of ecn/67531/metadc... · i3 whc-sd-wm-dp-191, rev. 1 tank 241-u-106, cores 747 and 148, analytical...

ENGINEERING CHANGE NOTICE PW. 1 Of 2 ROi.

ECN

2. ECW Category 3. Originator's Wame, Organization, MSIN, 4. USP Required? 5. Date tmark one) and TeLehone Wo.

Supplements\ t1 Direct Revision [X I Change ECN [I Temporary t1 Standby I1 Supersedure [I CanceUVoid [I

12% Modification Uork

Franciska H. Steen, Production [ I Y=S [ X I NO 09/25/96 Planning and Control, T6-06, 372-2495 6. Project Title/Wo./Uork Order No. 7. BLdg./Sys./Fac. No. a. Approval Designator

Q Tank 241-U-106 241-U-106 9. DocMent Numbers Changed by this ECW IO. Related ECY Yocs). 11. Related PO Wo.

(incLudes sheet no. and rev.) WHC-SD-WM-DP-191, Rev. 0 N /A N /A

12b. Uork Package 12c. Modification Uork Complete 12d. Restored to Original Condi- NO. tion [ T e o ~ . OP Standbv ECN onlvl . .

[ ] Yes (fiLL out BLk. N/A N/A N / A 12b)

12c, 12d) Design AuthoritylCog. Engineer

Signature & Date Design Authority/cog. Engineer

Signature h Date [ X I No (NA Elks. 12b.

138. Description of change 13b. Design Basetine Document? [1 Yes [ X I wo

14a. Justification (mark one) Criteria Change [ X I Design Improvement [ I Environmental [ ] Facility Deactivation [ ]

14b. Justification DetaiLs As-Found [I Facilitate const [ ] Const. Error/omission [ ] Design Error/Omlssion [ I This ECN will assist in the completion of the documentation process for this document.

See attached distribution.

A-7900-013-2 (05/96) GET095

A.7900.013-1

1. ECN (u$e no. f r o m pg. 1) ENGINEERING CHANGE NOTICE o f 2 ECN-633324

16. Des ign 17. Cost Impact 18. Schedu le Impact (days) V e r i f i c a t i o n R e q u i r e d

[ I Yes A d d i t i o n a l [ I $ A d d i t i o n a l [ I $ Improvement [ ] [ X I No s a v i n g s [ I $ Sav ings [ I 5 D e l a y [ I t h a t w i l l b e e f f e c t e d b y t h e change d e s c r i b e d in Block 13.

ENGINEERING CONSTRUCTION

19. Change Impact Review: I n d i c a t e t h e r e l a t e d documents ( o t h e r t h a n t h e e n g i n e e r i n g documents i d e n t i f i e d o n S i d e 1) E n t e r t h e a f f e c t e d document number i n Black 20.

r i Tnnk Calibration Manual r i Ssismiclstmrs Analysis r i SDDIDD _ - [ I [ I 11 [ I 11 [ I [ I [ I [ I [ I [ I [ I [ I [ I

Environmental Permit r i

Functional Design Criteria

Operating Specification

Criticality Specification

Conceptual Design Report

Equipment Spes.

Const. Spec.

Procurement Spec.

Vendor information

OM Manual

FSAFIJSAFI

Safety Equipment List

Radiation Work Permit

Environmental Impact Statement

Envlranmentai Report

StresdDesign Report

Interface Control Drawing

Calibration Pmooedurs

Installation Procsdura

Maintenance Procedure

Engineering Procedure

Operotin. instruction

Operating Procedure

Operational Safety Requirement

IEFD Drawing

Cell Arrangement Drawing

Essential Material Specification

Fac. Proc. Samp. Schedule

Inspection man

Inventow Adjustment Request

L J

[ I [ I [ I [ I [ I [ I [ I [ I [ I [ I [ I [ I [ I [ I

Health Physics Procedure

Spares Multiple Unit Listing

Test ProoedureilSpecific.tion

Component Index

ASME Coded Item

Human Factat Consideration

Computer Software

Electric Circuit Schedule

icRS Procsduro

Process Control MsnuaVman

Rooesf Flow Chart

Purchase Requisition

Tickler Fils

r 7 L J L J L J

20. Other A f f e c t e d Documents: (NOTE: Documents l i s t e d be low w i l l n o t b e r e v i s e d by t h i s ECN.) S i g n a t u r e s be low i n d i c a t e t h a t t h e s i g n i n g o r g a n i z a t i o n has been n o t i f i e d of o t h e r a f f e c t e d documents L i s t e d below.

Document Number R e v i s i o n I Document Number lRev is ion Document Number lRev is ion

I 21. Approva ls

S i g n a t u r e D a t e D e s i g n A u t h o r i t y

Cog. Eng. F.H. S t e e n

Cog. Mgr. C.T. N a r q u i s

QA T.L. Tung 7pL- % S a f e t y

Env i ron .

o t h e r

-&kif!%

s i g n a t u r e Des ign Agent

PE

QA

S a f e t y

D e s i g n

Env i ron.

o t h e r

D a t e

I DEPARTMEHT OF

s i g n a t u r e o r a C o n t r o l Number t h a t t r a c k s t h e A p p r o v a l S i g n a t u r e

I ADDITIONAL

I

A-7900-015-3 (05/96) GEF096

i3 WHC-SD-WM-DP-191, Rev. 1

Tank 241-U-106, Cores 747 and 148, Analytical Results for the Final Report

Franc iska H. Steen Westinghouse Hanford Company, Richland, WA 99352 U.S. Department o f Energy Contract DE-AC06-87RL10930

Org Code: 75725 Charge Code: MD378 B&R Code: EW 3120074 To ta l Pages: /35z

Key Words: Tank 241-U-106, Tank U-106, U-106, U Farm, Core 147, Core 148, A n a l y t i c a l Resul ts, F ina l Report, F i n a l

Abs t rac t : N/A

EDT/ECN: ECN-633324 UC: 2070

TRADEMARK DISCLAIMER. Reference h e r e i n t o any s p e c i f i c comnerc ia l p r o d u c t p rocess o r s e r v i c e b y t r a d e name, trademark, manufac turer , o r o therw ise , does n o t n e c e s s a r i l y c w k t i t u t e & i m p l y i t s endorsement. recomnendat ion, or f a v o r i n a hv t h e U n i t e d S t a t e s Government o r any agency t h e r e o f or i t s c o n t r a c t o r s o r s u b c o n t r a c t o r s .

P r i n t e d i n t h e U n i t e d S t a t e s of America. To o b t a i n c o p i e s o f t h i s document c o n t a c t . UHCfBcS Document C o n t r o l Serv ices , P.O. Box 1970, R a i L s t o p H6-08, R i c h l a n d UA 99352: Phone (609) 372-2420; Fax (509) 376-6989.

Date '

Approved for Public Release

A-6400-075 (10/95> GEF321

(1) Docwent Number RECORD OF REVISION

WHC-SD-WM-DP-191 Page 1 (2) Title Tank 241-U-106, Cores 147 and 148, Analyt ical Resul ts f o r t h e Final Report

Authoriied for Release (5) C q . Engr. I ( 6 ) cog. Hgr. Date

(3) Revision (4) Description of Change - Replace, Add, and Delete Pages

I I I

A-7520-005 (08/91) UEF168

Westinghouse Hanford Company

P.O. Box 1970 Richland, WA 99352

WHC-SD-WM-DP-191, REV. 1

ANALYTICAL SERVICES

TANK 241-U-106. CORES 147 AND 148 ANALYTICAL RESULTS FOR THE FINAL REPORT

Project Coordinator: FRANCISKA H. STEEN

Prepared for the U.S. Department of Energy Office of Environmental Restoration

and Waste Management

by

222-S Laboratory Westinghouse Hanford Company

Box 1970 Richland, Washington

0. IMO-076 Hanford Operations and Engineering Contractor for the US Department of Energy


THIS PAGE WAS INTENTIONALLY LEFT BLANK

ii

WHC.SD.WM.DP.191. REV 1 .

TABLE OF CONTENTS

Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

U-106 Sample Breakdown (Attachment 1) . . . . . . . . . . . . . . . . . . . 13

Progagating Reactive System Screening Tool . . . . . . . . . . . . . . . . 27

Sample Data Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65

Photographs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111

U-106 Extrusion Reports . . . . . . . . . . . . . . . . . . . . . . . . . 123

Sample Hand1 ing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136

Extrusion Worklist # 8675 Extrusion Worklist # 8676 Extrusion Worklist # 8677 Extrusion Worklist # 8678 Extrusion Worklist # 8679 Extrusion Worklist # 8680 Extrusion Worklist # 8688 Extrusion Worklist # 8942 Extrusion Worklist # 8943

(2811) . . . . . . . . . . . . . . . . . 138 (2812) . . . . . . . . . . . . . . . . . 139 (2813) . . . . . . . . . . . . . . . . . 140 (2818) . . . . . . . . . . . . . . . . . 141 (2919) . . . . . . . . . . . . . . . . . 142 (2820) . . . . . . . . . . . . . . . . . 143 (2824) . . . . . . . . . . . . . . . . . 144 (2857) . . . . . . . . . . . . . . . . . 145 (2858) . . . . . . . . . . . . . . . . . 146

Sample Preparations . . . . . . . . . . . . . . . . . . . . . . . . . . . 147

Fusion Digestion Worklist # 9468 (3079. 3080. 3083) . . . . . . . 149 Fusion Digestion Worklist # 9469 (3081. 3084. 3082. 3085) . . . . 150 Fusion Digestion Worklist # 9474 (3026. 3029. 3030) . . . . . . . 152 Fusion Digestion Worklist # 9475 (3031. 3032. 3033) . . . . . . . 153 Fusion Digestion Worklist # 9476 (3034. 3035) . . . . . . . . . . 154 Fusion Digestion Worklist # 10956 (3878. 3884) . . . . . . . . . . 155

Water Digestion Worklist # 9471 (3093. 3094) . . . . . . . . . . . 156 Water Digestion Worklist # 9472 (3095. 3096) . . . . . . . . . . . 157 Water Digestion Worklist # 9473 (3097. 3098. 3099) . . . . . . . . 158 Water Digestion Worklist # 9479 (3028. 3043) . . . . . . . . . . . 159 Water Digestion Worklist # 9480 (3044. 3045) . . . . . . . . . . . 160 Water Digestion Worklist # 9481 (3046. 3047) . . . . . . . . . . . 161 Water Digestion Worklist # 9482 (3048. 3049) . . . . . . . . . . . 162 . . . 163

Acid Digestion Worklist # 9470

Water Digestion Worklist # 10958 (3879. 3880. 3885. 3886)

Acid Digestion Worklist # 9477 (3027. 3036. 3037. 3038) . . . . . 168 Acid Digestion Worklist # 9478 (3039. 3040. 3041. 3042) . . . . . 170 Acid Digestion Worklist # 10957 (3887. 3888) . . . . . . . . . . . 172

(3086. 3087. 3088. 3089. 3090. 3091. 3092) . . . . . . . . . . . . . . 165

i i i

WHC.SD.WM.DP.191, REV 1 . TABLE OF CONTENTS (Continued)

Bulk Density Worklists . . . . . . . . . . . . . . . . . . . . . . . . . 173

Inorganic Analyses . . . . . . . . . . . . . . . . . . . . . . . . . . . 188

Differential Scanning Calorimetry (DSC) DSC Worklist # 11662 (3876. 3882) . . . . . . . . . . . . . . . . . 190 DSC Worklist # 12418 (3876. 3882) . . . . . . . . . . . . . . . . . 197 Thermogravimetric Analysis (TGA) TGA Worklist # 11655 (3876. 3882) . . . . . . . . . . . . . . . . . 198 Specific Gravity Analysis (SpG) SpG Worklist # 10598 (3063. 3064) . . . . . . . . . . . . . . . . . 205 Cyanide Analysis (CN) CN Worklist # 11327 (3071) . . . . . . . . . . . . . . . . . . . . 213 CN Worklist # 11709 (3066. 3067) . . . . . . . . . . . . . . . . 217.1 CN Worklist # 11711 (3070. 3068. 3069) . . . . . . . . . . . . . . 218 CN Worklist # 12653 (3010. 3011. 3012. 3013) . . . . . . . . . . . 230 CN Worklist # 12957 (3014. 3015) . . . . . . . . . . . . . . . . . 244 CN Worklist # 12958 (3016. 3065) . . . . . . . . . . . . . . . . . 256 Ion Chromatographic Analysis (IC) IC IC IC IC

Worklist # 10597 (3063. 3064) Worklist # 10803 (2860. 3051) Worklist # 10938 (3028. 3043) Worklist # 10939 (3044. 3045)

IC Worklist # 10940 (3046. 3047) IC Worklist # 10941 (3093. 3094) IC Worklist # 10942 (3096. 3095) IC Worklist # 10943 (3099. 3097. IC Worklist # 12204 (3885) . . IC Worklist # 12421 (3879) . . IC Worklist # 12474 (3048. 3049)

. . . . . . . . . . . . . . . . . 269 . . . . . . . . . . . . . . . . . 281 . . . . . . . . . . . . . . . . . 292 . . . . . . . . . . . . . . . . . 303 . . . . . . . . . . . . . . . . . 315 . . . . . . . . . . . . . . . . . 327 . . . . . . . . . . . . . . . . . 339 3098) . . . . . . . . . . . . . . 351 . . . . . . . . . . . . . . . . . . 365 . . . . . . . . . . . . . . . . . . 375 . . . . . . . . . . . . . . . . . 386

Inductively Coup1 ed P1 asma Spectroscopy Analysis (ICP) ICP Worklist # 10693 (3063. 3064) . . . . . . . . . . . . . . . . . 398 . . . . . . . . . . . . . . ICP Worklist # 10857 12860 30511 47 1 ICP ICP ICP ICP ICP ICP

Workl Workl Workl Workl Workl Workl

ist # ist # ist # ist # ist # ist #

10928 10929 10948 10949 .....

10950 11037

(3079 (3081. (3086. (3027. (3029. (3039.

~~- 3080; 3082. 3087. 3036. 3030) 3040.

3083) 3084. 3088. 3037. . . . 3041.

. . . 3085) 3089. 3038) . . . 3042)

. . . . . . . . . 3090. . . . . . . . . .

. . . . . . . . . 3091. . . . . . . . . .

. . . . . . . . . . . . . . . 3092) . . . . . . . . . . . . . . . . .

... 442 449 458 469 478 485

ICP Worklist # 11039 (3031. 3032. 3033) . . . . . . . . . . . . . . 494 ICP Worklist # 11042 (3034. 3035) . . . . . . . . . . . . . . . . . 501 ICP Worklist # 11838 (3026) . . . . . . . . . . . . . . . . . . . . 508

i v

WHC.SD.WM.DP.191, REV 1 . TABLE OF CONTENTS (Continued)

Uranium Analysis (U) U Worklist # 12211 (3878. 3884) . . . . . . . . . . . . . . . . . . 1129

Part I1

Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1

U-106 Sample Breakdown (Attachment 1) . . . . . . . . . . . . . . . 2-9

Sample Data Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-21

Chain of Custody Forms . . . . . . . . . . . . . . . . . . . . . . . . . 2-33

Inorganic Analyses . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-45

45-Day Safety Screening Results for Tank 241.U.106, Push Mode Cores 147 and 148

Differential Scanning Calorimetry (DSC) DSC Worklist # 10567 (3067. 3070) . . . . . . . . . DSC Worklist # 10568 (3065. 3066) . . . . . . . . . DSC Worklist # 10569 (3063. 3064) . . . . . . . . . DSC Worklist # 10570 (3068. 3069) . . . . . . . . . DSC Worklist # 10572 (3071) . . . . . . . . . . . . DSC Worklist # 10765 (3063. 3064. 3071) . . . . . . DSC Worklist # 10772 (2860. 3051) . . . . . . . . . DSC Worklist # 10774 (3011) . . . . . . . . . . . . DSC Worklist # 10776 (3012. 3013) . . . . . . . . . DSC Worklist # 10778 (3014. 3015) . . . . . . . . . DSC Worklist # 10843 (3010) . . . . . . . . . . . . DSC Worklist # 10913 (3067. 3068. 3069. 3070. 3011) DSC Worklist # 10916 (2860. 3051. 3012. 3013. 3014.

3017) . . . . . . . . . . . . DSC Worklist # 10930 (3010. 3065. 3066) . . . . . .

DSC Worklist # 10780 (3016. 3017) . . . . . . . . .

. . . . . . . . 2-47 . . . . . . . . 2-55 . . . . . . . . 2-61 . . . . . . . . 2-67 . . . . . . . . 2-73 . . . . . . . . 2-77 . . . . . . . . 2-79 . . . . . . . . 2-87 . . . . . . . . 2-92 . . . . . . . . 2-98 . . . . . . . 2-105 . . . . . . . 2-111 . . . . . . . 2-115 3015. 3016. . . . . . . . 2-116 . . . . . . . 2-119

Thermogravimetric Analysis (TGA) TGA Worklist # 10574 (3067. 3070) TGA Worklist # 10575 (3065. 3066) TGA Worklist # 10576 (3063. 3064) TGA Worklist # 10577 (3068. 3069)

TGA Worklist # 10773 (2860. 3051) TGA Worklist # 10775 (3010. 3011) TGA Worklist # 10777 (3012. 3013) TGA Worklist # 10779 (3014. 3015) TGA Worklist # 10781 (3016. 3017)

TGA Worklist # 10578 (3071) . . .

. . . . . . . . . . . . . . . . 2.121 . . . . . . . . . . . . . . . . 2-129 . . . . . . . . . . . . . . . . 2-135 . . . . . . . . . . . . . . . . 2-141 . . . . . . . . . . . . . . . . 2-149 . . . . . . . . . . . . . . . . 2-153 . . . . . . . . . . . . . . . . 2-160 . . . . . . . . . . . . . . . . 2-168 . . . . . . . . . . . . . . . . 2-178 . . . . . . . . . . . . . . . . 2-181

vi

WHC-SD-WM-DP-191, REV 1. TABLE OF CONTENTS (Continued)

This Document consists of two sections.

Part I consists of pages 1 through 1141, Pages 2, 14, 28, 66, 112, 123, 137, 148, 174, 189, 788, 789, 790, 791, 792, 793, 794, 795, 796, and 797 were intenetinally left blank.

Part I1 consists of pages 2-1 through 2-186 and pages 2-2, 2-10, 2-22, 2-34, and 2-46 were intentionally left blank.

TRADEMARKS:

Perkin-Elmer is a Registered Trademark of Research and Manufacturing Company, Inc. Mettler is a Registered Trademark of Mettler Electronics

vi i


NARRATIVE

1



2


TANK 241-U-106, CORES 107 AND 148, ANALYTICAL RESULTS FOR THE FINAL REPORT

This document is the final report deliverable for tank 241-U-1OG push mode core segments collected between May 8,1996 and May 10,1996 and received by the 222-S Laboratory between May 14, 1996 and May 16,1996. The segments were subsampled and analyzed in accordance with the Tank 241-U-106 Push Mode Core Sampling anddnalpis Plan (TSAF’) (Brown, T.M., 199G), the Historical Model Evaluation Data Requirements (Historical DQO) (Simpson, et al., 1995), Data Quality Objective to Support Resolution of the Organic Complexant Safety Issue (Organic DQO) (Turner, et al., 1995) and the Safety Screening Data Quality Objective (DQO) (Dukelow, et al., 1995). The analytical results are included in Table 1.

w ~ l e Handling

Attachment 1 is a cross reference to relate the tank farm identification numbers to the 222-S Laboratory LABCORE/LIMS sample numbers. These diagrams show the make-up of the core composites and secondary analyses requested. These diagrams and any changes made supersede the diagrams presented in Part 11 of this document. Sample handling and appearance information for the subsegments can be found in Part I1 of this document.

Eighteen of the nineteen samples submitted for DSC analysis exceeded the notification limit of 480 Jouledgram (dry weight basis) as stated in the Safety Screening DQO (Dukelow, et al., 1995). Cyanide analysis was requested for these samples, the results are included in this report. Reactive Screening System Tool (RSST) analysis was requested for the sample exhibiting the highest exotherm core 147 segment 5 lower half (S9GT004013). results are included in this document.

Two core composites were made, one for each core: 147 and 148. The core composite worksheets are included in this document.

No field blank was provided to the 222-S Laboratory

WHC-SD-WM-DP-191. REV. 1

t s Summary

The data summary report (Table 1) compiles the analytical results that comply with all applicable DQOs.

Inow-

Differential Scanning Calorimety (DSC)

The DSC analyses were performed on the core composite subsamples. The analyses were performed in duplicate on direct subsamples. The exothermic energy based on dry weight of subsample was calculated for all subsamples. The average of the TGA results for each subsample was used in the dry weight correction for that subsample. The results for all DSC analyses and the raw data for the core composite subsamples are included in this report.

The core composite subsamples exceeded the notification limit of 480 Joules/gram (dry weight basis). Appropriate notifications were made. The standard recoveries and RPDs for this analysis were within the required limits.

Thermogravimetric Analysis (TGA)

The TGA analyses were performed on the core composite subsamples. The analyses were performed in duplicate on direct subsamples. Typically results were determined by summing the weight loss steps which occurred below 200°C; weight loss steps above this were not used to determine the result. The results for all TGA analyses and the raw data for the core composite subsamples are included in this report.

The standard recoveries and RPDs for this analysis were within the required limits.

Sp.G.-Specific Gravity/Bulk Density

Specific gravity analyses were performed on the liquid subsamples. The results are provided in Table 1. The raw data are included in this revision. There are no exceptions to the quality control parameters stated in the TSAP for these samples.

Bulk density analyses were performed on direct solid subsamples. The results and raw data for all subsamples are reported in this revision. There are no exceptions to the quality control parameters stated in the TSAP for these samples.

- 4 -


Inductively Coupled Plasma Spectrophotometry (ICP)

The liquid subsamples were prepared for analysis by an acid adjustment of the direct subsample. This is indicated by a "D" in the aliquot class (A#) column in Table 1. Solid subsamples were prepared for analysis by performing an acid digest as indicated by an "A" in the A# column in Table 1 and fusion preparation as indicated by "F" in the A# column in Table 1.

The QC for all analytes were reviewed for this report. High WDs were reported for several analytes and were the result of sample inhomogeneity. Reruns were not requested. Table 2 shows a comparison o f the result of the sample with that of the serial dilution for those required analytes that had a spike recovery outside the 75% - 125% range as set by the Quality Assurance Plan for the 222-S Laboratories (WHC-SD-CP-QAPP-016). Serial dilutions are performed by diluting a sample fivefold. The results from the serial dilution may be found in the raw data and are signified by an "-L" at the end of the sample number. For acceptable performance the percent difference between the serial dilution and the undiluted results must be must be 110 percent. Five samples had serial dilutions greater than ten percent. This inaccuracy can be attributed to the low concentration of the analyte with respect to the detection limit.

Occasional preparation blanks showed results above the detection level. The levels of these contaminants in the preparation blanks are inconsequential when compared to the result for the sample and do not impact sample data quality. The standard recoveries for thus analysis were within the required limits.

- 5 -


Ion Chromatography (IC)

The IC analysis was performed on direct subsamples of liquid samples, as indicated by a blank in the A# column in Table 1. The solid subsamples were prepared for analyses by performing a water digest. This is indicated with a "W" in the A# column in Table 1.

High RPDs were reported for three of the subsamples submitted for analysis. These high RPDs were attributed to sample inhomogeneity. Additional reruns would not significantly improve the results due to the difficulty in obtaining representative samples of the material. Six subsamples had spike recoveries outside of the 75% to 125% range on several of the anions. No reruns were requested.

Occasional preparation blanks for chloride and nitrate showed results above the detection level. The levels of these analytes in the preparation blank are inconsequential when compared to the result for the sample. This contamination does not impact sample data quality. The standard recoveries for this analysis were within the required limits.

TICiTOC - Total Inorganic/Organic Carbon Persulfate

Total Inorganic Carbon (TIC) and Total Organic Carbon (TOC) by persulfate/coulometry analyses were performed in duplicate on direct subsamples. Low concentrations of TIC and TOC were noted in some preparation blanks, however the levels of contamination are inconsequential when compared to the result of the sample and do not impact sample data quality. A high RPDs was reported for one subsample. This was due to sample inhomogeneity. A rerun was not requested. The standard recoveries and spike recoveries for these analyses were within the required limits.

TOC -Total Organic Carbon By Furnace Oxidation

TOC by furnace oxidation analysis was requested as a secondary analysis for the samples that exceeded the DSC notification limits and the TOC by persulfate/coulometry did not account for the high exotherms. This analysis was performed on the four direct liquid subsamples. Low concentrations of TOC were noted in some preparation blanks, however the level is inconsequential when compared to the result of the sample. This contamination does not impact sample data quality. The standard recoveries, spike recoveries and RPDs for this analysis were within the required limits.

CN - Cyanide

Cyanide was requested as a secondary analysis due to the high energetics in the tank samples.

-1-


With the subsequent changes to the Organic DQO, the cyanide analyses would not have been required therefore the results are presented in this report as "opportunistic analyses". The cyanide by water method is for the determination of total cyanide in samples that contain only' soluble cyanide compounds. The cyanide results ranged from less than 4.23 crglg to 35.1 pg/g. The standard recoveries. spike recoveries and RPDs for these analyses were within the required limits.

Radionuc-

AT - Total Alpha

Total alpha activity (AT) analysis was performed on the solid core composite subsamples. The samples were prepared for analysis by performing a fusion digest in duplicate. The fusion preparation is indicated with an "F" in the A# column in Table 1. The results and the raw data for all subsamples are included in this revision. A high RPD was reported for sample 396TOO3884 and was due to sample inhomogeneity. No rerun was requested. The standard recoveries and spike recoveries for this analysis were within the required limits.

TB -Total Beta

Total beta activity (TB) was performed on the solid core composite subsamples. The samples were prepared for analysis by performing a fusion digest in duplicate. The fusion preparation is indicated with an "F" in A# column in Table 1. A high RPD was reported for sample 9967003884 and was due to sample inhomogeneity. No rerun was requested. The standard recoveries and spike recoveries for this analysis were within the required limits.

'"Sr - Strontium 90

Y"Sr analysis was performed on the solid core composite subsamples. The samples were prepared for analysis by performing a fusion digest in duplicate. The fusion preparation is indicated with an "F" in the A# column in Table 1. The preparation blanks showed results for strontium-90 slightly above the detection level. The levels in the preparation blanks are inconsequential when compared to the results for the samples. These contaminants do not impact sample data quality. A high RPD was reported for sample 896TOO3884 and was due to sample inhomogeneity. No rerun was requested. The standard recoveries for this analysis were within the required limits.

GEA - Gamma Energy Analysis

GEA analysis was performed on the solid subsamples. The samples were prepared for analysis by performing a fusion digest in duplicate. The fusion preparation is indicated with an "F" in the

- 8 -


A# column in Table 1.

Only the QC for required analytes (I3’Cs) were considered in this report. Other “opportunistic” analytes are included but were not reviewed for QC. High RPDs were reported for samples S96TO03079 and 396T003884. This was due to sample inhomogeneity and no rerun were requested. The standard recoveries for this analysis were within the required limits.

Actual detection limits for GEA analytes are not currently available. The latest GEA soflware. does not report a minimum detectable activity (MDA). If an analyte is reported as “less than”, the value reported is the detection limit.

U -Total Uranium

Uranium analysis was performed on the core composite subsamples. The samples were prepared for analysis by performing a fusion digest in duplicate. The fusion preparation is indicated with an “F” in the A# column in Table 1. The standard recoveries, spike recoveries and RPDs for this analysis were within the required limits.

- 9 -


Procrdllres

Table 3 lists the analytical procedures used for performing the sample analyses. Abbreviations Cor analyses are defined in the table notes.

Table 3. Analytical Procedures

Sample Portion

Preparution Procedure +

Analysis Procedure

Analysis + NIA SolidLiquid LA-514-114Rev. C-l LA-514-113 Rev. C-1

SolidLiquid NIA LA-514-114 Rev. C-l LA-560-112 Rev. B-1

I Bulk Density Solid NIA LO-160-103 Rev. B-0

Liquid NIA LA-5 10- I 12 Rev. C-3

NIA LA-695-102 Rev. A 4 LA-695-103 Rev. A-0

Liquid Solid

Solid Liquid

LA-504-101 Rev. E-0 NIA LA-533-105 Rev. D-1

Solid

Liquid

LA-505-159 Rev. D-0 LA-549-101 Rev. F-0

LA-504-101 Rev. E-0 NIA

LA-505-151 Rev. D-3 LA-505-161 Rev. B-1

~

Liquid Solid

NIA LA-342-100 Rev. D-0

Liquid NIA LA-344-105 Rev. D-1

- 10


AT/TB

C EA

'"Sr

U

Solid LA-549-101 Rev. F-0 LA-508-101 Rev. D-2

Solid LA-549-101 Rev. F-O LA-548-121 Rev. E-0

Solid LA-549-141 Rev. F-0 LA-220-IO1 Rev. D-1

Solid LA-549-101 Rev. F-0 LA-925-009 Rev. A-1

- 11 -


References

Brown, T. M., 1996, Tank 241-%IO6 Push Mode Core Sampling andAnalysis Plan, WHC-SD-WM-TSAP-093, Rev. 0, Westinghouse Hanford Company, Richland, WA 99352.

Dukelow, G. T., J. W. Hunt, H. Babad, and J. E. Meacham, 1995, Tank Safety Screening Data

Company, Richland, WA 99352

Simpson, B. C., and D. J. McCain, 1995, Historical Model Evaluation Data Requirements,

Quality Objective, WHC-SD-WM-SP-004, Rev. 2, Westinghouse Hanford

WHC-SD-WM-DQO-011. Rev. 0. Westinghouse Hanford Company, Richland, WA 99352.

Turner, D. A., H. Babad, L. L. Buckley, and J. E. Meacham, 1995, Data Quality Objective to Support Resolution of the Organic Complexant Sa f ty Issue, WHC-SD-WM-DQO-006, Rev. 2, Westinghouse Hanford Company, Richland, WA 99352.

- 1 2 -


ATTACHMENT 1

U-106 SAMPLE BREAKDOWN

13

WHC-SD-WM-DP-191, REV. I

(I)

16

This page cannot be converted.

Please view the native document

for the original page.

WHC-SD-WM-DP.191,

r-

N 0 8

s ffl

8

ki

0) N 0 0

0) ffl

L a, Q 2 = Q m 3 1

.- ; . . : . .. . . - . . , . . . ~ ~~~~

. - ... l _ _ . _ . . .. .. . . . . . . . WHC-SD-WM-DP-191, REV./

8

v)


0 (0

20

9

\"C-SD-WM-DP-191, REV. I

21


01 b 0) N 0 0

0) rn k

L

I

t


k I 3 2 P

WHC-SB-WM-DP-191, REV. I

E' 8

? 8

0) N 0

0

WHC-SD-WM-DP-191, REV. /

9

WHC-SD-WM-DP-191. REV. I

1

3


PROGAGATING REACTIVE SYSTEM SCREENING TOOL

27

WHC-SD-WM-DP-191. REV. 1


28

Internal Westinghouse h

Hanford Company Memo

Phone: 373-2162 Date: September 9, 1996 Subject:

WHC4iD-WM-DP-191, REV. 1

From: Process. Chemistry & Statistics 75764-PCS96-091

RSST ADIABATIC CALORIMETRY OF U-106 SLUDGE SAMPLE

To :

R2-12

T6-09

cc: T. M. Brown

DBB File/LB

SUMMARY/CONCLUSIONS

Sample S96T004013 from segment 3 of a U-106 core was dried over low heat to remove 17.4% moisture, then size-reduced for a total of two complete RSST tests. Testing at approx. 7 barg overpressure yielded weak self-heat events, starting at 210°C to 225"C, and ending at a maximum of 4OO0C, to give a maximum AT o f 119@C, (6 is Pefined below), a maximum self-heat rate of 42"C/min, and a maximum 1.01~10' mole/gram o f noncondensible gas generation in duplicate testing. The maximum derived estimator of energy yield is given by 158x(specific heat capacity)tl6 J/gdry.

PERFORMANCE OF WORK

Work was performed according to WHC-SD-WM-TP-104, and calculations (attachments 1 to 3) were made as outlined in WHC-SD-WM-DTR-026. treatment and experimental data were logged in WHC-N-1014-1, pg. 78-85, and separate hardcopies of instrumental data were retained in WHC-N-1376-1 to back up electronic copies.

Sample

SAMPLE TREATMENT

There was one sample submitted for RSST analysis from the U-106 tank. Table 1 identifies the tests based on this sample and reports the various states of moisture/volatiles loss it experienced.

29 Hanford Operations and Ensinssrina Contractor for the US Department of Ensrpy

F. H . Steen Page 2 September 9, 1996

75764-PCS96-091

Table 1. Sample I d e n t i f i c a t i o n and Percent V o l a t i l e s From As-Received t o Various S t a t e s

a Weight l o s s from as-received t o as-prepared f o r RSST.

the 4rv weisht b a s i s .

low due t o condensate on sample i n s u l a t i o n sheath.

Weight l o s s by 222-S l a b reported results f o r as-del ivered t o as-dry --

Calculated from loss on reac t ion i n RSST and loss on prepara t ion . Usually

As rece ived , t h e sample was a wet, s t i c k y mater ia l t h a t needed t o be d r i e d and s ize-reduced i n o rder t o make i t s u i t a b l e f o r RSST a n a l y s i s . This i s done f o r two reasons:

a )

b)

To be a b l e t o g e t t h e sample i n t o t h e RSST sample vesse l , and

To prevent t h e evolut ion of l a r g e amounts of water , which c r e a t e s sample voids , tends t o push sample out o f the sample holder , and compromises t h e thermal i n s u l a t i o n around t h e holder .

The sample was d r i e d i n a beaker s i t t i n g on a hot p l a t e a t low heat f o r two days. RSST holder . n i t rogen (assured by f i rs t f lush ing the bomb w i t h n i t rogen twice before a f i n a l f i l l ) . 1 “ C / m i n. During Tes t 960815, i t was noted t h a t t h e hea ter c i r c u i t had s u f f e r e d a blown fuse, and so the r u n was canceled a t approximately 212’C before any se l f -hea t ing was apparent . a complete hea t ing program i n Test 960819. Another a l i q u o t of prepared sample was r u n i n Test 960826 t o provide a d u p l i c a t e experiment t o v e r i f y the results obtained i n the two previous tes ts .

A f t e r having been d r i e d , i t was ground up f o r dispensing i n t o the Loaded samples were run i n t h e RSST under approximately 7 barg

The s e l e c t e d heat ing r a t e f o r a l l runs was approximately

After r e p a i r s , t h e same sample was re run through

F. H. Steen Page 3 September 9, 1996

WHC-SD-WM-DP-191, REV. I 75764-PCS96-091

THERMAL RESULTS

Test 9 6 w

Figure I (attachment 1) illustrates the thermal response from the abortive test 960815, and these results are summarized In Table 3 . During the heatup, the slow heat rate achieved indicated a partial heater failure that was subsequently found to be a blown fuse, so the run was canceled at a temperature of approximately 212°C. before the run was canceled, therefore the sample was viewed as intact and , available for a reheat-when repairs could be made to the RSST heater circuit. bomb.

-960819

The sample aliquot from the previous test was reheated in this run. results are illustrated in Figures 1 and 2 (attachment 2) and are reported in Table 3 . Between approximately 150°C and 225"C, the instrumentally driven heat rate was perturbed and depressed by passage of the sample through an endothermic regime. By 225'C, though, it was clear that the sample had finished traversing this regime and was contributing internally generated heat. The heat rate gyrated somewhat, exciting more heater offset, but finally attained a weak 42 "C/min rate before maximum heater compensating power and apparent reactant exhaustion at 340°C.

The general shape of the temperature rate curve in Figure 2 (attachment 2) is more complex than would be obtained from a simple first order reaction. The hesitation and acceleration occurring at low self-heat rates could possibly be due to the melt of more oxidizer, consequently followed by increased oxidation rates. The sample in test 960819 did not show any indication of propagation.

The initial stages of the complex self-heating event (where changes in reactant stoichiometry are not yet significant) were crudely, collectively fitted by Arrhenius parameters and a fixed value of baseline heating rate. The base1 ine value of 0.8IoC/min was determined by fitting baseline data at temperatures below the endothermic regime. These parameters are 1 isted in Table 3 .

The $ factor appearing in the tables, and defined by the footnote, removes the effects of instrument heat capacity from the initial stage and final state results. It is by definition always greater than unity, but is likely to be less than 1.09 in value. To estimate its value, one needs to provide an estimate of the average heat capacity that the sample possesses while the exothermic reaction i s occurring because, unfortunately, a measured value is not currently available.

The exothermic energy content of the sample could be calculated (attachment 2) from the baseline-corrected temperature change if an estimated average

No self-heating response was evident

The sample aliquot was left sealed up and undisturbed in the RSST

The

.31

WHC-SD-WM-DP-191, REVI F. H . Steen Page 4 September 9 , 1996

75764-PCS96-091

r eac t ing heat capac i ty were ava i l ab le . The formula t h a t would be used would be : -

Bdry = 85.8(C;yt) + 7.45 -2- !3- (1)

This i s provided f o r t h e convenience of those w i l l i n g t o venture a heat capac i ty e s t ima te i n order t o obtain an e s t ima te of s p e c i f i c energy r e l ease .

Test 960826

Figures 1 and 2 (attachment 3) comprise t h e thermal response r e s u l t s f o r t h i s test . The sample began t o se l f -hea t a t 210°C, t r ave r s ing several weak se l f -hea t ing regimes before a t t a i n i n g a maximum 14"C/min, then exhausting i t s e l f a t 400°C. thermograms taken from wet samples (S96T003071).

The i n i t i a l s e l f -hea t ing responses were c o l l e c t i v e l y and crudely f i t t e d by Arrhenius parameters repor ted in Table 3 . For t h i s t e s t t he value of qi i s un l ike ly t o have exceeded 1 . l .

The energy re leased from t h e sample i n t h i s t e s t would be es t imated by:

The events observed were i n approximate agreement with DSC

i f an average r eac t ing s p e c i f i c heat capac i ty were a v a i l a b l e . of equat ions (1) and (2 ) would be:

The average

Mean&, = (122.0 f 51) (Z;yt) + (11.7 r 6) J g&Y (3)

GAS PRODUCTION RESULTS

Test 960815

Pressure evolu t ion d a t a and gas production c a l c u l a t i o n results appear i n Figures 1 through 3 (attachment 1) and Tables 2 and 4 below. (Note t h a t t h e dry-weight-basis r e s u l t s reported in t h e t a b l e a r e based on TGA r e s u l t s on o r ig ina l samples from the core segment, not on RSST sample prepara t ion r e s u l t s ) . Figure 3 (attachment 1) was ca l cu la t ed from t h e instrumental da t a a s suggested i n t h e foo tno te s t o Table 2 (see WHC-SD-WM-DTR-026). C lea r ly some noncondensible gas was generated by non-exothermic decomposition during t h i s tes t . a u x i l i a r y d a t a i n Table 2.

Table 4 compares these ca l cu la t ions w i t h t hose based on the

32


F. H. Steen 75764-PCS96-091 Page 5 September 9, 1996,

Test 960819

Relevant results appear in Figures 1, 3 and 4 (attachment 2) and Tables 2 and 4 below. Figure 4 (attachment 2) are based on near-steady-state temperature distributions in the RSST bomb, and give erroneous results when temperatures rise or fall rapidly. generated in this reheat test.

The total gas generated in the aliquot used in the first two tests is the sum of each individual test. between tests.

Test 960826

Data for this test are illustrated in Figures 1, 3 and 4 (attachment 3), and results are collected in Tables 2 and 4. condensate and noncondensible gas upon heatup. two calculation methods for the first two tests with the corresponding value in test 960826 suggests that the auxiliary data method gives more internally consistent results in this instance.

It should be pointed out that the calculations which yield

Nevertheless, Table 4 indicates that more gas was

Its value is affected by slow leakage in I

This aliquot also generated Comparing the sums from the

33

WHC-SD-WM-DP-191, REV. I F. H . Steen Page 6 September 9 , 1996.

75764-PCS96-091

Table 3 . U-106 Self-Heat Resul ts .

Initial K IC'lmln) at

'c = 1 +C,,w,/avg. C.:"%.'"-. C.. in Joule/gl°C, see attached calculations for each test

Tat

960815 0.2352 3 . 8 ~ 1 0 .

960819 0.2297 4 . 6 ~ 1 0 ~ I- PV = NRT.,,.,,.. . = i

'Noncondensibls gases only

2 4 . U-106 Gas Production Resul t s .

r- + I1 - R x T-*, F = IdPIdll. x Tdp. in absolute uni

34

WHC-SD-WM-DP-191, REV.

F. H. Steen Page 7 September 9, 1996.

75764-PCS96-091

Feel free to call i f you have any further questions on this matter.

&& D. 6. Bechtold, Principal Scientist Process Chemistry & Statistics

dl s

Attachments (3)

35


75764-PCS96-091

Attachment 1

Figures and Calculations for RSST Results o f Test 960815; Sample U-106, S96T004013

Consisting o f 7 Pages including this cover page


T e s t 960815; Sample U-106, S96T004013

Lo

gure 1

2

37

WHC-SD-W-DP-191, REV. 1

Tes t 960815; Sample U-106, S96T004013

0 0 N

--

0 n -- P

0 D

-- r

-- 0 n

m PI r.

( 6 . t e q ) a ~ n s s a l d

m

gure 2

3

38

WHC-SD-VJM-DP-191, REV. I

Test 960815; Sample U-106, S96T004013

igure 3

4

39


Test 960815; Sample U-106, S96T004013

WEIGHT LOSSES '

%H,O =: 44.57% (determined by separate analyses)

= (See Calculations Test 960819)

% (total volatiles) react = 100 - 8 solids

= 100 - --[lo0 1 - 100 t %(2)"""] 100

= (See Calculations Test 960819)

(4)

5

40

WHC-SD-WM-DP-19'1, REV. I

Test 960815; Sample U-106, S96T004013

s N TOTAL S S R C O :

at 300 to 35OoC

Bv Calculated GraDh: N, = 0.1096 mole, Ne = 0 . 1 1 3 6 mole, w F e P = 10.57 grams .

- - = 3.sx10-4 mole W,prep 10.57 =am prep

AN - 0 .1136 - 0.1096

[ % E o r r = 2. 8x10 -6 1 0 0 - 17 a 47 = 4 . 2x10 -6 mole W,drY 1 0 0 - 44.57 gram dry

at 300 to 36Ooc

6

41

WHC-SD-WM-DP-191, REV, I

T e s t 960815; Sample U-106, S96T004013

BY Auxi 1 i arv' Datq: Po = 6.9843 barg, To = 20.84 OC, P, = 7.2167 barg, T, = 21.62 O (

V = 335cm3, R = 83.14- mole O K

1 - 1 335 7.2167 + 1.01325 - 6.9843 t 1.01325 - --

10.57 83.14[ 21.62 + 273.15 20.84 + 273.15 ] = 2. 7x10-a*

g1m W e D

AN - .7x10-4 100 - 17 -47 = 4.0x10-4 mole Wp.. 100 - 44.57 gram dry

7

42

WHC-SD-VdM-DP-191, REV. I

75764-PCS96-091

Attachment 2

F igu res and Ca lcu la t i ons for RSST Resul ts of Test 960819; Sample U-106, S96T004013

Cons is t i ng o f 11 Pages i n c l u d i n g t h i s cover page

1

43

WHC-sa-WM-DP-191, REV. 1 Test 960819; Sample U-106, S96T004013

0 0 v

. . . )

I :

Lo 0 lc 0 In 0

0 0 0 0 0 0 m N c

( % ) J O (3 f I gure 1

2

44

WHC-SD-WM-DP-191, REV. I Test 960819; Sample U-106, S96T004013

0 0 V . . .. 0 0 m

C

E ... m 0 -

0

- m c 3 ' -

E P

- : 5 - + w N V a r ' r - D

( D o - - II . 0

I1 0 wl II

+ . v r n

m m L U Y ~

r

0

0 c

0 0 + 8 .-


Test 960819; Sample U-106, S96T004013

0 Ln 0 Lo 0

m m m m r. r. 0 Lo

o - ( 6 ~ e q ) a A n s s a i d

- r l

0 0 m

0 Lo

- N

--

0

0 - N --

0 Lo

-- r

0 0 -- r

_ _ 0 Lo

igure 3

4

46

.. .,-: ,, , .. ,~ - . . . - ..._ .... .. . , , . . - .. ,, .. .. ... I . . I . . -. ,. . - . -. . . ._ . . . . -. , - . . ._- _-

WHC-SD-VdM-DP-191, REV. 1

--

Test 960819; Sample U-106, S96T004013

0 -- In - m

0

- c1 .- 0

0 In

- m

D 0

a\ 0 0 v ... (.

1 .7 ,.t . .-. 5- -

gure 4

5

47


Test 960819; Sample U-106, S96T004013

WEIGHT LOSSFS

%H,OpIep = grossWet - grossprep gross wet - tareprep

= See Calculations Test 960815

%H,O&Y = See Calculations Test 960815

% (total volatiles)react = 100 - B solidsreact

= 100 - [IO0 - 17.471 [lo0 -8 .801 1 0 0

= 24.73%

6

48

WMC-SD-WM-DP-191, REV. I

Test 960819; Sample U-106, S96T004013

TOTAL SPFCIFI C NONCO NDENSIBLE GAS PRODUCTION:

or 325.0 - 276.0 = 49.0 min. from onset

BY Ca lcu la ted GraPh: Ni = 0.1129 mole, N, = 0.1178 mole, w F e p = 10.57 grams ,

AN = 0.1178 - 0.1129 = 4.6x10-4 mole - -am prep w,prep 10.57

(%Zrr= 3 . 8x10 -6 100 - 17.47 = .7x10 -6 mole W$Y 100 - 44.57 gram dry

at 218 t o 344’C or -7.0 t o +74 min from onset

7

49

WHC-SD-WM-DP-191, WEV.1

T e s t 960819; Sample U-106, S96T004013

Bv Auxiliarv.Data: Po = 7.2167 barg, To = 21.62 OC, P, = I .6934 barg, T, = 25.08 OC

V = 335cm3, R = 83.14- mole 'K

1 + 1.01325 - Po + 1.01325 $% = *;['Ti, + 273.15 To + 273.15

' - 1 335 7.6934 t 1.01325 - 7.2167 + 1.01325 - -- 10.57 83.14[ 25.08 + 273.15 21.62 + 273.15 ]

8

50


Test 960819; Sample U-106, S96T004013

SELF-HEAT PARAMETERS

&,,e:

Ti 225"C, ti = 2 7 6 . 0 m i n , Te 34OoC, t, = 3 4 0 . 0 m i n

B 5 0 . 8 l 0 C / m i n ,

ATtrue = @AT,,,, = @( [T, - Ti l - BLt, - t i l )

= +(E340 - 2251

= 6 6 3 . 2 " C

- 0 . 8 1 r 3 4 0 . 0 - 2 7 6 . 0 1 )

(AT)""" = 4 2 . 1 2 a t 319'C uncorr

or 3 3 0 . 9 - 2 7 6 . 0 = 5 4 . 9 m i n f r o m onset

9


Test 960819; Sample U-106, S96T004013

THERMAL KINE TIC PARAMFTERS:

For the i n i t i a l s t a g e o f t h e runaway, dT/dt v s 2 5 -1000/(Tt273.15) d a t a f o r temperatures between 225°C and 295°C and f o r dT/dt values g r e a t e r than 0.1 "C/min a r e leas t - squares f i t by t h e func t ion

1000 where Z = - T + 273.15 ' = -250+273.15

w i t h parameters E = 146 f 21 KJ/mole, K,, = 0.74 f 0.23 "C/min; and cons tan ts B = 0.81 "C/min and R = 8.3144 Q/mole/"K.

10

52

WHC-SD-WM-BP-191, REV. I

Test 960819; Sample U-106, S96T004013

SPECIFIC EXOTHFRMIC ENERGY RELEASE:

Neglecting PV work,

Q = ATtrue (wieact) = ATcorr@ ( w : ~ ~ ~ ~ ) -

(Wsreact ) ('z?) + whcph] (W;eaCt) (z;eact) ) (E;Ft) = AT,,,,

(Wsreact

= AT,^,,[ (wsreact) + whcPh]

(100 - %H20prep) [ loo + p%)react -,,a,t) + B] 100 (100 - %H,Odry) wsBrep

(CP* Bdry = ATcoxr

= 63,2 (100 - 17.47) 100 + (-8.80) (E;eact) 0.8368 (100 - 44.67) [ 100 + 10.511

= 85.8(Epyt) t 7.45 -!- g a y

11

53

WHC-SD-WA-DP-191, REV. I

75764-PCS96-091

Attachment 3

Figures and Calcula t ions f o r RSST Resul ts o f Test 960826; Sample U-106, S96T004013

Consis t ing o f 11 Pages including t h i s cover page

1

54

WHC-SD-VdM-DP-191, REV. I Test 960826; Sample U-106, S96T004013

0 0 u7

0 0 v

0 0

0 0

0 0 m N r

( % I (31 I

0

gure 1

L

55

Test 960826; Sample U-106, S96T004013

- 0 + G1 r

gure 2

3

56


T e s t 960826; Sample U-106, S965004013

P

O m

- m --

0 0

- m --

0 u1

- N

0 O I-.

0 m -- c

0 0

-- c

O m

igure 3

4

~ ~ ~ - ~ 5 ~ ~ - D P - I 91, REV. /

Test 960826; Sample U-106, S96T004013

.r 0 m m - - - P 0 0 0

m N

r r r c - - ?

0 0 0 0 0 0 0

(alou) N

gure 4

5

58

VVHC-SD-WM-DP-191, REV. I

Test 960826; Sample U-106, S96T004013

WEIGHT LOSSFS '

%H,OPIeP = grossWee - grossprep gross wet - tareP**P

= See Calculations Test 960815

%H,Odly = See Calculations Test 960815

gross - gross, %( %)Ieact = 100 gross, - tare,

- - 1o056.69 - 57.68 = -10.71% 57.68 - 48.44

% (total volatiles)reaCt = 100 - % solidsreact

= 100 - ---[lo0 1 - 100

= 100 - 1 [ 1 0 0 - 17.471 [lo0 -10.711 100

= 26.31%

6

53


Test 960826; Sample U-106, S96T004013

TOTAL SPECIFIC NONCON DENSIBLE GAS PRODU CTION:

at 337 to 396'C , ('):on - 0.031 - o.oo34 bar 9.24 min gDreV

(2) w.prep

or 289 - 216.5 = 72.5 min. to

297 - 216.5 = 80.5 min from onset

BY Calcula t e d Graoh:

N, = 0.1082 mole, Ne = 0.1122 mole, wPep = 9.24 grams

LE=- A N 100 - %HZOPrep = 4, 3x10-4 100 - 17.47 w,dry w F e p 100 - %H,O dry 100 - 44.57

at 171'C to 222'~ 01

170 - 216.5 = -46.5 min to

230 - 216.5 = 13.5 min from onset


Test 960826; Sample U-106, S96T004013

BY Auxi 1 iarv' Data: Po = 6.9873 barg, To = 25.62 'C, P, = 7.3562 barg, T, s 22.2 O c

v = 335cm3, R = 83.14- mole 'X

1 Po + 1.01325 To + 273.15

1 335 7.3562 + 1.01325 - 6.9873 + 1.01325 - -- - 9.24 83.14[ 22.2 + 273.15

= 6 , 7 6 x 1 0 - " ~ gram prep

100 - 44.57 gram dry

25.52 + 273.15 ]

- - AN - .7Gx10-4 1 0 0 - 17-47 = 1~01x10-3 mole

W,dry

8

61

WHC-SD-W-DP-191, REV. I

Test 960826; Sample U-106, S96T004013

SELF-HEAT PARAMETFRS ,

&true:

Ti = 21OoC, ti = 2 1 6 . 5 min, Te = 4OO0C, t, = 2 9 7 . 7 min

B = 0 .87"C/min ,

ATtrue = $AT,,,, = a( [T, - Til - B [t, - t i l )

= $( [400 - 2101 - 0 . 8 7 L 2 9 7 . 7 - 2 1 6 . 5 1 )

= $1190C

0 ..8368 (C;yt) loo+(-10.71) 1 0 0 9 , 2 4

= 1 4 . 0 2 at 373°C

or 2 9 2 . 4 - 2 1 6 . 5 = 7 5 . 9 min from onset

WHC-SD-WM-DP-191, REV. I Test 960826; Sample U-106, S96T004013

THERMAL KINFTIC P m :

For the initial stage of the runaway, dT/dt vs Z = -lOOO/(T+273.15) data for temperatures between 210°C and 330'C are least-squares fit by the function

E. - IZ - ZSOJ - dT = dt ' + K300e

(6) 1000 where Z = - 'Oo0 T + 273.15 ' "" = -300+273.15

with parameters E = 160 k 1 1 KJ/mole, K, ,, = 1.39 f 0.12 "C/min; and constants B = 0.88/"C/min and R = 8.3144 j/mole/"K.

10

63


Test 960826; Sample U-106, S96T004013

SPECIFIC M I J T H B C E N E R G Y c & :

Neglecting PV work,

= 119 (100 - 1 7 . 4 7 ) 100 + ( - 1 0 . 7 1 ) ( C ; y t ) - + 0.83681 (100 - 4 4 . 5 7 ) [ 100 9 . 2 4

= 158.2(zpL,eaCt) + 1 6 . 0 J g&Y

11

64


SAMPLE DATA SUMMARY

65

WC-SB-w-bP-IgI, REV. I

WHC-SO-WM-DP-191, REV. I Y)

68

'rNI-IC-SD-WM-DP-191, REV. I


71

WHC-SB-VWDP-191, REV, I

72

WHC-Sa-WM-DP-191, REV. I

WHC-SD-VdM-DP-191, REV. 1


76

WHC-SD-WM-DP-191, BEY I

77

WC-SD-WM-DP-191, REV. I

WHC-SD-V'JM-DP-191, REV. I

82

WHGSD-W-DP-191, REV. I

84

WHC-SD-VdM-DP-191, REV. I

WWCSD-%’M-DP-191, REV./

89


92

WHC-SD-MIMA-DP-191, REV. I

93

WWC-SD-WM-DP-191, REV. I


95


97

WWC-SD-VdFd-DP-191, REV. I

R

M * WHC-SD-WM-DP-I 91, REV. I

101.

0, WWC-SD-WM-DP-191, REV. I

102


103

WHC-SD-WM-DP-191, REV. J c *

m

WMC-SD-WtJ-DP-191, REV. I

WHC-SD-WB%I-DP-191, REV. f

WHC-SD-WIA-DP-191, REV. I

10’9

N N

0

L

-.

W'HC-SD-W!A-DP-199, REV. /

WWC-SD-WM-DP-191, REV. I

WHC-8D-Wed-DP-191, REV. I


PHOTOGRAPHS



112


113 @EST AVAILABLE COPY

WHC-SD-WIW-DP-191, REV. I

214 BEST AVAILABLE COPY


BEST AVAILABLE COPY


216 BEST AVAllABLE COPY

WHC-SD-WM-DP-191, REV.)

BEST AVAILABLE COPY


3.18 BEST AVAllABLf COPY

WMC-SD-WM-DP-191, REV I

119 BEST AVAILABLE COPY

WHC-SD-YJM-DP-191, REV. I

t

zZo BEST AVAILABLE COPY

WHC-SD-WM-DP-I 91, REV. I

BEST AVAILABLE COPY

WHC-SD-YdM-DP-191, REV. I

$22 BEST AVAILABLE COPY


U-106 EXTRUSION REPORTS

123



124

~


Y-106 Core 147 Seement # 1 Riser #19

Date: May 21, 1996 Sampler serial #: 95-0995:

Cask serial #: C-2001

Labcore # S96TOO2857

Sample #: 96-2 15

Logbook #: WHC-N- 1342

Notes:

* * * * Liner liquid: None observed. * *

Hot Cell Temp 80.2 degrees F. Humidity 28 I. Check weights: 20 gms = 20.00 grams 500 gms = 500.01 grams Dose rate through the drill string was 1.4 R/hr.

Sampler valve closed before and after cutting cables. Extruded sample and performed photography.

Sample information:

* Collected approximately 230 mLs of drainable liquid (Ll). The liquid was amber in color and clear. No solids were present other than those present in drainable liquid. Subsampled liquid in one jar.

Subsample information:

* Subsampled Liquids: Drainable Liquid Y-106 Core 147 See ment # 1 J a r # 10090 (250 mL jar size) -314.5 gram net weight

Notes: * A total of 314.5 grams of solids were collected. The dose rate through the drill string was 1.4 R/hr.

125

Date: Sampler serial # Sample # Cask serial # 70 Logbook # Labcore #

WHC-SD-WM-DP-191, REV, I

U-106 Core 147 Riser #u

May 21, 1996 94-318s 96-2 16

WHC-N- 1342 S96T002858

Notes:

* * * * Liner liquid None observed. * *

Hot Cell Temp 80.1 degrees F. Humidity 31 96. Check weights: 20 gms = 20.00 grams 500 gms = 500.01 grams Dose rate through the drill string was 1.4 Rhr.


Sample information:

* Collected approximately 90 mLs of drainable liquid (Ll). The liquid was dark brown in color and opaque. Extruded approximately 8 inches of solids. The solids were dark brown in color and the texture resembled a sludge slurry (D2). The solids were subsampled in one jar.


* Subsampled Liquids: Drainable Liquid Y-106 Core 147 -Jar # 10061 (125 mL jar size) -132.0 gram net weight

Subsampled Solids: Upper Half Solids

-Jar # 10201 (250 mL jar size) -201.2 gram net weight

*

Notes: * A total of 333.2 grams of liquid and solids were collected. The dose rate through the drill string was 1.4 Rhr.

. . .... .. .. .

WHC-SD-WM-DP-191, REV./

Date: May 20, 1996 Sampler serial # 95-112s Sample #: 96-217 Cask serial # 73 Logbook # WHC-N-1342 Labcore # S96T002811

Notes:




Sample information:

* No drainable liquid. Extruded approximately 17 inches of solids. The solids were dark brown in color and the texture resembled a sludge slurry @2). The solids were subsampled in half segments.


* Subsampled Solids: Upper Half Solids U-106 Jar # 10190 (250 mL jar size) -178.7 gram net weight

Subsampled Solids: Lower Half Solids Y-106 Core 147 See ment # 3 Riser 19; -Jar # 10191 (250 mL jar size) -200.8 gram net weight

*

Notes: * A total of 379.5 grams of solids were collected. The dose rate through the drill string was 1.5 Rhr.

127

WHC-SB-WM-DP-191, REV. 1

y-106 Core 147 Semn-

Date: May 21, 1996 Sampler serial #: 95-313s


Labcore # S96T002812

Sample #: 96-218

Logbook #: WHC-N-1342

Notes:


Hot Cell Temp 80.1 degrees F. Humidity 31 %. Check weights: 20 gms = 20.00 grams 500 gms = 500.02 grams Dose rate through the drill string was 1.4 Rhr.


Sample information:

* No drainable liquid. Extruded approximately 19 inches of solids. The solids were dark brown in color and the texture resembled a sludge slurry (D2). The solids were subsampled in half segments,


* Subsampled Solids: Upper Half Solids y-106 Core 147 S~wment # 4 Riser te; -Jar # 10194 (250 mL jar size) -211.3 gram net weight

* Subsampled Solids: Lower Half Solids Y-106 Core 147 Segment # 4 Riser 19: J a r # 10199 (250 mL. jar size) -213.8 gram net weight


WHC-SD-WM-DP-191, REV.1 Y-106 Core 147 Se- m

Date: May 20, 1996 Sampler serial #: 94-052s

Cask serial #: 1011-C

Labcore #: S96T0028 13

Sample #: 96-2 19

Logbook # WHC-N-1342

Notes:


Hot Cell Temp 79.5 degrees F. Humidity 28 %. Check weights: 20 gms = 20.00 grams 500 gms = 500.02 grams Dose rate through the drill string was 700 mR/hr.


Sample information:

* No drainable liquid. Extruded approximately 14 inches of solids. The lower portion of solids were 4 inches in length, dark brown in color and the texture resembled a wet salt (M3). The upper portion was 10 inches in length, dark brown in color and the texture resembled a sludge slurry @2). The solids were subsampled in half segments.


* Subsampled Solids: Upper Half Solids Cnre 147 Segment # 5 Riser 19;


Subsampled Solids: Lower Half Solids # 5 K i


*

Notes: * A total of 351.6 grams of solids were collected. The dose rate through the drill string was 700 mRlhr.

129

Date: May 15, 1996 Sampler serial # 95-062s

Cask serial #: 1010-C

Labcore # 896T002823

Sample # 96-220


Notes:


Hot Cell Temp 78.8 degrees F. Humidity 43 %. Check weights: 20 gms = 20.00 grams 500 gms = 500.01 grams Dose rate through the drill string was 1 Rhr.


Sample information:

* Collected approximately 80 m L s of drainable liquid 0.1). The liquid was amber in color and opaque. No solids were present. The liquid was subsampled in one jar.


* Subsampled Liquid: Drainable Liquid


U-106

Notes: * A total of 116.5 grams of liquid were collected. The dose rate through the drill string was 1 Rhr.

230

WHC-SD-WM-DP-191, REV. I Y-106 Core 148 Segment #2 Ris&

Date: May 20, 1996 Sampler serial # 95-1563

Cask serial # C-1016


Sample #: 96-22 1


Notes:




Sample information:

* Collected approximately 80 mLs of drainable liquid (Ll). The liquid was brown gray in color and opaque. Extruded approximately 9 inches of solids. The solids were light gray to dark brown in color and the texture resembled a sludge slurry @2). Subsampled solids in half segments.


* Subsampled Liquid: Drainable Liquid U-106 Core 1 4 U k e n ' -Jar # 10063 (125 mL jar size) -124.1 gram net weight

Subsampled Solids: Upper Half Solids


Subsampled Solids: Lower Half Solids Y-106 Core 148 Sez ment # 2 J a r # 10058 (125 mL jar size) -120.8 gram net weight

* Core 148 ' .

*


Notes: * A total of 349.2 grams of liquid and solids were collected. The dose rate through the drill string was 1.5 R/hr.

y-106 Core 148 Seeme nt #3 R&&

Date: May 20, 1996 Sampler serial # 95-134s

Caskserial # 61


Sample # 96-222

Logbook # WHC-N-1342

Notes:


Hot Cell Temp 79.8 degrees F. Humidity 28 96. Check weights: 20 gms = 20.00 grams 500 gms = 500.03 grams Dose rate through the drill string was 1500 mR/hr.


Sample information:

* No drainable liquid. Extruded approximately 18 inches of solids, The solids were dark brown in color and the texture resembled a wet sludge @3). Subsampled solids in half segments.


* Subsampled Solids: Upper Half Solids Y-106 V -Jar # 10180 (250 mL jar size) -202.8 gram net weight

Subsampled Solids: Lower Half Solids Y-106 Core 148 &pent # 3 Riser 2; -Jar # 10186 (250 mL jar size) -197.4 gram net weight

* .

*

Notes:

WHC-SD-WM-DP-191, REV. I * A total of 400.2 grams of solids were collected. The dose rate through the drill string

was 1500 mR/hr.

133

__y. . I 1 .,. .


Date: May 20, 1996 Sampler serial #: 95-064s Sample #: 96-223 Cask serial #: C-2008 Logbook #: WHC-N-1342 Labcore #: S96T0028 19

Notes:


Hot Cell Temp 79.6 degrees F. Humidity 28 %. Check weights: 20 gms = 20.00 grams 500 gms = 500.03 grams Dose rate through the drill string was 1.3 R/hr.


Sample information:

* No drainable liquid. Extruded approximately 19 inches of solids. The solids were dark brown in color and the texture resembled a wet sludge 0 3 ) . Subsampled solids in half segments.


* Subsampled Solids: Upper Half Solids Y-106 C w d 4 8 Se@ment # 4 -Jar # 10187 (250 mL jar size) -227.1 gram net weight

Subsampled Solids: Lower Half Solids g-106 Core 148 J a r # 10060 (125 mL jar size) -194.3 gram net weight

* # 4 R& ' .


a34

WHGSD-WM-DP-191, REV. I Core 148 Seement #5

Date: May 21, 1996 Sampler serial #: 95-3 11s


Labcore #: S96T002820

Sample #: 96-224

Logbook # WHC-N- 1342

Notes:


Hot Cell Temp 79.5 degrees F. Humidity 28 96. Check weights: 20 gms = 20.00 grams 500 gms = 500.01 grams Dose rate through the drill string was 700 mR/hr.


Sample information:

* No drainable liquid. Extruded approximately 11 inches of solids. The lower portion of solids were 5 inches in length, dark brown in color and the texture resembled a moist salt (M4). The upper portion was 6 inches in length, dark brown in color and the texture resembled a sludge slurry @2). Subsampled solids in half segments.


* Subsampled Solids: Upper Half Solids y-106 cIpre148 Seement # 5 R iser -Jar # 10093 (250 mL jar size) -188.0 gram net weight

Subsampled Solids: Lower Half Solids


* Core 148 -t # 5 Riser 2;

Notes: * A total of 322.3 grams of solids were collected. The dose rate through the drill string was 700 mRihr.


SAMPLE HANDLING

136



237

WHC-SD-WM-DP-191, REV, I worklistrpt Version 2.1 OS/ISDS Page: 1 05/14/96 16:48

LABCORE Data Entry Template for Worklist# 8675

Analyst: R Instrument: BAOOO Book# dd Method LO-160-103 RevlMod

Worklist Comment: U-106 C147 SEG # 3 RISER 19 EXTRUSION

GROUP PROJECT S TYPE SAMPLE# R A -------TEST------ MATRIX ACTUAL FOUND DL UNIT

1 INSTCHKOI EXTRUOOI SOLID 20 Y/A

2 INSTCHKOZ EXTRUDOI SOLID goo'@ N/A

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 CP)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

1 0 SAMPLE

I 1 SAMPLE

12 SAMPLE

S96TOO2811 0

S96T002811 0

S96T002811 0

S96TOO28ll 0

S96T002811 0

S96T002811 0

S96T002811 0 .

S96T002811 0

S96TOO2811 0

S96T002811 0

DLIQVOLI

OLIQUTOI

EST.G/ML

EXTRUOOI

LLIQWTOI

NOTEBOOK

SLOVOLOl

SLDUT-01

APPEAR01

ORGVOLOI

SOL10 N/A 0 rnL

SOLlD N/A 0 g

SOLID N/A 0 g/mL

SOLI0 N/A &D"/eff SOLID Y/A 0 g

SOLID N/A fl-1342 SOLID N/A p/A- mL

SOLID N/A 374.5 g

SOLID N/A T h ? $ SOLID N/A 0 mL

Final page for worklist # 8675

Data Entry Comments:

Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

238

WHC-SD-WM-DP-191, REV. 1 worklistrpt Version 2. I 05/15/95 Page: I 05/14/96 16:49

8676 LABCORE Data Entry Template for Worklist#

Analyst: Instrument: BAOOO Book# p& Method: LO-160-103 RevlMod ,&I


GROUP PROJECT S TYPE SAMPLE# R A - - - - - - -TEST--- - - - MATRIX ACTUAL FOUND DL UNIT

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U- IO6 (P)

96000641 U-106 (P)

96000641 U-106 ( P I

96000641 U-106 (P)

1 INSTCHKOI

2 INSTCHKOZ

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

I D SAMPLE

11 SAMPLE

1 2 SAMPLE

S96TOO2812 0

S96T002812 0

S96T002812 0

S96T002812 0

S96T002812 0

S96T002812 0

S96T002812 0

596T002812 0

S96T002812 0

S96T002812 0

EXTRUDOI

EXTRUDOl

DL IQVOLI

DLlQUTOl

EST.GIML

EXTRUDDI

LLlQUTOl

NOTEBOOK

SLDVOLOI

SLDUT-01

APPEAR01

ORGVOLOl

SOLID d o N I A

SOLID j# s@m N I A

SOLID N I A 0 mL T-

U SOLID NIA g

SOLID N I A F g

SOLID NIA tZl-/342

SOLID N/A 4a5. J SOLID NIA mL

SOLID N I A c d &


nalyst Signature Date


Units shown for QC (SPK & STO) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

139

WHC-SD-WM-DP-I 91, REV. P worklistrpt Version 2. I OS/I5/95 Page: I 0511 4/96 1650


Analyst: rfl Instrument: BAOOO Book# && ‘ Method LO-160-103 Rev/Mod

Worklist Comment: U-106 C147 SEG 5 RISER 19 EXTRUSION --P

GROUP PROJECT S TYPE SAMPLE# R A - - - - - - - T E S T - - - - - - MATRIX ACTUAL FOUND DL UNIT

96000641 U-106 ( P I

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000611 U-106 (P)

96000661 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

1 INSTCHKOl

2 lNSTCHKO2

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

S96T002813 0

S96T002813 0

S96T002813 0

S96T002813 0

S96T002813 0

S96T002813 0

S96T002813 0

S96T002813 0

S96T002813 0

S96T002813 0

EXTRUDOl

EXTRUDOl

DLIPVOLl

DLIQUTOl

EST.G/ML

EXTRUDOl

LLlPUTOl

MOTEBOOK

SLDVOLOl

SLDUT-01

APPEAR01

ORGVOLOI




140

worklisttpt Version 2.1 05/15/95 WC-SO-WM-DP-191, REV, 1 Page: 1 05/14/94 16.50 LABCORE Data Entry Template for Worklist# 8678

Analyst: '- ' r: BAOOO Book# ,/f/h


L

' Method LO-160-103 Rev/Mod


96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 ( P I

96000643 U-106 ( P I

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

1 INSTCHKOI

2 INSTCHKOZ

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

1 2 SAMPLE

S96TD02818 0

S96T002818 0

S96T002818 0

S96T002818 0

S96T002818 0

S96T002818 0

S96T002818 0

~ 9 6 ~ 0 0 2 8 1 8 o

S96TO02818 0

S96T002818 0

EXTRUDOI

EXTRUDOI

DLIQVOLI

DLIQUTOl

EST.G/ML

EXTRUDOl

LLlPuTOl

NOTEBOOK

SLDVOLOl

SLDUT-01

APPEAR01

ORCVOLDI

2 0 MLPo SOLID ' NIA

SQLlD 500 5@*03 N/A

0 mL SOLID N/A

SOLID NIA g

SOLID NIA g/mL

SOLID NIA M.z/k%6 SOLID NIA g

SOLID H/A d75%? SOLID N/A Nd SOLlD N/A yoo.a g

SOLID NIA CT 'eh

0 0

0

mL

SOLID N/A e mL


5-L/, Y6 Analyst Signature Analyst Signature Date

Data Entv Comments:


141

WHCSSD-WM-DP-191, REV. \ worklistpl Version 2.1 05/15/95 Page: 1 05/14/96 16:5l


Analyst: cc Instrument: BAOOO Book# /l@- Method: LO-160-103 RevlMod 80 Worklist Comment: U-106 C148 SEG # 4 RISER 2 EXTRUSION


96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

1 INSTCHKOl

2 INSTCHKOZ

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

I 1 SAMPLE

12 SAMPLE

S96T002819 0

S96T002819 0

S96T002819 0

S96TO02819 0

596T002819 0

S96T002819 0

S96T002819 0

S96T002819 0

S96T002819 0

S96T002819 0

EXTRUDOI

EXTRUDOl

DLIQVOLI

OLIQUTOI

EST .GlML

EXTRUDOl

L L I PUT01

NOTEBOOK

SLDVOLOl

SLDUT-01

APPEAR01

ORGVOLOI

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOL ID

SOLID

SOLID

SOLID

SOLID

SOLID


Data Entv Comments:


WHC4XMVM-DP-191, REV. worklistrpt Version 2.1 OS/I5/95 Page: I 05/14/96 1652

LABCORE Data Entry Template for Worklist# 8680 /I

Analyst: Instrument: BAOOO Book# .N8 Method: LO-160-103 RevlMod 80 Worklist Comment: U-106 C148 SEG # 5 RISER 2 EXTRUSION


96000643 U-106 ( P I

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

9600061t3 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

1 INSTCHKOI

2 INSTCHKOZ

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

S96T002820 0

S96T002820 0

596'1002820 0

S96T002820 0

S96TOO28ZO 0

S96T002820 0

S96T002820 0

S96TOO2820 0

S%TD02820 0

S96T002820 0

EXTRUDOI

EXTRUDOI

DLlPVOLl

DLIQUTOI

EST. G/ML

EXTRUDOI

LLlQUTOl

NOTEBOOK

SLDVOLOl

SLDYT-Dl

APPEAR01

ORGVOLOI

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID



Units shown for QC (SPK & STW) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code. 143

W~C-~~-WM-DP-191, REV. I worklistrpt Version 2.1 05/15/95 Page: 1 05/15/96 08:42

8688 LABCORE Data Entry Ternpilate for Worklist#

Analyst: re Instrument: BAOOO Book# /,, Method LO-160-103 RevIMod 80 Worklist Comment: U-106 C148 SEG 2 RISER 2 EXTRUSION

GROUP PROJECT

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 ( P I

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

S TYPE SAMPLE# R A -------TEST------ MATRIX ACTUAL FOUND DL UNIT

1 INSTCHKOI

2 INSTCHKOZ

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

S96T002824 0

S96T002824 0

5967002824 0

S96T002824 0

S96T002824 0

S96T002824 0

S96T002824 0

S96T002824 0

S96T002824 0

S96T002824 0

EXTRUDOI

EXTRUDOl

DLIQVOLl

DL lQWOl

EST.G/ML

EXTRUDOI

LLIQYTOl

N 0 T E B 0 0 K

SLDVOLOl

SLDUT-01

APPEAR01

ORGVOLOI

SOLID a doem N/A

SOLID ~900 ''''.Crd. N/A

SOLID N/A e mL

SOLID N/A LELL-cl SOLID N/A LSS g/mL

SOLID N/A -f@ SOLID N/A 8 g

SOLID N/A

SOLID N/A CbY/R/"fi

SOLID N/A 0 mL



Units shown for QC (SPK C? STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

a44

WHG-SD-WU-DP-I 91, REV. I worklisttpt Version 2. I 05/15/95 Page: I 05/20/96 10:38


Analyst: Instrument: BAOOO Book# da Method LO-160-103 Rev/Mod f i Worklist Comment: U-106 C147 SEG # 1 RISER 19 EXTRUSION

GROUP PROJECT ~~

S TYPE SAMPLE# R A -------TEST-----

1 INSTCHKOI EXTRUDOI

2 INSTCHKO2 EXTRUDOI

96000641 U- IO6 (P)

96000641 U-106 ( P I

96000641 U - I 0 6 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

IO SAMPLE

11 SAMPLE

I2 SAMPLE

S96T002857 0

S96TO02857 0

196'1002857 0

S96T002857 0

S96TOOP857 0

S96T002857 0

S96T002857 0

S96T002857 0

S96T002857 0

S96T002857 0

OLIQVOLI

DL IQUTOl

EST.G/ML

EXTRUDOI

LLiauToi

NOTEBOOK

SLDVOLOl

SLDUT - 01

APPEAR01

ORGVOLOI

MATRIX ACTUAL FOUND DL UNIT

SOLID a AO*'' N/A

SOLID 508 sOD'o/ MIA

SOLID NfA ss mL

SOLID N/A 3/4,5 9

SOLID N/A 1.3 Io g/mL

SOLID NIA

0 SOLID N/A g

SOLID N/A fl-132 SOLID N/A 04 mL

SOLID N/A 0 9

SOLID N/A GTf!"

SOLID N/A 0 mL



~ Units shown for OC DPK & SlD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, " - . - - .-n-l,Replicate Number, A = Aliquot Code.

945

Page: I WHG-SD-WM-DP-191, REV. I

worklistTt Version 2.1 05/15/95 05/20/96 10:39


Analyst: <L- IF: BAOOO Book# P/A Method: LO-160-103 Rev/Mod



96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

1 INSTCHKOl

2 INSTCHKO2

3 SAMPLE

4 SAMPLE

5 SAMPLE

6 SAMPLE

7 SAMPLE

8 SAMPLE

9 SAMPLE

10 SAMPLE

11 SAMPLE

12 SAMPLE

S96T002858 0

S96T002858 0

596'1002858 0

S96T002858 0

S96TD02858 0

S96T002858 0

896T002858 0

S96TO02858 0

S96T002858 0

S96T002858 0

EXTRUDOI

EXTRUDOI

DLIPVOLI

DLI QUTOl

EST .G/ML

EXTRUDOI

LLIQUTOI

NOTEBOOK

SLDVOLOl

SLDUT-01

APPEAR01

ORGVOLDI


Date s-22-96

Dofa Entry Comments:

Units shown for QC (SPK & STO) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

k.46


SAMPLE PREPARATIONS

147

WHC-SD-WM-DP-191, REV, ) irorklistrpt Version 2. I OSIlSl9S Page: 1

LABCORE Data Entry Template for Worklist# 9468 !W03DG 10:03

Instrument: FUSOl Book# yh T Analyst:

Method: LA-549- 14 1 RevIMod

Worklist Comment: TANK#U-l06,CORE 147,SEG 2UH,3UH,3LH,FOR FUSION01 RTS!

GROUP PROJECT

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 ( P I

96000641 U-106 (P)

96000641 U-106 ( P I

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

S TYPE SAMPLE# R A -------TEST-----

1 BLNK-PREP FUSlONOl

2 SAMPLE

3 SAMPLE

4 DUP

5 DUP

6 SAMPLE

7 SAMPLE

8 DUP

9 DUP

1 0 SAMPLE

11 SAMPLE

1 2 DUP

13 DUP

FUSION01

S 9 6 T d 3 0 7 9 0 -- DOSE-02

S96T003079 0 F

DOSE-02

S96T003080 0 F

DOSE-02

S96T003083 0 F

S 9 6 T 0 0 3 0 8 4 0 -w12 +.

S 9 6 T 0 0 3 0 8 d O - DOSE-d2

MATRIX ACTUAL FOUND DL UNIT

SOLID didha N/A g/L

SOLID N/A 9da9 g/L

SOLID N/A 6 mrad lhour

SOLID $@?d*o@z N/A g/L

SOLID 7< @ NIA mrad lhour

SOLI0 NIA dboa'J g/L

SOLID N/A % mrad/hour

SOLID 2.06a 3.0512 NIA g/L

SOLID 7s/ -iT( N/A mraWhour

SOLID N/A g/L

SOLID NIA mrad/hour

SOLID 13% r?*al?d N/A g/L

SOLID qc ?s- N/A mrad/hour


-?-/F-FL Anal* Signature Date

Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Lim$ S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

249

WHC-SD-WM-DP-191, REV. 1 worklistrpt pei-sion 2.1 OS/l5/9S Paae: 1

9469 06/03/96 10:OS LABCORE Data Entry Template for Worklist# I

Analyst: kQ f . Instrument: FUSOl Book# ,//k Method: LA-549-141 Rev/Mod f . Worltlist Comment: TANK#U-l06,CORE 147,SEG 4UH,4LH,5UH,SLH,FUSIONOl RTS!

UNIT GROUP PROJECT S TYPE SAMPLE# R A - - - - - - - T E S T - - - - - - MATRIX ACTUAL FOUND DL

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U- IO6 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U- IO6 ( P I

5f000641 U-106 (P)

96000641 U-106 (P)

1 BLNK-PREP FUSION01

2 SAMPLE

3 SAMPLE

4 DUP

5 DUP

6 SAMPLE

7 SAMPLE

8 DUP

9 DUP

10 SAMPLE

11 SAMPLE

12 DUP

13 DUP

14 SAMPLE

15 SAMPLE

16 DUP

17 DUP

S96T003081 0 F

DOSE-02

S’96T003081 0 F

DOSE-02

S96T003084 04 . zzl SY6T00308$0 DOSE-02 *41W

S96T003082 D F FUSION01

S96T003082 0 F

59610030 DOSE-02

S96T003085 0 F

S96T0030

FUSION01

SOLID I 6-2m N/A g/L

SOLID N/A zdzar(! g/L

SOLID N/A mradfhour

SOLID 2&?@ z.6sib N/A g/L

SOLID d < d c N/A mradfhour

SOLID N/A 2‘b4/& g/L

SOLID N/A L5 mradfhour

SOLID z&&$ ‘d6@ N/A g/L

SOLID kf hr N/A mrad/hour

SOLID N/A 50 mradfhour

SOLID 2hS6 2.6620 N/A g/L

SOLID x b N/A mradfhour

SOLID N/A C?b?b g/L

SOLID N/A 4g mrad/hour

SOLID

I< = Replicate Nunlher, A = Aliquot Code.

a50

wo&istrpt-Version 2.1 05/15/95 Page: 2 06/03/96 I0:05

9469 LABCORE Data Entry TempRate for Worklist# GROUP PROJECT S TYPE SAMPLE# R A -------TEST------ MATRIX ACTUAL FOUND DL UNIT



7 -/d6 Analyd Signature Date

Units shown for QC (SPK & STD) may not r@ect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

151

WHC-SD-WM-DP-191, REV. I worklistrpt Version 2. I 05/15/95 Page: I 06103196 1O:l 1


Analyst: Instrument: FUSOl Book #

Method LA-549-141 RevIMod f f i Worklit Comment: TANK#U-l06,CORE 148,SEG 2UH,2LH,3UH, FUSION01 RTS!


96000643 U-106 (P)

96000643 U-106 (P)

96000643 U- IO6 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

1 ELNK-PREP FUSlONOl

2 SAMPLE S96T003026 0 F

4 DUP S96T003026 0 F

5 DUP S96T003026 0 DOSE-02

6 SAMPLE S96T003029 0 F FUSION01

8 DUP S96T003029 0 F

9 DUP

1 0 SAMPLE S96T003030 0 F

11 ' SAMPLE 96T00303

12 DUP S96T003030 0 F FUSlONOl

13 DUP DOSE-02

SOLID 1 d s N/A g/L

SOLID N/A &&& g!L

SOLID N/A /x w mrad/hour

SOLID 4 . d q*bw N/A g/L 7-444

SOLID N/A mrad/hour

SOLID d*oi# ?J@ N/A g/L

SOLID a @ N/A rnrad/hour *& SOLID

SOLI0 N/A ?d mrad/hour

SOLID ?d@ N/A g/L

SOLID 90 90 N/A mrad/hour$ t?C

N/A 2 . 0 3 - , g/L

b d


Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Nuinher, R = Replicate Number, A = Aliquot Code.

152

WHC-SD-WM-DP-~~~, REV. I worklistrpt Version 2.1 OSIISl95 Page: I 06/03/96 1O:ll


Analyst: Instrument: FUSOl Book# & Method: LA-549-141 RevlMod FLa Worklist Comment: TANK#U-l06,CORE 148,SEG 3LH,4UH,4LH, FUSION01 RTS!


96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 ( P I

96000643 U-106 (P)

96000643 U,-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 CP)

1 BLNK-PREP FUSION01

2 SAMPLE S96TO03031 0 F FUSION01

3 & 2 ! f 2 ~ 9 6 T 0 0 3 0 3 1 0 DOSE-02 + . a 5 u

4 DUP S96T003031 0 F FUSION01

5 DUP %TO03031 0 DOSE-02 ,5054’ 4 , Z ~

6 SAMPLE S96T003032 0 F FUS I ON01

DOSE-02

8 DUP S96T003032 0 F FUSION01 I 5 2 0 b F 135’34

2e-4,

9 DUP S96T003032 0 DOSE-02

10 SAMPLE S96T003033 0 F FUSION01

DOSE-02

12 DUP S96T003033 0 F FUSION01

13 DUP DOSE-02


153

workiistrpt Version 06/03/96 10:13

2.1 OSfl5/95 WHC-SD-WM-DP-191, REV, I Page: 1


Analyst: 5 #=- Instrument: FUSOl Book# dfl Method LA-549-141 RevlMod F-0 Worklist Comment: TANWU-106,CORE 148,SEG 5UH,5LH, FUSION01 RTS!


96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

961100643 u-io6 (P)

1 BLNK-PREP FUSION01 SOLID

2 SAMPLE S96T003034 0 F 0.5Q43~-7 ,mQ-

SOLID m r a V h o u r N/A 5 3 SAMPLE 5961003034 0 DOSE-02

4 DUP S96T003034 0 F FUSIONDl SOLID dO1?2ga.&9 N/A g/L

5 DUP S961003034 0 DOSE-02 SOLID 50 % N/A m r a V h o u r a5&3 --+,amL

6 SAMPLE S96T003035 0 F FUSION01 SOLID N/A 3, J U 4 g/L

7 SAMPLE S961003035 0 DOSE-02 SOLID N/A 5 0 mrad/hour

Q- 5 3 boy-+. d a

FUSION01 SOLID 9. / 4 q flo%a N/A g/L .

DOSE42 SOLID 30 30 N/A mrad/hour

Final page for workl@j # 9476 n

Data Errtry Comments:

Units shown for QC (SPK & SlW) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

154

WHC-SD-WM-DP-191, REV. I worklisttpt Version 2.1 05/15/95 Page: 1 07/19/96 10:31


Analyst: q K Instrument: FUSOl Book #

Method: LA-549-141 RevIMod

Worklist Comment: U106 C147/148 COMP FUSION01 SKB


1 BLNK-PREP FUSION01 SOLID / 8,250 N/A g/L

96000641 U-106 (P) d 2 SAMPLE S961003878 0 F FUSION01 SOLID N/A 2,oW g/L

96000641 U-106 ( P I 3 SAMPLE S96T003878 0 F DOSE-02 SOLID N/A 80 mradfhour

96000641 U-106 (P) ~4 DUP S96T003878 0 F FUS ON01 SOLI0 7,068 2,DqA N/A g/L

96000641 U-106 (P) 5 DUP S96T003878 0 F DOSE-02 SOLID 80 80 NIA mradfhour

, G I 7 0 , JSO<

,5-a 30.+ .~f ;o-h

96000643 U-106 (P) 6 SAMPLE S96T003884 0 F SOLID N/A 2,051 g/L

96000643 U-106 (P) 7 SAMPLE 596153884 0 F DOSE-02 SOLID N/A 80 mrad/hour

96000643 U-106 (P) 8 OUP 5961003884 0 F FUSioNoi SOLID ~ , O G I a , a z r u/A g/L 5d7/Y+ , ,l ,-oJ

96000613 U-106 (P) 9 DUP S96T003884 0 F DOSE-02 SOLID 80 75 N/A mradfhour


Analyst Signature Date

Units shown for QC (SPK & SlD) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

155

Page: I WHC-SD-WM-DP-191, REV. I worklistrpt Version 2.1 OS/l5/95 06/03/96 10:08


Analyst: iscD Instrument: H2001 Book# ,&/k Method: LA-504-101 RevIMod €9 Worklit Comment: TANK#U-l06,CORE 147,SEG 2UH,3UH, H20DIGO1 RTS!


1 ELNK-PREP HZOOIGOl SOLID I 5 N/A g/L

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 ( P I

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

2 SAMPLE S96T003DR 0 W H2ODICOl SOLID N/A [nmoql g/L 0.509 18- I I 0 0 4 3 SAMPLE S96TO03093 0 DOSE-02 SOLID N/A g c mrad/hour

S96TD03093 0 W HZODlGOl SOLID !3.M\ 5. \\3 N/A g/L $%-,'I3 ,OOQ

0.5149 ----3,1009

5 DUP S96T003093 0 DOSE-02 SOLID y r yg N/A mracVhour

6 SAMPLE S96T003094 0 W H2ODlGOl SOLID N/A 5.149 g/L

7 SAMPLE 'S967003094 0 DOSE-02 SOLID NIA g5 mrad lhour

HZODIGOI SOLID 4j,lllc1 5.ozZ N/A g/L a DUP_ S96T003094 0 W

9 OUP 'S96T003094 0 DOSE-02 SOLID 7 ! 7s N/A mrad/hour 0.3522 -.+,a@


Units shown for QC (SPK & SlD) may not rgZect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A =Aliquot Code.

156

Puge: I worklistrpt Version 2. I OSNS195 06/03/96 1098

WHC-SO-WM-DP-191, REV. I


Analyst: Instrument: H2001 Book# ?& Method: LA-504-101 RevIMod 6-6 Worklist Comment: TANK#U-I06,CORE 147,SEG 3LH,4UH, H20DIGO1 RTS!

S TYPE SAMPLE# R A - - - - - - - T E S T - - - - - - MATRIX ACTUAL FOUND DL UNIT GROUP PROJECT

96000641 U-106 ( P I

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

1 BLNK-PREP HZODIGOI SOLID I * 100 N/A s/L

Z SAMPLE S96T003095 0 U HZODIGOI SOLID N/A S*ioq g/L o.s-10q +.loo$ 3 SAMPLE 'S96T00309.5 0 DOSE-02 SOLID N/A 80 mrad/hour

4 DUP S96T003095 0 U HZODIGOI SOLID 5.\09 5.109 %/A S/L

5 DUP S96T003095 0 DOSE42 SOLID v5 W/A myad/hour

0. glodf --+. \ o m

6 SAMPLE S96T003096 0 U HZODlGOl SOLID N/A s*fiq& S/L

7 SAMPLE S96T003096 0 DOSE-02 SOLID N/A 75 mradlhour *.~UG?-?<

E DUP S96T003096 0 U H20OIG01 SOLID 5409A 4,0% N/A g/L

9 DUP r5D7's96T063096 0 DOSE-02 SOLID 7c 75 N/A mradlhour a ioap

Final page for worklist # 94'72

7-/ P-36

*& 7-60 &70 * 39s @W -=? *b

Units shown for QC (SPK & SlD) may not reflect the actual units. DL = Detection Limit, S = Worklist SIot Number, R = Replicate Number, A = Aliquot Code.

157

worklistrpt Version 06/03/96 10:09

WWC-SO-WM-DP-191, REV. I 2.1 05/15l95 ' Page: 1


Analyst: bd) ,, kV7- Instrument: H2001 Book# ?/A Method LA-504-101 Rev/Mod E-b ~

Worklist Comment: TANWU-106,CORE 147,SEG 4LH,SUH,5LH, HZODIGOl RTS!

GROUP PROJECT S TYPE SAMPLE# R A -------TEST------ MATRIX ACTUAL FOUND OL UNIT

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 1P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

1 BLNK-PREP

2 SAMPLE S96T0030:;$

3 SAMPLE S96T003097 0 0.512.4~ 9

5 DUP S96T003097 0

6 SAMPLE S96T003098 0 U

7 SAMPLE S96T003098 0

8 DUP

9 OUP

12 OUP- S96T003099

13 OUP ' S96Td03099 0

0 . 5 / 9 6 -p i&

H2OOIGOl

HZODIGOl

DOSE-02

HZODIGOI

DOSE-02

H2OOlGOl

DOSE-02

H2ODIGOl

DOSE-02

H2OOIGOl

DOSE-02

H2OOIGOI

DOSE-02

SOLID ' e foO N/A g/L

SOLlD N/A s/n?q g I L

SOLID N/A 5d mrad/hour

SOL10 h!&! 5.M N/A g l L

SOLID yo Go N/A mrad/hour

SOLID N/A 5& g;L

SOLID N/A 5 6 mrad/hour

SOLID s*a6 5 . e NIA g/L

SOLID so 55 N/A mrad/hour

SOLID NIA 5.68L g/L

SOLlD N/A 25 mrad/hour

SOLID 6ogd !?.Ad NIA g/L

SOLID 2c 25 N/A m r a a h o u r


a49 9 &8Pt


~

~

Units Ahown for QC (SPK & SlD) may not refect the actual units. DL = Detection L W t , S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

WHC-SD-WM-DP-191, REV. I worklistrpt Version 2. I OS/I5/95 Page: I 06/03/96 10:16


Analyst: Instrument: H2001 Book# ?& Illethod LA-504-101 Rev/Mod

Worklist Comment: TANWU-106,CORE 148,SEG 2UH,2LH, H20DIG01 RTS!

GROUP PROJECT S TYPE SAMPLE# R A -------TEST------ MATRIX ACTUAL FOUND OL UNIT

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P I

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

1 BLNK-PREP HZODlGOl SOLID ! ,167) N/A g /L

g/L 2 SAMPLE S96T003028 0 U HZODIGOl SOLID N/A

DOSE-02 SOLID N/A '$? mrad/hour ,500+-3. [m

3 SAMPLE S96TO03028 0

4 DUP S96T003028 0 U HZODIGOl SOLI0 s@J 5. 027 N/A g/L

5 DUP S96T003028 0 SOLID '53 N/A m r a d / h o u r * Qc DOSE-02

6 SAMPLE S96T003043 0 U HZODlGOl SOLID W/A S-O?? g/L

6- ~ ~ ~ ~ r = = 7 . /crag

DOSE-02 SOLID NIA 50 mrad lhour

8 DUP S96T003043 0 U H2ODIG01 SOLID $h?? !?& N/A g/L

9 DUP SP6T003043 0 DOSE-02 SOLID 60 50 N/A mrad lhour # QL S O Z c / g - ? . [ N

4- Final page for worklist # 9479

/

Units shown for QC (SPK & Sm) may not rglect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

159

Page: 1 WHO-W-WM-DP-I~I, REV. I

warklistrpt Version 2.1 05/15/95 06/03/96 I0:18


Analyst: ,,#& Instrument: H2001 Book #

Method: LA-504-101 Rev/Mod E-0 Worklist Comment: TANK#U-l06,CORE 148,SEG 3UH,3LH, H20DIGO1 RTS!


1 BLNK-PREP H2ODlGOl SOLID I /a N/A g/L

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 CP)

96000643 U-IO6 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 ( P I

2 SAMPLE S96T003044 0 W H2ODlGOl SOLID N/A 5080 g/L

3 SAMPLE S96T003044 0 DOSE-02 SOLID N/A /@ 4 DUP S96T003044 0 W H2ODlGOl SOLID 5.080 s//q N/A g/L

5 DUP f i N Y Y S96T003044 -=? DOSE-02 SOLID 10 0 (m N/A mrad lhour

6 SAMPLE S96T003045 0 W H2ODlGOl SOLID N/A s.Oy0 g/L

mrad lhour I 5 0 8 8 ~ 4 . I ~ 4

.rf- QC t.uwc-.

mrad/hour DOSE-02 SOLID N/A foo , 5-040y -=7. Iuzlp 7 SAMPLE S96TDD3045 0

8 DUP S96TOD3045 0 U HZODlGOl SOLID soyo 2012 N/A g/L

SOLID fO& 100 N/A myad/hour ' Qc w DOSE-02


$6 Data Entry Comments:

~~

Units shown for QC (SPK & SlD) may not r@ect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

WHC~SID.WM-DP-lSI, REV. I worklistrpt Version 2.1 05/15/95 Page: I 06/03/96 I0:19


Analyst: Instrument: €12001 Book #

Method: LA-504-101 Rev/Mod '-0 Worklit Comment: TANK#U-l06,CORE 148,SEG 4UH,4LH, H20DIGOl RTS!

GROUP PROJECT S TYPE SAMPLE# R A - - - - - - - T E S T - - - - - - MATRIX ACTUAL FOUND DL UAlT

1 BLNK-PREP HZODlGOl SOLID / I 100 N/A g / l

96000643 U-106 (P) 2 SAMPLE S96TOO3046 0 W H2OOlGOl SOLID N/A s.022 g/L

96000643 U-106 (P) :S2?$'%003046 0 DOSE-02 SOLID N/A ?d mrad/hour --.mJ

96000643 U-106 (P) 4 DUP S96T003046 0 W HZODIGOI SOLID 5;/322 5.675 N/A g/L

96000643 U-106 (P) 5 DUP z 9 6 T 0 0 3 0 4 6 0 DOSE-02 SOLID 9o % N/A mrad/hour

HZODIGOI SOLID N/A f y y r g/L

DOSE-02 SOLID N/A 40 mrad/hour

96000643 ~ - 1 0 6 (P) a DUP S96T00 47 0 W HZODIGOI SOLID %?y8 soy? N/A g/L

96000643 U-106 (P) 9 5a DUP ''%2{'@ DOSE-02 SOLID '' 70 N/A mrad/hour

~~ ~~ ~~

Units shown for QC (SPK & SlD) may not reflet the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Nuinher, A = Aliquot Code.

A611

WHC-SD-WWDP-191, REV. I worklistrpt Version 2.1 05/15/95 Page: 1 06/03/96 10:19


Analyst: & Instrument: H2001 Book #

Method: LA-504-101 Rev/Mod

Worklist Comnient: TANWU-106,CORE 148,SEG 5UH,5LH, H20DIGO1 RTS!


1 BLNK-PREP H2ODlGOl SOLID 1 1 N/A g/L

96000643 U-106 (P) 2 SAMPLE S96T003048 0 U H20DlG01 SOLID N/A 5336 g/L

53363 9 .I c o r 96000643 U-106 (P) 3 SAMPLE " S96T003048 0 DOSE-02 SOLID N/A A 2 mrad/hour

96000643 U-106 (P) 4 DUP S96TOD3048 0 U H2ODIGOl SOLID 5< a36 1'7 N/A g/L

96000643 U-106 (P) 5 DUP S96T003048 0 DOSE-02 SOLID 2s 2 5 N/A mhad/hour

96000643 U-106 (P) 6 SAMPLE S96T003049 0 U HZODlGOl SOLID W/A 5n2q g/L

0.51278 -3 t l-

o-52aPr 3 , I L 96000643 U-106 (P) 7 SAMPLE S96T003049 0 DOSE-02 SOLID N/A 2 0 mrad/hour

96000643 u-io6 (P) a DUP S96T003049 0 U H20DIGOl SOLID SL29 5/31 N/A g/L

96000643 U-106 (P) 9 DUP S96T003049 0 DOSE-02 SOLID 20 U/A mrad/hour


7-28 -76 Analyst Signature Date

6 4 . C T O O '-3 && e 3 1 7 "p 304?

Units shown for QC (XPK B STD) may not rq7ect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

. C -r "d , WHGSD-WM-DP-191, WEV.1 worklistrpt Version 2.1 05/1S/95 Page: 1 07/19/96 10:35


Analyst: %K Instrument: H2001 Book #

Method: LA-504-101 Rev/Mod

Worklist Comment: U106 C147/148 COMP H20DIGOl/H20ICP01 SKB

S TYPE SMPLE# R A - - - - - - -TEST-- - - - - MATRIX ACTUAL FOUND DL UNIT GROUP PROJECT

1 BLNK-PREP HZODlGOl SOLID t o.ji?o N/A g/L

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000643 U-106 ( P I

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

2 SAMPLE S96T003879 0 U SOLID N/A q , z O O g/L

3 SAMPLE S96TOO3879 0 W DOSE-02 SOLID NIA 60 mrad/hour

4 DUP S961003879 0 W HZODIG01 SOLID C ~ O O S'(030 N/A g/L

5 OUP S96T003879 0 W DOSE42 SOLID 60 50 N/A m r a u h o u r --3 ,/*0A

HPOICPOI SOLID N/A 5./13 g/L

DOSE-02 \ SOLID N/A mradlhour

6 SAMPLE S961003880 0 I 52300 i i .0266

7 SAMPLE S96T003880 0 I

8 DUP S96T003880 0 I SOLID 5.163 4. N/A ~IL &;os0 '? / . O Z S 6

9 DUP

10 SAMPLE

11 SAMPLE

12 DUP

13 DUP

14 SAMPLE

15 SAMPLE

16 OUP

1 7 DUP

S961003880 0 I

9961003885 0 U ~ S380 4

S96T003885 0 W

S96TOD3885 0 U ' S ' B C - - +

5961003885 0 W

S96TOOP886 0 I 5 2 f O T / 4 2 6 6

S96TO03886 0 I

S96TO03886 0 I 5.182- $/.02.&6

S96T003886 0 I

DOSE-02'

HPODIGOl

DOSE-02 * 100 a

. /004 H2ODIG01

DOSE-02

HZOlCPOl

DOSE-02

HZOlCPOl

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

SOLID

Data Entry Comments: klAl & M - m < b h d

Units shown for QC (SPK & STO) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R - Replicate Number, A = Aliquot Code. 163

._ . , ”’

worklistrpt Version 07/19/96 10:35

2.1 05/15/95 WHC-SD-WM-DP-191, REV. 1

Page: 2

LABCORE Data Entry Template for Worklist# 10958 GROUP PROJECT S TYPE SAMPLE# R A -------TEST------ MATRIX ACTUAL FOUND DL UNIT


&; Analyst Sigdture Date


m 0 L 0 e- 2 I - 9 I Analyst Signature Date


. . I 3

wvrklistrpt Version 06/03/9610:06

Page: I WHC-SD-WM-DP-191, REV. t 2.1 05/15/9S

LABCORE Data Entry Template for Worklist# 9470 - Analyst: DCD Instrument: ACDOl Book #

Method LA-505-159 Rev/Mod b-0 Worklist Comment: TANWU-106,CORE 147,SEG 2UH,3UH,3LH,4UH,4LH,5UH,5LH, ACIDIG


96000641 U-106 (P)

96000641 U-106 (P)

96000641 U- IO6 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 ( P I

96000641 U-106 (P)

1 BLNK-PREP

2 STD-PREP

3 SAMPLE

4 SAMPLE

5 DUP

6 OUP

7 SPK

8 SPK

9 SAMPLE

1 0 SAMPLE

11 DUP

12 DUP

13 SAMPLE

1 4 SAMPLE

1 5 DUP

16 OUP

17 SPK

18 SPK

ACID1 GO1

ACID1001

S96T003086 0 A ACIDIGOl

S96T003082 0 DOSE-02 .2s10 4. . O S 6 e

S96T003086 0 A ACIDIGOI

.~50.39 -,as0 e S96TDD3086 0 DOSE-02


S96T00308 0 DOSE-02 .2qgo 4 . C l s O ~


S96T00308g 0 DOSE-02 . 2 S J 3 & , K O A


S96T0030# DOSE-02 *25!-3 2 . b a a


S96T003083 0 DOSE-02 . t s w 2 .osDs

S96T003088 0 A ACIOlGOl

*zf;zJ3 -3 , W O Q S96T003088 0 DOSE-02

S96TOD3088 0 A ACIDIGOI , LSJB 4 +,,=Q

S96T003088 0 DOSE-02

SOLID I , 050 N A g/L

SOLID + -;636 N/A -sft. &E 4% A@ 7/If&6

RX.7 -71, V%

SOLID N/A 5.0 200 g/L

SOLID N/A 110 mrad/hour

SOLID 5.0200 5.0060 N/A g/L

SOLID //E N/A mrad lhour 3.0, 73.F

SOLID +/A q.9600 N/A g j L

SOLlD /l/A 110 N/A mrad/haur

SOLID N/A 5.02bO g/L

SOLID N/A mrad lhour

SOLID 5 . ~ 2 1 ~ ) S.O~(OO N/A g i L

SOLID N/A 5 . J W O g/L

SOLID N/A 110 mrad/hour

SOLI0 5.1980 XW80 N/A g/L

SOLID h / A I 10 N/A mradlhour

Units shown for QC (SPK & STW) may not reflet the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

3.65

Page: 2 . . WQ8D=WM*DP-I91, REM I worklistrpt Version 2.1 OS/lS/PS 06/03/96 10:06

9470 LABCORE Data Entry Template for Worklist# ~- GKOUP PROJECT S TYPE SAMPLE# R A - - - - - - -TEST--- - - - MATRIX ACTUAL FOUND DL UNIT

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U- IO6 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U- IO6 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 ( P I

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

19 SAMPLE

2 0 SAMPLE

21 DUP

22 DUP

2 3 SAMPLE

2 4 SAMPLE

25 DUP

2 6 DUP

27 SAMPLE

2 8 SAMPLE

29 OUP

30 DUP

31 SAMPLE

32 SAMPLE

3 3 DUP

3 4 DUP

35 SPK

36 SPK

S96T003089 0 A ACIDlGOl ~ 2 5 s ~ ~ 3 .ossa

S96T003089 0 DOSE-02

S96T003089 0 A AClDIGOl

-ZY%3 -=? .osoP S96TO03089 0 DOSE-02

S96T003090 0 A ACID 1GOl

~2S3y 3 . b 5 0 & S96TO03O%D 0 DOSE-02


S96T003080 0 DOSE-02 *fis/ -7 .Q50 a

S96TO03091 0 A ACIDIGOl

LS7Y 3 .@ Q S96T00309q 0 DOSE-02

S96T003091 0 A ACID I GO1

-2530% --+ .os0 1 S96T003091 0 DOSE-02

S96T003092 0 A ACIDlGOl

S96T003092 0 A AClDIGOl . 2 5 0 1 3 3 . o S O Q S96T003092 0 DOSE-02

~96~003092 o A AClDlGOl

+2hsLilyg+.os0 Q S96T003092 0 DOSE-02

SOLID N/A 5.1100 g i L

SOLID N/A q5 mrad/hour

SOLID S.JJ00 4.99LO N/A g/L

SOLID 7s' 75 N I A mrad/hour

SOLID N/A 5*06%0 g/L

SOLID N/A 90 m r a d/ h o u r

SOLID 5.0b80 5 . l b W N/A g/L

SOLID 90 qo N/A mrad/hour

SOLID H/A 5.1480 g/L

SOLID N/A mrad lhaur

SOLID 5.I480 &Ob00 N/A g / ~

SOLID /no N/A mrad/hour

SOLID N/A 5 , a q o g/L

SOLID N I A 105 mrad/hour

SOLID 6.03qO 5.0020 N/A g/L

SOLID bs' bf j N/A mrad/hour

SOLID .'& 5,1120 N/A g/L

SOLID MA ( 0 5 N/A mrad/hour

Data Entv Comments:

Units shown for QC (SPK & STD) mny not rflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A =Aliquot Code.

,

166

. Page: 3 WC-SD-WM-DP-191, REV, I

wrklislrpt Version 2.1 05/15/95 06/03/96 10:06

I LABCORE Data Entry Template for Worklist# 9470 -. PLOUP PROJECT S TYPE SAMPLE# R A -------TEST------ MATRIX ACTUAL FOUND DL UNIT


Units shown for QC (SPK & STD) may not rejlect the actual wits. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A =Aliquot Code.

3.67

c

worklistpt Version 2. I 05/15/95 WHWD-WM-DP-19' 9 REV* 1 Page: 1 06/25/96 10:46 LABCORE Data Entry Template for Worklist# 9477

____ ~~ ~ _ _ _ _ _ _____

Book # W k c i l . Analyst: JiJ= Instrument: ACDOl

Method: LA-505-159 RevIMod

Worklist Comment: TANWU-106,CORE 148,SEG 2UH,2LH,3UH,3LH, ACIDIGOl RTS!

GROUP PROJECT S TYPE SAMPLE# R A -------TEST------ MATRIX ACTUAL FWND DL UNIT

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U- IO6 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U - I 0 6 (P)


1 BLNK-PREP ACIDIGOI

2 STD-PREP ACIDIGOl

3 SAMPLE S96T003027 0 A ACIDlGOl

/.3-/737----3 0.0e

I z/fSac,y- 4 0. m

4 SAMPLE S96T003027 0 DOSE-02

5 DUP S96T003027 0 A ACIDIGOI

6 DUP S96T003027 0 DOSE-02

7 SPK S96T003027 0 A ACIDlGOl

a SPK S96TO03027 0 DOSE-02

9 SAMPLE S96T003036 0 A ACIDIGOl

DOSE-02 , Z / l S - @ O . o ~

10 SAMPLE S96T003036 0

11 DUP S96T003036 0 A ACIDIGOI

2284f9 O . O S a 12 DUP S96T003036 0 DOSE-02

13 SPK S96TO03036 0 A AClDlGOl

t 2 8 3 G F C i . O @ 1 4 SPK S96T003036 0 DOSE-02

15 SAMPLE S96T003037 0 A ACIDlGOl

, 2 2 5 4 p O . 6 0 16 SAMPLE S96T003037 0 DOSE-02

17 DUP S96T003037 0 A AClDlGOl

DOSE-02 o.osi3

i a ' DUP 2 / b ' ~ 3 0 3 7 0

S O L S D % N/A g / L

SOLID N/A 4.3Ch g/L

SOLID N/A 7s mrad lhour

SOLID %34d q.w N/A g/L

SOLID 75 35 N/A mrad/hour

SOLID Jh q . b G q N/A g i L

SOLID !$A 80 N/A mrad/hour

SOLID N/A 4.336 g/L

SOLID N I A 80 SOLID 4.% 4.0qd N I A g/L

SOLID qn N I A mrad/hour

SOLID &$4 4.wa N/A g/L

SOLID v/fl N I A mrad/hour

mrad lhour

SOLID NIA 4.S8 g i L

SOLID NIA 50 mrad lhour

SOLID 4 3 8 4.378 N/A g/L

SOLID 50 N I A mrad lhour

Units shown for QC (SPK & S'lQimq not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

168

WOW-Wh4-DP-I 91, REV. I worklistrpt Version 2.1 05/15/95 Page: 2 06/25/96 10:46

LABCORE Data Entry Template for Worklist# 9477 GROUP PROJECT S TYPE SAMPLE# R A -------TEST------ MATRIX ACTUAL FOUND DL UNIT

96000643 U-106 (P) 1 9 SAMPLE S96T003038 0 A AClDlGOl SOLID N/A 4./= g/L

DOSE-02 SOLID N/A 30 mrad/haur

96000643 U-106 ( P I P I DUP S96T003038 0 A AClDlGOl SOLID y.1.a 7.&4 N/A g/L

96000643 U-106 (P) 22 DUP S96T003038 0 DOSE-02 SOLID 50 50 N/A mradlhour ,2032 r-4 0-0-


Units shown for QC (SPK & S l D ) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

$69

VVHC-SD-WM-DP-191, REV. / workiistrpt Version 2.1 05/15/95 Page: I 06/03/96 10:15

LABCORE Data Entry Ternpaate for Worklist# 9478

Analyst: 3 ,& Instrument: ACDOl Book #W&, l h / ~ ~ c Z . Method LA-505-159 RevIMod F-3 Worldiit Comment: TANWU-106,CORE 148,SEG 4UH,4LH,5UH,5LH, ACIDIGOI RTS!


1 BLNK-PREP

2 STD-PREP

96000643 U-106 (P) 3 SAMPLE S96T003039 0 A

2 4 87r-W OSD 96000643 U-106 (P) 4 SAMPLE S96T003039 0

96000643 U-106 (P) 5 DUP S96T003039 0 A

96000643 U-106 (P) 6 2 5 ’ g ~ s 9 6 ~ ~ ~ 3 ~ 3 9 DUP o -0.-

96000643 U-106 (P) S96TO03039 0 A

96000643 U-106 (P) 8 SPK S96T003039 0

96000643 U-106 (P) 9 SAMPLE S96T003040 0 A

96000643 U- IO6 ( P : 2 $ ~ 6 6 T O 0 3 0 4 0 0

96000643 U-106 (P) 11 DUP S96T003040 0 A

OOS=b

, 2 5 8 2 ~ O’m 96000643 U-106 (P) 12 DUP S96T003040 0

96000643 U-106 (P) 13 SPK S96T003040 0 A

96000643 U-106 (P) 14 SPK

96000643 U-106 (P) 15 SAMPLE S96T003041 0 A

96000643 U-106 (P3BK~5’!003041 0 & ,94335- -0.-

4- DOSE-02

AClDlGOl

ACIDlGOl

ACIDIGOI

00SE-02

ACIDlGOl

DOSE-02

AClDlGOl

DOSE-02

ACIDIGOI

DOSE-02

ACIDIGOl

DOSE-02

ACIDIGOI

DOSE-02

ACIDIGOl

96000643 U-106 (P) 17 DUP S96T003041 0 A ACIDlGOl

7/ Q 1 2 J h 2 $ - * 0 . 0 ~ 96000643 U-106 ( P ) 9 R x ? 6 T 0 0 3 0 4 1 0 DOSE-02


SOLID I * W/A g l L

SOLID Zo N/A bL ”..r/.,?‘ SOLID N/A 4.94 g/L

SOLID N/A IUT mrad lhour

SOLID 4.%q 5.0% NIA g l L

SOLID \OD 130 N/A mrad/hour

SOLID fd!A 5.12 N/A g/L

SOLID bl!q 11.7 N/A mrad/hour

SOLID N/A u . q r - g/L

mrad/hour SOLID N/A \aQw - em‘ SOLID q.?s- 5.1Ly N/A g/L

SOLID qn lh3 N/A mrad/hour

SOLID W]R 4.41PC N/A g/L

SOLID nk\ I.00 N/A mrad/hour

SOLID NIA 4.67- g/L

SOLID N/A 40 mrad lhour

SOLID 4.6’5 4.3.3Y N/A g/L

SOLID 40 (--!o N/A mrad/hour

Units shown for QC (SPK & STO) may not rejlect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

9.70

. . - WHC-SD-WM-DP-191, REX Page: 2 worklistrpt Version 2.1 OS/15/9S

06/03/96 I0:IS LABCORE Data Entry Template for Worklist# 9478

MATRIX ACTUAL FOUND DL UNIT GROUP PROJECT S TYPE SAMPLE# R A -------TEST------

96000643 U-106 (P) 19 SPK S96T003041 0 A ACIDIC01 SOLID h)!h 4.s2.2 N/A g/L

96000643 U-106 (P) 20 SPK S96T003041 0 DOSE-02 SOLID #,a 25 N/A mradJhour ~ ~ a 2 ~ 4 p .+ 0.-

96000643 U-106 (P) 21 SAMPLE S96T003042 D A ACIDIGOl SOLID NIA 4.078 g/L

96000643 U-106 (P) 22 SAMPLE S96T003042 0 Q.J03?? -7 0.0%

DOSE-02 SOLID N/A d”S mrad/hour

96000643 U-106 (P) 2 3 DUP S96T003042 0 A ACIDlGOl SOLID 4.038 4-%4 N/A g/L

96000643 U-106 (P) 2 4 DUP S96T003042 0 DOSE-02 SOLID 37 3 7 N/A mrad/haur

I i r m page Tor worKiist K

Date

Units shown for QC (SPK & STD) may not rqlect the actual units. DL = Detection Limit, S = Worklist Slot Nunrber, R = Replicate Number, A =Aliquot Code.

171

-

----_* -_ - _--4s-- - = - -~ WHC-SD-WM-DP-191, REV. I -- 491, REV./

worklistvt Version 2.1 05/15/95 Page: I 07/19/96 10:33

10957 LABCORE Data Entry Template for Worklist# w h c - / A Analyst: xd ,fqy Instrument: ACDOl Book# L/hc-a

Method LA-505-159 Rev/Mod

Worklist Comment: U106 C147/148 C O W ACIDIGOI SKB


96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000643 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

96000641 U-106 (P)

1 BLNK-PREP

2 STD-PREP

3 SAMPLE

4 SAMPLE

5 DUP

6 DUP

7 SPK

8 SPK

9 SAMPLE

1 0 SAMPLE

11 DUP

12 OUP

13 SPK

14 SPK

ACIDIGOI

ACIDlGOl

S96T003887 0 A ACID 1 GO1 . 2 -+ I O€OL

S96T003887 0 A DOSE-02

S96T003887 0 A DOSE-02

S96T003887 0 A ClDlGOl .26909 *OCQt

S96T003887 0 A OOSE-02

S96T003888 0 A DOSE-02

896T003888 0 A ACIDlGOl 1 2 7 3 0 9 0S.L

S96T003888 0 A DOSE-02

S96T003888 0 A ACIDIGOI * J ? l t ; - ” ) >osoL.

S96T003888 0 A DOSE-02

SOLID N/A % g/L -%K-

SOLI0 N/A 30 mrad lhaur T, /do

T SOLID r W 5 YDb N/A g/L

SOLID $6 N/A mrad/hour

SOLID 37%0 N/A g/L

SOLID NA qd N/A mrad/hour

SOLID N/A cr//n g l L

SOLID ‘! N A 6’2’&35- mrad/hour

SOLID 5 , N O rOL/hO N/A g i i

SOLID 85 80 NIA mrad lhour

SOLID h/a 5,430 N/A g l L

SOLID 44 95 N I A mradlhour

inal page for worklist # 10957

g- Z/-% Date

Units shown for QC (SPK & m) may not reflect the actual units. DL = Detection Limit, S = Worklist Slot Number, R = RepScate Number, A = Aliquot Code.

172


BULK DENSITY WORKLISTS

173

p7. .

,

z75 900 BUT T U ~ I L A T ~ N U zzz P0 :E0 96/PZ/98

WHC-SD-WM-OP-191, REV. I

..'

I

P76 ' . BEST AVAILABLE COPY 600 3tJl 1 W I l A l t l N t J 222 SB :Sa 96/b2/90


I

F9

.. Li u 0

/ /

200 &

-__I - I- --AL&" i. c _*" -- *. I-... . .--.A& . - ---- J u n . 24. 1996 4:53AM WHC 222s LAB ROOM 2F B A C K S I D E ' No. 2331 P. 5/14

* . .. k 0 c, C A s H .

/

' Jun. 24. 1996 4:55AM .WHC 222s LAB ROOM 2F BACKSIDE No. 2331 P. 8/14

I .. * * d) . '.c,

2 .

WHC-SD-WM-DP-191, REV. I.

I

Jun. 24. 1996 . 4:57AM ' WHC 2225 LAB ROOM 2F BACKSIDE' No. 2331 P. 11/14

* .

. .'

,

. - L. ..... L . .. .. .. . . . - . _. . . . . . .._____.__I -.__I_ i I_

Jun. 24. 1996 4:59AM . . WHC 222s LAB ROOM 2F BACKSIDE No. 2331 P. 14/14

. . . . .

1 . '

.. 0) u k! n .

..


I

$I, Q) Q)

M M M

-SD-WM-DP-191, REV.

WHC 0 In -SD-WM-DP-191, REV. I

3886

WC-SD-WM-DP-191, REV. I


Pk . Num

1 2 3 4 5 6 7 8 9 10

- - - - - - Ret Component Time Name - - - - - - - - - - - - - - - -_ 0.87 1.06 FLUORIDE 1.18 1.65 CHLORIDE 2.00 NITRITE 3.06 BROMIDE 3.40 NITRATE 5.14 PHOSPHATE 6.84 SULFATE 9.06 OXALATE

Concentration w/ml

0.000 28.509 0.000 59.253

Totals

435.281 234.781 1256.153 242.537 294.706 252.341

2803.562 . - - - - - - - - -

Height

- - - - - - - - - - - 333 2640 1038 3966 18141 5458 27306 1987 5217 2402

68487 - - _ - - _ _ - - - -

40

30

File: 96082481.d09 Sample: 896T003885 SPIKE

NITRATE I

I 1

NITRITE I 20 . I

us

10

Area B1. Code - - - - - - - - - - - - - - -

1752 2 13636 2 6028 2 19432 2 102395 2 35204 2 271084 2 23310 1 74251 1 45831 1 _ - - _ _ - _ - _ _ 592923

%Delta

- - - - - - - 1.60

0.81 0.00 0.11 -2.20 2.25 2.39 3.27

I l l I ~ I I I I ~ I I I l ~ I I I I ~ I I I I ~ I I I I ~ I I I I ~ I I I I ~ I I I I ~ I I I I ~

0 1 2 3 4 5 6 7 8 9 10

Minutes

394

O Y I I 1/96 A-0004-1

Page: 1 WHC-SD-WM-DP-191, REV. 1

085s


Analyst: Ghb’ Instrument: IC00 a‘ Book# 147k !?. c/ Method: LA-533-105 Rev/Mod ’?, \ Worklist Comment: @IC-01 FOR U-106 SAMPLES

S Type Sample# R A Test Matrix Group# Project

1 CCB @IC-QC QC

2 ccv @IC-QC QC

RTS!

3 BLNK-PREP @IC-01 SOLID

4 SAMPLE 896T003879 0 W @IC-01 SOLID 96000641 U-106 (P ) Analytes Requested: N03-02

896T003879 0 W @IC-01 SOLID

S96T003879 0 W @IC-01 SOLID

5 DUP

6 SPK



Analyst Signature Date

S = Worklist Slot Numher. R = Replicate Number, A = Aliquot Code.

375

Page: I worklistdata Version 1.0 05/1S/96 09/11/96 10:31 WHC-SD-WM-DP-191, REV. I

LABCORE Completed Wosklist Report for Worklist# 12421

Analyst: ea1 Instrument: IC01 Book# 1 q f l - d Method ( # 5 3 3 - \ 0 5 R e v / M o d 3 I Worldist Comment: @IC-01 FOR U-106 SAMPLES

Seq Type Sample# R A Test Matrix Actual Found D1,or Yield Unit

RTS!

1 CCB 0

1 CCB 0

1 CCB 0

1 CCB 0

L CCB 0

1 CCB 0

1 CCB 0

1 CCB 0

2 C N 0

2ccv 0

2 c c v 0

2 C N 0

2 ccv D

2 c c v 0

z c c v a 2 C N 0

3 BLNK-PREP 0

3 BLNK-PRBP 0

-3 BLNK-PREP 0

3 BLNK-PREP 0

3 BLNK-PREP 0

3 BLWK-PREP 0

3 BLNK-PRKP 0

3 BLNK-PREP 0

@IC-QC

aIC-QC

PIC-QC

PIC-QC

@IC-QC

OIC-QC

PIC-QC

PIC-QC

@IC-QC

OIC-QC

PIC-QC

*IC-QC

OIL.-QC

OIC-QC

P.YC-QC

PIC-QC

@IC-01

OIC-01 OTC-Ol

*IC-01

PIC-01

@IC-01

&IC-01

OIC-01

4 SAXPLE 996T003879 0 W @IC-01

5 DUP S96TOO3879 0 W @IC-01

6 SPK s96~00~87$ a w OIC-01.

F PC

CL QC NO= QC

BR QC

NO3 QC

PO4 QC

SO4 QC

O m E l QC

F QC

CL QC

NO1 QC

BR QC

NOS QC

PO4 QC

SO4 QC

OXALATE2 QC

8-02 SDLLD

a - 0 1 SOLID

ma-aa BR-01 SOLTD

NO3-QZ SOLID

PoI-oa SOLID so*-a2 S O L I 3

oxALA!wa SOLID

NO3-62 SOLID

NO3-01 SOLID

NO3-01 SQLID

1

1

1

1

1

1

1

1

5.90.01

7.90.01

3.42~01

5.89e01

5.94001

5.45s01

6.31-02

5.15a02

1 1 I

I

L 1 I

1

NIA 1.84et05

5.94.01

Comments Section:

Final page €or worklist# 12421

Analyst Signature Date Analyst Signature Date

Units shuwn,fur QC (BLKBKG) may not rqlect the uctual units.

376

worklistdata Version 1.0 OS/lS/PG WHC-SD-WM-DP-191, REV. \ Puge: 2 09/11/96 10:31

LABCORE Completed Worklist Report for Worklist# 12421 Seq Type Sample# R A Test Matrix Actual Found DL or Yield Unit

Units shown for QC (BLK/BKG) may not reflect the actual mi&.

3'97

08/27/96 A-0004-1

Page: 1 \"~-SD-WAA-DP-I~~, REV. I

LABCORE Data Entry Template for Worklist# 12421 19:17

Worklist Comment: @IC-Ol FOR U-LO6 SAMPLES

s Type Sample# R A Teat Matrix moup# Project '

RTS!

1 CCB @IC-QC QC

@IC-QC QC

3 SAMPLE S96T003879 0 W @ I C - 0 1 SOLID 9 6 0 0 0 6 4 1 U-106 (P ) cmj+p W m K

Analytea Requested: N03-02

4 DUP S96T003879 0 W @ I C - 0 1 SOLID

5 SPK S96T003879 0 W @ I C - 0 1 SOLID


HI03 '76 Date Analystsignature Date

lay2 / s g I C S J

/ -GSW 9/9/991r

~~ ~

S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

1 Worklist#: 12421 I -

=> => => => => =>

-

- ;eq

1 2 3 4 5 6

-

- Save (F4 )

?ype

:CB :cv 3LNK-PREP SAMPLE )UP 3PK

396T003879 396T003879 ;96T003879

Data File: 12421SP.CSV

Seq# I Data File 1 96090311.d11 2 96090311.d12 3 96090311.d13 4 96090311.d14 5 96090311.d15 6 96090311.d16

;ample Name I Dilution CNST. BLANK L49N9-C STD ?REP. BLANK 396T003879 396T003879 DUP 396T003879 SPIKE

1.00 101.00 1.00 41.00 41.00 41.00

Abort(Shift-F3) ListFiles(Shift-Fl) UploadFile(F8)

WHC-SD-WM-DP-191, REV. I TOC- TOTAL ORGANIC CARBON ANALYSIS REPORT

TICTOC REV 2.0

Sample: 896T03876 DUP Date: 08/31/96 Time: 16:39:28

Sample Size = 1 UL Dil Factor = 1 Blank ID # = Blank Value = 2.83 ug/minute C

Analyst : SL HOOD Min Readings = 22 Max Readings = 22 % Difference = 1 0

== Reading 1 2 3 4 5 6 7 8 9

10 11 12 13 14 15 16 17 18 19 20 21 22

---- ---- Analysis Time 0.51 1.01 1.51 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50

10.00 10.50 11.00

==== Coulometer = 46.00 78.70

111.40 ' 141.90 168.80 193.10 213.70

' 231.70 248.40 269.20 300.80 353.50 449.00 595.60 781.60 978.40

1169.40 1343.70 1499.30 1631.10 1748.10 1850.40

% Difference == 0.00

41.55 29.35 21.49 15.94 12.58 9.64 7.77 6.72 7.73 10.51 14.91 21.27 24.61 23.80 20.11 16.33 12.97 10.38 8.08 6.69 5.53

__- _--

USER INPUT BLANK VALUE BLANK VALUJ3 = 31.13181 micrograms carbon BLANK FACTOR = 31.13181 / 11.00064 = +2.8E+00 ug/min Carbon

SAMPLE RESULTS:

( 1850.4 - 31.11912 ) (1)/(1) (12) = +1.51613+02 Molar Carbon < e < < WARNING - BLANK VALUE EXCEEDS 1.5 ug/min Carbon!!!!!>>>>

- ( 1850.4 - 31.11912 ) (1)/(1) - +1.81933+03 g/L Carbon

Sample Run By: 5s .D8613 SL HOOD 00002

II orkhstdatu Version 1.0 05/15/96 WHC-SD-WM-DP-191, REV. I Page: 1 09/09/96 09:12

LABCORE Completed Worklist Report for Worklist# 12677

Analyst: dgg Instrument: CARE32 Book#

Method: Rev/Mod

Worklist Comment: U-106 TICTOC. RCJ

Seq Type Sample# R A Test Matrix Actual Found DLor Yield Unit

1 BLllK

1 BLNK

2 STD

2 s m

3 SAMPLE

3 SAMPLE

4 DUP

4 DUP

5 SPK

5 SPR

6 SlulSlE

6 SAMPLE

7 DUP

7 DOP

8 SPK

8 SPK S96T003051 0 @TTCIIOCl TOC-02 LIQUID l.OOB+Ol 5.27.+01 52.700 % R.oorr-ry

Final page for worklist# 12677

Analyst Signature Date q-7-FL

Analysqgnature Date

7’76

Units shownfor QC (BLK/BKG) m y not r@ect the actunl units.

WHC-SD-WM-DP-191, REV I 09/05/96 10:42 Page: I A-0004-I

LABCORE Data Entry Template for Worklist# 12677 f , I C

Analyst: trnment: CARB2 Book# nc J 2 N l L e F

Method: LA-342-100 Rev/Mod f i c 27Jn)fJ-C

Workliit Comment: U-106 TICTOC. RCJ

S Type Sample# R A Test Matrix Group# Project

. 1 BLNK @TICTOCl LIQUID

. 2 STD @TICTOCl LIQUID

3 SAMPLE SY6T002860 0 @TICTOCl LIQUID 96000643 U-106 ( P ) Analytes Requested: TIC-02 , TOC-02

4 DUP SY6T002860 0 @TICTOCl LIQUID

5 SPK S96T002860 0 @TICTOCl LIQUID

6 SAMPLE S96T003051 0 @TICTOCl LIQUID 96000643 U-106 ( P ) Analytes Requested: TIC-02 , TOC-02

7 DUP S96T003051 0 @TICTOCl LIQUID

8 SPK 596T003051 0 @TICTOCl LIQUID


' 9496 Date

Data Entry Comments.

5- 8-rc Analyst Signhture Date

777 S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code.

WHC-SD-WM-DP-191, EEV I

d

d 0

e 4

T, 0

a ? o x C m

I 6

I m

nm


C, .;! 2 !>

i I

BEST AVA

WHC-SD-WM-DP-194, RE\( I

WORKBOOK PAGE BLANK1

pg of Carbon = ICI-CZI

I \342100\OUT\rT12677.WB1

~ ,-\

i 4 3

09/09/96 09 00 09


I \34210O\OUT\TTi2677.WBi

781 09/09/96 09:OO:i 5


WORKBOOK PAGE: SAM3

pg of CarbonlmL = (CI-C2) * DF I SS pg of CarbonlmL for TIC = 5 if C l c C2 Ng of CarbonlmL for TOC = 40 if C1 < C2

782 09/09/96 09:00:21

WHC-SD-WM-DP-191, REV. 1 WORKBOOK PAGE DUP4

pg of CarbonlmL = (CI-CZ) * DF I SS pg of CarbonlmL for TIC = 5 if C1 c C2 pg of CarbonlmL for TOC 40 if C1 c C2

SAMPLE WBl REV 1 0 342100ML

09:00:27 783

09/09/96


WORKBOOK PAGE: SPIKE5

I

IPercent Spike Recovery = (C2 - C1 (SPK SS) i SS) i ((SPK CONC) * (SPK VOL)) * 1

QC Actual in pgImL = Spike Value (pgIrnL) QC Found in pgImL = (Percent Spike Recovery)*(QC Actual) I100

I \3421 oo\ounm 2 6 7 7 . ~ ~ 1

734 09/09/96 09 00 33


WORKBOOK PAGE SAM6

pg of CarbonlmL = (CI-C2) * DF I SS pg of CarbonlmL for TIC = 5 if C1 C2 pg of CarbonlmL for TOC = 40 if C1 C2

II NIA II

h TIC I TOC

I \3421oo \oun~~ i2677 WBI 0 9 / 0 9 / ~ " 09 00:39


WORKBOOK PAGE: DUP7

pg of CarbonlmL = (Cl-CZ) * DF I SS pg of CarbonlmL for TIC 5 if C1 c CZ pg of CarbonlmL for TOC = 40 if C1 e CZ

786 09/09/96 09:00'45

~rltiC-SD-VJM-DP-191, REV. 1 WORKBOOK PAGE: SPIKE8

Percent Spike Recovery = (C2 - C1 * (SPK SS) I SS) I ((SPK CONC) * (SPK VOL)) * 1

QC Actual in p g h L = Spike Value (pglrnL) QC Found in p g h L = (Percent Spike Recovery)’(PC Actual) I 100

09:00:51 787

09/09/96


T H I S PAGE WAS INTENTIONALLY LEFT BLANK



789



791



792



733



794



795



796



797

2 0.89 3 1.04 FLUORIDE 4 1.53 CHLORIDE 5 1.82 NITRITE 6 2.70 BROMIDE 7 3.08 NITRATE

6.0

5.0

4.0

0.000 111 579 2 63.518 1623 8671 2 0.32 82.559 1505 7918 1 -1.29 527.762 6452 37206 1 -1.44 584.835 4236 26936 2 0.87

1 NITRATE

SULFATE I

602.883 4753 35834 2 -2.94 8 4.43 PHOSPHATE 557.118 1387 15862 1 -1.12 9 5.76 SULFATE 647.585 3893 49161 1 -2.26 10 7.54 OXALATE 533.500 1863 31406 1 -1.78

- - - - - - - - - _ - - - _ - - - I - - - - - - - - - - - - - - - - - -

Totals 3599.761 25824 213573

File: 96071401.d02 Sample: CCV 142N9B

7.0 8.0 I NITRITE I

1 '.'Yi PHOSPHATE us 3.0 I F L " ~ ~ D

2.0

1 .o 0.0

-1 .o 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I I I A 1 1 1 1 1 1 1 1

0 1 2 3 4 5 6 7 8 9 10

Minutes

274

% -

07/19/96 08. AOW4-I

F / ~ P / c j o 76 D B O ~ C I 7 x 7 27 WHGSD-WM-DP-191, REV, I Page: 1

LABCORE Data Entry Template for Worklist# 10950 k-P 9-

Book# 5~gflN&

Method LA-505-WlI161 RevIMod 3- I Worklist Comment: ICP U-106 (FUSION)

W H - T G

S Type Samgle# R A Test Matrix &OUR# Project

1 Icv BICP-QC QC

2 ICB OICP-QC QC

3 LLS OICP-QC QC

4 ICSA BICP-QC QC

5 ICSAB PICP-QC QC

6 PREPBLKPdmUA OICP-PO1 SOLID

F OICP-FO1 SOLID @ P - B d L

-0 F @ICP-FOl SOLID 96000643 U-106 (P) Analytss Requested: AG-F-01 , AL-F-01 , AS-F-01 , B-F-01 , BA-F-01 ,

BE-F-01 , BI-F-01 , CA-F-01 , CD-F-01 , CE-F-01 , CO-F-01 , CR-F-01 , CU-F-01 , FE-F-01 , K-F-01 , LA-F-01 , LI-F-01 , MG-F-01 , MN-F-01 , MO-F-01 , NA-F-01 , ND-F-01 , NI-F-01 , P-F-01 , PB-F-01 , S-F-01 , SB-F-01 , SE-F-01 , SI-F-01 , SM-F-01 , SR-F-01 , TI-F-01 , TL-F-01 , U-F-01 , V-F-01 , ZN-F-01 , ZR-F-01 y p/,+'

P P h 4 f '

- Y OICP-FO1 SOLID

F OICP-FO1 SOLID

11 ccv OICP-QC QC

12 c m @ICP-QC QC

13 SERDIL S96T003029 0 F @ICP-FOl SOLID

14 SAMPLE S96T003029 0 F BICP-PO1 SOLID 96000643 U-106 (P) An8lyt.s Requested: AD-F-01 , AL-F-01 , AS-F-01 , B-F-01 , BA-F-01 ,

BE-F-01 , BI-F-01 , CA-F-01 , CD-F-01 , CE-F-01 , CO-F-01 , CR-F-01 , CU-F-01 , FE-F-01 , IC-F-01 , LA-F-01 , LI-F-01 ,

A/& . sfid# I f o p ~ 9 L i D ~ j - t ~ n e - 4 6 be m - f i . / ' c d b, 305 t

Data Enhy Comments:

I = / . / 7 e + Y LCC c,

F S = Workllst Slot Number, R = Replicate Number, A = Aliquot Code.

,t!& I Z.O/Y 4-

6 Z 6 Z ZLF 6 0 9 a I T . P t - 96/80/80

&4+H z o o m MOO2 PZ6-Oh! +++ RSnOH3NILS3M

WHC-SD-WM-DP-191, REV \ WORKBOOK PAGE SPIKE5

Percent Spike Recovery = (C2 - C l * (SPK SS) i SS) i ((SPK CONC) * (SPK VOL)) * 1

QC Actual in pgIrnL =Spike Value (pgIrnL) QC Found in pgImL = (Percent Spike Recovery)*(QC Actual) I100

I \342100\OUT\TT10805 WE1 08/19/96 11:12:55

Mi:iimum Detectable Activity Report WHCSD-WM-DP-191, REV. I Page : 3 Acquisition date : 23-AUG-1996 15:20:24 Sample ID : S96T3878-DUP

Nuclide

BE-7 NA-22 NA-24 K-40 CR-51 MN-54 CO- 5 6 CO-58 FE-59 SE-75 SR-85 Y-88 NB-94 ZRNB-95 RU-103 RURH- 10 6

CD-109 AG-11OM SN-113

SB-124 SB-125 TE- 12 5m 1-131 CS-134 BA-140 LA-140 CEPR- 14 4 EU-152 HG-203 TL-208 BI-212 PB-212 BI-214 PB-214 RA-224 RA-226 AC-228 TH-228 TH-229 PA-233 UTH-233 PA-234M TH-234 U-235 NP-239 PU-239 AM-241 AM-243

AG- 108111

TE-123m

Bckgnd Sum

2400. 134. 6.

131. 1827. 27. 34. 29. 19.

2100. 1250.

4. 72. 154. 1432. 464. 154.

2004. 2428. 2019. 2103. 475. 2373. 1945. 1912. 465. 881. 13.

2139. 6.

1951. 1987. 41.

2278. 482. 1914. 2363. 2684. 46.

1912. 1922. 1898. 2286. 33.

1629. 2666. 2092. 2077. 1771. 1785.

Energy (keV)

477.59 1274.53 1368.55 1460.75 320.08 834.83 846.76 810.78 1099.25 264.66 514.01 1836.06 871.09 724-18 497.08 621.93 722.94 88.03 657-76 391.69 159.00 602.73 427.89 109.27 364.48 604.70 537.31 1596.21 133.51 1408.01 279.20 277.36 727.18 238.63 609.31 351.92 240.99 186.10 911.21 84.37 88.47 312.17 245.34 1001.03 63.29 185.71 106.12 129.30 59.54 74.67

MDA (uCi/L)

6.45543+00 3.63183-01 8.17033-02 3.74493+00 4.23883+00 1.13723-01 1.28723-01 1.14833-01 2.14303-01 6.80893-01 5.32753-01 8.39363-02 1.92003-01 5.50113-01 5.85533-01 7.38323+00 2.64243-01 1.02613+01 9.28493-01 8.17043-01 3.26603-01 3.68883-01 2.06833+00 9.93893+01 5.94483-01 3.66723-01 1.82813+00 1.42323-01 4.84223+00 3.98503-01 4.89393-01 6.34473+00 1.8734E+00 8.81923-01 8.18443-01 2.34313+00 9.97313+00 9.70353+00 6.00893-01 3.08703+01 1.45653+00 1.10683+00 3.67663+02 2.50653-01 1.91883+01 5.87763-01 1.30813+00 4.15293+03 3.53153+00 8.33273-01


-30 .

0 - 0

P

0 - 0 m

0 - 0

(u

0 - 0

wl

WHC-SD-VdM-DP-191, REV.

1 a 3\ I E 3 3 0 E

P ) + J x + J r ( m C a l p1 n o n