orderer: order - tejidosroca.com reach 2018.pdf · prüf- und forschungsinstitut pirmasens e.v. •...

Germany

Expertise: 1801832-01-30-01 d1 Datum / Date: 2018-03-13Dr. Anderie

Orderer:

Order:

Tejidos Roca SL

Polígono Ind San Augustin ES - 30430 Cehegin (Murcia) Spain

Recei ved: 2018-03-06

Test ítem:

Examination of materials

Your letter/Fax/Email dated 2018-03-01

Textiles, no skin contactP Samoyedo, col. gris,Q Samoyedo, col. marino,R Samoyedo, col. burdeos,S Samoyedo, col. crema,T Samoyedo, col. negro,

Test results:Description of the procedures, shortcuts and detailed results of the tested samples on the following pages.

Parameter

Alkylphenoles, OP+NP

Alkylphenole Ethoxylates, OPEO+NPEO

Chlorinated Phenoles, PCP

Chlorinated Paraffines, short-chain (sum)

Dimethylfumarate, DMF

Formaldehyde Textiles

Phthalates

Polycyclic aromatic hydrocarbons, PAH (sum)

Content of Lead after total digestión

Contení of Cadmium after total digestión

Prohibited aromatic amines, AZO

Tinorganic compounds

Unit

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

%

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

Result*

SEP

SEP

< 1.0

-

<0.1

<20

-

-

-

-

<20

< 1.0

Material

MP

MP

EP

EP

MP

MP

MP

Rating

0

0

0

0

0

0

0

Rating:0 = Sample meets the REACH Annex XVII requirements1 = Further test necessary2 = Sample failed the legal REACH Annex XVII requirements- = not tested or material not availableRemarks:n.n = not detectable (n.d.), MP = mixed materials, EP = single* Expiicit given results for mixed materials (MP) are the total cineqiialify the content of each material of the mixed sample is

aterial test, SEP = see detailed resultsent of the sample. For valúes with sign of

he gi)/e/i valué

;.(Institutsleituhg / Managing Director)(Abteilungsleitung / Department Management)

Prüf- und Forschungsinstitut Pirmasens e.V. • Marie-Curie-Strasse 19 • D-66953 Pirmasens • www.pfi-germany.de • [email protected]

Seite / page 1 von / of 3PFI-FB-PB01-04-2015-09

Germany

Expertise: 1801832-01-30-01 d1 Datum / Date: 2018-03-13Dr. Anderie

Appendix to expertise 1801832-01 -30-01 d1Single results of the tested samples

Parameter



Alkylphenole Ethoxylates,OPEO+NPEO

Alkylphenole Ethoxylates,OPEO+NPEO

Chlorinated Phenoles, PCP

Chlorinated Paraffines,short-chain (sum)

Dimethylfumarate, DMF




Phthalates

Polycyclic aromatic hydrocarbons, PAH(sum)

Contení of Lead after total digestión

Contení of Cadmium after totaldigestión





Material

1 : (P) TX, (Q) TX, (R) TX, (S) TX

2: (T) TX

1 : (P) TX, (Q) TX, (R) TX, (S) TX

2: (T) TX

1:(T)TX

PNR

1:(T)TX1:(P)TX

2: (Q) TX, (R) TX

3: (S) TX, (T) TX

PNR

PNR

PNR

PNR

1 : (P) TX, (J) TX, (R) TX, (S) TX

2: (T) TX

1:(P)TX, (Q)TX, (R)TX

2: (S) TX, (T) TX

Result*

<30NP<30OP

<30NP<30OP

< 100 NP< 100 OP

< 100 NP< 100 OP

< 1.0

-

<0.1

<20

<20

<20

-

-

-

-

<20

<20

< 1.0

< 1.0

Unit

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

mg/kg

Rating

0

0

0

0

0

0

0

0

0

0

0

0

0

ShortcutABBSBSLDFDKNDSLDSMEBFFLFFMFLFMGP

Englishshoe heelinsoleinsole leatherheel patchpress buttonsock leathersock materialpipinqheel lininq leatherheel lininq materiallininq leatherlininq materialwhole product

ShortcutGZHKHZKHKKKKNKOKVLEMHKMSNAD

Englishelasticheel capwoodno direct skin contactplástic compactbuttoncorkveleroleatherwith direct skin contactmetal loopseam coverinq

ShortcutOLOMPNRPPPTRSVRSV-ADSBSBLSchlSESMSN

Englishupper leatherupper materialtesting not relevantpaperboardty pical of productzipperzipper coveríngshoe laceshoe lace leatherloopsolé insertionfoambuckle

ShortcutSOSOSOLSRSWsyn.TXVKZBZMzsZWM

Englishoutsoleeyeletsolé leathersolé weltnew woolsynthetictextiletoe capfancy tapeintermedíatetoe spreadernot enouqh material

Examination Procedure:Test methods are part of the laboratory accreditation (D-PL-14150-01-00)

Shortened form: Alkylphenoles, OP+NPDeterminaron of Nonylphenole (NP) and Octylphenole (OP)using GC-MS after solvent extraction

Die Prüfergebnisse beziehen sien ausschlieBlich auf die Prüfgegenstánde. Ohne schriftliche Genehmigung des PFI darf die Expertise nicht auszugsweise verwendet werden. RestlichesUntersuchungsmaterial wird nach 10 Wochen vernichtet. In Einzelfállen kann eine Untervergabe an andere geeignete Prüflaboratorien erfolgen. Ein Verzeichnis der akkreditierten Prufverfahren undunsere geltenden Allgemeinen Gescháftsbedingungen kónnen auf unserer Internetseite eingesehen werden und werden Ihnen auf Anfrage gerne zugesandt. / Test results solé/y refer to the Ítemstested. Extracts of the expertise may not be used without written permission by PFI. Remaining materials will be destroyed after 10 weeks. In individual cases, tests can be carried out by qualifiedsubcontracting laboratories A list of accredited test methods and our applying general terms and conditíons are available on our website and will be sent to you on request.


Seite / page 2 von / of3PFI-FB-PB01 -04-2015-09

Germany

Expertise: 1801832-01 -30-01 d1 Datum / Date: 2018-03-13Dr. Anderíe

Shortened form: Alkylphenole Ethoxylates, OPEO+NPEODetermination of Nonylphenol ethoxylates (NPEO) and Octylphenol ethoxylates (OPEO)DIN EN ISO 18218-1:2015-11 for leather and DIN EN ISO 18254:2016-09 for textiles

Shortened form: Chlorinated Phenoles, PCPDetermination of PentachlorophenolDIN EN ISO 17070:2015-05

Shortened form: Chlorinated Paraffines, short-chain (sum)Determination of short-chain chlorinated paraffines (C10 - C13)DIN EN ISO 18219: 2016-02 for Leatheraccording to DIN EN ISO 18219: 2016-02 for textilesafter extraction with toluene with GC-MS for plastics

Shortened form: Formaldehyde TextilesDetermination of free and hvdrolytic Formaldehyde in textileDIN EN ISO 14184-1:2011-12 and BVL B 82.02-1:1985-06

Shortened form: PhthalatesDetermination of selected phthalatesTRDINCEN ISO/TS 16181; DIN SPEC 91181:2011-10according to CPSC-CH-C1001-09.4

Shortened form: Polycyclic aromatic hydrocarbons, PAH (sum)Determination of Polycvclíc Aromatic Hydrocarbons PAHaccording to AfPS GS 2014:01 PAK or ZEK 01.4-08:2011-11Remark: For sum formation only those PAH components were taken into account, which have been specified in the material above 0.2mg/kg

Shortened form: Content of Lead after total digestiónDetermination of Heavy Metals after total digestiónE DIN EN 17072-2: 2017-09 for leatherDIN EN 16711-1: 2016-02 for textilesDIN EN 14602: 2012 (incl. DIN EN 1122:2002) for plastics/metal parts/foamsCPSC-CH-E1002-08.3 / CPSC-CH-E 1003-09.1

Shortened form: Content of Cadmium after total digestiónDetermination of the content of Cadmium after total digestiónE DIN EN ISO 17072-2:2017-09 for leatherDIN EN 16711-1: 2016-02 for textilesDIN EN 14602: 2012 (incl. DIN EN 1122:2002) for plastics/metal parts/foams

Shortened form: Prohibited aromatic amines, AZODetection of prohibited aromatic amines from Azo-dvesDraft standard DIN EN ISO 17234-1:2012-10 and DIN EN ISO 17234-2:2011-06 and BVL B 82.02-3(V):2004-06 for leatherDIN EN 14362-1:2017-05 and BVL B 82.02-2:2004-06 for textiles and BVL B 82.02-4:2004-6 for polyesterDIN EN 14362-3:2017-05 and BVL B 82.02-9:2006-09 / BVL B 82.02-9:2006-09 revision:2008-03 (4-Amino-azobenzene) fortextiles/polyester

Shortened form: Tinorganic compoundsDetermination of Tinorganic compoundsTR DIN EN ISO/TS 16179; DIN SPEC 91179:2012-12Dibutyltin (DBT), Dioctyltin (DOT), Tributyltin (TBT), Triphenyltin (TPhT)

Test methods are not part of the laboratory accreditation (D-PL-14150-01-00)

Shortened form: Dimethylfumarate, DMFDetermination of DimethylfumarateTR DIN EN ISO/TS 16186; DIN SPEC 53280:2012-12

Die Prüfergebnisse beziehen sich ausschlielilich auf die Prüfgegenstande. Ohne schriftliche Genehmigung des PFI darf die Expertise nicht auszugsweise verwendet werden. RestlichesUntersuchungsmaterial wird nach 10 Wochen vernichtet. In Einzelfállen kann eine Untervergabe an andere geeignete Prüflaboratorien erfolgen. Ein Verzeichnis der akkreditierten Prüfverfahren undunsere geltenden Allgemeinen Gescháftsbedingungen kónnen auf unserer Internetseite eingesehen werden und werden Ihnen auf Anfrage gerne zugesandt. / Testresu/ts solé// refer to the Ítemstestad Extracts of the expertise may not be used without written permission by PFI. Remaining materials will be destroyed after 10 weeks. In individual cases, tests can be carried out by gualifiedsubcontracting laboratories. A list ofaccredited test methods and our applying general terms and conditions are available on our website and will be sent to you on request.


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