office of prevention, pesticides and ......1994/12/16 · cab'tp por!onn any...

,.: , \ -r'

If'

UNITED STATES ENVIRONMENTALPROTEcnON AGENCY •

WASHINGTON, D.C., 20460

DEC 16 1994 TOM DUAFALA TRICAL, INC: p.o. BOX 1327 HOLLISTER, CA. 95024

OfFICE Of PREVENTION, PESTICIDES AND

, TOXICSUBSTANCES

Subject: Label Amendment Submission of 6/20/94 in Response to, PR' Notice 93-7 EPA Reg. No. 11220-15 TRI-FORM 40/60

Dear Registrant:

The labeling cited above and submitted in connection with registration, under the Federal Insecticide. Fungicide, and Rodenticide Act (FIFRA), as amended, is accepted subject to the comments reflected on the enclosed sheet. A copy of your proposed labeling stamped "ACCEPTED WITH COMMENTS" is enclosed.

WHAT THIS ACCEPTANCE MEANS:

Based on your certification, the Agency has accepted the labeling changes that are necessary to comply with the Worker Protection Standard (WPS) labeling requirements of 40 CFR part 156. subpart K, described in PR Notices 93-7 and 93-1 L Any other fabeling changes submitted in connection with this amendment application but not directly related to compliance with the WPS h!ive not been reviewed or accepted by the Agency. If you wish to make such Changes, you must submit a separate 'amendment application proposing them. If your product is .currently suspended. the accept,ance of this labeling amendment does not affect the suspension ,In any way. "

WHAT YOU NEED TO DO NEx:T:

BY'the next label printing' I!lake all the sp~cified changes to ,your labeling~ ,Send to

EPA one (I) copy of the final printed labeling: " . ' . ' . -'. . . --

" ,

• 'AND

• BEFORE,selliiig or' dIstributing any product bearing'the fiI).al printed labeling

. I. ~, , • ~ - ~.- .',

WITHIN' one year from .dare of this acceptance . . ." '.' - --, ',- ,

, " .' '.

~:., .-;

I:'" .. , , , -.;

_. ·'.'i

'--.- .

'.

. ,

/" . ,.' '

.. - ,". ~.~: . , .. '

Page,2-, '.: -

, ,

Submit thefmal' prlnted lab~li~g via the U.S.'po~i~.l S~i-v:icef~: • - - '" • - , , .. > .. - '." '.

, '

" D6cunient Ptocessing~:Oesk(FIN-LABEL) . : Office of Pesticide Progr~ms (75b5C) . . . U$~ EnVironmental Protection Agency'

401 M Street, SW ' .. Wasmngton, D.C. 26460-dOO1 '

'. " " ,

"'.

Hand or courier deliveries offinalpdnted labeling may be made to: " . . '> , --<'..' -.c -'.' " • __ .' • , __ ,_ __ ,'" ~~~ __ ',-_

Attachment

Docliment Processing De~k (FIN-LABEl,.). Office of Pesticide Programs" ..' . Room 266A, Crystal Mall 2 1921 ]effe~son Davis Highway Arlington; V A 22202 ,

, -" . '-.

!-'::.:.. .. ...,

.' :."

.. : ~:.,

- -',

• ,> "

, ! ,.-

"

ll ..... .u.tJIUV.ou· ns, DeputY Chief 'str on Support Branch'

Re . tration· DhQsion (7505W) "

L_

\

" ~

_- i - -; _ ....

~:;;'-' -----

.,

\ -. "

Tri-Form 40/60 Label Column 1

RESTRICTED USE PESTICIDE For retail sale to and use only by Certified Applicators or persons under their direct supervision and only for those uses covered by the Certified Applicator's certification.

TRI-FORM 40/(?O A LIQUID SOIL FUMIGANT

FOR PREPLANT TREATMENT OF CROP LANDS TO CONTROL PLANT PARASITIC NEMATODES AND CERTAIN OTHER SOIL PESTS. NOT FOR USE IN GREENHOUSES OR OTHER ENCLOSED-AREAS.

ACTIVE INGREDIENTS: 1,3-Dichloropropena Chloropicrin

INERT INGREDIENTS: TOTAL

37.6% 59.4% 3.0%

100.0%

ConlaIns .t.51 pounds of1.3-Diehloropropene and 7 .. 13 pounda of chloropicrin porgallon.

Peligro: Si Usted no entiende fa etiqueta, busque a alguien para que sa la explique a Usted en detana.. (If you do not understand the faber. find someone to explain It to you in detail.

IN ALL CASES OF OVEREXPOSURE GET MEDICAL ATTENTION IMMEDIATELY.

TAKE PERSON TO A DOCTOR OR TO AN EMERGENCY TREATMENT FACILlTY_

FIRST AID IF INHALED: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-te-mouth. If breathing Is difficult. give oxygen. Call a physician.

IF ON SKIN: Immediately flush skin with plenty of water for at least 15 minutes while removIng contaminated clothing and shoes. Call a physician. If water Is not immedIately ava~able. remove excess chemIcal from skin with adsorbent material such as towel or dry soil. then proceed at once to a location where water Is avaifabte and thoroughly wash contaminated skin with plenty of waler. Cail a physician.

IF IN EYES: Immediately flush eyes with plenty ofwaterfor aUeas! 15 minutes. Cail a physician.

IF SWAllOWED: Do not Induce vomiting. Cail a physician or Polson Control Center immediately. Never give .anythlng by mouth to an unconscious person.

NOTE TO PHYSICIAN: Because rapid absorption may occur. through lungs if product Is aspirated and causes systemic effecls. the decision to Induce vomiting or not shouTd be made by a physician. If lavage is performed. endotracheal and/or esophageal control is suggested. Danger from lung aspiration must be: weIghed against toxIcity when considering emptying the stomach.

s_ Sido Panel For Additional Pree;luOOnary S1alemonls.

TRICAL P.O. Box 1327, Hollister CA 0502<1.

E.PA EST. 11220-CA-1.2,3,4;FL-1 E.PA REG. NO. 11220-15

NET CONTENTS •.••...•.• __ •• LBS.

,..;Jtp.p.~fl;mL -ht EP~J.~!§,d

UndeP~~ FL~rJ~iclde, Fwtdlckle, ... d Bodenlicl<!e Act 118 "",ended, tor the peetielde "lIIoiered under J!;PA Reg. No.

1/?~6 ~ <S:

)


PRECAUTIONARY STATEMENTS· HAZARD TO HUMANS

AND DOMESTIC ANIMALS: DANGER

HAZARDOUS LIQUID AND VAPOR DO NOT SWAllOW AN'( OF THIS PRODUCT. MAY BE FATAL IF SWAllOweD. DO NOT GET IN EYES. CAUSI;S SEVERE EYt; IN.,tURY. DO NOTGET ON SKIN. MAYBE FATAL IF ABSORBED TI-iROUGH nJE SKJN..CAUSESSKINBlJRNS. MAY CAUSE AtlERGlCSKIN REACTION. DO NOT BREATHE VAPOR. MAV SOE fATAL iF' INHALED. MAY CAUSE LUNG~ LIVER. AND KIDNEY DAMAGE AND RESPIRATORY SYSTEM IRRITA.TION UPON PROLONGED CONTACT.' THE USE Of THIS PRODUCT MAY BE HAZARDOUS TO YOUR HEALTH. ntiS PRODUCT CONTAINS 1.3--0ICHlOROPROPENE. WHICH HAS BEEN DETERMINED TO CAUSE TUMORS IN LADORA TORY ANiMAlS. RISKS CAN BE REOuceD BY EXACTLY FOLLOWING DIRCCllOHS FOR use. PRECAUTIONARY STATEMENTS. ANO BY WEARING THE PERSONAl PROTECTI\fE EQUIPMENT SPEClFlED tN-mIS-LABELING. • nus Fl.JUIGANT HAS THE CAPACITY TO CAUSE MARKED lRRrr" nON TO THE UPP,ER RESPIRATORY TRACT. A STRONG LACHRYMATOR (TEAR..pROOUCING EYE IRRrrANT). lOW CONCENTRA. nONS ARE CAPABLE OF CAUSING PAINfUL EYE IRRITATION. THE EFFECT MAY BE. SO POWERFUL THAT A PERSon ~Y BECQME TEMPORARILY BUNDED ANOPANJC,.STRICKEW. THAT. IN TURN.. MAY LEAD TO ACCIDENYS.

AIR CONCENTRATION LEVEL The- aocep!abt& ai- concenltalhn level ror persons exposed 10 cMoropic:rh rs 0.1 P?m (0.7 mgIM~. The air concenhallon level is measured by a crecl tMCltlg det&clion device, such as a MathesOQ.Kitagawa, Draeger, or Sensidymt.

PERSONAL PROTECTIVE EQUIPMENT (PPE) Che~tanl MalClrlats: Some matertsb thai are chemicaJ..f&'Sblant to lhif. product are hied below. If yC'AJ want more opoon$, foDoYo' Ihe lnslrudions for category H Of! an EPA chemical resi$lance category selection chart. PPE construcled of Saranax, neoprene .. and chbrinaled polyelhykmo proyide short·lerm contact or splash prot&etion against Jiquid of" (his prqdlJcL lonser-term prolGCtlon is provide<! by ppE conslructed of Vilon, Telbt,. and BI/J.L barrlei' lami"lales (fot example. Respond6r suits rnanufaclur&d by liCa-guard 01" Sivel'5hiakt gloves manufZlclured by North). Leather, canvaa. Of'" col1on materials offer no proteclion (rom this product and must not be wom wheon contact with

, this produc:t Is ponlbkt.

(1) HandJora P&ri'onning Dtroct-COntac:t Tas.k$.: Oirod-conlac1 tasks ato tasks Peor~ -, formed ouldoon;. or in • weD·venli'bled area. Thf))" nclude: • oquPmontc:anbraUon 01 adjuslment

equProltntdeanup and repaIr

• pt'tlOJd DmpIing • appkalion OC' soi'·seating outside an endo:s.od e~ • any adN!y t&ss than 6 fool from an un:s.hlekl&d pressurized han eonlainlng lbb

product. • reomovaJ onalP or plastic fikn • msale disposal

fumigant lr.msfer cleanup of smaIt spD!S preparing canlainors for aaralion

• any' othM handling task. not oIhl!lrwise lisled ., (2). (3). or (4) b&~ Applicalors and other handl&rs performing direcl-conlacllasks must W&.u::

• Covot1ll$ovetshorl-sfeeved sMt and short plInls. .. ~isr!lnl gloves."uch as barrier laminal. or '\Iaon. .. ~istanl foofwaarplls socks, .. ClwtmkakesEslant hellld!i1~r (or eveomead exposure, .. ChemicaJ.Rtsislanl apron • .. Ful-!ace Respinltor with elher an organlc.vapor.reomaving cartridga with. premier

!lpproved ror pesJicides (MSHAmIOSH approval number prertlC rC23C). Of •

canister approved for pesticides (MSHAINIOSH approval numbar prefix TC-1.cG). See fur\ber respiralor f&CI.ulromonls in the -Usor Safeoly R6Cjuiremonls· s;ec:lioP of the .......

(2) HaDdTors .. Enclosed Cabs: ApprJCators and othar handSeI'5 &1 onclos&d cabs must wear: -eo.."" • Shoe$ and socIcs •

.. Plus. 'I odor or lrriIalion flOm tllIs prodtlct can b6 delecl&d InskJo the endo:s.&d cab orifihoak'conceonlralion fevolotch!oroplcrin oxcoeods 0.1 ppm inskfo Ih& enclo$od c:ab. hanIfef's it the cab must wear a full-face res.piralor wlh &i!her an organic. vapot.ramoving cartridg& ¥.!iIh III prnliHer apP'OVIKi for p6&Ucldoa (MSHAINIOSH approval number plOrllt TC23C). or a ctmisler approved fot pG"SIicJdas lMSHN NIOSH appt:tN8lnumbor prerbc TC-14G). Soo (urlher respiralor requir&monls h tho "tkMSafoly RequiomtloJl!s" s&c:tkln of the IabeoL

... In addlion,,!hllt PPE $p6cifitlod n t1l fr)f'citecl..coJ\taci aclNiUes muslbo Imnurdlal&Jf DVaJabJa Tn lhlt anclosod cab and must be wom l tho handler Ioav&!. tho onclo5ed cab'tp por!onn any olr&Cl--ccnlacl aclivily. Th& endos&d cab mU5t f'IKt8t lh& requiramenb listoo In Iho Worker Prol&eOOo Standard (WPS) lor lII~ullural _eFR 170.240Cd)(5).

(3) Handh.s !q Tru810d hei! Within 72 Hoors Ancr ApplicaUon: Only thCI roJowrng handlorlasb MaY be perform&d In the Iroaled area within n hOOr1o after tba applicati:Jn Is complete: • A:s:sDSs.~\hg tho sol seal • Asses.:sing' pesl conlrot lIppllca!ion lechnlque. 01' application efficacy • Sampling_orsoilforlhisproducl All other lash are prohibilcd unlil the 72 ·hour period has e,cptm<f. Unr&:s: rn an enclosed cab as described In (2) aOOvIlt. hancHOJ'$ performlng tho lI00VO tasks In Ih& troaled ama lWhJn 72 hours after application must wear:

• Cov&laJ!s.. .. ChemicaHe:slsbmt Sh~.such as batrler lam;"a!e ex vltOrt, • ChemiclJ.te:slstanl lootweoar and socb, .. PJus..l odorot Imlation from this product can be defectod or lftho air concenlralion

Iewlolcbloropicrin exceeds 0.1 PPm. hanC~r$ must waara (ul-faco raspJraJotwith e:tber 3D organlc-vapor .... emovlng carlrkfge 'oIrih III preofiHer approved for p&$1ic:idCl$ (MSHAItOOSl-f approval numbe,. prefllt TC-23C). or a canistor approved for p&sIIdde. (USHA1N10SH approvlll number ~rlX rC-104G). $&a furlher rMpralor ,~ h!ho "User Saf~1y Requir&menb" lIeclion or 1M labot.

SOD RequIrements Conllnu&d In ThIrd Column

)


R&quIrem~nls. Continue<1:

(0() Handlers.Expo:sed to High ConcentratIons: HandiMs e:xposod 10 high aroom .. con¢el'tlrations or this product. such as cl&antlp following lal9G $pi~. k1--1ank cie.!lfling 0( bulk tanka. and exposure 10 [his producl 10 poorly venblaled areas. musl wear:

• Chemlc:aJ.resistanlsul,. ". • ChemlcaJ.resislant glovos, such as' barrieT famlnale or vlton.. • ChemkaJ..resisl&nt Cootwoar plus socks. • Chemal-resislant headgear, • SuppI»d-air respir.Jlor will:a MSHNNIOSH approval l'Iumbeqtl'llfpc TC.19C orsof.

contalMd brealhing apparabJs {SCM} with MSHAINJOSH' approval numw prefLlC' TC-13F. Seo further resplralor reqliremon!$ in the ~seF Safety Requiremenl$$edion o(!he label

USER SAFETY REQUIREMENTS 1. Respirator Requirements: When l! resplralor is rttqulred for use with Ihis produ~t. Ihe following criteria must be met: (&). Fllrf..fac8 respiralors musl b:o wom. (b). Cartridges or canisters Tusl be rep>c/ld daly or wfHIll odor or irritation from this product becomes appar&llt, Whi::hevet is sooner. eel. Respir.D!cn musl be fl·lesled and m.ch&<:lted using; a program Ih.al conforms 10 OSHA's roquitomenls (dosc:rlOed in 29 CFR Part 1910.134). (d). R&spiralor useis. must be trailed usioll • program thai conronns 10 OS!-tl\'s requirements (desc~d In 29 CFR Parl1910.134). eel. RlIspiralor L'SOrs must be. eJ:amin6d by a q:uaitiod medical prac:tiUoner 10 ensur. physical ability 10 safety waat the- sfylo of respirator 10 be; worn. 2. Never Fumigatlt alQ{lO: It is Impcltoltlm 10 always h.1vo an assistanl and proper prol&c:tMt equipmont In ClISO 0( accldenb. 3~ Ori\lOl'5 RMponsibiJi[ios: Drivers or appJieaUon 6qui;lmenl must lIcMso olhtlt' wMOB of .Ill precautions and procodl1ros. In lIddition, driver$. musllnslrud thoir' oolpers h the mechanical opttraOOn or the traclor and bow 10 s:afely work with Iho Iraclor and dmerwhikl fumTgalilg. 4. Dispo$~ of Contamfnaled Clothing: Discard cloIhhg and other absorbent materials thaI MV& b-Gen dre~hed or neo3viIy con"'mlnal&d wllh r.guid of this product. Do not reuse thom. 5. Clean and MaintaTn PPE: Folow' manurac[amu"s lns!MJclion. rot cleantnglmalnlaln. klg PPE. If no soch inslllJdions for washable$, use delerge:nl and hot .waler. Keep and wash PPE :!i'eparalely from other laundry, Wash PPE after each day';. use-. 6. Conlac! With Mouth: Never $i?hon Ihis proaUd. by mouth or us_e moulh 10 b~ out clogged (nes. no:zles, etc. 7. Heat IIIn~;. Avoidanc&: Use measures lo __ ~yold or mnlmlze heal arness while using this prodoct. Theslll moasllrG3 includo grndualadjuslmGl'ltlo he-a! and respu-alor !>Iress, fans for coolirlg, COOII'lg 'IIesls, fre-quenl breaks 10 cool down, frequent nlalctl o~ drinking water, and m2intaining we~hl from day to day.

USER SAFETY RECOMMENDATIONS Users $houl::l: • Wa:!i'h hands before eating, drinking, chewi1g gum. using tobacco, or usinglho loiktL • Removo ciothing fmmedialely If pestic:ida gels inside. Then wash thoroughly and pul

on cl&an c~ing. • Removo PPE knm&eiately aRer handling this product. Wash tho ou!"id. 01 gloves

berO(e romoving. As soon a. possib», W35!J Ihoroughly and <:nanga inlo clean cJothhg~

EMERGENCY: In CZlUII of an emergency endangering hoalth or tho enWonm.nt rn.-oIvhg thl$ product. call tM 24 Hour Emergeoncy Phon-Ill Numoor (8CO) 424·9300.

," --~ .. '--~

STORAGE, SHIPMENT AND DISPOSAL StilPPING, STORAGE: Agricultural Chemical. Do nof shfp or slaro with food, feeds. dtugs or dolhing'.

sl'ORAGE: store In lightf)'..clos.ed original contahor h:l coot pIaco away from dwolings, {)(lI noIl1lJow contamination o(seoQs, plants, fartilzera. or oIhot poslk:ide chemicals. Do not contzunin.ate food, feed sluffs, drugs, or domesllc water suppliM..

DISPOSAL: PestIdde wastM- are loxk. rmproper Wsposal of fll((;esl p6sllcidlll and rinsale-s Is a violation or Feder.al law. If lhesa waslet cannol be d"lSposed of by use according 10 label Insltucliooa. conlad your slafa pes.licide or environmental control agency. or the hazardous: wasta repreaonlatNe altha noarest EPA lltgionat CJlfJCe for guidance~ 8&cau$O 1.3 .. dkMo(Qprop6fI8 is corrosive uodM' certain condilklrls:, llusb III Dpp1icaUon oqu91116nt with fuel oi. kerosene or a similar type of pe:lroleum soN&nt Immedialely aRer use. Fil pumps. and melen wilh now motor ol or a 50% ~or Qlifue' oJ mixture oofota ,loring. Do nol use waler. Dispose of rinsale by app'cllblo Federa~ Statl) lind b=al regulations. Never lnltoduc:o rinsllole or unUli'ed prod'ud hl0 surface or underground waler suppJ;e,s ••

METAl CONT ""lHER DISPOSAl: To d"lSpose of conl':llIner empti&d during appkation op6ralion,. remove bun9s, fflal1 container In Ihe flOld jJsltreal&d and ensure thaI the contaIner is tree of liquid_ Orient contaIner such that venlilaUon of bung holos Is nolo reslricl&<!. Albw conlaners to Deralo ror al least 14 daYS'. Roplacill bun~ prior 10 transport. Mer aeration. offer conlaner 10 qlUliflOd rec:ondilioner or dispose or as li'II'(I(:lod by Stal. or Joear rogulalions.

RSFtU..ABLC CONT"lNERS: Contact Ihe company andtor tho company repl'floo"'!f.H for directions on cleaning and handling '6r~tab:o conla1nel$.

BULK OR IrtINIBUUC PROOUel' lRANSFERS: Dry break or dry disconned cou~lings are r&Cjured for aJ product [ransrers Involving buk containors for producls contalnhg 1.3-<f..:hloroprop-eM as of Sep!I!:Irnb&r 30. 1993.

____ ~--------______ ~-----4

ENVIRONMENTAL HAZARDS Do nor contaminate waler by cleanng of equipment or C'l$posar OfWA~&$. Seo "510(898. ShIpment .and Disposar section. In casa of spilb. property olSpo&e of conlamlnal&d matorials.

Ground Wa!el' Advrsory: 1,3-dichbropropentl Is known 10 move Ihttlugh soil and ulldl!:lr carlain CiUldiJQn& ~ 1M potential Jo reach ground waler 85 a re:;;ult olagriculturat use. Applicallon ... U&as whare aoib ara penneablo and ground water if. nur the .urlaca .. or in k,al'$t geology. coold l'Os;ul n ground wldor c:ontamfnalion.

PHYSICAL OR CHEMICAL HAZARDS-FlAMMABLE: Do no!u.o, pout .. • plt,. Of .font near heal or opan Ibmes. Do nol cui or weld c:onlalnar ..

)

Tri-Form 40/60 Label Columns 4,5

DIRECTIONS FOR USE It b II violation of FGderai bvi louse this produclln a rrumner Incoosislont wilh its labeling. Do not a~pJy lrois product ~ a wwy that w~1 contact worlcol'$ or other porscns, eithor cr.-eelly or through drln. Only protected hzmdkrs may be in the aroa during application. For a,ny Utquiremen(5 r;pecif.c layour state or Tme. consul th& agency responsibl& 10: pesticide: regulation.

r..--E-N-G-I-N-E-E-R-IN-G-C-O-N-T-R-O-L-S-R-E-Q-U-IR-E-M-E-'N'--Ts--'l

ME.t:HANICAl TRANSFER SYSTEM: Personal prol!l'Clrve equipment specif.oo for I -Dired Contact ActNiUes- musl be worn by lIle operator or the mechanical Iransfer . Ii :ilyslem. The operaloc or the mechanical transfor systom must haVIt available 10 him th$ manuracTurer's wrilen mlruclions (or operation or IIlIt system and must read and ! understand (or hava explakted to him In detail) the proper operalion and maintenance of . Ihe sysTem. WITH AlL SULK AND MlNJ..BUlK CONTAINERS: 1.3-dichloropropone and 1.3-<fichloropropene mbwd with chloropicrin must bo transferred through conn&eling hoses, pipes. andIOC" coupUngs surrtdenlly rJghllo prevenl handlors or oth&r persons rrom comlng In contact with liquid 1,3-<fcldoropropene. and/or chforopicrin. ' 1. All 1'10$&5. pIping, and lanks us&d tn connltClion willi 1,3-cflChioropropono and/or chloropicrin sha. be- appropriate rot use under Ihe pressure and vacuum conditions. to be encounTered. • 2. External $igld gaug" shal be: &qupPod with '<121""" 1;0 that pTpes to sight gao". can be shut 011' in case ofbreakago and leakage. 3.. Themechankallransforsyallim must be adequato 10 make n&eeSsary measure-menTs of tho peslicide being U$ed. 4. Shul-olr devices musl be insTalled on lhe exit end of an hoses and al all cfl$connecl poInts 10 ptevenl i&akago of 1.3-d~b1oroproperia andlor chbrop~rin product wOOn the transrer is sloP?OO and hose is removed or cli$connecled. A dl)' coopler thaI will minimb:e peslicide Jeali:age must be installed al the cI~cormfICt polnt. 5. The pressuro in hoses used to movo 1,3-dichloropropone IIndfor ch}Oropicrin beyond a pUmp must nol oxceed thl) mantJraclurer's maximum pressul'6 specifICation •

.

AGRICULTURAL USE REQUIREMENTS Use lhls product onl;t in act:Clrdanco with b tabe:llng and wl1h the Worker Prol&elion Standard. 40 CFR 170. Rofer to supplemental labeling under-Agricullural Us.e Roqulremonts- in tho Di:ocHon ror Use s.eclion ror Wonnation about Ihis slandard.

WARRANTY DISCLAIMER NOTICE Soller wlltfan!s lhat this product conforms to. the chemical doscftllion on the label and b reasonably fit for the purpoS&$ !ilal&d on the labet wflen us&<! In accordance with dil'ocUons under normal conditions of usa, but neilher this warranty nor any other warranty of MERCHANTABILITY ~lr FITNESRFOR A PARTICULAR PURPOSE. express or lmprl6d, extends 10 the USB or Ibis product contrary to label instructions. Of under abnormal condilions, or under condi1lons not reasonably fOf8$oeabkt 10 seDer. and buyer assumas the risk of arrJ .uch uu.

· INHERENT R1SKS OF USE: I is JmpossiOle to eliminate aD risks associat&d with use i of this. product. Crop injury. tack of performance. or oIher unintended consequonces m3y result i bocaU&El or such factors as use of 100 product contrary to label and label booklet inslrucUons i [mcludng conditions noled on the labal and bbol_bookkll. such as unfavorable tempora\uros, sol : CoQndnions, etc.), abnormal conditions (such as excessive ramfa!!, drought, tomadoos,

" : hurrican&s). presence of other materiab. tbe mannor of apprcalion, al of whkh ate boyond the , control of Iha. company or the seDer. All such risks .haD bo assumed by Boyar. !. LlM1TATION OF. REMEDIES: The"Oxcfusivo rem~ for JosS&$ or damagos rnull.ing : from. this product (Including c~1ms ba3ed on contrad. nogligsnco, strict liabilly, or other legal : lh~rie:s). shaD be liml&d 10, at the 'company's electCn.. ona of the following: (1) Refund or

• . • ptJrchase price paid by buyer or user for product bought; or, (2) Replacemllnt of amount of product ; undo The company shaU not be iablo for losses or damages resulting from handlrlg or use of Ihis f product unless Iho company is promptly notified of 5UeIl loss or damagoin writing. In no case shal ; Ihe company bill r~bl& for consequenlial OC' incidenlal damages or losses. The terms of the · Warranty Disclaimer above and this Limitation of Remedies cannot be varirtd by IIrrJ wriUen or · verbal staTement or agreements. No employee or sates. agenl 01 The company or the seller is 1 aulhorized To vary or exceed the terms of the WarranTy OlsclaimBr or this Llmitalion of Rem&d"t&e tn [ any manner.

I CA April,1994

POISON

POISONOUS UQUIDS, FLAMMABLE. n.0.5. (CONTAINS DICHLOROPROPENE, AND CHLOROPICRIN) UN 2929 INHALATION HAZARD

.... ,

Tri-Form Pamphlet Page 1

RESTRICTED USE PESTICIDE For relail sale 10 and use only by Certified Applicators or persons under their direct supervision and only for those uses covered by the Certified Applicator's certification.,

LABEL BOOKlET DIRECTIONS FOR USE JNClUotNG STORAGE. SHIPMENT AND DISPOSAL.: PRECAUTIONARY lNFORMA TIOH. INClUDING REQUIREMENTS FOR PERSONAL PROTECTIVE EQUIPMENT; ENGINEERING CONTROL AND REQUIREMENTS; AND AGRlCUlTURAl. USE REQUIREMENTS-

A UQUID SOLL FUMIGANT FOR PREPLANT TREATMENT OF CROP LANDS TO CONTROL PlANT PARAsmc NEMATODES

AND CERTAIN OTHER SOIL PESTS. NOT FOR USE IN GREENHOUSES OR OTHER ENCLOSED AREAS.

ACTIVE INGREDIENTS: 1,3-D1chloropropene ChloropIcrIn


37.6% 59.4%

3.0% 100.0%

ContaIns <4.51 pounds or 1.3-Dichloropcopcno and 7.13 pouncb of chloropicrin per galIon.

TRICAL P.O. Box 1327, Hollist= CA 05024

E.PA. EST. 11220·CA·1,2,3,4;FL·1 E.PA. REG. NO. 11220·15

NET CONTENTS •••••••••••••• LBS.

KEEP OUT OF REACH OF CHILDREN

DANGER 9 PELIGRO

POISON Peligro:. Si Usled no enUende la etiqueta. busque a alguien para que se fa expHque a Usted en detans. (If you do not understand the label, find someone to exp1ain it to you in detail.

IN ALL CASES OF OVEREXPOSURE GET MEDICAL ATTENTION IMMEDIATELY.

TAKE PERSON TO A DOCTOR OR TO AN EMERGENCY TREATMENT FACILllY.

FIRST AID IF INHALED: Remova to fresh air. If not breathing, glva artificial respIration, preferably mouth-to-mouth. If breathing is difficult. give oxygen. Call a physician.

IF ON SKIN: Immediately flush skin with plenty of water for at least 15 minutes whne removing contaminated dothing and shoes. Calt a physIcian. If water is not immediately available. remove excess chemical from skin with adsorbent material such as towel or dry son. then proceed at once to a location where water Is available and thorough1y wash contaminated skin with plenty of water. Call a physician. IF IN EYES: Immediately flush eyes with plenty ofwaterforatleast 15 minutes. Call a physk:ian.

IF SWALLOWED: Do not induce vomiting. Call a physician or Poison Control Center immedtafely. Never give anything by mouth to an unconscious person.

NOTE TO PHYSICIAN: Becausa rapId absorption may occur through lungs if' product Is aspirated and causes systemic effects, the decisIon to induce vomiting or not shook! ~ made by a physician. If lavage Is performed, endotracheal and/or esophageal control Is suggested. Danger from tung aspiration must be we)ghed against toxicity when considering emptyIng the s.lomach.

Soo Sido panol For .... cMitiona) precaulionary Slalomcnls.

1..2...

)


!:'RECAUTIONARY STATEMENTS HAZARD TO HUMANS


HAZARDOUS LIQUID AND VAPOR 00 NOT SWAUOW ANY OF THIS PRODUCT~ MAY BE FATAL IF SWAllOWED. ' , DO NOT GET u" EYES. CAUSES SEVERE EYE INJURY. DO NOT GET ON SKIN. MAY BE FATAL IF ABSORBED THROUGH THE SKIN. CAUSES SKIN BURNS. MAY CAUSE AllERGIC SKIN REACT10N~ DO NOT BREATHE VAPOR. MAY BE FATAL IF INHAlED. 'MAY CAUSE LUNG. lIVER. AND KIDNEY Dl\MAGE AND RESPIRATORY SYSTEM IRRITATION UPON PROLONGED CONTACT. THE USE Of THIS PRODUCT MAY BE HAZARDOUS TO YOUR' HEAlrn. THfS PRODUCT CONTAINS 1.3-DICHLORGPROPENE. WHICH HAS BEEN DETERMINED TO CAUSE TUMORS IN LABORATORY ~NIMALS .. RISKS CAN BE REDUCED BY EXACTLY FOUOWING DIRECTIONS FOR USE,. PRECAUTIONARY STATEMENTS, AND BY WEARING THE PERSONAL PROTECTIVE eQUIPMENT SPECIFIED IN THIS LABELING. THIS FUMIGANT HAS THE CAPACITY TO CAUSE MARKED IRRITATION TO TliE UPPER RESPIRATORY TRACT. A STRONG LA~HRYMATOR (TEAR.PROOUCING EYE IRRITANT). lOW CONCENTRATIONS ARE CAP. ABLE OF CAUSING PAINFUL EYE IRRIT ATlOW,. THE EFFECT MAY BE SO POWERFUL THAT A PERSON MA¥BECOMETEMPORARllYBUNDED AND PANIC-STruCKEN. THAT. IN. TURN. MAY LEAD TO ACCIDENTS ..

AIR CONCJ:;NTRATION LEVEL Tho acceplable 8r coocentraUon ~ve1 rot' persons expo56d 10 chloropicrh Is 0.1 ppm (0.7 mglM3). The air coneenlr3Uon level b meZl~ured by a dil'ocl r6ading detection device. such as 8 Malhlllson·Kilbgawa. Draeger. or Sensidyne.

PERSONAL PROTECTIVE EQUIPMENT (PPE) Chemic81·R~b.lant Malerials: Some mal&ria~ thai are chemlc~l'fIsisl.ant to this product are listed below. Ir)'ou wanl mOlll options. rollow the lluttudions for category H on an EPA chemical resistance C8t&gOry se!0cllon chart. PPE construct&d 01 SararteX, neoprene, and chlorinahxi 'polyetbyleno provide short·term contact or splash proteclion againsl\ktuid of !his product. Longer·loon protection ~ provid&d by PPE consltUc!&d-or Vilon. Teflon, and EVAL barrier lam~ale$ (for oXlImj)le. Responder suUs manufaclured by lif8-9uard or SJv~~hleld gloves manufac[ur&d by North). Loalh&r. canvDS. or collon materials offer no protection from this producl and must not bo worn when contact with !his prcduct is pos.sibh.

(1) HnndJers Perl'orming Dirod-Contad Tasks: Dllecl-conlacl !.asks ata tasks per. fonned outdoors or In ZI wetl.ven!ilated lIrea. They i"lclude:

equ~ment calibratlon or adjus.lmenl • &qu~menl cleanup and repair • ptoouct 5arnpling" • app5c:alicn Of ~oil.$ealing oub-Ida an enclostxf cab • anyaclivit), Jos.5 than 6, fool from an uMhleldlKl pr6ssurizod hon contalnlnlJ Ihls

p<Od""-• removal oflarp or plastic film

rinsalo dbposal fumigant lraMfer

• cleanup of small spins preparing contalne~ for a&rll!ion

• any other handling Ia~k nol othorwise Ibttxf h (2). (3), or (4) b6Iow App1ica[ors and other handlenl performlng diroct-con!.act tB.sb mu$.! wear.

• CoveraHs over ahort·!J\&oved shn and short panls, • Chem~l-te$.istant gloves. weh as barri&r lamlnale or v~, • Chernicakes.blanl rootwear pm 5OCk., • ChemlcaJ.resistant haadJ;&8r for ovothoad exposur., • ChemicaJ.re:s.islant apron. - Fu1l-face Respirator Wl1h elhar an organie.vapor-removlng cartrid~o with a" prefilter

approved fot' peslic:ldn (MSHAINIOSH approval number prefIX TC-23C). or • canister approvod for pe-s.tiddes (MSHAlNtoSH approval number prerIX Te. 14G). S&o further respirator requirements in 1M ~et Safely Requirements- section of tho

"""L (2) Handlers In Enclosed Cabs: App!iclliors and other handl&r$ In encmed cabs must wear:

• Coveralls. - Shoes and socks, • Plus, if' odor or irritaHon from Ihls producl can be detected imide th& endo&ed cab

or if aha air concentration lever of chloropicrin exceeds 0.1 ppm Inside Iho enclosed c:ab. handors In the cab must wear a full·face respirator wlh either an organicvapor.removing cartridge w.lh a prer~ar approv&cl for pe-s.1icidM (MSHNNIOSH approVal number prerlX TC-23C). or a c:anis.ler approved for p&alicid&$ (MSHN NIOSH approval number prefb: TC-14G). S&o further roapiralor requirements in the -USer Safely Roquiremonls· ~ecIlon of Ihe label

- tn addlion, lb& PPE 5pecl"1&d n (1) rordirect-conlad actNilles must be Immediate" DVaDabllt in the enclos.ad cab and must be worn lthe handler loaves. the enclo$ad cab to perform IIIny dirDcl-conlacl adivity. The enclose<! cab must m&61 the requirements \i$led In !bet Worker ProIeclion Standard (lNPS) for aRricultural peslicidC$-4DCFR 170.240Cd)(5).

(3) Handfers In Trealed Area WithIn n Hours .... ner .... ppricalion: On!'f Ihe foJowlng handler las.ks may be perl'ormocl in tho haled ZlreB within 72 hours liner the application is complete: • ksesmgfad"jUSln(J the sol seal • AuMS.tng pe-s.1 ccmtro~ application lechnlque. or appfK:Dllon effICaCY • Sampling air or Goil for this product AU olhor blsks Mit prohibiled until \he 72 .hour pariod tua .. oxpfr&d. Unles .. In an enclosed cab iDS dascribed in (2) above. handlenl p&rlonning lli6 above tasks In the trealed area witbln 72 hours aner applic:alion must wear:

• Covo.ralls. - CbemicakosJstllll! gbves.such as barrier lamlnale or vUan, • Chomical-rosislanl footwear end so.:b. - PJols.. if odor or Irritalion from Ihb prodtJcl canbodoleclodorlthoairCOflcenlmllon

kwal ofchIoropicrh exc&eds 0.1 ppm,. handlenJ mus.! wear a fuJl.race- ttrSpint.lor witb eithor an organic·vapor·romov!ng eariridge- with a prefiHor Dpprovod for p8511cidos (MSHAINIOSH approval numbelr prefllf. TC-23C). or a cani5tor approved for posUc::ld&s (MSHAINIOSH approval num!)er prefllf. TC-l<4G). See further rC5phior roquintmenls n tho "U$er Safely Requirements- section of !he label

S_ Requiremonts ConUnuod In ThIrd Column

1..2...

)

Tri-Form Pamphl~t Page 3

RequftGment.. ConUnuod:

(4) Handlers ~cd 10 High Concanlro.Uot1$: H8nd~ra o>:po$ed to high arooma concentrations or this product. such as c~8nup ro/Sowi.")Q IatQc spills, h-lank cleaning of bu'" hmks. and exposure 10 this. producl in poorlt 'IIonlilalod orcas, m~ wear.

~ Chemical-resblanl suI., ~ Chomical-rasistanl gloves. such as barrier [aminal" or vilon.

~ - Ch&mrcal-resislanl foofwaaf ptus. socks • .... - ChcmicaJ.reslstBnlhndgoar.

- Supp!iod.air ,&Sp~1or wilh MSHAINIOSH approval nwn~r prerO( TC-19C 01' Bt'lcontained broalhing appar.alus (SCBA) with MSHA/NlOSH opprov81 nuffibM' prefllC. TCo13F. See further rtsplralor roqulremonts in tho '"User Safety R&quiremen~'" section or !he Jabot.

USER SAFElY REQUIREMENTS ,. R8'$piraror Requiromenb;: 'Nben a respirator is tsqultltd for U$O wiIh thi$. product. the rollowrog c~eria musl be mal: (a). Full-race respirators musl be WOOl. (b). Carlridgos or canislor.; must be replaced oai)' or whon odor or kri!albn from lhis. product beeomes apparent. whichever Is sooner. ee). Respiralors must b& 11·le5(ed and fIIch(X:k(l'd using a program that confOll1l$ 10 OSHA's rctqlliremenls (described in 2S) CFR Part 1910.134). (d). Respfralor users musl be lrained usi-lg a program Ihat conforms 10 OSHA'. requirements (oM<:ribod iJ 29 CFR Pall 1910.134). (D). Respnlor U3ef'S must be examined by • qualil"l&d mDdical practitioner b ensure phya.icaI abiily to !lately wear the slylo of rttspiratOt 10 be worn. 2. Nover Fumigale alonG •• is ImporaliY'e 10 always havo an a:ssi$lant and prop&r prol!M:tNe equipment 1n case of 8ccidanls. • 3. Drivers RespomibiJillcs: OrNe/"S of 8pproeafIOn oquip>ment must advb& OthM workor$ of at precaulioM and procedures. In addition. dmel'S must mliuet Uwr.1r h&~rs in !he mechanical operation olllle lraclor and how 10 safalf WQI'i with lIl. lra<:lor arld dmerwhilD furn1ga&!g. .... Dispose 01 eontolmTnalod Clot bIng: Discard c:lothlng and otoor abs~nl matMiaIs that havo boon dt&f)(:ned C( heavil)' con{aminaled wiJ.h liquid oIlhl5 product. 00 not t'CIU301hem. S. Clean and Maintain PPE: Folow" manufacturer's inslrucJions for cl&anino/maitllaitr inll ppe, If no such instruc(jons for wash8bles. use dolergenl and hcl waler. KH:? arxJ wash PPE separalely from other laundry. Wash PPE aner each day's VSo'. 6. Contacl With Mouth: Never siphon !hi!. producl by mou!h 0( use moulh 10 blow 001 clogged InDS, nozzles, eTc, 7. Heat lItnMc Avoidance: Use measures To avoid Of" mnimi::.e heal liness whi'.o U&ing Ihis product. These measures i.,clude graduaT adjustment 10 heal aM re-spiraklr s.tress, fans for cooling, cooing vesls. (requent breaks 10 cool down, (requ&rIt i1Lakl!l of drinking water,.nd mainlaining weight (rom day 10 day.

USER SAFETY RECOMMENDATIONS Usors.l.hou\:i: • Wash hands berore eating, drinking, enewng gum, 1J~lng Iobaceo, or us_in--'lln~ Toilet. • Remove c!olhing Imroodialety if p&$l):;Id& gals Insklo. Than wash thoroughly and put

on clean. c\o.1hing. • Romavo PPE immlKfl3l~1'f aner handling this producL Wll$h the O1JIsJdo 0( gloves

before removing. As !loon as. pOS$ibJa., wash thoroughly 11M ch.ange 1010 cl&an ciolhng.

1 :Is.V~lOOO(Federal !:~o~~~~~~~. ~a~~u,~~!;nl ~1h b ~~rmg. 00 not apply 1hls produclln a wilylhal wi! conlact workers or olhar pe~ons, either drectly or Ihrough

'I drift. Only proIeeted handlers may be in tho- aroa dur1ng apprlCalion. For any requirements spoOr..: I byourStato orTribG. consul1he allency IBsponslbla ror peslk:ide rogulalion.

ENGINI;:ERING CONTROLS REQUIREMENTS • MECHANICAL lnANSFER SYSTEM; Personal proteclivlt oqutpmenl :!I~irl&d for "Dirod. Conlad AcliviUes." must be worn by !ho operator of the mecnanical transfer $YS1om. The operalor or !he mechanicallranster system must have available 10 him Iho manuraclurer'$ writen nslruclklns ror operation 0( Ih. syslsm and must read and tJnCJ6rstand (or haV& oxpJ.aJn~ 10 him In. detail) the proper operation and maintenance o( lhe"sysJem. wlrn ;ut. BULK AND MINI·BUlK CONTAINERS: 1,3-c:flChmopropena and 1.3-dicbbroproponoo ml.xlKf with chloiopicrin mu::>t be transferred lhrough connecting hos ... ~. and/or coupnn.Qs sufflCKlnlJy' light 10 prevent handJers « other persons from coming in conlact wnh J;qukl1,3-dichklrop~o. andlor chloropicrin. 1,. ).I hoses. pIping, and tanks used In conn&e:lk>n wiJ.h 1,3-dichloropropaoo andlor dlJoropkdn "hal be appropriate for uso under lb. pr&s$ure and vacuum c:ondilJons to be oncountered. 2. ElJemal sight gauges shal be &QuPPed with valves &0 thai pipes [0 sight gauge can be .bulol ~ cas·o 01 breakage and Joakag~, 3. 'The mechanlcallNlIlsfer syslem must )Je adOQ,uala 10 make n&Cesstlry measuremenb oflho pesticide being used. ... Shut~ devices must be installod on Ihe exit end or al hoses and al al disconnect ~ 10 prevent leakage of 1.3-<1ichloropropene amilor chbropicrin product woolliha I'tal'l$(er is stoppttd and hose Is removed or disconnected, A dry coupler !hal wil rnin¥nlzo ~tic:lde leakage must be inslal\&d al tho disconnect point S. Tho pressure in hoses used to mov~ 1.UlChlorop~a andlor chbropicrin beyond. pump musl not exceed Iha manufacturer's maximum pressure specif'lCalbn.

AGRICULTURAL USE REQUIREMENTS Uso: Ihis product only' In aceordanc:e ..... ith il:s 13baling and with the \o.,'orker Proleclion Standard. 40 CFR 170. TIli$ Standard contains requiremenlr. for tho proteclion of agriculurat workers on farms, forests, !lursenes. and (lreenhouses, and handJers 01 agncul!ural pesticides. It contains requirememls for Iraining, decontamlnalion, nQlir.ealion, and emergency assistance. tt also conlau,s. specifIC. inslruclions and excepTions petla.mg 10 the statemen!S in this laberog about ~onal prole-c:live e,quJ;>ment. reslfi::led..enTry inTelVab, and notirlCalbn to workers. The requiremenls in this box only apply to u::>es 01 this product IIl!"t are ~over09 by the Workor ProTection Slandard CNPS). ENTRY RESTR1CTXlN: Entry (including early entry thai woukf othOMiso bo pennittlXl under 1tJ& WPS) by any person-olher Ihan a correctly Irained and equipped handler wl'lo i:f, pelforming a handling task permillod on this labeing-is PROHIBITED from IhG' start or appIica5on. untl 72 hours aner ~pprlC8llon. In addition. If larps are used for Ihe ZIIppblion, non·handll;tr entry is prohlbled while Iarps are being rBmoved. NOTIFICATION: NolifJ workers of !ho applic"lion by wammg: Ih&m orally and by posling fumigant wam~ signs al entrances 10 h..,alec:1 areas. Tha signs must boar Ih$ sku' and crossbones symbol and stalo: (1) '"QANGERlPElIGRO," (2) ·koa under (unUga600. DO NOT ENTERINO ENTRE." (3) Ina dale and timo 01 fumigallon. EMERGENcY: In caS& 01 an emergency endangering heaUh or tha environment

invollli'lg: lhi:s product, callhe 24 Hour EmergDncy Phone Number (800) 424·g300.

'---------------;------' j (4) 1-3.Dichforopropeno lind Chloropicrin fumiganls in use, and (5) name:, addross. atld l&lepbono number of tha appfocslor. Posl!h& rum~ant w;JIm;,g sign irls!ead of Iha WPS sign fOl' this apprlCalion. but to1lo'H a' WPS requiremenTs perlainlnll to location. legibiily,

STORAGE, SHIPMENT AND DISPOSAL SHIPPJNG, sTORAGE: Agrkulural Chemical. 00 no{ !l.hip or $olen with food, f~, drugs orciolhiog.

STORAGE: store irlllghtly-.cJosed original CQnlai1ar In a cool place away (rom dwelings. 00 not alow contamination of aoeds. plants. (erti5%ers, or oth6r pMUcM chomlc.als. 00 po( eont.amrnat. food, reed $luffs. drtlgs. or dorrutsti: waler $uppJin.

DISPOSAl.: P61iclde wastM are lode. Impropar clis.posar of exce:ss PH6c:1de and msa!" Is a vooti:m or Federal law. tr !hase wastes c;annol be Cl$posod 0( by US$' accotd"1fJg 10 label IN.1ruclioM,, contact your slale pesl.k:1do or envirOflrnenlal control "gency: or the hazardous wasle reprosenlalNe 8t the n~arllt$t EPA regional otrlCe (or guida~o. Because l,J..dlchloropropeno Is c:orrosNe under cerlain conditions, rlush all IlIppf.calion equPment wah ruel 011, kerosane or a similar Iype or pelro1&um solvent Immed"l3lefy afler uso. Fil pumps and melel'S Wllb now molor oil or a 50% moTor oJlfuef 01 mixture before storing. 00 not 11$8 waleI'. Dispose of rinsale by awkable Federal. $1;"le and local regulalions. Nover Inlroduce rinsate or unused produetirlto surface or underground walM" suppies.

METAL CONTAINER DISPOSAL: To Ol$po$o of contajner emplilld doring .IIpp~tion oporation. remove bungs, invert. container in thD (1fJ1d j.:sllt6811td And ensuro !hal tho conlainer is freo or liquid. Orient conlaIner such Ihal venlUatiofi of bung holes b Ml reslricted. Ntaw conlai1ers 10 aerat& for al iIIasl 14 days. Replace bungs prior 10 transport. After aeraDon. offer conlai1or 10 qualified t&COnd1k>ner or cI~po&-e 01 as dlreclod by Stale or 5oc.aI regulations.

REFlUABLE CONTAINERS: Conlact the comp1Iny andfor tho c:ompany, reprosentalillo rord"~1ions. on cleaning and bandling reliDable conta'oets.

BULK OR MlNlOULK PRODUCT TRANSFERS: Dry break or dry disconnect eoupJlngs lIl'O required for aI produ¢l transfers klvolving buk contaheors ror prodvet5 c:ontaini1g 1,.34ddol'Opropeno as of Seplember 30. 1Q93.

ENVIRONMENTAL HAZARDS Do not oori;Jnunale water by cleanhg or equipmenl or disp00af oCwutes. See -slorage-, Shipment and Oisposar uction. III ease of 5pilb, properly di:sposs of con~minated malaMB-.

Ground W~lilr Advlsory: 1,J..d"lChbropropeno Is known 10> movo through .. oil and und&r certain condiioM hu tho po&onfl8l to reach ground waler.llS a ro .. ul of agrlcultt.ltal UB-e. Applkatiorl in .feallo wilDIe. soifs are pormoablo .and ground water .. nNl' tho 5ur!ao&, or in ka~lgeology. could r-ult In Slroundwaler conlaminatoo. '

PHYSICAL OR CHEMICAL HAZARDS FlAMMoI.Bl.E:. Do notuse, pour. spit. or sloro near boat (X' open r.amn. Do POl cut or weld cotIlainer.

·1 I _tze.. and timing of posl.ing ~nd rel)1oval. -, PPE FOR ENTRY DU-RING THE ENTRY-RESTRICTED PERIOD: PPE ror enTry

t: that is perrnUed by Ihis labeling is bled in the "Hazards 10 Humans and Domeslio: , t L-~~_·~.~·_.~ec~'~_n_d __ 'h_'_~_be __ '~n.~~ ______________________________________ ~ I ' I , i I

I

i f ,

~I--~------~-W-A~R~RAN~-TY~D~I-S-C-~~~~~~R--------~NOTICE: SeJler warranls that Ihls product conforms to L~e chembl descrption on The labet and is reasonably fi. for the purposes slatltd on Ihe Iahfll when used in accordance with directions. WKIer nonnaI condillons of Us(t. btll neilher !his warranty nor arry olher warnanty or MERCHANTABILITY or FITNESS fOR A PARTICUlAR PURPOSE. tlxpress 0( Implied, exlends to Iho use d!his produc:l contrary to labo! Inslructions, or under abnormal conditions, or undDr condlions not reasonllly fore:seeable 10 seJer, and huyer assum(t$ the risk of any such US&. INHERENT RISKS OF USE: 1 is impossible- to eliminate al i'$ks assoclaled with us& ollbis pn:ducL Crop hjm)" lack of porlormance. or oIher uninfended consequences may result because or such faclors as USD of 100 producl contrary 10 label and label booklet inslrocrlOns f.ncksding ccncWons noted on the label arx:llabel booklet, such as. unravo..,b~ temperatures, soil CIOI1dU:Ins. eCe..). abnormal conditions (such H excess;""e rainfalf. drougnl. tomadoes, ~). pttIsence or olher materiah. Ihe manner of apl'roca1ion. all of which life boyond Iho conJroIoi IhII company or !hili seller. Mauch rish shall be assumed by Buyor.

- I

UMITAnON OF REMEDIES: The exclusive remedy (or Jo:s:ses or dafMgC'5 resultlllg front Ihh protftK:t (hcluding claims based on conltacl, negligEmce, strict tiabiliy. or other legal 1beories). shal be liml&d to, at Ihe company's erecHon, one of the- rollowing: (1) Refund of purchase prictt paid by buyOf or user for product bough!: or, (2) ReplacemenT of llmount of product used. The aKDpany shall nol be liabkt for losses or damage5- resulting from handf~g or use or this producl un1esa: th& company is promptly notified of such Joss or damage n wrillr\g. In no caso shall rho company be liable for consequentlaJ or incidental damages or losses. Tho f&rms of 1h& W8rran!y Disdaimer .above and this Limitation of Romediet. cannot be valled by any wriUe-n or vItIbaI ~ or 1I9reement.. No empSoyee or aales agenl of the company or tho $oTler is aulhori:ed lovary or exceed tn& lerms of InD Warranty Disclaimer or Inl5 limitation 0( RemoO>MI In --. CA April. 1994

)

TRI-FORM 40/60 Pamphlet Page 4

GENERAL INFORMATION

This product is a mulli-purpose liquid fumigant for preplanl treatment of socl to control nematodes. symphylans, wireworms and ccrtain soil bome diseases in ' cropland. '

Before fumigation, soiT sampling for the type and number of pests present Is recommended. In fields where pre-treatment SOIl samples indicatd tho, presence or high population levels 01 nematodes, a successful fumigaUon cannol be expected to BlCIdicate entire poputations. Therefore, post·lrealmerit sampling is recommended to determine lhe need for additional pest management practices. •

Consult State Agriculluraf Experiment Station or Extension Sel'V;ca speciaTisls fot Information on other practices such as post-harvest deslruction of crop residues. weed oontror or other cultural practices. and USB of nematode resistant crop varieties l~t may aid In reducing crop losses from SOIl 00r00 pests.

GENERAL USE PRECAUTIONS

Soil fumigation using this product should be conducted only according to direction:; and conditions of use described in this labeling.

FORMULATOR USE OF 1.3-D1CHlOROPROPENE: labeling for end use products containing l.3-d"lChloropropene that are prepared and sold by formulators must comply with all precautionary statements, use precautions, environmental hazards. handling and proteclive equipment requIrements. maximum application rat~ and other exposure mitigalion measures specified in this product labeling.

RECONTAMINATION PREVENTION:· This product will control pests that are present In the soil treabnent zone at time of fumigation. It WIll not control pests that ara introduced Into soil 'aner fumigation. To avoid reinrcslation of treatlXi SOIl do rot use Irrigation waler, transplants. seed pieces, 01' equipment that could carry soil bome pests from infested land. Avoid contamination from moving infeslcx:l soil onto treated beds throU9h cultivation, movement of soll from below the treated zone. dumping contaminated tare soil in treated fields and soil contamina6on from equipment or crop remains. Clean equipment careluUy before entering treated fields.

BULK TRANSFERS: Dry break or dry disconnect couplings are required for atl producl transfers involving bulk containers for 1,3-d"tehloropropene as of September 30, 1993.

Do not use conlainer.s. pumps or olher l.r.ln:!.fer equipment made of aluminum, magnesium or their alloys. as under certain conditions 1,3-dichloropropene may be severely COfTOS.lve 10 such metal.s.

EQUIPMENT CLEAN-UP: Because 1,3-dichloropropene: Is COlTOsiva under certain conditions, flush all application equipment with fuel oil, kerosene or a similar type or pelroleum solvent immediately after use. Fil! pumps end meters with new motor 0;1 0( a 50% motor oiVruel oil mixture before storing. 00 not usc water. Dispose or rinsale by incOlfX'ration into field just lrealed or by other approved means. Never introduce rinsate or unused product into surface or underground water suppITes.

CHEMIGATlON: Do not apply 1.3-dichloropropene through any type ofinigation system.

FERTILITY INTERACTIONS: Fumigation may temporarily raise the level of ammonIa nitrogen and soluble salts in the SOIl. This 15 mast Jilcely to occur when heavy rates of fertilizer and fumigant are applied Ie soils thai are either cold, wet, acid, or high In organic matter. To avoid injury to certain crops including red bools, carrol$, com, radishes. cola crops, legumes (beans), lettuce. onions, and sugar beets, fertiUze as Indicated by soil tests made after fumigation.

To avoid ammonia irljury or nitrate starvation {or both) to crops grown on hIgh organic soils. do not use fertilizers containing ammonium salts. Use only fertilizers containing nnrates until alter the crop Is weD established and the soil lempe~lure is above 65 degrees F.

In mineraI soils, do not apply mora than 213 of the nitrogen requirements from fertilizers containing ammonium sal1$ until the crop ts well estahnshed end the soli temperature Is above 65 degreE.s F.

When using high rates of the product as required by certain slale nursery regulations, liming of highly acid s0l1s before fumigation may stimulate nitrification and reduce the possibility of ammonia toxicity. Certain nursery crops such as cilrus seedlings. Comus sp.. Cratsegus sp., spruce. and vegetable crops such as caulifiower have shov.n evidence of phosphorus deficiency rollowing fumIgation. To avoid this possible effect, It Is suggested thai additional phosphate ferbTlZer (foliar appflC-d) is recommended where experience indicates a derlCiency may occur_

10 /,2..

APPLICATION DIRECTIONS APPUCATION TIMING: ThIs. product can be applied at any tima of th6 year when soil conditions permit Conditions that allow rapid diffusloll of the fumigant as a gas through the soil noona!y give best results. Because this product does not provide resldoal control of soil pests, II should be used as a preplant appflCalion before p!anting each crop. The following soiltempernture -and moisture conditions 'Should exist at time of treatment. Failure to meet these conditions may ~esult in unsatisfactory product per!onnance:

SOIL CONDlnONS: Soil !empera!!!rR at the depth of apprlCalion must be between 40 degrees F and 80 degrees F. In areas where the soil temperature in the sprirlg may not reach 40 degrees Fin. time 10 anew application of this product prior to planting, late summer or early fan treatment Is recommended. Soil mojsblrn throughout the destre-d treatment zone should be: at 01'" near the permanent v.ilting point to allow optimum dispersion of the fumIgant, which moves as a gas through the soil air spaces. The permanent WIlting point varies with SOIl lexlure and organTc matter collient. Coarser texlured soDs can be fumigaled under conditions of higher soil mol.slure than finer textured soils: however, it the SOIl mol.slure Is \00 high, fumigant movement will be retarded and effectiveness or the lrealment will be reduced. Previous and/or local experience with !he :soi to be treated or the crop to be planted can often servs as a guJde to conditions that will be acceptable. If you do not know how to detel1nk"le the sol moistUre content of lhe area 10 be treated. consult YOlJ( local extension sesvice. or soil conservation service specialist or pest conlrol advisor {ag consultant) for assistance.

In general, no irrigation should immediately pl""eceda subsoiling or fumIgation: however, when surface SOIl moisture conditions are not likely to provide an adequate seal against fumigant loss, a very light sprinkler irrigatiOn-to wet the top 1 to 21l1Ches of soil may be useful.·

SOil PREPARATION: The SOI1 should be free of dods.· Large clods can prevent effective son sealing and reduce errectiveness of U,is product Plant residues should be thoroughly Incorporated Into the soil prior 10 Ireatmenl to . avoid inlerfering with application. Undecomposed plant material may harbor Pests that wiD not be controlled by fumIgation. Liltle or no crop residue should be present on the ~1 ~urface. Crop residue thaI is present should lie fiat to pennit the soil 10 be sealed errectively. Compacted sot! layers within the desired treatment zone should be fraclurcd before Or during application of ths -fumigant OCViatioll f~om the above conditions may result in unsatisfactory results.

PLA.CEMENT OF FUMIGANT: This product may be applied as either a broadcast (overa!!) or row treatment. II must be placed at least 10 inches below the final ~1 sLrlace. When s0!1 conditions anow. placement a minimum of 12 nclles betcw the final s0!1 surface is recommended. Deeper placement is recommended when fumIgating soil to be planted 10 deep-rooted plants. such as perennial rruit and nut crops, or to control deeply dis-tribuled pests.

APPLICATION METHODS AND EQUIPMENT BROADcAST APPLICATION: Use chisel (shank). Noble (sweep) pION orplow·sole application equipment. For best results when using chIsel equipment, use ripper-type. fO/Ward-swept shanks. Noble plow equipment is par1icuIarly userut for faU fumigation when the soil still contains some standing undecomposed plant material. Subsomng may bel necessary before application 8S described under -Soil Preparalion·~ Choose applkaUon equipment which allows the deepest aPP.ftCalion and best soil seal under existIng conditions.

The fumigant outlet spacing vanes with the type of appflC:ation equipment used. Wi!h chjsel flmiprnent a fumigant shank spacing of 12 to 24 inches is recommended. The outlet spacing for this equipment may be up to 1 112 times the appfation depth bul generally should be equal 10 the application depth and should not exceed the soil-shatlering capabilily of the chisels. The maximum ouIIel spacing should not exceed 24 inches. Wj!b plow'3n!e Nl!!ipmenl a 12·inch outlel spacIng is recommended. Do not exceed an outlel spadng of 18 inches. Wjth Noble ':sweeP) plow eq!!ipmen! use all out1~t spacing or 9-12 Inches along the- sweeps.

Broadcast apprlCaUon can be made in Ihe same direction or at an angllJ to the dirccron of row planting.. •

ROW APPttCATION: Use- chisel equlpmenl to treat a band or soil whem the crop Is to be planted, I.e. the plallt row. One or two chise!s per plant roN Is recommended. In general. when one chisel Is used, apply product at tha now rales given. When two chisels per plant raw are used, space tho chisels (fumigant oulIets) 8 to 12 inches apart and divide the flow rates equally betweell the two outlets. Regardless of the number of chisels used, !he: amount of fumigant applied per 1000 feet of plant row should remain the same. With certain deeper rooloo crops such as potaloes and sugar beels, higher f\O"N rales may be necessary to ensure adDqUate treatment of the zone of soil where primary root growth occurs: however, in no case should tho amount of fumrgant appUod per acre- excoed tho gallons pot acre- rollos. for broadcast treatment

)

TRI-FORM 40/60 Pamphlet Page 5

APPLICATION METHODS AND EQUIPMEN:r (Con6nuod):

To prevent seed gcrminalion problems cauSed by Improper seed-lo-soU contact or Improper seeding depth, 40 not place !he seed directly ever the furrow left by the applicator chisel(s). 'YVhen one chisel is u5tld per ptant row, place the seQCi about 4 inches 10 one side of !he chisel furrow. \Nhen two chisels are usod per planl row, plant the seed offset from the chisel trace.

SEALING THE SOIL AFTER APPUCATIOH: lmmedialely after chisel application oIlIle product, the soij should be ·sealed"" Ie prevent fumiganlloss and ensure Ulat an effeclNe concentration of rumigant is maintained wiUlin the soli for a perlod of several days.

for BroadCas.1 Trealmeo! fOa! f"m1ga!ionl. sealtng can be accomplishe<fwith equipment lhat will .uniformly mix the soil to a depth of 3 to 4 inches to efrecwely eliminate chisel 01"" plow !races which can allow dIrect e.s.cape of the fumigant A tandem disc or slmaar equipment may be used for this purpose. To maxim1z.e .sealing, steps should also be laken 10 compacllhe soil surface to further retard the rate of fumigant foss by fallowing with a ring roner, cultipackcr or roner in combination with tillage equipment Compaction or the sail $urface alone may give the appearance of adequate sealing without effectively disrupling chisel or plow !.races.

For Row Trea1ment forming the beds at the time of application :s.hould be accomplished in a manner thai places the fumigant alleasl12 inches from the nearest son'air inler\'ace. TIle closest soVair interface could be the furrow for multiple knife appflCalions or L'"Ie top of the bed for- single knife applications.. Row treatments into preformed beds should be sealed by disrupting the chisel trace using press sealers, ring rollers or by reforming !he beds and foUewing with such equipment - -

Sealing can also be improved by applying non-perforated plastic lilm. suc.h as polyethylene. over the entire area or in strips. Use of a film to seal the soil surface docs not eliminate the need 10 eliminate chisel traces prior 10 application af the plastic film unit::!:ss simultaneous appficalian and tarp layjng by the same pIece of equipment occurs and !he tarp is a minimum of 1 mil thick.

Proper soil conditions at the time of appRcation (see Soil Preparation section) are Important to ensure proper placement of rumigant (see Placement of Fumigant section) and to obtain adequate sealing. Prior tillage ~1Jld be a~le to e6minate clods and thoroughly mIx crop residues inlo the 50011.

SOIL FUMIGATION INTERVAL: leave the sQllundislurbed an? unplanled for at least 7 days aOer application 01 the fumigant A longer undis:urbed interval Is required if the soil becomes cold or wet,. and for de.eIHOOted tree. shrub and vine plantlrl9 sites.

After tI10 rumigaoon interval. to prevent phytotoxicity, anew the fumigant to dissipate completely before planting the crop. Under optimum so! conditions for dissipation. 1 week fpr each 10 gallons/acre is recommended. For Fruil nut and nursery crops at least three months should elapse between treatmcnt and planting. To hasten dissipalion.. espcciaDy if heavy rains or !ow temperatures cccur during the [realmcnt period. till the sci! 10 the depth of fumigant application. Use a knife-ike chisel without turning the soil 10 reduce the possibl1ily of recontaminaling \he trealed soi. Oissipalion is usually complete when Ihe odor of the product is no lcoger evident at the application depth. Seed may be used as a bfoassay 10 determine if the product is present jn the 50011 at concentrations sufficient to cause plant injury. Do not planl if the odor of the product is present within the zona of fumigation.

') .I

}

TRI-FORM 40/60 Pamphlet Page APPROVED USES

6

TRI-FORM 40/60 is a preplant soil fumigant for control of soil-borne pests such as woreworms and nematodes, and diseases caused by certain species of Rhizoc/onia, Pythium, Fusarium, Phytophlhora. and VertkJllium. TRI-FORM 40/60 is to be used in soil to be planted to the crops listed below.

APPLICATION RATES' TRI-FORM 40/60

'l"ype of Crop '1'reatJqent Soli Type

Brussel. Sprouts OVer-all Mineral CUcumbers (Broadca.st) Muck or peat Eggplant Floral Crops Melons Nursery Cropa

Onions Over-all (Broadcast)

Plant and Seed Beds Over-all Mineral Radishes (Broadcast) Muck or peat

Strawberries Over-all Hine"ral (Broadcast)

Sweet Potatoes Over-all (Broadcast)

TOlD.atoes over-all. Mineral. (Broadcast) Muck or peat

1 Usa tho higher rates in heavier soil.

'"Gallons Per Ac.re1

21 .. 9 to "36.3 58 .. 2 to; 81 .. 3

5~ .. D to 58.4-

29.1 to 36.3 58 .. 2 to 87" .. 3

58.2 to 81.3

51.0 to 58.4-

21 .. 9 to 36.3 58.2 to 87.3

~~T~!e highest rate on heavy soils ~uch as clay or ~uck and lowest rate on light saody ~olls.

2. Use highest rate for cy$t-fo~iog oeaatode. and Verticill!um wilt

3. ~~:t~~lbed applications =ay be made at the ~roadcast rates, but the amount used will be proportionately less per acre depending on the row spacing and width of treatment in the row or bed.

12 1.2....

WASHINGTON, D.C. 20460 /I

DEC 16 1994 TOM DUAFALA TRICAL, INC. P.O. BOX 1321 HOLLISTER, CA. 95024

OFFICE OF PREVENTKlN, PESTICIlES AID

TOXIC SUBSTANCES

Subject: Label Amendment Submission of 6; 20/94 in Response to PR l'~otice 93-1 EPA Reg. No, 11220-15 TRI-FORM 40/60

Dear Registrant:

The labeling cited above and submitted in connection with registration 'mder the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA), as amended, is accepted subject to the comments reflected on the enclosed sheet. A copy of your proposed labeling stamped "ACCEPTED WITH COMMENTS" is enclosed.

WHAT THIS ACCEPTANCE MEANS:

Based un your certification, the Agency has accepted the labeling changes that are necessary to comply with the Worker Protection Standard (WPS) labeling requIrements of 40 CFR part 156. subpart K. described in PR Noti:'es 93-1 and 93-11. Any other labeling changes submitted in connection with this amendment application but not direl:tly reiated to compliance with the WPS have not been reviewed or accepted by the Agency. [I' you wish to make such changes. you must submit a separate amendment application proposing them. [f your product is currently suspended. the acceptance of this labeling amendment does not affect the suspension in any way. .

WHAT YOU NEED TO DO NEXT:

By the ne't label printing make all the specified changes to your labeling. Send to EPA one (I) copy of the final printed labeling:

• BEFORE selling or distributing any product bearing the final printed labeling AND • WITHIN one year fro,n date of this acceptance.

" •

..

i

'.

..

Page 2

Submit the final printed labeling via the U.S. Postal Service to:

Document Processing Desk (FIN-LABEL) Office of Pesticide Programs (7505C) U.s. Environmental P-;otection Agency 401 M Street, SW Washington, D.C. 20460-0001

Hand or courier deliveries of final printed labeling may be .1lade to:

Attachment

Document Processing Desk (FIN-LABEL) Office of Pesticide Programs Room 266A, Crystal Mall 2 1921 Jefferson Davis Highway Arlington. VA 22202

o

Sincp.rely;

,...:rRlI1ki··ns, Deputy Chief str on Support Branch 'stration Division (7505W)

... '0 ,

• 1

.,

,"

. . ~

1

'1 "

'J

/ .

Tom Duafala Ph.D. Trical

Comments for: EPA REG. NO. 11220-15, 20,21 TFI-FORM 40/60, TRI-FORM 15, TRI-FORM 30

The following specific comments pertain to your WPS labeling submission concern in!! '"he product cited above:

-In section 1 under P~RSONAL PROTECTIVE EQUIPMENT delete "Application or soil-sealing outside .m enclosed cab" Add the Personal Protective Equipme~t section for "Applicators Outside an Enclosed Cab" on page 5 of. 11 of PR Notice 93-7 Supplement 4-E.

In section 1 nder PERSONhL PROTECTIV~ EQUIPMENT change "Applicators and other handle>:'s performing direct contact tasks must w~ar" to "Handlers performing direct contact tasks must wear:"

In section 1 under PERSONAL PROTECTl ".'E EQUIPMENT change "Any other handling tasks not otherwisp ::'isted in (2),(3), or (4) below" to "Any other handling tasks nClt otherwise listed in (2), (3) , (4) 0,: (5) below"

... Add the following to the end of th", PPE section for "Handlers '. Exposed to High Concentrations":

NOTE: In-tank cleaning of bulk t.·:lnks.· shi"ll be pf'!rformed by persons who have been specifically trained for this activity. refer to OHSA 29 CrR 1910.146 and the Telone ~~~~~~ide, ~ection on ;tocage tanks.

j\DD "~AL" after barrier laminate in the chemical-resistant statements.

." •

only

glove

Tri-Form 40/60 I.abel Column 1

RESTRICTED USE PESTICIDE For retail sala to and use onlY by Certifaed Aoplicalors or persons under their direcl supervis'on and only fw those uses covered by the Certified Applicator's certifK:alion.

TRI-FORM 40/60 A LIQUID SOIL FUMIGANT

FOR PREPLANT TREATMENT OF CROP L~NDS TO CONTRCL PLANT PARASITIC NEMATODES AND CERTAIN OTHER SOIL PESTS. NOT FOR USE IN GREENHOUSES OR OTHER ENCLOSED AREAS.

ACTIVE INGREDIENTS: l,3·Dichlolopropene Chloropicrin

INERT INGREDIENTS: TOTAl

37.6% 59.4%

3.0% 100.0%

ConLai,..4..51 poI&ndI ol1,l-OicNoropo.,neMCI 7.13pou11d1 oI~perg.1ion..


DANGER e PELIGRO

POISON Pcligro: SI Ustt:!d no IInlicndo la etiquela, busquo a alguicn para que 511 la explique a Usted cn ddtalle. (Ir:lOU do not ,,"nde~~nd the label, find $orneono to explain It to you In detail.

IN All CASES OF OVEREXPOSURE GET MEDICAL ATTENTION IMMEDIATELY.

TAKE PERSON TO A DOCTOR OR TO AN EMERGENCY TREATMENT FACILITY.

FIRST AID IF INHALED: Remove to fresh air. If not breathing, give artir .... ,:.: respiration, preferably mouth·to-rT'ICK.ilh. If breathing Is diffICult, give oxygen. Can a physician.

IF ON SKIN: Irrmediately fi!..sh skjn with plenty of water for at lea:!!t 15 minutes whDe removing contaminated clothing and $hoes. Call a phY$lc.ian. If water Is not kTvnediate!), a .... ailable. remove exceu chemical from skin with adsorbent material such as towel Of dry soi, then proceed at once to a locatioi'". where ~ter Is a .... ailable and thoroughly wash contaminated skin with plenty of water. Cau a physician.

IF IN EYES: Immediately flush eyes with plenty of water (0( at least 15 mInutes, Can a physk:1an.

IF SW,\UOWED: Do not Induce vcmiling. Can _ physlclan or POison Control Center inmedlalely. Never give anything by mouth to an "Jnconscious person,

NOTE TO PHYSICIAN: Because rapid absorption may occur through lungs I product Is aspirated and causes systemJe effects, the decision to hdute .... omiting or nol should be mad. by. physician. If lavage ls perfonned. endotrac ..... :· and/or esophageal control is :!ou9gested. Oanger (rom lung "~piraUon must be weighed against toxicity when cons\c.ering emptying the stomach.

s .. Side p.,. For AlISdilioftei Prec.lIliott.ary st.I.,..,.,".

TRJCAL P,O. Dox J~27. HolliotcX" CA OG02-1

E.PA. EST. 11220-CA·1.2.l,4.H.-l E.P.A. REG. NO. 11220 15

NET CONTENTS _ ............. IllS.

DEC t 6 1994 UIOd... 1M rod.rat ~1Wd .. r • ..JIdd., .... Roclenlieide Ad •• _endO<!, for Ihe peollcide rejIi ... .....t .....t ... EPA R9' No.

1/2- 'Z() -15

13


PRECAUTIONARY STATt:MENTS HAZARD TO HUMANS


HAZARDOUS LIQUID AND VAPOR • 00 NOT SWALLOW AHV "F nus rROOUCT. UAY DE FATAL w:

SWALLOWED. 00 NOT GET IN EYES. CAUSES SEVERE EYE ""'URY.

• DO NOT eET ON SIC..,. MAY BE FATAL F ABSOROED TlflOUCH nE SIC IN. CAUSES SKIN BURNS. MAY CAUSE AlLERGIC SK ... REACTION. DO NOT OREATHE VAPOR. MAY BE FATAl If NU.lEO. MAY CAuse LUNG. lIVER. AND KJONEY CAW-OE AND RESP,,"TORY SYSTEM IlRITATKlN UPON PROLONGED CONTACT.

• TlEUSEOfTHtSPROOUCTMAY DE HAlARDOUSTUYOLR HEALTH. THIS PRODUCT CONTAINS 1.l-OtCHLOROPROPENE. WHK::H HAS BEEN DETERUINED TO CAUSE TUMORS IN LABORATORY ANIMAlS. RISKS CAN BE RCOOCEDBY EXACTLY fOUowlNQ DJRECHONSFOR USE. PRECAUTIONARY STATEMENTS, AND BY WEARNG THE PERSONAL PROTECTIVe EQUIPMENT SPEClnED IH ntis lADELING.

• THIS fUMIGANT HAS THE CAPACITY TO CAUSE UARKEQ IRnrTATlON TO ntE UPPER RESPlRATORY TRACT. A STRONG LACHRntAJOR (TEAR-PRODUCING EYE IRRITANT), lOW CONCENTRATIONS ARE CAPA'3lE OFCAUSHG PAINFUL EYE IRRlrATION. THE EFFECT WAY BE SO POwEJtFUL THAT A PERSON MAY BECOME TE.,.VORARIlY BllNOCO AND PANK"~STRICKEN. THAT. IN TURN, ",,,y lEAO TO ACCIDENTS.

AIR CONCENTRATIO'J LEVEL The loe.plIO!. .r conelnll.lion t.val fot ~tI_ •• r ~ec1 10 ehlonJpicm ,. 0.' PP"l (0.7 rrogIMl). TNt lir eonell'lll1llion llvel • ""' ...... tod by • ".eeI ,Nd.-.g d.leclior! ~ ... ic:., ,ue!'! n I U.h,on·KiI'g''''I, er..g." or S.",id)'I'I4I.

PERSONAL PROTECTIVE EQUIPMENT (PPE) Cheffllal.Rftislani Mal.rlal,,; Some !'NI.,;,,, tNII .r. eMmil:::aI·' .... 1Jo1'II 10 lhill product .r. ble<! bt'tow •• )'OU ...... ,.. fJ\O<. o~". fo....., the ro,lrudion. for caleQOI"f H 011 '" EPA ct..mie&lln~l.fK,Ie (l1~ory uleo(lion cl\atl. PPE ODnIlrucltod 01 s..ral'lell:. r>eOtH_, Ind chkoM.laod po~.lh)'iIo'" provide ,hoII·I""" COIItact or .pII.h proIKlion .g.irl.1 SQuid of Ih~ produc:l. I.~,., ...... prolKliQfI. provid.d by we con,lrucled 01 V~OI\" Tenon, .nd €VAl bIIrrW "m .... I .. (IOf ••• ",pW. R .. ~ ''-1'' """uf.cl,,,<Id by lh1l1J11'd l:It S ........ "*" ;Iew .. ~"ufl_l...-c1' by NOrttI). l ... lhItf. c .......... Of ~HOII rnfl.' .... elf. no proteclion 1101n Ih. ptOCNcl ..wi INti 1101 k worn ....... COfttacl ..... __ PfOdud II pontillo.

(1) ~ Plrfoflll"'a Oit-cl-Coral.d lath.: o.ed<onlad ........ le"h pM'kwf'PIICI OI.IIdooft Of ill ........... nliLIled ..... n •• )' hdud.: ~uPmeM nJi!:ln,~ Of .diu"",,'" I>QUpn..M ci .. ""p and 'ep.lr proOt..ct .. mpling Ippblioll Of loi·".ktg outsid, .,. .nclMiod c.b Iny acl;"1')' .... lhaft e , .. , "Of') .n "n.hiald~ ptluurbiod hot. COfIIe~ 11'1 • ........ temo....1 cI!.atp Of plaslic: rom mu,l. dis.posll lo.mig.,.,I\I.,."ler ,"'I..up'" .", •• ,pits prapari-.g COft .. ..,.,. 'Of' .. raliol! _,.,. othM hand~ lIo,t rooI o!h ........ hied ~ rn. PI. Of (4) ~

~Ion Itftd oil\« hll'IdIIl't perlomoing CI.acl<onllC\lIo.l. "'u.I_I'-; _ c-,.. .. ov.r .hot! ........ <Id ,1Iir1 .t>d ,hott pa"''' _ ChIInIic.I-'".' ..... glew" •• t.;h •• bot".;., 1ItM-ia1'lJ# vIorI., - Chemic.,." ... ,.. 'ootwall ptJI.oc ... _ CNnWc.h .... lInt M.dge., 'Of' ov.mlld ".posur.. - Cha",ic:.,.,itlJo"I.p'on, . h,l-facl R"pOr'lof ...... 11 1."-"" o,,,I,.,ic·va;>Of· _irIg ur'lridg. wilh. pt" ••

'pPfo .. ,.,d 101 ~Iicid,. tMSH.t.INIOSH I'p;>rov.1 nurnbJot pt9r .. JC-2lC). ot • uNsI .. 'PPT1We<! lor p40,!icidft. (MS~IOSH lWOVIl flU"'. pt.r .. JC-14C). S .. lurlt..r ,e'p"I!ot 'I':!u""mertl. n ~ v.., 5.1.t)' Requif""",nl." '1C1ioro cI u-.. Iobol

(7) H.anctt.rw I., (nc:Jo.ed' Cabot: A9P'c,lon.otd oIhet ",.t\dlltl WI encbt<ld c.Dt; "''',. _or.

CO\I'II ....

S*", .nd loch, PIut.1 (,.Jot Of .oi.lior! I,omlhis ptoducl (In be d.lacll<l ~Ide the Incbsed ub Of 11"- .reO"'Cln:ra'ioIt IIvll dchiotopic,jn uueod' 0.' pPrI'I WlI~ Iha MCJot,~ cab. hal"'de,. in !he clb ",,,,I _at ...... ,~ 'Hp60.k.f will • .,.,., ." org.nic-.... por-r_r.o ~Iri~ .. ~'" I pt ...... I~ad lOf pe,l!cidft (MSKA.lNIOSH .~v .. ~ JIIN fC·2JC), Of .. (.llnil" .pproyld bpnGcIM. (MstW NIOSH IpPIOY"ftUfI\bet pt .... TC-T4C). s... fv,t .... ,"phlot ' ............. ~ 1M '\Ja. s.t., R.c;ur'",lnI." .. ",tIM 0I1hI libel ". ~IOII."'" pP£ 'pIC,"oed n (t) lot ~KI-eonlld ectW.-. _I be n-...'"" .... IiabWl h !he enclosed e,::-.nd _I be.....,,!he hIoIdlolr ....... "'" enclosed cab· 10 perform .n)' c:J'ICI-<:ontacl IClivilf. TNt IftCb .. d c.b tr\WI ~ .... ~""'f'II. iliad WI Itll Wc .... et ProI,ctiol! SIIMird (INPS) for "9riC"'''''' paslOcllt"",O CfR 170 240(dl(5).

p) H',",lrw III T,..'14 oAr .. Wllh'" 72 H_ Aftl' AppJ\clotlo<>: Only .... ~ hI.-.diw lfI,kI "'II)' be perfortntld " !hi "M!<Id If" "'""~ 12 '"-t "fl. lhe appkl!io-t

• c:ompIaI.: • A".lIing,.c"pSlrog , ..... 00'MI • .I..s,~.ro9 PI~I COf'lIoi. IWr"'ILoriltoCl1";"u •• e<t ';';0"=11;';"" .l'I'oe'cy I Simp""" u 00 ,~Iot II ... ",od\.OC1 All olhe, t.,.,.., .,. p'ol1ib,l.d vnhllto.12 ·hour period h., .~pl.....t. U"leon n I., Inclo,fod t:lIob" (!"1.('~ ... p) Ib(rvt. h.ndlt~ ptoriOf"'ir>g tf'o •• toO .. 1 I"" 1fI1!"I, IIIJ .. lef! ......... h" 1"} ~ Ir.., .~Io:;IT>oro "'u,1 .... r

• COIIal.lII. CI ..... O;c~1 '15Jo,Ilnl gbve1.Iu<h as b,oo"~r II· ''''1'' {"O' .. 101"1, C~"dc,.: '"!!.!an\lool..,,, .. , I~o'!' ,(>(1,. PIu'.' ~ Of _ ..... ·oon ,.(>m Ih" fl'oo:!ud rl .. to. .... I.<:!.,(!or. ""- Ir ("( .. nunl'll<:>'" ~v.ld (hiot?ptc:.n •• cf'fo(!, O.t ~...,. h .... ,.;,.'1 ,....;,\ _""v".e. tU:>irI!I")j'_1-o ..... , .n Otg ... IC·""';:>Qf ' ..... 0""'9 ('''''~.I ..,~h I ",.r .. ., .~ptcwld 1;)1 ~llo(".c:f'. ("'~H""J!Q~H .ppo"" .. I'um!,.t P'~" lC :1lC). or • C.n .. l.,. 'PP"Ovlod I.,.. .... ~icodft (MSHA/mO<;H .,-.pt"o ... 1 ~tJfY>~ ", .. r .. fC UG). S- luri"" '"p' .. lor r~.,. ........ !. h , .... 'V, ... S.· .. ..,. R~u;,.,.,...~I,· 1.-c!>Oft 01"" "''"*l

S .. Il..,ul,.",,,,,,, Conlinved I" ll'lird ~~

/3


Req~II. Conlinued:

( .. , Halr.dIwa UPQ .. d 10 HI;" Conuntr.II01'1': ~ •• ~..:t 10 hog'" li'borne eotICtlnlr.Iion, 01 ""it product,. .uch II dN"UP loIooorinQ"~ .~. n·I,1'IIo. d .. "i'og 01 b:,i. Ian"', and .I;;ooto ...... ,O 11'1. ptOdoCl Wi poorly ~.nt.ltl~ .r,." "",,'_at:

• ChtorNcal·, ••• t.rl! 11,11.

- O\elftbJ.,..,.iI'ln'lIbv ... l\IOCh.1 barrier "'",!rial, 01 ~Ion. • C~·,.".I.I'II: laotweat plus '(W;~'. • CtlMnieaJ.,nal.nt hNdg .. f, • Supp'-cl-•• fnpnlot _1'1 USH .... !NIOSH 'pPIOVw ,,\II'nbM pr.r. TC·'$C 01 •• ,. ~I.n.d t>r.llhng 'PPI!,.Iu, (SCBA1.tII MSI-WNIOSH apptO¥.1 nurJItMw pr.fll( TC-I3F. 54. lloIMw ,.to~IOf ,equir-*", iI,.. '\Jtw SaMtr R..,. ... ,.ucljan clihe II!)M,

USER SAFETY REQUIREMENTS 1. RIH~IotRlqui ...... nb: Wheft. respQJof.~for ... 1riIhlNlptOdud" ... ~ c!ileril mUir bIi met ('1. rlA-fae. , .. ~.&cw. fllMl btl wom. (b).~ Of c"'"" """I bIi , .. e.ell da., 01/ whtll odell' 01' MIllion "ont ... prodIId t. _. .~.ftt. trhC"- it 'ooneI'. (e). Rnpbion musl btl g·'",ed Mel NCo..c-l" "'FIg. prQgralll that confonJllllo OStiA", r~~ (dt.cribed ... ~ efR P,,, 11110.1)4). (d). A..pdIOl ""'.,. "",,I be lnIMd "'kif • P"O'iJfMI hi !;'OI\Ioml 10 OSHA', rt;quir.llltnb (d.Kri>Id n 29 erR PM. 11110.134). (Il, R"pnlor "' ... mul' be .:r.arnr...d by • quAiI"-.d ~".I pneltiGMt 10 _U" phy.ieat .~ 10 .... Iy...,. tN .fylt tI t"pnlOf 10 "....om. 2. N_ FWllig.11 .Son.: I It n.pet.liwI 10 l!.rays tIP • ..., ,. .... lInt and PfOpW

PfUlloCwl ~ ... ell. tIllC'CicIIftI:I" " Ori.,.,. R .. pontibiliu..: [)ri..,. of 'pPli:ltltvt ~I'II fftDl advII.l oItwIt -'-,nI 01.1 pt'liUlllioII:I,rwd ptOC","" lit Ndibn, ~ rllUSl"1Ivd thU ha~f1I ~ the fftIoC~icai ~~1iGn QlIha IIICIor ,rod how 10 .., .... "'OIk .1iA Ihe If-=IM .1'Id dffl ... whiIIlumig.lt'og, 4. OiSPQ61 ,,! Conlllmln,lad CIo:hlt'Q: OIturd clcthng ,rod oI~ ,bsOfbani ..... ~It ~ h ..... *11 dranch~ Of he .... i-( (""t.rN101li1d ...... " liQuid 01 Inil product, Do 1104 '«.I!.tt.alft. 5. CI .. " .nd Llaillwlll PPE: r,,1ow rn.nuftclu,.," nlt\lt:lioI'I. lot cle.~,",I.'" hg PPE .• no .ue" n,,!tucllot'l. kit ..., .. h.Nes. us. dtIIa~ .nd hoi w.,.,. ~P.net ........ PPE ""..f1Il.¥ "M! t>1MI' laundry. Wa,,, P'PE.ftM NoCh d.,,', ""., fl. c:..t.cl Wil" Uot..:',; N"".,,~ u.. product by rnouIh Of ",,, nooulh 10 blow GoA cloogol'Cl iM't, I'1oOZl~' •• Ie, 7 ..... , IIin ... A .. ~II'IC': U~I rnl!l$u", 10 IVoid 0( rnnioftlz. ""., iIInft. wtIIt usng Ihir. p.oduCl, Thau .......... inc"'~ g:'"du,i .djudm.n1lO toe,l .nd .n;>ir.\r;Jf .1 •• ". f.". lot cooling. cO<>lng ..... :s, "l1;u.nl bt .... 10 cool dowtI, Iraqu ...... ;,! ••• 01 bin.ing ..... Ier •• r.cIm •• ,IIw.;'g .... RigM "CoI"/I t:ly 10 C:q.

USER SAFETY RE-COMMENDATIONS u._.houkt. • w .... h.t1M:ft .'Of' •• ~ dM1ng, c~ v-a. "'WIG Iobtcco, Of aniolg 1M loW. • R_. cL1lhhg Innt~ ... "r' pt.ficiM gal. ifttlde. Tbton wash Ihor~ af'rd puI

at; clNn clOtN\g. • R~ PPE Immedilol.ry III ....... nd&rg ltIif prWucl. WI.h IN ouI.icM ttl gbl ..

bel'0f1 ' __ ~ino. Aa '00I"I .. ~allIt, ...... It t.otoueM, aM ~ r.to c"." clDlh"~,

[UERCENCY: IrI UM aI .It _~ .,.&rngamg tIM .. ot lha .rr.ftj ........ ~ !Nt ptvdud. ul "'- 24 Hwr EtM.g.-q ~ ~ (800) 424.tlOO,

STORAGE, SHIPMENr AND DISPOSAL SHIPPING. STORAGE: AII",ul",,.! Chel'liall Do noI.~ CII' ,lore wlh focMt.IMd •• drug. 01 cIolhn;.. STORACE: Siore n 1igN1y-c:1PNd cw'-oN! cont.".,.,. eooI pIaa .... , Iron! dINing., 00 noI • ..,.. cool.l.-.ti:w\ aI.Mod •• 1)11"11, '-lih .... Of o&haf' ,-.1Icidt c~lt. Do ftO! corQrMltlalood,llItd ,I""' •• drugs. "" doft'oe>,lk_ ..... uppiaa,

DISPOS.Al: P .. ticidt WI.I ..... :0~1c. lrnpnlpw cr.poa.1 cI ,.e-. pHlidia and .......... " , ... iolt!i.)ft cI F .... at n. • 1ht1. ..... 1" clWVlOl be d_pos,l'CI cI by ut. ICcordirlg 10 Ii~ "'strudioM. cClftlKt )'0l.Il' '111, pnIicidI Of anvirORr'l'lelUl conlrol 191"q', ot !he htz.rdout ... ,,11 rapr •• _lawl .. thI ...., .. 1 EPA ,~ ",,"0(;1 IOf guidtntl, a.c."". 1,3.-dichloropropt.,. II ~ urMIIt c.rt. ... ~;or... ftuth .1 199iCI"'" aqu~ ....... "" ~ '1f'OMI'II Of •• ~ fyPl cI patrt.IItn KIfwInt ~.,., til., ,""I. fl pumps .,I(! -",. .... _ rrMIIOf 01 Of I 50% IJIOIof oMuti 01 fn\,IlYfI btl"'l .kIftoI9. Do not u ..... I.r. [)it;potl cI ~.I. b'f .ppk:abIt r todItfIl. St. .. IfICI Ioct! .tg",ltli:lns, Nrw~ ~troduca ...... 1. Of _ad prtIc:I<Jel Wo • .,.rt"aw or IINHl'9'OUncI_l~ .u~.,

METAL CONTAINER DISPOSAl.! To If.pot. tIl COI'IItr- .mp.;'>1 c:tumg ~.liorI .fltion, "mov. Nlr>9'. ;"".rt Contlirlll " Ih& , .. Id Ptt trilled .,,4 1M .... that lhe ",,",aInw II , ... '" I"qvd. Orietll cont"'" .uett !hal ~tiorl cI bvftg hoIH II 1104 _1tic1td. I"-t conI.nars 10 ..... 1. for .. INti 14.,... l'\apIK. tJvr>vt pm, 10 Iramport, AIIIt' .... Lion, off., cOlf'llt,* 10 ~If'rt<d ,aeonditionar Of .~. cI II 6I'1C:ad bt Stal. Of be., ,.".liDnt.

REFQ..LADlE OONTAIN[RS: c,or.ttd N ~ an4Iot ~ ~ ,..,r .. _t.w. for ditloClion. 01'1 c".Mag...:l ~ , ....... ~,..

BUlK oR MIHIBUUC PRODUCT TRANSr[RS: Dry tin ... 01 6ty dleonroad ~ .... tqYi'ad for .1 produc1 tr.",I'rI Ift¥oMoIg bulk ctW'IlI ....... lot prvdvt-t. cor~''''nv 1,3-d"I'I~(Ipi'>tII .1 01 s.pI .... 30, 1991.

ENVIRONMENTAL HAZARDS Do fY.It corbmh ... , .... 1 .. by clt."r-v of toQ"~1 ot d_pot.1 of wn .... Sta 'SIOf'~, S"'lptntnl '1"4 CM..,o"r .... ;:IIOIl. n Uti 01 .poII. propatIy ditpu_ uI corot.min.,~ m.I ........

GI&Ul'ld .",.1., Aohrl.ooy: 1,U"I-,bt.Yy#OPIN".r.own B _.II'I!'O<I9h ,01.,..;' IIndtt c.rt.n tn~~~. ~,II 11'1, poC."h.1 to '.11<1'1 grour.d ..... , .............. of .g.ie" ..... t uu. ~k.t'0QtI WI ..... wt.., •• o-ot. ... pt"""~ end g~ .... 111 ill I\<tM ..... ,""_. Of'

r hf'lt ga<>\togy. t~uld .. wi ... ground ..... , ... n>t>I .......... 'OOfI.

PHYSICAL OR CHEMICAL HAZARDS rLAMM',lU..F.: 0 Jiu •• , pe¥', '01, Of'1'_ .... ...,1'I •• 10I"~"' ...... OofldMnI •• Id t<lO'>lllintt.

/3

Tri-Form 40/60 l.ahel Columns

DIRECTIONS FOR USE II ... vooial.on of Feder ........ 10 u •• 11* prodoJcl n • IN_' KontIt""I_""" I.to."'lI. Do fine

.~.,. If.:' ptOCIlICl A • "'J IhaI ¥I' conI~1 .... , •• ,.. Of ot~ ~,"oo' .•• hw d.edl)' 01 Il\IouO" drill 0,,'1 profe.elt<l han&.n. tI'\IIy be iIllh· .. dUl1f\1I Ippliull(>ll. FOt any t"Quif ..... ··, 1pw.J"-: 10 rOUt Slat, Of Trbe, conlul the ~wrt:t Ie'pot'IIt>it 101 ;"1'''-0. '..-,;Jut.Lion.

ENGINEERING CONTROLS REQUIREMENTS "'ECKANK:Al TRAkSH.R SVSTEIoI: P.~onal plOle<:INa e-qlli;tmenl lpect"«i 'Of -O;'ect ContKI kINiLi,,· mull M worn by 1M oyelalOf 01 tfle "'.chana' lral'l,l., ')I.IIm. TN opelalor 01 the mad.anicel',.,."" I)I,I,m mull t!.II' .".~" 10 him It .. manwl.ctww·. _U." ... tn.ocliont 101' O>*,lion 01 It!. .,..1 ...... nd mu,1 I .. d .nd understand (ot hall' upa.na.d 10 hinI .. .alll) lie pt")p4'r ~·.Iion.nd "",I,"anr.a ~ !he • .,. .. ".. wffH ALL BUlK AHa MlHI-BlTJ( CONTA,"ERS: t.l-d'..:~ ."Ct 1.).dichbopl ...... _tel ..... c~ """, to .. ",,,,""teI ~ CQI'Iftt(liIog hoe •• M-.... ar ~ ....... ~ tipllo prw.N l\anolara ..., dNf ....-IrurII COI'I'ing" 00IIlad wit! &quid 1.3 didlJ ep:op ... ancl'of chIoropo:M. t. AI hot ... ~ M'l LIMa ",ad h COftIItClioII wil.h '.3-4kt-~ ww.tI« c~.ha11 be apfftIpriale lor .......... ' hi P'''I'''. and vtClIUIIt eonclol" ~ be MCOCna.rad. 2. uitmal.igN;aug ... hal M..,Ipf.ad!.O v."'" .0 IhaI pPe.1o .iIIN Qo'ugt call be.hut 01111 CMoa 01 bftabge &IId~, 3. n..ntoadIanIcathllil •• ,..I ..... ""'" M adaqw'" 10 ".. ... '*"'vt "~"U'" "*'" olIN " .. ,~ *" usad. '. ShuI.c.f dowicaa _I M ... 11..114 Of! h .aI and of ,I boa" .nd at al cis(onnact poirIli &0 Pfevenl ".kage 0I1.J.dic.h~' .• aIOCSIcw e~ producl .....,. 1M 1'.Mt., ia llopptd er.cl "a Ia r.n"O¥ad Of' 6iKonneclad. A 6ty ew.,... lhal .... 1 mirWNz. pasllcidt INbga MUS' be milled .. U .. dilconnad poW. S. Ttle p'H.ure in tKJa .. ",ad &0 nIOYl 1,l-dichiolopt0geAe aIIdIot ehbtopiclol'l beyond. fIU"IIP f'It\Isl noC IIIC,," Iha ",.lKJfacll,l,.,·, "'Illirnurn Pf"" ..... peele'IOn.

AGRICULTURAL USE REQUIREMENTS Usa lb_ Pfodud only h aetOt\""l'IoCe .... ~h II lat>tw.g II\d .. ilh l!'I. Worl., PlOIacl;o,. St.oda.d, .0 CfR 170. R.I., 10 '11,,?~mlnlal I.IM-'nG lind., ·~ric;lIfur.1 Usa R~ .. r.I1ItI'l\.t.· n 11'1, [Hacl;o,. 'Of Un .eclion lot "'.Io:nw,tioll OIIbov1 C'lis .t.~.ro1.

WAHRANTY DISCLAIMEH NOTICE: s.a.r .... an.~. that ltI. prodv<:l CQN(W1I'>, 10'" ,""n.~ .. dMcrtllion _It.. DbM .nd It 1 •• ,onaDly iii. &or "" ~ •• ,Iail'd _1M ... btl ..... " U40tod"" ,,"CN1Ilncl .,ilh <:"",Iiona under notTna' cOl>Cf.ior •• of ""', buI ndl\to, Irlis ."'Inl, __ &n)' olhto, .... n.nty 01 MlRCHANTADlllTY 01 fITNESS FOR A. PAAT!ClI\..Ali PURPOSE. '~Pf'" Of~ ••• 1Mds 10 l1\li uU d Illlt ptodud COiWlry 10 IIt,1 in.lnKllOtI., or 4oI1'1def .t:>numal ConcrJioIII, Of IoIftidtIr

C:OI'd.~!OOI. ,w'OI'l.b'"IQr.'M"bl.10 ..... ".nc: 1I11)'1' oll'~' "- '~k 01 any I""h u ••• INHERENT RISKS OF USE: I It nponible 10 ,lirrinf,la ,.rah .u(>(:~.d ¥loth un oi this ~1. Clop r.j.ot). ~k 01 ptltformane., (It (IIh., \UliNencle<l COIl'eoqU.nc.t INIY '"ul bKlu,. 01 Iur.h lac!or. II :,in ot ,/'It ""odu<.l cOfllrlry 10 label and ~beI boollM in,lt\Iclion.

, (ind.lCfilg c.orocI.IionI. noI.~ on Ihtllabel and lah.tl ~itt, .lIIth It IIN.IIOfaWe l.m""".loJr •• , .01 condiIi::orII. .Ie,. a~1 ,O;..nd.(iOM (such as ue.ulva rainlal. d."OUght. 1otNocIo<H. hmc._). pt •• PC' el oIMr ........ 1M runnor 01 ~ .. 01 "'h~ ar. beyond Ihe UI.I~oIIM cO/'I'OI»"" Of !he .. .., ..... ,we.III"'" 'NI be a .. 1MMd bJ IWyw. LIMITATION CF REMEDIES: The ,lIc_Na f'IftIedy tot 101. ••• Of datMg .. I .. """" ".". !hit produd (rocfullng c ..... ~Nd on conllecl. ~ .. 'Irkt 5Ibo1Iy. fit olhet IIQ.a ........, •• haI M ImItd 10. at 1M compWly' •• '.dion. one 01 1M loIDwWlg: ,,, RM'und cI pwchtn prIc. p.aid by tM./yer or "..-Iot product boI.Ighl; 01'. (2' RapIKWfteNI el __ of pttldI.d IIttell. The CCIrI'(IM)' .. hal noI M i.ablt fOf lotI •• Of damaoe' r .. ~ "0ItI"'~ Of un 01 attil prodId uN.-. hi company it P'0IftPl1t noI,,{1td oI.uch 101. .. Of darA.lV'" _~. In no UN.haI IN COItI~ M iabIt lot CMlequanliti Of n:idtntal ~ Of t.a.... 1M IenM 01 1M Warra,." OiI.cIaiMI .boII. and lhiI l.irMalion 01 Remedin CIINICII M varied tit a", writ ... fW

.... rNI " .... IMN 01' agl .. ".enls. f\oo etnployH Of .aJe • .,.a of 1M torI'p&ny Of lhe ...... iI auIhoril.d 10 nry Of ellcHd lb. IWllls 0I1he W."anly 0iIda~ 01' \hill. Linilalion el FWIMdtiK n any maJV'IiIt.

CA April, 1994

POISON

POISONOUS LIQUIDS, FLAMMAOlE. n o.s. (CONTAINS OICHLOHOPROP[NE, AND CHLOROPICRIN) UN 2929 INHALATION HUARD

13

----------------------------------,


RESTRICTED USE PESTICIDE for retail sale 10 and use only by Ccrtifted Applicators or persons under their dire(..l supervision and only for Ihose uses covered by tho Certified Applicator's certification.

u\BEL BOOKLET DIRECTIONS FOR USE ..eLUDING STORAGE. SHIPMENT AND DISPOSAl; PRECA.UnOtu.RY N"QRMA.TION" ~umNO REQUIREMENTS FOR PERSONAL PROTECTNE EOUIPMENT; ENGIHEERIHG CONTROl AND REQUIREMENTS; AND AGRICUlTUfW. use R[QUIREMEHT5.

TRI-FORM 40/60 A uaUID SOIL FUMIGANT

FOR PREPLANT TREATMENT OF CROP LAND3 TO CONTROL PLANT PARASITIC NEMATODES

AND CERTAIN OTHER SOIL PESTS. NOT FOR USE IN GREENHOUSES OR OTHER ENCLOSED AREAS.

ACTIVE INGREDIENTS: 1,l-OkhlClfOprOpeno Chloropicrin


37.6% 59.4%

3.0% 100.0%

TRICAL P.O. Dox 1327. I-Iollistcr CA O~024

E.P.A. EST. 11220·CA-l,2,3,4;FL-l E.PA. REG. NO.1 1220-15

NET CONTENTS ••............ LBS.


DANGER EI PELIGRO

POISON Pcligro: SI Usted no entiende la etiquola, busque a alguicn para que sa la expllque a Usted en delalle. (If you do not understand the label, find someone 10 explain it to you In detail.

IN ALL CASES OF OVEREXPOSURE GET MEDICAL ATTENTIO: IMMEDIATEL v.

TAKE PERSON TO A DOCTOR OR TO AN EMERGENCY TREATMENT FACILiTY_

FIRST AID IF INHALED: Remove to fresh air. If not breathing, give artirlCial respiration, preferably mouth-to-moulh. If brcalhlng is dlffkult, give oxygen. Call i' physician.

IF ON SKIN: InT'J"Iediatcly nush skin with plenty of water (0( at least 15 minutes whi. removing contaminated' ·'ltJ-.lflg a,KI shoes. Call a physici.a11. If water Is not In-.medlateTy '~able, ~rllOY" excess chemical from skin with adsc:wbent mate, .. ,. h as towel or dry soi. then proceed al oncD to a JocaUon where .. 1\"r Is avaRablo ar.d thoroughly wash contilmlnated skIn WIth plcnty of water. Call a physician.

IF IN EYES: Immediately nush eyes with plenty of water for at Ica~t 15 minutes. Can a physician.

IF SWALLOWED: Do not IndueD vomitir;g. Call a physician or p"ison Conttol Cen!er mrnediately. Never give anything by mouth 10 an unconscious per:!'oOn.

NOTE TO PHYSICIAN: BecaLse rapid a~sorplion may occ.ur thmu']h lungs I product Is asplra!ed and causes systemic effec.ls. the decision 10 in<!UCD vomiting or not should be made by a physlcl."n. If lava<;e Is perf~d. endotracheal and/or esophageal (onttol Is sugg@stcJ. Danger from lung aspiration musl be we~hed a'Jain!.t IO)(icltf when considering ~mptyjng the :;Iomac.h.

r, i" 13


PHECAIJTIONARY STATEMENTS HAZARD TO HUMANS


HAZARDOUS LIQUID AND VAPOR. • DO NOT SWAllOW J.J.N OF nils PROOUCT. MAY BE fATAl. If

SWAlLOWE D. 00 Ii.;)T CET IN (YES. CAUSES SEVERE EYE INJURY', 00 NOT GET ONSKW, MAYBE FATAL If ABSORBED nnoUGH nE SKIN. CAUSES SKIN BURNS. WAY CAUSE AU£RCIC SKIN REACTK1N. 00 NOT DREATItE VAPOR. lotAY OE fATAL If "'HALED. MAY CAUSE LUNG, LNER. ANO KONEY DAIoIAGE AND RESPIRATORY SYSTEM IRRITATtOH UPON PROLONGED CONTACT. THE USEOF THIS PRODUCT MAY BE HAZARDOUS fOVOUR tEAlnt THIS PUOOUCT CONU.,..S U .. OICHlOROPROPENE. WtUCH HAS BEEN OET[RMHEO TO CAUSE TUMORS IN LADOAATQRY ANu.&AlS RISKS CAN DE REDUCED BY EXACTlY FOLLOWING DIRECTIONS FOR USE. PRECAUTIONARY SUleMF.NTS, ANO BY wEARHl THE PERSONAl. PRoTEclrve EQUIPMENT SPECifiED lH nilS LABELING. nils fUM)CANT HAS THE CAPACITY TO CAUSE w.RKeD iFUUTAOOH TO ntE UPPER Rf.SPlRAt.TORY TF\ACT. A STRONG LACHRYMATOR (TEAR.PROOUCtNG EVE lAAITANJ}.lOW CONCENTRATIONS ARE CAP· ABLE OF C\US~G PAINFUl EVE IRRJTArION. THE EfFECT tl.AY BE so poweRfUl TKAT A PERSON IolAY BECOMe TEYPQAARIlY BUNOEO AND PANIC-ST1UCKEN. THAT ..... TURN. MAY lEAD TO ACCtOENTS.

AIR CONCENTRATION LEVEL Th4 ,ocrplA~ Ii' conunlr.lbn Irtllt fOf p.an,on ••• poald 10 c~rn .. 0.1 ppm 10.1 mg!M'l). n. air OOf'IC.nnlu.. \I",al .. m"'1a"1d br • e.ad 'IAc:ng dal"'l~ atovica, .lICh ••• M'lhe~on·KQg'''''. o..,tog". 01 s.n'idyroa.

PERSONAL PROTECTIVE EQUIPMENT (PPE) C"-raical·R .... \.anl Malariele: .i-ofM ,...Iw" UWiI _ clMnMe.,. .... teni 10 ~ poO(!ucl,'. "-I.-d bekM-... you .. ,nllftOIe opIion., IoIi:Iw h InsltUdion. 101 UII~ H on .n EPA chlfl'lul r .. ~I.OOIo cel"9OtY .a:.cllon ch..rl. PPE COMlrucItod 01 s."I"11~ n~lne •• nd chbIYI.lad polye:hyitne pro~ida .. hotI·l.". conlKt Ot .pI.t.h ptOiKiion .gein~1 liqUid of Ihis Pfod .. cl. long"·I.,,.", prot.dlon .. ptOy.:"t<I by PPE ronltf\O(lad 01 V~on, Tanon •• 1>(1 EVAL. b .. rn. !amhll., <'01 .un!pla, R •• ~., IV~I INIn"' .. clvr.<i by li'e-gv.rd Of S .... ~h .. 1d g .... ~ •• ",.nvIAcl\lred by tkdl). l .. lhtl', celW ... 01 cortDr\ ",.1_11 0/1' .. no protedion hQfl1 I"" ",tOducl .nd mu.1 rtOI be -. wh.n conl.cl WA" I~" product iI p"ublt,

(1) Handle,. P.rfom.1"i1 OiNo<I-Contacl T ..... : Ohd-cOllted Lllh .,e lAth ptIf"~ formed wdoon Of n. w"'''lnliI.Ioit<l., .. , Thay hcluda: • aqu~ C.IbrA1ir.on Of adjv.kN-nI aqv~ clt,I'IoUP and I.~

• Pfo6.icl ,A,..,pr,ng I ,~.Iion Ot .oil· ••• 1irtg OUltidl ,n anc:1oa1d clb • .roy ~w.ty It .. I"'." eo ' .. 1 I,OnI .'1 "q ..... 1dId pt'''UNM t.o.l con"~ 1l'I • ........ I.~aI oIllrp Of pLnlic r;r., ""'ul.tllopo\ll f~igal\l tr,nll., claan"p01 &m.',poh pr';lAling conl.Int,..IOI' • .,...10:>rI

• '''y C/lheII\ln(lfong 1 .. " root othIrw ••• I~ ~ (1). (3). 01 ( ... ) bt.Iow .t.,;:.pliuol,,", .I\d .oIh11 hand .... parfomwng d"acl<C>nI.c! 110, ... mu.1 ...... r:

• Coooo.r." ""'., .IwHt.I"",ad ,hFllnd ,"""" panl., A Cherttlc.l- .... I.", glcnr ... .",cl"l .. ba.,.;"w \en>In.I. Ot ,,1oI!., A Chemlc.l-, ... tenl ;00"-"" p'" .oe .... • Chotmie.i ...... I.nI ~ •• f fof CNllfl'lled •• pOII"' •• • C .... miul· ..... I.nI.protl, A fill-lac. R •• ~.I01 ..... il" •• h.,.n ~~.,,~.,_r.g caNi6g1 'toil .... pNf • .,

.PPf"W1d lor ,,"Iicod .. ('~IOSH .pproooral Ml/II~ ~r~ fC.2lC), Of •

unp.-I .. l'ptO>Iad for pto'locidn t'-'SHAJ'NIOSH 'pprtw,1 "IPW PI.r~ TCt4C). s.. 'crth" rt'.pw.lor requir.mtnl. n I .... -V ... Sallty Ra<:w-....nl.· .aclion oIlhe b .....

p) tt,nd\e,.. I" Eroclou(1 C.b.: AppSc:.lor. .nt other } .... ~ ~ Inc:\»ad ubi ""' .. , WI.r:

Cover .... Shoet .rod .och, Pluto. I todof Of inl.lio/II.(WII '.till ~:vd\IC1 c." bot delected b.kte tM .nc\:Io1ad cab Of ...... ir cone.nltalion le"'ll 01 ~hkw~rin ucHdl 0.1 PP"I ~.Id. I~ ar>c:bt&cl ce~, handtrs n u.. cab ",u,1 _II' • Jvt·f.oe _pirator wi" Hh .... an orv",it;:· ".po,",,,,.,,ing ca"'idge ........ 1"1 • ptll,," 'ppn;P'II'ld b ~licdet IMSKAlNIOSI-t .pptO¥.' r.urnbar prtf~ TC-2'lC'. Of. canillat afIPtOVad for pallicldal (MSI-W NICSH .pPtOY'" nlHnbar pr.r~ TC-I4C). See r..,~ , •• plrllOt req,W_I.1rI 1M -0..,. 5.a1.t., RtoqIor'_n1.· .. dion of 1M.bel. In IiddliOt\!he PPE .pac/ild h (Il fotcJiracl-conlad ..eM .... _I be; .....,...,.1.., .."WoIe In the ancbtld cab ,nd"",,1 be -" r '* hardaI .. .,.. the IIftCIo .. d cab 10 £*fOtfll .,." dirlKl<on&Kl ec;1;..iy. The erac10lall cab ,,*,1 ..... tie '~.""'nI. ~11d IrI lhe Work.,. P~actbti SlatIda,dI {WPS) !of .pulurll pat.liI;ida ..... OCfR 170240(d}(5).

(J) H.rtdlara In T,..I..., Artoe WilhIft 71 "0"''' Aft .. Appncatian: OnJy h ~ hAnd.., !,at'" "'ay be parlorl>oed WI I"" "ultd .,. ..... ....., 72 ho&n ,"If I ..... ppk.lio/I

"c~.: • "",,"~'djutli-l~ lha .01 .... • ~ .. ~ ... ,ing pe.1 COf>lrol, .pp'c't.oIIl~hnlque, or .ppI(:.Iioft .woe:.cy • s ..... pIng ... Of.oiI I", Ih. producl All ....... , ta,h .,. pro"',bil...:!' ",,,,;111"0. 72 .1">0\1' period h •••• p1led. Unit'" In .n I!-rK1o:>tld ,:.b" d..cfbeod ;" 01 .boY'. h.ndle,. pttIo. ......... to,. aboY. I" .. h .... h •• IM ........ ~"in 72 h""'" .n" ,pplocal~ ",,,,1 W •• r:

· eov .... nr., • ChoImictl .• .,"I ... 1 gb.r.., .• uc'" II bltT., bomh.II'" "Ion. • Ch.moCal".,~I.hlloot ...... u".rw:1 .od., · P.". If oo1c.f 01' ~nI.I~!rom I .... product (.n be dIIaciadOt r Ih •• i' ~lf'Itr.tion

,.~.tt.f c""o,~rl'l •• t.adl 0.1 PP"\ .... nC,.~ """I _ar. I" .. ,.c. r"plrllor ..... " .A .... ' .... ""9 .... Ic·"'.~· .. fI"IOYng U"' ... 11\ • PI.r." 'D?""Ytd I", ..... llco<lH IM".I1A.1JIQ<;'H '~'IW.t nu ... t..f """, ... lC·1JCI, o:tI • c.an.I., .t>p"wt<I lor pI.IO;,.:!., IM<;I"'A:tJQ~H I?QIO'I'M n..,...bIf f>"Ir", lC- "GI. s.. lurt"" '"~~"or ,.,qu",",,,nl, il '!"o. -u, ... s.re!y Raq..tir ...... '1I'· .acliol'l 01 a-.. It~

S_ R .. ;"I,._n', Conlln",ad '" Third CoIu"""

Tri-Form Piilnohl"t Page 3

ltaoq"It.IMhl., Coftll",,":

(4) '''~ E...apo.ed to HIGh ~lIatioM: '''ndI.n •• ~.:4 10 h;"'h "~ conc;..-It.IiorI. 01 1M. ptOduc:t. Jueh II d .. nup I~"~ .pa. . ., lank. d"M>g 01 bu. lanh, .nd •• pcl'tIH.1o U\iI p~11'I pooIly ".nlllal.d ",,_, mUll ...... Ir:

• ChtolJlical-,"iI'lnI ,,,,1. - Q,.micill-"l.iI'ant gkov." IlKh.1 ban .. , ~rnIr .. "Of \I~OI'I. - Chernbl-"~i"."" lootw •• , poIws loch, - CMtT>QI-I ••• a.nI Madg • ." • ~ ... ",piI.1of ....... M5HA!NI05H ''>pro¥'" number pr.r. TC-I9C,. •• ,.

cOfll""" twNihftg 'ppat.M (SCBA) wllh MSHAJNIOStI IpptOY" ""'''~, pI.rlC TC-llF. s.. fut1M;t "'pW,1ot r~.,,*,I, ... tM Uel 541'''''1 RI'qWern.ne.~ uclion oIlhII .. t.t.

USER SAFETY REQUIREMENTS 1. R"ph,1ot RIqUIr~.: 'Ml ••• ,.phlor .. ,equlrMl rot ut. wjh uw. PlVdutt. Ih4t foIoMIg criMio _I M ~ t.). f~fK""plrMon _I to. worn. (b}.C.r\ridgn or U~M !MIlt be NPiKH daly CIt""'" odot « nbliol'l frtlftl Wt produd bec.ontH -war"" whi;he¥w II '00f'IN. (c). R •• pirMon nual to. 9.IHI..:I and fiI_ checked ",~. 0f09I'.,.1IIII1 eonIonM 10 OSHA', r4lqUlr-m. (det~ ft 2'0 efR P,tI 10l0.1l4,. (d).RHpDIar "' .. _I t.tr.~uth; • .-00""' "'~ ~ to OSHA', ' ..... _ .. ( ..... m.d h 10 CFft Part 11110.1l4,. (I'. RHprMor l1li ....

_, to. .-..rnheo by • .,ali'*, ,...,.. ptadiiDnw k- ...... phplc..al .bIIIy 10 • .,ett ..., 1M 'trle d r"pblor kI b4I wo .... 2. tMw ... FYIIIig,I. akin.. I .. ~I"', &0 aftt", N" ..w a".1anI and prop.' pldecUt, Jquipftlenl nu" d eceid,"'tt. 3. om.,. R .. ~ibtlitin: 1JrHa,. of app/Qlion ~ ""'" advlt. o4.hef -'-.... 01" pnuutlona aM proc~'" In addilorl, drH_ """I .... kvct IhN helpe .. ~ h ~ ~-*'" of faa "",lot er.d how 10 ,afetj -' wU'I h Ifadot and dtM>t .... "",..1",. <t. O;:.~a 01 ConIa~ftI;led c ~MrIo: [Mcard cklltwlg and Glher .~0fbenI IIlaI";'" th.1 No .... I>eIft cIr~had ct h ..... it cOI'lImAitad ",i:h ~ of Ihlt ptOdud. 00 /'IItlII 11101"',,-111. 5, CIIlIl\.nd Uai,.lain rPf: folvw I'NnUfKluflil nlruc;Iic>n. f", c!u"ing.'mar.lllin. ing we .• no sueh nsln.lclion. kw ... "h.a~. uta da4,'g"" and hoi. wal.,. Ke.;t and ..... " PPE up .. ,.le" ftor., 01"* lavndty. \\Inh PP( alia, .ach d.y·. v ... II. Con~ac:1 W>lh Mouth: N .... ., IIp~ IIlIt proojucl by ~ Of via mouth 10 bbw 0Yl cleggad ""'. nou"', ele. 7. u ... au"." AYoidanca: U .. mallUf .. loavokl CIt ".ninlil, htoel iItI .. , ... !'Iie "'''g lhit pt'Oducl. n .... meNUI" incWe gfldu.l.cr;",Lm4" 10 .... 1 .nd .. ,pj,.1or ,h, ... fl111 IOf cooling. COt:Ii:'lg nlll. f,eoqu,nI brll"" 10 cool c\ooIIfn, II~1oIIOl filah Q/ df;d,"'g .... I., •• rod 1T\UI1I~ w.oghlllOlTl d., to d .. y.

USER SAFETY RECOMMENDATIONS U.IB lhoutt: • W ... " hlNl. balot. 111""1. cIIin"ing. (.h-ng g,,",- Uling Iob.cco. or u.ing IhtlloNL • R.rnov. cloltmg hvnKI .. I .... I pa.liciOa g.ts .... ida. TMn ",aah IhorooJgt\tt .nd put

011 clNn clolhlog. • A_. PPE r,.-.1IIICf."" an., hatdrtg ""II PfOdycl W •• h Ihto oulliOa d gb."

barOAl "l"I'IIrIn~. As .oon II poa.tl ... w .. h ~..." .nd d'Ia"e- i'Ilo cliMrl clolhng.

EMERCENCY: In UII of an .meF1'ncy ~ngwino N.lh « "'" .rwironmenl ....... ~ng ... ptOdvel. c.ali/'l. 24 Hout ErnerQ'ney Phon. Number (aro) 424-(1300.

STORAGE, SHIPMENT AND DISPOSAL SlIlPPJNG. STORACE: ,t,griculIHaI Chanlkal. [)Q rd..~« ,~ wih 'ood, ,..,;Ia. df\lgl «dolhfi;.

STORAGE: Slott" lighlly . .;!OMd origNl cont.r..r ..... t'OIlI pa.c. --1 flOfft ."....Ioog1. [)Q ~ ..,." ccwMa"""'lioofIo 01 ....... ~n •• I~.,.. CIt ~ ~U;kiI chanlbll. [)Q noC ~.Iof:,d. fMid .Iyft',. drvgs.« dornnlic _I", .upp6M.

DISPOSA.l.: Pulc_ ••• 1 ... ,. IOllie. ImptOplf diapoMl of "Ilea .. p&llicld4l .1'14 ,..,,,1 .. " , ~lotIlion d fadetal r.w .• lMIoa w .. l ... eIIVIOI be cSilJIO'ad 01 by use accOld~ 10 r.t* Ntruc:1ionI, ...ontad 'PW .tal, pa1.t<1de Of _~ conItoI .~r>ey 01 IN haurdous ....... rapl ... oIIl", ... eM __ .1 EPA I~ dJ'1C' 'Of guid.nc' •. Oacau .. '.l-d'<h~ftI It C'Orn."Slva urw:r.r carta" (;CIr'I(Ww. IJut,h .1 p'p~.1iOI1 ~nI with '* ol "'fOMI'I Of •• miIt type of I*'oINtn .0),""

mm.cr .... Iy .... "' •• f. pump' .~ ""I.", w;a, n_ltlOIot 01 Of a.50"4 1ftOI0I o"uaI 01 midWII t*or. 'lome. Oa not III .... 1.,. [Mpot. of ma.l. b)' .ppkab&t f.d".l. SIll. and local ' .... I~. ""'If W!'odI.I::. mil" 01 _ad procIucl Wo ,1oIlf1Ol 01 IH'IOalQrouncI-"" ,"""",

METAL CONTAINER DISPOSAl.: To "pot, of conY ..... ~ ~ .ppblion ep."I;.;,n, ItrnClYlr ~ ........ " coni ...... In the r ... ·i ~I " .. I" and ~'lI'a thai ,~ COflI.~ .. fl" 01 'quid. Orllnl conl. __ aueh tt..I nnlialion 01 buog hole. ~ no(

,"Irid.d. Ntow Coni ........ 10 _.1. lor at .... I 14 dip. R.~. bunv- prot 10 IlInlpot\. .... " • .,.~ion,. 01'111 contahet 10 quaif'oad ,~ « clllpot. d .. clhclad by 5Iah Of Ior;.a 'aguialloM.

REFIl..l.ABLE corn AINERS: ConIad "'" c~ an4'ot hi c:ompany 'apr .. """" kit IIfncIbnl on C~ and hatdncJ ,.,.. ... ~. DlA.K OR a.UNIDlAJ( PROOOCT TRANSFERS: Dry btMt Col drt daconnad eouploge a,. reqWad lot .1 pro.:krct .,.n,f.,.. ~\oog ~ coru""'" tor ~ L.on&Mthg 1.,...010409'4*."" 01 s.pt ___ lO. ,tCI:!

ENVIRONMEN1AL HAZARDS 00 001 coni..,..,.' •• ,1" by clunlng oIlQUipmllnl 01 ;fspoa" 01 w .. I ... s- -Storag'. s,,-c-.nt end Ditpo.ar udloo\. .,. " .. ol .poII. pr~ d_t:--. 'JI ~1a""""I" "..1.,..11. CrvYI'lod W,I., Ad"laory: 1.l-d"hbroprope!>l •• nown 10 moY.ltu-ov;Jh.oi.od undH clft.in condiliot>e h .. ItwI po~iallo ,.ee'" oi'VUhd ",.Ier " a ""1011 c.4 .grlr;vlur .. ",a. A,ppr.u.t;"'" In ." ......... " ••• ar. p.,"".bIa lind ground •• 1. II _ "'- IUrflOl. 01 .... h",lgeolo;l. COo./1d ,.11>1 ko QI'OUnd .... 111 Conlam.nalUl.

PHYSIC,'L OR CHEMICAL IIAZAHDS Fl.AJ,O.1AfIlE_ 00 no!: us •• POU •• pI. vt100. _., 1'1 •• 1 01 op.n "'noH. 00J not C>.,,« ..... 1<1 Co<>lalr>er.

/0

1··- DIRECTIONS FOR USE I lilt. lioIIlioII 01 rl<$ef ........ t.o un lhit p~1 n • "'._. incon, .. ..,.. w~h" ~bt-kng. 00 no! , .;>PIt Ih. ptodvcl n • "'., INoI .... conlac:l wo, •• ", 01 oIh., pI .. O ..... • ~1'Iar dr.d't 01 INl:'Uih : dfll. 0...,. plolaciad haOOla", '''''''' l>I in the .. rll d",.ing applic.,ion. r or an" Il'qy;'am.nl. a~c j 10 yOOM St.1. 01 Trill. cOI'I,,,IIhI'gtn<.y "'POIlllbll few p'.:o:ida I'9<'LIoliorl .

,

I I ! I, , '

" , , I

! I I

, I I

ENGINEERING CONTROLS REQUIREMENTS MECHANICAL Tl1.ANSfER SYSTE"": P.llonel pI'(oil(lJr.a ~.t .pao;..rotd tot 'OWad Contact AtIJr.ilia,- mull be _n by IIMI """, .. IOf 01 Ih. meth'Ne" lran.f., • .,,1_. The opel.l« of ..... 1JtIC.hanic:.lllln,f., ,y,lI"" ~.I hay •• v.ilab&llo tin! "'" """""acu ... ·• wrll ... hllrvclions lor ~.Iion of Ule .,.1..,. .end -.r,1 reed .I'd ~tMd ,« ha" eIopMMtI kI ..... 1n detai) Ih." ptOpIf O;llll'1ion atWI ""iRllAAIICe VII the .y • ...,.. WITH AU. OUUC AND WUft·ouuc: CONTA'HERS: I.3«Mcl'Op'opana and 1.3-dlchboproPlftl "ad will c"'bopicrWt """I be .,_,.~ ~ CON'IICIJ'It hotM. ~. and/or coupItIg •• urrrtlMtly lighI &0 P'""" ....... « oIhw pen._ rror. tonIing "" conlKl wib 1Qvi:11.3-dlc:hlcNoprop. ... ~ chlotopClh. 1. ,. hot". "*'tiI"nd Ian'" ""ad ., COl'lMCIioft .. iUt 1.3-cSichlo.~ aadlOI chkwvplcrtn ..... be awop,;al. tot "'. WIder IhI' P'"".,.1f\od 'tIC"""' ,0I'Idii0nt to bo __ .

2. ElI_I.1gN Q,ui" .hal b41IQ\IPped 'fItiII ~a"".' ao thai P9ato 10 ,Ight 0'. CM be.hut 01 In t'" 01 br""ag. and Ita.aget. 3. TlIoII'IIICMnic:.llrantIN 1 .. ,1.,,, ,"",I b4I ada~.1iI 10 ,.. ... nec. .... ry mauw .. """", ellhe PHI.cide b41;,g usad. 4. ShuI-oI dwIc: .. /IIUII be 1n11.1acI on til' •• i .nd d al hot .. and at al cSit.COI'\MICI poinIslo PfW'"'nI ..... ag. 01 1.34ithbropr~na andf« c~, ... pro6.Jcl wt-. I"" Itan.l" • ,lopped alld ho •• II rarnoved'« dilconn.ded. A dty coupler' thai ~ lIIirWril. petlicida It .. bg. ""'11 be rlll .. IIeod., the "isconn.tCt pont. 5. The p",uuta n ho", u.1'd 10 mo.... '.J-doehbopropa_ .n4'", cl-bropicm bt,ond. P*#1'P """, no! eJc~ Ih, m.:mulac:l"f.'·' rnuirn"m veul:l" 1pt'C1'""lion.

AGRICULTURAL USE REQIIIREMENTS U •• Itla pl'oduo::. oN! r. .eco.d.f'K' .... ~" .b "bfiog and '''i1h ~'. Work., Pro!a.c:I;or. SLand'rd. -40 CFR 170. Thit S1."d.rd cool''''a ,lquir .... 111, fOf the ?follCl;"'" d 'gric"lur.1 _"1ft 01'1 t..nnl. for •• t.. nun'tf"·I •• nd gff'.r!'>ou.e •• and h.ndlal'l f.II '"fieulut.1 pl'!ilieid .... II c<'nl .. inl J( <luirem,,"tl fOi tr.in~"I9. dl(OtlI.",in.IM. nol.r""liotI • .rod ."*'g'ncy ... !!.I.'K'. • .~o conl.in, tPIKfo: "'1!flK~C-"'1 and '~[lplicrna parta.,hg 10 ~ slallm.n!s ., Ihit "being .boul PlBOO.~ proII[IH' ~uiplNlnl., I ... lricllod.enlry i'Il_.II ..... d nolloc .. licn 10 _or)..". The rfoG,·;'''''''1111 In lhit too. only 'P»'1 10 101 .. ' oIlhis p'oclI(llh .. I." CoY'fe<! 11., Ill. \·/orIP.., Prol. 10" SLa;,dlld (loWS). ENTRY RESTIUCTION~ £"l.y (indudlllg .. rly ."Iry I~ woukl 01'*"'''. be ptIIfmilld "n6N 1M WPS) tip .ny ~on-oIlMlr tN.n • COlrICI'tlr.inad Ilnd equipped hlndlar' who • parfonMoag. ha~ I .... pe.miled' on lIlit r.be~-. PROHl8lTEO "OtJIItIe ,II" of .ppic.tiotI II1'II. n hounI aIIlt' appkaliOl1. ... a66i.00n. I IarJ" "' u,ad kif tIMI .ppic'lion.. non·handler entry It prohbled' ....... ,.rpt .ra ba~ ra~. HOTlFICATKJH: NoIry 'fIrCrl.I'''' of the lu*c.tion by "'linn; I~.m Of."" and bJ poIli.'l8 'umigl~ warnng .;gnt .! Inlllnc; .. 10 I,. .. ..t ., .... Th. a<gn, 1711,1.1 ba.ar' \he .kul .nd CI'OI,bon ... ymbol .nd ,La'.: (1) "OANGERlPElIGRO.- (2) "Iv .. under 'u",ig.,;or" 00 NOT ENTEM-IO ENTRE." (3) the doll. and ,_ 01 lufllioaliol\, (4' ' • .).Dichbopropln •• nd Ch\ort.picnr, f"mig."I. n u •••• nd (~) ............ dd"". and I.r.phona number of "" .~?Ii:.IOf. PO'tI"'" Iwmig.nI Wllnf'>g aign in,I.a<! nilhi' WP$ lign lot Ihis appr.c.li:wt. but kIIow .1 WPS '..c(uir_l. paftlN.g "> ~.-A, ~Ay • • Iz •• and hming 01 po.ling .nd l.moYIot, PPE fOrt ENTItY DURlPm HIE £NTRY .. IU:STRlCn:D PERIOD: PPE for "nlry lhal It p"IInlllCl by lhit i.aobtolonll • hlad in Ihtt 'lbJllcr. 10 Hum.n •• nd Oo",u!ic Ato;"",iI' 11C100t1 ('Ilhit "belong'

i .'--1 __ ._. __ . _______ .... _. _____ .

I I

I

II I

WARRANTY DISClAIMER NOTICE.: s.a... ... ".nt. lhaIlh. pt'Odl,lCl cMlOlml 10 "" clMlmk.al dllUipliQr; 01'1 lhe label and II '''.onabty II lot t.a JIU<?OS" .Ialad 011 IN lat*....toen Vlad n ICCor<il'K' wilh cJHc.1 .... Uf'IdW ~ c:ondiiooll of "", ~I ntr."'"" "oil -".nIt lICIt "'1 01'- -111ft of MLRDWflABrt.1TY Of fITNESS fOR A PAATICt.JlAA PURPO::'C "pin. 01' ~ ••• I&rIde "> h "". d Ihia produd eonIr.,... 10 r.ballnllnrclion., 01 ~ abnormal COI'>dIi:Ine. 01 \Indw C'OI'IdIIoIw not , • .,ona.,. '(WH ... bIt 10 ....... ancl bo.ryll ••• UIMI 1M ria .. ollll)' '\11:." " ... INHERENT RISKS OF USE: I II hponb"l0 ~I •• ~ riab 8"oclrtlad wih ,,~. d !hie producl Clop i'IJurt. Iaoc .. d /:IoIrformarc •• Of dhar uninteftded COO1Iequanc.. nwy 'nul to.cav .. of .uch fac:1ote II vs. d IhI producl COl'''"", 10 "bel and 1rI~ booIo ... mlruclione fnc:li.lcfrlCt eondiI:kwIa noIad 0t'I Iha label and labal btooIlla4, .\OCh 11 unI'YOI.bJa I"""",.\ur ... loi1 OOftdiIioftt.. ek). .bnornI" c:ond¥::ItIl (.ueh .. ..c".IroI. ,.nI,.. dlOl...hl 1oma6ooaa. """'ic:a.s,. pr_.nn 01 oIh.ar IVI.,"". I .... l'I.rmll 01 .ppCic:.liof1 .• , 0I ....... ;.;h .r. bayOl'lClIha COft!""oIl~CotI'Ip.,,)' Of 1M .. ..,. M.ueh '." •• h.1 be IIwmadby Bvy.,. LIMITATION OF REMEDIES: T ...... eM .... 1""'Iody lor bt ... Of d.rnagae fI."'no f_ .. II producl (nc:bfing cllrr. ba,ed 0f1 corlnod. ~Ig.nu. ,Iriel "'billy. ", oIh1t' legal IhlOP;"') •• haI be romled 10. II. I~ .• c ....... p."i •• "'*:Ion. OIl. 01 IhI' fOIo¥MQ: (1) R.IIII'd 01 PUi'C~" porit. p.id hI btryar", "1'" for ~I bO:JgM. 0I'.1j'} R.pk(.."..ni oI'l'IOUn! 01 producl used. Th. ct'Pnpanl.hal no! tA "-bit I", !r;>,. •• , Of da"'''g ••• ,~,,~ing "0<11 h"ndw.g Of us. 01""" pr-oducl ......... the «omp...., Is P"UP'PI" I'IOI"-.d oI''.ICh bu or 0."'110" r. "'r~ing .., no nil .h.1 Ih. Cotnpa")' be '-able for cOflla.:; .... nlili « wocodf'onl., d,m.oel 01 ~"'. Th. '-nn. 01 I!'I.I W.na,,'y D_tle""" .~e • .-.:1 IJ"." llrnbl.:on ol ~mld"" unrool b4. ~."-d' to, • ..., _AI_ ", ... tt..1 .'.lfOm.,,1 Of IIgf_ ... " ... , •. No .m~_ 01 .. '*". "';I"'" crill •• " .... .,.."y or 'ha .. ...., ill ."tt-.J1od 10 .... ,., 01 •• cM(f II,. I.r,..,. crll ... W.".nly O...C::. .... "" 01 Ih_l'n~.1o:lorI crI ~"'1 n .nl "'.n....,.

CA April, 1994

TRI-FORM 110/60 Pamphlet P,'lgc II

GENERAL INFORMATION

This pro<"' ]s • muIti·pvrpou r~ ftl'nigant lot ,..~ ".!menl 01 ,oil to ~onllol M .... tadn, $),lrlrohylan1O, WIIeYI'O!TIU,.wld uttar. wi bomti <til •• ,e, in (:raplind.

OctoN fumlglltiQn, IOiI Sllfnpl'"ng for the typl and nurnbw of pull ,",em Is recM'lfllerdod. In leld, where ptf:·lrell&menl lOA samples ~1e Phe pr.sence 01 high pop.kb 1ev,.1, 01 nemalodlls, a sueeeliU fumigation c.annol be tJ:POCled 10 .rack_1t ,,"lire poput.lionl. 1her.be, p»ol·ln!IIilmenl .am~ is rec::CII'I"IInehIie 10 ...etermiM !he nMd kit ~tional pel' lnanagt'rnenl ptaC~ •.

Co,siJt, Sbil. ~\JHuraI Erper\rnf"'".1 S~W\ 01 Exlendnn SatVIce lpedabt. k:JI' inlotmllion on ctt-..r pr.Kkes . xh I poil·l\arwosl jes!rucliorl nf crop resldut!s, weed conltol Of' other cu/!ur..' ptae.lieel, and us. 01 ,...~tode resistant crop vwUes trot 1"\.1)' a~ in reducng ClOP V"tI, from loil t.om. pnls.

GENERAL USE PRECAUTIONS

SoiJ fum":;iI!ion usin<] hS ro-od.x:1 .!'lou:.:! bI ctnduclod on!)' acc0r6ng !o d:r~tjO/l' i.'M con..l,t.OI"I$ 'lfu\e ,~e:.cn~ ill \./lis label;",g.

FOHMULATOH USE OF 1,3 [)1CUlOR.OPROr~NE: Labe/'Nj lor end usc prc<:hx:!s r.onl.1.nilg ',;)..(!ichlc. .>propc1"lO \hal.~ prepared and sold by 1«muI.11OfS m.:sl com,.!, w,:h al procaulicw\ary sblemenl$, 1.1:1."

prf!C.Ol:Jlion.. env'onnll"nUl tlazatd1. NlMlmog and prolGC.tN. ~ol ux:;u"efocnl~. ma1i'l'U<T1 a~pI'.A1icJ'I ralel and other e1po:!.u~ mil.igil!ion fllC,UUfe) ~pecifoed in It,,:!. pr·ld..xlla~!ing.

nrCm.;T'.M1NA11C-~' PREVENTION:· Th:!. pr1:ld:.Kt w,lI cOfltrol fJ(:!!$.l'l.01l a'c p'f:$.enl j·,1he s~ trcalmenllona 0iI1 t:me 01 f,UT';:lilt.v.,. lI .... n re' c.OIl::d p<:~I$. tha ...... ifltrodu::ed in:o $.oiI ilher f"m:s .. hon. To .. void tt:jr.fe~!.l:..on of ~calW toOl do nol Uie lnigaw, ....... ,eT. Ir<ln~p~n!5. scoo pOe-cu. CW" eqli; ..... cnllhit ~tw.l:d C3fT)' :10001 bomo roei\:!. \rom inre~lf"c1 L:ofld. Allo.d CO/\,.1.mi!"\ilton frOfn mo "ing ilileslcd soil onlo treated beds Uvoug!'l culLiIl:'Iion. InO\ emenl 01 soli In)IT'. be!ow the waled lone. d&.mpit.g conlNr.h.Jlcd \ale soil i" Irea\eod foelds :'flil sOlI ccnlaminalion from ..,...iwnenl 01 crop remains. Clear. e-Qu:pmenl carelu' ... before entering tre.."'Ited foe\ds.

nUlK TRANsrcns: Dry blNk 0( ~ry d",cO"l~1 cO'~;)'''''~"lo .~ required fOf 011 prooi..Icl nnsfe" iolltJl';ng bu:k c<)"bi ~rs IOf 1.}.G.~ .. ·O"cprope .... l 01 Sepl.mbC"r 30, 19"JJ.

Do ."lot us. conl"Inors. purr,.-$ or olhl" '''nsfer equlpmont m.d. of .. Iuminum. m3!l"8sium Dr Il'oeir 01110,.1. al under cerialn condition, I.J-didllom~m,.oeNl may be so~"n::I.,com:n.lv.lo .uc.h molal ••

[QdIPM(NT CL[At~·UP: (3«:u~e I.J.-oJoCtklrt>...,o;~flIt l'l c(')m)~r.ofll uro::Ier cef1.a1n ccndllion~. :lu,h .n appkatiOfl t'(""~nl ..... ,lh Iud o~. kero$.ene (Jf • lim.l", type 01 pl:~de\lm ~oIv('nl ''l\mrrl'.l\e!y ah", I.:'~. ~,~ pumps and ~Ie", with ~ rnolot oil Of a ::C% motor ,JIl,'II,M'! ",l,. ;, ,ure ~Iore itorVl!]. 00 nol u.o .... aler. D"po,e of rio' lIe br lflCoqnril:..oro ir '0 (,e'd j\.l~1 lrealed CIt b)' othM "f'P'O"Ied mean •. Never inlr.:.duce ri!"l,ale (, .. Jnu,ed ptooUCI i-o'o Surf3CO or Ul"lderground "" .. ter 'u;opte~.

CHEM:GATION: 00 no: arop!r 1.J.dic.h!oror.-ore .... e L ... rOUlJh anf Iype of Irrigation sy,lem

FF.RTIUTY INT[RACTIONS: fUrn1931iot1 mil)' tempcnn:y rai'e t!">e .evel 01 .rnrnconla ni!rt:ogen ~ soluble ,;\", in "" 'olI. Th" is most I,ke'y to occur ~n heav)' ral." of fen,lizer .nd f,Jn.iganl are ePl'ied \0 $oOrIs th31 are ether cokt. _I. Kid. CIt high Itt Of'garlil; mallet". To avcoM:l injury 10 cer1.wl oops tnch,dng ~ bleb. canolJ. cr.wn. r;)d,~he'. co'e Clop'. Ifoo)urne, (bell .... ·.). iellucl!'. onion'. arid '\11)'" bee'~. ,(>rtrf~e liS indicaled by 10001 \o@o'ISmotod •• lletlurnirplion.

To avoid amlTlCll"1Lo ir;u.y ot tl<t'ale sl.vvalion (Of both) tc crop' VU'tM'I ()f'I t'IlliO~ or911~ ,oil., do root us. 'ertol<le" cont;tinlng arntnr:)f'llun ,.11.. Un w'r fet1r',e", oonbining ni"trilles ulltila',er the crop Is _I .,\.abIo~hrd a'ld the sorl lemperal~ I, .t.roYe :-.5 dfog!'eu F.

I,.. mineta! soil,. do nol .pp1y ~ \ha,.. 2f) of the ni~ req..dNmenll 'rom fen,5:I'e", con~ IITlfT"IO"Iivm satl, un" !he ~rap Is _I e,\ilbljsNod an( !he

'oifemperal'lI'fllb .~a65~' F.

~,.. u'~ hll)t, ra\ .. ~ of the producl III ~ed by certain Slil" nursery fi!'9UIatir.lnS, r.mifw) )f hiql+;" acrd ,or1, befeoo-e tumigaliM rNI'I .timlJale nitn'catioo .aocI r~. IN' ~,~m)'" 01 arnmenla Io,i;ity. eerYin ~ery CfOf'S ~l.I(h as cws S~I..-.gs. ..~GFTaJJ "lop. C,.r~J .p .• sproxe. and ve<Jebbie crops :!.uch a~ c.aot.~er hay. sJ-.cr,r,on evidence of pt.o.s.rh)rus d.,roeio.-.c:,. fo1owing Iclmigal.on. To avoid u-.;~ pouiUe .rt.cl. 'I Is ,ugg,ntP.d ttI"l add ~,a1 ~~I. le,tillzer (lor'lIr flppIied) " ~ ~ W'herl!l ... pt'r\(''lCe iod'ic.a'~' a dcki~'rCy ..... ;.r occ:.rr.

APPLICATION DIRECTIONS APPLlCA110N TIMING: n>l, prOOuc:l can t.e appliod 11111.')," t'lIlfl of Ih8 ye.r whe,.. 'loil condilion. permit. CondMKl, th.al ~Iow r.lpOd dlNI \ion of Ih8 lurnigflnl as a gaa fvough 1M soill'lCllTRllly gill. best nI,uII,. Boc.au'. f"Ii. pmdu:1 does noI provide residual ttnlrci of soil resls. K ,houId ~ used a. a preplant application before ~ each crop. The loIIowing sci ternper1llur. and moi'ltur. concMionl should v:i~1 al lime of lre:.m.nL FaiJuN 10 ff'leel lhIIsa r.Cll""odOtion, rna,. resuU in unsa!iIfKIQry producl porlonnanco:

SOIL CONDITIONS: Sol 1anpt@!tH\, .1 the depth 01 applic~UorI musl be between co d~, F and 80 clt-gnte,"'. In areas whe ... 1he .oiItamperatur. In Ih& .pring may not teach 40 degree, F in lime b a~ application Of tN, produ::l prior 10 p.,..Iing, IiIw summer Of .any f~ r,-eatl"ne' i. ~1.i"'ldotd.. Soil axiam Itvoughcut !he dulred r,-eatmonl zone should be at 01".... fie penn_lit ~ poinI 10 .. !bow optimum di.p.n.ion 01 the fumigant. which move. a. a ga, ltvough the ulil.ir spac ••. The perm.lnr8n1 wilbrlg paN ... wiII' vonth sOrl lell\ll'W and Df90lInic rn.tler conlenL CoII~er lello..red surl. e.an bI fumig.led under c.ondrtiQr;, 01 higher .001 moI,hJr. \ha,.. f.nor le,u.d .001.; howevflt'. if the soil molt I .... Is kXI hir]h, bnigant movemenl ....... be reardod and effto..:tN~1S of the nn."lent wiI he reduce-d. Previous and/or leal elpe~",-e vriII'Ilhe sci 10 ~ Ite.aled «Ihe crop \0 be planlC!d C4N\ often serve as a guide I:) conditions \hat "";1 be .acceptable. ",.ou do nol know- how" b delenrWre the s~ moislure cOtllenl 01 ~".e ar .. 10 be tre3\ed, CQn$ull yOU" local e~len$.iorI );et"o"oeo Of Iooa cooset\'ation " ... ic.e s~iJ:isl or pcsl control adliisOf ( .. g consu'!anl) fot n~i,laf"ICe.

In general. no irrigation ,houId immediol\ol)'" proce-d. 'ubulI1if"lo] Of ftHTIi~aGon; howoever. when surface $011 mO'slur. coild.tOQ!'IS are 001 IIkel)' 10 pruvidtt an adeq..r.l!e ,nl aga:O,1 ~igi'ln' los" a very ~hl spfl~k:rr i'Tiga\ron 10 wet the lop I IG 2 in:.hes 01 'loil m3)' be I,.;ulul.

SOil PR[PARATION: The,eIi should be free of ClvolS. La~ clods can prev~nt etlccliv. :!.c.iI sec.1ing and red.x:o e!fc..:!i;enr,u 01 L'1:) ~odllCL P\;I~,

residues ,hould be tho-oughl,. rt'O'pOnIled inlo l',e :!.ci pOor 10 l'Nt.ment to evoo irr!erleriog "";Ih IIpp!rcill;::.n. UndccOO"'po'e.::f ~:iYll loalerial rnay harb.:" f)(!);ls "al .... ,3 no! be controMed by lumtalltOcn. Lit:le CW" no cn:op le,i...l" should t.ro pruent on the )oiI iuriace. ClOP le,kll1e L";\! is pr""lot:nlshould " r~'lt \0 f.o(:rmit 1"- soil lo be sealed e~eclille!r. Com;..ac1ed ~~ !.lyer. within ttoe desifed ire.lltmeni lone should be frat:luted bcfOl"fII Of durinq .ppoClltr.lI"I of .... lurnirJanl DNiation"om!he.bow COfIdi\ions mil)' fesult in UOSOllblac.1ory results.

PlACEf.4ENT OF FUMIC,\NT: This producl ma)'" be JiPPI;ed u eilNt 8 broaoc.asl (oYe~1') 01 fOW treatmenl \I rmal be pbc.cd .. I \c!nt 10 inches below Itoe flll.ll sOo1 'Irlac.e. When SOIl condO'ion ... IIeM', placement a minimum 01 12 nchel below tI're final sol surlace i. recOt1Vi"lended. ~epcr placement is "eCQrfVT1oerded when fumigating ,cillo be plan1ed 10 det-p-roo1od plants •• uch as pefeoniallrvil and nul c.'ops. OIloccnlrol deep)' dj~L";W.ed roosts.

APPLICATION METHODS AND EQUIPMENT OROhOCAST APPlIC,\ liON: U$.e c.hi~el (s"""nIt), No~!e (~W(!ep) plow 0(

pIow.soa. IIppr.clltion e<;u;roTre,..l For best resuP.1 -..+.en using u.:~el e-Qufvrreol us ..... pper·type •• orw.rd·,.....epl 'hanks. Noble poow ~pmenl is partic\laor1, vselul lot fa); fl)l1'lr';.liorl..mm the sO~ s\ll c<)'"\ll.ns sc.wne slardw-og UO<Mccmposed plallt mall!lrial. Subsoi:ing ~y bI necP.UIIr/ be!~ appk.ation as oescn"bed under ~oiI P,eparaliorle

• Ct.:ro~. appfrca60n equ~n( ....trich .ao- !he deepesl .. ppfic.alron flrod be:.1 sOlI seal under ellis\ir19 c.ondrticn.,

The fl..'f!lKJani ou~IIP<lCing varies wi!t\ Ihe Iype of IIPP~re.atiorl ~ipmcnl used. 'rMu;n:.cLbU~ a fumir;ant s~k spacing 01 12 10 2-4 inches is rKOfTIfTIerded. n .. oullelspachg for this ~i;omenl rna,. be up 10 1 "2 times thIi .pprQl\i:Jn deplh bvigeoetlllly lhould be e-QU3llo !he 1I;Jp.calion depth and s~ fICII.1c.eed """ soil·shalle,:,.,g colpabl5l)' of",.. chi:!.e!s. "The rnillIimum outlet lPKir9 shedd not e,cH'd 24 inches. \YtJb nbw·:ullc mrfprncQJ • 12.n:h outlel ,"pacing il reocomrnended. 00 not e_em.,.. outlel spacing of 18 irw;hel. ~~cmiantnl us. an outlel ,pacing of 9-12 Ioct-res .\orw;j .... s_ps.

e~I.pprlCalion ;an be m81M h ... Sllmtll d;~1.ion Of al OIl" 111"9_ 10 the di.ectior"l of tOW p.nling.

ROW APPLICATION: U,. chisel ~nptne""IO trutal1arw:!' of.oI wheN the crop h to be planted. I. ...... plant row. OM or troIIIO chinll per pant row II recOfl"ll'T"lef"de. 111 oeneral ......... 11 cne chisel I. use-d, 8ppIy pr'OCU;l -' .... low r.lles given.. When toW chi,f'li pet' pant ruw .... used, .paGe t-. chisel, {fumigllOl ouI\I!ls) I!I 10 1"2 Inchto. apat1 and Gl'llicM 1M ftoo.rt rales eqJa:tyo belwNtl tie two outlel~. P.egardleu or Ihe mI"T1bet 01 eN,.I. u.ed. N &mOUnI. 0: brIOgiini appo«f per HXXlleoel of 'II;inl fC"4O should remain !he s.".... With cet\IIin dMper rocleod crops luch as potatoes .nd ,ug. beelJ. ,....,.her" flow fa"'. fila)'" be r.::euary 10 ensure lOdeQ.late Irea!mel'll 01 It-. zone of .ei ¥o+!ore primary rClOl 9'"O"">'lh occurs; ~ct. I,.. no c.s. Iohould Ihe amou,..1 of fumigant applied p"" .Cnt escoad 'h. 031100s par ilCro r..lal lor bmadc.ull'"Oalmenl.

TIn-FORM 110/60 Pamphlet Page 5

I\PPLICA. liON ME fHODS AND EQUIPMENT (Continued):

To 1)1'''''''' .tted gennina1ion pnXIIon .. uuNd by impropef' aMd-io-.oi c('nlKlOf Impropof IHding depth, do rd pa..c. ..... .oct d; • .c,U)' CY« "furrow len by .... &ppIcaa ,hisei('}' When one (hi.",;. uHCI pet planl row, piKe .... seed about .. Inches 10 one ,ide 01 ~ chi, .. furnr.,o.I. 'Mwl two chisels .... u.od par plant row. ~ \he .IM':! otI',d trom IhII dIi .. e.lIrlr ....

SEALING THE SI')IL AFTER ArPlICATlON: lmmodia\el, allet U\i.tiI appblion oIlhe prod"'t. fie .oJ shtUd till -sealed" 10 prevenl f~~lloss and trI, .... th.:at an ell'ectIYe GOrIUf"oIr.Il.ion oIlumganl is mainlainod wiUWIthe ,Coller. period of " ... era! da)' ••

for Bw'dcas' Ire;!!""! fQ;,J l.nnjg~. seil~ c..an bit ~pl:iJ.hcd wilh equi;xnenl!hal w.a I.nilonnty rrU. the :.oii b II dcplh 01 3 10 4 i'v:hes b ellccwely It\iminale c.h',eI or plow traces ....tIM:h un.allow (lml esupe 01 the lumiganl A Iotndr::m di,c or .im1aI ~';pmenl may be u.ed lot ~1 P'JPOs •. To m,;u:im;HII .eal;ng, :Iok-ps ,~Id a:,o bfo bken 10 com;.x.11he soillurfac.e to f<JI"L'1ct" rcbrd the rale or fomC;;3n' 10" by 1~9 wilh iI ring rotcr, CU:~?3C"er CJI ro.'1ct" in canbin3~ion WIth Io:;';'go eqllipmenl Compaction of u... 30001 .urfoKfI alone ma), gNO Uie aptl'CatolflUl of adeq<,;a:e $ulng w;~"IOU1 etfK~ve:y

d;,rupling c.hi.el or p:OW trac.cs.,

[QLftM Tff!iJ!mcnl bmi:'II) Iho bc..:!s ;al ~ t;rnII of ;arp;WIiOl"l should t-.o accomplis.hed in;a manner \hal pI.a~.u !he fumiganl ;alleasl 11 inc~J Irom the n<!:!'l!sl soil!.,;r W1lerlact!. n.a dos.est sc;il'OIi!- interlace could be ITlG I..,~ lor m~!!'?O knil., OlW ... ..at>onS 0( L'>o to, 01 Iho bc-j b Ji.~1e mit! oiIpf)roc.a.tio ... ,. RON L-e.:o:tr\e"ls into pre10rrncd bcds. sh;)u\d toe sNled b)' d,sOJpting L"e (,tt:H"1 1I.1Ce u$il"O] ~C$S $ca:Crs. rio,., rc:c,," tJI' b)' te!o'm:n-;I L--.o beds and IO:;CM-ing ..... ,11 s.uc:.h cquipm(.'fll

Scarng can abo tlI!' impfO"'~ by :lP;.lY~"l9 fIOIl.~rfcnled r!.nlie rOm, s.u.:h as po:)"c!hylene. avCf the enllre are;a or b s:rips. Us.a 0: a f,:m Lo seal Ihe sOlI surlac.e docs not el':nioal. Uw. need to I!~te chisel Iraces pn.::lI' 10 ~ppiut.on 01 the pY:Iolic Ilion unless JimuI~s OIp;*:alion and tatp lay~ by the same pee. of equipment OCCUD and h ~ is a minimum 011 m.i t.'lit.k...

Proper soil (.()(l(I.\.ion.s at IhIi lime of appliuolion (s.ca Soil Prep.;uat.On :Iooclion) are mporlanl 10 ensure proper p&.cerrw:nt of fu~al\l, (~ P\ac.emenl 01 fUrnfg"" S.CCW'l) and 10 oblairt adequate :Ioe.~r.q. Prior ~ .hould to. a~1e 10 c~le clods ;and lhcI"~hI)' mix uop residues into the s:jl.

SOIL FUJ.AIGAII0N INTERVAl: lea .... ;-" s~ onQ.$lurbed aI'od unpbnled lor ;al "cast 7 days a'ler 3prtkation of 1M !"rr:'-"Wll A longer Und.s\lfbed iolf'NOJi Is rcquirt:-d Ii !he :Ioc.il bec.omes en ~ or '" •• n:i for deep-roole<! troo, sh.'"Ub and ..-me :..bnlillg s,IeS.

Mlor 1.'"00 1 .. ,,;'').,:I00''I interval. 10 plevent ;.ohylotoxicily, a:1ow ~ lurn;';a'lt 10 d,~~i~1rO (.om~~elely ~rOf. planting the uop. Under op:,m\··" ~01 con.:jl\.ion. lor diU'P-lt.on. 1 ~klor eac:h 10 ~.,:IooY~e is rec.omm~.Jcd. rOl' tr-.... l nul OIInd nu.~ery crop~ Oil ~a~1 ~e moolhs should e1ilp$-. be~n .. ut.~nl alX! ~oIanlOng. To ha\lcn a.nip.il1forl, e$~1!)' il he .... )' tolin, or low ternpt"'OllloRl au .... d...-ing !he treatment period, til the .oiI to !he deilLt, of 'um,,-OIInl .. ppkOItion. U$ •• ~re"k. d\i$el witt'ocM turning ~ .OiI ~ rl"duc. the pon,bilily 01 rcconlaminalOng the n,~led ~oi. O~SOpalj()n is usualy com~l. ~n u-.e (.<lor 01 !he pt"Oo."Iuct is no IangM evident OIl ~ .. ppka:ion depth. Seed 1'Il<'). be u~ed liS ill bioa$ uy 10 delermio& ,f the produtl is pre~enl in ltoe ~OiI al conc.enlroltion:lo su!f,,~nl \.) c.au~e pta'll i'lUry. Do nor p!anl ,\ L~ odo( of I1lo ~odvo.:l i~ prescnt WI .. '"lir"l ltoc! zone oIlun'1i;a:.oon.

/3

TRl-F01ZN 1;0/60 Pamphlet Page 6

APPROVED USES TRI·FORM 40/(.J) is a prcpfant 50~ fumigLlnt for con:.tol of soil-borne pests Souch as woreworms and nem~to.:les. and diseases caused by certain species of Rhizoclonia, Pylh.um, Fusanum, PhylDl'lJlhor.l, ilnd Vct1icdlium. TRI.FORM 40/fll is to be used;:1 soil to be pla.nted to the crops lisk'\l bdow.

Crop

APPLICATION RATES TRI-FORM 40/60

type (:If Tr •• t.a.nt SoH Typ.

l!iru •• el Splioute Ov.£'-al1 "1neral Cucu.ber. ,Iro_dc •• t» Huck Qr peat Eg'ilphnt Floral era,. I1IIlon_ Hur •• 1:"}' Crop.

Onlona O".r-all (IIra.dc •• t:)

Plant: and S •• d •• 15. Ove.:--al1 "inaTal lI.di.h •• (llro.d.;:~.t) Klick or peat:

Str .... b.rrl •• Oller-all Hinera \ (Iraedc.at)

Sweet: rote toea Over-all '_I"o.dc.st.)

To ... toe. OVIPI"-.ll .. '!in~ .... l (9ro.dc;!lst.) I"!uc:~ ., f'e.at:

1'107£:

C,dlona 'er Af: ... 1

11.9 t.o 36.3 58.2: to 87.3

51.0 to 58 ••

19.1 t., :36.3 5B.:Z to 81.3

58.2: to !::'.l

~l.O '0 ~fI .•

21.'1 to 360.3 515.2 to 81.3

1, U.f! blo:;h~.t. r .. t.. on h~avy 11;011. 5UC~ a. c;;la1 01" .uc;;k a"d lowest. rat.. on 11qht •• ndy .011 ••

2. U •• bighe5t c.at. lor ~)'.t-!o ..... lr'9 ne;.a':;o<!e • .and Vt'ct.i<.:ill1u:. wilt cOl"ltrol.

3, Ro,", or bed U •••• ount 01'1 t.h. ro,",

appllcatlo~s may b .... de at the bro.~ca.t. rates. but. us.d ,,111 t.>. proportIonately les .. rer acr. dep(!ntJlng .... cl"i .,,4 ,..ldt.h ot t.reat.aer.t In the 1"001 01" bed.

13 I ., '7 . ~-.

office of prevention, pesticides and ......1994/12/16 · cab'tp por!onn any...

Documents