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Oil Seeds, Crush and Refining FEED and FOOD safety Barry Brakenhoff 1

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Page 1: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

Oil Seeds, Crush and Refining

FEED and FOOD safety Barry Brakenhoff

1

Page 2: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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- Cargill GOSCE - OilSeeds

- Origin - Uses for the Oilseeds

- Uses for the Oilseeds Oil - Uses for the Oilseeds Meal - Food / Feedsafety

Agenda

Page 3: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

Cargill GOSCE

• Operate in 18 countries in Western, Central & Eastern Europe

• Operate 19 crushing plants

• Operate 6 port facilities

• Operate 49 inland silos

• Sell from 4 biodiesel plants

• Trade grain & feed ingredients

• Employ around 3,600 people

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Page 4: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Countries

Page 5: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Cargill GOSCE focuses on the six major Grains & Oilseeds

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Sunflower Seed Rape Seed (Canola) Soya Bean

Wheat

Maize (Corn)

Barley

OILSEEDS

GRAINS

Page 6: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Countries of origin Oilseeds

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Sunflower Seed Rape Seed (Canola) Soya Beans

OILSEEDS

Page 7: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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FEED FOOD Technical

Uses for Oilseeds

Page 8: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

Uses for Oilseeds

Can you name products made from / with Oilseeds?

FOOD TECHNICAL FEED

Cooking oil/ Frying oil

Biodiesel Compound Feed (pigs/cows/chicken)

Margarines PVC (plastics) Fish feed

Lecithin Lubricants Fermentation basis

Page 9: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

Uses for Oilseeds

Can you name products made from / with Oilseeds? Did you think this?

Page 10: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Uses for Oilseeds

Oilseeds are processed for production of FOOD products

Page 11: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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42%

58%

Rape and Sun Oil

OilMeal (*)

20%

80%

Soy Oil

Uses of Oilseed Oil

Page 12: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Main use Seed Oils in Feed Stuffs

Crude Rapeseed Oil Aqua feed

Crude Sunflower Oil Poultry feed

Crude soybean oil Poultry feed

Page 13: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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58%

42%

Rape and Sun Meal

Meal (*)Oil80%

20%

Soy Meal

Uses of Oilseed Meal

>80% FEED

Page 14: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Feed safety

1kg Beef

3kg Pork

5kg Chicken

9 kg Insects

10 Kg of Feed results in:

Page 15: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Soy Meal 63%

Rape and Sun Meal

25%

Others 12%

Sources of Protein in Feeding

Source: Fevac.eu

Oilseed meals are the main source of protein in feedstuffs

Page 16: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

Food safety of Oilseeds/products

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Page 17: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Most important hazards Oilseeds RISK OIL MEAL By Products

Pesticides X (crude) X

PAH4/BaP X (refined) X

Bacteria (salmonella)

X

Dioxins / PCB’s If coconut Coconut and FAD

Mineral Oil X X

GMO X X X

=> In depth incoming raw material risk assessment is advised, combined with good process knowledge, in order to assure food/feed safe products.

Page 18: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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=> raw material material risk assessment

Page 19: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

Adjustment of Combine Harvester

Previous crop Tillage Cultivar (seeds)

Fungicides

Storage - Elevators

FOOD FEED

+ if MAIZE - if WHEAT or OILSEEDS

VARIETIES - or + SENSITIVE

more dust & admixture = more mycotoxins

Field

Use of fungicide at right time minimize mycotoxins spread

+ if NO TILLAGE - if TILLAGE

CUSTOMERS

Page 20: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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• Knowledge such as practices and local requirements in the supply chain • Data such as monitoring results • Product characteristics, change in (GMO) varieties • Climate circumstances (e.g. aflatoxin, wet means drying, etc)

Raw material risk assessment based on

HIGH RISK

MEDIUM

LOW RISK

Page 21: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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This means: may vary from year to year

Monitoring: So in depth monitoring in order to assure correct risk assessment/country need is done every year at start of crop. -> you can’t rely on previous year (e.g. aflatoxin in mais, or dioxin in rapeseed Ukrain)

Page 22: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

Pesticides Fertilizer

Herbicide

Insecticide

Fungicide

• Fertilizer • Treated seeds: Insecticide + Fungicide • Insecticide for bottom insects • Herbicide: weeds

• Herbicide: Generiek •Fungicide: Fusarium, Eyespot

•Fertilizor: Nitrogen

•Insecticide: At aphid contamination Fungicide: Septoria treatment

Herbicide: weeds •fertilizer: Foliar •Insecticide: Sesamia/Pyrale Mais

Fungicide: Flag leaf protection

Herbicide: Drying of the product before harvest

Page 23: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

Pesticides (limits)

Page 24: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

Pesticides Transfer Olie zaad of fruit

Oil % Transfer factor

Palm fruit 50-55 2 Cocos 20 5 Palm kernel 45 2 Rapeseed 40-45 2,5 Sunflower 40-45 2,5 Soy 19 5

20% oil

Soy bean

42% oil

Rape & Sun

5x +/-2,5x

Page 25: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Pesticides (limits) GORBE Product Assurance Team

20% oil

Soy

42% oil Rape

MRL of Chlorpyrifos in oilseeds is 0,05 mg/kg

0,125 mg/kg 0,250 mg/kg

What is the maximum MRL In the Soy and Rape oil?

Page 26: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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• One of the most common contaminants found in extracted rapeseed, soya and sunflower oils

• PAH4 and BaP contamination usually comes from the exhaust residues of poorly maintained direct heat grain dryers, or dryers using dirty fuels such as heavy fuel oil or diesel

PAH4

Poorly maintained burners often burn with a yellow flame, showing incomplete oxidation of the fuel and causing additional contaminants in the exhaust gases Most grain dryers pass the burner exhaust gasses directly through the grains

Page 27: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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• Maximum levels (GMP+) in crude oils for Feed are 160ug/kg, there is no EU legal limit for PAH4 for feed use.

• PAH4 is normally only a problem in oils only (and by products)

PAH4

Page 28: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Feed safety Bacteria / Salmonella • 2300 strains of salmonella have been

identified but only a few cause problems in humans

• 40% of food poisoning outbreaks are caused by salmonella

Salmonalla is not a problem in oil, but a problem in Meal

Page 29: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Feed safety Bacteria / Salmonella • Feed limits: Absent in 25 grams

Page 30: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Dioxins and PCB’s

The source of dioxins : - Byproducts of PCB production - Waste incineration - Formed by burning hydrocarbons and chloride

PCB’s were used in the past as cooling and insulating fluid for industrial transformers and capacitors

Page 31: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Dioxins and PCB’s (Limits)

Dioxins: Feed material from Action limit: 0,5 ng WHOPCDD/FTEQ/kg Rejection limit: 0,75 ng WHOPCDD/F-TEQ/kg

Page 32: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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• Moulds and fungi Often found in cereal grains, while not

toxic themselves, are often able to produce toxic by-products (mycotoxins)

• Naturally occurring poisons Found in some weed seeds such as

ambrosia, mustard, cotton etc

Mycotoxines / Natural Poisons

Page 33: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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• Moulds and fungi e.g. Aflatoxin Limits in Feed: (EU) 574/2011 / 2002/32/EC: 0,02 mg/kg GMP+ dairy farmer : 0,005 mg/kg

• Naturally occurring poisons Limits: Most of the cases not detectable

Mycotoxines / Natural Poisons (Limits)

Page 34: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Mercury(Hg), Cadmium (Cd), Lead (Pb), Arsenic (As) From environmental contamination (field) Or by admixture e.g. adding soil (adding weight)

Heavy metals

Page 35: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Feed limits Hg (0,1 mg/kg), Cd (1 mg/kg), Pb (10 mg/kg), As (2 mg/kg)

Heavy metals(limits)

Page 36: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Oil, grease and fuel contamination

• Oilseeds are particularly high risk as contaminating oil, grease and fuel will get extracted into the finished oil products

• Mineral oils, greases and fuels could contain dioxins, heavy metals and polychlorinated biphenyls (PCBs) which are all highly carcinogenic

• US uses mineral oils for dust suppression on the soybeans

Page 37: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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Ukraine Sun Flower oil: Sat C10-C56 from external sources Max 50 mg/kg ((EC)1151/2009) Other vegetable oils: Hydrocarbons C10-C40: 400 mg/kg (GMP+)

Oil, grease and fuel contamination (limits)

Page 38: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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• GM varieties of rape, soya, are being increasingly grown throughout the world

• Control of these crops at the farm level is often poor • Many food products in he EU are sold as containing no GM material • Most of the soy imported in the EU is GMO

GMO

Page 39: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

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• In Europe the legal limit for approved GM ‘inclusion’ is 0.9% and grains with a level greater than this must be labelled as GM

• 0.01% (or 1 GM grain per 10,000) is presently the limit of detection for today’s technology

GMO (Limits)

Page 40: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

Summary • Oilseeds are used for Feed and Food production

– Oil mainly for the food and biodiesel – Meal mainly for feed

• Biggest part of the Oilseeds are used for Feed production • Risks for Meal and Oil are different

Page 41: Oil Seeds, Crush and Refining - mvo.nl · PDF fileOil Seeds, Crush and Refining . FEED and FOOD safety . Barry Brakenhoff . 1 . 2 - Cargill GOSCE - OilSeeds - Origin ... rapeseed,

Questions?