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    WorkshopWorkshop

    ononEnvironmental HealthEnvironmental Health

    Hazards and SafetyHazards and Safety

    onon

    1313thth May 2009May 2009

    atatOFC, KanpurOFC, Kanpur

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    Environmental HealthEnvironmental HealthHazards and SafetyHazards and Safety

    By :By :

    Dr. Anurag TewariDr. Anurag TewariAssistant ProfessorAssistant Professor

    Head, Department of ChemistryHead, Department of Chemistry

    Pravneer Singh Academy of TechnologyPravneer Singh Academy of Technology

    Kalpi Raod ,Bhauti, KanpurKalpi Raod ,Bhauti, Kanpur-- 2020

    [email protected],[email protected]@rediffmail.com,[email protected]

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    Your EnvironmentYour Environment

    AirAir

    WaterWater

    SoilSoil

    Bio MassBio Mass

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    What are various things which areWhat are various things which are

    affecting your health ?affecting your health ?

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    Things in the environmentThings in the environment

    that can affect your healththat can affect your health

    ChemicalsChemicals -- in water and soilin water and soil

    PlantsPlants -- allergensallergens

    Air pollutionAir pollution

    MetalsMetals -- lead and mercurylead and mercury

    Sun exposureSun exposure

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    Indoor Air QualityIndoor Air Quality

    Dust & pet hair allergies and asthmaDust & pet hair allergies and asthma

    22ndnd hand tobacco smoke emphysemahand tobacco smoke emphysema

    Fine particlesFine particles

    (asbestos, silica, graphite, coal) lung disease(asbestos, silica, graphite, coal) lung disease

    Carbon monoxide deathCarbon monoxide death

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    Outdoor Air QualityOutdoor Air Quality

    OzoneOzone

    Carbon monoxideCarbon monoxide

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    Seasonal and NonSeasonal and Non--seasonal Allergensseasonal Allergensand Asthma Irritantsand Asthma Irritants

    Cigarette smokeCigarette smoke

    CockroachesCockroaches

    Dust mitesDust mites

    House dustHouse dust

    MouldMould

    PetsPets

    PollenPollen

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    Factors that Affect

    River and Stream Water Quality

    Runoff from localRunoff from localfarmsfarms -- increasesincreasesnitrate and phosphatenitrate and phosphatelevels in surface andlevels in surface andground water.ground water.

    Sewage runoff fromSewage runoff fromseptic systemsseptic systems

    (tanks), farms and(tanks), farms andwaste treatmentwaste treatmentplants.plants.

    Acid rainAcid rain

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    Water-borne Pathogenic Micro organismsPathogenic Micro organisms

    Faecal coliformFaecal coliform

    CryptosporidiumCryptosporidium

    Vibrio choleraeVibrio cholerae

    SalmonellaSalmonella

    GiardiaGiardia

    PhytoplanktonPhytoplankton

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    LeadLead

    PaintPaint

    Leaded gasolineLeaded gasoline

    Ceramic dishes &Ceramic dishes &

    mugsmugs

    Lead pipes andLead pipes and

    soldersolder

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    Children & LeadChildren & Lead

    Lead paintLead paint --in homesin homes

    prior to midprior to mid--1970s1970s

    Lead in jewelleryLead in jewellery

    Lead dust fromLead dust fromrenovation of homes,renovation of homes,

    buildings and bridgesbuildings and bridges

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    Symptoms ofLead PoisoningSymptoms ofLead Poisoning

    HeadachesHeadaches

    Muscle and joint weakness or painMuscle and joint weakness or painexcessive tiredness or lethargyexcessive tiredness or lethargy

    Behavioural problems or irritabilityBehavioural problems or irritability Difficulty concentratingDifficulty concentrating

    Loss of appetiteLoss of appetite

    Metallic taste in the mouthMetallic taste in the mouth

    Abdominal pain, nausea or vomitingAbdominal pain, nausea or vomiting

    ConstipationConstipation

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    MercuryMercury

    Heavy metalHeavy metal

    Found in thermometers andFound in thermometers and

    batteriesbatteries

    Contaminates water, soil, airContaminates water, soil, air

    Impairs the neurological systemImpairs the neurological system

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    Symptoms of Mercury PoisoningSymptoms of Mercury Poisoning

    Psychological changePsychological change

    Spontaneous abortionSpontaneous abortion

    Congenital malformationCongenital malformation

    ( from birth defects)( from birth defects)

    Damage brain and CNSDamage brain and CNS

    Tremors ( paralysis )andTremors ( paralysis )and

    gingivitis( infection of gums)gingivitis( infection of gums)

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    CadmiumCadmium

    By product ofzinc refiningBy product ofzinc refining

    Marine and aerospaceMarine and aerospace

    applicationsapplications

    PigmentsPigments

    Refined petroleum productsRefined petroleum products

    Stabilizers for PVCStabilizers for PVC

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    Symptoms of Cadmium poisoningSymptoms of Cadmium poisoning

    Diarrhoea , stomach painDiarrhoea , stomach pain

    Bone fractureBone fracture

    Kidney damageKidney damage

    Lungs damageLungs damage

    Damage immune systemDamage immune system

    Psychological disordersPsychological disorders

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    ArsenicArsenic

    Glass industryGlass industry

    Wood preservativeWood preservative

    Electronic goodsElectronic goods

    Wind blown dustWind blown dust

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    Symptoms of Arsenic poisoningSymptoms of Arsenic poisoning

    Decreased production ofDecreased production of

    RBCs and WBCsRBCs and WBCs

    Skin changesSkin changes

    Cancer developmentsCancer developments Infertility and miscarriagesInfertility and miscarriages

    with womenwith women

    Brain damageBrain damage

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    ChromiumChromium

    Steel and textile industrySteel and textile industry

    Leather industryLeather industry

    Electro platingElectro plating

    Mining of chromiumMining of chromium

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    Symptoms of chromium poisoningSymptoms of chromium poisoning

    Carcinogenic activityCarcinogenic activity

    Kidney and liver damageKidney and liver damage

    Lung cancerLung cancer

    Upset stomachUpset stomach

    Skin rashesSkin rashes

    Nose bleedingNose bleeding

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    What are various environmental risks whichWhat are various environmental risks which

    are creating adverse impact on environment ?are creating adverse impact on environment ?

    Environmental Risks = Various ImpactsEnvironmental Risks = Various Impacts

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    Environmental Risks of FarmingEnvironmental Risks of Farming

    Pesticide exposurePesticide exposure

    Fertilizer runoffFertilizer runoff

    Animal waste runoffAnimal waste runoff

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    Environmental Risks from IndustryEnvironmental Risks from Industry

    Solvent exposureSolvent exposure

    Toxic wasteToxic waste

    Air pollutionAir pollution

    Acid rainAcid rain

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    Toxic Chemicals in Our EnvironmentToxic Chemicals in Our Environment

    SolventsSolvents

    PCBsPCBs

    DioxinDioxin

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    DioxinDioxin

    A chemical by product of several industrialA chemical by product of several industrialprocesses:processes:

    Chemical manufacturingChemical manufacturing

    Garbage incineration and combustion ofGarbage incineration and combustion ofleaded gasleaded gas

    paper millspaper mills

    Dioxin is extremely toxic, and has beenDioxin is extremely toxic, and has beenlinked to:linked to:

    Human reproductive problems and birthHuman reproductive problems and birthdefectsdefects

    Impaired child development andImpaired child development andbehavioural effectsbehavioural effects

    Diabetes, and thyroid disordersDiabetes, and thyroid disorders

    ImmunosupressionImmunosupression

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    Dioxin ExposureDioxin Exposure

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    PCBsPCBs --polychloronatedbiphenylpolychloronatedbiphenyl

    An environmental estrogenAn environmental estrogen --a colourless oilya colourless oilycompound.compound.

    Used as an electrical insulator since the 1930sUsed as an electrical insulator since the 1930s

    Used in electrical transformers, capacitors, heatUsed in electrical transformers, capacitors, heattransfer systems, and hydraulic systems.transfer systems, and hydraulic systems.

    Also may be found in welding equipment, XAlso may be found in welding equipment, X--rayraymachines, refrigerators and microwave ovens.machines, refrigerators and microwave ovens.

    Chemically stable and resistant to heat andChemically stable and resistant to heat andburning.burning.

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    PCBs and Human HealthPCBs and Human Health

    PCBs remain in the environment for a long timePCBs remain in the environment for a long time --they dothey donot break downnot break down

    Elimination of PCBs from the body is very slowElimination of PCBs from the body is very slow --levels inlevels inbody tissues increase over timebody tissues increase over time

    PCBs build up in the food chainPCBs build up in the food chain

    PCBs cause cancer in test animalsPCBs cause cancer in test animals

    1968 exposure of 1200 Japanese to PCB1968 exposure of 1200 Japanese to PCB--contaminatedcontaminatedoil suffered stomach pain and skin problemsoil suffered stomach pain and skin problems

    (Yusho disease)(Yusho disease) Children exposed to PCBs before birth have a lowerIQChildren exposed to PCBs before birth have a lowerIQ

    and behaviour problemsand behaviour problems

    PCBs have been banned from production in the USAPCBs have been banned from production in the USA

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    PCBs and Fish ConsumptionPCBs and Fish Consumption

    Women of childbearing age should not eat fish listed onthe fish advisory.

    Properly cleaning, skinning, trimming and cooking the

    fish can minimize the intake of PCBs. Eat only skinless and boneless fillets with as much fat

    removed as possible.

    Eggs (or roe) should be discarded.

    Roasting or baking reduce levels of PCBs more thanfrying or microwaving. Cooking does not destroy PCBsnor does it lower their toxicity.

    Dont eat the juices or fats that cook out of the fish.

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    RadonRadon

    Radon is an invisible and odourless gasRadon is an invisible and odourless gas

    Sources of Radon:Sources of Radon:

    "Earth and rock beneath home "well water "building materials"Earth and rock beneath home "well water "building materials

    Health Effects From Exposure to Radon:Health Effects From Exposure to Radon: "contributes to 7,000"contributes to 7,000 --30,000 lung cancer deaths each year30,000 lung cancer deaths each year

    "smokers are at higher risk of developing Radon"smokers are at higher risk of developing Radon--induced lung cancerinduced lung cancer

    Radon Levels in Homes:Radon Levels in Homes:

    "average indoor radon level is 1.3 pico curies per liter (pCi/L) in USA"average indoor radon level is 1.3 pico curies per liter (pCi/L) in USA

    "average outdoor level is about 0.4pCi/L"average outdoor level is about 0.4pCi/L

    Most homes don't have a Radon problem, but there is a simple test toMost homes don't have a Radon problem, but there is a simple test tofind out if you do or don't have high Radon levels in your home.find out if you do or don't have high Radon levels in your home.

    The Environmental Protection Agency (EPA) and the SurgeonThe Environmental Protection Agency (EPA) and the SurgeonGeneral recommend that all homes below the 3General recommend that all homes below the 3rdrd floor be tested forfloor be tested forRadonRadon

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    The origin for this contamination is both natural and anthropogenicThe origin for this contamination is both natural and anthropogenic

    (by mining activities). The presence of these metallic elements in water(by mining activities). The presence of these metallic elements in water

    resources are affecting aquatic ecosystems balance.resources are affecting aquatic ecosystems balance.

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    Government and Industry RegulationsGovernment and Industry Regulations

    Methylenechloride, used to decaffeinatecoffee, has been replaced by a water process

    Various food additives and dyes have beenrestricted or eliminated by the Food and Drug

    Administration following tests showingadverse effects

    Dichlorvos, used for flea collars and "no pest"strips, was found carcinogenic in animals in1991, and was barred from these uses by theEnvironmental Protection Agency.

    Benzene, a gasoline additive, is no longerused in consumer products, because ofevidence it can cause cancer.

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    Government AgenciesGovernment Agencies

    Environmental Protection Agency (EPA)Environmental Protection Agency (EPA)

    National Institute of EnvironmentalNational Institute of Environmental

    Health Sciences (NIEHS)Health Sciences (NIEHS)

    US Geological Survey (USGS)US Geological Survey (USGS)

    Food and Drug Administration (FDA)Food and Drug Administration (FDA)

    Agency for Toxic Substances & DiseaseAgency for Toxic Substances & DiseaseRegistry (ASTDR)Registry (ASTDR)

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    Hazards should be communicatedHazards should be communicated ??

    Why Why

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    Hazard CommunicationHazard Communication

    Your Right to KnowYour Right to Know

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    Five Stages of the Program

    Chemical Inventory List (CIL)Chemical Inventory List (CIL)

    Material Safety Data Sheets (MSDSs)Material Safety Data Sheets (MSDSs)

    Labeling and Marking SystemsLabeling and Marking Systems

    Employee TrainingEmployee Training

    Written PlanWritten Plan

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    Hazard Communication

    Chemical Inventory List

    Department Name and Phone Number

    Inventory Supervisor

    Campus mailing address of the Inventory Supervisor

    Official Building Name & number

    Date ofInventory

    Page ( ) of ( )Chemical Name

    Common Name

    Location (room number) of the chemical

    Actual count of a chemical

    Maximum amount anticipatedContainer type and size

    Physical State and CAS Number

    Manufacturer, NFPA Rating

    Does the department have an MSDS for it ?

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    Hazard CommunicationHazard Communication

    Material Safety Data SheetsMaterial Safety Data Sheets

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    Hazard Communication

    Material Safety Data Sheets

    Company InformationCompany Information

    HazardousHazardous

    IngredientsIngredients

    Physical DataPhysical Data

    Fire and ExplosionFire and Explosion

    DataData Health Hazard DataHealth Hazard Data

    Reactivity DataReactivity Data

    Spill & LeakSpill & Leak

    ProceduresProcedures

    Special ProtectionSpecial Protection

    InformationInformation

    Special PrecautionsSpecial Precautions

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    Material Safety Data Sheets:

    Your Rights

    Your employer must have an MSDS forevery hazardous substance you use aspart of your job.

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    Material Safety Data Sheets:

    Your Rights

    If you request your own personal copy ofIf you request your own personal copy ofan MSDS, your employer has 15 daysan MSDS, your employer has 15 days

    to provide it.to provide it.

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    Hazard Communication

    Labeling and Marking Systems

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    Labeling and Marking Systems

    NFPA Diamonds

    HMIS Labels

    Uniform Laboratory Hazard Signage System

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    Labeling and Marking SystemsNFPA Diamonds

    Color coded,numerical ratingsystem

    Will be located nearmain entrances, firealarm panels, or onoutside entrancedoors

    Provide at-a-glancehazard information

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    Labeling and Marking Systems

    NFPA Diamonds

    Blue = Health

    Red = Flammability

    Yellow = Instability

    White = Specialhazard information

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    Labeling and Marking Systems

    HMIS Labels

    Designed to go on

    individual containers

    of products that

    dont have themanufacturers

    labels

    Same colorcode/numerical

    rating system as the

    NFPA diamonds

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    Labeling and Marking Systems

    Uniform Laboratory Signage

    Located on laboratory

    and chemical storagearea doors

    Pictographs depictworst hazards presentin lab or area

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    Hazard Communication

    Employee Training

    Training is required :

    Within the first 30 days of employment

    Whenever new hazards are introduced

    Annually

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    Hazard Communication

    The Written Plan

    If you are exposed to a hazardous substance at

    work, you should report it to your supervisor who

    will complete an Employee Exposure Report Form

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    Hazard Communication

    BE SAFE,

    NOT SORRY!

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    Hazard communicationHazard communication

    promotes safety at work placepromotes safety at work place ??

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    Safety Is Everybody's Business

    Help you decide that safety is everybodysHelp you decide that safety is everybodysbusiness, and whybusiness, and why

    Provide you with an understanding ofProvide you with an understanding ofaccident causesaccident causes

    Explain safety responsibilitiesExplain safety responsibilities

    For both employees and employersFor both employees and employers

    Introduce you to specific safety topicsIntroduce you to specific safety topics

    Fire safety, lab safety, office safetyFire safety, lab safety, office safety

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    Why Worry about Safety?

    Why do you need to be concerned about safety ?Why do you need to be concerned about safety ?

    Hur

    t

    DOL

    EPA

    $$$$

    Losttime

    WC Pain!

    Loss

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    Understanding Accident CausesUnderstanding Accident Causes

    Accidents are caused by:Accidents are caused by:

    Unsafe conditionsUnsafe conditions

    Unsafe actsUnsafe acts

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    Accident CausesAccident Causes

    Unsafe ConditionsUnsafe Conditions

    Easiest to correct (and very cost effective)Easiest to correct (and very cost effective)

    Easiest to preventEasiest to prevent

    Safety auditsSafety audits

    Safety inspectionsSafety inspections

    Maintenance schedules for equipmentMaintenance schedules for equipment

    Encouraging employee reportingEncouraging employee reporting

    Good housekeepingGood housekeeping

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    Accident CausesAccident Causes

    Unsafe ActsUnsafe Acts

    Most difficult to addressMost difficult to address

    Changing behavior isnt easyChanging behavior isnt easy

    Best prevented by developing a safetyBest prevented by developing a safety

    cultureculture

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    Which one is difficult to visualize or mitigate ?

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    Cost of AccidentsCost of Accidents

    Direct CostsDirect Costs

    Medical Costs (including workers comp)Medical Costs (including workers comp)

    Indemnity PaymentsIndemnity Payments

    Indirect CostsIndirect Costs

    Time Lost (by worker and supervisor)Time Lost (by worker and supervisor)

    Schedule delaysSchedule delays

    Training new employeesTraining new employees Cleanup time / equipment repairsCleanup time / equipment repairs

    Legal feesLegal fees

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    Cost of Accidents:

    On average, the indirect

    On average, the indirectcosts of accidentscosts of accidents

    exceed the direct costsexceed the direct costs

    by a 4:1 ratioby a 4:1 ratio

    The Iceberg EffectThe Iceberg Effect

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    So how do you protect yourself ?So how do you protect yourself ?

    ????????????????

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    Safety CulturesSafety Cultures

    Establish accountability for safetyEstablish accountability for safety

    Define safety responsibilitiesDefine safety responsibilities

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    Thank youThank you