quaternary Ammonium Salt and Sulfur Dioxide （CAS.No.26470-16-6）

25

Homo Polymers of Tertiary Amine (Hydrochloride Salt Type) （CAS.No.29566-78-7）

Homo Polymers of Quaternary Ammonium Salt （CAS.No.26062-79-3）

Copolymers of Quaternary Ammonium Salt and Acrylic Amide （CAS.No.29590-05-6）

28

CH2 CH CH

CH2 CH2N HCl

CH2

CH3n

CH2 CH CH

CH2 CH2N+ Cl-

CH3 CH3

CH2

n

CH2 CH CH

CH2 CH2N HCl

CH2 S

O O

H n

CH2 CH CH

CH2 CH2N+ Cl-

CH3 CH3

CH2 S

n

O O

CH CH

CH2 CH2N+ Cl-

CH3 CH3

CH2 CH2CH2 CH CH CH2

CH2 CH2

N HClCH2CH CH2

OH Cll m n

CH CH

CH2 CH2N+ Cl-

CH3 CH3

CH2 CH2 CH

C

NH2

O

CH2

l m n

Polyampholite Series is unique polymers in term of having both cationic and anionicfunctional groups in molecular structure developed through Nittobo Medical's proprietary.

Grade MolecularWeight(Mw) Conc.(%) Molecular Structure

PAS-410C － 40

PAS-DMS-1041 - 19

※Please feel free to contact us if you have any question about derivatives of these grades, unlisted grades as well as grades listed in table.

《Uses and Applications of Polyampholite Series》・Polymer flocculant, Emulsion breaker・Cleaner additive, etc.

Grade MolecularWeight(Mw) Conc.(%) Molecular Structure

PAA-03-E 3,000 20

※Please feel free to contact us if you have any question about derivatives of these grades, unlisted grades as well as grades listed in table.

Copolymer of Secondary Amine and Maleic acid (CAS.No.119599-51-8)

Polyallylamine (Ethanol Solution) (PAA:CAS.No.30551-89-4, Ethanol:CAS.No.64-17-5)

Copolymers of Quaternary Ammonium Salt and Sulfur Dioxide and Maleic acid (CAS.No.64598-61-4)

CH CH

CH2 CH2N HCl

CH2 CH

C

CH

C

O

H

O

H

OO

CH2

H nl m

CH2 CH

CH2

NH2 n

C

OH

O

CH CH

C

OH l

O

S

O O

CH2

CH2

N+

CH2

CH2

m

CH3

CH3

Cl

n

LCCP (Lower-Chlorine Containing Polymer) Series has been put on the market in an effortto alleviate the clorine constraint against the existing chlorine-containing products.Lowering of chlorine ion content of the products has been attained by replacing major portionof HCl in amine salt with CH3COOH for the existing products.

◎Features ① Polymer solution is neutral in state of aqueous solution. ② Corrosive property for metals is as low as 1/10 as compared with that of existing corresponding salt type of the product. ③ Polymer solution is more soluble in organic solvents such as alcohol than existing corresponding salts type of the product.

Grade MolecularWeight(Mw) Conc.(%) Molecular Structure

PAS-92A 5,000 20

※Please feel free to contact us if you have any question about derivatives of these grades, unlisted grades as well as grades listed in table.

《Comparison of pH 》 《Uses and Applications of Cationic polymers》Article ｐＨ（５％ａｑ．） Fiber and Textile : Fixing agent

ＰＡＳ－９２Ａ ab. ６．５ Ink-jet Printing : Improving performances of paper and textile

HCl salt type ab. ２．０ Paper Making : Fixing and sizing agent Metal Treatment : Corrosion inhibitor for picking acid

Water Disposal : Polymer flocculantOthers : Paint and pigment additive, Resin hardner, Aldehydes abosorbent, etc.

Copolymer of Secondary Amine and Sulfur Dioxide （CAS.No.701913-12-4）

CH2 CH CH

CH2 CH2N X

CH2 S

O O

H n

CH3COOH : ab.80%HCl : ab.20%

X

Fixing Agents

for Reactive Dyes

※Please contact us about various derivatives, other grades and any requests.

DANFIX　２～６％owf（Pale shade～Deep shade） Temperature：40～60℃　　Time　：　15～20min.

Dyeings are padded by aqueous solution of DANFIX (5-30g/L), then it is squeezed and dried.

※Please contact us about various derivatives, other grades and any requests.

Directions for useAfter fixing (necessary) and washing, prepaire the mixture of DANFIX-MM11 (4-8%owf)and DANFIX-MM12 (0.2-0.8%owf). Next, treat at room temperature for 10-20 minutes.Then wash, squeeze and dry.

(An example) 　40℃×20min.

room tem.×15min.

room temp.

Fixing ・waste water ・waste water

（DANFIX-SC-8) ・washing ・squeeze

・waste water ・dry

After fixing (necessary) and wash, prepare the mixture of DANFIX-MM11 (4-8%owf)and DANFIX-MM12 (0.2-0.8%owf). Then pad, squeeze and dry. (Not necessary to heat treatment.)

Notices

※The dyeings must washing enough before the treatment of DANFIX-MM11 and MM12.※DANFIX-MM11 and MM12 can not use a same bath with fixing and some cationic agents.※Please dicide treatment conditions by pretests. Apr.2013

Rubbing fastnessDry-rubbing Wet-rubbing

Rise to 1-2 ranks

(for blank)

Danfix-MM11

Danfix-MM12

Milky white viscousliquid

Anionic

Nonionic

Approx. 7

Approx. 7

Rubbing Fastnes Improvers

in water

Easy soluble

Danfix-7000 Danfix-PAA

Article Appearance Ionicity pH(1%sol.) Solubility

Article Danfix-SC-8 Danfix-505RE

Especially Improves chlorine-fastness

・Excellent chlorine-fastness

Yellow liquid

Specialty cationic polymer

Satisfactry soluble in water

Light yellow liquid

Dipping Method

Continuous Method

Appearance

Composition

Solubility

Properties

・Excellent wet-fastness

・Economical material

・Using worldwide

Milky white liquid

Excellent fastness for dry and wet rubbing

High qualities and excellent results in the world

Dipping Method

Continuous Method

・Good durability・Easy removal

・Good water absorbency

various fastnesses

・Corresponding to the

Danfix-5000

DANFIX-MM11(4%owf)

DANFIX-MM12(0.4%owf)